The crystal structure described by Li5Co7O3F13 crystallizes in the triclinic P1 space group. There are five inequivalent Li sites. In the first Li site, Li(1) is bonded in a distorted single-bond geometry to one F(2), one F(4), and one F(9) atom. In the second Li site, Li(2) is bonded in a distorted single-bond geometry to one F(12), one F(4), and one F(9) atom. In the third Li site, Li(3) is bonded in a distorted single-bond geometry to one F(11), one F(3), and one F(7) atom. In the fourth Li site, Li(4) is bonded in a distorted single-bond geometry to one F(11), one F(3), and one F(6) atom. In the fifth Li site, Li(5) is bonded in a 4-coordinate geometry to one O(3), one F(10), one F(13), and one F(8) atom. There are seven inequivalent Co sites. In the first Co site, Co(1) is bonded in a 2-coordinate geometry to one F(12), one F(13), one F(2), one F(4), and one F(9) atom. In the second Co site, Co(2) is bonded in a distorted linear geometry to one F(1) and one F(5) atom. In the third Co site, Co(3) is bonded in a distorted linear geometry to one O(1), one O(2), one F(2), one F(3), one F(4), and one F(6) atom. In the fourth Co site, Co(4) is bonded in a distorted square co-planar geometry to one O(1), one O(2), one F(1), and one F(5) atom. In the fifth Co site, Co(5) is bonded in a 2-coordinate geometry to one O(3), one F(11), one F(3), one F(6), and one F(7) atom. In the sixth Co site, Co(6) is bonded in a distorted linear geometry to one O(3) and one F(13) atom. In the seventh Co site, Co(7) is bonded in a 2-coordinate geometry to one F(11) and one F(9) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Co(3) and one Co(4) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Co(3) and one Co(4) atom. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one Li(5), one Co(5), and one Co(6) atom. There are thirteen inequivalent F sites. In the first F site, F(1) is bonded in a distorted water-like geometry to one Co(2) and one Co(4) atom. In the second F site, F(2) is bonded in a 2-coordinate geometry to one Li(1), one Co(1), and one Co(3) atom. In the third F site, F(3) is bonded in a 4-coordinate geometry to one Li(3), one Li(4), one Co(3), and one Co(5) atom. In the fourth F site, F(4) is bonded in a 4-coordinate geometry to one Li(1), one Li(2), one Co(1), and one Co(3) atom. In the fifth F site, F(5) is bonded in a distorted water-like geometry to one Co(2) and one Co(4) atom. In the sixth F site, F(6) is bonded in a 2-coordinate geometry to one Li(4), one Co(3), and one Co(5) atom. In the seventh F site, F(7) is bonded in a 1-coordinate geometry to one Li(3) and one Co(5) atom. In the eighth F site, F(8) is bonded in a distorted single-bond geometry to one Li(5) atom. In the ninth F site, F(9) is bonded in a 4-coordinate geometry to one Li(1), one Li(2), one Co(1), and one Co(7) atom. In the tenth F site, F(10) is bonded in a distorted single-bond geometry to one Li(5) atom. In the eleventh F site, F(11) is bonded in a 4-coordinate geometry to one Li(3), one Li(4), one Co(5), and one Co(7) atom. In the twelfth F site, F(12) is bonded in a 2-coordinate geometry to one Li(2) and one Co(1) atom. In the thirteenth F site, F(13) is bonded in a 3-coordinate geometry to one Li(5), one Co(1), and one Co(6) atom. is represented by the CIF card [CIF]
data_Li5Co7O3F13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.067
_cell_length_b   6.140
_cell_length_c   10.517
_cell_angle_alpha   73.075
_cell_angle_beta   73.342
_cell_angle_gamma   60.388
_symmetry_Int_Tables_number   1
_cell_volume   321.011
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.267  0.664  0.128  1.0
  Li  Li1  1  0.004  0.990  0.988  1.0
  Li  Li2  1  0.236  0.125  0.635  1.0
  Li  Li3  1  0.985  0.459  0.497  1.0
  Li  Li4  1  0.122  0.562  0.810  1.0
  Co  Co5  1  0.619  0.295  0.065  1.0
  Co  Co6  1  0.629  0.567  0.314  1.0
  Co  Co7  1  0.624  0.062  0.313  1.0
  Co  Co8  1  0.126  0.063  0.312  1.0
  Co  Co9  1  0.644  0.840  0.567  1.0
  Co  Co10  1  0.636  0.054  0.805  1.0
  Co  Co11  1  0.635  0.580  0.804  1.0
  O  O12  1  0.395  0.990  0.202  1.0
  O  O13  1  0.858  0.137  0.423  1.0
  O  O14  1  0.845  0.922  0.695  1.0
  F  F15  1  0.870  0.451  0.190  1.0
  F  F16  1  0.397  0.453  0.189  1.0
  F  F17  1  0.385  0.206  0.435  1.0
  F  F18  1  0.872  0.926  0.186  1.0
  F  F19  1  0.386  0.679  0.438  1.0
  F  F20  1  0.864  0.676  0.434  1.0
  F  F21  1  0.364  0.924  0.699  1.0
  F  F22  1  0.377  0.465  0.692  1.0
  F  F23  1  0.372  0.688  0.929  1.0
  F  F24  1  0.853  0.648  0.939  1.0
  F  F25  1  0.863  0.428  0.699  1.0
  F  F26  1  0.868  0.195  0.934  1.0
  F  F27  1  0.402  0.201  0.925  1.0
[/CIF]
.
The crystal structure described by Li5Co7O3F13 crystallizes in the triclinic P1 space group. There are five inequivalent Li sites. In the first Li site, Li(1) is bonded in a distorted single-bond geometry to one F(2), one F(4), and one F(9) atom. In the second Li site, Li(2) is bonded in a distorted single-bond geometry to one F(12), one F(4), and one F(9) atom. In the third Li site, Li(3) is bonded in a distorted single-bond geometry to one F(11), one F(3), and one F(7) atom. In the fourth Li site, Li(4) is bonded in a distorted single-bond geometry to one F(11), one F(3), and one F(6) atom. In the fifth Li site, Li(5) is bonded in a 4-coordinate geometry to one O(3), one F(10), one F(13), and one F(8) atom. There are seven inequivalent Co sites. In the first Co site, Co(1) is bonded in a 2-coordinate geometry to one F(12), one F(13), one F(2), one F(4), and one F(9) atom. In the second Co site, Co(2) is bonded in a distorted linear geometry to one F(1) and one F(5) atom. In the third Co site, Co(3) is bonded in a distorted linear geometry to one O(1), one O(2), one F(2), one F(3), one F(4), and one F(6) atom. In the fourth Co site, Co(4) is bonded in a distorted square co-planar geometry to one O(1), one O(2), one F(1), and one F(5) atom. In the fifth Co site, Co(5) is bonded in a 2-coordinate geometry to one O(3), one F(11), one F(3), one F(6), and one F(7) atom. In the sixth Co site, Co(6) is bonded in a distorted linear geometry to one O(3) and one F(13) atom. In the seventh Co site, Co(7) is bonded in a 2-coordinate geometry to one F(11) and one F(9) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Co(3) and one Co(4) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Co(3) and one Co(4) atom. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one Li(5), one Co(5), and one Co(6) atom. There are thirteen inequivalent F sites. In the first F site, F(1) is bonded in a distorted water-like geometry to one Co(2) and one Co(4) atom. In the second F site, F(2) is bonded in a 2-coordinate geometry to one Li(1), one Co(1), and one Co(3) atom. In the third F site, F(3) is bonded in a 4-coordinate geometry to one Li(3), one Li(4), one Co(3), and one Co(5) atom. In the fourth F site, F(4) is bonded in a 4-coordinate geometry to one Li(1), one Li(2), one Co(1), and one Co(3) atom. In the fifth F site, F(5) is bonded in a distorted water-like geometry to one Co(2) and one Co(4) atom. In the sixth F site, F(6) is bonded in a 2-coordinate geometry to one Li(4), one Co(3), and one Co(5) atom. In the seventh F site, F(7) is bonded in a 1-coordinate geometry to one Li(3) and one Co(5) atom. In the eighth F site, F(8) is bonded in a distorted single-bond geometry to one Li(5) atom. In the ninth F site, F(9) is bonded in a 4-coordinate geometry to one Li(1), one Li(2), one Co(1), and one Co(7) atom. In the tenth F site, F(10) is bonded in a distorted single-bond geometry to one Li(5) atom. In the eleventh F site, F(11) is bonded in a 4-coordinate geometry to one Li(3), one Li(4), one Co(5), and one Co(7) atom. In the twelfth F site, F(12) is bonded in a 2-coordinate geometry to one Li(2) and one Co(1) atom. In the thirteenth F site, F(13) is bonded in a 3-coordinate geometry to one Li(5), one Co(1), and one Co(6) atom. is represented by the CIF card [CIF]
data_Li5Co7O3F13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.067
_cell_length_b   6.140
_cell_length_c   10.517
_cell_angle_alpha   73.075
_cell_angle_beta   73.342
_cell_angle_gamma   60.388
_symmetry_Int_Tables_number   1
_cell_volume   321.011
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.267  0.664  0.128  1.0
  Li  Li1  1  0.004  0.990  0.988  1.0
  Li  Li2  1  0.236  0.125  0.635  1.0
  Li  Li3  1  0.985  0.459  0.497  1.0
  Li  Li4  1  0.122  0.562  0.810  1.0
  Co  Co5  1  0.619  0.295  0.065  1.0
  Co  Co6  1  0.629  0.567  0.314  1.0
  Co  Co7  1  0.624  0.062  0.313  1.0
  Co  Co8  1  0.126  0.063  0.312  1.0
  Co  Co9  1  0.644  0.840  0.567  1.0
  Co  Co10  1  0.636  0.054  0.805  1.0
  Co  Co11  1  0.635  0.580  0.804  1.0
  O  O12  1  0.395  0.990  0.202  1.0
  O  O13  1  0.858  0.137  0.423  1.0
  O  O14  1  0.845  0.922  0.695  1.0
  F  F15  1  0.870  0.451  0.190  1.0
  F  F16  1  0.397  0.453  0.189  1.0
  F  F17  1  0.385  0.206  0.435  1.0
  F  F18  1  0.872  0.926  0.186  1.0
  F  F19  1  0.386  0.679  0.438  1.0
  F  F20  1  0.864  0.676  0.434  1.0
  F  F21  1  0.364  0.924  0.699  1.0
  F  F22  1  0.377  0.465  0.692  1.0
  F  F23  1  0.372  0.688  0.929  1.0
  F  F24  1  0.853  0.648  0.939  1.0
  F  F25  1  0.863  0.428  0.699  1.0
  F  F26  1  0.868  0.195  0.934  1.0
  F  F27  1  0.402  0.201  0.925  1.0
[/CIF]
.