The material described by KP2(HO2)3 crystallizes in the monoclinic P2_1/c space group. K(1) is bonded in a distorted octahedral geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. There are two inequivalent P sites. In the first P site, P(1) is bonded in a trigonal non-coplanar geometry to one O(1), one O(2), and one O(3) atom. In the second P site, P(2) is bonded in a trigonal non-coplanar geometry to one O(4), one O(5), and one O(6) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(2) and one O(5) atom. In the second H site, H(2) is bonded in a linear geometry to one O(3) and one O(4) atom. In the third H site, H(3) is bonded in a linear geometry to one O(1) and one O(6) atom. There are six inequivalent O sites. In the first O site, O(3) is bonded in a distorted bent 120 degrees geometry to one K(1), one P(1), and one H(2) atom. In the second O site, O(4) is bonded in a distorted bent 120 degrees geometry to one K(1), one P(2), and one H(2) atom. In the third O site, O(5) is bonded in a distorted bent 120 degrees geometry to one K(1), one P(2), and one H(1) atom. In the fourth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one K(1), one P(2), and one H(3) atom. In the fifth O site, O(1) is bonded in a distorted bent 120 degrees geometry to one K(1), one P(1), and one H(3) atom. In the sixth O site, O(2) is bonded in a distorted bent 120 degrees geometry to one K(1), one P(1), and one H(1) atom. is represented by the CIF file [CIF]
data_KP2(HO2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.274
_cell_length_b   7.889
_cell_length_c   11.154
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   92.410
_symmetry_Int_Tables_number   1
_cell_volume   639.467
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.570  0.004  0.749  1.0
  K  K1  1  0.070  0.504  0.751  1.0
  K  K2  1  0.430  0.996  0.251  1.0
  K  K3  1  0.930  0.496  0.249  1.0
  P  P4  1  0.067  0.044  0.583  1.0
  P  P5  1  0.567  0.544  0.917  1.0
  P  P6  1  0.933  0.956  0.417  1.0
  P  P7  1  0.433  0.456  0.083  1.0
  P  P8  1  0.124  0.936  0.969  1.0
  P  P9  1  0.624  0.436  0.531  1.0
  P  P10  1  0.876  0.064  0.031  1.0
  P  P11  1  0.376  0.564  0.469  1.0
  H  H12  1  0.009  0.901  0.767  1.0
  H  H13  1  0.509  0.401  0.733  1.0
  H  H14  1  0.991  0.099  0.233  1.0
  H  H15  1  0.491  0.599  0.267  1.0
  H  H16  1  0.273  0.836  0.576  1.0
  H  H17  1  0.773  0.336  0.924  1.0
  H  H18  1  0.727  0.164  0.424  1.0
  H  H19  1  0.227  0.664  0.076  1.0
  H  H20  1  0.321  0.160  0.989  1.0
  H  H21  1  0.821  0.660  0.511  1.0
  H  H22  1  0.679  0.840  0.011  1.0
  H  H23  1  0.179  0.340  0.489  1.0
  O  O24  1  0.082  0.235  0.589  1.0
  O  O25  1  0.582  0.735  0.911  1.0
  O  O26  1  0.918  0.765  0.411  1.0
  O  O27  1  0.418  0.265  0.089  1.0
  O  O28  1  0.945  0.956  0.682  1.0
  O  O29  1  0.445  0.456  0.818  1.0
  O  O30  1  0.055  0.044  0.318  1.0
  O  O31  1  0.555  0.544  0.182  1.0
  O  O32  1  0.266  0.970  0.583  1.0
  O  O33  1  0.766  0.470  0.917  1.0
  O  O34  1  0.734  0.030  0.417  1.0
  O  O35  1  0.234  0.530  0.083  1.0
  O  O36  1  0.200  0.841  0.075  1.0
  O  O37  1  0.700  0.341  0.425  1.0
  O  O38  1  0.800  0.159  0.925  1.0
  O  O39  1  0.300  0.659  0.575  1.0
  O  O40  1  0.072  0.827  0.859  1.0
  O  O41  1  0.572  0.327  0.641  1.0
  O  O42  1  0.928  0.173  0.141  1.0
  O  O43  1  0.428  0.673  0.359  1.0
  O  O44  1  0.261  0.084  0.923  1.0
  O  O45  1  0.761  0.584  0.577  1.0
  O  O46  1  0.739  0.916  0.077  1.0
  O  O47  1  0.239  0.416  0.423  1.0
[/CIF]
.
The material described by KP2(HO2)3 crystallizes in the monoclinic P2_1/c space group. K(1) is bonded in a distorted octahedral geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. There are two inequivalent P sites. In the first P site, P(1) is bonded in a trigonal non-coplanar geometry to one O(1), one O(2), and one O(3) atom. In the second P site, P(2) is bonded in a trigonal non-coplanar geometry to one O(4), one O(5), and one O(6) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(2) and one O(5) atom. In the second H site, H(2) is bonded in a linear geometry to one O(3) and one O(4) atom. In the third H site, H(3) is bonded in a linear geometry to one O(1) and one O(6) atom. There are six inequivalent O sites. In the first O site, O(3) is bonded in a distorted bent 120 degrees geometry to one K(1), one P(1), and one H(2) atom. In the second O site, O(4) is bonded in a distorted bent 120 degrees geometry to one K(1), one P(2), and one H(2) atom. In the third O site, O(5) is bonded in a distorted bent 120 degrees geometry to one K(1), one P(2), and one H(1) atom. In the fourth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one K(1), one P(2), and one H(3) atom. In the fifth O site, O(1) is bonded in a distorted bent 120 degrees geometry to one K(1), one P(1), and one H(3) atom. In the sixth O site, O(2) is bonded in a distorted bent 120 degrees geometry to one K(1), one P(1), and one H(1) atom. is represented by the CIF file [CIF]
data_KP2(HO2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.274
_cell_length_b   7.889
_cell_length_c   11.154
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   92.410
_symmetry_Int_Tables_number   1
_cell_volume   639.467
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.570  0.004  0.749  1.0
  K  K1  1  0.070  0.504  0.751  1.0
  K  K2  1  0.430  0.996  0.251  1.0
  K  K3  1  0.930  0.496  0.249  1.0
  P  P4  1  0.067  0.044  0.583  1.0
  P  P5  1  0.567  0.544  0.917  1.0
  P  P6  1  0.933  0.956  0.417  1.0
  P  P7  1  0.433  0.456  0.083  1.0
  P  P8  1  0.124  0.936  0.969  1.0
  P  P9  1  0.624  0.436  0.531  1.0
  P  P10  1  0.876  0.064  0.031  1.0
  P  P11  1  0.376  0.564  0.469  1.0
  H  H12  1  0.009  0.901  0.767  1.0
  H  H13  1  0.509  0.401  0.733  1.0
  H  H14  1  0.991  0.099  0.233  1.0
  H  H15  1  0.491  0.599  0.267  1.0
  H  H16  1  0.273  0.836  0.576  1.0
  H  H17  1  0.773  0.336  0.924  1.0
  H  H18  1  0.727  0.164  0.424  1.0
  H  H19  1  0.227  0.664  0.076  1.0
  H  H20  1  0.321  0.160  0.989  1.0
  H  H21  1  0.821  0.660  0.511  1.0
  H  H22  1  0.679  0.840  0.011  1.0
  H  H23  1  0.179  0.340  0.489  1.0
  O  O24  1  0.082  0.235  0.589  1.0
  O  O25  1  0.582  0.735  0.911  1.0
  O  O26  1  0.918  0.765  0.411  1.0
  O  O27  1  0.418  0.265  0.089  1.0
  O  O28  1  0.945  0.956  0.682  1.0
  O  O29  1  0.445  0.456  0.818  1.0
  O  O30  1  0.055  0.044  0.318  1.0
  O  O31  1  0.555  0.544  0.182  1.0
  O  O32  1  0.266  0.970  0.583  1.0
  O  O33  1  0.766  0.470  0.917  1.0
  O  O34  1  0.734  0.030  0.417  1.0
  O  O35  1  0.234  0.530  0.083  1.0
  O  O36  1  0.200  0.841  0.075  1.0
  O  O37  1  0.700  0.341  0.425  1.0
  O  O38  1  0.800  0.159  0.925  1.0
  O  O39  1  0.300  0.659  0.575  1.0
  O  O40  1  0.072  0.827  0.859  1.0
  O  O41  1  0.572  0.327  0.641  1.0
  O  O42  1  0.928  0.173  0.141  1.0
  O  O43  1  0.428  0.673  0.359  1.0
  O  O44  1  0.261  0.084  0.923  1.0
  O  O45  1  0.761  0.584  0.577  1.0
  O  O46  1  0.739  0.916  0.077  1.0
  O  O47  1  0.239  0.416  0.423  1.0
[/CIF]
.