The structure described by FeNF4(NF)2 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two monofluoroamine molecules and one FeNF4 cluster. In the FeNF4 cluster, Fe(1) is bonded in a 3-coordinate geometry to one F(1), one F(2), one F(4), and one F(6) atom. N(1) is bonded in a single-bond geometry to one F(2) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Fe(1) atom. In the second F site, F(2) is bonded in a distorted bent 150 degrees geometry to one Fe(1) and one N(1) atom. In the third F site, F(4) is bonded in a single-bond geometry to one Fe(1) atom. In the fourth F site, F(6) is bonded in a single-bond geometry to one Fe(1) atom. is represented by the CIF card [CIF]
data_Fe(NF2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.943
_cell_length_b   6.169
_cell_length_c   6.327
_cell_angle_alpha   92.203
_cell_angle_beta   117.596
_cell_angle_gamma   115.028
_symmetry_Int_Tables_number   1
_cell_volume   178.172
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Fe  Fe0  1  0.067  0.954  0.011  1.0
  N  N1  1  0.594  0.228  0.744  1.0
  N  N2  1  0.495  0.742  0.156  1.0
  N  N3  1  0.021  0.410  0.464  1.0
  F  F4  1  0.083  0.825  0.262  1.0
  F  F5  1  0.821  0.191  0.789  1.0
  F  F6  1  0.106  0.327  0.329  1.0
  F  F7  1  0.871  0.742  0.707  1.0
  F  F8  1  0.522  0.761  0.955  1.0
  F  F9  1  0.401  0.226  0.087  1.0
[/CIF]
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The structure described by FeNF4(NF)2 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two monofluoroamine molecules and one FeNF4 cluster. In the FeNF4 cluster, Fe(1) is bonded in a 3-coordinate geometry to one F(1), one F(2), one F(4), and one F(6) atom. N(1) is bonded in a single-bond geometry to one F(2) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Fe(1) atom. In the second F site, F(2) is bonded in a distorted bent 150 degrees geometry to one Fe(1) and one N(1) atom. In the third F site, F(4) is bonded in a single-bond geometry to one Fe(1) atom. In the fourth F site, F(6) is bonded in a single-bond geometry to one Fe(1) atom. is represented by the CIF card [CIF]
data_Fe(NF2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.943
_cell_length_b   6.169
_cell_length_c   6.327
_cell_angle_alpha   92.203
_cell_angle_beta   117.596
_cell_angle_gamma   115.028
_symmetry_Int_Tables_number   1
_cell_volume   178.172
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Fe  Fe0  1  0.067  0.954  0.011  1.0
  N  N1  1  0.594  0.228  0.744  1.0
  N  N2  1  0.495  0.742  0.156  1.0
  N  N3  1  0.021  0.410  0.464  1.0
  F  F4  1  0.083  0.825  0.262  1.0
  F  F5  1  0.821  0.191  0.789  1.0
  F  F6  1  0.106  0.327  0.329  1.0
  F  F7  1  0.871  0.742  0.707  1.0
  F  F8  1  0.522  0.761  0.955  1.0
  F  F9  1  0.401  0.226  0.087  1.0
[/CIF]
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