The material structure described by PCl3 is Ammonia-like structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four phosphorus trichloride molecules. P(1) is bonded in a distorted trigonal non-coplanar geometry to one Cl(2) and two equivalent Cl(1) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one P(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one P(1) atom. is represented by the CIF file [CIF]
data_PCl3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.222
_cell_length_b   8.179
_cell_length_c   9.521
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   484.510
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.926  0.981  0.750  1.0
  P  P1  1  0.426  0.519  0.250  1.0
  P  P2  1  0.574  0.481  0.750  1.0
  P  P3  1  0.074  0.019  0.250  1.0
  Cl  Cl4  1  0.741  0.903  0.916  1.0
  Cl  Cl5  1  0.241  0.597  0.084  1.0
  Cl  Cl6  1  0.759  0.403  0.584  1.0
  Cl  Cl7  1  0.259  0.097  0.416  1.0
  Cl  Cl8  1  0.839  0.196  0.250  1.0
  Cl  Cl9  1  0.339  0.304  0.750  1.0
  Cl  Cl10  1  0.661  0.696  0.250  1.0
  Cl  Cl11  1  0.161  0.804  0.750  1.0
  Cl  Cl12  1  0.741  0.903  0.584  1.0
  Cl  Cl13  1  0.241  0.597  0.416  1.0
  Cl  Cl14  1  0.759  0.403  0.916  1.0
  Cl  Cl15  1  0.259  0.097  0.084  1.0
[/CIF]
.
The material structure described by PCl3 is Ammonia-like structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four phosphorus trichloride molecules. P(1) is bonded in a distorted trigonal non-coplanar geometry to one Cl(2) and two equivalent Cl(1) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one P(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one P(1) atom. is represented by the CIF file [CIF]
data_PCl3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.222
_cell_length_b   8.179
_cell_length_c   9.521
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   484.510
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.926  0.981  0.750  1.0
  P  P1  1  0.426  0.519  0.250  1.0
  P  P2  1  0.574  0.481  0.750  1.0
  P  P3  1  0.074  0.019  0.250  1.0
  Cl  Cl4  1  0.741  0.903  0.916  1.0
  Cl  Cl5  1  0.241  0.597  0.084  1.0
  Cl  Cl6  1  0.759  0.403  0.584  1.0
  Cl  Cl7  1  0.259  0.097  0.416  1.0
  Cl  Cl8  1  0.839  0.196  0.250  1.0
  Cl  Cl9  1  0.339  0.304  0.750  1.0
  Cl  Cl10  1  0.661  0.696  0.250  1.0
  Cl  Cl11  1  0.161  0.804  0.750  1.0
  Cl  Cl12  1  0.741  0.903  0.584  1.0
  Cl  Cl13  1  0.241  0.597  0.416  1.0
  Cl  Cl14  1  0.759  0.403  0.916  1.0
  Cl  Cl15  1  0.259  0.097  0.084  1.0
[/CIF]
.