The material described by Ce(RhP)2 crystallizes in the tetragonal P4/nmm space group. Ce(1) is bonded in a 16-coordinate geometry to four equivalent Rh(1), four equivalent Rh(2), four equivalent P(1), and four equivalent P(2) atoms. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a 5-coordinate geometry to four equivalent Ce(1), one P(1), and four equivalent P(2) atoms. In the second Rh site, Rh(2) is bonded in a 8-coordinate geometry to four equivalent Ce(1) and four equivalent P(1) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded in a 9-coordinate geometry to four equivalent Ce(1), one Rh(1), and four equivalent Rh(2) atoms. In the second P site, P(2) is bonded in a 8-coordinate geometry to four equivalent Ce(1) and four equivalent Rh(1) atoms. is represented by the CIF file [CIF]
data_Ce(PRh)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.153
_cell_length_b   4.153
_cell_length_c   9.450
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   163.002
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.250  0.250  0.744  1.0
  Ce  Ce1  1  0.750  0.750  0.256  1.0
  P  P2  1  0.250  0.250  0.139  1.0
  P  P3  1  0.750  0.750  0.861  1.0
  P  P4  1  0.750  0.250  0.500  1.0
  P  P5  1  0.250  0.750  0.500  1.0
  Rh  Rh6  1  0.250  0.250  0.388  1.0
  Rh  Rh7  1  0.750  0.750  0.612  1.0
  Rh  Rh8  1  0.750  0.250  0.000  1.0
  Rh  Rh9  1  0.250  0.750  0.000  1.0
[/CIF]
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The material described by Ce(RhP)2 crystallizes in the tetragonal P4/nmm space group. Ce(1) is bonded in a 16-coordinate geometry to four equivalent Rh(1), four equivalent Rh(2), four equivalent P(1), and four equivalent P(2) atoms. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a 5-coordinate geometry to four equivalent Ce(1), one P(1), and four equivalent P(2) atoms. In the second Rh site, Rh(2) is bonded in a 8-coordinate geometry to four equivalent Ce(1) and four equivalent P(1) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded in a 9-coordinate geometry to four equivalent Ce(1), one Rh(1), and four equivalent Rh(2) atoms. In the second P site, P(2) is bonded in a 8-coordinate geometry to four equivalent Ce(1) and four equivalent Rh(1) atoms. is represented by the CIF file [CIF]
data_Ce(PRh)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.153
_cell_length_b   4.153
_cell_length_c   9.450
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   163.002
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.250  0.250  0.744  1.0
  Ce  Ce1  1  0.750  0.750  0.256  1.0
  P  P2  1  0.250  0.250  0.139  1.0
  P  P3  1  0.750  0.750  0.861  1.0
  P  P4  1  0.750  0.250  0.500  1.0
  P  P5  1  0.250  0.750  0.500  1.0
  Rh  Rh6  1  0.250  0.250  0.388  1.0
  Rh  Rh7  1  0.750  0.750  0.612  1.0
  Rh  Rh8  1  0.750  0.250  0.000  1.0
  Rh  Rh9  1  0.250  0.750  0.000  1.0
[/CIF]
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