The structure described by WSCl4 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two WSCl4 clusters. W(1) is bonded in a distorted trigonal bipyramidal geometry to one S(1), one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. S(1) is bonded in a single-bond geometry to one W(1) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one W(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one W(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one W(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one W(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_WSCl4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.837
_cell_length_b   8.282
_cell_length_c   8.382
_cell_angle_alpha   101.764
_cell_angle_beta   93.247
_cell_angle_gamma   98.921
_symmetry_Int_Tables_number   1
_cell_volume   457.136
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  W  W0  1  0.153  0.218  0.762  1.0
  W  W1  1  0.847  0.782  0.238  1.0
  S  S2  1  0.328  0.288  0.987  1.0
  S  S3  1  0.672  0.712  0.013  1.0
  Cl  Cl4  1  0.840  0.125  0.829  1.0
  Cl  Cl5  1  0.825  0.062  0.328  1.0
  Cl  Cl6  1  0.372  0.271  0.573  1.0
  Cl  Cl7  1  0.039  0.458  0.733  1.0
  Cl  Cl8  1  0.961  0.542  0.267  1.0
  Cl  Cl9  1  0.628  0.729  0.427  1.0
  Cl  Cl10  1  0.175  0.938  0.672  1.0
  Cl  Cl11  1  0.160  0.875  0.171  1.0
[/CIF]
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The structure described by WSCl4 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two WSCl4 clusters. W(1) is bonded in a distorted trigonal bipyramidal geometry to one S(1), one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. S(1) is bonded in a single-bond geometry to one W(1) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one W(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one W(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one W(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one W(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_WSCl4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.837
_cell_length_b   8.282
_cell_length_c   8.382
_cell_angle_alpha   101.764
_cell_angle_beta   93.247
_cell_angle_gamma   98.921
_symmetry_Int_Tables_number   1
_cell_volume   457.136
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  W  W0  1  0.153  0.218  0.762  1.0
  W  W1  1  0.847  0.782  0.238  1.0
  S  S2  1  0.328  0.288  0.987  1.0
  S  S3  1  0.672  0.712  0.013  1.0
  Cl  Cl4  1  0.840  0.125  0.829  1.0
  Cl  Cl5  1  0.825  0.062  0.328  1.0
  Cl  Cl6  1  0.372  0.271  0.573  1.0
  Cl  Cl7  1  0.039  0.458  0.733  1.0
  Cl  Cl8  1  0.961  0.542  0.267  1.0
  Cl  Cl9  1  0.628  0.729  0.427  1.0
  Cl  Cl10  1  0.175  0.938  0.672  1.0
  Cl  Cl11  1  0.160  0.875  0.171  1.0
[/CIF]
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