 In 1791, she accompanied Potemkin to Saint Petersburg, where she was introduced to the nobility as his official mistress.In February 1796, Zofia arrived in Uman and announced her divorce from Jozef De Witte.In April 17, 1798, in Tulchyn, she remarried Stanisław Szczęsny Potocki, who had divorced his wife in order to marry her.