The structure described by (GaF3)24O2 crystallizes in the orthorhombic Imm2 space group. The structure consists of two water atoms inside a GaF3 framework. In the GaF3 framework, there are four inequivalent Ga sites. In the first Ga site, Ga(1) is bonded to one F(1), one F(3), two equivalent F(4), and two equivalent F(6) atoms to form corner-sharing GaF6 octahedra. The corner-sharing octahedral tilt angles range from 26-36°. In the second Ga site, Ga(2) is bonded to one F(2), one F(3), two equivalent F(5), and two equivalent F(7) atoms to form corner-sharing GaF6 octahedra. The corner-sharing octahedral tilt angles range from 27-36°. In the third Ga site, Ga(3) is bonded to one F(10), one F(12), one F(14), one F(5), one F(6), and one F(8) atom to form corner-sharing GaF6 octahedra. The corner-sharing octahedral tilt angles range from 26-36°. In the fourth Ga site, Ga(4) is bonded to one F(10), one F(11), one F(13), one F(4), one F(7), and one F(9) atom to form corner-sharing GaF6 octahedra. The corner-sharing octahedral tilt angles range from 26-36°. There are fourteen inequivalent F sites. In the first F site, F(6) is bonded in a bent 150 degrees geometry to one Ga(1) and one Ga(3) atom. In the second F site, F(7) is bonded in a bent 150 degrees geometry to one Ga(2) and one Ga(4) atom. In the third F site, F(8) is bonded in a bent 150 degrees geometry to two equivalent Ga(3) atoms. In the fourth F site, F(9) is bonded in a bent 150 degrees geometry to two equivalent Ga(4) atoms. In the fifth F site, F(10) is bonded in a bent 150 degrees geometry to one Ga(3) and one Ga(4) atom. In the sixth F site, F(11) is bonded in a bent 150 degrees geometry to two equivalent Ga(4) atoms. In the seventh F site, F(12) is bonded in a bent 150 degrees geometry to two equivalent Ga(3) atoms. In the eighth F site, F(13) is bonded in a bent 150 degrees geometry to two equivalent Ga(4) atoms. In the ninth F site, F(14) is bonded in a bent 150 degrees geometry to two equivalent Ga(3) atoms. In the tenth F site, F(1) is bonded in a bent 150 degrees geometry to two equivalent Ga(1) atoms. In the eleventh F site, F(2) is bonded in a bent 150 degrees geometry to two equivalent Ga(2) atoms. In the twelfth F site, F(3) is bonded in a bent 150 degrees geometry to one Ga(1) and one Ga(2) atom. In the thirteenth F site, F(4) is bonded in a bent 150 degrees geometry to one Ga(1) and one Ga(4) atom. In the fourteenth F site, F(5) is bonded in a bent 150 degrees geometry to one Ga(2) and one Ga(3) atom. is represented by the CIF file [CIF]
data_Ga12OF36
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.460
_cell_length_b   10.460
_cell_length_c   10.460
_cell_angle_alpha   138.978
_cell_angle_beta   105.790
_cell_angle_gamma   88.477
_symmetry_Int_Tables_number   1
_cell_volume   693.348
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.125  0.625  0.500  1.0
  Ga  Ga1  1  0.625  0.125  0.500  1.0
  Ga  Ga2  1  0.375  0.875  0.500  1.0
  Ga  Ga3  1  0.875  0.375  0.500  1.0
  Ga  Ga4  1  0.375  0.375  0.500  1.0
  Ga  Ga5  1  0.875  0.875  0.500  1.0
  Ga  Ga6  1  0.375  0.875  0.000  1.0
  Ga  Ga7  1  0.875  0.376  0.000  1.0
  Ga  Ga8  1  0.125  0.125  0.500  1.0
  Ga  Ga9  1  0.624  0.624  0.500  1.0
  Ga  Ga10  1  0.125  0.625  0.000  1.0
  Ga  Ga11  1  0.624  0.125  0.000  1.0
  O  O12  1  0.946  0.000  0.946  1.0
  F  F13  1  0.965  0.500  0.465  1.0
  F  F14  1  0.465  0.000  0.465  1.0
  F  F15  1  0.285  0.750  0.535  1.0
  F  F16  1  0.785  0.250  0.535  1.0
  F  F17  1  0.040  0.830  0.580  1.0
  F  F18  1  0.540  0.330  0.581  1.0
  F  F19  1  0.210  0.790  0.790  1.0
  F  F20  1  0.710  0.290  0.790  1.0
  F  F21  1  0.251  0.040  0.581  1.0
  F  F22  1  0.750  0.540  0.580  1.0
  F  F23  1  1.000  0.580  0.790  1.0
  F  F24  1  0.500  0.080  0.790  1.0
  F  F25  1  0.210  0.420  0.420  1.0
  F  F26  1  0.710  0.920  0.419  1.0
  F  F27  1  0.040  0.460  0.210  1.0
  F  F28  1  0.540  0.960  0.210  1.0
  F  F29  1  1.000  0.210  0.420  1.0
  F  F30  1  0.500  0.710  0.419  1.0
  F  F31  1  0.251  0.670  0.210  1.0
  F  F32  1  0.750  0.170  0.210  1.0
  F  F33  1  0.279  0.282  0.561  1.0
  F  F34  1  0.778  0.781  0.560  1.0
  F  F35  1  0.971  0.533  0.003  1.0
  F  F36  1  0.470  0.032  0.003  1.0
  F  F37  1  0.971  0.968  0.438  1.0
  F  F38  1  0.470  0.467  0.438  1.0
  F  F39  1  0.279  0.718  0.997  1.0
  F  F40  1  0.778  0.219  0.997  1.0
  F  F41  1  0.640  0.853  0.787  1.0
  F  F42  1  0.143  0.354  0.789  1.0
  F  F43  1  0.607  0.396  0.212  1.0
  F  F44  1  0.108  0.896  0.211  1.0
  F  F45  1  0.435  0.646  0.789  1.0
  F  F46  1  0.934  0.147  0.787  1.0
  F  F47  1  0.816  0.604  0.212  1.0
  F  F48  1  0.315  0.104  0.211  1.0
[/CIF]
.
The structure described by (GaF3)24O2 crystallizes in the orthorhombic Imm2 space group. The structure consists of two water atoms inside a GaF3 framework. In the GaF3 framework, there are four inequivalent Ga sites. In the first Ga site, Ga(1) is bonded to one F(1), one F(3), two equivalent F(4), and two equivalent F(6) atoms to form corner-sharing GaF6 octahedra. The corner-sharing octahedral tilt angles range from 26-36°. In the second Ga site, Ga(2) is bonded to one F(2), one F(3), two equivalent F(5), and two equivalent F(7) atoms to form corner-sharing GaF6 octahedra. The corner-sharing octahedral tilt angles range from 27-36°. In the third Ga site, Ga(3) is bonded to one F(10), one F(12), one F(14), one F(5), one F(6), and one F(8) atom to form corner-sharing GaF6 octahedra. The corner-sharing octahedral tilt angles range from 26-36°. In the fourth Ga site, Ga(4) is bonded to one F(10), one F(11), one F(13), one F(4), one F(7), and one F(9) atom to form corner-sharing GaF6 octahedra. The corner-sharing octahedral tilt angles range from 26-36°. There are fourteen inequivalent F sites. In the first F site, F(6) is bonded in a bent 150 degrees geometry to one Ga(1) and one Ga(3) atom. In the second F site, F(7) is bonded in a bent 150 degrees geometry to one Ga(2) and one Ga(4) atom. In the third F site, F(8) is bonded in a bent 150 degrees geometry to two equivalent Ga(3) atoms. In the fourth F site, F(9) is bonded in a bent 150 degrees geometry to two equivalent Ga(4) atoms. In the fifth F site, F(10) is bonded in a bent 150 degrees geometry to one Ga(3) and one Ga(4) atom. In the sixth F site, F(11) is bonded in a bent 150 degrees geometry to two equivalent Ga(4) atoms. In the seventh F site, F(12) is bonded in a bent 150 degrees geometry to two equivalent Ga(3) atoms. In the eighth F site, F(13) is bonded in a bent 150 degrees geometry to two equivalent Ga(4) atoms. In the ninth F site, F(14) is bonded in a bent 150 degrees geometry to two equivalent Ga(3) atoms. In the tenth F site, F(1) is bonded in a bent 150 degrees geometry to two equivalent Ga(1) atoms. In the eleventh F site, F(2) is bonded in a bent 150 degrees geometry to two equivalent Ga(2) atoms. In the twelfth F site, F(3) is bonded in a bent 150 degrees geometry to one Ga(1) and one Ga(2) atom. In the thirteenth F site, F(4) is bonded in a bent 150 degrees geometry to one Ga(1) and one Ga(4) atom. In the fourteenth F site, F(5) is bonded in a bent 150 degrees geometry to one Ga(2) and one Ga(3) atom. is represented by the CIF file [CIF]
data_Ga12OF36
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.460
_cell_length_b   10.460
_cell_length_c   10.460
_cell_angle_alpha   138.978
_cell_angle_beta   105.790
_cell_angle_gamma   88.477
_symmetry_Int_Tables_number   1
_cell_volume   693.348
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.125  0.625  0.500  1.0
  Ga  Ga1  1  0.625  0.125  0.500  1.0
  Ga  Ga2  1  0.375  0.875  0.500  1.0
  Ga  Ga3  1  0.875  0.375  0.500  1.0
  Ga  Ga4  1  0.375  0.375  0.500  1.0
  Ga  Ga5  1  0.875  0.875  0.500  1.0
  Ga  Ga6  1  0.375  0.875  0.000  1.0
  Ga  Ga7  1  0.875  0.376  0.000  1.0
  Ga  Ga8  1  0.125  0.125  0.500  1.0
  Ga  Ga9  1  0.624  0.624  0.500  1.0
  Ga  Ga10  1  0.125  0.625  0.000  1.0
  Ga  Ga11  1  0.624  0.125  0.000  1.0
  O  O12  1  0.946  0.000  0.946  1.0
  F  F13  1  0.965  0.500  0.465  1.0
  F  F14  1  0.465  0.000  0.465  1.0
  F  F15  1  0.285  0.750  0.535  1.0
  F  F16  1  0.785  0.250  0.535  1.0
  F  F17  1  0.040  0.830  0.580  1.0
  F  F18  1  0.540  0.330  0.581  1.0
  F  F19  1  0.210  0.790  0.790  1.0
  F  F20  1  0.710  0.290  0.790  1.0
  F  F21  1  0.251  0.040  0.581  1.0
  F  F22  1  0.750  0.540  0.580  1.0
  F  F23  1  1.000  0.580  0.790  1.0
  F  F24  1  0.500  0.080  0.790  1.0
  F  F25  1  0.210  0.420  0.420  1.0
  F  F26  1  0.710  0.920  0.419  1.0
  F  F27  1  0.040  0.460  0.210  1.0
  F  F28  1  0.540  0.960  0.210  1.0
  F  F29  1  1.000  0.210  0.420  1.0
  F  F30  1  0.500  0.710  0.419  1.0
  F  F31  1  0.251  0.670  0.210  1.0
  F  F32  1  0.750  0.170  0.210  1.0
  F  F33  1  0.279  0.282  0.561  1.0
  F  F34  1  0.778  0.781  0.560  1.0
  F  F35  1  0.971  0.533  0.003  1.0
  F  F36  1  0.470  0.032  0.003  1.0
  F  F37  1  0.971  0.968  0.438  1.0
  F  F38  1  0.470  0.467  0.438  1.0
  F  F39  1  0.279  0.718  0.997  1.0
  F  F40  1  0.778  0.219  0.997  1.0
  F  F41  1  0.640  0.853  0.787  1.0
  F  F42  1  0.143  0.354  0.789  1.0
  F  F43  1  0.607  0.396  0.212  1.0
  F  F44  1  0.108  0.896  0.211  1.0
  F  F45  1  0.435  0.646  0.789  1.0
  F  F46  1  0.934  0.147  0.787  1.0
  F  F47  1  0.816  0.604  0.212  1.0
  F  F48  1  0.315  0.104  0.211  1.0
[/CIF]
.