Wouthuysen–Field coupling, or the Wouthuysen–Field effect, is a mechanism that couples the excitation temperature, also called the spin temperature, of neutral hydrogen to Lyman-alpha radiation. This coupling plays a role in producing a difference in the temperature of neutral hydrogen and the cosmic microwave background at the end of the Dark Ages and the beginning of the epoch of reionization. It is named for Siegfried Adolf Wouthuysen and George B. Field.