The chemical traces of water have been found in this moon rock, called the Genesis Rock. The moon rock was collected by astronauts during the Apollo 15 mission in 1971 and is thought to be a piece of the moon's primordial crust. Image: NASA/Johnson Space Center
The discovery of "significant amounts" of water in moon rock samples collected by NASA's Apollo astronauts is challenging a longstanding theory about how the moon formed, scientists say.
Since the Apollo era, scientists have thought the moon came to be after a Mars-size object smashed into Earth early in the planet's history, generating a ring of debris that slowly coalesced over millions of years.
That process, scientists have said, should have flung away the water-forming element hydrogen into space.
But a new study suggests the accepted scenario is not possible given the amount of water found in moon rocks collected from the lunar surface in the early 1970s during the Apollo 15, 16 and 17 missions. By "water," the researchers don't mean liquid water, but hydroxyl, a chemical that includes the hydrogen and oxygen ingredients of water.
Those water-forming elements would have been on the moon all along, the scientist said. [Water on the Moon: The Search in Photos]
"I still think the impact scenario is the best formation scenario for the moon, but we need to reconcile the theory of hydrogen," study leader Hejiu Hui, an engineering researcher at the University of Notre Dame, told SPACE.com.
The results were published in Nature Geoscienceon Sunday (Feb. 17).
Water in moon's 'Genesis Rock'
Past studies have suggested water-forming elements came to the moon from outside sources long after the moon's crust cooled. The solar wind — a stream of particles emanating from the sun — as well as meteorites and comets were pegged as possible sources ofwater depositson the moon in recent studies.
But that explanation does not account for the amount of water found in the Apollo samples, the researchers stated in the new study.
Because they found hydroxyl deep inside each sampled rock, the scientists say they have eliminated the solar wind moon water explanation, because those particles can penetrate the surface only slightly. An impact from an asteroid or comet could push the hydrogen in further, but it would not be as pristine as the samples the researchers observed, because it would have melted from the heat of the asteroid collision.
Researchers probed samples from the late Apollo missions, including the famous "Genesis Rock" that was named for its advanced age of 4.5 billion years, about the same time the moon is thought to have formed.
Using an infrared spectrometer, the researchers found water embedded in the Genesis Rock, as well as all the Apollo samples they studied. This implies that the various landing sites of Apollo 15, 16 and 17 each had water present.
Hui's research flies in the face of past analyses of Apollo rocks that found they were very dry, except for a small bit of water attributed to the rock containers leaking when they were returned to Earth.
Past instruments that analyzed these samples, however, were not very sensitive. Hui said those older spectrometers had a sensitivity of around 50 parts per million (ppm), while his instruments were able to detect water at concentrations of about 6 ppm in anorthosites and 2.7 ppm in troctolites, which are both igneous rocks found in the moon's crust.
Troctolites form in the highlands as part of the moon's highland upper crust, and anorthosites are believed to be a part of the moon's "primary" crust, which solidified around the same time as other bodies in the solar system.