When this theory is applied to systems in solution, solvent cage effects must be taken into account.
In order to fix a defect with this theory, the "harpoon mechanism" has been proposed for the reaction between potassium and diatomic bromine. One constant involved in this theory is equal to Avogadro's constant times the cross section times the square root of 8 times the Boltzmann constant times temperature over pi times the reduced mass. When this theory is applied to systems in solution, solvent cage effects must be taken into account. In its fundamental equation, the frequency Z is multiplied by the steric factor and e to the negative activation energy over RT. Proposed by William Lewis and Max Trautz, it holds that the activation energy barrier will be overcome if the namesake angular-momentum-preserving phenomenon is "successful." For 10 points, name this theory that explains reaction rates in terms of reactant molecules hitting each other.
In order to fix a defect with this theory, the "harpoon mechanism" has been proposed for the reaction between potassium and diatomic bromine.
collision theory