The compound described by In(BO2)5 crystallizes in the monoclinic C2 space group. In(1) is bonded to two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms to form InO6 octahedra that share corners with six equivalent B(1)O4 tetrahedra and corners with six equivalent B(2)O4 tetrahedra. There are three inequivalent B sites. In the first B site, B(1) is bonded to one O(2), one O(3), one O(4), and one O(5) atom to form BO4 tetrahedra that share corners with three equivalent In(1)O6 octahedra,  a cornercorner with one B(3)O4 tetrahedra, and corners with three equivalent B(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 56-64°. In the second B site, B(2) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form BO4 tetrahedra that share corners with three equivalent In(1)O6 octahedra,  a cornercorner with one B(3)O4 tetrahedra, and corners with three equivalent B(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 57-64°. In the third B site, B(3) is bonded to two equivalent O(1) and two equivalent O(5) atoms to form corner-sharing BO4 tetrahedra. There are five inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one B(2) and one B(3) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one In(1), one B(1), and one B(2) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one In(1), one B(1), and one B(2) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one In(1), one B(1), and one B(2) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one B(1) and one B(3) atom. is represented by the CIF card [CIF]
data_In(BO2)5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.440
_cell_length_b   4.501
_cell_length_c   8.639
_cell_angle_alpha   82.926
_cell_angle_beta   75.539
_cell_angle_gamma   60.452
_symmetry_Int_Tables_number   1
_cell_volume   145.430
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.371  0.258  0.000  1.0
  B  B1  1  0.144  0.942  0.774  1.0
  B  B2  1  0.914  0.942  0.226  1.0
  B  B3  1  0.799  0.600  0.775  1.0
  B  B4  1  0.601  0.600  0.225  1.0
  B  B5  1  0.620  0.759  0.500  1.0
  O  O6  1  0.870  0.560  0.602  1.0
  O  O7  1  0.570  0.560  0.398  1.0
  O  O8  1  0.428  0.669  0.849  1.0
  O  O9  1  0.903  0.669  0.151  1.0
  O  O10  1  0.045  0.277  0.842  1.0
  O  O11  1  0.678  0.277  0.158  1.0
  O  O12  1  0.826  0.894  0.819  1.0
  O  O13  1  0.279  0.894  0.181  1.0
  O  O14  1  0.268  0.961  0.602  1.0
  O  O15  1  0.771  0.961  0.398  1.0
[/CIF]
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The compound described by In(BO2)5 crystallizes in the monoclinic C2 space group. In(1) is bonded to two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms to form InO6 octahedra that share corners with six equivalent B(1)O4 tetrahedra and corners with six equivalent B(2)O4 tetrahedra. There are three inequivalent B sites. In the first B site, B(1) is bonded to one O(2), one O(3), one O(4), and one O(5) atom to form BO4 tetrahedra that share corners with three equivalent In(1)O6 octahedra,  a cornercorner with one B(3)O4 tetrahedra, and corners with three equivalent B(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 56-64°. In the second B site, B(2) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form BO4 tetrahedra that share corners with three equivalent In(1)O6 octahedra,  a cornercorner with one B(3)O4 tetrahedra, and corners with three equivalent B(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 57-64°. In the third B site, B(3) is bonded to two equivalent O(1) and two equivalent O(5) atoms to form corner-sharing BO4 tetrahedra. There are five inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one B(2) and one B(3) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one In(1), one B(1), and one B(2) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one In(1), one B(1), and one B(2) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one In(1), one B(1), and one B(2) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one B(1) and one B(3) atom. is represented by the CIF card [CIF]
data_In(BO2)5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.440
_cell_length_b   4.501
_cell_length_c   8.639
_cell_angle_alpha   82.926
_cell_angle_beta   75.539
_cell_angle_gamma   60.452
_symmetry_Int_Tables_number   1
_cell_volume   145.430
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.371  0.258  0.000  1.0
  B  B1  1  0.144  0.942  0.774  1.0
  B  B2  1  0.914  0.942  0.226  1.0
  B  B3  1  0.799  0.600  0.775  1.0
  B  B4  1  0.601  0.600  0.225  1.0
  B  B5  1  0.620  0.759  0.500  1.0
  O  O6  1  0.870  0.560  0.602  1.0
  O  O7  1  0.570  0.560  0.398  1.0
  O  O8  1  0.428  0.669  0.849  1.0
  O  O9  1  0.903  0.669  0.151  1.0
  O  O10  1  0.045  0.277  0.842  1.0
  O  O11  1  0.678  0.277  0.158  1.0
  O  O12  1  0.826  0.894  0.819  1.0
  O  O13  1  0.279  0.894  0.181  1.0
  O  O14  1  0.268  0.961  0.602  1.0
  O  O15  1  0.771  0.961  0.398  1.0
[/CIF]
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