The structure described by NpMn2O5F8NpOF4 is Indium-like structured and crystallizes in the monoclinic C2 space group. The structure is zero-dimensional and consists of two NpMn2O5F8 clusters and two NpOF4 clusters. In each NpMn2O5F8 cluster, Np(2) is bonded in a 7-coordinate geometry to one O(2), two equivalent F(4), two equivalent F(5), and two equivalent F(6) atoms. Mn(1) is bonded in a tetrahedral geometry to one O(3), one O(4), one F(2), and one F(6) atom. There are three inequivalent O sites. In the first O site, O(2) is bonded in a single-bond geometry to one Np(2) atom. In the second O site, O(3) is bonded in a single-bond geometry to one Mn(1) atom. In the third O site, O(4) is bonded in a single-bond geometry to one Mn(1) atom. There are four inequivalent F sites. In the first F site, F(2) is bonded in a distorted single-bond geometry to one Mn(1) atom. In the second F site, F(4) is bonded in a single-bond geometry to one Np(2) atom. In the third F site, F(5) is bonded in a single-bond geometry to one Np(2) atom. In the fourth F site, F(6) is bonded in a distorted single-bond geometry to one Np(2) and one Mn(1) atom. In each NpOF4 cluster, Np(1) is bonded in a distorted square pyramidal geometry to one O(1), two equivalent F(1), and two equivalent F(3) atoms. O(1) is bonded in a single-bond geometry to one Np(1) atom. There are two inequivalent F sites. In the first F site, F(3) is bonded in a single-bond geometry to one Np(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one Np(1) atom. is represented by the CIF card [CIF]
data_NpMn(OF2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.305
_cell_length_b   7.305
_cell_length_c   9.817
_cell_angle_alpha   75.456
_cell_angle_beta   75.456
_cell_angle_gamma   59.522
_symmetry_Int_Tables_number   1
_cell_volume   432.208
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Np  Np0  1  0.544  0.456  0.500  1.0
  Np  Np1  1  0.250  0.750  0.000  1.0
  Mn  Mn2  1  0.348  0.058  0.259  1.0
  Mn  Mn3  1  0.942  0.652  0.741  1.0
  O  O4  1  0.796  0.204  0.500  1.0
  O  O5  1  0.003  0.997  0.000  1.0
  O  O6  1  0.147  0.288  0.283  1.0
  O  O7  1  0.712  0.853  0.717  1.0
  O  O8  1  0.577  0.047  0.243  1.0
  O  O9  1  0.953  0.423  0.757  1.0
  F  F10  1  0.612  0.501  0.284  1.0
  F  F11  1  0.499  0.388  0.716  1.0
  F  F12  1  0.324  0.857  0.400  1.0
  F  F13  1  0.143  0.676  0.600  1.0
  F  F14  1  0.389  0.297  0.486  1.0
  F  F15  1  0.703  0.611  0.514  1.0
  F  F16  1  0.371  0.428  0.012  1.0
  F  F17  1  0.572  0.629  0.988  1.0
  F  F18  1  0.167  0.684  0.212  1.0
  F  F19  1  0.316  0.833  0.788  1.0
  F  F20  1  0.328  0.975  0.108  1.0
  F  F21  1  0.025  0.672  0.892  1.0
[/CIF]
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The structure described by NpMn2O5F8NpOF4 is Indium-like structured and crystallizes in the monoclinic C2 space group. The structure is zero-dimensional and consists of two NpMn2O5F8 clusters and two NpOF4 clusters. In each NpMn2O5F8 cluster, Np(2) is bonded in a 7-coordinate geometry to one O(2), two equivalent F(4), two equivalent F(5), and two equivalent F(6) atoms. Mn(1) is bonded in a tetrahedral geometry to one O(3), one O(4), one F(2), and one F(6) atom. There are three inequivalent O sites. In the first O site, O(2) is bonded in a single-bond geometry to one Np(2) atom. In the second O site, O(3) is bonded in a single-bond geometry to one Mn(1) atom. In the third O site, O(4) is bonded in a single-bond geometry to one Mn(1) atom. There are four inequivalent F sites. In the first F site, F(2) is bonded in a distorted single-bond geometry to one Mn(1) atom. In the second F site, F(4) is bonded in a single-bond geometry to one Np(2) atom. In the third F site, F(5) is bonded in a single-bond geometry to one Np(2) atom. In the fourth F site, F(6) is bonded in a distorted single-bond geometry to one Np(2) and one Mn(1) atom. In each NpOF4 cluster, Np(1) is bonded in a distorted square pyramidal geometry to one O(1), two equivalent F(1), and two equivalent F(3) atoms. O(1) is bonded in a single-bond geometry to one Np(1) atom. There are two inequivalent F sites. In the first F site, F(3) is bonded in a single-bond geometry to one Np(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one Np(1) atom. is represented by the CIF card [CIF]
data_NpMn(OF2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.305
_cell_length_b   7.305
_cell_length_c   9.817
_cell_angle_alpha   75.456
_cell_angle_beta   75.456
_cell_angle_gamma   59.522
_symmetry_Int_Tables_number   1
_cell_volume   432.208
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Np  Np0  1  0.544  0.456  0.500  1.0
  Np  Np1  1  0.250  0.750  0.000  1.0
  Mn  Mn2  1  0.348  0.058  0.259  1.0
  Mn  Mn3  1  0.942  0.652  0.741  1.0
  O  O4  1  0.796  0.204  0.500  1.0
  O  O5  1  0.003  0.997  0.000  1.0
  O  O6  1  0.147  0.288  0.283  1.0
  O  O7  1  0.712  0.853  0.717  1.0
  O  O8  1  0.577  0.047  0.243  1.0
  O  O9  1  0.953  0.423  0.757  1.0
  F  F10  1  0.612  0.501  0.284  1.0
  F  F11  1  0.499  0.388  0.716  1.0
  F  F12  1  0.324  0.857  0.400  1.0
  F  F13  1  0.143  0.676  0.600  1.0
  F  F14  1  0.389  0.297  0.486  1.0
  F  F15  1  0.703  0.611  0.514  1.0
  F  F16  1  0.371  0.428  0.012  1.0
  F  F17  1  0.572  0.629  0.988  1.0
  F  F18  1  0.167  0.684  0.212  1.0
  F  F19  1  0.316  0.833  0.788  1.0
  F  F20  1  0.328  0.975  0.108  1.0
  F  F21  1  0.025  0.672  0.892  1.0
[/CIF]
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