The crystal structure described by Ag5HgSbO6 crystallizes in the trigonal P-31c space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a trigonal planar geometry to three equivalent O(1) atoms. In the second Ag site, Ag(2) is bonded in a linear geometry to two equivalent O(1) atoms. Hg(1) is bonded to six equivalent O(1) atoms to form distorted HgO6 octahedra that share edges with three equivalent Sb(1)O6 octahedra. Sb(1) is bonded to six equivalent O(1) atoms to form SbO6 octahedra that share edges with three equivalent Hg(1)O6 octahedra. O(1) is bonded to one Ag(1), one Ag(2), one Hg(1), and one Sb(1) atom to form a mixture of corner and edge-sharing OAg2HgSb tetrahedra. is represented by the CIF file [CIF]
data_Ag5HgSbO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.043
_cell_length_b   6.043
_cell_length_c   12.557
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   397.142
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.000  0.000  0.878  1.0
  Ag  Ag1  1  0.000  0.000  0.378  1.0
  Ag  Ag2  1  0.000  0.000  0.122  1.0
  Ag  Ag3  1  0.000  0.000  0.622  1.0
  Ag  Ag4  1  0.500  0.500  0.000  1.0
  Ag  Ag5  1  0.000  0.500  0.000  1.0
  Ag  Ag6  1  0.500  0.000  0.000  1.0
  Ag  Ag7  1  0.000  0.500  0.500  1.0
  Ag  Ag8  1  0.500  0.000  0.500  1.0
  Ag  Ag9  1  0.500  0.500  0.500  1.0
  Hg  Hg10  1  0.667  0.333  0.750  1.0
  Hg  Hg11  1  0.333  0.667  0.250  1.0
  Sb  Sb12  1  0.333  0.667  0.750  1.0
  Sb  Sb13  1  0.667  0.333  0.250  1.0
  O  O14  1  0.605  0.651  0.842  1.0
  O  O15  1  0.046  0.395  0.842  1.0
  O  O16  1  0.349  0.954  0.842  1.0
  O  O17  1  0.954  0.349  0.342  1.0
  O  O18  1  0.395  0.046  0.342  1.0
  O  O19  1  0.651  0.605  0.342  1.0
  O  O20  1  0.395  0.349  0.158  1.0
  O  O21  1  0.954  0.605  0.158  1.0
  O  O22  1  0.651  0.046  0.158  1.0
  O  O23  1  0.046  0.651  0.658  1.0
  O  O24  1  0.605  0.954  0.658  1.0
  O  O25  1  0.349  0.395  0.658  1.0
[/CIF]
.
The crystal structure described by Ag5HgSbO6 crystallizes in the trigonal P-31c space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a trigonal planar geometry to three equivalent O(1) atoms. In the second Ag site, Ag(2) is bonded in a linear geometry to two equivalent O(1) atoms. Hg(1) is bonded to six equivalent O(1) atoms to form distorted HgO6 octahedra that share edges with three equivalent Sb(1)O6 octahedra. Sb(1) is bonded to six equivalent O(1) atoms to form SbO6 octahedra that share edges with three equivalent Hg(1)O6 octahedra. O(1) is bonded to one Ag(1), one Ag(2), one Hg(1), and one Sb(1) atom to form a mixture of corner and edge-sharing OAg2HgSb tetrahedra. is represented by the CIF file [CIF]
data_Ag5HgSbO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.043
_cell_length_b   6.043
_cell_length_c   12.557
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   397.142
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.000  0.000  0.878  1.0
  Ag  Ag1  1  0.000  0.000  0.378  1.0
  Ag  Ag2  1  0.000  0.000  0.122  1.0
  Ag  Ag3  1  0.000  0.000  0.622  1.0
  Ag  Ag4  1  0.500  0.500  0.000  1.0
  Ag  Ag5  1  0.000  0.500  0.000  1.0
  Ag  Ag6  1  0.500  0.000  0.000  1.0
  Ag  Ag7  1  0.000  0.500  0.500  1.0
  Ag  Ag8  1  0.500  0.000  0.500  1.0
  Ag  Ag9  1  0.500  0.500  0.500  1.0
  Hg  Hg10  1  0.667  0.333  0.750  1.0
  Hg  Hg11  1  0.333  0.667  0.250  1.0
  Sb  Sb12  1  0.333  0.667  0.750  1.0
  Sb  Sb13  1  0.667  0.333  0.250  1.0
  O  O14  1  0.605  0.651  0.842  1.0
  O  O15  1  0.046  0.395  0.842  1.0
  O  O16  1  0.349  0.954  0.842  1.0
  O  O17  1  0.954  0.349  0.342  1.0
  O  O18  1  0.395  0.046  0.342  1.0
  O  O19  1  0.651  0.605  0.342  1.0
  O  O20  1  0.395  0.349  0.158  1.0
  O  O21  1  0.954  0.605  0.158  1.0
  O  O22  1  0.651  0.046  0.158  1.0
  O  O23  1  0.046  0.651  0.658  1.0
  O  O24  1  0.605  0.954  0.658  1.0
  O  O25  1  0.349  0.395  0.658  1.0
[/CIF]
.