The structure described by Li4WMnSb2O12 crystallizes in the triclinic P1 space group. There are eight inequivalent Li sites. In the first Li site, Li(1) is bonded in a 6-coordinate geometry to one O(1), one O(13), one O(16), one O(17), one O(21), and one O(7) atom. In the second Li site, Li(2) is bonded in a 6-coordinate geometry to one O(14), one O(15), one O(18), one O(2), one O(22), and one O(8) atom. In the third Li site, Li(3) is bonded in a 6-coordinate geometry to one O(11), one O(19), one O(24), one O(3), one O(5), and one O(9) atom. In the fourth Li site, Li(4) is bonded in a 6-coordinate geometry to one O(10), one O(12), one O(20), one O(23), one O(4), and one O(6) atom. In the fifth Li site, Li(5) is bonded in a 6-coordinate geometry to one O(10), one O(11), one O(17), one O(23), one O(3), and one O(7) atom. In the sixth Li site, Li(6) is bonded in a 6-coordinate geometry to one O(12), one O(18), one O(24), one O(4), one O(8), and one O(9) atom. In the seventh Li site, Li(7) is bonded to one O(13), one O(2), one O(21), one O(23), one O(5), and one O(8) atom to form distorted LiO6 octahedra that share  a cornercorner with one W(1)O6 octahedra,  a cornercorner with one W(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra,  an edgeedge with one Sb(3)O6 octahedra, and  a faceface with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 57-61°. In the eighth Li site, Li(8) is bonded to one O(1), one O(14), one O(22), one O(24), one O(6), and one O(7) atom to form distorted LiO6 octahedra that share  a cornercorner with one W(1)O6 octahedra,  a cornercorner with one W(2)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra,  an edgeedge with one Sb(4)O6 octahedra, and  a faceface with one Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 57-61°. There are two inequivalent W sites. In the first W site, W(1) is bonded to one O(16), one O(19), one O(21), one O(4), one O(6), and one O(9) atom to form WO6 octahedra that share  a cornercorner with one Li(7)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  a cornercorner with one Sb(1)O6 octahedra,  a cornercorner with one Sb(2)O6 octahedra, corners with two equivalent Sb(3)O6 octahedra, and corners with two equivalent Sb(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 38-61°. In the second W site, W(2) is bonded to one O(10), one O(15), one O(20), one O(22), one O(3), and one O(5) atom to form WO6 octahedra that share  a cornercorner with one Li(7)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  a cornercorner with one Sb(1)O6 octahedra,  a cornercorner with one Sb(2)O6 octahedra, corners with two equivalent Sb(3)O6 octahedra, and corners with two equivalent Sb(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 38-61°. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(12), one O(13), one O(17), one O(2), one O(23), and one O(8) atom to form MnO6 octahedra that share  a cornercorner with one Li(7)O6 octahedra,  a cornercorner with one Sb(3)O6 octahedra,  a cornercorner with one Sb(4)O6 octahedra, corners with two equivalent Sb(1)O6 octahedra, corners with two equivalent Sb(2)O6 octahedra, and  a faceface with one Li(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 35-60°. In the second Mn site, Mn(2) is bonded to one O(1), one O(11), one O(14), one O(18), one O(24), and one O(7) atom to form MnO6 octahedra that share  a cornercorner with one Li(8)O6 octahedra,  a cornercorner with one Sb(3)O6 octahedra,  a cornercorner with one Sb(4)O6 octahedra, corners with two equivalent Sb(1)O6 octahedra, corners with two equivalent Sb(2)O6 octahedra, and  a faceface with one Li(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 35-61°. There are four inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(1), one O(17), one O(21), one O(23), one O(3), and one O(7) atom to form SbO6 octahedra that share  a cornercorner with one W(1)O6 octahedra,  a cornercorner with one W(2)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra, and  an edgeedge with one Li(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 35-39°. In the second Sb site, Sb(2) is bonded to one O(18), one O(2), one O(22), one O(24), one O(4), and one O(8) atom to form SbO6 octahedra that share  a cornercorner with one W(1)O6 octahedra,  a cornercorner with one W(2)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra, and  an edgeedge with one Li(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 35-39°. In the third Sb site, Sb(3) is bonded to one O(11), one O(13), one O(15), one O(19), one O(5), and one O(9) atom to form SbO6 octahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra, corners with two equivalent W(1)O6 octahedra, corners with two equivalent W(2)O6 octahedra, and  an edgeedge with one Li(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 38-42°. In the fourth Sb site, Sb(4) is bonded to one O(10), one O(12), one O(14), one O(16), one O(20), and one O(6) atom to form SbO6 octahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra, corners with two equivalent W(1)O6 octahedra, corners with two equivalent W(2)O6 octahedra, and  an edgeedge with one Li(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 38-42°. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a distorted see-saw-like geometry to one Li(1), one Li(8), one Mn(2), and one Sb(1) atom. In the second O site, O(2) is bonded in a distorted see-saw-like geometry to one Li(2), one Li(7), one Mn(1), and one Sb(2) atom. In the third O site, O(3) is bonded to one Li(3), one Li(5), one W(2), and one Sb(1) atom to form distorted OLi2SbW trigonal pyramids that share  a cornercorner with one O(9)Li2SbW trigonal pyramid, corners with two equivalent O(17)Li2MnSb trigonal pyramids,  an edgeedge with one O(11)Li2MnSb trigonal pyramid, and  an edgeedge with one O(10)Li2SbW trigonal pyramid. In the fourth O site, O(4) is bonded to one Li(4), one Li(6), one W(1), and one Sb(2) atom to form distorted OLi2SbW trigonal pyramids that share  a cornercorner with one O(10)Li2SbW trigonal pyramid, corners with two equivalent O(18)Li2MnSb trigonal pyramids,  an edgeedge with one O(12)Li2MnSb trigonal pyramid, and  an edgeedge with one O(9)Li2SbW trigonal pyramid. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to one Li(3), one Li(7), one W(2), and one Sb(3) atom. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to one Li(4), one Li(8), one W(1), and one Sb(4) atom. In the seventh O site, O(7) is bonded in a 5-coordinate geometry to one Li(1), one Li(5), one Li(8), one Mn(2), and one Sb(1) atom. In the eighth O site, O(8) is bonded in a 5-coordinate geometry to one Li(2), one Li(6), one Li(7), one Mn(1), and one Sb(2) atom. In the ninth O site, O(9) is bonded to one Li(3), one Li(6), one W(1), and one Sb(3) atom to form OLi2SbW trigonal pyramids that share  a cornercorner with one O(12)Li2MnSb trigonal pyramid,  a cornercorner with one O(18)Li2MnSb trigonal pyramid,  a cornercorner with one O(3)Li2SbW trigonal pyramid,  an edgeedge with one O(11)Li2MnSb trigonal pyramid, and  an edgeedge with one O(4)Li2SbW trigonal pyramid. In the tenth O site, O(10) is bonded to one Li(4), one Li(5), one W(2), and one Sb(4) atom to form OLi2SbW trigonal pyramids that share  a cornercorner with one O(11)Li2MnSb trigonal pyramid,  a cornercorner with one O(17)Li2MnSb trigonal pyramid,  a cornercorner with one O(4)Li2SbW trigonal pyramid,  an edgeedge with one O(12)Li2MnSb trigonal pyramid, and  an edgeedge with one O(3)Li2SbW trigonal pyramid. In the eleventh O site, O(11) is bonded to one Li(3), one Li(5), one Mn(2), and one Sb(3) atom to form OLi2MnSb trigonal pyramids that share  a cornercorner with one O(17)Li2MnSb trigonal pyramid,  a cornercorner with one O(18)Li2MnSb trigonal pyramid,  a cornercorner with one O(10)Li2SbW trigonal pyramid,  an edgeedge with one O(3)Li2SbW trigonal pyramid, and  an edgeedge with one O(9)Li2SbW trigonal pyramid. In the twelfth O site, O(12) is bonded to one Li(4), one Li(6), one Mn(1), and one Sb(4) atom to form OLi2MnSb trigonal pyramids that share  a cornercorner with one O(17)Li2MnSb trigonal pyramid,  a cornercorner with one O(18)Li2MnSb trigonal pyramid,  a cornercorner with one O(9)Li2SbW trigonal pyramid,  an edgeedge with one O(10)Li2SbW trigonal pyramid, and  an edgeedge with one O(4)Li2SbW trigonal pyramid. In the thirteenth O site, O(13) is bonded in a distorted see-saw-like geometry to one Li(1), one Li(7), one Mn(1), and one Sb(3) atom. In the fourteenth O site, O(14) is bonded in a distorted see-saw-like geometry to one Li(2), one Li(8), one Mn(2), and one Sb(4) atom. In the fifteenth O site, O(15) is bonded in a distorted trigonal planar geometry to one Li(2), one W(2), and one Sb(3) atom. In the sixteenth O site, O(16) is bonded in a distorted trigonal planar geometry to one Li(1), one W(1), and one Sb(4) atom. In the seventeenth O site, O(17) is bonded to one Li(1), one Li(5), one Mn(1), and one Sb(1) atom to form OLi2MnSb trigonal pyramids that share  a cornercorner with one O(11)Li2MnSb trigonal pyramid,  a cornercorner with one O(12)Li2MnSb trigonal pyramid,  a cornercorner with one O(10)Li2SbW trigonal pyramid, and corners with two equivalent O(3)Li2SbW trigonal pyramids. In the eighteenth O site, O(18) is bonded to one Li(2), one Li(6), one Mn(2), and one Sb(2) atom to form OLi2MnSb trigonal pyramids that share  a cornercorner with one O(11)Li2MnSb trigonal pyramid,  a cornercorner with one O(12)Li2MnSb trigonal pyramid,  a cornercorner with one O(9)Li2SbW trigonal pyramid, and corners with two equivalent O(4)Li2SbW trigonal pyramids. In the nineteenth O site, O(19) is bonded in a distorted trigonal planar geometry to one Li(3), one W(1), and one Sb(3) atom. In the twentieth O site, O(20) is bonded in a distorted trigonal planar geometry to one Li(4), one W(2), and one Sb(4) atom. In the twenty-first O site, O(21) is bonded in a 4-coordinate geometry to one Li(1), one Li(7), one W(1), and one Sb(1) atom. In the twenty-second O site, O(22) is bonded in a 4-coordinate geometry to one Li(2), one Li(8), one W(2), and one Sb(2) atom. In the twenty-third O site, O(23) is bonded in a 5-coordinate geometry to one Li(4), one Li(5), one Li(7), one Mn(1), and one Sb(1) atom. In the twenty-fourth O site, O(24) is bonded in a 5-coordinate geometry to one Li(3), one Li(6), one Li(8), one Mn(2), and one Sb(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li4MnSb2WO12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.129
_cell_length_b   5.439
_cell_length_c   7.482
_cell_angle_alpha   94.501
_cell_angle_beta   89.885
_cell_angle_gamma   90.051
_symmetry_Int_Tables_number   1
_cell_volume   208.067
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.998  0.560  0.698  1.0
  Li  Li1  1  0.500  0.088  0.228  1.0
  Li  Li2  1  0.001  0.437  0.291  1.0
  Li  Li3  1  0.499  0.100  0.692  1.0
  Mn  Mn4  1  0.501  0.508  0.500  1.0
  O  O5  1  0.309  0.802  0.571  1.0
  O  O6  1  0.126  0.005  0.241  1.0
  O  O7  1  0.311  0.181  0.940  1.0
  O  O8  1  0.200  0.306  0.564  1.0
  O  O9  1  0.813  0.306  0.066  1.0
  O  O10  1  0.376  0.482  0.251  1.0
  O  O11  1  0.627  0.485  0.750  1.0
  O  O12  1  0.172  0.688  0.936  1.0
  O  O13  1  0.817  0.676  0.447  1.0
  O  O14  1  0.686  0.827  0.069  1.0
  O  O15  1  0.872  0.993  0.754  1.0
  O  O16  1  0.689  0.192  0.442  1.0
  Sb  Sb17  1  0.003  0.996  0.495  1.0
  Sb  Sb18  1  0.500  0.511  0.000  1.0
  W  W19  1  0.999  0.000  0.995  1.0
[/CIF]
.
The structure described by Li4WMnSb2O12 crystallizes in the triclinic P1 space group. There are eight inequivalent Li sites. In the first Li site, Li(1) is bonded in a 6-coordinate geometry to one O(1), one O(13), one O(16), one O(17), one O(21), and one O(7) atom. In the second Li site, Li(2) is bonded in a 6-coordinate geometry to one O(14), one O(15), one O(18), one O(2), one O(22), and one O(8) atom. In the third Li site, Li(3) is bonded in a 6-coordinate geometry to one O(11), one O(19), one O(24), one O(3), one O(5), and one O(9) atom. In the fourth Li site, Li(4) is bonded in a 6-coordinate geometry to one O(10), one O(12), one O(20), one O(23), one O(4), and one O(6) atom. In the fifth Li site, Li(5) is bonded in a 6-coordinate geometry to one O(10), one O(11), one O(17), one O(23), one O(3), and one O(7) atom. In the sixth Li site, Li(6) is bonded in a 6-coordinate geometry to one O(12), one O(18), one O(24), one O(4), one O(8), and one O(9) atom. In the seventh Li site, Li(7) is bonded to one O(13), one O(2), one O(21), one O(23), one O(5), and one O(8) atom to form distorted LiO6 octahedra that share  a cornercorner with one W(1)O6 octahedra,  a cornercorner with one W(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra,  an edgeedge with one Sb(3)O6 octahedra, and  a faceface with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 57-61°. In the eighth Li site, Li(8) is bonded to one O(1), one O(14), one O(22), one O(24), one O(6), and one O(7) atom to form distorted LiO6 octahedra that share  a cornercorner with one W(1)O6 octahedra,  a cornercorner with one W(2)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra,  an edgeedge with one Sb(4)O6 octahedra, and  a faceface with one Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 57-61°. There are two inequivalent W sites. In the first W site, W(1) is bonded to one O(16), one O(19), one O(21), one O(4), one O(6), and one O(9) atom to form WO6 octahedra that share  a cornercorner with one Li(7)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  a cornercorner with one Sb(1)O6 octahedra,  a cornercorner with one Sb(2)O6 octahedra, corners with two equivalent Sb(3)O6 octahedra, and corners with two equivalent Sb(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 38-61°. In the second W site, W(2) is bonded to one O(10), one O(15), one O(20), one O(22), one O(3), and one O(5) atom to form WO6 octahedra that share  a cornercorner with one Li(7)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  a cornercorner with one Sb(1)O6 octahedra,  a cornercorner with one Sb(2)O6 octahedra, corners with two equivalent Sb(3)O6 octahedra, and corners with two equivalent Sb(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 38-61°. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(12), one O(13), one O(17), one O(2), one O(23), and one O(8) atom to form MnO6 octahedra that share  a cornercorner with one Li(7)O6 octahedra,  a cornercorner with one Sb(3)O6 octahedra,  a cornercorner with one Sb(4)O6 octahedra, corners with two equivalent Sb(1)O6 octahedra, corners with two equivalent Sb(2)O6 octahedra, and  a faceface with one Li(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 35-60°. In the second Mn site, Mn(2) is bonded to one O(1), one O(11), one O(14), one O(18), one O(24), and one O(7) atom to form MnO6 octahedra that share  a cornercorner with one Li(8)O6 octahedra,  a cornercorner with one Sb(3)O6 octahedra,  a cornercorner with one Sb(4)O6 octahedra, corners with two equivalent Sb(1)O6 octahedra, corners with two equivalent Sb(2)O6 octahedra, and  a faceface with one Li(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 35-61°. There are four inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(1), one O(17), one O(21), one O(23), one O(3), and one O(7) atom to form SbO6 octahedra that share  a cornercorner with one W(1)O6 octahedra,  a cornercorner with one W(2)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra, and  an edgeedge with one Li(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 35-39°. In the second Sb site, Sb(2) is bonded to one O(18), one O(2), one O(22), one O(24), one O(4), and one O(8) atom to form SbO6 octahedra that share  a cornercorner with one W(1)O6 octahedra,  a cornercorner with one W(2)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra, and  an edgeedge with one Li(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 35-39°. In the third Sb site, Sb(3) is bonded to one O(11), one O(13), one O(15), one O(19), one O(5), and one O(9) atom to form SbO6 octahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra, corners with two equivalent W(1)O6 octahedra, corners with two equivalent W(2)O6 octahedra, and  an edgeedge with one Li(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 38-42°. In the fourth Sb site, Sb(4) is bonded to one O(10), one O(12), one O(14), one O(16), one O(20), and one O(6) atom to form SbO6 octahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra, corners with two equivalent W(1)O6 octahedra, corners with two equivalent W(2)O6 octahedra, and  an edgeedge with one Li(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 38-42°. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a distorted see-saw-like geometry to one Li(1), one Li(8), one Mn(2), and one Sb(1) atom. In the second O site, O(2) is bonded in a distorted see-saw-like geometry to one Li(2), one Li(7), one Mn(1), and one Sb(2) atom. In the third O site, O(3) is bonded to one Li(3), one Li(5), one W(2), and one Sb(1) atom to form distorted OLi2SbW trigonal pyramids that share  a cornercorner with one O(9)Li2SbW trigonal pyramid, corners with two equivalent O(17)Li2MnSb trigonal pyramids,  an edgeedge with one O(11)Li2MnSb trigonal pyramid, and  an edgeedge with one O(10)Li2SbW trigonal pyramid. In the fourth O site, O(4) is bonded to one Li(4), one Li(6), one W(1), and one Sb(2) atom to form distorted OLi2SbW trigonal pyramids that share  a cornercorner with one O(10)Li2SbW trigonal pyramid, corners with two equivalent O(18)Li2MnSb trigonal pyramids,  an edgeedge with one O(12)Li2MnSb trigonal pyramid, and  an edgeedge with one O(9)Li2SbW trigonal pyramid. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to one Li(3), one Li(7), one W(2), and one Sb(3) atom. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to one Li(4), one Li(8), one W(1), and one Sb(4) atom. In the seventh O site, O(7) is bonded in a 5-coordinate geometry to one Li(1), one Li(5), one Li(8), one Mn(2), and one Sb(1) atom. In the eighth O site, O(8) is bonded in a 5-coordinate geometry to one Li(2), one Li(6), one Li(7), one Mn(1), and one Sb(2) atom. In the ninth O site, O(9) is bonded to one Li(3), one Li(6), one W(1), and one Sb(3) atom to form OLi2SbW trigonal pyramids that share  a cornercorner with one O(12)Li2MnSb trigonal pyramid,  a cornercorner with one O(18)Li2MnSb trigonal pyramid,  a cornercorner with one O(3)Li2SbW trigonal pyramid,  an edgeedge with one O(11)Li2MnSb trigonal pyramid, and  an edgeedge with one O(4)Li2SbW trigonal pyramid. In the tenth O site, O(10) is bonded to one Li(4), one Li(5), one W(2), and one Sb(4) atom to form OLi2SbW trigonal pyramids that share  a cornercorner with one O(11)Li2MnSb trigonal pyramid,  a cornercorner with one O(17)Li2MnSb trigonal pyramid,  a cornercorner with one O(4)Li2SbW trigonal pyramid,  an edgeedge with one O(12)Li2MnSb trigonal pyramid, and  an edgeedge with one O(3)Li2SbW trigonal pyramid. In the eleventh O site, O(11) is bonded to one Li(3), one Li(5), one Mn(2), and one Sb(3) atom to form OLi2MnSb trigonal pyramids that share  a cornercorner with one O(17)Li2MnSb trigonal pyramid,  a cornercorner with one O(18)Li2MnSb trigonal pyramid,  a cornercorner with one O(10)Li2SbW trigonal pyramid,  an edgeedge with one O(3)Li2SbW trigonal pyramid, and  an edgeedge with one O(9)Li2SbW trigonal pyramid. In the twelfth O site, O(12) is bonded to one Li(4), one Li(6), one Mn(1), and one Sb(4) atom to form OLi2MnSb trigonal pyramids that share  a cornercorner with one O(17)Li2MnSb trigonal pyramid,  a cornercorner with one O(18)Li2MnSb trigonal pyramid,  a cornercorner with one O(9)Li2SbW trigonal pyramid,  an edgeedge with one O(10)Li2SbW trigonal pyramid, and  an edgeedge with one O(4)Li2SbW trigonal pyramid. In the thirteenth O site, O(13) is bonded in a distorted see-saw-like geometry to one Li(1), one Li(7), one Mn(1), and one Sb(3) atom. In the fourteenth O site, O(14) is bonded in a distorted see-saw-like geometry to one Li(2), one Li(8), one Mn(2), and one Sb(4) atom. In the fifteenth O site, O(15) is bonded in a distorted trigonal planar geometry to one Li(2), one W(2), and one Sb(3) atom. In the sixteenth O site, O(16) is bonded in a distorted trigonal planar geometry to one Li(1), one W(1), and one Sb(4) atom. In the seventeenth O site, O(17) is bonded to one Li(1), one Li(5), one Mn(1), and one Sb(1) atom to form OLi2MnSb trigonal pyramids that share  a cornercorner with one O(11)Li2MnSb trigonal pyramid,  a cornercorner with one O(12)Li2MnSb trigonal pyramid,  a cornercorner with one O(10)Li2SbW trigonal pyramid, and corners with two equivalent O(3)Li2SbW trigonal pyramids. In the eighteenth O site, O(18) is bonded to one Li(2), one Li(6), one Mn(2), and one Sb(2) atom to form OLi2MnSb trigonal pyramids that share  a cornercorner with one O(11)Li2MnSb trigonal pyramid,  a cornercorner with one O(12)Li2MnSb trigonal pyramid,  a cornercorner with one O(9)Li2SbW trigonal pyramid, and corners with two equivalent O(4)Li2SbW trigonal pyramids. In the nineteenth O site, O(19) is bonded in a distorted trigonal planar geometry to one Li(3), one W(1), and one Sb(3) atom. In the twentieth O site, O(20) is bonded in a distorted trigonal planar geometry to one Li(4), one W(2), and one Sb(4) atom. In the twenty-first O site, O(21) is bonded in a 4-coordinate geometry to one Li(1), one Li(7), one W(1), and one Sb(1) atom. In the twenty-second O site, O(22) is bonded in a 4-coordinate geometry to one Li(2), one Li(8), one W(2), and one Sb(2) atom. In the twenty-third O site, O(23) is bonded in a 5-coordinate geometry to one Li(4), one Li(5), one Li(7), one Mn(1), and one Sb(1) atom. In the twenty-fourth O site, O(24) is bonded in a 5-coordinate geometry to one Li(3), one Li(6), one Li(8), one Mn(2), and one Sb(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li4MnSb2WO12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.129
_cell_length_b   5.439
_cell_length_c   7.482
_cell_angle_alpha   94.501
_cell_angle_beta   89.885
_cell_angle_gamma   90.051
_symmetry_Int_Tables_number   1
_cell_volume   208.067
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.998  0.560  0.698  1.0
  Li  Li1  1  0.500  0.088  0.228  1.0
  Li  Li2  1  0.001  0.437  0.291  1.0
  Li  Li3  1  0.499  0.100  0.692  1.0
  Mn  Mn4  1  0.501  0.508  0.500  1.0
  O  O5  1  0.309  0.802  0.571  1.0
  O  O6  1  0.126  0.005  0.241  1.0
  O  O7  1  0.311  0.181  0.940  1.0
  O  O8  1  0.200  0.306  0.564  1.0
  O  O9  1  0.813  0.306  0.066  1.0
  O  O10  1  0.376  0.482  0.251  1.0
  O  O11  1  0.627  0.485  0.750  1.0
  O  O12  1  0.172  0.688  0.936  1.0
  O  O13  1  0.817  0.676  0.447  1.0
  O  O14  1  0.686  0.827  0.069  1.0
  O  O15  1  0.872  0.993  0.754  1.0
  O  O16  1  0.689  0.192  0.442  1.0
  Sb  Sb17  1  0.003  0.996  0.495  1.0
  Sb  Sb18  1  0.500  0.511  0.000  1.0
  W  W19  1  0.999  0.000  0.995  1.0
[/CIF]
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