The structure described by V3O2F5 crystallizes in the orthorhombic Pnma space group. There are two inequivalent V sites. In the first V site, V(1) is bonded in a 6-coordinate geometry to four equivalent O(1) and two equivalent F(3) atoms. In the second V site, V(2) is bonded in a 7-coordinate geometry to two equivalent O(1), two equivalent F(1), and three equivalent F(2) atoms. O(1) is bonded to two equivalent V(1) and two equivalent V(2) atoms to form a mixture of edge and corner-sharing OV4 tetrahedra. There are three inequivalent F sites. In the first F site, F(1) is bonded in a distorted bent 150 degrees geometry to two equivalent V(2) atoms. In the second F site, F(2) is bonded in a 3-coordinate geometry to three equivalent V(2) atoms. In the third F site, F(3) is bonded in a bent 150 degrees geometry to two equivalent V(1) atoms. is represented by the CIF file [CIF]
data_V3O2F5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.922
_cell_length_b   5.113
_cell_length_c   16.815
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   423.197
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.449  0.059  0.750  1.0
  V  V1  1  0.049  0.123  0.598  1.0
  V  V2  1  0.049  0.123  0.902  1.0
  V  V3  1  0.549  0.377  0.098  1.0
  V  V4  1  0.549  0.377  0.402  1.0
  V  V5  1  0.949  0.441  0.250  1.0
  V  V6  1  0.051  0.559  0.750  1.0
  V  V7  1  0.451  0.623  0.902  1.0
  V  V8  1  0.451  0.623  0.598  1.0
  V  V9  1  0.951  0.877  0.098  1.0
  V  V10  1  0.951  0.877  0.402  1.0
  V  V11  1  0.551  0.941  0.250  1.0
  O  O12  1  0.786  0.160  0.173  1.0
  O  O13  1  0.786  0.160  0.327  1.0
  O  O14  1  0.286  0.340  0.827  1.0
  O  O15  1  0.286  0.340  0.673  1.0
  O  O16  1  0.714  0.660  0.327  1.0
  O  O17  1  0.714  0.660  0.173  1.0
  O  O18  1  0.214  0.840  0.673  1.0
  O  O19  1  0.214  0.840  0.827  1.0
  F  F20  1  0.317  0.050  0.114  1.0
  F  F21  1  0.317  0.050  0.386  1.0
  F  F22  1  0.825  0.171  0.026  1.0
  F  F23  1  0.825  0.171  0.474  1.0
  F  F24  1  0.820  0.223  0.750  1.0
  F  F25  1  0.320  0.277  0.250  1.0
  F  F26  1  0.325  0.329  0.526  1.0
  F  F27  1  0.325  0.329  0.974  1.0
  F  F28  1  0.817  0.450  0.614  1.0
  F  F29  1  0.817  0.450  0.886  1.0
  F  F30  1  0.183  0.550  0.386  1.0
  F  F31  1  0.183  0.550  0.114  1.0
  F  F32  1  0.675  0.671  0.026  1.0
  F  F33  1  0.675  0.671  0.474  1.0
  F  F34  1  0.680  0.723  0.750  1.0
  F  F35  1  0.180  0.777  0.250  1.0
  F  F36  1  0.175  0.829  0.974  1.0
  F  F37  1  0.175  0.829  0.526  1.0
  F  F38  1  0.683  0.950  0.886  1.0
  F  F39  1  0.683  0.950  0.614  1.0
[/CIF]
.
The structure described by V3O2F5 crystallizes in the orthorhombic Pnma space group. There are two inequivalent V sites. In the first V site, V(1) is bonded in a 6-coordinate geometry to four equivalent O(1) and two equivalent F(3) atoms. In the second V site, V(2) is bonded in a 7-coordinate geometry to two equivalent O(1), two equivalent F(1), and three equivalent F(2) atoms. O(1) is bonded to two equivalent V(1) and two equivalent V(2) atoms to form a mixture of edge and corner-sharing OV4 tetrahedra. There are three inequivalent F sites. In the first F site, F(1) is bonded in a distorted bent 150 degrees geometry to two equivalent V(2) atoms. In the second F site, F(2) is bonded in a 3-coordinate geometry to three equivalent V(2) atoms. In the third F site, F(3) is bonded in a bent 150 degrees geometry to two equivalent V(1) atoms. is represented by the CIF file [CIF]
data_V3O2F5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.922
_cell_length_b   5.113
_cell_length_c   16.815
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   423.197
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.449  0.059  0.750  1.0
  V  V1  1  0.049  0.123  0.598  1.0
  V  V2  1  0.049  0.123  0.902  1.0
  V  V3  1  0.549  0.377  0.098  1.0
  V  V4  1  0.549  0.377  0.402  1.0
  V  V5  1  0.949  0.441  0.250  1.0
  V  V6  1  0.051  0.559  0.750  1.0
  V  V7  1  0.451  0.623  0.902  1.0
  V  V8  1  0.451  0.623  0.598  1.0
  V  V9  1  0.951  0.877  0.098  1.0
  V  V10  1  0.951  0.877  0.402  1.0
  V  V11  1  0.551  0.941  0.250  1.0
  O  O12  1  0.786  0.160  0.173  1.0
  O  O13  1  0.786  0.160  0.327  1.0
  O  O14  1  0.286  0.340  0.827  1.0
  O  O15  1  0.286  0.340  0.673  1.0
  O  O16  1  0.714  0.660  0.327  1.0
  O  O17  1  0.714  0.660  0.173  1.0
  O  O18  1  0.214  0.840  0.673  1.0
  O  O19  1  0.214  0.840  0.827  1.0
  F  F20  1  0.317  0.050  0.114  1.0
  F  F21  1  0.317  0.050  0.386  1.0
  F  F22  1  0.825  0.171  0.026  1.0
  F  F23  1  0.825  0.171  0.474  1.0
  F  F24  1  0.820  0.223  0.750  1.0
  F  F25  1  0.320  0.277  0.250  1.0
  F  F26  1  0.325  0.329  0.526  1.0
  F  F27  1  0.325  0.329  0.974  1.0
  F  F28  1  0.817  0.450  0.614  1.0
  F  F29  1  0.817  0.450  0.886  1.0
  F  F30  1  0.183  0.550  0.386  1.0
  F  F31  1  0.183  0.550  0.114  1.0
  F  F32  1  0.675  0.671  0.026  1.0
  F  F33  1  0.675  0.671  0.474  1.0
  F  F34  1  0.680  0.723  0.750  1.0
  F  F35  1  0.180  0.777  0.250  1.0
  F  F36  1  0.175  0.829  0.974  1.0
  F  F37  1  0.175  0.829  0.526  1.0
  F  F38  1  0.683  0.950  0.886  1.0
  F  F39  1  0.683  0.950  0.614  1.0
[/CIF]
.