The crystal structure described by Re3P4 crystallizes in the monoclinic C2/m space group. There are two inequivalent Re sites. In the first Re site, Re(1) is bonded in a 6-coordinate geometry to three equivalent P(1) and three equivalent P(2) atoms. In the second Re site, Re(2) is bonded to two equivalent P(1) and four equivalent P(2) atoms to form edge-sharing ReP6 octahedra. There are two inequivalent P sites. In the first P site, P(2) is bonded in a 5-coordinate geometry to two equivalent Re(2) and three equivalent Re(1) atoms. In the second P site, P(1) is bonded in a 5-coordinate geometry to one Re(2), three equivalent Re(1), and one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Re3P4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.033
_cell_length_b   6.043
_cell_length_c   6.282
_cell_angle_alpha   113.114
_cell_angle_beta   103.970
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   102.194
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.264  0.319  0.528  1.0
  Re  Re1  1  0.736  0.681  0.472  1.0
  Re  Re2  1  0.000  0.000  0.000  1.0
  P  P3  1  0.086  0.436  0.172  1.0
  P  P4  1  0.914  0.564  0.828  1.0
  P  P5  1  0.351  0.023  0.702  1.0
  P  P6  1  0.649  0.977  0.298  1.0
[/CIF]
.
The crystal structure described by Re3P4 crystallizes in the monoclinic C2/m space group. There are two inequivalent Re sites. In the first Re site, Re(1) is bonded in a 6-coordinate geometry to three equivalent P(1) and three equivalent P(2) atoms. In the second Re site, Re(2) is bonded to two equivalent P(1) and four equivalent P(2) atoms to form edge-sharing ReP6 octahedra. There are two inequivalent P sites. In the first P site, P(2) is bonded in a 5-coordinate geometry to two equivalent Re(2) and three equivalent Re(1) atoms. In the second P site, P(1) is bonded in a 5-coordinate geometry to one Re(2), three equivalent Re(1), and one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Re3P4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.033
_cell_length_b   6.043
_cell_length_c   6.282
_cell_angle_alpha   113.114
_cell_angle_beta   103.970
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   102.194
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.264  0.319  0.528  1.0
  Re  Re1  1  0.736  0.681  0.472  1.0
  Re  Re2  1  0.000  0.000  0.000  1.0
  P  P3  1  0.086  0.436  0.172  1.0
  P  P4  1  0.914  0.564  0.828  1.0
  P  P5  1  0.351  0.023  0.702  1.0
  P  P6  1  0.649  0.977  0.298  1.0
[/CIF]
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