The material described by KLiZnO2 crystallizes in the monoclinic C2/m space group. K(1) is bonded in a 7-coordinate geometry to two equivalent O(2) and five equivalent O(1) atoms. Li(1) is bonded to one O(1) and three equivalent O(2) atoms to form distorted LiO4 tetrahedra that share corners with two equivalent Li(1)O4 tetrahedra, corners with four equivalent Zn(1)O4 tetrahedra, edges with two equivalent Li(1)O4 tetrahedra, and edges with two equivalent Zn(1)O4 tetrahedra. Zn(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form distorted ZnO4 tetrahedra that share corners with two equivalent Zn(1)O4 tetrahedra, corners with four equivalent Li(1)O4 tetrahedra,  an edgeedge with one Zn(1)O4 tetrahedra, and edges with two equivalent Li(1)O4 tetrahedra. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to five equivalent K(1), one Li(1), and two equivalent Zn(1) atoms. In the second O site, O(2) is bonded in a 7-coordinate geometry to two equivalent K(1), three equivalent Li(1), and two equivalent Zn(1) atoms. is represented by the CIF file [CIF]
data_KLiZnO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.738
_cell_length_b   5.738
_cell_length_c   8.335
_cell_angle_alpha   61.395
_cell_angle_beta   61.395
_cell_angle_gamma   34.332
_symmetry_Int_Tables_number   1
_cell_volume   133.941
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.837  0.837  0.630  1.0
  K  K1  1  0.163  0.163  0.370  1.0
  Li  Li2  1  0.341  0.341  0.945  1.0
  Li  Li3  1  0.659  0.659  0.055  1.0
  Zn  Zn4  1  0.044  0.044  0.818  1.0
  Zn  Zn5  1  0.956  0.956  0.182  1.0
  O  O6  1  0.461  0.461  0.307  1.0
  O  O7  1  0.539  0.539  0.693  1.0
  O  O8  1  0.838  0.838  0.062  1.0
  O  O9  1  0.162  0.162  0.938  1.0
[/CIF]
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The material described by KLiZnO2 crystallizes in the monoclinic C2/m space group. K(1) is bonded in a 7-coordinate geometry to two equivalent O(2) and five equivalent O(1) atoms. Li(1) is bonded to one O(1) and three equivalent O(2) atoms to form distorted LiO4 tetrahedra that share corners with two equivalent Li(1)O4 tetrahedra, corners with four equivalent Zn(1)O4 tetrahedra, edges with two equivalent Li(1)O4 tetrahedra, and edges with two equivalent Zn(1)O4 tetrahedra. Zn(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form distorted ZnO4 tetrahedra that share corners with two equivalent Zn(1)O4 tetrahedra, corners with four equivalent Li(1)O4 tetrahedra,  an edgeedge with one Zn(1)O4 tetrahedra, and edges with two equivalent Li(1)O4 tetrahedra. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to five equivalent K(1), one Li(1), and two equivalent Zn(1) atoms. In the second O site, O(2) is bonded in a 7-coordinate geometry to two equivalent K(1), three equivalent Li(1), and two equivalent Zn(1) atoms. is represented by the CIF file [CIF]
data_KLiZnO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.738
_cell_length_b   5.738
_cell_length_c   8.335
_cell_angle_alpha   61.395
_cell_angle_beta   61.395
_cell_angle_gamma   34.332
_symmetry_Int_Tables_number   1
_cell_volume   133.941
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.837  0.837  0.630  1.0
  K  K1  1  0.163  0.163  0.370  1.0
  Li  Li2  1  0.341  0.341  0.945  1.0
  Li  Li3  1  0.659  0.659  0.055  1.0
  Zn  Zn4  1  0.044  0.044  0.818  1.0
  Zn  Zn5  1  0.956  0.956  0.182  1.0
  O  O6  1  0.461  0.461  0.307  1.0
  O  O7  1  0.539  0.539  0.693  1.0
  O  O8  1  0.838  0.838  0.062  1.0
  O  O9  1  0.162  0.162  0.938  1.0
[/CIF]
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