The structure described by Rb4Sn(SO)4 crystallizes in the triclinic P-1 space group. There are four inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 6-coordinate geometry to one S(4), two equivalent S(1), two equivalent S(2), and one O(1) atom. In the second Rb site, Rb(2) is bonded in a 1-coordinate geometry to one S(2) and one O(2) atom. In the third Rb site, Rb(3) is bonded in a 6-coordinate geometry to one S(4), one O(1), one O(2), one O(4), and two equivalent O(3) atoms. In the fourth Rb site, Rb(4) is bonded in a 5-coordinate geometry to two equivalent S(2), one O(1), one O(2), and one O(4) atom. Sn(1) is bonded in a 4-coordinate geometry to one S(1), one S(2), one S(3), and one S(4) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a 1-coordinate geometry to two equivalent Rb(1), one Sn(1), and one O(2) atom. In the second S site, S(2) is bonded in a 6-coordinate geometry to one Rb(2), two equivalent Rb(1), two equivalent Rb(4), and one Sn(1) atom. In the third S site, S(3) is bonded in a distorted water-like geometry to one Sn(1), one O(3), and one O(4) atom. In the fourth S site, S(4) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(3), one Sn(1), and one O(1) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Rb(1), one Rb(3), one Rb(4), and one S(4) atom. In the second O site, O(2) is bonded in a distorted tetrahedral geometry to one Rb(2), one Rb(3), one Rb(4), and one S(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to two equivalent Rb(3) and one S(3) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Rb(3), one Rb(4), and one S(3) atom. is represented by the CIF card [CIF]
data_Rb4Sn(SO)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.248
_cell_length_b   8.357
_cell_length_c   13.541
_cell_angle_alpha   102.440
_cell_angle_beta   97.037
_cell_angle_gamma   94.859
_symmetry_Int_Tables_number   1
_cell_volume   789.733
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.346  0.185  0.524  1.0
  Rb  Rb1  1  0.654  0.815  0.476  1.0
  Rb  Rb2  1  0.849  0.927  0.788  1.0
  Rb  Rb3  1  0.151  0.073  0.212  1.0
  Rb  Rb4  1  0.668  0.497  0.900  1.0
  Rb  Rb5  1  0.332  0.503  0.100  1.0
  Rb  Rb6  1  0.024  0.446  0.675  1.0
  Rb  Rb7  1  0.976  0.554  0.325  1.0
  Sn  Sn8  1  0.323  0.845  0.728  1.0
  Sn  Sn9  1  0.677  0.155  0.272  1.0
  S  S10  1  0.516  0.623  0.652  1.0
  S  S11  1  0.484  0.377  0.348  1.0
  S  S12  1  0.088  0.807  0.581  1.0
  S  S13  1  0.912  0.193  0.419  1.0
  S  S14  1  0.231  0.789  0.922  1.0
  S  S15  1  0.769  0.211  0.078  1.0
  S  S16  1  0.484  0.137  0.746  1.0
  S  S17  1  0.516  0.863  0.254  1.0
  O  O18  1  0.323  0.255  0.735  1.0
  O  O19  1  0.677  0.745  0.265  1.0
  O  O20  1  0.702  0.603  0.724  1.0
  O  O21  1  0.298  0.397  0.276  1.0
  O  O22  1  0.406  0.716  0.955  1.0
  O  O23  1  0.594  0.284  0.045  1.0
  O  O24  1  0.060  0.660  0.897  1.0
  O  O25  1  0.940  0.340  0.103  1.0
[/CIF]
.
The structure described by Rb4Sn(SO)4 crystallizes in the triclinic P-1 space group. There are four inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 6-coordinate geometry to one S(4), two equivalent S(1), two equivalent S(2), and one O(1) atom. In the second Rb site, Rb(2) is bonded in a 1-coordinate geometry to one S(2) and one O(2) atom. In the third Rb site, Rb(3) is bonded in a 6-coordinate geometry to one S(4), one O(1), one O(2), one O(4), and two equivalent O(3) atoms. In the fourth Rb site, Rb(4) is bonded in a 5-coordinate geometry to two equivalent S(2), one O(1), one O(2), and one O(4) atom. Sn(1) is bonded in a 4-coordinate geometry to one S(1), one S(2), one S(3), and one S(4) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a 1-coordinate geometry to two equivalent Rb(1), one Sn(1), and one O(2) atom. In the second S site, S(2) is bonded in a 6-coordinate geometry to one Rb(2), two equivalent Rb(1), two equivalent Rb(4), and one Sn(1) atom. In the third S site, S(3) is bonded in a distorted water-like geometry to one Sn(1), one O(3), and one O(4) atom. In the fourth S site, S(4) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(3), one Sn(1), and one O(1) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Rb(1), one Rb(3), one Rb(4), and one S(4) atom. In the second O site, O(2) is bonded in a distorted tetrahedral geometry to one Rb(2), one Rb(3), one Rb(4), and one S(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to two equivalent Rb(3) and one S(3) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Rb(3), one Rb(4), and one S(3) atom. is represented by the CIF card [CIF]
data_Rb4Sn(SO)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.248
_cell_length_b   8.357
_cell_length_c   13.541
_cell_angle_alpha   102.440
_cell_angle_beta   97.037
_cell_angle_gamma   94.859
_symmetry_Int_Tables_number   1
_cell_volume   789.733
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.346  0.185  0.524  1.0
  Rb  Rb1  1  0.654  0.815  0.476  1.0
  Rb  Rb2  1  0.849  0.927  0.788  1.0
  Rb  Rb3  1  0.151  0.073  0.212  1.0
  Rb  Rb4  1  0.668  0.497  0.900  1.0
  Rb  Rb5  1  0.332  0.503  0.100  1.0
  Rb  Rb6  1  0.024  0.446  0.675  1.0
  Rb  Rb7  1  0.976  0.554  0.325  1.0
  Sn  Sn8  1  0.323  0.845  0.728  1.0
  Sn  Sn9  1  0.677  0.155  0.272  1.0
  S  S10  1  0.516  0.623  0.652  1.0
  S  S11  1  0.484  0.377  0.348  1.0
  S  S12  1  0.088  0.807  0.581  1.0
  S  S13  1  0.912  0.193  0.419  1.0
  S  S14  1  0.231  0.789  0.922  1.0
  S  S15  1  0.769  0.211  0.078  1.0
  S  S16  1  0.484  0.137  0.746  1.0
  S  S17  1  0.516  0.863  0.254  1.0
  O  O18  1  0.323  0.255  0.735  1.0
  O  O19  1  0.677  0.745  0.265  1.0
  O  O20  1  0.702  0.603  0.724  1.0
  O  O21  1  0.298  0.397  0.276  1.0
  O  O22  1  0.406  0.716  0.955  1.0
  O  O23  1  0.594  0.284  0.045  1.0
  O  O24  1  0.060  0.660  0.897  1.0
  O  O25  1  0.940  0.340  0.103  1.0
[/CIF]
.