The crystal structure described by VOF is Baddeleyite-derived structured and crystallizes in the monoclinic P2_1/c space group. V(1) is bonded to four equivalent O(1) and three equivalent F(1) atoms to form a mixture of distorted corner and edge-sharing VO4F3 pentagonal bipyramids. O(1) is bonded to four equivalent V(1) atoms to form a mixture of corner and edge-sharing OV4 tetrahedra. F(1) is bonded in a distorted trigonal non-coplanar geometry to three equivalent V(1) atoms. is represented by the CIF card [CIF]
data_VOF
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.872
_cell_length_b   5.042
_cell_length_c   5.055
_cell_angle_alpha   101.948
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   121.478
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.966  0.795  0.695  1.0
  V  V1  1  0.534  0.295  0.695  1.0
  V  V2  1  0.466  0.705  0.305  1.0
  V  V3  1  0.034  0.205  0.305  1.0
  O  O4  1  0.747  0.990  0.455  1.0
  O  O5  1  0.753  0.490  0.455  1.0
  O  O6  1  0.247  0.510  0.545  1.0
  O  O7  1  0.253  0.010  0.545  1.0
  F  F8  1  0.197  0.861  0.049  1.0
  F  F9  1  0.303  0.361  0.049  1.0
  F  F10  1  0.697  0.639  0.951  1.0
  F  F11  1  0.803  0.139  0.951  1.0
[/CIF]
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The crystal structure described by VOF is Baddeleyite-derived structured and crystallizes in the monoclinic P2_1/c space group. V(1) is bonded to four equivalent O(1) and three equivalent F(1) atoms to form a mixture of distorted corner and edge-sharing VO4F3 pentagonal bipyramids. O(1) is bonded to four equivalent V(1) atoms to form a mixture of corner and edge-sharing OV4 tetrahedra. F(1) is bonded in a distorted trigonal non-coplanar geometry to three equivalent V(1) atoms. is represented by the CIF card [CIF]
data_VOF
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.872
_cell_length_b   5.042
_cell_length_c   5.055
_cell_angle_alpha   101.948
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   121.478
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.966  0.795  0.695  1.0
  V  V1  1  0.534  0.295  0.695  1.0
  V  V2  1  0.466  0.705  0.305  1.0
  V  V3  1  0.034  0.205  0.305  1.0
  O  O4  1  0.747  0.990  0.455  1.0
  O  O5  1  0.753  0.490  0.455  1.0
  O  O6  1  0.247  0.510  0.545  1.0
  O  O7  1  0.253  0.010  0.545  1.0
  F  F8  1  0.197  0.861  0.049  1.0
  F  F9  1  0.303  0.361  0.049  1.0
  F  F10  1  0.697  0.639  0.951  1.0
  F  F11  1  0.803  0.139  0.951  1.0
[/CIF]
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