The material structure described by RbIn3F10 crystallizes in the orthorhombic Pmma space group. Rb(1) is bonded in a 10-coordinate geometry to two equivalent F(5), four equivalent F(1), and four equivalent F(4) atoms. There are two inequivalent In sites. In the first In site, In(1) is bonded to one F(2), two equivalent F(1), two equivalent F(4), and two equivalent F(5) atoms to form InF7 pentagonal bipyramids that share corners with two equivalent In(2)F6 octahedra, corners with three equivalent In(1)F7 pentagonal bipyramids, and  an edgeedge with one In(1)F7 pentagonal bipyramid. The corner-sharing octahedral tilt angles are 44°. In the second In site, In(2) is bonded to two equivalent F(3) and four equivalent F(1) atoms to form InF6 octahedra that share corners with two equivalent In(2)F6 octahedra and corners with four equivalent In(1)F7 pentagonal bipyramids. The corner-sharing octahedral tilt angles are 36°. There are five inequivalent F sites. In the first F site, F(1) is bonded in a 2-coordinate geometry to one Rb(1), one In(1), and one In(2) atom. In the second F site, F(2) is bonded in a linear geometry to two equivalent In(1) atoms. In the third F site, F(3) is bonded in a bent 150 degrees geometry to two equivalent In(2) atoms. In the fourth F site, F(4) is bonded to two equivalent Rb(1) and two equivalent In(1) atoms to form a mixture of distorted corner and edge-sharing FRb2In2 tetrahedra. In the fifth F site, F(5) is bonded in a distorted bent 150 degrees geometry to one Rb(1) and two equivalent In(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_RbIn3F10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.599
_cell_length_b   7.827
_cell_length_c   8.028
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   414.630
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.015  0.500  0.250  1.0
  Rb  Rb1  1  0.985  0.500  0.750  1.0
  In  In2  1  0.500  0.271  0.500  1.0
  In  In3  1  0.500  0.729  0.000  1.0
  In  In4  1  0.000  0.000  0.500  1.0
  In  In5  1  0.000  0.000  0.000  1.0
  In  In6  1  0.500  0.271  0.000  1.0
  In  In7  1  0.500  0.729  0.500  1.0
  F  F8  1  0.194  0.199  0.938  1.0
  F  F9  1  0.194  0.801  0.562  1.0
  F  F10  1  0.806  0.199  0.062  1.0
  F  F11  1  0.806  0.801  0.438  1.0
  F  F12  1  0.194  0.199  0.562  1.0
  F  F13  1  0.194  0.801  0.938  1.0
  F  F14  1  0.806  0.199  0.438  1.0
  F  F15  1  0.806  0.801  0.062  1.0
  F  F16  1  0.500  0.000  0.000  1.0
  F  F17  1  0.500  0.000  0.500  1.0
  F  F18  1  0.098  0.000  0.250  1.0
  F  F19  1  0.902  0.000  0.750  1.0
  F  F20  1  0.683  0.500  0.025  1.0
  F  F21  1  0.683  0.500  0.475  1.0
  F  F22  1  0.317  0.500  0.975  1.0
  F  F23  1  0.317  0.500  0.525  1.0
  F  F24  1  0.414  0.717  0.250  1.0
  F  F25  1  0.414  0.283  0.250  1.0
  F  F26  1  0.586  0.717  0.750  1.0
  F  F27  1  0.586  0.283  0.750  1.0
[/CIF]
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The material structure described by RbIn3F10 crystallizes in the orthorhombic Pmma space group. Rb(1) is bonded in a 10-coordinate geometry to two equivalent F(5), four equivalent F(1), and four equivalent F(4) atoms. There are two inequivalent In sites. In the first In site, In(1) is bonded to one F(2), two equivalent F(1), two equivalent F(4), and two equivalent F(5) atoms to form InF7 pentagonal bipyramids that share corners with two equivalent In(2)F6 octahedra, corners with three equivalent In(1)F7 pentagonal bipyramids, and  an edgeedge with one In(1)F7 pentagonal bipyramid. The corner-sharing octahedral tilt angles are 44°. In the second In site, In(2) is bonded to two equivalent F(3) and four equivalent F(1) atoms to form InF6 octahedra that share corners with two equivalent In(2)F6 octahedra and corners with four equivalent In(1)F7 pentagonal bipyramids. The corner-sharing octahedral tilt angles are 36°. There are five inequivalent F sites. In the first F site, F(1) is bonded in a 2-coordinate geometry to one Rb(1), one In(1), and one In(2) atom. In the second F site, F(2) is bonded in a linear geometry to two equivalent In(1) atoms. In the third F site, F(3) is bonded in a bent 150 degrees geometry to two equivalent In(2) atoms. In the fourth F site, F(4) is bonded to two equivalent Rb(1) and two equivalent In(1) atoms to form a mixture of distorted corner and edge-sharing FRb2In2 tetrahedra. In the fifth F site, F(5) is bonded in a distorted bent 150 degrees geometry to one Rb(1) and two equivalent In(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_RbIn3F10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.599
_cell_length_b   7.827
_cell_length_c   8.028
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   414.630
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.015  0.500  0.250  1.0
  Rb  Rb1  1  0.985  0.500  0.750  1.0
  In  In2  1  0.500  0.271  0.500  1.0
  In  In3  1  0.500  0.729  0.000  1.0
  In  In4  1  0.000  0.000  0.500  1.0
  In  In5  1  0.000  0.000  0.000  1.0
  In  In6  1  0.500  0.271  0.000  1.0
  In  In7  1  0.500  0.729  0.500  1.0
  F  F8  1  0.194  0.199  0.938  1.0
  F  F9  1  0.194  0.801  0.562  1.0
  F  F10  1  0.806  0.199  0.062  1.0
  F  F11  1  0.806  0.801  0.438  1.0
  F  F12  1  0.194  0.199  0.562  1.0
  F  F13  1  0.194  0.801  0.938  1.0
  F  F14  1  0.806  0.199  0.438  1.0
  F  F15  1  0.806  0.801  0.062  1.0
  F  F16  1  0.500  0.000  0.000  1.0
  F  F17  1  0.500  0.000  0.500  1.0
  F  F18  1  0.098  0.000  0.250  1.0
  F  F19  1  0.902  0.000  0.750  1.0
  F  F20  1  0.683  0.500  0.025  1.0
  F  F21  1  0.683  0.500  0.475  1.0
  F  F22  1  0.317  0.500  0.975  1.0
  F  F23  1  0.317  0.500  0.525  1.0
  F  F24  1  0.414  0.717  0.250  1.0
  F  F25  1  0.414  0.283  0.250  1.0
  F  F26  1  0.586  0.717  0.750  1.0
  F  F27  1  0.586  0.283  0.750  1.0
[/CIF]
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