The material structure described by K2Li(NH2)3 crystallizes in the tetragonal P4_2/m space group. There are three inequivalent K sites. In the first K site, K(1) is bonded in a 12-coordinate geometry to two equivalent N(1), two equivalent N(2), two equivalent H(1), two equivalent H(3), and four equivalent H(2) atoms. In the second K site, K(2) is bonded in a 16-coordinate geometry to four equivalent N(2), four equivalent H(1), four equivalent H(2), and four equivalent H(3) atoms. In the third K site, K(3) is bonded in a 8-coordinate geometry to four equivalent N(2) and four equivalent H(1) atoms. Li(1) is bonded in a distorted trigonal non-coplanar geometry to one N(1) and two equivalent N(2) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 3-coordinate geometry to two equivalent K(1), one Li(1), and two equivalent H(1) atoms. In the second N site, N(2) is bonded in a distorted water-like geometry to one K(1), one K(2), one K(3), one Li(1), one H(2), and one H(3) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one K(1), one K(2), one K(3), and one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one K(2), two equivalent K(1), and one N(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one K(1), one K(2), and one N(2) atom. is represented by the CIF card [CIF]
data_K2Li(H2N)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.004
_cell_length_b   7.004
_cell_length_c   12.006
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   588.982
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.000  0.500  0.347  1.0
  K  K1  1  0.500  0.000  0.847  1.0
  K  K2  1  0.000  0.500  0.653  1.0
  K  K3  1  0.500  0.000  0.153  1.0
  K  K4  1  0.000  0.000  0.500  1.0
  K  K5  1  0.000  0.000  0.000  1.0
  K  K6  1  0.500  0.500  0.250  1.0
  K  K7  1  0.500  0.500  0.750  1.0
  Li  Li8  1  0.643  0.352  0.500  1.0
  Li  Li9  1  0.357  0.648  0.500  1.0
  Li  Li10  1  0.352  0.357  0.000  1.0
  Li  Li11  1  0.648  0.643  0.000  1.0
  H  H12  1  0.679  0.725  0.433  1.0
  H  H13  1  0.321  0.275  0.433  1.0
  H  H14  1  0.725  0.321  0.933  1.0
  H  H15  1  0.275  0.679  0.933  1.0
  H  H16  1  0.321  0.275  0.567  1.0
  H  H17  1  0.679  0.725  0.567  1.0
  H  H18  1  0.275  0.679  0.067  1.0
  H  H19  1  0.725  0.321  0.067  1.0
  H  H20  1  0.818  0.161  0.293  1.0
  H  H21  1  0.182  0.839  0.293  1.0
  H  H22  1  0.161  0.182  0.793  1.0
  H  H23  1  0.839  0.818  0.793  1.0
  H  H24  1  0.182  0.839  0.707  1.0
  H  H25  1  0.818  0.161  0.707  1.0
  H  H26  1  0.839  0.818  0.207  1.0
  H  H27  1  0.161  0.182  0.207  1.0
  H  H28  1  0.653  0.082  0.373  1.0
  H  H29  1  0.347  0.918  0.373  1.0
  H  H30  1  0.082  0.347  0.873  1.0
  H  H31  1  0.918  0.653  0.873  1.0
  H  H32  1  0.347  0.918  0.627  1.0
  H  H33  1  0.653  0.082  0.627  1.0
  H  H34  1  0.918  0.653  0.127  1.0
  H  H35  1  0.082  0.347  0.127  1.0
  N  N36  1  0.707  0.638  0.500  1.0
  N  N37  1  0.293  0.362  0.500  1.0
  N  N38  1  0.638  0.293  0.000  1.0
  N  N39  1  0.362  0.707  0.000  1.0
  N  N40  1  0.721  0.207  0.351  1.0
  N  N41  1  0.279  0.793  0.351  1.0
  N  N42  1  0.207  0.279  0.851  1.0
  N  N43  1  0.793  0.721  0.851  1.0
  N  N44  1  0.279  0.793  0.649  1.0
  N  N45  1  0.721  0.207  0.649  1.0
  N  N46  1  0.793  0.721  0.149  1.0
  N  N47  1  0.207  0.279  0.149  1.0
[/CIF]
.
The material structure described by K2Li(NH2)3 crystallizes in the tetragonal P4_2/m space group. There are three inequivalent K sites. In the first K site, K(1) is bonded in a 12-coordinate geometry to two equivalent N(1), two equivalent N(2), two equivalent H(1), two equivalent H(3), and four equivalent H(2) atoms. In the second K site, K(2) is bonded in a 16-coordinate geometry to four equivalent N(2), four equivalent H(1), four equivalent H(2), and four equivalent H(3) atoms. In the third K site, K(3) is bonded in a 8-coordinate geometry to four equivalent N(2) and four equivalent H(1) atoms. Li(1) is bonded in a distorted trigonal non-coplanar geometry to one N(1) and two equivalent N(2) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 3-coordinate geometry to two equivalent K(1), one Li(1), and two equivalent H(1) atoms. In the second N site, N(2) is bonded in a distorted water-like geometry to one K(1), one K(2), one K(3), one Li(1), one H(2), and one H(3) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one K(1), one K(2), one K(3), and one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one K(2), two equivalent K(1), and one N(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one K(1), one K(2), and one N(2) atom. is represented by the CIF card [CIF]
data_K2Li(H2N)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.004
_cell_length_b   7.004
_cell_length_c   12.006
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   588.982
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.000  0.500  0.347  1.0
  K  K1  1  0.500  0.000  0.847  1.0
  K  K2  1  0.000  0.500  0.653  1.0
  K  K3  1  0.500  0.000  0.153  1.0
  K  K4  1  0.000  0.000  0.500  1.0
  K  K5  1  0.000  0.000  0.000  1.0
  K  K6  1  0.500  0.500  0.250  1.0
  K  K7  1  0.500  0.500  0.750  1.0
  Li  Li8  1  0.643  0.352  0.500  1.0
  Li  Li9  1  0.357  0.648  0.500  1.0
  Li  Li10  1  0.352  0.357  0.000  1.0
  Li  Li11  1  0.648  0.643  0.000  1.0
  H  H12  1  0.679  0.725  0.433  1.0
  H  H13  1  0.321  0.275  0.433  1.0
  H  H14  1  0.725  0.321  0.933  1.0
  H  H15  1  0.275  0.679  0.933  1.0
  H  H16  1  0.321  0.275  0.567  1.0
  H  H17  1  0.679  0.725  0.567  1.0
  H  H18  1  0.275  0.679  0.067  1.0
  H  H19  1  0.725  0.321  0.067  1.0
  H  H20  1  0.818  0.161  0.293  1.0
  H  H21  1  0.182  0.839  0.293  1.0
  H  H22  1  0.161  0.182  0.793  1.0
  H  H23  1  0.839  0.818  0.793  1.0
  H  H24  1  0.182  0.839  0.707  1.0
  H  H25  1  0.818  0.161  0.707  1.0
  H  H26  1  0.839  0.818  0.207  1.0
  H  H27  1  0.161  0.182  0.207  1.0
  H  H28  1  0.653  0.082  0.373  1.0
  H  H29  1  0.347  0.918  0.373  1.0
  H  H30  1  0.082  0.347  0.873  1.0
  H  H31  1  0.918  0.653  0.873  1.0
  H  H32  1  0.347  0.918  0.627  1.0
  H  H33  1  0.653  0.082  0.627  1.0
  H  H34  1  0.918  0.653  0.127  1.0
  H  H35  1  0.082  0.347  0.127  1.0
  N  N36  1  0.707  0.638  0.500  1.0
  N  N37  1  0.293  0.362  0.500  1.0
  N  N38  1  0.638  0.293  0.000  1.0
  N  N39  1  0.362  0.707  0.000  1.0
  N  N40  1  0.721  0.207  0.351  1.0
  N  N41  1  0.279  0.793  0.351  1.0
  N  N42  1  0.207  0.279  0.851  1.0
  N  N43  1  0.793  0.721  0.851  1.0
  N  N44  1  0.279  0.793  0.649  1.0
  N  N45  1  0.721  0.207  0.649  1.0
  N  N46  1  0.793  0.721  0.149  1.0
  N  N47  1  0.207  0.279  0.149  1.0
[/CIF]
.