The crystal structure described by RbC4Bi(NS)4 crystallizes in the orthorhombic P2_12_12 space group. Rb(1) is bonded in a 4-coordinate geometry to two equivalent N(1), two equivalent N(2), and four equivalent S(2) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one N(2) and one S(1) atom. In the second C site, C(2) is bonded in a distorted linear geometry to one N(1) and one S(2) atom. Bi(1) is bonded in a 8-coordinate geometry to two equivalent N(1), two equivalent N(2), two equivalent S(1), and two equivalent S(2) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted single-bond geometry to one Rb(1), one C(2), and one Bi(1) atom. In the second N site, N(2) is bonded in a distorted single-bond geometry to one Rb(1), one C(1), and one Bi(1) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted water-like geometry to one C(1) and one Bi(1) atom. In the second S site, S(2) is bonded in a 4-coordinate geometry to two equivalent Rb(1), one C(2), and one Bi(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_RbBiC4(SN)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.549
_cell_length_b   7.735
_cell_length_c   11.299
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   572.430
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.684  0.000  0.500  1.0
  Rb  Rb1  1  0.316  0.500  0.000  1.0
  Bi  Bi2  1  0.926  0.000  0.000  1.0
  Bi  Bi3  1  0.074  0.500  0.500  1.0
  C  C4  1  0.563  0.535  0.631  1.0
  C  C5  1  0.116  0.794  0.742  1.0
  C  C6  1  0.563  0.465  0.369  1.0
  C  C7  1  0.437  0.035  0.869  1.0
  C  C8  1  0.116  0.206  0.258  1.0
  C  C9  1  0.437  0.965  0.131  1.0
  C  C10  1  0.884  0.706  0.242  1.0
  C  C11  1  0.884  0.294  0.758  1.0
  S  S12  1  0.378  0.396  0.662  1.0
  S  S13  1  0.171  0.164  0.397  1.0
  S  S14  1  0.171  0.836  0.603  1.0
  S  S15  1  0.622  0.896  0.838  1.0
  S  S16  1  0.829  0.336  0.897  1.0
  S  S17  1  0.829  0.664  0.103  1.0
  S  S18  1  0.378  0.604  0.338  1.0
  S  S19  1  0.622  0.104  0.162  1.0
  N  N20  1  0.922  0.731  0.343  1.0
  N  N21  1  0.699  0.370  0.389  1.0
  N  N22  1  0.699  0.630  0.611  1.0
  N  N23  1  0.301  0.130  0.889  1.0
  N  N24  1  0.922  0.269  0.657  1.0
  N  N25  1  0.078  0.231  0.157  1.0
  N  N26  1  0.078  0.769  0.843  1.0
  N  N27  1  0.301  0.870  0.111  1.0
[/CIF]
.
The crystal structure described by RbC4Bi(NS)4 crystallizes in the orthorhombic P2_12_12 space group. Rb(1) is bonded in a 4-coordinate geometry to two equivalent N(1), two equivalent N(2), and four equivalent S(2) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one N(2) and one S(1) atom. In the second C site, C(2) is bonded in a distorted linear geometry to one N(1) and one S(2) atom. Bi(1) is bonded in a 8-coordinate geometry to two equivalent N(1), two equivalent N(2), two equivalent S(1), and two equivalent S(2) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted single-bond geometry to one Rb(1), one C(2), and one Bi(1) atom. In the second N site, N(2) is bonded in a distorted single-bond geometry to one Rb(1), one C(1), and one Bi(1) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted water-like geometry to one C(1) and one Bi(1) atom. In the second S site, S(2) is bonded in a 4-coordinate geometry to two equivalent Rb(1), one C(2), and one Bi(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_RbBiC4(SN)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.549
_cell_length_b   7.735
_cell_length_c   11.299
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   572.430
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.684  0.000  0.500  1.0
  Rb  Rb1  1  0.316  0.500  0.000  1.0
  Bi  Bi2  1  0.926  0.000  0.000  1.0
  Bi  Bi3  1  0.074  0.500  0.500  1.0
  C  C4  1  0.563  0.535  0.631  1.0
  C  C5  1  0.116  0.794  0.742  1.0
  C  C6  1  0.563  0.465  0.369  1.0
  C  C7  1  0.437  0.035  0.869  1.0
  C  C8  1  0.116  0.206  0.258  1.0
  C  C9  1  0.437  0.965  0.131  1.0
  C  C10  1  0.884  0.706  0.242  1.0
  C  C11  1  0.884  0.294  0.758  1.0
  S  S12  1  0.378  0.396  0.662  1.0
  S  S13  1  0.171  0.164  0.397  1.0
  S  S14  1  0.171  0.836  0.603  1.0
  S  S15  1  0.622  0.896  0.838  1.0
  S  S16  1  0.829  0.336  0.897  1.0
  S  S17  1  0.829  0.664  0.103  1.0
  S  S18  1  0.378  0.604  0.338  1.0
  S  S19  1  0.622  0.104  0.162  1.0
  N  N20  1  0.922  0.731  0.343  1.0
  N  N21  1  0.699  0.370  0.389  1.0
  N  N22  1  0.699  0.630  0.611  1.0
  N  N23  1  0.301  0.130  0.889  1.0
  N  N24  1  0.922  0.269  0.657  1.0
  N  N25  1  0.078  0.231  0.157  1.0
  N  N26  1  0.078  0.769  0.843  1.0
  N  N27  1  0.301  0.870  0.111  1.0
[/CIF]
.