Its failure was recognized by Einstein, who noted that for a quantum harmonic oscillator at energies of less than kT, the Bose-Einstein statistics must be applied rather than the Maxwell-Boltzmann distribution.
Its failure was recognized by Einstein, who noted that for a quantum harmonic oscillator at energies of less than kT, the Bose-Einstein statistics must be applied rather than the Maxwell-Boltzmann distribution. It was improved yet again by treating the quantum oscillators as collective modes called phonons, a theory advanced by Debye. Derivable from the equipartition theorem, the total energy of an atom is 3kT, which is then multiplied by Avogadro's number. FTP, name this law which says that the product of atomic mass and heat capacity is approximately constant.
Its failure was recognized by Einstein, who noted that for a quantum harmonic oscillator at energies of less than kT, the Bose-Einstein statistics must be applied rather than the Maxwell-Boltzmann distribution.
law of Dulong and Petit