The compound described by VAgHgO4 crystallizes in the monoclinic C2 space group. V(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. Ag(1) is bonded in a 5-coordinate geometry to one O(1), one O(3), one O(4), and two equivalent O(2) atoms. There are two inequivalent Hg sites. In the first Hg site, Hg(1) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms. In the second Hg site, Hg(2) is bonded in a linear geometry to two equivalent O(3) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one V(1), one Ag(1), and one Hg(1) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one V(1) and two equivalent Ag(1) atoms. In the third O site, O(3) is bonded in a 4-coordinate geometry to one V(1), one Ag(1), one Hg(1), and one Hg(2) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one V(1), one Ag(1), and one Hg(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_VAgHgO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.988
_cell_length_b   5.988
_cell_length_c   7.254
_cell_angle_alpha   81.981
_cell_angle_beta   81.981
_cell_angle_gamma   55.582
_symmetry_Int_Tables_number   1
_cell_volume   211.883
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.690  0.683  0.770  1.0
  V  V1  1  0.317  0.310  0.230  1.0
  Ag  Ag2  1  0.628  0.648  0.279  1.0
  Ag  Ag3  1  0.352  0.372  0.721  1.0
  Hg  Hg4  1  0.009  0.991  0.000  1.0
  Hg  Hg5  1  0.973  0.027  0.500  1.0
  O  O6  1  0.487  0.780  0.975  1.0
  O  O7  1  0.220  0.513  0.025  1.0
  O  O8  1  0.264  0.499  0.408  1.0
  O  O9  1  0.501  0.736  0.592  1.0
  O  O10  1  0.807  0.914  0.732  1.0
  O  O11  1  0.086  0.193  0.268  1.0
  O  O12  1  0.665  0.049  0.212  1.0
  O  O13  1  0.951  0.335  0.788  1.0
[/CIF]
.
The compound described by VAgHgO4 crystallizes in the monoclinic C2 space group. V(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. Ag(1) is bonded in a 5-coordinate geometry to one O(1), one O(3), one O(4), and two equivalent O(2) atoms. There are two inequivalent Hg sites. In the first Hg site, Hg(1) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms. In the second Hg site, Hg(2) is bonded in a linear geometry to two equivalent O(3) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one V(1), one Ag(1), and one Hg(1) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one V(1) and two equivalent Ag(1) atoms. In the third O site, O(3) is bonded in a 4-coordinate geometry to one V(1), one Ag(1), one Hg(1), and one Hg(2) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one V(1), one Ag(1), and one Hg(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_VAgHgO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.988
_cell_length_b   5.988
_cell_length_c   7.254
_cell_angle_alpha   81.981
_cell_angle_beta   81.981
_cell_angle_gamma   55.582
_symmetry_Int_Tables_number   1
_cell_volume   211.883
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.690  0.683  0.770  1.0
  V  V1  1  0.317  0.310  0.230  1.0
  Ag  Ag2  1  0.628  0.648  0.279  1.0
  Ag  Ag3  1  0.352  0.372  0.721  1.0
  Hg  Hg4  1  0.009  0.991  0.000  1.0
  Hg  Hg5  1  0.973  0.027  0.500  1.0
  O  O6  1  0.487  0.780  0.975  1.0
  O  O7  1  0.220  0.513  0.025  1.0
  O  O8  1  0.264  0.499  0.408  1.0
  O  O9  1  0.501  0.736  0.592  1.0
  O  O10  1  0.807  0.914  0.732  1.0
  O  O11  1  0.086  0.193  0.268  1.0
  O  O12  1  0.665  0.049  0.212  1.0
  O  O13  1  0.951  0.335  0.788  1.0
[/CIF]
.