The compound described by Sb5O7I crystallizes in the monoclinic Pc space group. There are ten inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 3-coordinate geometry to one O(2), one O(5), and one O(6) atom. In the second Sb site, Sb(2) is bonded in a 4-coordinate geometry to one O(13), one O(14), one O(3), and one O(4) atom. In the third Sb site, Sb(3) is bonded in a distorted T-shaped geometry to one O(1), one O(11), and one O(12) atom. In the fourth Sb site, Sb(4) is bonded in a 3-coordinate geometry to one O(13), one O(14), one O(2), and one I(1) atom. In the fifth Sb site, Sb(5) is bonded in a distorted water-like geometry to one O(7), one O(8), and one I(2) atom. In the sixth Sb site, Sb(6) is bonded in a distorted trigonal non-coplanar geometry to one O(10), one O(2), and one O(9) atom. In the seventh Sb site, Sb(7) is bonded in a distorted T-shaped geometry to one O(11), one O(3), and one O(7) atom. In the eighth Sb site, Sb(8) is bonded in a distorted T-shaped geometry to one O(12), one O(4), and one O(8) atom. In the ninth Sb site, Sb(9) is bonded in a distorted T-shaped geometry to one O(4), one O(5), and one O(9) atom. In the tenth Sb site, Sb(10) is bonded in a 3-coordinate geometry to one O(1), one O(10), one O(6), and one I(1) atom. There are fourteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Sb(10) and one Sb(3) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Sb(1), one Sb(4), and one Sb(6) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Sb(2) and one Sb(7) atom. In the fourth O site, O(4) is bonded in a trigonal non-coplanar geometry to one Sb(2), one Sb(8), and one Sb(9) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Sb(1) and one Sb(9) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Sb(1) and one Sb(10) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one Sb(5) and one Sb(7) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Sb(5) and one Sb(8) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one Sb(6) and one Sb(9) atom. In the tenth O site, O(10) is bonded in a bent 150 degrees geometry to one Sb(10) and one Sb(6) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one Sb(3) and one Sb(7) atom. In the twelfth O site, O(12) is bonded in a bent 150 degrees geometry to one Sb(3) and one Sb(8) atom. In the thirteenth O site, O(13) is bonded in a water-like geometry to one Sb(2) and one Sb(4) atom. In the fourteenth O site, O(14) is bonded in a water-like geometry to one Sb(2) and one Sb(4) atom. There are two inequivalent I sites. In the first I site, I(1) is bonded in a distorted L-shaped geometry to one Sb(10) and one Sb(4) atom. In the second I site, I(2) is bonded in a single-bond geometry to one Sb(5) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sb5IO7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.317
_cell_length_b   13.972
_cell_length_c   12.311
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   106.289
_symmetry_Int_Tables_number   1
_cell_volume   1207.966
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.927  0.046  0.222  1.0
  Sb  Sb1  1  0.427  0.546  0.778  1.0
  Sb  Sb2  1  0.035  0.123  0.704  1.0
  Sb  Sb3  1  0.535  0.623  0.296  1.0
  Sb  Sb4  1  0.457  0.294  0.193  1.0
  Sb  Sb5  1  0.957  0.794  0.807  1.0
  Sb  Sb6  1  0.406  0.285  0.766  1.0
  Sb  Sb7  1  0.906  0.785  0.234  1.0
  Sb  Sb8  1  0.947  0.447  0.326  1.0
  Sb  Sb9  1  0.447  0.947  0.674  1.0
  Sb  Sb10  1  0.946  0.390  0.727  1.0
  Sb  Sb11  1  0.446  0.890  0.273  1.0
  Sb  Sb12  1  0.267  0.468  0.086  1.0
  Sb  Sb13  1  0.767  0.968  0.914  1.0
  Sb  Sb14  1  0.345  0.393  0.461  1.0
  Sb  Sb15  1  0.845  0.893  0.539  1.0
  Sb  Sb16  1  0.778  0.576  0.555  1.0
  Sb  Sb17  1  0.278  0.076  0.445  1.0
  Sb  Sb18  1  0.813  0.550  0.935  1.0
  Sb  Sb19  1  0.313  0.050  0.065  1.0
  I  I20  1  0.692  0.225  0.942  1.0
  I  I21  1  0.192  0.725  0.058  1.0
  I  I22  1  0.822  0.243  0.408  1.0
  I  I23  1  0.322  0.743  0.592  1.0
  O  O24  1  0.299  0.149  0.181  1.0
  O  O25  1  0.799  0.649  0.819  1.0
  O  O26  1  0.233  0.408  0.739  1.0
  O  O27  1  0.733  0.908  0.261  1.0
  O  O28  1  0.476  0.502  0.199  1.0
  O  O29  1  0.976  0.002  0.801  1.0
  O  O30  1  0.591  0.504  0.429  1.0
  O  O31  1  0.091  0.004  0.571  1.0
  O  O32  1  0.554  0.515  0.647  1.0
  O  O33  1  0.054  0.015  0.353  1.0
  O  O34  1  0.553  0.471  0.879  1.0
  O  O35  1  0.053  0.971  0.121  1.0
  O  O36  1  0.028  0.443  0.175  1.0
  O  O37  1  0.528  0.943  0.825  1.0
  O  O38  1  0.202  0.480  0.392  1.0
  O  O39  1  0.702  0.980  0.608  1.0
  O  O40  1  0.918  0.476  0.600  1.0
  O  O41  1  0.418  0.976  0.400  1.0
  O  O42  1  0.978  0.490  0.844  1.0
  O  O43  1  0.478  0.990  0.156  1.0
  O  O44  1  0.273  0.329  0.095  1.0
  O  O45  1  0.773  0.829  0.905  1.0
  O  O46  1  0.334  0.302  0.337  1.0
  O  O47  1  0.834  0.802  0.663  1.0
  O  O48  1  0.311  0.182  0.647  1.0
  O  O49  1  0.811  0.682  0.353  1.0
  O  O50  1  0.178  0.203  0.838  1.0
  O  O51  1  0.678  0.703  0.162  1.0
[/CIF]
.
The compound described by Sb5O7I crystallizes in the monoclinic Pc space group. There are ten inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 3-coordinate geometry to one O(2), one O(5), and one O(6) atom. In the second Sb site, Sb(2) is bonded in a 4-coordinate geometry to one O(13), one O(14), one O(3), and one O(4) atom. In the third Sb site, Sb(3) is bonded in a distorted T-shaped geometry to one O(1), one O(11), and one O(12) atom. In the fourth Sb site, Sb(4) is bonded in a 3-coordinate geometry to one O(13), one O(14), one O(2), and one I(1) atom. In the fifth Sb site, Sb(5) is bonded in a distorted water-like geometry to one O(7), one O(8), and one I(2) atom. In the sixth Sb site, Sb(6) is bonded in a distorted trigonal non-coplanar geometry to one O(10), one O(2), and one O(9) atom. In the seventh Sb site, Sb(7) is bonded in a distorted T-shaped geometry to one O(11), one O(3), and one O(7) atom. In the eighth Sb site, Sb(8) is bonded in a distorted T-shaped geometry to one O(12), one O(4), and one O(8) atom. In the ninth Sb site, Sb(9) is bonded in a distorted T-shaped geometry to one O(4), one O(5), and one O(9) atom. In the tenth Sb site, Sb(10) is bonded in a 3-coordinate geometry to one O(1), one O(10), one O(6), and one I(1) atom. There are fourteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Sb(10) and one Sb(3) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Sb(1), one Sb(4), and one Sb(6) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Sb(2) and one Sb(7) atom. In the fourth O site, O(4) is bonded in a trigonal non-coplanar geometry to one Sb(2), one Sb(8), and one Sb(9) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Sb(1) and one Sb(9) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Sb(1) and one Sb(10) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one Sb(5) and one Sb(7) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Sb(5) and one Sb(8) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one Sb(6) and one Sb(9) atom. In the tenth O site, O(10) is bonded in a bent 150 degrees geometry to one Sb(10) and one Sb(6) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one Sb(3) and one Sb(7) atom. In the twelfth O site, O(12) is bonded in a bent 150 degrees geometry to one Sb(3) and one Sb(8) atom. In the thirteenth O site, O(13) is bonded in a water-like geometry to one Sb(2) and one Sb(4) atom. In the fourteenth O site, O(14) is bonded in a water-like geometry to one Sb(2) and one Sb(4) atom. There are two inequivalent I sites. In the first I site, I(1) is bonded in a distorted L-shaped geometry to one Sb(10) and one Sb(4) atom. In the second I site, I(2) is bonded in a single-bond geometry to one Sb(5) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sb5IO7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.317
_cell_length_b   13.972
_cell_length_c   12.311
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   106.289
_symmetry_Int_Tables_number   1
_cell_volume   1207.966
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.927  0.046  0.222  1.0
  Sb  Sb1  1  0.427  0.546  0.778  1.0
  Sb  Sb2  1  0.035  0.123  0.704  1.0
  Sb  Sb3  1  0.535  0.623  0.296  1.0
  Sb  Sb4  1  0.457  0.294  0.193  1.0
  Sb  Sb5  1  0.957  0.794  0.807  1.0
  Sb  Sb6  1  0.406  0.285  0.766  1.0
  Sb  Sb7  1  0.906  0.785  0.234  1.0
  Sb  Sb8  1  0.947  0.447  0.326  1.0
  Sb  Sb9  1  0.447  0.947  0.674  1.0
  Sb  Sb10  1  0.946  0.390  0.727  1.0
  Sb  Sb11  1  0.446  0.890  0.273  1.0
  Sb  Sb12  1  0.267  0.468  0.086  1.0
  Sb  Sb13  1  0.767  0.968  0.914  1.0
  Sb  Sb14  1  0.345  0.393  0.461  1.0
  Sb  Sb15  1  0.845  0.893  0.539  1.0
  Sb  Sb16  1  0.778  0.576  0.555  1.0
  Sb  Sb17  1  0.278  0.076  0.445  1.0
  Sb  Sb18  1  0.813  0.550  0.935  1.0
  Sb  Sb19  1  0.313  0.050  0.065  1.0
  I  I20  1  0.692  0.225  0.942  1.0
  I  I21  1  0.192  0.725  0.058  1.0
  I  I22  1  0.822  0.243  0.408  1.0
  I  I23  1  0.322  0.743  0.592  1.0
  O  O24  1  0.299  0.149  0.181  1.0
  O  O25  1  0.799  0.649  0.819  1.0
  O  O26  1  0.233  0.408  0.739  1.0
  O  O27  1  0.733  0.908  0.261  1.0
  O  O28  1  0.476  0.502  0.199  1.0
  O  O29  1  0.976  0.002  0.801  1.0
  O  O30  1  0.591  0.504  0.429  1.0
  O  O31  1  0.091  0.004  0.571  1.0
  O  O32  1  0.554  0.515  0.647  1.0
  O  O33  1  0.054  0.015  0.353  1.0
  O  O34  1  0.553  0.471  0.879  1.0
  O  O35  1  0.053  0.971  0.121  1.0
  O  O36  1  0.028  0.443  0.175  1.0
  O  O37  1  0.528  0.943  0.825  1.0
  O  O38  1  0.202  0.480  0.392  1.0
  O  O39  1  0.702  0.980  0.608  1.0
  O  O40  1  0.918  0.476  0.600  1.0
  O  O41  1  0.418  0.976  0.400  1.0
  O  O42  1  0.978  0.490  0.844  1.0
  O  O43  1  0.478  0.990  0.156  1.0
  O  O44  1  0.273  0.329  0.095  1.0
  O  O45  1  0.773  0.829  0.905  1.0
  O  O46  1  0.334  0.302  0.337  1.0
  O  O47  1  0.834  0.802  0.663  1.0
  O  O48  1  0.311  0.182  0.647  1.0
  O  O49  1  0.811  0.682  0.353  1.0
  O  O50  1  0.178  0.203  0.838  1.0
  O  O51  1  0.678  0.703  0.162  1.0
[/CIF]
.