The compound described by Na2IrN2 crystallizes in the orthorhombic Immm space group. Na(1) is bonded to five equivalent N(1) atoms to form a mixture of corner and edge-sharing NaN5 square pyramids. Ir(1) is bonded in a linear geometry to two equivalent N(1) atoms. N(1) is bonded to five equivalent Na(1) and one Ir(1) atom to form a mixture of corner and edge-sharing NNa5Ir octahedra. The corner-sharing octahedral tilt angles range from 0-8°. is represented by the Crystallographic Information File (CIF) [CIF]
data_Na2IrN2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.155
_cell_length_b   4.029
_cell_length_c   6.759
_cell_angle_alpha   107.340
_cell_angle_beta   103.498
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   79.521
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.842  0.842  0.184  1.0
  Na  Na1  1  0.158  0.158  0.816  1.0
  Ir  Ir2  1  0.500  0.500  0.500  1.0
  N  N3  1  0.357  0.357  0.214  1.0
  N  N4  1  0.643  0.643  0.786  1.0
[/CIF]
.
The compound described by Na2IrN2 crystallizes in the orthorhombic Immm space group. Na(1) is bonded to five equivalent N(1) atoms to form a mixture of corner and edge-sharing NaN5 square pyramids. Ir(1) is bonded in a linear geometry to two equivalent N(1) atoms. N(1) is bonded to five equivalent Na(1) and one Ir(1) atom to form a mixture of corner and edge-sharing NNa5Ir octahedra. The corner-sharing octahedral tilt angles range from 0-8°. is represented by the Crystallographic Information File (CIF) [CIF]
data_Na2IrN2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.155
_cell_length_b   4.029
_cell_length_c   6.759
_cell_angle_alpha   107.340
_cell_angle_beta   103.498
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   79.521
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.842  0.842  0.184  1.0
  Na  Na1  1  0.158  0.158  0.816  1.0
  Ir  Ir2  1  0.500  0.500  0.500  1.0
  N  N3  1  0.357  0.357  0.214  1.0
  N  N4  1  0.643  0.643  0.786  1.0
[/CIF]
.