The compound described by CeY4Rh5 is Heusler-like structured and crystallizes in the tetragonal P4/mmm space group. Ce(1) is bonded in a body-centered cubic geometry to eight equivalent Rh(1) atoms. There are two inequivalent Y sites. In the first Y site, Y(1) is bonded in a body-centered cubic geometry to four equivalent Rh(1) and four equivalent Rh(2) atoms. In the second Y site, Y(2) is bonded in a body-centered cubic geometry to four equivalent Rh(2) and four equivalent Rh(3) atoms. There are three inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a body-centered cubic geometry to four equivalent Ce(1) and four equivalent Y(1) atoms. In the second Rh site, Rh(2) is bonded in a body-centered cubic geometry to four equivalent Y(1) and four equivalent Y(2) atoms. In the third Rh site, Rh(3) is bonded in a body-centered cubic geometry to eight equivalent Y(2) atoms. is represented by the CIF file [CIF]
data_CeY4Rh5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.402
_cell_length_b   3.402
_cell_length_c   17.450
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   202.004
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.000  0.000  0.000  1.0
  Y  Y1  1  0.000  0.000  0.202  1.0
  Y  Y2  1  0.000  0.000  0.401  1.0
  Y  Y3  1  0.000  0.000  0.599  1.0
  Y  Y4  1  0.000  0.000  0.798  1.0
  Rh  Rh5  1  0.500  0.500  0.099  1.0
  Rh  Rh6  1  0.500  0.500  0.301  1.0
  Rh  Rh7  1  0.500  0.500  0.500  1.0
  Rh  Rh8  1  0.500  0.500  0.699  1.0
  Rh  Rh9  1  0.500  0.500  0.901  1.0
[/CIF]
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The compound described by CeY4Rh5 is Heusler-like structured and crystallizes in the tetragonal P4/mmm space group. Ce(1) is bonded in a body-centered cubic geometry to eight equivalent Rh(1) atoms. There are two inequivalent Y sites. In the first Y site, Y(1) is bonded in a body-centered cubic geometry to four equivalent Rh(1) and four equivalent Rh(2) atoms. In the second Y site, Y(2) is bonded in a body-centered cubic geometry to four equivalent Rh(2) and four equivalent Rh(3) atoms. There are three inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a body-centered cubic geometry to four equivalent Ce(1) and four equivalent Y(1) atoms. In the second Rh site, Rh(2) is bonded in a body-centered cubic geometry to four equivalent Y(1) and four equivalent Y(2) atoms. In the third Rh site, Rh(3) is bonded in a body-centered cubic geometry to eight equivalent Y(2) atoms. is represented by the CIF file [CIF]
data_CeY4Rh5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.402
_cell_length_b   3.402
_cell_length_c   17.450
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   202.004
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.000  0.000  0.000  1.0
  Y  Y1  1  0.000  0.000  0.202  1.0
  Y  Y2  1  0.000  0.000  0.401  1.0
  Y  Y3  1  0.000  0.000  0.599  1.0
  Y  Y4  1  0.000  0.000  0.798  1.0
  Rh  Rh5  1  0.500  0.500  0.099  1.0
  Rh  Rh6  1  0.500  0.500  0.301  1.0
  Rh  Rh7  1  0.500  0.500  0.500  1.0
  Rh  Rh8  1  0.500  0.500  0.699  1.0
  Rh  Rh9  1  0.500  0.500  0.901  1.0
[/CIF]
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