The compound described by C2S3 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four 1,3,6,7-tetrathiapentalene-2,5-bisthione molecules. There are four inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(4), one S(2), and one S(3) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(4), one S(1), and one S(4) atom. In the third C site, C(3) is bonded in a trigonal planar geometry to one S(1), one S(5), and one S(6) atom. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(1), one C(2), and one S(6) atom. There are six inequivalent S sites. In the first S site, S(5) is bonded in a single-bond geometry to one C(3) atom. In the second S site, S(6) is bonded in an L-shaped geometry to one C(3) and one C(4) atom. In the third S site, S(1) is bonded in an L-shaped geometry to one C(2) and one C(3) atom. In the fourth S site, S(2) is bonded in a single-bond geometry to one C(1) atom. In the fifth S site, S(3) is bonded in a water-like geometry to one C(1) and one S(4) atom. In the sixth S site, S(4) is bonded in an L-shaped geometry to one C(2) and one S(3) atom. is represented by the CIF file [CIF]
data_C2S3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.478
_cell_length_b   10.473
_cell_length_c   10.670
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   108.428
_symmetry_Int_Tables_number   1
_cell_volume   898.842
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  C  C0  1  0.381  0.659  0.578  1.0
  C  C1  1  0.619  0.341  0.422  1.0
  C  C2  1  0.619  0.841  0.078  1.0
  C  C3  1  0.381  0.159  0.922  1.0
  C  C4  1  0.780  0.568  0.482  1.0
  C  C5  1  0.220  0.432  0.518  1.0
  C  C6  1  0.220  0.932  0.982  1.0
  C  C7  1  0.780  0.068  0.018  1.0
  C  C8  1  0.874  0.545  0.712  1.0
  C  C9  1  0.126  0.455  0.288  1.0
  C  C10  1  0.126  0.955  0.212  1.0
  C  C11  1  0.874  0.045  0.788  1.0
  C  C12  1  0.718  0.933  0.989  1.0
  C  C13  1  0.282  0.067  0.011  1.0
  C  C14  1  0.282  0.567  0.489  1.0
  C  C15  1  0.718  0.433  0.511  1.0
  S  S16  1  0.896  0.672  0.598  1.0
  S  S17  1  0.104  0.328  0.402  1.0
  S  S18  1  0.104  0.828  0.098  1.0
  S  S19  1  0.896  0.172  0.902  1.0
  S  S20  1  0.467  0.825  0.563  1.0
  S  S21  1  0.533  0.175  0.437  1.0
  S  S22  1  0.533  0.675  0.063  1.0
  S  S23  1  0.467  0.325  0.937  1.0
  S  S24  1  0.409  0.575  0.714  1.0
  S  S25  1  0.591  0.425  0.286  1.0
  S  S26  1  0.591  0.925  0.214  1.0
  S  S27  1  0.409  0.075  0.786  1.0
  S  S28  1  0.267  0.880  0.837  1.0
  S  S29  1  0.733  0.120  0.163  1.0
  S  S30  1  0.733  0.620  0.337  1.0
  S  S31  1  0.267  0.380  0.663  1.0
  S  S32  1  0.951  0.574  0.854  1.0
  S  S33  1  0.049  0.426  0.146  1.0
  S  S34  1  0.049  0.926  0.354  1.0
  S  S35  1  0.951  0.074  0.646  1.0
  S  S36  1  0.763  0.885  0.841  1.0
  S  S37  1  0.237  0.115  0.159  1.0
  S  S38  1  0.237  0.615  0.341  1.0
  S  S39  1  0.763  0.385  0.659  1.0
[/CIF]
.
The compound described by C2S3 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four 1,3,6,7-tetrathiapentalene-2,5-bisthione molecules. There are four inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(4), one S(2), and one S(3) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(4), one S(1), and one S(4) atom. In the third C site, C(3) is bonded in a trigonal planar geometry to one S(1), one S(5), and one S(6) atom. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(1), one C(2), and one S(6) atom. There are six inequivalent S sites. In the first S site, S(5) is bonded in a single-bond geometry to one C(3) atom. In the second S site, S(6) is bonded in an L-shaped geometry to one C(3) and one C(4) atom. In the third S site, S(1) is bonded in an L-shaped geometry to one C(2) and one C(3) atom. In the fourth S site, S(2) is bonded in a single-bond geometry to one C(1) atom. In the fifth S site, S(3) is bonded in a water-like geometry to one C(1) and one S(4) atom. In the sixth S site, S(4) is bonded in an L-shaped geometry to one C(2) and one S(3) atom. is represented by the CIF file [CIF]
data_C2S3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.478
_cell_length_b   10.473
_cell_length_c   10.670
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   108.428
_symmetry_Int_Tables_number   1
_cell_volume   898.842
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  C  C0  1  0.381  0.659  0.578  1.0
  C  C1  1  0.619  0.341  0.422  1.0
  C  C2  1  0.619  0.841  0.078  1.0
  C  C3  1  0.381  0.159  0.922  1.0
  C  C4  1  0.780  0.568  0.482  1.0
  C  C5  1  0.220  0.432  0.518  1.0
  C  C6  1  0.220  0.932  0.982  1.0
  C  C7  1  0.780  0.068  0.018  1.0
  C  C8  1  0.874  0.545  0.712  1.0
  C  C9  1  0.126  0.455  0.288  1.0
  C  C10  1  0.126  0.955  0.212  1.0
  C  C11  1  0.874  0.045  0.788  1.0
  C  C12  1  0.718  0.933  0.989  1.0
  C  C13  1  0.282  0.067  0.011  1.0
  C  C14  1  0.282  0.567  0.489  1.0
  C  C15  1  0.718  0.433  0.511  1.0
  S  S16  1  0.896  0.672  0.598  1.0
  S  S17  1  0.104  0.328  0.402  1.0
  S  S18  1  0.104  0.828  0.098  1.0
  S  S19  1  0.896  0.172  0.902  1.0
  S  S20  1  0.467  0.825  0.563  1.0
  S  S21  1  0.533  0.175  0.437  1.0
  S  S22  1  0.533  0.675  0.063  1.0
  S  S23  1  0.467  0.325  0.937  1.0
  S  S24  1  0.409  0.575  0.714  1.0
  S  S25  1  0.591  0.425  0.286  1.0
  S  S26  1  0.591  0.925  0.214  1.0
  S  S27  1  0.409  0.075  0.786  1.0
  S  S28  1  0.267  0.880  0.837  1.0
  S  S29  1  0.733  0.120  0.163  1.0
  S  S30  1  0.733  0.620  0.337  1.0
  S  S31  1  0.267  0.380  0.663  1.0
  S  S32  1  0.951  0.574  0.854  1.0
  S  S33  1  0.049  0.426  0.146  1.0
  S  S34  1  0.049  0.926  0.354  1.0
  S  S35  1  0.951  0.074  0.646  1.0
  S  S36  1  0.763  0.885  0.841  1.0
  S  S37  1  0.237  0.115  0.159  1.0
  S  S38  1  0.237  0.615  0.341  1.0
  S  S39  1  0.763  0.385  0.659  1.0
[/CIF]
.