A group including Kim, Lee, and Hyeon developed a version of this reaction that used hollow silica spheres to create spherical recyclable heterogeneous catalysts of a certain metal.
Baudoin developed an efficient one-pot way to generate ortho- substituted products based on this reaction, while Beller developed a technique using diadamantyl-n-butylphosphane ligands to carry out this reaction using in situ formed complex catalysts. A group including Kim, Lee, and Hyeon developed a version of this reaction that used hollow silica spheres to create spherical recyclable heterogeneous catalysts of a certain metal. This reaction is commonly used for macrocylicization in the synthesis of Rutamycin B. Sodium carbonate and potassium carbonate are commonly used in this reactionfor activation of one reagent for the transmetallation step. Nickel can be used as a catalyst for a version of this reaction for aryl chlorides. The mechanism of this reaction is somewhat similar to the Stille reaction, and it is an efficient way in a synthesis to create carbon-carbon bonds between two aryls. The traditional catalyst consists of four triphenylphosphines bound to a certain metal. For 10 points, name this palladium-catalyzed reaction that couples aryl boronic acids and aryl halides.
Baudoin developed an efficient one-pot way to generate ortho- substituted products based on this reaction, while Beller developed a technique using diadamantyl-n-butylphosphane ligands to carry out this reaction using in situ formed complex catalysts.
Suzuki-Miyaura coupling [or Suzuki-Miyaura reaction; or SM coupling]