The material structure described by LiAgF3 crystallizes in the triclinic P-1 space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded in a 4-coordinate geometry to one F(1), one F(2), one F(3), and one F(6) atom. In the second Li site, Li(2) is bonded in a 4-coordinate geometry to one F(3), one F(4), one F(5), and one F(6) atom. There are four inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a square co-planar geometry to two equivalent F(1) and two equivalent F(4) atoms. In the second Ag site, Ag(2) is bonded in an octahedral geometry to two equivalent F(2), two equivalent F(3), and two equivalent F(5) atoms. In the third Ag site, Ag(3) is bonded in an octahedral geometry to two equivalent F(1), two equivalent F(4), and two equivalent F(6) atoms. In the fourth Ag site, Ag(4) is bonded in a square co-planar geometry to two equivalent F(2) and two equivalent F(5) atoms. There are six inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one Li(1), one Ag(1), and one Ag(3) atom. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one Li(1), one Ag(2), and one Ag(4) atom. In the third F site, F(3) is bonded in a 3-coordinate geometry to one Li(1), one Li(2), and one Ag(2) atom. In the fourth F site, F(4) is bonded in a distorted trigonal planar geometry to one Li(2), one Ag(1), and one Ag(3) atom. In the fifth F site, F(5) is bonded in a 3-coordinate geometry to one Li(2), one Ag(2), and one Ag(4) atom. In the sixth F site, F(6) is bonded in a 3-coordinate geometry to one Li(1), one Li(2), and one Ag(3) atom. is represented by the CIF card [CIF]
data_LiAgF3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.494
_cell_length_b   5.640
_cell_length_c   8.381
_cell_angle_alpha   90.098
_cell_angle_beta   92.566
_cell_angle_gamma   89.780
_symmetry_Int_Tables_number   1
_cell_volume   259.465
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.028  0.018  0.270  1.0
  Li  Li1  1  0.473  0.517  0.229  1.0
  Li  Li2  1  0.527  0.483  0.771  1.0
  Li  Li3  1  0.972  0.982  0.730  1.0
  Ag  Ag4  1  0.000  0.500  0.500  1.0
  Ag  Ag5  1  0.000  0.500  0.000  1.0
  Ag  Ag6  1  0.500  0.000  0.500  1.0
  Ag  Ag7  1  0.500  0.000  0.000  1.0
  F  F8  1  0.153  0.162  0.552  1.0
  F  F9  1  0.181  0.137  0.890  1.0
  F  F10  1  0.166  0.339  0.216  1.0
  F  F11  1  0.316  0.638  0.611  1.0
  F  F12  1  0.345  0.663  0.949  1.0
  F  F13  1  0.337  0.839  0.284  1.0
  F  F14  1  0.663  0.161  0.716  1.0
  F  F15  1  0.655  0.337  0.051  1.0
  F  F16  1  0.684  0.362  0.389  1.0
  F  F17  1  0.834  0.661  0.784  1.0
  F  F18  1  0.819  0.863  0.110  1.0
  F  F19  1  0.847  0.838  0.448  1.0
[/CIF]
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The material structure described by LiAgF3 crystallizes in the triclinic P-1 space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded in a 4-coordinate geometry to one F(1), one F(2), one F(3), and one F(6) atom. In the second Li site, Li(2) is bonded in a 4-coordinate geometry to one F(3), one F(4), one F(5), and one F(6) atom. There are four inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a square co-planar geometry to two equivalent F(1) and two equivalent F(4) atoms. In the second Ag site, Ag(2) is bonded in an octahedral geometry to two equivalent F(2), two equivalent F(3), and two equivalent F(5) atoms. In the third Ag site, Ag(3) is bonded in an octahedral geometry to two equivalent F(1), two equivalent F(4), and two equivalent F(6) atoms. In the fourth Ag site, Ag(4) is bonded in a square co-planar geometry to two equivalent F(2) and two equivalent F(5) atoms. There are six inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one Li(1), one Ag(1), and one Ag(3) atom. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one Li(1), one Ag(2), and one Ag(4) atom. In the third F site, F(3) is bonded in a 3-coordinate geometry to one Li(1), one Li(2), and one Ag(2) atom. In the fourth F site, F(4) is bonded in a distorted trigonal planar geometry to one Li(2), one Ag(1), and one Ag(3) atom. In the fifth F site, F(5) is bonded in a 3-coordinate geometry to one Li(2), one Ag(2), and one Ag(4) atom. In the sixth F site, F(6) is bonded in a 3-coordinate geometry to one Li(1), one Li(2), and one Ag(3) atom. is represented by the CIF card [CIF]
data_LiAgF3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.494
_cell_length_b   5.640
_cell_length_c   8.381
_cell_angle_alpha   90.098
_cell_angle_beta   92.566
_cell_angle_gamma   89.780
_symmetry_Int_Tables_number   1
_cell_volume   259.465
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.028  0.018  0.270  1.0
  Li  Li1  1  0.473  0.517  0.229  1.0
  Li  Li2  1  0.527  0.483  0.771  1.0
  Li  Li3  1  0.972  0.982  0.730  1.0
  Ag  Ag4  1  0.000  0.500  0.500  1.0
  Ag  Ag5  1  0.000  0.500  0.000  1.0
  Ag  Ag6  1  0.500  0.000  0.500  1.0
  Ag  Ag7  1  0.500  0.000  0.000  1.0
  F  F8  1  0.153  0.162  0.552  1.0
  F  F9  1  0.181  0.137  0.890  1.0
  F  F10  1  0.166  0.339  0.216  1.0
  F  F11  1  0.316  0.638  0.611  1.0
  F  F12  1  0.345  0.663  0.949  1.0
  F  F13  1  0.337  0.839  0.284  1.0
  F  F14  1  0.663  0.161  0.716  1.0
  F  F15  1  0.655  0.337  0.051  1.0
  F  F16  1  0.684  0.362  0.389  1.0
  F  F17  1  0.834  0.661  0.784  1.0
  F  F18  1  0.819  0.863  0.110  1.0
  F  F19  1  0.847  0.838  0.448  1.0
[/CIF]
.