The compound described by Hf5CoP3 crystallizes in the orthorhombic Pnma space group. There are five inequivalent Hf sites. In the first Hf site, Hf(1) is bonded in a 6-coordinate geometry to one Co(1), two equivalent P(1), and three equivalent P(2) atoms. In the second Hf site, Hf(2) is bonded in a 7-coordinate geometry to three equivalent Co(1), one P(3), and three equivalent P(1) atoms. In the third Hf site, Hf(3) is bonded in a 4-coordinate geometry to one Co(1), one P(2), and three equivalent P(3) atoms. In the fourth Hf site, Hf(4) is bonded to one P(1), two equivalent P(2), and two equivalent P(3) atoms to form distorted edge-sharing HfP5 trigonal bipyramids. In the fifth Hf site, Hf(5) is bonded in a 6-coordinate geometry to two equivalent Co(1), one P(1), one P(2), and two equivalent P(3) atoms. Co(1) is bonded in a 9-coordinate geometry to one Hf(1), one Hf(3), two equivalent Hf(5), three equivalent Hf(2), and two equivalent P(1) atoms. There are three inequivalent P sites. In the first P site, P(3) is bonded in a 8-coordinate geometry to one Hf(2), two equivalent Hf(4), two equivalent Hf(5), and three equivalent Hf(3) atoms. In the second P site, P(1) is bonded in a 9-coordinate geometry to one Hf(4), one Hf(5), two equivalent Hf(1), three equivalent Hf(2), and two equivalent Co(1) atoms. In the third P site, P(2) is bonded to one Hf(3), one Hf(5), two equivalent Hf(4), and three equivalent Hf(1) atoms to form distorted edge-sharing PHf7 pentagonal bipyramids. is represented by the CIF card [CIF]
data_Hf5CoP3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.572
_cell_length_b   10.165
_cell_length_c   16.933
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   614.752
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Hf  Hf0  1  0.250  0.122  0.477  1.0
  Hf  Hf1  1  0.750  0.878  0.523  1.0
  Hf  Hf2  1  0.750  0.622  0.023  1.0
  Hf  Hf3  1  0.250  0.378  0.977  1.0
  Hf  Hf4  1  0.250  0.060  0.075  1.0
  Hf  Hf5  1  0.750  0.940  0.925  1.0
  Hf  Hf6  1  0.750  0.560  0.425  1.0
  Hf  Hf7  1  0.250  0.440  0.575  1.0
  Hf  Hf8  1  0.250  0.488  0.273  1.0
  Hf  Hf9  1  0.750  0.512  0.727  1.0
  Hf  Hf10  1  0.750  0.988  0.227  1.0
  Hf  Hf11  1  0.250  0.012  0.773  1.0
  Hf  Hf12  1  0.250  0.816  0.369  1.0
  Hf  Hf13  1  0.750  0.184  0.631  1.0
  Hf  Hf14  1  0.750  0.316  0.131  1.0
  Hf  Hf15  1  0.250  0.684  0.869  1.0
  Hf  Hf16  1  0.250  0.754  0.169  1.0
  Hf  Hf17  1  0.750  0.246  0.831  1.0
  Hf  Hf18  1  0.750  0.254  0.331  1.0
  Hf  Hf19  1  0.250  0.746  0.669  1.0
  Co  Co20  1  0.250  0.365  0.411  1.0
  Co  Co21  1  0.750  0.635  0.589  1.0
  Co  Co22  1  0.750  0.865  0.089  1.0
  Co  Co23  1  0.250  0.135  0.911  1.0
  P  P24  1  0.250  0.812  0.010  1.0
  P  P25  1  0.750  0.188  0.990  1.0
  P  P26  1  0.750  0.312  0.490  1.0
  P  P27  1  0.250  0.688  0.510  1.0
  P  P28  1  0.250  0.507  0.117  1.0
  P  P29  1  0.750  0.493  0.883  1.0
  P  P30  1  0.750  0.007  0.383  1.0
  P  P31  1  0.250  0.993  0.617  1.0
  P  P32  1  0.250  0.185  0.217  1.0
  P  P33  1  0.750  0.815  0.783  1.0
  P  P34  1  0.750  0.685  0.283  1.0
  P  P35  1  0.250  0.315  0.717  1.0
[/CIF]
.
The compound described by Hf5CoP3 crystallizes in the orthorhombic Pnma space group. There are five inequivalent Hf sites. In the first Hf site, Hf(1) is bonded in a 6-coordinate geometry to one Co(1), two equivalent P(1), and three equivalent P(2) atoms. In the second Hf site, Hf(2) is bonded in a 7-coordinate geometry to three equivalent Co(1), one P(3), and three equivalent P(1) atoms. In the third Hf site, Hf(3) is bonded in a 4-coordinate geometry to one Co(1), one P(2), and three equivalent P(3) atoms. In the fourth Hf site, Hf(4) is bonded to one P(1), two equivalent P(2), and two equivalent P(3) atoms to form distorted edge-sharing HfP5 trigonal bipyramids. In the fifth Hf site, Hf(5) is bonded in a 6-coordinate geometry to two equivalent Co(1), one P(1), one P(2), and two equivalent P(3) atoms. Co(1) is bonded in a 9-coordinate geometry to one Hf(1), one Hf(3), two equivalent Hf(5), three equivalent Hf(2), and two equivalent P(1) atoms. There are three inequivalent P sites. In the first P site, P(3) is bonded in a 8-coordinate geometry to one Hf(2), two equivalent Hf(4), two equivalent Hf(5), and three equivalent Hf(3) atoms. In the second P site, P(1) is bonded in a 9-coordinate geometry to one Hf(4), one Hf(5), two equivalent Hf(1), three equivalent Hf(2), and two equivalent Co(1) atoms. In the third P site, P(2) is bonded to one Hf(3), one Hf(5), two equivalent Hf(4), and three equivalent Hf(1) atoms to form distorted edge-sharing PHf7 pentagonal bipyramids. is represented by the CIF card [CIF]
data_Hf5CoP3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.572
_cell_length_b   10.165
_cell_length_c   16.933
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   614.752
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Hf  Hf0  1  0.250  0.122  0.477  1.0
  Hf  Hf1  1  0.750  0.878  0.523  1.0
  Hf  Hf2  1  0.750  0.622  0.023  1.0
  Hf  Hf3  1  0.250  0.378  0.977  1.0
  Hf  Hf4  1  0.250  0.060  0.075  1.0
  Hf  Hf5  1  0.750  0.940  0.925  1.0
  Hf  Hf6  1  0.750  0.560  0.425  1.0
  Hf  Hf7  1  0.250  0.440  0.575  1.0
  Hf  Hf8  1  0.250  0.488  0.273  1.0
  Hf  Hf9  1  0.750  0.512  0.727  1.0
  Hf  Hf10  1  0.750  0.988  0.227  1.0
  Hf  Hf11  1  0.250  0.012  0.773  1.0
  Hf  Hf12  1  0.250  0.816  0.369  1.0
  Hf  Hf13  1  0.750  0.184  0.631  1.0
  Hf  Hf14  1  0.750  0.316  0.131  1.0
  Hf  Hf15  1  0.250  0.684  0.869  1.0
  Hf  Hf16  1  0.250  0.754  0.169  1.0
  Hf  Hf17  1  0.750  0.246  0.831  1.0
  Hf  Hf18  1  0.750  0.254  0.331  1.0
  Hf  Hf19  1  0.250  0.746  0.669  1.0
  Co  Co20  1  0.250  0.365  0.411  1.0
  Co  Co21  1  0.750  0.635  0.589  1.0
  Co  Co22  1  0.750  0.865  0.089  1.0
  Co  Co23  1  0.250  0.135  0.911  1.0
  P  P24  1  0.250  0.812  0.010  1.0
  P  P25  1  0.750  0.188  0.990  1.0
  P  P26  1  0.750  0.312  0.490  1.0
  P  P27  1  0.250  0.688  0.510  1.0
  P  P28  1  0.250  0.507  0.117  1.0
  P  P29  1  0.750  0.493  0.883  1.0
  P  P30  1  0.750  0.007  0.383  1.0
  P  P31  1  0.250  0.993  0.617  1.0
  P  P32  1  0.250  0.185  0.217  1.0
  P  P33  1  0.750  0.815  0.783  1.0
  P  P34  1  0.750  0.685  0.283  1.0
  P  P35  1  0.250  0.315  0.717  1.0
[/CIF]
.