The structure described by KSnCPO7 crystallizes in the monoclinic P2_1 space group. K(1) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(3), and one O(5) atom. Sn(1) is bonded to one O(2), one O(3), one O(4), one O(5), one O(6), and one O(7) atom to form SnO6 octahedra that share corners with four equivalent P(1)O4 tetrahedra. C(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. P(1) is bonded to one O(4), one O(5), one O(6), and one O(7) atom to form PO4 tetrahedra that share corners with four equivalent Sn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 37-45°. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one K(1) and one C(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one K(1), one Sn(1), and one C(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one K(1), one Sn(1), and one C(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Sn(1) and one P(1) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one K(1), one Sn(1), and one P(1) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one Sn(1) and one P(1) atom. In the seventh O site, O(7) is bonded in a 2-coordinate geometry to one Sn(1) and one P(1) atom. is represented by the CIF card [CIF]
data_KSnPCO7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.583
_cell_length_b   5.317
_cell_length_c   10.620
_cell_angle_alpha   88.068
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   371.486
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.607  0.777  0.806  1.0
  K  K1  1  0.107  0.223  0.194  1.0
  Sn  Sn2  1  0.220  0.219  0.642  1.0
  Sn  Sn3  1  0.720  0.781  0.358  1.0
  P  P4  1  0.723  0.274  0.556  1.0
  P  P5  1  0.223  0.726  0.444  1.0
  C  C6  1  0.266  0.292  0.874  1.0
  C  C7  1  0.766  0.708  0.126  1.0
  O  O8  1  0.800  0.672  0.013  1.0
  O  O9  1  0.245  0.064  0.825  1.0
  O  O10  1  0.251  0.478  0.785  1.0
  O  O11  1  0.907  0.210  0.643  1.0
  O  O12  1  0.539  0.199  0.639  1.0
  O  O13  1  0.228  0.866  0.568  1.0
  O  O14  1  0.717  0.563  0.524  1.0
  O  O15  1  0.217  0.437  0.476  1.0
  O  O16  1  0.728  0.134  0.432  1.0
  O  O17  1  0.039  0.801  0.361  1.0
  O  O18  1  0.407  0.790  0.357  1.0
  O  O19  1  0.751  0.522  0.215  1.0
  O  O20  1  0.745  0.936  0.175  1.0
  O  O21  1  0.300  0.328  0.987  1.0
[/CIF]
.
The structure described by KSnCPO7 crystallizes in the monoclinic P2_1 space group. K(1) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(3), and one O(5) atom. Sn(1) is bonded to one O(2), one O(3), one O(4), one O(5), one O(6), and one O(7) atom to form SnO6 octahedra that share corners with four equivalent P(1)O4 tetrahedra. C(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. P(1) is bonded to one O(4), one O(5), one O(6), and one O(7) atom to form PO4 tetrahedra that share corners with four equivalent Sn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 37-45°. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one K(1) and one C(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one K(1), one Sn(1), and one C(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one K(1), one Sn(1), and one C(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Sn(1) and one P(1) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one K(1), one Sn(1), and one P(1) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one Sn(1) and one P(1) atom. In the seventh O site, O(7) is bonded in a 2-coordinate geometry to one Sn(1) and one P(1) atom. is represented by the CIF card [CIF]
data_KSnPCO7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.583
_cell_length_b   5.317
_cell_length_c   10.620
_cell_angle_alpha   88.068
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   371.486
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.607  0.777  0.806  1.0
  K  K1  1  0.107  0.223  0.194  1.0
  Sn  Sn2  1  0.220  0.219  0.642  1.0
  Sn  Sn3  1  0.720  0.781  0.358  1.0
  P  P4  1  0.723  0.274  0.556  1.0
  P  P5  1  0.223  0.726  0.444  1.0
  C  C6  1  0.266  0.292  0.874  1.0
  C  C7  1  0.766  0.708  0.126  1.0
  O  O8  1  0.800  0.672  0.013  1.0
  O  O9  1  0.245  0.064  0.825  1.0
  O  O10  1  0.251  0.478  0.785  1.0
  O  O11  1  0.907  0.210  0.643  1.0
  O  O12  1  0.539  0.199  0.639  1.0
  O  O13  1  0.228  0.866  0.568  1.0
  O  O14  1  0.717  0.563  0.524  1.0
  O  O15  1  0.217  0.437  0.476  1.0
  O  O16  1  0.728  0.134  0.432  1.0
  O  O17  1  0.039  0.801  0.361  1.0
  O  O18  1  0.407  0.790  0.357  1.0
  O  O19  1  0.751  0.522  0.215  1.0
  O  O20  1  0.745  0.936  0.175  1.0
  O  O21  1  0.300  0.328  0.987  1.0
[/CIF]
.