The material structure described by Rh3Ga5 is Magnesium tetraboride-like structured and crystallizes in the triclinic P-1 space group. There are three inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a 8-coordinate geometry to one Ga(2), one Ga(3), one Ga(5), two equivalent Ga(1), and three equivalent Ga(4) atoms. In the second Rh site, Rh(2) is bonded in a 8-coordinate geometry to one Ga(5), two equivalent Ga(3), two equivalent Ga(4), and three equivalent Ga(2) atoms. In the third Rh site, Rh(3) is bonded in a 8-coordinate geometry to one Ga(4), two equivalent Ga(1), two equivalent Ga(3), and three equivalent Ga(5) atoms. There are five inequivalent Ga sites. In the first Ga site, Ga(1) is bonded in a 4-coordinate geometry to two equivalent Rh(1) and two equivalent Rh(3) atoms. In the second Ga site, Ga(2) is bonded in a 4-coordinate geometry to one Rh(1) and three equivalent Rh(2) atoms. In the third Ga site, Ga(3) is bonded in a 5-coordinate geometry to one Rh(1), two equivalent Rh(2), and two equivalent Rh(3) atoms. In the fourth Ga site, Ga(4) is bonded in a 6-coordinate geometry to one Rh(3), two equivalent Rh(2), and three equivalent Rh(1) atoms. In the fifth Ga site, Ga(5) is bonded in a 5-coordinate geometry to one Rh(1), one Rh(2), and three equivalent Rh(3) atoms. is represented by the CIF card [CIF]
data_Ga5Rh3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.973
_cell_length_b   6.652
_cell_length_c   7.903
_cell_angle_alpha   100.918
_cell_angle_beta   104.642
_cell_angle_gamma   101.288
_symmetry_Int_Tables_number   1
_cell_volume   240.063
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.773  0.538  0.536  1.0
  Ga  Ga1  1  0.227  0.462  0.464  1.0
  Ga  Ga2  1  0.917  0.178  0.051  1.0
  Ga  Ga3  1  0.083  0.822  0.949  1.0
  Ga  Ga4  1  0.549  0.140  0.272  1.0
  Ga  Ga5  1  0.451  0.860  0.728  1.0
  Ga  Ga6  1  0.682  0.473  0.873  1.0
  Ga  Ga7  1  0.318  0.527  0.127  1.0
  Ga  Ga8  1  0.041  0.905  0.348  1.0
  Ga  Ga9  1  0.959  0.095  0.652  1.0
  Rh  Rh10  1  0.847  0.513  0.224  1.0
  Rh  Rh11  1  0.153  0.487  0.776  1.0
  Rh  Rh12  1  0.636  0.827  0.050  1.0
  Rh  Rh13  1  0.364  0.173  0.950  1.0
  Rh  Rh14  1  0.547  0.805  0.422  1.0
  Rh  Rh15  1  0.453  0.195  0.578  1.0
[/CIF]
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The material structure described by Rh3Ga5 is Magnesium tetraboride-like structured and crystallizes in the triclinic P-1 space group. There are three inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a 8-coordinate geometry to one Ga(2), one Ga(3), one Ga(5), two equivalent Ga(1), and three equivalent Ga(4) atoms. In the second Rh site, Rh(2) is bonded in a 8-coordinate geometry to one Ga(5), two equivalent Ga(3), two equivalent Ga(4), and three equivalent Ga(2) atoms. In the third Rh site, Rh(3) is bonded in a 8-coordinate geometry to one Ga(4), two equivalent Ga(1), two equivalent Ga(3), and three equivalent Ga(5) atoms. There are five inequivalent Ga sites. In the first Ga site, Ga(1) is bonded in a 4-coordinate geometry to two equivalent Rh(1) and two equivalent Rh(3) atoms. In the second Ga site, Ga(2) is bonded in a 4-coordinate geometry to one Rh(1) and three equivalent Rh(2) atoms. In the third Ga site, Ga(3) is bonded in a 5-coordinate geometry to one Rh(1), two equivalent Rh(2), and two equivalent Rh(3) atoms. In the fourth Ga site, Ga(4) is bonded in a 6-coordinate geometry to one Rh(3), two equivalent Rh(2), and three equivalent Rh(1) atoms. In the fifth Ga site, Ga(5) is bonded in a 5-coordinate geometry to one Rh(1), one Rh(2), and three equivalent Rh(3) atoms. is represented by the CIF card [CIF]
data_Ga5Rh3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.973
_cell_length_b   6.652
_cell_length_c   7.903
_cell_angle_alpha   100.918
_cell_angle_beta   104.642
_cell_angle_gamma   101.288
_symmetry_Int_Tables_number   1
_cell_volume   240.063
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.773  0.538  0.536  1.0
  Ga  Ga1  1  0.227  0.462  0.464  1.0
  Ga  Ga2  1  0.917  0.178  0.051  1.0
  Ga  Ga3  1  0.083  0.822  0.949  1.0
  Ga  Ga4  1  0.549  0.140  0.272  1.0
  Ga  Ga5  1  0.451  0.860  0.728  1.0
  Ga  Ga6  1  0.682  0.473  0.873  1.0
  Ga  Ga7  1  0.318  0.527  0.127  1.0
  Ga  Ga8  1  0.041  0.905  0.348  1.0
  Ga  Ga9  1  0.959  0.095  0.652  1.0
  Rh  Rh10  1  0.847  0.513  0.224  1.0
  Rh  Rh11  1  0.153  0.487  0.776  1.0
  Rh  Rh12  1  0.636  0.827  0.050  1.0
  Rh  Rh13  1  0.364  0.173  0.950  1.0
  Rh  Rh14  1  0.547  0.805  0.422  1.0
  Rh  Rh15  1  0.453  0.195  0.578  1.0
[/CIF]
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