The structure described by K2V2Mn3CO11 crystallizes in the hexagonal P6_3/m space group. K(1) is bonded in a 9-coordinate geometry to three equivalent O(1), three equivalent O(2), and three equivalent O(3) atoms. V(1) is bonded to one O(1) and three equivalent O(3) atoms to form VO4 tetrahedra that share corners with six equivalent Mn(1)O6 octahedra and  a cornercorner with one Mn(2)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 51-55°. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to six equivalent O(3) atoms to form MnO6 octahedra that share corners with six equivalent V(1)O4 tetrahedra and edges with three equivalent Mn(1)O6 octahedra. In the second Mn site, Mn(2) is bonded to two equivalent O(1) and three equivalent O(2) atoms to form MnO5 trigonal bipyramids that share corners with two equivalent V(1)O4 tetrahedra. C(1) is bonded in a trigonal planar geometry to three equivalent O(2) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to three equivalent K(1), one V(1), and one Mn(2) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to two equivalent K(1), one Mn(2), and one C(1) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one K(1), one V(1), and two equivalent Mn(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_K2Mn3V2CO11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.283
_cell_length_b   5.283
_cell_length_c   22.732
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   549.387
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.667  0.333  0.658  1.0
  K  K1  1  0.333  0.667  0.158  1.0
  K  K2  1  0.333  0.667  0.342  1.0
  K  K3  1  0.667  0.333  0.842  1.0
  Mn  Mn4  1  0.333  0.667  0.505  1.0
  Mn  Mn5  1  0.667  0.333  0.005  1.0
  Mn  Mn6  1  0.667  0.333  0.495  1.0
  Mn  Mn7  1  0.333  0.667  0.995  1.0
  Mn  Mn8  1  0.000  0.000  0.750  1.0
  Mn  Mn9  1  0.000  0.000  0.250  1.0
  V  V10  1  0.000  0.000  0.580  1.0
  V  V11  1  0.000  0.000  0.080  1.0
  V  V12  1  0.000  0.000  0.420  1.0
  V  V13  1  0.000  0.000  0.920  1.0
  C  C14  1  0.333  0.667  0.750  1.0
  C  C15  1  0.667  0.333  0.250  1.0
  O  O16  1  0.000  0.000  0.656  1.0
  O  O17  1  0.000  0.000  0.156  1.0
  O  O18  1  0.000  0.000  0.344  1.0
  O  O19  1  0.000  0.000  0.844  1.0
  O  O20  1  0.375  0.931  0.750  1.0
  O  O21  1  0.069  0.444  0.750  1.0
  O  O22  1  0.556  0.625  0.750  1.0
  O  O23  1  0.625  0.069  0.250  1.0
  O  O24  1  0.931  0.556  0.250  1.0
  O  O25  1  0.444  0.375  0.250  1.0
  O  O26  1  0.322  0.011  0.555  1.0
  O  O27  1  0.989  0.311  0.555  1.0
  O  O28  1  0.689  0.678  0.555  1.0
  O  O29  1  0.678  0.989  0.055  1.0
  O  O30  1  0.011  0.689  0.055  1.0
  O  O31  1  0.311  0.322  0.055  1.0
  O  O32  1  0.678  0.989  0.445  1.0
  O  O33  1  0.011  0.689  0.445  1.0
  O  O34  1  0.311  0.322  0.445  1.0
  O  O35  1  0.322  0.011  0.945  1.0
  O  O36  1  0.989  0.311  0.945  1.0
  O  O37  1  0.689  0.678  0.945  1.0
[/CIF]
.
The structure described by K2V2Mn3CO11 crystallizes in the hexagonal P6_3/m space group. K(1) is bonded in a 9-coordinate geometry to three equivalent O(1), three equivalent O(2), and three equivalent O(3) atoms. V(1) is bonded to one O(1) and three equivalent O(3) atoms to form VO4 tetrahedra that share corners with six equivalent Mn(1)O6 octahedra and  a cornercorner with one Mn(2)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 51-55°. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to six equivalent O(3) atoms to form MnO6 octahedra that share corners with six equivalent V(1)O4 tetrahedra and edges with three equivalent Mn(1)O6 octahedra. In the second Mn site, Mn(2) is bonded to two equivalent O(1) and three equivalent O(2) atoms to form MnO5 trigonal bipyramids that share corners with two equivalent V(1)O4 tetrahedra. C(1) is bonded in a trigonal planar geometry to three equivalent O(2) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to three equivalent K(1), one V(1), and one Mn(2) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to two equivalent K(1), one Mn(2), and one C(1) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one K(1), one V(1), and two equivalent Mn(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_K2Mn3V2CO11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.283
_cell_length_b   5.283
_cell_length_c   22.732
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   549.387
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.667  0.333  0.658  1.0
  K  K1  1  0.333  0.667  0.158  1.0
  K  K2  1  0.333  0.667  0.342  1.0
  K  K3  1  0.667  0.333  0.842  1.0
  Mn  Mn4  1  0.333  0.667  0.505  1.0
  Mn  Mn5  1  0.667  0.333  0.005  1.0
  Mn  Mn6  1  0.667  0.333  0.495  1.0
  Mn  Mn7  1  0.333  0.667  0.995  1.0
  Mn  Mn8  1  0.000  0.000  0.750  1.0
  Mn  Mn9  1  0.000  0.000  0.250  1.0
  V  V10  1  0.000  0.000  0.580  1.0
  V  V11  1  0.000  0.000  0.080  1.0
  V  V12  1  0.000  0.000  0.420  1.0
  V  V13  1  0.000  0.000  0.920  1.0
  C  C14  1  0.333  0.667  0.750  1.0
  C  C15  1  0.667  0.333  0.250  1.0
  O  O16  1  0.000  0.000  0.656  1.0
  O  O17  1  0.000  0.000  0.156  1.0
  O  O18  1  0.000  0.000  0.344  1.0
  O  O19  1  0.000  0.000  0.844  1.0
  O  O20  1  0.375  0.931  0.750  1.0
  O  O21  1  0.069  0.444  0.750  1.0
  O  O22  1  0.556  0.625  0.750  1.0
  O  O23  1  0.625  0.069  0.250  1.0
  O  O24  1  0.931  0.556  0.250  1.0
  O  O25  1  0.444  0.375  0.250  1.0
  O  O26  1  0.322  0.011  0.555  1.0
  O  O27  1  0.989  0.311  0.555  1.0
  O  O28  1  0.689  0.678  0.555  1.0
  O  O29  1  0.678  0.989  0.055  1.0
  O  O30  1  0.011  0.689  0.055  1.0
  O  O31  1  0.311  0.322  0.055  1.0
  O  O32  1  0.678  0.989  0.445  1.0
  O  O33  1  0.011  0.689  0.445  1.0
  O  O34  1  0.311  0.322  0.445  1.0
  O  O35  1  0.322  0.011  0.945  1.0
  O  O36  1  0.989  0.311  0.945  1.0
  O  O37  1  0.689  0.678  0.945  1.0
[/CIF]
.