The crystal structure described by Pt(N2I3)2 is Copper structured and crystallizes in the orthorhombic Pnnm space group. The structure is zero-dimensional and consists of two Pt(N2I3)2 clusters. Pt(1) is bonded in an octahedral geometry to two equivalent I(1), two equivalent I(2), and two equivalent I(3) atoms. N(1) is bonded in a bent 120 degrees geometry to one I(1) and one I(2) atom. There are three inequivalent I sites. In the first I site, I(1) is bonded in a distorted T-shaped geometry to one Pt(1) and two equivalent N(1) atoms. In the second I site, I(2) is bonded in a distorted bent 150 degrees geometry to one Pt(1) and two equivalent N(1) atoms. In the third I site, I(3) is bonded in a single-bond geometry to one Pt(1) atom. is represented by the CIF card [CIF]
data_Pt(I3N2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.955
_cell_length_b   8.492
_cell_length_c   10.819
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   730.853
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pt  Pt0  1  0.500  0.500  0.500  1.0
  Pt  Pt1  1  0.000  0.000  0.000  1.0
  I  I2  1  0.500  0.500  0.735  1.0
  I  I3  1  0.000  0.000  0.765  1.0
  I  I4  1  0.500  0.500  0.265  1.0
  I  I5  1  0.000  0.000  0.235  1.0
  I  I6  1  0.238  0.724  0.500  1.0
  I  I7  1  0.762  0.276  0.500  1.0
  I  I8  1  0.262  0.224  0.000  1.0
  I  I9  1  0.738  0.776  0.000  1.0
  I  I10  1  0.266  0.263  0.500  1.0
  I  I11  1  0.734  0.737  0.500  1.0
  I  I12  1  0.234  0.763  0.000  1.0
  I  I13  1  0.766  0.237  0.000  1.0
  N  N14  1  0.782  0.820  0.822  1.0
  N  N15  1  0.218  0.180  0.822  1.0
  N  N16  1  0.718  0.320  0.678  1.0
  N  N17  1  0.282  0.680  0.678  1.0
  N  N18  1  0.218  0.180  0.178  1.0
  N  N19  1  0.782  0.820  0.178  1.0
  N  N20  1  0.282  0.680  0.322  1.0
  N  N21  1  0.718  0.320  0.322  1.0
[/CIF]
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The crystal structure described by Pt(N2I3)2 is Copper structured and crystallizes in the orthorhombic Pnnm space group. The structure is zero-dimensional and consists of two Pt(N2I3)2 clusters. Pt(1) is bonded in an octahedral geometry to two equivalent I(1), two equivalent I(2), and two equivalent I(3) atoms. N(1) is bonded in a bent 120 degrees geometry to one I(1) and one I(2) atom. There are three inequivalent I sites. In the first I site, I(1) is bonded in a distorted T-shaped geometry to one Pt(1) and two equivalent N(1) atoms. In the second I site, I(2) is bonded in a distorted bent 150 degrees geometry to one Pt(1) and two equivalent N(1) atoms. In the third I site, I(3) is bonded in a single-bond geometry to one Pt(1) atom. is represented by the CIF card [CIF]
data_Pt(I3N2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.955
_cell_length_b   8.492
_cell_length_c   10.819
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   730.853
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pt  Pt0  1  0.500  0.500  0.500  1.0
  Pt  Pt1  1  0.000  0.000  0.000  1.0
  I  I2  1  0.500  0.500  0.735  1.0
  I  I3  1  0.000  0.000  0.765  1.0
  I  I4  1  0.500  0.500  0.265  1.0
  I  I5  1  0.000  0.000  0.235  1.0
  I  I6  1  0.238  0.724  0.500  1.0
  I  I7  1  0.762  0.276  0.500  1.0
  I  I8  1  0.262  0.224  0.000  1.0
  I  I9  1  0.738  0.776  0.000  1.0
  I  I10  1  0.266  0.263  0.500  1.0
  I  I11  1  0.734  0.737  0.500  1.0
  I  I12  1  0.234  0.763  0.000  1.0
  I  I13  1  0.766  0.237  0.000  1.0
  N  N14  1  0.782  0.820  0.822  1.0
  N  N15  1  0.218  0.180  0.822  1.0
  N  N16  1  0.718  0.320  0.678  1.0
  N  N17  1  0.282  0.680  0.678  1.0
  N  N18  1  0.218  0.180  0.178  1.0
  N  N19  1  0.782  0.820  0.178  1.0
  N  N20  1  0.282  0.680  0.322  1.0
  N  N21  1  0.718  0.320  0.322  1.0
[/CIF]
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