The structure described by WNSCl5 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two WNSCl5 clusters. W(1) is bonded to one N(1), one Cl(1), one Cl(3), one Cl(5), and two equivalent Cl(4) atoms to form distorted edge-sharing WNCl5 octahedra. N(1) is bonded in a linear geometry to one W(1) and one S(1) atom. S(1) is bonded in a water-like geometry to one N(1) and one Cl(2) atom. There are five inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one W(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one S(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one W(1) atom. In the fourth Cl site, Cl(4) is bonded in a water-like geometry to two equivalent W(1) atoms. In the fifth Cl site, Cl(5) is bonded in a single-bond geometry to one W(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_WSNCl5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.556
_cell_length_b   6.288
_cell_length_c   16.785
_cell_angle_alpha   69.786
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   946.471
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  W  W0  1  0.853  0.903  0.590  1.0
  W  W1  1  0.647  0.903  0.090  1.0
  W  W2  1  0.147  0.097  0.410  1.0
  W  W3  1  0.353  0.097  0.910  1.0
  S  S4  1  0.288  0.572  0.744  1.0
  S  S5  1  0.212  0.572  0.244  1.0
  S  S6  1  0.788  0.428  0.756  1.0
  S  S7  1  0.712  0.428  0.256  1.0
  N  N8  1  0.184  0.350  0.322  1.0
  N  N9  1  0.684  0.650  0.178  1.0
  N  N10  1  0.816  0.650  0.678  1.0
  N  N11  1  0.316  0.350  0.822  1.0
  Cl  Cl12  1  0.326  0.870  0.391  1.0
  Cl  Cl13  1  0.916  0.450  0.851  1.0
  Cl  Cl14  1  0.507  0.947  0.837  1.0
  Cl  Cl15  1  0.993  0.947  0.337  1.0
  Cl  Cl16  1  0.416  0.550  0.649  1.0
  Cl  Cl17  1  0.584  0.450  0.351  1.0
  Cl  Cl18  1  0.558  0.259  0.956  1.0
  Cl  Cl19  1  0.174  0.870  0.891  1.0
  Cl  Cl20  1  0.774  0.820  0.989  1.0
  Cl  Cl21  1  0.674  0.130  0.609  1.0
  Cl  Cl22  1  0.726  0.820  0.489  1.0
  Cl  Cl23  1  0.442  0.741  0.044  1.0
  Cl  Cl24  1  0.058  0.741  0.544  1.0
  Cl  Cl25  1  0.826  0.130  0.109  1.0
  Cl  Cl26  1  0.493  0.053  0.163  1.0
  Cl  Cl27  1  0.942  0.259  0.456  1.0
  Cl  Cl28  1  0.084  0.550  0.149  1.0
  Cl  Cl29  1  0.274  0.180  0.511  1.0
  Cl  Cl30  1  0.007  0.053  0.663  1.0
  Cl  Cl31  1  0.226  0.180  0.011  1.0
[/CIF]
.
The structure described by WNSCl5 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two WNSCl5 clusters. W(1) is bonded to one N(1), one Cl(1), one Cl(3), one Cl(5), and two equivalent Cl(4) atoms to form distorted edge-sharing WNCl5 octahedra. N(1) is bonded in a linear geometry to one W(1) and one S(1) atom. S(1) is bonded in a water-like geometry to one N(1) and one Cl(2) atom. There are five inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one W(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one S(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one W(1) atom. In the fourth Cl site, Cl(4) is bonded in a water-like geometry to two equivalent W(1) atoms. In the fifth Cl site, Cl(5) is bonded in a single-bond geometry to one W(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_WSNCl5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.556
_cell_length_b   6.288
_cell_length_c   16.785
_cell_angle_alpha   69.786
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   946.471
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  W  W0  1  0.853  0.903  0.590  1.0
  W  W1  1  0.647  0.903  0.090  1.0
  W  W2  1  0.147  0.097  0.410  1.0
  W  W3  1  0.353  0.097  0.910  1.0
  S  S4  1  0.288  0.572  0.744  1.0
  S  S5  1  0.212  0.572  0.244  1.0
  S  S6  1  0.788  0.428  0.756  1.0
  S  S7  1  0.712  0.428  0.256  1.0
  N  N8  1  0.184  0.350  0.322  1.0
  N  N9  1  0.684  0.650  0.178  1.0
  N  N10  1  0.816  0.650  0.678  1.0
  N  N11  1  0.316  0.350  0.822  1.0
  Cl  Cl12  1  0.326  0.870  0.391  1.0
  Cl  Cl13  1  0.916  0.450  0.851  1.0
  Cl  Cl14  1  0.507  0.947  0.837  1.0
  Cl  Cl15  1  0.993  0.947  0.337  1.0
  Cl  Cl16  1  0.416  0.550  0.649  1.0
  Cl  Cl17  1  0.584  0.450  0.351  1.0
  Cl  Cl18  1  0.558  0.259  0.956  1.0
  Cl  Cl19  1  0.174  0.870  0.891  1.0
  Cl  Cl20  1  0.774  0.820  0.989  1.0
  Cl  Cl21  1  0.674  0.130  0.609  1.0
  Cl  Cl22  1  0.726  0.820  0.489  1.0
  Cl  Cl23  1  0.442  0.741  0.044  1.0
  Cl  Cl24  1  0.058  0.741  0.544  1.0
  Cl  Cl25  1  0.826  0.130  0.109  1.0
  Cl  Cl26  1  0.493  0.053  0.163  1.0
  Cl  Cl27  1  0.942  0.259  0.456  1.0
  Cl  Cl28  1  0.084  0.550  0.149  1.0
  Cl  Cl29  1  0.274  0.180  0.511  1.0
  Cl  Cl30  1  0.007  0.053  0.663  1.0
  Cl  Cl31  1  0.226  0.180  0.011  1.0
[/CIF]
.