The crystal structure described by FeCl4N2TeS2Cl is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four tetrachloroferrat(iii) molecules and four N2TeS2Cl clusters. In each N2TeS2Cl cluster, there are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one Te(1) and one S(2) atom. Te(1) is bonded in a 3-coordinate geometry to one N(2), one S(1), and one Cl(1) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted water-like geometry to one N(1) and one Te(1) atom. In the second S site, S(2) is bonded in a bent 120 degrees geometry to one N(1) and one N(2) atom. Cl(1) is bonded in a single-bond geometry to one Te(1) atom. is represented by the CIF card [CIF]
data_FeTeS2N2Cl5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.568
_cell_length_b   7.642
_cell_length_c   12.820
_cell_angle_alpha   82.606
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1220.963
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Fe  Fe0  1  0.143  0.273  0.462  1.0
  Fe  Fe1  1  0.643  0.727  0.038  1.0
  Fe  Fe2  1  0.857  0.727  0.538  1.0
  Fe  Fe3  1  0.357  0.273  0.962  1.0
  Te  Te4  1  0.062  0.861  0.260  1.0
  Te  Te5  1  0.562  0.139  0.240  1.0
  Te  Te6  1  0.938  0.139  0.740  1.0
  Te  Te7  1  0.438  0.861  0.760  1.0
  S  S8  1  0.015  0.373  0.839  1.0
  S  S9  1  0.308  0.709  0.589  1.0
  S  S10  1  0.515  0.627  0.661  1.0
  S  S11  1  0.192  0.709  0.089  1.0
  S  S12  1  0.485  0.373  0.339  1.0
  S  S13  1  0.692  0.291  0.411  1.0
  S  S14  1  0.808  0.291  0.911  1.0
  S  S15  1  0.985  0.627  0.161  1.0
  N  N16  1  0.085  0.605  0.083  1.0
  N  N17  1  0.415  0.605  0.583  1.0
  N  N18  1  0.691  0.163  0.325  1.0
  N  N19  1  0.585  0.395  0.417  1.0
  N  N20  1  0.191  0.837  0.175  1.0
  N  N21  1  0.809  0.163  0.825  1.0
  N  N22  1  0.915  0.395  0.917  1.0
  N  N23  1  0.309  0.837  0.675  1.0
  Cl  Cl24  1  0.002  0.877  0.845  1.0
  Cl  Cl25  1  0.768  0.942  0.601  1.0
  Cl  Cl26  1  0.732  0.942  0.101  1.0
  Cl  Cl27  1  0.833  0.736  0.365  1.0
  Cl  Cl28  1  0.998  0.123  0.155  1.0
  Cl  Cl29  1  0.498  0.877  0.345  1.0
  Cl  Cl30  1  0.333  0.264  0.135  1.0
  Cl  Cl31  1  0.973  0.242  0.431  1.0
  Cl  Cl32  1  0.297  0.527  0.878  1.0
  Cl  Cl33  1  0.473  0.758  0.069  1.0
  Cl  Cl34  1  0.268  0.058  0.899  1.0
  Cl  Cl35  1  0.527  0.242  0.931  1.0
  Cl  Cl36  1  0.027  0.758  0.569  1.0
  Cl  Cl37  1  0.167  0.264  0.635  1.0
  Cl  Cl38  1  0.232  0.058  0.399  1.0
  Cl  Cl39  1  0.203  0.527  0.378  1.0
  Cl  Cl40  1  0.502  0.123  0.655  1.0
  Cl  Cl41  1  0.667  0.736  0.865  1.0
  Cl  Cl42  1  0.797  0.473  0.622  1.0
  Cl  Cl43  1  0.703  0.473  0.122  1.0
[/CIF]
.
The crystal structure described by FeCl4N2TeS2Cl is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four tetrachloroferrat(iii) molecules and four N2TeS2Cl clusters. In each N2TeS2Cl cluster, there are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one Te(1) and one S(2) atom. Te(1) is bonded in a 3-coordinate geometry to one N(2), one S(1), and one Cl(1) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted water-like geometry to one N(1) and one Te(1) atom. In the second S site, S(2) is bonded in a bent 120 degrees geometry to one N(1) and one N(2) atom. Cl(1) is bonded in a single-bond geometry to one Te(1) atom. is represented by the CIF card [CIF]
data_FeTeS2N2Cl5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.568
_cell_length_b   7.642
_cell_length_c   12.820
_cell_angle_alpha   82.606
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1220.963
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Fe  Fe0  1  0.143  0.273  0.462  1.0
  Fe  Fe1  1  0.643  0.727  0.038  1.0
  Fe  Fe2  1  0.857  0.727  0.538  1.0
  Fe  Fe3  1  0.357  0.273  0.962  1.0
  Te  Te4  1  0.062  0.861  0.260  1.0
  Te  Te5  1  0.562  0.139  0.240  1.0
  Te  Te6  1  0.938  0.139  0.740  1.0
  Te  Te7  1  0.438  0.861  0.760  1.0
  S  S8  1  0.015  0.373  0.839  1.0
  S  S9  1  0.308  0.709  0.589  1.0
  S  S10  1  0.515  0.627  0.661  1.0
  S  S11  1  0.192  0.709  0.089  1.0
  S  S12  1  0.485  0.373  0.339  1.0
  S  S13  1  0.692  0.291  0.411  1.0
  S  S14  1  0.808  0.291  0.911  1.0
  S  S15  1  0.985  0.627  0.161  1.0
  N  N16  1  0.085  0.605  0.083  1.0
  N  N17  1  0.415  0.605  0.583  1.0
  N  N18  1  0.691  0.163  0.325  1.0
  N  N19  1  0.585  0.395  0.417  1.0
  N  N20  1  0.191  0.837  0.175  1.0
  N  N21  1  0.809  0.163  0.825  1.0
  N  N22  1  0.915  0.395  0.917  1.0
  N  N23  1  0.309  0.837  0.675  1.0
  Cl  Cl24  1  0.002  0.877  0.845  1.0
  Cl  Cl25  1  0.768  0.942  0.601  1.0
  Cl  Cl26  1  0.732  0.942  0.101  1.0
  Cl  Cl27  1  0.833  0.736  0.365  1.0
  Cl  Cl28  1  0.998  0.123  0.155  1.0
  Cl  Cl29  1  0.498  0.877  0.345  1.0
  Cl  Cl30  1  0.333  0.264  0.135  1.0
  Cl  Cl31  1  0.973  0.242  0.431  1.0
  Cl  Cl32  1  0.297  0.527  0.878  1.0
  Cl  Cl33  1  0.473  0.758  0.069  1.0
  Cl  Cl34  1  0.268  0.058  0.899  1.0
  Cl  Cl35  1  0.527  0.242  0.931  1.0
  Cl  Cl36  1  0.027  0.758  0.569  1.0
  Cl  Cl37  1  0.167  0.264  0.635  1.0
  Cl  Cl38  1  0.232  0.058  0.399  1.0
  Cl  Cl39  1  0.203  0.527  0.378  1.0
  Cl  Cl40  1  0.502  0.123  0.655  1.0
  Cl  Cl41  1  0.667  0.736  0.865  1.0
  Cl  Cl42  1  0.797  0.473  0.622  1.0
  Cl  Cl43  1  0.703  0.473  0.122  1.0
[/CIF]
.