The energy of charge transfer from a ligand to the metal it coordinates is proportional to the difference between their values for the optical variety of this quantity.
The energy of charge transfer from a ligand to the metal it coordinates is proportional to the difference between their values for the optical variety of this quantity. The principle of equalization of this quantity posited by Sanderson states that its value for a group is the geometric mean of the values for each individual atom. Determination of it for orbitals was undertaken by Hinze and Jaffe. It has been posited to be proportional to the effective nuclear charge divided by the square of the covalent radius, defined as the additional strength of a heteronuclear bond, and defined as the average of the ionization energy and electron affinity. FTP name this quantity given various definitions by Allred and Rochow, Mulliken, and Pauling, which gives a numerical value to how much an atom likes electrons.
The energy of charge transfer from a ligand to the metal it coordinates is proportional to the difference between their values for the optical variety of this quantity.
{electronegativity}