The compound described by MgSb2O4 is Spinel structured and crystallizes in the cubic Fd-3m space group. Mg(1) is bonded to four equivalent O(1) atoms to form MgO4 tetrahedra that share corners with twelve equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles are 55°. Sb(1) is bonded to six equivalent O(1) atoms to form SbO6 octahedra that share corners with six equivalent Mg(1)O4 tetrahedra and edges with six equivalent Sb(1)O6 octahedra. O(1) is bonded in a distorted rectangular see-saw-like geometry to one Mg(1) and three equivalent Sb(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mg(SbO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.701
_cell_length_b   6.701
_cell_length_c   6.701
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   212.791
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.750  0.750  0.750  1.0
  Mg  Mg1  1  0.500  0.500  0.500  1.0
  Sb  Sb2  1  0.125  0.125  0.625  1.0
  Sb  Sb3  1  0.625  0.125  0.125  1.0
  Sb  Sb4  1  0.125  0.125  0.125  1.0
  Sb  Sb5  1  0.125  0.625  0.125  1.0
  O  O6  1  0.878  0.374  0.374  1.0
  O  O7  1  0.374  0.374  0.878  1.0
  O  O8  1  0.374  0.374  0.374  1.0
  O  O9  1  0.372  0.876  0.876  1.0
  O  O10  1  0.876  0.372  0.876  1.0
  O  O11  1  0.876  0.876  0.372  1.0
  O  O12  1  0.374  0.878  0.374  1.0
  O  O13  1  0.876  0.876  0.876  1.0
[/CIF]
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The compound described by MgSb2O4 is Spinel structured and crystallizes in the cubic Fd-3m space group. Mg(1) is bonded to four equivalent O(1) atoms to form MgO4 tetrahedra that share corners with twelve equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles are 55°. Sb(1) is bonded to six equivalent O(1) atoms to form SbO6 octahedra that share corners with six equivalent Mg(1)O4 tetrahedra and edges with six equivalent Sb(1)O6 octahedra. O(1) is bonded in a distorted rectangular see-saw-like geometry to one Mg(1) and three equivalent Sb(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mg(SbO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.701
_cell_length_b   6.701
_cell_length_c   6.701
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   212.791
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.750  0.750  0.750  1.0
  Mg  Mg1  1  0.500  0.500  0.500  1.0
  Sb  Sb2  1  0.125  0.125  0.625  1.0
  Sb  Sb3  1  0.625  0.125  0.125  1.0
  Sb  Sb4  1  0.125  0.125  0.125  1.0
  Sb  Sb5  1  0.125  0.625  0.125  1.0
  O  O6  1  0.878  0.374  0.374  1.0
  O  O7  1  0.374  0.374  0.878  1.0
  O  O8  1  0.374  0.374  0.374  1.0
  O  O9  1  0.372  0.876  0.876  1.0
  O  O10  1  0.876  0.372  0.876  1.0
  O  O11  1  0.876  0.876  0.372  1.0
  O  O12  1  0.374  0.878  0.374  1.0
  O  O13  1  0.876  0.876  0.876  1.0
[/CIF]
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