The material described by XeF4Sb2F11 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four Sb2F11 clusters and four XeF4 clusters. In each Sb2F11 cluster, Sb(1) is bonded to one F(2), one F(3), one F(4), one F(5), one F(7), and one F(8) atom to form corner-sharing SbF6 octahedra. The corner-sharing octahedra are not tilted. There are six inequivalent F sites. In the first F site, F(7) is bonded in a linear geometry to two equivalent Sb(1) atoms. In the second F site, F(8) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(4) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth F site, F(5) is bonded in a single-bond geometry to one Sb(1) atom. In each XeF4 cluster, Xe(1) is bonded in a square co-planar geometry to two equivalent F(1) and two equivalent F(6) atoms. There are two inequivalent F sites. In the first F site, F(6) is bonded in a single-bond geometry to one Xe(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one Xe(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sb2XeF15
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.278
_cell_length_b   8.278
_cell_length_c   10.645
_cell_angle_alpha   73.456
_cell_angle_beta   73.456
_cell_angle_gamma   64.849
_symmetry_Int_Tables_number   1
_cell_volume   621.537
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.755  0.630  0.618  1.0
  Sb  Sb1  1  0.370  0.245  0.882  1.0
  Sb  Sb2  1  0.245  0.370  0.382  1.0
  Sb  Sb3  1  0.630  0.755  0.118  1.0
  Xe  Xe4  1  0.102  0.898  0.750  1.0
  Xe  Xe5  1  0.898  0.102  0.250  1.0
  F  F6  1  0.961  0.090  0.616  1.0
  F  F7  1  0.910  0.039  0.884  1.0
  F  F8  1  0.039  0.910  0.384  1.0
  F  F9  1  0.090  0.961  0.116  1.0
  F  F10  1  0.878  0.760  0.652  1.0
  F  F11  1  0.240  0.122  0.848  1.0
  F  F12  1  0.122  0.240  0.348  1.0
  F  F13  1  0.760  0.878  0.152  1.0
  F  F14  1  0.706  0.811  0.461  1.0
  F  F15  1  0.189  0.294  0.039  1.0
  F  F16  1  0.294  0.189  0.539  1.0
  F  F17  1  0.811  0.706  0.961  1.0
  F  F18  1  0.661  0.491  0.566  1.0
  F  F19  1  0.509  0.339  0.934  1.0
  F  F20  1  0.339  0.509  0.434  1.0
  F  F21  1  0.491  0.661  0.066  1.0
  F  F22  1  0.844  0.437  0.758  1.0
  F  F23  1  0.563  0.156  0.742  1.0
  F  F24  1  0.156  0.563  0.242  1.0
  F  F25  1  0.437  0.844  0.258  1.0
  F  F26  1  0.273  0.785  0.593  1.0
  F  F27  1  0.215  0.727  0.907  1.0
  F  F28  1  0.727  0.215  0.407  1.0
  F  F29  1  0.785  0.273  0.093  1.0
  F  F30  1  0.000  0.500  0.500  1.0
  F  F31  1  0.500  0.000  0.000  1.0
  F  F32  1  0.532  0.752  0.726  1.0
  F  F33  1  0.248  0.468  0.774  1.0
  F  F34  1  0.468  0.248  0.274  1.0
  F  F35  1  0.752  0.532  0.226  1.0
[/CIF]
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The material described by XeF4Sb2F11 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four Sb2F11 clusters and four XeF4 clusters. In each Sb2F11 cluster, Sb(1) is bonded to one F(2), one F(3), one F(4), one F(5), one F(7), and one F(8) atom to form corner-sharing SbF6 octahedra. The corner-sharing octahedra are not tilted. There are six inequivalent F sites. In the first F site, F(7) is bonded in a linear geometry to two equivalent Sb(1) atoms. In the second F site, F(8) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(4) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth F site, F(5) is bonded in a single-bond geometry to one Sb(1) atom. In each XeF4 cluster, Xe(1) is bonded in a square co-planar geometry to two equivalent F(1) and two equivalent F(6) atoms. There are two inequivalent F sites. In the first F site, F(6) is bonded in a single-bond geometry to one Xe(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one Xe(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sb2XeF15
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.278
_cell_length_b   8.278
_cell_length_c   10.645
_cell_angle_alpha   73.456
_cell_angle_beta   73.456
_cell_angle_gamma   64.849
_symmetry_Int_Tables_number   1
_cell_volume   621.537
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.755  0.630  0.618  1.0
  Sb  Sb1  1  0.370  0.245  0.882  1.0
  Sb  Sb2  1  0.245  0.370  0.382  1.0
  Sb  Sb3  1  0.630  0.755  0.118  1.0
  Xe  Xe4  1  0.102  0.898  0.750  1.0
  Xe  Xe5  1  0.898  0.102  0.250  1.0
  F  F6  1  0.961  0.090  0.616  1.0
  F  F7  1  0.910  0.039  0.884  1.0
  F  F8  1  0.039  0.910  0.384  1.0
  F  F9  1  0.090  0.961  0.116  1.0
  F  F10  1  0.878  0.760  0.652  1.0
  F  F11  1  0.240  0.122  0.848  1.0
  F  F12  1  0.122  0.240  0.348  1.0
  F  F13  1  0.760  0.878  0.152  1.0
  F  F14  1  0.706  0.811  0.461  1.0
  F  F15  1  0.189  0.294  0.039  1.0
  F  F16  1  0.294  0.189  0.539  1.0
  F  F17  1  0.811  0.706  0.961  1.0
  F  F18  1  0.661  0.491  0.566  1.0
  F  F19  1  0.509  0.339  0.934  1.0
  F  F20  1  0.339  0.509  0.434  1.0
  F  F21  1  0.491  0.661  0.066  1.0
  F  F22  1  0.844  0.437  0.758  1.0
  F  F23  1  0.563  0.156  0.742  1.0
  F  F24  1  0.156  0.563  0.242  1.0
  F  F25  1  0.437  0.844  0.258  1.0
  F  F26  1  0.273  0.785  0.593  1.0
  F  F27  1  0.215  0.727  0.907  1.0
  F  F28  1  0.727  0.215  0.407  1.0
  F  F29  1  0.785  0.273  0.093  1.0
  F  F30  1  0.000  0.500  0.500  1.0
  F  F31  1  0.500  0.000  0.000  1.0
  F  F32  1  0.532  0.752  0.726  1.0
  F  F33  1  0.248  0.468  0.774  1.0
  F  F34  1  0.468  0.248  0.274  1.0
  F  F35  1  0.752  0.532  0.226  1.0
[/CIF]
.