The material structure described by BaSrBiSbO6 is Orthorhombic Perovskite-derived structured and crystallizes in the trigonal R3 space group. Ba(1) is bonded in a 9-coordinate geometry to three equivalent O(2) and six equivalent O(1) atoms. Sr(1) is bonded in a 6-coordinate geometry to three equivalent O(1) and three equivalent O(2) atoms. Bi(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form BiO6 octahedra that share corners with six equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 20-27°. Sb(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form SbO6 octahedra that share corners with six equivalent Bi(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 20-27°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to two equivalent Ba(1), one Sr(1), one Bi(1), and one Sb(1) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one Ba(1), one Sr(1), one Bi(1), and one Sb(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_BaSrBiSbO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.024
_cell_length_b   6.024
_cell_length_c   6.024
_cell_angle_alpha   60.999
_cell_angle_beta   60.999
_cell_angle_gamma   60.999
_symmetry_Int_Tables_number   1
_cell_volume   158.060
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.750  0.750  0.750  1.0
  Sr  Sr1  1  0.260  0.260  0.260  1.0
  Bi  Bi2  1  0.001  0.001  0.001  1.0
  Sb  Sb3  1  0.501  0.501  0.501  1.0
  O  O4  1  0.811  0.277  0.647  1.0
  O  O5  1  0.277  0.647  0.811  1.0
  O  O6  1  0.647  0.811  0.277  1.0
  O  O7  1  0.207  0.719  0.327  1.0
  O  O8  1  0.719  0.327  0.207  1.0
  O  O9  1  0.327  0.207  0.719  1.0
[/CIF]
.
The material structure described by BaSrBiSbO6 is Orthorhombic Perovskite-derived structured and crystallizes in the trigonal R3 space group. Ba(1) is bonded in a 9-coordinate geometry to three equivalent O(2) and six equivalent O(1) atoms. Sr(1) is bonded in a 6-coordinate geometry to three equivalent O(1) and three equivalent O(2) atoms. Bi(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form BiO6 octahedra that share corners with six equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 20-27°. Sb(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form SbO6 octahedra that share corners with six equivalent Bi(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 20-27°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to two equivalent Ba(1), one Sr(1), one Bi(1), and one Sb(1) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one Ba(1), one Sr(1), one Bi(1), and one Sb(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_BaSrBiSbO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.024
_cell_length_b   6.024
_cell_length_c   6.024
_cell_angle_alpha   60.999
_cell_angle_beta   60.999
_cell_angle_gamma   60.999
_symmetry_Int_Tables_number   1
_cell_volume   158.060
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.750  0.750  0.750  1.0
  Sr  Sr1  1  0.260  0.260  0.260  1.0
  Bi  Bi2  1  0.001  0.001  0.001  1.0
  Sb  Sb3  1  0.501  0.501  0.501  1.0
  O  O4  1  0.811  0.277  0.647  1.0
  O  O5  1  0.277  0.647  0.811  1.0
  O  O6  1  0.647  0.811  0.277  1.0
  O  O7  1  0.207  0.719  0.327  1.0
  O  O8  1  0.719  0.327  0.207  1.0
  O  O9  1  0.327  0.207  0.719  1.0
[/CIF]
.