The structure described by UCl5 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two UCl5 clusters. U(1) is bonded in a 2-coordinate geometry to one Cl(1), one Cl(2), one Cl(3), one Cl(4), and one Cl(5) atom. There are five inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one U(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one U(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one U(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one U(1) atom. In the fifth Cl site, Cl(5) is bonded in a single-bond geometry to one U(1) atom. is represented by the CIF card [CIF]
data_UCl5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.913
_cell_length_b   7.546
_cell_length_c   10.267
_cell_angle_alpha   108.550
_cell_angle_beta   91.043
_cell_angle_gamma   116.204
_symmetry_Int_Tables_number   1
_cell_volume   447.601
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  U  U0  1  0.893  0.001  0.211  1.0
  U  U1  1  0.107  0.999  0.789  1.0
  Cl  Cl2  1  0.517  0.772  0.420  1.0
  Cl  Cl3  1  0.483  0.228  0.580  1.0
  Cl  Cl4  1  0.273  0.213  0.958  1.0
  Cl  Cl5  1  0.727  0.787  0.042  1.0
  Cl  Cl6  1  0.255  0.771  0.848  1.0
  Cl  Cl7  1  0.745  0.229  0.152  1.0
  Cl  Cl8  1  0.952  0.229  0.748  1.0
  Cl  Cl9  1  0.048  0.771  0.252  1.0
  Cl  Cl10  1  0.895  0.766  0.673  1.0
  Cl  Cl11  1  0.105  0.234  0.327  1.0
[/CIF]
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The structure described by UCl5 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two UCl5 clusters. U(1) is bonded in a 2-coordinate geometry to one Cl(1), one Cl(2), one Cl(3), one Cl(4), and one Cl(5) atom. There are five inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one U(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one U(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one U(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one U(1) atom. In the fifth Cl site, Cl(5) is bonded in a single-bond geometry to one U(1) atom. is represented by the CIF card [CIF]
data_UCl5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.913
_cell_length_b   7.546
_cell_length_c   10.267
_cell_angle_alpha   108.550
_cell_angle_beta   91.043
_cell_angle_gamma   116.204
_symmetry_Int_Tables_number   1
_cell_volume   447.601
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  U  U0  1  0.893  0.001  0.211  1.0
  U  U1  1  0.107  0.999  0.789  1.0
  Cl  Cl2  1  0.517  0.772  0.420  1.0
  Cl  Cl3  1  0.483  0.228  0.580  1.0
  Cl  Cl4  1  0.273  0.213  0.958  1.0
  Cl  Cl5  1  0.727  0.787  0.042  1.0
  Cl  Cl6  1  0.255  0.771  0.848  1.0
  Cl  Cl7  1  0.745  0.229  0.152  1.0
  Cl  Cl8  1  0.952  0.229  0.748  1.0
  Cl  Cl9  1  0.048  0.771  0.252  1.0
  Cl  Cl10  1  0.895  0.766  0.673  1.0
  Cl  Cl11  1  0.105  0.234  0.327  1.0
[/CIF]
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