The material described by KSbS2 crystallizes in the monoclinic C2/c space group. K(1) is bonded to six equivalent S(1) atoms to form a mixture of distorted corner and edge-sharing KS6 octahedra. The corner-sharing octahedral tilt angles are 17°. Sb(1) is bonded in a see-saw-like geometry to four equivalent S(1) atoms. S(1) is bonded to three equivalent K(1) and two equivalent Sb(1) atoms to form a mixture of corner and edge-sharing SK3Sb2 square pyramids. is represented by the CIF card [CIF]
data_KSbS2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.389
_cell_length_b   6.389
_cell_length_c   6.911
_cell_angle_alpha   111.589
_cell_angle_beta   111.589
_cell_angle_gamma   92.159
_symmetry_Int_Tables_number   1
_cell_volume   238.986
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.857  0.143  0.750  1.0
  K  K1  1  0.143  0.857  0.250  1.0
  Sb  Sb2  1  0.591  0.409  0.250  1.0
  Sb  Sb3  1  0.409  0.591  0.750  1.0
  S  S4  1  0.223  0.371  0.278  1.0
  S  S5  1  0.629  0.777  0.222  1.0
  S  S6  1  0.371  0.223  0.778  1.0
  S  S7  1  0.777  0.629  0.722  1.0
[/CIF]
.
The material described by KSbS2 crystallizes in the monoclinic C2/c space group. K(1) is bonded to six equivalent S(1) atoms to form a mixture of distorted corner and edge-sharing KS6 octahedra. The corner-sharing octahedral tilt angles are 17°. Sb(1) is bonded in a see-saw-like geometry to four equivalent S(1) atoms. S(1) is bonded to three equivalent K(1) and two equivalent Sb(1) atoms to form a mixture of corner and edge-sharing SK3Sb2 square pyramids. is represented by the CIF card [CIF]
data_KSbS2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.389
_cell_length_b   6.389
_cell_length_c   6.911
_cell_angle_alpha   111.589
_cell_angle_beta   111.589
_cell_angle_gamma   92.159
_symmetry_Int_Tables_number   1
_cell_volume   238.986
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.857  0.143  0.750  1.0
  K  K1  1  0.143  0.857  0.250  1.0
  Sb  Sb2  1  0.591  0.409  0.250  1.0
  Sb  Sb3  1  0.409  0.591  0.750  1.0
  S  S4  1  0.223  0.371  0.278  1.0
  S  S5  1  0.629  0.777  0.222  1.0
  S  S6  1  0.371  0.223  0.778  1.0
  S  S7  1  0.777  0.629  0.722  1.0
[/CIF]
.