The structure described by LiVOF2 crystallizes in the triclinic P1 space group. There are eight inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(3), one O(6), one F(1), and one F(2) atom to form LiO2F2 tetrahedra that share  a cornercorner with one V(3)O2F4 octahedra,  a cornercorner with one V(7)O2F4 octahedra,  a cornercorner with one V(4)O3F3 octahedra,  a cornercorner with one V(5)O3F3 octahedra,  a cornercorner with one V(8)O4F2 octahedra, corners with two equivalent Li(2)O2F2 tetrahedra, and  an edgeedge with one V(2)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 26-72°. In the second Li site, Li(2) is bonded to one O(4), one O(7), one F(1), and one F(2) atom to form LiO2F2 tetrahedra that share  a cornercorner with one V(2)O2F4 octahedra,  a cornercorner with one V(6)O2F4 octahedra,  a cornercorner with one V(1)O3F3 octahedra,  a cornercorner with one V(5)O3F3 octahedra,  a cornercorner with one V(8)O4F2 octahedra, corners with two equivalent Li(1)O2F2 tetrahedra, and  an edgeedge with one V(3)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 24-73°. In the third Li site, Li(3) is bonded to one O(1), one F(3), one F(4), and one F(5) atom to form LiOF3 tetrahedra that share  a cornercorner with one V(2)O2F4 octahedra,  a cornercorner with one V(6)O2F4 octahedra,  a cornercorner with one V(1)O3F3 octahedra,  a cornercorner with one V(4)O3F3 octahedra,  a cornercorner with one V(5)O3F3 octahedra, corners with two equivalent Li(4)O2F2 tetrahedra, and  an edgeedge with one V(7)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 23-76°. In the fourth Li site, Li(4) is bonded to one O(2), one O(5), one F(3), and one F(4) atom to form LiO2F2 tetrahedra that share  a cornercorner with one V(3)O2F4 octahedra,  a cornercorner with one V(7)O2F4 octahedra,  a cornercorner with one V(1)O3F3 octahedra,  a cornercorner with one V(4)O3F3 octahedra,  a cornercorner with one V(8)O4F2 octahedra, corners with two equivalent Li(3)OF3 tetrahedra, and  an edgeedge with one V(6)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 24-74°. In the fifth Li site, Li(5) is bonded to one F(10), one F(15), one F(7), and one F(9) atom to form LiF4 tetrahedra that share  a cornercorner with one V(2)O2F4 octahedra,  a cornercorner with one V(6)O2F4 octahedra,  a cornercorner with one V(1)O3F3 octahedra,  a cornercorner with one V(4)O3F3 octahedra,  a cornercorner with one V(5)O3F3 octahedra, corners with two equivalent Li(6)F4 tetrahedra, and  an edgeedge with one V(7)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 17-63°. In the sixth Li site, Li(6) is bonded to one F(10), one F(16), one F(8), and one F(9) atom to form LiF4 tetrahedra that share  a cornercorner with one V(3)O2F4 octahedra,  a cornercorner with one V(7)O2F4 octahedra,  a cornercorner with one V(1)O3F3 octahedra,  a cornercorner with one V(4)O3F3 octahedra,  a cornercorner with one V(8)O4F2 octahedra, corners with two equivalent Li(5)F4 tetrahedra, and  an edgeedge with one V(6)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 26-62°. In the seventh Li site, Li(7) is bonded to one O(8), one F(11), one F(12), and one F(13) atom to form LiOF3 tetrahedra that share  a cornercorner with one V(3)O2F4 octahedra,  a cornercorner with one V(7)O2F4 octahedra,  a cornercorner with one V(4)O3F3 octahedra,  a cornercorner with one V(5)O3F3 octahedra,  a cornercorner with one V(8)O4F2 octahedra, corners with two equivalent Li(8)F4 tetrahedra, and  an edgeedge with one V(2)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 25-65°. In the eighth Li site, Li(8) is bonded to one F(11), one F(12), one F(14), and one F(6) atom to form LiF4 tetrahedra that share  a cornercorner with one V(2)O2F4 octahedra,  a cornercorner with one V(6)O2F4 octahedra,  a cornercorner with one V(1)O3F3 octahedra,  a cornercorner with one V(5)O3F3 octahedra,  a cornercorner with one V(8)O4F2 octahedra, corners with two equivalent Li(7)OF3 tetrahedra, and  an edgeedge with one V(3)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 29-65°. There are eight inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(2), one O(4), one F(14), one F(15), and one F(16) atom to form distorted VO3F3 octahedra that share  a cornercorner with one Li(5)F4 tetrahedra,  a cornercorner with one Li(6)F4 tetrahedra,  a cornercorner with one Li(8)F4 tetrahedra,  a cornercorner with one Li(2)O2F2 tetrahedra,  a cornercorner with one Li(4)O2F2 tetrahedra,  a cornercorner with one Li(3)OF3 tetrahedra,  an edgeedge with one V(2)O2F4 octahedra, edges with two equivalent V(3)O2F4 octahedra, and edges with two equivalent V(4)O3F3 octahedra. In the second V site, V(2) is bonded to one O(1), one O(3), one F(1), one F(11), one F(13), and one F(15) atom to form distorted VO2F4 octahedra that share  a cornercorner with one Li(5)F4 tetrahedra,  a cornercorner with one Li(8)F4 tetrahedra,  a cornercorner with one Li(2)O2F2 tetrahedra,  a cornercorner with one Li(3)OF3 tetrahedra,  an edgeedge with one V(1)O3F3 octahedra, edges with two equivalent V(4)O3F3 octahedra,  an edgeedge with one Li(1)O2F2 tetrahedra, and  an edgeedge with one Li(7)OF3 tetrahedra. In the third V site, V(3) is bonded to one O(2), one O(4), one F(12), one F(14), one F(16), and one F(2) atom to form distorted VO2F4 octahedra that share  a cornercorner with one Li(6)F4 tetrahedra,  a cornercorner with one Li(1)O2F2 tetrahedra,  a cornercorner with one Li(4)O2F2 tetrahedra,  a cornercorner with one Li(7)OF3 tetrahedra,  an edgeedge with one V(4)O3F3 octahedra, edges with two equivalent V(1)O3F3 octahedra,  an edgeedge with one Li(8)F4 tetrahedra, and  an edgeedge with one Li(2)O2F2 tetrahedra. In the fourth V site, V(4) is bonded to one O(1), one O(2), one O(3), one F(13), one F(15), and one F(16) atom to form distorted VO3F3 octahedra that share  a cornercorner with one Li(5)F4 tetrahedra,  a cornercorner with one Li(6)F4 tetrahedra,  a cornercorner with one Li(1)O2F2 tetrahedra,  a cornercorner with one Li(4)O2F2 tetrahedra,  a cornercorner with one Li(3)OF3 tetrahedra,  a cornercorner with one Li(7)OF3 tetrahedra,  an edgeedge with one V(3)O2F4 octahedra, edges with two equivalent V(2)O2F4 octahedra, and edges with two equivalent V(1)O3F3 octahedra. In the fifth V site, V(5) is bonded to one O(6), one O(7), one O(8), one F(5), one F(6), and one F(7) atom to form VO3F3 octahedra that share  a cornercorner with one Li(5)F4 tetrahedra,  a cornercorner with one Li(8)F4 tetrahedra,  a cornercorner with one Li(1)O2F2 tetrahedra,  a cornercorner with one Li(2)O2F2 tetrahedra,  a cornercorner with one Li(3)OF3 tetrahedra,  a cornercorner with one Li(7)OF3 tetrahedra,  an edgeedge with one V(6)O2F4 octahedra, edges with two equivalent V(7)O2F4 octahedra, and edges with two equivalent V(8)O4F2 octahedra. In the sixth V site, V(6) is bonded to one O(5), one O(7), one F(3), one F(6), one F(8), and one F(9) atom to form distorted VO2F4 octahedra that share  a cornercorner with one Li(5)F4 tetrahedra,  a cornercorner with one Li(8)F4 tetrahedra,  a cornercorner with one Li(2)O2F2 tetrahedra,  a cornercorner with one Li(3)OF3 tetrahedra,  an edgeedge with one V(5)O3F3 octahedra, edges with two equivalent V(8)O4F2 octahedra,  an edgeedge with one Li(6)F4 tetrahedra, and  an edgeedge with one Li(4)O2F2 tetrahedra. In the seventh V site, V(7) is bonded to one O(6), one O(8), one F(10), one F(4), one F(5), and one F(7) atom to form distorted VO2F4 octahedra that share  a cornercorner with one Li(6)F4 tetrahedra,  a cornercorner with one Li(1)O2F2 tetrahedra,  a cornercorner with one Li(4)O2F2 tetrahedra,  a cornercorner with one Li(7)OF3 tetrahedra,  an edgeedge with one V(8)O4F2 octahedra, edges with two equivalent V(5)O3F3 octahedra,  an edgeedge with one Li(5)F4 tetrahedra, and  an edgeedge with one Li(3)OF3 tetrahedra. In the eighth V site, V(8) is bonded to one O(5), one O(6), one O(7), one O(8), one F(6), and one F(8) atom to form VO4F2 octahedra that share  a cornercorner with one Li(6)F4 tetrahedra,  a cornercorner with one Li(8)F4 tetrahedra,  a cornercorner with one Li(1)O2F2 tetrahedra,  a cornercorner with one Li(2)O2F2 tetrahedra,  a cornercorner with one Li(4)O2F2 tetrahedra,  a cornercorner with one Li(7)OF3 tetrahedra,  an edgeedge with one V(7)O2F4 octahedra, edges with two equivalent V(6)O2F4 octahedra, and edges with two equivalent V(5)O3F3 octahedra. There are eight inequivalent O sites. In the first O site, O(1) is bonded to one Li(3), one V(1), one V(2), and one V(4) atom to form corner-sharing OLiV3 tetrahedra. In the second O site, O(2) is bonded to one Li(4), one V(1), one V(3), and one V(4) atom to form corner-sharing OLiV3 tetrahedra. In the third O site, O(3) is bonded in a distorted T-shaped geometry to one Li(1), one V(2), and one V(4) atom. In the fourth O site, O(4) is bonded in a distorted T-shaped geometry to one Li(2), one V(1), and one V(3) atom. In the fifth O site, O(5) is bonded in a distorted T-shaped geometry to one Li(4), one V(6), and one V(8) atom. In the sixth O site, O(6) is bonded to one Li(1), one V(5), one V(7), and one V(8) atom to form corner-sharing OLiV3 tetrahedra. In the seventh O site, O(7) is bonded to one Li(2), one V(5), one V(6), and one V(8) atom to form corner-sharing OLiV3 tetrahedra. In the eighth O site, O(8) is bonded in a rectangular see-saw-like geometry to one Li(7), one V(5), one V(7), and one V(8) atom. There are sixteen inequivalent F sites. In the first F site, F(1) is bonded in a distorted T-shaped geometry to one Li(1), one Li(2), and one V(2) atom. In the second F site, F(2) is bonded in a distorted T-shaped geometry to one Li(1), one Li(2), and one V(3) atom. In the third F site, F(3) is bonded in a distorted T-shaped geometry to one Li(3), one Li(4), and one V(6) atom. In the fourth F site, F(4) is bonded in a distorted T-shaped geometry to one Li(3), one Li(4), and one V(7) atom. In the fifth F site, F(5) is bonded in a T-shaped geometry to one Li(3), one V(5), and one V(7) atom. In the sixth F site, F(6) is bonded in a rectangular see-saw-like geometry to one Li(8), one V(5), one V(6), and one V(8) atom. In the seventh F site, F(7) is bonded in a T-shaped geometry to one Li(5), one V(5), and one V(7) atom. In the eighth F site, F(8) is bonded in a distorted T-shaped geometry to one Li(6), one V(6), and one V(8) atom. In the ninth F site, F(9) is bonded in a distorted trigonal non-coplanar geometry to one Li(5), one Li(6), and one V(6) atom. In the tenth F site, F(10) is bonded in a distorted T-shaped geometry to one Li(5), one Li(6), and one V(7) atom. In the eleventh F site, F(11) is bonded in a distorted trigonal non-coplanar geometry to one Li(7), one Li(8), and one V(2) atom. In the twelfth F site, F(12) is bonded in a distorted trigonal non-coplanar geometry to one Li(7), one Li(8), and one V(3) atom. In the thirteenth F site, F(13) is bonded in a distorted T-shaped geometry to one Li(7), one V(2), and one V(4) atom. In the fourteenth F site, F(14) is bonded in a distorted T-shaped geometry to one Li(8), one V(1), and one V(3) atom. In the fifteenth F site, F(15) is bonded in a rectangular see-saw-like geometry to one Li(5), one V(1), one V(2), and one V(4) atom. In the sixteenth F site, F(16) is bonded in a rectangular see-saw-like geometry to one Li(6), one V(1), one V(3), and one V(4) atom. is represented by the CIF card [CIF]
data_LiVOF2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.476
_cell_length_b   8.973
_cell_length_c   10.130
_cell_angle_alpha   90.385
_cell_angle_beta   90.200
_cell_angle_gamma   90.390
_symmetry_Int_Tables_number   1
_cell_volume   497.681
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.468  0.420  0.210  1.0
  Li  Li1  1  0.964  0.590  0.212  1.0
  Li  Li2  1  0.965  0.080  0.285  1.0
  Li  Li3  1  0.452  0.908  0.293  1.0
  Li  Li4  1  0.530  0.079  0.696  1.0
  Li  Li5  1  0.034  0.923  0.696  1.0
  Li  Li6  1  0.039  0.415  0.793  1.0
  Li  Li7  1  0.538  0.576  0.809  1.0
  V  V8  1  0.751  0.906  0.011  1.0
  V  V9  1  0.740  0.261  0.012  1.0
  V  V10  1  0.234  0.739  0.012  1.0
  V  V11  1  0.254  0.095  0.011  1.0
  V  V12  1  0.767  0.419  0.496  1.0
  V  V13  1  0.731  0.762  0.491  1.0
  V  V14  1  0.259  0.247  0.492  1.0
  V  V15  1  0.244  0.585  0.497  1.0
  O  O16  1  0.908  0.086  0.091  1.0
  O  O17  1  0.404  0.915  0.092  1.0
  O  O18  1  0.432  0.247  0.095  1.0
  O  O19  1  0.924  0.754  0.093  1.0
  O  O20  1  0.418  0.745  0.418  1.0
  O  O21  1  0.425  0.416  0.409  1.0
  O  O22  1  0.902  0.591  0.405  1.0
  O  O23  1  0.079  0.408  0.598  1.0
  F  F24  1  0.814  0.418  0.146  1.0
  F  F25  1  0.311  0.589  0.150  1.0
  F  F26  1  0.795  0.920  0.355  1.0
  F  F27  1  0.305  0.084  0.363  1.0
  F  F28  1  0.938  0.260  0.387  1.0
  F  F29  1  0.589  0.581  0.619  1.0
  F  F30  1  0.594  0.247  0.593  1.0
  F  F31  1  0.066  0.737  0.611  1.0
  F  F32  1  0.704  0.918  0.633  1.0
  F  F33  1  0.196  0.091  0.632  1.0
  F  F34  1  0.707  0.410  0.867  1.0
  F  F35  1  0.207  0.580  0.873  1.0
  F  F36  1  0.078  0.237  0.892  1.0
  F  F37  1  0.571  0.764  0.890  1.0
  F  F38  1  0.581  0.086  0.886  1.0
  F  F39  1  0.080  0.913  0.886  1.0
[/CIF]
.
The structure described by LiVOF2 crystallizes in the triclinic P1 space group. There are eight inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(3), one O(6), one F(1), and one F(2) atom to form LiO2F2 tetrahedra that share  a cornercorner with one V(3)O2F4 octahedra,  a cornercorner with one V(7)O2F4 octahedra,  a cornercorner with one V(4)O3F3 octahedra,  a cornercorner with one V(5)O3F3 octahedra,  a cornercorner with one V(8)O4F2 octahedra, corners with two equivalent Li(2)O2F2 tetrahedra, and  an edgeedge with one V(2)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 26-72°. In the second Li site, Li(2) is bonded to one O(4), one O(7), one F(1), and one F(2) atom to form LiO2F2 tetrahedra that share  a cornercorner with one V(2)O2F4 octahedra,  a cornercorner with one V(6)O2F4 octahedra,  a cornercorner with one V(1)O3F3 octahedra,  a cornercorner with one V(5)O3F3 octahedra,  a cornercorner with one V(8)O4F2 octahedra, corners with two equivalent Li(1)O2F2 tetrahedra, and  an edgeedge with one V(3)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 24-73°. In the third Li site, Li(3) is bonded to one O(1), one F(3), one F(4), and one F(5) atom to form LiOF3 tetrahedra that share  a cornercorner with one V(2)O2F4 octahedra,  a cornercorner with one V(6)O2F4 octahedra,  a cornercorner with one V(1)O3F3 octahedra,  a cornercorner with one V(4)O3F3 octahedra,  a cornercorner with one V(5)O3F3 octahedra, corners with two equivalent Li(4)O2F2 tetrahedra, and  an edgeedge with one V(7)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 23-76°. In the fourth Li site, Li(4) is bonded to one O(2), one O(5), one F(3), and one F(4) atom to form LiO2F2 tetrahedra that share  a cornercorner with one V(3)O2F4 octahedra,  a cornercorner with one V(7)O2F4 octahedra,  a cornercorner with one V(1)O3F3 octahedra,  a cornercorner with one V(4)O3F3 octahedra,  a cornercorner with one V(8)O4F2 octahedra, corners with two equivalent Li(3)OF3 tetrahedra, and  an edgeedge with one V(6)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 24-74°. In the fifth Li site, Li(5) is bonded to one F(10), one F(15), one F(7), and one F(9) atom to form LiF4 tetrahedra that share  a cornercorner with one V(2)O2F4 octahedra,  a cornercorner with one V(6)O2F4 octahedra,  a cornercorner with one V(1)O3F3 octahedra,  a cornercorner with one V(4)O3F3 octahedra,  a cornercorner with one V(5)O3F3 octahedra, corners with two equivalent Li(6)F4 tetrahedra, and  an edgeedge with one V(7)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 17-63°. In the sixth Li site, Li(6) is bonded to one F(10), one F(16), one F(8), and one F(9) atom to form LiF4 tetrahedra that share  a cornercorner with one V(3)O2F4 octahedra,  a cornercorner with one V(7)O2F4 octahedra,  a cornercorner with one V(1)O3F3 octahedra,  a cornercorner with one V(4)O3F3 octahedra,  a cornercorner with one V(8)O4F2 octahedra, corners with two equivalent Li(5)F4 tetrahedra, and  an edgeedge with one V(6)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 26-62°. In the seventh Li site, Li(7) is bonded to one O(8), one F(11), one F(12), and one F(13) atom to form LiOF3 tetrahedra that share  a cornercorner with one V(3)O2F4 octahedra,  a cornercorner with one V(7)O2F4 octahedra,  a cornercorner with one V(4)O3F3 octahedra,  a cornercorner with one V(5)O3F3 octahedra,  a cornercorner with one V(8)O4F2 octahedra, corners with two equivalent Li(8)F4 tetrahedra, and  an edgeedge with one V(2)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 25-65°. In the eighth Li site, Li(8) is bonded to one F(11), one F(12), one F(14), and one F(6) atom to form LiF4 tetrahedra that share  a cornercorner with one V(2)O2F4 octahedra,  a cornercorner with one V(6)O2F4 octahedra,  a cornercorner with one V(1)O3F3 octahedra,  a cornercorner with one V(5)O3F3 octahedra,  a cornercorner with one V(8)O4F2 octahedra, corners with two equivalent Li(7)OF3 tetrahedra, and  an edgeedge with one V(3)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 29-65°. There are eight inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(2), one O(4), one F(14), one F(15), and one F(16) atom to form distorted VO3F3 octahedra that share  a cornercorner with one Li(5)F4 tetrahedra,  a cornercorner with one Li(6)F4 tetrahedra,  a cornercorner with one Li(8)F4 tetrahedra,  a cornercorner with one Li(2)O2F2 tetrahedra,  a cornercorner with one Li(4)O2F2 tetrahedra,  a cornercorner with one Li(3)OF3 tetrahedra,  an edgeedge with one V(2)O2F4 octahedra, edges with two equivalent V(3)O2F4 octahedra, and edges with two equivalent V(4)O3F3 octahedra. In the second V site, V(2) is bonded to one O(1), one O(3), one F(1), one F(11), one F(13), and one F(15) atom to form distorted VO2F4 octahedra that share  a cornercorner with one Li(5)F4 tetrahedra,  a cornercorner with one Li(8)F4 tetrahedra,  a cornercorner with one Li(2)O2F2 tetrahedra,  a cornercorner with one Li(3)OF3 tetrahedra,  an edgeedge with one V(1)O3F3 octahedra, edges with two equivalent V(4)O3F3 octahedra,  an edgeedge with one Li(1)O2F2 tetrahedra, and  an edgeedge with one Li(7)OF3 tetrahedra. In the third V site, V(3) is bonded to one O(2), one O(4), one F(12), one F(14), one F(16), and one F(2) atom to form distorted VO2F4 octahedra that share  a cornercorner with one Li(6)F4 tetrahedra,  a cornercorner with one Li(1)O2F2 tetrahedra,  a cornercorner with one Li(4)O2F2 tetrahedra,  a cornercorner with one Li(7)OF3 tetrahedra,  an edgeedge with one V(4)O3F3 octahedra, edges with two equivalent V(1)O3F3 octahedra,  an edgeedge with one Li(8)F4 tetrahedra, and  an edgeedge with one Li(2)O2F2 tetrahedra. In the fourth V site, V(4) is bonded to one O(1), one O(2), one O(3), one F(13), one F(15), and one F(16) atom to form distorted VO3F3 octahedra that share  a cornercorner with one Li(5)F4 tetrahedra,  a cornercorner with one Li(6)F4 tetrahedra,  a cornercorner with one Li(1)O2F2 tetrahedra,  a cornercorner with one Li(4)O2F2 tetrahedra,  a cornercorner with one Li(3)OF3 tetrahedra,  a cornercorner with one Li(7)OF3 tetrahedra,  an edgeedge with one V(3)O2F4 octahedra, edges with two equivalent V(2)O2F4 octahedra, and edges with two equivalent V(1)O3F3 octahedra. In the fifth V site, V(5) is bonded to one O(6), one O(7), one O(8), one F(5), one F(6), and one F(7) atom to form VO3F3 octahedra that share  a cornercorner with one Li(5)F4 tetrahedra,  a cornercorner with one Li(8)F4 tetrahedra,  a cornercorner with one Li(1)O2F2 tetrahedra,  a cornercorner with one Li(2)O2F2 tetrahedra,  a cornercorner with one Li(3)OF3 tetrahedra,  a cornercorner with one Li(7)OF3 tetrahedra,  an edgeedge with one V(6)O2F4 octahedra, edges with two equivalent V(7)O2F4 octahedra, and edges with two equivalent V(8)O4F2 octahedra. In the sixth V site, V(6) is bonded to one O(5), one O(7), one F(3), one F(6), one F(8), and one F(9) atom to form distorted VO2F4 octahedra that share  a cornercorner with one Li(5)F4 tetrahedra,  a cornercorner with one Li(8)F4 tetrahedra,  a cornercorner with one Li(2)O2F2 tetrahedra,  a cornercorner with one Li(3)OF3 tetrahedra,  an edgeedge with one V(5)O3F3 octahedra, edges with two equivalent V(8)O4F2 octahedra,  an edgeedge with one Li(6)F4 tetrahedra, and  an edgeedge with one Li(4)O2F2 tetrahedra. In the seventh V site, V(7) is bonded to one O(6), one O(8), one F(10), one F(4), one F(5), and one F(7) atom to form distorted VO2F4 octahedra that share  a cornercorner with one Li(6)F4 tetrahedra,  a cornercorner with one Li(1)O2F2 tetrahedra,  a cornercorner with one Li(4)O2F2 tetrahedra,  a cornercorner with one Li(7)OF3 tetrahedra,  an edgeedge with one V(8)O4F2 octahedra, edges with two equivalent V(5)O3F3 octahedra,  an edgeedge with one Li(5)F4 tetrahedra, and  an edgeedge with one Li(3)OF3 tetrahedra. In the eighth V site, V(8) is bonded to one O(5), one O(6), one O(7), one O(8), one F(6), and one F(8) atom to form VO4F2 octahedra that share  a cornercorner with one Li(6)F4 tetrahedra,  a cornercorner with one Li(8)F4 tetrahedra,  a cornercorner with one Li(1)O2F2 tetrahedra,  a cornercorner with one Li(2)O2F2 tetrahedra,  a cornercorner with one Li(4)O2F2 tetrahedra,  a cornercorner with one Li(7)OF3 tetrahedra,  an edgeedge with one V(7)O2F4 octahedra, edges with two equivalent V(6)O2F4 octahedra, and edges with two equivalent V(5)O3F3 octahedra. There are eight inequivalent O sites. In the first O site, O(1) is bonded to one Li(3), one V(1), one V(2), and one V(4) atom to form corner-sharing OLiV3 tetrahedra. In the second O site, O(2) is bonded to one Li(4), one V(1), one V(3), and one V(4) atom to form corner-sharing OLiV3 tetrahedra. In the third O site, O(3) is bonded in a distorted T-shaped geometry to one Li(1), one V(2), and one V(4) atom. In the fourth O site, O(4) is bonded in a distorted T-shaped geometry to one Li(2), one V(1), and one V(3) atom. In the fifth O site, O(5) is bonded in a distorted T-shaped geometry to one Li(4), one V(6), and one V(8) atom. In the sixth O site, O(6) is bonded to one Li(1), one V(5), one V(7), and one V(8) atom to form corner-sharing OLiV3 tetrahedra. In the seventh O site, O(7) is bonded to one Li(2), one V(5), one V(6), and one V(8) atom to form corner-sharing OLiV3 tetrahedra. In the eighth O site, O(8) is bonded in a rectangular see-saw-like geometry to one Li(7), one V(5), one V(7), and one V(8) atom. There are sixteen inequivalent F sites. In the first F site, F(1) is bonded in a distorted T-shaped geometry to one Li(1), one Li(2), and one V(2) atom. In the second F site, F(2) is bonded in a distorted T-shaped geometry to one Li(1), one Li(2), and one V(3) atom. In the third F site, F(3) is bonded in a distorted T-shaped geometry to one Li(3), one Li(4), and one V(6) atom. In the fourth F site, F(4) is bonded in a distorted T-shaped geometry to one Li(3), one Li(4), and one V(7) atom. In the fifth F site, F(5) is bonded in a T-shaped geometry to one Li(3), one V(5), and one V(7) atom. In the sixth F site, F(6) is bonded in a rectangular see-saw-like geometry to one Li(8), one V(5), one V(6), and one V(8) atom. In the seventh F site, F(7) is bonded in a T-shaped geometry to one Li(5), one V(5), and one V(7) atom. In the eighth F site, F(8) is bonded in a distorted T-shaped geometry to one Li(6), one V(6), and one V(8) atom. In the ninth F site, F(9) is bonded in a distorted trigonal non-coplanar geometry to one Li(5), one Li(6), and one V(6) atom. In the tenth F site, F(10) is bonded in a distorted T-shaped geometry to one Li(5), one Li(6), and one V(7) atom. In the eleventh F site, F(11) is bonded in a distorted trigonal non-coplanar geometry to one Li(7), one Li(8), and one V(2) atom. In the twelfth F site, F(12) is bonded in a distorted trigonal non-coplanar geometry to one Li(7), one Li(8), and one V(3) atom. In the thirteenth F site, F(13) is bonded in a distorted T-shaped geometry to one Li(7), one V(2), and one V(4) atom. In the fourteenth F site, F(14) is bonded in a distorted T-shaped geometry to one Li(8), one V(1), and one V(3) atom. In the fifteenth F site, F(15) is bonded in a rectangular see-saw-like geometry to one Li(5), one V(1), one V(2), and one V(4) atom. In the sixteenth F site, F(16) is bonded in a rectangular see-saw-like geometry to one Li(6), one V(1), one V(3), and one V(4) atom. is represented by the CIF card [CIF]
data_LiVOF2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.476
_cell_length_b   8.973
_cell_length_c   10.130
_cell_angle_alpha   90.385
_cell_angle_beta   90.200
_cell_angle_gamma   90.390
_symmetry_Int_Tables_number   1
_cell_volume   497.681
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.468  0.420  0.210  1.0
  Li  Li1  1  0.964  0.590  0.212  1.0
  Li  Li2  1  0.965  0.080  0.285  1.0
  Li  Li3  1  0.452  0.908  0.293  1.0
  Li  Li4  1  0.530  0.079  0.696  1.0
  Li  Li5  1  0.034  0.923  0.696  1.0
  Li  Li6  1  0.039  0.415  0.793  1.0
  Li  Li7  1  0.538  0.576  0.809  1.0
  V  V8  1  0.751  0.906  0.011  1.0
  V  V9  1  0.740  0.261  0.012  1.0
  V  V10  1  0.234  0.739  0.012  1.0
  V  V11  1  0.254  0.095  0.011  1.0
  V  V12  1  0.767  0.419  0.496  1.0
  V  V13  1  0.731  0.762  0.491  1.0
  V  V14  1  0.259  0.247  0.492  1.0
  V  V15  1  0.244  0.585  0.497  1.0
  O  O16  1  0.908  0.086  0.091  1.0
  O  O17  1  0.404  0.915  0.092  1.0
  O  O18  1  0.432  0.247  0.095  1.0
  O  O19  1  0.924  0.754  0.093  1.0
  O  O20  1  0.418  0.745  0.418  1.0
  O  O21  1  0.425  0.416  0.409  1.0
  O  O22  1  0.902  0.591  0.405  1.0
  O  O23  1  0.079  0.408  0.598  1.0
  F  F24  1  0.814  0.418  0.146  1.0
  F  F25  1  0.311  0.589  0.150  1.0
  F  F26  1  0.795  0.920  0.355  1.0
  F  F27  1  0.305  0.084  0.363  1.0
  F  F28  1  0.938  0.260  0.387  1.0
  F  F29  1  0.589  0.581  0.619  1.0
  F  F30  1  0.594  0.247  0.593  1.0
  F  F31  1  0.066  0.737  0.611  1.0
  F  F32  1  0.704  0.918  0.633  1.0
  F  F33  1  0.196  0.091  0.632  1.0
  F  F34  1  0.707  0.410  0.867  1.0
  F  F35  1  0.207  0.580  0.873  1.0
  F  F36  1  0.078  0.237  0.892  1.0
  F  F37  1  0.571  0.764  0.890  1.0
  F  F38  1  0.581  0.086  0.886  1.0
  F  F39  1  0.080  0.913  0.886  1.0
[/CIF]
.