The crystal structure described by LaV2O2 crystallizes in the tetragonal I4_1/amd space group. La(1) is bonded in a distorted hexagonal planar geometry to six equivalent O(1) atoms. V(1) is bonded in a single-bond geometry to one O(1) atom. O(1) is bonded to three equivalent La(1) and one V(1) atom to form a mixture of corner and edge-sharing OLa3V tetrahedra. is represented by the CIF card [CIF]
data_LaV2O2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.398
_cell_length_b   8.398
_cell_length_c   8.398
_cell_angle_alpha   118.477
_cell_angle_beta   118.477
_cell_angle_gamma   92.658
_symmetry_Int_Tables_number   1
_cell_volume   427.921
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.875  0.125  0.250  1.0
  La  La1  1  0.875  0.625  0.750  1.0
  La  La2  1  0.375  0.125  0.250  1.0
  La  La3  1  0.875  0.125  0.750  1.0
  V  V4  1  0.566  0.393  0.826  1.0
  V  V5  1  0.566  0.740  0.174  1.0
  V  V6  1  0.490  0.816  0.674  1.0
  V  V7  1  0.184  0.510  0.326  1.0
  V  V8  1  0.184  0.857  0.674  1.0
  V  V9  1  0.143  0.816  0.326  1.0
  V  V10  1  0.260  0.434  0.826  1.0
  V  V11  1  0.607  0.434  0.174  1.0
  O  O12  1  0.666  0.327  0.660  1.0
  O  O13  1  0.666  0.006  0.340  1.0
  O  O14  1  0.756  0.916  0.840  1.0
  O  O15  1  0.084  0.244  0.160  1.0
  O  O16  1  0.084  0.923  0.840  1.0
  O  O17  1  0.077  0.916  0.160  1.0
  O  O18  1  0.994  0.334  0.660  1.0
  O  O19  1  0.673  0.334  0.340  1.0
[/CIF]
.
The crystal structure described by LaV2O2 crystallizes in the tetragonal I4_1/amd space group. La(1) is bonded in a distorted hexagonal planar geometry to six equivalent O(1) atoms. V(1) is bonded in a single-bond geometry to one O(1) atom. O(1) is bonded to three equivalent La(1) and one V(1) atom to form a mixture of corner and edge-sharing OLa3V tetrahedra. is represented by the CIF card [CIF]
data_LaV2O2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.398
_cell_length_b   8.398
_cell_length_c   8.398
_cell_angle_alpha   118.477
_cell_angle_beta   118.477
_cell_angle_gamma   92.658
_symmetry_Int_Tables_number   1
_cell_volume   427.921
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.875  0.125  0.250  1.0
  La  La1  1  0.875  0.625  0.750  1.0
  La  La2  1  0.375  0.125  0.250  1.0
  La  La3  1  0.875  0.125  0.750  1.0
  V  V4  1  0.566  0.393  0.826  1.0
  V  V5  1  0.566  0.740  0.174  1.0
  V  V6  1  0.490  0.816  0.674  1.0
  V  V7  1  0.184  0.510  0.326  1.0
  V  V8  1  0.184  0.857  0.674  1.0
  V  V9  1  0.143  0.816  0.326  1.0
  V  V10  1  0.260  0.434  0.826  1.0
  V  V11  1  0.607  0.434  0.174  1.0
  O  O12  1  0.666  0.327  0.660  1.0
  O  O13  1  0.666  0.006  0.340  1.0
  O  O14  1  0.756  0.916  0.840  1.0
  O  O15  1  0.084  0.244  0.160  1.0
  O  O16  1  0.084  0.923  0.840  1.0
  O  O17  1  0.077  0.916  0.160  1.0
  O  O18  1  0.994  0.334  0.660  1.0
  O  O19  1  0.673  0.334  0.340  1.0
[/CIF]
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