The crystal structure described by Li4WO5 is Caswellsilverite-like structured and crystallizes in the tetragonal I4 space group. Li(1) is bonded to one O(2) and five equivalent O(1) atoms to form LiO6 octahedra that share  a cornercorner with one W(1)O6 octahedra, corners with five equivalent Li(1)O6 octahedra, edges with three equivalent W(1)O6 octahedra, and edges with nine equivalent Li(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-16°. W(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form WO6 octahedra that share corners with two equivalent W(1)O6 octahedra, corners with four equivalent Li(1)O6 octahedra, and edges with twelve equivalent Li(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-7°. There are two inequivalent O sites. In the first O site, O(1) is bonded to five equivalent Li(1) and one W(1) atom to form OLi5W octahedra that share  a cornercorner with one O(2)Li4W2 octahedra, corners with five equivalent O(1)Li5W octahedra, edges with three equivalent O(2)Li4W2 octahedra, and edges with nine equivalent O(1)Li5W octahedra. The corner-sharing octahedral tilt angles range from 2-16°. In the second O site, O(2) is bonded to four equivalent Li(1) and two equivalent W(1) atoms to form OLi4W2 octahedra that share corners with two equivalent O(2)Li4W2 octahedra, corners with four equivalent O(1)Li5W octahedra, and edges with twelve equivalent O(1)Li5W octahedra. The corner-sharing octahedral tilt angles range from 0-7°. is represented by the CIF file [CIF]
data_Li4WO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.059
_cell_length_b   5.059
_cell_length_c   5.059
_cell_angle_alpha   99.472
_cell_angle_beta   99.479
_cell_angle_gamma   132.122
_symmetry_Int_Tables_number   1
_cell_volume   87.789
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.815  0.398  0.215  1.0
  Li  Li1  1  0.600  0.815  0.417  1.0
  Li  Li2  1  0.398  0.183  0.583  1.0
  Li  Li3  1  0.183  0.600  0.785  1.0
  W  W4  1  0.960  0.960  1.000  1.0
  O  O5  1  0.284  0.921  0.186  1.0
  O  O6  1  0.098  0.284  0.363  1.0
  O  O7  1  0.921  0.735  0.637  1.0
  O  O8  1  0.735  0.098  0.814  1.0
  O  O9  1  0.509  0.509  1.000  1.0
[/CIF]
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The crystal structure described by Li4WO5 is Caswellsilverite-like structured and crystallizes in the tetragonal I4 space group. Li(1) is bonded to one O(2) and five equivalent O(1) atoms to form LiO6 octahedra that share  a cornercorner with one W(1)O6 octahedra, corners with five equivalent Li(1)O6 octahedra, edges with three equivalent W(1)O6 octahedra, and edges with nine equivalent Li(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-16°. W(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form WO6 octahedra that share corners with two equivalent W(1)O6 octahedra, corners with four equivalent Li(1)O6 octahedra, and edges with twelve equivalent Li(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-7°. There are two inequivalent O sites. In the first O site, O(1) is bonded to five equivalent Li(1) and one W(1) atom to form OLi5W octahedra that share  a cornercorner with one O(2)Li4W2 octahedra, corners with five equivalent O(1)Li5W octahedra, edges with three equivalent O(2)Li4W2 octahedra, and edges with nine equivalent O(1)Li5W octahedra. The corner-sharing octahedral tilt angles range from 2-16°. In the second O site, O(2) is bonded to four equivalent Li(1) and two equivalent W(1) atoms to form OLi4W2 octahedra that share corners with two equivalent O(2)Li4W2 octahedra, corners with four equivalent O(1)Li5W octahedra, and edges with twelve equivalent O(1)Li5W octahedra. The corner-sharing octahedral tilt angles range from 0-7°. is represented by the CIF file [CIF]
data_Li4WO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.059
_cell_length_b   5.059
_cell_length_c   5.059
_cell_angle_alpha   99.472
_cell_angle_beta   99.479
_cell_angle_gamma   132.122
_symmetry_Int_Tables_number   1
_cell_volume   87.789
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.815  0.398  0.215  1.0
  Li  Li1  1  0.600  0.815  0.417  1.0
  Li  Li2  1  0.398  0.183  0.583  1.0
  Li  Li3  1  0.183  0.600  0.785  1.0
  W  W4  1  0.960  0.960  1.000  1.0
  O  O5  1  0.284  0.921  0.186  1.0
  O  O6  1  0.098  0.284  0.363  1.0
  O  O7  1  0.921  0.735  0.637  1.0
  O  O8  1  0.735  0.098  0.814  1.0
  O  O9  1  0.509  0.509  1.000  1.0
[/CIF]
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