The structure described by RuC3O3Br2 is Indium-like structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of two RuC3O3Br2 clusters. Ru(1) is bonded to one C(2), two equivalent C(1), one Br(1), and two equivalent Br(2) atoms to form edge-sharing RuC3Br3 octahedra. There are two inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Ru(1) and one O(2) atom. In the second C site, C(2) is bonded in a linear geometry to one Ru(1) and one O(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. There are two inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one Ru(1) atom. In the second Br site, Br(2) is bonded in an L-shaped geometry to two equivalent Ru(1) atoms. is represented by the CIF card [CIF]
data_RuC3Br2O3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.607
_cell_length_b   6.607
_cell_length_c   9.567
_cell_angle_alpha   76.596
_cell_angle_beta   76.596
_cell_angle_gamma   69.208
_symmetry_Int_Tables_number   1
_cell_volume   374.576
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ru  Ru0  1  0.937  0.937  0.211  1.0
  Ru  Ru1  1  0.063  0.063  0.789  1.0
  C  C2  1  0.909  0.279  0.648  1.0
  C  C3  1  0.279  0.909  0.648  1.0
  C  C4  1  0.091  0.721  0.352  1.0
  C  C5  1  0.238  0.238  0.798  1.0
  C  C6  1  0.721  0.091  0.352  1.0
  C  C7  1  0.762  0.762  0.202  1.0
  Br  Br8  1  0.171  0.171  0.226  1.0
  Br  Br9  1  0.763  0.237  0.000  1.0
  Br  Br10  1  0.829  0.829  0.774  1.0
  Br  Br11  1  0.237  0.763  0.000  1.0
  O  O12  1  0.344  0.344  0.794  1.0
  O  O13  1  0.656  0.656  0.206  1.0
  O  O14  1  0.191  0.590  0.435  1.0
  O  O15  1  0.590  0.191  0.435  1.0
  O  O16  1  0.410  0.809  0.565  1.0
  O  O17  1  0.809  0.410  0.565  1.0
[/CIF]
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The structure described by RuC3O3Br2 is Indium-like structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of two RuC3O3Br2 clusters. Ru(1) is bonded to one C(2), two equivalent C(1), one Br(1), and two equivalent Br(2) atoms to form edge-sharing RuC3Br3 octahedra. There are two inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Ru(1) and one O(2) atom. In the second C site, C(2) is bonded in a linear geometry to one Ru(1) and one O(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. There are two inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one Ru(1) atom. In the second Br site, Br(2) is bonded in an L-shaped geometry to two equivalent Ru(1) atoms. is represented by the CIF card [CIF]
data_RuC3Br2O3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.607
_cell_length_b   6.607
_cell_length_c   9.567
_cell_angle_alpha   76.596
_cell_angle_beta   76.596
_cell_angle_gamma   69.208
_symmetry_Int_Tables_number   1
_cell_volume   374.576
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ru  Ru0  1  0.937  0.937  0.211  1.0
  Ru  Ru1  1  0.063  0.063  0.789  1.0
  C  C2  1  0.909  0.279  0.648  1.0
  C  C3  1  0.279  0.909  0.648  1.0
  C  C4  1  0.091  0.721  0.352  1.0
  C  C5  1  0.238  0.238  0.798  1.0
  C  C6  1  0.721  0.091  0.352  1.0
  C  C7  1  0.762  0.762  0.202  1.0
  Br  Br8  1  0.171  0.171  0.226  1.0
  Br  Br9  1  0.763  0.237  0.000  1.0
  Br  Br10  1  0.829  0.829  0.774  1.0
  Br  Br11  1  0.237  0.763  0.000  1.0
  O  O12  1  0.344  0.344  0.794  1.0
  O  O13  1  0.656  0.656  0.206  1.0
  O  O14  1  0.191  0.590  0.435  1.0
  O  O15  1  0.590  0.191  0.435  1.0
  O  O16  1  0.410  0.809  0.565  1.0
  O  O17  1  0.809  0.410  0.565  1.0
[/CIF]
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