The compound described by Tl2CS3 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four Tl2CS3 clusters. Tl(1) is bonded in a 1-coordinate geometry to one S(1) atom. C(1) is bonded in a trigonal planar geometry to one S(2) and two equivalent S(1) atoms. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted L-shaped geometry to one Tl(1) and one C(1) atom. In the second S site, S(2) is bonded in a distorted single-bond geometry to one C(1) atom. is represented by the CIF file [CIF]
data_Tl2CS3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.605
_cell_length_b   6.605
_cell_length_c   9.517
_cell_angle_alpha   70.678
_cell_angle_beta   70.678
_cell_angle_gamma   82.737
_symmetry_Int_Tables_number   1
_cell_volume   369.656
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.615  0.104  0.624  1.0
  Tl  Tl1  1  0.385  0.896  0.376  1.0
  Tl  Tl2  1  0.104  0.615  0.124  1.0
  Tl  Tl3  1  0.896  0.385  0.876  1.0
  C  C4  1  0.917  0.083  0.250  1.0
  C  C5  1  0.083  0.917  0.750  1.0
  S  S6  1  0.153  0.125  0.099  1.0
  S  S7  1  0.719  0.281  0.250  1.0
  S  S8  1  0.847  0.875  0.901  1.0
  S  S9  1  0.875  0.847  0.401  1.0
  S  S10  1  0.125  0.153  0.599  1.0
  S  S11  1  0.281  0.719  0.750  1.0
[/CIF]
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The compound described by Tl2CS3 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four Tl2CS3 clusters. Tl(1) is bonded in a 1-coordinate geometry to one S(1) atom. C(1) is bonded in a trigonal planar geometry to one S(2) and two equivalent S(1) atoms. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted L-shaped geometry to one Tl(1) and one C(1) atom. In the second S site, S(2) is bonded in a distorted single-bond geometry to one C(1) atom. is represented by the CIF file [CIF]
data_Tl2CS3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.605
_cell_length_b   6.605
_cell_length_c   9.517
_cell_angle_alpha   70.678
_cell_angle_beta   70.678
_cell_angle_gamma   82.737
_symmetry_Int_Tables_number   1
_cell_volume   369.656
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.615  0.104  0.624  1.0
  Tl  Tl1  1  0.385  0.896  0.376  1.0
  Tl  Tl2  1  0.104  0.615  0.124  1.0
  Tl  Tl3  1  0.896  0.385  0.876  1.0
  C  C4  1  0.917  0.083  0.250  1.0
  C  C5  1  0.083  0.917  0.750  1.0
  S  S6  1  0.153  0.125  0.099  1.0
  S  S7  1  0.719  0.281  0.250  1.0
  S  S8  1  0.847  0.875  0.901  1.0
  S  S9  1  0.875  0.847  0.401  1.0
  S  S10  1  0.125  0.153  0.599  1.0
  S  S11  1  0.281  0.719  0.750  1.0
[/CIF]
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