 Van Hollebeke attended Stanford University, where she was named by the NCAA Honors Committee as a recipient of the NCAA Top VIII Award, and completed her senior year in 2007, majoring in human biology/pre-medicine.A three-year captain for the Cardinal, Van Hollebeke was an All-Pac-10 Conference First-Team selection, an NSCAA First-Team All-American Scholar Athlete, and was chosen as the ESPN Academic All-American of the Year.As a redshirt junior in 2006, she was one of two players in the conference to be selected in the All-Pac-10 First Team and the Pac-10 All-Academic First Team.