 She married Porphiry Grigoryevich Chebotaryov and had two children, Grigory and Valentina.Chebotaryova had earlier volunteered as a nurse during the Russo-Japanese War of 1904-1905 and had taken formal nursing courses at the time.Despite the fact that she did not move in the highest society circles, she was asked to join a group of women who nursed soldiers along with the Tsarina and her daughters at a Palace Hospital at Tsarskoye Selo.