The material described by NaN3 crystallizes in the monoclinic C2/m space group. Na(1) is bonded in a 8-coordinate geometry to two equivalent N(2) and six equivalent N(1) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 4-coordinate geometry to three equivalent Na(1) and one N(1) atom. In the second N site, N(2) is bonded in a linear geometry to two equivalent Na(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_NaN3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.091
_cell_length_b   4.091
_cell_length_c   4.785
_cell_angle_alpha   59.558
_cell_angle_beta   59.558
_cell_angle_gamma   60.513
_symmetry_Int_Tables_number   1
_cell_volume   56.458
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.000  0.000  0.000  1.0
  N  N1  1  0.497  0.497  0.624  1.0
  N  N2  1  0.000  0.000  0.500  1.0
  N  N3  1  0.503  0.503  0.376  1.0
[/CIF]
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The material described by NaN3 crystallizes in the monoclinic C2/m space group. Na(1) is bonded in a 8-coordinate geometry to two equivalent N(2) and six equivalent N(1) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 4-coordinate geometry to three equivalent Na(1) and one N(1) atom. In the second N site, N(2) is bonded in a linear geometry to two equivalent Na(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_NaN3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.091
_cell_length_b   4.091
_cell_length_c   4.785
_cell_angle_alpha   59.558
_cell_angle_beta   59.558
_cell_angle_gamma   60.513
_symmetry_Int_Tables_number   1
_cell_volume   56.458
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.000  0.000  0.000  1.0
  N  N1  1  0.497  0.497  0.624  1.0
  N  N2  1  0.000  0.000  0.500  1.0
  N  N3  1  0.503  0.503  0.376  1.0
[/CIF]
.