Apart from X-ray spectrometer technique, other older traditional methods are using the TouchStone and Acid to test the gold purity. But TouchStone and Acid are destructive testing - a tiny sample of gold is cut and then tested. The sample is rubbed on TouchStone and a drop of acid is put on it and the goldsmith observes the residue using a magnifying lens. Based on experience, gold smith can determine purity of sample.