Although the second law of thermodynamics can determine the equilibrium state that a system will evolve to, and steady states in dissipative systems can sometimes be predicted, there exists no general rule to predict the time evolution of systems distanced from equilibrium, e.g. chaotic systems, if they do not approach an equilibrium state. Their predictability usually deteriorates with time and to quantify predictability, the rate of divergence of system trajectories in phase space can be measured (Kolmogorov–Sinai entropy, Lyapunov exponents).