The structure described by FeBr(NO)3 is Indium-like structured and crystallizes in the hexagonal P6_3mc space group. The structure is zero-dimensional and consists of two FeBr(NO)3 clusters. Fe(1) is bonded in a tetrahedral geometry to three equivalent N(1) and one Br(1) atom. N(1) is bonded in a linear geometry to one Fe(1) and one O(1) atom. O(1) is bonded in a single-bond geometry to one N(1) atom. Br(1) is bonded in a single-bond geometry to one Fe(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_FeBr(NO)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.715
_cell_length_b   7.715
_cell_length_c   6.507
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   119.998
_symmetry_Int_Tables_number   1
_cell_volume   335.420
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Fe  Fe0  1  0.333  0.667  0.530  1.0
  Fe  Fe1  1  0.667  0.333  0.030  1.0
  Br  Br2  1  0.333  0.667  0.156  1.0
  Br  Br3  1  0.667  0.333  0.656  1.0
  N  N4  1  0.206  0.794  0.631  1.0
  N  N5  1  0.206  0.412  0.631  1.0
  N  N6  1  0.588  0.794  0.631  1.0
  N  N7  1  0.794  0.206  0.131  1.0
  N  N8  1  0.794  0.588  0.131  1.0
  N  N9  1  0.412  0.206  0.131  1.0
  O  O10  1  0.137  0.863  0.744  1.0
  O  O11  1  0.137  0.275  0.744  1.0
  O  O12  1  0.725  0.863  0.744  1.0
  O  O13  1  0.863  0.137  0.244  1.0
  O  O14  1  0.863  0.725  0.244  1.0
  O  O15  1  0.275  0.137  0.244  1.0
[/CIF]
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The structure described by FeBr(NO)3 is Indium-like structured and crystallizes in the hexagonal P6_3mc space group. The structure is zero-dimensional and consists of two FeBr(NO)3 clusters. Fe(1) is bonded in a tetrahedral geometry to three equivalent N(1) and one Br(1) atom. N(1) is bonded in a linear geometry to one Fe(1) and one O(1) atom. O(1) is bonded in a single-bond geometry to one N(1) atom. Br(1) is bonded in a single-bond geometry to one Fe(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_FeBr(NO)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.715
_cell_length_b   7.715
_cell_length_c   6.507
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   119.998
_symmetry_Int_Tables_number   1
_cell_volume   335.420
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Fe  Fe0  1  0.333  0.667  0.530  1.0
  Fe  Fe1  1  0.667  0.333  0.030  1.0
  Br  Br2  1  0.333  0.667  0.156  1.0
  Br  Br3  1  0.667  0.333  0.656  1.0
  N  N4  1  0.206  0.794  0.631  1.0
  N  N5  1  0.206  0.412  0.631  1.0
  N  N6  1  0.588  0.794  0.631  1.0
  N  N7  1  0.794  0.206  0.131  1.0
  N  N8  1  0.794  0.588  0.131  1.0
  N  N9  1  0.412  0.206  0.131  1.0
  O  O10  1  0.137  0.863  0.744  1.0
  O  O11  1  0.137  0.275  0.744  1.0
  O  O12  1  0.725  0.863  0.744  1.0
  O  O13  1  0.863  0.137  0.244  1.0
  O  O14  1  0.863  0.725  0.244  1.0
  O  O15  1  0.275  0.137  0.244  1.0
[/CIF]
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