Glorieta, la Casa de la Libertad, and la Universidad Mayor de San Francisco Xavier.  
It was founded as a result of mining activities overseen by Gonzalo Pizarro, who was interested in exploring the highland east region of the Andean Cordillera.  Located on the Rio Cachimayo, this city's main attractions are el Museo de la Recoleta, el Palacio de la Glorieta, la Casa de la Libertad, and la Universidad Mayor de San Francisco Xavier.  Founded by Pedro de Anz?res, it was originally named La Plata, and has also been called Charcas and Ciudad Blanca until its name was permanently changed on August 11, 1825 to honor a Venezuelan freedom fighter.  For 10 points, name this legal capital of Bolivia.
It was founded as a result of mining activities overseen by Gonzalo Pizarro, who was interested in exploring the highland east region of the Andean Cordillera.  
Sucre (accept the 3 names before mentioned)