The crystal structure described by NaAg3S2 crystallizes in the cubic Fd-3m space group. Na(1) is bonded to six equivalent S(1) atoms to form distorted edge-sharing NaS6 octahedra. Ag(1) is bonded in a distorted bent 150 degrees geometry to two equivalent S(1) atoms. S(1) is bonded in a 6-coordinate geometry to three equivalent Na(1) and three equivalent Ag(1) atoms. is represented by the CIF file [CIF]
data_NaAg3S2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.763
_cell_length_b   8.763
_cell_length_c   8.763
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   475.819
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.625  0.625  0.125  1.0
  Na  Na1  1  0.625  0.125  0.625  1.0
  Na  Na2  1  0.125  0.625  0.625  1.0
  Na  Na3  1  0.625  0.625  0.625  1.0
  Ag  Ag4  1  0.079  0.421  0.421  1.0
  Ag  Ag5  1  0.829  0.171  0.171  1.0
  Ag  Ag6  1  0.421  0.079  0.421  1.0
  Ag  Ag7  1  0.421  0.421  0.079  1.0
  Ag  Ag8  1  0.079  0.079  0.421  1.0
  Ag  Ag9  1  0.079  0.421  0.079  1.0
  Ag  Ag10  1  0.171  0.829  0.829  1.0
  Ag  Ag11  1  0.829  0.829  0.171  1.0
  Ag  Ag12  1  0.171  0.171  0.829  1.0
  Ag  Ag13  1  0.171  0.829  0.171  1.0
  Ag  Ag14  1  0.829  0.171  0.829  1.0
  Ag  Ag15  1  0.421  0.079  0.079  1.0
  S  S16  1  0.861  0.861  0.418  1.0
  S  S17  1  0.389  0.389  0.389  1.0
  S  S18  1  0.418  0.861  0.861  1.0
  S  S19  1  0.861  0.418  0.861  1.0
  S  S20  1  0.389  0.389  0.832  1.0
  S  S21  1  0.389  0.832  0.389  1.0
  S  S22  1  0.832  0.389  0.389  1.0
  S  S23  1  0.861  0.861  0.861  1.0
[/CIF]
.
The crystal structure described by NaAg3S2 crystallizes in the cubic Fd-3m space group. Na(1) is bonded to six equivalent S(1) atoms to form distorted edge-sharing NaS6 octahedra. Ag(1) is bonded in a distorted bent 150 degrees geometry to two equivalent S(1) atoms. S(1) is bonded in a 6-coordinate geometry to three equivalent Na(1) and three equivalent Ag(1) atoms. is represented by the CIF file [CIF]
data_NaAg3S2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.763
_cell_length_b   8.763
_cell_length_c   8.763
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   475.819
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.625  0.625  0.125  1.0
  Na  Na1  1  0.625  0.125  0.625  1.0
  Na  Na2  1  0.125  0.625  0.625  1.0
  Na  Na3  1  0.625  0.625  0.625  1.0
  Ag  Ag4  1  0.079  0.421  0.421  1.0
  Ag  Ag5  1  0.829  0.171  0.171  1.0
  Ag  Ag6  1  0.421  0.079  0.421  1.0
  Ag  Ag7  1  0.421  0.421  0.079  1.0
  Ag  Ag8  1  0.079  0.079  0.421  1.0
  Ag  Ag9  1  0.079  0.421  0.079  1.0
  Ag  Ag10  1  0.171  0.829  0.829  1.0
  Ag  Ag11  1  0.829  0.829  0.171  1.0
  Ag  Ag12  1  0.171  0.171  0.829  1.0
  Ag  Ag13  1  0.171  0.829  0.171  1.0
  Ag  Ag14  1  0.829  0.171  0.829  1.0
  Ag  Ag15  1  0.421  0.079  0.079  1.0
  S  S16  1  0.861  0.861  0.418  1.0
  S  S17  1  0.389  0.389  0.389  1.0
  S  S18  1  0.418  0.861  0.861  1.0
  S  S19  1  0.861  0.418  0.861  1.0
  S  S20  1  0.389  0.389  0.832  1.0
  S  S21  1  0.389  0.832  0.389  1.0
  S  S22  1  0.832  0.389  0.389  1.0
  S  S23  1  0.861  0.861  0.861  1.0
[/CIF]
.