An analogue to this theory applied to nucleons is also named for Bogoliubov, and the Pople-Nesbet equations, which encode the DODS procedure, distinguish one form of this technique. Coester and Kümmel improved this method with the coupled cluster technique. This theory contains the result that the f
An analogue to this theory applied to nucleons is also named for Bogoliubov, and the Pople-Nesbet equations, which encode the DODS procedure, distinguish one form of this technique. Coester and Kümmel improved this method with the coupled cluster technique. This theory contains the result that the first ionization energy of a molecule is equal to the negative orbital energy of its HOMO, named for Koopmans. The "restricted" variety of this method applies to molecules where all orbitals are fully occupied, and it is extended to singly- occupied orbitals by Roothaans equations. FTP, name this doubly eponymous method of quantum chemistry where the ground-state energy of an N-body system is approximated by a Slater determinant.
An analogue to this theory applied to nucleons is also named for Bogoliubov, and the Pople-Nesbet equations, which encode the DODS procedure, distinguish one form of this technique.
{Hartree-Fock} method [or {HF}; or {SCF}; or {self-consistent field}