The compound described by WPb3O5Cl2 crystallizes in the orthorhombic Cmcm space group. W(1) is bonded in a distorted trigonal bipyramidal geometry to one O(1), four equivalent O(2), and one Cl(1) atom. There are two inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 9-coordinate geometry to one O(1), four equivalent O(2), two equivalent Cl(1), and two equivalent Cl(2) atoms. In the second Pb site, Pb(2) is bonded in a 4-coordinate geometry to four equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to one W(1) and one Pb(1) atom. In the second O site, O(2) is bonded to one W(1), one Pb(1), and two equivalent Pb(2) atoms to form a mixture of distorted edge and corner-sharing OPb3W tetrahedra. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a 3-coordinate geometry to one W(1) and two equivalent Pb(1) atoms. In the second Cl site, Cl(2) is bonded in a linear geometry to two equivalent Pb(1) atoms. is represented by the CIF card [CIF]
data_Pb3WCl2O5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.230
_cell_length_b   7.230
_cell_length_c   11.279
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   133.360
_symmetry_Int_Tables_number   1
_cell_volume   428.675
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pb  Pb0  1  0.903  0.097  0.750  1.0
  Pb  Pb1  1  0.654  0.346  0.532  1.0
  Pb  Pb2  1  0.346  0.654  0.468  1.0
  Pb  Pb3  1  0.654  0.346  0.968  1.0
  Pb  Pb4  1  0.346  0.654  0.032  1.0
  Pb  Pb5  1  0.097  0.903  0.250  1.0
  W  W6  1  0.763  0.237  0.250  1.0
  W  W7  1  0.237  0.763  0.750  1.0
  Cl  Cl8  1  0.526  0.474  0.250  1.0
  Cl  Cl9  1  0.474  0.526  0.750  1.0
  Cl  Cl10  1  0.000  0.000  0.500  1.0
  Cl  Cl11  1  0.000  0.000  0.000  1.0
  O  O12  1  0.105  0.895  0.750  1.0
  O  O13  1  0.038  0.496  0.630  1.0
  O  O14  1  0.496  0.038  0.370  1.0
  O  O15  1  0.504  0.962  0.630  1.0
  O  O16  1  0.962  0.504  0.370  1.0
  O  O17  1  0.895  0.105  0.250  1.0
  O  O18  1  0.038  0.496  0.870  1.0
  O  O19  1  0.504  0.962  0.870  1.0
  O  O20  1  0.962  0.504  0.130  1.0
  O  O21  1  0.496  0.038  0.130  1.0
[/CIF]
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The compound described by WPb3O5Cl2 crystallizes in the orthorhombic Cmcm space group. W(1) is bonded in a distorted trigonal bipyramidal geometry to one O(1), four equivalent O(2), and one Cl(1) atom. There are two inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 9-coordinate geometry to one O(1), four equivalent O(2), two equivalent Cl(1), and two equivalent Cl(2) atoms. In the second Pb site, Pb(2) is bonded in a 4-coordinate geometry to four equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to one W(1) and one Pb(1) atom. In the second O site, O(2) is bonded to one W(1), one Pb(1), and two equivalent Pb(2) atoms to form a mixture of distorted edge and corner-sharing OPb3W tetrahedra. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a 3-coordinate geometry to one W(1) and two equivalent Pb(1) atoms. In the second Cl site, Cl(2) is bonded in a linear geometry to two equivalent Pb(1) atoms. is represented by the CIF card [CIF]
data_Pb3WCl2O5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.230
_cell_length_b   7.230
_cell_length_c   11.279
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   133.360
_symmetry_Int_Tables_number   1
_cell_volume   428.675
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pb  Pb0  1  0.903  0.097  0.750  1.0
  Pb  Pb1  1  0.654  0.346  0.532  1.0
  Pb  Pb2  1  0.346  0.654  0.468  1.0
  Pb  Pb3  1  0.654  0.346  0.968  1.0
  Pb  Pb4  1  0.346  0.654  0.032  1.0
  Pb  Pb5  1  0.097  0.903  0.250  1.0
  W  W6  1  0.763  0.237  0.250  1.0
  W  W7  1  0.237  0.763  0.750  1.0
  Cl  Cl8  1  0.526  0.474  0.250  1.0
  Cl  Cl9  1  0.474  0.526  0.750  1.0
  Cl  Cl10  1  0.000  0.000  0.500  1.0
  Cl  Cl11  1  0.000  0.000  0.000  1.0
  O  O12  1  0.105  0.895  0.750  1.0
  O  O13  1  0.038  0.496  0.630  1.0
  O  O14  1  0.496  0.038  0.370  1.0
  O  O15  1  0.504  0.962  0.630  1.0
  O  O16  1  0.962  0.504  0.370  1.0
  O  O17  1  0.895  0.105  0.250  1.0
  O  O18  1  0.038  0.496  0.870  1.0
  O  O19  1  0.504  0.962  0.870  1.0
  O  O20  1  0.962  0.504  0.130  1.0
  O  O21  1  0.496  0.038  0.130  1.0
[/CIF]
.