PJTE and combined PJTE plus JTE effects in molecular structures. There is a practically unlimited number of molecular systems for which the origin of their structural properties was revealed and/or rationalized based on the PJTE, or a combination of the PJTE and JTE. The latter stems from the fact that in any system with a JTE in the ground state the presence of a PJT active excited state is not excluded, and vice versa, the active excited state for the PJTE of the ground one may be degenerate, and hence JT active. Examples are shown, e.g., in Refs., including molecular systems like Na 3, C 3 H 3, C 4 X 4 (X= H, F, Cl, Br), CO 3, Si 4 R 4 (with R as large ligands), planar cyclic C n H n, all kind of coordination systems of transition metals, mixed-valence compounds, biological systems, origin of conformations, geometry of ligands' coordination, and others. Indeed, it is difficult to find a molecular system for which the PJTE implications are a priori excluded, which is understandable in view of the mentioned above unique role of the PJTE in such instabilities. Three methods to quench the PJTE have been documented: changing the electronic charge of the molecule, sandwiching the molecule with other ions and cyclic molecules, and manipulating the environment of the molecule.