Forbidden mechanism

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In physics, a forbidden mechanism or forbidden line is a spectral line emitted by atomic nuclei, atoms, or molecules undergoing nominally "forbidden" energy transitions not normally "allowed" by the selection rules of quantum mechanics. Obviously, any process which is truly forbidden will not happen. The typical usage of this term, is in a situation where, according to usual approximations (such as the electric-dipole approximation for the interaction with light), the process cannot happen, but at a higher level of approximation (e.g. magnetic dipole, or, electric quadrupole) the process is allowed but at a much lower rate.

A simple everyday example is "glow in the dark" materials. They absorb light and form an excited state whose decay involves a spin flip, and is therefore forbidden by electric dipole transitions. The result is emission of light slowly over minutes or hours. This process is known technically as phosphorescence.

Although the transitions are nominally "forbidden", there is a small probability of their spontaneous occurrence, should an atomic nucleus, atom or molecule be raised to an excited state. More precisely, there is a certain probability that such an excited entity will make a forbidden transition to a lower energy state per unit time; by definition, this probability is much lower than that for any transition permitted or allowed by the selection rules. Therefore, if a state can de-excite via a “permitted” transition (or otherwise, e.g. via collisions) it will almost certainly do so before any transition occurs via a “forbidden” route. Nevertheless, most “forbidden” transitions are only relatively unlikely: states that can only decay in this way (so-called meta-stable states) usually have lifetimes on the order milliseconds to seconds, compared to less than a microsecond for decay via permitted transitions. In some radioactive decay systems, multiple levels of “forbiddenness” can stretch life times by many orders of magnitude for each additional unit by which the system changes beyond what is most allowed under the selection rules.[citation needed] Such excited states can last years, or even for many billions of years (too long to have been measured).

In radioactive decay

Gamma decay



Beta decay

Beta decays here are classified according to the L-value of the emitted radiation. Unlike gamma decays, beta decays may proceed from a nucleus with a spin of zero and even parity, to a nucleus also with a spin of zero and even parity ("Fermi transition"). This is possible because the electron and neutrino emitted may be of opposing spin (giving a radiation total angular momentum of zero), thus preserving angular momentum of the initial state even if the nucleus remains at spin-zero before and after emission. This type of emission is "super-allowed" meaning that it is the most rapid type of beta decay in nuclei that are susceptible to a change in proton/neutron ratios that accompanies a beta decay process.

The next possible total angular momentum of the electron and neutrino emitted in beta decay is a combined spin of 1 (electron and neutrino spinning in the same direction), and is "allowed". This type of emission ("Gamow-Teller transition") changes nuclear spin by a unit of 1 to compensate. States involving higher angular momenta of the emitted radiation (2, 3, 4, etc.) are "forbidden", and are ranked in degree of forbiddenness by their increasing angular momentum.

Specifically, when L > 0, the decay is referred to as "forbidden". Nuclear selection rules require L-values greater than two to be accompanied by changes in both nuclear spin (J) and parity (π). The selection rules for the Lth forbidden transitions are:


where Δπ = 1 or −1 corresponds to no parity change or parity change, respectively. As noted, the special case of a "Fermi" 0+ → 0+ transition (which in gamma decay is absolutely forbidden) is referred to as "super-allowed" for beta decay, and proceeds very quickly if beta decay is possible. The following table lists the ΔJ and Δπ values for the first few values of L:

Forbiddenness ΔJ Δπ
Superallowed 0+ → 0+ no
Allowed 0, 1 no
First forbidden 0, 1, 2 yes
Second forbidden 1, 2, 3 no
Third forbidden 2, 3, 4 yes


In solid-state physics

Forbidden transitions in rare earth atoms such as erbium and neodymium make them useful as dopants for solid-state lasing media. In such media, the atoms are held in a matrix which keeps them from de-exciting by collision, and the long half life of their excited states makes them easy to "optically pump" to create a large population of excited atoms. Neodymium doped glass derives its unusual coloration from "forbidden" f-f transitions within the neodymium atom, and is used in extremely high power solid state lasers. Bulk semiconductor transitions can also be forbidden by symmetry, which change the functional form of the absorption spectrum, as can be shown in a Tauc plot.

In astrophysics



