The structure described by CsCN3H4 crystallizes in the orthorhombic Pnma space group. Cs(1) is bonded in a 5-coordinate geometry to one C(1), two equivalent H(1), and two equivalent H(2) atoms. C(1) is bonded in a trigonal planar geometry to one Cs(1), one N(1), and two equivalent N(2) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one C(1) and two equivalent H(1) atoms. In the second N site, N(2) is bonded in a water-like geometry to one C(1) and one H(2) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one Cs(1) and one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one Cs(1) and one N(2) atom. is represented by the CIF file [CIF]
data_CsH4CN3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.389
_cell_length_b   7.224
_cell_length_c   8.163
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   435.707
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.506  0.250  0.904  1.0
  Cs  Cs1  1  0.006  0.250  0.596  1.0
  Cs  Cs2  1  0.494  0.750  0.096  1.0
  Cs  Cs3  1  0.994  0.750  0.404  1.0
  H  H4  1  0.947  0.370  0.956  1.0
  H  H5  1  0.447  0.130  0.544  1.0
  H  H6  1  0.053  0.870  0.044  1.0
  H  H7  1  0.553  0.630  0.456  1.0
  H  H8  1  0.053  0.630  0.044  1.0
  H  H9  1  0.553  0.870  0.456  1.0
  H  H10  1  0.947  0.130  0.956  1.0
  H  H11  1  0.447  0.370  0.544  1.0
  H  H12  1  0.721  0.599  0.737  1.0
  H  H13  1  0.221  0.901  0.763  1.0
  H  H14  1  0.279  0.099  0.263  1.0
  H  H15  1  0.779  0.401  0.237  1.0
  H  H16  1  0.279  0.401  0.263  1.0
  H  H17  1  0.779  0.099  0.237  1.0
  H  H18  1  0.721  0.901  0.737  1.0
  H  H19  1  0.221  0.599  0.763  1.0
  C  C20  1  0.867  0.750  0.881  1.0
  C  C21  1  0.367  0.750  0.619  1.0
  C  C22  1  0.133  0.250  0.119  1.0
  C  C23  1  0.633  0.250  0.381  1.0
  N  N24  1  0.014  0.250  0.987  1.0
  N  N25  1  0.514  0.250  0.513  1.0
  N  N26  1  0.986  0.750  0.013  1.0
  N  N27  1  0.486  0.750  0.487  1.0
  N  N28  1  0.814  0.581  0.829  1.0
  N  N29  1  0.314  0.919  0.671  1.0
  N  N30  1  0.186  0.081  0.171  1.0
  N  N31  1  0.686  0.419  0.329  1.0
  N  N32  1  0.186  0.419  0.171  1.0
  N  N33  1  0.686  0.081  0.329  1.0
  N  N34  1  0.814  0.919  0.829  1.0
  N  N35  1  0.314  0.581  0.671  1.0
[/CIF]
.
The structure described by CsCN3H4 crystallizes in the orthorhombic Pnma space group. Cs(1) is bonded in a 5-coordinate geometry to one C(1), two equivalent H(1), and two equivalent H(2) atoms. C(1) is bonded in a trigonal planar geometry to one Cs(1), one N(1), and two equivalent N(2) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one C(1) and two equivalent H(1) atoms. In the second N site, N(2) is bonded in a water-like geometry to one C(1) and one H(2) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one Cs(1) and one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one Cs(1) and one N(2) atom. is represented by the CIF file [CIF]
data_CsH4CN3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.389
_cell_length_b   7.224
_cell_length_c   8.163
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   435.707
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.506  0.250  0.904  1.0
  Cs  Cs1  1  0.006  0.250  0.596  1.0
  Cs  Cs2  1  0.494  0.750  0.096  1.0
  Cs  Cs3  1  0.994  0.750  0.404  1.0
  H  H4  1  0.947  0.370  0.956  1.0
  H  H5  1  0.447  0.130  0.544  1.0
  H  H6  1  0.053  0.870  0.044  1.0
  H  H7  1  0.553  0.630  0.456  1.0
  H  H8  1  0.053  0.630  0.044  1.0
  H  H9  1  0.553  0.870  0.456  1.0
  H  H10  1  0.947  0.130  0.956  1.0
  H  H11  1  0.447  0.370  0.544  1.0
  H  H12  1  0.721  0.599  0.737  1.0
  H  H13  1  0.221  0.901  0.763  1.0
  H  H14  1  0.279  0.099  0.263  1.0
  H  H15  1  0.779  0.401  0.237  1.0
  H  H16  1  0.279  0.401  0.263  1.0
  H  H17  1  0.779  0.099  0.237  1.0
  H  H18  1  0.721  0.901  0.737  1.0
  H  H19  1  0.221  0.599  0.763  1.0
  C  C20  1  0.867  0.750  0.881  1.0
  C  C21  1  0.367  0.750  0.619  1.0
  C  C22  1  0.133  0.250  0.119  1.0
  C  C23  1  0.633  0.250  0.381  1.0
  N  N24  1  0.014  0.250  0.987  1.0
  N  N25  1  0.514  0.250  0.513  1.0
  N  N26  1  0.986  0.750  0.013  1.0
  N  N27  1  0.486  0.750  0.487  1.0
  N  N28  1  0.814  0.581  0.829  1.0
  N  N29  1  0.314  0.919  0.671  1.0
  N  N30  1  0.186  0.081  0.171  1.0
  N  N31  1  0.686  0.419  0.329  1.0
  N  N32  1  0.186  0.419  0.171  1.0
  N  N33  1  0.686  0.081  0.329  1.0
  N  N34  1  0.814  0.919  0.829  1.0
  N  N35  1  0.314  0.581  0.671  1.0
[/CIF]
.