The material structure described by NaAuO2 crystallizes in the orthorhombic Cmcm space group. Na(1) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. Au(1) is bonded in a rectangular see-saw-like geometry to four equivalent O(1) atoms. O(1) is bonded to three equivalent Na(1) and two equivalent Au(1) atoms to form a mixture of corner, face, and edge-sharing ONa3Au2 trigonal bipyramids. is represented by the CIF file [CIF]
data_NaAuO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.973
_cell_length_b   5.973
_cell_length_c   5.981
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   143.109
_symmetry_Int_Tables_number   1
_cell_volume   128.075
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.287  0.713  0.250  1.0
  Na  Na1  1  0.713  0.287  0.750  1.0
  Au  Au2  1  0.997  0.003  0.750  1.0
  Au  Au3  1  0.003  0.997  0.250  1.0
  O  O4  1  0.878  0.122  0.493  1.0
  O  O5  1  0.122  0.878  0.507  1.0
  O  O6  1  0.878  0.122  0.007  1.0
  O  O7  1  0.122  0.878  0.993  1.0
[/CIF]
.
The material structure described by NaAuO2 crystallizes in the orthorhombic Cmcm space group. Na(1) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. Au(1) is bonded in a rectangular see-saw-like geometry to four equivalent O(1) atoms. O(1) is bonded to three equivalent Na(1) and two equivalent Au(1) atoms to form a mixture of corner, face, and edge-sharing ONa3Au2 trigonal bipyramids. is represented by the CIF file [CIF]
data_NaAuO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.973
_cell_length_b   5.973
_cell_length_c   5.981
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   143.109
_symmetry_Int_Tables_number   1
_cell_volume   128.075
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.287  0.713  0.250  1.0
  Na  Na1  1  0.713  0.287  0.750  1.0
  Au  Au2  1  0.997  0.003  0.750  1.0
  Au  Au3  1  0.003  0.997  0.250  1.0
  O  O4  1  0.878  0.122  0.493  1.0
  O  O5  1  0.122  0.878  0.507  1.0
  O  O6  1  0.878  0.122  0.007  1.0
  O  O7  1  0.122  0.878  0.993  1.0
[/CIF]
.