The material described by K2InH2OCl5 crystallizes in the orthorhombic Pnma space group. K(1) is bonded in a 8-coordinate geometry to two equivalent Cl(1), two equivalent Cl(2), two equivalent Cl(3), and two equivalent Cl(4) atoms. In(1) is bonded in an octahedral geometry to one O(1), one Cl(1), one Cl(3), one Cl(4), and two equivalent Cl(2) atoms. H(1) is bonded in a single-bond geometry to one O(1) atom. O(1) is bonded in a distorted trigonal planar geometry to one In(1) and two equivalent H(1) atoms. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded to four equivalent K(1) and one In(1) atom to form a mixture of distorted corner, face, and edge-sharing ClK4In square pyramids. In the second Cl site, Cl(2) is bonded in a 1-coordinate geometry to two equivalent K(1) and one In(1) atom. In the third Cl site, Cl(3) is bonded in a 5-coordinate geometry to four equivalent K(1) and one In(1) atom. In the fourth Cl site, Cl(4) is bonded to four equivalent K(1) and one In(1) atom to form a mixture of distorted corner, face, and edge-sharing ClK4In square pyramids. is represented by the CIF card [CIF]
data_K2InH2Cl5O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.345
_cell_length_b   10.056
_cell_length_c   14.155
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1045.506
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.359  0.000  0.147  1.0
  K  K1  1  0.359  0.500  0.147  1.0
  K  K2  1  0.859  1.000  0.353  1.0
  K  K3  1  0.859  0.500  0.353  1.0
  K  K4  1  0.141  0.500  0.647  1.0
  K  K5  1  0.141  0.000  0.647  1.0
  K  K6  1  0.641  1.000  0.853  1.0
  K  K7  1  0.641  0.500  0.853  1.0
  In  In8  1  0.813  0.250  0.113  1.0
  In  In9  1  0.313  0.750  0.387  1.0
  In  In10  1  0.687  0.250  0.613  1.0
  In  In11  1  0.187  0.750  0.887  1.0
  H  H12  1  0.957  0.830  0.047  1.0
  H  H13  1  0.957  0.670  0.047  1.0
  H  H14  1  0.457  0.170  0.453  1.0
  H  H15  1  0.457  0.330  0.453  1.0
  H  H16  1  0.543  0.670  0.547  1.0
  H  H17  1  0.543  0.830  0.547  1.0
  H  H18  1  0.043  0.170  0.953  1.0
  H  H19  1  0.043  0.330  0.953  1.0
  Cl  Cl20  1  0.542  0.250  0.002  1.0
  Cl  Cl21  1  0.815  0.999  0.106  1.0
  Cl  Cl22  1  0.815  0.501  0.106  1.0
  Cl  Cl23  1  0.090  0.250  0.218  1.0
  Cl  Cl24  1  0.105  0.750  0.244  1.0
  Cl  Cl25  1  0.605  0.250  0.256  1.0
  Cl  Cl26  1  0.590  0.750  0.282  1.0
  Cl  Cl27  1  0.315  0.499  0.394  1.0
  Cl  Cl28  1  0.315  0.001  0.394  1.0
  Cl  Cl29  1  0.042  0.750  0.498  1.0
  Cl  Cl30  1  0.958  0.250  0.502  1.0
  Cl  Cl31  1  0.685  0.999  0.606  1.0
  Cl  Cl32  1  0.685  0.501  0.606  1.0
  Cl  Cl33  1  0.410  0.250  0.718  1.0
  Cl  Cl34  1  0.395  0.750  0.744  1.0
  Cl  Cl35  1  0.895  0.250  0.756  1.0
  Cl  Cl36  1  0.910  0.750  0.782  1.0
  Cl  Cl37  1  0.185  0.499  0.894  1.0
  Cl  Cl38  1  0.185  0.001  0.894  1.0
  Cl  Cl39  1  0.458  0.750  0.998  1.0
  O  O40  1  0.996  0.750  0.012  1.0
  O  O41  1  0.496  0.250  0.488  1.0
  O  O42  1  0.504  0.750  0.512  1.0
  O  O43  1  0.004  0.250  0.988  1.0
[/CIF]
.
The material described by K2InH2OCl5 crystallizes in the orthorhombic Pnma space group. K(1) is bonded in a 8-coordinate geometry to two equivalent Cl(1), two equivalent Cl(2), two equivalent Cl(3), and two equivalent Cl(4) atoms. In(1) is bonded in an octahedral geometry to one O(1), one Cl(1), one Cl(3), one Cl(4), and two equivalent Cl(2) atoms. H(1) is bonded in a single-bond geometry to one O(1) atom. O(1) is bonded in a distorted trigonal planar geometry to one In(1) and two equivalent H(1) atoms. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded to four equivalent K(1) and one In(1) atom to form a mixture of distorted corner, face, and edge-sharing ClK4In square pyramids. In the second Cl site, Cl(2) is bonded in a 1-coordinate geometry to two equivalent K(1) and one In(1) atom. In the third Cl site, Cl(3) is bonded in a 5-coordinate geometry to four equivalent K(1) and one In(1) atom. In the fourth Cl site, Cl(4) is bonded to four equivalent K(1) and one In(1) atom to form a mixture of distorted corner, face, and edge-sharing ClK4In square pyramids. is represented by the CIF card [CIF]
data_K2InH2Cl5O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.345
_cell_length_b   10.056
_cell_length_c   14.155
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1045.506
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.359  0.000  0.147  1.0
  K  K1  1  0.359  0.500  0.147  1.0
  K  K2  1  0.859  1.000  0.353  1.0
  K  K3  1  0.859  0.500  0.353  1.0
  K  K4  1  0.141  0.500  0.647  1.0
  K  K5  1  0.141  0.000  0.647  1.0
  K  K6  1  0.641  1.000  0.853  1.0
  K  K7  1  0.641  0.500  0.853  1.0
  In  In8  1  0.813  0.250  0.113  1.0
  In  In9  1  0.313  0.750  0.387  1.0
  In  In10  1  0.687  0.250  0.613  1.0
  In  In11  1  0.187  0.750  0.887  1.0
  H  H12  1  0.957  0.830  0.047  1.0
  H  H13  1  0.957  0.670  0.047  1.0
  H  H14  1  0.457  0.170  0.453  1.0
  H  H15  1  0.457  0.330  0.453  1.0
  H  H16  1  0.543  0.670  0.547  1.0
  H  H17  1  0.543  0.830  0.547  1.0
  H  H18  1  0.043  0.170  0.953  1.0
  H  H19  1  0.043  0.330  0.953  1.0
  Cl  Cl20  1  0.542  0.250  0.002  1.0
  Cl  Cl21  1  0.815  0.999  0.106  1.0
  Cl  Cl22  1  0.815  0.501  0.106  1.0
  Cl  Cl23  1  0.090  0.250  0.218  1.0
  Cl  Cl24  1  0.105  0.750  0.244  1.0
  Cl  Cl25  1  0.605  0.250  0.256  1.0
  Cl  Cl26  1  0.590  0.750  0.282  1.0
  Cl  Cl27  1  0.315  0.499  0.394  1.0
  Cl  Cl28  1  0.315  0.001  0.394  1.0
  Cl  Cl29  1  0.042  0.750  0.498  1.0
  Cl  Cl30  1  0.958  0.250  0.502  1.0
  Cl  Cl31  1  0.685  0.999  0.606  1.0
  Cl  Cl32  1  0.685  0.501  0.606  1.0
  Cl  Cl33  1  0.410  0.250  0.718  1.0
  Cl  Cl34  1  0.395  0.750  0.744  1.0
  Cl  Cl35  1  0.895  0.250  0.756  1.0
  Cl  Cl36  1  0.910  0.750  0.782  1.0
  Cl  Cl37  1  0.185  0.499  0.894  1.0
  Cl  Cl38  1  0.185  0.001  0.894  1.0
  Cl  Cl39  1  0.458  0.750  0.998  1.0
  O  O40  1  0.996  0.750  0.012  1.0
  O  O41  1  0.496  0.250  0.488  1.0
  O  O42  1  0.504  0.750  0.512  1.0
  O  O43  1  0.004  0.250  0.988  1.0
[/CIF]
.