The compound described by (H2O)2C2H9O6Cl2F is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four water molecules and two C2H9O6Cl2F clusters. In each C2H9O6Cl2F cluster, there are two inequivalent C sites. In the first C site, C(1) is bonded in a 4-coordinate geometry to one C(2), one Cl(1), one Cl(2), and one F(1) atom. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(1), and one O(2) atom. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(3) and one O(4) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(3) atom. In the third H site, H(3) is bonded in a distorted linear geometry to one O(3) and one O(6) atom. In the fourth H site, H(4) is bonded in a distorted single-bond geometry to one O(1) and one O(4) atom. In the fifth H site, H(5) is bonded in a linear geometry to one O(4) and one O(8) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one O(6) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one O(6) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one O(8) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one O(8) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one C(2) and one H(4) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one C(2) atom. In the third O site, O(3) is bonded in a trigonal non-coplanar geometry to one H(1), one H(2), and one H(3) atom. In the fourth O site, O(4) is bonded in a trigonal non-coplanar geometry to one H(1), one H(4), and one H(5) atom. In the fifth O site, O(6) is bonded in a distorted trigonal non-coplanar geometry to one H(3), one H(8), and one H(9) atom. In the sixth O site, O(8) is bonded in a distorted trigonal non-coplanar geometry to one H(12), one H(13), and one H(5) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one C(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one C(1) atom. F(1) is bonded in a single-bond geometry to one C(1) atom. is represented by the CIF file [CIF]
data_H13C2Cl2O8F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.555
_cell_length_b   8.925
_cell_length_c   9.325
_cell_angle_alpha   89.760
_cell_angle_beta   64.313
_cell_angle_gamma   68.853
_symmetry_Int_Tables_number   1
_cell_volume   588.501
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.853  0.483  0.733  1.0
  H  H1  1  0.147  0.517  0.267  1.0
  H  H2  1  0.633  0.560  0.705  1.0
  H  H3  1  0.367  0.440  0.295  1.0
  H  H4  1  0.763  0.661  0.641  1.0
  H  H5  1  0.237  0.339  0.359  1.0
  H  H6  1  0.019  0.477  0.807  1.0
  H  H7  1  0.981  0.523  0.193  1.0
  H  H8  1  0.005  0.301  0.766  1.0
  H  H9  1  0.995  0.699  0.234  1.0
  H  H10  1  0.821  0.956  0.929  1.0
  H  H11  1  0.179  0.044  0.071  1.0
  H  H12  1  0.997  0.799  0.810  1.0
  H  H13  1  0.003  0.201  0.190  1.0
  H  H14  1  0.782  0.881  0.536  1.0
  H  H15  1  0.218  0.119  0.464  1.0
  H  H16  1  0.797  0.881  0.702  1.0
  H  H17  1  0.203  0.119  0.298  1.0
  H  H18  1  0.443  0.944  0.793  1.0
  H  H19  1  0.557  0.056  0.207  1.0
  H  H20  1  0.324  0.838  0.831  1.0
  H  H21  1  0.676  0.162  0.169  1.0
  H  H22  1  0.192  0.060  0.746  1.0
  H  H23  1  0.808  0.940  0.254  1.0
  H  H24  1  0.022  0.049  0.731  1.0
  H  H25  1  0.978  0.951  0.269  1.0
  C  C26  1  0.399  0.358  0.781  1.0
  C  C27  1  0.601  0.642  0.219  1.0
  C  C28  1  0.295  0.547  0.795  1.0
  C  C29  1  0.705  0.453  0.205  1.0
  Cl  Cl30  1  0.544  0.272  0.572  1.0
  Cl  Cl31  1  0.456  0.728  0.428  1.0
  Cl  Cl32  1  0.535  0.311  0.886  1.0
  Cl  Cl33  1  0.465  0.689  0.114  1.0
  O  O34  1  0.131  0.594  0.808  1.0
  O  O35  1  0.869  0.406  0.192  1.0
  O  O36  1  0.389  0.631  0.786  1.0
  O  O37  1  0.611  0.369  0.214  1.0
  O  O38  1  0.768  0.547  0.652  1.0
  O  O39  1  0.232  0.453  0.348  1.0
  O  O40  1  0.932  0.424  0.806  1.0
  O  O41  1  0.068  0.576  0.194  1.0
  O  O42  1  0.907  0.910  0.813  1.0
  O  O43  1  0.093  0.090  0.187  1.0
  O  O44  1  0.731  0.854  0.646  1.0
  O  O45  1  0.269  0.146  0.354  1.0
  O  O46  1  0.312  0.953  0.850  1.0
  O  O47  1  0.688  0.047  0.150  1.0
  O  O48  1  0.106  0.110  0.696  1.0
  O  O49  1  0.894  0.890  0.304  1.0
  F  F50  1  0.270  0.288  0.844  1.0
  F  F51  1  0.730  0.712  0.156  1.0
[/CIF]
.
The compound described by (H2O)2C2H9O6Cl2F is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four water molecules and two C2H9O6Cl2F clusters. In each C2H9O6Cl2F cluster, there are two inequivalent C sites. In the first C site, C(1) is bonded in a 4-coordinate geometry to one C(2), one Cl(1), one Cl(2), and one F(1) atom. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(1), and one O(2) atom. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(3) and one O(4) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(3) atom. In the third H site, H(3) is bonded in a distorted linear geometry to one O(3) and one O(6) atom. In the fourth H site, H(4) is bonded in a distorted single-bond geometry to one O(1) and one O(4) atom. In the fifth H site, H(5) is bonded in a linear geometry to one O(4) and one O(8) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one O(6) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one O(6) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one O(8) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one O(8) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one C(2) and one H(4) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one C(2) atom. In the third O site, O(3) is bonded in a trigonal non-coplanar geometry to one H(1), one H(2), and one H(3) atom. In the fourth O site, O(4) is bonded in a trigonal non-coplanar geometry to one H(1), one H(4), and one H(5) atom. In the fifth O site, O(6) is bonded in a distorted trigonal non-coplanar geometry to one H(3), one H(8), and one H(9) atom. In the sixth O site, O(8) is bonded in a distorted trigonal non-coplanar geometry to one H(12), one H(13), and one H(5) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one C(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one C(1) atom. F(1) is bonded in a single-bond geometry to one C(1) atom. is represented by the CIF file [CIF]
data_H13C2Cl2O8F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.555
_cell_length_b   8.925
_cell_length_c   9.325
_cell_angle_alpha   89.760
_cell_angle_beta   64.313
_cell_angle_gamma   68.853
_symmetry_Int_Tables_number   1
_cell_volume   588.501
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.853  0.483  0.733  1.0
  H  H1  1  0.147  0.517  0.267  1.0
  H  H2  1  0.633  0.560  0.705  1.0
  H  H3  1  0.367  0.440  0.295  1.0
  H  H4  1  0.763  0.661  0.641  1.0
  H  H5  1  0.237  0.339  0.359  1.0
  H  H6  1  0.019  0.477  0.807  1.0
  H  H7  1  0.981  0.523  0.193  1.0
  H  H8  1  0.005  0.301  0.766  1.0
  H  H9  1  0.995  0.699  0.234  1.0
  H  H10  1  0.821  0.956  0.929  1.0
  H  H11  1  0.179  0.044  0.071  1.0
  H  H12  1  0.997  0.799  0.810  1.0
  H  H13  1  0.003  0.201  0.190  1.0
  H  H14  1  0.782  0.881  0.536  1.0
  H  H15  1  0.218  0.119  0.464  1.0
  H  H16  1  0.797  0.881  0.702  1.0
  H  H17  1  0.203  0.119  0.298  1.0
  H  H18  1  0.443  0.944  0.793  1.0
  H  H19  1  0.557  0.056  0.207  1.0
  H  H20  1  0.324  0.838  0.831  1.0
  H  H21  1  0.676  0.162  0.169  1.0
  H  H22  1  0.192  0.060  0.746  1.0
  H  H23  1  0.808  0.940  0.254  1.0
  H  H24  1  0.022  0.049  0.731  1.0
  H  H25  1  0.978  0.951  0.269  1.0
  C  C26  1  0.399  0.358  0.781  1.0
  C  C27  1  0.601  0.642  0.219  1.0
  C  C28  1  0.295  0.547  0.795  1.0
  C  C29  1  0.705  0.453  0.205  1.0
  Cl  Cl30  1  0.544  0.272  0.572  1.0
  Cl  Cl31  1  0.456  0.728  0.428  1.0
  Cl  Cl32  1  0.535  0.311  0.886  1.0
  Cl  Cl33  1  0.465  0.689  0.114  1.0
  O  O34  1  0.131  0.594  0.808  1.0
  O  O35  1  0.869  0.406  0.192  1.0
  O  O36  1  0.389  0.631  0.786  1.0
  O  O37  1  0.611  0.369  0.214  1.0
  O  O38  1  0.768  0.547  0.652  1.0
  O  O39  1  0.232  0.453  0.348  1.0
  O  O40  1  0.932  0.424  0.806  1.0
  O  O41  1  0.068  0.576  0.194  1.0
  O  O42  1  0.907  0.910  0.813  1.0
  O  O43  1  0.093  0.090  0.187  1.0
  O  O44  1  0.731  0.854  0.646  1.0
  O  O45  1  0.269  0.146  0.354  1.0
  O  O46  1  0.312  0.953  0.850  1.0
  O  O47  1  0.688  0.047  0.150  1.0
  O  O48  1  0.106  0.110  0.696  1.0
  O  O49  1  0.894  0.890  0.304  1.0
  F  F50  1  0.270  0.288  0.844  1.0
  F  F51  1  0.730  0.712  0.156  1.0
[/CIF]
.