 Empirically, this plot was notice as being a very good fit to the isotherm by Polanyi and also by deBoer and Zwikker but not pursued.This was due to criticism in the former case by Einstein and in the latter case by Brunauer.This flat surface equation may be used as a "standard curve" in the normal tradition of comparison curves, with the exception that the porous sample's early portion of the plot of formula_16 versus formula_17 acts as a self-standard.