Often when a photon is absorbed, the system is excited in the corresponding excited state, then it relaxes in an intermediate lower energy state, with a "non-radiative relaxation" (a relaxation that doesn't involve the emission of a photon, but e.g. involves the emission of vibrational energy) and then there is the emission of a photon with a lower energy than the absorbed one, because of the relaxation from the intermediate, lower energy state to the "ground state". Usually the strongest luminescence of the material is from the lower levels to the ground state. This process is called fluorescence. For instance, in semiconductors, most of the light emitted is at the frequency corresponding to the bandgap energy, i.e. from the bottom of the conduction band to the top of the valence band. In such systems, more light absorbed by the material, results in more electrons decaying non-radiatively to the lower states, and more luminescence in the emission wavelength.