The material structure described by Zr(PbO3)2 crystallizes in the monoclinic P2_1 space group. There are two inequivalent Zr sites. In the first Zr site, Zr(1) is bonded in a 6-coordinate geometry to one O(10), one O(2), one O(3), one O(5), one O(6), and one O(9) atom. In the second Zr site, Zr(2) is bonded to one O(11), one O(12), one O(2), one O(3), one O(7), and one O(8) atom to form distorted ZrO6 pentagonal pyramids that share  a cornercorner with one Pb(3)O6 pentagonal pyramid and  an edgeedge with one Pb(3)O6 pentagonal pyramid. There are four inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(4), one O(6), and two equivalent O(9) atoms. In the second Pb site, Pb(2) is bonded in a 6-coordinate geometry to one O(10), one O(7), two equivalent O(5), and two equivalent O(6) atoms. In the third Pb site, Pb(3) is bonded to one O(1), one O(10), one O(11), one O(12), one O(4), and one O(7) atom to form distorted PbO6 pentagonal pyramids that share  a cornercorner with one Zr(2)O6 pentagonal pyramid and  an edgeedge with one Zr(2)O6 pentagonal pyramid. In the fourth Pb site, Pb(4) is bonded in a 5-coordinate geometry to one O(1), one O(11), one O(2), and two equivalent O(8) atoms. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Pb(1), one Pb(3), and one Pb(4) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one Zr(1), one Zr(2), one Pb(1), and one Pb(4) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Zr(1) and one Zr(2) atom. In the fourth O site, O(4) is bonded in a distorted water-like geometry to one Pb(1) and one Pb(3) atom. In the fifth O site, O(5) is bonded in a trigonal non-coplanar geometry to one Zr(1) and two equivalent Pb(2) atoms. In the sixth O site, O(6) is bonded in a distorted rectangular see-saw-like geometry to one Zr(1), one Pb(1), and two equivalent Pb(2) atoms. In the seventh O site, O(7) is bonded in a distorted trigonal planar geometry to one Zr(2), one Pb(2), and one Pb(3) atom. In the eighth O site, O(8) is bonded in a distorted trigonal non-coplanar geometry to one Zr(2) and two equivalent Pb(4) atoms. In the ninth O site, O(9) is bonded in a distorted trigonal non-coplanar geometry to one Zr(1) and two equivalent Pb(1) atoms. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Zr(1), one Pb(2), and one Pb(3) atom. In the eleventh O site, O(11) is bonded in a distorted T-shaped geometry to one Zr(2), one Pb(3), and one Pb(4) atom. In the twelfth O site, O(12) is bonded in a distorted bent 120 degrees geometry to one Zr(2) and one Pb(3) atom. is represented by the CIF card [CIF]
data_Zr(PbO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.909
_cell_length_b   8.782
_cell_length_c   11.287
_cell_angle_alpha   89.734
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   585.719
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr0  1  0.255  0.743  0.086  1.0
  Zr  Zr1  1  0.222  0.252  0.609  1.0
  Zr  Zr2  1  0.755  0.257  0.414  1.0
  Zr  Zr3  1  0.722  0.748  0.891  1.0
  Pb  Pb4  1  0.970  0.886  0.349  1.0
  Pb  Pb5  1  0.330  0.515  0.336  1.0
  Pb  Pb6  1  0.394  0.408  0.936  1.0
  Pb  Pb7  1  0.363  0.061  0.865  1.0
  Pb  Pb8  1  0.470  0.114  0.151  1.0
  Pb  Pb9  1  0.830  0.485  0.164  1.0
  Pb  Pb10  1  0.863  0.939  0.635  1.0
  Pb  Pb11  1  0.894  0.592  0.564  1.0
  O  O12  1  0.191  0.187  0.993  1.0
  O  O13  1  0.995  0.109  0.496  1.0
  O  O14  1  0.993  0.808  0.990  1.0
  O  O15  1  0.139  0.766  0.487  1.0
  O  O16  1  0.022  0.358  0.283  1.0
  O  O17  1  0.036  0.684  0.239  1.0
  O  O18  1  0.191  0.449  0.497  1.0
  O  O19  1  0.142  0.048  0.713  1.0
  O  O20  1  0.253  0.939  0.214  1.0
  O  O21  1  0.178  0.512  0.065  1.0
  O  O22  1  0.405  0.283  0.767  1.0
  O  O23  1  0.421  0.630  0.856  1.0
  O  O24  1  0.493  0.192  0.510  1.0
  O  O25  1  0.639  0.234  0.013  1.0
  O  O26  1  0.691  0.813  0.507  1.0
  O  O27  1  0.495  0.891  0.004  1.0
  O  O28  1  0.536  0.316  0.261  1.0
  O  O29  1  0.522  0.642  0.217  1.0
  O  O30  1  0.691  0.551  0.003  1.0
  O  O31  1  0.642  0.952  0.787  1.0
  O  O32  1  0.753  0.061  0.286  1.0
  O  O33  1  0.678  0.488  0.435  1.0
  O  O34  1  0.921  0.370  0.644  1.0
  O  O35  1  0.905  0.717  0.733  1.0
[/CIF]
.
The material structure described by Zr(PbO3)2 crystallizes in the monoclinic P2_1 space group. There are two inequivalent Zr sites. In the first Zr site, Zr(1) is bonded in a 6-coordinate geometry to one O(10), one O(2), one O(3), one O(5), one O(6), and one O(9) atom. In the second Zr site, Zr(2) is bonded to one O(11), one O(12), one O(2), one O(3), one O(7), and one O(8) atom to form distorted ZrO6 pentagonal pyramids that share  a cornercorner with one Pb(3)O6 pentagonal pyramid and  an edgeedge with one Pb(3)O6 pentagonal pyramid. There are four inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(4), one O(6), and two equivalent O(9) atoms. In the second Pb site, Pb(2) is bonded in a 6-coordinate geometry to one O(10), one O(7), two equivalent O(5), and two equivalent O(6) atoms. In the third Pb site, Pb(3) is bonded to one O(1), one O(10), one O(11), one O(12), one O(4), and one O(7) atom to form distorted PbO6 pentagonal pyramids that share  a cornercorner with one Zr(2)O6 pentagonal pyramid and  an edgeedge with one Zr(2)O6 pentagonal pyramid. In the fourth Pb site, Pb(4) is bonded in a 5-coordinate geometry to one O(1), one O(11), one O(2), and two equivalent O(8) atoms. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Pb(1), one Pb(3), and one Pb(4) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one Zr(1), one Zr(2), one Pb(1), and one Pb(4) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Zr(1) and one Zr(2) atom. In the fourth O site, O(4) is bonded in a distorted water-like geometry to one Pb(1) and one Pb(3) atom. In the fifth O site, O(5) is bonded in a trigonal non-coplanar geometry to one Zr(1) and two equivalent Pb(2) atoms. In the sixth O site, O(6) is bonded in a distorted rectangular see-saw-like geometry to one Zr(1), one Pb(1), and two equivalent Pb(2) atoms. In the seventh O site, O(7) is bonded in a distorted trigonal planar geometry to one Zr(2), one Pb(2), and one Pb(3) atom. In the eighth O site, O(8) is bonded in a distorted trigonal non-coplanar geometry to one Zr(2) and two equivalent Pb(4) atoms. In the ninth O site, O(9) is bonded in a distorted trigonal non-coplanar geometry to one Zr(1) and two equivalent Pb(1) atoms. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Zr(1), one Pb(2), and one Pb(3) atom. In the eleventh O site, O(11) is bonded in a distorted T-shaped geometry to one Zr(2), one Pb(3), and one Pb(4) atom. In the twelfth O site, O(12) is bonded in a distorted bent 120 degrees geometry to one Zr(2) and one Pb(3) atom. is represented by the CIF card [CIF]
data_Zr(PbO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.909
_cell_length_b   8.782
_cell_length_c   11.287
_cell_angle_alpha   89.734
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   585.719
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr0  1  0.255  0.743  0.086  1.0
  Zr  Zr1  1  0.222  0.252  0.609  1.0
  Zr  Zr2  1  0.755  0.257  0.414  1.0
  Zr  Zr3  1  0.722  0.748  0.891  1.0
  Pb  Pb4  1  0.970  0.886  0.349  1.0
  Pb  Pb5  1  0.330  0.515  0.336  1.0
  Pb  Pb6  1  0.394  0.408  0.936  1.0
  Pb  Pb7  1  0.363  0.061  0.865  1.0
  Pb  Pb8  1  0.470  0.114  0.151  1.0
  Pb  Pb9  1  0.830  0.485  0.164  1.0
  Pb  Pb10  1  0.863  0.939  0.635  1.0
  Pb  Pb11  1  0.894  0.592  0.564  1.0
  O  O12  1  0.191  0.187  0.993  1.0
  O  O13  1  0.995  0.109  0.496  1.0
  O  O14  1  0.993  0.808  0.990  1.0
  O  O15  1  0.139  0.766  0.487  1.0
  O  O16  1  0.022  0.358  0.283  1.0
  O  O17  1  0.036  0.684  0.239  1.0
  O  O18  1  0.191  0.449  0.497  1.0
  O  O19  1  0.142  0.048  0.713  1.0
  O  O20  1  0.253  0.939  0.214  1.0
  O  O21  1  0.178  0.512  0.065  1.0
  O  O22  1  0.405  0.283  0.767  1.0
  O  O23  1  0.421  0.630  0.856  1.0
  O  O24  1  0.493  0.192  0.510  1.0
  O  O25  1  0.639  0.234  0.013  1.0
  O  O26  1  0.691  0.813  0.507  1.0
  O  O27  1  0.495  0.891  0.004  1.0
  O  O28  1  0.536  0.316  0.261  1.0
  O  O29  1  0.522  0.642  0.217  1.0
  O  O30  1  0.691  0.551  0.003  1.0
  O  O31  1  0.642  0.952  0.787  1.0
  O  O32  1  0.753  0.061  0.286  1.0
  O  O33  1  0.678  0.488  0.435  1.0
  O  O34  1  0.921  0.370  0.644  1.0
  O  O35  1  0.905  0.717  0.733  1.0
[/CIF]
.