The structure described by NHS9 is Indium-like structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four nonathiazecane molecules. N(1) is bonded in a distorted trigonal planar geometry to one H(1) and two equivalent S(5) atoms. H(1) is bonded in a single-bond geometry to one N(1) atom. There are five inequivalent S sites. In the first S site, S(5) is bonded in a distorted single-bond geometry to one N(1) and one S(4) atom. In the second S site, S(1) is bonded in a water-like geometry to two equivalent S(2) atoms. In the third S site, S(2) is bonded in a bent 120 degrees geometry to one S(1) and one S(3) atom. In the fourth S site, S(3) is bonded in a water-like geometry to one S(2) and one S(4) atom. In the fifth S site, S(4) is bonded in a water-like geometry to one S(3) and one S(5) atom. is represented by the CIF card [CIF]
data_HS9N
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.582
_cell_length_b   14.273
_cell_length_c   15.191
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1210.292
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.831  0.350  0.750  1.0
  H  H1  1  0.331  0.150  0.250  1.0
  H  H2  1  0.669  0.850  0.750  1.0
  H  H3  1  0.169  0.650  0.250  1.0
  S  S4  1  0.320  0.537  0.750  1.0
  S  S5  1  0.820  0.963  0.250  1.0
  S  S6  1  0.180  0.037  0.750  1.0
  S  S7  1  0.680  0.463  0.250  1.0
  S  S8  1  0.148  0.478  0.642  1.0
  S  S9  1  0.648  0.022  0.358  1.0
  S  S10  1  0.352  0.978  0.858  1.0
  S  S11  1  0.852  0.522  0.142  1.0
  S  S12  1  0.852  0.522  0.358  1.0
  S  S13  1  0.352  0.978  0.642  1.0
  S  S14  1  0.648  0.022  0.142  1.0
  S  S15  1  0.148  0.478  0.858  1.0
  S  S16  1  0.369  0.397  0.565  1.0
  S  S17  1  0.869  0.103  0.435  1.0
  S  S18  1  0.131  0.897  0.935  1.0
  S  S19  1  0.631  0.603  0.065  1.0
  S  S20  1  0.631  0.603  0.435  1.0
  S  S21  1  0.131  0.897  0.565  1.0
  S  S22  1  0.869  0.103  0.065  1.0
  S  S23  1  0.369  0.397  0.935  1.0
  S  S24  1  0.372  0.260  0.614  1.0
  S  S25  1  0.872  0.240  0.386  1.0
  S  S26  1  0.128  0.760  0.886  1.0
  S  S27  1  0.628  0.740  0.114  1.0
  S  S28  1  0.628  0.740  0.386  1.0
  S  S29  1  0.128  0.760  0.614  1.0
  S  S30  1  0.872  0.240  0.114  1.0
  S  S31  1  0.372  0.260  0.886  1.0
  S  S32  1  0.721  0.234  0.651  1.0
  S  S33  1  0.221  0.266  0.349  1.0
  S  S34  1  0.779  0.734  0.849  1.0
  S  S35  1  0.279  0.766  0.151  1.0
  S  S36  1  0.279  0.766  0.349  1.0
  S  S37  1  0.779  0.734  0.651  1.0
  S  S38  1  0.221  0.266  0.151  1.0
  S  S39  1  0.721  0.234  0.849  1.0
  N  N40  1  0.779  0.281  0.750  1.0
  N  N41  1  0.279  0.219  0.250  1.0
  N  N42  1  0.721  0.781  0.750  1.0
  N  N43  1  0.221  0.719  0.250  1.0
[/CIF]
.
The structure described by NHS9 is Indium-like structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four nonathiazecane molecules. N(1) is bonded in a distorted trigonal planar geometry to one H(1) and two equivalent S(5) atoms. H(1) is bonded in a single-bond geometry to one N(1) atom. There are five inequivalent S sites. In the first S site, S(5) is bonded in a distorted single-bond geometry to one N(1) and one S(4) atom. In the second S site, S(1) is bonded in a water-like geometry to two equivalent S(2) atoms. In the third S site, S(2) is bonded in a bent 120 degrees geometry to one S(1) and one S(3) atom. In the fourth S site, S(3) is bonded in a water-like geometry to one S(2) and one S(4) atom. In the fifth S site, S(4) is bonded in a water-like geometry to one S(3) and one S(5) atom. is represented by the CIF card [CIF]
data_HS9N
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.582
_cell_length_b   14.273
_cell_length_c   15.191
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1210.292
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.831  0.350  0.750  1.0
  H  H1  1  0.331  0.150  0.250  1.0
  H  H2  1  0.669  0.850  0.750  1.0
  H  H3  1  0.169  0.650  0.250  1.0
  S  S4  1  0.320  0.537  0.750  1.0
  S  S5  1  0.820  0.963  0.250  1.0
  S  S6  1  0.180  0.037  0.750  1.0
  S  S7  1  0.680  0.463  0.250  1.0
  S  S8  1  0.148  0.478  0.642  1.0
  S  S9  1  0.648  0.022  0.358  1.0
  S  S10  1  0.352  0.978  0.858  1.0
  S  S11  1  0.852  0.522  0.142  1.0
  S  S12  1  0.852  0.522  0.358  1.0
  S  S13  1  0.352  0.978  0.642  1.0
  S  S14  1  0.648  0.022  0.142  1.0
  S  S15  1  0.148  0.478  0.858  1.0
  S  S16  1  0.369  0.397  0.565  1.0
  S  S17  1  0.869  0.103  0.435  1.0
  S  S18  1  0.131  0.897  0.935  1.0
  S  S19  1  0.631  0.603  0.065  1.0
  S  S20  1  0.631  0.603  0.435  1.0
  S  S21  1  0.131  0.897  0.565  1.0
  S  S22  1  0.869  0.103  0.065  1.0
  S  S23  1  0.369  0.397  0.935  1.0
  S  S24  1  0.372  0.260  0.614  1.0
  S  S25  1  0.872  0.240  0.386  1.0
  S  S26  1  0.128  0.760  0.886  1.0
  S  S27  1  0.628  0.740  0.114  1.0
  S  S28  1  0.628  0.740  0.386  1.0
  S  S29  1  0.128  0.760  0.614  1.0
  S  S30  1  0.872  0.240  0.114  1.0
  S  S31  1  0.372  0.260  0.886  1.0
  S  S32  1  0.721  0.234  0.651  1.0
  S  S33  1  0.221  0.266  0.349  1.0
  S  S34  1  0.779  0.734  0.849  1.0
  S  S35  1  0.279  0.766  0.151  1.0
  S  S36  1  0.279  0.766  0.349  1.0
  S  S37  1  0.779  0.734  0.651  1.0
  S  S38  1  0.221  0.266  0.151  1.0
  S  S39  1  0.721  0.234  0.849  1.0
  N  N40  1  0.779  0.281  0.750  1.0
  N  N41  1  0.279  0.219  0.250  1.0
  N  N42  1  0.721  0.781  0.750  1.0
  N  N43  1  0.221  0.719  0.250  1.0
[/CIF]
.