The structure described by Tb5(PdIn2)2 crystallizes in the orthorhombic Pbam space group. There are three inequivalent Tb sites. In the first Tb site, Tb(1) is bonded in a distorted body-centered cubic geometry to four equivalent In(1) and four equivalent In(2) atoms. In the second Tb site, Tb(2) is bonded in a 10-coordinate geometry to four equivalent Pd(1), two equivalent In(1), and four equivalent In(2) atoms. In the third Tb site, Tb(3) is bonded in a 8-coordinate geometry to two equivalent Pd(1), two equivalent In(2), and four equivalent In(1) atoms. Pd(1) is bonded in a 9-coordinate geometry to two equivalent Tb(3), four equivalent Tb(2), one In(1), and two equivalent In(2) atoms. There are two inequivalent In sites. In the first In site, In(1) is bonded in a 9-coordinate geometry to two equivalent Tb(1), two equivalent Tb(2), four equivalent Tb(3), one Pd(1), and one In(2) atom. In the second In site, In(2) is bonded in a 11-coordinate geometry to two equivalent Tb(1), two equivalent Tb(3), four equivalent Tb(2), two equivalent Pd(1), and one In(1) atom. is represented by the CIF card [CIF]
data_Tb5(In2Pd)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.064
_cell_length_b   18.262
_cell_length_c   3.649
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   537.295
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tb  Tb0  1  0.500  0.500  0.000  1.0
  Tb  Tb1  1  0.000  0.000  0.000  1.0
  Tb  Tb2  1  0.743  0.280  0.000  1.0
  Tb  Tb3  1  0.257  0.720  0.000  1.0
  Tb  Tb4  1  0.757  0.780  0.000  1.0
  Tb  Tb5  1  0.243  0.220  0.000  1.0
  Tb  Tb6  1  0.618  0.083  0.000  1.0
  Tb  Tb7  1  0.382  0.917  0.000  1.0
  Tb  Tb8  1  0.882  0.583  0.000  1.0
  Tb  Tb9  1  0.118  0.417  0.000  1.0
  In  In10  1  0.710  0.931  0.500  1.0
  In  In11  1  0.290  0.069  0.500  1.0
  In  In12  1  0.790  0.431  0.500  1.0
  In  In13  1  0.210  0.569  0.500  1.0
  In  In14  1  0.576  0.650  0.500  1.0
  In  In15  1  0.424  0.350  0.500  1.0
  In  In16  1  0.924  0.150  0.500  1.0
  In  In17  1  0.076  0.850  0.500  1.0
  Pd  Pd18  1  0.527  0.195  0.500  1.0
  Pd  Pd19  1  0.473  0.805  0.500  1.0
  Pd  Pd20  1  0.973  0.695  0.500  1.0
  Pd  Pd21  1  0.027  0.305  0.500  1.0
[/CIF]
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The structure described by Tb5(PdIn2)2 crystallizes in the orthorhombic Pbam space group. There are three inequivalent Tb sites. In the first Tb site, Tb(1) is bonded in a distorted body-centered cubic geometry to four equivalent In(1) and four equivalent In(2) atoms. In the second Tb site, Tb(2) is bonded in a 10-coordinate geometry to four equivalent Pd(1), two equivalent In(1), and four equivalent In(2) atoms. In the third Tb site, Tb(3) is bonded in a 8-coordinate geometry to two equivalent Pd(1), two equivalent In(2), and four equivalent In(1) atoms. Pd(1) is bonded in a 9-coordinate geometry to two equivalent Tb(3), four equivalent Tb(2), one In(1), and two equivalent In(2) atoms. There are two inequivalent In sites. In the first In site, In(1) is bonded in a 9-coordinate geometry to two equivalent Tb(1), two equivalent Tb(2), four equivalent Tb(3), one Pd(1), and one In(2) atom. In the second In site, In(2) is bonded in a 11-coordinate geometry to two equivalent Tb(1), two equivalent Tb(3), four equivalent Tb(2), two equivalent Pd(1), and one In(1) atom. is represented by the CIF card [CIF]
data_Tb5(In2Pd)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.064
_cell_length_b   18.262
_cell_length_c   3.649
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   537.295
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tb  Tb0  1  0.500  0.500  0.000  1.0
  Tb  Tb1  1  0.000  0.000  0.000  1.0
  Tb  Tb2  1  0.743  0.280  0.000  1.0
  Tb  Tb3  1  0.257  0.720  0.000  1.0
  Tb  Tb4  1  0.757  0.780  0.000  1.0
  Tb  Tb5  1  0.243  0.220  0.000  1.0
  Tb  Tb6  1  0.618  0.083  0.000  1.0
  Tb  Tb7  1  0.382  0.917  0.000  1.0
  Tb  Tb8  1  0.882  0.583  0.000  1.0
  Tb  Tb9  1  0.118  0.417  0.000  1.0
  In  In10  1  0.710  0.931  0.500  1.0
  In  In11  1  0.290  0.069  0.500  1.0
  In  In12  1  0.790  0.431  0.500  1.0
  In  In13  1  0.210  0.569  0.500  1.0
  In  In14  1  0.576  0.650  0.500  1.0
  In  In15  1  0.424  0.350  0.500  1.0
  In  In16  1  0.924  0.150  0.500  1.0
  In  In17  1  0.076  0.850  0.500  1.0
  Pd  Pd18  1  0.527  0.195  0.500  1.0
  Pd  Pd19  1  0.473  0.805  0.500  1.0
  Pd  Pd20  1  0.973  0.695  0.500  1.0
  Pd  Pd21  1  0.027  0.305  0.500  1.0
[/CIF]
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