The material described by NiNH5O3HNO3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two nitric acid molecules and two NiNH5O3 clusters. In each NiNH5O3 cluster, Ni(1) is bonded in a 7-coordinate geometry to one H(1), one H(2), one H(3), one H(5), one H(6), one O(2), and one O(4) atom. N(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(4) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one Ni(1) and one H(2) atom. In the second H site, H(2) is bonded in a distorted single-bond geometry to one Ni(1) and one H(1) atom. In the third H site, H(3) is bonded in a distorted single-bond geometry to one Ni(1) and one H(6) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one Ni(1) atom. In the fifth H site, H(6) is bonded in an L-shaped geometry to one Ni(1) and one H(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one N(1) atom. In the second O site, O(2) is bonded in an L-shaped geometry to one Ni(1) and one N(1) atom. In the third O site, O(4) is bonded in an L-shaped geometry to one Ni(1) and one N(1) atom. is represented by the CIF file [CIF]
data_NiH6(NO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.093
_cell_length_b   6.057
_cell_length_c   11.877
_cell_angle_alpha   102.530
_cell_angle_beta   99.357
_cell_angle_gamma   104.317
_symmetry_Int_Tables_number   1
_cell_volume   403.647
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ni  Ni0  1  0.173  0.169  0.727  1.0
  Ni  Ni1  1  0.827  0.831  0.273  1.0
  H  H2  1  0.581  0.660  0.366  1.0
  H  H3  1  0.419  0.340  0.634  1.0
  H  H4  1  0.366  0.215  0.594  1.0
  H  H5  1  0.634  0.785  0.406  1.0
  H  H6  1  0.892  0.531  0.270  1.0
  H  H7  1  0.108  0.469  0.730  1.0
  H  H8  1  0.251  0.341  0.106  1.0
  H  H9  1  0.749  0.659  0.894  1.0
  H  H10  1  0.259  0.210  0.861  1.0
  H  H11  1  0.741  0.790  0.139  1.0
  H  H12  1  0.831  0.535  0.207  1.0
  H  H13  1  0.169  0.465  0.793  1.0
  N  N14  1  0.059  0.243  0.370  1.0
  N  N15  1  0.941  0.757  0.630  1.0
  N  N16  1  0.335  0.062  0.119  1.0
  N  N17  1  0.665  0.938  0.881  1.0
  O  O18  1  0.174  0.452  0.399  1.0
  O  O19  1  0.826  0.548  0.601  1.0
  O  O20  1  0.152  0.071  0.361  1.0
  O  O21  1  0.848  0.929  0.639  1.0
  O  O22  1  0.261  0.863  0.126  1.0
  O  O23  1  0.739  0.137  0.874  1.0
  O  O24  1  0.834  0.177  0.342  1.0
  O  O25  1  0.166  0.823  0.658  1.0
  O  O26  1  0.525  0.167  0.107  1.0
  O  O27  1  0.475  0.833  0.893  1.0
  O  O28  1  0.169  0.195  0.124  1.0
  O  O29  1  0.831  0.805  0.876  1.0
[/CIF]
.
The material described by NiNH5O3HNO3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two nitric acid molecules and two NiNH5O3 clusters. In each NiNH5O3 cluster, Ni(1) is bonded in a 7-coordinate geometry to one H(1), one H(2), one H(3), one H(5), one H(6), one O(2), and one O(4) atom. N(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(4) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one Ni(1) and one H(2) atom. In the second H site, H(2) is bonded in a distorted single-bond geometry to one Ni(1) and one H(1) atom. In the third H site, H(3) is bonded in a distorted single-bond geometry to one Ni(1) and one H(6) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one Ni(1) atom. In the fifth H site, H(6) is bonded in an L-shaped geometry to one Ni(1) and one H(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one N(1) atom. In the second O site, O(2) is bonded in an L-shaped geometry to one Ni(1) and one N(1) atom. In the third O site, O(4) is bonded in an L-shaped geometry to one Ni(1) and one N(1) atom. is represented by the CIF file [CIF]
data_NiH6(NO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.093
_cell_length_b   6.057
_cell_length_c   11.877
_cell_angle_alpha   102.530
_cell_angle_beta   99.357
_cell_angle_gamma   104.317
_symmetry_Int_Tables_number   1
_cell_volume   403.647
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ni  Ni0  1  0.173  0.169  0.727  1.0
  Ni  Ni1  1  0.827  0.831  0.273  1.0
  H  H2  1  0.581  0.660  0.366  1.0
  H  H3  1  0.419  0.340  0.634  1.0
  H  H4  1  0.366  0.215  0.594  1.0
  H  H5  1  0.634  0.785  0.406  1.0
  H  H6  1  0.892  0.531  0.270  1.0
  H  H7  1  0.108  0.469  0.730  1.0
  H  H8  1  0.251  0.341  0.106  1.0
  H  H9  1  0.749  0.659  0.894  1.0
  H  H10  1  0.259  0.210  0.861  1.0
  H  H11  1  0.741  0.790  0.139  1.0
  H  H12  1  0.831  0.535  0.207  1.0
  H  H13  1  0.169  0.465  0.793  1.0
  N  N14  1  0.059  0.243  0.370  1.0
  N  N15  1  0.941  0.757  0.630  1.0
  N  N16  1  0.335  0.062  0.119  1.0
  N  N17  1  0.665  0.938  0.881  1.0
  O  O18  1  0.174  0.452  0.399  1.0
  O  O19  1  0.826  0.548  0.601  1.0
  O  O20  1  0.152  0.071  0.361  1.0
  O  O21  1  0.848  0.929  0.639  1.0
  O  O22  1  0.261  0.863  0.126  1.0
  O  O23  1  0.739  0.137  0.874  1.0
  O  O24  1  0.834  0.177  0.342  1.0
  O  O25  1  0.166  0.823  0.658  1.0
  O  O26  1  0.525  0.167  0.107  1.0
  O  O27  1  0.475  0.833  0.893  1.0
  O  O28  1  0.169  0.195  0.124  1.0
  O  O29  1  0.831  0.805  0.876  1.0
[/CIF]
.