The compound described by KrSbF7 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four KrSbF7 clusters. Kr(1) is bonded in a linear geometry to one F(3) and one F(4) atom. Sb(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(4), one F(5), one F(6), and one F(7) atom. There are seven inequivalent F sites. In the first F site, F(7) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one Kr(1) atom. In the fifth F site, F(4) is bonded in a distorted bent 120 degrees geometry to one Kr(1) and one Sb(1) atom. In the sixth F site, F(5) is bonded in a single-bond geometry to one Sb(1) atom. In the seventh F site, F(6) is bonded in a single-bond geometry to one Sb(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_SbKrF7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.474
_cell_length_b   5.210
_cell_length_c   10.680
_cell_angle_alpha   84.404
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   580.052
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.992  0.601  0.731  1.0
  Sb  Sb1  1  0.492  0.399  0.769  1.0
  Sb  Sb2  1  0.008  0.399  0.269  1.0
  Sb  Sb3  1  0.508  0.601  0.231  1.0
  Kr  Kr4  1  0.234  0.977  0.524  1.0
  Kr  Kr5  1  0.734  0.023  0.976  1.0
  Kr  Kr6  1  0.766  0.023  0.476  1.0
  Kr  Kr7  1  0.266  0.977  0.024  1.0
  F  F8  1  0.865  0.493  0.623  1.0
  F  F9  1  0.365  0.507  0.877  1.0
  F  F10  1  0.135  0.507  0.377  1.0
  F  F11  1  0.635  0.493  0.123  1.0
  F  F12  1  0.099  0.331  0.692  1.0
  F  F13  1  0.599  0.669  0.808  1.0
  F  F14  1  0.901  0.669  0.308  1.0
  F  F15  1  0.401  0.331  0.192  1.0
  F  F16  1  0.118  0.142  0.977  1.0
  F  F17  1  0.618  0.858  0.523  1.0
  F  F18  1  0.882  0.858  0.023  1.0
  F  F19  1  0.382  0.142  0.477  1.0
  F  F20  1  0.442  0.799  0.072  1.0
  F  F21  1  0.942  0.201  0.428  1.0
  F  F22  1  0.558  0.201  0.928  1.0
  F  F23  1  0.058  0.799  0.572  1.0
  F  F24  1  0.576  0.418  0.376  1.0
  F  F25  1  0.076  0.582  0.124  1.0
  F  F26  1  0.424  0.582  0.624  1.0
  F  F27  1  0.924  0.418  0.876  1.0
  F  F28  1  0.608  0.897  0.250  1.0
  F  F29  1  0.108  0.103  0.250  1.0
  F  F30  1  0.392  0.103  0.750  1.0
  F  F31  1  0.892  0.897  0.750  1.0
  F  F32  1  0.372  0.747  0.313  1.0
  F  F33  1  0.872  0.253  0.187  1.0
  F  F34  1  0.628  0.253  0.687  1.0
  F  F35  1  0.128  0.747  0.813  1.0
[/CIF]
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The compound described by KrSbF7 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four KrSbF7 clusters. Kr(1) is bonded in a linear geometry to one F(3) and one F(4) atom. Sb(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(4), one F(5), one F(6), and one F(7) atom. There are seven inequivalent F sites. In the first F site, F(7) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one Kr(1) atom. In the fifth F site, F(4) is bonded in a distorted bent 120 degrees geometry to one Kr(1) and one Sb(1) atom. In the sixth F site, F(5) is bonded in a single-bond geometry to one Sb(1) atom. In the seventh F site, F(6) is bonded in a single-bond geometry to one Sb(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_SbKrF7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.474
_cell_length_b   5.210
_cell_length_c   10.680
_cell_angle_alpha   84.404
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   580.052
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.992  0.601  0.731  1.0
  Sb  Sb1  1  0.492  0.399  0.769  1.0
  Sb  Sb2  1  0.008  0.399  0.269  1.0
  Sb  Sb3  1  0.508  0.601  0.231  1.0
  Kr  Kr4  1  0.234  0.977  0.524  1.0
  Kr  Kr5  1  0.734  0.023  0.976  1.0
  Kr  Kr6  1  0.766  0.023  0.476  1.0
  Kr  Kr7  1  0.266  0.977  0.024  1.0
  F  F8  1  0.865  0.493  0.623  1.0
  F  F9  1  0.365  0.507  0.877  1.0
  F  F10  1  0.135  0.507  0.377  1.0
  F  F11  1  0.635  0.493  0.123  1.0
  F  F12  1  0.099  0.331  0.692  1.0
  F  F13  1  0.599  0.669  0.808  1.0
  F  F14  1  0.901  0.669  0.308  1.0
  F  F15  1  0.401  0.331  0.192  1.0
  F  F16  1  0.118  0.142  0.977  1.0
  F  F17  1  0.618  0.858  0.523  1.0
  F  F18  1  0.882  0.858  0.023  1.0
  F  F19  1  0.382  0.142  0.477  1.0
  F  F20  1  0.442  0.799  0.072  1.0
  F  F21  1  0.942  0.201  0.428  1.0
  F  F22  1  0.558  0.201  0.928  1.0
  F  F23  1  0.058  0.799  0.572  1.0
  F  F24  1  0.576  0.418  0.376  1.0
  F  F25  1  0.076  0.582  0.124  1.0
  F  F26  1  0.424  0.582  0.624  1.0
  F  F27  1  0.924  0.418  0.876  1.0
  F  F28  1  0.608  0.897  0.250  1.0
  F  F29  1  0.108  0.103  0.250  1.0
  F  F30  1  0.392  0.103  0.750  1.0
  F  F31  1  0.892  0.897  0.750  1.0
  F  F32  1  0.372  0.747  0.313  1.0
  F  F33  1  0.872  0.253  0.187  1.0
  F  F34  1  0.628  0.253  0.687  1.0
  F  F35  1  0.128  0.747  0.813  1.0
[/CIF]
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