The structure described by Mn2InC10O10I is Hg_xSn structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one Mn2InC10O10I cluster. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one In(1), one C(1), one C(10), one C(3), one C(6), and one C(9) atom to form corner-sharing MnInC5 square pyramids. In the second Mn site, Mn(2) is bonded to one In(1), one C(2), one C(4), one C(5), one C(7), and one C(8) atom to form corner-sharing MnInC5 square pyramids. In(1) is bonded to one Mn(1), one Mn(2), and two equivalent I(1) atoms to form distorted edge-sharing InMn2I2 tetrahedra. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Mn(1) and one O(2) atom. In the second C site, C(2) is bonded in a linear geometry to one Mn(2) and one O(1,4) atom. In the third C site, C(3) is bonded in a linear geometry to one Mn(1) and one O(6) atom. In the fourth C site, C(4) is bonded in a linear geometry to one Mn(2) and one O(9) atom. In the fifth C site, C(5) is bonded in a linear geometry to one Mn(2) and one O(1,4) atom. In the sixth C site, C(6) is bonded in a linear geometry to one Mn(1) and one O(8) atom. In the seventh C site, C(7) is bonded in a linear geometry to one Mn(2) and one O(3) atom. In the eighth C site, C(8) is bonded in a linear geometry to one Mn(2) and one O(5) atom. In the ninth C site, C(9) is bonded in a linear geometry to one Mn(1) and one O(7) atom. In the tenth C site, C(10) is bonded in a linear geometry to one Mn(1) and one O(10) atom. There are nine inequivalent O sites. In the first O site, O(1,4) is bonded in a single-bond geometry to one C(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(7) atom. In the fourth O site, O(5) is bonded in a single-bond geometry to one C(8) atom. In the fifth O site, O(6) is bonded in a single-bond geometry to one C(3) atom. In the sixth O site, O(7) is bonded in a single-bond geometry to one C(9) atom. In the seventh O site, O(8) is bonded in a single-bond geometry to one C(6) atom. In the eighth O site, O(9) is bonded in a single-bond geometry to one C(4) atom. In the ninth O site, O(10) is bonded in a single-bond geometry to one C(10) atom. I(1) is bonded in an L-shaped geometry to two equivalent In(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mn2InC10IO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.159
_cell_length_b   10.055
_cell_length_c   10.559
_cell_angle_alpha   117.069
_cell_angle_beta   92.427
_cell_angle_gamma   92.991
_symmetry_Int_Tables_number   1
_cell_volume   862.305
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.249  0.718  0.070  1.0
  Mn  Mn1  1  0.757  0.756  0.591  1.0
  Mn  Mn2  1  0.751  0.282  0.930  1.0
  Mn  Mn3  1  0.243  0.244  0.409  1.0
  In  In4  1  0.160  1.000  0.157  1.0
  In  In5  1  0.840  0.000  0.843  1.0
  C  C6  1  0.609  0.215  0.014  1.0
  C  C7  1  0.310  0.400  0.578  1.0
  C  C8  1  0.376  0.787  0.234  1.0
  C  C9  1  0.208  0.107  0.480  1.0
  C  C10  1  0.430  0.181  0.368  1.0
  C  C11  1  0.903  0.297  0.825  1.0
  C  C12  1  0.735  0.647  0.693  1.0
  C  C13  1  0.046  0.286  0.431  1.0
  C  C14  1  0.624  0.213  0.766  1.0
  C  C15  1  0.265  0.353  0.307  1.0
  C  C16  1  0.118  0.672  0.913  1.0
  C  C17  1  0.792  0.893  0.520  1.0
  C  C18  1  0.304  0.527  0.998  1.0
  C  C19  1  0.690  0.600  0.422  1.0
  C  C20  1  0.570  0.819  0.632  1.0
  C  C21  1  0.954  0.714  0.569  1.0
  C  C22  1  0.097  0.703  0.175  1.0
  C  C23  1  0.696  0.473  0.002  1.0
  C  C24  1  0.391  0.785  0.986  1.0
  C  C25  1  0.882  0.328  0.087  1.0
  I  I26  1  0.836  0.952  0.101  1.0
  I  I27  1  0.164  0.048  0.899  1.0
  O  O28  1  0.356  0.501  0.685  1.0
  O  O29  1  0.480  0.823  0.932  1.0
  O  O30  1  0.717  0.574  0.750  1.0
  O  O31  1  0.548  0.145  0.346  1.0
  O  O32  1  0.074  0.685  0.550  1.0
  O  O33  1  0.926  0.315  0.450  1.0
  O  O34  1  0.520  0.177  0.068  1.0
  O  O35  1  0.455  0.826  0.335  1.0
  O  O36  1  0.039  0.638  0.813  1.0
  O  O37  1  0.644  0.499  0.315  1.0
  O  O38  1  0.997  0.306  0.759  1.0
  O  O39  1  0.814  0.977  0.475  1.0
  O  O40  1  0.452  0.855  0.654  1.0
  O  O41  1  0.341  0.406  0.949  1.0
  O  O42  1  0.186  0.023  0.525  1.0
  O  O43  1  0.283  0.426  0.250  1.0
  O  O44  1  0.003  0.694  0.241  1.0
  O  O45  1  0.961  0.362  0.187  1.0
  O  O46  1  0.659  0.594  0.051  1.0
  O  O47  1  0.545  0.174  0.665  1.0
[/CIF]
.
The structure described by Mn2InC10O10I is Hg_xSn structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one Mn2InC10O10I cluster. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one In(1), one C(1), one C(10), one C(3), one C(6), and one C(9) atom to form corner-sharing MnInC5 square pyramids. In the second Mn site, Mn(2) is bonded to one In(1), one C(2), one C(4), one C(5), one C(7), and one C(8) atom to form corner-sharing MnInC5 square pyramids. In(1) is bonded to one Mn(1), one Mn(2), and two equivalent I(1) atoms to form distorted edge-sharing InMn2I2 tetrahedra. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Mn(1) and one O(2) atom. In the second C site, C(2) is bonded in a linear geometry to one Mn(2) and one O(1,4) atom. In the third C site, C(3) is bonded in a linear geometry to one Mn(1) and one O(6) atom. In the fourth C site, C(4) is bonded in a linear geometry to one Mn(2) and one O(9) atom. In the fifth C site, C(5) is bonded in a linear geometry to one Mn(2) and one O(1,4) atom. In the sixth C site, C(6) is bonded in a linear geometry to one Mn(1) and one O(8) atom. In the seventh C site, C(7) is bonded in a linear geometry to one Mn(2) and one O(3) atom. In the eighth C site, C(8) is bonded in a linear geometry to one Mn(2) and one O(5) atom. In the ninth C site, C(9) is bonded in a linear geometry to one Mn(1) and one O(7) atom. In the tenth C site, C(10) is bonded in a linear geometry to one Mn(1) and one O(10) atom. There are nine inequivalent O sites. In the first O site, O(1,4) is bonded in a single-bond geometry to one C(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(7) atom. In the fourth O site, O(5) is bonded in a single-bond geometry to one C(8) atom. In the fifth O site, O(6) is bonded in a single-bond geometry to one C(3) atom. In the sixth O site, O(7) is bonded in a single-bond geometry to one C(9) atom. In the seventh O site, O(8) is bonded in a single-bond geometry to one C(6) atom. In the eighth O site, O(9) is bonded in a single-bond geometry to one C(4) atom. In the ninth O site, O(10) is bonded in a single-bond geometry to one C(10) atom. I(1) is bonded in an L-shaped geometry to two equivalent In(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mn2InC10IO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.159
_cell_length_b   10.055
_cell_length_c   10.559
_cell_angle_alpha   117.069
_cell_angle_beta   92.427
_cell_angle_gamma   92.991
_symmetry_Int_Tables_number   1
_cell_volume   862.305
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.249  0.718  0.070  1.0
  Mn  Mn1  1  0.757  0.756  0.591  1.0
  Mn  Mn2  1  0.751  0.282  0.930  1.0
  Mn  Mn3  1  0.243  0.244  0.409  1.0
  In  In4  1  0.160  1.000  0.157  1.0
  In  In5  1  0.840  0.000  0.843  1.0
  C  C6  1  0.609  0.215  0.014  1.0
  C  C7  1  0.310  0.400  0.578  1.0
  C  C8  1  0.376  0.787  0.234  1.0
  C  C9  1  0.208  0.107  0.480  1.0
  C  C10  1  0.430  0.181  0.368  1.0
  C  C11  1  0.903  0.297  0.825  1.0
  C  C12  1  0.735  0.647  0.693  1.0
  C  C13  1  0.046  0.286  0.431  1.0
  C  C14  1  0.624  0.213  0.766  1.0
  C  C15  1  0.265  0.353  0.307  1.0
  C  C16  1  0.118  0.672  0.913  1.0
  C  C17  1  0.792  0.893  0.520  1.0
  C  C18  1  0.304  0.527  0.998  1.0
  C  C19  1  0.690  0.600  0.422  1.0
  C  C20  1  0.570  0.819  0.632  1.0
  C  C21  1  0.954  0.714  0.569  1.0
  C  C22  1  0.097  0.703  0.175  1.0
  C  C23  1  0.696  0.473  0.002  1.0
  C  C24  1  0.391  0.785  0.986  1.0
  C  C25  1  0.882  0.328  0.087  1.0
  I  I26  1  0.836  0.952  0.101  1.0
  I  I27  1  0.164  0.048  0.899  1.0
  O  O28  1  0.356  0.501  0.685  1.0
  O  O29  1  0.480  0.823  0.932  1.0
  O  O30  1  0.717  0.574  0.750  1.0
  O  O31  1  0.548  0.145  0.346  1.0
  O  O32  1  0.074  0.685  0.550  1.0
  O  O33  1  0.926  0.315  0.450  1.0
  O  O34  1  0.520  0.177  0.068  1.0
  O  O35  1  0.455  0.826  0.335  1.0
  O  O36  1  0.039  0.638  0.813  1.0
  O  O37  1  0.644  0.499  0.315  1.0
  O  O38  1  0.997  0.306  0.759  1.0
  O  O39  1  0.814  0.977  0.475  1.0
  O  O40  1  0.452  0.855  0.654  1.0
  O  O41  1  0.341  0.406  0.949  1.0
  O  O42  1  0.186  0.023  0.525  1.0
  O  O43  1  0.283  0.426  0.250  1.0
  O  O44  1  0.003  0.694  0.241  1.0
  O  O45  1  0.961  0.362  0.187  1.0
  O  O46  1  0.659  0.594  0.051  1.0
  O  O47  1  0.545  0.174  0.665  1.0
[/CIF]
.