The structure described by YbCoC6(N2O)3O2 crystallizes in the hexagonal P6_3/m space group. The structure consists of four water atoms inside a YbCoC6(N2O)3 framework. In the YbCoC6(N2O)3 framework, Yb(1) is bonded in a 9-coordinate geometry to six equivalent N(1) and three equivalent O(2) atoms. Co(1) is bonded in an octahedral geometry to six equivalent C(1) atoms. C(1) is bonded in a linear geometry to one Co(1) and one N(1) atom. N(1) is bonded in a linear geometry to one Yb(1) and one C(1) atom. O(2) is bonded in a single-bond geometry to one Yb(1) atom. is represented by the CIF card [CIF]
data_YbCoC6N6O5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.775
_cell_length_b   7.775
_cell_length_c   12.730
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   666.417
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Yb  Yb0  1  0.333  0.667  0.750  1.0
  Yb  Yb1  1  0.667  0.333  0.250  1.0
  Co  Co2  1  0.000  0.000  0.000  1.0
  Co  Co3  1  0.000  0.000  0.500  1.0
  C  C4  1  0.767  0.898  0.918  1.0
  C  C5  1  0.233  0.102  0.082  1.0
  C  C6  1  0.131  0.233  0.918  1.0
  C  C7  1  0.233  0.102  0.418  1.0
  C  C8  1  0.869  0.767  0.082  1.0
  C  C9  1  0.767  0.898  0.582  1.0
  C  C10  1  0.102  0.869  0.918  1.0
  C  C11  1  0.869  0.767  0.418  1.0
  C  C12  1  0.898  0.131  0.082  1.0
  C  C13  1  0.131  0.233  0.582  1.0
  C  C14  1  0.898  0.131  0.418  1.0
  C  C15  1  0.102  0.869  0.582  1.0
  N  N16  1  0.621  0.832  0.869  1.0
  N  N17  1  0.379  0.168  0.131  1.0
  N  N18  1  0.211  0.379  0.869  1.0
  N  N19  1  0.379  0.168  0.369  1.0
  N  N20  1  0.789  0.621  0.131  1.0
  N  N21  1  0.621  0.832  0.631  1.0
  N  N22  1  0.168  0.789  0.869  1.0
  N  N23  1  0.789  0.621  0.369  1.0
  N  N24  1  0.832  0.211  0.131  1.0
  N  N25  1  0.211  0.379  0.631  1.0
  N  N26  1  0.832  0.211  0.369  1.0
  N  N27  1  0.168  0.789  0.631  1.0
  O  O28  1  0.667  0.333  0.845  1.0
  O  O29  1  0.333  0.667  0.155  1.0
  O  O30  1  0.333  0.667  0.345  1.0
  O  O31  1  0.667  0.333  0.655  1.0
  O  O32  1  0.921  0.437  0.750  1.0
  O  O33  1  0.079  0.563  0.250  1.0
  O  O34  1  0.515  0.079  0.750  1.0
  O  O35  1  0.485  0.921  0.250  1.0
  O  O36  1  0.563  0.485  0.750  1.0
  O  O37  1  0.437  0.515  0.250  1.0
[/CIF]
.
The structure described by YbCoC6(N2O)3O2 crystallizes in the hexagonal P6_3/m space group. The structure consists of four water atoms inside a YbCoC6(N2O)3 framework. In the YbCoC6(N2O)3 framework, Yb(1) is bonded in a 9-coordinate geometry to six equivalent N(1) and three equivalent O(2) atoms. Co(1) is bonded in an octahedral geometry to six equivalent C(1) atoms. C(1) is bonded in a linear geometry to one Co(1) and one N(1) atom. N(1) is bonded in a linear geometry to one Yb(1) and one C(1) atom. O(2) is bonded in a single-bond geometry to one Yb(1) atom. is represented by the CIF card [CIF]
data_YbCoC6N6O5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.775
_cell_length_b   7.775
_cell_length_c   12.730
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   666.417
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Yb  Yb0  1  0.333  0.667  0.750  1.0
  Yb  Yb1  1  0.667  0.333  0.250  1.0
  Co  Co2  1  0.000  0.000  0.000  1.0
  Co  Co3  1  0.000  0.000  0.500  1.0
  C  C4  1  0.767  0.898  0.918  1.0
  C  C5  1  0.233  0.102  0.082  1.0
  C  C6  1  0.131  0.233  0.918  1.0
  C  C7  1  0.233  0.102  0.418  1.0
  C  C8  1  0.869  0.767  0.082  1.0
  C  C9  1  0.767  0.898  0.582  1.0
  C  C10  1  0.102  0.869  0.918  1.0
  C  C11  1  0.869  0.767  0.418  1.0
  C  C12  1  0.898  0.131  0.082  1.0
  C  C13  1  0.131  0.233  0.582  1.0
  C  C14  1  0.898  0.131  0.418  1.0
  C  C15  1  0.102  0.869  0.582  1.0
  N  N16  1  0.621  0.832  0.869  1.0
  N  N17  1  0.379  0.168  0.131  1.0
  N  N18  1  0.211  0.379  0.869  1.0
  N  N19  1  0.379  0.168  0.369  1.0
  N  N20  1  0.789  0.621  0.131  1.0
  N  N21  1  0.621  0.832  0.631  1.0
  N  N22  1  0.168  0.789  0.869  1.0
  N  N23  1  0.789  0.621  0.369  1.0
  N  N24  1  0.832  0.211  0.131  1.0
  N  N25  1  0.211  0.379  0.631  1.0
  N  N26  1  0.832  0.211  0.369  1.0
  N  N27  1  0.168  0.789  0.631  1.0
  O  O28  1  0.667  0.333  0.845  1.0
  O  O29  1  0.333  0.667  0.155  1.0
  O  O30  1  0.333  0.667  0.345  1.0
  O  O31  1  0.667  0.333  0.655  1.0
  O  O32  1  0.921  0.437  0.750  1.0
  O  O33  1  0.079  0.563  0.250  1.0
  O  O34  1  0.515  0.079  0.750  1.0
  O  O35  1  0.485  0.921  0.250  1.0
  O  O36  1  0.563  0.485  0.750  1.0
  O  O37  1  0.437  0.515  0.250  1.0
[/CIF]
.