The crystal structure described by MnP2HO8 crystallizes in the monoclinic P2_1/c space group. Mn(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms. P(1) is bonded in a trigonal planar geometry to one O(2), one O(3), and one O(4) atom. H(1) is bonded in a linear geometry to two equivalent O(2) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Mn(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one P(1) and one H(1) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Mn(1) and one P(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Mn(1) and one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_MnP2HO8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.746
_cell_length_b   7.861
_cell_length_c   10.530
_cell_angle_alpha   56.504
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   396.646
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.000  0.000  0.000  1.0
  Mn  Mn1  1  0.500  0.000  0.500  1.0
  P  P2  1  0.238  0.238  0.162  1.0
  P  P3  1  0.762  0.762  0.838  1.0
  P  P4  1  0.738  0.762  0.338  1.0
  P  P5  1  0.262  0.238  0.662  1.0
  H  H6  1  0.000  0.500  0.500  1.0
  H  H7  1  0.500  0.500  0.000  1.0
  O  O8  1  0.780  0.170  0.932  1.0
  O  O9  1  0.220  0.830  0.068  1.0
  O  O10  1  0.280  0.830  0.568  1.0
  O  O11  1  0.720  0.170  0.432  1.0
  O  O12  1  0.321  0.415  0.010  1.0
  O  O13  1  0.679  0.585  0.990  1.0
  O  O14  1  0.821  0.585  0.490  1.0
  O  O15  1  0.179  0.415  0.510  1.0
  O  O16  1  0.092  0.082  0.162  1.0
  O  O17  1  0.908  0.918  0.838  1.0
  O  O18  1  0.592  0.918  0.338  1.0
  O  O19  1  0.408  0.082  0.662  1.0
  O  O20  1  0.206  0.231  0.803  1.0
  O  O21  1  0.794  0.769  0.197  1.0
  O  O22  1  0.706  0.769  0.697  1.0
  O  O23  1  0.294  0.231  0.303  1.0
[/CIF]
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The crystal structure described by MnP2HO8 crystallizes in the monoclinic P2_1/c space group. Mn(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms. P(1) is bonded in a trigonal planar geometry to one O(2), one O(3), and one O(4) atom. H(1) is bonded in a linear geometry to two equivalent O(2) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Mn(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one P(1) and one H(1) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Mn(1) and one P(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Mn(1) and one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_MnP2HO8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.746
_cell_length_b   7.861
_cell_length_c   10.530
_cell_angle_alpha   56.504
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   396.646
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.000  0.000  0.000  1.0
  Mn  Mn1  1  0.500  0.000  0.500  1.0
  P  P2  1  0.238  0.238  0.162  1.0
  P  P3  1  0.762  0.762  0.838  1.0
  P  P4  1  0.738  0.762  0.338  1.0
  P  P5  1  0.262  0.238  0.662  1.0
  H  H6  1  0.000  0.500  0.500  1.0
  H  H7  1  0.500  0.500  0.000  1.0
  O  O8  1  0.780  0.170  0.932  1.0
  O  O9  1  0.220  0.830  0.068  1.0
  O  O10  1  0.280  0.830  0.568  1.0
  O  O11  1  0.720  0.170  0.432  1.0
  O  O12  1  0.321  0.415  0.010  1.0
  O  O13  1  0.679  0.585  0.990  1.0
  O  O14  1  0.821  0.585  0.490  1.0
  O  O15  1  0.179  0.415  0.510  1.0
  O  O16  1  0.092  0.082  0.162  1.0
  O  O17  1  0.908  0.918  0.838  1.0
  O  O18  1  0.592  0.918  0.338  1.0
  O  O19  1  0.408  0.082  0.662  1.0
  O  O20  1  0.206  0.231  0.803  1.0
  O  O21  1  0.794  0.769  0.197  1.0
  O  O22  1  0.706  0.769  0.697  1.0
  O  O23  1  0.294  0.231  0.303  1.0
[/CIF]
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