The compound described by NaIn(MoO4)2 crystallizes in the triclinic P-1 space group. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded in a 5-coordinate geometry to one O(11), one O(12), one O(16), one O(2), and one O(3) atom. In the second Na site, Na(2) is bonded in a 5-coordinate geometry to one O(14), one O(4), one O(5), one O(6), and one O(8) atom. There are four inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one O(15), one O(2), one O(4), and one O(5) atom to form MoO4 tetrahedra that share corners with three equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 19-51°. In the second Mo site, Mo(2) is bonded to one O(10), one O(12), one O(3), and one O(9) atom to form MoO4 tetrahedra that share  a cornercorner with one In(1)O6 octahedra and corners with two equivalent In(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 32-48°. In the third Mo site, Mo(3) is bonded to one O(11), one O(13), one O(16), and one O(8) atom to form MoO4 tetrahedra that share corners with three equivalent In(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 34-58°. In the fourth Mo site, Mo(4) is bonded to one O(1), one O(14), one O(6), and one O(7) atom to form MoO4 tetrahedra that share  a cornercorner with one In(2)O6 octahedra and corners with two equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-49°. There are two inequivalent In sites. In the first In site, In(1) is bonded to one O(1), one O(15), one O(4), one O(5), one O(6), and one O(9) atom to form InO6 octahedra that share  a cornercorner with one Mo(2)O4 tetrahedra, corners with two equivalent Mo(4)O4 tetrahedra, and corners with three equivalent Mo(1)O4 tetrahedra. In the second In site, In(2) is bonded to one O(10), one O(11), one O(12), one O(13), one O(16), and one O(7) atom to form InO6 octahedra that share  a cornercorner with one Mo(4)O4 tetrahedra, corners with two equivalent Mo(2)O4 tetrahedra, and corners with three equivalent Mo(3)O4 tetrahedra. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Mo(4) and one In(1) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Na(1) and one Mo(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Na(1) and one Mo(2) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Na(2), one Mo(1), and one In(1) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Na(2), one Mo(1), and one In(1) atom. In the sixth O site, O(6) is bonded in a trigonal planar geometry to one Na(2), one Mo(4), and one In(1) atom. In the seventh O site, O(7) is bonded in a linear geometry to one Mo(4) and one In(2) atom. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one Na(2) and one Mo(3) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one Mo(2) and one In(1) atom. In the tenth O site, O(10) is bonded in a bent 150 degrees geometry to one Mo(2) and one In(2) atom. In the eleventh O site, O(11) is bonded in a trigonal planar geometry to one Na(1), one Mo(3), and one In(2) atom. In the twelfth O site, O(12) is bonded in a 3-coordinate geometry to one Na(1), one Mo(2), and one In(2) atom. In the thirteenth O site, O(13) is bonded in a bent 150 degrees geometry to one Mo(3) and one In(2) atom. In the fourteenth O site, O(14) is bonded in a bent 150 degrees geometry to one Na(2) and one Mo(4) atom. In the fifteenth O site, O(15) is bonded in a bent 150 degrees geometry to one Mo(1) and one In(1) atom. In the sixteenth O site, O(16) is bonded in a distorted trigonal planar geometry to one Na(1), one Mo(3), and one In(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_NaIn(MoO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.285
_cell_length_b   7.291
_cell_length_c   15.064
_cell_angle_alpha   92.005
_cell_angle_beta   92.018
_cell_angle_gamma   99.113
_symmetry_Int_Tables_number   1
_cell_volume   788.929
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.482  0.318  0.126  1.0
  Na  Na1  1  0.518  0.682  0.874  1.0
  Na  Na2  1  0.037  0.695  0.620  1.0
  Na  Na3  1  0.963  0.305  0.380  1.0
  In  In4  1  0.324  0.693  0.389  1.0
  In  In5  1  0.676  0.307  0.611  1.0
  In  In6  1  0.814  0.721  0.086  1.0
  In  In7  1  0.186  0.279  0.914  1.0
  Mo  Mo8  1  0.471  0.237  0.383  1.0
  Mo  Mo9  1  0.529  0.763  0.617  1.0
  Mo  Mo10  1  0.335  0.769  0.139  1.0
  Mo  Mo11  1  0.952  0.247  0.114  1.0
  Mo  Mo12  1  0.048  0.753  0.886  1.0
  Mo  Mo13  1  0.843  0.768  0.349  1.0
  Mo  Mo14  1  0.157  0.232  0.651  1.0
  Mo  Mo15  1  0.665  0.231  0.861  1.0
  O  O16  1  0.619  0.680  0.391  1.0
  O  O17  1  0.418  0.713  0.717  1.0
  O  O18  1  0.397  0.007  0.157  1.0
  O  O19  1  0.341  0.719  0.532  1.0
  O  O20  1  0.381  0.320  0.609  1.0
  O  O21  1  0.704  0.613  0.602  1.0
  O  O22  1  0.979  0.365  0.610  1.0
  O  O23  1  0.826  0.757  0.230  1.0
  O  O24  1  0.016  0.240  0.226  1.0
  O  O25  1  0.316  0.661  0.245  1.0
  O  O26  1  0.888  0.272  0.921  1.0
  O  O27  1  0.173  0.305  0.058  1.0
  O  O28  1  0.488  0.325  0.925  1.0
  O  O29  1  0.827  0.020  0.079  1.0
  O  O30  1  0.907  0.996  0.389  1.0
  O  O31  1  0.112  0.728  0.079  1.0
  O  O32  1  0.362  0.996  0.382  1.0
  O  O33  1  0.582  0.287  0.283  1.0
  O  O34  1  0.659  0.281  0.468  1.0
  O  O35  1  0.603  0.993  0.843  1.0
  O  O36  1  0.202  0.580  0.897  1.0
  O  O37  1  0.021  0.635  0.390  1.0
  O  O38  1  0.798  0.420  0.103  1.0
  O  O39  1  0.684  0.339  0.755  1.0
  O  O40  1  0.984  0.760  0.774  1.0
  O  O41  1  0.638  0.004  0.618  1.0
  O  O42  1  0.173  0.980  0.921  1.0
  O  O43  1  0.512  0.675  0.075  1.0
  O  O44  1  0.296  0.387  0.398  1.0
  O  O45  1  0.093  0.004  0.611  1.0
  O  O46  1  0.174  0.243  0.770  1.0
  O  O47  1  0.827  0.695  0.942  1.0
[/CIF]
.
The compound described by NaIn(MoO4)2 crystallizes in the triclinic P-1 space group. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded in a 5-coordinate geometry to one O(11), one O(12), one O(16), one O(2), and one O(3) atom. In the second Na site, Na(2) is bonded in a 5-coordinate geometry to one O(14), one O(4), one O(5), one O(6), and one O(8) atom. There are four inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one O(15), one O(2), one O(4), and one O(5) atom to form MoO4 tetrahedra that share corners with three equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 19-51°. In the second Mo site, Mo(2) is bonded to one O(10), one O(12), one O(3), and one O(9) atom to form MoO4 tetrahedra that share  a cornercorner with one In(1)O6 octahedra and corners with two equivalent In(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 32-48°. In the third Mo site, Mo(3) is bonded to one O(11), one O(13), one O(16), and one O(8) atom to form MoO4 tetrahedra that share corners with three equivalent In(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 34-58°. In the fourth Mo site, Mo(4) is bonded to one O(1), one O(14), one O(6), and one O(7) atom to form MoO4 tetrahedra that share  a cornercorner with one In(2)O6 octahedra and corners with two equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-49°. There are two inequivalent In sites. In the first In site, In(1) is bonded to one O(1), one O(15), one O(4), one O(5), one O(6), and one O(9) atom to form InO6 octahedra that share  a cornercorner with one Mo(2)O4 tetrahedra, corners with two equivalent Mo(4)O4 tetrahedra, and corners with three equivalent Mo(1)O4 tetrahedra. In the second In site, In(2) is bonded to one O(10), one O(11), one O(12), one O(13), one O(16), and one O(7) atom to form InO6 octahedra that share  a cornercorner with one Mo(4)O4 tetrahedra, corners with two equivalent Mo(2)O4 tetrahedra, and corners with three equivalent Mo(3)O4 tetrahedra. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Mo(4) and one In(1) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Na(1) and one Mo(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Na(1) and one Mo(2) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Na(2), one Mo(1), and one In(1) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Na(2), one Mo(1), and one In(1) atom. In the sixth O site, O(6) is bonded in a trigonal planar geometry to one Na(2), one Mo(4), and one In(1) atom. In the seventh O site, O(7) is bonded in a linear geometry to one Mo(4) and one In(2) atom. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one Na(2) and one Mo(3) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one Mo(2) and one In(1) atom. In the tenth O site, O(10) is bonded in a bent 150 degrees geometry to one Mo(2) and one In(2) atom. In the eleventh O site, O(11) is bonded in a trigonal planar geometry to one Na(1), one Mo(3), and one In(2) atom. In the twelfth O site, O(12) is bonded in a 3-coordinate geometry to one Na(1), one Mo(2), and one In(2) atom. In the thirteenth O site, O(13) is bonded in a bent 150 degrees geometry to one Mo(3) and one In(2) atom. In the fourteenth O site, O(14) is bonded in a bent 150 degrees geometry to one Na(2) and one Mo(4) atom. In the fifteenth O site, O(15) is bonded in a bent 150 degrees geometry to one Mo(1) and one In(1) atom. In the sixteenth O site, O(16) is bonded in a distorted trigonal planar geometry to one Na(1), one Mo(3), and one In(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_NaIn(MoO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.285
_cell_length_b   7.291
_cell_length_c   15.064
_cell_angle_alpha   92.005
_cell_angle_beta   92.018
_cell_angle_gamma   99.113
_symmetry_Int_Tables_number   1
_cell_volume   788.929
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.482  0.318  0.126  1.0
  Na  Na1  1  0.518  0.682  0.874  1.0
  Na  Na2  1  0.037  0.695  0.620  1.0
  Na  Na3  1  0.963  0.305  0.380  1.0
  In  In4  1  0.324  0.693  0.389  1.0
  In  In5  1  0.676  0.307  0.611  1.0
  In  In6  1  0.814  0.721  0.086  1.0
  In  In7  1  0.186  0.279  0.914  1.0
  Mo  Mo8  1  0.471  0.237  0.383  1.0
  Mo  Mo9  1  0.529  0.763  0.617  1.0
  Mo  Mo10  1  0.335  0.769  0.139  1.0
  Mo  Mo11  1  0.952  0.247  0.114  1.0
  Mo  Mo12  1  0.048  0.753  0.886  1.0
  Mo  Mo13  1  0.843  0.768  0.349  1.0
  Mo  Mo14  1  0.157  0.232  0.651  1.0
  Mo  Mo15  1  0.665  0.231  0.861  1.0
  O  O16  1  0.619  0.680  0.391  1.0
  O  O17  1  0.418  0.713  0.717  1.0
  O  O18  1  0.397  0.007  0.157  1.0
  O  O19  1  0.341  0.719  0.532  1.0
  O  O20  1  0.381  0.320  0.609  1.0
  O  O21  1  0.704  0.613  0.602  1.0
  O  O22  1  0.979  0.365  0.610  1.0
  O  O23  1  0.826  0.757  0.230  1.0
  O  O24  1  0.016  0.240  0.226  1.0
  O  O25  1  0.316  0.661  0.245  1.0
  O  O26  1  0.888  0.272  0.921  1.0
  O  O27  1  0.173  0.305  0.058  1.0
  O  O28  1  0.488  0.325  0.925  1.0
  O  O29  1  0.827  0.020  0.079  1.0
  O  O30  1  0.907  0.996  0.389  1.0
  O  O31  1  0.112  0.728  0.079  1.0
  O  O32  1  0.362  0.996  0.382  1.0
  O  O33  1  0.582  0.287  0.283  1.0
  O  O34  1  0.659  0.281  0.468  1.0
  O  O35  1  0.603  0.993  0.843  1.0
  O  O36  1  0.202  0.580  0.897  1.0
  O  O37  1  0.021  0.635  0.390  1.0
  O  O38  1  0.798  0.420  0.103  1.0
  O  O39  1  0.684  0.339  0.755  1.0
  O  O40  1  0.984  0.760  0.774  1.0
  O  O41  1  0.638  0.004  0.618  1.0
  O  O42  1  0.173  0.980  0.921  1.0
  O  O43  1  0.512  0.675  0.075  1.0
  O  O44  1  0.296  0.387  0.398  1.0
  O  O45  1  0.093  0.004  0.611  1.0
  O  O46  1  0.174  0.243  0.770  1.0
  O  O47  1  0.827  0.695  0.942  1.0
[/CIF]
.