The material described by BS2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two octaboron hexadecasulfide molecules. There are four inequivalent B sites. In the first B site, B(1) is bonded in a trigonal planar geometry to one S(1), one S(3), and one S(8) atom. In the second B site, B(2) is bonded in a trigonal planar geometry to one S(2), one S(3), and one S(4) atom. In the third B site, B(3) is bonded in a trigonal planar geometry to one S(4), one S(5), and one S(7) atom. In the fourth B site, B(4) is bonded in a trigonal planar geometry to one S(6), one S(7), and one S(8) atom. There are eight inequivalent S sites. In the first S site, S(5) is bonded in a distorted single-bond geometry to one B(3) atom. In the second S site, S(6) is bonded in a distorted single-bond geometry to one B(4) atom. In the third S site, S(7) is bonded in a water-like geometry to one B(3) and one B(4) atom. In the fourth S site, S(8) is bonded in a bent 120 degrees geometry to one B(1) and one B(4) atom. In the fifth S site, S(1) is bonded in a distorted single-bond geometry to one B(1) atom. In the sixth S site, S(2) is bonded in a distorted single-bond geometry to one B(2) atom. In the seventh S site, S(3) is bonded in a water-like geometry to one B(1) and one B(2) atom. In the eighth S site, S(4) is bonded in a bent 120 degrees geometry to one B(2) and one B(3) atom. is represented by the CIF card [CIF]
data_BS2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.207
_cell_length_b   12.322
_cell_length_c   21.561
_cell_angle_alpha   104.657
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1081.315
_cell_formula_units_Z   16
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.630  0.220  0.133  1.0
  B  B1  1  0.130  0.280  0.367  1.0
  B  B2  1  0.370  0.780  0.867  1.0
  B  B3  1  0.870  0.720  0.633  1.0
  B  B4  1  0.812  0.308  0.034  1.0
  B  B5  1  0.312  0.192  0.466  1.0
  B  B6  1  0.188  0.692  0.966  1.0
  B  B7  1  0.688  0.808  0.534  1.0
  B  B8  1  0.884  0.785  0.096  1.0
  B  B9  1  0.384  0.715  0.404  1.0
  B  B10  1  0.116  0.215  0.904  1.0
  B  B11  1  0.616  0.285  0.596  1.0
  B  B12  1  0.658  0.992  0.160  1.0
  B  B13  1  0.158  0.508  0.340  1.0
  B  B14  1  0.342  0.008  0.840  1.0
  B  B15  1  0.842  0.492  0.660  1.0
  S  S16  1  0.518  0.364  0.164  1.0
  S  S17  1  0.018  0.136  0.336  1.0
  S  S18  1  0.482  0.636  0.836  1.0
  S  S19  1  0.982  0.864  0.664  1.0
  S  S20  1  0.659  0.430  0.090  1.0
  S  S21  1  0.159  0.070  0.410  1.0
  S  S22  1  0.341  0.570  0.910  1.0
  S  S23  1  0.841  0.930  0.590  1.0
  S  S24  1  0.809  0.175  0.055  1.0
  S  S25  1  0.309  0.325  0.445  1.0
  S  S26  1  0.191  0.825  0.945  1.0
  S  S27  1  0.691  0.675  0.555  1.0
  S  S28  1  0.946  0.337  0.960  1.0
  S  S29  1  0.446  0.163  0.540  1.0
  S  S30  1  0.054  0.663  0.040  1.0
  S  S31  1  0.554  0.837  0.460  1.0
  S  S32  1  0.747  0.756  0.169  1.0
  S  S33  1  0.247  0.744  0.331  1.0
  S  S34  1  0.253  0.244  0.831  1.0
  S  S35  1  0.753  0.256  0.669  1.0
  S  S36  1  0.576  0.911  0.217  1.0
  S  S37  1  0.076  0.589  0.283  1.0
  S  S38  1  0.424  0.089  0.783  1.0
  S  S39  1  0.924  0.411  0.717  1.0
  S  S40  1  0.841  0.925  0.085  1.0
  S  S41  1  0.341  0.575  0.415  1.0
  S  S42  1  0.159  0.075  0.915  1.0
  S  S43  1  0.659  0.425  0.585  1.0
  S  S44  1  0.536  0.137  0.190  1.0
  S  S45  1  0.036  0.363  0.310  1.0
  S  S46  1  0.464  0.863  0.810  1.0
  S  S47  1  0.964  0.637  0.690  1.0
[/CIF]
.
The material described by BS2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two octaboron hexadecasulfide molecules. There are four inequivalent B sites. In the first B site, B(1) is bonded in a trigonal planar geometry to one S(1), one S(3), and one S(8) atom. In the second B site, B(2) is bonded in a trigonal planar geometry to one S(2), one S(3), and one S(4) atom. In the third B site, B(3) is bonded in a trigonal planar geometry to one S(4), one S(5), and one S(7) atom. In the fourth B site, B(4) is bonded in a trigonal planar geometry to one S(6), one S(7), and one S(8) atom. There are eight inequivalent S sites. In the first S site, S(5) is bonded in a distorted single-bond geometry to one B(3) atom. In the second S site, S(6) is bonded in a distorted single-bond geometry to one B(4) atom. In the third S site, S(7) is bonded in a water-like geometry to one B(3) and one B(4) atom. In the fourth S site, S(8) is bonded in a bent 120 degrees geometry to one B(1) and one B(4) atom. In the fifth S site, S(1) is bonded in a distorted single-bond geometry to one B(1) atom. In the sixth S site, S(2) is bonded in a distorted single-bond geometry to one B(2) atom. In the seventh S site, S(3) is bonded in a water-like geometry to one B(1) and one B(2) atom. In the eighth S site, S(4) is bonded in a bent 120 degrees geometry to one B(2) and one B(3) atom. is represented by the CIF card [CIF]
data_BS2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.207
_cell_length_b   12.322
_cell_length_c   21.561
_cell_angle_alpha   104.657
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1081.315
_cell_formula_units_Z   16
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.630  0.220  0.133  1.0
  B  B1  1  0.130  0.280  0.367  1.0
  B  B2  1  0.370  0.780  0.867  1.0
  B  B3  1  0.870  0.720  0.633  1.0
  B  B4  1  0.812  0.308  0.034  1.0
  B  B5  1  0.312  0.192  0.466  1.0
  B  B6  1  0.188  0.692  0.966  1.0
  B  B7  1  0.688  0.808  0.534  1.0
  B  B8  1  0.884  0.785  0.096  1.0
  B  B9  1  0.384  0.715  0.404  1.0
  B  B10  1  0.116  0.215  0.904  1.0
  B  B11  1  0.616  0.285  0.596  1.0
  B  B12  1  0.658  0.992  0.160  1.0
  B  B13  1  0.158  0.508  0.340  1.0
  B  B14  1  0.342  0.008  0.840  1.0
  B  B15  1  0.842  0.492  0.660  1.0
  S  S16  1  0.518  0.364  0.164  1.0
  S  S17  1  0.018  0.136  0.336  1.0
  S  S18  1  0.482  0.636  0.836  1.0
  S  S19  1  0.982  0.864  0.664  1.0
  S  S20  1  0.659  0.430  0.090  1.0
  S  S21  1  0.159  0.070  0.410  1.0
  S  S22  1  0.341  0.570  0.910  1.0
  S  S23  1  0.841  0.930  0.590  1.0
  S  S24  1  0.809  0.175  0.055  1.0
  S  S25  1  0.309  0.325  0.445  1.0
  S  S26  1  0.191  0.825  0.945  1.0
  S  S27  1  0.691  0.675  0.555  1.0
  S  S28  1  0.946  0.337  0.960  1.0
  S  S29  1  0.446  0.163  0.540  1.0
  S  S30  1  0.054  0.663  0.040  1.0
  S  S31  1  0.554  0.837  0.460  1.0
  S  S32  1  0.747  0.756  0.169  1.0
  S  S33  1  0.247  0.744  0.331  1.0
  S  S34  1  0.253  0.244  0.831  1.0
  S  S35  1  0.753  0.256  0.669  1.0
  S  S36  1  0.576  0.911  0.217  1.0
  S  S37  1  0.076  0.589  0.283  1.0
  S  S38  1  0.424  0.089  0.783  1.0
  S  S39  1  0.924  0.411  0.717  1.0
  S  S40  1  0.841  0.925  0.085  1.0
  S  S41  1  0.341  0.575  0.415  1.0
  S  S42  1  0.159  0.075  0.915  1.0
  S  S43  1  0.659  0.425  0.585  1.0
  S  S44  1  0.536  0.137  0.190  1.0
  S  S45  1  0.036  0.363  0.310  1.0
  S  S46  1  0.464  0.863  0.810  1.0
  S  S47  1  0.964  0.637  0.690  1.0
[/CIF]
.