The "anti" version of this effect occurs when the mechanism involves free radicals.
The "anti" version of this effect occurs when the mechanism involves free radicals. A typical example of the normal version is the production of 2-chloropropane when hydrogen chloride adds to propylene. Partially explained by Moris Selig Kharasch, it states that in addition reactions to unsymmetrical alkenes, the electron-rich component of the reagent adds to the carbon atom with fewer hydrogen atoms bound to it. FTP, what is this rule of chemistry named for the Russian who first stated it?
The "anti" version of this effect occurs when the mechanism involves free radicals.
Markovnikov’s rule