The material structure described by Li3Cs2B5O10 crystallizes in the orthorhombic C222_1 space group. There are two inequivalent Cs sites. In the first Cs site, Cs(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent O(5) atoms. In the second Cs site, Cs(2) is bonded in a 6-coordinate geometry to two equivalent O(3), two equivalent O(4), and two equivalent O(5) atoms. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded in a 4-coordinate geometry to two equivalent O(1) and two equivalent O(2) atoms. In the second Li site, Li(2) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(4), and two equivalent O(5) atoms. There are three inequivalent B sites. In the first B site, B(1) is bonded in a tetrahedral geometry to two equivalent O(2) and two equivalent O(3) atoms. In the second B site, B(2) is bonded in a trigonal planar geometry to one O(1), one O(3), and one O(4) atom. In the third B site, B(3) is bonded in a trigonal planar geometry to one O(2), one O(4), and one O(5) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Cs(1), one Li(1), one Li(2), and one B(2) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Cs(1), one Li(1), one Li(2), one B(1), and one B(3) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Cs(1), one Cs(2), one B(1), and one B(2) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Cs(2), one Li(2), one B(2), and one B(3) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Cs(1), one Cs(2), two equivalent Li(2), and one B(3) atom. is represented by the CIF card [CIF]
data_Cs2Li3(BO2)5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.909
_cell_length_b   6.909
_cell_length_c   13.074
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   115.487
_symmetry_Int_Tables_number   1
_cell_volume   563.332
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.709  0.709  0.500  1.0
  Cs  Cs1  1  0.291  0.291  0.000  1.0
  Cs  Cs2  1  0.766  0.234  0.250  1.0
  Cs  Cs3  1  0.234  0.766  0.750  1.0
  Li  Li4  1  0.320  0.680  0.250  1.0
  Li  Li5  1  0.680  0.320  0.750  1.0
  Li  Li6  1  0.445  0.822  0.037  1.0
  Li  Li7  1  0.555  0.178  0.537  1.0
  Li  Li8  1  0.822  0.445  0.963  1.0
  Li  Li9  1  0.178  0.555  0.463  1.0
  B  B10  1  0.084  0.916  0.250  1.0
  B  B11  1  0.916  0.084  0.750  1.0
  B  B12  1  0.722  0.719  0.164  1.0
  B  B13  1  0.278  0.281  0.664  1.0
  B  B14  1  0.719  0.722  0.836  1.0
  B  B15  1  0.281  0.278  0.336  1.0
  B  B16  1  0.285  0.954  0.418  1.0
  B  B17  1  0.715  0.046  0.918  1.0
  B  B18  1  0.954  0.285  0.582  1.0
  B  B19  1  0.046  0.715  0.082  1.0
  O  O20  1  0.522  0.696  0.150  1.0
  O  O21  1  0.478  0.304  0.650  1.0
  O  O22  1  0.696  0.522  0.850  1.0
  O  O23  1  0.304  0.478  0.350  1.0
  O  O24  1  0.149  0.827  0.341  1.0
  O  O25  1  0.851  0.173  0.841  1.0
  O  O26  1  0.827  0.149  0.659  1.0
  O  O27  1  0.173  0.851  0.159  1.0
  O  O28  1  0.172  0.152  0.253  1.0
  O  O29  1  0.828  0.848  0.753  1.0
  O  O30  1  0.152  0.172  0.747  1.0
  O  O31  1  0.848  0.828  0.247  1.0
  O  O32  1  0.181  0.370  0.593  1.0
  O  O33  1  0.819  0.630  0.093  1.0
  O  O34  1  0.370  0.181  0.407  1.0
  O  O35  1  0.630  0.819  0.907  1.0
  O  O36  1  0.341  0.870  0.499  1.0
  O  O37  1  0.659  0.130  0.999  1.0
  O  O38  1  0.870  0.341  0.501  1.0
  O  O39  1  0.130  0.659  0.001  1.0
[/CIF]
.
The material structure described by Li3Cs2B5O10 crystallizes in the orthorhombic C222_1 space group. There are two inequivalent Cs sites. In the first Cs site, Cs(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent O(5) atoms. In the second Cs site, Cs(2) is bonded in a 6-coordinate geometry to two equivalent O(3), two equivalent O(4), and two equivalent O(5) atoms. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded in a 4-coordinate geometry to two equivalent O(1) and two equivalent O(2) atoms. In the second Li site, Li(2) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(4), and two equivalent O(5) atoms. There are three inequivalent B sites. In the first B site, B(1) is bonded in a tetrahedral geometry to two equivalent O(2) and two equivalent O(3) atoms. In the second B site, B(2) is bonded in a trigonal planar geometry to one O(1), one O(3), and one O(4) atom. In the third B site, B(3) is bonded in a trigonal planar geometry to one O(2), one O(4), and one O(5) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Cs(1), one Li(1), one Li(2), and one B(2) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Cs(1), one Li(1), one Li(2), one B(1), and one B(3) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Cs(1), one Cs(2), one B(1), and one B(2) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Cs(2), one Li(2), one B(2), and one B(3) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Cs(1), one Cs(2), two equivalent Li(2), and one B(3) atom. is represented by the CIF card [CIF]
data_Cs2Li3(BO2)5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.909
_cell_length_b   6.909
_cell_length_c   13.074
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   115.487
_symmetry_Int_Tables_number   1
_cell_volume   563.332
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.709  0.709  0.500  1.0
  Cs  Cs1  1  0.291  0.291  0.000  1.0
  Cs  Cs2  1  0.766  0.234  0.250  1.0
  Cs  Cs3  1  0.234  0.766  0.750  1.0
  Li  Li4  1  0.320  0.680  0.250  1.0
  Li  Li5  1  0.680  0.320  0.750  1.0
  Li  Li6  1  0.445  0.822  0.037  1.0
  Li  Li7  1  0.555  0.178  0.537  1.0
  Li  Li8  1  0.822  0.445  0.963  1.0
  Li  Li9  1  0.178  0.555  0.463  1.0
  B  B10  1  0.084  0.916  0.250  1.0
  B  B11  1  0.916  0.084  0.750  1.0
  B  B12  1  0.722  0.719  0.164  1.0
  B  B13  1  0.278  0.281  0.664  1.0
  B  B14  1  0.719  0.722  0.836  1.0
  B  B15  1  0.281  0.278  0.336  1.0
  B  B16  1  0.285  0.954  0.418  1.0
  B  B17  1  0.715  0.046  0.918  1.0
  B  B18  1  0.954  0.285  0.582  1.0
  B  B19  1  0.046  0.715  0.082  1.0
  O  O20  1  0.522  0.696  0.150  1.0
  O  O21  1  0.478  0.304  0.650  1.0
  O  O22  1  0.696  0.522  0.850  1.0
  O  O23  1  0.304  0.478  0.350  1.0
  O  O24  1  0.149  0.827  0.341  1.0
  O  O25  1  0.851  0.173  0.841  1.0
  O  O26  1  0.827  0.149  0.659  1.0
  O  O27  1  0.173  0.851  0.159  1.0
  O  O28  1  0.172  0.152  0.253  1.0
  O  O29  1  0.828  0.848  0.753  1.0
  O  O30  1  0.152  0.172  0.747  1.0
  O  O31  1  0.848  0.828  0.247  1.0
  O  O32  1  0.181  0.370  0.593  1.0
  O  O33  1  0.819  0.630  0.093  1.0
  O  O34  1  0.370  0.181  0.407  1.0
  O  O35  1  0.630  0.819  0.907  1.0
  O  O36  1  0.341  0.870  0.499  1.0
  O  O37  1  0.659  0.130  0.999  1.0
  O  O38  1  0.870  0.341  0.501  1.0
  O  O39  1  0.130  0.659  0.001  1.0
[/CIF]
.