The compound described by SmTiFe5Co6 crystallizes in the orthorhombic Imm2 space group. Sm(1) is bonded in a 20-coordinate geometry to one Ti(1), two equivalent Fe(2), eight equivalent Fe(1), one Co(4), two equivalent Co(2), two equivalent Co(3), and four equivalent Co(1) atoms. Ti(1) is bonded in a 14-coordinate geometry to one Sm(1), four equivalent Fe(1), one Co(4), two equivalent Co(1), two equivalent Co(2), and four equivalent Co(3) atoms. There are two inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to two equivalent Sm(1), one Ti(1), one Fe(2), two equivalent Fe(1), one Co(2), one Co(4), two equivalent Co(1), and two equivalent Co(3) atoms to form distorted FeSm2TiFe3Co6 cuboctahedra that share corners with two equivalent Fe(2)Sm2Fe4Co6 cuboctahedra, corners with ten equivalent Fe(1)Sm2TiFe3Co6 cuboctahedra,  an edgeedge with one Fe(2)Sm2Fe4Co6 cuboctahedra, edges with four equivalent Fe(1)Sm2TiFe3Co6 cuboctahedra, faces with two equivalent Fe(2)Sm2Fe4Co6 cuboctahedra, and faces with six equivalent Fe(1)Sm2TiFe3Co6 cuboctahedra. In the second Fe site, Fe(2) is bonded to two equivalent Sm(1), four equivalent Fe(1), two equivalent Co(1), two equivalent Co(3), and two equivalent Co(4) atoms to form distorted FeSm2Fe4Co6 cuboctahedra that share corners with eight equivalent Fe(1)Sm2TiFe3Co6 cuboctahedra, edges with two equivalent Fe(2)Sm2Fe4Co6 cuboctahedra, edges with four equivalent Fe(1)Sm2TiFe3Co6 cuboctahedra, and faces with eight equivalent Fe(1)Sm2TiFe3Co6 cuboctahedra. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded in a 12-coordinate geometry to two equivalent Sm(1), one Ti(1), one Fe(2), four equivalent Fe(1), one Co(2), one Co(4), and two equivalent Co(3) atoms. In the second Co site, Co(2) is bonded in a 12-coordinate geometry to two equivalent Sm(1), two equivalent Ti(1), four equivalent Fe(1), two equivalent Co(1), and two equivalent Co(3) atoms. In the third Co site, Co(3) is bonded in a 14-coordinate geometry to one Sm(1), two equivalent Ti(1), one Fe(2), four equivalent Fe(1), one Co(2), one Co(3), two equivalent Co(1), and two equivalent Co(4) atoms. In the fourth Co site, Co(4) is bonded in a 1-coordinate geometry to one Sm(1), one Ti(1), two equivalent Fe(2), four equivalent Fe(1), two equivalent Co(1), and four equivalent Co(3) atoms. is represented by the CIF card [CIF]
data_SmTiFe5Co6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.706
_cell_length_b   6.448
_cell_length_c   6.448
_cell_angle_alpha   98.209
_cell_angle_beta   111.403
_cell_angle_gamma   68.597
_symmetry_Int_Tables_number   1
_cell_volume   169.608
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sm  Sm0  1  0.000  0.003  0.003  1.0
  Ti  Ti1  1  0.000  0.625  0.625  1.0
  Fe  Fe2  1  0.500  0.002  0.503  1.0
  Fe  Fe3  1  0.001  0.002  0.503  1.0
  Fe  Fe4  1  0.500  0.503  0.002  1.0
  Fe  Fe5  1  0.999  0.503  0.002  1.0
  Fe  Fe6  1  0.500  0.232  0.232  1.0
  Co  Co7  1  0.725  0.777  0.228  1.0
  Co  Co8  1  0.275  0.228  0.777  1.0
  Co  Co9  1  0.500  0.774  0.774  1.0
  Co  Co10  1  0.641  0.358  0.641  1.0
  Co  Co11  1  0.359  0.641  0.358  1.0
  Co  Co12  1  0.000  0.351  0.351  1.0
[/CIF]
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The compound described by SmTiFe5Co6 crystallizes in the orthorhombic Imm2 space group. Sm(1) is bonded in a 20-coordinate geometry to one Ti(1), two equivalent Fe(2), eight equivalent Fe(1), one Co(4), two equivalent Co(2), two equivalent Co(3), and four equivalent Co(1) atoms. Ti(1) is bonded in a 14-coordinate geometry to one Sm(1), four equivalent Fe(1), one Co(4), two equivalent Co(1), two equivalent Co(2), and four equivalent Co(3) atoms. There are two inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to two equivalent Sm(1), one Ti(1), one Fe(2), two equivalent Fe(1), one Co(2), one Co(4), two equivalent Co(1), and two equivalent Co(3) atoms to form distorted FeSm2TiFe3Co6 cuboctahedra that share corners with two equivalent Fe(2)Sm2Fe4Co6 cuboctahedra, corners with ten equivalent Fe(1)Sm2TiFe3Co6 cuboctahedra,  an edgeedge with one Fe(2)Sm2Fe4Co6 cuboctahedra, edges with four equivalent Fe(1)Sm2TiFe3Co6 cuboctahedra, faces with two equivalent Fe(2)Sm2Fe4Co6 cuboctahedra, and faces with six equivalent Fe(1)Sm2TiFe3Co6 cuboctahedra. In the second Fe site, Fe(2) is bonded to two equivalent Sm(1), four equivalent Fe(1), two equivalent Co(1), two equivalent Co(3), and two equivalent Co(4) atoms to form distorted FeSm2Fe4Co6 cuboctahedra that share corners with eight equivalent Fe(1)Sm2TiFe3Co6 cuboctahedra, edges with two equivalent Fe(2)Sm2Fe4Co6 cuboctahedra, edges with four equivalent Fe(1)Sm2TiFe3Co6 cuboctahedra, and faces with eight equivalent Fe(1)Sm2TiFe3Co6 cuboctahedra. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded in a 12-coordinate geometry to two equivalent Sm(1), one Ti(1), one Fe(2), four equivalent Fe(1), one Co(2), one Co(4), and two equivalent Co(3) atoms. In the second Co site, Co(2) is bonded in a 12-coordinate geometry to two equivalent Sm(1), two equivalent Ti(1), four equivalent Fe(1), two equivalent Co(1), and two equivalent Co(3) atoms. In the third Co site, Co(3) is bonded in a 14-coordinate geometry to one Sm(1), two equivalent Ti(1), one Fe(2), four equivalent Fe(1), one Co(2), one Co(3), two equivalent Co(1), and two equivalent Co(4) atoms. In the fourth Co site, Co(4) is bonded in a 1-coordinate geometry to one Sm(1), one Ti(1), two equivalent Fe(2), four equivalent Fe(1), two equivalent Co(1), and four equivalent Co(3) atoms. is represented by the CIF card [CIF]
data_SmTiFe5Co6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.706
_cell_length_b   6.448
_cell_length_c   6.448
_cell_angle_alpha   98.209
_cell_angle_beta   111.403
_cell_angle_gamma   68.597
_symmetry_Int_Tables_number   1
_cell_volume   169.608
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sm  Sm0  1  0.000  0.003  0.003  1.0
  Ti  Ti1  1  0.000  0.625  0.625  1.0
  Fe  Fe2  1  0.500  0.002  0.503  1.0
  Fe  Fe3  1  0.001  0.002  0.503  1.0
  Fe  Fe4  1  0.500  0.503  0.002  1.0
  Fe  Fe5  1  0.999  0.503  0.002  1.0
  Fe  Fe6  1  0.500  0.232  0.232  1.0
  Co  Co7  1  0.725  0.777  0.228  1.0
  Co  Co8  1  0.275  0.228  0.777  1.0
  Co  Co9  1  0.500  0.774  0.774  1.0
  Co  Co10  1  0.641  0.358  0.641  1.0
  Co  Co11  1  0.359  0.641  0.358  1.0
  Co  Co12  1  0.000  0.351  0.351  1.0
[/CIF]
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