The structure described by KSO3F crystallizes in the orthorhombic Pnma space group. K(1) is bonded in a 8-coordinate geometry to one O(2), six equivalent O(1), and one F(1) atom. S(1) is bonded in a tetrahedral geometry to one O(2), two equivalent O(1), and one F(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to three equivalent K(1) and one S(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one K(1) and one S(1) atom. F(1) is bonded in a distorted single-bond geometry to one K(1) and one S(1) atom. is represented by the CIF card [CIF]
data_KSO3F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.041
_cell_length_b   7.556
_cell_length_c   8.823
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   402.701
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.250  0.342  0.677  1.0
  K  K1  1  0.250  0.158  0.177  1.0
  K  K2  1  0.750  0.658  0.323  1.0
  K  K3  1  0.750  0.842  0.823  1.0
  S  S4  1  0.250  0.800  0.556  1.0
  S  S5  1  0.250  0.700  0.056  1.0
  S  S6  1  0.750  0.200  0.444  1.0
  S  S7  1  0.750  0.300  0.944  1.0
  O  O8  1  0.047  0.702  0.584  1.0
  O  O9  1  0.453  0.798  0.084  1.0
  O  O10  1  0.547  0.298  0.416  1.0
  O  O11  1  0.953  0.202  0.916  1.0
  O  O12  1  0.953  0.298  0.416  1.0
  O  O13  1  0.547  0.202  0.916  1.0
  O  O14  1  0.453  0.702  0.584  1.0
  O  O15  1  0.047  0.798  0.084  1.0
  O  O16  1  0.250  0.912  0.423  1.0
  O  O17  1  0.250  0.588  0.923  1.0
  O  O18  1  0.750  0.088  0.577  1.0
  O  O19  1  0.750  0.412  0.077  1.0
  F  F20  1  0.250  0.946  0.697  1.0
  F  F21  1  0.250  0.554  0.197  1.0
  F  F22  1  0.750  0.054  0.303  1.0
  F  F23  1  0.750  0.446  0.803  1.0
[/CIF]
.
The structure described by KSO3F crystallizes in the orthorhombic Pnma space group. K(1) is bonded in a 8-coordinate geometry to one O(2), six equivalent O(1), and one F(1) atom. S(1) is bonded in a tetrahedral geometry to one O(2), two equivalent O(1), and one F(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to three equivalent K(1) and one S(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one K(1) and one S(1) atom. F(1) is bonded in a distorted single-bond geometry to one K(1) and one S(1) atom. is represented by the CIF card [CIF]
data_KSO3F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.041
_cell_length_b   7.556
_cell_length_c   8.823
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   402.701
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.250  0.342  0.677  1.0
  K  K1  1  0.250  0.158  0.177  1.0
  K  K2  1  0.750  0.658  0.323  1.0
  K  K3  1  0.750  0.842  0.823  1.0
  S  S4  1  0.250  0.800  0.556  1.0
  S  S5  1  0.250  0.700  0.056  1.0
  S  S6  1  0.750  0.200  0.444  1.0
  S  S7  1  0.750  0.300  0.944  1.0
  O  O8  1  0.047  0.702  0.584  1.0
  O  O9  1  0.453  0.798  0.084  1.0
  O  O10  1  0.547  0.298  0.416  1.0
  O  O11  1  0.953  0.202  0.916  1.0
  O  O12  1  0.953  0.298  0.416  1.0
  O  O13  1  0.547  0.202  0.916  1.0
  O  O14  1  0.453  0.702  0.584  1.0
  O  O15  1  0.047  0.798  0.084  1.0
  O  O16  1  0.250  0.912  0.423  1.0
  O  O17  1  0.250  0.588  0.923  1.0
  O  O18  1  0.750  0.088  0.577  1.0
  O  O19  1  0.750  0.412  0.077  1.0
  F  F20  1  0.250  0.946  0.697  1.0
  F  F21  1  0.250  0.554  0.197  1.0
  F  F22  1  0.750  0.054  0.303  1.0
  F  F23  1  0.750  0.446  0.803  1.0
[/CIF]
.