This is plotted in black in Fig. 2, for angles of incidence exceeding the critical angle, for three values of the refractive index. It can be seen that a refractive index of 1.45 is not enough to give a 45° phase difference, whereas a refractive index of 1.5 is enough (by a slim margin) to give a 45° phase difference at two angles of incidence: about 50.2° and 53.3°.