The crystal structure described by ZnGeAsP is Stannite-like structured and crystallizes in the orthorhombic I2_12_12_1 space group. Zn(1) is bonded to two equivalent As(1) and two equivalent P(1) atoms to form ZnAs2P2 tetrahedra that share corners with four equivalent Zn(1)As2P2 tetrahedra and corners with eight equivalent Ge(1)As2P2 tetrahedra. Ge(1) is bonded to two equivalent As(1) and two equivalent P(1) atoms to form GeAs2P2 tetrahedra that share corners with four equivalent Ge(1)As2P2 tetrahedra and corners with eight equivalent Zn(1)As2P2 tetrahedra. As(1) is bonded to two equivalent Zn(1) and two equivalent Ge(1) atoms to form AsZn2Ge2 tetrahedra that share corners with four equivalent As(1)Zn2Ge2 tetrahedra and corners with eight equivalent P(1)Zn2Ge2 tetrahedra. P(1) is bonded to two equivalent Zn(1) and two equivalent Ge(1) atoms to form PZn2Ge2 tetrahedra that share corners with four equivalent P(1)Zn2Ge2 tetrahedra and corners with eight equivalent As(1)Zn2Ge2 tetrahedra. is represented by the CIF card [CIF]
data_ZnGeAsP
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.833
_cell_length_b   6.833
_cell_length_c   6.833
_cell_angle_alpha   131.583
_cell_angle_beta   131.258
_cell_angle_gamma   71.146
_symmetry_Int_Tables_number   1
_cell_volume   175.640
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.631  0.381  0.250  1.0
  Zn  Zn1  1  0.869  0.119  0.750  1.0
  Ge  Ge2  1  0.130  0.880  0.250  1.0
  Ge  Ge3  1  0.370  0.620  0.750  1.0
  As  As4  1  0.250  0.499  0.249  1.0
  As  As5  1  0.750  0.001  0.251  1.0
  P  P6  1  0.494  0.250  0.744  1.0
  P  P7  1  0.006  0.750  0.756  1.0
[/CIF]
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The crystal structure described by ZnGeAsP is Stannite-like structured and crystallizes in the orthorhombic I2_12_12_1 space group. Zn(1) is bonded to two equivalent As(1) and two equivalent P(1) atoms to form ZnAs2P2 tetrahedra that share corners with four equivalent Zn(1)As2P2 tetrahedra and corners with eight equivalent Ge(1)As2P2 tetrahedra. Ge(1) is bonded to two equivalent As(1) and two equivalent P(1) atoms to form GeAs2P2 tetrahedra that share corners with four equivalent Ge(1)As2P2 tetrahedra and corners with eight equivalent Zn(1)As2P2 tetrahedra. As(1) is bonded to two equivalent Zn(1) and two equivalent Ge(1) atoms to form AsZn2Ge2 tetrahedra that share corners with four equivalent As(1)Zn2Ge2 tetrahedra and corners with eight equivalent P(1)Zn2Ge2 tetrahedra. P(1) is bonded to two equivalent Zn(1) and two equivalent Ge(1) atoms to form PZn2Ge2 tetrahedra that share corners with four equivalent P(1)Zn2Ge2 tetrahedra and corners with eight equivalent As(1)Zn2Ge2 tetrahedra. is represented by the CIF card [CIF]
data_ZnGeAsP
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.833
_cell_length_b   6.833
_cell_length_c   6.833
_cell_angle_alpha   131.583
_cell_angle_beta   131.258
_cell_angle_gamma   71.146
_symmetry_Int_Tables_number   1
_cell_volume   175.640
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.631  0.381  0.250  1.0
  Zn  Zn1  1  0.869  0.119  0.750  1.0
  Ge  Ge2  1  0.130  0.880  0.250  1.0
  Ge  Ge3  1  0.370  0.620  0.750  1.0
  As  As4  1  0.250  0.499  0.249  1.0
  As  As5  1  0.750  0.001  0.251  1.0
  P  P6  1  0.494  0.250  0.744  1.0
  P  P7  1  0.006  0.750  0.756  1.0
[/CIF]
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