National Radio Astronomy Observatory
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September 20, 2004


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Cold Sugar in Space Provides Clue to the Molecular Origin of Life



Glycoaldehyde is composed of 2 carbon atoms, 2 oxygen atoms and 4 hydrogen atoms and is called a 2-carbon sugar. Glycolaldehyde can react with a 3-carbon sugar to produce a 5-carbon sugar called ribose. Ribose molecules form the backbone structure of the molecules DNA and RNA, which carry the genetic code of living organisms.

On Earth, most chemical reactions occur in liquid water. Conditions are quite different in interstellar space, and most of the complex molecules appear to form on or under the surfaces of tiny dust grains. In this scenario, smaller molecules such as water, formaldehyde, methane, ammonia, carbon dioxide, or methanol, coat the surfaces and interiors of dust grains in the clouds. When a shock wave, caused by the infall or outflow of material in the star-formation process, hits the dust grains, it provides the energy to assemble more-complex molecules from the simpler ones, and also to free the newly-formed molecules from the dust grains. Once the shock has passed, the molecules cool into a cold, thin gas.


The actual formation of a planetary system is such a hot process that any prebiotic molecules would likely be destroyed. However, this study has shown that such molecules may form in very cold regions following the passage of a shock wave. Such conditions might be typical of the outer regions of a young solar system following the star-formation process. A repository of prebiotic molecules might exist in these outer regions, which is also where comets are formed, the scientists said. It has long been suggested that a collision with a comet or an encounter with the passing tail of a comet might "seed" a young planet with prebiotic material.

Hollis worked with Philip Jewell of the National Radio Astronomy Observatory in Green Bank, WV, Frank Lovas of the National Institute of Standards and Technology in Gaithersburg, MD, and Anthony Remijan of NASA's Goddard Space Flight Center. The scientists reported their findings in the September 20 issue of the Astrophysical Journal Letters.

The discovery of the cold glycolaldehyde was made by detecting faint radio emission from the molecules. Molecules rotate end-for-end. When they change from a higher rotational energy level to a lower energy level, they emit radio waves at precise frequencies. Conversely, they can absorb radio waves at specific frequencies and change from a lower rotational energy level to a higher one. A set of frequencies emitted or absorbed by a particular molecule forms a unique "fingerprint" identifying that molecule. The cold glycolaldehyde was identified both by emission from the molecules and by absorption of radio waves emitted by a background source, all between 13 GHz and 22 GHz in frequency.

"The large diameter and great precision of the GBT made this discovery possible, and also holds the promise of discovering additional new complex interstellar molecules," Jewell said. The GBT, dedicated in 2000, is the world's largest fully- steerable radio-telescope antenna. Its dish reflector has more than 2 acres of signal-collecting area.


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