The compound described by MnAg4P6(HO3)6 crystallizes in the triclinic P-1 space group. Mn(1) is bonded in a distorted square co-planar geometry to two equivalent H(1), two equivalent H(3), and two equivalent O(1) atoms. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a see-saw-like geometry to one O(4), one O(6), one O(7), and one O(9) atom. In the second Ag site, Ag(2) is bonded to one O(4), one O(6), one O(9), and two equivalent O(5) atoms to form AgO5 trigonal bipyramids that share  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, corners with three equivalent P(1)O4 tetrahedra, and  an edgeedge with one Ag(2)O5 trigonal bipyramid. There are three inequivalent P sites. In the first P site, P(1) is bonded to one O(2), one O(3), one O(5), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, and corners with three equivalent Ag(2)O5 trigonal bipyramids. In the second P site, P(2) is bonded to one O(3), one O(6), one O(7), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, and  a cornercorner with one Ag(2)O5 trigonal bipyramid. In the third P site, P(3) is bonded to one O(1), one O(2), one O(4), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, and  a cornercorner with one Ag(2)O5 trigonal bipyramid. There are three inequivalent H sites. In the first H site, H(1) is bonded in a distorted L-shaped geometry to one Mn(1) and one H(2) atom. In the second H site, H(2) is bonded in a distorted single-bond geometry to one H(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one Mn(1) atom. There are nine inequivalent O sites. In the first O site, O(9) is bonded in a 3-coordinate geometry to one Ag(1), one Ag(2), and one P(1) atom. In the second O site, O(1) is bonded in a bent 120 degrees geometry to one Mn(1) and one P(3) atom. In the third O site, O(2) is bonded in a bent 120 degrees geometry to one P(1) and one P(3) atom. In the fourth O site, O(3) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. In the fifth O site, O(4) is bonded in a distorted single-bond geometry to one Ag(1), one Ag(2), and one P(3) atom. In the sixth O site, O(5) is bonded in a 3-coordinate geometry to two equivalent Ag(2) and one P(1) atom. In the seventh O site, O(6) is bonded in a 3-coordinate geometry to one Ag(1), one Ag(2), and one P(2) atom. In the eighth O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Ag(1) and one P(2) atom. In the ninth O site, O(8) is bonded in a bent 120 degrees geometry to one P(2) and one P(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_MnAg4P6(HO3)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.629
_cell_length_b   8.937
_cell_length_c   9.117
_cell_angle_alpha   85.079
_cell_angle_beta   81.576
_cell_angle_gamma   68.421
_symmetry_Int_Tables_number   1
_cell_volume   496.531
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.000  0.000  0.000  1.0
  Ag  Ag1  1  0.355  0.408  0.753  1.0
  Ag  Ag2  1  0.645  0.592  0.247  1.0
  Ag  Ag3  1  0.218  0.810  0.501  1.0
  Ag  Ag4  1  0.782  0.190  0.499  1.0
  P  P5  1  0.710  0.792  0.574  1.0
  P  P6  1  0.290  0.208  0.426  1.0
  P  P7  1  0.821  0.484  0.750  1.0
  P  P8  1  0.179  0.516  0.250  1.0
  P  P9  1  0.434  0.750  0.834  1.0
  P  P10  1  0.566  0.250  0.166  1.0
  H  H11  1  0.024  0.055  0.773  1.0
  H  H12  1  0.976  0.945  0.227  1.0
  H  H13  1  0.943  0.877  0.204  1.0
  H  H14  1  0.057  0.123  0.796  1.0
  H  H15  1  0.917  0.873  0.922  1.0
  H  H16  1  0.083  0.127  0.078  1.0
  O  O17  1  0.680  0.156  0.028  1.0
  O  O18  1  0.320  0.844  0.972  1.0
  O  O19  1  0.549  0.859  0.726  1.0
  O  O20  1  0.451  0.141  0.274  1.0
  O  O21  1  0.869  0.615  0.629  1.0
  O  O22  1  0.131  0.385  0.371  1.0
  O  O23  1  0.304  0.691  0.747  1.0
  O  O24  1  0.696  0.309  0.253  1.0
  O  O25  1  0.850  0.893  0.535  1.0
  O  O26  1  0.150  0.107  0.465  1.0
  O  O27  1  0.706  0.393  0.685  1.0
  O  O28  1  0.294  0.607  0.315  1.0
  O  O29  1  0.971  0.612  0.187  1.0
  O  O30  1  0.029  0.388  0.813  1.0
  O  O31  1  0.649  0.600  0.879  1.0
  O  O32  1  0.351  0.400  0.121  1.0
  O  O33  1  0.579  0.777  0.458  1.0
  O  O34  1  0.421  0.223  0.542  1.0
[/CIF]
.
The compound described by MnAg4P6(HO3)6 crystallizes in the triclinic P-1 space group. Mn(1) is bonded in a distorted square co-planar geometry to two equivalent H(1), two equivalent H(3), and two equivalent O(1) atoms. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a see-saw-like geometry to one O(4), one O(6), one O(7), and one O(9) atom. In the second Ag site, Ag(2) is bonded to one O(4), one O(6), one O(9), and two equivalent O(5) atoms to form AgO5 trigonal bipyramids that share  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, corners with three equivalent P(1)O4 tetrahedra, and  an edgeedge with one Ag(2)O5 trigonal bipyramid. There are three inequivalent P sites. In the first P site, P(1) is bonded to one O(2), one O(3), one O(5), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, and corners with three equivalent Ag(2)O5 trigonal bipyramids. In the second P site, P(2) is bonded to one O(3), one O(6), one O(7), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, and  a cornercorner with one Ag(2)O5 trigonal bipyramid. In the third P site, P(3) is bonded to one O(1), one O(2), one O(4), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, and  a cornercorner with one Ag(2)O5 trigonal bipyramid. There are three inequivalent H sites. In the first H site, H(1) is bonded in a distorted L-shaped geometry to one Mn(1) and one H(2) atom. In the second H site, H(2) is bonded in a distorted single-bond geometry to one H(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one Mn(1) atom. There are nine inequivalent O sites. In the first O site, O(9) is bonded in a 3-coordinate geometry to one Ag(1), one Ag(2), and one P(1) atom. In the second O site, O(1) is bonded in a bent 120 degrees geometry to one Mn(1) and one P(3) atom. In the third O site, O(2) is bonded in a bent 120 degrees geometry to one P(1) and one P(3) atom. In the fourth O site, O(3) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. In the fifth O site, O(4) is bonded in a distorted single-bond geometry to one Ag(1), one Ag(2), and one P(3) atom. In the sixth O site, O(5) is bonded in a 3-coordinate geometry to two equivalent Ag(2) and one P(1) atom. In the seventh O site, O(6) is bonded in a 3-coordinate geometry to one Ag(1), one Ag(2), and one P(2) atom. In the eighth O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Ag(1) and one P(2) atom. In the ninth O site, O(8) is bonded in a bent 120 degrees geometry to one P(2) and one P(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_MnAg4P6(HO3)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.629
_cell_length_b   8.937
_cell_length_c   9.117
_cell_angle_alpha   85.079
_cell_angle_beta   81.576
_cell_angle_gamma   68.421
_symmetry_Int_Tables_number   1
_cell_volume   496.531
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.000  0.000  0.000  1.0
  Ag  Ag1  1  0.355  0.408  0.753  1.0
  Ag  Ag2  1  0.645  0.592  0.247  1.0
  Ag  Ag3  1  0.218  0.810  0.501  1.0
  Ag  Ag4  1  0.782  0.190  0.499  1.0
  P  P5  1  0.710  0.792  0.574  1.0
  P  P6  1  0.290  0.208  0.426  1.0
  P  P7  1  0.821  0.484  0.750  1.0
  P  P8  1  0.179  0.516  0.250  1.0
  P  P9  1  0.434  0.750  0.834  1.0
  P  P10  1  0.566  0.250  0.166  1.0
  H  H11  1  0.024  0.055  0.773  1.0
  H  H12  1  0.976  0.945  0.227  1.0
  H  H13  1  0.943  0.877  0.204  1.0
  H  H14  1  0.057  0.123  0.796  1.0
  H  H15  1  0.917  0.873  0.922  1.0
  H  H16  1  0.083  0.127  0.078  1.0
  O  O17  1  0.680  0.156  0.028  1.0
  O  O18  1  0.320  0.844  0.972  1.0
  O  O19  1  0.549  0.859  0.726  1.0
  O  O20  1  0.451  0.141  0.274  1.0
  O  O21  1  0.869  0.615  0.629  1.0
  O  O22  1  0.131  0.385  0.371  1.0
  O  O23  1  0.304  0.691  0.747  1.0
  O  O24  1  0.696  0.309  0.253  1.0
  O  O25  1  0.850  0.893  0.535  1.0
  O  O26  1  0.150  0.107  0.465  1.0
  O  O27  1  0.706  0.393  0.685  1.0
  O  O28  1  0.294  0.607  0.315  1.0
  O  O29  1  0.971  0.612  0.187  1.0
  O  O30  1  0.029  0.388  0.813  1.0
  O  O31  1  0.649  0.600  0.879  1.0
  O  O32  1  0.351  0.400  0.121  1.0
  O  O33  1  0.579  0.777  0.458  1.0
  O  O34  1  0.421  0.223  0.542  1.0
[/CIF]
.