The material described by CdC4H20S4(NO6)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one CdC4H20S4(NO6)2 cluster. Cd(1) is bonded to two equivalent O(2), two equivalent O(3), and two equivalent O(6) atoms to form CdO6 octahedra that share corners with two equivalent S(1)CNO2 tetrahedra. There are two inequivalent C sites. In the first C site, C(1) is bonded in a trigonal non-coplanar geometry to one H(1), one H(3), one H(4), and one S(1) atom. In the second C site, C(2) is bonded in a trigonal non-coplanar geometry to one H(2), one H(5), one H(6), and one S(2) atom. N(1) is bonded in a distorted bent 120 degrees geometry to one S(1) and one S(2) atom. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(1) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(2) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(2) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one O(6) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one O(3) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one O(3) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one O(6) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded to one C(1), one N(1), one O(1), and one O(2) atom to form distorted SCNO2 tetrahedra that share  a cornercorner with one Cd(1)O6 octahedra and  a cornercorner with one S(2)CNO2 tetrahedra. The corner-sharing octahedral tilt angles are 40°. In the second S site, S(2) is bonded to one C(2), one N(1), one O(4), and one O(5) atom to form distorted corner-sharing SCNO2 tetrahedra. There are six inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Cd(1) and one S(1) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one Cd(1), one H(8), and one H(9) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one S(2) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one S(2) atom. In the sixth O site, O(6) is bonded in a distorted water-like geometry to one Cd(1), one H(10), and one H(7) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CdH20C4S4(NO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.694
_cell_length_b   8.163
_cell_length_c   8.564
_cell_angle_alpha   70.610
_cell_angle_beta   75.213
_cell_angle_gamma   64.081
_symmetry_Int_Tables_number   1
_cell_volume   452.489
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.500  0.000  0.500  1.0
  H  H1  1  0.816  0.163  0.948  1.0
  H  H2  1  0.995  0.479  0.812  1.0
  H  H3  1  0.005  0.521  0.188  1.0
  H  H4  1  0.184  0.837  0.052  1.0
  H  H5  1  0.855  0.943  0.910  1.0
  H  H6  1  0.145  0.057  0.090  1.0
  H  H7  1  0.629  0.069  0.022  1.0
  H  H8  1  0.196  0.288  0.738  1.0
  H  H9  1  0.804  0.712  0.262  1.0
  H  H10  1  0.143  0.528  0.615  1.0
  H  H11  1  0.857  0.472  0.385  1.0
  H  H12  1  0.209  0.877  0.717  1.0
  H  H13  1  0.598  0.602  0.678  1.0
  H  H14  1  0.337  0.302  0.227  1.0
  H  H15  1  0.663  0.698  0.773  1.0
  H  H16  1  0.371  0.931  0.978  1.0
  H  H17  1  0.079  0.082  0.620  1.0
  H  H18  1  0.791  0.123  0.283  1.0
  H  H19  1  0.921  0.918  0.380  1.0
  H  H20  1  0.402  0.398  0.322  1.0
  C  C21  1  0.749  0.082  0.923  1.0
  C  C22  1  0.141  0.435  0.741  1.0
  C  C23  1  0.859  0.565  0.259  1.0
  C  C24  1  0.251  0.918  0.077  1.0
  S  S25  1  0.653  0.205  0.731  1.0
  S  S26  1  0.347  0.795  0.269  1.0
  S  S27  1  0.294  0.460  0.849  1.0
  S  S28  1  0.706  0.540  0.151  1.0
  N  N29  1  0.508  0.415  0.741  1.0
  N  N30  1  0.492  0.585  0.259  1.0
  O  O31  1  0.186  0.779  0.399  1.0
  O  O32  1  0.551  0.098  0.710  1.0
  O  O33  1  0.349  0.299  0.340  1.0
  O  O34  1  0.296  0.329  0.015  1.0
  O  O35  1  0.704  0.671  0.985  1.0
  O  O36  1  0.219  0.658  0.849  1.0
  O  O37  1  0.781  0.342  0.151  1.0
  O  O38  1  0.651  0.701  0.660  1.0
  O  O39  1  0.814  0.221  0.601  1.0
  O  O40  1  0.793  0.994  0.339  1.0
  O  O41  1  0.207  0.006  0.661  1.0
  O  O42  1  0.449  0.902  0.290  1.0
[/CIF]
.
The material described by CdC4H20S4(NO6)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one CdC4H20S4(NO6)2 cluster. Cd(1) is bonded to two equivalent O(2), two equivalent O(3), and two equivalent O(6) atoms to form CdO6 octahedra that share corners with two equivalent S(1)CNO2 tetrahedra. There are two inequivalent C sites. In the first C site, C(1) is bonded in a trigonal non-coplanar geometry to one H(1), one H(3), one H(4), and one S(1) atom. In the second C site, C(2) is bonded in a trigonal non-coplanar geometry to one H(2), one H(5), one H(6), and one S(2) atom. N(1) is bonded in a distorted bent 120 degrees geometry to one S(1) and one S(2) atom. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(1) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(2) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(2) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one O(6) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one O(3) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one O(3) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one O(6) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded to one C(1), one N(1), one O(1), and one O(2) atom to form distorted SCNO2 tetrahedra that share  a cornercorner with one Cd(1)O6 octahedra and  a cornercorner with one S(2)CNO2 tetrahedra. The corner-sharing octahedral tilt angles are 40°. In the second S site, S(2) is bonded to one C(2), one N(1), one O(4), and one O(5) atom to form distorted corner-sharing SCNO2 tetrahedra. There are six inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Cd(1) and one S(1) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one Cd(1), one H(8), and one H(9) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one S(2) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one S(2) atom. In the sixth O site, O(6) is bonded in a distorted water-like geometry to one Cd(1), one H(10), and one H(7) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CdH20C4S4(NO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.694
_cell_length_b   8.163
_cell_length_c   8.564
_cell_angle_alpha   70.610
_cell_angle_beta   75.213
_cell_angle_gamma   64.081
_symmetry_Int_Tables_number   1
_cell_volume   452.489
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.500  0.000  0.500  1.0
  H  H1  1  0.816  0.163  0.948  1.0
  H  H2  1  0.995  0.479  0.812  1.0
  H  H3  1  0.005  0.521  0.188  1.0
  H  H4  1  0.184  0.837  0.052  1.0
  H  H5  1  0.855  0.943  0.910  1.0
  H  H6  1  0.145  0.057  0.090  1.0
  H  H7  1  0.629  0.069  0.022  1.0
  H  H8  1  0.196  0.288  0.738  1.0
  H  H9  1  0.804  0.712  0.262  1.0
  H  H10  1  0.143  0.528  0.615  1.0
  H  H11  1  0.857  0.472  0.385  1.0
  H  H12  1  0.209  0.877  0.717  1.0
  H  H13  1  0.598  0.602  0.678  1.0
  H  H14  1  0.337  0.302  0.227  1.0
  H  H15  1  0.663  0.698  0.773  1.0
  H  H16  1  0.371  0.931  0.978  1.0
  H  H17  1  0.079  0.082  0.620  1.0
  H  H18  1  0.791  0.123  0.283  1.0
  H  H19  1  0.921  0.918  0.380  1.0
  H  H20  1  0.402  0.398  0.322  1.0
  C  C21  1  0.749  0.082  0.923  1.0
  C  C22  1  0.141  0.435  0.741  1.0
  C  C23  1  0.859  0.565  0.259  1.0
  C  C24  1  0.251  0.918  0.077  1.0
  S  S25  1  0.653  0.205  0.731  1.0
  S  S26  1  0.347  0.795  0.269  1.0
  S  S27  1  0.294  0.460  0.849  1.0
  S  S28  1  0.706  0.540  0.151  1.0
  N  N29  1  0.508  0.415  0.741  1.0
  N  N30  1  0.492  0.585  0.259  1.0
  O  O31  1  0.186  0.779  0.399  1.0
  O  O32  1  0.551  0.098  0.710  1.0
  O  O33  1  0.349  0.299  0.340  1.0
  O  O34  1  0.296  0.329  0.015  1.0
  O  O35  1  0.704  0.671  0.985  1.0
  O  O36  1  0.219  0.658  0.849  1.0
  O  O37  1  0.781  0.342  0.151  1.0
  O  O38  1  0.651  0.701  0.660  1.0
  O  O39  1  0.814  0.221  0.601  1.0
  O  O40  1  0.793  0.994  0.339  1.0
  O  O41  1  0.207  0.006  0.661  1.0
  O  O42  1  0.449  0.902  0.290  1.0
[/CIF]
.