The material described by KAu(O3I)4 crystallizes in the triclinic P1 space group. K(1) is bonded in a 9-coordinate geometry to one O(1), one O(10), one O(11), one O(2), one O(4), one O(5), one O(6), one O(7), and one O(9) atom. Au(1) is bonded in a rectangular see-saw-like geometry to one O(10), one O(11), one O(2), and one O(3) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one K(1), one I(1), and one I(4) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one K(1), one Au(1), and one I(3) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Au(1) and one I(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one K(1), one I(1), and one I(3) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one K(1) and one I(1) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one K(1) and one I(2) atom. In the seventh O site, O(7) is bonded in a distorted bent 120 degrees geometry to one K(1) and one I(4) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one I(4) atom. In the ninth O site, O(9) is bonded in a 1-coordinate geometry to one K(1) and one I(3) atom. In the tenth O site, O(10) is bonded in a distorted trigonal non-coplanar geometry to one K(1), one Au(1), and one I(4) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one K(1), one Au(1), and one I(2) atom. In the twelfth O site, O(12) is bonded in a single-bond geometry to one I(2) atom. There are four inequivalent I sites. In the first I site, I(1) is bonded in a 3-coordinate geometry to one O(1), one O(3), one O(4), and one O(5) atom. In the second I site, I(2) is bonded in a 3-coordinate geometry to one O(11), one O(12), and one O(6) atom. In the third I site, I(3) is bonded in a 3-coordinate geometry to one O(2), one O(4), and one O(9) atom. In the fourth I site, I(4) is bonded in a 3-coordinate geometry to one O(1), one O(10), one O(7), and one O(8) atom. is represented by the CIF file [CIF]
data_KAu(IO3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.905
_cell_length_b   7.413
_cell_length_c   8.246
_cell_angle_alpha   104.964
_cell_angle_beta   93.781
_cell_angle_gamma   112.436
_symmetry_Int_Tables_number   1
_cell_volume   316.779
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.191  0.099  0.885  1.0
  Au  Au1  1  0.415  0.097  0.374  1.0
  I  I2  1  0.501  0.789  0.585  1.0
  I  I3  1  0.883  0.403  0.235  1.0
  I  I4  1  0.807  0.444  0.744  1.0
  I  I5  1  0.504  0.743  0.065  1.0
  O  O6  1  0.354  0.781  0.772  1.0
  O  O7  1  0.480  0.299  0.608  1.0
  O  O8  1  0.266  0.863  0.472  1.0
  O  O9  1  0.818  0.695  0.751  1.0
  O  O10  1  0.760  0.041  0.661  1.0
  O  O11  1  0.865  0.153  0.119  1.0
  O  O12  1  0.223  0.504  0.003  1.0
  O  O13  1  0.641  0.755  0.274  1.0
  O  O14  1  0.682  0.429  0.940  1.0
  O  O15  1  0.314  0.902  0.135  1.0
  O  O16  1  0.546  0.331  0.271  1.0
  O  O17  1  0.027  0.430  0.449  1.0
[/CIF]
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The material described by KAu(O3I)4 crystallizes in the triclinic P1 space group. K(1) is bonded in a 9-coordinate geometry to one O(1), one O(10), one O(11), one O(2), one O(4), one O(5), one O(6), one O(7), and one O(9) atom. Au(1) is bonded in a rectangular see-saw-like geometry to one O(10), one O(11), one O(2), and one O(3) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one K(1), one I(1), and one I(4) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one K(1), one Au(1), and one I(3) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Au(1) and one I(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one K(1), one I(1), and one I(3) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one K(1) and one I(1) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one K(1) and one I(2) atom. In the seventh O site, O(7) is bonded in a distorted bent 120 degrees geometry to one K(1) and one I(4) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one I(4) atom. In the ninth O site, O(9) is bonded in a 1-coordinate geometry to one K(1) and one I(3) atom. In the tenth O site, O(10) is bonded in a distorted trigonal non-coplanar geometry to one K(1), one Au(1), and one I(4) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one K(1), one Au(1), and one I(2) atom. In the twelfth O site, O(12) is bonded in a single-bond geometry to one I(2) atom. There are four inequivalent I sites. In the first I site, I(1) is bonded in a 3-coordinate geometry to one O(1), one O(3), one O(4), and one O(5) atom. In the second I site, I(2) is bonded in a 3-coordinate geometry to one O(11), one O(12), and one O(6) atom. In the third I site, I(3) is bonded in a 3-coordinate geometry to one O(2), one O(4), and one O(9) atom. In the fourth I site, I(4) is bonded in a 3-coordinate geometry to one O(1), one O(10), one O(7), and one O(8) atom. is represented by the CIF file [CIF]
data_KAu(IO3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.905
_cell_length_b   7.413
_cell_length_c   8.246
_cell_angle_alpha   104.964
_cell_angle_beta   93.781
_cell_angle_gamma   112.436
_symmetry_Int_Tables_number   1
_cell_volume   316.779
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.191  0.099  0.885  1.0
  Au  Au1  1  0.415  0.097  0.374  1.0
  I  I2  1  0.501  0.789  0.585  1.0
  I  I3  1  0.883  0.403  0.235  1.0
  I  I4  1  0.807  0.444  0.744  1.0
  I  I5  1  0.504  0.743  0.065  1.0
  O  O6  1  0.354  0.781  0.772  1.0
  O  O7  1  0.480  0.299  0.608  1.0
  O  O8  1  0.266  0.863  0.472  1.0
  O  O9  1  0.818  0.695  0.751  1.0
  O  O10  1  0.760  0.041  0.661  1.0
  O  O11  1  0.865  0.153  0.119  1.0
  O  O12  1  0.223  0.504  0.003  1.0
  O  O13  1  0.641  0.755  0.274  1.0
  O  O14  1  0.682  0.429  0.940  1.0
  O  O15  1  0.314  0.902  0.135  1.0
  O  O16  1  0.546  0.331  0.271  1.0
  O  O17  1  0.027  0.430  0.449  1.0
[/CIF]
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