The material structure described by Ag2In2GeS6 crystallizes in the monoclinic Cc space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a distorted rectangular see-saw-like geometry to one S(1), one S(2), one S(3), and one S(5) atom. In the second Ag site, Ag(2) is bonded in a 6-coordinate geometry to one S(3), one S(4), one S(5), one S(6), and two equivalent S(2) atoms. There are two inequivalent In sites. In the first In site, In(1) is bonded in a 4-coordinate geometry to one S(2), one S(4), one S(5), and one S(6) atom. In the second In site, In(2) is bonded in a distorted T-shaped geometry to one S(1), one S(2), and one S(3) atom. Ge(1) is bonded in a distorted tetrahedral geometry to one S(1), one S(3), one S(5), and one S(6) atom. There are six inequivalent S sites. In the first S site, S(1) is bonded in a 4-coordinate geometry to one Ag(1), one In(2), one Ge(1), and one S(4) atom. In the second S site, S(2) is bonded in a 5-coordinate geometry to one Ag(1), two equivalent Ag(2), one In(1), and one In(2) atom. In the third S site, S(3) is bonded in a 4-coordinate geometry to one Ag(1), one Ag(2), one In(2), and one Ge(1) atom. In the fourth S site, S(4) is bonded in a 3-coordinate geometry to one Ag(2), one In(1), and one S(1) atom. In the fifth S site, S(5) is bonded in a 4-coordinate geometry to one Ag(1), one Ag(2), one In(1), and one Ge(1) atom. In the sixth S site, S(6) is bonded in a distorted trigonal non-coplanar geometry to one Ag(2), one In(1), and one Ge(1) atom. is represented by the CIF file [CIF]
data_In2Ag2GeS6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.737
_cell_length_b   7.608
_cell_length_c   7.608
_cell_angle_alpha   76.762
_cell_angle_beta   68.650
_cell_angle_gamma   68.650
_symmetry_Int_Tables_number   1
_cell_volume   535.808
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.524  0.521  0.675  1.0
  In  In1  1  0.024  0.675  0.521  1.0
  In  In2  1  0.799  0.653  0.871  1.0
  In  In3  1  0.299  0.871  0.653  1.0
  Ag  Ag4  1  0.831  0.104  0.073  1.0
  Ag  Ag5  1  0.331  0.073  0.104  1.0
  Ag  Ag6  1  0.003  0.127  0.580  1.0
  Ag  Ag7  1  0.503  0.580  0.127  1.0
  Ge  Ge8  1  0.629  0.043  0.539  1.0
  Ge  Ge9  1  0.129  0.539  0.043  1.0
  S  S10  1  0.524  0.978  0.360  1.0
  S  S11  1  0.024  0.360  0.978  1.0
  S  S12  1  0.724  0.370  0.842  1.0
  S  S13  1  0.224  0.842  0.370  1.0
  S  S14  1  0.554  0.890  0.833  1.0
  S  S15  1  0.054  0.833  0.890  1.0
  S  S16  1  0.618  0.695  0.309  1.0
  S  S17  1  0.118  0.309  0.695  1.0
  S  S18  1  0.358  0.407  0.008  1.0
  S  S19  1  0.858  0.008  0.407  1.0
  S  S20  1  0.530  0.338  0.420  1.0
  S  S21  1  0.030  0.420  0.338  1.0
[/CIF]
.
The material structure described by Ag2In2GeS6 crystallizes in the monoclinic Cc space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a distorted rectangular see-saw-like geometry to one S(1), one S(2), one S(3), and one S(5) atom. In the second Ag site, Ag(2) is bonded in a 6-coordinate geometry to one S(3), one S(4), one S(5), one S(6), and two equivalent S(2) atoms. There are two inequivalent In sites. In the first In site, In(1) is bonded in a 4-coordinate geometry to one S(2), one S(4), one S(5), and one S(6) atom. In the second In site, In(2) is bonded in a distorted T-shaped geometry to one S(1), one S(2), and one S(3) atom. Ge(1) is bonded in a distorted tetrahedral geometry to one S(1), one S(3), one S(5), and one S(6) atom. There are six inequivalent S sites. In the first S site, S(1) is bonded in a 4-coordinate geometry to one Ag(1), one In(2), one Ge(1), and one S(4) atom. In the second S site, S(2) is bonded in a 5-coordinate geometry to one Ag(1), two equivalent Ag(2), one In(1), and one In(2) atom. In the third S site, S(3) is bonded in a 4-coordinate geometry to one Ag(1), one Ag(2), one In(2), and one Ge(1) atom. In the fourth S site, S(4) is bonded in a 3-coordinate geometry to one Ag(2), one In(1), and one S(1) atom. In the fifth S site, S(5) is bonded in a 4-coordinate geometry to one Ag(1), one Ag(2), one In(1), and one Ge(1) atom. In the sixth S site, S(6) is bonded in a distorted trigonal non-coplanar geometry to one Ag(2), one In(1), and one Ge(1) atom. is represented by the CIF file [CIF]
data_In2Ag2GeS6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.737
_cell_length_b   7.608
_cell_length_c   7.608
_cell_angle_alpha   76.762
_cell_angle_beta   68.650
_cell_angle_gamma   68.650
_symmetry_Int_Tables_number   1
_cell_volume   535.808
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.524  0.521  0.675  1.0
  In  In1  1  0.024  0.675  0.521  1.0
  In  In2  1  0.799  0.653  0.871  1.0
  In  In3  1  0.299  0.871  0.653  1.0
  Ag  Ag4  1  0.831  0.104  0.073  1.0
  Ag  Ag5  1  0.331  0.073  0.104  1.0
  Ag  Ag6  1  0.003  0.127  0.580  1.0
  Ag  Ag7  1  0.503  0.580  0.127  1.0
  Ge  Ge8  1  0.629  0.043  0.539  1.0
  Ge  Ge9  1  0.129  0.539  0.043  1.0
  S  S10  1  0.524  0.978  0.360  1.0
  S  S11  1  0.024  0.360  0.978  1.0
  S  S12  1  0.724  0.370  0.842  1.0
  S  S13  1  0.224  0.842  0.370  1.0
  S  S14  1  0.554  0.890  0.833  1.0
  S  S15  1  0.054  0.833  0.890  1.0
  S  S16  1  0.618  0.695  0.309  1.0
  S  S17  1  0.118  0.309  0.695  1.0
  S  S18  1  0.358  0.407  0.008  1.0
  S  S19  1  0.858  0.008  0.407  1.0
  S  S20  1  0.530  0.338  0.420  1.0
  S  S21  1  0.030  0.420  0.338  1.0
[/CIF]
.