The compound described by V2O3F crystallizes in the orthorhombic Pna2_1 space group. There are two inequivalent V sites. In the first V site, V(1) is bonded in a 6-coordinate geometry to one O(3), two equivalent O(1), two equivalent O(2), and one F(1) atom. In the second V site, V(2) is bonded to one O(1), one O(2), two equivalent O(3), and two equivalent F(1) atoms to form corner-sharing VO4F2 octahedra. The corner-sharing octahedral tilt angles are 49°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one V(2) and two equivalent V(1) atoms. In the second O site, O(2) is bonded in a trigonal non-coplanar geometry to one V(2) and two equivalent V(1) atoms. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one V(1) and two equivalent V(2) atoms. F(1) is bonded in a 3-coordinate geometry to one V(1) and two equivalent V(2) atoms. is represented by the CIF file [CIF]
data_V2O3F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.765
_cell_length_b   5.785
_cell_length_c   10.233
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   282.068
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.056  0.506  0.025  1.0
  V  V1  1  0.539  0.744  0.232  1.0
  V  V2  1  0.039  0.244  0.268  1.0
  V  V3  1  0.556  0.006  0.475  1.0
  V  V4  1  0.444  0.506  0.525  1.0
  V  V5  1  0.961  0.744  0.732  1.0
  V  V6  1  0.461  0.244  0.768  1.0
  V  V7  1  0.944  0.006  0.975  1.0
  O  O8  1  0.792  0.752  0.083  1.0
  O  O9  1  0.842  0.248  0.094  1.0
  O  O10  1  0.270  0.500  0.167  1.0
  O  O11  1  0.770  0.000  0.333  1.0
  O  O12  1  0.342  0.748  0.406  1.0
  O  O13  1  0.292  0.252  0.417  1.0
  O  O14  1  0.708  0.752  0.583  1.0
  O  O15  1  0.658  0.248  0.594  1.0
  O  O16  1  0.230  0.500  0.667  1.0
  O  O17  1  0.730  0.000  0.833  1.0
  O  O18  1  0.158  0.748  0.906  1.0
  O  O19  1  0.208  0.252  0.917  1.0
  F  F20  1  0.273  0.994  0.167  1.0
  F  F21  1  0.773  0.494  0.333  1.0
  F  F22  1  0.227  0.994  0.667  1.0
  F  F23  1  0.727  0.494  0.833  1.0
[/CIF]
.
The compound described by V2O3F crystallizes in the orthorhombic Pna2_1 space group. There are two inequivalent V sites. In the first V site, V(1) is bonded in a 6-coordinate geometry to one O(3), two equivalent O(1), two equivalent O(2), and one F(1) atom. In the second V site, V(2) is bonded to one O(1), one O(2), two equivalent O(3), and two equivalent F(1) atoms to form corner-sharing VO4F2 octahedra. The corner-sharing octahedral tilt angles are 49°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one V(2) and two equivalent V(1) atoms. In the second O site, O(2) is bonded in a trigonal non-coplanar geometry to one V(2) and two equivalent V(1) atoms. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one V(1) and two equivalent V(2) atoms. F(1) is bonded in a 3-coordinate geometry to one V(1) and two equivalent V(2) atoms. is represented by the CIF file [CIF]
data_V2O3F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.765
_cell_length_b   5.785
_cell_length_c   10.233
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   282.068
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.056  0.506  0.025  1.0
  V  V1  1  0.539  0.744  0.232  1.0
  V  V2  1  0.039  0.244  0.268  1.0
  V  V3  1  0.556  0.006  0.475  1.0
  V  V4  1  0.444  0.506  0.525  1.0
  V  V5  1  0.961  0.744  0.732  1.0
  V  V6  1  0.461  0.244  0.768  1.0
  V  V7  1  0.944  0.006  0.975  1.0
  O  O8  1  0.792  0.752  0.083  1.0
  O  O9  1  0.842  0.248  0.094  1.0
  O  O10  1  0.270  0.500  0.167  1.0
  O  O11  1  0.770  0.000  0.333  1.0
  O  O12  1  0.342  0.748  0.406  1.0
  O  O13  1  0.292  0.252  0.417  1.0
  O  O14  1  0.708  0.752  0.583  1.0
  O  O15  1  0.658  0.248  0.594  1.0
  O  O16  1  0.230  0.500  0.667  1.0
  O  O17  1  0.730  0.000  0.833  1.0
  O  O18  1  0.158  0.748  0.906  1.0
  O  O19  1  0.208  0.252  0.917  1.0
  F  F20  1  0.273  0.994  0.167  1.0
  F  F21  1  0.773  0.494  0.333  1.0
  F  F22  1  0.227  0.994  0.667  1.0
  F  F23  1  0.727  0.494  0.833  1.0
[/CIF]
.