The compound described by OsCl6(SCl3)2 is Indium-derived structured and crystallizes in the trigonal R-3m space group. The structure is zero-dimensional and consists of three hexachloro osmium molecules and six SCl3 clusters. In each SCl3 cluster, S(1) is bonded in a distorted trigonal non-coplanar geometry to three equivalent Cl(1) atoms. Cl(1) is bonded in a single-bond geometry to one S(1) atom. is represented by the CIF card [CIF]
data_Os(SCl6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.251
_cell_length_b   8.251
_cell_length_c   8.251
_cell_angle_alpha   77.984
_cell_angle_beta   77.984
_cell_angle_gamma   77.984
_symmetry_Int_Tables_number   1
_cell_volume   529.251
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Os  Os0  1  0.000  0.000  0.000  1.0
  S  S1  1  0.212  0.212  0.212  1.0
  S  S2  1  0.788  0.788  0.788  1.0
  Cl  Cl3  1  0.834  0.834  0.534  1.0
  Cl  Cl4  1  0.186  0.866  0.186  1.0
  Cl  Cl5  1  0.186  0.186  0.866  1.0
  Cl  Cl6  1  0.866  0.186  0.186  1.0
  Cl  Cl7  1  0.134  0.814  0.814  1.0
  Cl  Cl8  1  0.814  0.134  0.814  1.0
  Cl  Cl9  1  0.814  0.814  0.134  1.0
  Cl  Cl10  1  0.166  0.466  0.166  1.0
  Cl  Cl11  1  0.166  0.166  0.466  1.0
  Cl  Cl12  1  0.466  0.166  0.166  1.0
  Cl  Cl13  1  0.534  0.834  0.834  1.0
  Cl  Cl14  1  0.834  0.534  0.834  1.0
[/CIF]
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The compound described by OsCl6(SCl3)2 is Indium-derived structured and crystallizes in the trigonal R-3m space group. The structure is zero-dimensional and consists of three hexachloro osmium molecules and six SCl3 clusters. In each SCl3 cluster, S(1) is bonded in a distorted trigonal non-coplanar geometry to three equivalent Cl(1) atoms. Cl(1) is bonded in a single-bond geometry to one S(1) atom. is represented by the CIF card [CIF]
data_Os(SCl6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.251
_cell_length_b   8.251
_cell_length_c   8.251
_cell_angle_alpha   77.984
_cell_angle_beta   77.984
_cell_angle_gamma   77.984
_symmetry_Int_Tables_number   1
_cell_volume   529.251
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Os  Os0  1  0.000  0.000  0.000  1.0
  S  S1  1  0.212  0.212  0.212  1.0
  S  S2  1  0.788  0.788  0.788  1.0
  Cl  Cl3  1  0.834  0.834  0.534  1.0
  Cl  Cl4  1  0.186  0.866  0.186  1.0
  Cl  Cl5  1  0.186  0.186  0.866  1.0
  Cl  Cl6  1  0.866  0.186  0.186  1.0
  Cl  Cl7  1  0.134  0.814  0.814  1.0
  Cl  Cl8  1  0.814  0.134  0.814  1.0
  Cl  Cl9  1  0.814  0.814  0.134  1.0
  Cl  Cl10  1  0.166  0.466  0.166  1.0
  Cl  Cl11  1  0.166  0.166  0.466  1.0
  Cl  Cl12  1  0.466  0.166  0.166  1.0
  Cl  Cl13  1  0.534  0.834  0.834  1.0
  Cl  Cl14  1  0.834  0.534  0.834  1.0
[/CIF]
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