The material described by AsNS2(NS)2 is Indium-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four AsNS2 clusters and four NS clusters. In each AsNS2 cluster, As(1) is bonded in a distorted single-bond geometry to one N(1) and two equivalent S(3) atoms. N(1) is bonded in a single-bond geometry to one As(1) atom. S(3) is bonded in a 2-coordinate geometry to one As(1) and one S(3) atom. In each NS cluster, N(2) is bonded in an L-shaped geometry to one S(1) and one S(2) atom. There are two inequivalent S sites. In the first S site, S(2) is bonded in an L-shaped geometry to two equivalent N(2) atoms. In the second S site, S(1) is bonded in an L-shaped geometry to two equivalent N(2) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_AsS4N3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.172
_cell_length_b   10.305
_cell_length_c   10.699
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1011.231
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.094  0.750  0.251  1.0
  As  As1  1  0.406  0.750  0.751  1.0
  As  As2  1  0.906  0.250  0.749  1.0
  As  As3  1  0.594  0.250  0.249  1.0
  S  S4  1  0.735  0.750  0.465  1.0
  S  S5  1  0.765  0.750  0.965  1.0
  S  S6  1  0.265  0.250  0.535  1.0
  S  S7  1  0.235  0.250  0.035  1.0
  S  S8  1  0.946  0.750  0.584  1.0
  S  S9  1  0.554  0.750  0.084  1.0
  S  S10  1  0.054  0.250  0.416  1.0
  S  S11  1  0.446  0.250  0.916  1.0
  S  S12  1  0.145  0.650  0.063  1.0
  S  S13  1  0.355  0.850  0.563  1.0
  S  S14  1  0.855  0.150  0.937  1.0
  S  S15  1  0.645  0.350  0.437  1.0
  S  S16  1  0.855  0.350  0.937  1.0
  S  S17  1  0.645  0.150  0.437  1.0
  S  S18  1  0.145  0.850  0.063  1.0
  S  S19  1  0.355  0.650  0.563  1.0
  N  N20  1  0.285  0.750  0.298  1.0
  N  N21  1  0.215  0.750  0.798  1.0
  N  N22  1  0.715  0.250  0.702  1.0
  N  N23  1  0.785  0.250  0.202  1.0
  N  N24  1  0.840  0.635  0.524  1.0
  N  N25  1  0.660  0.865  0.024  1.0
  N  N26  1  0.160  0.135  0.476  1.0
  N  N27  1  0.340  0.365  0.976  1.0
  N  N28  1  0.160  0.365  0.476  1.0
  N  N29  1  0.340  0.135  0.976  1.0
  N  N30  1  0.840  0.865  0.524  1.0
  N  N31  1  0.660  0.635  0.024  1.0
[/CIF]
.
The material described by AsNS2(NS)2 is Indium-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four AsNS2 clusters and four NS clusters. In each AsNS2 cluster, As(1) is bonded in a distorted single-bond geometry to one N(1) and two equivalent S(3) atoms. N(1) is bonded in a single-bond geometry to one As(1) atom. S(3) is bonded in a 2-coordinate geometry to one As(1) and one S(3) atom. In each NS cluster, N(2) is bonded in an L-shaped geometry to one S(1) and one S(2) atom. There are two inequivalent S sites. In the first S site, S(2) is bonded in an L-shaped geometry to two equivalent N(2) atoms. In the second S site, S(1) is bonded in an L-shaped geometry to two equivalent N(2) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_AsS4N3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.172
_cell_length_b   10.305
_cell_length_c   10.699
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1011.231
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.094  0.750  0.251  1.0
  As  As1  1  0.406  0.750  0.751  1.0
  As  As2  1  0.906  0.250  0.749  1.0
  As  As3  1  0.594  0.250  0.249  1.0
  S  S4  1  0.735  0.750  0.465  1.0
  S  S5  1  0.765  0.750  0.965  1.0
  S  S6  1  0.265  0.250  0.535  1.0
  S  S7  1  0.235  0.250  0.035  1.0
  S  S8  1  0.946  0.750  0.584  1.0
  S  S9  1  0.554  0.750  0.084  1.0
  S  S10  1  0.054  0.250  0.416  1.0
  S  S11  1  0.446  0.250  0.916  1.0
  S  S12  1  0.145  0.650  0.063  1.0
  S  S13  1  0.355  0.850  0.563  1.0
  S  S14  1  0.855  0.150  0.937  1.0
  S  S15  1  0.645  0.350  0.437  1.0
  S  S16  1  0.855  0.350  0.937  1.0
  S  S17  1  0.645  0.150  0.437  1.0
  S  S18  1  0.145  0.850  0.063  1.0
  S  S19  1  0.355  0.650  0.563  1.0
  N  N20  1  0.285  0.750  0.298  1.0
  N  N21  1  0.215  0.750  0.798  1.0
  N  N22  1  0.715  0.250  0.702  1.0
  N  N23  1  0.785  0.250  0.202  1.0
  N  N24  1  0.840  0.635  0.524  1.0
  N  N25  1  0.660  0.865  0.024  1.0
  N  N26  1  0.160  0.135  0.476  1.0
  N  N27  1  0.340  0.365  0.976  1.0
  N  N28  1  0.160  0.365  0.476  1.0
  N  N29  1  0.340  0.135  0.976  1.0
  N  N30  1  0.840  0.865  0.524  1.0
  N  N31  1  0.660  0.635  0.024  1.0
[/CIF]
.