The material structure described by Na3Sr4La3Ti10O30 crystallizes in the orthorhombic Fmm2 space group. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded to one O(10), one O(11), one O(6), one O(9), two equivalent O(4), two equivalent O(8), and four equivalent O(3) atoms to form distorted NaO12 cuboctahedra that share corners with four equivalent Na(1)O12 cuboctahedra, corners with four equivalent Na(2)O12 cuboctahedra, corners with four equivalent Sr(2)O12 cuboctahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra, faces with four equivalent La(1)O12 cuboctahedra, faces with four equivalent Ti(1)O6 octahedra, and faces with four equivalent Ti(2)O6 octahedra. In the second Na site, Na(2) is bonded to two equivalent O(11), two equivalent O(9), four equivalent O(7), and four equivalent O(8) atoms to form distorted NaO12 cuboctahedra that share corners with four equivalent Na(2)O12 cuboctahedra, corners with eight equivalent Na(1)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, faces with four equivalent La(2)O12 cuboctahedra, and faces with eight equivalent Ti(2)O6 octahedra. There are two inequivalent Sr sites. In the first Sr site, Sr(1) is bonded to one O(10), one O(6), two equivalent O(1), two equivalent O(4), two equivalent O(5), and four equivalent O(2) atoms to form distorted SrO12 cuboctahedra that share corners with four equivalent La(1)O12 cuboctahedra, corners with eight equivalent Sr(1)O12 cuboctahedra,  a faceface with one Na(1)O12 cuboctahedra, faces with five equivalent Sr(2)O12 cuboctahedra, faces with four equivalent Ti(1)O6 octahedra, and faces with four equivalent Ti(3)O6 octahedra. In the second Sr site, Sr(2) is bonded to one O(10), one O(6), two equivalent O(1), two equivalent O(4), two equivalent O(5), and four equivalent O(2) atoms to form SrO12 cuboctahedra that share corners with four equivalent Na(1)O12 cuboctahedra, corners with eight equivalent Sr(2)O12 cuboctahedra,  a faceface with one La(1)O12 cuboctahedra, faces with five equivalent Sr(1)O12 cuboctahedra, faces with four equivalent Ti(1)O6 octahedra, and faces with four equivalent Ti(3)O6 octahedra. There are two inequivalent La sites. In the first La site, La(1) is bonded to one O(10), one O(11), one O(6), one O(9), two equivalent O(4), two equivalent O(8), and four equivalent O(3) atoms to form distorted LaO12 cuboctahedra that share corners with four equivalent Sr(1)O12 cuboctahedra, corners with four equivalent La(1)O12 cuboctahedra, corners with four equivalent La(2)O12 cuboctahedra,  a faceface with one Na(2)O12 cuboctahedra,  a faceface with one Sr(2)O12 cuboctahedra, faces with four equivalent Na(1)O12 cuboctahedra, faces with four equivalent Ti(1)O6 octahedra, and faces with four equivalent Ti(2)O6 octahedra. In the second La site, La(2) is bonded to two equivalent O(11), two equivalent O(9), four equivalent O(7), and four equivalent O(8) atoms to form distorted LaO12 cuboctahedra that share corners with four equivalent La(2)O12 cuboctahedra, corners with eight equivalent La(1)O12 cuboctahedra, faces with two equivalent Na(1)O12 cuboctahedra, faces with four equivalent Na(2)O12 cuboctahedra, and faces with eight equivalent Ti(2)O6 octahedra. There are three inequivalent Ti sites. In the first Ti site, Ti(1) is bonded to one O(10), one O(2), one O(3), one O(6), and two equivalent O(4) atoms to form TiO6 octahedra that share  a cornercorner with one Ti(2)O6 octahedra,  a cornercorner with one Ti(3)O6 octahedra, corners with four equivalent Ti(1)O6 octahedra, faces with two equivalent Na(1)O12 cuboctahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Sr(2)O12 cuboctahedra, and faces with two equivalent La(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 3-18°. In the second Ti site, Ti(2) is bonded to one O(11), one O(3), one O(7), one O(9), and two equivalent O(8) atoms to form TiO6 octahedra that share  a cornercorner with one Ti(1)O6 octahedra, corners with five equivalent Ti(2)O6 octahedra, faces with two equivalent Na(1)O12 cuboctahedra, faces with two equivalent Na(2)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, and faces with two equivalent La(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-19°. In the third Ti site, Ti(3) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(5) atoms to form TiO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra, corners with four equivalent Ti(3)O6 octahedra, faces with four equivalent Sr(1)O12 cuboctahedra, and faces with four equivalent Sr(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-11°. There are eleven inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to two equivalent Sr(1), two equivalent Sr(2), and two equivalent Ti(3) atoms. In the second O site, O(2) is bonded in a 6-coordinate geometry to two equivalent Sr(1), two equivalent Sr(2), one Ti(1), and one Ti(3) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to two equivalent Na(1), two equivalent La(1), one Ti(1), and one Ti(2) atom. In the fourth O site, O(4) is bonded in a distorted linear geometry to one Na(1), one Sr(1), one Sr(2), one La(1), and two equivalent Ti(1) atoms. In the fifth O site, O(5) is bonded in a 2-coordinate geometry to two equivalent Sr(1), two equivalent Sr(2), and two equivalent Ti(3) atoms. In the sixth O site, O(6) is bonded in a 2-coordinate geometry to one Na(1), one Sr(1), one Sr(2), one La(1), and two equivalent Ti(1) atoms. In the seventh O site, O(7) is bonded in a 4-coordinate geometry to two equivalent Na(2), two equivalent La(2), and two equivalent Ti(2) atoms. In the eighth O site, O(8) is bonded in a distorted linear geometry to one Na(1), one Na(2), one La(1), one La(2), and two equivalent Ti(2) atoms. In the ninth O site, O(9) is bonded in a 4-coordinate geometry to one Na(1), one Na(2), one La(1), one La(2), and two equivalent Ti(2) atoms. In the tenth O site, O(10) is bonded in a 2-coordinate geometry to one Na(1), one Sr(1), one Sr(2), one La(1), and two equivalent Ti(1) atoms. In the eleventh O site, O(11) is bonded in a 4-coordinate geometry to one Na(1), one Na(2), one La(1), one La(2), and two equivalent Ti(2) atoms. is represented by the CIF card [CIF]
data_Na3Sr4La3Ti10O30
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.554
_cell_length_b   27.764
_cell_length_c   7.889
_cell_angle_alpha   44.734
_cell_angle_beta   135.256
_cell_angle_gamma   120.302
_symmetry_Int_Tables_number   1
_cell_volume   602.660
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.500  0.699  0.252  1.0
  Na  Na1  1  0.500  0.500  0.250  1.0
  Na  Na2  1  0.500  0.301  0.249  1.0
  Sr  Sr3  1  0.500  0.898  0.752  1.0
  Sr  Sr4  1  0.500  0.900  0.250  1.0
  Sr  Sr5  1  0.500  0.102  0.744  1.0
  Sr  Sr6  1  0.500  0.100  0.248  1.0
  La  La7  1  0.500  0.699  0.754  1.0
  La  La8  1  0.500  0.500  0.750  1.0
  La  La9  1  0.500  0.301  0.750  1.0
  Ti  Ti10  1  0.003  0.797  0.508  1.0
  Ti  Ti11  1  0.001  0.599  0.503  1.0
  Ti  Ti12  1  0.997  0.797  0.005  1.0
  Ti  Ti13  1  0.999  0.401  0.498  1.0
  Ti  Ti14  1  0.999  0.599  0.002  1.0
  Ti  Ti15  1  0.001  0.401  0.999  1.0
  Ti  Ti16  1  0.003  0.203  0.995  1.0
  Ti  Ti17  1  0.000  0.000  1.000  1.0
  Ti  Ti18  1  0.997  0.203  0.492  1.0
  Ti  Ti19  1  0.000  0.000  0.500  1.0
  O  O20  1  0.000  0.000  0.750  1.0
  O  O21  1  0.049  0.899  0.776  1.0
  O  O22  1  0.077  0.698  0.787  1.0
  O  O23  1  0.013  0.797  0.264  1.0
  O  O24  1  0.500  0.991  0.274  1.0
  O  O25  1  0.500  0.810  0.725  1.0
  O  O26  1  0.083  0.500  0.784  1.0
  O  O27  1  0.000  0.599  0.252  1.0
  O  O28  1  0.500  0.616  0.718  1.0
  O  O29  1  0.500  0.785  0.296  1.0
  O  O30  1  0.987  0.797  0.751  1.0
  O  O31  1  0.951  0.899  0.227  1.0
  O  O32  1  0.077  0.302  0.779  1.0
  O  O33  1  0.013  0.203  0.749  1.0
  O  O34  1  1.000  0.401  0.248  1.0
  O  O35  1  0.500  0.583  0.300  1.0
  O  O36  1  0.500  0.417  0.716  1.0
  O  O37  1  1.000  0.599  0.752  1.0
  O  O38  1  0.923  0.698  0.210  1.0
  O  O39  1  0.049  0.101  0.770  1.0
  O  O40  1  0.987  0.203  0.236  1.0
  O  O41  1  0.500  0.384  0.296  1.0
  O  O42  1  0.500  0.215  0.719  1.0
  O  O43  1  0.000  0.401  0.749  1.0
  O  O44  1  0.917  0.500  0.201  1.0
  O  O45  1  0.500  0.190  0.273  1.0
  O  O46  1  0.500  0.009  0.727  1.0
  O  O47  1  0.923  0.302  0.202  1.0
  O  O48  1  0.951  0.101  0.221  1.0
  O  O49  1  0.000  0.000  0.250  1.0
[/CIF]
.
The material structure described by Na3Sr4La3Ti10O30 crystallizes in the orthorhombic Fmm2 space group. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded to one O(10), one O(11), one O(6), one O(9), two equivalent O(4), two equivalent O(8), and four equivalent O(3) atoms to form distorted NaO12 cuboctahedra that share corners with four equivalent Na(1)O12 cuboctahedra, corners with four equivalent Na(2)O12 cuboctahedra, corners with four equivalent Sr(2)O12 cuboctahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra, faces with four equivalent La(1)O12 cuboctahedra, faces with four equivalent Ti(1)O6 octahedra, and faces with four equivalent Ti(2)O6 octahedra. In the second Na site, Na(2) is bonded to two equivalent O(11), two equivalent O(9), four equivalent O(7), and four equivalent O(8) atoms to form distorted NaO12 cuboctahedra that share corners with four equivalent Na(2)O12 cuboctahedra, corners with eight equivalent Na(1)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, faces with four equivalent La(2)O12 cuboctahedra, and faces with eight equivalent Ti(2)O6 octahedra. There are two inequivalent Sr sites. In the first Sr site, Sr(1) is bonded to one O(10), one O(6), two equivalent O(1), two equivalent O(4), two equivalent O(5), and four equivalent O(2) atoms to form distorted SrO12 cuboctahedra that share corners with four equivalent La(1)O12 cuboctahedra, corners with eight equivalent Sr(1)O12 cuboctahedra,  a faceface with one Na(1)O12 cuboctahedra, faces with five equivalent Sr(2)O12 cuboctahedra, faces with four equivalent Ti(1)O6 octahedra, and faces with four equivalent Ti(3)O6 octahedra. In the second Sr site, Sr(2) is bonded to one O(10), one O(6), two equivalent O(1), two equivalent O(4), two equivalent O(5), and four equivalent O(2) atoms to form SrO12 cuboctahedra that share corners with four equivalent Na(1)O12 cuboctahedra, corners with eight equivalent Sr(2)O12 cuboctahedra,  a faceface with one La(1)O12 cuboctahedra, faces with five equivalent Sr(1)O12 cuboctahedra, faces with four equivalent Ti(1)O6 octahedra, and faces with four equivalent Ti(3)O6 octahedra. There are two inequivalent La sites. In the first La site, La(1) is bonded to one O(10), one O(11), one O(6), one O(9), two equivalent O(4), two equivalent O(8), and four equivalent O(3) atoms to form distorted LaO12 cuboctahedra that share corners with four equivalent Sr(1)O12 cuboctahedra, corners with four equivalent La(1)O12 cuboctahedra, corners with four equivalent La(2)O12 cuboctahedra,  a faceface with one Na(2)O12 cuboctahedra,  a faceface with one Sr(2)O12 cuboctahedra, faces with four equivalent Na(1)O12 cuboctahedra, faces with four equivalent Ti(1)O6 octahedra, and faces with four equivalent Ti(2)O6 octahedra. In the second La site, La(2) is bonded to two equivalent O(11), two equivalent O(9), four equivalent O(7), and four equivalent O(8) atoms to form distorted LaO12 cuboctahedra that share corners with four equivalent La(2)O12 cuboctahedra, corners with eight equivalent La(1)O12 cuboctahedra, faces with two equivalent Na(1)O12 cuboctahedra, faces with four equivalent Na(2)O12 cuboctahedra, and faces with eight equivalent Ti(2)O6 octahedra. There are three inequivalent Ti sites. In the first Ti site, Ti(1) is bonded to one O(10), one O(2), one O(3), one O(6), and two equivalent O(4) atoms to form TiO6 octahedra that share  a cornercorner with one Ti(2)O6 octahedra,  a cornercorner with one Ti(3)O6 octahedra, corners with four equivalent Ti(1)O6 octahedra, faces with two equivalent Na(1)O12 cuboctahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Sr(2)O12 cuboctahedra, and faces with two equivalent La(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 3-18°. In the second Ti site, Ti(2) is bonded to one O(11), one O(3), one O(7), one O(9), and two equivalent O(8) atoms to form TiO6 octahedra that share  a cornercorner with one Ti(1)O6 octahedra, corners with five equivalent Ti(2)O6 octahedra, faces with two equivalent Na(1)O12 cuboctahedra, faces with two equivalent Na(2)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, and faces with two equivalent La(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-19°. In the third Ti site, Ti(3) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(5) atoms to form TiO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra, corners with four equivalent Ti(3)O6 octahedra, faces with four equivalent Sr(1)O12 cuboctahedra, and faces with four equivalent Sr(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-11°. There are eleven inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to two equivalent Sr(1), two equivalent Sr(2), and two equivalent Ti(3) atoms. In the second O site, O(2) is bonded in a 6-coordinate geometry to two equivalent Sr(1), two equivalent Sr(2), one Ti(1), and one Ti(3) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to two equivalent Na(1), two equivalent La(1), one Ti(1), and one Ti(2) atom. In the fourth O site, O(4) is bonded in a distorted linear geometry to one Na(1), one Sr(1), one Sr(2), one La(1), and two equivalent Ti(1) atoms. In the fifth O site, O(5) is bonded in a 2-coordinate geometry to two equivalent Sr(1), two equivalent Sr(2), and two equivalent Ti(3) atoms. In the sixth O site, O(6) is bonded in a 2-coordinate geometry to one Na(1), one Sr(1), one Sr(2), one La(1), and two equivalent Ti(1) atoms. In the seventh O site, O(7) is bonded in a 4-coordinate geometry to two equivalent Na(2), two equivalent La(2), and two equivalent Ti(2) atoms. In the eighth O site, O(8) is bonded in a distorted linear geometry to one Na(1), one Na(2), one La(1), one La(2), and two equivalent Ti(2) atoms. In the ninth O site, O(9) is bonded in a 4-coordinate geometry to one Na(1), one Na(2), one La(1), one La(2), and two equivalent Ti(2) atoms. In the tenth O site, O(10) is bonded in a 2-coordinate geometry to one Na(1), one Sr(1), one Sr(2), one La(1), and two equivalent Ti(1) atoms. In the eleventh O site, O(11) is bonded in a 4-coordinate geometry to one Na(1), one Na(2), one La(1), one La(2), and two equivalent Ti(2) atoms. is represented by the CIF card [CIF]
data_Na3Sr4La3Ti10O30
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.554
_cell_length_b   27.764
_cell_length_c   7.889
_cell_angle_alpha   44.734
_cell_angle_beta   135.256
_cell_angle_gamma   120.302
_symmetry_Int_Tables_number   1
_cell_volume   602.660
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.500  0.699  0.252  1.0
  Na  Na1  1  0.500  0.500  0.250  1.0
  Na  Na2  1  0.500  0.301  0.249  1.0
  Sr  Sr3  1  0.500  0.898  0.752  1.0
  Sr  Sr4  1  0.500  0.900  0.250  1.0
  Sr  Sr5  1  0.500  0.102  0.744  1.0
  Sr  Sr6  1  0.500  0.100  0.248  1.0
  La  La7  1  0.500  0.699  0.754  1.0
  La  La8  1  0.500  0.500  0.750  1.0
  La  La9  1  0.500  0.301  0.750  1.0
  Ti  Ti10  1  0.003  0.797  0.508  1.0
  Ti  Ti11  1  0.001  0.599  0.503  1.0
  Ti  Ti12  1  0.997  0.797  0.005  1.0
  Ti  Ti13  1  0.999  0.401  0.498  1.0
  Ti  Ti14  1  0.999  0.599  0.002  1.0
  Ti  Ti15  1  0.001  0.401  0.999  1.0
  Ti  Ti16  1  0.003  0.203  0.995  1.0
  Ti  Ti17  1  0.000  0.000  1.000  1.0
  Ti  Ti18  1  0.997  0.203  0.492  1.0
  Ti  Ti19  1  0.000  0.000  0.500  1.0
  O  O20  1  0.000  0.000  0.750  1.0
  O  O21  1  0.049  0.899  0.776  1.0
  O  O22  1  0.077  0.698  0.787  1.0
  O  O23  1  0.013  0.797  0.264  1.0
  O  O24  1  0.500  0.991  0.274  1.0
  O  O25  1  0.500  0.810  0.725  1.0
  O  O26  1  0.083  0.500  0.784  1.0
  O  O27  1  0.000  0.599  0.252  1.0
  O  O28  1  0.500  0.616  0.718  1.0
  O  O29  1  0.500  0.785  0.296  1.0
  O  O30  1  0.987  0.797  0.751  1.0
  O  O31  1  0.951  0.899  0.227  1.0
  O  O32  1  0.077  0.302  0.779  1.0
  O  O33  1  0.013  0.203  0.749  1.0
  O  O34  1  1.000  0.401  0.248  1.0
  O  O35  1  0.500  0.583  0.300  1.0
  O  O36  1  0.500  0.417  0.716  1.0
  O  O37  1  1.000  0.599  0.752  1.0
  O  O38  1  0.923  0.698  0.210  1.0
  O  O39  1  0.049  0.101  0.770  1.0
  O  O40  1  0.987  0.203  0.236  1.0
  O  O41  1  0.500  0.384  0.296  1.0
  O  O42  1  0.500  0.215  0.719  1.0
  O  O43  1  0.000  0.401  0.749  1.0
  O  O44  1  0.917  0.500  0.201  1.0
  O  O45  1  0.500  0.190  0.273  1.0
  O  O46  1  0.500  0.009  0.727  1.0
  O  O47  1  0.923  0.302  0.202  1.0
  O  O48  1  0.951  0.101  0.221  1.0
  O  O49  1  0.000  0.000  0.250  1.0
[/CIF]
.