The compound described by LaSrInO4 crystallizes in the orthorhombic Pca2_1 space group. Sr(1) is bonded in a 6-coordinate geometry to one O(1), one O(4), two equivalent O(2), and two equivalent O(3) atoms. La(1) is bonded in a 6-coordinate geometry to one O(2), one O(3), two equivalent O(1), and two equivalent O(4) atoms. In(1) is bonded to one O(3), one O(4), two equivalent O(1), and two equivalent O(2) atoms to form corner-sharing InO6 octahedra. The corner-sharing octahedral tilt angles range from 24-29°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to one Sr(1), two equivalent La(1), and two equivalent In(1) atoms. In the second O site, O(2) is bonded to two equivalent Sr(1), one La(1), and two equivalent In(1) atoms to form distorted OSr2LaIn2 trigonal bipyramids that share corners with two equivalent O(4)SrLa2In tetrahedra, corners with five equivalent O(3)Sr2LaIn tetrahedra,  an edgeedge with one O(3)Sr2LaIn tetrahedra, edges with two equivalent O(4)SrLa2In tetrahedra, and edges with two equivalent O(2)Sr2LaIn2 trigonal bipyramids. In the third O site, O(3) is bonded to two equivalent Sr(1), one La(1), and one In(1) atom to form OSr2LaIn tetrahedra that share corners with two equivalent O(3)Sr2LaIn tetrahedra, corners with five equivalent O(4)SrLa2In tetrahedra, corners with five equivalent O(2)Sr2LaIn2 trigonal bipyramids, and  an edgeedge with one O(2)Sr2LaIn2 trigonal bipyramid. In the fourth O site, O(4) is bonded to one Sr(1), two equivalent La(1), and one In(1) atom to form distorted OSrLa2In tetrahedra that share corners with two equivalent O(4)SrLa2In tetrahedra, corners with five equivalent O(3)Sr2LaIn tetrahedra, corners with two equivalent O(2)Sr2LaIn2 trigonal bipyramids, and edges with two equivalent O(2)Sr2LaIn2 trigonal bipyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_SrLaInO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.982
_cell_length_b   5.991
_cell_length_c   12.539
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   449.351
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.469  0.014  0.353  1.0
  Sr  Sr1  1  0.031  0.514  0.647  1.0
  Sr  Sr2  1  0.469  0.514  0.147  1.0
  Sr  Sr3  1  0.031  0.014  0.853  1.0
  La  La4  1  0.549  0.486  0.854  1.0
  La  La5  1  0.951  0.986  0.146  1.0
  La  La6  1  0.549  0.986  0.646  1.0
  La  La7  1  0.951  0.486  0.354  1.0
  In  In8  1  0.496  0.998  0.001  1.0
  In  In9  1  0.496  0.498  0.499  1.0
  In  In10  1  0.004  0.498  0.999  1.0
  In  In11  1  0.004  0.998  0.501  1.0
  O  O12  1  0.721  0.779  0.470  1.0
  O  O13  1  0.290  0.707  0.966  1.0
  O  O14  1  0.779  0.279  0.530  1.0
  O  O15  1  0.210  0.207  0.034  1.0
  O  O16  1  0.290  0.207  0.534  1.0
  O  O17  1  0.721  0.279  0.030  1.0
  O  O18  1  0.210  0.707  0.466  1.0
  O  O19  1  0.779  0.779  0.970  1.0
  O  O20  1  0.563  0.919  0.172  1.0
  O  O21  1  0.470  0.597  0.677  1.0
  O  O22  1  0.937  0.419  0.828  1.0
  O  O23  1  0.030  0.097  0.323  1.0
  O  O24  1  0.470  0.097  0.823  1.0
  O  O25  1  0.563  0.419  0.328  1.0
  O  O26  1  0.030  0.597  0.177  1.0
  O  O27  1  0.937  0.919  0.672  1.0
[/CIF]
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The compound described by LaSrInO4 crystallizes in the orthorhombic Pca2_1 space group. Sr(1) is bonded in a 6-coordinate geometry to one O(1), one O(4), two equivalent O(2), and two equivalent O(3) atoms. La(1) is bonded in a 6-coordinate geometry to one O(2), one O(3), two equivalent O(1), and two equivalent O(4) atoms. In(1) is bonded to one O(3), one O(4), two equivalent O(1), and two equivalent O(2) atoms to form corner-sharing InO6 octahedra. The corner-sharing octahedral tilt angles range from 24-29°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to one Sr(1), two equivalent La(1), and two equivalent In(1) atoms. In the second O site, O(2) is bonded to two equivalent Sr(1), one La(1), and two equivalent In(1) atoms to form distorted OSr2LaIn2 trigonal bipyramids that share corners with two equivalent O(4)SrLa2In tetrahedra, corners with five equivalent O(3)Sr2LaIn tetrahedra,  an edgeedge with one O(3)Sr2LaIn tetrahedra, edges with two equivalent O(4)SrLa2In tetrahedra, and edges with two equivalent O(2)Sr2LaIn2 trigonal bipyramids. In the third O site, O(3) is bonded to two equivalent Sr(1), one La(1), and one In(1) atom to form OSr2LaIn tetrahedra that share corners with two equivalent O(3)Sr2LaIn tetrahedra, corners with five equivalent O(4)SrLa2In tetrahedra, corners with five equivalent O(2)Sr2LaIn2 trigonal bipyramids, and  an edgeedge with one O(2)Sr2LaIn2 trigonal bipyramid. In the fourth O site, O(4) is bonded to one Sr(1), two equivalent La(1), and one In(1) atom to form distorted OSrLa2In tetrahedra that share corners with two equivalent O(4)SrLa2In tetrahedra, corners with five equivalent O(3)Sr2LaIn tetrahedra, corners with two equivalent O(2)Sr2LaIn2 trigonal bipyramids, and edges with two equivalent O(2)Sr2LaIn2 trigonal bipyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_SrLaInO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.982
_cell_length_b   5.991
_cell_length_c   12.539
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   449.351
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.469  0.014  0.353  1.0
  Sr  Sr1  1  0.031  0.514  0.647  1.0
  Sr  Sr2  1  0.469  0.514  0.147  1.0
  Sr  Sr3  1  0.031  0.014  0.853  1.0
  La  La4  1  0.549  0.486  0.854  1.0
  La  La5  1  0.951  0.986  0.146  1.0
  La  La6  1  0.549  0.986  0.646  1.0
  La  La7  1  0.951  0.486  0.354  1.0
  In  In8  1  0.496  0.998  0.001  1.0
  In  In9  1  0.496  0.498  0.499  1.0
  In  In10  1  0.004  0.498  0.999  1.0
  In  In11  1  0.004  0.998  0.501  1.0
  O  O12  1  0.721  0.779  0.470  1.0
  O  O13  1  0.290  0.707  0.966  1.0
  O  O14  1  0.779  0.279  0.530  1.0
  O  O15  1  0.210  0.207  0.034  1.0
  O  O16  1  0.290  0.207  0.534  1.0
  O  O17  1  0.721  0.279  0.030  1.0
  O  O18  1  0.210  0.707  0.466  1.0
  O  O19  1  0.779  0.779  0.970  1.0
  O  O20  1  0.563  0.919  0.172  1.0
  O  O21  1  0.470  0.597  0.677  1.0
  O  O22  1  0.937  0.419  0.828  1.0
  O  O23  1  0.030  0.097  0.323  1.0
  O  O24  1  0.470  0.097  0.823  1.0
  O  O25  1  0.563  0.419  0.328  1.0
  O  O26  1  0.030  0.597  0.177  1.0
  O  O27  1  0.937  0.919  0.672  1.0
[/CIF]
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