The structure described by MnAgN crystallizes in the monoclinic C2/m space group. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one Ag(2), one N(1), and three equivalent N(2) atoms to form distorted MnAgN4 tetrahedra that share corners with two equivalent Mn(1)AgN4 tetrahedra, corners with two equivalent N(2)Mn4Ag2 trigonal pyramids, and edges with two equivalent Mn(1)AgN4 tetrahedra. In the second Mn site, Mn(2) is bonded in a distorted T-shaped geometry to two equivalent Ag(2), one N(2), and two equivalent N(1) atoms. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a single-bond geometry to five equivalent Ag(2) and one N(1) atom. In the second Ag site, Ag(2) is bonded in a 13-coordinate geometry to one Mn(1), two equivalent Mn(2), three equivalent Ag(2), five equivalent Ag(1), and two equivalent N(2) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted rectangular see-saw-like geometry to one Mn(1), two equivalent Mn(2), and one Ag(1) atom. In the second N site, N(2) is bonded to one Mn(2), three equivalent Mn(1), and two equivalent Ag(2) atoms to form distorted NMn4Ag2 trigonal pyramids that share corners with two equivalent Mn(1)AgN4 tetrahedra and edges with four equivalent N(2)Mn4Ag2 trigonal pyramids. is represented by the CIF file [CIF]
data_MnAgN
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.253
_cell_length_b   3.350
_cell_length_c   8.677
_cell_angle_alpha   90.000
_cell_angle_beta   101.287
_cell_angle_gamma   74.459
_symmetry_Int_Tables_number   1
_cell_volume   171.476
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.533  0.733  0.900  1.0
  Mn  Mn1  1  0.467  0.267  0.100  1.0
  Mn  Mn2  1  0.117  0.442  0.898  1.0
  Mn  Mn3  1  0.883  0.558  0.102  1.0
  Ag  Ag4  1  0.685  0.658  0.593  1.0
  Ag  Ag5  1  0.315  0.342  0.407  1.0
  Ag  Ag6  1  0.154  0.923  0.639  1.0
  Ag  Ag7  1  0.846  0.077  0.361  1.0
  N  N8  1  0.811  0.595  0.873  1.0
  N  N9  1  0.189  0.405  0.127  1.0
  N  N10  1  0.415  0.293  0.867  1.0
  N  N11  1  0.585  0.707  0.133  1.0
[/CIF]
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The structure described by MnAgN crystallizes in the monoclinic C2/m space group. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one Ag(2), one N(1), and three equivalent N(2) atoms to form distorted MnAgN4 tetrahedra that share corners with two equivalent Mn(1)AgN4 tetrahedra, corners with two equivalent N(2)Mn4Ag2 trigonal pyramids, and edges with two equivalent Mn(1)AgN4 tetrahedra. In the second Mn site, Mn(2) is bonded in a distorted T-shaped geometry to two equivalent Ag(2), one N(2), and two equivalent N(1) atoms. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a single-bond geometry to five equivalent Ag(2) and one N(1) atom. In the second Ag site, Ag(2) is bonded in a 13-coordinate geometry to one Mn(1), two equivalent Mn(2), three equivalent Ag(2), five equivalent Ag(1), and two equivalent N(2) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted rectangular see-saw-like geometry to one Mn(1), two equivalent Mn(2), and one Ag(1) atom. In the second N site, N(2) is bonded to one Mn(2), three equivalent Mn(1), and two equivalent Ag(2) atoms to form distorted NMn4Ag2 trigonal pyramids that share corners with two equivalent Mn(1)AgN4 tetrahedra and edges with four equivalent N(2)Mn4Ag2 trigonal pyramids. is represented by the CIF file [CIF]
data_MnAgN
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.253
_cell_length_b   3.350
_cell_length_c   8.677
_cell_angle_alpha   90.000
_cell_angle_beta   101.287
_cell_angle_gamma   74.459
_symmetry_Int_Tables_number   1
_cell_volume   171.476
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.533  0.733  0.900  1.0
  Mn  Mn1  1  0.467  0.267  0.100  1.0
  Mn  Mn2  1  0.117  0.442  0.898  1.0
  Mn  Mn3  1  0.883  0.558  0.102  1.0
  Ag  Ag4  1  0.685  0.658  0.593  1.0
  Ag  Ag5  1  0.315  0.342  0.407  1.0
  Ag  Ag6  1  0.154  0.923  0.639  1.0
  Ag  Ag7  1  0.846  0.077  0.361  1.0
  N  N8  1  0.811  0.595  0.873  1.0
  N  N9  1  0.189  0.405  0.127  1.0
  N  N10  1  0.415  0.293  0.867  1.0
  N  N11  1  0.585  0.707  0.133  1.0
[/CIF]
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