The crystal structure described by NiC4H10(N4S)2 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four NiC4H10(N4S)2 clusters. Ni(1) is bonded in a rectangular see-saw-like geometry to two equivalent N(1) and two equivalent N(3) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one N(4) atom. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one N(2), one N(3), and one S(1) atom. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Ni(1), one C(1), and one H(1) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(1), one C(2), and one H(2) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Ni(1), one C(2), and one H(3) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(1), one H(4), and one H(5) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(4) atom. S(1) is bonded in a single-bond geometry to one C(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_NiH10C4(SN4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.506
_cell_length_b   8.506
_cell_length_c   9.205
_cell_angle_alpha   71.397
_cell_angle_beta   71.397
_cell_angle_gamma   56.607
_symmetry_Int_Tables_number   1
_cell_volume   518.257
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ni  Ni0  1  0.110  0.890  0.250  1.0
  Ni  Ni1  1  0.890  0.110  0.750  1.0
  H  H2  1  0.764  0.114  0.221  1.0
  H  H3  1  0.886  0.236  0.279  1.0
  H  H4  1  0.236  0.886  0.779  1.0
  H  H5  1  0.114  0.764  0.721  1.0
  H  H6  1  0.904  0.669  0.045  1.0
  H  H7  1  0.331  0.096  0.455  1.0
  H  H8  1  0.096  0.331  0.955  1.0
  H  H9  1  0.669  0.904  0.545  1.0
  H  H10  1  0.366  0.589  0.151  1.0
  H  H11  1  0.411  0.634  0.349  1.0
  H  H12  1  0.634  0.411  0.849  1.0
  H  H13  1  0.589  0.366  0.651  1.0
  H  H14  1  0.547  0.121  0.124  1.0
  H  H15  1  0.879  0.453  0.376  1.0
  H  H16  1  0.453  0.879  0.876  1.0
  H  H17  1  0.121  0.547  0.624  1.0
  H  H18  1  0.600  0.898  0.103  1.0
  H  H19  1  0.102  0.400  0.397  1.0
  H  H20  1  0.400  0.102  0.897  1.0
  H  H21  1  0.898  0.600  0.603  1.0
  C  C22  1  0.825  0.902  0.135  1.0
  C  C23  1  0.098  0.175  0.365  1.0
  C  C24  1  0.175  0.098  0.865  1.0
  C  C25  1  0.902  0.825  0.635  1.0
  C  C26  1  0.148  0.627  0.089  1.0
  C  C27  1  0.373  0.852  0.411  1.0
  C  C28  1  0.852  0.373  0.911  1.0
  C  C29  1  0.627  0.148  0.589  1.0
  S  S30  1  0.287  0.447  0.981  1.0
  S  S31  1  0.553  0.713  0.519  1.0
  S  S32  1  0.713  0.553  0.019  1.0
  S  S33  1  0.447  0.287  0.481  1.0
  N  N34  1  0.878  0.987  0.191  1.0
  N  N35  1  0.013  0.122  0.309  1.0
  N  N36  1  0.122  0.013  0.809  1.0
  N  N37  1  0.987  0.878  0.691  1.0
  N  N38  1  0.953  0.727  0.091  1.0
  N  N39  1  0.273  0.047  0.409  1.0
  N  N40  1  0.047  0.273  0.909  1.0
  N  N41  1  0.727  0.953  0.591  1.0
  N  N42  1  0.219  0.674  0.165  1.0
  N  N43  1  0.326  0.781  0.335  1.0
  N  N44  1  0.781  0.326  0.835  1.0
  N  N45  1  0.674  0.219  0.665  1.0
  N  N46  1  0.645  0.982  0.111  1.0
  N  N47  1  0.018  0.355  0.389  1.0
  N  N48  1  0.355  0.018  0.889  1.0
  N  N49  1  0.982  0.645  0.611  1.0
[/CIF]
.
The crystal structure described by NiC4H10(N4S)2 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four NiC4H10(N4S)2 clusters. Ni(1) is bonded in a rectangular see-saw-like geometry to two equivalent N(1) and two equivalent N(3) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one N(4) atom. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one N(2), one N(3), and one S(1) atom. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Ni(1), one C(1), and one H(1) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(1), one C(2), and one H(2) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Ni(1), one C(2), and one H(3) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(1), one H(4), and one H(5) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(4) atom. S(1) is bonded in a single-bond geometry to one C(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_NiH10C4(SN4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.506
_cell_length_b   8.506
_cell_length_c   9.205
_cell_angle_alpha   71.397
_cell_angle_beta   71.397
_cell_angle_gamma   56.607
_symmetry_Int_Tables_number   1
_cell_volume   518.257
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ni  Ni0  1  0.110  0.890  0.250  1.0
  Ni  Ni1  1  0.890  0.110  0.750  1.0
  H  H2  1  0.764  0.114  0.221  1.0
  H  H3  1  0.886  0.236  0.279  1.0
  H  H4  1  0.236  0.886  0.779  1.0
  H  H5  1  0.114  0.764  0.721  1.0
  H  H6  1  0.904  0.669  0.045  1.0
  H  H7  1  0.331  0.096  0.455  1.0
  H  H8  1  0.096  0.331  0.955  1.0
  H  H9  1  0.669  0.904  0.545  1.0
  H  H10  1  0.366  0.589  0.151  1.0
  H  H11  1  0.411  0.634  0.349  1.0
  H  H12  1  0.634  0.411  0.849  1.0
  H  H13  1  0.589  0.366  0.651  1.0
  H  H14  1  0.547  0.121  0.124  1.0
  H  H15  1  0.879  0.453  0.376  1.0
  H  H16  1  0.453  0.879  0.876  1.0
  H  H17  1  0.121  0.547  0.624  1.0
  H  H18  1  0.600  0.898  0.103  1.0
  H  H19  1  0.102  0.400  0.397  1.0
  H  H20  1  0.400  0.102  0.897  1.0
  H  H21  1  0.898  0.600  0.603  1.0
  C  C22  1  0.825  0.902  0.135  1.0
  C  C23  1  0.098  0.175  0.365  1.0
  C  C24  1  0.175  0.098  0.865  1.0
  C  C25  1  0.902  0.825  0.635  1.0
  C  C26  1  0.148  0.627  0.089  1.0
  C  C27  1  0.373  0.852  0.411  1.0
  C  C28  1  0.852  0.373  0.911  1.0
  C  C29  1  0.627  0.148  0.589  1.0
  S  S30  1  0.287  0.447  0.981  1.0
  S  S31  1  0.553  0.713  0.519  1.0
  S  S32  1  0.713  0.553  0.019  1.0
  S  S33  1  0.447  0.287  0.481  1.0
  N  N34  1  0.878  0.987  0.191  1.0
  N  N35  1  0.013  0.122  0.309  1.0
  N  N36  1  0.122  0.013  0.809  1.0
  N  N37  1  0.987  0.878  0.691  1.0
  N  N38  1  0.953  0.727  0.091  1.0
  N  N39  1  0.273  0.047  0.409  1.0
  N  N40  1  0.047  0.273  0.909  1.0
  N  N41  1  0.727  0.953  0.591  1.0
  N  N42  1  0.219  0.674  0.165  1.0
  N  N43  1  0.326  0.781  0.335  1.0
  N  N44  1  0.781  0.326  0.835  1.0
  N  N45  1  0.674  0.219  0.665  1.0
  N  N46  1  0.645  0.982  0.111  1.0
  N  N47  1  0.018  0.355  0.389  1.0
  N  N48  1  0.355  0.018  0.889  1.0
  N  N49  1  0.982  0.645  0.611  1.0
[/CIF]
.