The compound described by Ho2Mn3Sb3O14 crystallizes in the monoclinic C2/m space group. There are two inequivalent Ho sites. In the first Ho site, Ho(1) is bonded to two equivalent O(1), two equivalent O(3), and four equivalent O(5) atoms to form distorted HoO8 hexagonal bipyramids that share edges with two equivalent Sb(1)O6 octahedra and edges with four equivalent Sb(2)O6 octahedra. In the second Ho site, Ho(2) is bonded in a distorted body-centered cubic geometry to two equivalent O(1), two equivalent O(3), and four equivalent O(4) atoms. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a distorted body-centered cubic geometry to two equivalent O(1), two equivalent O(2), two equivalent O(4), and two equivalent O(5) atoms. In the second Mn site, Mn(2) is bonded to two equivalent O(2) and four equivalent O(4) atoms to form MnO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra and corners with four equivalent Sb(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-52°. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to two equivalent O(2) and four equivalent O(5) atoms to form SbO6 octahedra that share corners with two equivalent Mn(2)O6 octahedra, corners with four equivalent Sb(2)O6 octahedra, and edges with two equivalent Ho(1)O8 hexagonal bipyramids. The corner-sharing octahedral tilt angles range from 46-49°. In the second Sb site, Sb(2) is bonded to two equivalent O(3), two equivalent O(4), and two equivalent O(5) atoms to form SbO6 octahedra that share corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Sb(1)O6 octahedra, corners with two equivalent Sb(2)O6 octahedra, and edges with two equivalent Ho(1)O8 hexagonal bipyramids. The corner-sharing octahedral tilt angles range from 49-52°. There are five inequivalent O sites. In the first O site, O(1) is bonded to one Ho(1), one Ho(2), and two equivalent Mn(1) atoms to form OHo2Mn2 tetrahedra that share corners with two equivalent O(3)Ho2Sb2 tetrahedra, corners with four equivalent O(1)Ho2Mn2 tetrahedra, corners with four equivalent O(4)HoMn2Sb tetrahedra, corners with four equivalent O(5)HoMnSb2 tetrahedra,  an edgeedge with one O(3)Ho2Sb2 tetrahedra, edges with two equivalent O(4)HoMn2Sb tetrahedra, and edges with two equivalent O(5)HoMnSb2 tetrahedra. In the second O site, O(2) is bonded in a 4-coordinate geometry to one Mn(2), two equivalent Mn(1), and one Sb(1) atom. In the third O site, O(3) is bonded to one Ho(1), one Ho(2), and two equivalent Sb(2) atoms to form distorted OHo2Sb2 tetrahedra that share corners with two equivalent O(1)Ho2Mn2 tetrahedra, corners with four equivalent O(3)Ho2Sb2 tetrahedra, corners with four equivalent O(4)HoMn2Sb tetrahedra, corners with four equivalent O(5)HoMnSb2 tetrahedra,  an edgeedge with one O(1)Ho2Mn2 tetrahedra, edges with two equivalent O(4)HoMn2Sb tetrahedra, and edges with two equivalent O(5)HoMnSb2 tetrahedra. In the fourth O site, O(4) is bonded to one Ho(2), one Mn(1), one Mn(2), and one Sb(2) atom to form distorted OHoMn2Sb tetrahedra that share corners with two equivalent O(1)Ho2Mn2 tetrahedra, corners with two equivalent O(3)Ho2Sb2 tetrahedra, corners with two equivalent O(5)HoMnSb2 tetrahedra, corners with six equivalent O(4)HoMn2Sb tetrahedra,  an edgeedge with one O(1)Ho2Mn2 tetrahedra,  an edgeedge with one O(3)Ho2Sb2 tetrahedra,  an edgeedge with one O(4)HoMn2Sb tetrahedra, and  an edgeedge with one O(5)HoMnSb2 tetrahedra. In the fifth O site, O(5) is bonded to one Ho(1), one Mn(1), one Sb(1), and one Sb(2) atom to form distorted OHoMnSb2 tetrahedra that share corners with two equivalent O(1)Ho2Mn2 tetrahedra, corners with two equivalent O(3)Ho2Sb2 tetrahedra, corners with two equivalent O(4)HoMn2Sb tetrahedra, corners with six equivalent O(5)HoMnSb2 tetrahedra,  an edgeedge with one O(1)Ho2Mn2 tetrahedra,  an edgeedge with one O(3)Ho2Sb2 tetrahedra,  an edgeedge with one O(4)HoMn2Sb tetrahedra, and  an edgeedge with one O(5)HoMnSb2 tetrahedra. is represented by the CIF card [CIF]
data_Ho2Mn3Sb3O14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.261
_cell_length_b   7.261
_cell_length_c   7.237
_cell_angle_alpha   60.621
_cell_angle_beta   60.621
_cell_angle_gamma   60.703
_symmetry_Int_Tables_number   1
_cell_volume   273.797
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ho  Ho0  1  0.000  0.000  0.000  1.0
  Ho  Ho1  1  0.000  0.000  0.500  1.0
  Mn  Mn2  1  0.500  0.000  0.000  1.0
  Mn  Mn3  1  0.000  0.500  0.000  1.0
  Mn  Mn4  1  0.500  0.500  0.500  1.0
  Sb  Sb5  1  0.500  0.500  0.000  1.0
  Sb  Sb6  1  0.000  0.500  0.500  1.0
  Sb  Sb7  1  0.500  0.000  0.500  1.0
  O  O8  1  0.871  0.871  0.881  1.0
  O  O9  1  0.129  0.129  0.119  1.0
  O  O10  1  0.575  0.575  0.178  1.0
  O  O11  1  0.168  0.168  0.592  1.0
  O  O12  1  0.157  0.593  0.577  1.0
  O  O13  1  0.587  0.170  0.168  1.0
  O  O14  1  0.170  0.587  0.168  1.0
  O  O15  1  0.593  0.157  0.577  1.0
  O  O16  1  0.425  0.425  0.822  1.0
  O  O17  1  0.832  0.832  0.408  1.0
  O  O18  1  0.843  0.407  0.423  1.0
  O  O19  1  0.413  0.830  0.832  1.0
  O  O20  1  0.830  0.413  0.832  1.0
  O  O21  1  0.407  0.843  0.423  1.0
[/CIF]
.
The compound described by Ho2Mn3Sb3O14 crystallizes in the monoclinic C2/m space group. There are two inequivalent Ho sites. In the first Ho site, Ho(1) is bonded to two equivalent O(1), two equivalent O(3), and four equivalent O(5) atoms to form distorted HoO8 hexagonal bipyramids that share edges with two equivalent Sb(1)O6 octahedra and edges with four equivalent Sb(2)O6 octahedra. In the second Ho site, Ho(2) is bonded in a distorted body-centered cubic geometry to two equivalent O(1), two equivalent O(3), and four equivalent O(4) atoms. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a distorted body-centered cubic geometry to two equivalent O(1), two equivalent O(2), two equivalent O(4), and two equivalent O(5) atoms. In the second Mn site, Mn(2) is bonded to two equivalent O(2) and four equivalent O(4) atoms to form MnO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra and corners with four equivalent Sb(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-52°. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to two equivalent O(2) and four equivalent O(5) atoms to form SbO6 octahedra that share corners with two equivalent Mn(2)O6 octahedra, corners with four equivalent Sb(2)O6 octahedra, and edges with two equivalent Ho(1)O8 hexagonal bipyramids. The corner-sharing octahedral tilt angles range from 46-49°. In the second Sb site, Sb(2) is bonded to two equivalent O(3), two equivalent O(4), and two equivalent O(5) atoms to form SbO6 octahedra that share corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Sb(1)O6 octahedra, corners with two equivalent Sb(2)O6 octahedra, and edges with two equivalent Ho(1)O8 hexagonal bipyramids. The corner-sharing octahedral tilt angles range from 49-52°. There are five inequivalent O sites. In the first O site, O(1) is bonded to one Ho(1), one Ho(2), and two equivalent Mn(1) atoms to form OHo2Mn2 tetrahedra that share corners with two equivalent O(3)Ho2Sb2 tetrahedra, corners with four equivalent O(1)Ho2Mn2 tetrahedra, corners with four equivalent O(4)HoMn2Sb tetrahedra, corners with four equivalent O(5)HoMnSb2 tetrahedra,  an edgeedge with one O(3)Ho2Sb2 tetrahedra, edges with two equivalent O(4)HoMn2Sb tetrahedra, and edges with two equivalent O(5)HoMnSb2 tetrahedra. In the second O site, O(2) is bonded in a 4-coordinate geometry to one Mn(2), two equivalent Mn(1), and one Sb(1) atom. In the third O site, O(3) is bonded to one Ho(1), one Ho(2), and two equivalent Sb(2) atoms to form distorted OHo2Sb2 tetrahedra that share corners with two equivalent O(1)Ho2Mn2 tetrahedra, corners with four equivalent O(3)Ho2Sb2 tetrahedra, corners with four equivalent O(4)HoMn2Sb tetrahedra, corners with four equivalent O(5)HoMnSb2 tetrahedra,  an edgeedge with one O(1)Ho2Mn2 tetrahedra, edges with two equivalent O(4)HoMn2Sb tetrahedra, and edges with two equivalent O(5)HoMnSb2 tetrahedra. In the fourth O site, O(4) is bonded to one Ho(2), one Mn(1), one Mn(2), and one Sb(2) atom to form distorted OHoMn2Sb tetrahedra that share corners with two equivalent O(1)Ho2Mn2 tetrahedra, corners with two equivalent O(3)Ho2Sb2 tetrahedra, corners with two equivalent O(5)HoMnSb2 tetrahedra, corners with six equivalent O(4)HoMn2Sb tetrahedra,  an edgeedge with one O(1)Ho2Mn2 tetrahedra,  an edgeedge with one O(3)Ho2Sb2 tetrahedra,  an edgeedge with one O(4)HoMn2Sb tetrahedra, and  an edgeedge with one O(5)HoMnSb2 tetrahedra. In the fifth O site, O(5) is bonded to one Ho(1), one Mn(1), one Sb(1), and one Sb(2) atom to form distorted OHoMnSb2 tetrahedra that share corners with two equivalent O(1)Ho2Mn2 tetrahedra, corners with two equivalent O(3)Ho2Sb2 tetrahedra, corners with two equivalent O(4)HoMn2Sb tetrahedra, corners with six equivalent O(5)HoMnSb2 tetrahedra,  an edgeedge with one O(1)Ho2Mn2 tetrahedra,  an edgeedge with one O(3)Ho2Sb2 tetrahedra,  an edgeedge with one O(4)HoMn2Sb tetrahedra, and  an edgeedge with one O(5)HoMnSb2 tetrahedra. is represented by the CIF card [CIF]
data_Ho2Mn3Sb3O14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.261
_cell_length_b   7.261
_cell_length_c   7.237
_cell_angle_alpha   60.621
_cell_angle_beta   60.621
_cell_angle_gamma   60.703
_symmetry_Int_Tables_number   1
_cell_volume   273.797
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ho  Ho0  1  0.000  0.000  0.000  1.0
  Ho  Ho1  1  0.000  0.000  0.500  1.0
  Mn  Mn2  1  0.500  0.000  0.000  1.0
  Mn  Mn3  1  0.000  0.500  0.000  1.0
  Mn  Mn4  1  0.500  0.500  0.500  1.0
  Sb  Sb5  1  0.500  0.500  0.000  1.0
  Sb  Sb6  1  0.000  0.500  0.500  1.0
  Sb  Sb7  1  0.500  0.000  0.500  1.0
  O  O8  1  0.871  0.871  0.881  1.0
  O  O9  1  0.129  0.129  0.119  1.0
  O  O10  1  0.575  0.575  0.178  1.0
  O  O11  1  0.168  0.168  0.592  1.0
  O  O12  1  0.157  0.593  0.577  1.0
  O  O13  1  0.587  0.170  0.168  1.0
  O  O14  1  0.170  0.587  0.168  1.0
  O  O15  1  0.593  0.157  0.577  1.0
  O  O16  1  0.425  0.425  0.822  1.0
  O  O17  1  0.832  0.832  0.408  1.0
  O  O18  1  0.843  0.407  0.423  1.0
  O  O19  1  0.413  0.830  0.832  1.0
  O  O20  1  0.830  0.413  0.832  1.0
  O  O21  1  0.407  0.843  0.423  1.0
[/CIF]
.