In 2011, Liu et al. showed that the NTE phenomenon originates from the existence of high pressure, small volume configurations with higher entropy, with their configurations present in the stable phase matrix through thermal fluctuations. They were able to predict both the colossal positive thermal expansion (In cerium) and zero and infinite negative thermal expansion (in Fe 3 Pt). Alternatively, large negative and positive thermal expansion may result from the design of internal microstructure.