These compounds react with an alpha-bromoester and zinc metal to form a beta-ketoester in the Blaise reaction. One of them reacts with an arene to give an aryl ketone in a reaction similar to the Friedel-Crafts acylation, called the Hoesch reaction. These non-ester functional groups produce a strong peak at 2250 inverse centimeters in an IR spectrum and can be reduced to aldehydes by DIBAL-H. They are hydrolyzed to form (*) amino acids in the second step of the Strecker synthesis. A polymer of this functional group forms a synthetic rubber commonly used in laboratory gloves. In a reaction named for Kolbe, these compounds are produced by reducing primary amides or by reacting alkyl halides with hydrogen cyanide. For 10 points name this funct
These compounds react with an alpha-bromoester and zinc metal to form a beta-ketoester in the Blaise reaction. One of them reacts with an arene to give an aryl ketone in a reaction similar to the Friedel-Crafts acylation, called the Hoesch reaction. These non-ester functional groups produce a strong peak at 2250 inverse centimeters in an IR spectrum and can be reduced to aldehydes by DIBAL-H. They are hydrolyzed to form (*) amino acids in the second step of the Strecker synthesis. A polymer of this functional group forms a synthetic rubber commonly used in laboratory gloves. In a reaction named for Kolbe, these compounds are produced by reducing primary amides or by reacting alkyl halides with hydrogen cyanide. For 10 points name this functional group containing a carbon triple bonded to nitrogen.
These compounds react with an alpha-bromoester and zinc metal to form a beta-ketoester in the Blaise reaction.