The material described by WAgZn2O6 crystallizes in the triclinic P1 space group. W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form WO6 octahedra that share corners with two equivalent Zn(1)O4 trigonal pyramids and  an edgeedge with one Zn(1)O4 trigonal pyramid. Ag(1) is bonded in a rectangular see-saw-like geometry to one O(1), one O(2), one O(3), and one O(6) atom. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(2), one O(5), and one O(6) atom to form distorted ZnO4 trigonal pyramids that share corners with two equivalent W(1)O6 octahedra and  an edgeedge with one W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-60°. In the second Zn site, Zn(2) is bonded in a 5-coordinate geometry to one O(1), one O(3), one O(4), one O(5), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded to one W(1), one Ag(1), one Zn(1), and one Zn(2) atom to form distorted edge-sharing OZn2AgW trigonal pyramids. In the second O site, O(2) is bonded in a trigonal planar geometry to one W(1), one Ag(1), and one Zn(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one W(1), one Ag(1), and one Zn(2) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one W(1) and one Zn(2) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one W(1), one Zn(1), and one Zn(2) atom. In the sixth O site, O(6) is bonded to one W(1), one Ag(1), one Zn(1), and one Zn(2) atom to form edge-sharing OZn2AgW tetrahedra. is represented by the CIF file [CIF]
data_Zn2AgWO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.123
_cell_length_b   5.541
_cell_length_c   5.687
_cell_angle_alpha   114.918
_cell_angle_beta   115.506
_cell_angle_gamma   90.020
_symmetry_Int_Tables_number   1
_cell_volume   128.826
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.686  0.192  0.461  1.0
  Zn  Zn1  1  0.278  0.671  0.474  1.0
  Ag  Ag2  1  0.521  0.521  0.020  1.0
  W  W3  1  0.004  0.017  0.006  1.0
  O  O4  1  0.312  0.845  0.218  1.0
  O  O5  1  0.766  0.237  0.845  1.0
  O  O6  1  0.671  0.743  0.850  1.0
  O  O7  1  0.066  0.864  0.675  1.0
  O  O8  1  0.000  0.235  0.373  1.0
  O  O9  1  0.377  0.339  0.224  1.0
[/CIF]
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The material described by WAgZn2O6 crystallizes in the triclinic P1 space group. W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form WO6 octahedra that share corners with two equivalent Zn(1)O4 trigonal pyramids and  an edgeedge with one Zn(1)O4 trigonal pyramid. Ag(1) is bonded in a rectangular see-saw-like geometry to one O(1), one O(2), one O(3), and one O(6) atom. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(2), one O(5), and one O(6) atom to form distorted ZnO4 trigonal pyramids that share corners with two equivalent W(1)O6 octahedra and  an edgeedge with one W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-60°. In the second Zn site, Zn(2) is bonded in a 5-coordinate geometry to one O(1), one O(3), one O(4), one O(5), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded to one W(1), one Ag(1), one Zn(1), and one Zn(2) atom to form distorted edge-sharing OZn2AgW trigonal pyramids. In the second O site, O(2) is bonded in a trigonal planar geometry to one W(1), one Ag(1), and one Zn(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one W(1), one Ag(1), and one Zn(2) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one W(1) and one Zn(2) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one W(1), one Zn(1), and one Zn(2) atom. In the sixth O site, O(6) is bonded to one W(1), one Ag(1), one Zn(1), and one Zn(2) atom to form edge-sharing OZn2AgW tetrahedra. is represented by the CIF file [CIF]
data_Zn2AgWO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.123
_cell_length_b   5.541
_cell_length_c   5.687
_cell_angle_alpha   114.918
_cell_angle_beta   115.506
_cell_angle_gamma   90.020
_symmetry_Int_Tables_number   1
_cell_volume   128.826
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.686  0.192  0.461  1.0
  Zn  Zn1  1  0.278  0.671  0.474  1.0
  Ag  Ag2  1  0.521  0.521  0.020  1.0
  W  W3  1  0.004  0.017  0.006  1.0
  O  O4  1  0.312  0.845  0.218  1.0
  O  O5  1  0.766  0.237  0.845  1.0
  O  O6  1  0.671  0.743  0.850  1.0
  O  O7  1  0.066  0.864  0.675  1.0
  O  O8  1  0.000  0.235  0.373  1.0
  O  O9  1  0.377  0.339  0.224  1.0
[/CIF]
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