The crystal structure described by MnCdO2 is Caswellsilverite structured and crystallizes in the monoclinic P2/c space group. Mn(1) is bonded to six equivalent O(1) atoms to form MnO6 octahedra that share corners with six equivalent Cd(1)O6 octahedra, edges with six equivalent Mn(1)O6 octahedra, and edges with six equivalent Cd(1)O6 octahedra. The corner-sharing octahedral tilt angles are 5°. Cd(1) is bonded to six equivalent O(1) atoms to form CdO6 octahedra that share corners with six equivalent Mn(1)O6 octahedra, edges with six equivalent Mn(1)O6 octahedra, and edges with six equivalent Cd(1)O6 octahedra. The corner-sharing octahedral tilt angles are 5°. O(1) is bonded to three equivalent Mn(1) and three equivalent Cd(1) atoms to form a mixture of edge and corner-sharing OMn3Cd3 octahedra. The corner-sharing octahedra are not tilted. is represented by the CIF file [CIF]
data_MnCdO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.229
_cell_length_b   3.232
_cell_length_c   5.628
_cell_angle_alpha   73.371
_cell_angle_beta   73.330
_cell_angle_gamma   60.031
_symmetry_Int_Tables_number   1
_cell_volume   48.015
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.000  0.000  0.000  1.0
  Mn  Mn1  1  0.500  0.500  0.500  1.0
  O  O2  1  0.242  0.243  0.273  1.0
  O  O3  1  0.758  0.757  0.727  1.0
[/CIF]
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The crystal structure described by MnCdO2 is Caswellsilverite structured and crystallizes in the monoclinic P2/c space group. Mn(1) is bonded to six equivalent O(1) atoms to form MnO6 octahedra that share corners with six equivalent Cd(1)O6 octahedra, edges with six equivalent Mn(1)O6 octahedra, and edges with six equivalent Cd(1)O6 octahedra. The corner-sharing octahedral tilt angles are 5°. Cd(1) is bonded to six equivalent O(1) atoms to form CdO6 octahedra that share corners with six equivalent Mn(1)O6 octahedra, edges with six equivalent Mn(1)O6 octahedra, and edges with six equivalent Cd(1)O6 octahedra. The corner-sharing octahedral tilt angles are 5°. O(1) is bonded to three equivalent Mn(1) and three equivalent Cd(1) atoms to form a mixture of edge and corner-sharing OMn3Cd3 octahedra. The corner-sharing octahedra are not tilted. is represented by the CIF file [CIF]
data_MnCdO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.229
_cell_length_b   3.232
_cell_length_c   5.628
_cell_angle_alpha   73.371
_cell_angle_beta   73.330
_cell_angle_gamma   60.031
_symmetry_Int_Tables_number   1
_cell_volume   48.015
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.000  0.000  0.000  1.0
  Mn  Mn1  1  0.500  0.500  0.500  1.0
  O  O2  1  0.242  0.243  0.273  1.0
  O  O3  1  0.758  0.757  0.727  1.0
[/CIF]
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