The compound described by Zn(SbO2)2 crystallizes in the orthorhombic Pbcm space group. Zn(1) is bonded to two equivalent O(1) and two equivalent O(3) atoms to form corner-sharing ZnO4 tetrahedra. Sb(1) is bonded in a 4-coordinate geometry to one O(2), one O(3), and two equivalent O(1) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Zn(1) and two equivalent Sb(1) atoms. In the second O site, O(2) is bonded in a water-like geometry to two equivalent Sb(1) atoms. In the third O site, O(3) is bonded to two equivalent Zn(1) and two equivalent Sb(1) atoms to form distorted corner-sharing OZn2Sb2 trigonal pyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_Zn(SbO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.644
_cell_length_b   10.045
_cell_length_c   11.184
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   409.385
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.345  0.858  0.750  1.0
  Zn  Zn1  1  0.345  0.642  0.250  1.0
  Zn  Zn2  1  0.655  0.358  0.750  1.0
  Zn  Zn3  1  0.655  0.142  0.250  1.0
  Sb  Sb4  1  0.085  0.626  0.905  1.0
  Sb  Sb5  1  0.085  0.874  0.405  1.0
  Sb  Sb6  1  0.915  0.374  0.405  1.0
  Sb  Sb7  1  0.085  0.874  0.095  1.0
  Sb  Sb8  1  0.915  0.374  0.095  1.0
  Sb  Sb9  1  0.085  0.626  0.595  1.0
  Sb  Sb10  1  0.915  0.126  0.595  1.0
  Sb  Sb11  1  0.915  0.126  0.905  1.0
  O  O12  1  0.766  0.463  0.600  1.0
  O  O13  1  0.234  0.537  0.400  1.0
  O  O14  1  0.764  0.750  0.500  1.0
  O  O15  1  0.234  0.963  0.600  1.0
  O  O16  1  0.234  0.963  0.900  1.0
  O  O17  1  0.832  0.759  0.250  1.0
  O  O18  1  0.766  0.037  0.400  1.0
  O  O19  1  0.168  0.259  0.250  1.0
  O  O20  1  0.764  0.750  0.000  1.0
  O  O21  1  0.236  0.250  0.500  1.0
  O  O22  1  0.766  0.463  0.900  1.0
  O  O23  1  0.168  0.241  0.750  1.0
  O  O24  1  0.832  0.741  0.750  1.0
  O  O25  1  0.236  0.250  0.000  1.0
  O  O26  1  0.766  0.037  0.100  1.0
  O  O27  1  0.234  0.537  0.100  1.0
[/CIF]
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The compound described by Zn(SbO2)2 crystallizes in the orthorhombic Pbcm space group. Zn(1) is bonded to two equivalent O(1) and two equivalent O(3) atoms to form corner-sharing ZnO4 tetrahedra. Sb(1) is bonded in a 4-coordinate geometry to one O(2), one O(3), and two equivalent O(1) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Zn(1) and two equivalent Sb(1) atoms. In the second O site, O(2) is bonded in a water-like geometry to two equivalent Sb(1) atoms. In the third O site, O(3) is bonded to two equivalent Zn(1) and two equivalent Sb(1) atoms to form distorted corner-sharing OZn2Sb2 trigonal pyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_Zn(SbO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.644
_cell_length_b   10.045
_cell_length_c   11.184
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   409.385
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.345  0.858  0.750  1.0
  Zn  Zn1  1  0.345  0.642  0.250  1.0
  Zn  Zn2  1  0.655  0.358  0.750  1.0
  Zn  Zn3  1  0.655  0.142  0.250  1.0
  Sb  Sb4  1  0.085  0.626  0.905  1.0
  Sb  Sb5  1  0.085  0.874  0.405  1.0
  Sb  Sb6  1  0.915  0.374  0.405  1.0
  Sb  Sb7  1  0.085  0.874  0.095  1.0
  Sb  Sb8  1  0.915  0.374  0.095  1.0
  Sb  Sb9  1  0.085  0.626  0.595  1.0
  Sb  Sb10  1  0.915  0.126  0.595  1.0
  Sb  Sb11  1  0.915  0.126  0.905  1.0
  O  O12  1  0.766  0.463  0.600  1.0
  O  O13  1  0.234  0.537  0.400  1.0
  O  O14  1  0.764  0.750  0.500  1.0
  O  O15  1  0.234  0.963  0.600  1.0
  O  O16  1  0.234  0.963  0.900  1.0
  O  O17  1  0.832  0.759  0.250  1.0
  O  O18  1  0.766  0.037  0.400  1.0
  O  O19  1  0.168  0.259  0.250  1.0
  O  O20  1  0.764  0.750  0.000  1.0
  O  O21  1  0.236  0.250  0.500  1.0
  O  O22  1  0.766  0.463  0.900  1.0
  O  O23  1  0.168  0.241  0.750  1.0
  O  O24  1  0.832  0.741  0.750  1.0
  O  O25  1  0.236  0.250  0.000  1.0
  O  O26  1  0.766  0.037  0.100  1.0
  O  O27  1  0.234  0.537  0.100  1.0
[/CIF]
.