The compound described by SmFe10TiV crystallizes in the orthorhombic Imm2 space group. Sm(1) is bonded in a 20-coordinate geometry to one Ti(1), one V(1), two equivalent Fe(1), two equivalent Fe(2), two equivalent Fe(5), four equivalent Fe(3), and eight equivalent Fe(4) atoms. Ti(1) is bonded in a 14-coordinate geometry to one Sm(1), one V(1), two equivalent Fe(2), two equivalent Fe(3), four equivalent Fe(4), and four equivalent Fe(5) atoms. V(1) is bonded in a 14-coordinate geometry to one Sm(1), one Ti(1), two equivalent Fe(1), two equivalent Fe(3), four equivalent Fe(4), and four equivalent Fe(5) atoms. There are five inequivalent Fe sites. In the first Fe site, Fe(1) is bonded in a 12-coordinate geometry to two equivalent Sm(1), two equivalent V(1), two equivalent Fe(3), two equivalent Fe(5), and four equivalent Fe(4) atoms. In the second Fe site, Fe(2) is bonded in a 12-coordinate geometry to two equivalent Sm(1), two equivalent Ti(1), two equivalent Fe(3), two equivalent Fe(5), and four equivalent Fe(4) atoms. In the third Fe site, Fe(3) is bonded in a 12-coordinate geometry to two equivalent Sm(1), one Ti(1), one V(1), one Fe(1), one Fe(2), two equivalent Fe(5), and four equivalent Fe(4) atoms. In the fourth Fe site, Fe(4) is bonded to two equivalent Sm(1), one Ti(1), one V(1), one Fe(1), one Fe(2), two equivalent Fe(3), two equivalent Fe(4), and two equivalent Fe(5) atoms to form a mixture of distorted corner, edge, and face-sharing FeSm2TiVFe8 cuboctahedra. In the fifth Fe site, Fe(5) is bonded in a 14-coordinate geometry to one Sm(1), two equivalent Ti(1), two equivalent V(1), one Fe(1), one Fe(2), one Fe(5), two equivalent Fe(3), and four equivalent Fe(4) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_SmTiVFe10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.702
_cell_length_b   6.503
_cell_length_c   6.503
_cell_angle_alpha   97.881
_cell_angle_beta   111.193
_cell_angle_gamma   68.807
_symmetry_Int_Tables_number   1
_cell_volume   172.842
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sm  Sm0  1  0.001  0.999  0.001  1.0
  Ti  Ti1  1  0.641  0.359  0.641  1.0
  V  V2  1  0.351  0.649  0.351  1.0
  Fe  Fe3  1  0.731  0.769  0.231  1.0
  Fe  Fe4  1  0.274  0.226  0.774  1.0
  Fe  Fe5  1  0.499  0.774  0.773  1.0
  Fe  Fe6  1  0.499  0.227  0.226  1.0
  Fe  Fe7  1  0.500  0.998  0.499  1.0
  Fe  Fe8  1  0.001  0.998  0.499  1.0
  Fe  Fe9  1  0.500  0.501  0.002  1.0
  Fe  Fe10  1  0.001  0.501  0.002  1.0
  Fe  Fe11  1  0.001  0.358  0.360  1.0
  Fe  Fe12  1  0.001  0.640  0.642  1.0
[/CIF]
.
The compound described by SmFe10TiV crystallizes in the orthorhombic Imm2 space group. Sm(1) is bonded in a 20-coordinate geometry to one Ti(1), one V(1), two equivalent Fe(1), two equivalent Fe(2), two equivalent Fe(5), four equivalent Fe(3), and eight equivalent Fe(4) atoms. Ti(1) is bonded in a 14-coordinate geometry to one Sm(1), one V(1), two equivalent Fe(2), two equivalent Fe(3), four equivalent Fe(4), and four equivalent Fe(5) atoms. V(1) is bonded in a 14-coordinate geometry to one Sm(1), one Ti(1), two equivalent Fe(1), two equivalent Fe(3), four equivalent Fe(4), and four equivalent Fe(5) atoms. There are five inequivalent Fe sites. In the first Fe site, Fe(1) is bonded in a 12-coordinate geometry to two equivalent Sm(1), two equivalent V(1), two equivalent Fe(3), two equivalent Fe(5), and four equivalent Fe(4) atoms. In the second Fe site, Fe(2) is bonded in a 12-coordinate geometry to two equivalent Sm(1), two equivalent Ti(1), two equivalent Fe(3), two equivalent Fe(5), and four equivalent Fe(4) atoms. In the third Fe site, Fe(3) is bonded in a 12-coordinate geometry to two equivalent Sm(1), one Ti(1), one V(1), one Fe(1), one Fe(2), two equivalent Fe(5), and four equivalent Fe(4) atoms. In the fourth Fe site, Fe(4) is bonded to two equivalent Sm(1), one Ti(1), one V(1), one Fe(1), one Fe(2), two equivalent Fe(3), two equivalent Fe(4), and two equivalent Fe(5) atoms to form a mixture of distorted corner, edge, and face-sharing FeSm2TiVFe8 cuboctahedra. In the fifth Fe site, Fe(5) is bonded in a 14-coordinate geometry to one Sm(1), two equivalent Ti(1), two equivalent V(1), one Fe(1), one Fe(2), one Fe(5), two equivalent Fe(3), and four equivalent Fe(4) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_SmTiVFe10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.702
_cell_length_b   6.503
_cell_length_c   6.503
_cell_angle_alpha   97.881
_cell_angle_beta   111.193
_cell_angle_gamma   68.807
_symmetry_Int_Tables_number   1
_cell_volume   172.842
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sm  Sm0  1  0.001  0.999  0.001  1.0
  Ti  Ti1  1  0.641  0.359  0.641  1.0
  V  V2  1  0.351  0.649  0.351  1.0
  Fe  Fe3  1  0.731  0.769  0.231  1.0
  Fe  Fe4  1  0.274  0.226  0.774  1.0
  Fe  Fe5  1  0.499  0.774  0.773  1.0
  Fe  Fe6  1  0.499  0.227  0.226  1.0
  Fe  Fe7  1  0.500  0.998  0.499  1.0
  Fe  Fe8  1  0.001  0.998  0.499  1.0
  Fe  Fe9  1  0.500  0.501  0.002  1.0
  Fe  Fe10  1  0.001  0.501  0.002  1.0
  Fe  Fe11  1  0.001  0.358  0.360  1.0
  Fe  Fe12  1  0.001  0.640  0.642  1.0
[/CIF]
.