The material described by CSbH3SOCl6 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four CSbH3SOCl6 clusters. C(1) is bonded in a trigonal non-coplanar geometry to one H(1), one H(2), one H(3), and one S(1) atom. Sb(1) is bonded in an octahedral geometry to one O(1), one Cl(1), one Cl(2), one Cl(3), one Cl(5), and one Cl(6) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. S(1) is bonded in a 3-coordinate geometry to one C(1), one O(1), and one Cl(4) atom. O(1) is bonded in a bent 120 degrees geometry to one Sb(1) and one S(1) atom. There are six inequivalent Cl sites. In the first Cl site, Cl(6) is bonded in a single-bond geometry to one Sb(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Sb(1) atom. In the third Cl site, Cl(2) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth Cl site, Cl(3) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth Cl site, Cl(4) is bonded in a single-bond geometry to one S(1) atom. In the sixth Cl site, Cl(5) is bonded in a single-bond geometry to one Sb(1) atom. is represented by the CIF card [CIF]
data_SbH3CSCl6O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   20.166
_cell_length_b   6.774
_cell_length_c   10.609
_cell_angle_alpha   60.362
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1259.624
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.625  0.050  0.285  1.0
  Sb  Sb1  1  0.125  0.950  0.215  1.0
  Sb  Sb2  1  0.375  0.950  0.715  1.0
  Sb  Sb3  1  0.875  0.050  0.785  1.0
  H  H4  1  0.137  0.039  0.707  1.0
  H  H5  1  0.943  0.961  0.369  1.0
  H  H6  1  0.637  0.961  0.793  1.0
  H  H7  1  0.118  0.255  0.524  1.0
  H  H8  1  0.443  0.039  0.131  1.0
  H  H9  1  0.863  0.961  0.293  1.0
  H  H10  1  0.363  0.039  0.207  1.0
  H  H11  1  0.882  0.745  0.476  1.0
  H  H12  1  0.382  0.255  0.024  1.0
  H  H13  1  0.557  0.961  0.869  1.0
  H  H14  1  0.618  0.745  0.976  1.0
  H  H15  1  0.057  0.039  0.631  1.0
  C  C16  1  0.890  0.922  0.392  1.0
  C  C17  1  0.390  0.078  0.108  1.0
  C  C18  1  0.610  0.922  0.892  1.0
  C  C19  1  0.110  0.078  0.608  1.0
  S  S20  1  0.644  0.090  0.962  1.0
  S  S21  1  0.856  0.090  0.462  1.0
  S  S22  1  0.356  0.910  0.038  1.0
  S  S23  1  0.144  0.910  0.538  1.0
  Cl  Cl24  1  0.656  0.046  0.502  1.0
  Cl  Cl25  1  0.344  0.954  0.498  1.0
  Cl  Cl26  1  0.207  0.668  0.360  1.0
  Cl  Cl27  1  0.541  0.774  0.391  1.0
  Cl  Cl28  1  0.793  0.332  0.640  1.0
  Cl  Cl29  1  0.624  0.406  0.791  1.0
  Cl  Cl30  1  0.293  0.668  0.860  1.0
  Cl  Cl31  1  0.545  0.344  0.214  1.0
  Cl  Cl32  1  0.707  0.332  0.140  1.0
  Cl  Cl33  1  0.703  0.763  0.317  1.0
  Cl  Cl34  1  0.459  0.226  0.609  1.0
  Cl  Cl35  1  0.376  0.594  0.209  1.0
  Cl  Cl36  1  0.297  0.237  0.683  1.0
  Cl  Cl37  1  0.045  0.656  0.286  1.0
  Cl  Cl38  1  0.203  0.237  0.183  1.0
  Cl  Cl39  1  0.844  0.046  0.002  1.0
  Cl  Cl40  1  0.455  0.656  0.786  1.0
  Cl  Cl41  1  0.797  0.763  0.817  1.0
  Cl  Cl42  1  0.959  0.774  0.891  1.0
  Cl  Cl43  1  0.876  0.406  0.291  1.0
  Cl  Cl44  1  0.156  0.954  0.998  1.0
  Cl  Cl45  1  0.041  0.226  0.109  1.0
  Cl  Cl46  1  0.124  0.594  0.709  1.0
  Cl  Cl47  1  0.955  0.344  0.714  1.0
  O  O48  1  0.095  0.952  0.417  1.0
  O  O49  1  0.905  0.048  0.583  1.0
  O  O50  1  0.595  0.048  0.083  1.0
  O  O51  1  0.405  0.952  0.917  1.0
[/CIF]
.
The material described by CSbH3SOCl6 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four CSbH3SOCl6 clusters. C(1) is bonded in a trigonal non-coplanar geometry to one H(1), one H(2), one H(3), and one S(1) atom. Sb(1) is bonded in an octahedral geometry to one O(1), one Cl(1), one Cl(2), one Cl(3), one Cl(5), and one Cl(6) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. S(1) is bonded in a 3-coordinate geometry to one C(1), one O(1), and one Cl(4) atom. O(1) is bonded in a bent 120 degrees geometry to one Sb(1) and one S(1) atom. There are six inequivalent Cl sites. In the first Cl site, Cl(6) is bonded in a single-bond geometry to one Sb(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Sb(1) atom. In the third Cl site, Cl(2) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth Cl site, Cl(3) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth Cl site, Cl(4) is bonded in a single-bond geometry to one S(1) atom. In the sixth Cl site, Cl(5) is bonded in a single-bond geometry to one Sb(1) atom. is represented by the CIF card [CIF]
data_SbH3CSCl6O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   20.166
_cell_length_b   6.774
_cell_length_c   10.609
_cell_angle_alpha   60.362
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1259.624
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.625  0.050  0.285  1.0
  Sb  Sb1  1  0.125  0.950  0.215  1.0
  Sb  Sb2  1  0.375  0.950  0.715  1.0
  Sb  Sb3  1  0.875  0.050  0.785  1.0
  H  H4  1  0.137  0.039  0.707  1.0
  H  H5  1  0.943  0.961  0.369  1.0
  H  H6  1  0.637  0.961  0.793  1.0
  H  H7  1  0.118  0.255  0.524  1.0
  H  H8  1  0.443  0.039  0.131  1.0
  H  H9  1  0.863  0.961  0.293  1.0
  H  H10  1  0.363  0.039  0.207  1.0
  H  H11  1  0.882  0.745  0.476  1.0
  H  H12  1  0.382  0.255  0.024  1.0
  H  H13  1  0.557  0.961  0.869  1.0
  H  H14  1  0.618  0.745  0.976  1.0
  H  H15  1  0.057  0.039  0.631  1.0
  C  C16  1  0.890  0.922  0.392  1.0
  C  C17  1  0.390  0.078  0.108  1.0
  C  C18  1  0.610  0.922  0.892  1.0
  C  C19  1  0.110  0.078  0.608  1.0
  S  S20  1  0.644  0.090  0.962  1.0
  S  S21  1  0.856  0.090  0.462  1.0
  S  S22  1  0.356  0.910  0.038  1.0
  S  S23  1  0.144  0.910  0.538  1.0
  Cl  Cl24  1  0.656  0.046  0.502  1.0
  Cl  Cl25  1  0.344  0.954  0.498  1.0
  Cl  Cl26  1  0.207  0.668  0.360  1.0
  Cl  Cl27  1  0.541  0.774  0.391  1.0
  Cl  Cl28  1  0.793  0.332  0.640  1.0
  Cl  Cl29  1  0.624  0.406  0.791  1.0
  Cl  Cl30  1  0.293  0.668  0.860  1.0
  Cl  Cl31  1  0.545  0.344  0.214  1.0
  Cl  Cl32  1  0.707  0.332  0.140  1.0
  Cl  Cl33  1  0.703  0.763  0.317  1.0
  Cl  Cl34  1  0.459  0.226  0.609  1.0
  Cl  Cl35  1  0.376  0.594  0.209  1.0
  Cl  Cl36  1  0.297  0.237  0.683  1.0
  Cl  Cl37  1  0.045  0.656  0.286  1.0
  Cl  Cl38  1  0.203  0.237  0.183  1.0
  Cl  Cl39  1  0.844  0.046  0.002  1.0
  Cl  Cl40  1  0.455  0.656  0.786  1.0
  Cl  Cl41  1  0.797  0.763  0.817  1.0
  Cl  Cl42  1  0.959  0.774  0.891  1.0
  Cl  Cl43  1  0.876  0.406  0.291  1.0
  Cl  Cl44  1  0.156  0.954  0.998  1.0
  Cl  Cl45  1  0.041  0.226  0.109  1.0
  Cl  Cl46  1  0.124  0.594  0.709  1.0
  Cl  Cl47  1  0.955  0.344  0.714  1.0
  O  O48  1  0.095  0.952  0.417  1.0
  O  O49  1  0.905  0.048  0.583  1.0
  O  O50  1  0.595  0.048  0.083  1.0
  O  O51  1  0.405  0.952  0.917  1.0
[/CIF]
.