A second phase transition is observed at T = 1170 K, in which an order–disorder transition occurs, as entropic effects dominate at high temperature. The high-temperature disordered phase is explained as a quasi-melted phase in which only the surface becomes disordered between 1170 K and the bulk melting temperature of 1337 K. This phase is not completely disordered, however, as this melting process allows the effects of the substrate interactions to become important again in determining the surface structure. This results in a recovery of the square (1×1) structure within the disordered phase and makes sense as at high temperatures the energy reduction allowed by the hexagonal reconstruction can be presumed to be less significant.