The material structure described by VO2 is trigonal omega-like structured and crystallizes in the tetragonal I4_1/a space group. V(1) is bonded to six equivalent O(1) atoms to form edge-sharing VO6 octahedra. O(1) is bonded in a distorted trigonal non-coplanar geometry to three equivalent V(1) atoms. is represented by the CIF card [CIF]
data_VO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.920
_cell_length_b   5.920
_cell_length_c   5.932
_cell_angle_alpha   120.029
_cell_angle_beta   120.029
_cell_angle_gamma   89.840
_symmetry_Int_Tables_number   1
_cell_volume   147.097
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.500  0.500  0.000  1.0
  V  V1  1  1.000  0.000  0.500  1.0
  V  V2  1  1.000  0.500  1.000  1.0
  V  V3  1  0.000  0.500  0.500  1.0
  O  O4  1  0.761  0.734  0.033  1.0
  O  O5  1  0.201  0.738  0.467  1.0
  O  O6  1  0.239  0.266  0.967  1.0
  O  O7  1  0.228  0.701  0.967  1.0
  O  O8  1  0.799  0.262  0.533  1.0
  O  O9  1  0.234  0.271  0.533  1.0
  O  O10  1  0.766  0.729  0.467  1.0
  O  O11  1  0.772  0.299  0.033  1.0
[/CIF]
.
The material structure described by VO2 is trigonal omega-like structured and crystallizes in the tetragonal I4_1/a space group. V(1) is bonded to six equivalent O(1) atoms to form edge-sharing VO6 octahedra. O(1) is bonded in a distorted trigonal non-coplanar geometry to three equivalent V(1) atoms. is represented by the CIF card [CIF]
data_VO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.920
_cell_length_b   5.920
_cell_length_c   5.932
_cell_angle_alpha   120.029
_cell_angle_beta   120.029
_cell_angle_gamma   89.840
_symmetry_Int_Tables_number   1
_cell_volume   147.097
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.500  0.500  0.000  1.0
  V  V1  1  1.000  0.000  0.500  1.0
  V  V2  1  1.000  0.500  1.000  1.0
  V  V3  1  0.000  0.500  0.500  1.0
  O  O4  1  0.761  0.734  0.033  1.0
  O  O5  1  0.201  0.738  0.467  1.0
  O  O6  1  0.239  0.266  0.967  1.0
  O  O7  1  0.228  0.701  0.967  1.0
  O  O8  1  0.799  0.262  0.533  1.0
  O  O9  1  0.234  0.271  0.533  1.0
  O  O10  1  0.766  0.729  0.467  1.0
  O  O11  1  0.772  0.299  0.033  1.0
[/CIF]
.