The material structure described by LiSbO3 crystallizes in the triclinic P-1 space group. Li(1) is bonded to one O(2), one O(3), and two equivalent O(1) atoms to form LiO4 tetrahedra that share corners with eight equivalent Sb(1)O6 octahedra and  an edgeedge with one Li(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 58-62°. Sb(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form SbO6 octahedra that share corners with eight equivalent Li(1)O4 tetrahedra and edges with three equivalent Sb(1)O6 octahedra. There are three inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Li(1) and two equivalent Sb(1) atoms to form distorted edge-sharing OLi2Sb2 tetrahedra. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Li(1) and two equivalent Sb(1) atoms. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Li(1) and two equivalent Sb(1) atoms. is represented by the CIF card [CIF]
data_LiSbO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.622
_cell_length_b   5.234
_cell_length_c   9.702
_cell_angle_alpha   86.946
_cell_angle_beta   42.983
_cell_angle_gamma   51.171
_symmetry_Int_Tables_number   1
_cell_volume   115.399
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.043  0.457  0.156  1.0
  Li  Li1  1  0.955  0.543  0.845  1.0
  Sb  Sb2  1  0.338  0.500  0.331  1.0
  Sb  Sb3  1  0.661  0.500  0.669  1.0
  O  O4  1  0.207  0.292  0.279  1.0
  O  O5  1  0.791  0.708  0.722  1.0
  O  O6  1  0.676  0.179  0.553  1.0
  O  O7  1  0.036  0.820  0.091  1.0
  O  O8  1  0.322  0.821  0.448  1.0
  O  O9  1  0.962  0.180  0.909  1.0
[/CIF]
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The material structure described by LiSbO3 crystallizes in the triclinic P-1 space group. Li(1) is bonded to one O(2), one O(3), and two equivalent O(1) atoms to form LiO4 tetrahedra that share corners with eight equivalent Sb(1)O6 octahedra and  an edgeedge with one Li(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 58-62°. Sb(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form SbO6 octahedra that share corners with eight equivalent Li(1)O4 tetrahedra and edges with three equivalent Sb(1)O6 octahedra. There are three inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Li(1) and two equivalent Sb(1) atoms to form distorted edge-sharing OLi2Sb2 tetrahedra. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Li(1) and two equivalent Sb(1) atoms. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Li(1) and two equivalent Sb(1) atoms. is represented by the CIF card [CIF]
data_LiSbO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.622
_cell_length_b   5.234
_cell_length_c   9.702
_cell_angle_alpha   86.946
_cell_angle_beta   42.983
_cell_angle_gamma   51.171
_symmetry_Int_Tables_number   1
_cell_volume   115.399
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.043  0.457  0.156  1.0
  Li  Li1  1  0.955  0.543  0.845  1.0
  Sb  Sb2  1  0.338  0.500  0.331  1.0
  Sb  Sb3  1  0.661  0.500  0.669  1.0
  O  O4  1  0.207  0.292  0.279  1.0
  O  O5  1  0.791  0.708  0.722  1.0
  O  O6  1  0.676  0.179  0.553  1.0
  O  O7  1  0.036  0.820  0.091  1.0
  O  O8  1  0.322  0.821  0.448  1.0
  O  O9  1  0.962  0.180  0.909  1.0
[/CIF]
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