The material described by Pb2CoWO6 is Pb (Zr_0.50 Ti_0.48) O_3-derived structured and crystallizes in the monoclinic C2/m space group. W(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form WO6 octahedra that share corners with six equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 15-19°. Co(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form CoO6 octahedra that share corners with six equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 15-19°. Pb(1) is bonded in a 5-coordinate geometry to one O(1) and four equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one W(1), one Co(1), and one Pb(1) atom. In the second O site, O(2) is bonded in a distorted rectangular see-saw-like geometry to one W(1), one Co(1), and two equivalent Pb(1) atoms. is represented by the CIF file [CIF]
data_CoPb2WO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.710
_cell_length_b   5.722
_cell_length_c   5.722
_cell_angle_alpha   60.038
_cell_angle_beta   60.739
_cell_angle_gamma   90.741
_symmetry_Int_Tables_number   1
_cell_volume   132.873
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.500  0.500  0.000  1.0
  O  O1  1  0.181  0.239  0.058  1.0
  O  O2  1  0.819  0.761  0.942  1.0
  O  O3  1  0.271  0.274  0.522  1.0
  O  O4  1  0.729  0.208  0.997  1.0
  O  O5  1  0.729  0.726  0.479  1.0
  O  O6  1  0.271  0.792  0.003  1.0
  Pb  Pb7  1  0.260  0.750  0.490  1.0
  Pb  Pb8  1  0.740  0.250  0.510  1.0
  W  W9  1  0.000  0.000  1.000  1.0
[/CIF]
.
The material described by Pb2CoWO6 is Pb (Zr_0.50 Ti_0.48) O_3-derived structured and crystallizes in the monoclinic C2/m space group. W(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form WO6 octahedra that share corners with six equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 15-19°. Co(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form CoO6 octahedra that share corners with six equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 15-19°. Pb(1) is bonded in a 5-coordinate geometry to one O(1) and four equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one W(1), one Co(1), and one Pb(1) atom. In the second O site, O(2) is bonded in a distorted rectangular see-saw-like geometry to one W(1), one Co(1), and two equivalent Pb(1) atoms. is represented by the CIF file [CIF]
data_CoPb2WO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.710
_cell_length_b   5.722
_cell_length_c   5.722
_cell_angle_alpha   60.038
_cell_angle_beta   60.739
_cell_angle_gamma   90.741
_symmetry_Int_Tables_number   1
_cell_volume   132.873
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.500  0.500  0.000  1.0
  O  O1  1  0.181  0.239  0.058  1.0
  O  O2  1  0.819  0.761  0.942  1.0
  O  O3  1  0.271  0.274  0.522  1.0
  O  O4  1  0.729  0.208  0.997  1.0
  O  O5  1  0.729  0.726  0.479  1.0
  O  O6  1  0.271  0.792  0.003  1.0
  Pb  Pb7  1  0.260  0.750  0.490  1.0
  Pb  Pb8  1  0.740  0.250  0.510  1.0
  W  W9  1  0.000  0.000  1.000  1.0
[/CIF]
.