This reaction was extended by Yoshia and Oshima by using lambda-3 hypervalent bromanes to synthesize
This reaction was extended by Yoshia and Oshima by using lambda-3 hypervalent bromanes to synthesize formates, and one popular catalyst for this reaction is potassium caroate supported on hydrated silica. Imada's chiral bisflavin catalyzes an asymmetric version of this reaction. A group of flavin-containing enzymes expressed by Cunninghamella Echinulata can catalyze this reaction and are referred to as its namesake monoxygenases. The use of BTSP instead of the usual reagent for this reaction can cut down on the competing Prilzhaev reaction. Its not ozonolysis, but this reaction has a Crigee-like intermediate followed by a migratory insertion. MMPP and H2O2 in trifluorobromate are popular reagents for this reaction, which is more commonly catalyzed by mCPBA. This reaction preferentially moves cyclohexyls over benzyls and aryls over methyls, and it is used to synthesize lactones from cyclic ketones. It begins with an attack on a carbonyl group by a peracid, followed by scission of a peroxide bond. For 10 points, name this doubly-eponymous oxidation using peracids, which synthesizes esters.
This reaction was extended by Yoshia and Oshima by using lambda-3 hypervalent bromanes to synthesize formates, and one popular catalyst for this reaction is potassium caroate supported on hydrated silica.
Baeyer-Villiger oxidation