The compound described by LiV(PO3)4 crystallizes in the monoclinic P2_1 space group. Li(1) is bonded in a distorted trigonal non-coplanar geometry to one O(12), one O(6), and one O(9) atom. V(1) is bonded in a 6-coordinate geometry to one O(11), one O(12), one O(2), one O(3), one O(4), and one O(9) atom. There are four inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(3), one O(5), and one O(6) atom to form corner-sharing PO4 tetrahedra. In the second P site, P(2) is bonded to one O(1), one O(2), one O(4), and one O(7) atom to form corner-sharing PO4 tetrahedra. In the third P site, P(3) is bonded to one O(10), one O(12), one O(5), and one O(9) atom to form corner-sharing PO4 tetrahedra. In the fourth P site, P(4) is bonded to one O(10), one O(11), one O(7), and one O(8) atom to form corner-sharing PO4 tetrahedra. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one P(1) and one P(2) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one V(1) and one P(2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one V(1) and one P(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one V(1) and one P(2) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one P(1) and one P(3) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Li(1) and one P(1) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one P(2) and one P(4) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one P(4) atom. In the ninth O site, O(9) is bonded in a distorted trigonal planar geometry to one Li(1), one V(1), and one P(3) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one P(3) and one P(4) atom. In the eleventh O site, O(11) is bonded in a distorted linear geometry to one V(1) and one P(4) atom. In the twelfth O site, O(12) is bonded in a 2-coordinate geometry to one Li(1), one V(1), and one P(3) atom. is represented by the CIF card [CIF]
data_LiV(PO3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.754
_cell_length_b   7.018
_cell_length_c   7.404
_cell_angle_alpha   85.735
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   453.664
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.365  0.653  0.668  1.0
  Li  Li1  1  0.865  0.347  0.332  1.0
  V  V2  1  0.928  0.772  0.228  1.0
  V  V3  1  0.428  0.228  0.772  1.0
  P  P4  1  0.372  0.015  0.415  1.0
  P  P5  1  0.575  0.918  0.093  1.0
  P  P6  1  0.734  0.609  0.594  1.0
  P  P7  1  0.376  0.571  0.075  1.0
  P  P8  1  0.876  0.429  0.925  1.0
  P  P9  1  0.234  0.391  0.406  1.0
  P  P10  1  0.075  0.082  0.907  1.0
  P  P11  1  0.872  0.985  0.585  1.0
  O  O12  1  0.962  0.980  0.774  1.0
  O  O13  1  0.546  0.015  0.908  1.0
  O  O14  1  0.977  0.893  0.452  1.0
  O  O15  1  0.735  0.922  0.166  1.0
  O  O16  1  0.737  0.833  0.635  1.0
  O  O17  1  0.311  0.823  0.467  1.0
  O  O18  1  0.532  0.695  0.093  1.0
  O  O19  1  0.246  0.692  0.015  1.0
  O  O20  1  0.784  0.594  0.399  1.0
  O  O21  1  0.871  0.522  0.719  1.0
  O  O22  1  0.915  0.593  0.039  1.0
  O  O23  1  0.581  0.532  0.651  1.0
  O  O24  1  0.081  0.468  0.349  1.0
  O  O25  1  0.415  0.407  0.961  1.0
  O  O26  1  0.371  0.478  0.281  1.0
  O  O27  1  0.284  0.406  0.601  1.0
  O  O28  1  0.746  0.308  0.985  1.0
  O  O29  1  0.032  0.305  0.907  1.0
  O  O30  1  0.811  0.177  0.533  1.0
  O  O31  1  0.237  0.167  0.365  1.0
  O  O32  1  0.235  0.078  0.834  1.0
  O  O33  1  0.477  0.107  0.548  1.0
  O  O34  1  0.046  0.985  0.092  1.0
  O  O35  1  0.462  0.020  0.226  1.0
[/CIF]
.
The compound described by LiV(PO3)4 crystallizes in the monoclinic P2_1 space group. Li(1) is bonded in a distorted trigonal non-coplanar geometry to one O(12), one O(6), and one O(9) atom. V(1) is bonded in a 6-coordinate geometry to one O(11), one O(12), one O(2), one O(3), one O(4), and one O(9) atom. There are four inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(3), one O(5), and one O(6) atom to form corner-sharing PO4 tetrahedra. In the second P site, P(2) is bonded to one O(1), one O(2), one O(4), and one O(7) atom to form corner-sharing PO4 tetrahedra. In the third P site, P(3) is bonded to one O(10), one O(12), one O(5), and one O(9) atom to form corner-sharing PO4 tetrahedra. In the fourth P site, P(4) is bonded to one O(10), one O(11), one O(7), and one O(8) atom to form corner-sharing PO4 tetrahedra. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one P(1) and one P(2) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one V(1) and one P(2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one V(1) and one P(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one V(1) and one P(2) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one P(1) and one P(3) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Li(1) and one P(1) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one P(2) and one P(4) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one P(4) atom. In the ninth O site, O(9) is bonded in a distorted trigonal planar geometry to one Li(1), one V(1), and one P(3) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one P(3) and one P(4) atom. In the eleventh O site, O(11) is bonded in a distorted linear geometry to one V(1) and one P(4) atom. In the twelfth O site, O(12) is bonded in a 2-coordinate geometry to one Li(1), one V(1), and one P(3) atom. is represented by the CIF card [CIF]
data_LiV(PO3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.754
_cell_length_b   7.018
_cell_length_c   7.404
_cell_angle_alpha   85.735
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   453.664
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.365  0.653  0.668  1.0
  Li  Li1  1  0.865  0.347  0.332  1.0
  V  V2  1  0.928  0.772  0.228  1.0
  V  V3  1  0.428  0.228  0.772  1.0
  P  P4  1  0.372  0.015  0.415  1.0
  P  P5  1  0.575  0.918  0.093  1.0
  P  P6  1  0.734  0.609  0.594  1.0
  P  P7  1  0.376  0.571  0.075  1.0
  P  P8  1  0.876  0.429  0.925  1.0
  P  P9  1  0.234  0.391  0.406  1.0
  P  P10  1  0.075  0.082  0.907  1.0
  P  P11  1  0.872  0.985  0.585  1.0
  O  O12  1  0.962  0.980  0.774  1.0
  O  O13  1  0.546  0.015  0.908  1.0
  O  O14  1  0.977  0.893  0.452  1.0
  O  O15  1  0.735  0.922  0.166  1.0
  O  O16  1  0.737  0.833  0.635  1.0
  O  O17  1  0.311  0.823  0.467  1.0
  O  O18  1  0.532  0.695  0.093  1.0
  O  O19  1  0.246  0.692  0.015  1.0
  O  O20  1  0.784  0.594  0.399  1.0
  O  O21  1  0.871  0.522  0.719  1.0
  O  O22  1  0.915  0.593  0.039  1.0
  O  O23  1  0.581  0.532  0.651  1.0
  O  O24  1  0.081  0.468  0.349  1.0
  O  O25  1  0.415  0.407  0.961  1.0
  O  O26  1  0.371  0.478  0.281  1.0
  O  O27  1  0.284  0.406  0.601  1.0
  O  O28  1  0.746  0.308  0.985  1.0
  O  O29  1  0.032  0.305  0.907  1.0
  O  O30  1  0.811  0.177  0.533  1.0
  O  O31  1  0.237  0.167  0.365  1.0
  O  O32  1  0.235  0.078  0.834  1.0
  O  O33  1  0.477  0.107  0.548  1.0
  O  O34  1  0.046  0.985  0.092  1.0
  O  O35  1  0.462  0.020  0.226  1.0
[/CIF]
.