The compound described by C3PN6H15S is Indium-like structured and crystallizes in the hexagonal P6_3 space group. The structure is zero-dimensional and consists of two C3PN6H15S clusters. C(1) is bonded to one N(2), one H(1), one H(2), and one H(3) atom to form CH3N tetrahedra that share  a cornercorner with one P(1)SN3 tetrahedra. P(1) is bonded to three equivalent N(2) and one S(1) atom to form PSN3 tetrahedra that share corners with three equivalent C(1)H3N tetrahedra. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted water-like geometry to one N(2), one H(4), and one H(5) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one C(1), one P(1), and one N(1) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(1) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(1) atom. S(1) is bonded in a single-bond geometry to one P(1) atom. is represented by the CIF file [CIF]
data_PH15C3SN6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.763
_cell_length_b   9.763
_cell_length_c   7.753
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   640.002
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.333  0.667  0.331  1.0
  P  P1  1  0.667  0.333  0.831  1.0
  H  H2  1  0.291  0.281  0.382  1.0
  H  H3  1  0.719  0.011  0.382  1.0
  H  H4  1  0.989  0.709  0.382  1.0
  H  H5  1  0.709  0.719  0.882  1.0
  H  H6  1  0.281  0.989  0.882  1.0
  H  H7  1  0.011  0.291  0.882  1.0
  H  H8  1  0.193  0.344  0.236  1.0
  H  H9  1  0.656  0.849  0.236  1.0
  H  H10  1  0.151  0.807  0.236  1.0
  H  H11  1  0.807  0.656  0.736  1.0
  H  H12  1  0.344  0.151  0.736  1.0
  H  H13  1  0.849  0.193  0.736  1.0
  H  H14  1  0.128  0.302  0.457  1.0
  H  H15  1  0.698  0.826  0.457  1.0
  H  H16  1  0.174  0.872  0.457  1.0
  H  H17  1  0.872  0.698  0.957  1.0
  H  H18  1  0.302  0.174  0.957  1.0
  H  H19  1  0.826  0.128  0.957  1.0
  H  H20  1  0.326  0.495  0.671  1.0
  H  H21  1  0.505  0.830  0.671  1.0
  H  H22  1  0.170  0.674  0.671  1.0
  H  H23  1  0.674  0.505  0.171  1.0
  H  H24  1  0.495  0.170  0.171  1.0
  H  H25  1  0.830  0.326  0.171  1.0
  H  H26  1  0.478  0.483  0.587  1.0
  H  H27  1  0.517  0.995  0.587  1.0
  H  H28  1  0.005  0.522  0.587  1.0
  H  H29  1  0.522  0.517  0.087  1.0
  H  H30  1  0.483  0.005  0.087  1.0
  H  H31  1  0.995  0.478  0.087  1.0
  C  C32  1  0.232  0.351  0.370  1.0
  C  C33  1  0.649  0.882  0.370  1.0
  C  C34  1  0.118  0.768  0.370  1.0
  C  C35  1  0.768  0.649  0.870  1.0
  C  C36  1  0.351  0.118  0.870  1.0
  C  C37  1  0.882  0.232  0.870  1.0
  S  S38  1  0.333  0.667  0.077  1.0
  S  S39  1  0.667  0.333  0.577  1.0
  N  N40  1  0.414  0.541  0.580  1.0
  N  N41  1  0.459  0.873  0.580  1.0
  N  N42  1  0.127  0.586  0.580  1.0
  N  N43  1  0.586  0.459  0.080  1.0
  N  N44  1  0.541  0.127  0.080  1.0
  N  N45  1  0.873  0.414  0.080  1.0
  N  N46  1  0.346  0.515  0.413  1.0
  N  N47  1  0.485  0.832  0.413  1.0
  N  N48  1  0.168  0.654  0.413  1.0
  N  N49  1  0.654  0.485  0.913  1.0
  N  N50  1  0.515  0.168  0.913  1.0
  N  N51  1  0.832  0.346  0.913  1.0
[/CIF]
.
The compound described by C3PN6H15S is Indium-like structured and crystallizes in the hexagonal P6_3 space group. The structure is zero-dimensional and consists of two C3PN6H15S clusters. C(1) is bonded to one N(2), one H(1), one H(2), and one H(3) atom to form CH3N tetrahedra that share  a cornercorner with one P(1)SN3 tetrahedra. P(1) is bonded to three equivalent N(2) and one S(1) atom to form PSN3 tetrahedra that share corners with three equivalent C(1)H3N tetrahedra. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted water-like geometry to one N(2), one H(4), and one H(5) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one C(1), one P(1), and one N(1) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(1) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(1) atom. S(1) is bonded in a single-bond geometry to one P(1) atom. is represented by the CIF file [CIF]
data_PH15C3SN6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.763
_cell_length_b   9.763
_cell_length_c   7.753
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   640.002
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.333  0.667  0.331  1.0
  P  P1  1  0.667  0.333  0.831  1.0
  H  H2  1  0.291  0.281  0.382  1.0
  H  H3  1  0.719  0.011  0.382  1.0
  H  H4  1  0.989  0.709  0.382  1.0
  H  H5  1  0.709  0.719  0.882  1.0
  H  H6  1  0.281  0.989  0.882  1.0
  H  H7  1  0.011  0.291  0.882  1.0
  H  H8  1  0.193  0.344  0.236  1.0
  H  H9  1  0.656  0.849  0.236  1.0
  H  H10  1  0.151  0.807  0.236  1.0
  H  H11  1  0.807  0.656  0.736  1.0
  H  H12  1  0.344  0.151  0.736  1.0
  H  H13  1  0.849  0.193  0.736  1.0
  H  H14  1  0.128  0.302  0.457  1.0
  H  H15  1  0.698  0.826  0.457  1.0
  H  H16  1  0.174  0.872  0.457  1.0
  H  H17  1  0.872  0.698  0.957  1.0
  H  H18  1  0.302  0.174  0.957  1.0
  H  H19  1  0.826  0.128  0.957  1.0
  H  H20  1  0.326  0.495  0.671  1.0
  H  H21  1  0.505  0.830  0.671  1.0
  H  H22  1  0.170  0.674  0.671  1.0
  H  H23  1  0.674  0.505  0.171  1.0
  H  H24  1  0.495  0.170  0.171  1.0
  H  H25  1  0.830  0.326  0.171  1.0
  H  H26  1  0.478  0.483  0.587  1.0
  H  H27  1  0.517  0.995  0.587  1.0
  H  H28  1  0.005  0.522  0.587  1.0
  H  H29  1  0.522  0.517  0.087  1.0
  H  H30  1  0.483  0.005  0.087  1.0
  H  H31  1  0.995  0.478  0.087  1.0
  C  C32  1  0.232  0.351  0.370  1.0
  C  C33  1  0.649  0.882  0.370  1.0
  C  C34  1  0.118  0.768  0.370  1.0
  C  C35  1  0.768  0.649  0.870  1.0
  C  C36  1  0.351  0.118  0.870  1.0
  C  C37  1  0.882  0.232  0.870  1.0
  S  S38  1  0.333  0.667  0.077  1.0
  S  S39  1  0.667  0.333  0.577  1.0
  N  N40  1  0.414  0.541  0.580  1.0
  N  N41  1  0.459  0.873  0.580  1.0
  N  N42  1  0.127  0.586  0.580  1.0
  N  N43  1  0.586  0.459  0.080  1.0
  N  N44  1  0.541  0.127  0.080  1.0
  N  N45  1  0.873  0.414  0.080  1.0
  N  N46  1  0.346  0.515  0.413  1.0
  N  N47  1  0.485  0.832  0.413  1.0
  N  N48  1  0.168  0.654  0.413  1.0
  N  N49  1  0.654  0.485  0.913  1.0
  N  N50  1  0.515  0.168  0.913  1.0
  N  N51  1  0.832  0.346  0.913  1.0
[/CIF]
.