The fact that the Harvard classification of a star indicated its surface or photospheric temperature (or more precisely, its effective temperature) was not fully understood until after its development, though by the time the first Hertzsprung–Russell diagram was formulated (by 1914), this was generally suspected to be true. In the 1920s, the Indian physicist Meghnad Saha derived a theory of ionization by extending well-known ideas in physical chemistry pertaining to the dissociation of molecules to the ionization of atoms. First he applied it to the solar chromosphere, then to stellar spectra.