The material described by MgRhSbO4 crystallizes in the monoclinic Pm space group. Mg(1) is bonded in a 6-coordinate geometry to one O(1), one O(4), two equivalent O(2), and two equivalent O(3) atoms. Rh(1) is bonded to one O(2), one O(3), two equivalent O(1), and two equivalent O(4) atoms to form edge-sharing RhO6 octahedra. Sb(1) is bonded in a 3-coordinate geometry to one O(1), two equivalent O(2), and two equivalent O(3) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded to one Mg(1), two equivalent Rh(1), and one Sb(1) atom to form corner-sharing OMgSbRh2 trigonal pyramids. In the second O site, O(2) is bonded in a 5-coordinate geometry to two equivalent Mg(1), one Rh(1), and two equivalent Sb(1) atoms. In the third O site, O(3) is bonded in a 5-coordinate geometry to two equivalent Mg(1), one Rh(1), and two equivalent Sb(1) atoms. In the fourth O site, O(4) is bonded in a trigonal non-coplanar geometry to one Mg(1) and two equivalent Rh(1) atoms. is represented by the CIF card [CIF]
data_MgSbRhO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.193
_cell_length_b   5.050
_cell_length_c   5.831
_cell_angle_alpha   88.829
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   93.997
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.000  0.059  0.579  1.0
  Sb  Sb1  1  0.000  0.059  0.079  1.0
  Rh  Rh2  1  0.500  0.534  0.508  1.0
  O  O3  1  0.000  0.345  0.322  1.0
  O  O4  1  0.500  0.893  0.291  1.0
  O  O5  1  0.500  0.214  0.734  1.0
  O  O6  1  0.000  0.687  0.681  1.0
[/CIF]
.
The material described by MgRhSbO4 crystallizes in the monoclinic Pm space group. Mg(1) is bonded in a 6-coordinate geometry to one O(1), one O(4), two equivalent O(2), and two equivalent O(3) atoms. Rh(1) is bonded to one O(2), one O(3), two equivalent O(1), and two equivalent O(4) atoms to form edge-sharing RhO6 octahedra. Sb(1) is bonded in a 3-coordinate geometry to one O(1), two equivalent O(2), and two equivalent O(3) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded to one Mg(1), two equivalent Rh(1), and one Sb(1) atom to form corner-sharing OMgSbRh2 trigonal pyramids. In the second O site, O(2) is bonded in a 5-coordinate geometry to two equivalent Mg(1), one Rh(1), and two equivalent Sb(1) atoms. In the third O site, O(3) is bonded in a 5-coordinate geometry to two equivalent Mg(1), one Rh(1), and two equivalent Sb(1) atoms. In the fourth O site, O(4) is bonded in a trigonal non-coplanar geometry to one Mg(1) and two equivalent Rh(1) atoms. is represented by the CIF card [CIF]
data_MgSbRhO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.193
_cell_length_b   5.050
_cell_length_c   5.831
_cell_angle_alpha   88.829
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   93.997
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.000  0.059  0.579  1.0
  Sb  Sb1  1  0.000  0.059  0.079  1.0
  Rh  Rh2  1  0.500  0.534  0.508  1.0
  O  O3  1  0.000  0.345  0.322  1.0
  O  O4  1  0.500  0.893  0.291  1.0
  O  O5  1  0.500  0.214  0.734  1.0
  O  O6  1  0.000  0.687  0.681  1.0
[/CIF]
.