The crystal structure described by CdSO3 crystallizes in the monoclinic P2_1/c space group. There are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded to one O(1), one O(3), one O(4), one O(6), and two equivalent O(5) atoms to form a mixture of distorted corner and edge-sharing CdO6 pentagonal pyramids. In the second Cd site, Cd(2) is bonded to one O(1), one O(3), one O(4), one O(6), and two equivalent O(2) atoms to form distorted corner-sharing CdO6 pentagonal pyramids. There are two inequivalent S sites. In the first S site, S(1) is bonded in a trigonal non-coplanar geometry to one O(2), one O(4), and one O(6) atom. In the second S site, S(2) is bonded in a trigonal non-coplanar geometry to one O(1), one O(3), and one O(5) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Cd(1), one Cd(2), and one S(2) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent Cd(2) and one S(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Cd(1), one Cd(2), and one S(2) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Cd(1), one Cd(2), and one S(1) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to two equivalent Cd(1) and one S(2) atom. In the sixth O site, O(6) is bonded in a trigonal planar geometry to one Cd(1), one Cd(2), and one S(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CdSO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.824
_cell_length_b   5.654
_cell_length_c   8.753
_cell_angle_alpha   79.780
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   624.565
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.420  0.321  0.885  1.0
  Cd  Cd1  1  0.254  0.867  0.654  1.0
  Cd  Cd2  1  0.920  0.679  0.615  1.0
  Cd  Cd3  1  0.746  0.133  0.346  1.0
  Cd  Cd4  1  0.754  0.133  0.846  1.0
  Cd  Cd5  1  0.580  0.679  0.115  1.0
  Cd  Cd6  1  0.080  0.321  0.385  1.0
  Cd  Cd7  1  0.246  0.867  0.154  1.0
  S  S8  1  0.326  0.461  0.484  1.0
  S  S9  1  0.174  0.461  0.984  1.0
  S  S10  1  0.826  0.539  0.016  1.0
  S  S11  1  0.674  0.539  0.516  1.0
  S  S12  1  0.979  0.903  0.247  1.0
  S  S13  1  0.521  0.903  0.747  1.0
  S  S14  1  0.021  0.097  0.753  1.0
  S  S15  1  0.479  0.097  0.253  1.0
  O  O16  1  0.092  0.005  0.246  1.0
  O  O17  1  0.241  0.688  0.919  1.0
  O  O18  1  0.577  0.082  0.838  1.0
  O  O19  1  0.759  0.312  0.081  1.0
  O  O20  1  0.259  0.688  0.419  1.0
  O  O21  1  0.657  0.492  0.348  1.0
  O  O22  1  0.978  0.664  0.366  1.0
  O  O23  1  0.746  0.751  0.004  1.0
  O  O24  1  0.343  0.508  0.652  1.0
  O  O25  1  0.908  0.995  0.754  1.0
  O  O26  1  0.022  0.336  0.634  1.0
  O  O27  1  0.754  0.751  0.504  1.0
  O  O28  1  0.408  0.005  0.746  1.0
  O  O29  1  0.157  0.508  0.152  1.0
  O  O30  1  0.843  0.492  0.848  1.0
  O  O31  1  0.246  0.249  0.496  1.0
  O  O32  1  0.741  0.312  0.581  1.0
  O  O33  1  0.077  0.918  0.662  1.0
  O  O34  1  0.923  0.082  0.338  1.0
  O  O35  1  0.592  0.995  0.254  1.0
  O  O36  1  0.522  0.664  0.866  1.0
  O  O37  1  0.254  0.249  0.996  1.0
  O  O38  1  0.478  0.336  0.134  1.0
  O  O39  1  0.423  0.918  0.162  1.0
[/CIF]
.
The crystal structure described by CdSO3 crystallizes in the monoclinic P2_1/c space group. There are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded to one O(1), one O(3), one O(4), one O(6), and two equivalent O(5) atoms to form a mixture of distorted corner and edge-sharing CdO6 pentagonal pyramids. In the second Cd site, Cd(2) is bonded to one O(1), one O(3), one O(4), one O(6), and two equivalent O(2) atoms to form distorted corner-sharing CdO6 pentagonal pyramids. There are two inequivalent S sites. In the first S site, S(1) is bonded in a trigonal non-coplanar geometry to one O(2), one O(4), and one O(6) atom. In the second S site, S(2) is bonded in a trigonal non-coplanar geometry to one O(1), one O(3), and one O(5) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Cd(1), one Cd(2), and one S(2) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent Cd(2) and one S(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Cd(1), one Cd(2), and one S(2) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Cd(1), one Cd(2), and one S(1) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to two equivalent Cd(1) and one S(2) atom. In the sixth O site, O(6) is bonded in a trigonal planar geometry to one Cd(1), one Cd(2), and one S(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CdSO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.824
_cell_length_b   5.654
_cell_length_c   8.753
_cell_angle_alpha   79.780
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   624.565
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.420  0.321  0.885  1.0
  Cd  Cd1  1  0.254  0.867  0.654  1.0
  Cd  Cd2  1  0.920  0.679  0.615  1.0
  Cd  Cd3  1  0.746  0.133  0.346  1.0
  Cd  Cd4  1  0.754  0.133  0.846  1.0
  Cd  Cd5  1  0.580  0.679  0.115  1.0
  Cd  Cd6  1  0.080  0.321  0.385  1.0
  Cd  Cd7  1  0.246  0.867  0.154  1.0
  S  S8  1  0.326  0.461  0.484  1.0
  S  S9  1  0.174  0.461  0.984  1.0
  S  S10  1  0.826  0.539  0.016  1.0
  S  S11  1  0.674  0.539  0.516  1.0
  S  S12  1  0.979  0.903  0.247  1.0
  S  S13  1  0.521  0.903  0.747  1.0
  S  S14  1  0.021  0.097  0.753  1.0
  S  S15  1  0.479  0.097  0.253  1.0
  O  O16  1  0.092  0.005  0.246  1.0
  O  O17  1  0.241  0.688  0.919  1.0
  O  O18  1  0.577  0.082  0.838  1.0
  O  O19  1  0.759  0.312  0.081  1.0
  O  O20  1  0.259  0.688  0.419  1.0
  O  O21  1  0.657  0.492  0.348  1.0
  O  O22  1  0.978  0.664  0.366  1.0
  O  O23  1  0.746  0.751  0.004  1.0
  O  O24  1  0.343  0.508  0.652  1.0
  O  O25  1  0.908  0.995  0.754  1.0
  O  O26  1  0.022  0.336  0.634  1.0
  O  O27  1  0.754  0.751  0.504  1.0
  O  O28  1  0.408  0.005  0.746  1.0
  O  O29  1  0.157  0.508  0.152  1.0
  O  O30  1  0.843  0.492  0.848  1.0
  O  O31  1  0.246  0.249  0.496  1.0
  O  O32  1  0.741  0.312  0.581  1.0
  O  O33  1  0.077  0.918  0.662  1.0
  O  O34  1  0.923  0.082  0.338  1.0
  O  O35  1  0.592  0.995  0.254  1.0
  O  O36  1  0.522  0.664  0.866  1.0
  O  O37  1  0.254  0.249  0.996  1.0
  O  O38  1  0.478  0.336  0.134  1.0
  O  O39  1  0.423  0.918  0.162  1.0
[/CIF]
.