This reaction begins with nucleophilic addition by a hydroxide group, resulting in a namesake tetrahedral intermediate, which then reacts with another molecule of reactant in a disproportionation step.
This reaction is the progenitor and analogue of the metal alkoxide- catalyzed ester formation named for Tischenko and is similar in product to the Meerwein-Ponndorf-Verley reduction; it was recently discovered that lithium bromide is a near-ideal catalyst for all three, though the traditional form of this reaction uses a metal hydroxide as its catalyst. This reaction begins with nucleophilic addition by a hydroxide group, resulting in a namesake tetrahedral intermediate, which then reacts with another molecule of reactant in a disproportionation step. Formaldehyde can be used to increase the yield of one of this reaction's products in its "crossed" variant. If the reactant aldehyde has an alpha hydrogen, the aldol condensation accomplishes the same thins as this reaction faster. For ten points, name this reaction in which an acid and alcohol are formed from aldehydes, and which is named for an Italian chemist.
This reaction is the progenitor and analogue of the metal alkoxide- catalyzed ester formation named for Tischenko and is similar in product to the Meerwein-Ponndorf-Verley reduction; it was recently discovered that lithium bromide is a near-ideal catalyst for all three, though the traditional form of this reaction uses a metal hydroxide as its catalyst.
the {Cannizzaro} reaction