The structure described by RhSbO4 is Hydrophilite-derived structured and crystallizes in the orthorhombic Cmmm space group. Rh(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form RhO6 octahedra that share corners with eight equivalent Sb(1)O6 octahedra and edges with two equivalent Rh(1)O6 octahedra. The corner-sharing octahedral tilt angles are 52°. Sb(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form SbO6 octahedra that share corners with eight equivalent Rh(1)O6 octahedra and edges with two equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles are 52°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to two equivalent Rh(1) and one Sb(1) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Rh(1) and two equivalent Sb(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_SbRhO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.668
_cell_length_b   4.668
_cell_length_c   3.217
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.971
_symmetry_Int_Tables_number   1
_cell_volume   70.106
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.000  0.000  0.000  1.0
  Rh  Rh1  1  0.500  0.500  0.500  1.0
  O  O2  1  0.306  0.306  0.000  1.0
  O  O3  1  0.192  0.808  0.500  1.0
  O  O4  1  0.808  0.192  0.500  1.0
  O  O5  1  0.694  0.694  0.000  1.0
[/CIF]
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The structure described by RhSbO4 is Hydrophilite-derived structured and crystallizes in the orthorhombic Cmmm space group. Rh(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form RhO6 octahedra that share corners with eight equivalent Sb(1)O6 octahedra and edges with two equivalent Rh(1)O6 octahedra. The corner-sharing octahedral tilt angles are 52°. Sb(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form SbO6 octahedra that share corners with eight equivalent Rh(1)O6 octahedra and edges with two equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles are 52°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to two equivalent Rh(1) and one Sb(1) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Rh(1) and two equivalent Sb(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_SbRhO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.668
_cell_length_b   4.668
_cell_length_c   3.217
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.971
_symmetry_Int_Tables_number   1
_cell_volume   70.106
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.000  0.000  0.000  1.0
  Rh  Rh1  1  0.500  0.500  0.500  1.0
  O  O2  1  0.306  0.306  0.000  1.0
  O  O3  1  0.192  0.808  0.500  1.0
  O  O4  1  0.808  0.192  0.500  1.0
  O  O5  1  0.694  0.694  0.000  1.0
[/CIF]
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