The compound described by Li4V3MnO8 is Stannite-like structured and crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(2), one O(4), one O(7), and one O(8) atom to form LiO4 tetrahedra that share corners with two equivalent Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra, corners with two equivalent V(1)O4 tetrahedra, corners with two equivalent V(2)O4 tetrahedra, corners with two equivalent V(3)O4 tetrahedra, and corners with two equivalent Mn(1)O4 tetrahedra. In the second Li site, Li(2) is bonded to one O(1), one O(3), one O(5), and one O(6) atom to form LiO4 tetrahedra that share corners with two equivalent Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra, corners with two equivalent V(1)O4 tetrahedra, corners with two equivalent V(2)O4 tetrahedra, corners with two equivalent V(3)O4 tetrahedra, and corners with two equivalent Mn(1)O4 tetrahedra. In the third Li site, Li(3) is bonded to one O(3), one O(4), one O(6), and one O(8) atom to form LiO4 tetrahedra that share corners with two equivalent Li(1)O4 tetrahedra, corners with two equivalent Li(2)O4 tetrahedra, corners with two equivalent V(1)O4 tetrahedra, corners with two equivalent V(2)O4 tetrahedra, corners with two equivalent V(3)O4 tetrahedra, and corners with two equivalent Mn(1)O4 tetrahedra. In the fourth Li site, Li(4) is bonded to one O(1), one O(2), one O(5), and one O(7) atom to form LiO4 tetrahedra that share corners with two equivalent Li(1)O4 tetrahedra, corners with two equivalent Li(2)O4 tetrahedra, corners with two equivalent V(1)O4 tetrahedra, corners with two equivalent V(2)O4 tetrahedra, corners with two equivalent V(3)O4 tetrahedra, and corners with two equivalent Mn(1)O4 tetrahedra. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(3), one O(7), and one O(8) atom to form VO4 tetrahedra that share corners with two equivalent Li(1)O4 tetrahedra, corners with two equivalent Li(2)O4 tetrahedra, corners with two equivalent Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra, corners with two equivalent V(3)O4 tetrahedra, and corners with two equivalent Mn(1)O4 tetrahedra. In the second V site, V(2) is bonded to one O(2), one O(4), one O(5), and one O(6) atom to form VO4 tetrahedra that share corners with two equivalent Li(1)O4 tetrahedra, corners with two equivalent Li(2)O4 tetrahedra, corners with two equivalent Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra, corners with two equivalent V(3)O4 tetrahedra, and corners with two equivalent Mn(1)O4 tetrahedra. In the third V site, V(3) is bonded to one O(3), one O(4), one O(5), and one O(7) atom to form VO4 tetrahedra that share corners with two equivalent Li(1)O4 tetrahedra, corners with two equivalent Li(2)O4 tetrahedra, corners with two equivalent Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra, corners with two equivalent V(1)O4 tetrahedra, and corners with two equivalent V(2)O4 tetrahedra. Mn(1) is bonded to one O(1), one O(2), one O(6), and one O(8) atom to form MnO4 tetrahedra that share corners with two equivalent Li(1)O4 tetrahedra, corners with two equivalent Li(2)O4 tetrahedra, corners with two equivalent Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra, corners with two equivalent V(1)O4 tetrahedra, and corners with two equivalent V(2)O4 tetrahedra. There are eight inequivalent O sites. In the first O site, O(1) is bonded to one Li(2), one Li(4), one V(1), and one Mn(1) atom to form OLi2MnV tetrahedra that share corners with two equivalent O(2)Li2MnV tetrahedra, corners with two equivalent O(6)Li2MnV tetrahedra, corners with two equivalent O(8)Li2MnV tetrahedra, corners with two equivalent O(3)Li2V2 tetrahedra, corners with two equivalent O(5)Li2V2 tetrahedra, and corners with two equivalent O(7)Li2V2 tetrahedra. In the second O site, O(2) is bonded to one Li(1), one Li(4), one V(2), and one Mn(1) atom to form OLi2MnV tetrahedra that share corners with two equivalent O(1)Li2MnV tetrahedra, corners with two equivalent O(6)Li2MnV tetrahedra, corners with two equivalent O(8)Li2MnV tetrahedra, corners with two equivalent O(4)Li2V2 tetrahedra, corners with two equivalent O(5)Li2V2 tetrahedra, and corners with two equivalent O(7)Li2V2 tetrahedra. In the third O site, O(3) is bonded to one Li(2), one Li(3), one V(1), and one V(3) atom to form OLi2V2 tetrahedra that share corners with two equivalent O(1)Li2MnV tetrahedra, corners with two equivalent O(6)Li2MnV tetrahedra, corners with two equivalent O(8)Li2MnV tetrahedra, corners with two equivalent O(4)Li2V2 tetrahedra, corners with two equivalent O(5)Li2V2 tetrahedra, and corners with two equivalent O(7)Li2V2 tetrahedra. In the fourth O site, O(4) is bonded to one Li(1), one Li(3), one V(2), and one V(3) atom to form OLi2V2 tetrahedra that share corners with two equivalent O(2)Li2MnV tetrahedra, corners with two equivalent O(6)Li2MnV tetrahedra, corners with two equivalent O(8)Li2MnV tetrahedra, corners with two equivalent O(3)Li2V2 tetrahedra, corners with two equivalent O(5)Li2V2 tetrahedra, and corners with two equivalent O(7)Li2V2 tetrahedra. In the fifth O site, O(5) is bonded to one Li(2), one Li(4), one V(2), and one V(3) atom to form OLi2V2 tetrahedra that share corners with two equivalent O(1)Li2MnV tetrahedra, corners with two equivalent O(2)Li2MnV tetrahedra, corners with two equivalent O(6)Li2MnV tetrahedra, corners with two equivalent O(3)Li2V2 tetrahedra, corners with two equivalent O(4)Li2V2 tetrahedra, and corners with two equivalent O(7)Li2V2 tetrahedra. In the sixth O site, O(6) is bonded to one Li(2), one Li(3), one V(2), and one Mn(1) atom to form OLi2MnV tetrahedra that share corners with two equivalent O(1)Li2MnV tetrahedra, corners with two equivalent O(2)Li2MnV tetrahedra, corners with two equivalent O(8)Li2MnV tetrahedra, corners with two equivalent O(3)Li2V2 tetrahedra, corners with two equivalent O(4)Li2V2 tetrahedra, and corners with two equivalent O(5)Li2V2 tetrahedra. In the seventh O site, O(7) is bonded to one Li(1), one Li(4), one V(1), and one V(3) atom to form OLi2V2 tetrahedra that share corners with two equivalent O(1)Li2MnV tetrahedra, corners with two equivalent O(2)Li2MnV tetrahedra, corners with two equivalent O(8)Li2MnV tetrahedra, corners with two equivalent O(3)Li2V2 tetrahedra, corners with two equivalent O(4)Li2V2 tetrahedra, and corners with two equivalent O(5)Li2V2 tetrahedra. In the eighth O site, O(8) is bonded to one Li(1), one Li(3), one V(1), and one Mn(1) atom to form OLi2MnV tetrahedra that share corners with two equivalent O(1)Li2MnV tetrahedra, corners with two equivalent O(2)Li2MnV tetrahedra, corners with two equivalent O(6)Li2MnV tetrahedra, corners with two equivalent O(3)Li2V2 tetrahedra, corners with two equivalent O(4)Li2V2 tetrahedra, and corners with two equivalent O(7)Li2V2 tetrahedra. is represented by the CIF file [CIF]
data_Li4MnV3O8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.099
_cell_length_b   5.724
_cell_length_c   6.582
_cell_angle_alpha   90.836
_cell_angle_beta   90.075
_cell_angle_gamma   90.001
_symmetry_Int_Tables_number   1
_cell_volume   192.103
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.009  0.080  0.376  1.0
  Li  Li1  1  0.506  0.409  0.873  1.0
  Li  Li2  1  0.010  0.585  0.121  1.0
  Li  Li3  1  0.503  0.923  0.627  1.0
  Mn  Mn4  1  0.503  0.914  0.126  1.0
  V  V5  1  0.998  0.084  0.876  1.0
  V  V6  1  0.510  0.410  0.369  1.0
  V  V7  1  0.009  0.588  0.629  1.0
  O  O8  1  0.624  0.082  0.873  1.0
  O  O9  1  0.607  0.111  0.386  1.0
  O  O10  1  0.110  0.413  0.861  1.0
  O  O11  1  0.142  0.428  0.384  1.0
  O  O12  1  0.623  0.573  0.603  1.0
  O  O13  1  0.609  0.567  0.146  1.0
  O  O14  1  0.110  0.909  0.632  1.0
  O  O15  1  0.099  0.924  0.117  1.0
[/CIF]
.
The compound described by Li4V3MnO8 is Stannite-like structured and crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(2), one O(4), one O(7), and one O(8) atom to form LiO4 tetrahedra that share corners with two equivalent Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra, corners with two equivalent V(1)O4 tetrahedra, corners with two equivalent V(2)O4 tetrahedra, corners with two equivalent V(3)O4 tetrahedra, and corners with two equivalent Mn(1)O4 tetrahedra. In the second Li site, Li(2) is bonded to one O(1), one O(3), one O(5), and one O(6) atom to form LiO4 tetrahedra that share corners with two equivalent Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra, corners with two equivalent V(1)O4 tetrahedra, corners with two equivalent V(2)O4 tetrahedra, corners with two equivalent V(3)O4 tetrahedra, and corners with two equivalent Mn(1)O4 tetrahedra. In the third Li site, Li(3) is bonded to one O(3), one O(4), one O(6), and one O(8) atom to form LiO4 tetrahedra that share corners with two equivalent Li(1)O4 tetrahedra, corners with two equivalent Li(2)O4 tetrahedra, corners with two equivalent V(1)O4 tetrahedra, corners with two equivalent V(2)O4 tetrahedra, corners with two equivalent V(3)O4 tetrahedra, and corners with two equivalent Mn(1)O4 tetrahedra. In the fourth Li site, Li(4) is bonded to one O(1), one O(2), one O(5), and one O(7) atom to form LiO4 tetrahedra that share corners with two equivalent Li(1)O4 tetrahedra, corners with two equivalent Li(2)O4 tetrahedra, corners with two equivalent V(1)O4 tetrahedra, corners with two equivalent V(2)O4 tetrahedra, corners with two equivalent V(3)O4 tetrahedra, and corners with two equivalent Mn(1)O4 tetrahedra. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(3), one O(7), and one O(8) atom to form VO4 tetrahedra that share corners with two equivalent Li(1)O4 tetrahedra, corners with two equivalent Li(2)O4 tetrahedra, corners with two equivalent Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra, corners with two equivalent V(3)O4 tetrahedra, and corners with two equivalent Mn(1)O4 tetrahedra. In the second V site, V(2) is bonded to one O(2), one O(4), one O(5), and one O(6) atom to form VO4 tetrahedra that share corners with two equivalent Li(1)O4 tetrahedra, corners with two equivalent Li(2)O4 tetrahedra, corners with two equivalent Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra, corners with two equivalent V(3)O4 tetrahedra, and corners with two equivalent Mn(1)O4 tetrahedra. In the third V site, V(3) is bonded to one O(3), one O(4), one O(5), and one O(7) atom to form VO4 tetrahedra that share corners with two equivalent Li(1)O4 tetrahedra, corners with two equivalent Li(2)O4 tetrahedra, corners with two equivalent Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra, corners with two equivalent V(1)O4 tetrahedra, and corners with two equivalent V(2)O4 tetrahedra. Mn(1) is bonded to one O(1), one O(2), one O(6), and one O(8) atom to form MnO4 tetrahedra that share corners with two equivalent Li(1)O4 tetrahedra, corners with two equivalent Li(2)O4 tetrahedra, corners with two equivalent Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra, corners with two equivalent V(1)O4 tetrahedra, and corners with two equivalent V(2)O4 tetrahedra. There are eight inequivalent O sites. In the first O site, O(1) is bonded to one Li(2), one Li(4), one V(1), and one Mn(1) atom to form OLi2MnV tetrahedra that share corners with two equivalent O(2)Li2MnV tetrahedra, corners with two equivalent O(6)Li2MnV tetrahedra, corners with two equivalent O(8)Li2MnV tetrahedra, corners with two equivalent O(3)Li2V2 tetrahedra, corners with two equivalent O(5)Li2V2 tetrahedra, and corners with two equivalent O(7)Li2V2 tetrahedra. In the second O site, O(2) is bonded to one Li(1), one Li(4), one V(2), and one Mn(1) atom to form OLi2MnV tetrahedra that share corners with two equivalent O(1)Li2MnV tetrahedra, corners with two equivalent O(6)Li2MnV tetrahedra, corners with two equivalent O(8)Li2MnV tetrahedra, corners with two equivalent O(4)Li2V2 tetrahedra, corners with two equivalent O(5)Li2V2 tetrahedra, and corners with two equivalent O(7)Li2V2 tetrahedra. In the third O site, O(3) is bonded to one Li(2), one Li(3), one V(1), and one V(3) atom to form OLi2V2 tetrahedra that share corners with two equivalent O(1)Li2MnV tetrahedra, corners with two equivalent O(6)Li2MnV tetrahedra, corners with two equivalent O(8)Li2MnV tetrahedra, corners with two equivalent O(4)Li2V2 tetrahedra, corners with two equivalent O(5)Li2V2 tetrahedra, and corners with two equivalent O(7)Li2V2 tetrahedra. In the fourth O site, O(4) is bonded to one Li(1), one Li(3), one V(2), and one V(3) atom to form OLi2V2 tetrahedra that share corners with two equivalent O(2)Li2MnV tetrahedra, corners with two equivalent O(6)Li2MnV tetrahedra, corners with two equivalent O(8)Li2MnV tetrahedra, corners with two equivalent O(3)Li2V2 tetrahedra, corners with two equivalent O(5)Li2V2 tetrahedra, and corners with two equivalent O(7)Li2V2 tetrahedra. In the fifth O site, O(5) is bonded to one Li(2), one Li(4), one V(2), and one V(3) atom to form OLi2V2 tetrahedra that share corners with two equivalent O(1)Li2MnV tetrahedra, corners with two equivalent O(2)Li2MnV tetrahedra, corners with two equivalent O(6)Li2MnV tetrahedra, corners with two equivalent O(3)Li2V2 tetrahedra, corners with two equivalent O(4)Li2V2 tetrahedra, and corners with two equivalent O(7)Li2V2 tetrahedra. In the sixth O site, O(6) is bonded to one Li(2), one Li(3), one V(2), and one Mn(1) atom to form OLi2MnV tetrahedra that share corners with two equivalent O(1)Li2MnV tetrahedra, corners with two equivalent O(2)Li2MnV tetrahedra, corners with two equivalent O(8)Li2MnV tetrahedra, corners with two equivalent O(3)Li2V2 tetrahedra, corners with two equivalent O(4)Li2V2 tetrahedra, and corners with two equivalent O(5)Li2V2 tetrahedra. In the seventh O site, O(7) is bonded to one Li(1), one Li(4), one V(1), and one V(3) atom to form OLi2V2 tetrahedra that share corners with two equivalent O(1)Li2MnV tetrahedra, corners with two equivalent O(2)Li2MnV tetrahedra, corners with two equivalent O(8)Li2MnV tetrahedra, corners with two equivalent O(3)Li2V2 tetrahedra, corners with two equivalent O(4)Li2V2 tetrahedra, and corners with two equivalent O(5)Li2V2 tetrahedra. In the eighth O site, O(8) is bonded to one Li(1), one Li(3), one V(1), and one Mn(1) atom to form OLi2MnV tetrahedra that share corners with two equivalent O(1)Li2MnV tetrahedra, corners with two equivalent O(2)Li2MnV tetrahedra, corners with two equivalent O(6)Li2MnV tetrahedra, corners with two equivalent O(3)Li2V2 tetrahedra, corners with two equivalent O(4)Li2V2 tetrahedra, and corners with two equivalent O(7)Li2V2 tetrahedra. is represented by the CIF file [CIF]
data_Li4MnV3O8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.099
_cell_length_b   5.724
_cell_length_c   6.582
_cell_angle_alpha   90.836
_cell_angle_beta   90.075
_cell_angle_gamma   90.001
_symmetry_Int_Tables_number   1
_cell_volume   192.103
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.009  0.080  0.376  1.0
  Li  Li1  1  0.506  0.409  0.873  1.0
  Li  Li2  1  0.010  0.585  0.121  1.0
  Li  Li3  1  0.503  0.923  0.627  1.0
  Mn  Mn4  1  0.503  0.914  0.126  1.0
  V  V5  1  0.998  0.084  0.876  1.0
  V  V6  1  0.510  0.410  0.369  1.0
  V  V7  1  0.009  0.588  0.629  1.0
  O  O8  1  0.624  0.082  0.873  1.0
  O  O9  1  0.607  0.111  0.386  1.0
  O  O10  1  0.110  0.413  0.861  1.0
  O  O11  1  0.142  0.428  0.384  1.0
  O  O12  1  0.623  0.573  0.603  1.0
  O  O13  1  0.609  0.567  0.146  1.0
  O  O14  1  0.110  0.909  0.632  1.0
  O  O15  1  0.099  0.924  0.117  1.0
[/CIF]
.