The crystal structure described by Te(WO4)2 crystallizes in the monoclinic P2/c space group. W(1) is bonded to one O(1), one O(3), two equivalent O(2), and two equivalent O(4) atoms to form distorted WO6 octahedra that share corners with four equivalent Te(1)O6 octahedra and edges with two equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 39-58°. Te(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form distorted TeO6 octahedra that share corners with eight equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 39-58°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one W(1) and one Te(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent W(1) and one Te(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one W(1) and one Te(1) atom. In the fourth O site, O(4) is bonded in a water-like geometry to two equivalent W(1) atoms. is represented by the CIF card [CIF]
data_Te(WO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.749
_cell_length_b   5.279
_cell_length_c   10.914
_cell_angle_alpha   68.304
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   307.744
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.404  0.500  0.750  1.0
  Te  Te1  1  0.596  0.500  0.250  1.0
  W  W2  1  0.153  0.250  0.510  1.0
  W  W3  1  0.153  0.750  0.990  1.0
  W  W4  1  0.847  0.750  0.490  1.0
  W  W5  1  0.847  0.250  0.010  1.0
  O  O6  1  0.390  0.719  0.882  1.0
  O  O7  1  0.390  0.281  0.618  1.0
  O  O8  1  0.610  0.281  0.118  1.0
  O  O9  1  0.610  0.719  0.382  1.0
  O  O10  1  0.875  0.138  0.410  1.0
  O  O11  1  0.875  0.862  0.090  1.0
  O  O12  1  0.125  0.862  0.590  1.0
  O  O13  1  0.125  0.138  0.910  1.0
  O  O14  1  0.637  0.266  0.866  1.0
  O  O15  1  0.637  0.734  0.634  1.0
  O  O16  1  0.363  0.734  0.134  1.0
  O  O17  1  0.363  0.266  0.366  1.0
  O  O18  1  0.923  0.639  0.893  1.0
  O  O19  1  0.077  0.361  0.107  1.0
  O  O20  1  0.923  0.361  0.607  1.0
  O  O21  1  0.077  0.639  0.393  1.0
[/CIF]
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The crystal structure described by Te(WO4)2 crystallizes in the monoclinic P2/c space group. W(1) is bonded to one O(1), one O(3), two equivalent O(2), and two equivalent O(4) atoms to form distorted WO6 octahedra that share corners with four equivalent Te(1)O6 octahedra and edges with two equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 39-58°. Te(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form distorted TeO6 octahedra that share corners with eight equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 39-58°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one W(1) and one Te(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent W(1) and one Te(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one W(1) and one Te(1) atom. In the fourth O site, O(4) is bonded in a water-like geometry to two equivalent W(1) atoms. is represented by the CIF card [CIF]
data_Te(WO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.749
_cell_length_b   5.279
_cell_length_c   10.914
_cell_angle_alpha   68.304
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   307.744
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.404  0.500  0.750  1.0
  Te  Te1  1  0.596  0.500  0.250  1.0
  W  W2  1  0.153  0.250  0.510  1.0
  W  W3  1  0.153  0.750  0.990  1.0
  W  W4  1  0.847  0.750  0.490  1.0
  W  W5  1  0.847  0.250  0.010  1.0
  O  O6  1  0.390  0.719  0.882  1.0
  O  O7  1  0.390  0.281  0.618  1.0
  O  O8  1  0.610  0.281  0.118  1.0
  O  O9  1  0.610  0.719  0.382  1.0
  O  O10  1  0.875  0.138  0.410  1.0
  O  O11  1  0.875  0.862  0.090  1.0
  O  O12  1  0.125  0.862  0.590  1.0
  O  O13  1  0.125  0.138  0.910  1.0
  O  O14  1  0.637  0.266  0.866  1.0
  O  O15  1  0.637  0.734  0.634  1.0
  O  O16  1  0.363  0.734  0.134  1.0
  O  O17  1  0.363  0.266  0.366  1.0
  O  O18  1  0.923  0.639  0.893  1.0
  O  O19  1  0.077  0.361  0.107  1.0
  O  O20  1  0.923  0.361  0.607  1.0
  O  O21  1  0.077  0.639  0.393  1.0
[/CIF]
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