The compound described by Li5Co3(SbO5)2 is Caswellsilverite-derived structured and crystallizes in the triclinic P1 space group. There are ten inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(13), one O(15), one O(17), one O(19), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra, corners with two equivalent Co(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra,  an edgeedge with one Sb(3)O6 octahedra, and  an edgeedge with one Sb(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-11°. In the second Li site, Li(2) is bonded to one O(10), one O(12), one O(14), one O(16), one O(18), and one O(20) atom to form LiO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  a cornercorner with one Li(9)O6 octahedra, corners with two equivalent Co(4)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra,  an edgeedge with one Sb(3)O6 octahedra, and  an edgeedge with one Sb(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-12°. In the third Li site, Li(3) is bonded to one O(10), one O(12), one O(13), one O(17), one O(20), and one O(4) atom to form LiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Sb(2)O6 octahedra,  a cornercorner with one Sb(4)O6 octahedra, corners with two equivalent Co(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra,  an edgeedge with one Sb(3)O6 octahedra, and  an edgeedge with one Sb(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-15°. In the fourth Li site, Li(4) is bonded to one O(11), one O(14), one O(18), one O(19), one O(3), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one Sb(1)O6 octahedra,  a cornercorner with one Sb(3)O6 octahedra, corners with two equivalent Co(5)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra,  an edgeedge with one Sb(3)O6 octahedra, and  an edgeedge with one Sb(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-15°. In the fifth Li site, Li(5) is bonded to one O(10), one O(12), one O(15), one O(18), one O(19), and one O(2) atom to form LiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Sb(2)O6 octahedra,  a cornercorner with one Sb(4)O6 octahedra, corners with two equivalent Co(3)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra, and  an edgeedge with one Sb(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-15°. In the sixth Li site, Li(6) is bonded to one O(1), one O(11), one O(16), one O(17), one O(20), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Sb(1)O6 octahedra,  a cornercorner with one Sb(3)O6 octahedra, corners with two equivalent Co(6)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra, and  an edgeedge with one Sb(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-14°. In the seventh Li site, Li(7) is bonded to one O(1), one O(15), one O(18), one O(5), one O(8), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Sb(2)O6 octahedra, corners with two equivalent Sb(4)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra, and  an edgeedge with one Sb(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-8°. In the eighth Li site, Li(8) is bonded to one O(10), one O(16), one O(17), one O(2), one O(6), and one O(7) atom to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one Sb(1)O6 octahedra, corners with two equivalent Sb(3)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra, and  an edgeedge with one Sb(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-8°. In the ninth Li site, Li(9) is bonded to one O(11), one O(13), one O(20), one O(3), one O(6), and one O(7) atom to form LiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Sb(4)O6 octahedra, corners with two equivalent Sb(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Sb(3)O6 octahedra, and  an edgeedge with one Sb(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-8°. In the tenth Li site, Li(10) is bonded to one O(12), one O(14), one O(19), one O(4), one O(5), and one O(8) atom to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one Sb(3)O6 octahedra, corners with two equivalent Sb(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Sb(3)O6 octahedra, and  an edgeedge with one Sb(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-8°. There are six inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(13), one O(15), one O(2), one O(4), one O(6), and one O(8) atom to form CoO6 octahedra that share  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one Sb(1)O6 octahedra,  a cornercorner with one Sb(3)O6 octahedra, corners with two equivalent Li(1)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra, and  an edgeedge with one Sb(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-11°. In the second Co site, Co(2) is bonded to one O(1), one O(15), one O(17), one O(4), one O(5), and one O(7) atom to form CoO6 octahedra that share  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  a cornercorner with one Li(9)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra, corners with two equivalent Li(3)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra, and  an edgeedge with one Sb(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-15°. In the third Co site, Co(3) is bonded to one O(13), one O(19), one O(2), one O(3), one O(5), and one O(7) atom to form CoO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  a cornercorner with one Li(9)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra, corners with two equivalent Li(5)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra,  an edgeedge with one Sb(3)O6 octahedra, and  an edgeedge with one Sb(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-15°. In the fourth Co site, Co(4) is bonded to one O(1), one O(14), one O(16), one O(3), one O(5), and one O(7) atom to form CoO6 octahedra that share  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Sb(2)O6 octahedra,  a cornercorner with one Sb(4)O6 octahedra, corners with two equivalent Li(2)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra, and  an edgeedge with one Sb(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-12°. In the fifth Co site, Co(5) is bonded to one O(16), one O(18), one O(2), one O(3), one O(6), and one O(8) atom to form CoO6 octahedra that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra, corners with two equivalent Li(4)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra, and  an edgeedge with one Sb(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-14°. In the sixth Co site, Co(6) is bonded to one O(1), one O(14), one O(20), one O(4), one O(6), and one O(8) atom to form CoO6 octahedra that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra, corners with two equivalent Li(6)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra,  an edgeedge with one Sb(3)O6 octahedra, and  an edgeedge with one Sb(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-15°. There are four inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(12), one O(16), one O(17), one O(2), one O(5), and one O(9) atom to form SbO6 octahedra that share  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra, corners with two equivalent Li(10)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra, and  an edgeedge with one Sb(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-7°. In the second Sb site, Sb(2) is bonded to one O(1), one O(10), one O(11), one O(15), one O(18), and one O(6) atom to form SbO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra, corners with two equivalent Li(9)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra, and  an edgeedge with one Sb(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-7°. In the third Sb site, Sb(3) is bonded to one O(10), one O(11), one O(14), one O(19), one O(4), and one O(7) atom to form SbO6 octahedra that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra, corners with two equivalent Li(8)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra, and  an edgeedge with one Sb(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-7°. In the fourth Sb site, Sb(4) is bonded to one O(12), one O(13), one O(20), one O(3), one O(8), and one O(9) atom to form SbO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(9)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra, corners with two equivalent Li(7)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra, and  an edgeedge with one Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-7°. There are twenty inequivalent O sites. In the first O site, O(1) is bonded to one Li(6), one Li(7), one Co(2), one Co(4), one Co(6), and one Sb(2) atom to form OLi2Co3Sb octahedra that share  a cornercorner with one O(3)Li2Co3Sb octahedra,  a cornercorner with one O(5)Li2Co3Sb octahedra,  a cornercorner with one O(15)Li3Co2Sb octahedra,  a cornercorner with one O(10)Li4Sb2 octahedra, corners with two equivalent O(20)Li4CoSb octahedra,  an edgeedge with one O(4)Li2Co3Sb octahedra,  an edgeedge with one O(5)Li2Co3Sb octahedra,  an edgeedge with one O(6)Li2Co3Sb octahedra,  an edgeedge with one O(7)Li2Co3Sb octahedra,  an edgeedge with one O(8)Li2Co3Sb octahedra,  an edgeedge with one O(14)Li3Co2Sb octahedra,  an edgeedge with one O(15)Li3Co2Sb octahedra,  an edgeedge with one O(16)Li3Co2Sb octahedra,  an edgeedge with one O(17)Li4CoSb octahedra,  an edgeedge with one O(18)Li4CoSb octahedra,  an edgeedge with one O(11)Li4Sb2 octahedra, and  an edgeedge with one O(9)Li4Sb2 octahedra. The corner-sharing octahedral tilt angles range from 4-14°. In the second O site, O(2) is bonded to one Li(5), one Li(8), one Co(1), one Co(3), one Co(5), and one Sb(1) atom to form OLi2Co3Sb octahedra that share  a cornercorner with one O(4)Li2Co3Sb octahedra,  a cornercorner with one O(6)Li2Co3Sb octahedra,  a cornercorner with one O(16)Li3Co2Sb octahedra,  a cornercorner with one O(9)Li4Sb2 octahedra, corners with two equivalent O(19)Li4CoSb octahedra,  an edgeedge with one O(3)Li2Co3Sb octahedra,  an edgeedge with one O(5)Li2Co3Sb octahedra,  an edgeedge with one O(6)Li2Co3Sb octahedra,  an edgeedge with one O(7)Li2Co3Sb octahedra,  an edgeedge with one O(8)Li2Co3Sb octahedra,  an edgeedge with one O(13)Li3Co2Sb octahedra,  an edgeedge with one O(15)Li3Co2Sb octahedra,  an edgeedge with one O(16)Li3Co2Sb octahedra,  an edgeedge with one O(17)Li4CoSb octahedra,  an edgeedge with one O(18)Li4CoSb octahedra,  an edgeedge with one O(10)Li4Sb2 octahedra, and  an edgeedge with one O(12)Li4Sb2 octahedra. The corner-sharing octahedral tilt angles range from 2-15°. In the third O site, O(3) is bonded to one Li(4), one Li(9), one Co(3), one Co(4), one Co(5), and one Sb(4) atom to form OLi2Co3Sb octahedra that share  a cornercorner with one O(1)Li2Co3Sb octahedra,  a cornercorner with one O(7)Li2Co3Sb octahedra,  a cornercorner with one O(13)Li3Co2Sb octahedra,  a cornercorner with one O(12)Li4Sb2 octahedra, corners with two equivalent O(18)Li4CoSb octahedra,  an edgeedge with one O(2)Li2Co3Sb octahedra,  an edgeedge with one O(5)Li2Co3Sb octahedra,  an edgeedge with one O(6)Li2Co3Sb octahedra,  an edgeedge with one O(7)Li2Co3Sb octahedra,  an edgeedge with one O(8)Li2Co3Sb octahedra,  an edgeedge with one O(13)Li3Co2Sb octahedra,  an edgeedge with one O(14)Li3Co2Sb octahedra,  an edgeedge with one O(16)Li3Co2Sb octahedra,  an edgeedge with one O(19)Li4CoSb octahedra,  an edgeedge with one O(20)Li4CoSb octahedra,  an edgeedge with one O(11)Li4Sb2 octahedra, and  an edgeedge with one O(9)Li4Sb2 octahedra. The corner-sharing octahedral tilt angles range from 4-15°. In the fourth O site, O(4) is bonded to one Li(10), one Li(3), one Co(1), one Co(2), one Co(6), and one Sb(3) atom to form OLi2Co3Sb octahedra that share  a cornercorner with one O(2)Li2Co3Sb octahedra,  a cornercorner with one O(8)Li2Co3Sb octahedra,  a cornercorner with one O(14)Li3Co2Sb octahedra,  a cornercorner with one O(11)Li4Sb2 octahedra, corners with two equivalent O(17)Li4CoSb octahedra,  an edgeedge with one O(1)Li2Co3Sb octahedra,  an edgeedge with one O(5)Li2Co3Sb octahedra,  an edgeedge with one O(6)Li2Co3Sb octahedra,  an edgeedge with one O(7)Li2Co3Sb octahedra,  an edgeedge with one O(8)Li2Co3Sb octahedra,  an edgeedge with one O(13)Li3Co2Sb octahedra,  an edgeedge with one O(14)Li3Co2Sb octahedra,  an edgeedge with one O(15)Li3Co2Sb octahedra,  an edgeedge with one O(19)Li4CoSb octahedra,  an edgeedge with one O(20)Li4CoSb octahedra,  an edgeedge with one O(10)Li4Sb2 octahedra, and  an edgeedge with one O(12)Li4Sb2 octahedra. The corner-sharing octahedral tilt angles range from 2-16°. In the fifth O site, O(5) is bonded to one Li(10), one Li(7), one Co(2), one Co(3), one Co(4), and one Sb(1) atom to form OLi2Co3Sb octahedra that share  a cornercorner with one O(1)Li2Co3Sb octahedra,  a cornercorner with one O(7)Li2Co3Sb octahedra,  a cornercorner with one O(13)Li3Co2Sb octahedra,  a cornercorner with one O(18)Li4CoSb octahedra, corners with two equivalent O(12)Li4Sb2 octahedra,  an edgeedge with one O(1)Li2Co3Sb octahedra,  an edgeedge with one O(2)Li2Co3Sb octahedra,  an edgeedge with one O(3)Li2Co3Sb octahedra,  an edgeedge with one O(4)Li2Co3Sb octahedra,  an edgeedge with one O(7)Li2Co3Sb octahedra,  an edgeedge with one O(8)Li2Co3Sb octahedra,  an edgeedge with one O(14)Li3Co2Sb octahedra,  an edgeedge with one O(15)Li3Co2Sb octahedra,  an edgeedge with one O(16)Li3Co2Sb octahedra,  an edgeedge with one O(17)Li4CoSb octahedra,  an edgeedge with one O(19)Li4CoSb octahedra, and  an edgeedge with one O(9)Li4Sb2 octahedra. The corner-sharing octahedral tilt angles range from 4-8°. In the sixth O site, O(6) is bonded to one Li(8), one Li(9), one Co(1), one Co(5), one Co(6), and one Sb(2) atom to form OLi2Co3Sb octahedra that share  a cornercorner with one O(2)Li2Co3Sb octahedra,  a cornercorner with one O(8)Li2Co3Sb octahedra,  a cornercorner with one O(14)Li3Co2Sb octahedra,  a cornercorner with one O(17)Li4CoSb octahedra, corners with two equivalent O(11)Li4Sb2 octahedra,  an edgeedge with one O(1)Li2Co3Sb octahedra,  an edgeedge with one O(2)Li2Co3Sb octahedra,  an edgeedge with one O(3)Li2Co3Sb octahedra,  an edgeedge with one O(4)Li2Co3Sb octahedra,  an edgeedge with one O(7)Li2Co3Sb octahedra,  an edgeedge with one O(8)Li2Co3Sb octahedra,  an edgeedge with one O(13)Li3Co2Sb octahedra,  an edgeedge with one O(15)Li3Co2Sb octahedra,  an edgeedge with one O(16)Li3Co2Sb octahedra,  an edgeedge with one O(18)Li4CoSb octahedra,  an edgeedge with one O(20)Li4CoSb octahedra, and  an edgeedge with one O(10)Li4Sb2 octahedra. The corner-sharing octahedral tilt angles range from 1-9°. In the seventh O site, O(7) is bonded to one Li(8), one Li(9), one Co(2), one Co(3), one Co(4), and one Sb(3) atom to form OLi2Co3Sb octahedra that share  a cornercorner with one O(3)Li2Co3Sb octahedra,  a cornercorner with one O(5)Li2Co3Sb octahedra,  a cornercorner with one O(15)Li3Co2Sb octahedra,  a cornercorner with one O(20)Li4CoSb octahedra, corners with two equivalent O(10)Li4Sb2 octahedra,  an edgeedge with one O(1)Li2Co3Sb octahedra,  an edgeedge with one O(2)Li2Co3Sb octahedra,  an edgeedge with one O(3)Li2Co3Sb octahedra,  an edgeedge with one O(4)Li2Co3Sb octahedra,  an edgeedge with one O(5)Li2Co3Sb octahedra,  an edgeedge with one O(6)Li2Co3Sb octahedra,  an edgeedge with one O(13)Li3Co2Sb octahedra,  an edgeedge with one O(14)Li3Co2Sb octahedra,  an edgeedge with one O(16)Li3Co2Sb octahedra,  an edgeedge with one O(17)Li4CoSb octahedra,  an edgeedge with one O(19)Li4CoSb octahedra, and  an edgeedge with one O(11)Li4Sb2 octahedra. The corner-sharing octahedral tilt angles range from 4-8°. In the eighth O site, O(8) is bonded to one Li(10), one Li(7), one Co(1), one Co(5), one Co(6), and one Sb(4) atom to form OLi2Co3Sb octahedra that share  a cornercorner with one O(4)Li2Co3Sb octahedra,  a cornercorner with one O(6)Li2Co3Sb octahedra,  a cornercorner with one O(16)Li3Co2Sb octahedra,  a cornercorner with one O(19)Li4CoSb octahedra, corners with two equivalent O(9)Li4Sb2 octahedra,  an edgeedge with one O(1)Li2Co3Sb octahedra,  an edgeedge with one O(2)Li2Co3Sb octahedra,  an edgeedge with one O(3)Li2Co3Sb octahedra,  an edgeedge with one O(4)Li2Co3Sb octahedra,  an edgeedge with one O(5)Li2Co3Sb octahedra,  an edgeedge with one O(6)Li2Co3Sb octahedra,  an edgeedge with one O(13)Li3Co2Sb octahedra,  an edgeedge with one O(14)Li3Co2Sb octahedra,  an edgeedge with one O(15)Li3Co2Sb octahedra,  an edgeedge with one O(18)Li4CoSb octahedra,  an edgeedge with one O(20)Li4CoSb octahedra, and  an edgeedge with one O(12)Li4Sb2 octahedra. The corner-sharing octahedral tilt angles range from 1-8°. In the ninth O site, O(9) is bonded to one Li(1), one Li(4), one Li(6), one Li(7), one Sb(1), and one Sb(4) atom to form OLi4Sb2 octahedra that share  a cornercorner with one O(2)Li2Co3Sb octahedra,  a cornercorner with one O(14)Li3Co2Sb octahedra,  a cornercorner with one O(17)Li4CoSb octahedra,  a cornercorner with one O(11)Li4Sb2 octahedra, corners with two equivalent O(8)Li2Co3Sb octahedra,  an edgeedge with one O(1)Li2Co3Sb octahedra,  an edgeedge with one O(3)Li2Co3Sb octahedra,  an edgeedge with one O(5)Li2Co3Sb octahedra,  an edgeedge with one O(13)Li3Co2Sb octahedra,  an edgeedge with one O(15)Li3Co2Sb octahedra,  an edgeedge with one O(16)Li3Co2Sb octahedra,  an edgeedge with one O(17)Li4CoSb octahedra,  an edgeedge with one O(18)Li4CoSb octahedra,  an edgeedge with one O(19)Li4CoSb octahedra,  an edgeedge with one O(20)Li4CoSb octahedra,  an edgeedge with one O(11)Li4Sb2 octahedra, and  an edgeedge with one O(12)Li4Sb2 octahedra. The corner-sharing octahedral tilt angles range from 0-13°. In the tenth O site, O(10) is bonded to one Li(2), one Li(3), one Li(5), one Li(8), one Sb(2), and one Sb(3) atom to form OLi4Sb2 octahedra that share  a cornercorner with one O(1)Li2Co3Sb octahedra,  a cornercorner with one O(13)Li3Co2Sb octahedra,  a cornercorner with one O(18)Li4CoSb octahedra,  a cornercorner with one O(12)Li4Sb2 octahedra, corners with two equivalent O(7)Li2Co3Sb octahedra,  an edgeedge with one O(2)Li2Co3Sb octahedra,  an edgeedge with one O(4)Li2Co3Sb octahedra,  an edgeedge with one O(6)Li2Co3Sb octahedra,  an edgeedge with one O(14)Li3Co2Sb octahedra,  an edgeedge with one O(15)Li3Co2Sb octahedra,  an edgeedge with one O(16)Li3Co2Sb octahedra,  an edgeedge with one O(17)Li4CoSb octahedra,  an edgeedge with one O(18)Li4CoSb octahedra,  an edgeedge with one O(19)Li4CoSb octahedra,  an edgeedge with one O(20)Li4CoSb octahedra,  an edgeedge with one O(11)Li4Sb2 octahedra, and  an edgeedge with one O(12)Li4Sb2 octahedra. The corner-sharing octahedral tilt angles range from 1-14°. In the eleventh O site, O(11) is bonded to one Li(1), one Li(4), one Li(6), one Li(9), one Sb(2), and one Sb(3) atom to form OLi4Sb2 octahedra that share  a cornercorner with one O(4)Li2Co3Sb octahedra,  a cornercorner with one O(16)Li3Co2Sb octahedra,  a cornercorner with one O(19)Li4CoSb octahedra,  a cornercorner with one O(9)Li4Sb2 octahedra, corners with two equivalent O(6)Li2Co3Sb octahedra,  an edgeedge with one O(1)Li2Co3Sb octahedra,  an edgeedge with one O(3)Li2Co3Sb octahedra,  an edgeedge with one O(7)Li2Co3Sb octahedra,  an edgeedge with one O(13)Li3Co2Sb octahedra,  an edgeedge with one O(14)Li3Co2Sb octahedra,  an edgeedge with one O(15)Li3Co2Sb octahedra,  an edgeedge with one O(17)Li4CoSb octahedra,  an edgeedge with one O(18)Li4CoSb octahedra,  an edgeedge with one O(19)Li4CoSb octahedra,  an edgeedge with one O(20)Li4CoSb octahedra,  an edgeedge with one O(10)Li4Sb2 octahedra, and  an edgeedge with one O(9)Li4Sb2 octahedra. The corner-sharing octahedral tilt angles range from 0-13°. In the twelfth O site, O(12) is bonded to one Li(10), one Li(2), one Li(3), one Li(5), one Sb(1), and one Sb(4) atom to form OLi4Sb2 octahedra that share  a cornercorner with one O(3)Li2Co3Sb octahedra,  a cornercorner with one O(15)Li3Co2Sb octahedra,  a cornercorner with one O(20)Li4CoSb octahedra,  a cornercorner with one O(10)Li4Sb2 octahedra, corners with two equivalent O(5)Li2Co3Sb octahedra,  an edgeedge with one O(2)Li2Co3Sb octahedra,  an edgeedge with one O(4)Li2Co3Sb octahedra,  an edgeedge with one O(8)Li2Co3Sb octahedra,  an edgeedge with one O(13)Li3Co2Sb octahedra,  an edgeedge with one O(14)Li3Co2Sb octahedra,  an edgeedge with one O(16)Li3Co2Sb octahedra,  an edgeedge with one O(17)Li4CoSb octahedra,  an edgeedge with one O(18)Li4CoSb octahedra,  an edgeedge with one O(19)Li4CoSb octahedra,  an edgeedge with one O(20)Li4CoSb octahedra,  an edgeedge with one O(10)Li4Sb2 octahedra, and  an edgeedge with one O(9)Li4Sb2 octahedra. The corner-sharing octahedral tilt angles range from 1-13°. In the thirteenth O site, O(13) is bonded to one Li(1), one Li(3), one Li(9), one Co(1), one Co(3), and one Sb(4) atom to form OLi3Co2Sb octahedra that share  a cornercorner with one O(3)Li2Co3Sb octahedra,  a cornercorner with one O(5)Li2Co3Sb octahedra,  a cornercorner with one O(20)Li4CoSb octahedra,  a cornercorner with one O(10)Li4Sb2 octahedra, corners with two equivalent O(15)Li3Co2Sb octahedra,  an edgeedge with one O(2)Li2Co3Sb octahedra,  an edgeedge with one O(3)Li2Co3Sb octahedra,  an edgeedge with one O(4)Li2Co3Sb octahedra,  an edgeedge with one O(6)Li2Co3Sb octahedra,  an edgeedge with one O(7)Li2Co3Sb octahedra,  an edgeedge with one O(8)Li2Co3Sb octahedra,  an edgeedge with one O(17)Li4CoSb octahedra,  an edgeedge with one O(19)Li4CoSb octahedra,  an edgeedge with one O(20)Li4CoSb octahedra,  an edgeedge with one O(11)Li4Sb2 octahedra,  an edgeedge with one O(12)Li4Sb2 octahedra, and  an edgeedge with one O(9)Li4Sb2 octahedra. The corner-sharing octahedral tilt angles range from 0-14°. In the fourteenth O site, O(14) is bonded to one Li(10), one Li(2), one Li(4), one Co(4), one Co(6), and one Sb(3) atom to form OLi3Co2Sb octahedra that share  a cornercorner with one O(4)Li2Co3Sb octahedra,  a cornercorner with one O(6)Li2Co3Sb octahedra,  a cornercorner with one O(19)Li4CoSb octahedra,  a cornercorner with one O(9)Li4Sb2 octahedra, corners with two equivalent O(16)Li3Co2Sb octahedra,  an edgeedge with one O(1)Li2Co3Sb octahedra,  an edgeedge with one O(3)Li2Co3Sb octahedra,  an edgeedge with one O(4)Li2Co3Sb octahedra,  an edgeedge with one O(5)Li2Co3Sb octahedra,  an edgeedge with one O(7)Li2Co3Sb octahedra,  an edgeedge with one O(8)Li2Co3Sb octahedra,  an edgeedge with one O(18)Li4CoSb octahedra,  an edgeedge with one O(19)Li4CoSb octahedra,  an edgeedge with one O(20)Li4CoSb octahedra,  an edgeedge with one O(10)Li4Sb2 octahedra,  an edgeedge with one O(11)Li4Sb2 octahedra, and  an edgeedge with one O(12)Li4Sb2 octahedra. The corner-sharing octahedral tilt angles range from 1-13°. In the fifteenth O site, O(15) is bonded to one Li(1), one Li(5), one Li(7), one Co(1), one Co(2), and one Sb(2) atom to form OLi3Co2Sb octahedra that share  a cornercorner with one O(1)Li2Co3Sb octahedra,  a cornercorner with one O(7)Li2Co3Sb octahedra,  a cornercorner with one O(18)Li4CoSb octahedra,  a cornercorner with one O(12)Li4Sb2 octahedra, corners with two equivalent O(13)Li3Co2Sb octahedra,  an edgeedge with one O(1)Li2Co3Sb octahedra,  an edgeedge with one O(2)Li2Co3Sb octahedra,  an edgeedge with one O(4)Li2Co3Sb octahedra,  an edgeedge with one O(5)Li2Co3Sb octahedra,  an edgeedge with one O(6)Li2Co3Sb octahedra,  an edgeedge with one O(8)Li2Co3Sb octahedra,  an edgeedge with one O(17)Li4CoSb octahedra,  an edgeedge with one O(18)Li4CoSb octahedra,  an edgeedge with one O(19)Li4CoSb octahedra,  an edgeedge with one O(10)Li4Sb2 octahedra,  an edgeedge with one O(11)Li4Sb2 octahedra, and  an edgeedge with one O(9)Li4Sb2 octahedra. The corner-sharing octahedral tilt angles range from 0-13°. In the sixteenth O site, O(16) is bonded to one Li(2), one Li(6), one Li(8), one Co(4), one Co(5), and one Sb(1) atom to form OLi3Co2Sb octahedra that share  a cornercorner with one O(2)Li2Co3Sb octahedra,  a cornercorner with one O(8)Li2Co3Sb octahedra,  a cornercorner with one O(17)Li4CoSb octahedra,  a cornercorner with one O(11)Li4Sb2 octahedra, corners with two equivalent O(14)Li3Co2Sb octahedra,  an edgeedge with one O(1)Li2Co3Sb octahedra,  an edgeedge with one O(2)Li2Co3Sb octahedra,  an edgeedge with one O(3)Li2Co3Sb octahedra,  an edgeedge with one O(5)Li2Co3Sb octahedra,  an edgeedge with one O(6)Li2Co3Sb octahedra,  an edgeedge with one O(7)Li2Co3Sb octahedra,  an edgeedge with one O(17)Li4CoSb octahedra,  an edgeedge with one O(18)Li4CoSb octahedra,  an edgeedge with one O(20)Li4CoSb octahedra,  an edgeedge with one O(10)Li4Sb2 octahedra,  an edgeedge with one O(12)Li4Sb2 octahedra, and  an edgeedge with one O(9)Li4Sb2 octahedra. The corner-sharing octahedral tilt angles range from 1-13°. In the seventeenth O site, O(17) is bonded to one Li(1), one Li(3), one Li(6), one Li(8), one Co(2), and one Sb(1) atom to form OLi4CoSb octahedra that share  a cornercorner with one O(6)Li2Co3Sb octahedra,  a cornercorner with one O(16)Li3Co2Sb octahedra,  a cornercorner with one O(19)Li4CoSb octahedra,  a cornercorner with one O(9)Li4Sb2 octahedra, corners with two equivalent O(4)Li2Co3Sb octahedra,  an edgeedge with one O(1)Li2Co3Sb octahedra,  an edgeedge with one O(2)Li2Co3Sb octahedra,  an edgeedge with one O(5)Li2Co3Sb octahedra,  an edgeedge with one O(7)Li2Co3Sb octahedra,  an edgeedge with one O(13)Li3Co2Sb octahedra,  an edgeedge with one O(15)Li3Co2Sb octahedra,  an edgeedge with one O(16)Li3Co2Sb octahedra,  an edgeedge with one O(20)Li4CoSb octahedra,  an edgeedge with one O(10)Li4Sb2 octahedra,  an edgeedge with one O(11)Li4Sb2 octahedra,  an edgeedge with one O(12)Li4Sb2 octahedra, and  an edgeedge with one O(9)Li4Sb2 octahedra. The corner-sharing octahedral tilt angles range from 0-16°. In the eighteenth O site, O(18) is bonded to one Li(2), one Li(4), one Li(5), one Li(7), one Co(5), and one Sb(2) atom to form OLi4CoSb octahedra that share  a cornercorner with one O(5)Li2Co3Sb octahedra,  a cornercorner with one O(15)Li3Co2Sb octahedra,  a cornercorner with one O(20)Li4CoSb octahedra,  a cornercorner with one O(10)Li4Sb2 octahedra, corners with two equivalent O(3)Li2Co3Sb octahedra,  an edgeedge with one O(1)Li2Co3Sb octahedra,  an edgeedge with one O(2)Li2Co3Sb octahedra,  an edgeedge with one O(6)Li2Co3Sb octahedra,  an edgeedge with one O(8)Li2Co3Sb octahedra,  an edgeedge with one O(14)Li3Co2Sb octahedra,  an edgeedge with one O(15)Li3Co2Sb octahedra,  an edgeedge with one O(16)Li3Co2Sb octahedra,  an edgeedge with one O(19)Li4CoSb octahedra,  an edgeedge with one O(10)Li4Sb2 octahedra,  an edgeedge with one O(11)Li4Sb2 octahedra,  an edgeedge with one O(12)Li4Sb2 octahedra, and  an edgeedge with one O(9)Li4Sb2 octahedra. The corner-sharing octahedral tilt angles range from 0-15°. In the nineteenth O site, O(19) is bonded to one Li(1), one Li(10), one Li(4), one Li(5), one Co(3), and one Sb(3) atom to form OLi4CoSb octahedra that share  a cornercorner with one O(8)Li2Co3Sb octahedra,  a cornercorner with one O(14)Li3Co2Sb octahedra,  a cornercorner with one O(17)Li4CoSb octahedra,  a cornercorner with one O(11)Li4Sb2 octahedra, corners with two equivalent O(2)Li2Co3Sb octahedra,  an edgeedge with one O(3)Li2Co3Sb octahedra,  an edgeedge with one O(4)Li2Co3Sb octahedra,  an edgeedge with one O(5)Li2Co3Sb octahedra,  an edgeedge with one O(7)Li2Co3Sb octahedra,  an edgeedge with one O(13)Li3Co2Sb octahedra,  an edgeedge with one O(14)Li3Co2Sb octahedra,  an edgeedge with one O(15)Li3Co2Sb octahedra,  an edgeedge with one O(18)Li4CoSb octahedra,  an edgeedge with one O(10)Li4Sb2 octahedra,  an edgeedge with one O(11)Li4Sb2 octahedra,  an edgeedge with one O(12)Li4Sb2 octahedra, and  an edgeedge with one O(9)Li4Sb2 octahedra. The corner-sharing octahedral tilt angles range from 0-15°. In the twentieth O site, O(20) is bonded to one Li(2), one Li(3), one Li(6), one Li(9), one Co(6), and one Sb(4) atom to form OLi4CoSb octahedra that share  a cornercorner with one O(7)Li2Co3Sb octahedra,  a cornercorner with one O(13)Li3Co2Sb octahedra,  a cornercorner with one O(18)Li4CoSb octahedra,  a cornercorner with one O(12)Li4Sb2 octahedra, corners with two equivalent O(1)Li2Co3Sb octahedra,  an edgeedge with one O(3)Li2Co3Sb octahedra,  an edgeedge with one O(4)Li2Co3Sb octahedra,  an edgeedge with one O(6)Li2Co3Sb octahedra,  an edgeedge with one O(8)Li2Co3Sb octahedra,  an edgeedge with one O(13)Li3Co2Sb octahedra,  an edgeedge with one O(14)Li3Co2Sb octahedra,  an edgeedge with one O(16)Li3Co2Sb octahedra,  an edgeedge with one O(17)Li4CoSb octahedra,  an edgeedge with one O(10)Li4Sb2 octahedra,  an edgeedge with one O(11)Li4Sb2 octahedra,  an edgeedge with one O(12)Li4Sb2 octahedra, and  an edgeedge with one O(9)Li4Sb2 octahedra. The corner-sharing octahedral tilt angles range from 0-14°. is represented by the CIF file [CIF]
data_Li5Co3(SbO5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.250
_cell_length_b   5.311
_cell_length_c   8.088
_cell_angle_alpha   108.138
_cell_angle_beta   103.409
_cell_angle_gamma   99.469
_symmetry_Int_Tables_number   1
_cell_volume   201.484
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.494  0.008  0.999  1.0
  Co  Co1  1  0.992  0.808  0.104  1.0
  Co  Co2  1  0.018  0.192  0.898  1.0
  Li  Li3  1  0.999  1.000  0.501  1.0
  Li  Li4  1  0.503  0.837  0.606  1.0
  Li  Li5  1  0.499  0.163  0.395  1.0
  Li  Li6  1  0.491  0.608  0.191  1.0
  Li  Li7  1  0.511  0.396  0.809  1.0
  O  O8  1  0.233  0.208  0.165  1.0
  O  O9  1  0.768  0.788  0.839  1.0
  O  O10  1  0.764  0.414  0.068  1.0
  O  O11  1  0.238  0.592  0.933  1.0
  O  O12  1  0.775  0.591  0.453  1.0
  O  O13  1  0.223  0.407  0.547  1.0
  O  O14  1  0.230  0.961  0.744  1.0
  O  O15  1  0.766  0.035  0.251  1.0
  O  O16  1  0.237  0.772  0.340  1.0
  O  O17  1  0.763  0.225  0.658  1.0
  Sb  Sb18  1  0.005  0.406  0.299  1.0
  Sb  Sb19  1  0.993  0.592  0.701  1.0
[/CIF]
.
The compound described by Li5Co3(SbO5)2 is Caswellsilverite-derived structured and crystallizes in the triclinic P1 space group. There are ten inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(13), one O(15), one O(17), one O(19), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra, corners with two equivalent Co(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra,  an edgeedge with one Sb(3)O6 octahedra, and  an edgeedge with one Sb(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-11°. In the second Li site, Li(2) is bonded to one O(10), one O(12), one O(14), one O(16), one O(18), and one O(20) atom to form LiO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  a cornercorner with one Li(9)O6 octahedra, corners with two equivalent Co(4)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra,  an edgeedge with one Sb(3)O6 octahedra, and  an edgeedge with one Sb(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-12°. In the third Li site, Li(3) is bonded to one O(10), one O(12), one O(13), one O(17), one O(20), and one O(4) atom to form LiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Sb(2)O6 octahedra,  a cornercorner with one Sb(4)O6 octahedra, corners with two equivalent Co(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra,  an edgeedge with one Sb(3)O6 octahedra, and  an edgeedge with one Sb(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-15°. In the fourth Li site, Li(4) is bonded to one O(11), one O(14), one O(18), one O(19), one O(3), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one Sb(1)O6 octahedra,  a cornercorner with one Sb(3)O6 octahedra, corners with two equivalent Co(5)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra,  an edgeedge with one Sb(3)O6 octahedra, and  an edgeedge with one Sb(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-15°. In the fifth Li site, Li(5) is bonded to one O(10), one O(12), one O(15), one O(18), one O(19), and one O(2) atom to form LiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Sb(2)O6 octahedra,  a cornercorner with one Sb(4)O6 octahedra, corners with two equivalent Co(3)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra, and  an edgeedge with one Sb(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-15°. In the sixth Li site, Li(6) is bonded to one O(1), one O(11), one O(16), one O(17), one O(20), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Sb(1)O6 octahedra,  a cornercorner with one Sb(3)O6 octahedra, corners with two equivalent Co(6)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra, and  an edgeedge with one Sb(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-14°. In the seventh Li site, Li(7) is bonded to one O(1), one O(15), one O(18), one O(5), one O(8), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Sb(2)O6 octahedra, corners with two equivalent Sb(4)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra, and  an edgeedge with one Sb(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-8°. In the eighth Li site, Li(8) is bonded to one O(10), one O(16), one O(17), one O(2), one O(6), and one O(7) atom to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one Sb(1)O6 octahedra, corners with two equivalent Sb(3)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra, and  an edgeedge with one Sb(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-8°. In the ninth Li site, Li(9) is bonded to one O(11), one O(13), one O(20), one O(3), one O(6), and one O(7) atom to form LiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Sb(4)O6 octahedra, corners with two equivalent Sb(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Sb(3)O6 octahedra, and  an edgeedge with one Sb(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-8°. In the tenth Li site, Li(10) is bonded to one O(12), one O(14), one O(19), one O(4), one O(5), and one O(8) atom to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one Sb(3)O6 octahedra, corners with two equivalent Sb(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Sb(3)O6 octahedra, and  an edgeedge with one Sb(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-8°. There are six inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(13), one O(15), one O(2), one O(4), one O(6), and one O(8) atom to form CoO6 octahedra that share  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one Sb(1)O6 octahedra,  a cornercorner with one Sb(3)O6 octahedra, corners with two equivalent Li(1)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra, and  an edgeedge with one Sb(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-11°. In the second Co site, Co(2) is bonded to one O(1), one O(15), one O(17), one O(4), one O(5), and one O(7) atom to form CoO6 octahedra that share  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  a cornercorner with one Li(9)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra, corners with two equivalent Li(3)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra, and  an edgeedge with one Sb(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-15°. In the third Co site, Co(3) is bonded to one O(13), one O(19), one O(2), one O(3), one O(5), and one O(7) atom to form CoO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  a cornercorner with one Li(9)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra, corners with two equivalent Li(5)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra,  an edgeedge with one Sb(3)O6 octahedra, and  an edgeedge with one Sb(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-15°. In the fourth Co site, Co(4) is bonded to one O(1), one O(14), one O(16), one O(3), one O(5), and one O(7) atom to form CoO6 octahedra that share  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Sb(2)O6 octahedra,  a cornercorner with one Sb(4)O6 octahedra, corners with two equivalent Li(2)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra, and  an edgeedge with one Sb(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-12°. In the fifth Co site, Co(5) is bonded to one O(16), one O(18), one O(2), one O(3), one O(6), and one O(8) atom to form CoO6 octahedra that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra, corners with two equivalent Li(4)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra, and  an edgeedge with one Sb(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-14°. In the sixth Co site, Co(6) is bonded to one O(1), one O(14), one O(20), one O(4), one O(6), and one O(8) atom to form CoO6 octahedra that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra, corners with two equivalent Li(6)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra,  an edgeedge with one Sb(3)O6 octahedra, and  an edgeedge with one Sb(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-15°. There are four inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(12), one O(16), one O(17), one O(2), one O(5), and one O(9) atom to form SbO6 octahedra that share  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra, corners with two equivalent Li(10)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra, and  an edgeedge with one Sb(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-7°. In the second Sb site, Sb(2) is bonded to one O(1), one O(10), one O(11), one O(15), one O(18), and one O(6) atom to form SbO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra, corners with two equivalent Li(9)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra, and  an edgeedge with one Sb(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-7°. In the third Sb site, Sb(3) is bonded to one O(10), one O(11), one O(14), one O(19), one O(4), and one O(7) atom to form SbO6 octahedra that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra, corners with two equivalent Li(8)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra, and  an edgeedge with one Sb(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-7°. In the fourth Sb site, Sb(4) is bonded to one O(12), one O(13), one O(20), one O(3), one O(8), and one O(9) atom to form SbO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(9)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra, corners with two equivalent Li(7)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra, and  an edgeedge with one Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-7°. There are twenty inequivalent O sites. In the first O site, O(1) is bonded to one Li(6), one Li(7), one Co(2), one Co(4), one Co(6), and one Sb(2) atom to form OLi2Co3Sb octahedra that share  a cornercorner with one O(3)Li2Co3Sb octahedra,  a cornercorner with one O(5)Li2Co3Sb octahedra,  a cornercorner with one O(15)Li3Co2Sb octahedra,  a cornercorner with one O(10)Li4Sb2 octahedra, corners with two equivalent O(20)Li4CoSb octahedra,  an edgeedge with one O(4)Li2Co3Sb octahedra,  an edgeedge with one O(5)Li2Co3Sb octahedra,  an edgeedge with one O(6)Li2Co3Sb octahedra,  an edgeedge with one O(7)Li2Co3Sb octahedra,  an edgeedge with one O(8)Li2Co3Sb octahedra,  an edgeedge with one O(14)Li3Co2Sb octahedra,  an edgeedge with one O(15)Li3Co2Sb octahedra,  an edgeedge with one O(16)Li3Co2Sb octahedra,  an edgeedge with one O(17)Li4CoSb octahedra,  an edgeedge with one O(18)Li4CoSb octahedra,  an edgeedge with one O(11)Li4Sb2 octahedra, and  an edgeedge with one O(9)Li4Sb2 octahedra. The corner-sharing octahedral tilt angles range from 4-14°. In the second O site, O(2) is bonded to one Li(5), one Li(8), one Co(1), one Co(3), one Co(5), and one Sb(1) atom to form OLi2Co3Sb octahedra that share  a cornercorner with one O(4)Li2Co3Sb octahedra,  a cornercorner with one O(6)Li2Co3Sb octahedra,  a cornercorner with one O(16)Li3Co2Sb octahedra,  a cornercorner with one O(9)Li4Sb2 octahedra, corners with two equivalent O(19)Li4CoSb octahedra,  an edgeedge with one O(3)Li2Co3Sb octahedra,  an edgeedge with one O(5)Li2Co3Sb octahedra,  an edgeedge with one O(6)Li2Co3Sb octahedra,  an edgeedge with one O(7)Li2Co3Sb octahedra,  an edgeedge with one O(8)Li2Co3Sb octahedra,  an edgeedge with one O(13)Li3Co2Sb octahedra,  an edgeedge with one O(15)Li3Co2Sb octahedra,  an edgeedge with one O(16)Li3Co2Sb octahedra,  an edgeedge with one O(17)Li4CoSb octahedra,  an edgeedge with one O(18)Li4CoSb octahedra,  an edgeedge with one O(10)Li4Sb2 octahedra, and  an edgeedge with one O(12)Li4Sb2 octahedra. The corner-sharing octahedral tilt angles range from 2-15°. In the third O site, O(3) is bonded to one Li(4), one Li(9), one Co(3), one Co(4), one Co(5), and one Sb(4) atom to form OLi2Co3Sb octahedra that share  a cornercorner with one O(1)Li2Co3Sb octahedra,  a cornercorner with one O(7)Li2Co3Sb octahedra,  a cornercorner with one O(13)Li3Co2Sb octahedra,  a cornercorner with one O(12)Li4Sb2 octahedra, corners with two equivalent O(18)Li4CoSb octahedra,  an edgeedge with one O(2)Li2Co3Sb octahedra,  an edgeedge with one O(5)Li2Co3Sb octahedra,  an edgeedge with one O(6)Li2Co3Sb octahedra,  an edgeedge with one O(7)Li2Co3Sb octahedra,  an edgeedge with one O(8)Li2Co3Sb octahedra,  an edgeedge with one O(13)Li3Co2Sb octahedra,  an edgeedge with one O(14)Li3Co2Sb octahedra,  an edgeedge with one O(16)Li3Co2Sb octahedra,  an edgeedge with one O(19)Li4CoSb octahedra,  an edgeedge with one O(20)Li4CoSb octahedra,  an edgeedge with one O(11)Li4Sb2 octahedra, and  an edgeedge with one O(9)Li4Sb2 octahedra. The corner-sharing octahedral tilt angles range from 4-15°. In the fourth O site, O(4) is bonded to one Li(10), one Li(3), one Co(1), one Co(2), one Co(6), and one Sb(3) atom to form OLi2Co3Sb octahedra that share  a cornercorner with one O(2)Li2Co3Sb octahedra,  a cornercorner with one O(8)Li2Co3Sb octahedra,  a cornercorner with one O(14)Li3Co2Sb octahedra,  a cornercorner with one O(11)Li4Sb2 octahedra, corners with two equivalent O(17)Li4CoSb octahedra,  an edgeedge with one O(1)Li2Co3Sb octahedra,  an edgeedge with one O(5)Li2Co3Sb octahedra,  an edgeedge with one O(6)Li2Co3Sb octahedra,  an edgeedge with one O(7)Li2Co3Sb octahedra,  an edgeedge with one O(8)Li2Co3Sb octahedra,  an edgeedge with one O(13)Li3Co2Sb octahedra,  an edgeedge with one O(14)Li3Co2Sb octahedra,  an edgeedge with one O(15)Li3Co2Sb octahedra,  an edgeedge with one O(19)Li4CoSb octahedra,  an edgeedge with one O(20)Li4CoSb octahedra,  an edgeedge with one O(10)Li4Sb2 octahedra, and  an edgeedge with one O(12)Li4Sb2 octahedra. The corner-sharing octahedral tilt angles range from 2-16°. In the fifth O site, O(5) is bonded to one Li(10), one Li(7), one Co(2), one Co(3), one Co(4), and one Sb(1) atom to form OLi2Co3Sb octahedra that share  a cornercorner with one O(1)Li2Co3Sb octahedra,  a cornercorner with one O(7)Li2Co3Sb octahedra,  a cornercorner with one O(13)Li3Co2Sb octahedra,  a cornercorner with one O(18)Li4CoSb octahedra, corners with two equivalent O(12)Li4Sb2 octahedra,  an edgeedge with one O(1)Li2Co3Sb octahedra,  an edgeedge with one O(2)Li2Co3Sb octahedra,  an edgeedge with one O(3)Li2Co3Sb octahedra,  an edgeedge with one O(4)Li2Co3Sb octahedra,  an edgeedge with one O(7)Li2Co3Sb octahedra,  an edgeedge with one O(8)Li2Co3Sb octahedra,  an edgeedge with one O(14)Li3Co2Sb octahedra,  an edgeedge with one O(15)Li3Co2Sb octahedra,  an edgeedge with one O(16)Li3Co2Sb octahedra,  an edgeedge with one O(17)Li4CoSb octahedra,  an edgeedge with one O(19)Li4CoSb octahedra, and  an edgeedge with one O(9)Li4Sb2 octahedra. The corner-sharing octahedral tilt angles range from 4-8°. In the sixth O site, O(6) is bonded to one Li(8), one Li(9), one Co(1), one Co(5), one Co(6), and one Sb(2) atom to form OLi2Co3Sb octahedra that share  a cornercorner with one O(2)Li2Co3Sb octahedra,  a cornercorner with one O(8)Li2Co3Sb octahedra,  a cornercorner with one O(14)Li3Co2Sb octahedra,  a cornercorner with one O(17)Li4CoSb octahedra, corners with two equivalent O(11)Li4Sb2 octahedra,  an edgeedge with one O(1)Li2Co3Sb octahedra,  an edgeedge with one O(2)Li2Co3Sb octahedra,  an edgeedge with one O(3)Li2Co3Sb octahedra,  an edgeedge with one O(4)Li2Co3Sb octahedra,  an edgeedge with one O(7)Li2Co3Sb octahedra,  an edgeedge with one O(8)Li2Co3Sb octahedra,  an edgeedge with one O(13)Li3Co2Sb octahedra,  an edgeedge with one O(15)Li3Co2Sb octahedra,  an edgeedge with one O(16)Li3Co2Sb octahedra,  an edgeedge with one O(18)Li4CoSb octahedra,  an edgeedge with one O(20)Li4CoSb octahedra, and  an edgeedge with one O(10)Li4Sb2 octahedra. The corner-sharing octahedral tilt angles range from 1-9°. In the seventh O site, O(7) is bonded to one Li(8), one Li(9), one Co(2), one Co(3), one Co(4), and one Sb(3) atom to form OLi2Co3Sb octahedra that share  a cornercorner with one O(3)Li2Co3Sb octahedra,  a cornercorner with one O(5)Li2Co3Sb octahedra,  a cornercorner with one O(15)Li3Co2Sb octahedra,  a cornercorner with one O(20)Li4CoSb octahedra, corners with two equivalent O(10)Li4Sb2 octahedra,  an edgeedge with one O(1)Li2Co3Sb octahedra,  an edgeedge with one O(2)Li2Co3Sb octahedra,  an edgeedge with one O(3)Li2Co3Sb octahedra,  an edgeedge with one O(4)Li2Co3Sb octahedra,  an edgeedge with one O(5)Li2Co3Sb octahedra,  an edgeedge with one O(6)Li2Co3Sb octahedra,  an edgeedge with one O(13)Li3Co2Sb octahedra,  an edgeedge with one O(14)Li3Co2Sb octahedra,  an edgeedge with one O(16)Li3Co2Sb octahedra,  an edgeedge with one O(17)Li4CoSb octahedra,  an edgeedge with one O(19)Li4CoSb octahedra, and  an edgeedge with one O(11)Li4Sb2 octahedra. The corner-sharing octahedral tilt angles range from 4-8°. In the eighth O site, O(8) is bonded to one Li(10), one Li(7), one Co(1), one Co(5), one Co(6), and one Sb(4) atom to form OLi2Co3Sb octahedra that share  a cornercorner with one O(4)Li2Co3Sb octahedra,  a cornercorner with one O(6)Li2Co3Sb octahedra,  a cornercorner with one O(16)Li3Co2Sb octahedra,  a cornercorner with one O(19)Li4CoSb octahedra, corners with two equivalent O(9)Li4Sb2 octahedra,  an edgeedge with one O(1)Li2Co3Sb octahedra,  an edgeedge with one O(2)Li2Co3Sb octahedra,  an edgeedge with one O(3)Li2Co3Sb octahedra,  an edgeedge with one O(4)Li2Co3Sb octahedra,  an edgeedge with one O(5)Li2Co3Sb octahedra,  an edgeedge with one O(6)Li2Co3Sb octahedra,  an edgeedge with one O(13)Li3Co2Sb octahedra,  an edgeedge with one O(14)Li3Co2Sb octahedra,  an edgeedge with one O(15)Li3Co2Sb octahedra,  an edgeedge with one O(18)Li4CoSb octahedra,  an edgeedge with one O(20)Li4CoSb octahedra, and  an edgeedge with one O(12)Li4Sb2 octahedra. The corner-sharing octahedral tilt angles range from 1-8°. In the ninth O site, O(9) is bonded to one Li(1), one Li(4), one Li(6), one Li(7), one Sb(1), and one Sb(4) atom to form OLi4Sb2 octahedra that share  a cornercorner with one O(2)Li2Co3Sb octahedra,  a cornercorner with one O(14)Li3Co2Sb octahedra,  a cornercorner with one O(17)Li4CoSb octahedra,  a cornercorner with one O(11)Li4Sb2 octahedra, corners with two equivalent O(8)Li2Co3Sb octahedra,  an edgeedge with one O(1)Li2Co3Sb octahedra,  an edgeedge with one O(3)Li2Co3Sb octahedra,  an edgeedge with one O(5)Li2Co3Sb octahedra,  an edgeedge with one O(13)Li3Co2Sb octahedra,  an edgeedge with one O(15)Li3Co2Sb octahedra,  an edgeedge with one O(16)Li3Co2Sb octahedra,  an edgeedge with one O(17)Li4CoSb octahedra,  an edgeedge with one O(18)Li4CoSb octahedra,  an edgeedge with one O(19)Li4CoSb octahedra,  an edgeedge with one O(20)Li4CoSb octahedra,  an edgeedge with one O(11)Li4Sb2 octahedra, and  an edgeedge with one O(12)Li4Sb2 octahedra. The corner-sharing octahedral tilt angles range from 0-13°. In the tenth O site, O(10) is bonded to one Li(2), one Li(3), one Li(5), one Li(8), one Sb(2), and one Sb(3) atom to form OLi4Sb2 octahedra that share  a cornercorner with one O(1)Li2Co3Sb octahedra,  a cornercorner with one O(13)Li3Co2Sb octahedra,  a cornercorner with one O(18)Li4CoSb octahedra,  a cornercorner with one O(12)Li4Sb2 octahedra, corners with two equivalent O(7)Li2Co3Sb octahedra,  an edgeedge with one O(2)Li2Co3Sb octahedra,  an edgeedge with one O(4)Li2Co3Sb octahedra,  an edgeedge with one O(6)Li2Co3Sb octahedra,  an edgeedge with one O(14)Li3Co2Sb octahedra,  an edgeedge with one O(15)Li3Co2Sb octahedra,  an edgeedge with one O(16)Li3Co2Sb octahedra,  an edgeedge with one O(17)Li4CoSb octahedra,  an edgeedge with one O(18)Li4CoSb octahedra,  an edgeedge with one O(19)Li4CoSb octahedra,  an edgeedge with one O(20)Li4CoSb octahedra,  an edgeedge with one O(11)Li4Sb2 octahedra, and  an edgeedge with one O(12)Li4Sb2 octahedra. The corner-sharing octahedral tilt angles range from 1-14°. In the eleventh O site, O(11) is bonded to one Li(1), one Li(4), one Li(6), one Li(9), one Sb(2), and one Sb(3) atom to form OLi4Sb2 octahedra that share  a cornercorner with one O(4)Li2Co3Sb octahedra,  a cornercorner with one O(16)Li3Co2Sb octahedra,  a cornercorner with one O(19)Li4CoSb octahedra,  a cornercorner with one O(9)Li4Sb2 octahedra, corners with two equivalent O(6)Li2Co3Sb octahedra,  an edgeedge with one O(1)Li2Co3Sb octahedra,  an edgeedge with one O(3)Li2Co3Sb octahedra,  an edgeedge with one O(7)Li2Co3Sb octahedra,  an edgeedge with one O(13)Li3Co2Sb octahedra,  an edgeedge with one O(14)Li3Co2Sb octahedra,  an edgeedge with one O(15)Li3Co2Sb octahedra,  an edgeedge with one O(17)Li4CoSb octahedra,  an edgeedge with one O(18)Li4CoSb octahedra,  an edgeedge with one O(19)Li4CoSb octahedra,  an edgeedge with one O(20)Li4CoSb octahedra,  an edgeedge with one O(10)Li4Sb2 octahedra, and  an edgeedge with one O(9)Li4Sb2 octahedra. The corner-sharing octahedral tilt angles range from 0-13°. In the twelfth O site, O(12) is bonded to one Li(10), one Li(2), one Li(3), one Li(5), one Sb(1), and one Sb(4) atom to form OLi4Sb2 octahedra that share  a cornercorner with one O(3)Li2Co3Sb octahedra,  a cornercorner with one O(15)Li3Co2Sb octahedra,  a cornercorner with one O(20)Li4CoSb octahedra,  a cornercorner with one O(10)Li4Sb2 octahedra, corners with two equivalent O(5)Li2Co3Sb octahedra,  an edgeedge with one O(2)Li2Co3Sb octahedra,  an edgeedge with one O(4)Li2Co3Sb octahedra,  an edgeedge with one O(8)Li2Co3Sb octahedra,  an edgeedge with one O(13)Li3Co2Sb octahedra,  an edgeedge with one O(14)Li3Co2Sb octahedra,  an edgeedge with one O(16)Li3Co2Sb octahedra,  an edgeedge with one O(17)Li4CoSb octahedra,  an edgeedge with one O(18)Li4CoSb octahedra,  an edgeedge with one O(19)Li4CoSb octahedra,  an edgeedge with one O(20)Li4CoSb octahedra,  an edgeedge with one O(10)Li4Sb2 octahedra, and  an edgeedge with one O(9)Li4Sb2 octahedra. The corner-sharing octahedral tilt angles range from 1-13°. In the thirteenth O site, O(13) is bonded to one Li(1), one Li(3), one Li(9), one Co(1), one Co(3), and one Sb(4) atom to form OLi3Co2Sb octahedra that share  a cornercorner with one O(3)Li2Co3Sb octahedra,  a cornercorner with one O(5)Li2Co3Sb octahedra,  a cornercorner with one O(20)Li4CoSb octahedra,  a cornercorner with one O(10)Li4Sb2 octahedra, corners with two equivalent O(15)Li3Co2Sb octahedra,  an edgeedge with one O(2)Li2Co3Sb octahedra,  an edgeedge with one O(3)Li2Co3Sb octahedra,  an edgeedge with one O(4)Li2Co3Sb octahedra,  an edgeedge with one O(6)Li2Co3Sb octahedra,  an edgeedge with one O(7)Li2Co3Sb octahedra,  an edgeedge with one O(8)Li2Co3Sb octahedra,  an edgeedge with one O(17)Li4CoSb octahedra,  an edgeedge with one O(19)Li4CoSb octahedra,  an edgeedge with one O(20)Li4CoSb octahedra,  an edgeedge with one O(11)Li4Sb2 octahedra,  an edgeedge with one O(12)Li4Sb2 octahedra, and  an edgeedge with one O(9)Li4Sb2 octahedra. The corner-sharing octahedral tilt angles range from 0-14°. In the fourteenth O site, O(14) is bonded to one Li(10), one Li(2), one Li(4), one Co(4), one Co(6), and one Sb(3) atom to form OLi3Co2Sb octahedra that share  a cornercorner with one O(4)Li2Co3Sb octahedra,  a cornercorner with one O(6)Li2Co3Sb octahedra,  a cornercorner with one O(19)Li4CoSb octahedra,  a cornercorner with one O(9)Li4Sb2 octahedra, corners with two equivalent O(16)Li3Co2Sb octahedra,  an edgeedge with one O(1)Li2Co3Sb octahedra,  an edgeedge with one O(3)Li2Co3Sb octahedra,  an edgeedge with one O(4)Li2Co3Sb octahedra,  an edgeedge with one O(5)Li2Co3Sb octahedra,  an edgeedge with one O(7)Li2Co3Sb octahedra,  an edgeedge with one O(8)Li2Co3Sb octahedra,  an edgeedge with one O(18)Li4CoSb octahedra,  an edgeedge with one O(19)Li4CoSb octahedra,  an edgeedge with one O(20)Li4CoSb octahedra,  an edgeedge with one O(10)Li4Sb2 octahedra,  an edgeedge with one O(11)Li4Sb2 octahedra, and  an edgeedge with one O(12)Li4Sb2 octahedra. The corner-sharing octahedral tilt angles range from 1-13°. In the fifteenth O site, O(15) is bonded to one Li(1), one Li(5), one Li(7), one Co(1), one Co(2), and one Sb(2) atom to form OLi3Co2Sb octahedra that share  a cornercorner with one O(1)Li2Co3Sb octahedra,  a cornercorner with one O(7)Li2Co3Sb octahedra,  a cornercorner with one O(18)Li4CoSb octahedra,  a cornercorner with one O(12)Li4Sb2 octahedra, corners with two equivalent O(13)Li3Co2Sb octahedra,  an edgeedge with one O(1)Li2Co3Sb octahedra,  an edgeedge with one O(2)Li2Co3Sb octahedra,  an edgeedge with one O(4)Li2Co3Sb octahedra,  an edgeedge with one O(5)Li2Co3Sb octahedra,  an edgeedge with one O(6)Li2Co3Sb octahedra,  an edgeedge with one O(8)Li2Co3Sb octahedra,  an edgeedge with one O(17)Li4CoSb octahedra,  an edgeedge with one O(18)Li4CoSb octahedra,  an edgeedge with one O(19)Li4CoSb octahedra,  an edgeedge with one O(10)Li4Sb2 octahedra,  an edgeedge with one O(11)Li4Sb2 octahedra, and  an edgeedge with one O(9)Li4Sb2 octahedra. The corner-sharing octahedral tilt angles range from 0-13°. In the sixteenth O site, O(16) is bonded to one Li(2), one Li(6), one Li(8), one Co(4), one Co(5), and one Sb(1) atom to form OLi3Co2Sb octahedra that share  a cornercorner with one O(2)Li2Co3Sb octahedra,  a cornercorner with one O(8)Li2Co3Sb octahedra,  a cornercorner with one O(17)Li4CoSb octahedra,  a cornercorner with one O(11)Li4Sb2 octahedra, corners with two equivalent O(14)Li3Co2Sb octahedra,  an edgeedge with one O(1)Li2Co3Sb octahedra,  an edgeedge with one O(2)Li2Co3Sb octahedra,  an edgeedge with one O(3)Li2Co3Sb octahedra,  an edgeedge with one O(5)Li2Co3Sb octahedra,  an edgeedge with one O(6)Li2Co3Sb octahedra,  an edgeedge with one O(7)Li2Co3Sb octahedra,  an edgeedge with one O(17)Li4CoSb octahedra,  an edgeedge with one O(18)Li4CoSb octahedra,  an edgeedge with one O(20)Li4CoSb octahedra,  an edgeedge with one O(10)Li4Sb2 octahedra,  an edgeedge with one O(12)Li4Sb2 octahedra, and  an edgeedge with one O(9)Li4Sb2 octahedra. The corner-sharing octahedral tilt angles range from 1-13°. In the seventeenth O site, O(17) is bonded to one Li(1), one Li(3), one Li(6), one Li(8), one Co(2), and one Sb(1) atom to form OLi4CoSb octahedra that share  a cornercorner with one O(6)Li2Co3Sb octahedra,  a cornercorner with one O(16)Li3Co2Sb octahedra,  a cornercorner with one O(19)Li4CoSb octahedra,  a cornercorner with one O(9)Li4Sb2 octahedra, corners with two equivalent O(4)Li2Co3Sb octahedra,  an edgeedge with one O(1)Li2Co3Sb octahedra,  an edgeedge with one O(2)Li2Co3Sb octahedra,  an edgeedge with one O(5)Li2Co3Sb octahedra,  an edgeedge with one O(7)Li2Co3Sb octahedra,  an edgeedge with one O(13)Li3Co2Sb octahedra,  an edgeedge with one O(15)Li3Co2Sb octahedra,  an edgeedge with one O(16)Li3Co2Sb octahedra,  an edgeedge with one O(20)Li4CoSb octahedra,  an edgeedge with one O(10)Li4Sb2 octahedra,  an edgeedge with one O(11)Li4Sb2 octahedra,  an edgeedge with one O(12)Li4Sb2 octahedra, and  an edgeedge with one O(9)Li4Sb2 octahedra. The corner-sharing octahedral tilt angles range from 0-16°. In the eighteenth O site, O(18) is bonded to one Li(2), one Li(4), one Li(5), one Li(7), one Co(5), and one Sb(2) atom to form OLi4CoSb octahedra that share  a cornercorner with one O(5)Li2Co3Sb octahedra,  a cornercorner with one O(15)Li3Co2Sb octahedra,  a cornercorner with one O(20)Li4CoSb octahedra,  a cornercorner with one O(10)Li4Sb2 octahedra, corners with two equivalent O(3)Li2Co3Sb octahedra,  an edgeedge with one O(1)Li2Co3Sb octahedra,  an edgeedge with one O(2)Li2Co3Sb octahedra,  an edgeedge with one O(6)Li2Co3Sb octahedra,  an edgeedge with one O(8)Li2Co3Sb octahedra,  an edgeedge with one O(14)Li3Co2Sb octahedra,  an edgeedge with one O(15)Li3Co2Sb octahedra,  an edgeedge with one O(16)Li3Co2Sb octahedra,  an edgeedge with one O(19)Li4CoSb octahedra,  an edgeedge with one O(10)Li4Sb2 octahedra,  an edgeedge with one O(11)Li4Sb2 octahedra,  an edgeedge with one O(12)Li4Sb2 octahedra, and  an edgeedge with one O(9)Li4Sb2 octahedra. The corner-sharing octahedral tilt angles range from 0-15°. In the nineteenth O site, O(19) is bonded to one Li(1), one Li(10), one Li(4), one Li(5), one Co(3), and one Sb(3) atom to form OLi4CoSb octahedra that share  a cornercorner with one O(8)Li2Co3Sb octahedra,  a cornercorner with one O(14)Li3Co2Sb octahedra,  a cornercorner with one O(17)Li4CoSb octahedra,  a cornercorner with one O(11)Li4Sb2 octahedra, corners with two equivalent O(2)Li2Co3Sb octahedra,  an edgeedge with one O(3)Li2Co3Sb octahedra,  an edgeedge with one O(4)Li2Co3Sb octahedra,  an edgeedge with one O(5)Li2Co3Sb octahedra,  an edgeedge with one O(7)Li2Co3Sb octahedra,  an edgeedge with one O(13)Li3Co2Sb octahedra,  an edgeedge with one O(14)Li3Co2Sb octahedra,  an edgeedge with one O(15)Li3Co2Sb octahedra,  an edgeedge with one O(18)Li4CoSb octahedra,  an edgeedge with one O(10)Li4Sb2 octahedra,  an edgeedge with one O(11)Li4Sb2 octahedra,  an edgeedge with one O(12)Li4Sb2 octahedra, and  an edgeedge with one O(9)Li4Sb2 octahedra. The corner-sharing octahedral tilt angles range from 0-15°. In the twentieth O site, O(20) is bonded to one Li(2), one Li(3), one Li(6), one Li(9), one Co(6), and one Sb(4) atom to form OLi4CoSb octahedra that share  a cornercorner with one O(7)Li2Co3Sb octahedra,  a cornercorner with one O(13)Li3Co2Sb octahedra,  a cornercorner with one O(18)Li4CoSb octahedra,  a cornercorner with one O(12)Li4Sb2 octahedra, corners with two equivalent O(1)Li2Co3Sb octahedra,  an edgeedge with one O(3)Li2Co3Sb octahedra,  an edgeedge with one O(4)Li2Co3Sb octahedra,  an edgeedge with one O(6)Li2Co3Sb octahedra,  an edgeedge with one O(8)Li2Co3Sb octahedra,  an edgeedge with one O(13)Li3Co2Sb octahedra,  an edgeedge with one O(14)Li3Co2Sb octahedra,  an edgeedge with one O(16)Li3Co2Sb octahedra,  an edgeedge with one O(17)Li4CoSb octahedra,  an edgeedge with one O(10)Li4Sb2 octahedra,  an edgeedge with one O(11)Li4Sb2 octahedra,  an edgeedge with one O(12)Li4Sb2 octahedra, and  an edgeedge with one O(9)Li4Sb2 octahedra. The corner-sharing octahedral tilt angles range from 0-14°. is represented by the CIF file [CIF]
data_Li5Co3(SbO5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.250
_cell_length_b   5.311
_cell_length_c   8.088
_cell_angle_alpha   108.138
_cell_angle_beta   103.409
_cell_angle_gamma   99.469
_symmetry_Int_Tables_number   1
_cell_volume   201.484
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.494  0.008  0.999  1.0
  Co  Co1  1  0.992  0.808  0.104  1.0
  Co  Co2  1  0.018  0.192  0.898  1.0
  Li  Li3  1  0.999  1.000  0.501  1.0
  Li  Li4  1  0.503  0.837  0.606  1.0
  Li  Li5  1  0.499  0.163  0.395  1.0
  Li  Li6  1  0.491  0.608  0.191  1.0
  Li  Li7  1  0.511  0.396  0.809  1.0
  O  O8  1  0.233  0.208  0.165  1.0
  O  O9  1  0.768  0.788  0.839  1.0
  O  O10  1  0.764  0.414  0.068  1.0
  O  O11  1  0.238  0.592  0.933  1.0
  O  O12  1  0.775  0.591  0.453  1.0
  O  O13  1  0.223  0.407  0.547  1.0
  O  O14  1  0.230  0.961  0.744  1.0
  O  O15  1  0.766  0.035  0.251  1.0
  O  O16  1  0.237  0.772  0.340  1.0
  O  O17  1  0.763  0.225  0.658  1.0
  Sb  Sb18  1  0.005  0.406  0.299  1.0
  Sb  Sb19  1  0.993  0.592  0.701  1.0
[/CIF]
.