The compound described by MgWMn2FeO6 crystallizes in the triclinic P1 space group. Mg(1) is bonded to one O(1), one O(2), one O(3), one O(4), and one O(5) atom to form distorted MgO5 trigonal bipyramids that share corners with three equivalent W(1)O6 octahedra,  a cornercorner with one Mn(2)O5 trigonal bipyramid,  an edgeedge with one W(1)O6 octahedra, and edges with two equivalent Mn(2)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 2-70°. W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form WO6 octahedra that share  a cornercorner with one Mn(2)O5 trigonal bipyramid, corners with three equivalent Mg(1)O5 trigonal bipyramids,  an edgeedge with one Mg(1)O5 trigonal bipyramid, and edges with two equivalent Mn(2)O5 trigonal bipyramids. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(4), one O(5), and one O(6) atom. In the second Mn site, Mn(2) is bonded to one O(1), one O(2), one O(3), one O(4), and one O(5) atom to form MnO5 trigonal bipyramids that share  a cornercorner with one W(1)O6 octahedra,  a cornercorner with one Mg(1)O5 trigonal bipyramid, edges with two equivalent W(1)O6 octahedra, and edges with two equivalent Mg(1)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 59°. Fe(1) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(3), one O(4), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to one Mg(1), one W(1), one Mn(1), one Mn(2), and one Fe(1) atom. In the second O site, O(2) is bonded to one Mg(1), one W(1), one Mn(1), one Mn(2), and one Fe(1) atom to form distorted OMgMn2FeW trigonal bipyramids that share corners with three equivalent O(4)MgMn2FeW trigonal bipyramids, corners with two equivalent O(3)MgMnFeW trigonal pyramids,  an edgeedge with one O(4)MgMn2FeW trigonal bipyramid, and  an edgeedge with one O(3)MgMnFeW trigonal pyramid. In the third O site, O(3) is bonded to one Mg(1), one W(1), one Mn(2), and one Fe(1) atom to form a mixture of corner and edge-sharing OMgMnFeW trigonal pyramids. In the fourth O site, O(4) is bonded to one Mg(1), one W(1), one Mn(1), one Mn(2), and one Fe(1) atom to form distorted OMgMn2FeW trigonal bipyramids that share corners with three equivalent O(2)MgMn2FeW trigonal bipyramids, corners with four equivalent O(3)MgMnFeW trigonal pyramids, and  an edgeedge with one O(2)MgMn2FeW trigonal bipyramid. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to one Mg(1), one W(1), one Mn(1), and one Mn(2) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one W(1), one Mn(1), and one Fe(1) atom. is represented by the CIF card [CIF]
data_MgMn2FeWO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.392
_cell_length_b   5.561
_cell_length_c   6.156
_cell_angle_alpha   61.548
_cell_angle_beta   58.309
_cell_angle_gamma   68.330
_symmetry_Int_Tables_number   1
_cell_volume   136.319
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.393  0.853  0.462  1.0
  Mn  Mn1  1  0.833  0.700  0.685  1.0
  Mn  Mn2  1  0.230  0.408  0.105  1.0
  Fe  Fe3  1  0.620  0.268  0.529  1.0
  W  W4  1  0.983  0.027  0.019  1.0
  O  O5  1  0.114  0.996  0.293  1.0
  O  O6  1  0.813  0.640  0.330  1.0
  O  O7  1  0.569  0.221  0.244  1.0
  O  O8  1  0.177  0.410  0.765  1.0
  O  O9  1  0.374  0.805  0.816  1.0
  O  O10  1  0.808  0.048  0.789  1.0
[/CIF]
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The compound described by MgWMn2FeO6 crystallizes in the triclinic P1 space group. Mg(1) is bonded to one O(1), one O(2), one O(3), one O(4), and one O(5) atom to form distorted MgO5 trigonal bipyramids that share corners with three equivalent W(1)O6 octahedra,  a cornercorner with one Mn(2)O5 trigonal bipyramid,  an edgeedge with one W(1)O6 octahedra, and edges with two equivalent Mn(2)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 2-70°. W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form WO6 octahedra that share  a cornercorner with one Mn(2)O5 trigonal bipyramid, corners with three equivalent Mg(1)O5 trigonal bipyramids,  an edgeedge with one Mg(1)O5 trigonal bipyramid, and edges with two equivalent Mn(2)O5 trigonal bipyramids. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(4), one O(5), and one O(6) atom. In the second Mn site, Mn(2) is bonded to one O(1), one O(2), one O(3), one O(4), and one O(5) atom to form MnO5 trigonal bipyramids that share  a cornercorner with one W(1)O6 octahedra,  a cornercorner with one Mg(1)O5 trigonal bipyramid, edges with two equivalent W(1)O6 octahedra, and edges with two equivalent Mg(1)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 59°. Fe(1) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(3), one O(4), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to one Mg(1), one W(1), one Mn(1), one Mn(2), and one Fe(1) atom. In the second O site, O(2) is bonded to one Mg(1), one W(1), one Mn(1), one Mn(2), and one Fe(1) atom to form distorted OMgMn2FeW trigonal bipyramids that share corners with three equivalent O(4)MgMn2FeW trigonal bipyramids, corners with two equivalent O(3)MgMnFeW trigonal pyramids,  an edgeedge with one O(4)MgMn2FeW trigonal bipyramid, and  an edgeedge with one O(3)MgMnFeW trigonal pyramid. In the third O site, O(3) is bonded to one Mg(1), one W(1), one Mn(2), and one Fe(1) atom to form a mixture of corner and edge-sharing OMgMnFeW trigonal pyramids. In the fourth O site, O(4) is bonded to one Mg(1), one W(1), one Mn(1), one Mn(2), and one Fe(1) atom to form distorted OMgMn2FeW trigonal bipyramids that share corners with three equivalent O(2)MgMn2FeW trigonal bipyramids, corners with four equivalent O(3)MgMnFeW trigonal pyramids, and  an edgeedge with one O(2)MgMn2FeW trigonal bipyramid. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to one Mg(1), one W(1), one Mn(1), and one Mn(2) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one W(1), one Mn(1), and one Fe(1) atom. is represented by the CIF card [CIF]
data_MgMn2FeWO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.392
_cell_length_b   5.561
_cell_length_c   6.156
_cell_angle_alpha   61.548
_cell_angle_beta   58.309
_cell_angle_gamma   68.330
_symmetry_Int_Tables_number   1
_cell_volume   136.319
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.393  0.853  0.462  1.0
  Mn  Mn1  1  0.833  0.700  0.685  1.0
  Mn  Mn2  1  0.230  0.408  0.105  1.0
  Fe  Fe3  1  0.620  0.268  0.529  1.0
  W  W4  1  0.983  0.027  0.019  1.0
  O  O5  1  0.114  0.996  0.293  1.0
  O  O6  1  0.813  0.640  0.330  1.0
  O  O7  1  0.569  0.221  0.244  1.0
  O  O8  1  0.177  0.410  0.765  1.0
  O  O9  1  0.374  0.805  0.816  1.0
  O  O10  1  0.808  0.048  0.789  1.0
[/CIF]
.