The structure described by LiVMnP2(HO5)2 crystallizes in the triclinic P-1 space group. Li(1) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(3), one O(5), and one O(6) atom. V(1) is bonded to one O(10), one O(2), one O(5), one O(7), one O(8), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra, corners with two equivalent P(1)O4 tetrahedra, and corners with two equivalent P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 44-49°. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to two equivalent O(1), two equivalent O(4), and two equivalent O(5) atoms to form MnO6 octahedra that share corners with two equivalent V(1)O6 octahedra, corners with two equivalent P(1)O4 tetrahedra, and corners with two equivalent P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 49°. In the second Mn site, Mn(2) is bonded to two equivalent O(3), two equivalent O(6), and two equivalent O(7) atoms to form MnO6 octahedra that share corners with two equivalent V(1)O6 octahedra, corners with two equivalent P(1)O4 tetrahedra, and corners with two equivalent P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 44°. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(3), one O(4), one O(8), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra, and corners with two equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 34-51°. In the second P site, P(2) is bonded to one O(1), one O(10), one O(2), and one O(6) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra, and corners with two equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 37-52°. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(5) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(7) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Li(1), one Mn(1), and one P(2) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Li(1), one V(1), and one P(2) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Li(1), one Mn(2), and one P(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Mn(1) and one P(1) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Li(1), one V(1), one Mn(1), and one H(1) atom. In the sixth O site, O(6) is bonded in a distorted T-shaped geometry to one Li(1), one Mn(2), and one P(2) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one V(1), one Mn(2), and one H(2) atom. In the eighth O site, O(8) is bonded in a 2-coordinate geometry to one V(1) and one P(1) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one V(1) and one P(1) atom. In the tenth O site, O(10) is bonded in a distorted bent 150 degrees geometry to one V(1) and one P(2) atom. is represented by the CIF file [CIF]
data_LiMnVP2(HO5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.786
_cell_length_b   7.432
_cell_length_c   7.990
_cell_angle_alpha   116.456
_cell_angle_beta   89.984
_cell_angle_gamma   91.112
_symmetry_Int_Tables_number   1
_cell_volume   360.682
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.173  0.617  0.762  1.0
  Li  Li1  1  0.827  0.383  0.238  1.0
  Mn  Mn2  1  0.000  0.000  0.000  1.0
  Mn  Mn3  1  0.500  0.500  0.500  1.0
  V  V4  1  0.255  0.750  0.250  1.0
  V  V5  1  0.745  0.250  0.750  1.0
  P  P6  1  0.600  0.725  0.951  1.0
  P  P7  1  0.100  0.223  0.454  1.0
  P  P8  1  0.900  0.777  0.546  1.0
  P  P9  1  0.400  0.275  0.049  1.0
  H  H10  1  0.035  0.319  0.975  1.0
  H  H11  1  0.516  0.834  0.497  1.0
  H  H12  1  0.484  0.166  0.503  1.0
  H  H13  1  0.965  0.681  0.025  1.0
  O  O14  1  0.044  0.821  0.705  1.0
  O  O15  1  0.008  0.709  0.353  1.0
  O  O16  1  0.453  0.666  0.791  1.0
  O  O17  1  0.731  0.906  0.972  1.0
  O  O18  1  0.088  0.762  0.040  1.0
  O  O19  1  0.231  0.412  0.490  1.0
  O  O20  1  0.410  0.729  0.445  1.0
  O  O21  1  0.739  0.547  0.923  1.0
  O  O22  1  0.514  0.213  0.862  1.0
  O  O23  1  0.763  0.956  0.581  1.0
  O  O24  1  0.237  0.044  0.419  1.0
  O  O25  1  0.486  0.787  0.138  1.0
  O  O26  1  0.261  0.453  0.077  1.0
  O  O27  1  0.590  0.271  0.555  1.0
  O  O28  1  0.769  0.588  0.510  1.0
  O  O29  1  0.912  0.238  0.960  1.0
  O  O30  1  0.269  0.094  0.028  1.0
  O  O31  1  0.547  0.334  0.209  1.0
  O  O32  1  0.992  0.291  0.647  1.0
  O  O33  1  0.956  0.179  0.295  1.0
[/CIF]
.
The structure described by LiVMnP2(HO5)2 crystallizes in the triclinic P-1 space group. Li(1) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(3), one O(5), and one O(6) atom. V(1) is bonded to one O(10), one O(2), one O(5), one O(7), one O(8), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra, corners with two equivalent P(1)O4 tetrahedra, and corners with two equivalent P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 44-49°. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to two equivalent O(1), two equivalent O(4), and two equivalent O(5) atoms to form MnO6 octahedra that share corners with two equivalent V(1)O6 octahedra, corners with two equivalent P(1)O4 tetrahedra, and corners with two equivalent P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 49°. In the second Mn site, Mn(2) is bonded to two equivalent O(3), two equivalent O(6), and two equivalent O(7) atoms to form MnO6 octahedra that share corners with two equivalent V(1)O6 octahedra, corners with two equivalent P(1)O4 tetrahedra, and corners with two equivalent P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 44°. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(3), one O(4), one O(8), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra, and corners with two equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 34-51°. In the second P site, P(2) is bonded to one O(1), one O(10), one O(2), and one O(6) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra, and corners with two equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 37-52°. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(5) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(7) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Li(1), one Mn(1), and one P(2) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Li(1), one V(1), and one P(2) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Li(1), one Mn(2), and one P(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Mn(1) and one P(1) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Li(1), one V(1), one Mn(1), and one H(1) atom. In the sixth O site, O(6) is bonded in a distorted T-shaped geometry to one Li(1), one Mn(2), and one P(2) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one V(1), one Mn(2), and one H(2) atom. In the eighth O site, O(8) is bonded in a 2-coordinate geometry to one V(1) and one P(1) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one V(1) and one P(1) atom. In the tenth O site, O(10) is bonded in a distorted bent 150 degrees geometry to one V(1) and one P(2) atom. is represented by the CIF file [CIF]
data_LiMnVP2(HO5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.786
_cell_length_b   7.432
_cell_length_c   7.990
_cell_angle_alpha   116.456
_cell_angle_beta   89.984
_cell_angle_gamma   91.112
_symmetry_Int_Tables_number   1
_cell_volume   360.682
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.173  0.617  0.762  1.0
  Li  Li1  1  0.827  0.383  0.238  1.0
  Mn  Mn2  1  0.000  0.000  0.000  1.0
  Mn  Mn3  1  0.500  0.500  0.500  1.0
  V  V4  1  0.255  0.750  0.250  1.0
  V  V5  1  0.745  0.250  0.750  1.0
  P  P6  1  0.600  0.725  0.951  1.0
  P  P7  1  0.100  0.223  0.454  1.0
  P  P8  1  0.900  0.777  0.546  1.0
  P  P9  1  0.400  0.275  0.049  1.0
  H  H10  1  0.035  0.319  0.975  1.0
  H  H11  1  0.516  0.834  0.497  1.0
  H  H12  1  0.484  0.166  0.503  1.0
  H  H13  1  0.965  0.681  0.025  1.0
  O  O14  1  0.044  0.821  0.705  1.0
  O  O15  1  0.008  0.709  0.353  1.0
  O  O16  1  0.453  0.666  0.791  1.0
  O  O17  1  0.731  0.906  0.972  1.0
  O  O18  1  0.088  0.762  0.040  1.0
  O  O19  1  0.231  0.412  0.490  1.0
  O  O20  1  0.410  0.729  0.445  1.0
  O  O21  1  0.739  0.547  0.923  1.0
  O  O22  1  0.514  0.213  0.862  1.0
  O  O23  1  0.763  0.956  0.581  1.0
  O  O24  1  0.237  0.044  0.419  1.0
  O  O25  1  0.486  0.787  0.138  1.0
  O  O26  1  0.261  0.453  0.077  1.0
  O  O27  1  0.590  0.271  0.555  1.0
  O  O28  1  0.769  0.588  0.510  1.0
  O  O29  1  0.912  0.238  0.960  1.0
  O  O30  1  0.269  0.094  0.028  1.0
  O  O31  1  0.547  0.334  0.209  1.0
  O  O32  1  0.992  0.291  0.647  1.0
  O  O33  1  0.956  0.179  0.295  1.0
[/CIF]
.