The material described by PtO3Cl4O2 is Indium-derived structured and crystallizes in the monoclinic Cc space group. The structure is zero-dimensional and consists of four 7782-44-7 molecules and four PtO3Cl4 clusters. In each PtO3Cl4 cluster, Pt(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Pt(1) and one O(5) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Pt(1) atom. In the third O site, O(5) is bonded in a single-bond geometry to one O(1) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Pt(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Pt(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Pt(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Pt(1) atom. is represented by the CIF card [CIF]
data_PtCl4O5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.730
_cell_length_b   6.730
_cell_length_c   11.189
_cell_angle_alpha   86.885
_cell_angle_beta   86.885
_cell_angle_gamma   106.933
_symmetry_Int_Tables_number   1
_cell_volume   482.792
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pt  Pt0  1  0.165  0.813  0.898  1.0
  Pt  Pt1  1  0.813  0.165  0.398  1.0
  Cl  Cl2  1  0.451  0.110  0.862  1.0
  Cl  Cl3  1  0.110  0.451  0.362  1.0
  Cl  Cl4  1  0.876  0.515  0.914  1.0
  Cl  Cl5  1  0.515  0.876  0.414  1.0
  Cl  Cl6  1  0.016  0.947  0.357  1.0
  Cl  Cl7  1  0.947  0.016  0.857  1.0
  Cl  Cl8  1  0.135  0.847  0.098  1.0
  Cl  Cl9  1  0.847  0.135  0.598  1.0
  O  O10  1  0.144  0.776  0.660  1.0
  O  O11  1  0.776  0.144  0.160  1.0
  O  O12  1  0.645  0.336  0.389  1.0
  O  O13  1  0.336  0.645  0.889  1.0
  O  O14  1  0.421  0.365  0.585  1.0
  O  O15  1  0.365  0.421  0.085  1.0
  O  O16  1  0.521  0.464  0.141  1.0
  O  O17  1  0.464  0.521  0.641  1.0
  O  O18  1  0.975  0.683  0.624  1.0
  O  O19  1  0.683  0.975  0.124  1.0
[/CIF]
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The material described by PtO3Cl4O2 is Indium-derived structured and crystallizes in the monoclinic Cc space group. The structure is zero-dimensional and consists of four 7782-44-7 molecules and four PtO3Cl4 clusters. In each PtO3Cl4 cluster, Pt(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Pt(1) and one O(5) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Pt(1) atom. In the third O site, O(5) is bonded in a single-bond geometry to one O(1) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Pt(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Pt(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Pt(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Pt(1) atom. is represented by the CIF card [CIF]
data_PtCl4O5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.730
_cell_length_b   6.730
_cell_length_c   11.189
_cell_angle_alpha   86.885
_cell_angle_beta   86.885
_cell_angle_gamma   106.933
_symmetry_Int_Tables_number   1
_cell_volume   482.792
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pt  Pt0  1  0.165  0.813  0.898  1.0
  Pt  Pt1  1  0.813  0.165  0.398  1.0
  Cl  Cl2  1  0.451  0.110  0.862  1.0
  Cl  Cl3  1  0.110  0.451  0.362  1.0
  Cl  Cl4  1  0.876  0.515  0.914  1.0
  Cl  Cl5  1  0.515  0.876  0.414  1.0
  Cl  Cl6  1  0.016  0.947  0.357  1.0
  Cl  Cl7  1  0.947  0.016  0.857  1.0
  Cl  Cl8  1  0.135  0.847  0.098  1.0
  Cl  Cl9  1  0.847  0.135  0.598  1.0
  O  O10  1  0.144  0.776  0.660  1.0
  O  O11  1  0.776  0.144  0.160  1.0
  O  O12  1  0.645  0.336  0.389  1.0
  O  O13  1  0.336  0.645  0.889  1.0
  O  O14  1  0.421  0.365  0.585  1.0
  O  O15  1  0.365  0.421  0.085  1.0
  O  O16  1  0.521  0.464  0.141  1.0
  O  O17  1  0.464  0.521  0.641  1.0
  O  O18  1  0.975  0.683  0.624  1.0
  O  O19  1  0.683  0.975  0.124  1.0
[/CIF]
.