The crystal structure described by Sr3Pr3Mn2Cu2O13 crystallizes in the orthorhombic Amm2 space group. There are three inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 9-coordinate geometry to one O(1), two equivalent O(3), two equivalent O(4), and four equivalent O(6) atoms. In the second Sr site, Sr(2) is bonded in a distorted q6 geometry to two equivalent O(7), four equivalent O(5), and four equivalent O(6) atoms. In the third Sr site, Sr(3) is bonded in a distorted q6 geometry to two equivalent O(7), four equivalent O(5), and four equivalent O(6) atoms. There are three inequivalent Pr sites. In the first Pr site, Pr(1) is bonded in a 9-coordinate geometry to one O(2), two equivalent O(3), two equivalent O(4), and four equivalent O(6) atoms. In the second Pr site, Pr(2) is bonded in a 9-coordinate geometry to one O(4), two equivalent O(1), two equivalent O(2), and four equivalent O(5) atoms. In the third Pr site, Pr(3) is bonded in a 9-coordinate geometry to one O(3), two equivalent O(1), two equivalent O(2), and four equivalent O(5) atoms. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(7), and four equivalent O(5) atoms to form MnO6 octahedra that share  a cornercorner with one Mn(2)O6 octahedra and corners with four equivalent Cu(1)O5 square pyramids. The corner-sharing octahedra are not tilted. In the second Mn site, Mn(2) is bonded to one O(4), one O(7), and four equivalent O(6) atoms to form MnO6 octahedra that share  a cornercorner with one Mn(1)O6 octahedra and corners with four equivalent Cu(2)O5 square pyramids. The corner-sharing octahedra are not tilted. There are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to one O(2) and four equivalent O(5) atoms to form CuO5 square pyramids that share corners with four equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles are 3°. In the second Cu site, Cu(2) is bonded to one O(3) and four equivalent O(6) atoms to form CuO5 square pyramids that share corners with four equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles are 3°. There are seven inequivalent O sites. In the first O site, O(7) is bonded in a distorted linear geometry to two equivalent Sr(2), two equivalent Sr(3), one Mn(1), and one Mn(2) atom. In the second O site, O(1) is bonded to one Sr(1), two equivalent Pr(2), two equivalent Pr(3), and one Mn(1) atom to form distorted OSrPr4Mn octahedra that share corners with four equivalent O(6)Sr3PrMnCu octahedra, corners with four equivalent O(1)SrPr4Mn octahedra, corners with eight equivalent O(5)Sr2Pr2MnCu octahedra, edges with two equivalent O(4)Sr2Pr3Mn octahedra, and faces with four equivalent O(5)Sr2Pr2MnCu octahedra. The corner-sharing octahedral tilt angles range from 11-53°. In the third O site, O(2) is bonded in a 6-coordinate geometry to one Pr(1), two equivalent Pr(2), two equivalent Pr(3), and one Cu(1) atom. In the fourth O site, O(3) is bonded in a 6-coordinate geometry to two equivalent Sr(1), one Pr(3), two equivalent Pr(1), and one Cu(2) atom. In the fifth O site, O(4) is bonded to two equivalent Sr(1), one Pr(2), two equivalent Pr(1), and one Mn(2) atom to form distorted OSr2Pr3Mn octahedra that share corners with four equivalent O(5)Sr2Pr2MnCu octahedra, corners with four equivalent O(4)Sr2Pr3Mn octahedra, corners with eight equivalent O(6)Sr3PrMnCu octahedra, edges with two equivalent O(1)SrPr4Mn octahedra, and faces with four equivalent O(6)Sr3PrMnCu octahedra. The corner-sharing octahedral tilt angles range from 13-53°. In the sixth O site, O(5) is bonded to one Sr(2), one Sr(3), one Pr(2), one Pr(3), one Mn(1), and one Cu(1) atom to form distorted OSr2Pr2MnCu octahedra that share  a cornercorner with one O(4)Sr2Pr3Mn octahedra, corners with two equivalent O(5)Sr2Pr2MnCu octahedra, corners with two equivalent O(1)SrPr4Mn octahedra, corners with six equivalent O(6)Sr3PrMnCu octahedra,  an edgeedge with one O(6)Sr3PrMnCu octahedra, edges with two equivalent O(5)Sr2Pr2MnCu octahedra,  a faceface with one O(1)SrPr4Mn octahedra, and faces with four equivalent O(5)Sr2Pr2MnCu octahedra. The corner-sharing octahedral tilt angles range from 1-61°. In the seventh O site, O(6) is bonded to one Sr(1), one Sr(2), one Sr(3), one Pr(1), one Mn(2), and one Cu(2) atom to form distorted OSr3PrMnCu octahedra that share  a cornercorner with one O(1)SrPr4Mn octahedra, corners with two equivalent O(4)Sr2Pr3Mn octahedra, corners with two equivalent O(6)Sr3PrMnCu octahedra, corners with six equivalent O(5)Sr2Pr2MnCu octahedra,  an edgeedge with one O(5)Sr2Pr2MnCu octahedra, edges with two equivalent O(6)Sr3PrMnCu octahedra,  a faceface with one O(4)Sr2Pr3Mn octahedra, and faces with four equivalent O(6)Sr3PrMnCu octahedra. The corner-sharing octahedral tilt angles range from 1-61°. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sr3Pr3Mn2Cu2O13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.337
_cell_length_b   10.337
_cell_length_c   5.433
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   149.530
_symmetry_Int_Tables_number   1
_cell_volume   294.387
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.681  0.319  0.000  1.0
  Sr  Sr1  1  0.001  0.999  0.500  1.0
  Sr  Sr2  1  0.503  0.497  0.000  1.0
  Pr  Pr3  1  0.177  0.823  0.500  1.0
  Pr  Pr4  1  0.321  0.679  0.000  1.0
  Pr  Pr5  1  0.821  0.179  0.500  1.0
  Mn  Mn6  1  0.906  0.094  0.000  1.0
  Mn  Mn7  1  0.094  0.906  0.000  1.0
  Cu  Cu8  1  0.405  0.595  0.500  1.0
  Cu  Cu9  1  0.598  0.402  0.500  1.0
  O  O10  1  0.807  0.193  0.000  1.0
  O  O11  1  0.293  0.707  0.500  1.0
  O  O12  1  0.708  0.292  0.500  1.0
  O  O13  1  0.197  0.803  0.000  1.0
  O  O14  1  0.152  0.346  0.244  1.0
  O  O15  1  0.654  0.848  0.756  1.0
  O  O16  1  0.654  0.848  0.244  1.0
  O  O17  1  0.152  0.346  0.756  1.0
  O  O18  1  0.337  0.150  0.250  1.0
  O  O19  1  0.850  0.663  0.750  1.0
  O  O20  1  0.850  0.663  0.250  1.0
  O  O21  1  0.337  0.150  0.750  1.0
  O  O22  1  1.000  0.000  0.000  1.0
[/CIF]
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The crystal structure described by Sr3Pr3Mn2Cu2O13 crystallizes in the orthorhombic Amm2 space group. There are three inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 9-coordinate geometry to one O(1), two equivalent O(3), two equivalent O(4), and four equivalent O(6) atoms. In the second Sr site, Sr(2) is bonded in a distorted q6 geometry to two equivalent O(7), four equivalent O(5), and four equivalent O(6) atoms. In the third Sr site, Sr(3) is bonded in a distorted q6 geometry to two equivalent O(7), four equivalent O(5), and four equivalent O(6) atoms. There are three inequivalent Pr sites. In the first Pr site, Pr(1) is bonded in a 9-coordinate geometry to one O(2), two equivalent O(3), two equivalent O(4), and four equivalent O(6) atoms. In the second Pr site, Pr(2) is bonded in a 9-coordinate geometry to one O(4), two equivalent O(1), two equivalent O(2), and four equivalent O(5) atoms. In the third Pr site, Pr(3) is bonded in a 9-coordinate geometry to one O(3), two equivalent O(1), two equivalent O(2), and four equivalent O(5) atoms. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(7), and four equivalent O(5) atoms to form MnO6 octahedra that share  a cornercorner with one Mn(2)O6 octahedra and corners with four equivalent Cu(1)O5 square pyramids. The corner-sharing octahedra are not tilted. In the second Mn site, Mn(2) is bonded to one O(4), one O(7), and four equivalent O(6) atoms to form MnO6 octahedra that share  a cornercorner with one Mn(1)O6 octahedra and corners with four equivalent Cu(2)O5 square pyramids. The corner-sharing octahedra are not tilted. There are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to one O(2) and four equivalent O(5) atoms to form CuO5 square pyramids that share corners with four equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles are 3°. In the second Cu site, Cu(2) is bonded to one O(3) and four equivalent O(6) atoms to form CuO5 square pyramids that share corners with four equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles are 3°. There are seven inequivalent O sites. In the first O site, O(7) is bonded in a distorted linear geometry to two equivalent Sr(2), two equivalent Sr(3), one Mn(1), and one Mn(2) atom. In the second O site, O(1) is bonded to one Sr(1), two equivalent Pr(2), two equivalent Pr(3), and one Mn(1) atom to form distorted OSrPr4Mn octahedra that share corners with four equivalent O(6)Sr3PrMnCu octahedra, corners with four equivalent O(1)SrPr4Mn octahedra, corners with eight equivalent O(5)Sr2Pr2MnCu octahedra, edges with two equivalent O(4)Sr2Pr3Mn octahedra, and faces with four equivalent O(5)Sr2Pr2MnCu octahedra. The corner-sharing octahedral tilt angles range from 11-53°. In the third O site, O(2) is bonded in a 6-coordinate geometry to one Pr(1), two equivalent Pr(2), two equivalent Pr(3), and one Cu(1) atom. In the fourth O site, O(3) is bonded in a 6-coordinate geometry to two equivalent Sr(1), one Pr(3), two equivalent Pr(1), and one Cu(2) atom. In the fifth O site, O(4) is bonded to two equivalent Sr(1), one Pr(2), two equivalent Pr(1), and one Mn(2) atom to form distorted OSr2Pr3Mn octahedra that share corners with four equivalent O(5)Sr2Pr2MnCu octahedra, corners with four equivalent O(4)Sr2Pr3Mn octahedra, corners with eight equivalent O(6)Sr3PrMnCu octahedra, edges with two equivalent O(1)SrPr4Mn octahedra, and faces with four equivalent O(6)Sr3PrMnCu octahedra. The corner-sharing octahedral tilt angles range from 13-53°. In the sixth O site, O(5) is bonded to one Sr(2), one Sr(3), one Pr(2), one Pr(3), one Mn(1), and one Cu(1) atom to form distorted OSr2Pr2MnCu octahedra that share  a cornercorner with one O(4)Sr2Pr3Mn octahedra, corners with two equivalent O(5)Sr2Pr2MnCu octahedra, corners with two equivalent O(1)SrPr4Mn octahedra, corners with six equivalent O(6)Sr3PrMnCu octahedra,  an edgeedge with one O(6)Sr3PrMnCu octahedra, edges with two equivalent O(5)Sr2Pr2MnCu octahedra,  a faceface with one O(1)SrPr4Mn octahedra, and faces with four equivalent O(5)Sr2Pr2MnCu octahedra. The corner-sharing octahedral tilt angles range from 1-61°. In the seventh O site, O(6) is bonded to one Sr(1), one Sr(2), one Sr(3), one Pr(1), one Mn(2), and one Cu(2) atom to form distorted OSr3PrMnCu octahedra that share  a cornercorner with one O(1)SrPr4Mn octahedra, corners with two equivalent O(4)Sr2Pr3Mn octahedra, corners with two equivalent O(6)Sr3PrMnCu octahedra, corners with six equivalent O(5)Sr2Pr2MnCu octahedra,  an edgeedge with one O(5)Sr2Pr2MnCu octahedra, edges with two equivalent O(6)Sr3PrMnCu octahedra,  a faceface with one O(4)Sr2Pr3Mn octahedra, and faces with four equivalent O(6)Sr3PrMnCu octahedra. The corner-sharing octahedral tilt angles range from 1-61°. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sr3Pr3Mn2Cu2O13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.337
_cell_length_b   10.337
_cell_length_c   5.433
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   149.530
_symmetry_Int_Tables_number   1
_cell_volume   294.387
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.681  0.319  0.000  1.0
  Sr  Sr1  1  0.001  0.999  0.500  1.0
  Sr  Sr2  1  0.503  0.497  0.000  1.0
  Pr  Pr3  1  0.177  0.823  0.500  1.0
  Pr  Pr4  1  0.321  0.679  0.000  1.0
  Pr  Pr5  1  0.821  0.179  0.500  1.0
  Mn  Mn6  1  0.906  0.094  0.000  1.0
  Mn  Mn7  1  0.094  0.906  0.000  1.0
  Cu  Cu8  1  0.405  0.595  0.500  1.0
  Cu  Cu9  1  0.598  0.402  0.500  1.0
  O  O10  1  0.807  0.193  0.000  1.0
  O  O11  1  0.293  0.707  0.500  1.0
  O  O12  1  0.708  0.292  0.500  1.0
  O  O13  1  0.197  0.803  0.000  1.0
  O  O14  1  0.152  0.346  0.244  1.0
  O  O15  1  0.654  0.848  0.756  1.0
  O  O16  1  0.654  0.848  0.244  1.0
  O  O17  1  0.152  0.346  0.756  1.0
  O  O18  1  0.337  0.150  0.250  1.0
  O  O19  1  0.850  0.663  0.750  1.0
  O  O20  1  0.850  0.663  0.250  1.0
  O  O21  1  0.337  0.150  0.750  1.0
  O  O22  1  1.000  0.000  0.000  1.0
[/CIF]
.