The compound described by Li4Co5SnO12 crystallizes in the triclinic P1 space group. There are eight inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(11), one O(15), one O(21), one O(23), and one O(7) atom to form distorted LiO6 octahedra that share  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra, corners with three equivalent Co(7)O6 octahedra, corners with three equivalent Sn(2)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra, edges with three equivalent Li(5)O6 octahedra, and  a faceface with one Co(10)O6 octahedra. The corner-sharing octahedral tilt angles range from 10-50°. In the second Li site, Li(2) is bonded to one O(12), one O(16), one O(2), one O(22), one O(24), and one O(8) atom to form distorted LiO6 octahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra, corners with three equivalent Co(8)O6 octahedra, corners with three equivalent Sn(1)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra, edges with three equivalent Li(6)O6 octahedra, and  a faceface with one Co(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 10-52°. In the third Li site, Li(3) is bonded to one O(13), one O(17), one O(19), one O(3), one O(5), and one O(9) atom to form distorted LiO6 octahedra that share  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra, corners with three equivalent Co(8)O6 octahedra, corners with three equivalent Sn(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra, edges with three equivalent Li(7)O6 octahedra, and  a faceface with one Co(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 9-52°. In the fourth Li site, Li(4) is bonded to one O(10), one O(14), one O(18), one O(20), one O(4), and one O(6) atom to form LiO6 octahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra, corners with three equivalent Co(7)O6 octahedra, corners with three equivalent Sn(2)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra, edges with three equivalent Li(8)O6 octahedra, and  a faceface with one Co(10)O6 octahedra. The corner-sharing octahedral tilt angles range from 10-50°. In the fifth Li site, Li(5) is bonded to one O(1), one O(11), one O(15), one O(21), one O(23), and one O(7) atom to form distorted LiO6 octahedra that share  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra, corners with three equivalent Co(10)O6 octahedra, corners with three equivalent Sn(2)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra, edges with three equivalent Li(1)O6 octahedra, and  a faceface with one Co(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 10-50°. In the sixth Li site, Li(6) is bonded to one O(12), one O(16), one O(2), one O(22), one O(24), and one O(8) atom to form distorted LiO6 octahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra, corners with three equivalent Co(9)O6 octahedra, corners with three equivalent Sn(1)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra, edges with three equivalent Li(2)O6 octahedra, and  a faceface with one Co(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 9-50°. In the seventh Li site, Li(7) is bonded to one O(13), one O(17), one O(19), one O(3), one O(5), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra, corners with three equivalent Co(9)O6 octahedra, corners with three equivalent Sn(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra, edges with three equivalent Li(3)O6 octahedra, and  a faceface with one Co(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 9-50°. In the eighth Li site, Li(8) is bonded to one O(10), one O(14), one O(18), one O(20), one O(4), and one O(6) atom to form LiO6 octahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra, corners with three equivalent Co(10)O6 octahedra, corners with three equivalent Sn(2)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra, edges with three equivalent Li(4)O6 octahedra, and  a faceface with one Co(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 9-50°. There are ten inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(18), one O(2), one O(20), one O(22), one O(24), and one O(4) atom to form CoO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra, edges with three equivalent Co(3)O6 octahedra, and edges with three equivalent Co(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 12-13°. In the second Co site, Co(2) is bonded to one O(1), one O(17), one O(19), one O(21), one O(23), and one O(3) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra, edges with three equivalent Co(4)O6 octahedra, and edges with three equivalent Co(6)O6 octahedra. The corner-sharing octahedral tilt angles are 12°. In the third Co site, Co(3) is bonded to one O(18), one O(2), one O(20), one O(22), one O(24), and one O(4) atom to form CoO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra, edges with three equivalent Co(1)O6 octahedra, and edges with three equivalent Co(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 9-12°. In the fourth Co site, Co(4) is bonded to one O(1), one O(17), one O(19), one O(21), one O(23), and one O(3) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra, edges with three equivalent Co(2)O6 octahedra, and edges with three equivalent Co(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 12-13°. In the fifth Co site, Co(5) is bonded to one O(18), one O(2), one O(20), one O(22), one O(24), and one O(4) atom to form CoO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra, edges with three equivalent Co(1)O6 octahedra, and edges with three equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 10-13°. In the sixth Co site, Co(6) is bonded to one O(1), one O(17), one O(19), one O(21), one O(23), and one O(3) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra, edges with three equivalent Co(2)O6 octahedra, and edges with three equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 9-10°. In the seventh Co site, Co(7) is bonded to one O(10), one O(11), one O(14), one O(15), one O(6), and one O(7) atom to form CoO6 octahedra that share corners with three equivalent Li(1)O6 octahedra, corners with three equivalent Li(4)O6 octahedra, edges with three equivalent Co(10)O6 octahedra, edges with three equivalent Sn(2)O6 octahedra,  a faceface with one Li(5)O6 octahedra, and  a faceface with one Li(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-45°. In the eighth Co site, Co(8) is bonded to one O(12), one O(13), one O(16), one O(5), one O(8), and one O(9) atom to form CoO6 octahedra that share corners with three equivalent Li(2)O6 octahedra, corners with three equivalent Li(3)O6 octahedra, edges with three equivalent Co(9)O6 octahedra, edges with three equivalent Sn(1)O6 octahedra,  a faceface with one Li(6)O6 octahedra, and  a faceface with one Li(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 43-45°. In the ninth Co site, Co(9) is bonded to one O(12), one O(13), one O(16), one O(5), one O(8), and one O(9) atom to form CoO6 octahedra that share corners with three equivalent Li(6)O6 octahedra, corners with three equivalent Li(7)O6 octahedra, edges with three equivalent Co(8)O6 octahedra, edges with three equivalent Sn(1)O6 octahedra,  a faceface with one Li(2)O6 octahedra, and  a faceface with one Li(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 43-45°. In the tenth Co site, Co(10) is bonded to one O(10), one O(11), one O(14), one O(15), one O(6), and one O(7) atom to form CoO6 octahedra that share corners with three equivalent Li(5)O6 octahedra, corners with three equivalent Li(8)O6 octahedra, edges with three equivalent Co(7)O6 octahedra, edges with three equivalent Sn(2)O6 octahedra,  a faceface with one Li(1)O6 octahedra, and  a faceface with one Li(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-45°. There are two inequivalent Sn sites. In the first Sn site, Sn(1) is bonded to one O(12), one O(13), one O(16), one O(5), one O(8), and one O(9) atom to form SnO6 octahedra that share corners with three equivalent Li(2)O6 octahedra, corners with three equivalent Li(3)O6 octahedra, corners with three equivalent Li(6)O6 octahedra, corners with three equivalent Li(7)O6 octahedra, edges with three equivalent Co(8)O6 octahedra, and edges with three equivalent Co(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-52°. In the second Sn site, Sn(2) is bonded to one O(10), one O(11), one O(14), one O(15), one O(6), and one O(7) atom to form SnO6 octahedra that share corners with three equivalent Li(1)O6 octahedra, corners with three equivalent Li(4)O6 octahedra, corners with three equivalent Li(5)O6 octahedra, corners with three equivalent Li(8)O6 octahedra, edges with three equivalent Co(10)O6 octahedra, and edges with three equivalent Co(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-50°. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), one Li(5), one Co(2), one Co(4), and one Co(6) atom to form OLi2Co3 square pyramids that share  a cornercorner with one O(17)Li2Co3 square pyramid,  a cornercorner with one O(19)Li2Co3 square pyramid,  a cornercorner with one O(21)Li2Co3 square pyramid,  a cornercorner with one O(23)Li2Co3 square pyramid,  a cornercorner with one O(3)Li2Co3 square pyramid, corners with two equivalent O(11)Li2Co2Sn trigonal bipyramids, corners with two equivalent O(15)Li2Co2Sn trigonal bipyramids,  an edgeedge with one O(17)Li2Co3 square pyramid,  an edgeedge with one O(19)Li2Co3 square pyramid,  an edgeedge with one O(3)Li2Co3 square pyramid, edges with two equivalent O(21)Li2Co3 square pyramids, edges with two equivalent O(23)Li2Co3 square pyramids, and  an edgeedge with one O(7)Li2Co2Sn trigonal bipyramid. In the second O site, O(2) is bonded to one Li(2), one Li(6), one Co(1), one Co(3), and one Co(5) atom to form OLi2Co3 square pyramids that share  a cornercorner with one O(18)Li2Co3 square pyramid,  a cornercorner with one O(20)Li2Co3 square pyramid,  a cornercorner with one O(22)Li2Co3 square pyramid,  a cornercorner with one O(24)Li2Co3 square pyramid,  a cornercorner with one O(4)Li2Co3 square pyramid, corners with two equivalent O(12)Li2Co2Sn trigonal bipyramids, corners with two equivalent O(16)Li2Co2Sn trigonal bipyramids,  an edgeedge with one O(18)Li2Co3 square pyramid,  an edgeedge with one O(20)Li2Co3 square pyramid,  an edgeedge with one O(4)Li2Co3 square pyramid, edges with two equivalent O(22)Li2Co3 square pyramids, edges with two equivalent O(24)Li2Co3 square pyramids, and  an edgeedge with one O(8)Li2Co2Sn trigonal bipyramid. In the third O site, O(3) is bonded to one Li(3), one Li(7), one Co(2), one Co(4), and one Co(6) atom to form OLi2Co3 square pyramids that share  a cornercorner with one O(1)Li2Co3 square pyramid,  a cornercorner with one O(17)Li2Co3 square pyramid,  a cornercorner with one O(19)Li2Co3 square pyramid,  a cornercorner with one O(21)Li2Co3 square pyramid,  a cornercorner with one O(23)Li2Co3 square pyramid, corners with two equivalent O(13)Li2Co2Sn trigonal bipyramids, corners with two equivalent O(9)Li2Co2Sn trigonal bipyramids,  an edgeedge with one O(1)Li2Co3 square pyramid,  an edgeedge with one O(21)Li2Co3 square pyramid,  an edgeedge with one O(23)Li2Co3 square pyramid, edges with two equivalent O(17)Li2Co3 square pyramids, edges with two equivalent O(19)Li2Co3 square pyramids, and  an edgeedge with one O(5)Li2Co2Sn trigonal bipyramid. In the fourth O site, O(4) is bonded to one Li(4), one Li(8), one Co(1), one Co(3), and one Co(5) atom to form OLi2Co3 square pyramids that share  a cornercorner with one O(18)Li2Co3 square pyramid,  a cornercorner with one O(2)Li2Co3 square pyramid,  a cornercorner with one O(20)Li2Co3 square pyramid,  a cornercorner with one O(22)Li2Co3 square pyramid,  a cornercorner with one O(24)Li2Co3 square pyramid, corners with two equivalent O(10)Li2Co2Sn trigonal bipyramids, corners with two equivalent O(14)Li2Co2Sn trigonal bipyramids,  an edgeedge with one O(2)Li2Co3 square pyramid,  an edgeedge with one O(22)Li2Co3 square pyramid,  an edgeedge with one O(24)Li2Co3 square pyramid, edges with two equivalent O(18)Li2Co3 square pyramids, edges with two equivalent O(20)Li2Co3 square pyramids, and  an edgeedge with one O(6)Li2Co2Sn trigonal bipyramid. In the fifth O site, O(5) is bonded to one Li(3), one Li(7), one Co(8), one Co(9), and one Sn(1) atom to form distorted OLi2Co2Sn trigonal bipyramids that share corners with two equivalent O(17)Li2Co3 square pyramids, corners with two equivalent O(19)Li2Co3 square pyramids,  a cornercorner with one O(12)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(13)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(16)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(8)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(9)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(3)Li2Co3 square pyramid,  an edgeedge with one O(12)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(16)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(8)Li2Co2Sn trigonal bipyramid, edges with two equivalent O(13)Li2Co2Sn trigonal bipyramids, and edges with two equivalent O(9)Li2Co2Sn trigonal bipyramids. In the sixth O site, O(6) is bonded to one Li(4), one Li(8), one Co(10), one Co(7), and one Sn(2) atom to form distorted OLi2Co2Sn trigonal bipyramids that share corners with two equivalent O(18)Li2Co3 square pyramids, corners with two equivalent O(20)Li2Co3 square pyramids,  a cornercorner with one O(10)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(11)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(14)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(15)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(7)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(4)Li2Co3 square pyramid,  an edgeedge with one O(11)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(15)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(7)Li2Co2Sn trigonal bipyramid, edges with two equivalent O(10)Li2Co2Sn trigonal bipyramids, and edges with two equivalent O(14)Li2Co2Sn trigonal bipyramids. In the seventh O site, O(7) is bonded to one Li(1), one Li(5), one Co(10), one Co(7), and one Sn(2) atom to form distorted OLi2Co2Sn trigonal bipyramids that share corners with two equivalent O(21)Li2Co3 square pyramids, corners with two equivalent O(23)Li2Co3 square pyramids,  a cornercorner with one O(10)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(11)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(14)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(15)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(6)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(1)Li2Co3 square pyramid,  an edgeedge with one O(10)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(14)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(6)Li2Co2Sn trigonal bipyramid, edges with two equivalent O(11)Li2Co2Sn trigonal bipyramids, and edges with two equivalent O(15)Li2Co2Sn trigonal bipyramids. In the eighth O site, O(8) is bonded to one Li(2), one Li(6), one Co(8), one Co(9), and one Sn(1) atom to form distorted OLi2Co2Sn trigonal bipyramids that share corners with two equivalent O(22)Li2Co3 square pyramids, corners with two equivalent O(24)Li2Co3 square pyramids,  a cornercorner with one O(12)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(13)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(16)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(5)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(9)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(2)Li2Co3 square pyramid,  an edgeedge with one O(13)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(5)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(9)Li2Co2Sn trigonal bipyramid, edges with two equivalent O(12)Li2Co2Sn trigonal bipyramids, and edges with two equivalent O(16)Li2Co2Sn trigonal bipyramids. In the ninth O site, O(9) is bonded to one Li(3), one Li(7), one Co(8), one Co(9), and one Sn(1) atom to form distorted OLi2Co2Sn trigonal bipyramids that share corners with two equivalent O(19)Li2Co3 square pyramids, corners with two equivalent O(3)Li2Co3 square pyramids,  a cornercorner with one O(12)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(13)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(16)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(5)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(8)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(17)Li2Co3 square pyramid,  an edgeedge with one O(12)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(16)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(8)Li2Co2Sn trigonal bipyramid, edges with two equivalent O(13)Li2Co2Sn trigonal bipyramids, and edges with two equivalent O(5)Li2Co2Sn trigonal bipyramids. In the tenth O site, O(10) is bonded to one Li(4), one Li(8), one Co(10), one Co(7), and one Sn(2) atom to form distorted OLi2Co2Sn trigonal bipyramids that share corners with two equivalent O(20)Li2Co3 square pyramids, corners with two equivalent O(4)Li2Co3 square pyramids,  a cornercorner with one O(11)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(14)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(15)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(6)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(7)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(18)Li2Co3 square pyramid,  an edgeedge with one O(11)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(15)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(7)Li2Co2Sn trigonal bipyramid, edges with two equivalent O(14)Li2Co2Sn trigonal bipyramids, and edges with two equivalent O(6)Li2Co2Sn trigonal bipyramids. In the eleventh O site, O(11) is bonded to one Li(1), one Li(5), one Co(10), one Co(7), and one Sn(2) atom to form distorted OLi2Co2Sn trigonal bipyramids that share corners with two equivalent O(1)Li2Co3 square pyramids, corners with two equivalent O(23)Li2Co3 square pyramids,  a cornercorner with one O(10)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(14)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(15)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(6)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(7)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(21)Li2Co3 square pyramid,  an edgeedge with one O(10)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(14)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(6)Li2Co2Sn trigonal bipyramid, edges with two equivalent O(15)Li2Co2Sn trigonal bipyramids, and edges with two equivalent O(7)Li2Co2Sn trigonal bipyramids. In the twelfth O site, O(12) is bonded to one Li(2), one Li(6), one Co(8), one Co(9), and one Sn(1) atom to form distorted OLi2Co2Sn trigonal bipyramids that share corners with two equivalent O(2)Li2Co3 square pyramids, corners with two equivalent O(24)Li2Co3 square pyramids,  a cornercorner with one O(13)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(16)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(5)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(8)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(9)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(22)Li2Co3 square pyramid,  an edgeedge with one O(13)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(5)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(9)Li2Co2Sn trigonal bipyramid, edges with two equivalent O(16)Li2Co2Sn trigonal bipyramids, and edges with two equivalent O(8)Li2Co2Sn trigonal bipyramids. In the thirteenth O site, O(13) is bonded to one Li(3), one Li(7), one Co(8), one Co(9), and one Sn(1) atom to form distorted OLi2Co2Sn trigonal bipyramids that share corners with two equivalent O(17)Li2Co3 square pyramids, corners with two equivalent O(3)Li2Co3 square pyramids,  a cornercorner with one O(12)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(16)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(5)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(8)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(9)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(19)Li2Co3 square pyramid,  an edgeedge with one O(12)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(16)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(8)Li2Co2Sn trigonal bipyramid, edges with two equivalent O(5)Li2Co2Sn trigonal bipyramids, and edges with two equivalent O(9)Li2Co2Sn trigonal bipyramids. In the fourteenth O site, O(14) is bonded to one Li(4), one Li(8), one Co(10), one Co(7), and one Sn(2) atom to form distorted OLi2Co2Sn trigonal bipyramids that share corners with two equivalent O(18)Li2Co3 square pyramids, corners with two equivalent O(4)Li2Co3 square pyramids,  a cornercorner with one O(10)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(11)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(15)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(6)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(7)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(20)Li2Co3 square pyramid,  an edgeedge with one O(11)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(15)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(7)Li2Co2Sn trigonal bipyramid, edges with two equivalent O(10)Li2Co2Sn trigonal bipyramids, and edges with two equivalent O(6)Li2Co2Sn trigonal bipyramids. In the fifteenth O site, O(15) is bonded to one Li(1), one Li(5), one Co(10), one Co(7), and one Sn(2) atom to form distorted OLi2Co2Sn trigonal bipyramids that share corners with two equivalent O(1)Li2Co3 square pyramids, corners with two equivalent O(21)Li2Co3 square pyramids,  a cornercorner with one O(10)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(11)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(14)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(6)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(7)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(23)Li2Co3 square pyramid,  an edgeedge with one O(10)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(14)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(6)Li2Co2Sn trigonal bipyramid, edges with two equivalent O(11)Li2Co2Sn trigonal bipyramids, and edges with two equivalent O(7)Li2Co2Sn trigonal bipyramids. In the sixteenth O site, O(16) is bonded to one Li(2), one Li(6), one Co(8), one Co(9), and one Sn(1) atom to form distorted OLi2Co2Sn trigonal bipyramids that share corners with two equivalent O(2)Li2Co3 square pyramids, corners with two equivalent O(22)Li2Co3 square pyramids,  a cornercorner with one O(12)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(13)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(5)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(8)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(9)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(24)Li2Co3 square pyramid,  an edgeedge with one O(13)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(5)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(9)Li2Co2Sn trigonal bipyramid, edges with two equivalent O(12)Li2Co2Sn trigonal bipyramids, and edges with two equivalent O(8)Li2Co2Sn trigonal bipyramids. In the seventeenth O site, O(17) is bonded to one Li(3), one Li(7), one Co(2), one Co(4), and one Co(6) atom to form OLi2Co3 square pyramids that share  a cornercorner with one O(1)Li2Co3 square pyramid,  a cornercorner with one O(19)Li2Co3 square pyramid,  a cornercorner with one O(21)Li2Co3 square pyramid,  a cornercorner with one O(23)Li2Co3 square pyramid,  a cornercorner with one O(3)Li2Co3 square pyramid, corners with two equivalent O(13)Li2Co2Sn trigonal bipyramids, corners with two equivalent O(5)Li2Co2Sn trigonal bipyramids,  an edgeedge with one O(1)Li2Co3 square pyramid,  an edgeedge with one O(21)Li2Co3 square pyramid,  an edgeedge with one O(23)Li2Co3 square pyramid, edges with two equivalent O(19)Li2Co3 square pyramids, edges with two equivalent O(3)Li2Co3 square pyramids, and  an edgeedge with one O(9)Li2Co2Sn trigonal bipyramid. In the eighteenth O site, O(18) is bonded to one Li(4), one Li(8), one Co(1), one Co(3), and one Co(5) atom to form OLi2Co3 square pyramids that share  a cornercorner with one O(2)Li2Co3 square pyramid,  a cornercorner with one O(20)Li2Co3 square pyramid,  a cornercorner with one O(22)Li2Co3 square pyramid,  a cornercorner with one O(24)Li2Co3 square pyramid,  a cornercorner with one O(4)Li2Co3 square pyramid, corners with two equivalent O(14)Li2Co2Sn trigonal bipyramids, corners with two equivalent O(6)Li2Co2Sn trigonal bipyramids,  an edgeedge with one O(2)Li2Co3 square pyramid,  an edgeedge with one O(22)Li2Co3 square pyramid,  an edgeedge with one O(24)Li2Co3 square pyramid, edges with two equivalent O(20)Li2Co3 square pyramids, edges with two equivalent O(4)Li2Co3 square pyramids, and  an edgeedge with one O(10)Li2Co2Sn trigonal bipyramid. In the nineteenth O site, O(19) is bonded to one Li(3), one Li(7), one Co(2), one Co(4), and one Co(6) atom to form OLi2Co3 square pyramids that share  a cornercorner with one O(1)Li2Co3 square pyramid,  a cornercorner with one O(17)Li2Co3 square pyramid,  a cornercorner with one O(21)Li2Co3 square pyramid,  a cornercorner with one O(23)Li2Co3 square pyramid,  a cornercorner with one O(3)Li2Co3 square pyramid, corners with two equivalent O(5)Li2Co2Sn trigonal bipyramids, corners with two equivalent O(9)Li2Co2Sn trigonal bipyramids,  an edgeedge with one O(1)Li2Co3 square pyramid,  an edgeedge with one O(21)Li2Co3 square pyramid,  an edgeedge with one O(23)Li2Co3 square pyramid, edges with two equivalent O(17)Li2Co3 square pyramids, edges with two equivalent O(3)Li2Co3 square pyramids, and  an edgeedge with one O(13)Li2Co2Sn trigonal bipyramid. In the twentieth O site, O(20) is bonded to one Li(4), one Li(8), one Co(1), one Co(3), and one Co(5) atom to form OLi2Co3 square pyramids that share  a cornercorner with one O(18)Li2Co3 square pyramid,  a cornercorner with one O(2)Li2Co3 square pyramid,  a cornercorner with one O(22)Li2Co3 square pyramid,  a cornercorner with one O(24)Li2Co3 square pyramid,  a cornercorner with one O(4)Li2Co3 square pyramid, corners with two equivalent O(10)Li2Co2Sn trigonal bipyramids, corners with two equivalent O(6)Li2Co2Sn trigonal bipyramids,  an edgeedge with one O(2)Li2Co3 square pyramid,  an edgeedge with one O(22)Li2Co3 square pyramid,  an edgeedge with one O(24)Li2Co3 square pyramid, edges with two equivalent O(18)Li2Co3 square pyramids, edges with two equivalent O(4)Li2Co3 square pyramids, and  an edgeedge with one O(14)Li2Co2Sn trigonal bipyramid. In the twenty-first O site, O(21) is bonded to one Li(1), one Li(5), one Co(2), one Co(4), and one Co(6) atom to form OLi2Co3 square pyramids that share  a cornercorner with one O(1)Li2Co3 square pyramid,  a cornercorner with one O(17)Li2Co3 square pyramid,  a cornercorner with one O(19)Li2Co3 square pyramid,  a cornercorner with one O(23)Li2Co3 square pyramid,  a cornercorner with one O(3)Li2Co3 square pyramid, corners with two equivalent O(15)Li2Co2Sn trigonal bipyramids, corners with two equivalent O(7)Li2Co2Sn trigonal bipyramids,  an edgeedge with one O(17)Li2Co3 square pyramid,  an edgeedge with one O(19)Li2Co3 square pyramid,  an edgeedge with one O(3)Li2Co3 square pyramid, edges with two equivalent O(1)Li2Co3 square pyramids, edges with two equivalent O(23)Li2Co3 square pyramids, and  an edgeedge with one O(11)Li2Co2Sn trigonal bipyramid. In the twenty-second O site, O(22) is bonded to one Li(2), one Li(6), one Co(1), one Co(3), and one Co(5) atom to form OLi2Co3 square pyramids that share  a cornercorner with one O(18)Li2Co3 square pyramid,  a cornercorner with one O(2)Li2Co3 square pyramid,  a cornercorner with one O(20)Li2Co3 square pyramid,  a cornercorner with one O(24)Li2Co3 square pyramid,  a cornercorner with one O(4)Li2Co3 square pyramid, corners with two equivalent O(16)Li2Co2Sn trigonal bipyramids, corners with two equivalent O(8)Li2Co2Sn trigonal bipyramids,  an edgeedge with one O(18)Li2Co3 square pyramid,  an edgeedge with one O(20)Li2Co3 square pyramid,  an edgeedge with one O(4)Li2Co3 square pyramid, edges with two equivalent O(2)Li2Co3 square pyramids, edges with two equivalent O(24)Li2Co3 square pyramids, and  an edgeedge with one O(12)Li2Co2Sn trigonal bipyramid. In the twenty-third O site, O(23) is bonded to one Li(1), one Li(5), one Co(2), one Co(4), and one Co(6) atom to form OLi2Co3 square pyramids that share  a cornercorner with one O(1)Li2Co3 square pyramid,  a cornercorner with one O(17)Li2Co3 square pyramid,  a cornercorner with one O(19)Li2Co3 square pyramid,  a cornercorner with one O(21)Li2Co3 square pyramid,  a cornercorner with one O(3)Li2Co3 square pyramid, corners with two equivalent O(11)Li2Co2Sn trigonal bipyramids, corners with two equivalent O(7)Li2Co2Sn trigonal bipyramids,  an edgeedge with one O(17)Li2Co3 square pyramid,  an edgeedge with one O(19)Li2Co3 square pyramid,  an edgeedge with one O(3)Li2Co3 square pyramid, edges with two equivalent O(1)Li2Co3 square pyramids, edges with two equivalent O(21)Li2Co3 square pyramids, and  an edgeedge with one O(15)Li2Co2Sn trigonal bipyramid. In the twenty-fourth O site, O(24) is bonded to one Li(2), one Li(6), one Co(1), one Co(3), and one Co(5) atom to form OLi2Co3 square pyramids that share  a cornercorner with one O(18)Li2Co3 square pyramid,  a cornercorner with one O(2)Li2Co3 square pyramid,  a cornercorner with one O(20)Li2Co3 square pyramid,  a cornercorner with one O(22)Li2Co3 square pyramid,  a cornercorner with one O(4)Li2Co3 square pyramid, corners with two equivalent O(12)Li2Co2Sn trigonal bipyramids, corners with two equivalent O(8)Li2Co2Sn trigonal bipyramids,  an edgeedge with one O(18)Li2Co3 square pyramid,  an edgeedge with one O(20)Li2Co3 square pyramid,  an edgeedge with one O(4)Li2Co3 square pyramid, edges with two equivalent O(2)Li2Co3 square pyramids, edges with two equivalent O(22)Li2Co3 square pyramids, and  an edgeedge with one O(16)Li2Co2Sn trigonal bipyramid. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li4Co5SnO12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.144
_cell_length_b   5.083
_cell_length_c   19.844
_cell_angle_alpha   92.598
_cell_angle_beta   84.914
_cell_angle_gamma   120.329
_symmetry_Int_Tables_number   1
_cell_volume   446.082
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.208  0.337  0.370  1.0
  Li  Li1  1  0.716  0.345  0.870  1.0
  Li  Li2  1  0.632  0.339  0.130  1.0
  Li  Li3  1  0.129  0.338  0.630  1.0
  Li  Li4  1  0.871  0.665  0.371  1.0
  Li  Li5  1  0.371  0.661  0.871  1.0
  Li  Li6  1  0.294  0.667  0.129  1.0
  Li  Li7  1  0.788  0.661  0.630  1.0
  Co  Co8  1  0.749  0.998  0.750  1.0
  Co  Co9  1  0.585  0.667  0.250  1.0
  Co  Co10  1  0.083  0.667  0.750  1.0
  Co  Co11  1  0.918  0.333  0.250  1.0
  Co  Co12  1  0.417  0.333  0.750  1.0
  Co  Co13  1  0.250  1.000  0.250  1.0
  Co  Co14  1  0.831  0.667  0.500  1.0
  Co  Co15  1  0.333  0.665  1.000  1.0
  Co  Co16  1  0.668  0.335  1.000  1.0
  Co  Co17  1  0.165  0.334  0.500  1.0
  Sn  Sn18  1  0.996  0.997  0.000  1.0
  Sn  Sn19  1  0.503  0.000  0.500  1.0
  O  O20  1  0.912  0.000  0.298  1.0
  O  O21  1  0.409  0.996  0.798  1.0
  O  O22  1  0.590  0.000  0.202  1.0
  O  O23  1  0.087  0.995  0.702  1.0
  O  O24  1  0.331  0.989  0.053  1.0
  O  O25  1  0.826  0.999  0.558  1.0
  O  O26  1  0.170  0.002  0.445  1.0
  O  O27  1  0.662  0.993  0.944  1.0
  O  O28  1  0.637  0.650  0.058  1.0
  O  O29  1  0.138  0.650  0.556  1.0
  O  O30  1  0.520  0.655  0.443  1.0
  O  O31  1  0.009  0.650  0.943  1.0
  O  O32  1  0.991  0.351  0.056  1.0
  O  O33  1  0.486  0.349  0.557  1.0
  O  O34  1  0.864  0.346  0.443  1.0
  O  O35  1  0.359  0.357  0.945  1.0
  O  O36  1  0.299  0.334  0.198  1.0
  O  O37  1  0.780  0.360  0.699  1.0
  O  O38  1  0.964  0.665  0.198  1.0
  O  O39  1  0.417  0.644  0.700  1.0
  O  O40  1  0.536  0.337  0.302  1.0
  O  O41  1  0.080  0.361  0.801  1.0
  O  O42  1  0.200  0.664  0.302  1.0
  O  O43  1  0.726  0.645  0.800  1.0
[/CIF]
.
The compound described by Li4Co5SnO12 crystallizes in the triclinic P1 space group. There are eight inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(11), one O(15), one O(21), one O(23), and one O(7) atom to form distorted LiO6 octahedra that share  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra, corners with three equivalent Co(7)O6 octahedra, corners with three equivalent Sn(2)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra, edges with three equivalent Li(5)O6 octahedra, and  a faceface with one Co(10)O6 octahedra. The corner-sharing octahedral tilt angles range from 10-50°. In the second Li site, Li(2) is bonded to one O(12), one O(16), one O(2), one O(22), one O(24), and one O(8) atom to form distorted LiO6 octahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra, corners with three equivalent Co(8)O6 octahedra, corners with three equivalent Sn(1)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra, edges with three equivalent Li(6)O6 octahedra, and  a faceface with one Co(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 10-52°. In the third Li site, Li(3) is bonded to one O(13), one O(17), one O(19), one O(3), one O(5), and one O(9) atom to form distorted LiO6 octahedra that share  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra, corners with three equivalent Co(8)O6 octahedra, corners with three equivalent Sn(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra, edges with three equivalent Li(7)O6 octahedra, and  a faceface with one Co(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 9-52°. In the fourth Li site, Li(4) is bonded to one O(10), one O(14), one O(18), one O(20), one O(4), and one O(6) atom to form LiO6 octahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra, corners with three equivalent Co(7)O6 octahedra, corners with three equivalent Sn(2)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra, edges with three equivalent Li(8)O6 octahedra, and  a faceface with one Co(10)O6 octahedra. The corner-sharing octahedral tilt angles range from 10-50°. In the fifth Li site, Li(5) is bonded to one O(1), one O(11), one O(15), one O(21), one O(23), and one O(7) atom to form distorted LiO6 octahedra that share  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra, corners with three equivalent Co(10)O6 octahedra, corners with three equivalent Sn(2)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra, edges with three equivalent Li(1)O6 octahedra, and  a faceface with one Co(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 10-50°. In the sixth Li site, Li(6) is bonded to one O(12), one O(16), one O(2), one O(22), one O(24), and one O(8) atom to form distorted LiO6 octahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra, corners with three equivalent Co(9)O6 octahedra, corners with three equivalent Sn(1)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra, edges with three equivalent Li(2)O6 octahedra, and  a faceface with one Co(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 9-50°. In the seventh Li site, Li(7) is bonded to one O(13), one O(17), one O(19), one O(3), one O(5), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra, corners with three equivalent Co(9)O6 octahedra, corners with three equivalent Sn(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra, edges with three equivalent Li(3)O6 octahedra, and  a faceface with one Co(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 9-50°. In the eighth Li site, Li(8) is bonded to one O(10), one O(14), one O(18), one O(20), one O(4), and one O(6) atom to form LiO6 octahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra, corners with three equivalent Co(10)O6 octahedra, corners with three equivalent Sn(2)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra, edges with three equivalent Li(4)O6 octahedra, and  a faceface with one Co(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 9-50°. There are ten inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(18), one O(2), one O(20), one O(22), one O(24), and one O(4) atom to form CoO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra, edges with three equivalent Co(3)O6 octahedra, and edges with three equivalent Co(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 12-13°. In the second Co site, Co(2) is bonded to one O(1), one O(17), one O(19), one O(21), one O(23), and one O(3) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra, edges with three equivalent Co(4)O6 octahedra, and edges with three equivalent Co(6)O6 octahedra. The corner-sharing octahedral tilt angles are 12°. In the third Co site, Co(3) is bonded to one O(18), one O(2), one O(20), one O(22), one O(24), and one O(4) atom to form CoO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra, edges with three equivalent Co(1)O6 octahedra, and edges with three equivalent Co(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 9-12°. In the fourth Co site, Co(4) is bonded to one O(1), one O(17), one O(19), one O(21), one O(23), and one O(3) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra, edges with three equivalent Co(2)O6 octahedra, and edges with three equivalent Co(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 12-13°. In the fifth Co site, Co(5) is bonded to one O(18), one O(2), one O(20), one O(22), one O(24), and one O(4) atom to form CoO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra, edges with three equivalent Co(1)O6 octahedra, and edges with three equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 10-13°. In the sixth Co site, Co(6) is bonded to one O(1), one O(17), one O(19), one O(21), one O(23), and one O(3) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra, edges with three equivalent Co(2)O6 octahedra, and edges with three equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 9-10°. In the seventh Co site, Co(7) is bonded to one O(10), one O(11), one O(14), one O(15), one O(6), and one O(7) atom to form CoO6 octahedra that share corners with three equivalent Li(1)O6 octahedra, corners with three equivalent Li(4)O6 octahedra, edges with three equivalent Co(10)O6 octahedra, edges with three equivalent Sn(2)O6 octahedra,  a faceface with one Li(5)O6 octahedra, and  a faceface with one Li(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-45°. In the eighth Co site, Co(8) is bonded to one O(12), one O(13), one O(16), one O(5), one O(8), and one O(9) atom to form CoO6 octahedra that share corners with three equivalent Li(2)O6 octahedra, corners with three equivalent Li(3)O6 octahedra, edges with three equivalent Co(9)O6 octahedra, edges with three equivalent Sn(1)O6 octahedra,  a faceface with one Li(6)O6 octahedra, and  a faceface with one Li(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 43-45°. In the ninth Co site, Co(9) is bonded to one O(12), one O(13), one O(16), one O(5), one O(8), and one O(9) atom to form CoO6 octahedra that share corners with three equivalent Li(6)O6 octahedra, corners with three equivalent Li(7)O6 octahedra, edges with three equivalent Co(8)O6 octahedra, edges with three equivalent Sn(1)O6 octahedra,  a faceface with one Li(2)O6 octahedra, and  a faceface with one Li(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 43-45°. In the tenth Co site, Co(10) is bonded to one O(10), one O(11), one O(14), one O(15), one O(6), and one O(7) atom to form CoO6 octahedra that share corners with three equivalent Li(5)O6 octahedra, corners with three equivalent Li(8)O6 octahedra, edges with three equivalent Co(7)O6 octahedra, edges with three equivalent Sn(2)O6 octahedra,  a faceface with one Li(1)O6 octahedra, and  a faceface with one Li(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-45°. There are two inequivalent Sn sites. In the first Sn site, Sn(1) is bonded to one O(12), one O(13), one O(16), one O(5), one O(8), and one O(9) atom to form SnO6 octahedra that share corners with three equivalent Li(2)O6 octahedra, corners with three equivalent Li(3)O6 octahedra, corners with three equivalent Li(6)O6 octahedra, corners with three equivalent Li(7)O6 octahedra, edges with three equivalent Co(8)O6 octahedra, and edges with three equivalent Co(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-52°. In the second Sn site, Sn(2) is bonded to one O(10), one O(11), one O(14), one O(15), one O(6), and one O(7) atom to form SnO6 octahedra that share corners with three equivalent Li(1)O6 octahedra, corners with three equivalent Li(4)O6 octahedra, corners with three equivalent Li(5)O6 octahedra, corners with three equivalent Li(8)O6 octahedra, edges with three equivalent Co(10)O6 octahedra, and edges with three equivalent Co(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-50°. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), one Li(5), one Co(2), one Co(4), and one Co(6) atom to form OLi2Co3 square pyramids that share  a cornercorner with one O(17)Li2Co3 square pyramid,  a cornercorner with one O(19)Li2Co3 square pyramid,  a cornercorner with one O(21)Li2Co3 square pyramid,  a cornercorner with one O(23)Li2Co3 square pyramid,  a cornercorner with one O(3)Li2Co3 square pyramid, corners with two equivalent O(11)Li2Co2Sn trigonal bipyramids, corners with two equivalent O(15)Li2Co2Sn trigonal bipyramids,  an edgeedge with one O(17)Li2Co3 square pyramid,  an edgeedge with one O(19)Li2Co3 square pyramid,  an edgeedge with one O(3)Li2Co3 square pyramid, edges with two equivalent O(21)Li2Co3 square pyramids, edges with two equivalent O(23)Li2Co3 square pyramids, and  an edgeedge with one O(7)Li2Co2Sn trigonal bipyramid. In the second O site, O(2) is bonded to one Li(2), one Li(6), one Co(1), one Co(3), and one Co(5) atom to form OLi2Co3 square pyramids that share  a cornercorner with one O(18)Li2Co3 square pyramid,  a cornercorner with one O(20)Li2Co3 square pyramid,  a cornercorner with one O(22)Li2Co3 square pyramid,  a cornercorner with one O(24)Li2Co3 square pyramid,  a cornercorner with one O(4)Li2Co3 square pyramid, corners with two equivalent O(12)Li2Co2Sn trigonal bipyramids, corners with two equivalent O(16)Li2Co2Sn trigonal bipyramids,  an edgeedge with one O(18)Li2Co3 square pyramid,  an edgeedge with one O(20)Li2Co3 square pyramid,  an edgeedge with one O(4)Li2Co3 square pyramid, edges with two equivalent O(22)Li2Co3 square pyramids, edges with two equivalent O(24)Li2Co3 square pyramids, and  an edgeedge with one O(8)Li2Co2Sn trigonal bipyramid. In the third O site, O(3) is bonded to one Li(3), one Li(7), one Co(2), one Co(4), and one Co(6) atom to form OLi2Co3 square pyramids that share  a cornercorner with one O(1)Li2Co3 square pyramid,  a cornercorner with one O(17)Li2Co3 square pyramid,  a cornercorner with one O(19)Li2Co3 square pyramid,  a cornercorner with one O(21)Li2Co3 square pyramid,  a cornercorner with one O(23)Li2Co3 square pyramid, corners with two equivalent O(13)Li2Co2Sn trigonal bipyramids, corners with two equivalent O(9)Li2Co2Sn trigonal bipyramids,  an edgeedge with one O(1)Li2Co3 square pyramid,  an edgeedge with one O(21)Li2Co3 square pyramid,  an edgeedge with one O(23)Li2Co3 square pyramid, edges with two equivalent O(17)Li2Co3 square pyramids, edges with two equivalent O(19)Li2Co3 square pyramids, and  an edgeedge with one O(5)Li2Co2Sn trigonal bipyramid. In the fourth O site, O(4) is bonded to one Li(4), one Li(8), one Co(1), one Co(3), and one Co(5) atom to form OLi2Co3 square pyramids that share  a cornercorner with one O(18)Li2Co3 square pyramid,  a cornercorner with one O(2)Li2Co3 square pyramid,  a cornercorner with one O(20)Li2Co3 square pyramid,  a cornercorner with one O(22)Li2Co3 square pyramid,  a cornercorner with one O(24)Li2Co3 square pyramid, corners with two equivalent O(10)Li2Co2Sn trigonal bipyramids, corners with two equivalent O(14)Li2Co2Sn trigonal bipyramids,  an edgeedge with one O(2)Li2Co3 square pyramid,  an edgeedge with one O(22)Li2Co3 square pyramid,  an edgeedge with one O(24)Li2Co3 square pyramid, edges with two equivalent O(18)Li2Co3 square pyramids, edges with two equivalent O(20)Li2Co3 square pyramids, and  an edgeedge with one O(6)Li2Co2Sn trigonal bipyramid. In the fifth O site, O(5) is bonded to one Li(3), one Li(7), one Co(8), one Co(9), and one Sn(1) atom to form distorted OLi2Co2Sn trigonal bipyramids that share corners with two equivalent O(17)Li2Co3 square pyramids, corners with two equivalent O(19)Li2Co3 square pyramids,  a cornercorner with one O(12)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(13)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(16)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(8)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(9)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(3)Li2Co3 square pyramid,  an edgeedge with one O(12)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(16)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(8)Li2Co2Sn trigonal bipyramid, edges with two equivalent O(13)Li2Co2Sn trigonal bipyramids, and edges with two equivalent O(9)Li2Co2Sn trigonal bipyramids. In the sixth O site, O(6) is bonded to one Li(4), one Li(8), one Co(10), one Co(7), and one Sn(2) atom to form distorted OLi2Co2Sn trigonal bipyramids that share corners with two equivalent O(18)Li2Co3 square pyramids, corners with two equivalent O(20)Li2Co3 square pyramids,  a cornercorner with one O(10)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(11)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(14)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(15)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(7)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(4)Li2Co3 square pyramid,  an edgeedge with one O(11)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(15)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(7)Li2Co2Sn trigonal bipyramid, edges with two equivalent O(10)Li2Co2Sn trigonal bipyramids, and edges with two equivalent O(14)Li2Co2Sn trigonal bipyramids. In the seventh O site, O(7) is bonded to one Li(1), one Li(5), one Co(10), one Co(7), and one Sn(2) atom to form distorted OLi2Co2Sn trigonal bipyramids that share corners with two equivalent O(21)Li2Co3 square pyramids, corners with two equivalent O(23)Li2Co3 square pyramids,  a cornercorner with one O(10)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(11)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(14)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(15)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(6)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(1)Li2Co3 square pyramid,  an edgeedge with one O(10)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(14)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(6)Li2Co2Sn trigonal bipyramid, edges with two equivalent O(11)Li2Co2Sn trigonal bipyramids, and edges with two equivalent O(15)Li2Co2Sn trigonal bipyramids. In the eighth O site, O(8) is bonded to one Li(2), one Li(6), one Co(8), one Co(9), and one Sn(1) atom to form distorted OLi2Co2Sn trigonal bipyramids that share corners with two equivalent O(22)Li2Co3 square pyramids, corners with two equivalent O(24)Li2Co3 square pyramids,  a cornercorner with one O(12)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(13)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(16)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(5)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(9)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(2)Li2Co3 square pyramid,  an edgeedge with one O(13)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(5)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(9)Li2Co2Sn trigonal bipyramid, edges with two equivalent O(12)Li2Co2Sn trigonal bipyramids, and edges with two equivalent O(16)Li2Co2Sn trigonal bipyramids. In the ninth O site, O(9) is bonded to one Li(3), one Li(7), one Co(8), one Co(9), and one Sn(1) atom to form distorted OLi2Co2Sn trigonal bipyramids that share corners with two equivalent O(19)Li2Co3 square pyramids, corners with two equivalent O(3)Li2Co3 square pyramids,  a cornercorner with one O(12)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(13)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(16)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(5)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(8)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(17)Li2Co3 square pyramid,  an edgeedge with one O(12)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(16)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(8)Li2Co2Sn trigonal bipyramid, edges with two equivalent O(13)Li2Co2Sn trigonal bipyramids, and edges with two equivalent O(5)Li2Co2Sn trigonal bipyramids. In the tenth O site, O(10) is bonded to one Li(4), one Li(8), one Co(10), one Co(7), and one Sn(2) atom to form distorted OLi2Co2Sn trigonal bipyramids that share corners with two equivalent O(20)Li2Co3 square pyramids, corners with two equivalent O(4)Li2Co3 square pyramids,  a cornercorner with one O(11)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(14)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(15)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(6)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(7)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(18)Li2Co3 square pyramid,  an edgeedge with one O(11)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(15)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(7)Li2Co2Sn trigonal bipyramid, edges with two equivalent O(14)Li2Co2Sn trigonal bipyramids, and edges with two equivalent O(6)Li2Co2Sn trigonal bipyramids. In the eleventh O site, O(11) is bonded to one Li(1), one Li(5), one Co(10), one Co(7), and one Sn(2) atom to form distorted OLi2Co2Sn trigonal bipyramids that share corners with two equivalent O(1)Li2Co3 square pyramids, corners with two equivalent O(23)Li2Co3 square pyramids,  a cornercorner with one O(10)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(14)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(15)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(6)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(7)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(21)Li2Co3 square pyramid,  an edgeedge with one O(10)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(14)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(6)Li2Co2Sn trigonal bipyramid, edges with two equivalent O(15)Li2Co2Sn trigonal bipyramids, and edges with two equivalent O(7)Li2Co2Sn trigonal bipyramids. In the twelfth O site, O(12) is bonded to one Li(2), one Li(6), one Co(8), one Co(9), and one Sn(1) atom to form distorted OLi2Co2Sn trigonal bipyramids that share corners with two equivalent O(2)Li2Co3 square pyramids, corners with two equivalent O(24)Li2Co3 square pyramids,  a cornercorner with one O(13)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(16)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(5)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(8)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(9)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(22)Li2Co3 square pyramid,  an edgeedge with one O(13)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(5)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(9)Li2Co2Sn trigonal bipyramid, edges with two equivalent O(16)Li2Co2Sn trigonal bipyramids, and edges with two equivalent O(8)Li2Co2Sn trigonal bipyramids. In the thirteenth O site, O(13) is bonded to one Li(3), one Li(7), one Co(8), one Co(9), and one Sn(1) atom to form distorted OLi2Co2Sn trigonal bipyramids that share corners with two equivalent O(17)Li2Co3 square pyramids, corners with two equivalent O(3)Li2Co3 square pyramids,  a cornercorner with one O(12)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(16)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(5)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(8)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(9)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(19)Li2Co3 square pyramid,  an edgeedge with one O(12)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(16)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(8)Li2Co2Sn trigonal bipyramid, edges with two equivalent O(5)Li2Co2Sn trigonal bipyramids, and edges with two equivalent O(9)Li2Co2Sn trigonal bipyramids. In the fourteenth O site, O(14) is bonded to one Li(4), one Li(8), one Co(10), one Co(7), and one Sn(2) atom to form distorted OLi2Co2Sn trigonal bipyramids that share corners with two equivalent O(18)Li2Co3 square pyramids, corners with two equivalent O(4)Li2Co3 square pyramids,  a cornercorner with one O(10)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(11)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(15)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(6)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(7)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(20)Li2Co3 square pyramid,  an edgeedge with one O(11)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(15)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(7)Li2Co2Sn trigonal bipyramid, edges with two equivalent O(10)Li2Co2Sn trigonal bipyramids, and edges with two equivalent O(6)Li2Co2Sn trigonal bipyramids. In the fifteenth O site, O(15) is bonded to one Li(1), one Li(5), one Co(10), one Co(7), and one Sn(2) atom to form distorted OLi2Co2Sn trigonal bipyramids that share corners with two equivalent O(1)Li2Co3 square pyramids, corners with two equivalent O(21)Li2Co3 square pyramids,  a cornercorner with one O(10)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(11)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(14)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(6)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(7)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(23)Li2Co3 square pyramid,  an edgeedge with one O(10)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(14)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(6)Li2Co2Sn trigonal bipyramid, edges with two equivalent O(11)Li2Co2Sn trigonal bipyramids, and edges with two equivalent O(7)Li2Co2Sn trigonal bipyramids. In the sixteenth O site, O(16) is bonded to one Li(2), one Li(6), one Co(8), one Co(9), and one Sn(1) atom to form distorted OLi2Co2Sn trigonal bipyramids that share corners with two equivalent O(2)Li2Co3 square pyramids, corners with two equivalent O(22)Li2Co3 square pyramids,  a cornercorner with one O(12)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(13)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(5)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(8)Li2Co2Sn trigonal bipyramid,  a cornercorner with one O(9)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(24)Li2Co3 square pyramid,  an edgeedge with one O(13)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(5)Li2Co2Sn trigonal bipyramid,  an edgeedge with one O(9)Li2Co2Sn trigonal bipyramid, edges with two equivalent O(12)Li2Co2Sn trigonal bipyramids, and edges with two equivalent O(8)Li2Co2Sn trigonal bipyramids. In the seventeenth O site, O(17) is bonded to one Li(3), one Li(7), one Co(2), one Co(4), and one Co(6) atom to form OLi2Co3 square pyramids that share  a cornercorner with one O(1)Li2Co3 square pyramid,  a cornercorner with one O(19)Li2Co3 square pyramid,  a cornercorner with one O(21)Li2Co3 square pyramid,  a cornercorner with one O(23)Li2Co3 square pyramid,  a cornercorner with one O(3)Li2Co3 square pyramid, corners with two equivalent O(13)Li2Co2Sn trigonal bipyramids, corners with two equivalent O(5)Li2Co2Sn trigonal bipyramids,  an edgeedge with one O(1)Li2Co3 square pyramid,  an edgeedge with one O(21)Li2Co3 square pyramid,  an edgeedge with one O(23)Li2Co3 square pyramid, edges with two equivalent O(19)Li2Co3 square pyramids, edges with two equivalent O(3)Li2Co3 square pyramids, and  an edgeedge with one O(9)Li2Co2Sn trigonal bipyramid. In the eighteenth O site, O(18) is bonded to one Li(4), one Li(8), one Co(1), one Co(3), and one Co(5) atom to form OLi2Co3 square pyramids that share  a cornercorner with one O(2)Li2Co3 square pyramid,  a cornercorner with one O(20)Li2Co3 square pyramid,  a cornercorner with one O(22)Li2Co3 square pyramid,  a cornercorner with one O(24)Li2Co3 square pyramid,  a cornercorner with one O(4)Li2Co3 square pyramid, corners with two equivalent O(14)Li2Co2Sn trigonal bipyramids, corners with two equivalent O(6)Li2Co2Sn trigonal bipyramids,  an edgeedge with one O(2)Li2Co3 square pyramid,  an edgeedge with one O(22)Li2Co3 square pyramid,  an edgeedge with one O(24)Li2Co3 square pyramid, edges with two equivalent O(20)Li2Co3 square pyramids, edges with two equivalent O(4)Li2Co3 square pyramids, and  an edgeedge with one O(10)Li2Co2Sn trigonal bipyramid. In the nineteenth O site, O(19) is bonded to one Li(3), one Li(7), one Co(2), one Co(4), and one Co(6) atom to form OLi2Co3 square pyramids that share  a cornercorner with one O(1)Li2Co3 square pyramid,  a cornercorner with one O(17)Li2Co3 square pyramid,  a cornercorner with one O(21)Li2Co3 square pyramid,  a cornercorner with one O(23)Li2Co3 square pyramid,  a cornercorner with one O(3)Li2Co3 square pyramid, corners with two equivalent O(5)Li2Co2Sn trigonal bipyramids, corners with two equivalent O(9)Li2Co2Sn trigonal bipyramids,  an edgeedge with one O(1)Li2Co3 square pyramid,  an edgeedge with one O(21)Li2Co3 square pyramid,  an edgeedge with one O(23)Li2Co3 square pyramid, edges with two equivalent O(17)Li2Co3 square pyramids, edges with two equivalent O(3)Li2Co3 square pyramids, and  an edgeedge with one O(13)Li2Co2Sn trigonal bipyramid. In the twentieth O site, O(20) is bonded to one Li(4), one Li(8), one Co(1), one Co(3), and one Co(5) atom to form OLi2Co3 square pyramids that share  a cornercorner with one O(18)Li2Co3 square pyramid,  a cornercorner with one O(2)Li2Co3 square pyramid,  a cornercorner with one O(22)Li2Co3 square pyramid,  a cornercorner with one O(24)Li2Co3 square pyramid,  a cornercorner with one O(4)Li2Co3 square pyramid, corners with two equivalent O(10)Li2Co2Sn trigonal bipyramids, corners with two equivalent O(6)Li2Co2Sn trigonal bipyramids,  an edgeedge with one O(2)Li2Co3 square pyramid,  an edgeedge with one O(22)Li2Co3 square pyramid,  an edgeedge with one O(24)Li2Co3 square pyramid, edges with two equivalent O(18)Li2Co3 square pyramids, edges with two equivalent O(4)Li2Co3 square pyramids, and  an edgeedge with one O(14)Li2Co2Sn trigonal bipyramid. In the twenty-first O site, O(21) is bonded to one Li(1), one Li(5), one Co(2), one Co(4), and one Co(6) atom to form OLi2Co3 square pyramids that share  a cornercorner with one O(1)Li2Co3 square pyramid,  a cornercorner with one O(17)Li2Co3 square pyramid,  a cornercorner with one O(19)Li2Co3 square pyramid,  a cornercorner with one O(23)Li2Co3 square pyramid,  a cornercorner with one O(3)Li2Co3 square pyramid, corners with two equivalent O(15)Li2Co2Sn trigonal bipyramids, corners with two equivalent O(7)Li2Co2Sn trigonal bipyramids,  an edgeedge with one O(17)Li2Co3 square pyramid,  an edgeedge with one O(19)Li2Co3 square pyramid,  an edgeedge with one O(3)Li2Co3 square pyramid, edges with two equivalent O(1)Li2Co3 square pyramids, edges with two equivalent O(23)Li2Co3 square pyramids, and  an edgeedge with one O(11)Li2Co2Sn trigonal bipyramid. In the twenty-second O site, O(22) is bonded to one Li(2), one Li(6), one Co(1), one Co(3), and one Co(5) atom to form OLi2Co3 square pyramids that share  a cornercorner with one O(18)Li2Co3 square pyramid,  a cornercorner with one O(2)Li2Co3 square pyramid,  a cornercorner with one O(20)Li2Co3 square pyramid,  a cornercorner with one O(24)Li2Co3 square pyramid,  a cornercorner with one O(4)Li2Co3 square pyramid, corners with two equivalent O(16)Li2Co2Sn trigonal bipyramids, corners with two equivalent O(8)Li2Co2Sn trigonal bipyramids,  an edgeedge with one O(18)Li2Co3 square pyramid,  an edgeedge with one O(20)Li2Co3 square pyramid,  an edgeedge with one O(4)Li2Co3 square pyramid, edges with two equivalent O(2)Li2Co3 square pyramids, edges with two equivalent O(24)Li2Co3 square pyramids, and  an edgeedge with one O(12)Li2Co2Sn trigonal bipyramid. In the twenty-third O site, O(23) is bonded to one Li(1), one Li(5), one Co(2), one Co(4), and one Co(6) atom to form OLi2Co3 square pyramids that share  a cornercorner with one O(1)Li2Co3 square pyramid,  a cornercorner with one O(17)Li2Co3 square pyramid,  a cornercorner with one O(19)Li2Co3 square pyramid,  a cornercorner with one O(21)Li2Co3 square pyramid,  a cornercorner with one O(3)Li2Co3 square pyramid, corners with two equivalent O(11)Li2Co2Sn trigonal bipyramids, corners with two equivalent O(7)Li2Co2Sn trigonal bipyramids,  an edgeedge with one O(17)Li2Co3 square pyramid,  an edgeedge with one O(19)Li2Co3 square pyramid,  an edgeedge with one O(3)Li2Co3 square pyramid, edges with two equivalent O(1)Li2Co3 square pyramids, edges with two equivalent O(21)Li2Co3 square pyramids, and  an edgeedge with one O(15)Li2Co2Sn trigonal bipyramid. In the twenty-fourth O site, O(24) is bonded to one Li(2), one Li(6), one Co(1), one Co(3), and one Co(5) atom to form OLi2Co3 square pyramids that share  a cornercorner with one O(18)Li2Co3 square pyramid,  a cornercorner with one O(2)Li2Co3 square pyramid,  a cornercorner with one O(20)Li2Co3 square pyramid,  a cornercorner with one O(22)Li2Co3 square pyramid,  a cornercorner with one O(4)Li2Co3 square pyramid, corners with two equivalent O(12)Li2Co2Sn trigonal bipyramids, corners with two equivalent O(8)Li2Co2Sn trigonal bipyramids,  an edgeedge with one O(18)Li2Co3 square pyramid,  an edgeedge with one O(20)Li2Co3 square pyramid,  an edgeedge with one O(4)Li2Co3 square pyramid, edges with two equivalent O(2)Li2Co3 square pyramids, edges with two equivalent O(22)Li2Co3 square pyramids, and  an edgeedge with one O(16)Li2Co2Sn trigonal bipyramid. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li4Co5SnO12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.144
_cell_length_b   5.083
_cell_length_c   19.844
_cell_angle_alpha   92.598
_cell_angle_beta   84.914
_cell_angle_gamma   120.329
_symmetry_Int_Tables_number   1
_cell_volume   446.082
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.208  0.337  0.370  1.0
  Li  Li1  1  0.716  0.345  0.870  1.0
  Li  Li2  1  0.632  0.339  0.130  1.0
  Li  Li3  1  0.129  0.338  0.630  1.0
  Li  Li4  1  0.871  0.665  0.371  1.0
  Li  Li5  1  0.371  0.661  0.871  1.0
  Li  Li6  1  0.294  0.667  0.129  1.0
  Li  Li7  1  0.788  0.661  0.630  1.0
  Co  Co8  1  0.749  0.998  0.750  1.0
  Co  Co9  1  0.585  0.667  0.250  1.0
  Co  Co10  1  0.083  0.667  0.750  1.0
  Co  Co11  1  0.918  0.333  0.250  1.0
  Co  Co12  1  0.417  0.333  0.750  1.0
  Co  Co13  1  0.250  1.000  0.250  1.0
  Co  Co14  1  0.831  0.667  0.500  1.0
  Co  Co15  1  0.333  0.665  1.000  1.0
  Co  Co16  1  0.668  0.335  1.000  1.0
  Co  Co17  1  0.165  0.334  0.500  1.0
  Sn  Sn18  1  0.996  0.997  0.000  1.0
  Sn  Sn19  1  0.503  0.000  0.500  1.0
  O  O20  1  0.912  0.000  0.298  1.0
  O  O21  1  0.409  0.996  0.798  1.0
  O  O22  1  0.590  0.000  0.202  1.0
  O  O23  1  0.087  0.995  0.702  1.0
  O  O24  1  0.331  0.989  0.053  1.0
  O  O25  1  0.826  0.999  0.558  1.0
  O  O26  1  0.170  0.002  0.445  1.0
  O  O27  1  0.662  0.993  0.944  1.0
  O  O28  1  0.637  0.650  0.058  1.0
  O  O29  1  0.138  0.650  0.556  1.0
  O  O30  1  0.520  0.655  0.443  1.0
  O  O31  1  0.009  0.650  0.943  1.0
  O  O32  1  0.991  0.351  0.056  1.0
  O  O33  1  0.486  0.349  0.557  1.0
  O  O34  1  0.864  0.346  0.443  1.0
  O  O35  1  0.359  0.357  0.945  1.0
  O  O36  1  0.299  0.334  0.198  1.0
  O  O37  1  0.780  0.360  0.699  1.0
  O  O38  1  0.964  0.665  0.198  1.0
  O  O39  1  0.417  0.644  0.700  1.0
  O  O40  1  0.536  0.337  0.302  1.0
  O  O41  1  0.080  0.361  0.801  1.0
  O  O42  1  0.200  0.664  0.302  1.0
  O  O43  1  0.726  0.645  0.800  1.0
[/CIF]
.