Chen et al. used a dimeric boron species and a rhodium catalyst to form terminal organoboranes by reacting a bond between these two atoms.
Chen et al. used a dimeric boron species and a rhodium catalyst to form terminal organoboranes by reacting a bond between these two atoms. Periana et al. used sulfuric acid and a platinum II catalyst to react this type of bond and produce methyl bisulphate. That reaction was an improvement on one using stoichiometric platinum IV to react a bond between these two atoms and produce methanol as developed by Shilov. In a fraud case at Columbia University, falsified NMR spectra supposedly showed reactions involving this type of bond in papers by Bengu Sezen, who had worked in the lab of Dalibor Sames. When present in a ligand, this type of bond can interact with the metal atom in an (*) agostic interaction. Along with a carbon-nitrogen bond, a bond between these two atoms is broken in a reaction which uses aqueous silver oxide and methyl iodide to form a tertiary amine leaving group, as developed by Hofmann. A bond of this type on an aromatic ring is replaced as the net result of a Friedel-Crafts alkylation, and bonds of this type are formed when using Raney Nickel to react an alkene. For 10 points, name this type of bond formed when converting unsaturated to saturated fats, the only type of bond found in methane.
Chen et al. used a dimeric boron species and a rhodium catalyst to form terminal organoboranes by reacting a bond between these two atoms.
C-H bond [or carbon-hydrogen bond. Order does not matter. Prompt on “sigma” bond, “single” bond, etc]