The crystal structure described by Mn(WB)2 crystallizes in the tetragonal P4/mbm space group. W(1) is bonded in a 10-coordinate geometry to four equivalent Mn(1) and six equivalent B(1) atoms. Mn(1) is bonded to eight equivalent W(1) and four equivalent B(1) atoms to form a mixture of corner and face-sharing MnB4W8 cuboctahedra. B(1) is bonded in a 9-coordinate geometry to six equivalent W(1), two equivalent Mn(1), and one B(1) atom. is represented by the CIF file [CIF]
data_Mn(BW)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.156
_cell_length_b   5.811
_cell_length_c   5.811
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   106.583
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.000  0.500  0.500  1.0
  Mn  Mn1  1  0.000  0.000  0.000  1.0
  B  B2  1  0.000  0.613  0.113  1.0
  B  B3  1  0.000  0.387  0.887  1.0
  B  B4  1  0.000  0.887  0.613  1.0
  B  B5  1  0.000  0.113  0.387  1.0
  W  W6  1  0.500  0.678  0.822  1.0
  W  W7  1  0.500  0.322  0.178  1.0
  W  W8  1  0.500  0.178  0.678  1.0
  W  W9  1  0.500  0.822  0.322  1.0
[/CIF]
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The crystal structure described by Mn(WB)2 crystallizes in the tetragonal P4/mbm space group. W(1) is bonded in a 10-coordinate geometry to four equivalent Mn(1) and six equivalent B(1) atoms. Mn(1) is bonded to eight equivalent W(1) and four equivalent B(1) atoms to form a mixture of corner and face-sharing MnB4W8 cuboctahedra. B(1) is bonded in a 9-coordinate geometry to six equivalent W(1), two equivalent Mn(1), and one B(1) atom. is represented by the CIF file [CIF]
data_Mn(BW)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.156
_cell_length_b   5.811
_cell_length_c   5.811
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   106.583
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.000  0.500  0.500  1.0
  Mn  Mn1  1  0.000  0.000  0.000  1.0
  B  B2  1  0.000  0.613  0.113  1.0
  B  B3  1  0.000  0.387  0.887  1.0
  B  B4  1  0.000  0.887  0.613  1.0
  B  B5  1  0.000  0.113  0.387  1.0
  W  W6  1  0.500  0.678  0.822  1.0
  W  W7  1  0.500  0.322  0.178  1.0
  W  W8  1  0.500  0.178  0.678  1.0
  W  W9  1  0.500  0.822  0.322  1.0
[/CIF]
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