The material described by Cr(CoN)3 crystallizes in the monoclinic P2_1/m space group. Cr(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one N(3) atom. There are three inequivalent Co sites. In the first Co site, Co(1) is bonded in a see-saw-like geometry to one N(2), one N(3), and two equivalent N(1) atoms. In the second Co site, Co(2) is bonded in a see-saw-like geometry to one N(1), one N(3), and two equivalent N(2) atoms. In the third Co site, Co(3) is bonded in a see-saw-like geometry to one N(1), one N(2), and two equivalent N(3) atoms. There are three inequivalent N sites. In the first N site, N(1) is bonded to one Cr(1), one Co(2), one Co(3), and two equivalent Co(1) atoms to form a mixture of edge and corner-sharing NCrCo4 trigonal bipyramids. In the second N site, N(2) is bonded to one Cr(1), one Co(1), one Co(3), and two equivalent Co(2) atoms to form a mixture of edge and corner-sharing NCrCo4 trigonal bipyramids. In the third N site, N(3) is bonded to one Cr(1), one Co(1), one Co(2), and two equivalent Co(3) atoms to form a mixture of edge and corner-sharing NCrCo4 trigonal bipyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_Cr(CoN)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.384
_cell_length_b   6.302
_cell_length_c   3.876
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   119.281
_symmetry_Int_Tables_number   1
_cell_volume   136.022
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.664  0.333  0.750  1.0
  Cr  Cr1  1  0.336  0.667  0.250  1.0
  Co  Co2  1  0.823  0.641  0.250  1.0
  Co  Co3  1  0.822  0.181  0.250  1.0
  Co  Co4  1  0.361  0.180  0.250  1.0
  Co  Co5  1  0.177  0.359  0.750  1.0
  Co  Co6  1  0.178  0.819  0.750  1.0
  Co  Co7  1  0.639  0.820  0.750  1.0
  N  N8  1  0.832  0.661  0.750  1.0
  N  N9  1  0.831  0.170  0.750  1.0
  N  N10  1  0.340  0.170  0.750  1.0
  N  N11  1  0.168  0.339  0.250  1.0
  N  N12  1  0.169  0.830  0.250  1.0
  N  N13  1  0.660  0.830  0.250  1.0
[/CIF]
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The material described by Cr(CoN)3 crystallizes in the monoclinic P2_1/m space group. Cr(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one N(3) atom. There are three inequivalent Co sites. In the first Co site, Co(1) is bonded in a see-saw-like geometry to one N(2), one N(3), and two equivalent N(1) atoms. In the second Co site, Co(2) is bonded in a see-saw-like geometry to one N(1), one N(3), and two equivalent N(2) atoms. In the third Co site, Co(3) is bonded in a see-saw-like geometry to one N(1), one N(2), and two equivalent N(3) atoms. There are three inequivalent N sites. In the first N site, N(1) is bonded to one Cr(1), one Co(2), one Co(3), and two equivalent Co(1) atoms to form a mixture of edge and corner-sharing NCrCo4 trigonal bipyramids. In the second N site, N(2) is bonded to one Cr(1), one Co(1), one Co(3), and two equivalent Co(2) atoms to form a mixture of edge and corner-sharing NCrCo4 trigonal bipyramids. In the third N site, N(3) is bonded to one Cr(1), one Co(1), one Co(2), and two equivalent Co(3) atoms to form a mixture of edge and corner-sharing NCrCo4 trigonal bipyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_Cr(CoN)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.384
_cell_length_b   6.302
_cell_length_c   3.876
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   119.281
_symmetry_Int_Tables_number   1
_cell_volume   136.022
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.664  0.333  0.750  1.0
  Cr  Cr1  1  0.336  0.667  0.250  1.0
  Co  Co2  1  0.823  0.641  0.250  1.0
  Co  Co3  1  0.822  0.181  0.250  1.0
  Co  Co4  1  0.361  0.180  0.250  1.0
  Co  Co5  1  0.177  0.359  0.750  1.0
  Co  Co6  1  0.178  0.819  0.750  1.0
  Co  Co7  1  0.639  0.820  0.750  1.0
  N  N8  1  0.832  0.661  0.750  1.0
  N  N9  1  0.831  0.170  0.750  1.0
  N  N10  1  0.340  0.170  0.750  1.0
  N  N11  1  0.168  0.339  0.250  1.0
  N  N12  1  0.169  0.830  0.250  1.0
  N  N13  1  0.660  0.830  0.250  1.0
[/CIF]
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