The material structure described by MoO2 is Hydrophilite-like structured and crystallizes in the tetragonal P4_2/mnm space group. Mo(1) is bonded to six equivalent O(1) atoms to form a mixture of edge and corner-sharing MoO6 octahedra. The corner-sharing octahedral tilt angles are 51°. O(1) is bonded in a trigonal planar geometry to three equivalent Mo(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_MoO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.190
_cell_length_b   4.633
_cell_length_c   4.639
_cell_angle_alpha   89.998
_cell_angle_beta   89.999
_cell_angle_gamma   90.007
_symmetry_Int_Tables_number   1
_cell_volume   68.546
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mo  Mo0  1  1.000  0.500  0.500  1.0
  Mo  Mo1  1  0.500  1.000  0.000  1.0
  O  O2  1  1.000  0.196  0.195  1.0
  O  O3  1  0.500  0.304  0.695  1.0
  O  O4  1  0.000  0.804  0.805  1.0
  O  O5  1  0.500  0.696  0.305  1.0
[/CIF]
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The material structure described by MoO2 is Hydrophilite-like structured and crystallizes in the tetragonal P4_2/mnm space group. Mo(1) is bonded to six equivalent O(1) atoms to form a mixture of edge and corner-sharing MoO6 octahedra. The corner-sharing octahedral tilt angles are 51°. O(1) is bonded in a trigonal planar geometry to three equivalent Mo(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_MoO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.190
_cell_length_b   4.633
_cell_length_c   4.639
_cell_angle_alpha   89.998
_cell_angle_beta   89.999
_cell_angle_gamma   90.007
_symmetry_Int_Tables_number   1
_cell_volume   68.546
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mo  Mo0  1  1.000  0.500  0.500  1.0
  Mo  Mo1  1  0.500  1.000  0.000  1.0
  O  O2  1  1.000  0.196  0.195  1.0
  O  O3  1  0.500  0.304  0.695  1.0
  O  O4  1  0.000  0.804  0.805  1.0
  O  O5  1  0.500  0.696  0.305  1.0
[/CIF]
.