The crystal structure described by RbTm(WO4)2 crystallizes in the monoclinic P2_1/c space group. Rb(1) is bonded in a 8-coordinate geometry to one O(6), one O(7), two equivalent O(2), two equivalent O(4), and two equivalent O(5) atoms. Tm(1) is bonded in a 8-coordinate geometry to one O(3), one O(4), one O(6), one O(8), two equivalent O(1), and two equivalent O(7) atoms. There are two inequivalent W sites. In the first W site, W(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(6), and one O(8) atom. In the second W site, W(2) is bonded in a 5-coordinate geometry to one O(1), one O(5), one O(6), one O(7), and one O(8) atom. There are eight inequivalent O sites. In the first O site, O(5) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one W(2) atom. In the second O site, O(6) is bonded in a 3-coordinate geometry to one Rb(1), one Tm(1), one W(1), and one W(2) atom. In the third O site, O(7) is bonded in a distorted bent 150 degrees geometry to one Rb(1), two equivalent Tm(1), and one W(2) atom. In the fourth O site, O(8) is bonded in a 3-coordinate geometry to one Tm(1), one W(1), and one W(2) atom. In the fifth O site, O(1) is bonded in a 4-coordinate geometry to two equivalent Tm(1), one W(1), and one W(2) atom. In the sixth O site, O(2) is bonded in a 3-coordinate geometry to two equivalent Rb(1) and one W(1) atom. In the seventh O site, O(3) is bonded in a bent 150 degrees geometry to one Tm(1) and one W(1) atom. In the eighth O site, O(4) is bonded in a 4-coordinate geometry to two equivalent Rb(1), one Tm(1), and one W(1) atom. is represented by the CIF card [CIF]
data_RbTm(WO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.029
_cell_length_b   9.042
_cell_length_c   10.367
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   99.248
_symmetry_Int_Tables_number   1
_cell_volume   742.817
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.073  0.512  0.213  1.0
  Rb  Rb1  1  0.927  0.488  0.787  1.0
  Rb  Rb2  1  0.427  0.488  0.713  1.0
  Rb  Rb3  1  0.573  0.512  0.287  1.0
  Tm  Tm4  1  0.021  0.060  0.777  1.0
  Tm  Tm5  1  0.979  0.940  0.223  1.0
  Tm  Tm6  1  0.479  0.940  0.277  1.0
  Tm  Tm7  1  0.521  0.060  0.723  1.0
  W  W8  1  0.287  0.220  0.010  1.0
  W  W9  1  0.713  0.780  0.990  1.0
  W  W10  1  0.213  0.780  0.510  1.0
  W  W11  1  0.787  0.220  0.490  1.0
  W  W12  1  0.179  0.162  0.489  1.0
  W  W13  1  0.821  0.838  0.511  1.0
  W  W14  1  0.321  0.838  0.989  1.0
  W  W15  1  0.679  0.162  0.011  1.0
  O  O16  1  0.256  0.009  0.389  1.0
  O  O17  1  0.744  0.991  0.611  1.0
  O  O18  1  0.244  0.991  0.889  1.0
  O  O19  1  0.756  0.009  0.111  1.0
  O  O20  1  0.350  0.395  0.087  1.0
  O  O21  1  0.650  0.605  0.913  1.0
  O  O22  1  0.150  0.605  0.587  1.0
  O  O23  1  0.850  0.395  0.413  1.0
  O  O24  1  0.113  0.133  0.115  1.0
  O  O25  1  0.887  0.867  0.885  1.0
  O  O26  1  0.387  0.867  0.615  1.0
  O  O27  1  0.613  0.133  0.385  1.0
  O  O28  1  0.335  0.732  0.369  1.0
  O  O29  1  0.665  0.268  0.631  1.0
  O  O30  1  0.165  0.268  0.869  1.0
  O  O31  1  0.835  0.732  0.131  1.0
  O  O32  1  0.268  0.330  0.413  1.0
  O  O33  1  0.732  0.670  0.587  1.0
  O  O34  1  0.232  0.670  0.913  1.0
  O  O35  1  0.768  0.330  0.087  1.0
  O  O36  1  0.003  0.225  0.604  1.0
  O  O37  1  0.997  0.775  0.396  1.0
  O  O38  1  0.497  0.775  0.104  1.0
  O  O39  1  0.503  0.225  0.896  1.0
  O  O40  1  0.305  0.153  0.637  1.0
  O  O41  1  0.695  0.847  0.363  1.0
  O  O42  1  0.195  0.847  0.137  1.0
  O  O43  1  0.805  0.153  0.863  1.0
  O  O44  1  0.451  0.090  0.102  1.0
  O  O45  1  0.549  0.910  0.898  1.0
  O  O46  1  0.049  0.910  0.602  1.0
  O  O47  1  0.951  0.090  0.398  1.0
[/CIF]
.
The crystal structure described by RbTm(WO4)2 crystallizes in the monoclinic P2_1/c space group. Rb(1) is bonded in a 8-coordinate geometry to one O(6), one O(7), two equivalent O(2), two equivalent O(4), and two equivalent O(5) atoms. Tm(1) is bonded in a 8-coordinate geometry to one O(3), one O(4), one O(6), one O(8), two equivalent O(1), and two equivalent O(7) atoms. There are two inequivalent W sites. In the first W site, W(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(6), and one O(8) atom. In the second W site, W(2) is bonded in a 5-coordinate geometry to one O(1), one O(5), one O(6), one O(7), and one O(8) atom. There are eight inequivalent O sites. In the first O site, O(5) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one W(2) atom. In the second O site, O(6) is bonded in a 3-coordinate geometry to one Rb(1), one Tm(1), one W(1), and one W(2) atom. In the third O site, O(7) is bonded in a distorted bent 150 degrees geometry to one Rb(1), two equivalent Tm(1), and one W(2) atom. In the fourth O site, O(8) is bonded in a 3-coordinate geometry to one Tm(1), one W(1), and one W(2) atom. In the fifth O site, O(1) is bonded in a 4-coordinate geometry to two equivalent Tm(1), one W(1), and one W(2) atom. In the sixth O site, O(2) is bonded in a 3-coordinate geometry to two equivalent Rb(1) and one W(1) atom. In the seventh O site, O(3) is bonded in a bent 150 degrees geometry to one Tm(1) and one W(1) atom. In the eighth O site, O(4) is bonded in a 4-coordinate geometry to two equivalent Rb(1), one Tm(1), and one W(1) atom. is represented by the CIF card [CIF]
data_RbTm(WO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.029
_cell_length_b   9.042
_cell_length_c   10.367
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   99.248
_symmetry_Int_Tables_number   1
_cell_volume   742.817
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.073  0.512  0.213  1.0
  Rb  Rb1  1  0.927  0.488  0.787  1.0
  Rb  Rb2  1  0.427  0.488  0.713  1.0
  Rb  Rb3  1  0.573  0.512  0.287  1.0
  Tm  Tm4  1  0.021  0.060  0.777  1.0
  Tm  Tm5  1  0.979  0.940  0.223  1.0
  Tm  Tm6  1  0.479  0.940  0.277  1.0
  Tm  Tm7  1  0.521  0.060  0.723  1.0
  W  W8  1  0.287  0.220  0.010  1.0
  W  W9  1  0.713  0.780  0.990  1.0
  W  W10  1  0.213  0.780  0.510  1.0
  W  W11  1  0.787  0.220  0.490  1.0
  W  W12  1  0.179  0.162  0.489  1.0
  W  W13  1  0.821  0.838  0.511  1.0
  W  W14  1  0.321  0.838  0.989  1.0
  W  W15  1  0.679  0.162  0.011  1.0
  O  O16  1  0.256  0.009  0.389  1.0
  O  O17  1  0.744  0.991  0.611  1.0
  O  O18  1  0.244  0.991  0.889  1.0
  O  O19  1  0.756  0.009  0.111  1.0
  O  O20  1  0.350  0.395  0.087  1.0
  O  O21  1  0.650  0.605  0.913  1.0
  O  O22  1  0.150  0.605  0.587  1.0
  O  O23  1  0.850  0.395  0.413  1.0
  O  O24  1  0.113  0.133  0.115  1.0
  O  O25  1  0.887  0.867  0.885  1.0
  O  O26  1  0.387  0.867  0.615  1.0
  O  O27  1  0.613  0.133  0.385  1.0
  O  O28  1  0.335  0.732  0.369  1.0
  O  O29  1  0.665  0.268  0.631  1.0
  O  O30  1  0.165  0.268  0.869  1.0
  O  O31  1  0.835  0.732  0.131  1.0
  O  O32  1  0.268  0.330  0.413  1.0
  O  O33  1  0.732  0.670  0.587  1.0
  O  O34  1  0.232  0.670  0.913  1.0
  O  O35  1  0.768  0.330  0.087  1.0
  O  O36  1  0.003  0.225  0.604  1.0
  O  O37  1  0.997  0.775  0.396  1.0
  O  O38  1  0.497  0.775  0.104  1.0
  O  O39  1  0.503  0.225  0.896  1.0
  O  O40  1  0.305  0.153  0.637  1.0
  O  O41  1  0.695  0.847  0.363  1.0
  O  O42  1  0.195  0.847  0.137  1.0
  O  O43  1  0.805  0.153  0.863  1.0
  O  O44  1  0.451  0.090  0.102  1.0
  O  O45  1  0.549  0.910  0.898  1.0
  O  O46  1  0.049  0.910  0.602  1.0
  O  O47  1  0.951  0.090  0.398  1.0
[/CIF]
.