The compound described by KC(NO2)2 crystallizes in the monoclinic C2/c space group. K(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms. C(1) is bonded in a distorted trigonal planar geometry to one C(1), one N(1), and one N(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(1), one O(1), and one O(4) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(1), one O(2), and one O(3) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent K(1) and one N(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent K(1) and one N(2) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to two equivalent K(1) and one N(2) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to two equivalent K(1) and one N(1) atom. is represented by the CIF file [CIF]
data_KC(NO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.673
_cell_length_b   7.673
_cell_length_c   9.150
_cell_angle_alpha   75.975
_cell_angle_beta   75.975
_cell_angle_gamma   61.056
_symmetry_Int_Tables_number   1
_cell_volume   452.447
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.976  0.667  0.295  1.0
  K  K1  1  0.333  0.024  0.205  1.0
  K  K2  1  0.024  0.333  0.705  1.0
  K  K3  1  0.667  0.976  0.795  1.0
  C  C4  1  0.318  0.724  0.668  1.0
  C  C5  1  0.276  0.682  0.832  1.0
  C  C6  1  0.682  0.276  0.332  1.0
  C  C7  1  0.724  0.318  0.168  1.0
  N  N8  1  0.259  0.815  0.921  1.0
  N  N9  1  0.501  0.268  0.401  1.0
  N  N10  1  0.185  0.741  0.579  1.0
  N  N11  1  0.741  0.185  0.079  1.0
  N  N12  1  0.815  0.259  0.421  1.0
  N  N13  1  0.732  0.499  0.099  1.0
  N  N14  1  0.499  0.732  0.599  1.0
  N  N15  1  0.268  0.501  0.901  1.0
  O  O16  1  0.785  0.232  0.565  1.0
  O  O17  1  0.629  0.671  0.686  1.0
  O  O18  1  0.531  0.800  0.461  1.0
  O  O19  1  0.469  0.200  0.539  1.0
  O  O20  1  0.671  0.629  0.186  1.0
  O  O21  1  0.030  0.719  0.651  1.0
  O  O22  1  0.970  0.281  0.349  1.0
  O  O23  1  0.719  0.030  0.151  1.0
  O  O24  1  0.232  0.785  0.065  1.0
  O  O25  1  0.800  0.531  0.961  1.0
  O  O26  1  0.768  0.215  0.935  1.0
  O  O27  1  0.329  0.371  0.814  1.0
  O  O28  1  0.371  0.329  0.314  1.0
  O  O29  1  0.215  0.768  0.435  1.0
  O  O30  1  0.281  0.970  0.849  1.0
  O  O31  1  0.200  0.469  0.039  1.0
[/CIF]
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The compound described by KC(NO2)2 crystallizes in the monoclinic C2/c space group. K(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms. C(1) is bonded in a distorted trigonal planar geometry to one C(1), one N(1), and one N(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(1), one O(1), and one O(4) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(1), one O(2), and one O(3) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent K(1) and one N(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent K(1) and one N(2) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to two equivalent K(1) and one N(2) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to two equivalent K(1) and one N(1) atom. is represented by the CIF file [CIF]
data_KC(NO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.673
_cell_length_b   7.673
_cell_length_c   9.150
_cell_angle_alpha   75.975
_cell_angle_beta   75.975
_cell_angle_gamma   61.056
_symmetry_Int_Tables_number   1
_cell_volume   452.447
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.976  0.667  0.295  1.0
  K  K1  1  0.333  0.024  0.205  1.0
  K  K2  1  0.024  0.333  0.705  1.0
  K  K3  1  0.667  0.976  0.795  1.0
  C  C4  1  0.318  0.724  0.668  1.0
  C  C5  1  0.276  0.682  0.832  1.0
  C  C6  1  0.682  0.276  0.332  1.0
  C  C7  1  0.724  0.318  0.168  1.0
  N  N8  1  0.259  0.815  0.921  1.0
  N  N9  1  0.501  0.268  0.401  1.0
  N  N10  1  0.185  0.741  0.579  1.0
  N  N11  1  0.741  0.185  0.079  1.0
  N  N12  1  0.815  0.259  0.421  1.0
  N  N13  1  0.732  0.499  0.099  1.0
  N  N14  1  0.499  0.732  0.599  1.0
  N  N15  1  0.268  0.501  0.901  1.0
  O  O16  1  0.785  0.232  0.565  1.0
  O  O17  1  0.629  0.671  0.686  1.0
  O  O18  1  0.531  0.800  0.461  1.0
  O  O19  1  0.469  0.200  0.539  1.0
  O  O20  1  0.671  0.629  0.186  1.0
  O  O21  1  0.030  0.719  0.651  1.0
  O  O22  1  0.970  0.281  0.349  1.0
  O  O23  1  0.719  0.030  0.151  1.0
  O  O24  1  0.232  0.785  0.065  1.0
  O  O25  1  0.800  0.531  0.961  1.0
  O  O26  1  0.768  0.215  0.935  1.0
  O  O27  1  0.329  0.371  0.814  1.0
  O  O28  1  0.371  0.329  0.314  1.0
  O  O29  1  0.215  0.768  0.435  1.0
  O  O30  1  0.281  0.970  0.849  1.0
  O  O31  1  0.200  0.469  0.039  1.0
[/CIF]
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