The compound described by H3OClO4 is Indium-like structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four hypochlorous acid;tetrahydrate molecules. There are three inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(1) and one O(4) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(4) atom. There are four inequivalent O sites. In the first O site, O(4) is bonded in a trigonal planar geometry to one H(1), one H(2), and one H(3) atom. In the second O site, O(1) is bonded in a distorted bent 120 degrees geometry to one H(1) and one Cl(1) atom. In the third O site, O(2) is bonded in a single-bond geometry to one Cl(1) atom. In the fourth O site, O(3) is bonded in a single-bond geometry to one Cl(1) atom. Cl(1) is bonded in a tetrahedral geometry to one O(1), one O(2), and two equivalent O(3) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_H3ClO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.457
_cell_length_b   7.109
_cell_length_c   9.792
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   449.526
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.250  0.580  0.813  1.0
  H  H1  1  0.250  0.920  0.313  1.0
  H  H2  1  0.750  0.420  0.187  1.0
  H  H3  1  0.750  0.080  0.687  1.0
  H  H4  1  0.750  0.141  0.104  1.0
  H  H5  1  0.750  0.150  0.266  1.0
  H  H6  1  0.750  0.350  0.766  1.0
  H  H7  1  0.750  0.359  0.604  1.0
  H  H8  1  0.250  0.850  0.734  1.0
  H  H9  1  0.250  0.859  0.896  1.0
  H  H10  1  0.250  0.650  0.234  1.0
  H  H11  1  0.250  0.641  0.396  1.0
  Cl  Cl12  1  0.250  0.306  0.924  1.0
  Cl  Cl13  1  0.250  0.194  0.424  1.0
  Cl  Cl14  1  0.750  0.694  0.076  1.0
  Cl  Cl15  1  0.750  0.806  0.576  1.0
  O  O16  1  0.250  0.432  0.790  1.0
  O  O17  1  0.250  0.068  0.290  1.0
  O  O18  1  0.750  0.568  0.210  1.0
  O  O19  1  0.750  0.932  0.710  1.0
  O  O20  1  0.250  0.431  0.038  1.0
  O  O21  1  0.250  0.069  0.538  1.0
  O  O22  1  0.750  0.569  0.962  1.0
  O  O23  1  0.750  0.931  0.462  1.0
  O  O24  1  0.066  0.192  0.914  1.0
  O  O25  1  0.434  0.308  0.414  1.0
  O  O26  1  0.566  0.808  0.086  1.0
  O  O27  1  0.934  0.692  0.586  1.0
  O  O28  1  0.934  0.808  0.086  1.0
  O  O29  1  0.566  0.692  0.586  1.0
  O  O30  1  0.434  0.192  0.914  1.0
  O  O31  1  0.066  0.308  0.414  1.0
  O  O32  1  0.750  0.225  0.183  1.0
  O  O33  1  0.750  0.275  0.683  1.0
  O  O34  1  0.250  0.775  0.817  1.0
  O  O35  1  0.250  0.725  0.317  1.0
[/CIF]
.
The compound described by H3OClO4 is Indium-like structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four hypochlorous acid;tetrahydrate molecules. There are three inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(1) and one O(4) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(4) atom. There are four inequivalent O sites. In the first O site, O(4) is bonded in a trigonal planar geometry to one H(1), one H(2), and one H(3) atom. In the second O site, O(1) is bonded in a distorted bent 120 degrees geometry to one H(1) and one Cl(1) atom. In the third O site, O(2) is bonded in a single-bond geometry to one Cl(1) atom. In the fourth O site, O(3) is bonded in a single-bond geometry to one Cl(1) atom. Cl(1) is bonded in a tetrahedral geometry to one O(1), one O(2), and two equivalent O(3) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_H3ClO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.457
_cell_length_b   7.109
_cell_length_c   9.792
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   449.526
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.250  0.580  0.813  1.0
  H  H1  1  0.250  0.920  0.313  1.0
  H  H2  1  0.750  0.420  0.187  1.0
  H  H3  1  0.750  0.080  0.687  1.0
  H  H4  1  0.750  0.141  0.104  1.0
  H  H5  1  0.750  0.150  0.266  1.0
  H  H6  1  0.750  0.350  0.766  1.0
  H  H7  1  0.750  0.359  0.604  1.0
  H  H8  1  0.250  0.850  0.734  1.0
  H  H9  1  0.250  0.859  0.896  1.0
  H  H10  1  0.250  0.650  0.234  1.0
  H  H11  1  0.250  0.641  0.396  1.0
  Cl  Cl12  1  0.250  0.306  0.924  1.0
  Cl  Cl13  1  0.250  0.194  0.424  1.0
  Cl  Cl14  1  0.750  0.694  0.076  1.0
  Cl  Cl15  1  0.750  0.806  0.576  1.0
  O  O16  1  0.250  0.432  0.790  1.0
  O  O17  1  0.250  0.068  0.290  1.0
  O  O18  1  0.750  0.568  0.210  1.0
  O  O19  1  0.750  0.932  0.710  1.0
  O  O20  1  0.250  0.431  0.038  1.0
  O  O21  1  0.250  0.069  0.538  1.0
  O  O22  1  0.750  0.569  0.962  1.0
  O  O23  1  0.750  0.931  0.462  1.0
  O  O24  1  0.066  0.192  0.914  1.0
  O  O25  1  0.434  0.308  0.414  1.0
  O  O26  1  0.566  0.808  0.086  1.0
  O  O27  1  0.934  0.692  0.586  1.0
  O  O28  1  0.934  0.808  0.086  1.0
  O  O29  1  0.566  0.692  0.586  1.0
  O  O30  1  0.434  0.192  0.914  1.0
  O  O31  1  0.066  0.308  0.414  1.0
  O  O32  1  0.750  0.225  0.183  1.0
  O  O33  1  0.750  0.275  0.683  1.0
  O  O34  1  0.250  0.775  0.817  1.0
  O  O35  1  0.250  0.725  0.317  1.0
[/CIF]
.