The compound described by (VO(O2)2NH3)2Ni(NH3)6 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one Ni(NH3)6 cluster and two VO(O2)2NH3 clusters. In the Ni(NH3)6 cluster, Ni(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent N(3), and two equivalent N(4) atoms. There are three inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal non-coplanar geometry to one Ni(1), one H(1), one H(6), and one H(9) atom. In the second N site, N(3) is bonded in a distorted trigonal non-coplanar geometry to one Ni(1), one H(10), one H(11), and one H(8) atom. In the third N site, N(4) is bonded in a distorted trigonal non-coplanar geometry to one Ni(1), one H(2), one H(4), and one H(5) atom. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(4) atom. In the third H site, H(4) is bonded in a single-bond geometry to one N(4) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one N(4) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one N(1) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one N(3) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one N(1) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one N(3) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one N(3) atom. In each VO(O2)2NH3 cluster, V(1) is bonded in a 6-coordinate geometry to one N(2), one O(1), one O(2), one O(3), one O(4), and one O(5) atom. N(2) is bonded in a distorted trigonal non-coplanar geometry to one V(1), one H(12), one H(3), and one H(7) atom. There are three inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(7) is bonded in a single-bond geometry to one N(2) atom. In the third H site, H(12) is bonded in a single-bond geometry to one N(2) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one V(1) and one O(4) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one V(1) and one O(5) atom. In the third O site, O(3) is bonded in a single-bond geometry to one V(1) atom. In the fourth O site, O(4) is bonded in a 2-coordinate geometry to one V(1) and one O(1) atom. In the fifth O site, O(5) is bonded in a 2-coordinate geometry to one V(1) and one O(2) atom. is represented by the CIF file [CIF]
data_V2NiH24(N4O5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.089
_cell_length_b   7.589
_cell_length_c   9.406
_cell_angle_alpha   105.208
_cell_angle_beta   94.842
_cell_angle_gamma   97.115
_symmetry_Int_Tables_number   1
_cell_volume   413.119
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.541  0.884  0.673  1.0
  V  V1  1  0.459  0.116  0.327  1.0
  Ni  Ni2  1  0.000  0.500  0.000  1.0
  H  H3  1  0.993  0.564  0.732  1.0
  H  H4  1  0.957  0.139  0.848  1.0
  H  H5  1  0.072  0.198  0.433  1.0
  H  H6  1  0.849  0.825  0.010  1.0
  H  H7  1  0.151  0.175  0.990  1.0
  H  H8  1  0.787  0.772  0.162  1.0
  H  H9  1  0.811  0.374  0.709  1.0
  H  H10  1  0.728  0.624  0.489  1.0
  H  H11  1  0.574  0.438  0.073  1.0
  H  H12  1  0.746  0.582  0.779  1.0
  H  H13  1  0.007  0.436  0.268  1.0
  H  H14  1  0.213  0.228  0.838  1.0
  H  H15  1  0.609  0.264  0.933  1.0
  H  H16  1  0.254  0.418  0.221  1.0
  H  H17  1  0.426  0.562  0.927  1.0
  H  H18  1  0.708  0.279  0.106  1.0
  H  H19  1  0.928  0.802  0.567  1.0
  H  H20  1  0.189  0.626  0.291  1.0
  H  H21  1  0.268  0.187  0.569  1.0
  H  H22  1  0.043  0.861  0.152  1.0
  H  H23  1  0.391  0.736  0.067  1.0
  H  H24  1  0.732  0.813  0.431  1.0
  H  H25  1  0.272  0.376  0.511  1.0
  H  H26  1  0.292  0.721  0.894  1.0
  N  N27  1  0.129  0.497  0.221  1.0
  N  N28  1  0.237  0.234  0.477  1.0
  N  N29  1  0.314  0.645  0.968  1.0
  N  N30  1  0.908  0.769  0.092  1.0
  N  N31  1  0.871  0.503  0.779  1.0
  N  N32  1  0.763  0.766  0.523  1.0
  N  N33  1  0.686  0.355  0.032  1.0
  N  N34  1  0.092  0.231  0.908  1.0
  O  O35  1  0.654  0.108  0.629  1.0
  O  O36  1  0.241  0.785  0.687  1.0
  O  O37  1  0.759  0.215  0.313  1.0
  O  O38  1  0.693  0.880  0.826  1.0
  O  O39  1  0.307  0.120  0.174  1.0
  O  O40  1  0.533  0.870  0.283  1.0
  O  O41  1  0.346  0.892  0.371  1.0
  O  O42  1  0.467  0.130  0.717  1.0
  O  O43  1  0.362  0.651  0.595  1.0
  O  O44  1  0.638  0.349  0.405  1.0
[/CIF]
.
The compound described by (VO(O2)2NH3)2Ni(NH3)6 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one Ni(NH3)6 cluster and two VO(O2)2NH3 clusters. In the Ni(NH3)6 cluster, Ni(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent N(3), and two equivalent N(4) atoms. There are three inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal non-coplanar geometry to one Ni(1), one H(1), one H(6), and one H(9) atom. In the second N site, N(3) is bonded in a distorted trigonal non-coplanar geometry to one Ni(1), one H(10), one H(11), and one H(8) atom. In the third N site, N(4) is bonded in a distorted trigonal non-coplanar geometry to one Ni(1), one H(2), one H(4), and one H(5) atom. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(4) atom. In the third H site, H(4) is bonded in a single-bond geometry to one N(4) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one N(4) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one N(1) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one N(3) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one N(1) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one N(3) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one N(3) atom. In each VO(O2)2NH3 cluster, V(1) is bonded in a 6-coordinate geometry to one N(2), one O(1), one O(2), one O(3), one O(4), and one O(5) atom. N(2) is bonded in a distorted trigonal non-coplanar geometry to one V(1), one H(12), one H(3), and one H(7) atom. There are three inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(7) is bonded in a single-bond geometry to one N(2) atom. In the third H site, H(12) is bonded in a single-bond geometry to one N(2) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one V(1) and one O(4) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one V(1) and one O(5) atom. In the third O site, O(3) is bonded in a single-bond geometry to one V(1) atom. In the fourth O site, O(4) is bonded in a 2-coordinate geometry to one V(1) and one O(1) atom. In the fifth O site, O(5) is bonded in a 2-coordinate geometry to one V(1) and one O(2) atom. is represented by the CIF file [CIF]
data_V2NiH24(N4O5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.089
_cell_length_b   7.589
_cell_length_c   9.406
_cell_angle_alpha   105.208
_cell_angle_beta   94.842
_cell_angle_gamma   97.115
_symmetry_Int_Tables_number   1
_cell_volume   413.119
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.541  0.884  0.673  1.0
  V  V1  1  0.459  0.116  0.327  1.0
  Ni  Ni2  1  0.000  0.500  0.000  1.0
  H  H3  1  0.993  0.564  0.732  1.0
  H  H4  1  0.957  0.139  0.848  1.0
  H  H5  1  0.072  0.198  0.433  1.0
  H  H6  1  0.849  0.825  0.010  1.0
  H  H7  1  0.151  0.175  0.990  1.0
  H  H8  1  0.787  0.772  0.162  1.0
  H  H9  1  0.811  0.374  0.709  1.0
  H  H10  1  0.728  0.624  0.489  1.0
  H  H11  1  0.574  0.438  0.073  1.0
  H  H12  1  0.746  0.582  0.779  1.0
  H  H13  1  0.007  0.436  0.268  1.0
  H  H14  1  0.213  0.228  0.838  1.0
  H  H15  1  0.609  0.264  0.933  1.0
  H  H16  1  0.254  0.418  0.221  1.0
  H  H17  1  0.426  0.562  0.927  1.0
  H  H18  1  0.708  0.279  0.106  1.0
  H  H19  1  0.928  0.802  0.567  1.0
  H  H20  1  0.189  0.626  0.291  1.0
  H  H21  1  0.268  0.187  0.569  1.0
  H  H22  1  0.043  0.861  0.152  1.0
  H  H23  1  0.391  0.736  0.067  1.0
  H  H24  1  0.732  0.813  0.431  1.0
  H  H25  1  0.272  0.376  0.511  1.0
  H  H26  1  0.292  0.721  0.894  1.0
  N  N27  1  0.129  0.497  0.221  1.0
  N  N28  1  0.237  0.234  0.477  1.0
  N  N29  1  0.314  0.645  0.968  1.0
  N  N30  1  0.908  0.769  0.092  1.0
  N  N31  1  0.871  0.503  0.779  1.0
  N  N32  1  0.763  0.766  0.523  1.0
  N  N33  1  0.686  0.355  0.032  1.0
  N  N34  1  0.092  0.231  0.908  1.0
  O  O35  1  0.654  0.108  0.629  1.0
  O  O36  1  0.241  0.785  0.687  1.0
  O  O37  1  0.759  0.215  0.313  1.0
  O  O38  1  0.693  0.880  0.826  1.0
  O  O39  1  0.307  0.120  0.174  1.0
  O  O40  1  0.533  0.870  0.283  1.0
  O  O41  1  0.346  0.892  0.371  1.0
  O  O42  1  0.467  0.130  0.717  1.0
  O  O43  1  0.362  0.651  0.595  1.0
  O  O44  1  0.638  0.349  0.405  1.0
[/CIF]
.