The material described by LiCaEuFeO6 is (Cubic) Perovskite-derived structured and crystallizes in the cubic F-43m space group. Li(1) is bonded to six equivalent O(1) atoms to form LiO6 octahedra that share corners with six equivalent Fe(1)O6 octahedra, faces with four equivalent Ca(1)O12 cuboctahedra, and faces with four equivalent Eu(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. Ca(1) is bonded to twelve equivalent O(1) atoms to form CaO12 cuboctahedra that share corners with twelve equivalent Ca(1)O12 cuboctahedra, faces with six equivalent Eu(1)O12 cuboctahedra, faces with four equivalent Li(1)O6 octahedra, and faces with four equivalent Fe(1)O6 octahedra. Eu(1) is bonded to twelve equivalent O(1) atoms to form EuO12 cuboctahedra that share corners with twelve equivalent Eu(1)O12 cuboctahedra, faces with six equivalent Ca(1)O12 cuboctahedra, faces with four equivalent Li(1)O6 octahedra, and faces with four equivalent Fe(1)O6 octahedra. Fe(1) is bonded to six equivalent O(1) atoms to form FeO6 octahedra that share corners with six equivalent Li(1)O6 octahedra, faces with four equivalent Ca(1)O12 cuboctahedra, and faces with four equivalent Eu(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. O(1) is bonded in a distorted linear geometry to one Li(1), two equivalent Ca(1), two equivalent Eu(1), and one Fe(1) atom. is represented by the CIF card [CIF]
data_LiCaEuFeO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.372
_cell_length_b   5.372
_cell_length_c   5.372
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   109.645
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.500  0.500  0.500  1.0
  Ca  Ca1  1  0.750  0.750  0.750  1.0
  Eu  Eu2  1  0.250  0.250  0.250  1.0
  Fe  Fe3  1  0.000  0.000  0.000  1.0
  O  O4  1  0.758  0.242  0.242  1.0
  O  O5  1  0.242  0.758  0.758  1.0
  O  O6  1  0.758  0.242  0.758  1.0
  O  O7  1  0.242  0.758  0.242  1.0
  O  O8  1  0.758  0.758  0.242  1.0
  O  O9  1  0.242  0.242  0.758  1.0
[/CIF]
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The material described by LiCaEuFeO6 is (Cubic) Perovskite-derived structured and crystallizes in the cubic F-43m space group. Li(1) is bonded to six equivalent O(1) atoms to form LiO6 octahedra that share corners with six equivalent Fe(1)O6 octahedra, faces with four equivalent Ca(1)O12 cuboctahedra, and faces with four equivalent Eu(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. Ca(1) is bonded to twelve equivalent O(1) atoms to form CaO12 cuboctahedra that share corners with twelve equivalent Ca(1)O12 cuboctahedra, faces with six equivalent Eu(1)O12 cuboctahedra, faces with four equivalent Li(1)O6 octahedra, and faces with four equivalent Fe(1)O6 octahedra. Eu(1) is bonded to twelve equivalent O(1) atoms to form EuO12 cuboctahedra that share corners with twelve equivalent Eu(1)O12 cuboctahedra, faces with six equivalent Ca(1)O12 cuboctahedra, faces with four equivalent Li(1)O6 octahedra, and faces with four equivalent Fe(1)O6 octahedra. Fe(1) is bonded to six equivalent O(1) atoms to form FeO6 octahedra that share corners with six equivalent Li(1)O6 octahedra, faces with four equivalent Ca(1)O12 cuboctahedra, and faces with four equivalent Eu(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. O(1) is bonded in a distorted linear geometry to one Li(1), two equivalent Ca(1), two equivalent Eu(1), and one Fe(1) atom. is represented by the CIF card [CIF]
data_LiCaEuFeO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.372
_cell_length_b   5.372
_cell_length_c   5.372
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   109.645
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.500  0.500  0.500  1.0
  Ca  Ca1  1  0.750  0.750  0.750  1.0
  Eu  Eu2  1  0.250  0.250  0.250  1.0
  Fe  Fe3  1  0.000  0.000  0.000  1.0
  O  O4  1  0.758  0.242  0.242  1.0
  O  O5  1  0.242  0.758  0.758  1.0
  O  O6  1  0.758  0.242  0.758  1.0
  O  O7  1  0.242  0.758  0.242  1.0
  O  O8  1  0.758  0.758  0.242  1.0
  O  O9  1  0.242  0.242  0.758  1.0
[/CIF]
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