The crystal structure described by PdF4 crystallizes in the orthorhombic Fdd2 space group. Pd(1) is bonded to two equivalent F(1) and four equivalent F(2) atoms to form corner-sharing PdF6 octahedra. The corner-sharing octahedral tilt angles are 50°. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Pd(1) atom. In the second F site, F(2) is bonded in a bent 120 degrees geometry to two equivalent Pd(1) atoms. is represented by the CIF file [CIF]
data_PdF4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.415
_cell_length_b   5.415
_cell_length_c   5.509
_cell_angle_alpha   105.933
_cell_angle_beta   105.933
_cell_angle_gamma   116.195
_symmetry_Int_Tables_number   1
_cell_volume   123.876
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pd  Pd0  1  0.740  0.240  0.500  1.0
  Pd  Pd1  1  0.990  0.990  0.000  1.0
  F  F2  1  0.971  0.749  0.185  1.0
  F  F3  1  0.563  0.786  0.815  1.0
  F  F4  1  0.019  0.296  0.312  1.0
  F  F5  1  0.984  0.707  0.688  1.0
  F  F6  1  0.046  0.269  0.812  1.0
  F  F7  1  0.457  0.234  0.188  1.0
  F  F8  1  0.536  0.813  0.315  1.0
  F  F9  1  0.499  0.221  0.685  1.0
[/CIF]
.
The crystal structure described by PdF4 crystallizes in the orthorhombic Fdd2 space group. Pd(1) is bonded to two equivalent F(1) and four equivalent F(2) atoms to form corner-sharing PdF6 octahedra. The corner-sharing octahedral tilt angles are 50°. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Pd(1) atom. In the second F site, F(2) is bonded in a bent 120 degrees geometry to two equivalent Pd(1) atoms. is represented by the CIF file [CIF]
data_PdF4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.415
_cell_length_b   5.415
_cell_length_c   5.509
_cell_angle_alpha   105.933
_cell_angle_beta   105.933
_cell_angle_gamma   116.195
_symmetry_Int_Tables_number   1
_cell_volume   123.876
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pd  Pd0  1  0.740  0.240  0.500  1.0
  Pd  Pd1  1  0.990  0.990  0.000  1.0
  F  F2  1  0.971  0.749  0.185  1.0
  F  F3  1  0.563  0.786  0.815  1.0
  F  F4  1  0.019  0.296  0.312  1.0
  F  F5  1  0.984  0.707  0.688  1.0
  F  F6  1  0.046  0.269  0.812  1.0
  F  F7  1  0.457  0.234  0.188  1.0
  F  F8  1  0.536  0.813  0.315  1.0
  F  F9  1  0.499  0.221  0.685  1.0
[/CIF]
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