The crystal structure described by Ti2B crystallizes in the tetragonal I4/mcm space group. Ti(1) is bonded in a distorted bent 150 degrees geometry to two equivalent B(1) atoms. B(1) is bonded to four equivalent Ti(1) and two equivalent B(1) atoms to form corner-sharing BTi4B2 octahedra. The corner-sharing octahedral tilt angles range from 0-40°. is represented by the CIF card [CIF]
data_Ti2B
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.843
_cell_length_b   4.843
_cell_length_c   4.843
_cell_angle_alpha   99.586
_cell_angle_beta   99.586
_cell_angle_gamma   131.832
_symmetry_Int_Tables_number   1
_cell_volume   77.290
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.158  0.658  0.816  1.0
  Ti  Ti1  1  0.842  0.342  0.184  1.0
  Ti  Ti2  1  0.342  0.158  0.500  1.0
  Ti  Ti3  1  0.658  0.842  0.500  1.0
  B  B4  1  0.500  0.500  0.000  1.0
  B  B5  1  0.000  0.000  0.000  1.0
[/CIF]
.
The crystal structure described by Ti2B crystallizes in the tetragonal I4/mcm space group. Ti(1) is bonded in a distorted bent 150 degrees geometry to two equivalent B(1) atoms. B(1) is bonded to four equivalent Ti(1) and two equivalent B(1) atoms to form corner-sharing BTi4B2 octahedra. The corner-sharing octahedral tilt angles range from 0-40°. is represented by the CIF card [CIF]
data_Ti2B
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.843
_cell_length_b   4.843
_cell_length_c   4.843
_cell_angle_alpha   99.586
_cell_angle_beta   99.586
_cell_angle_gamma   131.832
_symmetry_Int_Tables_number   1
_cell_volume   77.290
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.158  0.658  0.816  1.0
  Ti  Ti1  1  0.842  0.342  0.184  1.0
  Ti  Ti2  1  0.342  0.158  0.500  1.0
  Ti  Ti3  1  0.658  0.842  0.500  1.0
  B  B4  1  0.500  0.500  0.000  1.0
  B  B5  1  0.000  0.000  0.000  1.0
[/CIF]
.