The material structure described by SbSI2 crystallizes in the orthorhombic Pmc2_1 space group. Sb(1) is bonded in a 5-coordinate geometry to two equivalent S(1), one I(2), and two equivalent I(1) atoms. S(1) is bonded in a water-like geometry to two equivalent Sb(1) atoms. There are two inequivalent I sites. In the first I site, I(1) is bonded in a rectangular see-saw-like geometry to two equivalent Sb(1) and two equivalent I(1) atoms. In the second I site, I(2) is bonded in a distorted single-bond geometry to one Sb(1) and two equivalent I(2) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_SbSI2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.400
_cell_length_b   6.254
_cell_length_c   9.172
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   367.097
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.750  0.390  0.605  1.0
  Sb  Sb1  1  0.750  0.890  0.895  1.0
  S  S2  1  0.750  0.776  0.629  1.0
  S  S3  1  0.750  0.276  0.871  1.0
  I  I4  1  0.250  0.858  0.767  1.0
  I  I5  1  0.250  0.358  0.733  1.0
  I  I6  1  0.750  0.511  0.252  1.0
  I  I7  1  0.750  0.011  0.248  1.0
[/CIF]
.
The material structure described by SbSI2 crystallizes in the orthorhombic Pmc2_1 space group. Sb(1) is bonded in a 5-coordinate geometry to two equivalent S(1), one I(2), and two equivalent I(1) atoms. S(1) is bonded in a water-like geometry to two equivalent Sb(1) atoms. There are two inequivalent I sites. In the first I site, I(1) is bonded in a rectangular see-saw-like geometry to two equivalent Sb(1) and two equivalent I(1) atoms. In the second I site, I(2) is bonded in a distorted single-bond geometry to one Sb(1) and two equivalent I(2) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_SbSI2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.400
_cell_length_b   6.254
_cell_length_c   9.172
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   367.097
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.750  0.390  0.605  1.0
  Sb  Sb1  1  0.750  0.890  0.895  1.0
  S  S2  1  0.750  0.776  0.629  1.0
  S  S3  1  0.750  0.276  0.871  1.0
  I  I4  1  0.250  0.858  0.767  1.0
  I  I5  1  0.250  0.358  0.733  1.0
  I  I6  1  0.750  0.511  0.252  1.0
  I  I7  1  0.750  0.011  0.248  1.0
[/CIF]
.