The material structure described by MgGd2Mo2(O4Cl)2 crystallizes in the monoclinic C2 space group. Mg(1) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent O(4), and two equivalent Cl(1) atoms. Gd(1) is bonded in a 8-coordinate geometry to one O(1), one O(4), two equivalent O(2), two equivalent O(3), and two equivalent Cl(1) atoms. Mo(1) is bonded in a distorted tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a T-shaped geometry to one Mg(1), one Gd(1), and one Mo(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to two equivalent Gd(1) and one Mo(1) atom. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Gd(1) and one Mo(1) atom. In the fourth O site, O(4) is bonded in a T-shaped geometry to one Mg(1), one Gd(1), and one Mo(1) atom. Cl(1) is bonded in a distorted trigonal non-coplanar geometry to one Mg(1) and two equivalent Gd(1) atoms. is represented by the CIF card [CIF]
data_Gd2MgMo2(ClO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.532
_cell_length_b   6.536
_cell_length_c   7.005
_cell_angle_alpha   73.611
_cell_angle_beta   73.582
_cell_angle_gamma   67.179
_symmetry_Int_Tables_number   1
_cell_volume   259.328
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Gd  Gd0  1  0.231  0.241  0.891  1.0
  Gd  Gd1  1  0.758  0.768  0.109  1.0
  Mg  Mg2  1  0.687  0.313  0.500  1.0
  Mo  Mo3  1  0.645  0.636  0.734  1.0
  Mo  Mo4  1  0.363  0.354  0.267  1.0
  Cl  Cl5  1  0.946  0.050  0.252  1.0
  Cl  Cl6  1  0.951  0.053  0.748  1.0
  O  O7  1  0.385  0.242  0.539  1.0
  O  O8  1  0.486  0.876  0.866  1.0
  O  O9  1  0.757  0.615  0.461  1.0
  O  O10  1  0.457  0.097  0.153  1.0
  O  O11  1  0.123  0.513  0.134  1.0
  O  O12  1  0.552  0.523  0.226  1.0
  O  O13  1  0.903  0.543  0.847  1.0
  O  O14  1  0.476  0.447  0.773  1.0
[/CIF]
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The material structure described by MgGd2Mo2(O4Cl)2 crystallizes in the monoclinic C2 space group. Mg(1) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent O(4), and two equivalent Cl(1) atoms. Gd(1) is bonded in a 8-coordinate geometry to one O(1), one O(4), two equivalent O(2), two equivalent O(3), and two equivalent Cl(1) atoms. Mo(1) is bonded in a distorted tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a T-shaped geometry to one Mg(1), one Gd(1), and one Mo(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to two equivalent Gd(1) and one Mo(1) atom. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Gd(1) and one Mo(1) atom. In the fourth O site, O(4) is bonded in a T-shaped geometry to one Mg(1), one Gd(1), and one Mo(1) atom. Cl(1) is bonded in a distorted trigonal non-coplanar geometry to one Mg(1) and two equivalent Gd(1) atoms. is represented by the CIF card [CIF]
data_Gd2MgMo2(ClO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.532
_cell_length_b   6.536
_cell_length_c   7.005
_cell_angle_alpha   73.611
_cell_angle_beta   73.582
_cell_angle_gamma   67.179
_symmetry_Int_Tables_number   1
_cell_volume   259.328
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Gd  Gd0  1  0.231  0.241  0.891  1.0
  Gd  Gd1  1  0.758  0.768  0.109  1.0
  Mg  Mg2  1  0.687  0.313  0.500  1.0
  Mo  Mo3  1  0.645  0.636  0.734  1.0
  Mo  Mo4  1  0.363  0.354  0.267  1.0
  Cl  Cl5  1  0.946  0.050  0.252  1.0
  Cl  Cl6  1  0.951  0.053  0.748  1.0
  O  O7  1  0.385  0.242  0.539  1.0
  O  O8  1  0.486  0.876  0.866  1.0
  O  O9  1  0.757  0.615  0.461  1.0
  O  O10  1  0.457  0.097  0.153  1.0
  O  O11  1  0.123  0.513  0.134  1.0
  O  O12  1  0.552  0.523  0.226  1.0
  O  O13  1  0.903  0.543  0.847  1.0
  O  O14  1  0.476  0.447  0.773  1.0
[/CIF]
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