The compound described by MgV4MnCoO12 crystallizes in the triclinic P1 space group. Mg(1) is bonded in a 6-coordinate geometry to one O(12), one O(2), one O(3), one O(5), one O(6), and one O(9) atom. There are four inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(2), one O(4), and one O(6) atom to form VO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, and corners with two equivalent V(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 30-61°. In the second V site, V(2) is bonded to one O(3), one O(4), one O(6), and one O(8) atom to form VO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, and corners with two equivalent V(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 20-64°. In the third V site, V(3) is bonded to one O(10), one O(5), one O(7), and one O(9) atom to form VO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, and corners with two equivalent V(4)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 30-61°. In the fourth V site, V(4) is bonded to one O(11), one O(12), one O(7), and one O(9) atom to form VO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, and corners with two equivalent V(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 24-63°. Mn(1) is bonded to one O(1), one O(10), one O(11), one O(12), one O(3), and one O(8) atom to form MnO6 octahedra that share  a cornercorner with one V(1)O4 tetrahedra,  a cornercorner with one V(3)O4 tetrahedra, corners with two equivalent V(2)O4 tetrahedra, corners with two equivalent V(4)O4 tetrahedra, and edges with two equivalent Co(1)O6 octahedra. Co(1) is bonded to one O(1), one O(10), one O(12), one O(2), one O(3), and one O(5) atom to form CoO6 octahedra that share  a cornercorner with one V(2)O4 tetrahedra,  a cornercorner with one V(4)O4 tetrahedra, corners with two equivalent V(1)O4 tetrahedra, corners with two equivalent V(3)O4 tetrahedra, and edges with two equivalent Mn(1)O6 octahedra. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one V(1), one Mn(1), and one Co(1) atom. In the second O site, O(2) is bonded in a distorted T-shaped geometry to one Mg(1), one V(1), and one Co(1) atom. In the third O site, O(3) is bonded to one Mg(1), one V(2), one Mn(1), and one Co(1) atom to form a mixture of distorted corner and edge-sharing OMgMnVCo tetrahedra. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one V(1) and one V(2) atom. In the fifth O site, O(5) is bonded in a distorted T-shaped geometry to one Mg(1), one V(3), and one Co(1) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Mg(1), one V(1), and one V(2) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one V(3) and one V(4) atom. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one V(2) and one Mn(1) atom. In the ninth O site, O(9) is bonded in a distorted trigonal planar geometry to one Mg(1), one V(3), and one V(4) atom. In the tenth O site, O(10) is bonded in a distorted trigonal planar geometry to one V(3), one Mn(1), and one Co(1) atom. In the eleventh O site, O(11) is bonded in a bent 150 degrees geometry to one V(4) and one Mn(1) atom. In the twelfth O site, O(12) is bonded to one Mg(1), one V(4), one Mn(1), and one Co(1) atom to form a mixture of distorted corner and edge-sharing OMgMnVCo tetrahedra. is represented by the CIF card [CIF]
data_MgMnV4CoO12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.035
_cell_length_b   6.991
_cell_length_c   5.741
_cell_angle_alpha   73.178
_cell_angle_beta   107.083
_cell_angle_gamma   99.743
_symmetry_Int_Tables_number   1
_cell_volume   257.230
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.278  0.269  0.267  1.0
  Mn  Mn1  1  0.914  0.917  0.247  1.0
  V  V2  1  0.194  0.613  0.782  1.0
  V  V3  1  0.388  0.811  0.276  1.0
  V  V4  1  0.617  0.199  0.720  1.0
  V  V5  1  0.819  0.391  0.230  1.0
  Co  Co6  1  0.087  0.084  0.752  1.0
  O  O7  1  0.034  0.801  0.667  1.0
  O  O8  1  0.089  0.370  0.802  1.0
  O  O9  1  0.211  0.005  0.147  1.0
  O  O10  1  0.364  0.664  0.598  1.0
  O  O11  1  0.367  0.106  0.672  1.0
  O  O12  1  0.313  0.590  0.114  1.0
  O  O13  1  0.665  0.365  0.910  1.0
  O  O14  1  0.622  0.906  0.258  1.0
  O  O15  1  0.603  0.321  0.393  1.0
  O  O16  1  0.798  0.032  0.833  1.0
  O  O17  1  0.914  0.629  0.231  1.0
  O  O18  1  0.002  0.206  0.351  1.0
[/CIF]
.
The compound described by MgV4MnCoO12 crystallizes in the triclinic P1 space group. Mg(1) is bonded in a 6-coordinate geometry to one O(12), one O(2), one O(3), one O(5), one O(6), and one O(9) atom. There are four inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(2), one O(4), and one O(6) atom to form VO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, and corners with two equivalent V(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 30-61°. In the second V site, V(2) is bonded to one O(3), one O(4), one O(6), and one O(8) atom to form VO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, and corners with two equivalent V(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 20-64°. In the third V site, V(3) is bonded to one O(10), one O(5), one O(7), and one O(9) atom to form VO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, and corners with two equivalent V(4)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 30-61°. In the fourth V site, V(4) is bonded to one O(11), one O(12), one O(7), and one O(9) atom to form VO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, and corners with two equivalent V(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 24-63°. Mn(1) is bonded to one O(1), one O(10), one O(11), one O(12), one O(3), and one O(8) atom to form MnO6 octahedra that share  a cornercorner with one V(1)O4 tetrahedra,  a cornercorner with one V(3)O4 tetrahedra, corners with two equivalent V(2)O4 tetrahedra, corners with two equivalent V(4)O4 tetrahedra, and edges with two equivalent Co(1)O6 octahedra. Co(1) is bonded to one O(1), one O(10), one O(12), one O(2), one O(3), and one O(5) atom to form CoO6 octahedra that share  a cornercorner with one V(2)O4 tetrahedra,  a cornercorner with one V(4)O4 tetrahedra, corners with two equivalent V(1)O4 tetrahedra, corners with two equivalent V(3)O4 tetrahedra, and edges with two equivalent Mn(1)O6 octahedra. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one V(1), one Mn(1), and one Co(1) atom. In the second O site, O(2) is bonded in a distorted T-shaped geometry to one Mg(1), one V(1), and one Co(1) atom. In the third O site, O(3) is bonded to one Mg(1), one V(2), one Mn(1), and one Co(1) atom to form a mixture of distorted corner and edge-sharing OMgMnVCo tetrahedra. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one V(1) and one V(2) atom. In the fifth O site, O(5) is bonded in a distorted T-shaped geometry to one Mg(1), one V(3), and one Co(1) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Mg(1), one V(1), and one V(2) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one V(3) and one V(4) atom. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one V(2) and one Mn(1) atom. In the ninth O site, O(9) is bonded in a distorted trigonal planar geometry to one Mg(1), one V(3), and one V(4) atom. In the tenth O site, O(10) is bonded in a distorted trigonal planar geometry to one V(3), one Mn(1), and one Co(1) atom. In the eleventh O site, O(11) is bonded in a bent 150 degrees geometry to one V(4) and one Mn(1) atom. In the twelfth O site, O(12) is bonded to one Mg(1), one V(4), one Mn(1), and one Co(1) atom to form a mixture of distorted corner and edge-sharing OMgMnVCo tetrahedra. is represented by the CIF card [CIF]
data_MgMnV4CoO12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.035
_cell_length_b   6.991
_cell_length_c   5.741
_cell_angle_alpha   73.178
_cell_angle_beta   107.083
_cell_angle_gamma   99.743
_symmetry_Int_Tables_number   1
_cell_volume   257.230
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.278  0.269  0.267  1.0
  Mn  Mn1  1  0.914  0.917  0.247  1.0
  V  V2  1  0.194  0.613  0.782  1.0
  V  V3  1  0.388  0.811  0.276  1.0
  V  V4  1  0.617  0.199  0.720  1.0
  V  V5  1  0.819  0.391  0.230  1.0
  Co  Co6  1  0.087  0.084  0.752  1.0
  O  O7  1  0.034  0.801  0.667  1.0
  O  O8  1  0.089  0.370  0.802  1.0
  O  O9  1  0.211  0.005  0.147  1.0
  O  O10  1  0.364  0.664  0.598  1.0
  O  O11  1  0.367  0.106  0.672  1.0
  O  O12  1  0.313  0.590  0.114  1.0
  O  O13  1  0.665  0.365  0.910  1.0
  O  O14  1  0.622  0.906  0.258  1.0
  O  O15  1  0.603  0.321  0.393  1.0
  O  O16  1  0.798  0.032  0.833  1.0
  O  O17  1  0.914  0.629  0.231  1.0
  O  O18  1  0.002  0.206  0.351  1.0
[/CIF]
.