The material structure described by Na2LiGaAs2 crystallizes in the orthorhombic Cmce space group. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded in a 7-coordinate geometry to two equivalent Ga(1), two equivalent As(1), and three equivalent As(2) atoms. In the second Na site, Na(2) is bonded in a 5-coordinate geometry to two equivalent Ga(1), two equivalent As(2), and three equivalent As(1) atoms. Li(1) is bonded in a 4-coordinate geometry to three equivalent Ga(1), two equivalent As(1), and two equivalent As(2) atoms. Ga(1) is bonded in a 11-coordinate geometry to two equivalent Na(1), two equivalent Na(2), three equivalent Li(1), two equivalent As(1), and two equivalent As(2) atoms. There are two inequivalent As sites. In the first As site, As(1) is bonded in a 9-coordinate geometry to two equivalent Na(1), three equivalent Na(2), two equivalent Li(1), and two equivalent Ga(1) atoms. In the second As site, As(2) is bonded in a 9-coordinate geometry to two equivalent Na(2), three equivalent Na(1), two equivalent Li(1), and two equivalent Ga(1) atoms. is represented by the CIF card [CIF]
data_Na2LiGaAs2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.335
_cell_length_b   9.335
_cell_length_c   5.922
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   98.670
_symmetry_Int_Tables_number   1
_cell_volume   510.199
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.428  0.072  0.250  1.0
  Na  Na1  1  0.072  0.428  0.750  1.0
  Na  Na2  1  0.572  0.928  0.750  1.0
  Na  Na3  1  0.324  0.676  0.279  1.0
  Na  Na4  1  0.824  0.176  0.221  1.0
  Na  Na5  1  0.676  0.324  0.721  1.0
  Na  Na6  1  0.176  0.824  0.779  1.0
  Na  Na7  1  0.928  0.572  0.250  1.0
  Li  Li8  1  0.381  0.381  0.500  1.0
  Li  Li9  1  0.119  0.119  0.000  1.0
  Li  Li10  1  0.619  0.619  0.500  1.0
  Li  Li11  1  0.881  0.881  0.000  1.0
  Ga  Ga12  1  0.869  0.869  0.500  1.0
  Ga  Ga13  1  0.131  0.131  0.500  1.0
  Ga  Ga14  1  0.631  0.631  0.000  1.0
  Ga  Ga15  1  0.369  0.369  0.000  1.0
  As  As16  1  0.107  0.893  0.281  1.0
  As  As17  1  0.607  0.393  0.219  1.0
  As  As18  1  0.893  0.107  0.719  1.0
  As  As19  1  0.393  0.607  0.781  1.0
  As  As20  1  0.143  0.357  0.250  1.0
  As  As21  1  0.357  0.143  0.750  1.0
  As  As22  1  0.857  0.643  0.750  1.0
  As  As23  1  0.643  0.857  0.250  1.0
[/CIF]
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The material structure described by Na2LiGaAs2 crystallizes in the orthorhombic Cmce space group. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded in a 7-coordinate geometry to two equivalent Ga(1), two equivalent As(1), and three equivalent As(2) atoms. In the second Na site, Na(2) is bonded in a 5-coordinate geometry to two equivalent Ga(1), two equivalent As(2), and three equivalent As(1) atoms. Li(1) is bonded in a 4-coordinate geometry to three equivalent Ga(1), two equivalent As(1), and two equivalent As(2) atoms. Ga(1) is bonded in a 11-coordinate geometry to two equivalent Na(1), two equivalent Na(2), three equivalent Li(1), two equivalent As(1), and two equivalent As(2) atoms. There are two inequivalent As sites. In the first As site, As(1) is bonded in a 9-coordinate geometry to two equivalent Na(1), three equivalent Na(2), two equivalent Li(1), and two equivalent Ga(1) atoms. In the second As site, As(2) is bonded in a 9-coordinate geometry to two equivalent Na(2), three equivalent Na(1), two equivalent Li(1), and two equivalent Ga(1) atoms. is represented by the CIF card [CIF]
data_Na2LiGaAs2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.335
_cell_length_b   9.335
_cell_length_c   5.922
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   98.670
_symmetry_Int_Tables_number   1
_cell_volume   510.199
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.428  0.072  0.250  1.0
  Na  Na1  1  0.072  0.428  0.750  1.0
  Na  Na2  1  0.572  0.928  0.750  1.0
  Na  Na3  1  0.324  0.676  0.279  1.0
  Na  Na4  1  0.824  0.176  0.221  1.0
  Na  Na5  1  0.676  0.324  0.721  1.0
  Na  Na6  1  0.176  0.824  0.779  1.0
  Na  Na7  1  0.928  0.572  0.250  1.0
  Li  Li8  1  0.381  0.381  0.500  1.0
  Li  Li9  1  0.119  0.119  0.000  1.0
  Li  Li10  1  0.619  0.619  0.500  1.0
  Li  Li11  1  0.881  0.881  0.000  1.0
  Ga  Ga12  1  0.869  0.869  0.500  1.0
  Ga  Ga13  1  0.131  0.131  0.500  1.0
  Ga  Ga14  1  0.631  0.631  0.000  1.0
  Ga  Ga15  1  0.369  0.369  0.000  1.0
  As  As16  1  0.107  0.893  0.281  1.0
  As  As17  1  0.607  0.393  0.219  1.0
  As  As18  1  0.893  0.107  0.719  1.0
  As  As19  1  0.393  0.607  0.781  1.0
  As  As20  1  0.143  0.357  0.250  1.0
  As  As21  1  0.357  0.143  0.750  1.0
  As  As22  1  0.857  0.643  0.750  1.0
  As  As23  1  0.643  0.857  0.250  1.0
[/CIF]
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