The crystal structure described by PtF5 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two PtF5 clusters. There are two inequivalent Pt sites. In the first Pt site, Pt(1) is bonded to one F(1), one F(10), one F(3), one F(4), one F(5), and one F(6) atom to form corner-sharing PtF6 octahedra. The corner-sharing octahedral tilt angles are 50°. In the second Pt site, Pt(2) is bonded to one F(1), one F(2), one F(6), one F(7), one F(8), and one F(9) atom to form corner-sharing PtF6 octahedra. The corner-sharing octahedral tilt angles are 50°. There are ten inequivalent F sites. In the first F site, F(7) is bonded in a single-bond geometry to one Pt(2) atom. In the second F site, F(8) is bonded in a single-bond geometry to one Pt(2) atom. In the third F site, F(1) is bonded in a bent 120 degrees geometry to one Pt(1) and one Pt(2) atom. In the fourth F site, F(9) is bonded in a single-bond geometry to one Pt(2) atom. In the fifth F site, F(2) is bonded in a single-bond geometry to one Pt(2) atom. In the sixth F site, F(10) is bonded in a single-bond geometry to one Pt(1) atom. In the seventh F site, F(3) is bonded in a single-bond geometry to one Pt(1) atom. In the eighth F site, F(4) is bonded in a single-bond geometry to one Pt(1) atom. In the ninth F site, F(5) is bonded in a single-bond geometry to one Pt(1) atom. In the tenth F site, F(6) is bonded in a bent 120 degrees geometry to one Pt(1) and one Pt(2) atom. is represented by the CIF file [CIF]
data_PtF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.357
_cell_length_b   9.745
_cell_length_c   12.189
_cell_angle_alpha   90.000
_cell_angle_beta   99.578
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   627.434
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pt  Pt0  1  0.999  0.252  0.000  1.0
  Pt  Pt1  1  0.001  0.752  0.500  1.0
  Pt  Pt2  1  0.001  0.748  1.000  1.0
  Pt  Pt3  1  0.999  0.248  0.500  1.0
  Pt  Pt4  1  0.306  1.000  0.202  1.0
  Pt  Pt5  1  0.694  0.500  0.298  1.0
  Pt  Pt6  1  0.694  0.000  0.798  1.0
  Pt  Pt7  1  0.306  0.500  0.702  1.0
  F  F8  1  0.106  0.830  0.155  1.0
  F  F9  1  0.894  0.330  0.345  1.0
  F  F10  1  0.894  0.170  0.845  1.0
  F  F11  1  0.106  0.670  0.655  1.0
  F  F12  1  0.492  0.156  0.248  1.0
  F  F13  1  0.508  0.656  0.252  1.0
  F  F14  1  0.508  0.844  0.752  1.0
  F  F15  1  0.492  0.344  0.748  1.0
  F  F16  1  0.810  0.406  0.953  1.0
  F  F17  1  0.190  0.906  0.548  1.0
  F  F18  1  0.190  0.594  0.048  1.0
  F  F19  1  0.810  0.094  0.453  1.0
  F  F20  1  0.099  0.329  0.142  1.0
  F  F21  1  0.902  0.829  0.358  1.0
  F  F22  1  0.902  0.671  0.858  1.0
  F  F23  1  0.099  0.171  0.642  1.0
  F  F24  1  0.721  0.335  0.546  1.0
  F  F25  1  0.279  0.835  0.954  1.0
  F  F26  1  0.279  0.665  0.454  1.0
  F  F27  1  0.721  0.165  0.046  1.0
  F  F28  1  0.202  0.082  0.048  1.0
  F  F29  1  0.798  0.582  0.452  1.0
  F  F30  1  0.798  0.918  0.952  1.0
  F  F31  1  0.202  0.418  0.548  1.0
  F  F32  1  0.413  0.419  0.346  1.0
  F  F33  1  0.587  0.919  0.154  1.0
  F  F34  1  0.587  0.581  0.654  1.0
  F  F35  1  0.413  0.081  0.846  1.0
  F  F36  1  0.600  0.081  0.657  1.0
  F  F37  1  0.400  0.581  0.843  1.0
  F  F38  1  0.400  0.919  0.343  1.0
  F  F39  1  0.600  0.419  0.157  1.0
  F  F40  1  0.015  0.074  0.246  1.0
  F  F41  1  0.985  0.574  0.254  1.0
  F  F42  1  0.985  0.926  0.754  1.0
  F  F43  1  0.015  0.426  0.746  1.0
  F  F44  1  0.290  0.323  0.954  1.0
  F  F45  1  0.710  0.823  0.546  1.0
  F  F46  1  0.710  0.677  0.046  1.0
  F  F47  1  0.290  0.177  0.454  1.0
[/CIF]
.
The crystal structure described by PtF5 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two PtF5 clusters. There are two inequivalent Pt sites. In the first Pt site, Pt(1) is bonded to one F(1), one F(10), one F(3), one F(4), one F(5), and one F(6) atom to form corner-sharing PtF6 octahedra. The corner-sharing octahedral tilt angles are 50°. In the second Pt site, Pt(2) is bonded to one F(1), one F(2), one F(6), one F(7), one F(8), and one F(9) atom to form corner-sharing PtF6 octahedra. The corner-sharing octahedral tilt angles are 50°. There are ten inequivalent F sites. In the first F site, F(7) is bonded in a single-bond geometry to one Pt(2) atom. In the second F site, F(8) is bonded in a single-bond geometry to one Pt(2) atom. In the third F site, F(1) is bonded in a bent 120 degrees geometry to one Pt(1) and one Pt(2) atom. In the fourth F site, F(9) is bonded in a single-bond geometry to one Pt(2) atom. In the fifth F site, F(2) is bonded in a single-bond geometry to one Pt(2) atom. In the sixth F site, F(10) is bonded in a single-bond geometry to one Pt(1) atom. In the seventh F site, F(3) is bonded in a single-bond geometry to one Pt(1) atom. In the eighth F site, F(4) is bonded in a single-bond geometry to one Pt(1) atom. In the ninth F site, F(5) is bonded in a single-bond geometry to one Pt(1) atom. In the tenth F site, F(6) is bonded in a bent 120 degrees geometry to one Pt(1) and one Pt(2) atom. is represented by the CIF file [CIF]
data_PtF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.357
_cell_length_b   9.745
_cell_length_c   12.189
_cell_angle_alpha   90.000
_cell_angle_beta   99.578
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   627.434
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pt  Pt0  1  0.999  0.252  0.000  1.0
  Pt  Pt1  1  0.001  0.752  0.500  1.0
  Pt  Pt2  1  0.001  0.748  1.000  1.0
  Pt  Pt3  1  0.999  0.248  0.500  1.0
  Pt  Pt4  1  0.306  1.000  0.202  1.0
  Pt  Pt5  1  0.694  0.500  0.298  1.0
  Pt  Pt6  1  0.694  0.000  0.798  1.0
  Pt  Pt7  1  0.306  0.500  0.702  1.0
  F  F8  1  0.106  0.830  0.155  1.0
  F  F9  1  0.894  0.330  0.345  1.0
  F  F10  1  0.894  0.170  0.845  1.0
  F  F11  1  0.106  0.670  0.655  1.0
  F  F12  1  0.492  0.156  0.248  1.0
  F  F13  1  0.508  0.656  0.252  1.0
  F  F14  1  0.508  0.844  0.752  1.0
  F  F15  1  0.492  0.344  0.748  1.0
  F  F16  1  0.810  0.406  0.953  1.0
  F  F17  1  0.190  0.906  0.548  1.0
  F  F18  1  0.190  0.594  0.048  1.0
  F  F19  1  0.810  0.094  0.453  1.0
  F  F20  1  0.099  0.329  0.142  1.0
  F  F21  1  0.902  0.829  0.358  1.0
  F  F22  1  0.902  0.671  0.858  1.0
  F  F23  1  0.099  0.171  0.642  1.0
  F  F24  1  0.721  0.335  0.546  1.0
  F  F25  1  0.279  0.835  0.954  1.0
  F  F26  1  0.279  0.665  0.454  1.0
  F  F27  1  0.721  0.165  0.046  1.0
  F  F28  1  0.202  0.082  0.048  1.0
  F  F29  1  0.798  0.582  0.452  1.0
  F  F30  1  0.798  0.918  0.952  1.0
  F  F31  1  0.202  0.418  0.548  1.0
  F  F32  1  0.413  0.419  0.346  1.0
  F  F33  1  0.587  0.919  0.154  1.0
  F  F34  1  0.587  0.581  0.654  1.0
  F  F35  1  0.413  0.081  0.846  1.0
  F  F36  1  0.600  0.081  0.657  1.0
  F  F37  1  0.400  0.581  0.843  1.0
  F  F38  1  0.400  0.919  0.343  1.0
  F  F39  1  0.600  0.419  0.157  1.0
  F  F40  1  0.015  0.074  0.246  1.0
  F  F41  1  0.985  0.574  0.254  1.0
  F  F42  1  0.985  0.926  0.754  1.0
  F  F43  1  0.015  0.426  0.746  1.0
  F  F44  1  0.290  0.323  0.954  1.0
  F  F45  1  0.710  0.823  0.546  1.0
  F  F46  1  0.710  0.677  0.046  1.0
  F  F47  1  0.290  0.177  0.454  1.0
[/CIF]
.