The structure described by Cs2Pd3P4O14 crystallizes in the orthorhombic Cmc2_1 space group. There are two inequivalent Cs sites. In the first Cs site, Cs(1) is bonded in a 10-coordinate geometry to two equivalent O(3), two equivalent O(4), two equivalent O(6), two equivalent O(7), and two equivalent O(8) atoms. In the second Cs site, Cs(2) is bonded in a 6-coordinate geometry to one O(1), one O(5), two equivalent O(2), and two equivalent O(7) atoms. There are three inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a square co-planar geometry to two equivalent O(4) and two equivalent O(8) atoms. In the second Pd site, Pd(2) is bonded in a rectangular see-saw-like geometry to two equivalent O(3) and two equivalent O(6) atoms. In the third Pd site, Pd(3) is bonded in a square co-planar geometry to two equivalent O(2) and two equivalent O(7) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form corner-sharing PO4 tetrahedra. In the second P site, P(2) is bonded to one O(5), one O(6), one O(7), and one O(8) atom to form corner-sharing PO4 tetrahedra. There are eight inequivalent O sites. In the first O site, O(7) is bonded in a 2-coordinate geometry to one Cs(1), one Cs(2), one Pd(3), and one P(2) atom. In the second O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Cs(2) and two equivalent P(1) atoms. In the third O site, O(2) is bonded in a 2-coordinate geometry to one Cs(2), one Pd(3), and one P(1) atom. In the fourth O site, O(3) is bonded in a 2-coordinate geometry to one Cs(1), one Pd(2), and one P(1) atom. In the fifth O site, O(4) is bonded in a 2-coordinate geometry to one Cs(1), one Pd(1), and one P(1) atom. In the sixth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Cs(1), one Pd(1), and one P(2) atom. In the seventh O site, O(5) is bonded in a bent 120 degrees geometry to one Cs(2) and two equivalent P(2) atoms. In the eighth O site, O(6) is bonded in a 2-coordinate geometry to one Cs(1), one Pd(2), and one P(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Cs2P4Pd3O14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.294
_cell_length_b   8.294
_cell_length_c   14.636
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   124.337
_symmetry_Int_Tables_number   1
_cell_volume   831.354
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.933  0.067  0.090  1.0
  Cs  Cs1  1  0.067  0.933  0.590  1.0
  Cs  Cs2  1  0.782  0.218  0.825  1.0
  Cs  Cs3  1  0.218  0.782  0.325  1.0
  P  P4  1  0.303  0.328  0.295  1.0
  P  P5  1  0.672  0.697  0.295  1.0
  P  P6  1  0.697  0.672  0.795  1.0
  P  P7  1  0.328  0.303  0.795  1.0
  P  P8  1  0.598  0.032  0.551  1.0
  P  P9  1  0.968  0.402  0.551  1.0
  P  P10  1  0.402  0.968  0.051  1.0
  P  P11  1  0.032  0.598  0.051  1.0
  Pd  Pd12  1  0.889  0.111  0.396  1.0
  Pd  Pd13  1  0.111  0.889  0.896  1.0
  Pd  Pd14  1  0.621  0.379  0.162  1.0
  Pd  Pd15  1  0.379  0.621  0.662  1.0
  Pd  Pd16  1  0.626  0.374  0.434  1.0
  Pd  Pd17  1  0.374  0.626  0.934  1.0
  O  O18  1  0.434  0.566  0.303  1.0
  O  O19  1  0.566  0.434  0.803  1.0
  O  O20  1  0.357  0.248  0.375  1.0
  O  O21  1  0.752  0.643  0.375  1.0
  O  O22  1  0.643  0.752  0.875  1.0
  O  O23  1  0.248  0.357  0.875  1.0
  O  O24  1  0.342  0.277  0.199  1.0
  O  O25  1  0.723  0.658  0.199  1.0
  O  O26  1  0.658  0.723  0.699  1.0
  O  O27  1  0.277  0.342  0.699  1.0
  O  O28  1  0.091  0.268  0.296  1.0
  O  O29  1  0.732  0.909  0.296  1.0
  O  O30  1  0.909  0.732  0.796  1.0
  O  O31  1  0.268  0.091  0.796  1.0
  O  O32  1  0.781  0.219  0.606  1.0
  O  O33  1  0.219  0.781  0.106  1.0
  O  O34  1  0.462  0.895  0.626  1.0
  O  O35  1  0.105  0.538  0.626  1.0
  O  O36  1  0.538  0.105  0.126  1.0
  O  O37  1  0.895  0.462  0.126  1.0
  O  O38  1  0.494  0.109  0.497  1.0
  O  O39  1  0.891  0.506  0.497  1.0
  O  O40  1  0.506  0.891  0.997  1.0
  O  O41  1  0.109  0.494  0.997  1.0
  O  O42  1  0.681  0.943  0.491  1.0
  O  O43  1  0.057  0.319  0.491  1.0
  O  O44  1  0.319  0.057  0.991  1.0
  O  O45  1  0.943  0.681  0.991  1.0
[/CIF]
.
The structure described by Cs2Pd3P4O14 crystallizes in the orthorhombic Cmc2_1 space group. There are two inequivalent Cs sites. In the first Cs site, Cs(1) is bonded in a 10-coordinate geometry to two equivalent O(3), two equivalent O(4), two equivalent O(6), two equivalent O(7), and two equivalent O(8) atoms. In the second Cs site, Cs(2) is bonded in a 6-coordinate geometry to one O(1), one O(5), two equivalent O(2), and two equivalent O(7) atoms. There are three inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a square co-planar geometry to two equivalent O(4) and two equivalent O(8) atoms. In the second Pd site, Pd(2) is bonded in a rectangular see-saw-like geometry to two equivalent O(3) and two equivalent O(6) atoms. In the third Pd site, Pd(3) is bonded in a square co-planar geometry to two equivalent O(2) and two equivalent O(7) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form corner-sharing PO4 tetrahedra. In the second P site, P(2) is bonded to one O(5), one O(6), one O(7), and one O(8) atom to form corner-sharing PO4 tetrahedra. There are eight inequivalent O sites. In the first O site, O(7) is bonded in a 2-coordinate geometry to one Cs(1), one Cs(2), one Pd(3), and one P(2) atom. In the second O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Cs(2) and two equivalent P(1) atoms. In the third O site, O(2) is bonded in a 2-coordinate geometry to one Cs(2), one Pd(3), and one P(1) atom. In the fourth O site, O(3) is bonded in a 2-coordinate geometry to one Cs(1), one Pd(2), and one P(1) atom. In the fifth O site, O(4) is bonded in a 2-coordinate geometry to one Cs(1), one Pd(1), and one P(1) atom. In the sixth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Cs(1), one Pd(1), and one P(2) atom. In the seventh O site, O(5) is bonded in a bent 120 degrees geometry to one Cs(2) and two equivalent P(2) atoms. In the eighth O site, O(6) is bonded in a 2-coordinate geometry to one Cs(1), one Pd(2), and one P(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Cs2P4Pd3O14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.294
_cell_length_b   8.294
_cell_length_c   14.636
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   124.337
_symmetry_Int_Tables_number   1
_cell_volume   831.354
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.933  0.067  0.090  1.0
  Cs  Cs1  1  0.067  0.933  0.590  1.0
  Cs  Cs2  1  0.782  0.218  0.825  1.0
  Cs  Cs3  1  0.218  0.782  0.325  1.0
  P  P4  1  0.303  0.328  0.295  1.0
  P  P5  1  0.672  0.697  0.295  1.0
  P  P6  1  0.697  0.672  0.795  1.0
  P  P7  1  0.328  0.303  0.795  1.0
  P  P8  1  0.598  0.032  0.551  1.0
  P  P9  1  0.968  0.402  0.551  1.0
  P  P10  1  0.402  0.968  0.051  1.0
  P  P11  1  0.032  0.598  0.051  1.0
  Pd  Pd12  1  0.889  0.111  0.396  1.0
  Pd  Pd13  1  0.111  0.889  0.896  1.0
  Pd  Pd14  1  0.621  0.379  0.162  1.0
  Pd  Pd15  1  0.379  0.621  0.662  1.0
  Pd  Pd16  1  0.626  0.374  0.434  1.0
  Pd  Pd17  1  0.374  0.626  0.934  1.0
  O  O18  1  0.434  0.566  0.303  1.0
  O  O19  1  0.566  0.434  0.803  1.0
  O  O20  1  0.357  0.248  0.375  1.0
  O  O21  1  0.752  0.643  0.375  1.0
  O  O22  1  0.643  0.752  0.875  1.0
  O  O23  1  0.248  0.357  0.875  1.0
  O  O24  1  0.342  0.277  0.199  1.0
  O  O25  1  0.723  0.658  0.199  1.0
  O  O26  1  0.658  0.723  0.699  1.0
  O  O27  1  0.277  0.342  0.699  1.0
  O  O28  1  0.091  0.268  0.296  1.0
  O  O29  1  0.732  0.909  0.296  1.0
  O  O30  1  0.909  0.732  0.796  1.0
  O  O31  1  0.268  0.091  0.796  1.0
  O  O32  1  0.781  0.219  0.606  1.0
  O  O33  1  0.219  0.781  0.106  1.0
  O  O34  1  0.462  0.895  0.626  1.0
  O  O35  1  0.105  0.538  0.626  1.0
  O  O36  1  0.538  0.105  0.126  1.0
  O  O37  1  0.895  0.462  0.126  1.0
  O  O38  1  0.494  0.109  0.497  1.0
  O  O39  1  0.891  0.506  0.497  1.0
  O  O40  1  0.506  0.891  0.997  1.0
  O  O41  1  0.109  0.494  0.997  1.0
  O  O42  1  0.681  0.943  0.491  1.0
  O  O43  1  0.057  0.319  0.491  1.0
  O  O44  1  0.319  0.057  0.991  1.0
  O  O45  1  0.943  0.681  0.991  1.0
[/CIF]
.