The material described by AsF6(I)2 is Indium-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of four 7553-56-2 molecules and four AsF6 clusters. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to one F(1), one F(4), two equivalent F(2), and two equivalent F(3) atoms. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one As(1) atom. is represented by the CIF card [CIF]
data_As(IF3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.293
_cell_length_b   7.293
_cell_length_c   15.476
_cell_angle_alpha   83.293
_cell_angle_beta   83.293
_cell_angle_gamma   120.287
_symmetry_Int_Tables_number   1
_cell_volume   691.012
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.458  0.458  0.281  1.0
  As  As1  1  0.542  0.542  0.719  1.0
  I  I2  1  0.963  0.468  0.587  1.0
  I  I3  1  0.468  0.963  0.587  1.0
  I  I4  1  0.037  0.532  0.413  1.0
  I  I5  1  0.532  0.037  0.413  1.0
  F  F6  1  0.570  0.570  0.169  1.0
  F  F7  1  0.430  0.430  0.831  1.0
  F  F8  1  0.714  0.513  0.304  1.0
  F  F9  1  0.513  0.714  0.304  1.0
  F  F10  1  0.286  0.487  0.696  1.0
  F  F11  1  0.487  0.286  0.696  1.0
  F  F12  1  0.397  0.195  0.266  1.0
  F  F13  1  0.195  0.397  0.266  1.0
  F  F14  1  0.603  0.805  0.734  1.0
  F  F15  1  0.805  0.603  0.734  1.0
  F  F16  1  0.343  0.343  0.398  1.0
  F  F17  1  0.657  0.657  0.602  1.0
[/CIF]
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The material described by AsF6(I)2 is Indium-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of four 7553-56-2 molecules and four AsF6 clusters. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to one F(1), one F(4), two equivalent F(2), and two equivalent F(3) atoms. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one As(1) atom. is represented by the CIF card [CIF]
data_As(IF3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.293
_cell_length_b   7.293
_cell_length_c   15.476
_cell_angle_alpha   83.293
_cell_angle_beta   83.293
_cell_angle_gamma   120.287
_symmetry_Int_Tables_number   1
_cell_volume   691.012
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.458  0.458  0.281  1.0
  As  As1  1  0.542  0.542  0.719  1.0
  I  I2  1  0.963  0.468  0.587  1.0
  I  I3  1  0.468  0.963  0.587  1.0
  I  I4  1  0.037  0.532  0.413  1.0
  I  I5  1  0.532  0.037  0.413  1.0
  F  F6  1  0.570  0.570  0.169  1.0
  F  F7  1  0.430  0.430  0.831  1.0
  F  F8  1  0.714  0.513  0.304  1.0
  F  F9  1  0.513  0.714  0.304  1.0
  F  F10  1  0.286  0.487  0.696  1.0
  F  F11  1  0.487  0.286  0.696  1.0
  F  F12  1  0.397  0.195  0.266  1.0
  F  F13  1  0.195  0.397  0.266  1.0
  F  F14  1  0.603  0.805  0.734  1.0
  F  F15  1  0.805  0.603  0.734  1.0
  F  F16  1  0.343  0.343  0.398  1.0
  F  F17  1  0.657  0.657  0.602  1.0
[/CIF]
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