The structure described by NaSr3CeP3O13 crystallizes in the trigonal P-3 space group. Na(1) is bonded in a 6-coordinate geometry to three equivalent O(1) and three equivalent O(2) atoms. Sr(1) is bonded in a 8-coordinate geometry to one O(1), one O(2), one O(5), two equivalent O(4), and three equivalent O(3) atoms. Ce(1) is bonded in a 9-coordinate geometry to three equivalent O(1), three equivalent O(2), and three equivalent O(4) atoms. P(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are five inequivalent O sites. In the first O site, O(4) is bonded in a 4-coordinate geometry to two equivalent Sr(1), one Ce(1), and one P(1) atom. In the second O site, O(5) is bonded in a trigonal planar geometry to three equivalent Sr(1) atoms. In the third O site, O(1) is bonded in a 1-coordinate geometry to one Na(1), one Sr(1), one Ce(1), and one P(1) atom. In the fourth O site, O(2) is bonded to one Na(1), one Sr(1), one Ce(1), and one P(1) atom to form distorted edge-sharing ONaSrCeP tetrahedra. In the fifth O site, O(3) is bonded in a distorted single-bond geometry to three equivalent Sr(1) and one P(1) atom. is represented by the CIF card [CIF]
data_NaSr3CeP3O13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.774
_cell_length_b   9.774
_cell_length_c   7.183
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   594.284
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.667  0.333  0.021  1.0
  Na  Na1  1  0.333  0.667  0.979  1.0
  Sr  Sr2  1  0.769  0.016  0.246  1.0
  Sr  Sr3  1  0.984  0.753  0.246  1.0
  Sr  Sr4  1  0.247  0.231  0.246  1.0
  Sr  Sr5  1  0.231  0.984  0.754  1.0
  Sr  Sr6  1  0.016  0.247  0.754  1.0
  Sr  Sr7  1  0.753  0.769  0.754  1.0
  Ce  Ce8  1  0.667  0.333  0.521  1.0
  Ce  Ce9  1  0.333  0.667  0.479  1.0
  P  P10  1  0.624  0.032  0.742  1.0
  P  P11  1  0.968  0.592  0.742  1.0
  P  P12  1  0.408  0.376  0.742  1.0
  P  P13  1  0.376  0.968  0.258  1.0
  P  P14  1  0.032  0.408  0.258  1.0
  P  P15  1  0.592  0.624  0.258  1.0
  O  O16  1  0.502  0.853  0.715  1.0
  O  O17  1  0.147  0.648  0.715  1.0
  O  O18  1  0.352  0.498  0.715  1.0
  O  O19  1  0.498  0.147  0.285  1.0
  O  O20  1  0.853  0.352  0.285  1.0
  O  O21  1  0.648  0.502  0.285  1.0
  O  O22  1  0.540  0.130  0.774  1.0
  O  O23  1  0.870  0.410  0.774  1.0
  O  O24  1  0.590  0.460  0.774  1.0
  O  O25  1  0.460  0.870  0.226  1.0
  O  O26  1  0.130  0.590  0.226  1.0
  O  O27  1  0.410  0.540  0.226  1.0
  O  O28  1  0.737  0.049  0.902  1.0
  O  O29  1  0.951  0.688  0.902  1.0
  O  O30  1  0.312  0.263  0.902  1.0
  O  O31  1  0.263  0.951  0.098  1.0
  O  O32  1  0.049  0.312  0.098  1.0
  O  O33  1  0.688  0.737  0.098  1.0
  O  O34  1  0.725  0.107  0.562  1.0
  O  O35  1  0.893  0.618  0.562  1.0
  O  O36  1  0.382  0.275  0.562  1.0
  O  O37  1  0.275  0.893  0.438  1.0
  O  O38  1  0.107  0.382  0.438  1.0
  O  O39  1  0.618  0.725  0.438  1.0
  O  O40  1  0.000  0.000  0.310  1.0
  O  O41  1  0.000  0.000  0.690  1.0
[/CIF]
.
The structure described by NaSr3CeP3O13 crystallizes in the trigonal P-3 space group. Na(1) is bonded in a 6-coordinate geometry to three equivalent O(1) and three equivalent O(2) atoms. Sr(1) is bonded in a 8-coordinate geometry to one O(1), one O(2), one O(5), two equivalent O(4), and three equivalent O(3) atoms. Ce(1) is bonded in a 9-coordinate geometry to three equivalent O(1), three equivalent O(2), and three equivalent O(4) atoms. P(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are five inequivalent O sites. In the first O site, O(4) is bonded in a 4-coordinate geometry to two equivalent Sr(1), one Ce(1), and one P(1) atom. In the second O site, O(5) is bonded in a trigonal planar geometry to three equivalent Sr(1) atoms. In the third O site, O(1) is bonded in a 1-coordinate geometry to one Na(1), one Sr(1), one Ce(1), and one P(1) atom. In the fourth O site, O(2) is bonded to one Na(1), one Sr(1), one Ce(1), and one P(1) atom to form distorted edge-sharing ONaSrCeP tetrahedra. In the fifth O site, O(3) is bonded in a distorted single-bond geometry to three equivalent Sr(1) and one P(1) atom. is represented by the CIF card [CIF]
data_NaSr3CeP3O13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.774
_cell_length_b   9.774
_cell_length_c   7.183
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   594.284
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.667  0.333  0.021  1.0
  Na  Na1  1  0.333  0.667  0.979  1.0
  Sr  Sr2  1  0.769  0.016  0.246  1.0
  Sr  Sr3  1  0.984  0.753  0.246  1.0
  Sr  Sr4  1  0.247  0.231  0.246  1.0
  Sr  Sr5  1  0.231  0.984  0.754  1.0
  Sr  Sr6  1  0.016  0.247  0.754  1.0
  Sr  Sr7  1  0.753  0.769  0.754  1.0
  Ce  Ce8  1  0.667  0.333  0.521  1.0
  Ce  Ce9  1  0.333  0.667  0.479  1.0
  P  P10  1  0.624  0.032  0.742  1.0
  P  P11  1  0.968  0.592  0.742  1.0
  P  P12  1  0.408  0.376  0.742  1.0
  P  P13  1  0.376  0.968  0.258  1.0
  P  P14  1  0.032  0.408  0.258  1.0
  P  P15  1  0.592  0.624  0.258  1.0
  O  O16  1  0.502  0.853  0.715  1.0
  O  O17  1  0.147  0.648  0.715  1.0
  O  O18  1  0.352  0.498  0.715  1.0
  O  O19  1  0.498  0.147  0.285  1.0
  O  O20  1  0.853  0.352  0.285  1.0
  O  O21  1  0.648  0.502  0.285  1.0
  O  O22  1  0.540  0.130  0.774  1.0
  O  O23  1  0.870  0.410  0.774  1.0
  O  O24  1  0.590  0.460  0.774  1.0
  O  O25  1  0.460  0.870  0.226  1.0
  O  O26  1  0.130  0.590  0.226  1.0
  O  O27  1  0.410  0.540  0.226  1.0
  O  O28  1  0.737  0.049  0.902  1.0
  O  O29  1  0.951  0.688  0.902  1.0
  O  O30  1  0.312  0.263  0.902  1.0
  O  O31  1  0.263  0.951  0.098  1.0
  O  O32  1  0.049  0.312  0.098  1.0
  O  O33  1  0.688  0.737  0.098  1.0
  O  O34  1  0.725  0.107  0.562  1.0
  O  O35  1  0.893  0.618  0.562  1.0
  O  O36  1  0.382  0.275  0.562  1.0
  O  O37  1  0.275  0.893  0.438  1.0
  O  O38  1  0.107  0.382  0.438  1.0
  O  O39  1  0.618  0.725  0.438  1.0
  O  O40  1  0.000  0.000  0.310  1.0
  O  O41  1  0.000  0.000  0.690  1.0
[/CIF]
.