The compound described by Ce2Pd2Sn crystallizes in the tetragonal P4/mbm space group. Ce(1) is bonded in a 10-coordinate geometry to six equivalent Pd(1) and four equivalent Sn(1) atoms. Pd(1) is bonded in a 9-coordinate geometry to six equivalent Ce(1), one Pd(1), and two equivalent Sn(1) atoms. Sn(1) is bonded to eight equivalent Ce(1) and four equivalent Pd(1) atoms to form a mixture of corner and face-sharing SnCe8Pd4 cuboctahedra. is represented by the CIF card [CIF]
data_Ce2SnPd2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.838
_cell_length_b   7.838
_cell_length_c   3.874
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.017
_symmetry_Int_Tables_number   1
_cell_volume   237.994
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.680  0.180  0.500  1.0
  Ce  Ce1  1  0.320  0.820  0.500  1.0
  Ce  Ce2  1  0.180  0.320  0.500  1.0
  Ce  Ce3  1  0.820  0.680  0.500  1.0
  Sn  Sn4  1  0.000  0.000  0.000  1.0
  Sn  Sn5  1  0.500  0.500  0.000  1.0
  Pd  Pd6  1  0.126  0.626  0.000  1.0
  Pd  Pd7  1  0.874  0.374  0.000  1.0
  Pd  Pd8  1  0.626  0.874  0.000  1.0
  Pd  Pd9  1  0.374  0.126  0.000  1.0
[/CIF]
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The compound described by Ce2Pd2Sn crystallizes in the tetragonal P4/mbm space group. Ce(1) is bonded in a 10-coordinate geometry to six equivalent Pd(1) and four equivalent Sn(1) atoms. Pd(1) is bonded in a 9-coordinate geometry to six equivalent Ce(1), one Pd(1), and two equivalent Sn(1) atoms. Sn(1) is bonded to eight equivalent Ce(1) and four equivalent Pd(1) atoms to form a mixture of corner and face-sharing SnCe8Pd4 cuboctahedra. is represented by the CIF card [CIF]
data_Ce2SnPd2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.838
_cell_length_b   7.838
_cell_length_c   3.874
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.017
_symmetry_Int_Tables_number   1
_cell_volume   237.994
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.680  0.180  0.500  1.0
  Ce  Ce1  1  0.320  0.820  0.500  1.0
  Ce  Ce2  1  0.180  0.320  0.500  1.0
  Ce  Ce3  1  0.820  0.680  0.500  1.0
  Sn  Sn4  1  0.000  0.000  0.000  1.0
  Sn  Sn5  1  0.500  0.500  0.000  1.0
  Pd  Pd6  1  0.126  0.626  0.000  1.0
  Pd  Pd7  1  0.874  0.374  0.000  1.0
  Pd  Pd8  1  0.626  0.874  0.000  1.0
  Pd  Pd9  1  0.374  0.126  0.000  1.0
[/CIF]
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