The compound described by RbLiBi2(MoO4)4 crystallizes in the monoclinic C2/c space group. Rb(1) is bonded in a 10-coordinate geometry to two equivalent O(2), two equivalent O(3), two equivalent O(6), two equivalent O(7), and two equivalent O(8) atoms. Li(1) is bonded in a 4-coordinate geometry to two equivalent O(2) and two equivalent O(8) atoms. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a tetrahedral geometry to one O(2), one O(3), one O(5), and one O(6) atom. In the second Mo site, Mo(2) is bonded in a tetrahedral geometry to one O(1), one O(4), one O(7), and one O(8) atom. Bi(1) is bonded in a 8-coordinate geometry to one O(3), one O(7), two equivalent O(1), two equivalent O(4), and two equivalent O(5) atoms. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Mo(2) and two equivalent Bi(1) atoms. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Rb(1), one Li(1), and one Mo(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Rb(1), one Mo(1), and one Bi(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Mo(2) and two equivalent Bi(1) atoms. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Mo(1) and two equivalent Bi(1) atoms. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one Rb(1) and one Mo(1) atom. In the seventh O site, O(7) is bonded in a 1-coordinate geometry to one Rb(1), one Mo(2), and one Bi(1) atom. In the eighth O site, O(8) is bonded in a 2-coordinate geometry to one Rb(1), one Li(1), and one Mo(2) atom. is represented by the CIF card [CIF]
data_RbLiBi2(MoO4)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.106
_cell_length_b   7.106
_cell_length_c   19.868
_cell_angle_alpha   89.007
_cell_angle_beta   89.007
_cell_angle_gamma   135.539
_symmetry_Int_Tables_number   1
_cell_volume   702.013
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.969  0.031  0.250  1.0
  Rb  Rb1  1  0.031  0.969  0.750  1.0
  Li  Li2  1  0.686  0.314  0.250  1.0
  Li  Li3  1  0.314  0.686  0.750  1.0
  Bi  Bi4  1  0.848  0.145  0.036  1.0
  Bi  Bi5  1  0.855  0.152  0.464  1.0
  Bi  Bi6  1  0.152  0.855  0.964  1.0
  Bi  Bi7  1  0.145  0.848  0.536  1.0
  Mo  Mo8  1  0.751  0.266  0.851  1.0
  Mo  Mo9  1  0.544  0.419  0.093  1.0
  Mo  Mo10  1  0.249  0.734  0.149  1.0
  Mo  Mo11  1  0.419  0.544  0.593  1.0
  Mo  Mo12  1  0.581  0.456  0.407  1.0
  Mo  Mo13  1  0.456  0.581  0.907  1.0
  Mo  Mo14  1  0.734  0.249  0.649  1.0
  Mo  Mo15  1  0.266  0.751  0.351  1.0
  O  O16  1  0.174  0.514  0.544  1.0
  O  O17  1  0.064  0.478  0.214  1.0
  O  O18  1  0.522  0.936  0.286  1.0
  O  O19  1  0.596  0.898  0.135  1.0
  O  O20  1  0.233  0.271  0.961  1.0
  O  O21  1  0.068  0.585  0.069  1.0
  O  O22  1  0.102  0.404  0.365  1.0
  O  O23  1  0.826  0.486  0.456  1.0
  O  O24  1  0.014  0.729  0.326  1.0
  O  O25  1  0.773  0.689  0.896  1.0
  O  O26  1  0.404  0.102  0.865  1.0
  O  O27  1  0.767  0.729  0.039  1.0
  O  O28  1  0.271  0.233  0.461  1.0
  O  O29  1  0.486  0.826  0.956  1.0
  O  O30  1  0.585  0.068  0.569  1.0
  O  O31  1  0.729  0.767  0.539  1.0
  O  O32  1  0.415  0.932  0.431  1.0
  O  O33  1  0.486  0.303  0.329  1.0
  O  O34  1  0.514  0.697  0.671  1.0
  O  O35  1  0.697  0.514  0.171  1.0
  O  O36  1  0.303  0.486  0.829  1.0
  O  O37  1  0.729  0.014  0.826  1.0
  O  O38  1  0.689  0.773  0.396  1.0
  O  O39  1  0.311  0.227  0.604  1.0
  O  O40  1  0.514  0.174  0.044  1.0
  O  O41  1  0.932  0.415  0.931  1.0
  O  O42  1  0.898  0.596  0.635  1.0
  O  O43  1  0.986  0.271  0.674  1.0
  O  O44  1  0.478  0.064  0.714  1.0
  O  O45  1  0.271  0.986  0.174  1.0
  O  O46  1  0.936  0.522  0.786  1.0
  O  O47  1  0.227  0.311  0.104  1.0
[/CIF]
.
The compound described by RbLiBi2(MoO4)4 crystallizes in the monoclinic C2/c space group. Rb(1) is bonded in a 10-coordinate geometry to two equivalent O(2), two equivalent O(3), two equivalent O(6), two equivalent O(7), and two equivalent O(8) atoms. Li(1) is bonded in a 4-coordinate geometry to two equivalent O(2) and two equivalent O(8) atoms. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a tetrahedral geometry to one O(2), one O(3), one O(5), and one O(6) atom. In the second Mo site, Mo(2) is bonded in a tetrahedral geometry to one O(1), one O(4), one O(7), and one O(8) atom. Bi(1) is bonded in a 8-coordinate geometry to one O(3), one O(7), two equivalent O(1), two equivalent O(4), and two equivalent O(5) atoms. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Mo(2) and two equivalent Bi(1) atoms. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Rb(1), one Li(1), and one Mo(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Rb(1), one Mo(1), and one Bi(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Mo(2) and two equivalent Bi(1) atoms. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Mo(1) and two equivalent Bi(1) atoms. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one Rb(1) and one Mo(1) atom. In the seventh O site, O(7) is bonded in a 1-coordinate geometry to one Rb(1), one Mo(2), and one Bi(1) atom. In the eighth O site, O(8) is bonded in a 2-coordinate geometry to one Rb(1), one Li(1), and one Mo(2) atom. is represented by the CIF card [CIF]
data_RbLiBi2(MoO4)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.106
_cell_length_b   7.106
_cell_length_c   19.868
_cell_angle_alpha   89.007
_cell_angle_beta   89.007
_cell_angle_gamma   135.539
_symmetry_Int_Tables_number   1
_cell_volume   702.013
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.969  0.031  0.250  1.0
  Rb  Rb1  1  0.031  0.969  0.750  1.0
  Li  Li2  1  0.686  0.314  0.250  1.0
  Li  Li3  1  0.314  0.686  0.750  1.0
  Bi  Bi4  1  0.848  0.145  0.036  1.0
  Bi  Bi5  1  0.855  0.152  0.464  1.0
  Bi  Bi6  1  0.152  0.855  0.964  1.0
  Bi  Bi7  1  0.145  0.848  0.536  1.0
  Mo  Mo8  1  0.751  0.266  0.851  1.0
  Mo  Mo9  1  0.544  0.419  0.093  1.0
  Mo  Mo10  1  0.249  0.734  0.149  1.0
  Mo  Mo11  1  0.419  0.544  0.593  1.0
  Mo  Mo12  1  0.581  0.456  0.407  1.0
  Mo  Mo13  1  0.456  0.581  0.907  1.0
  Mo  Mo14  1  0.734  0.249  0.649  1.0
  Mo  Mo15  1  0.266  0.751  0.351  1.0
  O  O16  1  0.174  0.514  0.544  1.0
  O  O17  1  0.064  0.478  0.214  1.0
  O  O18  1  0.522  0.936  0.286  1.0
  O  O19  1  0.596  0.898  0.135  1.0
  O  O20  1  0.233  0.271  0.961  1.0
  O  O21  1  0.068  0.585  0.069  1.0
  O  O22  1  0.102  0.404  0.365  1.0
  O  O23  1  0.826  0.486  0.456  1.0
  O  O24  1  0.014  0.729  0.326  1.0
  O  O25  1  0.773  0.689  0.896  1.0
  O  O26  1  0.404  0.102  0.865  1.0
  O  O27  1  0.767  0.729  0.039  1.0
  O  O28  1  0.271  0.233  0.461  1.0
  O  O29  1  0.486  0.826  0.956  1.0
  O  O30  1  0.585  0.068  0.569  1.0
  O  O31  1  0.729  0.767  0.539  1.0
  O  O32  1  0.415  0.932  0.431  1.0
  O  O33  1  0.486  0.303  0.329  1.0
  O  O34  1  0.514  0.697  0.671  1.0
  O  O35  1  0.697  0.514  0.171  1.0
  O  O36  1  0.303  0.486  0.829  1.0
  O  O37  1  0.729  0.014  0.826  1.0
  O  O38  1  0.689  0.773  0.396  1.0
  O  O39  1  0.311  0.227  0.604  1.0
  O  O40  1  0.514  0.174  0.044  1.0
  O  O41  1  0.932  0.415  0.931  1.0
  O  O42  1  0.898  0.596  0.635  1.0
  O  O43  1  0.986  0.271  0.674  1.0
  O  O44  1  0.478  0.064  0.714  1.0
  O  O45  1  0.271  0.986  0.174  1.0
  O  O46  1  0.936  0.522  0.786  1.0
  O  O47  1  0.227  0.311  0.104  1.0
[/CIF]
.