The crystal structure described by NaBi3V2O10 crystallizes in the triclinic P1 space group. Na(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(6), one O(8), and one O(9) atom. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(10), one O(3), one O(6), and one O(7) atom to form VO4 tetrahedra that share  a cornercorner with one Bi(2)O5 square pyramid. In the second V site, V(2) is bonded to one O(4), one O(5), one O(8), and one O(9) atom to form VO4 tetrahedra that share corners with two equivalent Bi(2)O5 square pyramids. There are three inequivalent Bi sites. In the first Bi site, Bi(1) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(3), one O(5), and one O(7) atom. In the second Bi site, Bi(2) is bonded to one O(1), one O(2), one O(4), one O(6), and one O(8) atom to form distorted BiO5 square pyramids that share  a cornercorner with one V(1)O4 tetrahedra and corners with two equivalent V(2)O4 tetrahedra. In the third Bi site, Bi(3) is bonded in a 6-coordinate geometry to one O(1), one O(10), one O(2), one O(4), one O(5), and one O(7) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded to one Na(1), one Bi(1), one Bi(2), and one Bi(3) atom to form edge-sharing ONaBi3 tetrahedra. In the second O site, O(2) is bonded to one Na(1), one Bi(1), one Bi(2), and one Bi(3) atom to form edge-sharing ONaBi3 tetrahedra. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one Na(1), one V(1), and one Bi(1) atom. In the fourth O site, O(4) is bonded in a 1-coordinate geometry to one V(2), one Bi(2), and one Bi(3) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one V(2), one Bi(1), and one Bi(3) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Na(1), one V(1), and one Bi(2) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one V(1), one Bi(1), and one Bi(3) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one Na(1), one V(2), and one Bi(2) atom. In the ninth O site, O(9) is bonded in a distorted bent 120 degrees geometry to one Na(1) and one V(2) atom. In the tenth O site, O(10) is bonded in a single-bond geometry to one V(1) and one Bi(3) atom. is represented by the CIF card [CIF]
data_NaV2Bi3O10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.644
_cell_length_b   7.220
_cell_length_c   7.243
_cell_angle_alpha   107.076
_cell_angle_beta   112.695
_cell_angle_gamma   96.332
_symmetry_Int_Tables_number   1
_cell_volume   251.786
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.697  0.624  0.809  1.0
  V  V1  1  0.651  0.157  0.854  1.0
  V  V2  1  0.345  0.843  0.140  1.0
  Bi  Bi3  1  0.913  0.247  0.480  1.0
  Bi  Bi4  1  0.091  0.756  0.534  1.0
  Bi  Bi5  1  0.307  0.384  0.213  1.0
  O  O6  1  0.742  0.498  0.456  1.0
  O  O7  1  0.249  0.490  0.519  1.0
  O  O8  1  0.842  0.307  0.783  1.0
  O  O9  1  0.166  0.687  0.219  1.0
  O  O10  1  0.434  0.105  0.299  1.0
  O  O11  1  0.551  0.903  0.693  1.0
  O  O12  1  0.870  0.196  0.124  1.0
  O  O13  1  0.144  0.799  0.873  1.0
  O  O14  1  0.628  0.770  0.169  1.0
  O  O15  1  0.369  0.233  0.836  1.0
[/CIF]
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The crystal structure described by NaBi3V2O10 crystallizes in the triclinic P1 space group. Na(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(6), one O(8), and one O(9) atom. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(10), one O(3), one O(6), and one O(7) atom to form VO4 tetrahedra that share  a cornercorner with one Bi(2)O5 square pyramid. In the second V site, V(2) is bonded to one O(4), one O(5), one O(8), and one O(9) atom to form VO4 tetrahedra that share corners with two equivalent Bi(2)O5 square pyramids. There are three inequivalent Bi sites. In the first Bi site, Bi(1) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(3), one O(5), and one O(7) atom. In the second Bi site, Bi(2) is bonded to one O(1), one O(2), one O(4), one O(6), and one O(8) atom to form distorted BiO5 square pyramids that share  a cornercorner with one V(1)O4 tetrahedra and corners with two equivalent V(2)O4 tetrahedra. In the third Bi site, Bi(3) is bonded in a 6-coordinate geometry to one O(1), one O(10), one O(2), one O(4), one O(5), and one O(7) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded to one Na(1), one Bi(1), one Bi(2), and one Bi(3) atom to form edge-sharing ONaBi3 tetrahedra. In the second O site, O(2) is bonded to one Na(1), one Bi(1), one Bi(2), and one Bi(3) atom to form edge-sharing ONaBi3 tetrahedra. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one Na(1), one V(1), and one Bi(1) atom. In the fourth O site, O(4) is bonded in a 1-coordinate geometry to one V(2), one Bi(2), and one Bi(3) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one V(2), one Bi(1), and one Bi(3) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Na(1), one V(1), and one Bi(2) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one V(1), one Bi(1), and one Bi(3) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one Na(1), one V(2), and one Bi(2) atom. In the ninth O site, O(9) is bonded in a distorted bent 120 degrees geometry to one Na(1) and one V(2) atom. In the tenth O site, O(10) is bonded in a single-bond geometry to one V(1) and one Bi(3) atom. is represented by the CIF card [CIF]
data_NaV2Bi3O10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.644
_cell_length_b   7.220
_cell_length_c   7.243
_cell_angle_alpha   107.076
_cell_angle_beta   112.695
_cell_angle_gamma   96.332
_symmetry_Int_Tables_number   1
_cell_volume   251.786
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.697  0.624  0.809  1.0
  V  V1  1  0.651  0.157  0.854  1.0
  V  V2  1  0.345  0.843  0.140  1.0
  Bi  Bi3  1  0.913  0.247  0.480  1.0
  Bi  Bi4  1  0.091  0.756  0.534  1.0
  Bi  Bi5  1  0.307  0.384  0.213  1.0
  O  O6  1  0.742  0.498  0.456  1.0
  O  O7  1  0.249  0.490  0.519  1.0
  O  O8  1  0.842  0.307  0.783  1.0
  O  O9  1  0.166  0.687  0.219  1.0
  O  O10  1  0.434  0.105  0.299  1.0
  O  O11  1  0.551  0.903  0.693  1.0
  O  O12  1  0.870  0.196  0.124  1.0
  O  O13  1  0.144  0.799  0.873  1.0
  O  O14  1  0.628  0.770  0.169  1.0
  O  O15  1  0.369  0.233  0.836  1.0
[/CIF]
.