The structure described by MnAg2SnS4 is Stannite-like structured and crystallizes in the orthorhombic Pmn2_1 space group. Mn(1) is bonded to one S(1), one S(3), and two equivalent S(2) atoms to form MnS4 tetrahedra that share corners with four equivalent Sn(1)S4 tetrahedra and corners with eight equivalent Ag(1)S4 tetrahedra. Ag(1) is bonded to one S(1), one S(3), and two equivalent S(2) atoms to form AgS4 tetrahedra that share corners with four equivalent Mn(1)S4 tetrahedra, corners with four equivalent Ag(1)S4 tetrahedra, and corners with four equivalent Sn(1)S4 tetrahedra. Sn(1) is bonded to one S(1), one S(3), and two equivalent S(2) atoms to form SnS4 tetrahedra that share corners with four equivalent Mn(1)S4 tetrahedra and corners with eight equivalent Ag(1)S4 tetrahedra. There are three inequivalent S sites. In the first S site, S(1) is bonded to one Mn(1), two equivalent Ag(1), and one Sn(1) atom to form corner-sharing SMnAg2Sn tetrahedra. In the second S site, S(2) is bonded to one Mn(1), two equivalent Ag(1), and one Sn(1) atom to form corner-sharing SMnAg2Sn tetrahedra. In the third S site, S(3) is bonded to one Mn(1), two equivalent Ag(1), and one Sn(1) atom to form corner-sharing SMnAg2Sn tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_MnAg2SnS4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.787
_cell_length_b   7.198
_cell_length_c   8.002
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   390.927
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.505  0.346  0.000  1.0
  Mn  Mn1  1  0.005  0.654  0.500  1.0
  Ag  Ag2  1  0.517  0.828  0.752  1.0
  Ag  Ag3  1  0.017  0.172  0.748  1.0
  Ag  Ag4  1  0.017  0.172  0.252  1.0
  Ag  Ag5  1  0.517  0.828  0.248  1.0
  Sn  Sn6  1  0.001  0.661  0.000  1.0
  Sn  Sn7  1  0.501  0.339  0.500  1.0
  S  S8  1  0.860  0.349  0.000  1.0
  S  S9  1  0.360  0.651  0.500  1.0
  S  S10  1  0.894  0.829  0.746  1.0
  S  S11  1  0.394  0.171  0.754  1.0
  S  S12  1  0.394  0.171  0.246  1.0
  S  S13  1  0.894  0.829  0.254  1.0
  S  S14  1  0.363  0.651  0.000  1.0
  S  S15  1  0.863  0.349  0.500  1.0
[/CIF]
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The structure described by MnAg2SnS4 is Stannite-like structured and crystallizes in the orthorhombic Pmn2_1 space group. Mn(1) is bonded to one S(1), one S(3), and two equivalent S(2) atoms to form MnS4 tetrahedra that share corners with four equivalent Sn(1)S4 tetrahedra and corners with eight equivalent Ag(1)S4 tetrahedra. Ag(1) is bonded to one S(1), one S(3), and two equivalent S(2) atoms to form AgS4 tetrahedra that share corners with four equivalent Mn(1)S4 tetrahedra, corners with four equivalent Ag(1)S4 tetrahedra, and corners with four equivalent Sn(1)S4 tetrahedra. Sn(1) is bonded to one S(1), one S(3), and two equivalent S(2) atoms to form SnS4 tetrahedra that share corners with four equivalent Mn(1)S4 tetrahedra and corners with eight equivalent Ag(1)S4 tetrahedra. There are three inequivalent S sites. In the first S site, S(1) is bonded to one Mn(1), two equivalent Ag(1), and one Sn(1) atom to form corner-sharing SMnAg2Sn tetrahedra. In the second S site, S(2) is bonded to one Mn(1), two equivalent Ag(1), and one Sn(1) atom to form corner-sharing SMnAg2Sn tetrahedra. In the third S site, S(3) is bonded to one Mn(1), two equivalent Ag(1), and one Sn(1) atom to form corner-sharing SMnAg2Sn tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_MnAg2SnS4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.787
_cell_length_b   7.198
_cell_length_c   8.002
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   390.927
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.505  0.346  0.000  1.0
  Mn  Mn1  1  0.005  0.654  0.500  1.0
  Ag  Ag2  1  0.517  0.828  0.752  1.0
  Ag  Ag3  1  0.017  0.172  0.748  1.0
  Ag  Ag4  1  0.017  0.172  0.252  1.0
  Ag  Ag5  1  0.517  0.828  0.248  1.0
  Sn  Sn6  1  0.001  0.661  0.000  1.0
  Sn  Sn7  1  0.501  0.339  0.500  1.0
  S  S8  1  0.860  0.349  0.000  1.0
  S  S9  1  0.360  0.651  0.500  1.0
  S  S10  1  0.894  0.829  0.746  1.0
  S  S11  1  0.394  0.171  0.754  1.0
  S  S12  1  0.394  0.171  0.246  1.0
  S  S13  1  0.894  0.829  0.254  1.0
  S  S14  1  0.363  0.651  0.000  1.0
  S  S15  1  0.863  0.349  0.500  1.0
[/CIF]
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