The material structure described by Ce4Co2Sn5 crystallizes in the monoclinic C2/m space group. There are two inequivalent Ce sites. In the first Ce site, Ce(1) is bonded in a 10-coordinate geometry to two equivalent Co(1), one Sn(2), three equivalent Sn(3), and four equivalent Sn(1) atoms. In the second Ce site, Ce(2) is bonded in a 9-coordinate geometry to two equivalent Co(1), two equivalent Sn(2), two equivalent Sn(3), and three equivalent Sn(1) atoms. Co(1) is bonded in a 9-coordinate geometry to two equivalent Ce(1), two equivalent Ce(2), one Sn(1), one Sn(2), and three equivalent Sn(3) atoms. There are three inequivalent Sn sites. In the first Sn site, Sn(1) is bonded in a 9-coordinate geometry to three equivalent Ce(2), four equivalent Ce(1), one Co(1), and one Sn(1) atom. In the second Sn site, Sn(2) is bonded in a 12-coordinate geometry to two equivalent Ce(1), four equivalent Ce(2), two equivalent Co(1), and four equivalent Sn(3) atoms. In the third Sn site, Sn(3) is bonded in a 8-coordinate geometry to two equivalent Ce(2), three equivalent Ce(1), three equivalent Co(1), and two equivalent Sn(2) atoms. is represented by the CIF card [CIF]
data_Ce4Co2Sn5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.505
_cell_length_b   7.505
_cell_length_c   11.065
_cell_angle_alpha   53.534
_cell_angle_beta   53.534
_cell_angle_gamma   35.711
_symmetry_Int_Tables_number   1
_cell_volume   284.111
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.067  0.067  0.775  1.0
  Ce  Ce1  1  0.933  0.933  0.225  1.0
  Ce  Ce2  1  0.333  0.333  0.782  1.0
  Ce  Ce3  1  0.667  0.667  0.218  1.0
  Co  Co4  1  0.769  0.769  0.649  1.0
  Co  Co5  1  0.231  0.231  0.351  1.0
  Sn  Sn6  1  0.376  0.376  0.049  1.0
  Sn  Sn7  1  0.624  0.624  0.951  1.0
  Sn  Sn8  1  0.000  0.000  0.500  1.0
  Sn  Sn9  1  0.349  0.349  0.476  1.0
  Sn  Sn10  1  0.651  0.651  0.524  1.0
[/CIF]
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The material structure described by Ce4Co2Sn5 crystallizes in the monoclinic C2/m space group. There are two inequivalent Ce sites. In the first Ce site, Ce(1) is bonded in a 10-coordinate geometry to two equivalent Co(1), one Sn(2), three equivalent Sn(3), and four equivalent Sn(1) atoms. In the second Ce site, Ce(2) is bonded in a 9-coordinate geometry to two equivalent Co(1), two equivalent Sn(2), two equivalent Sn(3), and three equivalent Sn(1) atoms. Co(1) is bonded in a 9-coordinate geometry to two equivalent Ce(1), two equivalent Ce(2), one Sn(1), one Sn(2), and three equivalent Sn(3) atoms. There are three inequivalent Sn sites. In the first Sn site, Sn(1) is bonded in a 9-coordinate geometry to three equivalent Ce(2), four equivalent Ce(1), one Co(1), and one Sn(1) atom. In the second Sn site, Sn(2) is bonded in a 12-coordinate geometry to two equivalent Ce(1), four equivalent Ce(2), two equivalent Co(1), and four equivalent Sn(3) atoms. In the third Sn site, Sn(3) is bonded in a 8-coordinate geometry to two equivalent Ce(2), three equivalent Ce(1), three equivalent Co(1), and two equivalent Sn(2) atoms. is represented by the CIF card [CIF]
data_Ce4Co2Sn5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.505
_cell_length_b   7.505
_cell_length_c   11.065
_cell_angle_alpha   53.534
_cell_angle_beta   53.534
_cell_angle_gamma   35.711
_symmetry_Int_Tables_number   1
_cell_volume   284.111
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.067  0.067  0.775  1.0
  Ce  Ce1  1  0.933  0.933  0.225  1.0
  Ce  Ce2  1  0.333  0.333  0.782  1.0
  Ce  Ce3  1  0.667  0.667  0.218  1.0
  Co  Co4  1  0.769  0.769  0.649  1.0
  Co  Co5  1  0.231  0.231  0.351  1.0
  Sn  Sn6  1  0.376  0.376  0.049  1.0
  Sn  Sn7  1  0.624  0.624  0.951  1.0
  Sn  Sn8  1  0.000  0.000  0.500  1.0
  Sn  Sn9  1  0.349  0.349  0.476  1.0
  Sn  Sn10  1  0.651  0.651  0.524  1.0
[/CIF]
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