The crystal structure described by Mn3Zn(O3I)8 crystallizes in the triclinic P1 space group. There are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in an octahedral geometry to one O(10), one O(13), one O(20), one O(21), one O(23), and one O(4) atom. In the second Mn site, Mn(2) is bonded in an octahedral geometry to one O(11), one O(15), one O(18), one O(2), one O(5), and one O(7) atom. In the third Mn site, Mn(3) is bonded in an octahedral geometry to one O(1), one O(12), one O(16), one O(17), one O(6), and one O(8) atom. Zn(1) is bonded in an octahedral geometry to one O(14), one O(19), one O(22), one O(24), one O(3), and one O(9) atom. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Mn(3) and one I(3) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Mn(2) and one I(4) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one I(3) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Mn(1) and one I(4) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Mn(2) and one I(1) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Mn(3) and one I(2) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one Mn(2) and one I(5) atom. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one Mn(3) and one I(6) atom. In the ninth O site, O(9) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one I(5) atom. In the tenth O site, O(10) is bonded in a bent 150 degrees geometry to one Mn(1) and one I(6) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one Mn(2) and one I(3) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Mn(3) and one I(4) atom. In the thirteenth O site, O(13) is bonded in a bent 150 degrees geometry to one Mn(1) and one I(7) atom. In the fourteenth O site, O(14) is bonded in a bent 150 degrees geometry to one Zn(1) and one I(8) atom. In the fifteenth O site, O(15) is bonded in a bent 120 degrees geometry to one Mn(2) and one I(7) atom. In the sixteenth O site, O(16) is bonded in a bent 120 degrees geometry to one Mn(3) and one I(8) atom. In the seventeenth O site, O(17) is bonded in a bent 150 degrees geometry to one Mn(3) and one I(7) atom. In the eighteenth O site, O(18) is bonded in a distorted bent 150 degrees geometry to one Mn(2) and one I(8) atom. In the nineteenth O site, O(19) is bonded in a bent 120 degrees geometry to one Zn(1) and one I(1) atom. In the twentieth O site, O(20) is bonded in a bent 120 degrees geometry to one Mn(1) and one I(2) atom. In the twenty-first O site, O(21) is bonded in a distorted bent 150 degrees geometry to one Mn(1) and one I(1) atom. In the twenty-second O site, O(22) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one I(2) atom. In the twenty-third O site, O(23) is bonded in a bent 120 degrees geometry to one Mn(1) and one I(5) atom. In the twenty-fourth O site, O(24) is bonded in a bent 120 degrees geometry to one Zn(1) and one I(6) atom. There are eight inequivalent I sites. In the first I site, I(1) is bonded in a 3-coordinate geometry to one O(19), one O(21), and one O(5) atom. In the second I site, I(2) is bonded in a 3-coordinate geometry to one O(20), one O(22), and one O(6) atom. In the third I site, I(3) is bonded in a 3-coordinate geometry to one O(1), one O(11), and one O(3) atom. In the fourth I site, I(4) is bonded in a 3-coordinate geometry to one O(12), one O(2), and one O(4) atom. In the fifth I site, I(5) is bonded in a distorted trigonal non-coplanar geometry to one O(23), one O(7), and one O(9) atom. In the sixth I site, I(6) is bonded in a distorted trigonal non-coplanar geometry to one O(10), one O(24), and one O(8) atom. In the seventh I site, I(7) is bonded in a distorted trigonal non-coplanar geometry to one O(13), one O(15), and one O(17) atom. In the eighth I site, I(8) is bonded in a distorted trigonal non-coplanar geometry to one O(14), one O(16), and one O(18) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mn3Zn(IO3)8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.310
_cell_length_b   11.224
_cell_length_c   11.256
_cell_angle_alpha   119.527
_cell_angle_beta   89.975
_cell_angle_gamma   90.086
_symmetry_Int_Tables_number   1
_cell_volume   583.667
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.652  0.239  0.493  1.0
  Mn  Mn1  1  0.149  0.260  0.004  1.0
  Mn  Mn2  1  0.647  0.740  0.996  1.0
  Zn  Zn3  1  0.160  0.760  0.507  1.0
  I  I4  1  0.235  0.420  0.349  1.0
  I  I5  1  0.740  0.584  0.652  1.0
  I  I6  1  0.225  0.913  0.846  1.0
  I  I7  1  0.727  0.087  0.151  1.0
  I  I8  1  0.747  0.080  0.682  1.0
  I  I9  1  0.242  0.914  0.318  1.0
  I  I10  1  0.247  0.417  0.815  1.0
  I  I11  1  0.749  0.584  0.188  1.0
  O  O12  1  0.424  0.880  0.960  1.0
  O  O13  1  0.924  0.119  0.036  1.0
  O  O14  1  0.384  0.802  0.681  1.0
  O  O15  1  0.887  0.197  0.315  1.0
  O  O16  1  0.387  0.307  0.183  1.0
  O  O17  1  0.888  0.696  0.818  1.0
  O  O18  1  0.919  0.221  0.823  1.0
  O  O19  1  0.418  0.777  0.176  1.0
  O  O20  1  0.941  0.934  0.657  1.0
  O  O21  1  0.435  0.062  0.344  1.0
  O  O22  1  0.374  0.076  0.884  1.0
  O  O23  1  0.873  0.924  0.115  1.0
  O  O24  1  0.424  0.280  0.673  1.0
  O  O25  1  0.929  0.721  0.329  1.0
  O  O26  1  0.365  0.394  0.955  1.0
  O  O27  1  0.865  0.607  0.046  1.0
  O  O28  1  0.434  0.566  0.840  1.0
  O  O29  1  0.934  0.434  0.160  1.0
  O  O30  1  0.377  0.584  0.383  1.0
  O  O31  1  0.882  0.421  0.618  1.0
  O  O32  1  0.450  0.388  0.458  1.0
  O  O33  1  0.954  0.616  0.541  1.0
  O  O34  1  0.863  0.104  0.541  1.0
  O  O35  1  0.358  0.891  0.459  1.0
[/CIF]
.
The crystal structure described by Mn3Zn(O3I)8 crystallizes in the triclinic P1 space group. There are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in an octahedral geometry to one O(10), one O(13), one O(20), one O(21), one O(23), and one O(4) atom. In the second Mn site, Mn(2) is bonded in an octahedral geometry to one O(11), one O(15), one O(18), one O(2), one O(5), and one O(7) atom. In the third Mn site, Mn(3) is bonded in an octahedral geometry to one O(1), one O(12), one O(16), one O(17), one O(6), and one O(8) atom. Zn(1) is bonded in an octahedral geometry to one O(14), one O(19), one O(22), one O(24), one O(3), and one O(9) atom. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Mn(3) and one I(3) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Mn(2) and one I(4) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one I(3) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Mn(1) and one I(4) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Mn(2) and one I(1) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Mn(3) and one I(2) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one Mn(2) and one I(5) atom. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one Mn(3) and one I(6) atom. In the ninth O site, O(9) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one I(5) atom. In the tenth O site, O(10) is bonded in a bent 150 degrees geometry to one Mn(1) and one I(6) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one Mn(2) and one I(3) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Mn(3) and one I(4) atom. In the thirteenth O site, O(13) is bonded in a bent 150 degrees geometry to one Mn(1) and one I(7) atom. In the fourteenth O site, O(14) is bonded in a bent 150 degrees geometry to one Zn(1) and one I(8) atom. In the fifteenth O site, O(15) is bonded in a bent 120 degrees geometry to one Mn(2) and one I(7) atom. In the sixteenth O site, O(16) is bonded in a bent 120 degrees geometry to one Mn(3) and one I(8) atom. In the seventeenth O site, O(17) is bonded in a bent 150 degrees geometry to one Mn(3) and one I(7) atom. In the eighteenth O site, O(18) is bonded in a distorted bent 150 degrees geometry to one Mn(2) and one I(8) atom. In the nineteenth O site, O(19) is bonded in a bent 120 degrees geometry to one Zn(1) and one I(1) atom. In the twentieth O site, O(20) is bonded in a bent 120 degrees geometry to one Mn(1) and one I(2) atom. In the twenty-first O site, O(21) is bonded in a distorted bent 150 degrees geometry to one Mn(1) and one I(1) atom. In the twenty-second O site, O(22) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one I(2) atom. In the twenty-third O site, O(23) is bonded in a bent 120 degrees geometry to one Mn(1) and one I(5) atom. In the twenty-fourth O site, O(24) is bonded in a bent 120 degrees geometry to one Zn(1) and one I(6) atom. There are eight inequivalent I sites. In the first I site, I(1) is bonded in a 3-coordinate geometry to one O(19), one O(21), and one O(5) atom. In the second I site, I(2) is bonded in a 3-coordinate geometry to one O(20), one O(22), and one O(6) atom. In the third I site, I(3) is bonded in a 3-coordinate geometry to one O(1), one O(11), and one O(3) atom. In the fourth I site, I(4) is bonded in a 3-coordinate geometry to one O(12), one O(2), and one O(4) atom. In the fifth I site, I(5) is bonded in a distorted trigonal non-coplanar geometry to one O(23), one O(7), and one O(9) atom. In the sixth I site, I(6) is bonded in a distorted trigonal non-coplanar geometry to one O(10), one O(24), and one O(8) atom. In the seventh I site, I(7) is bonded in a distorted trigonal non-coplanar geometry to one O(13), one O(15), and one O(17) atom. In the eighth I site, I(8) is bonded in a distorted trigonal non-coplanar geometry to one O(14), one O(16), and one O(18) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mn3Zn(IO3)8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.310
_cell_length_b   11.224
_cell_length_c   11.256
_cell_angle_alpha   119.527
_cell_angle_beta   89.975
_cell_angle_gamma   90.086
_symmetry_Int_Tables_number   1
_cell_volume   583.667
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.652  0.239  0.493  1.0
  Mn  Mn1  1  0.149  0.260  0.004  1.0
  Mn  Mn2  1  0.647  0.740  0.996  1.0
  Zn  Zn3  1  0.160  0.760  0.507  1.0
  I  I4  1  0.235  0.420  0.349  1.0
  I  I5  1  0.740  0.584  0.652  1.0
  I  I6  1  0.225  0.913  0.846  1.0
  I  I7  1  0.727  0.087  0.151  1.0
  I  I8  1  0.747  0.080  0.682  1.0
  I  I9  1  0.242  0.914  0.318  1.0
  I  I10  1  0.247  0.417  0.815  1.0
  I  I11  1  0.749  0.584  0.188  1.0
  O  O12  1  0.424  0.880  0.960  1.0
  O  O13  1  0.924  0.119  0.036  1.0
  O  O14  1  0.384  0.802  0.681  1.0
  O  O15  1  0.887  0.197  0.315  1.0
  O  O16  1  0.387  0.307  0.183  1.0
  O  O17  1  0.888  0.696  0.818  1.0
  O  O18  1  0.919  0.221  0.823  1.0
  O  O19  1  0.418  0.777  0.176  1.0
  O  O20  1  0.941  0.934  0.657  1.0
  O  O21  1  0.435  0.062  0.344  1.0
  O  O22  1  0.374  0.076  0.884  1.0
  O  O23  1  0.873  0.924  0.115  1.0
  O  O24  1  0.424  0.280  0.673  1.0
  O  O25  1  0.929  0.721  0.329  1.0
  O  O26  1  0.365  0.394  0.955  1.0
  O  O27  1  0.865  0.607  0.046  1.0
  O  O28  1  0.434  0.566  0.840  1.0
  O  O29  1  0.934  0.434  0.160  1.0
  O  O30  1  0.377  0.584  0.383  1.0
  O  O31  1  0.882  0.421  0.618  1.0
  O  O32  1  0.450  0.388  0.458  1.0
  O  O33  1  0.954  0.616  0.541  1.0
  O  O34  1  0.863  0.104  0.541  1.0
  O  O35  1  0.358  0.891  0.459  1.0
[/CIF]
.