The structure described by PtC4S2(OI)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one PtC4S2(OI)2 cluster. Pt(1) is bonded in a square co-planar geometry to two equivalent S(1) and two equivalent I(1) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a bent 150 degrees geometry to one C(2) and one S(1) atom. In the second C site, C(2) is bonded in a single-bond geometry to one C(1) atom. S(1) is bonded in a distorted trigonal planar geometry to one Pt(1), one C(1), and one O(1) atom. O(1) is bonded in a single-bond geometry to one S(1) atom. I(1) is bonded in a single-bond geometry to one Pt(1) atom. is represented by the CIF card [CIF]
data_PtC4S2(IO)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.550
_cell_length_b   6.638
_cell_length_c   8.835
_cell_angle_alpha   76.550
_cell_angle_beta   81.326
_cell_angle_gamma   80.371
_symmetry_Int_Tables_number   1
_cell_volume   365.780
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pt  Pt0  1  0.000  0.000  0.000  1.0
  C  C1  1  0.205  0.691  0.309  1.0
  C  C2  1  0.795  0.309  0.691  1.0
  C  C3  1  0.333  0.701  0.404  1.0
  C  C4  1  0.667  0.299  0.596  1.0
  S  S5  1  0.999  0.761  0.223  1.0
  S  S6  1  0.001  0.239  0.777  1.0
  I  I7  1  0.307  0.750  0.877  1.0
  I  I8  1  0.693  0.250  0.123  1.0
  O  O9  1  0.813  0.666  0.294  1.0
  O  O10  1  0.187  0.334  0.706  1.0
[/CIF]
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The structure described by PtC4S2(OI)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one PtC4S2(OI)2 cluster. Pt(1) is bonded in a square co-planar geometry to two equivalent S(1) and two equivalent I(1) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a bent 150 degrees geometry to one C(2) and one S(1) atom. In the second C site, C(2) is bonded in a single-bond geometry to one C(1) atom. S(1) is bonded in a distorted trigonal planar geometry to one Pt(1), one C(1), and one O(1) atom. O(1) is bonded in a single-bond geometry to one S(1) atom. I(1) is bonded in a single-bond geometry to one Pt(1) atom. is represented by the CIF card [CIF]
data_PtC4S2(IO)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.550
_cell_length_b   6.638
_cell_length_c   8.835
_cell_angle_alpha   76.550
_cell_angle_beta   81.326
_cell_angle_gamma   80.371
_symmetry_Int_Tables_number   1
_cell_volume   365.780
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pt  Pt0  1  0.000  0.000  0.000  1.0
  C  C1  1  0.205  0.691  0.309  1.0
  C  C2  1  0.795  0.309  0.691  1.0
  C  C3  1  0.333  0.701  0.404  1.0
  C  C4  1  0.667  0.299  0.596  1.0
  S  S5  1  0.999  0.761  0.223  1.0
  S  S6  1  0.001  0.239  0.777  1.0
  I  I7  1  0.307  0.750  0.877  1.0
  I  I8  1  0.693  0.250  0.123  1.0
  O  O9  1  0.813  0.666  0.294  1.0
  O  O10  1  0.187  0.334  0.706  1.0
[/CIF]
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