 Centerville has six land borders, including West Pike Run Township to the north, California to the east and northeast, West Brownsville to the east-southeast, East Bethlehem Township to the south-southwest, Deemston to the west, and Beallsville to the northwest.Across the Monongahela River in Fayette County to the south, Centerville runs adjacent with Brownsville and Luzerne Township.At the 2010 census there were 3,263 people, 1,359 households, and 971 families living in the borough.