The crystal structure described by NaMoSbO5 crystallizes in the monoclinic P2_1/c space group. Na(1) is bonded to one O(1), one O(5), two equivalent O(2), and two equivalent O(3) atoms to form distorted NaO6 octahedra that share corners with two equivalent Na(1)O6 octahedra, corners with five equivalent Mo(1)O4 tetrahedra, and  an edgeedge with one Na(1)O6 octahedra. The corner-sharing octahedral tilt angles are 80°. Mo(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form MoO4 tetrahedra that share corners with five equivalent Na(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 42-53°. Sb(1) is bonded in a rectangular see-saw-like geometry to one O(1), one O(4), and two equivalent O(5) atoms. There are five inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Na(1), one Mo(1), and one Sb(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent Na(1) and one Mo(1) atom. In the third O site, O(3) is bonded in a distorted T-shaped geometry to two equivalent Na(1) and one Mo(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Mo(1) and one Sb(1) atom. In the fifth O site, O(5) is bonded in a trigonal planar geometry to one Na(1) and two equivalent Sb(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_NaSbMoO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.201
_cell_length_b   5.736
_cell_length_c   8.698
_cell_angle_alpha   77.307
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   545.135
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.360  0.467  0.585  1.0
  Na  Na1  1  0.140  0.967  0.585  1.0
  Na  Na2  1  0.860  0.033  0.415  1.0
  Na  Na3  1  0.640  0.533  0.415  1.0
  Sb  Sb4  1  0.164  0.180  0.950  1.0
  Sb  Sb5  1  0.836  0.820  0.050  1.0
  Sb  Sb6  1  0.664  0.320  0.050  1.0
  Sb  Sb7  1  0.336  0.680  0.950  1.0
  Mo  Mo8  1  0.408  0.058  0.297  1.0
  Mo  Mo9  1  0.092  0.558  0.297  1.0
  Mo  Mo10  1  0.592  0.942  0.703  1.0
  Mo  Mo11  1  0.908  0.442  0.703  1.0
  O  O12  1  0.958  0.749  0.251  1.0
  O  O13  1  0.819  0.341  0.564  1.0
  O  O14  1  0.542  0.249  0.251  1.0
  O  O15  1  0.953  0.741  0.628  1.0
  O  O16  1  0.173  0.575  0.112  1.0
  O  O17  1  0.327  0.075  0.112  1.0
  O  O18  1  0.453  0.759  0.372  1.0
  O  O19  1  0.547  0.241  0.628  1.0
  O  O20  1  0.737  0.549  0.166  1.0
  O  O21  1  0.458  0.751  0.749  1.0
  O  O22  1  0.319  0.159  0.436  1.0
  O  O23  1  0.237  0.951  0.834  1.0
  O  O24  1  0.681  0.841  0.564  1.0
  O  O25  1  0.673  0.925  0.888  1.0
  O  O26  1  0.263  0.451  0.834  1.0
  O  O27  1  0.047  0.259  0.372  1.0
  O  O28  1  0.827  0.425  0.888  1.0
  O  O29  1  0.042  0.251  0.749  1.0
  O  O30  1  0.763  0.049  0.166  1.0
  O  O31  1  0.181  0.659  0.436  1.0
[/CIF]
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The crystal structure described by NaMoSbO5 crystallizes in the monoclinic P2_1/c space group. Na(1) is bonded to one O(1), one O(5), two equivalent O(2), and two equivalent O(3) atoms to form distorted NaO6 octahedra that share corners with two equivalent Na(1)O6 octahedra, corners with five equivalent Mo(1)O4 tetrahedra, and  an edgeedge with one Na(1)O6 octahedra. The corner-sharing octahedral tilt angles are 80°. Mo(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form MoO4 tetrahedra that share corners with five equivalent Na(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 42-53°. Sb(1) is bonded in a rectangular see-saw-like geometry to one O(1), one O(4), and two equivalent O(5) atoms. There are five inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Na(1), one Mo(1), and one Sb(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent Na(1) and one Mo(1) atom. In the third O site, O(3) is bonded in a distorted T-shaped geometry to two equivalent Na(1) and one Mo(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Mo(1) and one Sb(1) atom. In the fifth O site, O(5) is bonded in a trigonal planar geometry to one Na(1) and two equivalent Sb(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_NaSbMoO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.201
_cell_length_b   5.736
_cell_length_c   8.698
_cell_angle_alpha   77.307
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   545.135
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.360  0.467  0.585  1.0
  Na  Na1  1  0.140  0.967  0.585  1.0
  Na  Na2  1  0.860  0.033  0.415  1.0
  Na  Na3  1  0.640  0.533  0.415  1.0
  Sb  Sb4  1  0.164  0.180  0.950  1.0
  Sb  Sb5  1  0.836  0.820  0.050  1.0
  Sb  Sb6  1  0.664  0.320  0.050  1.0
  Sb  Sb7  1  0.336  0.680  0.950  1.0
  Mo  Mo8  1  0.408  0.058  0.297  1.0
  Mo  Mo9  1  0.092  0.558  0.297  1.0
  Mo  Mo10  1  0.592  0.942  0.703  1.0
  Mo  Mo11  1  0.908  0.442  0.703  1.0
  O  O12  1  0.958  0.749  0.251  1.0
  O  O13  1  0.819  0.341  0.564  1.0
  O  O14  1  0.542  0.249  0.251  1.0
  O  O15  1  0.953  0.741  0.628  1.0
  O  O16  1  0.173  0.575  0.112  1.0
  O  O17  1  0.327  0.075  0.112  1.0
  O  O18  1  0.453  0.759  0.372  1.0
  O  O19  1  0.547  0.241  0.628  1.0
  O  O20  1  0.737  0.549  0.166  1.0
  O  O21  1  0.458  0.751  0.749  1.0
  O  O22  1  0.319  0.159  0.436  1.0
  O  O23  1  0.237  0.951  0.834  1.0
  O  O24  1  0.681  0.841  0.564  1.0
  O  O25  1  0.673  0.925  0.888  1.0
  O  O26  1  0.263  0.451  0.834  1.0
  O  O27  1  0.047  0.259  0.372  1.0
  O  O28  1  0.827  0.425  0.888  1.0
  O  O29  1  0.042  0.251  0.749  1.0
  O  O30  1  0.763  0.049  0.166  1.0
  O  O31  1  0.181  0.659  0.436  1.0
[/CIF]
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