The material structure described by KTeO4 crystallizes in the monoclinic C2/c space group. K(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form distorted KO6 octahedra that share corners with eight equivalent Te(1)O6 octahedra and edges with two equivalent K(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-67°. Te(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form TeO6 octahedra that share corners with eight equivalent K(1)O6 octahedra and edges with two equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-67°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one K(1) and two equivalent Te(1) atoms. In the second O site, O(2) is bonded in a 3-coordinate geometry to two equivalent K(1) and one Te(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_KTeO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.085
_cell_length_b   7.085
_cell_length_c   5.176
_cell_angle_alpha   69.646
_cell_angle_beta   69.646
_cell_angle_gamma   109.010
_symmetry_Int_Tables_number   1
_cell_volume   196.673
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.662  0.338  0.250  1.0
  K  K1  1  0.338  0.662  0.750  1.0
  Te  Te2  1  0.924  0.076  0.750  1.0
  Te  Te3  1  0.076  0.924  0.250  1.0
  O  O4  1  0.787  0.888  0.222  1.0
  O  O5  1  0.112  0.213  0.278  1.0
  O  O6  1  0.213  0.112  0.778  1.0
  O  O7  1  0.888  0.787  0.722  1.0
  O  O8  1  0.627  0.001  0.784  1.0
  O  O9  1  0.999  0.373  0.716  1.0
  O  O10  1  0.373  0.999  0.216  1.0
  O  O11  1  0.001  0.627  0.284  1.0
[/CIF]
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The material structure described by KTeO4 crystallizes in the monoclinic C2/c space group. K(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form distorted KO6 octahedra that share corners with eight equivalent Te(1)O6 octahedra and edges with two equivalent K(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-67°. Te(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form TeO6 octahedra that share corners with eight equivalent K(1)O6 octahedra and edges with two equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-67°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one K(1) and two equivalent Te(1) atoms. In the second O site, O(2) is bonded in a 3-coordinate geometry to two equivalent K(1) and one Te(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_KTeO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.085
_cell_length_b   7.085
_cell_length_c   5.176
_cell_angle_alpha   69.646
_cell_angle_beta   69.646
_cell_angle_gamma   109.010
_symmetry_Int_Tables_number   1
_cell_volume   196.673
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.662  0.338  0.250  1.0
  K  K1  1  0.338  0.662  0.750  1.0
  Te  Te2  1  0.924  0.076  0.750  1.0
  Te  Te3  1  0.076  0.924  0.250  1.0
  O  O4  1  0.787  0.888  0.222  1.0
  O  O5  1  0.112  0.213  0.278  1.0
  O  O6  1  0.213  0.112  0.778  1.0
  O  O7  1  0.888  0.787  0.722  1.0
  O  O8  1  0.627  0.001  0.784  1.0
  O  O9  1  0.999  0.373  0.716  1.0
  O  O10  1  0.373  0.999  0.216  1.0
  O  O11  1  0.001  0.627  0.284  1.0
[/CIF]
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