The crystal structure described by K3ReC4(N2O)2 crystallizes in the triclinic P-1 space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 4-coordinate geometry to one N(1), one N(2), and two equivalent O(1) atoms. In the second K site, K(2) is bonded in a 4-coordinate geometry to two equivalent C(2) and two equivalent N(2) atoms. Re(1) is bonded in a 2-coordinate geometry to two equivalent C(1), two equivalent N(1), and two equivalent O(1) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one Re(1) and one N(2) atom. In the second C site, C(2) is bonded in a distorted single-bond geometry to one K(2) and one N(1) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 3-coordinate geometry to one K(1), one Re(1), and one C(2) atom. In the second N site, N(2) is bonded in a distorted single-bond geometry to one K(1), one K(2), and one C(1) atom. O(1) is bonded in a distorted single-bond geometry to two equivalent K(1) and one Re(1) atom. is represented by the CIF file [CIF]
data_K3ReC4(N2O)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.195
_cell_length_b   9.017
_cell_length_c   7.235
_cell_angle_alpha   102.350
_cell_angle_beta   118.968
_cell_angle_gamma   104.180
_symmetry_Int_Tables_number   1
_cell_volume   366.281
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.355  0.087  0.711  1.0
  K  K1  1  0.645  0.913  0.289  1.0
  K  K2  1  0.500  0.500  0.500  1.0
  Re  Re3  1  0.000  0.000  0.000  1.0
  C  C4  1  0.635  0.862  0.808  1.0
  C  C5  1  0.940  0.706  0.927  1.0
  C  C6  1  0.060  0.294  0.073  1.0
  C  C7  1  0.365  0.138  0.192  1.0
  N  N8  1  0.857  0.203  0.954  1.0
  N  N9  1  0.432  0.787  0.696  1.0
  N  N10  1  0.143  0.797  0.046  1.0
  N  N11  1  0.568  0.213  0.304  1.0
  O  O12  1  0.982  0.974  0.737  1.0
  O  O13  1  0.018  0.026  0.263  1.0
[/CIF]
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The crystal structure described by K3ReC4(N2O)2 crystallizes in the triclinic P-1 space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 4-coordinate geometry to one N(1), one N(2), and two equivalent O(1) atoms. In the second K site, K(2) is bonded in a 4-coordinate geometry to two equivalent C(2) and two equivalent N(2) atoms. Re(1) is bonded in a 2-coordinate geometry to two equivalent C(1), two equivalent N(1), and two equivalent O(1) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one Re(1) and one N(2) atom. In the second C site, C(2) is bonded in a distorted single-bond geometry to one K(2) and one N(1) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 3-coordinate geometry to one K(1), one Re(1), and one C(2) atom. In the second N site, N(2) is bonded in a distorted single-bond geometry to one K(1), one K(2), and one C(1) atom. O(1) is bonded in a distorted single-bond geometry to two equivalent K(1) and one Re(1) atom. is represented by the CIF file [CIF]
data_K3ReC4(N2O)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.195
_cell_length_b   9.017
_cell_length_c   7.235
_cell_angle_alpha   102.350
_cell_angle_beta   118.968
_cell_angle_gamma   104.180
_symmetry_Int_Tables_number   1
_cell_volume   366.281
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.355  0.087  0.711  1.0
  K  K1  1  0.645  0.913  0.289  1.0
  K  K2  1  0.500  0.500  0.500  1.0
  Re  Re3  1  0.000  0.000  0.000  1.0
  C  C4  1  0.635  0.862  0.808  1.0
  C  C5  1  0.940  0.706  0.927  1.0
  C  C6  1  0.060  0.294  0.073  1.0
  C  C7  1  0.365  0.138  0.192  1.0
  N  N8  1  0.857  0.203  0.954  1.0
  N  N9  1  0.432  0.787  0.696  1.0
  N  N10  1  0.143  0.797  0.046  1.0
  N  N11  1  0.568  0.213  0.304  1.0
  O  O12  1  0.982  0.974  0.737  1.0
  O  O13  1  0.018  0.026  0.263  1.0
[/CIF]
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