FTP, name this effect, the transfer of spin polarization from one population to another via relaxation, named for an American physicist.
This effect was experimentally verified by Carver and Schlicter using electron-saturated samples of lithium, and one recently developed protocol that uses it is the DPFGSE experiment. The steady-state enhancement of this effect is derived by setting the ratio of bulk magnetization equal to the ratio of two gyromagnetic ratios, and for a short peptide, it must be measured in the rotational frame rather than the laboratory frame. Commonly used for protein domain structure determination, it is the basis of the ROESY and NOESY ? variations of NMR. FTP, name this effect, the transfer of spin polarization from one population to another via relaxation, named for an American physicist.
This effect was experimentally verified by Carver and Schlicter using electron-saturated samples of lithium, and one recently developed protocol that uses it is the DPFGSE experiment.
{Nuclear Overhauser} Effect