The structure described by (AlCl4)2N2 is Silicon tetrafluoride-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four ammonia atoms and four AlCl4 clusters. In each AlCl4 cluster, Al(1) is bonded in a tetrahedral geometry to one Cl(1), one Cl(2), and two equivalent Cl(3) atoms. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Al(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Al(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Al(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_AlNCl4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.319
_cell_length_b   9.571
_cell_length_c   11.435
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   801.014
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Al  Al0  1  0.250  0.810  0.067  1.0
  Al  Al1  1  0.250  0.690  0.567  1.0
  Al  Al2  1  0.750  0.190  0.933  1.0
  Al  Al3  1  0.750  0.310  0.433  1.0
  N  N4  1  0.250  0.325  0.185  1.0
  N  N5  1  0.250  0.175  0.685  1.0
  N  N6  1  0.750  0.675  0.815  1.0
  N  N7  1  0.750  0.825  0.315  1.0
  Cl  Cl8  1  0.250  0.948  0.216  1.0
  Cl  Cl9  1  0.250  0.552  0.716  1.0
  Cl  Cl10  1  0.750  0.052  0.784  1.0
  Cl  Cl11  1  0.750  0.448  0.284  1.0
  Cl  Cl12  1  0.250  0.922  0.903  1.0
  Cl  Cl13  1  0.250  0.578  0.403  1.0
  Cl  Cl14  1  0.750  0.078  0.097  1.0
  Cl  Cl15  1  0.750  0.422  0.597  1.0
  Cl  Cl16  1  0.012  0.679  0.077  1.0
  Cl  Cl17  1  0.488  0.821  0.577  1.0
  Cl  Cl18  1  0.512  0.321  0.923  1.0
  Cl  Cl19  1  0.988  0.179  0.423  1.0
  Cl  Cl20  1  0.988  0.321  0.923  1.0
  Cl  Cl21  1  0.512  0.179  0.423  1.0
  Cl  Cl22  1  0.488  0.679  0.077  1.0
  Cl  Cl23  1  0.012  0.821  0.577  1.0
[/CIF]
.
The structure described by (AlCl4)2N2 is Silicon tetrafluoride-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four ammonia atoms and four AlCl4 clusters. In each AlCl4 cluster, Al(1) is bonded in a tetrahedral geometry to one Cl(1), one Cl(2), and two equivalent Cl(3) atoms. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Al(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Al(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Al(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_AlNCl4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.319
_cell_length_b   9.571
_cell_length_c   11.435
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   801.014
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Al  Al0  1  0.250  0.810  0.067  1.0
  Al  Al1  1  0.250  0.690  0.567  1.0
  Al  Al2  1  0.750  0.190  0.933  1.0
  Al  Al3  1  0.750  0.310  0.433  1.0
  N  N4  1  0.250  0.325  0.185  1.0
  N  N5  1  0.250  0.175  0.685  1.0
  N  N6  1  0.750  0.675  0.815  1.0
  N  N7  1  0.750  0.825  0.315  1.0
  Cl  Cl8  1  0.250  0.948  0.216  1.0
  Cl  Cl9  1  0.250  0.552  0.716  1.0
  Cl  Cl10  1  0.750  0.052  0.784  1.0
  Cl  Cl11  1  0.750  0.448  0.284  1.0
  Cl  Cl12  1  0.250  0.922  0.903  1.0
  Cl  Cl13  1  0.250  0.578  0.403  1.0
  Cl  Cl14  1  0.750  0.078  0.097  1.0
  Cl  Cl15  1  0.750  0.422  0.597  1.0
  Cl  Cl16  1  0.012  0.679  0.077  1.0
  Cl  Cl17  1  0.488  0.821  0.577  1.0
  Cl  Cl18  1  0.512  0.321  0.923  1.0
  Cl  Cl19  1  0.988  0.179  0.423  1.0
  Cl  Cl20  1  0.988  0.321  0.923  1.0
  Cl  Cl21  1  0.512  0.179  0.423  1.0
  Cl  Cl22  1  0.488  0.679  0.077  1.0
  Cl  Cl23  1  0.012  0.821  0.577  1.0
[/CIF]
.