The material structure described by Rb3SbF6 crystallizes in the triclinic P-1 space group. There are three inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a distorted hexagonal planar geometry to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms. In the second Rb site, Rb(2) is bonded in a distorted hexagonal planar geometry to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms. In the third Rb site, Rb(3) is bonded in a distorted hexagonal planar geometry to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms. Sb(1) is bonded in an octahedral geometry to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a distorted rectangular see-saw-like geometry to one Rb(1), one Rb(2), one Rb(3), and one Sb(1) atom. In the second F site, F(2) is bonded in a distorted rectangular see-saw-like geometry to one Rb(1), one Rb(2), one Rb(3), and one Sb(1) atom. In the third F site, F(3) is bonded in a distorted rectangular see-saw-like geometry to one Rb(1), one Rb(2), one Rb(3), and one Sb(1) atom. is represented by the CIF file [CIF]
data_Rb3SbF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.839
_cell_length_b   7.262
_cell_length_c   7.277
_cell_angle_alpha   76.471
_cell_angle_beta   112.633
_cell_angle_gamma   127.716
_symmetry_Int_Tables_number   1
_cell_volume   341.084
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.000  0.000  0.500  1.0
  Rb  Rb1  1  0.500  0.500  0.000  1.0
  Rb  Rb2  1  0.000  0.500  0.000  1.0
  Sb  Sb3  1  0.000  0.000  0.000  1.0
  F  F4  1  0.049  0.277  0.773  1.0
  F  F5  1  0.951  0.723  0.227  1.0
  F  F6  1  0.779  0.709  0.782  1.0
  F  F7  1  0.221  0.291  0.218  1.0
  F  F8  1  0.773  0.991  0.067  1.0
  F  F9  1  0.227  0.009  0.933  1.0
[/CIF]
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The material structure described by Rb3SbF6 crystallizes in the triclinic P-1 space group. There are three inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a distorted hexagonal planar geometry to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms. In the second Rb site, Rb(2) is bonded in a distorted hexagonal planar geometry to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms. In the third Rb site, Rb(3) is bonded in a distorted hexagonal planar geometry to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms. Sb(1) is bonded in an octahedral geometry to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a distorted rectangular see-saw-like geometry to one Rb(1), one Rb(2), one Rb(3), and one Sb(1) atom. In the second F site, F(2) is bonded in a distorted rectangular see-saw-like geometry to one Rb(1), one Rb(2), one Rb(3), and one Sb(1) atom. In the third F site, F(3) is bonded in a distorted rectangular see-saw-like geometry to one Rb(1), one Rb(2), one Rb(3), and one Sb(1) atom. is represented by the CIF file [CIF]
data_Rb3SbF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.839
_cell_length_b   7.262
_cell_length_c   7.277
_cell_angle_alpha   76.471
_cell_angle_beta   112.633
_cell_angle_gamma   127.716
_symmetry_Int_Tables_number   1
_cell_volume   341.084
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.000  0.000  0.500  1.0
  Rb  Rb1  1  0.500  0.500  0.000  1.0
  Rb  Rb2  1  0.000  0.500  0.000  1.0
  Sb  Sb3  1  0.000  0.000  0.000  1.0
  F  F4  1  0.049  0.277  0.773  1.0
  F  F5  1  0.951  0.723  0.227  1.0
  F  F6  1  0.779  0.709  0.782  1.0
  F  F7  1  0.221  0.291  0.218  1.0
  F  F8  1  0.773  0.991  0.067  1.0
  F  F9  1  0.227  0.009  0.933  1.0
[/CIF]
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