The structure described by Li5Ti2V5O12 is beta Polonium-derived structured and crystallizes in the monoclinic C2 space group. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form LiO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Ti(1)O6 octahedra,  a cornercorner with one Ti(2)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one Ti(2)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(4)O6 octahedra, edges with three equivalent Li(2)O6 octahedra, and edges with three equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-7°. In the second Li site, Li(2) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form LiO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Ti(1)O6 octahedra,  a cornercorner with one Ti(2)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one Ti(2)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(4)O6 octahedra, edges with three equivalent Li(1)O6 octahedra, and edges with three equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-9°. In the third Li site, Li(3) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms to form LiO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent V(1)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent V(1)O6 octahedra, edges with three equivalent Ti(1)O6 octahedra, and edges with three equivalent V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-7°. There are two inequivalent Ti sites. In the first Ti site, Ti(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms to form TiO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent V(1)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent V(1)O6 octahedra, edges with three equivalent Li(3)O6 octahedra, and edges with three equivalent V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-5°. In the second Ti site, Ti(2) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms to form TiO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent V(1)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent V(1)O6 octahedra, edges with three equivalent V(2)O6 octahedra, and edges with three equivalent V(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-2°. There are four inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form VO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Ti(1)O6 octahedra,  a cornercorner with one Ti(2)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one Ti(2)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(4)O6 octahedra, edges with three equivalent Li(1)O6 octahedra, and edges with three equivalent Li(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-7°. In the second V site, V(2) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms to form VO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent V(1)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent V(1)O6 octahedra, edges with three equivalent Ti(2)O6 octahedra, and edges with three equivalent V(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-7°. In the third V site, V(3) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms to form VO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent V(1)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent V(1)O6 octahedra, edges with three equivalent Li(3)O6 octahedra, and edges with three equivalent Ti(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-7°. In the fourth V site, V(4) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms to form VO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent V(1)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent V(1)O6 octahedra, edges with three equivalent Ti(2)O6 octahedra, and edges with three equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-9°. There are six inequivalent O sites. In the first O site, O(5) is bonded to one Li(1), one Li(2), one Li(3), one Ti(1), one V(1), and one V(3) atom to form OLi3TiV2 octahedra that share  a cornercorner with one O(2)Li2TiV3 octahedra,  a cornercorner with one O(4)Li2TiV3 octahedra,  a cornercorner with one O(6)Li2TiV3 octahedra,  a cornercorner with one O(1)Li3TiV2 octahedra,  a cornercorner with one O(3)Li3TiV2 octahedra,  a cornercorner with one O(5)Li3TiV2 octahedra,  an edgeedge with one O(2)Li2TiV3 octahedra,  an edgeedge with one O(4)Li2TiV3 octahedra,  an edgeedge with one O(6)Li2TiV3 octahedra,  an edgeedge with one O(5)Li3TiV2 octahedra, edges with four equivalent O(1)Li3TiV2 octahedra, and edges with four equivalent O(3)Li3TiV2 octahedra. The corner-sharing octahedral tilt angles range from 1-5°. In the second O site, O(6) is bonded to one Li(1), one Li(2), one Ti(2), one V(1), one V(2), and one V(4) atom to form OLi2TiV3 octahedra that share  a cornercorner with one O(2)Li2TiV3 octahedra,  a cornercorner with one O(4)Li2TiV3 octahedra,  a cornercorner with one O(6)Li2TiV3 octahedra,  a cornercorner with one O(1)Li3TiV2 octahedra,  a cornercorner with one O(3)Li3TiV2 octahedra,  a cornercorner with one O(5)Li3TiV2 octahedra,  an edgeedge with one O(6)Li2TiV3 octahedra,  an edgeedge with one O(1)Li3TiV2 octahedra,  an edgeedge with one O(3)Li3TiV2 octahedra,  an edgeedge with one O(5)Li3TiV2 octahedra, edges with four equivalent O(2)Li2TiV3 octahedra, and edges with four equivalent O(4)Li2TiV3 octahedra. The corner-sharing octahedral tilt angles range from 0-7°. In the third O site, O(1) is bonded to one Li(1), one Li(2), one Li(3), one Ti(1), one V(1), and one V(3) atom to form OLi3TiV2 octahedra that share  a cornercorner with one O(2)Li2TiV3 octahedra,  a cornercorner with one O(4)Li2TiV3 octahedra,  a cornercorner with one O(6)Li2TiV3 octahedra,  a cornercorner with one O(1)Li3TiV2 octahedra,  a cornercorner with one O(3)Li3TiV2 octahedra,  a cornercorner with one O(5)Li3TiV2 octahedra,  an edgeedge with one O(2)Li2TiV3 octahedra,  an edgeedge with one O(4)Li2TiV3 octahedra,  an edgeedge with one O(6)Li2TiV3 octahedra,  an edgeedge with one O(1)Li3TiV2 octahedra, edges with four equivalent O(3)Li3TiV2 octahedra, and edges with four equivalent O(5)Li3TiV2 octahedra. The corner-sharing octahedral tilt angles range from 1-7°. In the fourth O site, O(2) is bonded to one Li(1), one Li(2), one Ti(2), one V(1), one V(2), and one V(4) atom to form OLi2TiV3 octahedra that share  a cornercorner with one O(2)Li2TiV3 octahedra,  a cornercorner with one O(4)Li2TiV3 octahedra,  a cornercorner with one O(6)Li2TiV3 octahedra,  a cornercorner with one O(1)Li3TiV2 octahedra,  a cornercorner with one O(3)Li3TiV2 octahedra,  a cornercorner with one O(5)Li3TiV2 octahedra,  an edgeedge with one O(2)Li2TiV3 octahedra,  an edgeedge with one O(1)Li3TiV2 octahedra,  an edgeedge with one O(3)Li3TiV2 octahedra,  an edgeedge with one O(5)Li3TiV2 octahedra, edges with four equivalent O(4)Li2TiV3 octahedra, and edges with four equivalent O(6)Li2TiV3 octahedra. The corner-sharing octahedral tilt angles range from 1-5°. In the fifth O site, O(3) is bonded to one Li(1), one Li(2), one Li(3), one Ti(1), one V(1), and one V(3) atom to form OLi3TiV2 octahedra that share  a cornercorner with one O(2)Li2TiV3 octahedra,  a cornercorner with one O(4)Li2TiV3 octahedra,  a cornercorner with one O(6)Li2TiV3 octahedra,  a cornercorner with one O(1)Li3TiV2 octahedra,  a cornercorner with one O(3)Li3TiV2 octahedra,  a cornercorner with one O(5)Li3TiV2 octahedra,  an edgeedge with one O(2)Li2TiV3 octahedra,  an edgeedge with one O(4)Li2TiV3 octahedra,  an edgeedge with one O(6)Li2TiV3 octahedra,  an edgeedge with one O(3)Li3TiV2 octahedra, edges with four equivalent O(1)Li3TiV2 octahedra, and edges with four equivalent O(5)Li3TiV2 octahedra. The corner-sharing octahedral tilt angles range from 2-5°. In the sixth O site, O(4) is bonded to one Li(1), one Li(2), one Ti(2), one V(1), one V(2), and one V(4) atom to form OLi2TiV3 octahedra that share  a cornercorner with one O(2)Li2TiV3 octahedra,  a cornercorner with one O(4)Li2TiV3 octahedra,  a cornercorner with one O(6)Li2TiV3 octahedra,  a cornercorner with one O(1)Li3TiV2 octahedra,  a cornercorner with one O(3)Li3TiV2 octahedra,  a cornercorner with one O(5)Li3TiV2 octahedra,  an edgeedge with one O(4)Li2TiV3 octahedra,  an edgeedge with one O(1)Li3TiV2 octahedra,  an edgeedge with one O(3)Li3TiV2 octahedra,  an edgeedge with one O(5)Li3TiV2 octahedra, edges with four equivalent O(2)Li2TiV3 octahedra, and edges with four equivalent O(6)Li2TiV3 octahedra. The corner-sharing octahedral tilt angles range from 0-7°. is represented by the CIF card [CIF]
data_Li5Ti2V5O12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.217
_cell_length_b   5.217
_cell_length_c   10.049
_cell_angle_alpha   84.583
_cell_angle_beta   95.417
_cell_angle_gamma   59.122
_symmetry_Int_Tables_number   1
_cell_volume   230.438
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.159  0.671  0.505  1.0
  Li  Li1  1  0.325  0.835  0.995  1.0
  Li  Li2  1  0.671  0.159  0.995  1.0
  Li  Li3  1  0.835  0.325  0.505  1.0
  Li  Li4  1  0.920  0.920  0.750  1.0
  Ti  Ti5  1  0.252  0.252  0.750  1.0
  Ti  Ti6  1  0.751  0.751  0.250  1.0
  V  V7  1  0.997  0.506  0.996  1.0
  V  V8  1  0.506  0.997  0.504  1.0
  V  V9  1  0.422  0.422  0.250  1.0
  V  V10  1  0.580  0.580  0.750  1.0
  V  V11  1  0.083  0.083  0.250  1.0
  O  O12  1  0.966  0.220  0.865  1.0
  O  O13  1  0.220  0.966  0.635  1.0
  O  O14  1  0.118  0.387  0.368  1.0
  O  O15  1  0.387  0.118  0.132  1.0
  O  O16  1  0.300  0.517  0.866  1.0
  O  O17  1  0.517  0.300  0.634  1.0
  O  O18  1  0.485  0.705  0.371  1.0
  O  O19  1  0.705  0.485  0.129  1.0
  O  O20  1  0.604  0.881  0.864  1.0
  O  O21  1  0.881  0.604  0.636  1.0
  O  O22  1  0.796  0.022  0.372  1.0
  O  O23  1  0.022  0.796  0.128  1.0
[/CIF]
.
The structure described by Li5Ti2V5O12 is beta Polonium-derived structured and crystallizes in the monoclinic C2 space group. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form LiO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Ti(1)O6 octahedra,  a cornercorner with one Ti(2)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one Ti(2)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(4)O6 octahedra, edges with three equivalent Li(2)O6 octahedra, and edges with three equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-7°. In the second Li site, Li(2) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form LiO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Ti(1)O6 octahedra,  a cornercorner with one Ti(2)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one Ti(2)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(4)O6 octahedra, edges with three equivalent Li(1)O6 octahedra, and edges with three equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-9°. In the third Li site, Li(3) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms to form LiO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent V(1)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent V(1)O6 octahedra, edges with three equivalent Ti(1)O6 octahedra, and edges with three equivalent V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-7°. There are two inequivalent Ti sites. In the first Ti site, Ti(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms to form TiO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent V(1)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent V(1)O6 octahedra, edges with three equivalent Li(3)O6 octahedra, and edges with three equivalent V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-5°. In the second Ti site, Ti(2) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms to form TiO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent V(1)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent V(1)O6 octahedra, edges with three equivalent V(2)O6 octahedra, and edges with three equivalent V(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-2°. There are four inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form VO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Ti(1)O6 octahedra,  a cornercorner with one Ti(2)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one Ti(2)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(4)O6 octahedra, edges with three equivalent Li(1)O6 octahedra, and edges with three equivalent Li(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-7°. In the second V site, V(2) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms to form VO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent V(1)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent V(1)O6 octahedra, edges with three equivalent Ti(2)O6 octahedra, and edges with three equivalent V(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-7°. In the third V site, V(3) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms to form VO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent V(1)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent V(1)O6 octahedra, edges with three equivalent Li(3)O6 octahedra, and edges with three equivalent Ti(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-7°. In the fourth V site, V(4) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms to form VO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent V(1)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent V(1)O6 octahedra, edges with three equivalent Ti(2)O6 octahedra, and edges with three equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-9°. There are six inequivalent O sites. In the first O site, O(5) is bonded to one Li(1), one Li(2), one Li(3), one Ti(1), one V(1), and one V(3) atom to form OLi3TiV2 octahedra that share  a cornercorner with one O(2)Li2TiV3 octahedra,  a cornercorner with one O(4)Li2TiV3 octahedra,  a cornercorner with one O(6)Li2TiV3 octahedra,  a cornercorner with one O(1)Li3TiV2 octahedra,  a cornercorner with one O(3)Li3TiV2 octahedra,  a cornercorner with one O(5)Li3TiV2 octahedra,  an edgeedge with one O(2)Li2TiV3 octahedra,  an edgeedge with one O(4)Li2TiV3 octahedra,  an edgeedge with one O(6)Li2TiV3 octahedra,  an edgeedge with one O(5)Li3TiV2 octahedra, edges with four equivalent O(1)Li3TiV2 octahedra, and edges with four equivalent O(3)Li3TiV2 octahedra. The corner-sharing octahedral tilt angles range from 1-5°. In the second O site, O(6) is bonded to one Li(1), one Li(2), one Ti(2), one V(1), one V(2), and one V(4) atom to form OLi2TiV3 octahedra that share  a cornercorner with one O(2)Li2TiV3 octahedra,  a cornercorner with one O(4)Li2TiV3 octahedra,  a cornercorner with one O(6)Li2TiV3 octahedra,  a cornercorner with one O(1)Li3TiV2 octahedra,  a cornercorner with one O(3)Li3TiV2 octahedra,  a cornercorner with one O(5)Li3TiV2 octahedra,  an edgeedge with one O(6)Li2TiV3 octahedra,  an edgeedge with one O(1)Li3TiV2 octahedra,  an edgeedge with one O(3)Li3TiV2 octahedra,  an edgeedge with one O(5)Li3TiV2 octahedra, edges with four equivalent O(2)Li2TiV3 octahedra, and edges with four equivalent O(4)Li2TiV3 octahedra. The corner-sharing octahedral tilt angles range from 0-7°. In the third O site, O(1) is bonded to one Li(1), one Li(2), one Li(3), one Ti(1), one V(1), and one V(3) atom to form OLi3TiV2 octahedra that share  a cornercorner with one O(2)Li2TiV3 octahedra,  a cornercorner with one O(4)Li2TiV3 octahedra,  a cornercorner with one O(6)Li2TiV3 octahedra,  a cornercorner with one O(1)Li3TiV2 octahedra,  a cornercorner with one O(3)Li3TiV2 octahedra,  a cornercorner with one O(5)Li3TiV2 octahedra,  an edgeedge with one O(2)Li2TiV3 octahedra,  an edgeedge with one O(4)Li2TiV3 octahedra,  an edgeedge with one O(6)Li2TiV3 octahedra,  an edgeedge with one O(1)Li3TiV2 octahedra, edges with four equivalent O(3)Li3TiV2 octahedra, and edges with four equivalent O(5)Li3TiV2 octahedra. The corner-sharing octahedral tilt angles range from 1-7°. In the fourth O site, O(2) is bonded to one Li(1), one Li(2), one Ti(2), one V(1), one V(2), and one V(4) atom to form OLi2TiV3 octahedra that share  a cornercorner with one O(2)Li2TiV3 octahedra,  a cornercorner with one O(4)Li2TiV3 octahedra,  a cornercorner with one O(6)Li2TiV3 octahedra,  a cornercorner with one O(1)Li3TiV2 octahedra,  a cornercorner with one O(3)Li3TiV2 octahedra,  a cornercorner with one O(5)Li3TiV2 octahedra,  an edgeedge with one O(2)Li2TiV3 octahedra,  an edgeedge with one O(1)Li3TiV2 octahedra,  an edgeedge with one O(3)Li3TiV2 octahedra,  an edgeedge with one O(5)Li3TiV2 octahedra, edges with four equivalent O(4)Li2TiV3 octahedra, and edges with four equivalent O(6)Li2TiV3 octahedra. The corner-sharing octahedral tilt angles range from 1-5°. In the fifth O site, O(3) is bonded to one Li(1), one Li(2), one Li(3), one Ti(1), one V(1), and one V(3) atom to form OLi3TiV2 octahedra that share  a cornercorner with one O(2)Li2TiV3 octahedra,  a cornercorner with one O(4)Li2TiV3 octahedra,  a cornercorner with one O(6)Li2TiV3 octahedra,  a cornercorner with one O(1)Li3TiV2 octahedra,  a cornercorner with one O(3)Li3TiV2 octahedra,  a cornercorner with one O(5)Li3TiV2 octahedra,  an edgeedge with one O(2)Li2TiV3 octahedra,  an edgeedge with one O(4)Li2TiV3 octahedra,  an edgeedge with one O(6)Li2TiV3 octahedra,  an edgeedge with one O(3)Li3TiV2 octahedra, edges with four equivalent O(1)Li3TiV2 octahedra, and edges with four equivalent O(5)Li3TiV2 octahedra. The corner-sharing octahedral tilt angles range from 2-5°. In the sixth O site, O(4) is bonded to one Li(1), one Li(2), one Ti(2), one V(1), one V(2), and one V(4) atom to form OLi2TiV3 octahedra that share  a cornercorner with one O(2)Li2TiV3 octahedra,  a cornercorner with one O(4)Li2TiV3 octahedra,  a cornercorner with one O(6)Li2TiV3 octahedra,  a cornercorner with one O(1)Li3TiV2 octahedra,  a cornercorner with one O(3)Li3TiV2 octahedra,  a cornercorner with one O(5)Li3TiV2 octahedra,  an edgeedge with one O(4)Li2TiV3 octahedra,  an edgeedge with one O(1)Li3TiV2 octahedra,  an edgeedge with one O(3)Li3TiV2 octahedra,  an edgeedge with one O(5)Li3TiV2 octahedra, edges with four equivalent O(2)Li2TiV3 octahedra, and edges with four equivalent O(6)Li2TiV3 octahedra. The corner-sharing octahedral tilt angles range from 0-7°. is represented by the CIF card [CIF]
data_Li5Ti2V5O12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.217
_cell_length_b   5.217
_cell_length_c   10.049
_cell_angle_alpha   84.583
_cell_angle_beta   95.417
_cell_angle_gamma   59.122
_symmetry_Int_Tables_number   1
_cell_volume   230.438
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.159  0.671  0.505  1.0
  Li  Li1  1  0.325  0.835  0.995  1.0
  Li  Li2  1  0.671  0.159  0.995  1.0
  Li  Li3  1  0.835  0.325  0.505  1.0
  Li  Li4  1  0.920  0.920  0.750  1.0
  Ti  Ti5  1  0.252  0.252  0.750  1.0
  Ti  Ti6  1  0.751  0.751  0.250  1.0
  V  V7  1  0.997  0.506  0.996  1.0
  V  V8  1  0.506  0.997  0.504  1.0
  V  V9  1  0.422  0.422  0.250  1.0
  V  V10  1  0.580  0.580  0.750  1.0
  V  V11  1  0.083  0.083  0.250  1.0
  O  O12  1  0.966  0.220  0.865  1.0
  O  O13  1  0.220  0.966  0.635  1.0
  O  O14  1  0.118  0.387  0.368  1.0
  O  O15  1  0.387  0.118  0.132  1.0
  O  O16  1  0.300  0.517  0.866  1.0
  O  O17  1  0.517  0.300  0.634  1.0
  O  O18  1  0.485  0.705  0.371  1.0
  O  O19  1  0.705  0.485  0.129  1.0
  O  O20  1  0.604  0.881  0.864  1.0
  O  O21  1  0.881  0.604  0.636  1.0
  O  O22  1  0.796  0.022  0.372  1.0
  O  O23  1  0.022  0.796  0.128  1.0
[/CIF]
.