The structure described by KSbMo2O8 crystallizes in the triclinic P-1 space group. K(1) is bonded in a 6-coordinate geometry to one O(2), one O(3), one O(4), one O(6), and two equivalent O(7) atoms. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a distorted tetrahedral geometry to one O(2), one O(4), one O(5), and one O(6) atom. In the second Mo site, Mo(2) is bonded in a 6-coordinate geometry to one O(1), one O(7), two equivalent O(3), and two equivalent O(8) atoms. Sb(1) is bonded in a 5-coordinate geometry to one O(1), one O(6), one O(8), and two equivalent O(5) atoms. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one Mo(2) and one Sb(1) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one K(1) and one Mo(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one K(1) and two equivalent Mo(2) atoms. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one K(1) and one Mo(1) atom. In the fifth O site, O(5) is bonded in a 2-coordinate geometry to one Mo(1) and two equivalent Sb(1) atoms. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one K(1), one Mo(1), and one Sb(1) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to two equivalent K(1) and one Mo(2) atom. In the eighth O site, O(8) is bonded in a distorted trigonal planar geometry to two equivalent Mo(2) and one Sb(1) atom. is represented by the CIF card [CIF]
data_KSb(MoO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.104
_cell_length_b   7.558
_cell_length_c   10.440
_cell_angle_alpha   90.507
_cell_angle_beta   100.563
_cell_angle_gamma   107.646
_symmetry_Int_Tables_number   1
_cell_volume   376.407
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.597  0.964  0.688  1.0
  K  K1  1  0.403  0.036  0.312  1.0
  Sb  Sb2  1  0.948  0.530  0.808  1.0
  Sb  Sb3  1  0.052  0.470  0.192  1.0
  Mo  Mo4  1  0.642  0.756  0.073  1.0
  Mo  Mo5  1  0.788  0.635  0.460  1.0
  Mo  Mo6  1  0.358  0.244  0.927  1.0
  Mo  Mo7  1  0.212  0.365  0.540  1.0
  O  O8  1  0.134  0.379  0.713  1.0
  O  O9  1  0.897  0.959  0.145  1.0
  O  O10  1  0.864  0.326  0.447  1.0
  O  O11  1  0.505  0.810  0.918  1.0
  O  O12  1  0.495  0.190  0.082  1.0
  O  O13  1  0.196  0.427  0.966  1.0
  O  O14  1  0.359  0.708  0.174  1.0
  O  O15  1  0.734  0.852  0.462  1.0
  O  O16  1  0.266  0.148  0.538  1.0
  O  O17  1  0.372  0.469  0.385  1.0
  O  O18  1  0.804  0.573  0.034  1.0
  O  O19  1  0.103  0.041  0.855  1.0
  O  O20  1  0.641  0.292  0.826  1.0
  O  O21  1  0.866  0.621  0.287  1.0
  O  O22  1  0.136  0.674  0.553  1.0
  O  O23  1  0.628  0.531  0.615  1.0
[/CIF]
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The structure described by KSbMo2O8 crystallizes in the triclinic P-1 space group. K(1) is bonded in a 6-coordinate geometry to one O(2), one O(3), one O(4), one O(6), and two equivalent O(7) atoms. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a distorted tetrahedral geometry to one O(2), one O(4), one O(5), and one O(6) atom. In the second Mo site, Mo(2) is bonded in a 6-coordinate geometry to one O(1), one O(7), two equivalent O(3), and two equivalent O(8) atoms. Sb(1) is bonded in a 5-coordinate geometry to one O(1), one O(6), one O(8), and two equivalent O(5) atoms. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one Mo(2) and one Sb(1) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one K(1) and one Mo(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one K(1) and two equivalent Mo(2) atoms. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one K(1) and one Mo(1) atom. In the fifth O site, O(5) is bonded in a 2-coordinate geometry to one Mo(1) and two equivalent Sb(1) atoms. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one K(1), one Mo(1), and one Sb(1) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to two equivalent K(1) and one Mo(2) atom. In the eighth O site, O(8) is bonded in a distorted trigonal planar geometry to two equivalent Mo(2) and one Sb(1) atom. is represented by the CIF card [CIF]
data_KSb(MoO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.104
_cell_length_b   7.558
_cell_length_c   10.440
_cell_angle_alpha   90.507
_cell_angle_beta   100.563
_cell_angle_gamma   107.646
_symmetry_Int_Tables_number   1
_cell_volume   376.407
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.597  0.964  0.688  1.0
  K  K1  1  0.403  0.036  0.312  1.0
  Sb  Sb2  1  0.948  0.530  0.808  1.0
  Sb  Sb3  1  0.052  0.470  0.192  1.0
  Mo  Mo4  1  0.642  0.756  0.073  1.0
  Mo  Mo5  1  0.788  0.635  0.460  1.0
  Mo  Mo6  1  0.358  0.244  0.927  1.0
  Mo  Mo7  1  0.212  0.365  0.540  1.0
  O  O8  1  0.134  0.379  0.713  1.0
  O  O9  1  0.897  0.959  0.145  1.0
  O  O10  1  0.864  0.326  0.447  1.0
  O  O11  1  0.505  0.810  0.918  1.0
  O  O12  1  0.495  0.190  0.082  1.0
  O  O13  1  0.196  0.427  0.966  1.0
  O  O14  1  0.359  0.708  0.174  1.0
  O  O15  1  0.734  0.852  0.462  1.0
  O  O16  1  0.266  0.148  0.538  1.0
  O  O17  1  0.372  0.469  0.385  1.0
  O  O18  1  0.804  0.573  0.034  1.0
  O  O19  1  0.103  0.041  0.855  1.0
  O  O20  1  0.641  0.292  0.826  1.0
  O  O21  1  0.866  0.621  0.287  1.0
  O  O22  1  0.136  0.674  0.553  1.0
  O  O23  1  0.628  0.531  0.615  1.0
[/CIF]
.