April 9, 08
Scientists Discover New Form of “Superinsulator” Material

Scientists have discovered a new fundamental state of matter, a superinsulator created by scientists at Argonne National Laboratory in collaboration with several European institutions that opens the door to a new generation of super microelectronics and could lead to a new class of superconductive materials.

Led by Argonne senior scientist Valerii Vinokur and Russian scientist Tatyana Baturina, the international team fashioned a thin film of titanium nitride with they then chilled to near absolute zero.

When they tried to pass a current through the material, the researchers noticed that its resistance suddenly increased by a factor of 100,000 once the temperature dropped below a certain threshold. The same sudden change also occurred when the researchers decreased the external magnetic field.

"Titanium nitride films as well as films prepared from some other materials can be either superconductors or insulators depending on the thickness of the film. If you take the film which is just on the insulating side of the transition and decrease the temperature or magnetic field, then the film all of a sudden becomes a superinsulator," Vinokur said.

Like superconductors, which have applications in many different areas of physics, from accelerators to magnetic levitation (maglev) trains to MRI machines, superinsulators could eventually find their way into a number of products, including circuits, sensors and battery shields.

If, for example, a battery is left exposed to the air, the charge will eventually drain from it in a matter of days or weeks because the air is not a perfect insulator, according to Vinokur. "If you pass a current through a superconductor, then it will carry the current forever; conversely, if you have a superinsulator, then it will hold a charge forever," he said.

Additionally, scientists could eventually form superinsulators that would encapsulate superconducting wires, creating an optimally efficient electrical pathway with almost no energy lost as heat. A miniature version of these superinsulated superconducting wires could find their way into more efficient electrical circuits.

Titanium nitride's sudden transition to a superinsulator occurs because the electrons in the material join together in twosomes called Cooper pairs. When these Cooper pairs of electrons join together in long chains, they enable the unrestricted motion of electrons and the easy flow of current, creating a superconductor. In superinsulators, however, the Cooper pairs stay separate from each other, forming self-locking roadblocks. "In superinsulators, Cooper pairs avoid each other, creating enormous electric forces that oppose penetration of the current into the material,” Vinokur said. "It's exactly the opposite of the superconductor," he added.

The theory behind the experiment stemmed from Argonne's Materials Theory Institute, which Vinokur organized six years ago in the laboratory's Materials Science Division. The MTI hosts a handful of visiting scholars from around the world who then perform cutting-edge research on the most pressing questions in condensed matter physics. Upon completion of their tenure at Argonne, these scientists return to their home institutions but continue to collaborate on the joint projects. The MTI attracts the world's best condensed matter scientists, including Russian "experimental star" Tatyana Baturina, who, according to Vinokur, "became a driving force in our work on superinsulators."