The structure described by PuOCl is Matlockite structured and crystallizes in the tetragonal P4/nmm space group. Pu(1) is bonded in a 9-coordinate geometry to four equivalent O(1) and five equivalent Cl(1) atoms. O(1) is bonded to four equivalent Pu(1) atoms to form a mixture of corner and edge-sharing OPu4 tetrahedra. Cl(1) is bonded in a 5-coordinate geometry to five equivalent Pu(1) atoms. is represented by the CIF file [CIF]
data_PuClO
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.970
_cell_length_b   3.970
_cell_length_c   6.860
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   108.130
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pu  Pu0  1  0.500  0.000  0.820  1.0
  Pu  Pu1  1  0.000  0.500  0.180  1.0
  Cl  Cl2  1  0.000  0.500  0.630  1.0
  Cl  Cl3  1  0.500  0.000  0.370  1.0
  O  O4  1  0.000  0.000  0.000  1.0
  O  O5  1  0.500  0.500  0.000  1.0
[/CIF]
.
The structure described by PuOCl is Matlockite structured and crystallizes in the tetragonal P4/nmm space group. Pu(1) is bonded in a 9-coordinate geometry to four equivalent O(1) and five equivalent Cl(1) atoms. O(1) is bonded to four equivalent Pu(1) atoms to form a mixture of corner and edge-sharing OPu4 tetrahedra. Cl(1) is bonded in a 5-coordinate geometry to five equivalent Pu(1) atoms. is represented by the CIF file [CIF]
data_PuClO
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.970
_cell_length_b   3.970
_cell_length_c   6.860
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   108.130
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pu  Pu0  1  0.500  0.000  0.820  1.0
  Pu  Pu1  1  0.000  0.500  0.180  1.0
  Cl  Cl2  1  0.000  0.500  0.630  1.0
  Cl  Cl3  1  0.500  0.000  0.370  1.0
  O  O4  1  0.000  0.000  0.000  1.0
  O  O5  1  0.500  0.500  0.000  1.0
[/CIF]
.