The release of nitrogen gas from AIBN is coupled to the synthesis of two of these compounds.
The McConnell stacking rule for these compounds uses the so-called */non-* ("star non star") rule to predict if their orbitals will be disjoint or nondisjoint. The Beckwith-Houk transition state model explains why the 5-hexenyl ring closure of these compounds is exo. The rate of rearrangement of these compounds is listed in an horlogerie. Many reactions involving these compounds have an order of 1.5 with respect to them. Geminate recombination limits the reactivity of these compounds according to their namesake cage mechanism. Sigma donors and acceptors on these compounds will synergistically reduce their overall energy. These compounds form stable adducts with nitroso or nitrone groups. One of these compounds with a propeller-like structure is formed by reacting trityl chloride with (*) silver, and turns a darker shade of yellow when exposed to air. By definition, these compounds have a SOMO. The release of nitrogen gas from AIBN is coupled to the synthesis of two of these compounds. Anti-Markovnikov addition of hydrogen bromide across a double bond forms one of them in the first step. For 10 points, name these paramagnetic compounds which have an odd number of electrons.
The McConnell stacking rule for these compounds uses the so-called */non-* ("star non star") rule to predict if their orbitals will be disjoint or nondisjoint.
free radicals [or biradicals]