The compound described by KInBP2HO9 crystallizes in the triclinic P-1 space group. K(1) is bonded in a 10-coordinate geometry to one O(5), one O(7), one O(8), one O(9), two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms. In(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(9) atom to form InO6 octahedra that share  a cornercorner with one B(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, and corners with three equivalent P(1)O4 tetrahedra. B(1) is bonded to one O(2), one O(6), one O(7), and one O(8) atom to form BO4 tetrahedra that share  a cornercorner with one In(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra, and corners with two equivalent P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 49°. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(5), one O(7), and one O(9) atom to form PO4 tetrahedra that share corners with three equivalent In(1)O6 octahedra and  a cornercorner with one B(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 41-51°. In the second P site, P(2) is bonded to one O(3), one O(4), one O(6), and one O(8) atom to form PO4 tetrahedra that share corners with two equivalent In(1)O6 octahedra and corners with two equivalent B(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 40-56°. H(1) is bonded in a single-bond geometry to one O(2) atom. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to two equivalent K(1), one In(1), and one P(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one In(1), one B(1), and one H(1) atom. In the third O site, O(3) is bonded in a 1-coordinate geometry to two equivalent K(1), one In(1), and one P(2) atom. In the fourth O site, O(4) is bonded in a 2-coordinate geometry to two equivalent K(1), one In(1), and one P(2) atom. In the fifth O site, O(5) is bonded in a 2-coordinate geometry to one K(1), one In(1), and one P(1) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one B(1) and one P(2) atom. In the seventh O site, O(7) is bonded in a distorted bent 120 degrees geometry to one K(1), one B(1), and one P(1) atom. In the eighth O site, O(8) is bonded in a 2-coordinate geometry to one K(1), one B(1), and one P(2) atom. In the ninth O site, O(9) is bonded in a 2-coordinate geometry to one K(1), one In(1), and one P(1) atom. is represented by the CIF file [CIF]
data_KInBP2HO9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.275
_cell_length_b   8.279
_cell_length_c   8.388
_cell_angle_alpha   89.003
_cell_angle_beta   79.793
_cell_angle_gamma   87.242
_symmetry_Int_Tables_number   1
_cell_volume   360.094
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.279  0.176  0.885  1.0
  K  K1  1  0.721  0.824  0.115  1.0
  In  In2  1  0.279  0.694  0.797  1.0
  In  In3  1  0.721  0.306  0.203  1.0
  B  B4  1  0.102  0.767  0.440  1.0
  B  B5  1  0.898  0.233  0.560  1.0
  P  P6  1  0.217  0.563  0.189  1.0
  P  P7  1  0.783  0.437  0.811  1.0
  P  P8  1  0.805  0.926  0.699  1.0
  P  P9  1  0.195  0.074  0.301  1.0
  H  H10  1  0.403  0.617  0.471  1.0
  H  H11  1  0.597  0.383  0.529  1.0
  O  O12  1  0.279  0.683  0.050  1.0
  O  O13  1  0.721  0.317  0.950  1.0
  O  O14  1  0.274  0.686  0.539  1.0
  O  O15  1  0.726  0.314  0.461  1.0
  O  O16  1  0.030  0.913  0.791  1.0
  O  O17  1  0.970  0.087  0.209  1.0
  O  O18  1  0.557  0.871  0.800  1.0
  O  O19  1  0.443  0.129  0.200  1.0
  O  O20  1  0.915  0.583  0.857  1.0
  O  O21  1  0.085  0.417  0.143  1.0
  O  O22  1  0.866  0.829  0.540  1.0
  O  O23  1  0.134  0.171  0.460  1.0
  O  O24  1  0.027  0.653  0.328  1.0
  O  O25  1  0.973  0.347  0.672  1.0
  O  O26  1  0.748  0.105  0.655  1.0
  O  O27  1  0.252  0.895  0.345  1.0
  O  O28  1  0.465  0.516  0.256  1.0
  O  O29  1  0.535  0.484  0.744  1.0
[/CIF]
.
The compound described by KInBP2HO9 crystallizes in the triclinic P-1 space group. K(1) is bonded in a 10-coordinate geometry to one O(5), one O(7), one O(8), one O(9), two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms. In(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(9) atom to form InO6 octahedra that share  a cornercorner with one B(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, and corners with three equivalent P(1)O4 tetrahedra. B(1) is bonded to one O(2), one O(6), one O(7), and one O(8) atom to form BO4 tetrahedra that share  a cornercorner with one In(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra, and corners with two equivalent P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 49°. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(5), one O(7), and one O(9) atom to form PO4 tetrahedra that share corners with three equivalent In(1)O6 octahedra and  a cornercorner with one B(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 41-51°. In the second P site, P(2) is bonded to one O(3), one O(4), one O(6), and one O(8) atom to form PO4 tetrahedra that share corners with two equivalent In(1)O6 octahedra and corners with two equivalent B(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 40-56°. H(1) is bonded in a single-bond geometry to one O(2) atom. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to two equivalent K(1), one In(1), and one P(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one In(1), one B(1), and one H(1) atom. In the third O site, O(3) is bonded in a 1-coordinate geometry to two equivalent K(1), one In(1), and one P(2) atom. In the fourth O site, O(4) is bonded in a 2-coordinate geometry to two equivalent K(1), one In(1), and one P(2) atom. In the fifth O site, O(5) is bonded in a 2-coordinate geometry to one K(1), one In(1), and one P(1) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one B(1) and one P(2) atom. In the seventh O site, O(7) is bonded in a distorted bent 120 degrees geometry to one K(1), one B(1), and one P(1) atom. In the eighth O site, O(8) is bonded in a 2-coordinate geometry to one K(1), one B(1), and one P(2) atom. In the ninth O site, O(9) is bonded in a 2-coordinate geometry to one K(1), one In(1), and one P(1) atom. is represented by the CIF file [CIF]
data_KInBP2HO9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.275
_cell_length_b   8.279
_cell_length_c   8.388
_cell_angle_alpha   89.003
_cell_angle_beta   79.793
_cell_angle_gamma   87.242
_symmetry_Int_Tables_number   1
_cell_volume   360.094
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.279  0.176  0.885  1.0
  K  K1  1  0.721  0.824  0.115  1.0
  In  In2  1  0.279  0.694  0.797  1.0
  In  In3  1  0.721  0.306  0.203  1.0
  B  B4  1  0.102  0.767  0.440  1.0
  B  B5  1  0.898  0.233  0.560  1.0
  P  P6  1  0.217  0.563  0.189  1.0
  P  P7  1  0.783  0.437  0.811  1.0
  P  P8  1  0.805  0.926  0.699  1.0
  P  P9  1  0.195  0.074  0.301  1.0
  H  H10  1  0.403  0.617  0.471  1.0
  H  H11  1  0.597  0.383  0.529  1.0
  O  O12  1  0.279  0.683  0.050  1.0
  O  O13  1  0.721  0.317  0.950  1.0
  O  O14  1  0.274  0.686  0.539  1.0
  O  O15  1  0.726  0.314  0.461  1.0
  O  O16  1  0.030  0.913  0.791  1.0
  O  O17  1  0.970  0.087  0.209  1.0
  O  O18  1  0.557  0.871  0.800  1.0
  O  O19  1  0.443  0.129  0.200  1.0
  O  O20  1  0.915  0.583  0.857  1.0
  O  O21  1  0.085  0.417  0.143  1.0
  O  O22  1  0.866  0.829  0.540  1.0
  O  O23  1  0.134  0.171  0.460  1.0
  O  O24  1  0.027  0.653  0.328  1.0
  O  O25  1  0.973  0.347  0.672  1.0
  O  O26  1  0.748  0.105  0.655  1.0
  O  O27  1  0.252  0.895  0.345  1.0
  O  O28  1  0.465  0.516  0.256  1.0
  O  O29  1  0.535  0.484  0.744  1.0
[/CIF]
.