The structure described by Na3CuP2NH6O13 crystallizes in the monoclinic P2_1/m space group. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded to one O(10), one O(2), one O(4), one O(5), one O(6), and one O(9) atom to form distorted NaO6 octahedra that share  a cornercorner with one Na(1)O6 octahedra,  a cornercorner with one Na(2)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra,  an edgeedge with one Na(1)O6 octahedra, and  an edgeedge with one Na(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-56°. In the second Na site, Na(2) is bonded to one O(1), one O(5), one O(6), one O(7), and two equivalent O(9) atoms to form distorted NaO6 octahedra that share corners with two equivalent Na(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, and edges with two equivalent Na(1)O6 octahedra. The corner-sharing octahedral tilt angles are 56°. Cu(1) is bonded in a distorted square co-planar geometry to two equivalent O(2) and two equivalent O(4) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(3), and two equivalent O(2) atoms to form PO4 tetrahedra that share  a cornercorner with one Na(2)O6 octahedra, corners with two equivalent Na(1)O6 octahedra, and  a cornercorner with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 56-58°. In the second P site, P(2) is bonded to one O(3), one O(5), and two equivalent O(4) atoms to form PO4 tetrahedra that share  a cornercorner with one Na(2)O6 octahedra, corners with four equivalent Na(1)O6 octahedra, and  a cornercorner with one P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 58-68°. N(1) is bonded in a trigonal planar geometry to one O(6), one O(7), and one O(8) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(9) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(9) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(10) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(10) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Na(2) and one P(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Na(1), one Cu(1), and one P(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Na(1), one Cu(1), and one P(2) atom. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to one Na(2), two equivalent Na(1), and one P(2) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one Na(2), two equivalent Na(1), and one N(1) atom. In the seventh O site, O(7) is bonded in a water-like geometry to one Na(2) and one N(1) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one N(1) atom. In the ninth O site, O(9) is bonded in a distorted water-like geometry to one Na(1), one Na(2), one H(1), and one H(2) atom. In the tenth O site, O(10) is bonded in a distorted water-like geometry to two equivalent Na(1), one H(3), and one H(4) atom. is represented by the CIF card [CIF]
data_Na3CuP2H6NO13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.424
_cell_length_b   8.472
_cell_length_c   10.106
_cell_angle_alpha   90.000
_cell_angle_beta   107.517
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   606.099
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.962  0.466  0.177  1.0
  Na  Na1  1  0.038  0.966  0.823  1.0
  Na  Na2  1  0.038  0.534  0.823  1.0
  Na  Na3  1  0.962  0.034  0.177  1.0
  Na  Na4  1  0.157  0.750  0.428  1.0
  Na  Na5  1  0.843  0.250  0.572  1.0
  Cu  Cu6  1  0.500  0.500  0.000  1.0
  Cu  Cu7  1  0.500  0.000  0.000  1.0
  P  P8  1  0.672  0.750  0.241  1.0
  P  P9  1  0.328  0.250  0.759  1.0
  P  P10  1  0.274  0.750  0.123  1.0
  P  P11  1  0.726  0.250  0.877  1.0
  H  H12  1  0.196  0.398  0.478  1.0
  H  H13  1  0.804  0.898  0.522  1.0
  H  H14  1  0.804  0.602  0.522  1.0
  H  H15  1  0.196  0.102  0.478  1.0
  H  H16  1  0.320  0.438  0.383  1.0
  H  H17  1  0.680  0.938  0.617  1.0
  H  H18  1  0.680  0.562  0.617  1.0
  H  H19  1  0.320  0.062  0.383  1.0
  H  H20  1  0.264  0.250  0.140  1.0
  H  H21  1  0.736  0.750  0.860  1.0
  H  H22  1  0.086  0.250  0.009  1.0
  H  H23  1  0.914  0.750  0.991  1.0
  N  N24  1  0.620  0.250  0.280  1.0
  N  N25  1  0.380  0.750  0.720  1.0
  O  O26  1  0.812  0.750  0.386  1.0
  O  O27  1  0.188  0.250  0.614  1.0
  O  O28  1  0.685  0.599  0.159  1.0
  O  O29  1  0.315  0.099  0.841  1.0
  O  O30  1  0.315  0.401  0.841  1.0
  O  O31  1  0.685  0.901  0.159  1.0
  O  O32  1  0.461  0.750  0.260  1.0
  O  O33  1  0.539  0.250  0.740  1.0
  O  O34  1  0.282  0.598  0.042  1.0
  O  O35  1  0.718  0.098  0.958  1.0
  O  O36  1  0.718  0.402  0.958  1.0
  O  O37  1  0.282  0.902  0.042  1.0
  O  O38  1  0.104  0.750  0.178  1.0
  O  O39  1  0.896  0.250  0.822  1.0
  O  O40  1  0.799  0.250  0.307  1.0
  O  O41  1  0.201  0.750  0.693  1.0
  O  O42  1  0.547  0.250  0.379  1.0
  O  O43  1  0.453  0.750  0.621  1.0
  O  O44  1  0.515  0.250  0.155  1.0
  O  O45  1  0.485  0.750  0.845  1.0
  O  O46  1  0.203  0.469  0.402  1.0
  O  O47  1  0.797  0.969  0.598  1.0
  O  O48  1  0.797  0.531  0.598  1.0
  O  O49  1  0.203  0.031  0.402  1.0
  O  O50  1  0.124  0.250  0.111  1.0
  O  O51  1  0.876  0.750  0.889  1.0
[/CIF]
.
The structure described by Na3CuP2NH6O13 crystallizes in the monoclinic P2_1/m space group. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded to one O(10), one O(2), one O(4), one O(5), one O(6), and one O(9) atom to form distorted NaO6 octahedra that share  a cornercorner with one Na(1)O6 octahedra,  a cornercorner with one Na(2)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra,  an edgeedge with one Na(1)O6 octahedra, and  an edgeedge with one Na(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-56°. In the second Na site, Na(2) is bonded to one O(1), one O(5), one O(6), one O(7), and two equivalent O(9) atoms to form distorted NaO6 octahedra that share corners with two equivalent Na(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, and edges with two equivalent Na(1)O6 octahedra. The corner-sharing octahedral tilt angles are 56°. Cu(1) is bonded in a distorted square co-planar geometry to two equivalent O(2) and two equivalent O(4) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(3), and two equivalent O(2) atoms to form PO4 tetrahedra that share  a cornercorner with one Na(2)O6 octahedra, corners with two equivalent Na(1)O6 octahedra, and  a cornercorner with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 56-58°. In the second P site, P(2) is bonded to one O(3), one O(5), and two equivalent O(4) atoms to form PO4 tetrahedra that share  a cornercorner with one Na(2)O6 octahedra, corners with four equivalent Na(1)O6 octahedra, and  a cornercorner with one P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 58-68°. N(1) is bonded in a trigonal planar geometry to one O(6), one O(7), and one O(8) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(9) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(9) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(10) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(10) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Na(2) and one P(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Na(1), one Cu(1), and one P(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Na(1), one Cu(1), and one P(2) atom. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to one Na(2), two equivalent Na(1), and one P(2) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one Na(2), two equivalent Na(1), and one N(1) atom. In the seventh O site, O(7) is bonded in a water-like geometry to one Na(2) and one N(1) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one N(1) atom. In the ninth O site, O(9) is bonded in a distorted water-like geometry to one Na(1), one Na(2), one H(1), and one H(2) atom. In the tenth O site, O(10) is bonded in a distorted water-like geometry to two equivalent Na(1), one H(3), and one H(4) atom. is represented by the CIF card [CIF]
data_Na3CuP2H6NO13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.424
_cell_length_b   8.472
_cell_length_c   10.106
_cell_angle_alpha   90.000
_cell_angle_beta   107.517
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   606.099
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.962  0.466  0.177  1.0
  Na  Na1  1  0.038  0.966  0.823  1.0
  Na  Na2  1  0.038  0.534  0.823  1.0
  Na  Na3  1  0.962  0.034  0.177  1.0
  Na  Na4  1  0.157  0.750  0.428  1.0
  Na  Na5  1  0.843  0.250  0.572  1.0
  Cu  Cu6  1  0.500  0.500  0.000  1.0
  Cu  Cu7  1  0.500  0.000  0.000  1.0
  P  P8  1  0.672  0.750  0.241  1.0
  P  P9  1  0.328  0.250  0.759  1.0
  P  P10  1  0.274  0.750  0.123  1.0
  P  P11  1  0.726  0.250  0.877  1.0
  H  H12  1  0.196  0.398  0.478  1.0
  H  H13  1  0.804  0.898  0.522  1.0
  H  H14  1  0.804  0.602  0.522  1.0
  H  H15  1  0.196  0.102  0.478  1.0
  H  H16  1  0.320  0.438  0.383  1.0
  H  H17  1  0.680  0.938  0.617  1.0
  H  H18  1  0.680  0.562  0.617  1.0
  H  H19  1  0.320  0.062  0.383  1.0
  H  H20  1  0.264  0.250  0.140  1.0
  H  H21  1  0.736  0.750  0.860  1.0
  H  H22  1  0.086  0.250  0.009  1.0
  H  H23  1  0.914  0.750  0.991  1.0
  N  N24  1  0.620  0.250  0.280  1.0
  N  N25  1  0.380  0.750  0.720  1.0
  O  O26  1  0.812  0.750  0.386  1.0
  O  O27  1  0.188  0.250  0.614  1.0
  O  O28  1  0.685  0.599  0.159  1.0
  O  O29  1  0.315  0.099  0.841  1.0
  O  O30  1  0.315  0.401  0.841  1.0
  O  O31  1  0.685  0.901  0.159  1.0
  O  O32  1  0.461  0.750  0.260  1.0
  O  O33  1  0.539  0.250  0.740  1.0
  O  O34  1  0.282  0.598  0.042  1.0
  O  O35  1  0.718  0.098  0.958  1.0
  O  O36  1  0.718  0.402  0.958  1.0
  O  O37  1  0.282  0.902  0.042  1.0
  O  O38  1  0.104  0.750  0.178  1.0
  O  O39  1  0.896  0.250  0.822  1.0
  O  O40  1  0.799  0.250  0.307  1.0
  O  O41  1  0.201  0.750  0.693  1.0
  O  O42  1  0.547  0.250  0.379  1.0
  O  O43  1  0.453  0.750  0.621  1.0
  O  O44  1  0.515  0.250  0.155  1.0
  O  O45  1  0.485  0.750  0.845  1.0
  O  O46  1  0.203  0.469  0.402  1.0
  O  O47  1  0.797  0.969  0.598  1.0
  O  O48  1  0.797  0.531  0.598  1.0
  O  O49  1  0.203  0.031  0.402  1.0
  O  O50  1  0.124  0.250  0.111  1.0
  O  O51  1  0.876  0.750  0.889  1.0
[/CIF]
.