The structure described by Pu5Rh4 crystallizes in the orthorhombic Pnma space group. There are three inequivalent Pu sites. In the first Pu site, Pu(1) is bonded in a 7-coordinate geometry to one Rh(3), two equivalent Rh(2), and four equivalent Rh(1) atoms. In the second Pu site, Pu(2) is bonded in a 7-coordinate geometry to one Pu(3), one Rh(2), two equivalent Rh(3), and three equivalent Rh(1) atoms. In the third Pu site, Pu(3) is bonded in a 8-coordinate geometry to two equivalent Pu(2), two equivalent Rh(1), two equivalent Rh(2), and two equivalent Rh(3) atoms. There are three inequivalent Rh sites. In the first Rh site, Rh(3) is bonded in a 10-coordinate geometry to two equivalent Pu(1), two equivalent Pu(3), four equivalent Pu(2), and two equivalent Rh(2) atoms. In the second Rh site, Rh(1) is bonded in a 8-coordinate geometry to one Pu(3), three equivalent Pu(2), and four equivalent Pu(1) atoms. In the third Rh site, Rh(2) is bonded in a 10-coordinate geometry to two equivalent Pu(2), two equivalent Pu(3), four equivalent Pu(1), and two equivalent Rh(3) atoms. is represented by the CIF file [CIF]
data_Pu5Rh4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.902
_cell_length_b   7.334
_cell_length_c   14.592
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   738.615
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pu  Pu0  1  0.994  0.820  0.912  1.0
  Pu  Pu1  1  0.494  0.680  0.588  1.0
  Pu  Pu2  1  0.506  0.320  0.088  1.0
  Pu  Pu3  1  0.006  0.180  0.412  1.0
  Pu  Pu4  1  0.994  0.820  0.588  1.0
  Pu  Pu5  1  0.494  0.680  0.912  1.0
  Pu  Pu6  1  0.506  0.320  0.412  1.0
  Pu  Pu7  1  0.006  0.180  0.088  1.0
  Pu  Pu8  1  0.874  0.653  0.365  1.0
  Pu  Pu9  1  0.374  0.847  0.135  1.0
  Pu  Pu10  1  0.626  0.153  0.635  1.0
  Pu  Pu11  1  0.126  0.347  0.865  1.0
  Pu  Pu12  1  0.126  0.347  0.635  1.0
  Pu  Pu13  1  0.626  0.153  0.865  1.0
  Pu  Pu14  1  0.374  0.847  0.365  1.0
  Pu  Pu15  1  0.874  0.653  0.135  1.0
  Pu  Pu16  1  0.375  0.034  0.750  1.0
  Pu  Pu17  1  0.875  0.466  0.750  1.0
  Pu  Pu18  1  0.125  0.534  0.250  1.0
  Pu  Pu19  1  0.625  0.966  0.250  1.0
  Rh  Rh20  1  0.798  0.456  0.533  1.0
  Rh  Rh21  1  0.298  0.044  0.967  1.0
  Rh  Rh22  1  0.702  0.956  0.467  1.0
  Rh  Rh23  1  0.202  0.544  0.033  1.0
  Rh  Rh24  1  0.202  0.544  0.467  1.0
  Rh  Rh25  1  0.702  0.956  0.033  1.0
  Rh  Rh26  1  0.298  0.044  0.533  1.0
  Rh  Rh27  1  0.798  0.456  0.967  1.0
  Rh  Rh28  1  0.199  0.712  0.750  1.0
  Rh  Rh29  1  0.699  0.788  0.750  1.0
  Rh  Rh30  1  0.301  0.212  0.250  1.0
  Rh  Rh31  1  0.801  0.288  0.250  1.0
  Rh  Rh32  1  0.980  0.052  0.750  1.0
  Rh  Rh33  1  0.480  0.448  0.750  1.0
  Rh  Rh34  1  0.520  0.552  0.250  1.0
  Rh  Rh35  1  0.020  0.948  0.250  1.0
[/CIF]
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The structure described by Pu5Rh4 crystallizes in the orthorhombic Pnma space group. There are three inequivalent Pu sites. In the first Pu site, Pu(1) is bonded in a 7-coordinate geometry to one Rh(3), two equivalent Rh(2), and four equivalent Rh(1) atoms. In the second Pu site, Pu(2) is bonded in a 7-coordinate geometry to one Pu(3), one Rh(2), two equivalent Rh(3), and three equivalent Rh(1) atoms. In the third Pu site, Pu(3) is bonded in a 8-coordinate geometry to two equivalent Pu(2), two equivalent Rh(1), two equivalent Rh(2), and two equivalent Rh(3) atoms. There are three inequivalent Rh sites. In the first Rh site, Rh(3) is bonded in a 10-coordinate geometry to two equivalent Pu(1), two equivalent Pu(3), four equivalent Pu(2), and two equivalent Rh(2) atoms. In the second Rh site, Rh(1) is bonded in a 8-coordinate geometry to one Pu(3), three equivalent Pu(2), and four equivalent Pu(1) atoms. In the third Rh site, Rh(2) is bonded in a 10-coordinate geometry to two equivalent Pu(2), two equivalent Pu(3), four equivalent Pu(1), and two equivalent Rh(3) atoms. is represented by the CIF file [CIF]
data_Pu5Rh4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.902
_cell_length_b   7.334
_cell_length_c   14.592
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   738.615
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pu  Pu0  1  0.994  0.820  0.912  1.0
  Pu  Pu1  1  0.494  0.680  0.588  1.0
  Pu  Pu2  1  0.506  0.320  0.088  1.0
  Pu  Pu3  1  0.006  0.180  0.412  1.0
  Pu  Pu4  1  0.994  0.820  0.588  1.0
  Pu  Pu5  1  0.494  0.680  0.912  1.0
  Pu  Pu6  1  0.506  0.320  0.412  1.0
  Pu  Pu7  1  0.006  0.180  0.088  1.0
  Pu  Pu8  1  0.874  0.653  0.365  1.0
  Pu  Pu9  1  0.374  0.847  0.135  1.0
  Pu  Pu10  1  0.626  0.153  0.635  1.0
  Pu  Pu11  1  0.126  0.347  0.865  1.0
  Pu  Pu12  1  0.126  0.347  0.635  1.0
  Pu  Pu13  1  0.626  0.153  0.865  1.0
  Pu  Pu14  1  0.374  0.847  0.365  1.0
  Pu  Pu15  1  0.874  0.653  0.135  1.0
  Pu  Pu16  1  0.375  0.034  0.750  1.0
  Pu  Pu17  1  0.875  0.466  0.750  1.0
  Pu  Pu18  1  0.125  0.534  0.250  1.0
  Pu  Pu19  1  0.625  0.966  0.250  1.0
  Rh  Rh20  1  0.798  0.456  0.533  1.0
  Rh  Rh21  1  0.298  0.044  0.967  1.0
  Rh  Rh22  1  0.702  0.956  0.467  1.0
  Rh  Rh23  1  0.202  0.544  0.033  1.0
  Rh  Rh24  1  0.202  0.544  0.467  1.0
  Rh  Rh25  1  0.702  0.956  0.033  1.0
  Rh  Rh26  1  0.298  0.044  0.533  1.0
  Rh  Rh27  1  0.798  0.456  0.967  1.0
  Rh  Rh28  1  0.199  0.712  0.750  1.0
  Rh  Rh29  1  0.699  0.788  0.750  1.0
  Rh  Rh30  1  0.301  0.212  0.250  1.0
  Rh  Rh31  1  0.801  0.288  0.250  1.0
  Rh  Rh32  1  0.980  0.052  0.750  1.0
  Rh  Rh33  1  0.480  0.448  0.750  1.0
  Rh  Rh34  1  0.520  0.552  0.250  1.0
  Rh  Rh35  1  0.020  0.948  0.250  1.0
[/CIF]
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