The material structure described by LiSb(PO3)4 crystallizes in the monoclinic P2_1 space group. Li(1) is bonded in a distorted rectangular see-saw-like geometry to one O(10), one O(11), one O(4), and one O(9) atom. Sb(1) is bonded in a 6-coordinate geometry to one O(10), one O(11), one O(2), one O(4), one O(5), and one O(8) atom. There are four inequivalent P sites. In the first P site, P(1) is bonded to one O(5), one O(6), one O(7), and one O(8) atom to form corner-sharing PO4 tetrahedra. In the second P site, P(2) is bonded to one O(1), one O(4), one O(7), and one O(9) atom to form corner-sharing PO4 tetrahedra. In the third P site, P(3) is bonded to one O(1), one O(10), one O(11), and one O(12) atom to form corner-sharing PO4 tetrahedra. In the fourth P site, P(4) is bonded to one O(12), one O(2), one O(3), and one O(6) atom to form corner-sharing PO4 tetrahedra. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one P(2) and one P(3) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Sb(1) and one P(4) atom. In the third O site, O(3) is bonded in a single-bond geometry to one P(4) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Li(1), one Sb(1), and one P(2) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Sb(1) and one P(1) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one P(1) and one P(4) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one Sb(1) and one P(1) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Li(1) and one P(2) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Li(1), one Sb(1), and one P(3) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one Li(1), one Sb(1), and one P(3) atom. In the twelfth O site, O(12) is bonded in a bent 150 degrees geometry to one P(3) and one P(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiSb(PO3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.607
_cell_length_b   7.072
_cell_length_c   7.856
_cell_angle_alpha   88.908
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   478.067
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.404  0.713  0.652  1.0
  Li  Li1  1  0.904  0.287  0.348  1.0
  Sb  Sb2  1  0.228  0.241  0.771  1.0
  Sb  Sb3  1  0.728  0.759  0.229  1.0
  P  P4  1  0.874  0.434  0.906  1.0
  P  P5  1  0.009  0.607  0.593  1.0
  P  P6  1  0.398  0.991  0.396  1.0
  P  P7  1  0.898  0.009  0.604  1.0
  P  P8  1  0.374  0.566  0.094  1.0
  P  P9  1  0.173  0.913  0.107  1.0
  P  P10  1  0.673  0.087  0.893  1.0
  P  P11  1  0.509  0.393  0.407  1.0
  O  O12  1  0.008  0.830  0.623  1.0
  O  O13  1  0.700  0.021  0.075  1.0
  O  O14  1  0.519  0.062  0.810  1.0
  O  O15  1  0.665  0.455  0.340  1.0
  O  O16  1  0.019  0.938  0.190  1.0
  O  O17  1  0.347  0.423  0.959  1.0
  O  O18  1  0.847  0.577  0.041  1.0
  O  O19  1  0.165  0.545  0.660  1.0
  O  O20  1  0.720  0.310  0.886  1.0
  O  O21  1  0.372  0.462  0.277  1.0
  O  O22  1  0.518  0.686  0.069  1.0
  O  O23  1  0.200  0.979  0.925  1.0
  O  O24  1  0.460  0.440  0.584  1.0
  O  O25  1  0.501  0.817  0.403  1.0
  O  O26  1  0.220  0.690  0.114  1.0
  O  O27  1  0.872  0.538  0.723  1.0
  O  O28  1  0.291  1.000  0.546  1.0
  O  O29  1  0.791  0.000  0.454  1.0
  O  O30  1  0.810  0.989  0.783  1.0
  O  O31  1  0.310  0.011  0.217  1.0
  O  O32  1  0.018  0.314  0.931  1.0
  O  O33  1  0.508  0.170  0.377  1.0
  O  O34  1  0.001  0.183  0.597  1.0
  O  O35  1  0.960  0.560  0.416  1.0
[/CIF]
.
The material structure described by LiSb(PO3)4 crystallizes in the monoclinic P2_1 space group. Li(1) is bonded in a distorted rectangular see-saw-like geometry to one O(10), one O(11), one O(4), and one O(9) atom. Sb(1) is bonded in a 6-coordinate geometry to one O(10), one O(11), one O(2), one O(4), one O(5), and one O(8) atom. There are four inequivalent P sites. In the first P site, P(1) is bonded to one O(5), one O(6), one O(7), and one O(8) atom to form corner-sharing PO4 tetrahedra. In the second P site, P(2) is bonded to one O(1), one O(4), one O(7), and one O(9) atom to form corner-sharing PO4 tetrahedra. In the third P site, P(3) is bonded to one O(1), one O(10), one O(11), and one O(12) atom to form corner-sharing PO4 tetrahedra. In the fourth P site, P(4) is bonded to one O(12), one O(2), one O(3), and one O(6) atom to form corner-sharing PO4 tetrahedra. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one P(2) and one P(3) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Sb(1) and one P(4) atom. In the third O site, O(3) is bonded in a single-bond geometry to one P(4) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Li(1), one Sb(1), and one P(2) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Sb(1) and one P(1) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one P(1) and one P(4) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one Sb(1) and one P(1) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Li(1) and one P(2) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Li(1), one Sb(1), and one P(3) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one Li(1), one Sb(1), and one P(3) atom. In the twelfth O site, O(12) is bonded in a bent 150 degrees geometry to one P(3) and one P(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiSb(PO3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.607
_cell_length_b   7.072
_cell_length_c   7.856
_cell_angle_alpha   88.908
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   478.067
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.404  0.713  0.652  1.0
  Li  Li1  1  0.904  0.287  0.348  1.0
  Sb  Sb2  1  0.228  0.241  0.771  1.0
  Sb  Sb3  1  0.728  0.759  0.229  1.0
  P  P4  1  0.874  0.434  0.906  1.0
  P  P5  1  0.009  0.607  0.593  1.0
  P  P6  1  0.398  0.991  0.396  1.0
  P  P7  1  0.898  0.009  0.604  1.0
  P  P8  1  0.374  0.566  0.094  1.0
  P  P9  1  0.173  0.913  0.107  1.0
  P  P10  1  0.673  0.087  0.893  1.0
  P  P11  1  0.509  0.393  0.407  1.0
  O  O12  1  0.008  0.830  0.623  1.0
  O  O13  1  0.700  0.021  0.075  1.0
  O  O14  1  0.519  0.062  0.810  1.0
  O  O15  1  0.665  0.455  0.340  1.0
  O  O16  1  0.019  0.938  0.190  1.0
  O  O17  1  0.347  0.423  0.959  1.0
  O  O18  1  0.847  0.577  0.041  1.0
  O  O19  1  0.165  0.545  0.660  1.0
  O  O20  1  0.720  0.310  0.886  1.0
  O  O21  1  0.372  0.462  0.277  1.0
  O  O22  1  0.518  0.686  0.069  1.0
  O  O23  1  0.200  0.979  0.925  1.0
  O  O24  1  0.460  0.440  0.584  1.0
  O  O25  1  0.501  0.817  0.403  1.0
  O  O26  1  0.220  0.690  0.114  1.0
  O  O27  1  0.872  0.538  0.723  1.0
  O  O28  1  0.291  1.000  0.546  1.0
  O  O29  1  0.791  0.000  0.454  1.0
  O  O30  1  0.810  0.989  0.783  1.0
  O  O31  1  0.310  0.011  0.217  1.0
  O  O32  1  0.018  0.314  0.931  1.0
  O  O33  1  0.508  0.170  0.377  1.0
  O  O34  1  0.001  0.183  0.597  1.0
  O  O35  1  0.960  0.560  0.416  1.0
[/CIF]
.