The structure described by CaRhIn2 crystallizes in the orthorhombic Pnma space group. There are two inequivalent Ca sites. In the first Ca site, Ca(1) is bonded in a 13-coordinate geometry to one Rh(2), two equivalent Rh(1), four equivalent In(1), and six equivalent In(2) atoms. In the second Ca site, Ca(2) is bonded in a 13-coordinate geometry to one Rh(1), two equivalent Rh(2), four equivalent In(2), and six equivalent In(1) atoms. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a 9-coordinate geometry to one Ca(2), two equivalent Ca(1), two equivalent In(2), and four equivalent In(1) atoms. In the second Rh site, Rh(2) is bonded in a 9-coordinate geometry to one Ca(1), two equivalent Ca(2), two equivalent In(1), and four equivalent In(2) atoms. There are two inequivalent In sites. In the first In site, In(1) is bonded in a 3-coordinate geometry to two equivalent Ca(1), three equivalent Ca(2), one Rh(2), two equivalent Rh(1), and one In(2) atom. In the second In site, In(2) is bonded in a 12-coordinate geometry to two equivalent Ca(2), three equivalent Ca(1), one Rh(1), two equivalent Rh(2), one In(1), and three equivalent In(2) atoms. is represented by the CIF card [CIF]
data_CaIn2Rh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.733
_cell_length_b   7.832
_cell_length_c   15.946
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   716.034
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ca  Ca0  1  0.753  0.750  0.897  1.0
  Ca  Ca1  1  0.247  0.250  0.103  1.0
  Ca  Ca2  1  0.253  0.250  0.603  1.0
  Ca  Ca3  1  0.747  0.750  0.397  1.0
  Ca  Ca4  1  0.043  0.750  0.638  1.0
  Ca  Ca5  1  0.957  0.250  0.362  1.0
  Ca  Ca6  1  0.543  0.250  0.862  1.0
  Ca  Ca7  1  0.457  0.750  0.138  1.0
  In  In8  1  0.542  0.551  0.712  1.0
  In  In9  1  0.458  0.449  0.288  1.0
  In  In10  1  0.042  0.449  0.788  1.0
  In  In11  1  0.458  0.051  0.288  1.0
  In  In12  1  0.958  0.551  0.212  1.0
  In  In13  1  0.542  0.949  0.712  1.0
  In  In14  1  0.958  0.949  0.212  1.0
  In  In15  1  0.042  0.051  0.788  1.0
  In  In16  1  0.747  0.055  0.539  1.0
  In  In17  1  0.253  0.945  0.461  1.0
  In  In18  1  0.247  0.945  0.961  1.0
  In  In19  1  0.253  0.555  0.461  1.0
  In  In20  1  0.753  0.055  0.039  1.0
  In  In21  1  0.747  0.445  0.539  1.0
  In  In22  1  0.753  0.445  0.039  1.0
  In  In23  1  0.247  0.555  0.961  1.0
  Rh  Rh24  1  0.275  0.750  0.814  1.0
  Rh  Rh25  1  0.725  0.250  0.186  1.0
  Rh  Rh26  1  0.775  0.250  0.686  1.0
  Rh  Rh27  1  0.225  0.750  0.314  1.0
  Rh  Rh28  1  0.519  0.750  0.571  1.0
  Rh  Rh29  1  0.481  0.250  0.429  1.0
  Rh  Rh30  1  0.019  0.250  0.929  1.0
  Rh  Rh31  1  0.981  0.750  0.071  1.0
[/CIF]
.
The structure described by CaRhIn2 crystallizes in the orthorhombic Pnma space group. There are two inequivalent Ca sites. In the first Ca site, Ca(1) is bonded in a 13-coordinate geometry to one Rh(2), two equivalent Rh(1), four equivalent In(1), and six equivalent In(2) atoms. In the second Ca site, Ca(2) is bonded in a 13-coordinate geometry to one Rh(1), two equivalent Rh(2), four equivalent In(2), and six equivalent In(1) atoms. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a 9-coordinate geometry to one Ca(2), two equivalent Ca(1), two equivalent In(2), and four equivalent In(1) atoms. In the second Rh site, Rh(2) is bonded in a 9-coordinate geometry to one Ca(1), two equivalent Ca(2), two equivalent In(1), and four equivalent In(2) atoms. There are two inequivalent In sites. In the first In site, In(1) is bonded in a 3-coordinate geometry to two equivalent Ca(1), three equivalent Ca(2), one Rh(2), two equivalent Rh(1), and one In(2) atom. In the second In site, In(2) is bonded in a 12-coordinate geometry to two equivalent Ca(2), three equivalent Ca(1), one Rh(1), two equivalent Rh(2), one In(1), and three equivalent In(2) atoms. is represented by the CIF card [CIF]
data_CaIn2Rh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.733
_cell_length_b   7.832
_cell_length_c   15.946
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   716.034
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ca  Ca0  1  0.753  0.750  0.897  1.0
  Ca  Ca1  1  0.247  0.250  0.103  1.0
  Ca  Ca2  1  0.253  0.250  0.603  1.0
  Ca  Ca3  1  0.747  0.750  0.397  1.0
  Ca  Ca4  1  0.043  0.750  0.638  1.0
  Ca  Ca5  1  0.957  0.250  0.362  1.0
  Ca  Ca6  1  0.543  0.250  0.862  1.0
  Ca  Ca7  1  0.457  0.750  0.138  1.0
  In  In8  1  0.542  0.551  0.712  1.0
  In  In9  1  0.458  0.449  0.288  1.0
  In  In10  1  0.042  0.449  0.788  1.0
  In  In11  1  0.458  0.051  0.288  1.0
  In  In12  1  0.958  0.551  0.212  1.0
  In  In13  1  0.542  0.949  0.712  1.0
  In  In14  1  0.958  0.949  0.212  1.0
  In  In15  1  0.042  0.051  0.788  1.0
  In  In16  1  0.747  0.055  0.539  1.0
  In  In17  1  0.253  0.945  0.461  1.0
  In  In18  1  0.247  0.945  0.961  1.0
  In  In19  1  0.253  0.555  0.461  1.0
  In  In20  1  0.753  0.055  0.039  1.0
  In  In21  1  0.747  0.445  0.539  1.0
  In  In22  1  0.753  0.445  0.039  1.0
  In  In23  1  0.247  0.555  0.961  1.0
  Rh  Rh24  1  0.275  0.750  0.814  1.0
  Rh  Rh25  1  0.725  0.250  0.186  1.0
  Rh  Rh26  1  0.775  0.250  0.686  1.0
  Rh  Rh27  1  0.225  0.750  0.314  1.0
  Rh  Rh28  1  0.519  0.750  0.571  1.0
  Rh  Rh29  1  0.481  0.250  0.429  1.0
  Rh  Rh30  1  0.019  0.250  0.929  1.0
  Rh  Rh31  1  0.981  0.750  0.071  1.0
[/CIF]
.