The crystal structure described by Li4Mn3Co3(WO8)2 is Hausmannite-derived structured and crystallizes in the monoclinic Cm space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(12), one O(3), and two equivalent O(9) atoms to form LiO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, corners with three equivalent W(2)O6 octahedra, and corners with four equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-62°. In the second Li site, Li(2) is bonded to one O(5), one O(7), and two equivalent O(11) atoms to form distorted LiO4 tetrahedra that share  a cornercorner with one Co(2)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with three equivalent W(2)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra, and edges with two equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 58-64°. In the third Li site, Li(3) is bonded to one O(4), one O(8), and two equivalent O(1) atoms to form distorted LiO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, corners with three equivalent W(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 59-66°. In the fourth Li site, Li(4) is bonded to one O(10), one O(2), and two equivalent O(6) atoms to form LiO4 tetrahedra that share  a cornercorner with one Co(2)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with three equivalent W(1)O6 octahedra, and corners with four equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-62°. There are two inequivalent W sites. In the first W site, W(1) is bonded to one O(2), one O(8), two equivalent O(1), and two equivalent O(6) atoms to form WO6 octahedra that share corners with two equivalent Co(2)O6 octahedra, corners with four equivalent Mn(2)O6 octahedra, corners with three equivalent Li(3)O4 tetrahedra, corners with three equivalent Li(4)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra, and edges with two equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-51°. In the second W site, W(2) is bonded to one O(12), one O(7), two equivalent O(11), and two equivalent O(9) atoms to form WO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra, corners with four equivalent Co(1)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra, corners with three equivalent Li(2)O4 tetrahedra,  an edgeedge with one Co(2)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-53°. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(3), one O(4), two equivalent O(11), and two equivalent O(6) atoms to form MnO6 octahedra that share corners with two equivalent W(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one W(1)O6 octahedra, edges with four equivalent Co(1)O6 octahedra, and  an edgeedge with one Li(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 53°. In the second Mn site, Mn(2) is bonded to one O(1), one O(10), one O(12), one O(5), one O(8), and one O(9) atom to form MnO6 octahedra that share corners with two equivalent W(1)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one W(2)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 50-51°. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(11), one O(2), one O(3), one O(4), one O(6), and one O(7) atom to form CoO6 octahedra that share corners with two equivalent W(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one W(1)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and  an edgeedge with one Li(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 48°. In the second Co site, Co(2) is bonded to one O(10), one O(5), two equivalent O(1), and two equivalent O(9) atoms to form CoO6 octahedra that share corners with two equivalent W(1)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one W(2)O6 octahedra, edges with four equivalent Mn(2)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles are 46°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Li(3), one W(1), one Mn(2), and one Co(2) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one Li(4), one W(1), and two equivalent Co(1) atoms. In the third O site, O(3) is bonded to one Li(1), one Mn(1), and two equivalent Co(1) atoms to form distorted corner-sharing OLiMnCo2 trigonal pyramids. In the fourth O site, O(4) is bonded to one Li(3), one Mn(1), and two equivalent Co(1) atoms to form corner-sharing OLiMnCo2 tetrahedra. In the fifth O site, O(5) is bonded to one Li(2), two equivalent Mn(2), and one Co(2) atom to form corner-sharing OLiMn2Co tetrahedra. In the sixth O site, O(6) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), one W(1), one Mn(1), and one Co(1) atom. In the seventh O site, O(7) is bonded in a rectangular see-saw-like geometry to one Li(2), one W(2), and two equivalent Co(1) atoms. In the eighth O site, O(8) is bonded in a rectangular see-saw-like geometry to one Li(3), one W(1), and two equivalent Mn(2) atoms. In the ninth O site, O(9) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one W(2), one Mn(2), and one Co(2) atom. In the tenth O site, O(10) is bonded to one Li(4), two equivalent Mn(2), and one Co(2) atom to form distorted corner-sharing OLiMn2Co trigonal pyramids. In the eleventh O site, O(11) is bonded in a rectangular see-saw-like geometry to one Li(2), one W(2), one Mn(1), and one Co(1) atom. In the twelfth O site, O(12) is bonded in a 4-coordinate geometry to one Li(1), one W(2), and two equivalent Mn(2) atoms. is represented by the CIF file [CIF]
data_Li4Mn3Co3(WO8)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.995
_cell_length_b   5.995
_cell_length_c   9.863
_cell_angle_alpha   88.526
_cell_angle_beta   88.526
_cell_angle_gamma   58.953
_symmetry_Int_Tables_number   1
_cell_volume   303.591
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.662  0.662  0.093  1.0
  Li  Li1  1  0.998  0.998  0.010  1.0
  Li  Li2  1  0.002  0.002  0.516  1.0
  Li  Li3  1  0.332  0.332  0.593  1.0
  Mn  Mn4  1  0.832  0.832  0.789  1.0
  Mn  Mn5  1  0.168  0.658  0.286  1.0
  Mn  Mn6  1  0.658  0.168  0.286  1.0
  Co  Co7  1  0.351  0.813  0.783  1.0
  Co  Co8  1  0.813  0.351  0.783  1.0
  Co  Co9  1  0.169  0.169  0.287  1.0
  W  W10  1  0.667  0.667  0.514  1.0
  W  W11  1  0.320  0.320  0.013  1.0
  O  O12  1  0.352  0.834  0.417  1.0
  O  O13  1  0.517  0.517  0.645  1.0
  O  O14  1  0.669  0.669  0.887  1.0
  O  O15  1  0.999  0.999  0.705  1.0
  O  O16  1  0.997  0.997  0.199  1.0
  O  O17  1  0.834  0.352  0.417  1.0
  O  O18  1  0.522  0.960  0.648  1.0
  O  O19  1  0.960  0.522  0.648  1.0
  O  O20  1  0.171  0.171  0.911  1.0
  O  O21  1  0.834  0.834  0.408  1.0
  O  O22  1  0.033  0.480  0.143  1.0
  O  O23  1  0.480  0.033  0.143  1.0
  O  O24  1  0.338  0.338  0.386  1.0
  O  O25  1  0.175  0.652  0.914  1.0
  O  O26  1  0.477  0.477  0.157  1.0
  O  O27  1  0.652  0.175  0.914  1.0
[/CIF]
.
The crystal structure described by Li4Mn3Co3(WO8)2 is Hausmannite-derived structured and crystallizes in the monoclinic Cm space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(12), one O(3), and two equivalent O(9) atoms to form LiO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, corners with three equivalent W(2)O6 octahedra, and corners with four equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-62°. In the second Li site, Li(2) is bonded to one O(5), one O(7), and two equivalent O(11) atoms to form distorted LiO4 tetrahedra that share  a cornercorner with one Co(2)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with three equivalent W(2)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra, and edges with two equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 58-64°. In the third Li site, Li(3) is bonded to one O(4), one O(8), and two equivalent O(1) atoms to form distorted LiO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, corners with three equivalent W(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 59-66°. In the fourth Li site, Li(4) is bonded to one O(10), one O(2), and two equivalent O(6) atoms to form LiO4 tetrahedra that share  a cornercorner with one Co(2)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with three equivalent W(1)O6 octahedra, and corners with four equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-62°. There are two inequivalent W sites. In the first W site, W(1) is bonded to one O(2), one O(8), two equivalent O(1), and two equivalent O(6) atoms to form WO6 octahedra that share corners with two equivalent Co(2)O6 octahedra, corners with four equivalent Mn(2)O6 octahedra, corners with three equivalent Li(3)O4 tetrahedra, corners with three equivalent Li(4)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra, and edges with two equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-51°. In the second W site, W(2) is bonded to one O(12), one O(7), two equivalent O(11), and two equivalent O(9) atoms to form WO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra, corners with four equivalent Co(1)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra, corners with three equivalent Li(2)O4 tetrahedra,  an edgeedge with one Co(2)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-53°. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(3), one O(4), two equivalent O(11), and two equivalent O(6) atoms to form MnO6 octahedra that share corners with two equivalent W(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one W(1)O6 octahedra, edges with four equivalent Co(1)O6 octahedra, and  an edgeedge with one Li(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 53°. In the second Mn site, Mn(2) is bonded to one O(1), one O(10), one O(12), one O(5), one O(8), and one O(9) atom to form MnO6 octahedra that share corners with two equivalent W(1)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one W(2)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 50-51°. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(11), one O(2), one O(3), one O(4), one O(6), and one O(7) atom to form CoO6 octahedra that share corners with two equivalent W(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one W(1)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and  an edgeedge with one Li(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 48°. In the second Co site, Co(2) is bonded to one O(10), one O(5), two equivalent O(1), and two equivalent O(9) atoms to form CoO6 octahedra that share corners with two equivalent W(1)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one W(2)O6 octahedra, edges with four equivalent Mn(2)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles are 46°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Li(3), one W(1), one Mn(2), and one Co(2) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one Li(4), one W(1), and two equivalent Co(1) atoms. In the third O site, O(3) is bonded to one Li(1), one Mn(1), and two equivalent Co(1) atoms to form distorted corner-sharing OLiMnCo2 trigonal pyramids. In the fourth O site, O(4) is bonded to one Li(3), one Mn(1), and two equivalent Co(1) atoms to form corner-sharing OLiMnCo2 tetrahedra. In the fifth O site, O(5) is bonded to one Li(2), two equivalent Mn(2), and one Co(2) atom to form corner-sharing OLiMn2Co tetrahedra. In the sixth O site, O(6) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), one W(1), one Mn(1), and one Co(1) atom. In the seventh O site, O(7) is bonded in a rectangular see-saw-like geometry to one Li(2), one W(2), and two equivalent Co(1) atoms. In the eighth O site, O(8) is bonded in a rectangular see-saw-like geometry to one Li(3), one W(1), and two equivalent Mn(2) atoms. In the ninth O site, O(9) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one W(2), one Mn(2), and one Co(2) atom. In the tenth O site, O(10) is bonded to one Li(4), two equivalent Mn(2), and one Co(2) atom to form distorted corner-sharing OLiMn2Co trigonal pyramids. In the eleventh O site, O(11) is bonded in a rectangular see-saw-like geometry to one Li(2), one W(2), one Mn(1), and one Co(1) atom. In the twelfth O site, O(12) is bonded in a 4-coordinate geometry to one Li(1), one W(2), and two equivalent Mn(2) atoms. is represented by the CIF file [CIF]
data_Li4Mn3Co3(WO8)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.995
_cell_length_b   5.995
_cell_length_c   9.863
_cell_angle_alpha   88.526
_cell_angle_beta   88.526
_cell_angle_gamma   58.953
_symmetry_Int_Tables_number   1
_cell_volume   303.591
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.662  0.662  0.093  1.0
  Li  Li1  1  0.998  0.998  0.010  1.0
  Li  Li2  1  0.002  0.002  0.516  1.0
  Li  Li3  1  0.332  0.332  0.593  1.0
  Mn  Mn4  1  0.832  0.832  0.789  1.0
  Mn  Mn5  1  0.168  0.658  0.286  1.0
  Mn  Mn6  1  0.658  0.168  0.286  1.0
  Co  Co7  1  0.351  0.813  0.783  1.0
  Co  Co8  1  0.813  0.351  0.783  1.0
  Co  Co9  1  0.169  0.169  0.287  1.0
  W  W10  1  0.667  0.667  0.514  1.0
  W  W11  1  0.320  0.320  0.013  1.0
  O  O12  1  0.352  0.834  0.417  1.0
  O  O13  1  0.517  0.517  0.645  1.0
  O  O14  1  0.669  0.669  0.887  1.0
  O  O15  1  0.999  0.999  0.705  1.0
  O  O16  1  0.997  0.997  0.199  1.0
  O  O17  1  0.834  0.352  0.417  1.0
  O  O18  1  0.522  0.960  0.648  1.0
  O  O19  1  0.960  0.522  0.648  1.0
  O  O20  1  0.171  0.171  0.911  1.0
  O  O21  1  0.834  0.834  0.408  1.0
  O  O22  1  0.033  0.480  0.143  1.0
  O  O23  1  0.480  0.033  0.143  1.0
  O  O24  1  0.338  0.338  0.386  1.0
  O  O25  1  0.175  0.652  0.914  1.0
  O  O26  1  0.477  0.477  0.157  1.0
  O  O27  1  0.652  0.175  0.914  1.0
[/CIF]
.