The compound described by La(NH2SO3)3 crystallizes in the hexagonal P6_3 space group. La(1) is bonded in a 9-coordinate geometry to three equivalent O(1), three equivalent O(2), and three equivalent O(3) atoms. N(1) is bonded in a distorted trigonal non-coplanar geometry to one H(1), one H(2), and one S(1) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. S(1) is bonded in a tetrahedral geometry to one N(1), one O(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(2) is bonded in a distorted single-bond geometry to one La(1) and one S(1) atom. In the second O site, O(3) is bonded in a distorted bent 150 degrees geometry to one La(1) and one S(1) atom. In the third O site, O(1) is bonded in a distorted single-bond geometry to one La(1) and one S(1) atom. is represented by the CIF file [CIF]
data_LaH6S3(NO3)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.028
_cell_length_b   10.028
_cell_length_c   5.899
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   513.717
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.333  0.667  0.247  1.0
  La  La1  1  0.667  0.333  0.747  1.0
  H  H2  1  0.334  0.265  0.239  1.0
  H  H3  1  0.931  0.666  0.239  1.0
  H  H4  1  0.735  0.069  0.239  1.0
  H  H5  1  0.666  0.735  0.739  1.0
  H  H6  1  0.069  0.334  0.739  1.0
  H  H7  1  0.265  0.931  0.739  1.0
  H  H8  1  0.203  0.108  0.373  1.0
  H  H9  1  0.905  0.797  0.373  1.0
  H  H10  1  0.892  0.095  0.373  1.0
  H  H11  1  0.797  0.892  0.873  1.0
  H  H12  1  0.095  0.203  0.873  1.0
  H  H13  1  0.108  0.905  0.873  1.0
  S  S14  1  0.400  0.086  0.248  1.0
  S  S15  1  0.685  0.600  0.248  1.0
  S  S16  1  0.914  0.315  0.248  1.0
  S  S17  1  0.600  0.914  0.748  1.0
  S  S18  1  0.315  0.400  0.748  1.0
  S  S19  1  0.086  0.685  0.748  1.0
  N  N20  1  0.274  0.147  0.235  1.0
  N  N21  1  0.873  0.726  0.235  1.0
  N  N22  1  0.853  0.127  0.235  1.0
  N  N23  1  0.726  0.853  0.735  1.0
  N  N24  1  0.127  0.274  0.735  1.0
  N  N25  1  0.147  0.873  0.735  1.0
  O  O26  1  0.306  0.918  0.248  1.0
  O  O27  1  0.612  0.694  0.248  1.0
  O  O28  1  0.082  0.388  0.248  1.0
  O  O29  1  0.694  0.082  0.748  1.0
  O  O30  1  0.388  0.306  0.748  1.0
  O  O31  1  0.918  0.612  0.748  1.0
  O  O32  1  0.347  0.495  0.543  1.0
  O  O33  1  0.148  0.653  0.543  1.0
  O  O34  1  0.505  0.852  0.543  1.0
  O  O35  1  0.653  0.505  0.043  1.0
  O  O36  1  0.852  0.347  0.043  1.0
  O  O37  1  0.495  0.148  0.043  1.0
  O  O38  1  0.652  0.506  0.456  1.0
  O  O39  1  0.854  0.348  0.456  1.0
  O  O40  1  0.494  0.146  0.456  1.0
  O  O41  1  0.348  0.494  0.956  1.0
  O  O42  1  0.146  0.652  0.956  1.0
  O  O43  1  0.506  0.854  0.956  1.0
[/CIF]
.
The compound described by La(NH2SO3)3 crystallizes in the hexagonal P6_3 space group. La(1) is bonded in a 9-coordinate geometry to three equivalent O(1), three equivalent O(2), and three equivalent O(3) atoms. N(1) is bonded in a distorted trigonal non-coplanar geometry to one H(1), one H(2), and one S(1) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. S(1) is bonded in a tetrahedral geometry to one N(1), one O(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(2) is bonded in a distorted single-bond geometry to one La(1) and one S(1) atom. In the second O site, O(3) is bonded in a distorted bent 150 degrees geometry to one La(1) and one S(1) atom. In the third O site, O(1) is bonded in a distorted single-bond geometry to one La(1) and one S(1) atom. is represented by the CIF file [CIF]
data_LaH6S3(NO3)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.028
_cell_length_b   10.028
_cell_length_c   5.899
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   513.717
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.333  0.667  0.247  1.0
  La  La1  1  0.667  0.333  0.747  1.0
  H  H2  1  0.334  0.265  0.239  1.0
  H  H3  1  0.931  0.666  0.239  1.0
  H  H4  1  0.735  0.069  0.239  1.0
  H  H5  1  0.666  0.735  0.739  1.0
  H  H6  1  0.069  0.334  0.739  1.0
  H  H7  1  0.265  0.931  0.739  1.0
  H  H8  1  0.203  0.108  0.373  1.0
  H  H9  1  0.905  0.797  0.373  1.0
  H  H10  1  0.892  0.095  0.373  1.0
  H  H11  1  0.797  0.892  0.873  1.0
  H  H12  1  0.095  0.203  0.873  1.0
  H  H13  1  0.108  0.905  0.873  1.0
  S  S14  1  0.400  0.086  0.248  1.0
  S  S15  1  0.685  0.600  0.248  1.0
  S  S16  1  0.914  0.315  0.248  1.0
  S  S17  1  0.600  0.914  0.748  1.0
  S  S18  1  0.315  0.400  0.748  1.0
  S  S19  1  0.086  0.685  0.748  1.0
  N  N20  1  0.274  0.147  0.235  1.0
  N  N21  1  0.873  0.726  0.235  1.0
  N  N22  1  0.853  0.127  0.235  1.0
  N  N23  1  0.726  0.853  0.735  1.0
  N  N24  1  0.127  0.274  0.735  1.0
  N  N25  1  0.147  0.873  0.735  1.0
  O  O26  1  0.306  0.918  0.248  1.0
  O  O27  1  0.612  0.694  0.248  1.0
  O  O28  1  0.082  0.388  0.248  1.0
  O  O29  1  0.694  0.082  0.748  1.0
  O  O30  1  0.388  0.306  0.748  1.0
  O  O31  1  0.918  0.612  0.748  1.0
  O  O32  1  0.347  0.495  0.543  1.0
  O  O33  1  0.148  0.653  0.543  1.0
  O  O34  1  0.505  0.852  0.543  1.0
  O  O35  1  0.653  0.505  0.043  1.0
  O  O36  1  0.852  0.347  0.043  1.0
  O  O37  1  0.495  0.148  0.043  1.0
  O  O38  1  0.652  0.506  0.456  1.0
  O  O39  1  0.854  0.348  0.456  1.0
  O  O40  1  0.494  0.146  0.456  1.0
  O  O41  1  0.348  0.494  0.956  1.0
  O  O42  1  0.146  0.652  0.956  1.0
  O  O43  1  0.506  0.854  0.956  1.0
[/CIF]
.