The crystal structure described by VMo5AgCu6O24 crystallizes in the triclinic P1 space group. V(1) is bonded to one O(11), one O(22), one O(5), and one O(7) atom to form VO4 tetrahedra that share  a cornercorner with one Cu(3)O6 octahedra,  a cornercorner with one Cu(6)O6 octahedra, corners with two equivalent Cu(4)O6 octahedra,  a cornercorner with one Cu(1)O5 square pyramid, and  a cornercorner with one Cu(5)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 48-67°. There are five inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one O(1), one O(12), one O(4), and one O(8) atom to form MoO4 tetrahedra that share  a cornercorner with one Cu(3)O6 octahedra,  a cornercorner with one Cu(4)O6 octahedra,  a cornercorner with one Cu(6)O6 octahedra,  a cornercorner with one Cu(1)O5 square pyramid, and corners with two equivalent Cu(5)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 54-68°. In the second Mo site, Mo(2) is bonded to one O(10), one O(16), one O(2), and one O(6) atom to form MoO4 tetrahedra that share  a cornercorner with one Cu(3)O6 octahedra, corners with two equivalent Cu(6)O6 octahedra,  a cornercorner with one Cu(2)O5 trigonal bipyramid, and  a cornercorner with one Cu(5)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 9-43°. In the third Mo site, Mo(3) is bonded to one O(15), one O(19), one O(23), and one O(9) atom to form MoO4 tetrahedra that share  a cornercorner with one Cu(4)O6 octahedra, corners with two equivalent Cu(1)O5 square pyramids,  a cornercorner with one Cu(2)O5 trigonal bipyramid, and  a cornercorner with one Cu(5)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles are 6°. In the fourth Mo site, Mo(4) is bonded to one O(13), one O(17), one O(21), and one O(24) atom to form MoO4 tetrahedra that share  a cornercorner with one Cu(3)O6 octahedra,  a cornercorner with one Cu(4)O6 octahedra,  a cornercorner with one Cu(6)O6 octahedra,  a cornercorner with one Cu(1)O5 square pyramid, and corners with two equivalent Cu(2)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 11-66°. In the fifth Mo site, Mo(5) is bonded to one O(14), one O(18), one O(20), and one O(3) atom to form MoO4 tetrahedra that share  a cornercorner with one Cu(4)O6 octahedra,  a cornercorner with one Cu(6)O6 octahedra, corners with two equivalent Cu(3)O6 octahedra, and  a cornercorner with one Cu(2)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 27-56°. Ag(1) is bonded in a rectangular see-saw-like geometry to one O(20), one O(21), one O(4), and one O(5) atom. There are six inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to one O(23), one O(24), one O(7), one O(8), and one O(9) atom to form distorted CuO5 square pyramids that share  a cornercorner with one Cu(6)O6 octahedra,  a cornercorner with one V(1)O4 tetrahedra,  a cornercorner with one Mo(1)O4 tetrahedra,  a cornercorner with one Mo(4)O4 tetrahedra, corners with two equivalent Mo(3)O4 tetrahedra, and  an edgeedge with one Cu(2)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles are 83°. In the second Cu site, Cu(2) is bonded to one O(13), one O(24), one O(3), one O(6), and one O(9) atom to form distorted CuO5 trigonal bipyramids that share  a cornercorner with one Mo(2)O4 tetrahedra,  a cornercorner with one Mo(3)O4 tetrahedra,  a cornercorner with one Mo(5)O4 tetrahedra, corners with two equivalent Mo(4)O4 tetrahedra,  an edgeedge with one Cu(3)O6 octahedra, and  an edgeedge with one Cu(1)O5 square pyramid. In the third Cu site, Cu(3) is bonded to one O(10), one O(11), one O(13), one O(14), one O(3), and one O(4) atom to form distorted CuO6 octahedra that share  a cornercorner with one V(1)O4 tetrahedra,  a cornercorner with one Mo(1)O4 tetrahedra,  a cornercorner with one Mo(2)O4 tetrahedra,  a cornercorner with one Mo(4)O4 tetrahedra, corners with two equivalent Mo(5)O4 tetrahedra,  an edgeedge with one Cu(4)O6 octahedra, and  an edgeedge with one Cu(2)O5 trigonal bipyramid. In the fourth Cu site, Cu(4) is bonded to one O(11), one O(12), one O(14), one O(15), one O(21), and one O(22) atom to form distorted CuO6 octahedra that share  a cornercorner with one Mo(1)O4 tetrahedra,  a cornercorner with one Mo(3)O4 tetrahedra,  a cornercorner with one Mo(4)O4 tetrahedra,  a cornercorner with one Mo(5)O4 tetrahedra, corners with two equivalent V(1)O4 tetrahedra,  an edgeedge with one Cu(3)O6 octahedra, and  an edgeedge with one Cu(5)O5 trigonal bipyramid. In the fifth Cu site, Cu(5) is bonded to one O(1), one O(12), one O(16), one O(19), and one O(22) atom to form distorted CuO5 trigonal bipyramids that share  a cornercorner with one V(1)O4 tetrahedra,  a cornercorner with one Mo(2)O4 tetrahedra,  a cornercorner with one Mo(3)O4 tetrahedra, corners with two equivalent Mo(1)O4 tetrahedra,  an edgeedge with one Cu(4)O6 octahedra, and  an edgeedge with one Cu(6)O6 octahedra. In the sixth Cu site, Cu(6) is bonded to one O(1), one O(16), one O(17), one O(18), one O(2), and one O(7) atom to form distorted CuO6 octahedra that share  a cornercorner with one Cu(1)O5 square pyramid,  a cornercorner with one V(1)O4 tetrahedra,  a cornercorner with one Mo(1)O4 tetrahedra,  a cornercorner with one Mo(4)O4 tetrahedra,  a cornercorner with one Mo(5)O4 tetrahedra, corners with two equivalent Mo(2)O4 tetrahedra, and  an edgeedge with one Cu(5)O5 trigonal bipyramid. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Mo(1), one Cu(5), and one Cu(6) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Mo(2) and one Cu(6) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Mo(5), one Cu(2), and one Cu(3) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one Mo(1), one Ag(1), and one Cu(3) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one V(1) and one Ag(1) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one Mo(2) and one Cu(2) atom. In the seventh O site, O(7) is bonded in a distorted bent 150 degrees geometry to one V(1), one Cu(1), and one Cu(6) atom. In the eighth O site, O(8) is bonded in a linear geometry to one Mo(1) and one Cu(1) atom. In the ninth O site, O(9) is bonded in a distorted trigonal planar geometry to one Mo(3), one Cu(1), and one Cu(2) atom. In the tenth O site, O(10) is bonded in a linear geometry to one Mo(2) and one Cu(3) atom. In the eleventh O site, O(11) is bonded in a distorted trigonal planar geometry to one V(1), one Cu(3), and one Cu(4) atom. In the twelfth O site, O(12) is bonded in a 3-coordinate geometry to one Mo(1), one Cu(4), and one Cu(5) atom. In the thirteenth O site, O(13) is bonded in a distorted bent 150 degrees geometry to one Mo(4), one Cu(2), and one Cu(3) atom. In the fourteenth O site, O(14) is bonded in a distorted trigonal planar geometry to one Mo(5), one Cu(3), and one Cu(4) atom. In the fifteenth O site, O(15) is bonded in a linear geometry to one Mo(3) and one Cu(4) atom. In the sixteenth O site, O(16) is bonded in a 3-coordinate geometry to one Mo(2), one Cu(5), and one Cu(6) atom. In the seventeenth O site, O(17) is bonded in a linear geometry to one Mo(4) and one Cu(6) atom. In the eighteenth O site, O(18) is bonded in a bent 150 degrees geometry to one Mo(5) and one Cu(6) atom. In the nineteenth O site, O(19) is bonded in a bent 150 degrees geometry to one Mo(3) and one Cu(5) atom. In the twentieth O site, O(20) is bonded in a bent 150 degrees geometry to one Mo(5) and one Ag(1) atom. In the twenty-first O site, O(21) is bonded in a distorted trigonal planar geometry to one Mo(4), one Ag(1), and one Cu(4) atom. In the twenty-second O site, O(22) is bonded in a trigonal planar geometry to one V(1), one Cu(4), and one Cu(5) atom. In the twenty-third O site, O(23) is bonded in a bent 150 degrees geometry to one Mo(3) and one Cu(1) atom. In the twenty-fourth O site, O(24) is bonded in a trigonal planar geometry to one Mo(4), one Cu(1), and one Cu(2) atom. is represented by the CIF card [CIF]
data_VCu6AgMo5O24
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.841
_cell_length_b   8.603
_cell_length_c   9.930
_cell_angle_alpha   101.935
_cell_angle_beta   103.112
_cell_angle_gamma   101.185
_symmetry_Int_Tables_number   1
_cell_volume   538.779
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.106  0.091  0.339  1.0
  Cu  Cu1  1  0.050  0.206  0.017  1.0
  Cu  Cu2  1  0.253  0.269  0.767  1.0
  Cu  Cu3  1  0.368  0.942  0.593  1.0
  Cu  Cu4  1  0.617  0.046  0.392  1.0
  Cu  Cu5  1  0.753  0.737  0.238  1.0
  Cu  Cu6  1  0.953  0.801  0.993  1.0
  Ag  Ag7  1  0.991  0.488  0.484  1.0
  Mo  Mo8  1  0.233  0.671  0.260  1.0
  Mo  Mo9  1  0.406  0.725  0.881  1.0
  Mo  Mo10  1  0.594  0.279  0.118  1.0
  Mo  Mo11  1  0.770  0.333  0.743  1.0
  Mo  Mo12  1  0.891  0.907  0.656  1.0
  O  O13  1  0.007  0.751  0.178  1.0
  O  O14  1  0.233  0.782  0.983  1.0
  O  O15  1  0.142  0.028  0.651  1.0
  O  O16  1  0.225  0.678  0.440  1.0
  O  O17  1  0.145  0.282  0.438  1.0
  O  O18  1  0.320  0.508  0.796  1.0
  O  O19  1  0.085  0.091  0.162  1.0
  O  O20  1  0.182  0.467  0.166  1.0
  O  O21  1  0.335  0.225  0.996  1.0
  O  O22  1  0.409  0.836  0.748  1.0
  O  O23  1  0.327  0.011  0.413  1.0
  O  O24  1  0.495  0.768  0.265  1.0
  O  O25  1  0.507  0.235  0.736  1.0
  O  O26  1  0.665  0.983  0.580  1.0
  O  O27  1  0.589  0.165  0.249  1.0
  O  O28  1  0.663  0.779  0.004  1.0
  O  O29  1  0.824  0.537  0.839  1.0
  O  O30  1  0.904  0.899  0.836  1.0
  O  O31  1  0.682  0.496  0.207  1.0
  O  O32  1  0.852  0.708  0.553  1.0
  O  O33  1  0.774  0.327  0.563  1.0
  O  O34  1  0.861  0.974  0.352  1.0
  O  O35  1  0.768  0.222  0.017  1.0
  O  O36  1  0.989  0.241  0.819  1.0
[/CIF]
.
The crystal structure described by VMo5AgCu6O24 crystallizes in the triclinic P1 space group. V(1) is bonded to one O(11), one O(22), one O(5), and one O(7) atom to form VO4 tetrahedra that share  a cornercorner with one Cu(3)O6 octahedra,  a cornercorner with one Cu(6)O6 octahedra, corners with two equivalent Cu(4)O6 octahedra,  a cornercorner with one Cu(1)O5 square pyramid, and  a cornercorner with one Cu(5)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 48-67°. There are five inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one O(1), one O(12), one O(4), and one O(8) atom to form MoO4 tetrahedra that share  a cornercorner with one Cu(3)O6 octahedra,  a cornercorner with one Cu(4)O6 octahedra,  a cornercorner with one Cu(6)O6 octahedra,  a cornercorner with one Cu(1)O5 square pyramid, and corners with two equivalent Cu(5)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 54-68°. In the second Mo site, Mo(2) is bonded to one O(10), one O(16), one O(2), and one O(6) atom to form MoO4 tetrahedra that share  a cornercorner with one Cu(3)O6 octahedra, corners with two equivalent Cu(6)O6 octahedra,  a cornercorner with one Cu(2)O5 trigonal bipyramid, and  a cornercorner with one Cu(5)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 9-43°. In the third Mo site, Mo(3) is bonded to one O(15), one O(19), one O(23), and one O(9) atom to form MoO4 tetrahedra that share  a cornercorner with one Cu(4)O6 octahedra, corners with two equivalent Cu(1)O5 square pyramids,  a cornercorner with one Cu(2)O5 trigonal bipyramid, and  a cornercorner with one Cu(5)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles are 6°. In the fourth Mo site, Mo(4) is bonded to one O(13), one O(17), one O(21), and one O(24) atom to form MoO4 tetrahedra that share  a cornercorner with one Cu(3)O6 octahedra,  a cornercorner with one Cu(4)O6 octahedra,  a cornercorner with one Cu(6)O6 octahedra,  a cornercorner with one Cu(1)O5 square pyramid, and corners with two equivalent Cu(2)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 11-66°. In the fifth Mo site, Mo(5) is bonded to one O(14), one O(18), one O(20), and one O(3) atom to form MoO4 tetrahedra that share  a cornercorner with one Cu(4)O6 octahedra,  a cornercorner with one Cu(6)O6 octahedra, corners with two equivalent Cu(3)O6 octahedra, and  a cornercorner with one Cu(2)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 27-56°. Ag(1) is bonded in a rectangular see-saw-like geometry to one O(20), one O(21), one O(4), and one O(5) atom. There are six inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to one O(23), one O(24), one O(7), one O(8), and one O(9) atom to form distorted CuO5 square pyramids that share  a cornercorner with one Cu(6)O6 octahedra,  a cornercorner with one V(1)O4 tetrahedra,  a cornercorner with one Mo(1)O4 tetrahedra,  a cornercorner with one Mo(4)O4 tetrahedra, corners with two equivalent Mo(3)O4 tetrahedra, and  an edgeedge with one Cu(2)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles are 83°. In the second Cu site, Cu(2) is bonded to one O(13), one O(24), one O(3), one O(6), and one O(9) atom to form distorted CuO5 trigonal bipyramids that share  a cornercorner with one Mo(2)O4 tetrahedra,  a cornercorner with one Mo(3)O4 tetrahedra,  a cornercorner with one Mo(5)O4 tetrahedra, corners with two equivalent Mo(4)O4 tetrahedra,  an edgeedge with one Cu(3)O6 octahedra, and  an edgeedge with one Cu(1)O5 square pyramid. In the third Cu site, Cu(3) is bonded to one O(10), one O(11), one O(13), one O(14), one O(3), and one O(4) atom to form distorted CuO6 octahedra that share  a cornercorner with one V(1)O4 tetrahedra,  a cornercorner with one Mo(1)O4 tetrahedra,  a cornercorner with one Mo(2)O4 tetrahedra,  a cornercorner with one Mo(4)O4 tetrahedra, corners with two equivalent Mo(5)O4 tetrahedra,  an edgeedge with one Cu(4)O6 octahedra, and  an edgeedge with one Cu(2)O5 trigonal bipyramid. In the fourth Cu site, Cu(4) is bonded to one O(11), one O(12), one O(14), one O(15), one O(21), and one O(22) atom to form distorted CuO6 octahedra that share  a cornercorner with one Mo(1)O4 tetrahedra,  a cornercorner with one Mo(3)O4 tetrahedra,  a cornercorner with one Mo(4)O4 tetrahedra,  a cornercorner with one Mo(5)O4 tetrahedra, corners with two equivalent V(1)O4 tetrahedra,  an edgeedge with one Cu(3)O6 octahedra, and  an edgeedge with one Cu(5)O5 trigonal bipyramid. In the fifth Cu site, Cu(5) is bonded to one O(1), one O(12), one O(16), one O(19), and one O(22) atom to form distorted CuO5 trigonal bipyramids that share  a cornercorner with one V(1)O4 tetrahedra,  a cornercorner with one Mo(2)O4 tetrahedra,  a cornercorner with one Mo(3)O4 tetrahedra, corners with two equivalent Mo(1)O4 tetrahedra,  an edgeedge with one Cu(4)O6 octahedra, and  an edgeedge with one Cu(6)O6 octahedra. In the sixth Cu site, Cu(6) is bonded to one O(1), one O(16), one O(17), one O(18), one O(2), and one O(7) atom to form distorted CuO6 octahedra that share  a cornercorner with one Cu(1)O5 square pyramid,  a cornercorner with one V(1)O4 tetrahedra,  a cornercorner with one Mo(1)O4 tetrahedra,  a cornercorner with one Mo(4)O4 tetrahedra,  a cornercorner with one Mo(5)O4 tetrahedra, corners with two equivalent Mo(2)O4 tetrahedra, and  an edgeedge with one Cu(5)O5 trigonal bipyramid. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Mo(1), one Cu(5), and one Cu(6) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Mo(2) and one Cu(6) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Mo(5), one Cu(2), and one Cu(3) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one Mo(1), one Ag(1), and one Cu(3) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one V(1) and one Ag(1) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one Mo(2) and one Cu(2) atom. In the seventh O site, O(7) is bonded in a distorted bent 150 degrees geometry to one V(1), one Cu(1), and one Cu(6) atom. In the eighth O site, O(8) is bonded in a linear geometry to one Mo(1) and one Cu(1) atom. In the ninth O site, O(9) is bonded in a distorted trigonal planar geometry to one Mo(3), one Cu(1), and one Cu(2) atom. In the tenth O site, O(10) is bonded in a linear geometry to one Mo(2) and one Cu(3) atom. In the eleventh O site, O(11) is bonded in a distorted trigonal planar geometry to one V(1), one Cu(3), and one Cu(4) atom. In the twelfth O site, O(12) is bonded in a 3-coordinate geometry to one Mo(1), one Cu(4), and one Cu(5) atom. In the thirteenth O site, O(13) is bonded in a distorted bent 150 degrees geometry to one Mo(4), one Cu(2), and one Cu(3) atom. In the fourteenth O site, O(14) is bonded in a distorted trigonal planar geometry to one Mo(5), one Cu(3), and one Cu(4) atom. In the fifteenth O site, O(15) is bonded in a linear geometry to one Mo(3) and one Cu(4) atom. In the sixteenth O site, O(16) is bonded in a 3-coordinate geometry to one Mo(2), one Cu(5), and one Cu(6) atom. In the seventeenth O site, O(17) is bonded in a linear geometry to one Mo(4) and one Cu(6) atom. In the eighteenth O site, O(18) is bonded in a bent 150 degrees geometry to one Mo(5) and one Cu(6) atom. In the nineteenth O site, O(19) is bonded in a bent 150 degrees geometry to one Mo(3) and one Cu(5) atom. In the twentieth O site, O(20) is bonded in a bent 150 degrees geometry to one Mo(5) and one Ag(1) atom. In the twenty-first O site, O(21) is bonded in a distorted trigonal planar geometry to one Mo(4), one Ag(1), and one Cu(4) atom. In the twenty-second O site, O(22) is bonded in a trigonal planar geometry to one V(1), one Cu(4), and one Cu(5) atom. In the twenty-third O site, O(23) is bonded in a bent 150 degrees geometry to one Mo(3) and one Cu(1) atom. In the twenty-fourth O site, O(24) is bonded in a trigonal planar geometry to one Mo(4), one Cu(1), and one Cu(2) atom. is represented by the CIF card [CIF]
data_VCu6AgMo5O24
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.841
_cell_length_b   8.603
_cell_length_c   9.930
_cell_angle_alpha   101.935
_cell_angle_beta   103.112
_cell_angle_gamma   101.185
_symmetry_Int_Tables_number   1
_cell_volume   538.779
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.106  0.091  0.339  1.0
  Cu  Cu1  1  0.050  0.206  0.017  1.0
  Cu  Cu2  1  0.253  0.269  0.767  1.0
  Cu  Cu3  1  0.368  0.942  0.593  1.0
  Cu  Cu4  1  0.617  0.046  0.392  1.0
  Cu  Cu5  1  0.753  0.737  0.238  1.0
  Cu  Cu6  1  0.953  0.801  0.993  1.0
  Ag  Ag7  1  0.991  0.488  0.484  1.0
  Mo  Mo8  1  0.233  0.671  0.260  1.0
  Mo  Mo9  1  0.406  0.725  0.881  1.0
  Mo  Mo10  1  0.594  0.279  0.118  1.0
  Mo  Mo11  1  0.770  0.333  0.743  1.0
  Mo  Mo12  1  0.891  0.907  0.656  1.0
  O  O13  1  0.007  0.751  0.178  1.0
  O  O14  1  0.233  0.782  0.983  1.0
  O  O15  1  0.142  0.028  0.651  1.0
  O  O16  1  0.225  0.678  0.440  1.0
  O  O17  1  0.145  0.282  0.438  1.0
  O  O18  1  0.320  0.508  0.796  1.0
  O  O19  1  0.085  0.091  0.162  1.0
  O  O20  1  0.182  0.467  0.166  1.0
  O  O21  1  0.335  0.225  0.996  1.0
  O  O22  1  0.409  0.836  0.748  1.0
  O  O23  1  0.327  0.011  0.413  1.0
  O  O24  1  0.495  0.768  0.265  1.0
  O  O25  1  0.507  0.235  0.736  1.0
  O  O26  1  0.665  0.983  0.580  1.0
  O  O27  1  0.589  0.165  0.249  1.0
  O  O28  1  0.663  0.779  0.004  1.0
  O  O29  1  0.824  0.537  0.839  1.0
  O  O30  1  0.904  0.899  0.836  1.0
  O  O31  1  0.682  0.496  0.207  1.0
  O  O32  1  0.852  0.708  0.553  1.0
  O  O33  1  0.774  0.327  0.563  1.0
  O  O34  1  0.861  0.974  0.352  1.0
  O  O35  1  0.768  0.222  0.017  1.0
  O  O36  1  0.989  0.241  0.819  1.0
[/CIF]
.