The Gin synthesis of Nominine relies on an intermolecular version of this reaction, while Ishihara's triamine catalysts allow acroleins to undergo this reaction.
The Gin synthesis of Nominine relies on an intermolecular version of this reaction, while Ishihara's triamine catalysts allow acroleins to undergo this reaction. Rajaram and Sigman's catalysts facilitate the oxo-variation of this reaction, which uses carbonyl compounds to create pyrans, and this reaction was one of the first understood through the use of Fukui's theory. Seelig's ribozymes catalyze it in vivo, and a more familiar variation uses 1,1-diarylethylene and is named for Wagner and Juaregg. The aza variation of this reaction is used to synthesize pyridines, while this reaction prefers a transition state in which the groups on one reactant are pointed inwards, called the "endo" state. FTP, name this [4+2] cycloaddition reaction that creates a cyclohexene derivative from a diene and a dienophile.
The Gin synthesis of Nominine relies on an intermolecular version of this reaction, while Ishihara's triamine catalysts allow acroleins to undergo this reaction.
Diels-Alder reaction