Asymmetric induction occurs with FelkinÂ–Anh selectivity or by a mechanism named for this process.
Asymmetric induction occurs with FelkinÂ–Anh selectivity or by a mechanism named for this process. This process can explain why, all else equal, the stability constant beta-1,1 ("beta one one") is usually greater than beta-1,2 ("beta one two"). The effect named for this process explains why siderophores (sih-DER-oh-fores) have such low K-sub-m values. The chirality of propeller compounds formed by this process is labeled lambda or delta. Complexometric titrations rely on titrants that can effect this process, which, unusually, is controlled by entropy. EthyleneÂ·diÂ·amine, or "en," and its tetra-acetic ("tetra"-ah-SEE-tik) acid derivative EÂ·DÂ·TÂ·A facilitate this process because they're polydentate. For 10 points, what process, in which metals are surrounded by a clawlike ligand, is o⧔en used to treat heavy metal poisoning?
Asymmetric induction occurs with FelkinÂ–Anh selectivity or by a mechanism named for this process.
chelation [or chelation control; or the chelate effect; prompt on "binding" to metals or similar answers; prompt on "coordination"]