The compound described by KLiGd2(MoO4)4 crystallizes in the monoclinic C2/c space group. K(1) is bonded in a 10-coordinate geometry to two equivalent O(2), two equivalent O(5), two equivalent O(6), two equivalent O(7), and two equivalent O(8) atoms. Li(1) is bonded in a 4-coordinate geometry to two equivalent O(5) and two equivalent O(8) atoms. Gd(1) is bonded in a 8-coordinate geometry to one O(6), one O(7), two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a tetrahedral geometry to one O(1), one O(3), one O(5), and one O(6) atom. In the second Mo site, Mo(2) is bonded in a tetrahedral geometry to one O(2), one O(4), one O(7), and one O(8) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to two equivalent Gd(1) and one Mo(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one K(1) and one Mo(2) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to two equivalent Gd(1) and one Mo(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to two equivalent Gd(1) and one Mo(2) atom. In the fifth O site, O(5) is bonded in a 2-coordinate geometry to one K(1), one Li(1), and one Mo(1) atom. In the sixth O site, O(6) is bonded in a 2-coordinate geometry to one K(1), one Gd(1), and one Mo(1) atom. In the seventh O site, O(7) is bonded in a distorted bent 120 degrees geometry to one K(1), one Gd(1), and one Mo(2) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one K(1), one Li(1), and one Mo(2) atom. is represented by the CIF card [CIF]
data_KLiGd2(MoO4)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.962
_cell_length_b   6.962
_cell_length_c   19.652
_cell_angle_alpha   88.839
_cell_angle_beta   88.839
_cell_angle_gamma   135.149
_symmetry_Int_Tables_number   1
_cell_volume   670.891
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.531  0.469  0.750  1.0
  K  K1  1  0.469  0.531  0.250  1.0
  Li  Li2  1  0.814  0.186  0.750  1.0
  Li  Li3  1  0.186  0.814  0.250  1.0
  Gd  Gd4  1  0.647  0.354  0.533  1.0
  Gd  Gd5  1  0.353  0.646  0.467  1.0
  Gd  Gd6  1  0.646  0.353  0.967  1.0
  Gd  Gd7  1  0.354  0.647  0.033  1.0
  Mo  Mo8  1  0.919  0.043  0.592  1.0
  Mo  Mo9  1  0.081  0.957  0.408  1.0
  Mo  Mo10  1  0.957  0.081  0.908  1.0
  Mo  Mo11  1  0.043  0.919  0.092  1.0
  Mo  Mo12  1  0.233  0.747  0.649  1.0
  Mo  Mo13  1  0.767  0.253  0.351  1.0
  Mo  Mo14  1  0.253  0.767  0.851  1.0
  Mo  Mo15  1  0.747  0.233  0.149  1.0
  O  O16  1  0.670  0.008  0.543  1.0
  O  O17  1  0.330  0.992  0.457  1.0
  O  O18  1  0.992  0.330  0.957  1.0
  O  O19  1  0.008  0.670  0.043  1.0
  O  O20  1  0.489  0.768  0.674  1.0
  O  O21  1  0.511  0.232  0.326  1.0
  O  O22  1  0.232  0.511  0.826  1.0
  O  O23  1  0.768  0.489  0.174  1.0
  O  O24  1  0.724  0.763  0.962  1.0
  O  O25  1  0.276  0.237  0.038  1.0
  O  O26  1  0.237  0.276  0.538  1.0
  O  O27  1  0.763  0.724  0.462  1.0
  O  O28  1  0.434  0.914  0.933  1.0
  O  O29  1  0.566  0.086  0.067  1.0
  O  O30  1  0.086  0.566  0.567  1.0
  O  O31  1  0.914  0.434  0.433  1.0
  O  O32  1  0.801  0.985  0.829  1.0
  O  O33  1  0.199  0.015  0.171  1.0
  O  O34  1  0.015  0.199  0.671  1.0
  O  O35  1  0.985  0.801  0.329  1.0
  O  O36  1  0.723  0.812  0.102  1.0
  O  O37  1  0.277  0.188  0.898  1.0
  O  O38  1  0.188  0.277  0.398  1.0
  O  O39  1  0.812  0.723  0.602  1.0
  O  O40  1  0.398  0.095  0.633  1.0
  O  O41  1  0.602  0.905  0.367  1.0
  O  O42  1  0.905  0.602  0.867  1.0
  O  O43  1  0.095  0.398  0.133  1.0
  O  O44  1  0.436  0.029  0.786  1.0
  O  O45  1  0.564  0.971  0.214  1.0
  O  O46  1  0.971  0.564  0.714  1.0
  O  O47  1  0.029  0.436  0.286  1.0
[/CIF]
.
The compound described by KLiGd2(MoO4)4 crystallizes in the monoclinic C2/c space group. K(1) is bonded in a 10-coordinate geometry to two equivalent O(2), two equivalent O(5), two equivalent O(6), two equivalent O(7), and two equivalent O(8) atoms. Li(1) is bonded in a 4-coordinate geometry to two equivalent O(5) and two equivalent O(8) atoms. Gd(1) is bonded in a 8-coordinate geometry to one O(6), one O(7), two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a tetrahedral geometry to one O(1), one O(3), one O(5), and one O(6) atom. In the second Mo site, Mo(2) is bonded in a tetrahedral geometry to one O(2), one O(4), one O(7), and one O(8) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to two equivalent Gd(1) and one Mo(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one K(1) and one Mo(2) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to two equivalent Gd(1) and one Mo(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to two equivalent Gd(1) and one Mo(2) atom. In the fifth O site, O(5) is bonded in a 2-coordinate geometry to one K(1), one Li(1), and one Mo(1) atom. In the sixth O site, O(6) is bonded in a 2-coordinate geometry to one K(1), one Gd(1), and one Mo(1) atom. In the seventh O site, O(7) is bonded in a distorted bent 120 degrees geometry to one K(1), one Gd(1), and one Mo(2) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one K(1), one Li(1), and one Mo(2) atom. is represented by the CIF card [CIF]
data_KLiGd2(MoO4)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.962
_cell_length_b   6.962
_cell_length_c   19.652
_cell_angle_alpha   88.839
_cell_angle_beta   88.839
_cell_angle_gamma   135.149
_symmetry_Int_Tables_number   1
_cell_volume   670.891
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.531  0.469  0.750  1.0
  K  K1  1  0.469  0.531  0.250  1.0
  Li  Li2  1  0.814  0.186  0.750  1.0
  Li  Li3  1  0.186  0.814  0.250  1.0
  Gd  Gd4  1  0.647  0.354  0.533  1.0
  Gd  Gd5  1  0.353  0.646  0.467  1.0
  Gd  Gd6  1  0.646  0.353  0.967  1.0
  Gd  Gd7  1  0.354  0.647  0.033  1.0
  Mo  Mo8  1  0.919  0.043  0.592  1.0
  Mo  Mo9  1  0.081  0.957  0.408  1.0
  Mo  Mo10  1  0.957  0.081  0.908  1.0
  Mo  Mo11  1  0.043  0.919  0.092  1.0
  Mo  Mo12  1  0.233  0.747  0.649  1.0
  Mo  Mo13  1  0.767  0.253  0.351  1.0
  Mo  Mo14  1  0.253  0.767  0.851  1.0
  Mo  Mo15  1  0.747  0.233  0.149  1.0
  O  O16  1  0.670  0.008  0.543  1.0
  O  O17  1  0.330  0.992  0.457  1.0
  O  O18  1  0.992  0.330  0.957  1.0
  O  O19  1  0.008  0.670  0.043  1.0
  O  O20  1  0.489  0.768  0.674  1.0
  O  O21  1  0.511  0.232  0.326  1.0
  O  O22  1  0.232  0.511  0.826  1.0
  O  O23  1  0.768  0.489  0.174  1.0
  O  O24  1  0.724  0.763  0.962  1.0
  O  O25  1  0.276  0.237  0.038  1.0
  O  O26  1  0.237  0.276  0.538  1.0
  O  O27  1  0.763  0.724  0.462  1.0
  O  O28  1  0.434  0.914  0.933  1.0
  O  O29  1  0.566  0.086  0.067  1.0
  O  O30  1  0.086  0.566  0.567  1.0
  O  O31  1  0.914  0.434  0.433  1.0
  O  O32  1  0.801  0.985  0.829  1.0
  O  O33  1  0.199  0.015  0.171  1.0
  O  O34  1  0.015  0.199  0.671  1.0
  O  O35  1  0.985  0.801  0.329  1.0
  O  O36  1  0.723  0.812  0.102  1.0
  O  O37  1  0.277  0.188  0.898  1.0
  O  O38  1  0.188  0.277  0.398  1.0
  O  O39  1  0.812  0.723  0.602  1.0
  O  O40  1  0.398  0.095  0.633  1.0
  O  O41  1  0.602  0.905  0.367  1.0
  O  O42  1  0.905  0.602  0.867  1.0
  O  O43  1  0.095  0.398  0.133  1.0
  O  O44  1  0.436  0.029  0.786  1.0
  O  O45  1  0.564  0.971  0.214  1.0
  O  O46  1  0.971  0.564  0.714  1.0
  O  O47  1  0.029  0.436  0.286  1.0
[/CIF]
.