The crystal structure described by K2GaP2 crystallizes in the monoclinic P2_1/c space group. There are four inequivalent K sites. In the first K site, K(1) is bonded in a 4-coordinate geometry to one P(2), one P(3), and two equivalent P(4) atoms. In the second K site, K(2) is bonded in a 9-coordinate geometry to one Ga(2), two equivalent Ga(1), one P(1), one P(2), two equivalent P(3), and two equivalent P(4) atoms. In the third K site, K(3) is bonded in a 2-coordinate geometry to one P(2), two equivalent P(1), and two equivalent P(3) atoms. In the fourth K site, K(4) is bonded in a 5-coordinate geometry to one P(4), two equivalent P(1), and two equivalent P(2) atoms. There are two inequivalent Ga sites. In the first Ga site, Ga(1) is bonded in a distorted trigonal planar geometry to two equivalent K(2), one P(1), one P(3), and one P(4) atom. In the second Ga site, Ga(2) is bonded in a distorted trigonal planar geometry to one K(2), one P(2), one P(3), and one P(4) atom. There are four inequivalent P sites. In the first P site, P(1) is bonded in a 7-coordinate geometry to one K(2), two equivalent K(3), two equivalent K(4), one Ga(1), and one P(2) atom. In the second P site, P(2) is bonded in a 7-coordinate geometry to one K(1), one K(2), one K(3), two equivalent K(4), one Ga(2), and one P(1) atom. In the third P site, P(3) is bonded in a 7-coordinate geometry to one K(1), two equivalent K(2), two equivalent K(3), one Ga(1), and one Ga(2) atom. In the fourth P site, P(4) is bonded in a 2-coordinate geometry to one K(4), two equivalent K(1), two equivalent K(2), one Ga(1), and one Ga(2) atom. is represented by the CIF card [CIF]
data_K2GaP2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.981
_cell_length_b   8.676
_cell_length_c   10.940
_cell_angle_alpha   61.493
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1166.130
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.117  0.512  0.933  1.0
  K  K1  1  0.383  0.512  0.433  1.0
  K  K2  1  0.883  0.488  0.067  1.0
  K  K3  1  0.613  0.214  0.973  1.0
  K  K4  1  0.628  0.013  0.462  1.0
  K  K5  1  0.387  0.786  0.027  1.0
  K  K6  1  0.887  0.214  0.473  1.0
  K  K7  1  0.867  0.576  0.600  1.0
  K  K8  1  0.367  0.424  0.900  1.0
  K  K9  1  0.133  0.424  0.400  1.0
  K  K10  1  0.633  0.576  0.100  1.0
  K  K11  1  0.872  0.013  0.962  1.0
  K  K12  1  0.372  0.987  0.538  1.0
  K  K13  1  0.128  0.987  0.038  1.0
  K  K14  1  0.617  0.488  0.567  1.0
  K  K15  1  0.113  0.786  0.527  1.0
  Ga  Ga16  1  0.558  0.006  0.758  1.0
  Ga  Ga17  1  0.058  0.994  0.742  1.0
  Ga  Ga18  1  0.442  0.994  0.242  1.0
  Ga  Ga19  1  0.783  0.855  0.753  1.0
  Ga  Ga20  1  0.283  0.145  0.747  1.0
  Ga  Ga21  1  0.217  0.145  0.247  1.0
  Ga  Ga22  1  0.717  0.855  0.253  1.0
  Ga  Ga23  1  0.942  0.006  0.258  1.0
  P  P24  1  0.537  0.734  0.778  1.0
  P  P25  1  0.318  0.365  0.219  1.0
  P  P26  1  0.818  0.635  0.281  1.0
  P  P27  1  0.713  0.108  0.725  1.0
  P  P28  1  0.213  0.892  0.775  1.0
  P  P29  1  0.287  0.892  0.275  1.0
  P  P30  1  0.787  0.108  0.225  1.0
  P  P31  1  0.556  0.794  0.256  1.0
  P  P32  1  0.056  0.206  0.244  1.0
  P  P33  1  0.444  0.206  0.744  1.0
  P  P34  1  0.682  0.635  0.781  1.0
  P  P35  1  0.944  0.794  0.756  1.0
  P  P36  1  0.963  0.734  0.278  1.0
  P  P37  1  0.463  0.266  0.222  1.0
  P  P38  1  0.037  0.266  0.722  1.0
  P  P39  1  0.182  0.365  0.719  1.0
[/CIF]
.
The crystal structure described by K2GaP2 crystallizes in the monoclinic P2_1/c space group. There are four inequivalent K sites. In the first K site, K(1) is bonded in a 4-coordinate geometry to one P(2), one P(3), and two equivalent P(4) atoms. In the second K site, K(2) is bonded in a 9-coordinate geometry to one Ga(2), two equivalent Ga(1), one P(1), one P(2), two equivalent P(3), and two equivalent P(4) atoms. In the third K site, K(3) is bonded in a 2-coordinate geometry to one P(2), two equivalent P(1), and two equivalent P(3) atoms. In the fourth K site, K(4) is bonded in a 5-coordinate geometry to one P(4), two equivalent P(1), and two equivalent P(2) atoms. There are two inequivalent Ga sites. In the first Ga site, Ga(1) is bonded in a distorted trigonal planar geometry to two equivalent K(2), one P(1), one P(3), and one P(4) atom. In the second Ga site, Ga(2) is bonded in a distorted trigonal planar geometry to one K(2), one P(2), one P(3), and one P(4) atom. There are four inequivalent P sites. In the first P site, P(1) is bonded in a 7-coordinate geometry to one K(2), two equivalent K(3), two equivalent K(4), one Ga(1), and one P(2) atom. In the second P site, P(2) is bonded in a 7-coordinate geometry to one K(1), one K(2), one K(3), two equivalent K(4), one Ga(2), and one P(1) atom. In the third P site, P(3) is bonded in a 7-coordinate geometry to one K(1), two equivalent K(2), two equivalent K(3), one Ga(1), and one Ga(2) atom. In the fourth P site, P(4) is bonded in a 2-coordinate geometry to one K(4), two equivalent K(1), two equivalent K(2), one Ga(1), and one Ga(2) atom. is represented by the CIF card [CIF]
data_K2GaP2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.981
_cell_length_b   8.676
_cell_length_c   10.940
_cell_angle_alpha   61.493
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1166.130
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.117  0.512  0.933  1.0
  K  K1  1  0.383  0.512  0.433  1.0
  K  K2  1  0.883  0.488  0.067  1.0
  K  K3  1  0.613  0.214  0.973  1.0
  K  K4  1  0.628  0.013  0.462  1.0
  K  K5  1  0.387  0.786  0.027  1.0
  K  K6  1  0.887  0.214  0.473  1.0
  K  K7  1  0.867  0.576  0.600  1.0
  K  K8  1  0.367  0.424  0.900  1.0
  K  K9  1  0.133  0.424  0.400  1.0
  K  K10  1  0.633  0.576  0.100  1.0
  K  K11  1  0.872  0.013  0.962  1.0
  K  K12  1  0.372  0.987  0.538  1.0
  K  K13  1  0.128  0.987  0.038  1.0
  K  K14  1  0.617  0.488  0.567  1.0
  K  K15  1  0.113  0.786  0.527  1.0
  Ga  Ga16  1  0.558  0.006  0.758  1.0
  Ga  Ga17  1  0.058  0.994  0.742  1.0
  Ga  Ga18  1  0.442  0.994  0.242  1.0
  Ga  Ga19  1  0.783  0.855  0.753  1.0
  Ga  Ga20  1  0.283  0.145  0.747  1.0
  Ga  Ga21  1  0.217  0.145  0.247  1.0
  Ga  Ga22  1  0.717  0.855  0.253  1.0
  Ga  Ga23  1  0.942  0.006  0.258  1.0
  P  P24  1  0.537  0.734  0.778  1.0
  P  P25  1  0.318  0.365  0.219  1.0
  P  P26  1  0.818  0.635  0.281  1.0
  P  P27  1  0.713  0.108  0.725  1.0
  P  P28  1  0.213  0.892  0.775  1.0
  P  P29  1  0.287  0.892  0.275  1.0
  P  P30  1  0.787  0.108  0.225  1.0
  P  P31  1  0.556  0.794  0.256  1.0
  P  P32  1  0.056  0.206  0.244  1.0
  P  P33  1  0.444  0.206  0.744  1.0
  P  P34  1  0.682  0.635  0.781  1.0
  P  P35  1  0.944  0.794  0.756  1.0
  P  P36  1  0.963  0.734  0.278  1.0
  P  P37  1  0.463  0.266  0.222  1.0
  P  P38  1  0.037  0.266  0.722  1.0
  P  P39  1  0.182  0.365  0.719  1.0
[/CIF]
.