The material structure described by VNbF6 crystallizes in the trigonal R-3 space group. Nb(1) is bonded to six equivalent F(1) atoms to form NbF6 octahedra that share corners with six equivalent V(1)F6 octahedra. The corner-sharing octahedral tilt angles are 35°. V(1) is bonded to six equivalent F(1) atoms to form VF6 octahedra that share corners with six equivalent Nb(1)F6 octahedra. The corner-sharing octahedral tilt angles are 35°. F(1) is bonded in a bent 150 degrees geometry to one Nb(1) and one V(1) atom. is represented by the CIF file [CIF]
data_NbVF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.659
_cell_length_b   5.659
_cell_length_c   5.659
_cell_angle_alpha   55.015
_cell_angle_beta   55.015
_cell_angle_gamma   55.015
_symmetry_Int_Tables_number   1
_cell_volume   113.272
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Nb  Nb0  1  0.500  0.500  0.500  1.0
  V  V1  1  0.000  0.000  0.000  1.0
  F  F2  1  0.869  0.249  0.634  1.0
  F  F3  1  0.249  0.634  0.869  1.0
  F  F4  1  0.366  0.131  0.751  1.0
  F  F5  1  0.751  0.366  0.131  1.0
  F  F6  1  0.131  0.751  0.366  1.0
  F  F7  1  0.634  0.869  0.249  1.0
[/CIF]
.
The material structure described by VNbF6 crystallizes in the trigonal R-3 space group. Nb(1) is bonded to six equivalent F(1) atoms to form NbF6 octahedra that share corners with six equivalent V(1)F6 octahedra. The corner-sharing octahedral tilt angles are 35°. V(1) is bonded to six equivalent F(1) atoms to form VF6 octahedra that share corners with six equivalent Nb(1)F6 octahedra. The corner-sharing octahedral tilt angles are 35°. F(1) is bonded in a bent 150 degrees geometry to one Nb(1) and one V(1) atom. is represented by the CIF file [CIF]
data_NbVF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.659
_cell_length_b   5.659
_cell_length_c   5.659
_cell_angle_alpha   55.015
_cell_angle_beta   55.015
_cell_angle_gamma   55.015
_symmetry_Int_Tables_number   1
_cell_volume   113.272
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Nb  Nb0  1  0.500  0.500  0.500  1.0
  V  V1  1  0.000  0.000  0.000  1.0
  F  F2  1  0.869  0.249  0.634  1.0
  F  F3  1  0.249  0.634  0.869  1.0
  F  F4  1  0.366  0.131  0.751  1.0
  F  F5  1  0.751  0.366  0.131  1.0
  F  F6  1  0.131  0.751  0.366  1.0
  F  F7  1  0.634  0.869  0.249  1.0
[/CIF]
.