The material structure described by DyV2(FeCo)5 crystallizes in the orthorhombic Imm2 space group. Dy(1) is bonded in a 20-coordinate geometry to one V(1), one V(2), two equivalent Fe(2), eight equivalent Fe(1), two equivalent Co(2), two equivalent Co(3), and four equivalent Co(1) atoms. There are two inequivalent V sites. In the first V site, V(1) is bonded in a 14-coordinate geometry to one Dy(1), one V(2), two equivalent Fe(2), four equivalent Fe(1), two equivalent Co(1), and four equivalent Co(3) atoms. In the second V site, V(2) is bonded in a 14-coordinate geometry to one Dy(1), one V(1), four equivalent Fe(1), two equivalent Co(1), two equivalent Co(2), and four equivalent Co(3) atoms. There are two inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to two equivalent Dy(1), one V(1), one V(2), one Fe(2), two equivalent Fe(1), one Co(2), two equivalent Co(1), and two equivalent Co(3) atoms to form distorted FeDy2V2Fe3Co5 cuboctahedra that share corners with two equivalent Fe(2)Dy2V2Fe4Co4 cuboctahedra, corners with ten equivalent Fe(1)Dy2V2Fe3Co5 cuboctahedra,  an edgeedge with one Fe(2)Dy2V2Fe4Co4 cuboctahedra, edges with four equivalent Fe(1)Dy2V2Fe3Co5 cuboctahedra, faces with two equivalent Fe(2)Dy2V2Fe4Co4 cuboctahedra, and faces with six equivalent Fe(1)Dy2V2Fe3Co5 cuboctahedra. In the second Fe site, Fe(2) is bonded to two equivalent Dy(1), two equivalent V(1), four equivalent Fe(1), two equivalent Co(1), and two equivalent Co(3) atoms to form distorted FeDy2V2Fe4Co4 cuboctahedra that share corners with eight equivalent Fe(1)Dy2V2Fe3Co5 cuboctahedra, edges with two equivalent Fe(2)Dy2V2Fe4Co4 cuboctahedra, edges with four equivalent Fe(1)Dy2V2Fe3Co5 cuboctahedra, and faces with eight equivalent Fe(1)Dy2V2Fe3Co5 cuboctahedra. There are three inequivalent Co sites. In the first Co site, Co(1) is bonded in a 12-coordinate geometry to two equivalent Dy(1), one V(1), one V(2), one Fe(2), four equivalent Fe(1), one Co(2), and two equivalent Co(3) atoms. In the second Co site, Co(2) is bonded in a 12-coordinate geometry to two equivalent Dy(1), two equivalent V(2), four equivalent Fe(1), two equivalent Co(1), and two equivalent Co(3) atoms. In the third Co site, Co(3) is bonded in a 14-coordinate geometry to one Dy(1), two equivalent V(1), two equivalent V(2), one Fe(2), four equivalent Fe(1), one Co(2), one Co(3), and two equivalent Co(1) atoms. is represented by the CIF card [CIF]
data_DyV2(FeCo)5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.654
_cell_length_b   6.365
_cell_length_c   6.365
_cell_angle_alpha   97.415
_cell_angle_beta   111.443
_cell_angle_gamma   68.557
_symmetry_Int_Tables_number   1
_cell_volume   163.371
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Dy  Dy0  1  0.000  0.999  0.999  1.0
  V  V1  1  0.000  0.359  0.359  1.0
  V  V2  1  0.000  0.642  0.642  1.0
  Fe  Fe3  1  0.501  0.999  0.501  1.0
  Fe  Fe4  1  0.002  0.999  0.501  1.0
  Fe  Fe5  1  0.499  0.501  0.999  1.0
  Fe  Fe6  1  0.998  0.501  0.999  1.0
  Fe  Fe7  1  0.500  0.225  0.225  1.0
  Co  Co8  1  0.725  0.776  0.226  1.0
  Co  Co9  1  0.275  0.226  0.776  1.0
  Co  Co10  1  0.500  0.776  0.776  1.0
  Co  Co11  1  0.641  0.358  0.640  1.0
  Co  Co12  1  0.359  0.640  0.358  1.0
[/CIF]
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The material structure described by DyV2(FeCo)5 crystallizes in the orthorhombic Imm2 space group. Dy(1) is bonded in a 20-coordinate geometry to one V(1), one V(2), two equivalent Fe(2), eight equivalent Fe(1), two equivalent Co(2), two equivalent Co(3), and four equivalent Co(1) atoms. There are two inequivalent V sites. In the first V site, V(1) is bonded in a 14-coordinate geometry to one Dy(1), one V(2), two equivalent Fe(2), four equivalent Fe(1), two equivalent Co(1), and four equivalent Co(3) atoms. In the second V site, V(2) is bonded in a 14-coordinate geometry to one Dy(1), one V(1), four equivalent Fe(1), two equivalent Co(1), two equivalent Co(2), and four equivalent Co(3) atoms. There are two inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to two equivalent Dy(1), one V(1), one V(2), one Fe(2), two equivalent Fe(1), one Co(2), two equivalent Co(1), and two equivalent Co(3) atoms to form distorted FeDy2V2Fe3Co5 cuboctahedra that share corners with two equivalent Fe(2)Dy2V2Fe4Co4 cuboctahedra, corners with ten equivalent Fe(1)Dy2V2Fe3Co5 cuboctahedra,  an edgeedge with one Fe(2)Dy2V2Fe4Co4 cuboctahedra, edges with four equivalent Fe(1)Dy2V2Fe3Co5 cuboctahedra, faces with two equivalent Fe(2)Dy2V2Fe4Co4 cuboctahedra, and faces with six equivalent Fe(1)Dy2V2Fe3Co5 cuboctahedra. In the second Fe site, Fe(2) is bonded to two equivalent Dy(1), two equivalent V(1), four equivalent Fe(1), two equivalent Co(1), and two equivalent Co(3) atoms to form distorted FeDy2V2Fe4Co4 cuboctahedra that share corners with eight equivalent Fe(1)Dy2V2Fe3Co5 cuboctahedra, edges with two equivalent Fe(2)Dy2V2Fe4Co4 cuboctahedra, edges with four equivalent Fe(1)Dy2V2Fe3Co5 cuboctahedra, and faces with eight equivalent Fe(1)Dy2V2Fe3Co5 cuboctahedra. There are three inequivalent Co sites. In the first Co site, Co(1) is bonded in a 12-coordinate geometry to two equivalent Dy(1), one V(1), one V(2), one Fe(2), four equivalent Fe(1), one Co(2), and two equivalent Co(3) atoms. In the second Co site, Co(2) is bonded in a 12-coordinate geometry to two equivalent Dy(1), two equivalent V(2), four equivalent Fe(1), two equivalent Co(1), and two equivalent Co(3) atoms. In the third Co site, Co(3) is bonded in a 14-coordinate geometry to one Dy(1), two equivalent V(1), two equivalent V(2), one Fe(2), four equivalent Fe(1), one Co(2), one Co(3), and two equivalent Co(1) atoms. is represented by the CIF card [CIF]
data_DyV2(FeCo)5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.654
_cell_length_b   6.365
_cell_length_c   6.365
_cell_angle_alpha   97.415
_cell_angle_beta   111.443
_cell_angle_gamma   68.557
_symmetry_Int_Tables_number   1
_cell_volume   163.371
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Dy  Dy0  1  0.000  0.999  0.999  1.0
  V  V1  1  0.000  0.359  0.359  1.0
  V  V2  1  0.000  0.642  0.642  1.0
  Fe  Fe3  1  0.501  0.999  0.501  1.0
  Fe  Fe4  1  0.002  0.999  0.501  1.0
  Fe  Fe5  1  0.499  0.501  0.999  1.0
  Fe  Fe6  1  0.998  0.501  0.999  1.0
  Fe  Fe7  1  0.500  0.225  0.225  1.0
  Co  Co8  1  0.725  0.776  0.226  1.0
  Co  Co9  1  0.275  0.226  0.776  1.0
  Co  Co10  1  0.500  0.776  0.776  1.0
  Co  Co11  1  0.641  0.358  0.640  1.0
  Co  Co12  1  0.359  0.640  0.358  1.0
[/CIF]
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