The material structure described by (Be(NO2)3)4(NO2)10(NO)2(O2)5 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two hydrogen peroxide molecules, five nitrous acid molecules, one nitroxyl molecule, one water atom, and two Be(NO2)3 clusters. In one of the Be(NO2)3 clusters, Be(1) is bonded in a trigonal planar geometry to one O(26), one O(27), and one O(8) atom. There are three inequivalent N sites. In the first N site, N(4) is bonded in a bent 120 degrees geometry to one O(27) and one O(3) atom. In the second N site, N(7) is bonded in a bent 120 degrees geometry to one O(24) and one O(26) atom. In the third N site, N(11) is bonded in a bent 120 degrees geometry to one O(7) and one O(8) atom. There are six inequivalent O sites. In the first O site, O(24) is bonded in a single-bond geometry to one N(7) atom. In the second O site, O(26) is bonded in a bent 120 degrees geometry to one Be(1) and one N(7) atom. In the third O site, O(27) is bonded in a bent 120 degrees geometry to one Be(1) and one N(4) atom. In the fourth O site, O(3) is bonded in a single-bond geometry to one N(4) atom. In the fifth O site, O(7) is bonded in a single-bond geometry to one N(11) atom. In the sixth O site, O(8) is bonded in a bent 120 degrees geometry to one Be(1) and one N(11) atom. In one of the Be(NO2)3 clusters, Be(2) is bonded in a tetrahedral geometry to one O(12), one O(21), one O(22), and one O(9) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a water-like geometry to one O(21) and one O(9) atom. In the second N site, N(3) is bonded in a bent 120 degrees geometry to one O(22) and one O(23) atom. In the third N site, N(8) is bonded in a bent 120 degrees geometry to one O(12) and one O(20) atom. There are six inequivalent O sites. In the first O site, O(22) is bonded in a bent 120 degrees geometry to one Be(2) and one N(3) atom. In the second O site, O(21) is bonded in an L-shaped geometry to one Be(2) and one N(1) atom. In the third O site, O(20) is bonded in a single-bond geometry to one N(8) atom. In the fourth O site, O(23) is bonded in a distorted single-bond geometry to one N(3) atom. In the fifth O site, O(9) is bonded in an L-shaped geometry to one Be(2) and one N(1) atom. In the sixth O site, O(12) is bonded in a bent 120 degrees geometry to one Be(2) and one N(8) atom. is represented by the CIF card [CIF]
data_Be(N3O7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.214
_cell_length_b   8.213
_cell_length_c   14.728
_cell_angle_alpha   89.624
_cell_angle_beta   102.201
_cell_angle_gamma   107.614
_symmetry_Int_Tables_number   1
_cell_volume   811.367
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Be  Be0  1  0.831  0.972  0.963  1.0
  Be  Be1  1  0.752  0.428  0.515  1.0
  N  N2  1  0.487  0.416  0.556  1.0
  N  N3  1  0.076  0.308  0.325  1.0
  N  N4  1  0.914  0.300  0.653  1.0
  N  N5  1  0.933  0.877  0.821  1.0
  N  N6  1  0.763  0.396  0.180  1.0
  N  N7  1  0.223  0.161  0.051  1.0
  N  N8  1  0.836  0.274  0.909  1.0
  N  N9  1  0.988  0.688  0.480  1.0
  N  N10  1  0.181  0.568  0.867  1.0
  N  N11  1  0.017  0.024  0.596  1.0
  N  N12  1  0.682  0.859  0.107  1.0
  N  N13  1  0.354  0.919  0.299  1.0
  O  O14  1  0.484  0.944  0.764  1.0
  O  O15  1  0.222  0.431  0.348  1.0
  O  O16  1  0.035  0.801  0.795  1.0
  O  O17  1  0.544  0.951  0.692  1.0
  O  O18  1  0.190  0.048  0.605  1.0
  O  O19  1  0.330  0.547  0.706  1.0
  O  O20  1  0.692  0.002  0.133  1.0
  O  O21  1  0.743  0.834  0.033  1.0
  O  O22  1  0.661  0.520  0.591  1.0
  O  O23  1  0.860  0.928  0.560  1.0
  O  O24  1  0.924  0.383  0.174  1.0
  O  O25  1  0.866  0.534  0.443  1.0
  O  O26  1  0.021  0.168  0.354  1.0
  O  O27  1  0.486  0.900  0.360  1.0
  O  O28  1  0.201  0.643  0.062  1.0
  O  O29  1  0.331  0.582  0.850  1.0
  O  O30  1  0.364  0.246  0.022  1.0
  O  O31  1  0.675  0.362  0.243  1.0
  O  O32  1  0.318  0.588  0.117  1.0
  O  O33  1  0.104  0.764  0.434  1.0
  O  O34  1  0.503  0.320  0.490  1.0
  O  O35  1  0.873  0.296  0.564  1.0
  O  O36  1  0.987  0.191  0.689  1.0
  O  O37  1  0.741  0.372  0.898  1.0
  O  O38  1  0.204  0.100  0.125  1.0
  O  O39  1  0.756  0.130  0.952  1.0
  O  O40  1  0.963  0.899  0.914  1.0
  O  O41  1  0.191  0.828  0.260  1.0
[/CIF]
.
The material structure described by (Be(NO2)3)4(NO2)10(NO)2(O2)5 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two hydrogen peroxide molecules, five nitrous acid molecules, one nitroxyl molecule, one water atom, and two Be(NO2)3 clusters. In one of the Be(NO2)3 clusters, Be(1) is bonded in a trigonal planar geometry to one O(26), one O(27), and one O(8) atom. There are three inequivalent N sites. In the first N site, N(4) is bonded in a bent 120 degrees geometry to one O(27) and one O(3) atom. In the second N site, N(7) is bonded in a bent 120 degrees geometry to one O(24) and one O(26) atom. In the third N site, N(11) is bonded in a bent 120 degrees geometry to one O(7) and one O(8) atom. There are six inequivalent O sites. In the first O site, O(24) is bonded in a single-bond geometry to one N(7) atom. In the second O site, O(26) is bonded in a bent 120 degrees geometry to one Be(1) and one N(7) atom. In the third O site, O(27) is bonded in a bent 120 degrees geometry to one Be(1) and one N(4) atom. In the fourth O site, O(3) is bonded in a single-bond geometry to one N(4) atom. In the fifth O site, O(7) is bonded in a single-bond geometry to one N(11) atom. In the sixth O site, O(8) is bonded in a bent 120 degrees geometry to one Be(1) and one N(11) atom. In one of the Be(NO2)3 clusters, Be(2) is bonded in a tetrahedral geometry to one O(12), one O(21), one O(22), and one O(9) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a water-like geometry to one O(21) and one O(9) atom. In the second N site, N(3) is bonded in a bent 120 degrees geometry to one O(22) and one O(23) atom. In the third N site, N(8) is bonded in a bent 120 degrees geometry to one O(12) and one O(20) atom. There are six inequivalent O sites. In the first O site, O(22) is bonded in a bent 120 degrees geometry to one Be(2) and one N(3) atom. In the second O site, O(21) is bonded in an L-shaped geometry to one Be(2) and one N(1) atom. In the third O site, O(20) is bonded in a single-bond geometry to one N(8) atom. In the fourth O site, O(23) is bonded in a distorted single-bond geometry to one N(3) atom. In the fifth O site, O(9) is bonded in an L-shaped geometry to one Be(2) and one N(1) atom. In the sixth O site, O(12) is bonded in a bent 120 degrees geometry to one Be(2) and one N(8) atom. is represented by the CIF card [CIF]
data_Be(N3O7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.214
_cell_length_b   8.213
_cell_length_c   14.728
_cell_angle_alpha   89.624
_cell_angle_beta   102.201
_cell_angle_gamma   107.614
_symmetry_Int_Tables_number   1
_cell_volume   811.367
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Be  Be0  1  0.831  0.972  0.963  1.0
  Be  Be1  1  0.752  0.428  0.515  1.0
  N  N2  1  0.487  0.416  0.556  1.0
  N  N3  1  0.076  0.308  0.325  1.0
  N  N4  1  0.914  0.300  0.653  1.0
  N  N5  1  0.933  0.877  0.821  1.0
  N  N6  1  0.763  0.396  0.180  1.0
  N  N7  1  0.223  0.161  0.051  1.0
  N  N8  1  0.836  0.274  0.909  1.0
  N  N9  1  0.988  0.688  0.480  1.0
  N  N10  1  0.181  0.568  0.867  1.0
  N  N11  1  0.017  0.024  0.596  1.0
  N  N12  1  0.682  0.859  0.107  1.0
  N  N13  1  0.354  0.919  0.299  1.0
  O  O14  1  0.484  0.944  0.764  1.0
  O  O15  1  0.222  0.431  0.348  1.0
  O  O16  1  0.035  0.801  0.795  1.0
  O  O17  1  0.544  0.951  0.692  1.0
  O  O18  1  0.190  0.048  0.605  1.0
  O  O19  1  0.330  0.547  0.706  1.0
  O  O20  1  0.692  0.002  0.133  1.0
  O  O21  1  0.743  0.834  0.033  1.0
  O  O22  1  0.661  0.520  0.591  1.0
  O  O23  1  0.860  0.928  0.560  1.0
  O  O24  1  0.924  0.383  0.174  1.0
  O  O25  1  0.866  0.534  0.443  1.0
  O  O26  1  0.021  0.168  0.354  1.0
  O  O27  1  0.486  0.900  0.360  1.0
  O  O28  1  0.201  0.643  0.062  1.0
  O  O29  1  0.331  0.582  0.850  1.0
  O  O30  1  0.364  0.246  0.022  1.0
  O  O31  1  0.675  0.362  0.243  1.0
  O  O32  1  0.318  0.588  0.117  1.0
  O  O33  1  0.104  0.764  0.434  1.0
  O  O34  1  0.503  0.320  0.490  1.0
  O  O35  1  0.873  0.296  0.564  1.0
  O  O36  1  0.987  0.191  0.689  1.0
  O  O37  1  0.741  0.372  0.898  1.0
  O  O38  1  0.204  0.100  0.125  1.0
  O  O39  1  0.756  0.130  0.952  1.0
  O  O40  1  0.963  0.899  0.914  1.0
  O  O41  1  0.191  0.828  0.260  1.0
[/CIF]
.