The compound described by (NS)2SO3F is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two 293-40-3 molecules and four SO3F clusters. In each SO3F cluster, S(3) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one F(1) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(3) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(3) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(3) atom. F(1) is bonded in a single-bond geometry to one S(3) atom. is represented by the CIF file [CIF]
data_S3N2O3F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.319
_cell_length_b   7.219
_cell_length_c   13.973
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   108.443
_symmetry_Int_Tables_number   1
_cell_volume   604.648
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  S  S0  1  0.785  0.558  0.392  1.0
  S  S1  1  0.215  0.942  0.892  1.0
  S  S2  1  0.215  0.442  0.608  1.0
  S  S3  1  0.785  0.058  0.108  1.0
  S  S4  1  0.010  0.249  0.422  1.0
  S  S5  1  0.990  0.251  0.922  1.0
  S  S6  1  0.990  0.751  0.578  1.0
  S  S7  1  0.010  0.749  0.078  1.0
  S  S8  1  0.395  0.347  0.155  1.0
  S  S9  1  0.605  0.153  0.655  1.0
  S  S10  1  0.605  0.653  0.845  1.0
  S  S11  1  0.395  0.847  0.345  1.0
  N  N12  1  0.140  0.306  0.519  1.0
  N  N13  1  0.860  0.194  0.019  1.0
  N  N14  1  0.860  0.694  0.481  1.0
  N  N15  1  0.140  0.806  0.981  1.0
  N  N16  1  0.870  0.377  0.384  1.0
  N  N17  1  0.130  0.123  0.884  1.0
  N  N18  1  0.130  0.623  0.616  1.0
  N  N19  1  0.870  0.877  0.116  1.0
  O  O20  1  0.628  0.416  0.183  1.0
  O  O21  1  0.372  0.084  0.683  1.0
  O  O22  1  0.372  0.584  0.817  1.0
  O  O23  1  0.628  0.916  0.317  1.0
  O  O24  1  0.339  0.189  0.085  1.0
  O  O25  1  0.661  0.311  0.585  1.0
  O  O26  1  0.661  0.811  0.915  1.0
  O  O27  1  0.339  0.689  0.415  1.0
  O  O28  1  0.231  0.329  0.230  1.0
  O  O29  1  0.769  0.171  0.730  1.0
  O  O30  1  0.769  0.671  0.770  1.0
  O  O31  1  0.231  0.829  0.270  1.0
  F  F32  1  0.369  0.531  0.091  1.0
  F  F33  1  0.631  0.969  0.591  1.0
  F  F34  1  0.631  0.469  0.909  1.0
  F  F35  1  0.369  0.031  0.409  1.0
[/CIF]
.
The compound described by (NS)2SO3F is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two 293-40-3 molecules and four SO3F clusters. In each SO3F cluster, S(3) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one F(1) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(3) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(3) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(3) atom. F(1) is bonded in a single-bond geometry to one S(3) atom. is represented by the CIF file [CIF]
data_S3N2O3F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.319
_cell_length_b   7.219
_cell_length_c   13.973
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   108.443
_symmetry_Int_Tables_number   1
_cell_volume   604.648
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  S  S0  1  0.785  0.558  0.392  1.0
  S  S1  1  0.215  0.942  0.892  1.0
  S  S2  1  0.215  0.442  0.608  1.0
  S  S3  1  0.785  0.058  0.108  1.0
  S  S4  1  0.010  0.249  0.422  1.0
  S  S5  1  0.990  0.251  0.922  1.0
  S  S6  1  0.990  0.751  0.578  1.0
  S  S7  1  0.010  0.749  0.078  1.0
  S  S8  1  0.395  0.347  0.155  1.0
  S  S9  1  0.605  0.153  0.655  1.0
  S  S10  1  0.605  0.653  0.845  1.0
  S  S11  1  0.395  0.847  0.345  1.0
  N  N12  1  0.140  0.306  0.519  1.0
  N  N13  1  0.860  0.194  0.019  1.0
  N  N14  1  0.860  0.694  0.481  1.0
  N  N15  1  0.140  0.806  0.981  1.0
  N  N16  1  0.870  0.377  0.384  1.0
  N  N17  1  0.130  0.123  0.884  1.0
  N  N18  1  0.130  0.623  0.616  1.0
  N  N19  1  0.870  0.877  0.116  1.0
  O  O20  1  0.628  0.416  0.183  1.0
  O  O21  1  0.372  0.084  0.683  1.0
  O  O22  1  0.372  0.584  0.817  1.0
  O  O23  1  0.628  0.916  0.317  1.0
  O  O24  1  0.339  0.189  0.085  1.0
  O  O25  1  0.661  0.311  0.585  1.0
  O  O26  1  0.661  0.811  0.915  1.0
  O  O27  1  0.339  0.689  0.415  1.0
  O  O28  1  0.231  0.329  0.230  1.0
  O  O29  1  0.769  0.171  0.730  1.0
  O  O30  1  0.769  0.671  0.770  1.0
  O  O31  1  0.231  0.829  0.270  1.0
  F  F32  1  0.369  0.531  0.091  1.0
  F  F33  1  0.631  0.969  0.591  1.0
  F  F34  1  0.631  0.469  0.909  1.0
  F  F35  1  0.369  0.031  0.409  1.0
[/CIF]
.