The material described by RbCd(NO2)3 crystallizes in the trigonal R3 space group. Rb(1) is bonded in a distorted q6 geometry to six equivalent O(1) and six equivalent O(2) atoms. Cd(1) is bonded in a 9-coordinate geometry to three equivalent N(1), three equivalent O(1), and three equivalent O(2) atoms. N(1) is bonded in a distorted trigonal planar geometry to one Cd(1), one O(1), and one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to two equivalent Rb(1), one Cd(1), and one N(1) atom. In the second O site, O(2) is bonded in a 1-coordinate geometry to two equivalent Rb(1), one Cd(1), and one N(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_RbCd(NO2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.500
_cell_length_b   5.500
_cell_length_c   5.500
_cell_angle_alpha   90.556
_cell_angle_beta   90.556
_cell_angle_gamma   90.556
_symmetry_Int_Tables_number   1
_cell_volume   166.382
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.455  0.455  0.455  1.0
  Cd  Cd1  1  0.987  0.987  0.987  1.0
  N  N2  1  0.932  0.533  0.971  1.0
  N  N3  1  0.533  0.971  0.932  1.0
  N  N4  1  0.971  0.932  0.533  1.0
  O  O5  1  0.420  0.772  0.932  1.0
  O  O6  1  0.932  0.420  0.772  1.0
  O  O7  1  0.161  0.940  0.403  1.0
  O  O8  1  0.403  0.161  0.940  1.0
  O  O9  1  0.940  0.403  0.161  1.0
  O  O10  1  0.772  0.932  0.420  1.0
[/CIF]
.
The material described by RbCd(NO2)3 crystallizes in the trigonal R3 space group. Rb(1) is bonded in a distorted q6 geometry to six equivalent O(1) and six equivalent O(2) atoms. Cd(1) is bonded in a 9-coordinate geometry to three equivalent N(1), three equivalent O(1), and three equivalent O(2) atoms. N(1) is bonded in a distorted trigonal planar geometry to one Cd(1), one O(1), and one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to two equivalent Rb(1), one Cd(1), and one N(1) atom. In the second O site, O(2) is bonded in a 1-coordinate geometry to two equivalent Rb(1), one Cd(1), and one N(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_RbCd(NO2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.500
_cell_length_b   5.500
_cell_length_c   5.500
_cell_angle_alpha   90.556
_cell_angle_beta   90.556
_cell_angle_gamma   90.556
_symmetry_Int_Tables_number   1
_cell_volume   166.382
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.455  0.455  0.455  1.0
  Cd  Cd1  1  0.987  0.987  0.987  1.0
  N  N2  1  0.932  0.533  0.971  1.0
  N  N3  1  0.533  0.971  0.932  1.0
  N  N4  1  0.971  0.932  0.533  1.0
  O  O5  1  0.420  0.772  0.932  1.0
  O  O6  1  0.932  0.420  0.772  1.0
  O  O7  1  0.161  0.940  0.403  1.0
  O  O8  1  0.403  0.161  0.940  1.0
  O  O9  1  0.940  0.403  0.161  1.0
  O  O10  1  0.772  0.932  0.420  1.0
[/CIF]
.