The structure described by Li3SbS3 crystallizes in the monoclinic P2_1/c space group. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded to two equivalent S(1) and two equivalent S(3) atoms to form a mixture of edge and corner-sharing LiS4 tetrahedra. In the second Li site, Li(2) is bonded in a distorted trigonal non-coplanar geometry to one S(3) and two equivalent S(2) atoms. In the third Li site, Li(3) is bonded to one S(2), one S(3), and two equivalent S(1) atoms to form a mixture of edge and corner-sharing LiS4 tetrahedra. Sb(1) is bonded in a 3-coordinate geometry to one S(1), one S(2), and one S(3) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a distorted pentagonal planar geometry to two equivalent Li(1), two equivalent Li(3), and one Sb(1) atom. In the second S site, S(2) is bonded in a 4-coordinate geometry to one Li(3), two equivalent Li(2), and one Sb(1) atom. In the third S site, S(3) is bonded to one Li(2), one Li(3), two equivalent Li(1), and one Sb(1) atom to form distorted corner-sharing SLi4Sb trigonal bipyramids. is represented by the CIF card [CIF]
data_Li3SbS3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.925
_cell_length_b   4.154
_cell_length_c   12.730
_cell_angle_alpha   73.088
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   603.369
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.451  0.890  0.613  1.0
  Li  Li1  1  0.973  0.814  0.625  1.0
  Li  Li2  1  0.223  0.426  0.017  1.0
  Li  Li3  1  0.049  0.890  0.113  1.0
  Li  Li4  1  0.527  0.814  0.125  1.0
  Li  Li5  1  0.723  0.574  0.483  1.0
  Li  Li6  1  0.277  0.426  0.517  1.0
  Li  Li7  1  0.473  0.186  0.875  1.0
  Li  Li8  1  0.951  0.110  0.887  1.0
  Li  Li9  1  0.777  0.574  0.983  1.0
  Li  Li10  1  0.027  0.186  0.375  1.0
  Li  Li11  1  0.549  0.110  0.387  1.0
  Sb  Sb12  1  0.693  0.522  0.749  1.0
  Sb  Sb13  1  0.807  0.522  0.249  1.0
  Sb  Sb14  1  0.193  0.478  0.751  1.0
  Sb  Sb15  1  0.307  0.478  0.251  1.0
  S  S16  1  0.655  0.982  0.576  1.0
  S  S17  1  0.587  0.662  0.898  1.0
  S  S18  1  0.845  0.982  0.076  1.0
  S  S19  1  0.882  0.682  0.803  1.0
  S  S20  1  0.913  0.662  0.398  1.0
  S  S21  1  0.618  0.682  0.303  1.0
  S  S22  1  0.382  0.318  0.697  1.0
  S  S23  1  0.087  0.338  0.602  1.0
  S  S24  1  0.118  0.318  0.197  1.0
  S  S25  1  0.155  0.018  0.924  1.0
  S  S26  1  0.413  0.338  0.102  1.0
  S  S27  1  0.345  0.018  0.424  1.0
[/CIF]
.
The structure described by Li3SbS3 crystallizes in the monoclinic P2_1/c space group. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded to two equivalent S(1) and two equivalent S(3) atoms to form a mixture of edge and corner-sharing LiS4 tetrahedra. In the second Li site, Li(2) is bonded in a distorted trigonal non-coplanar geometry to one S(3) and two equivalent S(2) atoms. In the third Li site, Li(3) is bonded to one S(2), one S(3), and two equivalent S(1) atoms to form a mixture of edge and corner-sharing LiS4 tetrahedra. Sb(1) is bonded in a 3-coordinate geometry to one S(1), one S(2), and one S(3) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a distorted pentagonal planar geometry to two equivalent Li(1), two equivalent Li(3), and one Sb(1) atom. In the second S site, S(2) is bonded in a 4-coordinate geometry to one Li(3), two equivalent Li(2), and one Sb(1) atom. In the third S site, S(3) is bonded to one Li(2), one Li(3), two equivalent Li(1), and one Sb(1) atom to form distorted corner-sharing SLi4Sb trigonal bipyramids. is represented by the CIF card [CIF]
data_Li3SbS3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.925
_cell_length_b   4.154
_cell_length_c   12.730
_cell_angle_alpha   73.088
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   603.369
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.451  0.890  0.613  1.0
  Li  Li1  1  0.973  0.814  0.625  1.0
  Li  Li2  1  0.223  0.426  0.017  1.0
  Li  Li3  1  0.049  0.890  0.113  1.0
  Li  Li4  1  0.527  0.814  0.125  1.0
  Li  Li5  1  0.723  0.574  0.483  1.0
  Li  Li6  1  0.277  0.426  0.517  1.0
  Li  Li7  1  0.473  0.186  0.875  1.0
  Li  Li8  1  0.951  0.110  0.887  1.0
  Li  Li9  1  0.777  0.574  0.983  1.0
  Li  Li10  1  0.027  0.186  0.375  1.0
  Li  Li11  1  0.549  0.110  0.387  1.0
  Sb  Sb12  1  0.693  0.522  0.749  1.0
  Sb  Sb13  1  0.807  0.522  0.249  1.0
  Sb  Sb14  1  0.193  0.478  0.751  1.0
  Sb  Sb15  1  0.307  0.478  0.251  1.0
  S  S16  1  0.655  0.982  0.576  1.0
  S  S17  1  0.587  0.662  0.898  1.0
  S  S18  1  0.845  0.982  0.076  1.0
  S  S19  1  0.882  0.682  0.803  1.0
  S  S20  1  0.913  0.662  0.398  1.0
  S  S21  1  0.618  0.682  0.303  1.0
  S  S22  1  0.382  0.318  0.697  1.0
  S  S23  1  0.087  0.338  0.602  1.0
  S  S24  1  0.118  0.318  0.197  1.0
  S  S25  1  0.155  0.018  0.924  1.0
  S  S26  1  0.413  0.338  0.102  1.0
  S  S27  1  0.345  0.018  0.424  1.0
[/CIF]
.