The structure described by GdTlS2O9 crystallizes in the monoclinic P2_1/c space group. Gd(1) is bonded in a 8-coordinate geometry to one O(2), one O(3), one O(4), one O(5), one O(6), one O(7), one O(8), and one O(9) atom. Tl(1) is bonded in a single-bond geometry to one O(1) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a tetrahedral geometry to one O(2), one O(6), one O(7), and one O(8) atom. In the second S site, S(2) is bonded in a tetrahedral geometry to one O(1), one O(3), one O(4), and one O(9) atom. There are nine inequivalent O sites. In the first O site, O(5) is bonded in a single-bond geometry to one Gd(1) atom. In the second O site, O(6) is bonded in a distorted water-like geometry to one Gd(1) and one S(1) atom. In the third O site, O(7) is bonded in a distorted single-bond geometry to one Gd(1) and one S(1) atom. In the fourth O site, O(8) is bonded in a bent 150 degrees geometry to one Gd(1) and one S(1) atom. In the fifth O site, O(1) is bonded in a single-bond geometry to one Tl(1) and one S(2) atom. In the sixth O site, O(9) is bonded in a bent 150 degrees geometry to one Gd(1) and one S(2) atom. In the seventh O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Gd(1) and one S(1) atom. In the eighth O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Gd(1) and one S(2) atom. In the ninth O site, O(4) is bonded in a bent 120 degrees geometry to one Gd(1) and one S(2) atom. is represented by the CIF file [CIF]
data_GdTlS2O9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.526
_cell_length_b   10.599
_cell_length_c   10.285
_cell_angle_alpha   119.846
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   806.163
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Gd  Gd0  1  0.356  0.962  0.717  1.0
  Gd  Gd1  1  0.644  0.038  0.283  1.0
  Gd  Gd2  1  0.856  0.538  0.783  1.0
  Gd  Gd3  1  0.144  0.462  0.217  1.0
  Tl  Tl4  1  0.330  0.688  0.968  1.0
  Tl  Tl5  1  0.670  0.312  0.032  1.0
  Tl  Tl6  1  0.830  0.812  0.532  1.0
  Tl  Tl7  1  0.170  0.188  0.468  1.0
  S  S8  1  0.131  0.317  0.872  1.0
  S  S9  1  0.869  0.683  0.128  1.0
  S  S10  1  0.631  0.183  0.628  1.0
  S  S11  1  0.369  0.817  0.372  1.0
  S  S12  1  0.200  0.603  0.599  1.0
  S  S13  1  0.800  0.397  0.401  1.0
  S  S14  1  0.700  0.897  0.901  1.0
  S  S15  1  0.300  0.103  0.099  1.0
  O  O16  1  0.781  0.040  0.968  1.0
  O  O17  1  0.219  0.960  0.032  1.0
  O  O18  1  0.281  0.460  0.532  1.0
  O  O19  1  0.719  0.540  0.468  1.0
  O  O20  1  0.205  0.178  0.762  1.0
  O  O21  1  0.795  0.822  0.238  1.0
  O  O22  1  0.705  0.322  0.738  1.0
  O  O23  1  0.295  0.678  0.262  1.0
  O  O24  1  0.314  0.724  0.675  1.0
  O  O25  1  0.686  0.276  0.325  1.0
  O  O26  1  0.814  0.776  0.825  1.0
  O  O27  1  0.186  0.224  0.175  1.0
  O  O28  1  0.384  0.117  0.979  1.0
  O  O29  1  0.616  0.883  0.021  1.0
  O  O30  1  0.884  0.383  0.521  1.0
  O  O31  1  0.116  0.617  0.479  1.0
  O  O32  1  0.092  0.944  0.768  1.0
  O  O33  1  0.908  0.056  0.232  1.0
  O  O34  1  0.592  0.556  0.732  1.0
  O  O35  1  0.408  0.444  0.268  1.0
  O  O36  1  0.251  0.420  0.979  1.0
  O  O37  1  0.749  0.580  0.021  1.0
  O  O38  1  0.751  0.080  0.521  1.0
  O  O39  1  0.249  0.920  0.479  1.0
  O  O40  1  0.013  0.298  0.968  1.0
  O  O41  1  0.987  0.702  0.032  1.0
  O  O42  1  0.513  0.202  0.532  1.0
  O  O43  1  0.487  0.798  0.468  1.0
  O  O44  1  0.058  0.381  0.786  1.0
  O  O45  1  0.942  0.619  0.214  1.0
  O  O46  1  0.558  0.119  0.714  1.0
  O  O47  1  0.442  0.881  0.286  1.0
  O  O48  1  0.588  0.885  0.785  1.0
  O  O49  1  0.412  0.115  0.215  1.0
  O  O50  1  0.088  0.615  0.715  1.0
  O  O51  1  0.912  0.385  0.285  1.0
[/CIF]
.
The structure described by GdTlS2O9 crystallizes in the monoclinic P2_1/c space group. Gd(1) is bonded in a 8-coordinate geometry to one O(2), one O(3), one O(4), one O(5), one O(6), one O(7), one O(8), and one O(9) atom. Tl(1) is bonded in a single-bond geometry to one O(1) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a tetrahedral geometry to one O(2), one O(6), one O(7), and one O(8) atom. In the second S site, S(2) is bonded in a tetrahedral geometry to one O(1), one O(3), one O(4), and one O(9) atom. There are nine inequivalent O sites. In the first O site, O(5) is bonded in a single-bond geometry to one Gd(1) atom. In the second O site, O(6) is bonded in a distorted water-like geometry to one Gd(1) and one S(1) atom. In the third O site, O(7) is bonded in a distorted single-bond geometry to one Gd(1) and one S(1) atom. In the fourth O site, O(8) is bonded in a bent 150 degrees geometry to one Gd(1) and one S(1) atom. In the fifth O site, O(1) is bonded in a single-bond geometry to one Tl(1) and one S(2) atom. In the sixth O site, O(9) is bonded in a bent 150 degrees geometry to one Gd(1) and one S(2) atom. In the seventh O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Gd(1) and one S(1) atom. In the eighth O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Gd(1) and one S(2) atom. In the ninth O site, O(4) is bonded in a bent 120 degrees geometry to one Gd(1) and one S(2) atom. is represented by the CIF file [CIF]
data_GdTlS2O9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.526
_cell_length_b   10.599
_cell_length_c   10.285
_cell_angle_alpha   119.846
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   806.163
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Gd  Gd0  1  0.356  0.962  0.717  1.0
  Gd  Gd1  1  0.644  0.038  0.283  1.0
  Gd  Gd2  1  0.856  0.538  0.783  1.0
  Gd  Gd3  1  0.144  0.462  0.217  1.0
  Tl  Tl4  1  0.330  0.688  0.968  1.0
  Tl  Tl5  1  0.670  0.312  0.032  1.0
  Tl  Tl6  1  0.830  0.812  0.532  1.0
  Tl  Tl7  1  0.170  0.188  0.468  1.0
  S  S8  1  0.131  0.317  0.872  1.0
  S  S9  1  0.869  0.683  0.128  1.0
  S  S10  1  0.631  0.183  0.628  1.0
  S  S11  1  0.369  0.817  0.372  1.0
  S  S12  1  0.200  0.603  0.599  1.0
  S  S13  1  0.800  0.397  0.401  1.0
  S  S14  1  0.700  0.897  0.901  1.0
  S  S15  1  0.300  0.103  0.099  1.0
  O  O16  1  0.781  0.040  0.968  1.0
  O  O17  1  0.219  0.960  0.032  1.0
  O  O18  1  0.281  0.460  0.532  1.0
  O  O19  1  0.719  0.540  0.468  1.0
  O  O20  1  0.205  0.178  0.762  1.0
  O  O21  1  0.795  0.822  0.238  1.0
  O  O22  1  0.705  0.322  0.738  1.0
  O  O23  1  0.295  0.678  0.262  1.0
  O  O24  1  0.314  0.724  0.675  1.0
  O  O25  1  0.686  0.276  0.325  1.0
  O  O26  1  0.814  0.776  0.825  1.0
  O  O27  1  0.186  0.224  0.175  1.0
  O  O28  1  0.384  0.117  0.979  1.0
  O  O29  1  0.616  0.883  0.021  1.0
  O  O30  1  0.884  0.383  0.521  1.0
  O  O31  1  0.116  0.617  0.479  1.0
  O  O32  1  0.092  0.944  0.768  1.0
  O  O33  1  0.908  0.056  0.232  1.0
  O  O34  1  0.592  0.556  0.732  1.0
  O  O35  1  0.408  0.444  0.268  1.0
  O  O36  1  0.251  0.420  0.979  1.0
  O  O37  1  0.749  0.580  0.021  1.0
  O  O38  1  0.751  0.080  0.521  1.0
  O  O39  1  0.249  0.920  0.479  1.0
  O  O40  1  0.013  0.298  0.968  1.0
  O  O41  1  0.987  0.702  0.032  1.0
  O  O42  1  0.513  0.202  0.532  1.0
  O  O43  1  0.487  0.798  0.468  1.0
  O  O44  1  0.058  0.381  0.786  1.0
  O  O45  1  0.942  0.619  0.214  1.0
  O  O46  1  0.558  0.119  0.714  1.0
  O  O47  1  0.442  0.881  0.286  1.0
  O  O48  1  0.588  0.885  0.785  1.0
  O  O49  1  0.412  0.115  0.215  1.0
  O  O50  1  0.088  0.615  0.715  1.0
  O  O51  1  0.912  0.385  0.285  1.0
[/CIF]
.