New technology offers hope for storing carbon dioxide underground


In a paper published today in Science my colleagues and I report on a successful trial converting carbon dioxide (CO2) to rock and storing it underground in Iceland. Although we trialled only a small amount of CO2, this method has enormous potential.

Here’s how it works.

Turning CO2 to rock


The idea itself to convert CO2 into carbonate minerals, the basis of limestone, is not new. In fact, Earth itself has been using this conversion technique for aeons to control atmospheric CO? levels.

However, scientific opinion had it up to now that converting CO2 from a gas to a solid (known as mineralisation) would take thousands (or tens of thousands) of years, and would be too slow to be used on an industrial scale.

To settle this question, we prepared a field trial using Reykjavik Energy’s injection and monitoring wells. In 2012, after many years of preparation, we injected 248 tonnes of CO2 in two separate phases into basalt rocks around 550m underground.

Most CO2 sequestration projects inject and store “supercritical CO2”, which is CO2 gas that has been compressed under pressure to considerably decrease its volume*. However, supercritical CO2 is buoyant, like a gas, and this approach has thus proved controversial due to the possibility of leaks from the storage reservoir upwards into groundwater and eventually back to the atmosphere.

In fact, some European countries such as the Netherlands have stopped their efforts to store supercritical CO? on land because of lack of public acceptance, driven by the fear of possible leaks in the unforeseeable future. Austria went even so far as to ban underground storage of carbon dioxide outright.

The injection well with monitoring station in the background.
Dom Wolff-Boenisch, Author provided

Our Icelandic trial worked in a different way. We first dissolved CO2 in water to create sparkling water. This carbonated water has two advantages over supercritical CO2 gas.


Second, the CO2 cannot escape because it is dissolved and will not rise to the surface. As long as it remains under pressure it will not rise to the surface (you can see the same effect when you crack open a soda can; only then is the dissolved CO2 released back into the air).

Dissolving basalt means elements such as calcium, magnesium, and iron are released into pore water. Basaltic rocks are rich in these metals that team up with the dissolved CO2 and form solid carbonate minerals.

Through observations and tracer studies at the monitoring well, we found that over 95% of the injected CO2 (around 235 tonnes) was converted to carbonate minerals in less than two years. While the initial amount of injected CO2 was small, the Icelandic field trial clearly shows that mineralisation of CO? is feasible and more importantly, fast.

Storing CO2 under the oceans

The good news is this technology need not be exclusive to Iceland. Mineralisation of CO2 requires basaltic or peridotitic rocks because these types of rocks are rich in the metals required to form carbonates and bind the CO2.


The overall potential storage capacity for CO2 is much larger than the global CO2 emissions of many centuries. The mineralisation process removes the crucial problem of buoyancy and the need for permanent monitoring of the injected CO2 to stop and remedy potential leakage to the surface, an issue that supercritical CO2 injection sites will face for centuries or even millennia to come.

On the downside, CO2 mineralisation with carbonated water requires substantial amounts of water, meaning that this mineralisation technique can only succeed where vast supplies of water are available.


In the case of our trial, a tonne of mineralised CO2 via carbonated water cost about US$17, roughly twice that of using supercritical CO2 for storage.


*Correction: The sentence has been corrected to note that gas volume rather than density decreases when it is compressed. Thankyou to the readers who pointed out the error.

The Conversation

Dom Wolff-Boenisch, Senior Lecturer, Western Australian School of Mines, Curtin University



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