 A pyroelectric nanogenerator is an energy harvesting device converting the external thermal energy into an electrical energy by using nano-structured pyroelectric materials.Usually, harvesting thermoelectric energy mainly relies on the Seebeck effect that utilizes a temperature difference between two ends of the device for driving the diffusion of charge carriers.However, in an environment that the temperature is spatially uniform without a gradient, such as in the outdoors, the Seebeck effect cannot be used to harvest thermal energy from a time-dependent temperature fluctuation.