The compound described by Li(N2O)2(NO2)2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight nitrous acid molecules and four Li(N2O)2 clusters. In each Li(N2O)2 cluster, Li(1) is bonded in a distorted hexagonal planar geometry to two equivalent N(2), two equivalent N(3), and two equivalent O(2) atoms. There are two inequivalent N sites. In the first N site, N(3) is bonded in a 3-coordinate geometry to one Li(1), one N(2), and one O(2) atom. In the second N site, N(2) is bonded in a 2-coordinate geometry to one Li(1) and one N(3) atom. O(2) is bonded in an L-shaped geometry to one Li(1) and one N(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li(NO)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.865
_cell_length_b   6.865
_cell_length_c   23.913
_cell_angle_alpha   89.782
_cell_angle_beta   89.782
_cell_angle_gamma   121.777
_symmetry_Int_Tables_number   1
_cell_volume   958.032
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.000  0.500  0.000  1.0
  Li  Li1  1  0.500  0.000  0.500  1.0
  N  N2  1  0.999  0.504  0.250  1.0
  N  N3  1  0.001  0.496  0.750  1.0
  N  N4  1  0.827  0.724  1.000  1.0
  N  N5  1  0.496  0.001  0.250  1.0
  N  N6  1  0.173  0.276  0.000  1.0
  N  N7  1  0.504  0.999  0.750  1.0
  N  N8  1  0.309  0.473  0.000  1.0
  N  N9  1  0.276  0.173  0.500  1.0
  N  N10  1  0.691  0.527  1.000  1.0
  N  N11  1  0.724  0.827  0.500  1.0
  N  N12  1  0.527  0.691  0.500  1.0
  N  N13  1  0.473  0.309  0.500  1.0
  O  O14  1  0.018  0.666  0.224  1.0
  O  O15  1  0.982  0.334  0.776  1.0
  O  O16  1  0.348  0.674  1.000  1.0
  O  O17  1  0.334  0.982  0.276  1.0
  O  O18  1  0.652  0.326  0.000  1.0
  O  O19  1  0.666  0.018  0.724  1.0
  O  O20  1  0.136  0.500  0.281  1.0
  O  O21  1  0.326  0.652  0.500  1.0
  O  O22  1  0.864  0.500  0.719  1.0
  O  O23  1  0.674  0.348  0.500  1.0
  O  O24  1  0.500  0.864  0.219  1.0
  O  O25  1  0.500  0.136  0.781  1.0
[/CIF]
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The compound described by Li(N2O)2(NO2)2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight nitrous acid molecules and four Li(N2O)2 clusters. In each Li(N2O)2 cluster, Li(1) is bonded in a distorted hexagonal planar geometry to two equivalent N(2), two equivalent N(3), and two equivalent O(2) atoms. There are two inequivalent N sites. In the first N site, N(3) is bonded in a 3-coordinate geometry to one Li(1), one N(2), and one O(2) atom. In the second N site, N(2) is bonded in a 2-coordinate geometry to one Li(1) and one N(3) atom. O(2) is bonded in an L-shaped geometry to one Li(1) and one N(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li(NO)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.865
_cell_length_b   6.865
_cell_length_c   23.913
_cell_angle_alpha   89.782
_cell_angle_beta   89.782
_cell_angle_gamma   121.777
_symmetry_Int_Tables_number   1
_cell_volume   958.032
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.000  0.500  0.000  1.0
  Li  Li1  1  0.500  0.000  0.500  1.0
  N  N2  1  0.999  0.504  0.250  1.0
  N  N3  1  0.001  0.496  0.750  1.0
  N  N4  1  0.827  0.724  1.000  1.0
  N  N5  1  0.496  0.001  0.250  1.0
  N  N6  1  0.173  0.276  0.000  1.0
  N  N7  1  0.504  0.999  0.750  1.0
  N  N8  1  0.309  0.473  0.000  1.0
  N  N9  1  0.276  0.173  0.500  1.0
  N  N10  1  0.691  0.527  1.000  1.0
  N  N11  1  0.724  0.827  0.500  1.0
  N  N12  1  0.527  0.691  0.500  1.0
  N  N13  1  0.473  0.309  0.500  1.0
  O  O14  1  0.018  0.666  0.224  1.0
  O  O15  1  0.982  0.334  0.776  1.0
  O  O16  1  0.348  0.674  1.000  1.0
  O  O17  1  0.334  0.982  0.276  1.0
  O  O18  1  0.652  0.326  0.000  1.0
  O  O19  1  0.666  0.018  0.724  1.0
  O  O20  1  0.136  0.500  0.281  1.0
  O  O21  1  0.326  0.652  0.500  1.0
  O  O22  1  0.864  0.500  0.719  1.0
  O  O23  1  0.674  0.348  0.500  1.0
  O  O24  1  0.500  0.864  0.219  1.0
  O  O25  1  0.500  0.136  0.781  1.0
[/CIF]
.