A reaction named for this man is implicated in the enzyme-catalyzed formation of a phenylalanine precursor from chorismate in plants. A variant of that reaction produces a gamma,delta-unsaturated ketone from an allylic acid, and is named for this man and Ireland. Another reaction named for this man is driven to completion by deprotonation of the product, and has an intramolecular variant named for Dieckmann. The first reaction is essentially irreversible due to the formation of a carbonyl double bond in contrast to a similar pericyclic [3,3] si
A reaction named for this man is implicated in the enzyme-catalyzed formation of a phenylalanine precursor from chorismate in plants. A variant of that reaction produces a gamma,delta-unsaturated ketone from an allylic acid, and is named for this man and Ireland. Another reaction named for this man is driven to completion by deprotonation of the product, and has an intramolecular variant named for Dieckmann. The first reaction is essentially irreversible due to the formation of a carbonyl double bond in contrast to a similar pericyclic [3,3] sigmatropic rearrangement named for Cope. FTP identify this chemist who gives his name to a rearrangement reaction and the production of a beta-keto ester from the condensation of two equivalents of an ester.
A reaction named for this man is implicated in the enzyme-catalyzed formation of a phenylalanine precursor from chorismate in plants.