The material structure described by Ag2ZnC4(NS)4 crystallizes in the monoclinic Cc space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to one S(1), one S(4), and two equivalent S(3) atoms to form corner-sharing AgS4 tetrahedra. In the second Ag site, Ag(2) is bonded to one S(1), one S(4), and two equivalent S(2) atoms to form corner-sharing AgS4 tetrahedra. Zn(1) is bonded in a tetrahedral geometry to one N(1), one N(2), one N(3), and one N(4) atom. There are four inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one N(3) and one S(4) atom. In the second C site, C(2) is bonded in a distorted linear geometry to one N(4) and one S(1) atom. In the third C site, C(3) is bonded in a distorted linear geometry to one N(1) and one S(2) atom. In the fourth C site, C(4) is bonded in a distorted linear geometry to one N(2) and one S(3) atom. There are four inequivalent N sites. In the first N site, N(1) is bonded in a bent 150 degrees geometry to one Zn(1) and one C(3) atom. In the second N site, N(2) is bonded in a bent 150 degrees geometry to one Zn(1) and one C(4) atom. In the third N site, N(3) is bonded in a linear geometry to one Zn(1) and one C(1) atom. In the fourth N site, N(4) is bonded in a linear geometry to one Zn(1) and one C(2) atom. There are four inequivalent S sites. In the first S site, S(4) is bonded in a trigonal non-coplanar geometry to one Ag(1), one Ag(2), and one C(1) atom. In the second S site, S(1) is bonded in a trigonal non-coplanar geometry to one Ag(1), one Ag(2), and one C(2) atom. In the third S site, S(2) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Ag(2) and one C(3) atom. In the fourth S site, S(3) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Ag(1) and one C(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_ZnAg2C4(SN)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.705
_cell_length_b   10.705
_cell_length_c   7.938
_cell_angle_alpha   83.969
_cell_angle_beta   83.969
_cell_angle_gamma   42.747
_symmetry_Int_Tables_number   1
_cell_volume   613.453
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.869  0.541  0.487  1.0
  Zn  Zn1  1  0.541  0.869  0.987  1.0
  Ag  Ag2  1  0.311  0.508  0.973  1.0
  Ag  Ag3  1  0.092  0.908  0.500  1.0
  Ag  Ag4  1  0.508  0.311  0.473  1.0
  Ag  Ag5  1  0.908  0.092  0.000  1.0
  C  C6  1  0.612  0.542  0.904  1.0
  C  C7  1  0.866  0.796  0.085  1.0
  C  C8  1  0.796  0.866  0.585  1.0
  C  C9  1  0.185  0.061  0.203  1.0
  C  C10  1  0.061  0.185  0.703  1.0
  C  C11  1  0.341  0.231  0.777  1.0
  C  C12  1  0.542  0.612  0.404  1.0
  C  C13  1  0.231  0.341  0.277  1.0
  S  S14  1  0.015  0.793  0.128  1.0
  S  S15  1  0.168  0.976  0.766  1.0
  S  S16  1  0.237  0.439  0.713  1.0
  S  S17  1  0.439  0.237  0.213  1.0
  S  S18  1  0.396  0.612  0.355  1.0
  S  S19  1  0.612  0.396  0.855  1.0
  S  S20  1  0.793  0.015  0.628  1.0
  S  S21  1  0.976  0.168  0.266  1.0
  N  N22  1  0.335  0.983  0.158  1.0
  N  N23  1  0.418  0.080  0.819  1.0
  N  N24  1  0.647  0.613  0.431  1.0
  N  N25  1  0.983  0.335  0.658  1.0
  N  N26  1  0.800  0.757  0.560  1.0
  N  N27  1  0.080  0.418  0.319  1.0
  N  N28  1  0.613  0.647  0.931  1.0
  N  N29  1  0.757  0.800  0.060  1.0
[/CIF]
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The material structure described by Ag2ZnC4(NS)4 crystallizes in the monoclinic Cc space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to one S(1), one S(4), and two equivalent S(3) atoms to form corner-sharing AgS4 tetrahedra. In the second Ag site, Ag(2) is bonded to one S(1), one S(4), and two equivalent S(2) atoms to form corner-sharing AgS4 tetrahedra. Zn(1) is bonded in a tetrahedral geometry to one N(1), one N(2), one N(3), and one N(4) atom. There are four inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one N(3) and one S(4) atom. In the second C site, C(2) is bonded in a distorted linear geometry to one N(4) and one S(1) atom. In the third C site, C(3) is bonded in a distorted linear geometry to one N(1) and one S(2) atom. In the fourth C site, C(4) is bonded in a distorted linear geometry to one N(2) and one S(3) atom. There are four inequivalent N sites. In the first N site, N(1) is bonded in a bent 150 degrees geometry to one Zn(1) and one C(3) atom. In the second N site, N(2) is bonded in a bent 150 degrees geometry to one Zn(1) and one C(4) atom. In the third N site, N(3) is bonded in a linear geometry to one Zn(1) and one C(1) atom. In the fourth N site, N(4) is bonded in a linear geometry to one Zn(1) and one C(2) atom. There are four inequivalent S sites. In the first S site, S(4) is bonded in a trigonal non-coplanar geometry to one Ag(1), one Ag(2), and one C(1) atom. In the second S site, S(1) is bonded in a trigonal non-coplanar geometry to one Ag(1), one Ag(2), and one C(2) atom. In the third S site, S(2) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Ag(2) and one C(3) atom. In the fourth S site, S(3) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Ag(1) and one C(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_ZnAg2C4(SN)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.705
_cell_length_b   10.705
_cell_length_c   7.938
_cell_angle_alpha   83.969
_cell_angle_beta   83.969
_cell_angle_gamma   42.747
_symmetry_Int_Tables_number   1
_cell_volume   613.453
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.869  0.541  0.487  1.0
  Zn  Zn1  1  0.541  0.869  0.987  1.0
  Ag  Ag2  1  0.311  0.508  0.973  1.0
  Ag  Ag3  1  0.092  0.908  0.500  1.0
  Ag  Ag4  1  0.508  0.311  0.473  1.0
  Ag  Ag5  1  0.908  0.092  0.000  1.0
  C  C6  1  0.612  0.542  0.904  1.0
  C  C7  1  0.866  0.796  0.085  1.0
  C  C8  1  0.796  0.866  0.585  1.0
  C  C9  1  0.185  0.061  0.203  1.0
  C  C10  1  0.061  0.185  0.703  1.0
  C  C11  1  0.341  0.231  0.777  1.0
  C  C12  1  0.542  0.612  0.404  1.0
  C  C13  1  0.231  0.341  0.277  1.0
  S  S14  1  0.015  0.793  0.128  1.0
  S  S15  1  0.168  0.976  0.766  1.0
  S  S16  1  0.237  0.439  0.713  1.0
  S  S17  1  0.439  0.237  0.213  1.0
  S  S18  1  0.396  0.612  0.355  1.0
  S  S19  1  0.612  0.396  0.855  1.0
  S  S20  1  0.793  0.015  0.628  1.0
  S  S21  1  0.976  0.168  0.266  1.0
  N  N22  1  0.335  0.983  0.158  1.0
  N  N23  1  0.418  0.080  0.819  1.0
  N  N24  1  0.647  0.613  0.431  1.0
  N  N25  1  0.983  0.335  0.658  1.0
  N  N26  1  0.800  0.757  0.560  1.0
  N  N27  1  0.080  0.418  0.319  1.0
  N  N28  1  0.613  0.647  0.931  1.0
  N  N29  1  0.757  0.800  0.060  1.0
[/CIF]
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