The material structure described by Co3Bi(CO)9 is Indium-like structured and crystallizes in the hexagonal P6_3mc space group. The structure is zero-dimensional and consists of two Co3Bi(CO)9 clusters. Co(1) is bonded to one C(2), one C(3), two equivalent C(1), and one Bi(1) atom to form distorted edge-sharing CoBiC4 trigonal pyramids. There are three inequivalent C sites. In the first C site, C(1) is bonded in a 3-coordinate geometry to two equivalent Co(1) and one O(2) atom. In the second C site, C(2) is bonded in a linear geometry to one Co(1) and one O(1) atom. In the third C site, C(3) is bonded in a linear geometry to one Co(1) and one O(3) atom. Bi(1) is bonded in a 3-coordinate geometry to three equivalent Co(1) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(3) atom. is represented by the CIF file [CIF]
data_Co3Bi(CO)9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.285
_cell_length_b   11.285
_cell_length_c   7.625
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   840.970
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.258  0.515  0.314  1.0
  Co  Co1  1  0.742  0.485  0.814  1.0
  Co  Co2  1  0.515  0.258  0.814  1.0
  Co  Co3  1  0.742  0.258  0.814  1.0
  Co  Co4  1  0.258  0.742  0.314  1.0
  Co  Co5  1  0.485  0.742  0.314  1.0
  Bi  Bi6  1  0.667  0.333  0.528  1.0
  Bi  Bi7  1  0.333  0.667  0.028  1.0
  C  C8  1  0.444  0.556  0.329  1.0
  C  C9  1  0.187  0.813  0.173  1.0
  C  C10  1  0.437  0.219  0.022  1.0
  C  C11  1  0.813  0.625  0.673  1.0
  C  C12  1  0.219  0.781  0.522  1.0
  C  C13  1  0.781  0.563  0.022  1.0
  C  C14  1  0.625  0.813  0.173  1.0
  C  C15  1  0.889  0.444  0.829  1.0
  C  C16  1  0.781  0.219  0.022  1.0
  C  C17  1  0.187  0.375  0.173  1.0
  C  C18  1  0.375  0.187  0.673  1.0
  C  C19  1  0.111  0.556  0.329  1.0
  C  C20  1  0.813  0.187  0.673  1.0
  C  C21  1  0.556  0.444  0.829  1.0
  C  C22  1  0.556  0.111  0.829  1.0
  C  C23  1  0.219  0.437  0.522  1.0
  C  C24  1  0.563  0.781  0.522  1.0
  C  C25  1  0.444  0.889  0.329  1.0
  O  O26  1  0.863  0.726  0.592  1.0
  O  O27  1  0.496  0.991  0.844  1.0
  O  O28  1  0.137  0.863  0.092  1.0
  O  O29  1  0.274  0.137  0.592  1.0
  O  O30  1  0.009  0.504  0.844  1.0
  O  O31  1  0.617  0.808  0.658  1.0
  O  O32  1  0.504  0.496  0.344  1.0
  O  O33  1  0.863  0.137  0.592  1.0
  O  O34  1  0.496  0.504  0.844  1.0
  O  O35  1  0.192  0.808  0.658  1.0
  O  O36  1  0.137  0.274  0.092  1.0
  O  O37  1  0.726  0.863  0.092  1.0
  O  O38  1  0.192  0.383  0.658  1.0
  O  O39  1  0.504  0.009  0.344  1.0
  O  O40  1  0.383  0.192  0.158  1.0
  O  O41  1  0.808  0.192  0.158  1.0
  O  O42  1  0.808  0.617  0.158  1.0
  O  O43  1  0.991  0.496  0.344  1.0
[/CIF]
.
The material structure described by Co3Bi(CO)9 is Indium-like structured and crystallizes in the hexagonal P6_3mc space group. The structure is zero-dimensional and consists of two Co3Bi(CO)9 clusters. Co(1) is bonded to one C(2), one C(3), two equivalent C(1), and one Bi(1) atom to form distorted edge-sharing CoBiC4 trigonal pyramids. There are three inequivalent C sites. In the first C site, C(1) is bonded in a 3-coordinate geometry to two equivalent Co(1) and one O(2) atom. In the second C site, C(2) is bonded in a linear geometry to one Co(1) and one O(1) atom. In the third C site, C(3) is bonded in a linear geometry to one Co(1) and one O(3) atom. Bi(1) is bonded in a 3-coordinate geometry to three equivalent Co(1) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(3) atom. is represented by the CIF file [CIF]
data_Co3Bi(CO)9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.285
_cell_length_b   11.285
_cell_length_c   7.625
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   840.970
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.258  0.515  0.314  1.0
  Co  Co1  1  0.742  0.485  0.814  1.0
  Co  Co2  1  0.515  0.258  0.814  1.0
  Co  Co3  1  0.742  0.258  0.814  1.0
  Co  Co4  1  0.258  0.742  0.314  1.0
  Co  Co5  1  0.485  0.742  0.314  1.0
  Bi  Bi6  1  0.667  0.333  0.528  1.0
  Bi  Bi7  1  0.333  0.667  0.028  1.0
  C  C8  1  0.444  0.556  0.329  1.0
  C  C9  1  0.187  0.813  0.173  1.0
  C  C10  1  0.437  0.219  0.022  1.0
  C  C11  1  0.813  0.625  0.673  1.0
  C  C12  1  0.219  0.781  0.522  1.0
  C  C13  1  0.781  0.563  0.022  1.0
  C  C14  1  0.625  0.813  0.173  1.0
  C  C15  1  0.889  0.444  0.829  1.0
  C  C16  1  0.781  0.219  0.022  1.0
  C  C17  1  0.187  0.375  0.173  1.0
  C  C18  1  0.375  0.187  0.673  1.0
  C  C19  1  0.111  0.556  0.329  1.0
  C  C20  1  0.813  0.187  0.673  1.0
  C  C21  1  0.556  0.444  0.829  1.0
  C  C22  1  0.556  0.111  0.829  1.0
  C  C23  1  0.219  0.437  0.522  1.0
  C  C24  1  0.563  0.781  0.522  1.0
  C  C25  1  0.444  0.889  0.329  1.0
  O  O26  1  0.863  0.726  0.592  1.0
  O  O27  1  0.496  0.991  0.844  1.0
  O  O28  1  0.137  0.863  0.092  1.0
  O  O29  1  0.274  0.137  0.592  1.0
  O  O30  1  0.009  0.504  0.844  1.0
  O  O31  1  0.617  0.808  0.658  1.0
  O  O32  1  0.504  0.496  0.344  1.0
  O  O33  1  0.863  0.137  0.592  1.0
  O  O34  1  0.496  0.504  0.844  1.0
  O  O35  1  0.192  0.808  0.658  1.0
  O  O36  1  0.137  0.274  0.092  1.0
  O  O37  1  0.726  0.863  0.092  1.0
  O  O38  1  0.192  0.383  0.658  1.0
  O  O39  1  0.504  0.009  0.344  1.0
  O  O40  1  0.383  0.192  0.158  1.0
  O  O41  1  0.808  0.192  0.158  1.0
  O  O42  1  0.808  0.617  0.158  1.0
  O  O43  1  0.991  0.496  0.344  1.0
[/CIF]
.