For example, triethylamine and water are miscible in all proportions below 19 °C, but above this critical temperature, solutions of certain compositions separate into two phases at equilibrium with each other. This means that Δ Δ G mix is negative for mixing of the two phases below 19 °C and positive above this temperature. Therefore, Δ Δ S mix = − − ( ∂ ∂ Δ Δ G mix ∂ ∂ T ) P is negative for mixing of these two equilibrium phases. This is due to the formation of attractive hydrogen bonds between the two components that prevent random mixing. Triethylamine molecules cannot form hydrogen bonds with each other but only with water molecules, so in solution they remain associated to water molecules with loss of entropy. The mixing that occurs below 19 °C is due not to entropy but to the enthalpy of formation of the hydrogen bonds.