The material described by Pb(O3Cl)2 crystallizes in the orthorhombic Fdd2 space group. Pb(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), and four equivalent O(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Pb(1) and one Cl(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Pb(1) and one Cl(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to two equivalent Pb(1) and one Cl(1) atom. Cl(1) is bonded in a trigonal non-coplanar geometry to one O(1), one O(2), and one O(3) atom. is represented by the CIF file [CIF]
data_Pb(ClO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.944
_cell_length_b   6.944
_cell_length_c   7.333
_cell_angle_alpha   106.256
_cell_angle_beta   106.256
_cell_angle_gamma   114.125
_symmetry_Int_Tables_number   1
_cell_volume   276.641
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pb  Pb0  1  0.750  0.250  0.500  1.0
  Pb  Pb1  1  0.000  0.000  0.000  1.0
  Cl  Cl2  1  0.410  0.515  0.544  1.0
  Cl  Cl3  1  0.971  0.867  0.456  1.0
  Cl  Cl4  1  0.265  0.660  0.044  1.0
  Cl  Cl5  1  0.617  0.221  0.956  1.0
  O  O6  1  0.203  0.449  0.585  1.0
  O  O7  1  0.864  0.618  0.415  1.0
  O  O8  1  0.199  0.453  0.085  1.0
  O  O9  1  0.368  0.114  0.915  1.0
  O  O10  1  0.341  0.865  0.244  1.0
  O  O11  1  0.621  0.097  0.756  1.0
  O  O12  1  0.729  0.146  0.109  1.0
  O  O13  1  0.038  0.620  0.891  1.0
  O  O14  1  0.896  0.979  0.609  1.0
  O  O15  1  0.370  0.288  0.391  1.0
  O  O16  1  0.847  0.871  0.256  1.0
  O  O17  1  0.615  0.591  0.744  1.0
[/CIF]
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The material described by Pb(O3Cl)2 crystallizes in the orthorhombic Fdd2 space group. Pb(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), and four equivalent O(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Pb(1) and one Cl(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Pb(1) and one Cl(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to two equivalent Pb(1) and one Cl(1) atom. Cl(1) is bonded in a trigonal non-coplanar geometry to one O(1), one O(2), and one O(3) atom. is represented by the CIF file [CIF]
data_Pb(ClO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.944
_cell_length_b   6.944
_cell_length_c   7.333
_cell_angle_alpha   106.256
_cell_angle_beta   106.256
_cell_angle_gamma   114.125
_symmetry_Int_Tables_number   1
_cell_volume   276.641
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pb  Pb0  1  0.750  0.250  0.500  1.0
  Pb  Pb1  1  0.000  0.000  0.000  1.0
  Cl  Cl2  1  0.410  0.515  0.544  1.0
  Cl  Cl3  1  0.971  0.867  0.456  1.0
  Cl  Cl4  1  0.265  0.660  0.044  1.0
  Cl  Cl5  1  0.617  0.221  0.956  1.0
  O  O6  1  0.203  0.449  0.585  1.0
  O  O7  1  0.864  0.618  0.415  1.0
  O  O8  1  0.199  0.453  0.085  1.0
  O  O9  1  0.368  0.114  0.915  1.0
  O  O10  1  0.341  0.865  0.244  1.0
  O  O11  1  0.621  0.097  0.756  1.0
  O  O12  1  0.729  0.146  0.109  1.0
  O  O13  1  0.038  0.620  0.891  1.0
  O  O14  1  0.896  0.979  0.609  1.0
  O  O15  1  0.370  0.288  0.391  1.0
  O  O16  1  0.847  0.871  0.256  1.0
  O  O17  1  0.615  0.591  0.744  1.0
[/CIF]
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