The compound described by Sc5Re24 crystallizes in the cubic I-43m space group. There are two inequivalent Sc sites. In the first Sc site, Sc(1) is bonded in a 16-coordinate geometry to one Sc(2), six equivalent Re(1), and nine equivalent Re(2) atoms. In the second Sc site, Sc(2) is bonded in a 16-coordinate geometry to four equivalent Sc(1) and twelve equivalent Re(2) atoms. There are two inequivalent Re sites. In the first Re site, Re(2) is bonded to one Sc(2), three equivalent Sc(1), three equivalent Re(2), and five equivalent Re(1) atoms to form a mixture of distorted edge, corner, and face-sharing ReSc4Re8 cuboctahedra. In the second Re site, Re(1) is bonded in a 13-coordinate geometry to two equivalent Sc(1), five equivalent Re(2), and six equivalent Re(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sc5Re24
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.414
_cell_length_b   8.414
_cell_length_c   8.414
_cell_angle_alpha   109.471
_cell_angle_beta   109.471
_cell_angle_gamma   109.471
_symmetry_Int_Tables_number   1
_cell_volume   458.552
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sc  Sc0  1  0.000  0.000  0.367  1.0
  Sc  Sc1  1  0.000  0.367  0.000  1.0
  Sc  Sc2  1  0.367  0.000  0.000  1.0
  Sc  Sc3  1  0.633  0.633  0.633  1.0
  Sc  Sc4  1  0.000  0.000  0.000  1.0
  Re  Re5  1  0.677  0.280  0.677  1.0
  Re  Re6  1  0.323  0.000  0.603  1.0
  Re  Re7  1  0.603  0.000  0.323  1.0
  Re  Re8  1  0.000  0.603  0.323  1.0
  Re  Re9  1  0.720  0.397  0.397  1.0
  Re  Re10  1  0.397  0.720  0.397  1.0
  Re  Re11  1  0.677  0.677  0.280  1.0
  Re  Re12  1  0.378  0.378  0.185  1.0
  Re  Re13  1  0.622  0.808  0.000  1.0
  Re  Re14  1  0.808  0.622  0.000  1.0
  Re  Re15  1  0.000  0.808  0.622  1.0
  Re  Re16  1  0.815  0.192  0.192  1.0
  Re  Re17  1  0.192  0.815  0.192  1.0
  Re  Re18  1  0.808  0.000  0.622  1.0
  Re  Re19  1  0.622  0.000  0.808  1.0
  Re  Re20  1  0.000  0.622  0.808  1.0
  Re  Re21  1  0.185  0.378  0.378  1.0
  Re  Re22  1  0.378  0.185  0.378  1.0
  Re  Re23  1  0.192  0.192  0.815  1.0
  Re  Re24  1  0.280  0.677  0.677  1.0
  Re  Re25  1  0.000  0.323  0.603  1.0
  Re  Re26  1  0.323  0.603  0.000  1.0
  Re  Re27  1  0.603  0.323  0.000  1.0
  Re  Re28  1  0.397  0.397  0.720  1.0
[/CIF]
.
The compound described by Sc5Re24 crystallizes in the cubic I-43m space group. There are two inequivalent Sc sites. In the first Sc site, Sc(1) is bonded in a 16-coordinate geometry to one Sc(2), six equivalent Re(1), and nine equivalent Re(2) atoms. In the second Sc site, Sc(2) is bonded in a 16-coordinate geometry to four equivalent Sc(1) and twelve equivalent Re(2) atoms. There are two inequivalent Re sites. In the first Re site, Re(2) is bonded to one Sc(2), three equivalent Sc(1), three equivalent Re(2), and five equivalent Re(1) atoms to form a mixture of distorted edge, corner, and face-sharing ReSc4Re8 cuboctahedra. In the second Re site, Re(1) is bonded in a 13-coordinate geometry to two equivalent Sc(1), five equivalent Re(2), and six equivalent Re(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sc5Re24
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.414
_cell_length_b   8.414
_cell_length_c   8.414
_cell_angle_alpha   109.471
_cell_angle_beta   109.471
_cell_angle_gamma   109.471
_symmetry_Int_Tables_number   1
_cell_volume   458.552
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sc  Sc0  1  0.000  0.000  0.367  1.0
  Sc  Sc1  1  0.000  0.367  0.000  1.0
  Sc  Sc2  1  0.367  0.000  0.000  1.0
  Sc  Sc3  1  0.633  0.633  0.633  1.0
  Sc  Sc4  1  0.000  0.000  0.000  1.0
  Re  Re5  1  0.677  0.280  0.677  1.0
  Re  Re6  1  0.323  0.000  0.603  1.0
  Re  Re7  1  0.603  0.000  0.323  1.0
  Re  Re8  1  0.000  0.603  0.323  1.0
  Re  Re9  1  0.720  0.397  0.397  1.0
  Re  Re10  1  0.397  0.720  0.397  1.0
  Re  Re11  1  0.677  0.677  0.280  1.0
  Re  Re12  1  0.378  0.378  0.185  1.0
  Re  Re13  1  0.622  0.808  0.000  1.0
  Re  Re14  1  0.808  0.622  0.000  1.0
  Re  Re15  1  0.000  0.808  0.622  1.0
  Re  Re16  1  0.815  0.192  0.192  1.0
  Re  Re17  1  0.192  0.815  0.192  1.0
  Re  Re18  1  0.808  0.000  0.622  1.0
  Re  Re19  1  0.622  0.000  0.808  1.0
  Re  Re20  1  0.000  0.622  0.808  1.0
  Re  Re21  1  0.185  0.378  0.378  1.0
  Re  Re22  1  0.378  0.185  0.378  1.0
  Re  Re23  1  0.192  0.192  0.815  1.0
  Re  Re24  1  0.280  0.677  0.677  1.0
  Re  Re25  1  0.000  0.323  0.603  1.0
  Re  Re26  1  0.323  0.603  0.000  1.0
  Re  Re27  1  0.603  0.323  0.000  1.0
  Re  Re28  1  0.397  0.397  0.720  1.0
[/CIF]
.