The structure described by Co(O3Cl)2 is alpha structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of two Co(O3Cl)2 clusters. Co(1) is bonded in a distorted octahedral geometry to four equivalent O(1) and two equivalent Cl(1) atoms. There are two inequivalent O sites. In the first O site, O(2) is bonded in a single-bond geometry to one Cl(1) atom. In the second O site, O(1) is bonded in a single-bond geometry to one Co(1) atom. Cl(1) is bonded in a water-like geometry to one Co(1) and one O(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Co(ClO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.952
_cell_length_b   5.952
_cell_length_c   4.771
_cell_angle_alpha   71.307
_cell_angle_beta   71.307
_cell_angle_gamma   72.699
_symmetry_Int_Tables_number   1
_cell_volume   148.033
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.000  0.000  0.000  1.0
  Cl  Cl1  1  0.272  0.272  0.906  1.0
  Cl  Cl2  1  0.728  0.728  0.094  1.0
  O  O3  1  0.846  0.233  0.750  1.0
  O  O4  1  0.233  0.846  0.750  1.0
  O  O5  1  0.154  0.767  0.250  1.0
  O  O6  1  0.767  0.154  0.250  1.0
  O  O7  1  0.290  0.290  0.213  1.0
  O  O8  1  0.710  0.710  0.787  1.0
[/CIF]
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The structure described by Co(O3Cl)2 is alpha structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of two Co(O3Cl)2 clusters. Co(1) is bonded in a distorted octahedral geometry to four equivalent O(1) and two equivalent Cl(1) atoms. There are two inequivalent O sites. In the first O site, O(2) is bonded in a single-bond geometry to one Cl(1) atom. In the second O site, O(1) is bonded in a single-bond geometry to one Co(1) atom. Cl(1) is bonded in a water-like geometry to one Co(1) and one O(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Co(ClO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.952
_cell_length_b   5.952
_cell_length_c   4.771
_cell_angle_alpha   71.307
_cell_angle_beta   71.307
_cell_angle_gamma   72.699
_symmetry_Int_Tables_number   1
_cell_volume   148.033
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.000  0.000  0.000  1.0
  Cl  Cl1  1  0.272  0.272  0.906  1.0
  Cl  Cl2  1  0.728  0.728  0.094  1.0
  O  O3  1  0.846  0.233  0.750  1.0
  O  O4  1  0.233  0.846  0.750  1.0
  O  O5  1  0.154  0.767  0.250  1.0
  O  O6  1  0.767  0.154  0.250  1.0
  O  O7  1  0.290  0.290  0.213  1.0
  O  O8  1  0.710  0.710  0.787  1.0
[/CIF]
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