The structure described by AuF5 is Indium-like structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four AuF5 clusters. Au(1) is bonded to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom to form edge-sharing AuF6 octahedra. There are six inequivalent F sites. In the first F site, F(5) is bonded in a single-bond geometry to one Au(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one Au(1) atom. In the third F site, F(6) is bonded in a single-bond geometry to one Au(1) atom. In the fourth F site, F(2) is bonded in a single-bond geometry to one Au(1) atom. In the fifth F site, F(3) is bonded in a water-like geometry to two equivalent Au(1) atoms. In the sixth F site, F(4) is bonded in a water-like geometry to two equivalent Au(1) atoms. is represented by the CIF file [CIF]
data_AuF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.770
_cell_length_b   9.211
_cell_length_c   14.891
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   654.327
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Au  Au0  1  0.072  0.129  0.144  1.0
  Au  Au1  1  0.572  0.371  0.856  1.0
  Au  Au2  1  0.428  0.629  0.356  1.0
  Au  Au3  1  0.928  0.871  0.644  1.0
  Au  Au4  1  0.928  0.871  0.856  1.0
  Au  Au5  1  0.428  0.629  0.144  1.0
  Au  Au6  1  0.572  0.371  0.644  1.0
  Au  Au7  1  0.072  0.129  0.356  1.0
  F  F8  1  0.252  0.025  0.052  1.0
  F  F9  1  0.752  0.475  0.948  1.0
  F  F10  1  0.248  0.525  0.448  1.0
  F  F11  1  0.748  0.975  0.552  1.0
  F  F12  1  0.748  0.975  0.948  1.0
  F  F13  1  0.248  0.525  0.052  1.0
  F  F14  1  0.752  0.475  0.552  1.0
  F  F15  1  0.252  0.025  0.448  1.0
  F  F16  1  0.379  0.262  0.351  1.0
  F  F17  1  0.879  0.238  0.649  1.0
  F  F18  1  0.121  0.762  0.149  1.0
  F  F19  1  0.621  0.738  0.851  1.0
  F  F20  1  0.621  0.738  0.649  1.0
  F  F21  1  0.121  0.762  0.351  1.0
  F  F22  1  0.879  0.238  0.851  1.0
  F  F23  1  0.379  0.262  0.149  1.0
  F  F24  1  0.895  0.235  0.250  1.0
  F  F25  1  0.395  0.265  0.750  1.0
  F  F26  1  0.605  0.735  0.250  1.0
  F  F27  1  0.105  0.765  0.750  1.0
  F  F28  1  0.242  0.020  0.250  1.0
  F  F29  1  0.742  0.480  0.750  1.0
  F  F30  1  0.258  0.520  0.250  1.0
  F  F31  1  0.758  0.980  0.750  1.0
  F  F32  1  0.762  0.997  0.355  1.0
  F  F33  1  0.262  0.503  0.645  1.0
  F  F34  1  0.738  0.497  0.145  1.0
  F  F35  1  0.238  0.003  0.855  1.0
  F  F36  1  0.238  0.003  0.645  1.0
  F  F37  1  0.738  0.497  0.355  1.0
  F  F38  1  0.262  0.503  0.855  1.0
  F  F39  1  0.762  0.997  0.145  1.0
  F  F40  1  0.902  0.240  0.447  1.0
  F  F41  1  0.402  0.260  0.553  1.0
  F  F42  1  0.598  0.740  0.053  1.0
  F  F43  1  0.098  0.760  0.947  1.0
  F  F44  1  0.098  0.760  0.553  1.0
  F  F45  1  0.598  0.740  0.447  1.0
  F  F46  1  0.402  0.260  0.947  1.0
  F  F47  1  0.902  0.240  0.053  1.0
[/CIF]
.
The structure described by AuF5 is Indium-like structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four AuF5 clusters. Au(1) is bonded to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom to form edge-sharing AuF6 octahedra. There are six inequivalent F sites. In the first F site, F(5) is bonded in a single-bond geometry to one Au(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one Au(1) atom. In the third F site, F(6) is bonded in a single-bond geometry to one Au(1) atom. In the fourth F site, F(2) is bonded in a single-bond geometry to one Au(1) atom. In the fifth F site, F(3) is bonded in a water-like geometry to two equivalent Au(1) atoms. In the sixth F site, F(4) is bonded in a water-like geometry to two equivalent Au(1) atoms. is represented by the CIF file [CIF]
data_AuF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.770
_cell_length_b   9.211
_cell_length_c   14.891
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   654.327
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Au  Au0  1  0.072  0.129  0.144  1.0
  Au  Au1  1  0.572  0.371  0.856  1.0
  Au  Au2  1  0.428  0.629  0.356  1.0
  Au  Au3  1  0.928  0.871  0.644  1.0
  Au  Au4  1  0.928  0.871  0.856  1.0
  Au  Au5  1  0.428  0.629  0.144  1.0
  Au  Au6  1  0.572  0.371  0.644  1.0
  Au  Au7  1  0.072  0.129  0.356  1.0
  F  F8  1  0.252  0.025  0.052  1.0
  F  F9  1  0.752  0.475  0.948  1.0
  F  F10  1  0.248  0.525  0.448  1.0
  F  F11  1  0.748  0.975  0.552  1.0
  F  F12  1  0.748  0.975  0.948  1.0
  F  F13  1  0.248  0.525  0.052  1.0
  F  F14  1  0.752  0.475  0.552  1.0
  F  F15  1  0.252  0.025  0.448  1.0
  F  F16  1  0.379  0.262  0.351  1.0
  F  F17  1  0.879  0.238  0.649  1.0
  F  F18  1  0.121  0.762  0.149  1.0
  F  F19  1  0.621  0.738  0.851  1.0
  F  F20  1  0.621  0.738  0.649  1.0
  F  F21  1  0.121  0.762  0.351  1.0
  F  F22  1  0.879  0.238  0.851  1.0
  F  F23  1  0.379  0.262  0.149  1.0
  F  F24  1  0.895  0.235  0.250  1.0
  F  F25  1  0.395  0.265  0.750  1.0
  F  F26  1  0.605  0.735  0.250  1.0
  F  F27  1  0.105  0.765  0.750  1.0
  F  F28  1  0.242  0.020  0.250  1.0
  F  F29  1  0.742  0.480  0.750  1.0
  F  F30  1  0.258  0.520  0.250  1.0
  F  F31  1  0.758  0.980  0.750  1.0
  F  F32  1  0.762  0.997  0.355  1.0
  F  F33  1  0.262  0.503  0.645  1.0
  F  F34  1  0.738  0.497  0.145  1.0
  F  F35  1  0.238  0.003  0.855  1.0
  F  F36  1  0.238  0.003  0.645  1.0
  F  F37  1  0.738  0.497  0.355  1.0
  F  F38  1  0.262  0.503  0.855  1.0
  F  F39  1  0.762  0.997  0.145  1.0
  F  F40  1  0.902  0.240  0.447  1.0
  F  F41  1  0.402  0.260  0.553  1.0
  F  F42  1  0.598  0.740  0.053  1.0
  F  F43  1  0.098  0.760  0.947  1.0
  F  F44  1  0.098  0.760  0.553  1.0
  F  F45  1  0.598  0.740  0.447  1.0
  F  F46  1  0.402  0.260  0.947  1.0
  F  F47  1  0.902  0.240  0.053  1.0
[/CIF]
.