The structure described by WOF4 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of six WOF4 clusters. In two of the WOF4 clusters, W(2) is bonded in a 6-coordinate geometry to one O(2), one F(1), one F(2), one F(6), and two equivalent F(8) atoms. O(2) is bonded in a single-bond geometry to one W(2) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one W(2) atom. In the second F site, F(2) is bonded in a single-bond geometry to one W(2) atom. In the third F site, F(6) is bonded in a single-bond geometry to one W(2) atom. In the fourth F site, F(8) is bonded in a distorted water-like geometry to two equivalent W(2) atoms. In four of the WOF4 clusters, W(1) is bonded in a 5-coordinate geometry to one O(1), one F(3), one F(4), one F(5), and one F(7) atom. O(1) is bonded in a single-bond geometry to one W(1) atom. There are four inequivalent F sites. In the first F site, F(3) is bonded in a single-bond geometry to one W(1) atom. In the second F site, F(4) is bonded in a single-bond geometry to one W(1) atom. In the third F site, F(5) is bonded in a single-bond geometry to one W(1) atom. In the fourth F site, F(7) is bonded in a single-bond geometry to one W(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_WOF4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.647
_cell_length_b   7.752
_cell_length_c   10.428
_cell_angle_alpha   68.379
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   800.117
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  W  W0  1  0.409  0.371  0.840  1.0
  W  W1  1  0.909  0.629  0.660  1.0
  W  W2  1  0.858  0.053  0.076  1.0
  W  W3  1  0.358  0.947  0.424  1.0
  W  W4  1  0.642  0.053  0.576  1.0
  W  W5  1  0.142  0.947  0.924  1.0
  W  W6  1  0.091  0.371  0.340  1.0
  W  W7  1  0.591  0.629  0.160  1.0
  O  O8  1  0.041  0.506  0.736  1.0
  O  O9  1  0.541  0.494  0.764  1.0
  O  O10  1  0.292  0.986  0.266  1.0
  O  O11  1  0.792  0.014  0.234  1.0
  O  O12  1  0.208  0.986  0.766  1.0
  O  O13  1  0.708  0.014  0.734  1.0
  O  O14  1  0.459  0.506  0.236  1.0
  O  O15  1  0.959  0.494  0.264  1.0
  F  F16  1  0.200  0.168  0.950  1.0
  F  F17  1  0.735  0.187  0.951  1.0
  F  F18  1  0.311  0.385  0.685  1.0
  F  F19  1  0.805  0.443  0.640  1.0
  F  F20  1  0.944  0.709  0.469  1.0
  F  F21  1  0.447  0.727  0.453  1.0
  F  F22  1  0.551  0.875  0.146  1.0
  F  F23  1  0.020  0.923  0.126  1.0
  F  F24  1  0.305  0.557  0.860  1.0
  F  F25  1  0.811  0.615  0.815  1.0
  F  F26  1  0.235  0.813  0.549  1.0
  F  F27  1  0.700  0.832  0.550  1.0
  F  F28  1  0.556  0.709  0.969  1.0
  F  F29  1  0.053  0.727  0.953  1.0
  F  F30  1  0.949  0.875  0.646  1.0
  F  F31  1  0.480  0.923  0.626  1.0
  F  F32  1  0.520  0.077  0.374  1.0
  F  F33  1  0.051  0.125  0.354  1.0
  F  F34  1  0.947  0.273  0.047  1.0
  F  F35  1  0.444  0.291  0.031  1.0
  F  F36  1  0.300  0.168  0.450  1.0
  F  F37  1  0.765  0.187  0.451  1.0
  F  F38  1  0.189  0.385  0.185  1.0
  F  F39  1  0.695  0.443  0.140  1.0
  F  F40  1  0.980  0.077  0.874  1.0
  F  F41  1  0.449  0.125  0.854  1.0
  F  F42  1  0.553  0.273  0.547  1.0
  F  F43  1  0.056  0.291  0.531  1.0
  F  F44  1  0.195  0.557  0.360  1.0
  F  F45  1  0.689  0.615  0.315  1.0
  F  F46  1  0.265  0.813  0.049  1.0
  F  F47  1  0.800  0.832  0.050  1.0
[/CIF]
.
The structure described by WOF4 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of six WOF4 clusters. In two of the WOF4 clusters, W(2) is bonded in a 6-coordinate geometry to one O(2), one F(1), one F(2), one F(6), and two equivalent F(8) atoms. O(2) is bonded in a single-bond geometry to one W(2) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one W(2) atom. In the second F site, F(2) is bonded in a single-bond geometry to one W(2) atom. In the third F site, F(6) is bonded in a single-bond geometry to one W(2) atom. In the fourth F site, F(8) is bonded in a distorted water-like geometry to two equivalent W(2) atoms. In four of the WOF4 clusters, W(1) is bonded in a 5-coordinate geometry to one O(1), one F(3), one F(4), one F(5), and one F(7) atom. O(1) is bonded in a single-bond geometry to one W(1) atom. There are four inequivalent F sites. In the first F site, F(3) is bonded in a single-bond geometry to one W(1) atom. In the second F site, F(4) is bonded in a single-bond geometry to one W(1) atom. In the third F site, F(5) is bonded in a single-bond geometry to one W(1) atom. In the fourth F site, F(7) is bonded in a single-bond geometry to one W(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_WOF4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.647
_cell_length_b   7.752
_cell_length_c   10.428
_cell_angle_alpha   68.379
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   800.117
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  W  W0  1  0.409  0.371  0.840  1.0
  W  W1  1  0.909  0.629  0.660  1.0
  W  W2  1  0.858  0.053  0.076  1.0
  W  W3  1  0.358  0.947  0.424  1.0
  W  W4  1  0.642  0.053  0.576  1.0
  W  W5  1  0.142  0.947  0.924  1.0
  W  W6  1  0.091  0.371  0.340  1.0
  W  W7  1  0.591  0.629  0.160  1.0
  O  O8  1  0.041  0.506  0.736  1.0
  O  O9  1  0.541  0.494  0.764  1.0
  O  O10  1  0.292  0.986  0.266  1.0
  O  O11  1  0.792  0.014  0.234  1.0
  O  O12  1  0.208  0.986  0.766  1.0
  O  O13  1  0.708  0.014  0.734  1.0
  O  O14  1  0.459  0.506  0.236  1.0
  O  O15  1  0.959  0.494  0.264  1.0
  F  F16  1  0.200  0.168  0.950  1.0
  F  F17  1  0.735  0.187  0.951  1.0
  F  F18  1  0.311  0.385  0.685  1.0
  F  F19  1  0.805  0.443  0.640  1.0
  F  F20  1  0.944  0.709  0.469  1.0
  F  F21  1  0.447  0.727  0.453  1.0
  F  F22  1  0.551  0.875  0.146  1.0
  F  F23  1  0.020  0.923  0.126  1.0
  F  F24  1  0.305  0.557  0.860  1.0
  F  F25  1  0.811  0.615  0.815  1.0
  F  F26  1  0.235  0.813  0.549  1.0
  F  F27  1  0.700  0.832  0.550  1.0
  F  F28  1  0.556  0.709  0.969  1.0
  F  F29  1  0.053  0.727  0.953  1.0
  F  F30  1  0.949  0.875  0.646  1.0
  F  F31  1  0.480  0.923  0.626  1.0
  F  F32  1  0.520  0.077  0.374  1.0
  F  F33  1  0.051  0.125  0.354  1.0
  F  F34  1  0.947  0.273  0.047  1.0
  F  F35  1  0.444  0.291  0.031  1.0
  F  F36  1  0.300  0.168  0.450  1.0
  F  F37  1  0.765  0.187  0.451  1.0
  F  F38  1  0.189  0.385  0.185  1.0
  F  F39  1  0.695  0.443  0.140  1.0
  F  F40  1  0.980  0.077  0.874  1.0
  F  F41  1  0.449  0.125  0.854  1.0
  F  F42  1  0.553  0.273  0.547  1.0
  F  F43  1  0.056  0.291  0.531  1.0
  F  F44  1  0.195  0.557  0.360  1.0
  F  F45  1  0.689  0.615  0.315  1.0
  F  F46  1  0.265  0.813  0.049  1.0
  F  F47  1  0.800  0.832  0.050  1.0
[/CIF]
.