The material described by Li2VP3O10 crystallizes in the monoclinic C2/c space group. Li(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra, corners with three equivalent P(1)O4 tetrahedra, and  an edgeedge with one V(1)O6 octahedra. The corner-sharing octahedral tilt angles are 38°. V(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms to form distorted VO6 octahedra that share corners with two equivalent Li(1)O4 tetrahedra, corners with four equivalent P(1)O4 tetrahedra,  an edgeedge with one P(2)O4 tetrahedra, and edges with two equivalent Li(1)O4 tetrahedra. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(2), one O(3), one O(4), and one O(5) atom to form PO4 tetrahedra that share corners with two equivalent V(1)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra, and corners with three equivalent Li(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 31-41°. In the second P site, P(2) is bonded to two equivalent O(1) and two equivalent O(5) atoms to form PO4 tetrahedra that share corners with two equivalent Li(1)O4 tetrahedra, corners with two equivalent P(1)O4 tetrahedra, and  an edgeedge with one V(1)O6 octahedra. There are five inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Li(1), one V(1), and one P(2) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Li(1) and one P(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Li(1), one V(1), and one P(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal non-coplanar geometry to one Li(1), one V(1), and one P(1) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. is represented by the CIF card [CIF]
data_Li2VP3O10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.018
_cell_length_b   8.018
_cell_length_c   9.715
_cell_angle_alpha   57.472
_cell_angle_beta   57.472
_cell_angle_gamma   53.197
_symmetry_Int_Tables_number   1
_cell_volume   399.564
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.715  0.744  0.963  1.0
  Li  Li1  1  0.744  0.715  0.463  1.0
  Li  Li2  1  0.256  0.285  0.537  1.0
  Li  Li3  1  0.285  0.256  0.037  1.0
  V  V4  1  0.334  0.666  0.750  1.0
  V  V5  1  0.666  0.334  0.250  1.0
  P  P6  1  0.803  0.441  0.814  1.0
  P  P7  1  0.441  0.803  0.314  1.0
  P  P8  1  0.951  0.049  0.750  1.0
  P  P9  1  0.049  0.951  0.250  1.0
  P  P10  1  0.559  0.197  0.686  1.0
  P  P11  1  0.197  0.559  0.186  1.0
  O  O12  1  0.973  0.815  0.847  1.0
  O  O13  1  0.815  0.973  0.347  1.0
  O  O14  1  0.552  0.983  0.811  1.0
  O  O15  1  0.723  0.470  0.985  1.0
  O  O16  1  0.625  0.606  0.721  1.0
  O  O17  1  0.983  0.552  0.311  1.0
  O  O18  1  0.821  0.192  0.874  1.0
  O  O19  1  0.470  0.723  0.485  1.0
  O  O20  1  0.606  0.625  0.221  1.0
  O  O21  1  0.808  0.179  0.626  1.0
  O  O22  1  0.192  0.821  0.374  1.0
  O  O23  1  0.394  0.375  0.779  1.0
  O  O24  1  0.530  0.277  0.515  1.0
  O  O25  1  0.179  0.808  0.126  1.0
  O  O26  1  0.017  0.448  0.689  1.0
  O  O27  1  0.375  0.394  0.279  1.0
  O  O28  1  0.277  0.530  0.015  1.0
  O  O29  1  0.448  0.017  0.189  1.0
  O  O30  1  0.185  0.027  0.653  1.0
  O  O31  1  0.027  0.185  0.153  1.0
[/CIF]
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The material described by Li2VP3O10 crystallizes in the monoclinic C2/c space group. Li(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra, corners with three equivalent P(1)O4 tetrahedra, and  an edgeedge with one V(1)O6 octahedra. The corner-sharing octahedral tilt angles are 38°. V(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms to form distorted VO6 octahedra that share corners with two equivalent Li(1)O4 tetrahedra, corners with four equivalent P(1)O4 tetrahedra,  an edgeedge with one P(2)O4 tetrahedra, and edges with two equivalent Li(1)O4 tetrahedra. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(2), one O(3), one O(4), and one O(5) atom to form PO4 tetrahedra that share corners with two equivalent V(1)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra, and corners with three equivalent Li(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 31-41°. In the second P site, P(2) is bonded to two equivalent O(1) and two equivalent O(5) atoms to form PO4 tetrahedra that share corners with two equivalent Li(1)O4 tetrahedra, corners with two equivalent P(1)O4 tetrahedra, and  an edgeedge with one V(1)O6 octahedra. There are five inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Li(1), one V(1), and one P(2) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Li(1) and one P(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Li(1), one V(1), and one P(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal non-coplanar geometry to one Li(1), one V(1), and one P(1) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. is represented by the CIF card [CIF]
data_Li2VP3O10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.018
_cell_length_b   8.018
_cell_length_c   9.715
_cell_angle_alpha   57.472
_cell_angle_beta   57.472
_cell_angle_gamma   53.197
_symmetry_Int_Tables_number   1
_cell_volume   399.564
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.715  0.744  0.963  1.0
  Li  Li1  1  0.744  0.715  0.463  1.0
  Li  Li2  1  0.256  0.285  0.537  1.0
  Li  Li3  1  0.285  0.256  0.037  1.0
  V  V4  1  0.334  0.666  0.750  1.0
  V  V5  1  0.666  0.334  0.250  1.0
  P  P6  1  0.803  0.441  0.814  1.0
  P  P7  1  0.441  0.803  0.314  1.0
  P  P8  1  0.951  0.049  0.750  1.0
  P  P9  1  0.049  0.951  0.250  1.0
  P  P10  1  0.559  0.197  0.686  1.0
  P  P11  1  0.197  0.559  0.186  1.0
  O  O12  1  0.973  0.815  0.847  1.0
  O  O13  1  0.815  0.973  0.347  1.0
  O  O14  1  0.552  0.983  0.811  1.0
  O  O15  1  0.723  0.470  0.985  1.0
  O  O16  1  0.625  0.606  0.721  1.0
  O  O17  1  0.983  0.552  0.311  1.0
  O  O18  1  0.821  0.192  0.874  1.0
  O  O19  1  0.470  0.723  0.485  1.0
  O  O20  1  0.606  0.625  0.221  1.0
  O  O21  1  0.808  0.179  0.626  1.0
  O  O22  1  0.192  0.821  0.374  1.0
  O  O23  1  0.394  0.375  0.779  1.0
  O  O24  1  0.530  0.277  0.515  1.0
  O  O25  1  0.179  0.808  0.126  1.0
  O  O26  1  0.017  0.448  0.689  1.0
  O  O27  1  0.375  0.394  0.279  1.0
  O  O28  1  0.277  0.530  0.015  1.0
  O  O29  1  0.448  0.017  0.189  1.0
  O  O30  1  0.185  0.027  0.653  1.0
  O  O31  1  0.027  0.185  0.153  1.0
[/CIF]
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