The structure described by CaAgF5 crystallizes in the triclinic P-1 space group. Ca(1) is bonded in a 2-coordinate geometry to one F(1), one F(2), one F(3), one F(4), and one F(5) atom. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 6-coordinate geometry to two equivalent F(1), two equivalent F(3), and two equivalent F(4) atoms. In the second Ag site, Ag(2) is bonded in a 6-coordinate geometry to two equivalent F(1), two equivalent F(2), and two equivalent F(5) atoms. There are five inequivalent F sites. In the first F site, F(1) is bonded in a 3-coordinate geometry to one Ca(1), one Ag(1), and one Ag(2) atom. In the second F site, F(2) is bonded in a linear geometry to one Ca(1) and one Ag(2) atom. In the third F site, F(3) is bonded in a linear geometry to one Ca(1) and one Ag(1) atom. In the fourth F site, F(4) is bonded in a distorted L-shaped geometry to one Ca(1) and one Ag(1) atom. In the fifth F site, F(5) is bonded in a distorted bent 120 degrees geometry to one Ca(1) and one Ag(2) atom. is represented by the CIF file [CIF]
data_CaAgF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.751
_cell_length_b   5.817
_cell_length_c   8.121
_cell_angle_alpha   110.445
_cell_angle_beta   96.323
_cell_angle_gamma   108.870
_symmetry_Int_Tables_number   1
_cell_volume   233.162
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ca  Ca0  1  0.459  0.458  0.254  1.0
  Ca  Ca1  1  0.541  0.542  0.746  1.0
  Ag  Ag2  1  0.000  0.000  0.000  1.0
  Ag  Ag3  1  0.000  0.000  0.500  1.0
  F  F4  1  0.900  0.898  0.744  1.0
  F  F5  1  0.100  0.102  0.256  1.0
  F  F6  1  0.261  0.779  0.628  1.0
  F  F7  1  0.789  0.258  0.880  1.0
  F  F8  1  0.326  0.303  0.979  1.0
  F  F9  1  0.305  0.323  0.531  1.0
  F  F10  1  0.674  0.697  0.021  1.0
  F  F11  1  0.695  0.677  0.469  1.0
  F  F12  1  0.211  0.742  0.120  1.0
  F  F13  1  0.739  0.221  0.372  1.0
[/CIF]
.
The structure described by CaAgF5 crystallizes in the triclinic P-1 space group. Ca(1) is bonded in a 2-coordinate geometry to one F(1), one F(2), one F(3), one F(4), and one F(5) atom. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 6-coordinate geometry to two equivalent F(1), two equivalent F(3), and two equivalent F(4) atoms. In the second Ag site, Ag(2) is bonded in a 6-coordinate geometry to two equivalent F(1), two equivalent F(2), and two equivalent F(5) atoms. There are five inequivalent F sites. In the first F site, F(1) is bonded in a 3-coordinate geometry to one Ca(1), one Ag(1), and one Ag(2) atom. In the second F site, F(2) is bonded in a linear geometry to one Ca(1) and one Ag(2) atom. In the third F site, F(3) is bonded in a linear geometry to one Ca(1) and one Ag(1) atom. In the fourth F site, F(4) is bonded in a distorted L-shaped geometry to one Ca(1) and one Ag(1) atom. In the fifth F site, F(5) is bonded in a distorted bent 120 degrees geometry to one Ca(1) and one Ag(2) atom. is represented by the CIF file [CIF]
data_CaAgF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.751
_cell_length_b   5.817
_cell_length_c   8.121
_cell_angle_alpha   110.445
_cell_angle_beta   96.323
_cell_angle_gamma   108.870
_symmetry_Int_Tables_number   1
_cell_volume   233.162
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ca  Ca0  1  0.459  0.458  0.254  1.0
  Ca  Ca1  1  0.541  0.542  0.746  1.0
  Ag  Ag2  1  0.000  0.000  0.000  1.0
  Ag  Ag3  1  0.000  0.000  0.500  1.0
  F  F4  1  0.900  0.898  0.744  1.0
  F  F5  1  0.100  0.102  0.256  1.0
  F  F6  1  0.261  0.779  0.628  1.0
  F  F7  1  0.789  0.258  0.880  1.0
  F  F8  1  0.326  0.303  0.979  1.0
  F  F9  1  0.305  0.323  0.531  1.0
  F  F10  1  0.674  0.697  0.021  1.0
  F  F11  1  0.695  0.677  0.469  1.0
  F  F12  1  0.211  0.742  0.120  1.0
  F  F13  1  0.739  0.221  0.372  1.0
[/CIF]
.