The namesake of this reaction also developed a reaction to convert N-oxides of tertiary amines to an alkene using mCPBA ("m-C-P-B-A") through his namesake elimination.
It's not the aldol reaction, but the fact that this reaction proceeds through a chair-like transition state was elucidated in the Doering-Roth ("during-roth") experiment. A common route for synthesizing acyl pyrÂ·rolÂ·idines couples the aza-variant of this reaction with a Mannich ("manic") reaction. Delta-epsilon unsaturated carbonyls are generated a ter a keto-enol tautÂ·oÂ·merÂ·izÂ·ation in the oxy-variant of this reaction. A single peak is observed on an H-NMR spectrum of bullvalene ("bull"-VAY-leen) because of  luxionality ( luk-shon-AL-ity) due to degenerate occurrences of this reaction. The namesake of this reaction also developed a reaction to convert N-oxides of tertiary amines to an alkene using mCPBA ("m-C-P-B-A") through his namesake elimination. This pericyclic reaction involves the heat-catalyzed isomerization of one- ve-diÂ·enes. For 10 points, name this reaction, which like the Claisen rearrangement exempli es a three- ve sigmatropic reaction.
It's not the aldol reaction, but the fact that this reaction proceeds through a chair-like transition state was elucidated in the Doering-Roth ("during-roth") experiment.
Cope rearrangement [do not accept "Cope elimination"]