The compound described by NaAg(CO2)2 crystallizes in the monoclinic Pc space group. Na(1) is bonded to one O(1), one O(3), two equivalent O(2), and two equivalent O(4) atoms to form distorted edge-sharing NaO6 octahedra. Ag(1) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(4) atom. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(3) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Na(1), one Ag(1), and one C(2) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to two equivalent Na(1), one Ag(1), and one C(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Na(1), one Ag(1), and one C(2) atom. In the fourth O site, O(4) is bonded to two equivalent Na(1), one Ag(1), and one C(1) atom to form distorted corner-sharing ONa2AgC tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_NaAg(CO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.316
_cell_length_b   3.556
_cell_length_c   11.096
_cell_angle_alpha   83.831
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   208.511
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.810  0.687  0.854  1.0
  Na  Na1  1  0.190  0.687  0.354  1.0
  Ag  Ag2  1  0.677  0.298  0.157  1.0
  Ag  Ag3  1  0.323  0.298  0.657  1.0
  C  C4  1  0.711  0.114  0.439  1.0
  C  C5  1  0.289  0.114  0.939  1.0
  C  C6  1  0.817  0.895  0.559  1.0
  C  C7  1  0.183  0.895  0.059  1.0
  O  O8  1  0.976  0.725  0.048  1.0
  O  O9  1  0.024  0.725  0.548  1.0
  O  O10  1  0.514  0.230  0.938  1.0
  O  O11  1  0.486  0.230  0.438  1.0
  O  O12  1  0.310  0.899  0.156  1.0
  O  O13  1  0.690  0.899  0.656  1.0
  O  O14  1  0.138  0.152  0.849  1.0
  O  O15  1  0.862  0.152  0.349  1.0
[/CIF]
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The compound described by NaAg(CO2)2 crystallizes in the monoclinic Pc space group. Na(1) is bonded to one O(1), one O(3), two equivalent O(2), and two equivalent O(4) atoms to form distorted edge-sharing NaO6 octahedra. Ag(1) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(4) atom. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(3) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Na(1), one Ag(1), and one C(2) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to two equivalent Na(1), one Ag(1), and one C(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Na(1), one Ag(1), and one C(2) atom. In the fourth O site, O(4) is bonded to two equivalent Na(1), one Ag(1), and one C(1) atom to form distorted corner-sharing ONa2AgC tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_NaAg(CO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.316
_cell_length_b   3.556
_cell_length_c   11.096
_cell_angle_alpha   83.831
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   208.511
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.810  0.687  0.854  1.0
  Na  Na1  1  0.190  0.687  0.354  1.0
  Ag  Ag2  1  0.677  0.298  0.157  1.0
  Ag  Ag3  1  0.323  0.298  0.657  1.0
  C  C4  1  0.711  0.114  0.439  1.0
  C  C5  1  0.289  0.114  0.939  1.0
  C  C6  1  0.817  0.895  0.559  1.0
  C  C7  1  0.183  0.895  0.059  1.0
  O  O8  1  0.976  0.725  0.048  1.0
  O  O9  1  0.024  0.725  0.548  1.0
  O  O10  1  0.514  0.230  0.938  1.0
  O  O11  1  0.486  0.230  0.438  1.0
  O  O12  1  0.310  0.899  0.156  1.0
  O  O13  1  0.690  0.899  0.656  1.0
  O  O14  1  0.138  0.152  0.849  1.0
  O  O15  1  0.862  0.152  0.349  1.0
[/CIF]
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