The crystal structure described by P2N3SOCl5 is High Pressure (4-7GPa) Tellurium structured and crystallizes in the orthorhombic P2_12_12_1 space group. The structure is zero-dimensional and consists of four P2N3SOCl5 clusters. There are two inequivalent P sites. In the first P site, P(1) is bonded to one N(2), one N(3), one Cl(1), and one Cl(3) atom to form PN2Cl2 tetrahedra that share  a cornercorner with one P(2)N2Cl2 tetrahedra and  a cornercorner with one S(1)N2ClO tetrahedra. In the second P site, P(2) is bonded to one N(1), one N(2), one Cl(4), and one Cl(5) atom to form PN2Cl2 tetrahedra that share  a cornercorner with one P(1)N2Cl2 tetrahedra and  a cornercorner with one S(1)N2ClO tetrahedra. There are three inequivalent N sites. In the first N site, N(2) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. In the second N site, N(3) is bonded in a bent 120 degrees geometry to one P(1) and one S(1) atom. In the third N site, N(1) is bonded in a bent 120 degrees geometry to one P(2) and one S(1) atom. S(1) is bonded to one N(1), one N(3), one O(1), and one Cl(2) atom to form distorted SN2ClO tetrahedra that share  a cornercorner with one P(1)N2Cl2 tetrahedra and  a cornercorner with one P(2)N2Cl2 tetrahedra. O(1) is bonded in a single-bond geometry to one S(1) atom. There are five inequivalent Cl sites. In the first Cl site, Cl(5) is bonded in a single-bond geometry to one P(2) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one P(1) atom. In the third Cl site, Cl(2) is bonded in a single-bond geometry to one S(1) atom. In the fourth Cl site, Cl(3) is bonded in a single-bond geometry to one P(1) atom. In the fifth Cl site, Cl(4) is bonded in a single-bond geometry to one P(2) atom. is represented by the CIF card [CIF]
data_P2SN3Cl5O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.947
_cell_length_b   8.861
_cell_length_c   17.266
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1215.923
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.312  0.297  0.120  1.0
  P  P1  1  0.912  0.954  0.288  1.0
  P  P2  1  0.688  0.797  0.380  1.0
  P  P3  1  0.188  0.703  0.620  1.0
  P  P4  1  0.412  0.546  0.712  1.0
  P  P5  1  0.088  0.454  0.212  1.0
  P  P6  1  0.812  0.203  0.880  1.0
  P  P7  1  0.588  0.046  0.788  1.0
  S  S8  1  0.177  0.391  0.624  1.0
  S  S9  1  0.823  0.891  0.876  1.0
  S  S10  1  0.677  0.109  0.376  1.0
  S  S11  1  0.323  0.609  0.124  1.0
  N  N12  1  0.306  0.395  0.693  1.0
  N  N13  1  0.151  0.300  0.174  1.0
  N  N14  1  0.409  0.455  0.105  1.0
  N  N15  1  0.651  0.200  0.826  1.0
  N  N16  1  0.194  0.605  0.193  1.0
  N  N17  1  0.591  0.955  0.395  1.0
  N  N18  1  0.091  0.545  0.605  1.0
  N  N19  1  0.849  0.800  0.326  1.0
  N  N20  1  0.694  0.895  0.807  1.0
  N  N21  1  0.806  0.105  0.307  1.0
  N  N22  1  0.909  0.045  0.895  1.0
  N  N23  1  0.349  0.700  0.674  1.0
  Cl  Cl24  1  0.748  0.297  0.982  1.0
  Cl  Cl25  1  0.180  0.662  0.026  1.0
  Cl  Cl26  1  0.015  0.846  0.660  1.0
  Cl  Cl27  1  0.820  0.162  0.474  1.0
  Cl  Cl28  1  0.155  0.984  0.315  1.0
  Cl  Cl29  1  0.752  0.703  0.482  1.0
  Cl  Cl30  1  0.655  0.516  0.685  1.0
  Cl  Cl31  1  0.845  0.484  0.185  1.0
  Cl  Cl32  1  0.915  0.938  0.173  1.0
  Cl  Cl33  1  0.680  0.838  0.974  1.0
  Cl  Cl34  1  0.485  0.154  0.160  1.0
  Cl  Cl35  1  0.252  0.797  0.518  1.0
  Cl  Cl36  1  0.345  0.016  0.815  1.0
  Cl  Cl37  1  0.415  0.562  0.827  1.0
  Cl  Cl38  1  0.985  0.346  0.840  1.0
  Cl  Cl39  1  0.248  0.203  0.018  1.0
  Cl  Cl40  1  0.515  0.654  0.340  1.0
  Cl  Cl41  1  0.085  0.438  0.327  1.0
  Cl  Cl42  1  0.585  0.062  0.673  1.0
  Cl  Cl43  1  0.320  0.338  0.526  1.0
  O  O44  1  0.558  0.230  0.369  1.0
  O  O45  1  0.058  0.270  0.631  1.0
  O  O46  1  0.942  0.770  0.869  1.0
  O  O47  1  0.442  0.730  0.131  1.0
[/CIF]
.
The crystal structure described by P2N3SOCl5 is High Pressure (4-7GPa) Tellurium structured and crystallizes in the orthorhombic P2_12_12_1 space group. The structure is zero-dimensional and consists of four P2N3SOCl5 clusters. There are two inequivalent P sites. In the first P site, P(1) is bonded to one N(2), one N(3), one Cl(1), and one Cl(3) atom to form PN2Cl2 tetrahedra that share  a cornercorner with one P(2)N2Cl2 tetrahedra and  a cornercorner with one S(1)N2ClO tetrahedra. In the second P site, P(2) is bonded to one N(1), one N(2), one Cl(4), and one Cl(5) atom to form PN2Cl2 tetrahedra that share  a cornercorner with one P(1)N2Cl2 tetrahedra and  a cornercorner with one S(1)N2ClO tetrahedra. There are three inequivalent N sites. In the first N site, N(2) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. In the second N site, N(3) is bonded in a bent 120 degrees geometry to one P(1) and one S(1) atom. In the third N site, N(1) is bonded in a bent 120 degrees geometry to one P(2) and one S(1) atom. S(1) is bonded to one N(1), one N(3), one O(1), and one Cl(2) atom to form distorted SN2ClO tetrahedra that share  a cornercorner with one P(1)N2Cl2 tetrahedra and  a cornercorner with one P(2)N2Cl2 tetrahedra. O(1) is bonded in a single-bond geometry to one S(1) atom. There are five inequivalent Cl sites. In the first Cl site, Cl(5) is bonded in a single-bond geometry to one P(2) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one P(1) atom. In the third Cl site, Cl(2) is bonded in a single-bond geometry to one S(1) atom. In the fourth Cl site, Cl(3) is bonded in a single-bond geometry to one P(1) atom. In the fifth Cl site, Cl(4) is bonded in a single-bond geometry to one P(2) atom. is represented by the CIF card [CIF]
data_P2SN3Cl5O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.947
_cell_length_b   8.861
_cell_length_c   17.266
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1215.923
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.312  0.297  0.120  1.0
  P  P1  1  0.912  0.954  0.288  1.0
  P  P2  1  0.688  0.797  0.380  1.0
  P  P3  1  0.188  0.703  0.620  1.0
  P  P4  1  0.412  0.546  0.712  1.0
  P  P5  1  0.088  0.454  0.212  1.0
  P  P6  1  0.812  0.203  0.880  1.0
  P  P7  1  0.588  0.046  0.788  1.0
  S  S8  1  0.177  0.391  0.624  1.0
  S  S9  1  0.823  0.891  0.876  1.0
  S  S10  1  0.677  0.109  0.376  1.0
  S  S11  1  0.323  0.609  0.124  1.0
  N  N12  1  0.306  0.395  0.693  1.0
  N  N13  1  0.151  0.300  0.174  1.0
  N  N14  1  0.409  0.455  0.105  1.0
  N  N15  1  0.651  0.200  0.826  1.0
  N  N16  1  0.194  0.605  0.193  1.0
  N  N17  1  0.591  0.955  0.395  1.0
  N  N18  1  0.091  0.545  0.605  1.0
  N  N19  1  0.849  0.800  0.326  1.0
  N  N20  1  0.694  0.895  0.807  1.0
  N  N21  1  0.806  0.105  0.307  1.0
  N  N22  1  0.909  0.045  0.895  1.0
  N  N23  1  0.349  0.700  0.674  1.0
  Cl  Cl24  1  0.748  0.297  0.982  1.0
  Cl  Cl25  1  0.180  0.662  0.026  1.0
  Cl  Cl26  1  0.015  0.846  0.660  1.0
  Cl  Cl27  1  0.820  0.162  0.474  1.0
  Cl  Cl28  1  0.155  0.984  0.315  1.0
  Cl  Cl29  1  0.752  0.703  0.482  1.0
  Cl  Cl30  1  0.655  0.516  0.685  1.0
  Cl  Cl31  1  0.845  0.484  0.185  1.0
  Cl  Cl32  1  0.915  0.938  0.173  1.0
  Cl  Cl33  1  0.680  0.838  0.974  1.0
  Cl  Cl34  1  0.485  0.154  0.160  1.0
  Cl  Cl35  1  0.252  0.797  0.518  1.0
  Cl  Cl36  1  0.345  0.016  0.815  1.0
  Cl  Cl37  1  0.415  0.562  0.827  1.0
  Cl  Cl38  1  0.985  0.346  0.840  1.0
  Cl  Cl39  1  0.248  0.203  0.018  1.0
  Cl  Cl40  1  0.515  0.654  0.340  1.0
  Cl  Cl41  1  0.085  0.438  0.327  1.0
  Cl  Cl42  1  0.585  0.062  0.673  1.0
  Cl  Cl43  1  0.320  0.338  0.526  1.0
  O  O44  1  0.558  0.230  0.369  1.0
  O  O45  1  0.058  0.270  0.631  1.0
  O  O46  1  0.942  0.770  0.869  1.0
  O  O47  1  0.442  0.730  0.131  1.0
[/CIF]
.