The compound described by CsO3Cl is Potassium chlorate-like structured and crystallizes in the trigonal R3m space group. Cs(1) is bonded in a 9-coordinate geometry to nine equivalent O(1) atoms. O(1) is bonded in a distorted single-bond geometry to three equivalent Cs(1) and one Cl(1) atom. Cl(1) is bonded in a trigonal non-coplanar geometry to three equivalent O(1) atoms. is represented by the CIF file [CIF]
data_CsClO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.790
_cell_length_b   4.790
_cell_length_c   4.790
_cell_angle_alpha   85.845
_cell_angle_beta   85.845
_cell_angle_gamma   85.845
_symmetry_Int_Tables_number   1
_cell_volume   109.079
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.975  0.975  0.975  1.0
  Cl  Cl1  1  0.490  0.490  0.490  1.0
  O  O2  1  0.801  0.429  0.429  1.0
  O  O3  1  0.429  0.801  0.429  1.0
  O  O4  1  0.429  0.429  0.801  1.0
[/CIF]
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The compound described by CsO3Cl is Potassium chlorate-like structured and crystallizes in the trigonal R3m space group. Cs(1) is bonded in a 9-coordinate geometry to nine equivalent O(1) atoms. O(1) is bonded in a distorted single-bond geometry to three equivalent Cs(1) and one Cl(1) atom. Cl(1) is bonded in a trigonal non-coplanar geometry to three equivalent O(1) atoms. is represented by the CIF file [CIF]
data_CsClO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.790
_cell_length_b   4.790
_cell_length_c   4.790
_cell_angle_alpha   85.845
_cell_angle_beta   85.845
_cell_angle_gamma   85.845
_symmetry_Int_Tables_number   1
_cell_volume   109.079
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.975  0.975  0.975  1.0
  Cl  Cl1  1  0.490  0.490  0.490  1.0
  O  O2  1  0.801  0.429  0.429  1.0
  O  O3  1  0.429  0.801  0.429  1.0
  O  O4  1  0.429  0.429  0.801  1.0
[/CIF]
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