The material described by CN3H6PF6 is Tetraauricupride structured and crystallizes in the trigonal R-3m space group. The structure is zero-dimensional and consists of six guanidinium molecules and six PF6 clusters. In each PF6 cluster, P(1,2) is bonded in an octahedral geometry to six equivalent F(1,2) atoms. F(1,2) is bonded in a single-bond geometry to one P(1,2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_PH6C(NF2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.832
_cell_length_b   7.832
_cell_length_c   7.832
_cell_angle_alpha   64.188
_cell_angle_beta   64.188
_cell_angle_gamma   64.188
_symmetry_Int_Tables_number   1
_cell_volume   370.940
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.000  0.000  0.000  1.0
  P  P1  1  0.500  0.500  0.500  1.0
  H  H2  1  0.497  0.987  0.778  1.0
  H  H3  1  0.497  0.778  0.987  1.0
  H  H4  1  0.778  0.497  0.987  1.0
  H  H5  1  0.987  0.497  0.778  1.0
  H  H6  1  0.987  0.778  0.497  1.0
  H  H7  1  0.778  0.987  0.497  1.0
  H  H8  1  0.503  0.013  0.222  1.0
  H  H9  1  0.503  0.222  0.013  1.0
  H  H10  1  0.222  0.503  0.013  1.0
  H  H11  1  0.013  0.503  0.222  1.0
  H  H12  1  0.013  0.222  0.503  1.0
  H  H13  1  0.222  0.013  0.503  1.0
  C  C14  1  0.752  0.752  0.752  1.0
  C  C15  1  0.248  0.248  0.248  1.0
  N  N16  1  0.566  0.844  0.844  1.0
  N  N17  1  0.844  0.566  0.844  1.0
  N  N18  1  0.844  0.844  0.566  1.0
  N  N19  1  0.434  0.156  0.156  1.0
  N  N20  1  0.156  0.434  0.156  1.0
  N  N21  1  0.156  0.156  0.434  1.0
  F  F22  1  0.135  0.856  0.856  1.0
  F  F23  1  0.856  0.135  0.856  1.0
  F  F24  1  0.856  0.856  0.135  1.0
  F  F25  1  0.865  0.144  0.144  1.0
  F  F26  1  0.144  0.865  0.144  1.0
  F  F27  1  0.144  0.144  0.865  1.0
  F  F28  1  0.737  0.458  0.458  1.0
  F  F29  1  0.458  0.737  0.458  1.0
  F  F30  1  0.458  0.458  0.737  1.0
  F  F31  1  0.263  0.542  0.542  1.0
  F  F32  1  0.542  0.263  0.542  1.0
  F  F33  1  0.542  0.542  0.263  1.0
[/CIF]
.
The material described by CN3H6PF6 is Tetraauricupride structured and crystallizes in the trigonal R-3m space group. The structure is zero-dimensional and consists of six guanidinium molecules and six PF6 clusters. In each PF6 cluster, P(1,2) is bonded in an octahedral geometry to six equivalent F(1,2) atoms. F(1,2) is bonded in a single-bond geometry to one P(1,2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_PH6C(NF2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.832
_cell_length_b   7.832
_cell_length_c   7.832
_cell_angle_alpha   64.188
_cell_angle_beta   64.188
_cell_angle_gamma   64.188
_symmetry_Int_Tables_number   1
_cell_volume   370.940
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.000  0.000  0.000  1.0
  P  P1  1  0.500  0.500  0.500  1.0
  H  H2  1  0.497  0.987  0.778  1.0
  H  H3  1  0.497  0.778  0.987  1.0
  H  H4  1  0.778  0.497  0.987  1.0
  H  H5  1  0.987  0.497  0.778  1.0
  H  H6  1  0.987  0.778  0.497  1.0
  H  H7  1  0.778  0.987  0.497  1.0
  H  H8  1  0.503  0.013  0.222  1.0
  H  H9  1  0.503  0.222  0.013  1.0
  H  H10  1  0.222  0.503  0.013  1.0
  H  H11  1  0.013  0.503  0.222  1.0
  H  H12  1  0.013  0.222  0.503  1.0
  H  H13  1  0.222  0.013  0.503  1.0
  C  C14  1  0.752  0.752  0.752  1.0
  C  C15  1  0.248  0.248  0.248  1.0
  N  N16  1  0.566  0.844  0.844  1.0
  N  N17  1  0.844  0.566  0.844  1.0
  N  N18  1  0.844  0.844  0.566  1.0
  N  N19  1  0.434  0.156  0.156  1.0
  N  N20  1  0.156  0.434  0.156  1.0
  N  N21  1  0.156  0.156  0.434  1.0
  F  F22  1  0.135  0.856  0.856  1.0
  F  F23  1  0.856  0.135  0.856  1.0
  F  F24  1  0.856  0.856  0.135  1.0
  F  F25  1  0.865  0.144  0.144  1.0
  F  F26  1  0.144  0.865  0.144  1.0
  F  F27  1  0.144  0.144  0.865  1.0
  F  F28  1  0.737  0.458  0.458  1.0
  F  F29  1  0.458  0.737  0.458  1.0
  F  F30  1  0.458  0.458  0.737  1.0
  F  F31  1  0.263  0.542  0.542  1.0
  F  F32  1  0.542  0.263  0.542  1.0
  F  F33  1  0.542  0.542  0.263  1.0
[/CIF]
.