The material structure described by KIn(GeO3)4 crystallizes in the orthorhombic Amm2 space group. K(1) is bonded in a 10-coordinate geometry to two equivalent O(3), four equivalent O(1), and four equivalent O(4) atoms. In(1) is bonded in a 6-coordinate geometry to two equivalent O(2), two equivalent O(3), and two equivalent O(5) atoms. Ge(1) is bonded to one O(2), one O(3), one O(4), one O(5), and two equivalent O(1) atoms to form corner-sharing GeO6 octahedra. The corner-sharing octahedral tilt angles range from 13-34°. There are five inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one K(1) and two equivalent Ge(1) atoms. In the second O site, O(2) is bonded in a 3-coordinate geometry to one In(1) and two equivalent Ge(1) atoms. In the third O site, O(3) is bonded in a distorted square co-planar geometry to one K(1), one In(1), and two equivalent Ge(1) atoms. In the fourth O site, O(4) is bonded in a distorted square co-planar geometry to two equivalent K(1) and two equivalent Ge(1) atoms. In the fifth O site, O(5) is bonded in a distorted T-shaped geometry to one In(1) and two equivalent Ge(1) atoms. is represented by the CIF file [CIF]
data_KIn(GeO3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.306
_cell_length_b   5.306
_cell_length_c   7.510
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   88.839
_symmetry_Int_Tables_number   1
_cell_volume   211.432
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.984  0.016  0.000  1.0
  In  In1  1  0.518  0.482  0.500  1.0
  Ge  Ge2  1  0.494  0.990  0.245  1.0
  Ge  Ge3  1  0.494  0.990  0.755  1.0
  Ge  Ge4  1  0.010  0.506  0.755  1.0
  Ge  Ge5  1  0.010  0.506  0.245  1.0
  O  O6  1  0.221  0.220  0.265  1.0
  O  O7  1  0.780  0.779  0.265  1.0
  O  O8  1  0.780  0.779  0.735  1.0
  O  O9  1  0.221  0.220  0.735  1.0
  O  O10  1  0.296  0.704  0.306  1.0
  O  O11  1  0.711  0.289  0.237  1.0
  O  O12  1  0.711  0.289  0.763  1.0
  O  O13  1  0.296  0.704  0.694  1.0
  O  O14  1  0.475  0.958  0.000  1.0
  O  O15  1  0.521  0.068  0.500  1.0
  O  O16  1  0.042  0.525  0.000  1.0
  O  O17  1  0.932  0.479  0.500  1.0
[/CIF]
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The material structure described by KIn(GeO3)4 crystallizes in the orthorhombic Amm2 space group. K(1) is bonded in a 10-coordinate geometry to two equivalent O(3), four equivalent O(1), and four equivalent O(4) atoms. In(1) is bonded in a 6-coordinate geometry to two equivalent O(2), two equivalent O(3), and two equivalent O(5) atoms. Ge(1) is bonded to one O(2), one O(3), one O(4), one O(5), and two equivalent O(1) atoms to form corner-sharing GeO6 octahedra. The corner-sharing octahedral tilt angles range from 13-34°. There are five inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one K(1) and two equivalent Ge(1) atoms. In the second O site, O(2) is bonded in a 3-coordinate geometry to one In(1) and two equivalent Ge(1) atoms. In the third O site, O(3) is bonded in a distorted square co-planar geometry to one K(1), one In(1), and two equivalent Ge(1) atoms. In the fourth O site, O(4) is bonded in a distorted square co-planar geometry to two equivalent K(1) and two equivalent Ge(1) atoms. In the fifth O site, O(5) is bonded in a distorted T-shaped geometry to one In(1) and two equivalent Ge(1) atoms. is represented by the CIF file [CIF]
data_KIn(GeO3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.306
_cell_length_b   5.306
_cell_length_c   7.510
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   88.839
_symmetry_Int_Tables_number   1
_cell_volume   211.432
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.984  0.016  0.000  1.0
  In  In1  1  0.518  0.482  0.500  1.0
  Ge  Ge2  1  0.494  0.990  0.245  1.0
  Ge  Ge3  1  0.494  0.990  0.755  1.0
  Ge  Ge4  1  0.010  0.506  0.755  1.0
  Ge  Ge5  1  0.010  0.506  0.245  1.0
  O  O6  1  0.221  0.220  0.265  1.0
  O  O7  1  0.780  0.779  0.265  1.0
  O  O8  1  0.780  0.779  0.735  1.0
  O  O9  1  0.221  0.220  0.735  1.0
  O  O10  1  0.296  0.704  0.306  1.0
  O  O11  1  0.711  0.289  0.237  1.0
  O  O12  1  0.711  0.289  0.763  1.0
  O  O13  1  0.296  0.704  0.694  1.0
  O  O14  1  0.475  0.958  0.000  1.0
  O  O15  1  0.521  0.068  0.500  1.0
  O  O16  1  0.042  0.525  0.000  1.0
  O  O17  1  0.932  0.479  0.500  1.0
[/CIF]
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