The material described by NH4SbCl6 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four ammonium molecules and four SbCl6 clusters. In each SbCl6 cluster, Sb(1) is bonded in an octahedral geometry to two equivalent Cl(1), two equivalent Cl(2), and two equivalent Cl(3) atoms. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Sb(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Sb(1) atom. is represented by the CIF file [CIF]
data_SbH4NCl6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.962
_cell_length_b   6.962
_cell_length_c   12.325
_cell_angle_alpha   79.597
_cell_angle_beta   79.597
_cell_angle_gamma   55.230
_symmetry_Int_Tables_number   1
_cell_volume   480.394
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.000  0.500  0.000  1.0
  Sb  Sb1  1  0.500  0.000  0.500  1.0
  H  H2  1  0.015  0.981  0.319  1.0
  H  H3  1  0.132  0.729  0.262  1.0
  H  H4  1  0.981  0.015  0.819  1.0
  H  H5  1  0.729  0.132  0.762  1.0
  H  H6  1  0.271  0.868  0.238  1.0
  H  H7  1  0.019  0.985  0.181  1.0
  H  H8  1  0.868  0.271  0.738  1.0
  H  H9  1  0.985  0.019  0.681  1.0
  N  N10  1  0.109  0.891  0.250  1.0
  N  N11  1  0.891  0.109  0.750  1.0
  Cl  Cl12  1  0.534  0.307  0.390  1.0
  Cl  Cl13  1  0.307  0.534  0.890  1.0
  Cl  Cl14  1  0.794  0.906  0.034  1.0
  Cl  Cl15  1  0.201  0.375  0.165  1.0
  Cl  Cl16  1  0.625  0.799  0.335  1.0
  Cl  Cl17  1  0.906  0.794  0.534  1.0
  Cl  Cl18  1  0.094  0.206  0.466  1.0
  Cl  Cl19  1  0.375  0.201  0.665  1.0
  Cl  Cl20  1  0.799  0.625  0.835  1.0
  Cl  Cl21  1  0.206  0.094  0.966  1.0
  Cl  Cl22  1  0.693  0.466  0.110  1.0
  Cl  Cl23  1  0.466  0.693  0.610  1.0
[/CIF]
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The material described by NH4SbCl6 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four ammonium molecules and four SbCl6 clusters. In each SbCl6 cluster, Sb(1) is bonded in an octahedral geometry to two equivalent Cl(1), two equivalent Cl(2), and two equivalent Cl(3) atoms. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Sb(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Sb(1) atom. is represented by the CIF file [CIF]
data_SbH4NCl6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.962
_cell_length_b   6.962
_cell_length_c   12.325
_cell_angle_alpha   79.597
_cell_angle_beta   79.597
_cell_angle_gamma   55.230
_symmetry_Int_Tables_number   1
_cell_volume   480.394
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.000  0.500  0.000  1.0
  Sb  Sb1  1  0.500  0.000  0.500  1.0
  H  H2  1  0.015  0.981  0.319  1.0
  H  H3  1  0.132  0.729  0.262  1.0
  H  H4  1  0.981  0.015  0.819  1.0
  H  H5  1  0.729  0.132  0.762  1.0
  H  H6  1  0.271  0.868  0.238  1.0
  H  H7  1  0.019  0.985  0.181  1.0
  H  H8  1  0.868  0.271  0.738  1.0
  H  H9  1  0.985  0.019  0.681  1.0
  N  N10  1  0.109  0.891  0.250  1.0
  N  N11  1  0.891  0.109  0.750  1.0
  Cl  Cl12  1  0.534  0.307  0.390  1.0
  Cl  Cl13  1  0.307  0.534  0.890  1.0
  Cl  Cl14  1  0.794  0.906  0.034  1.0
  Cl  Cl15  1  0.201  0.375  0.165  1.0
  Cl  Cl16  1  0.625  0.799  0.335  1.0
  Cl  Cl17  1  0.906  0.794  0.534  1.0
  Cl  Cl18  1  0.094  0.206  0.466  1.0
  Cl  Cl19  1  0.375  0.201  0.665  1.0
  Cl  Cl20  1  0.799  0.625  0.835  1.0
  Cl  Cl21  1  0.206  0.094  0.966  1.0
  Cl  Cl22  1  0.693  0.466  0.110  1.0
  Cl  Cl23  1  0.466  0.693  0.610  1.0
[/CIF]
.