The structure described by HSCs crystallizes in the tetragonal I4/m space group. There are two inequivalent Cs sites. In the first Cs site, Cs(1) is bonded in a 8-coordinate geometry to four equivalent H(1) and four equivalent S(1) atoms. In the second Cs site, Cs(2) is bonded in a 8-coordinate geometry to four equivalent H(1) and four equivalent S(1) atoms. H(1) is bonded in a distorted single-bond geometry to two equivalent Cs(1), two equivalent Cs(2), and one S(1) atom. S(1) is bonded in a single-bond geometry to two equivalent Cs(1), two equivalent Cs(2), and one H(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CsHS
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.451
_cell_length_b   7.451
_cell_length_c   7.451
_cell_angle_alpha   112.215
_cell_angle_beta   112.215
_cell_angle_gamma   104.114
_symmetry_Int_Tables_number   1
_cell_volume   316.371
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.250  0.750  0.500  1.0
  Cs  Cs1  1  0.267  0.267  0.000  1.0
  Cs  Cs2  1  0.733  0.733  0.000  1.0
  Cs  Cs3  1  0.750  0.250  0.500  1.0
  H  H4  1  0.086  0.242  0.328  1.0
  H  H5  1  0.242  0.914  0.156  1.0
  H  H6  1  0.758  0.086  0.844  1.0
  H  H7  1  0.914  0.758  0.672  1.0
  S  S8  1  0.242  0.751  0.993  1.0
  S  S9  1  0.249  0.242  0.490  1.0
  S  S10  1  0.751  0.758  0.510  1.0
  S  S11  1  0.758  0.249  0.007  1.0
[/CIF]
.
The structure described by HSCs crystallizes in the tetragonal I4/m space group. There are two inequivalent Cs sites. In the first Cs site, Cs(1) is bonded in a 8-coordinate geometry to four equivalent H(1) and four equivalent S(1) atoms. In the second Cs site, Cs(2) is bonded in a 8-coordinate geometry to four equivalent H(1) and four equivalent S(1) atoms. H(1) is bonded in a distorted single-bond geometry to two equivalent Cs(1), two equivalent Cs(2), and one S(1) atom. S(1) is bonded in a single-bond geometry to two equivalent Cs(1), two equivalent Cs(2), and one H(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CsHS
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.451
_cell_length_b   7.451
_cell_length_c   7.451
_cell_angle_alpha   112.215
_cell_angle_beta   112.215
_cell_angle_gamma   104.114
_symmetry_Int_Tables_number   1
_cell_volume   316.371
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.250  0.750  0.500  1.0
  Cs  Cs1  1  0.267  0.267  0.000  1.0
  Cs  Cs2  1  0.733  0.733  0.000  1.0
  Cs  Cs3  1  0.750  0.250  0.500  1.0
  H  H4  1  0.086  0.242  0.328  1.0
  H  H5  1  0.242  0.914  0.156  1.0
  H  H6  1  0.758  0.086  0.844  1.0
  H  H7  1  0.914  0.758  0.672  1.0
  S  S8  1  0.242  0.751  0.993  1.0
  S  S9  1  0.249  0.242  0.490  1.0
  S  S10  1  0.751  0.758  0.510  1.0
  S  S11  1  0.758  0.249  0.007  1.0
[/CIF]
.