The compound described by C2TeS2(N2Cl)2 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four chloro tellurohypochlorite;thiourea molecules. C(1) is bonded in a 2-coordinate geometry to one N(1), one N(2), and one S(1) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one C(1) atom. In the second N site, N(2) is bonded in a single-bond geometry to one C(1) atom. Te(1) is bonded in a distorted square co-planar geometry to two equivalent S(1) and two equivalent Cl(1) atoms. S(1) is bonded in a water-like geometry to one C(1) and one Te(1) atom. Cl(1) is bonded in a single-bond geometry to one Te(1) atom. is represented by the CIF card [CIF]
data_TeC2S2(N2Cl)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.180
_cell_length_b   9.180
_cell_length_c   10.136
_cell_angle_alpha   60.425
_cell_angle_beta   60.425
_cell_angle_gamma   50.461
_symmetry_Int_Tables_number   1
_cell_volume   552.084
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.107  0.893  0.750  1.0
  Te  Te1  1  0.893  0.107  0.250  1.0
  C  C2  1  0.217  0.491  0.085  1.0
  C  C3  1  0.509  0.783  0.415  1.0
  C  C4  1  0.783  0.509  0.915  1.0
  C  C5  1  0.491  0.217  0.585  1.0
  S  S6  1  0.280  0.506  0.876  1.0
  S  S7  1  0.494  0.720  0.624  1.0
  S  S8  1  0.720  0.494  0.124  1.0
  S  S9  1  0.506  0.280  0.376  1.0
  N  N10  1  0.211  0.336  0.186  1.0
  N  N11  1  0.664  0.789  0.314  1.0
  N  N12  1  0.789  0.664  0.814  1.0
  N  N13  1  0.336  0.211  0.686  1.0
  N  N14  1  0.197  0.640  0.097  1.0
  N  N15  1  0.360  0.803  0.403  1.0
  N  N16  1  0.803  0.360  0.903  1.0
  N  N17  1  0.640  0.197  0.597  1.0
  Cl  Cl18  1  0.781  0.972  0.939  1.0
  Cl  Cl19  1  0.028  0.219  0.561  1.0
  Cl  Cl20  1  0.219  0.028  0.061  1.0
  Cl  Cl21  1  0.972  0.781  0.439  1.0
[/CIF]
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The compound described by C2TeS2(N2Cl)2 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four chloro tellurohypochlorite;thiourea molecules. C(1) is bonded in a 2-coordinate geometry to one N(1), one N(2), and one S(1) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one C(1) atom. In the second N site, N(2) is bonded in a single-bond geometry to one C(1) atom. Te(1) is bonded in a distorted square co-planar geometry to two equivalent S(1) and two equivalent Cl(1) atoms. S(1) is bonded in a water-like geometry to one C(1) and one Te(1) atom. Cl(1) is bonded in a single-bond geometry to one Te(1) atom. is represented by the CIF card [CIF]
data_TeC2S2(N2Cl)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.180
_cell_length_b   9.180
_cell_length_c   10.136
_cell_angle_alpha   60.425
_cell_angle_beta   60.425
_cell_angle_gamma   50.461
_symmetry_Int_Tables_number   1
_cell_volume   552.084
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.107  0.893  0.750  1.0
  Te  Te1  1  0.893  0.107  0.250  1.0
  C  C2  1  0.217  0.491  0.085  1.0
  C  C3  1  0.509  0.783  0.415  1.0
  C  C4  1  0.783  0.509  0.915  1.0
  C  C5  1  0.491  0.217  0.585  1.0
  S  S6  1  0.280  0.506  0.876  1.0
  S  S7  1  0.494  0.720  0.624  1.0
  S  S8  1  0.720  0.494  0.124  1.0
  S  S9  1  0.506  0.280  0.376  1.0
  N  N10  1  0.211  0.336  0.186  1.0
  N  N11  1  0.664  0.789  0.314  1.0
  N  N12  1  0.789  0.664  0.814  1.0
  N  N13  1  0.336  0.211  0.686  1.0
  N  N14  1  0.197  0.640  0.097  1.0
  N  N15  1  0.360  0.803  0.403  1.0
  N  N16  1  0.803  0.360  0.903  1.0
  N  N17  1  0.640  0.197  0.597  1.0
  Cl  Cl18  1  0.781  0.972  0.939  1.0
  Cl  Cl19  1  0.028  0.219  0.561  1.0
  Cl  Cl20  1  0.219  0.028  0.061  1.0
  Cl  Cl21  1  0.972  0.781  0.439  1.0
[/CIF]
.