The material described by Li6V3Mn(PO4)6 crystallizes in the triclinic P1 space group. There are six inequivalent Li sites. In the first Li site, Li(1) is bonded in a 6-coordinate geometry to one O(1), one O(14), one O(16), one O(2), one O(6), and one O(7) atom. In the second Li site, Li(2) is bonded to one O(16), one O(18), one O(20), one O(5), one O(7), and one O(9) atom to form distorted LiO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a faceface with one V(3)O6 octahedra, and  a faceface with one Mn(1)O6 octahedra. In the third Li site, Li(3) is bonded in a 6-coordinate geometry to one O(11), one O(13), one O(18), one O(20), one O(21), and one O(8) atom. In the fourth Li site, Li(4) is bonded in a 6-coordinate geometry to one O(12), one O(14), one O(17), one O(4), one O(5), and one O(7) atom. In the fifth Li site, Li(5) is bonded to one O(11), one O(14), one O(19), one O(21), one O(4), and one O(6) atom to form distorted LiO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a faceface with one V(1)O6 octahedra, and  a faceface with one V(2)O6 octahedra. In the sixth Li site, Li(6) is bonded in a 6-coordinate geometry to one O(11), one O(18), one O(19), one O(23), one O(24), and one O(9) atom. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(10), one O(14), one O(17), one O(4), and one O(6) atom to form VO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra, and  a faceface with one Li(5)O6 octahedra. In the second V site, V(2) is bonded to one O(11), one O(15), one O(19), one O(21), one O(24), and one O(8) atom to form VO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra, and  a faceface with one Li(5)O6 octahedra. In the third V site, V(3) is bonded to one O(13), one O(18), one O(20), one O(22), one O(23), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra, and  a faceface with one Li(2)O6 octahedra. Mn(1) is bonded to one O(12), one O(16), one O(2), one O(3), one O(5), and one O(7) atom to form distorted MnO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra, and  a faceface with one Li(2)O6 octahedra. There are six inequivalent P sites. In the first P site, P(1) is bonded to one O(14), one O(22), one O(24), and one O(5) atom to form PO4 tetrahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, and  a cornercorner with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 16-50°. In the second P site, P(2) is bonded to one O(16), one O(23), one O(4), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, and  a cornercorner with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 29-47°. In the third P site, P(3) is bonded to one O(13), one O(15), one O(6), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, and  a cornercorner with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 16-49°. In the fourth P site, P(4) is bonded to one O(10), one O(12), one O(18), and one O(19) atom to form PO4 tetrahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, and  a cornercorner with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 15-48°. In the fifth P site, P(5) is bonded to one O(17), one O(2), one O(21), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, and  a cornercorner with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 29-48°. In the sixth P site, P(6) is bonded to one O(1), one O(11), one O(20), and one O(3) atom to form PO4 tetrahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, and  a cornercorner with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 17-49°. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Li(1), one V(1), and one P(6) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Li(1), one Mn(1), and one P(5) atom. In the third O site, O(3) is bonded in a linear geometry to one Mn(1) and one P(6) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Li(4), one Li(5), one V(1), and one P(2) atom. In the fifth O site, O(5) is bonded in a rectangular see-saw-like geometry to one Li(2), one Li(4), one Mn(1), and one P(1) atom. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Li(1), one Li(5), one V(1), and one P(3) atom. In the seventh O site, O(7) is bonded to one Li(1), one Li(2), one Li(4), one Mn(1), and one P(3) atom to form distorted corner-sharing OLi3MnP trigonal bipyramids. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one Li(3), one V(2), and one P(2) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one Li(2), one Li(6), one V(3), and one P(5) atom. In the tenth O site, O(10) is bonded in a linear geometry to one V(1) and one P(4) atom. In the eleventh O site, O(11) is bonded to one Li(3), one Li(5), one Li(6), one V(2), and one P(6) atom to form distorted corner-sharing OLi3VP trigonal bipyramids. In the twelfth O site, O(12) is bonded in a 3-coordinate geometry to one Li(4), one Mn(1), and one P(4) atom. In the thirteenth O site, O(13) is bonded in a 3-coordinate geometry to one Li(3), one V(3), and one P(3) atom. In the fourteenth O site, O(14) is bonded to one Li(1), one Li(4), one Li(5), one V(1), and one P(1) atom to form distorted OLi3VP trigonal bipyramids that share  a cornercorner with one O(11)Li3VP trigonal bipyramid and corners with two equivalent O(7)Li3MnP trigonal bipyramids. In the fifteenth O site, O(15) is bonded in a linear geometry to one V(2) and one P(3) atom. In the sixteenth O site, O(16) is bonded in a 4-coordinate geometry to one Li(1), one Li(2), one Mn(1), and one P(2) atom. In the seventeenth O site, O(17) is bonded in a 3-coordinate geometry to one Li(4), one V(1), and one P(5) atom. In the eighteenth O site, O(18) is bonded to one Li(2), one Li(3), one Li(6), one V(3), and one P(4) atom to form distorted OLi3VP trigonal bipyramids that share  a cornercorner with one O(7)Li3MnP trigonal bipyramid and corners with two equivalent O(11)Li3VP trigonal bipyramids. In the nineteenth O site, O(19) is bonded in a rectangular see-saw-like geometry to one Li(5), one Li(6), one V(2), and one P(4) atom. In the twentieth O site, O(20) is bonded in a rectangular see-saw-like geometry to one Li(2), one Li(3), one V(3), and one P(6) atom. In the twenty-first O site, O(21) is bonded in a 3-coordinate geometry to one Li(3), one Li(5), one V(2), and one P(5) atom. In the twenty-second O site, O(22) is bonded in a linear geometry to one V(3) and one P(1) atom. In the twenty-third O site, O(23) is bonded in a 3-coordinate geometry to one Li(6), one V(3), and one P(2) atom. In the twenty-fourth O site, O(24) is bonded in a 3-coordinate geometry to one Li(6), one V(2), and one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li6MnV3(PO4)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.456
_cell_length_b   8.598
_cell_length_c   8.647
_cell_angle_alpha   61.419
_cell_angle_beta   61.754
_cell_angle_gamma   62.781
_symmetry_Int_Tables_number   1
_cell_volume   464.126
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.255  0.125  0.842  1.0
  Li  Li1  1  0.997  0.501  0.999  1.0
  Li  Li2  1  0.128  0.258  0.341  1.0
  Li  Li3  1  0.872  0.741  0.662  1.0
  Li  Li4  1  0.499  1.000  0.501  1.0
  Li  Li5  1  0.742  0.874  0.159  1.0
  Mn  Mn6  1  0.856  0.362  0.851  1.0
  V  V7  1  0.636  0.145  0.645  1.0
  V  V8  1  0.363  0.855  0.355  1.0
  V  V9  1  0.146  0.636  0.143  1.0
  P  P10  1  0.550  0.753  0.963  1.0
  P  P11  1  0.950  0.049  0.248  1.0
  P  P12  1  0.248  0.450  0.537  1.0
  P  P13  1  0.750  0.549  0.464  1.0
  P  P14  1  0.052  0.949  0.750  1.0
  P  P15  1  0.453  0.250  0.036  1.0
  O  O16  1  0.466  0.188  0.889  1.0
  O  O17  1  0.031  0.109  0.798  1.0
  O  O18  1  0.617  0.320  0.974  1.0
  O  O19  1  0.763  0.062  0.417  1.0
  O  O20  1  0.748  0.612  0.924  1.0
  O  O21  1  0.393  0.256  0.579  1.0
  O  O22  1  0.081  0.454  0.728  1.0
  O  O23  1  0.116  0.021  0.299  1.0
  O  O24  1  0.062  0.762  0.917  1.0
  O  O25  1  0.682  0.386  0.527  1.0
  O  O26  1  0.458  0.086  0.226  1.0
  O  O27  1  0.811  0.538  0.613  1.0
  O  O28  1  0.186  0.464  0.389  1.0
  O  O29  1  0.540  0.917  0.774  1.0
  O  O30  1  0.316  0.612  0.479  1.0
  O  O31  1  0.942  0.234  0.079  1.0
  O  O32  1  0.884  0.979  0.701  1.0
  O  O33  1  0.914  0.544  0.275  1.0
  O  O34  1  0.604  0.744  0.422  1.0
  O  O35  1  0.256  0.395  0.077  1.0
  O  O36  1  0.238  0.935  0.581  1.0
  O  O37  1  0.388  0.681  0.025  1.0
  O  O38  1  0.977  0.884  0.202  1.0
  O  O39  1  0.531  0.817  0.112  1.0
[/CIF]
.
The material described by Li6V3Mn(PO4)6 crystallizes in the triclinic P1 space group. There are six inequivalent Li sites. In the first Li site, Li(1) is bonded in a 6-coordinate geometry to one O(1), one O(14), one O(16), one O(2), one O(6), and one O(7) atom. In the second Li site, Li(2) is bonded to one O(16), one O(18), one O(20), one O(5), one O(7), and one O(9) atom to form distorted LiO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a faceface with one V(3)O6 octahedra, and  a faceface with one Mn(1)O6 octahedra. In the third Li site, Li(3) is bonded in a 6-coordinate geometry to one O(11), one O(13), one O(18), one O(20), one O(21), and one O(8) atom. In the fourth Li site, Li(4) is bonded in a 6-coordinate geometry to one O(12), one O(14), one O(17), one O(4), one O(5), and one O(7) atom. In the fifth Li site, Li(5) is bonded to one O(11), one O(14), one O(19), one O(21), one O(4), and one O(6) atom to form distorted LiO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a faceface with one V(1)O6 octahedra, and  a faceface with one V(2)O6 octahedra. In the sixth Li site, Li(6) is bonded in a 6-coordinate geometry to one O(11), one O(18), one O(19), one O(23), one O(24), and one O(9) atom. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(10), one O(14), one O(17), one O(4), and one O(6) atom to form VO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra, and  a faceface with one Li(5)O6 octahedra. In the second V site, V(2) is bonded to one O(11), one O(15), one O(19), one O(21), one O(24), and one O(8) atom to form VO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra, and  a faceface with one Li(5)O6 octahedra. In the third V site, V(3) is bonded to one O(13), one O(18), one O(20), one O(22), one O(23), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra, and  a faceface with one Li(2)O6 octahedra. Mn(1) is bonded to one O(12), one O(16), one O(2), one O(3), one O(5), and one O(7) atom to form distorted MnO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra, and  a faceface with one Li(2)O6 octahedra. There are six inequivalent P sites. In the first P site, P(1) is bonded to one O(14), one O(22), one O(24), and one O(5) atom to form PO4 tetrahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, and  a cornercorner with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 16-50°. In the second P site, P(2) is bonded to one O(16), one O(23), one O(4), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, and  a cornercorner with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 29-47°. In the third P site, P(3) is bonded to one O(13), one O(15), one O(6), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, and  a cornercorner with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 16-49°. In the fourth P site, P(4) is bonded to one O(10), one O(12), one O(18), and one O(19) atom to form PO4 tetrahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, and  a cornercorner with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 15-48°. In the fifth P site, P(5) is bonded to one O(17), one O(2), one O(21), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, and  a cornercorner with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 29-48°. In the sixth P site, P(6) is bonded to one O(1), one O(11), one O(20), and one O(3) atom to form PO4 tetrahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, and  a cornercorner with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 17-49°. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Li(1), one V(1), and one P(6) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Li(1), one Mn(1), and one P(5) atom. In the third O site, O(3) is bonded in a linear geometry to one Mn(1) and one P(6) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Li(4), one Li(5), one V(1), and one P(2) atom. In the fifth O site, O(5) is bonded in a rectangular see-saw-like geometry to one Li(2), one Li(4), one Mn(1), and one P(1) atom. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Li(1), one Li(5), one V(1), and one P(3) atom. In the seventh O site, O(7) is bonded to one Li(1), one Li(2), one Li(4), one Mn(1), and one P(3) atom to form distorted corner-sharing OLi3MnP trigonal bipyramids. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one Li(3), one V(2), and one P(2) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one Li(2), one Li(6), one V(3), and one P(5) atom. In the tenth O site, O(10) is bonded in a linear geometry to one V(1) and one P(4) atom. In the eleventh O site, O(11) is bonded to one Li(3), one Li(5), one Li(6), one V(2), and one P(6) atom to form distorted corner-sharing OLi3VP trigonal bipyramids. In the twelfth O site, O(12) is bonded in a 3-coordinate geometry to one Li(4), one Mn(1), and one P(4) atom. In the thirteenth O site, O(13) is bonded in a 3-coordinate geometry to one Li(3), one V(3), and one P(3) atom. In the fourteenth O site, O(14) is bonded to one Li(1), one Li(4), one Li(5), one V(1), and one P(1) atom to form distorted OLi3VP trigonal bipyramids that share  a cornercorner with one O(11)Li3VP trigonal bipyramid and corners with two equivalent O(7)Li3MnP trigonal bipyramids. In the fifteenth O site, O(15) is bonded in a linear geometry to one V(2) and one P(3) atom. In the sixteenth O site, O(16) is bonded in a 4-coordinate geometry to one Li(1), one Li(2), one Mn(1), and one P(2) atom. In the seventeenth O site, O(17) is bonded in a 3-coordinate geometry to one Li(4), one V(1), and one P(5) atom. In the eighteenth O site, O(18) is bonded to one Li(2), one Li(3), one Li(6), one V(3), and one P(4) atom to form distorted OLi3VP trigonal bipyramids that share  a cornercorner with one O(7)Li3MnP trigonal bipyramid and corners with two equivalent O(11)Li3VP trigonal bipyramids. In the nineteenth O site, O(19) is bonded in a rectangular see-saw-like geometry to one Li(5), one Li(6), one V(2), and one P(4) atom. In the twentieth O site, O(20) is bonded in a rectangular see-saw-like geometry to one Li(2), one Li(3), one V(3), and one P(6) atom. In the twenty-first O site, O(21) is bonded in a 3-coordinate geometry to one Li(3), one Li(5), one V(2), and one P(5) atom. In the twenty-second O site, O(22) is bonded in a linear geometry to one V(3) and one P(1) atom. In the twenty-third O site, O(23) is bonded in a 3-coordinate geometry to one Li(6), one V(3), and one P(2) atom. In the twenty-fourth O site, O(24) is bonded in a 3-coordinate geometry to one Li(6), one V(2), and one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li6MnV3(PO4)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.456
_cell_length_b   8.598
_cell_length_c   8.647
_cell_angle_alpha   61.419
_cell_angle_beta   61.754
_cell_angle_gamma   62.781
_symmetry_Int_Tables_number   1
_cell_volume   464.126
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.255  0.125  0.842  1.0
  Li  Li1  1  0.997  0.501  0.999  1.0
  Li  Li2  1  0.128  0.258  0.341  1.0
  Li  Li3  1  0.872  0.741  0.662  1.0
  Li  Li4  1  0.499  1.000  0.501  1.0
  Li  Li5  1  0.742  0.874  0.159  1.0
  Mn  Mn6  1  0.856  0.362  0.851  1.0
  V  V7  1  0.636  0.145  0.645  1.0
  V  V8  1  0.363  0.855  0.355  1.0
  V  V9  1  0.146  0.636  0.143  1.0
  P  P10  1  0.550  0.753  0.963  1.0
  P  P11  1  0.950  0.049  0.248  1.0
  P  P12  1  0.248  0.450  0.537  1.0
  P  P13  1  0.750  0.549  0.464  1.0
  P  P14  1  0.052  0.949  0.750  1.0
  P  P15  1  0.453  0.250  0.036  1.0
  O  O16  1  0.466  0.188  0.889  1.0
  O  O17  1  0.031  0.109  0.798  1.0
  O  O18  1  0.617  0.320  0.974  1.0
  O  O19  1  0.763  0.062  0.417  1.0
  O  O20  1  0.748  0.612  0.924  1.0
  O  O21  1  0.393  0.256  0.579  1.0
  O  O22  1  0.081  0.454  0.728  1.0
  O  O23  1  0.116  0.021  0.299  1.0
  O  O24  1  0.062  0.762  0.917  1.0
  O  O25  1  0.682  0.386  0.527  1.0
  O  O26  1  0.458  0.086  0.226  1.0
  O  O27  1  0.811  0.538  0.613  1.0
  O  O28  1  0.186  0.464  0.389  1.0
  O  O29  1  0.540  0.917  0.774  1.0
  O  O30  1  0.316  0.612  0.479  1.0
  O  O31  1  0.942  0.234  0.079  1.0
  O  O32  1  0.884  0.979  0.701  1.0
  O  O33  1  0.914  0.544  0.275  1.0
  O  O34  1  0.604  0.744  0.422  1.0
  O  O35  1  0.256  0.395  0.077  1.0
  O  O36  1  0.238  0.935  0.581  1.0
  O  O37  1  0.388  0.681  0.025  1.0
  O  O38  1  0.977  0.884  0.202  1.0
  O  O39  1  0.531  0.817  0.112  1.0
[/CIF]
.