 On 5 July 2013, after Mallorca's top flight relegation, Pina signed a five-year deal with Villarreal CF, in turn promoted.He scored his first goal for his new team on 4 October, starting and netting the closer in a 3–0 home win over Granada CF.Pina was heavily played during his three-year spell at the "Estadio El Madrigal" by manager Marcelino Garcia Toral, whether as a starter or a replacement.