The material structure described by GdB2HO5 crystallizes in the monoclinic Pc space group. There are two inequivalent Gd sites. In the first Gd site, Gd(1) is bonded in a 6-coordinate geometry to one O(1), one O(10), one O(3), one O(4), one O(5), and one O(7) atom. In the second Gd site, Gd(2) is bonded in a distorted pentagonal bipyramidal geometry to one O(10), one O(2), one O(3), one O(4), one O(6), one O(8), and one O(9) atom. There are four inequivalent B sites. In the first B site, B(1) is bonded in a trigonal planar geometry to one O(6), one O(7), and one O(9) atom. In the second B site, B(2) is bonded in a trigonal planar geometry to one O(10), one O(5), and one O(8) atom. In the third B site, B(3) is bonded in a trigonal planar geometry to one O(1), one O(3), and one O(8) atom. In the fourth B site, B(4) is bonded in a linear geometry to one O(2) and one O(4) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a distorted bent 150 degrees geometry to one O(5) and one O(6) atom. In the second H site, H(2) is bonded in a distorted bent 150 degrees geometry to one O(1) and one O(9) atom. There are ten inequivalent O sites. In the first O site, O(9) is bonded in a 2-coordinate geometry to one Gd(2), one B(1), and one H(2) atom. In the second O site, O(10) is bonded in a distorted trigonal planar geometry to one Gd(1), one Gd(2), and one B(2) atom. In the third O site, O(1) is bonded in a 3-coordinate geometry to one Gd(1), one B(3), and one H(2) atom. In the fourth O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Gd(2) and one B(4) atom. In the fifth O site, O(3) is bonded in a distorted single-bond geometry to one Gd(1), one Gd(2), and one B(3) atom. In the sixth O site, O(4) is bonded in a distorted single-bond geometry to one Gd(1), one Gd(2), and one B(4) atom. In the seventh O site, O(5) is bonded in a distorted trigonal planar geometry to one Gd(1), one B(2), and one H(1) atom. In the eighth O site, O(6) is bonded in a distorted trigonal planar geometry to one Gd(2), one B(1), and one H(1) atom. In the ninth O site, O(7) is bonded in a distorted bent 150 degrees geometry to one Gd(1) and one B(1) atom. In the tenth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Gd(2), one B(2), and one B(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_GdB2HO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.513
_cell_length_b   5.921
_cell_length_c   11.211
_cell_angle_alpha   85.621
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   431.099
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Gd  Gd0  1  0.350  0.763  0.581  1.0
  Gd  Gd1  1  0.150  0.263  0.081  1.0
  Gd  Gd2  1  0.638  0.299  0.424  1.0
  Gd  Gd3  1  0.862  0.799  0.924  1.0
  B  B4  1  0.372  0.811  0.887  1.0
  B  B5  1  0.128  0.311  0.387  1.0
  B  B6  1  0.660  0.174  0.112  1.0
  B  B7  1  0.840  0.674  0.612  1.0
  B  B8  1  0.431  0.994  0.272  1.0
  B  B9  1  0.069  0.494  0.772  1.0
  B  B10  1  0.621  0.099  0.717  1.0
  B  B11  1  0.879  0.599  0.217  1.0
  H  H12  1  0.541  0.442  0.991  1.0
  H  H13  1  0.959  0.942  0.491  1.0
  H  H14  1  0.273  0.863  0.055  1.0
  H  H15  1  0.227  0.363  0.555  1.0
  O  O16  1  0.301  0.940  0.186  1.0
  O  O17  1  0.199  0.440  0.686  1.0
  O  O18  1  0.715  0.108  0.815  1.0
  O  O19  1  0.785  0.608  0.315  1.0
  O  O20  1  0.421  0.966  0.395  1.0
  O  O21  1  0.079  0.466  0.895  1.0
  O  O22  1  0.572  0.093  0.606  1.0
  O  O23  1  0.928  0.593  0.106  1.0
  O  O24  1  0.511  0.305  0.049  1.0
  O  O25  1  0.989  0.805  0.549  1.0
  O  O26  1  0.537  0.696  0.938  1.0
  O  O27  1  0.963  0.196  0.438  1.0
  O  O28  1  0.338  0.860  0.769  1.0
  O  O29  1  0.162  0.360  0.269  1.0
  O  O30  1  0.614  0.128  0.235  1.0
  O  O31  1  0.886  0.628  0.735  1.0
  O  O32  1  0.275  0.398  0.469  1.0
  O  O33  1  0.225  0.898  0.969  1.0
  O  O34  1  0.667  0.593  0.566  1.0
  O  O35  1  0.833  0.093  0.066  1.0
[/CIF]
.
The material structure described by GdB2HO5 crystallizes in the monoclinic Pc space group. There are two inequivalent Gd sites. In the first Gd site, Gd(1) is bonded in a 6-coordinate geometry to one O(1), one O(10), one O(3), one O(4), one O(5), and one O(7) atom. In the second Gd site, Gd(2) is bonded in a distorted pentagonal bipyramidal geometry to one O(10), one O(2), one O(3), one O(4), one O(6), one O(8), and one O(9) atom. There are four inequivalent B sites. In the first B site, B(1) is bonded in a trigonal planar geometry to one O(6), one O(7), and one O(9) atom. In the second B site, B(2) is bonded in a trigonal planar geometry to one O(10), one O(5), and one O(8) atom. In the third B site, B(3) is bonded in a trigonal planar geometry to one O(1), one O(3), and one O(8) atom. In the fourth B site, B(4) is bonded in a linear geometry to one O(2) and one O(4) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a distorted bent 150 degrees geometry to one O(5) and one O(6) atom. In the second H site, H(2) is bonded in a distorted bent 150 degrees geometry to one O(1) and one O(9) atom. There are ten inequivalent O sites. In the first O site, O(9) is bonded in a 2-coordinate geometry to one Gd(2), one B(1), and one H(2) atom. In the second O site, O(10) is bonded in a distorted trigonal planar geometry to one Gd(1), one Gd(2), and one B(2) atom. In the third O site, O(1) is bonded in a 3-coordinate geometry to one Gd(1), one B(3), and one H(2) atom. In the fourth O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Gd(2) and one B(4) atom. In the fifth O site, O(3) is bonded in a distorted single-bond geometry to one Gd(1), one Gd(2), and one B(3) atom. In the sixth O site, O(4) is bonded in a distorted single-bond geometry to one Gd(1), one Gd(2), and one B(4) atom. In the seventh O site, O(5) is bonded in a distorted trigonal planar geometry to one Gd(1), one B(2), and one H(1) atom. In the eighth O site, O(6) is bonded in a distorted trigonal planar geometry to one Gd(2), one B(1), and one H(1) atom. In the ninth O site, O(7) is bonded in a distorted bent 150 degrees geometry to one Gd(1) and one B(1) atom. In the tenth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Gd(2), one B(2), and one B(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_GdB2HO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.513
_cell_length_b   5.921
_cell_length_c   11.211
_cell_angle_alpha   85.621
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   431.099
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Gd  Gd0  1  0.350  0.763  0.581  1.0
  Gd  Gd1  1  0.150  0.263  0.081  1.0
  Gd  Gd2  1  0.638  0.299  0.424  1.0
  Gd  Gd3  1  0.862  0.799  0.924  1.0
  B  B4  1  0.372  0.811  0.887  1.0
  B  B5  1  0.128  0.311  0.387  1.0
  B  B6  1  0.660  0.174  0.112  1.0
  B  B7  1  0.840  0.674  0.612  1.0
  B  B8  1  0.431  0.994  0.272  1.0
  B  B9  1  0.069  0.494  0.772  1.0
  B  B10  1  0.621  0.099  0.717  1.0
  B  B11  1  0.879  0.599  0.217  1.0
  H  H12  1  0.541  0.442  0.991  1.0
  H  H13  1  0.959  0.942  0.491  1.0
  H  H14  1  0.273  0.863  0.055  1.0
  H  H15  1  0.227  0.363  0.555  1.0
  O  O16  1  0.301  0.940  0.186  1.0
  O  O17  1  0.199  0.440  0.686  1.0
  O  O18  1  0.715  0.108  0.815  1.0
  O  O19  1  0.785  0.608  0.315  1.0
  O  O20  1  0.421  0.966  0.395  1.0
  O  O21  1  0.079  0.466  0.895  1.0
  O  O22  1  0.572  0.093  0.606  1.0
  O  O23  1  0.928  0.593  0.106  1.0
  O  O24  1  0.511  0.305  0.049  1.0
  O  O25  1  0.989  0.805  0.549  1.0
  O  O26  1  0.537  0.696  0.938  1.0
  O  O27  1  0.963  0.196  0.438  1.0
  O  O28  1  0.338  0.860  0.769  1.0
  O  O29  1  0.162  0.360  0.269  1.0
  O  O30  1  0.614  0.128  0.235  1.0
  O  O31  1  0.886  0.628  0.735  1.0
  O  O32  1  0.275  0.398  0.469  1.0
  O  O33  1  0.225  0.898  0.969  1.0
  O  O34  1  0.667  0.593  0.566  1.0
  O  O35  1  0.833  0.093  0.066  1.0
[/CIF]
.