The crystal structure described by ZrS2O11(O2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 7782-44-7 molecules and one ZrS2O11 cluster. In the ZrS2O11 cluster, Zr(1) is bonded to one O(12), one O(2), one O(4), one O(7), and one O(8) atom to form distorted ZrO5 trigonal bipyramids that share corners with two equivalent S(2)O4 tetrahedra and  an edgeedge with one S(1)O4 tetrahedra. There are two inequivalent S sites. In the first S site, S(1) is bonded to one O(10), one O(15), one O(4), and one O(8) atom to form SO4 tetrahedra that share  an edgeedge with one Zr(1)O5 trigonal bipyramid. In the second S site, S(2) is bonded to one O(14), one O(2), one O(3), and one O(7) atom to form SO4 tetrahedra that share corners with two equivalent Zr(1)O5 trigonal bipyramids. There are eleven inequivalent O sites. In the first O site, O(14) is bonded in a single-bond geometry to one S(2) atom. In the second O site, O(15) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(2) is bonded in a bent 150 degrees geometry to one Zr(1) and one S(2) atom. In the fourth O site, O(3) is bonded in a single-bond geometry to one S(2) atom. In the fifth O site, O(4) is bonded in a water-like geometry to one Zr(1) and one S(1) atom. In the sixth O site, O(7) is bonded in a bent 150 degrees geometry to one Zr(1) and one S(2) atom. In the seventh O site, O(8) is bonded in a water-like geometry to one Zr(1) and one S(1) atom. In the eighth O site, O(10) is bonded in a single-bond geometry to one S(1) atom. In the ninth O site, O(11) is bonded in a single-bond geometry to one O(13) atom. In the tenth O site, O(12) is bonded in a distorted bent 120 degrees geometry to one Zr(1) and one O(13) atom. In the eleventh O site, O(13) is bonded in a bent 120 degrees geometry to one O(11) and one O(12) atom. is represented by the CIF file [CIF]
data_ZrS2O15
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.125
_cell_length_b   7.640
_cell_length_c   12.900
_cell_angle_alpha   96.342
_cell_angle_beta   109.952
_cell_angle_gamma   90.301
_symmetry_Int_Tables_number   1
_cell_volume   655.327
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr0  1  0.823  0.544  0.808  1.0
  Zr  Zr1  1  0.177  0.456  0.192  1.0
  S  S2  1  0.692  0.320  0.607  1.0
  S  S3  1  0.308  0.680  0.393  1.0
  S  S4  1  0.747  0.279  0.995  1.0
  S  S5  1  0.253  0.721  0.005  1.0
  O  O6  1  0.946  0.833  0.683  1.0
  O  O7  1  0.054  0.167  0.317  1.0
  O  O8  1  0.776  0.437  0.932  1.0
  O  O9  1  0.224  0.563  0.068  1.0
  O  O10  1  0.818  0.123  0.950  1.0
  O  O11  1  0.182  0.877  0.050  1.0
  O  O12  1  0.839  0.296  0.727  1.0
  O  O13  1  0.161  0.704  0.273  1.0
  O  O14  1  0.307  0.369  0.741  1.0
  O  O15  1  0.693  0.631  0.259  1.0
  O  O16  1  0.189  0.470  0.688  1.0
  O  O17  1  0.811  0.530  0.312  1.0
  O  O18  1  0.100  0.660  0.885  1.0
  O  O19  1  0.900  0.340  0.115  1.0
  O  O20  1  0.667  0.522  0.631  1.0
  O  O21  1  0.333  0.478  0.369  1.0
  O  O22  1  0.845  0.899  0.601  1.0
  O  O23  1  0.155  0.101  0.399  1.0
  O  O24  1  0.789  0.285  0.526  1.0
  O  O25  1  0.211  0.715  0.474  1.0
  O  O26  1  0.398  0.952  0.776  1.0
  O  O27  1  0.602  0.048  0.224  1.0
  O  O28  1  0.583  0.714  0.802  1.0
  O  O29  1  0.417  0.286  0.198  1.0
  O  O30  1  0.559  0.892  0.776  1.0
  O  O31  1  0.441  0.108  0.224  1.0
  O  O32  1  0.549  0.278  0.998  1.0
  O  O33  1  0.451  0.722  0.002  1.0
  O  O34  1  0.507  0.220  0.585  1.0
  O  O35  1  0.493  0.780  0.415  1.0
[/CIF]
.
The crystal structure described by ZrS2O11(O2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 7782-44-7 molecules and one ZrS2O11 cluster. In the ZrS2O11 cluster, Zr(1) is bonded to one O(12), one O(2), one O(4), one O(7), and one O(8) atom to form distorted ZrO5 trigonal bipyramids that share corners with two equivalent S(2)O4 tetrahedra and  an edgeedge with one S(1)O4 tetrahedra. There are two inequivalent S sites. In the first S site, S(1) is bonded to one O(10), one O(15), one O(4), and one O(8) atom to form SO4 tetrahedra that share  an edgeedge with one Zr(1)O5 trigonal bipyramid. In the second S site, S(2) is bonded to one O(14), one O(2), one O(3), and one O(7) atom to form SO4 tetrahedra that share corners with two equivalent Zr(1)O5 trigonal bipyramids. There are eleven inequivalent O sites. In the first O site, O(14) is bonded in a single-bond geometry to one S(2) atom. In the second O site, O(15) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(2) is bonded in a bent 150 degrees geometry to one Zr(1) and one S(2) atom. In the fourth O site, O(3) is bonded in a single-bond geometry to one S(2) atom. In the fifth O site, O(4) is bonded in a water-like geometry to one Zr(1) and one S(1) atom. In the sixth O site, O(7) is bonded in a bent 150 degrees geometry to one Zr(1) and one S(2) atom. In the seventh O site, O(8) is bonded in a water-like geometry to one Zr(1) and one S(1) atom. In the eighth O site, O(10) is bonded in a single-bond geometry to one S(1) atom. In the ninth O site, O(11) is bonded in a single-bond geometry to one O(13) atom. In the tenth O site, O(12) is bonded in a distorted bent 120 degrees geometry to one Zr(1) and one O(13) atom. In the eleventh O site, O(13) is bonded in a bent 120 degrees geometry to one O(11) and one O(12) atom. is represented by the CIF file [CIF]
data_ZrS2O15
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.125
_cell_length_b   7.640
_cell_length_c   12.900
_cell_angle_alpha   96.342
_cell_angle_beta   109.952
_cell_angle_gamma   90.301
_symmetry_Int_Tables_number   1
_cell_volume   655.327
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr0  1  0.823  0.544  0.808  1.0
  Zr  Zr1  1  0.177  0.456  0.192  1.0
  S  S2  1  0.692  0.320  0.607  1.0
  S  S3  1  0.308  0.680  0.393  1.0
  S  S4  1  0.747  0.279  0.995  1.0
  S  S5  1  0.253  0.721  0.005  1.0
  O  O6  1  0.946  0.833  0.683  1.0
  O  O7  1  0.054  0.167  0.317  1.0
  O  O8  1  0.776  0.437  0.932  1.0
  O  O9  1  0.224  0.563  0.068  1.0
  O  O10  1  0.818  0.123  0.950  1.0
  O  O11  1  0.182  0.877  0.050  1.0
  O  O12  1  0.839  0.296  0.727  1.0
  O  O13  1  0.161  0.704  0.273  1.0
  O  O14  1  0.307  0.369  0.741  1.0
  O  O15  1  0.693  0.631  0.259  1.0
  O  O16  1  0.189  0.470  0.688  1.0
  O  O17  1  0.811  0.530  0.312  1.0
  O  O18  1  0.100  0.660  0.885  1.0
  O  O19  1  0.900  0.340  0.115  1.0
  O  O20  1  0.667  0.522  0.631  1.0
  O  O21  1  0.333  0.478  0.369  1.0
  O  O22  1  0.845  0.899  0.601  1.0
  O  O23  1  0.155  0.101  0.399  1.0
  O  O24  1  0.789  0.285  0.526  1.0
  O  O25  1  0.211  0.715  0.474  1.0
  O  O26  1  0.398  0.952  0.776  1.0
  O  O27  1  0.602  0.048  0.224  1.0
  O  O28  1  0.583  0.714  0.802  1.0
  O  O29  1  0.417  0.286  0.198  1.0
  O  O30  1  0.559  0.892  0.776  1.0
  O  O31  1  0.441  0.108  0.224  1.0
  O  O32  1  0.549  0.278  0.998  1.0
  O  O33  1  0.451  0.722  0.002  1.0
  O  O34  1  0.507  0.220  0.585  1.0
  O  O35  1  0.493  0.780  0.415  1.0
[/CIF]
.