MIDA can be used as a protecting group for one example of this type of reaction. One reaction of this type is typically carried out using an inorganic base such as cesium carbonate or potassium carbonate alongside a tetrakis-triphenylphosphine complex. Secondary and tertiary amines can be synthesized using one of these reactions named for Buchwald and Hartwig. One of these reactions replaces the usual central step with a migratory insertion followed by a beta-hydride elimination. A Grignard reagent is used in one of these reactions named for Kumada, while other examples using tin and zinc catalysts are named for Stille and Negishi. The catalytic cycle of these reactions consists of a reductive elimination, an oxidative addition, and a trans
MIDA can be used as a protecting group for one example of this type of reaction. One reaction of this type is typically carried out using an inorganic base such as cesium carbonate or potassium carbonate alongside a tetrakis-triphenylphosphine complex. Secondary and tertiary amines can be synthesized using one of these reactions named for Buchwald and Hartwig. One of these reactions replaces the usual central step with a migratory insertion followed by a beta-hydride elimination. A Grignard reagent is used in one of these reactions named for Kumada, while other examples using tin and zinc catalysts are named for Stille and Negishi. The catalytic cycle of these reactions consists of a reductive elimination, an oxidative addition, and a transmetalation. For 10 points, name these reactions, one example of which uses a palladium catalyst to make a carbon-carbon bond between a boronic acid and a halide, which is named for Suzuki.