The structure described by LiVBO4 crystallizes in the trigonal R-3 space group. Li(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form distorted LiO4 tetrahedra that share corners with four equivalent B(1)O4 tetrahedra and corners with four equivalent V(1)O4 trigonal pyramids. V(1) is bonded to one O(2), one O(3), and two equivalent O(1) atoms to form distorted VO4 trigonal pyramids that share corners with two equivalent B(1)O4 tetrahedra, corners with four equivalent Li(1)O4 tetrahedra, and corners with two equivalent V(1)O4 trigonal pyramids. B(1) is bonded to one O(2), one O(3), and two equivalent O(4) atoms to form BO4 tetrahedra that share corners with two equivalent B(1)O4 tetrahedra, corners with four equivalent Li(1)O4 tetrahedra, and corners with two equivalent V(1)O4 trigonal pyramids. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Li(1) and two equivalent V(1) atoms. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Li(1), one V(1), and one B(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Li(1), one V(1), and one B(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Li(1) and two equivalent B(1) atoms. is represented by the CIF file [CIF]
data_LiVBO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.038
_cell_length_b   8.038
_cell_length_c   8.038
_cell_angle_alpha   106.601
_cell_angle_beta   106.601
_cell_angle_gamma   106.601
_symmetry_Int_Tables_number   1
_cell_volume   437.065
_cell_formula_units_Z   6
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.915  0.524  0.764  1.0
  Li  Li1  1  0.476  0.236  0.085  1.0
  Li  Li2  1  0.236  0.085  0.476  1.0
  Li  Li3  1  0.764  0.915  0.524  1.0
  Li  Li4  1  0.524  0.764  0.915  1.0
  Li  Li5  1  0.085  0.476  0.236  1.0
  V  V6  1  0.863  0.147  0.298  1.0
  V  V7  1  0.702  0.137  0.853  1.0
  V  V8  1  0.853  0.702  0.137  1.0
  V  V9  1  0.147  0.298  0.863  1.0
  V  V10  1  0.298  0.863  0.147  1.0
  V  V11  1  0.137  0.853  0.702  1.0
  B  B12  1  0.616  0.231  0.455  1.0
  B  B13  1  0.769  0.545  0.384  1.0
  B  B14  1  0.545  0.384  0.769  1.0
  B  B15  1  0.455  0.616  0.231  1.0
  B  B16  1  0.231  0.455  0.616  1.0
  B  B17  1  0.384  0.769  0.545  1.0
  O  O18  1  0.706  0.049  0.048  1.0
  O  O19  1  0.952  0.294  0.951  1.0
  O  O20  1  0.738  0.121  0.452  1.0
  O  O21  1  0.548  0.262  0.879  1.0
  O  O22  1  0.413  0.092  0.345  1.0
  O  O23  1  0.655  0.336  0.652  1.0
  O  O24  1  0.879  0.548  0.262  1.0
  O  O25  1  0.664  0.348  0.345  1.0
  O  O26  1  0.908  0.655  0.587  1.0
  O  O27  1  0.655  0.587  0.908  1.0
  O  O28  1  0.348  0.345  0.664  1.0
  O  O29  1  0.951  0.952  0.294  1.0
  O  O30  1  0.049  0.048  0.706  1.0
  O  O31  1  0.652  0.655  0.336  1.0
  O  O32  1  0.345  0.413  0.092  1.0
  O  O33  1  0.092  0.345  0.413  1.0
  O  O34  1  0.336  0.652  0.655  1.0
  O  O35  1  0.121  0.452  0.738  1.0
  O  O36  1  0.345  0.664  0.348  1.0
  O  O37  1  0.587  0.908  0.655  1.0
  O  O38  1  0.452  0.738  0.121  1.0
  O  O39  1  0.262  0.879  0.548  1.0
  O  O40  1  0.048  0.706  0.049  1.0
  O  O41  1  0.294  0.951  0.952  1.0
[/CIF]
.
The structure described by LiVBO4 crystallizes in the trigonal R-3 space group. Li(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form distorted LiO4 tetrahedra that share corners with four equivalent B(1)O4 tetrahedra and corners with four equivalent V(1)O4 trigonal pyramids. V(1) is bonded to one O(2), one O(3), and two equivalent O(1) atoms to form distorted VO4 trigonal pyramids that share corners with two equivalent B(1)O4 tetrahedra, corners with four equivalent Li(1)O4 tetrahedra, and corners with two equivalent V(1)O4 trigonal pyramids. B(1) is bonded to one O(2), one O(3), and two equivalent O(4) atoms to form BO4 tetrahedra that share corners with two equivalent B(1)O4 tetrahedra, corners with four equivalent Li(1)O4 tetrahedra, and corners with two equivalent V(1)O4 trigonal pyramids. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Li(1) and two equivalent V(1) atoms. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Li(1), one V(1), and one B(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Li(1), one V(1), and one B(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Li(1) and two equivalent B(1) atoms. is represented by the CIF file [CIF]
data_LiVBO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.038
_cell_length_b   8.038
_cell_length_c   8.038
_cell_angle_alpha   106.601
_cell_angle_beta   106.601
_cell_angle_gamma   106.601
_symmetry_Int_Tables_number   1
_cell_volume   437.065
_cell_formula_units_Z   6
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.915  0.524  0.764  1.0
  Li  Li1  1  0.476  0.236  0.085  1.0
  Li  Li2  1  0.236  0.085  0.476  1.0
  Li  Li3  1  0.764  0.915  0.524  1.0
  Li  Li4  1  0.524  0.764  0.915  1.0
  Li  Li5  1  0.085  0.476  0.236  1.0
  V  V6  1  0.863  0.147  0.298  1.0
  V  V7  1  0.702  0.137  0.853  1.0
  V  V8  1  0.853  0.702  0.137  1.0
  V  V9  1  0.147  0.298  0.863  1.0
  V  V10  1  0.298  0.863  0.147  1.0
  V  V11  1  0.137  0.853  0.702  1.0
  B  B12  1  0.616  0.231  0.455  1.0
  B  B13  1  0.769  0.545  0.384  1.0
  B  B14  1  0.545  0.384  0.769  1.0
  B  B15  1  0.455  0.616  0.231  1.0
  B  B16  1  0.231  0.455  0.616  1.0
  B  B17  1  0.384  0.769  0.545  1.0
  O  O18  1  0.706  0.049  0.048  1.0
  O  O19  1  0.952  0.294  0.951  1.0
  O  O20  1  0.738  0.121  0.452  1.0
  O  O21  1  0.548  0.262  0.879  1.0
  O  O22  1  0.413  0.092  0.345  1.0
  O  O23  1  0.655  0.336  0.652  1.0
  O  O24  1  0.879  0.548  0.262  1.0
  O  O25  1  0.664  0.348  0.345  1.0
  O  O26  1  0.908  0.655  0.587  1.0
  O  O27  1  0.655  0.587  0.908  1.0
  O  O28  1  0.348  0.345  0.664  1.0
  O  O29  1  0.951  0.952  0.294  1.0
  O  O30  1  0.049  0.048  0.706  1.0
  O  O31  1  0.652  0.655  0.336  1.0
  O  O32  1  0.345  0.413  0.092  1.0
  O  O33  1  0.092  0.345  0.413  1.0
  O  O34  1  0.336  0.652  0.655  1.0
  O  O35  1  0.121  0.452  0.738  1.0
  O  O36  1  0.345  0.664  0.348  1.0
  O  O37  1  0.587  0.908  0.655  1.0
  O  O38  1  0.452  0.738  0.121  1.0
  O  O39  1  0.262  0.879  0.548  1.0
  O  O40  1  0.048  0.706  0.049  1.0
  O  O41  1  0.294  0.951  0.952  1.0
[/CIF]
.