The compound described by Na2HTeSO5F3 crystallizes in the monoclinic P2_1/c space group. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded in a 7-coordinate geometry to one O(2), two equivalent O(4), two equivalent O(5), one F(2), and one F(3) atom. In the second Na site, Na(2) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(4), one F(1), one F(2), and one F(3) atom. H(1) is bonded in a distorted linear geometry to one O(1) and one O(3) atom. Te(1) is bonded to one O(1), one O(3), one F(1), one F(2), and one F(3) atom to form distorted TeO2F3 square pyramids that share  a cornercorner with one S(1)O4 tetrahedra. S(1) is bonded to one O(2), one O(3), one O(4), and one O(5) atom to form SO4 tetrahedra that share  a cornercorner with one Te(1)O2F3 square pyramid. There are five inequivalent O sites. In the first O site, O(4) is bonded in a 4-coordinate geometry to one Na(2), two equivalent Na(1), and one S(1) atom. In the second O site, O(5) is bonded in a 3-coordinate geometry to two equivalent Na(1) and one S(1) atom. In the third O site, O(1) is bonded in a 3-coordinate geometry to one Na(2), one H(1), and one Te(1) atom. In the fourth O site, O(2) is bonded in a 3-coordinate geometry to one Na(1), one Na(2), and one S(1) atom. In the fifth O site, O(3) is bonded in a distorted bent 120 degrees geometry to one H(1), one Te(1), and one S(1) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a bent 120 degrees geometry to one Na(2) and one Te(1) atom. In the second F site, F(2) is bonded in a 3-coordinate geometry to one Na(1), one Na(2), and one Te(1) atom. In the third F site, F(3) is bonded in a distorted T-shaped geometry to one Na(1), one Na(2), and one Te(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Na2TeHSO5F3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.572
_cell_length_b   8.376
_cell_length_c   10.909
_cell_angle_alpha   89.679
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   691.831
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.500  0.444  0.759  1.0
  Na  Na1  1  0.000  0.556  0.741  1.0
  Na  Na2  1  0.500  0.556  0.241  1.0
  Na  Na3  1  1.000  0.444  0.259  1.0
  Na  Na4  1  0.232  0.253  0.528  1.0
  Na  Na5  1  0.732  0.747  0.972  1.0
  Na  Na6  1  0.768  0.747  0.472  1.0
  Na  Na7  1  0.268  0.253  0.028  1.0
  Te  Te8  1  0.465  0.916  0.715  1.0
  Te  Te9  1  0.965  0.084  0.785  1.0
  Te  Te10  1  0.535  0.084  0.285  1.0
  Te  Te11  1  0.035  0.916  0.215  1.0
  H  H12  1  0.147  0.930  0.934  1.0
  H  H13  1  0.647  0.070  0.566  1.0
  H  H14  1  0.853  0.070  0.066  1.0
  H  H15  1  0.353  0.930  0.434  1.0
  S  S16  1  0.238  0.642  0.512  1.0
  S  S17  1  0.738  0.358  0.988  1.0
  S  S18  1  0.762  0.358  0.488  1.0
  S  S19  1  0.262  0.642  0.012  1.0
  O  O20  1  0.160  0.040  0.893  1.0
  O  O21  1  0.660  0.960  0.607  1.0
  O  O22  1  0.840  0.960  0.107  1.0
  O  O23  1  0.340  0.040  0.393  1.0
  O  O24  1  0.056  0.693  0.542  1.0
  O  O25  1  0.556  0.307  0.958  1.0
  O  O26  1  0.944  0.307  0.458  1.0
  O  O27  1  0.444  0.693  0.042  1.0
  O  O28  1  0.365  0.785  0.529  1.0
  O  O29  1  0.865  0.215  0.971  1.0
  O  O30  1  0.635  0.215  0.471  1.0
  O  O31  1  0.135  0.785  0.029  1.0
  O  O32  1  0.295  0.514  0.598  1.0
  O  O33  1  0.795  0.486  0.902  1.0
  O  O34  1  0.705  0.486  0.402  1.0
  O  O35  1  0.205  0.514  0.098  1.0
  O  O36  1  0.247  0.593  0.883  1.0
  O  O37  1  0.747  0.407  0.617  1.0
  O  O38  1  0.753  0.407  0.117  1.0
  O  O39  1  0.253  0.593  0.383  1.0
  F  F40  1  0.102  0.027  0.639  1.0
  F  F41  1  0.602  0.973  0.861  1.0
  F  F42  1  0.898  0.973  0.361  1.0
  F  F43  1  0.398  0.027  0.139  1.0
  F  F44  1  0.095  0.290  0.764  1.0
  F  F45  1  0.595  0.710  0.736  1.0
  F  F46  1  0.905  0.710  0.236  1.0
  F  F47  1  0.405  0.290  0.264  1.0
  F  F48  1  0.428  0.157  0.695  1.0
  F  F49  1  0.928  0.843  0.805  1.0
  F  F50  1  0.572  0.843  0.305  1.0
  F  F51  1  0.072  0.157  0.195  1.0
[/CIF]
.
The compound described by Na2HTeSO5F3 crystallizes in the monoclinic P2_1/c space group. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded in a 7-coordinate geometry to one O(2), two equivalent O(4), two equivalent O(5), one F(2), and one F(3) atom. In the second Na site, Na(2) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(4), one F(1), one F(2), and one F(3) atom. H(1) is bonded in a distorted linear geometry to one O(1) and one O(3) atom. Te(1) is bonded to one O(1), one O(3), one F(1), one F(2), and one F(3) atom to form distorted TeO2F3 square pyramids that share  a cornercorner with one S(1)O4 tetrahedra. S(1) is bonded to one O(2), one O(3), one O(4), and one O(5) atom to form SO4 tetrahedra that share  a cornercorner with one Te(1)O2F3 square pyramid. There are five inequivalent O sites. In the first O site, O(4) is bonded in a 4-coordinate geometry to one Na(2), two equivalent Na(1), and one S(1) atom. In the second O site, O(5) is bonded in a 3-coordinate geometry to two equivalent Na(1) and one S(1) atom. In the third O site, O(1) is bonded in a 3-coordinate geometry to one Na(2), one H(1), and one Te(1) atom. In the fourth O site, O(2) is bonded in a 3-coordinate geometry to one Na(1), one Na(2), and one S(1) atom. In the fifth O site, O(3) is bonded in a distorted bent 120 degrees geometry to one H(1), one Te(1), and one S(1) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a bent 120 degrees geometry to one Na(2) and one Te(1) atom. In the second F site, F(2) is bonded in a 3-coordinate geometry to one Na(1), one Na(2), and one Te(1) atom. In the third F site, F(3) is bonded in a distorted T-shaped geometry to one Na(1), one Na(2), and one Te(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Na2TeHSO5F3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.572
_cell_length_b   8.376
_cell_length_c   10.909
_cell_angle_alpha   89.679
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   691.831
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.500  0.444  0.759  1.0
  Na  Na1  1  0.000  0.556  0.741  1.0
  Na  Na2  1  0.500  0.556  0.241  1.0
  Na  Na3  1  1.000  0.444  0.259  1.0
  Na  Na4  1  0.232  0.253  0.528  1.0
  Na  Na5  1  0.732  0.747  0.972  1.0
  Na  Na6  1  0.768  0.747  0.472  1.0
  Na  Na7  1  0.268  0.253  0.028  1.0
  Te  Te8  1  0.465  0.916  0.715  1.0
  Te  Te9  1  0.965  0.084  0.785  1.0
  Te  Te10  1  0.535  0.084  0.285  1.0
  Te  Te11  1  0.035  0.916  0.215  1.0
  H  H12  1  0.147  0.930  0.934  1.0
  H  H13  1  0.647  0.070  0.566  1.0
  H  H14  1  0.853  0.070  0.066  1.0
  H  H15  1  0.353  0.930  0.434  1.0
  S  S16  1  0.238  0.642  0.512  1.0
  S  S17  1  0.738  0.358  0.988  1.0
  S  S18  1  0.762  0.358  0.488  1.0
  S  S19  1  0.262  0.642  0.012  1.0
  O  O20  1  0.160  0.040  0.893  1.0
  O  O21  1  0.660  0.960  0.607  1.0
  O  O22  1  0.840  0.960  0.107  1.0
  O  O23  1  0.340  0.040  0.393  1.0
  O  O24  1  0.056  0.693  0.542  1.0
  O  O25  1  0.556  0.307  0.958  1.0
  O  O26  1  0.944  0.307  0.458  1.0
  O  O27  1  0.444  0.693  0.042  1.0
  O  O28  1  0.365  0.785  0.529  1.0
  O  O29  1  0.865  0.215  0.971  1.0
  O  O30  1  0.635  0.215  0.471  1.0
  O  O31  1  0.135  0.785  0.029  1.0
  O  O32  1  0.295  0.514  0.598  1.0
  O  O33  1  0.795  0.486  0.902  1.0
  O  O34  1  0.705  0.486  0.402  1.0
  O  O35  1  0.205  0.514  0.098  1.0
  O  O36  1  0.247  0.593  0.883  1.0
  O  O37  1  0.747  0.407  0.617  1.0
  O  O38  1  0.753  0.407  0.117  1.0
  O  O39  1  0.253  0.593  0.383  1.0
  F  F40  1  0.102  0.027  0.639  1.0
  F  F41  1  0.602  0.973  0.861  1.0
  F  F42  1  0.898  0.973  0.361  1.0
  F  F43  1  0.398  0.027  0.139  1.0
  F  F44  1  0.095  0.290  0.764  1.0
  F  F45  1  0.595  0.710  0.736  1.0
  F  F46  1  0.905  0.710  0.236  1.0
  F  F47  1  0.405  0.290  0.264  1.0
  F  F48  1  0.428  0.157  0.695  1.0
  F  F49  1  0.928  0.843  0.805  1.0
  F  F50  1  0.572  0.843  0.305  1.0
  F  F51  1  0.072  0.157  0.195  1.0
[/CIF]
.