The crystal structure described by (SbF4)4(F2)5 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of five hydrofluoric acid atoms and one SbF4 cluster. In the SbF4 cluster, Sb(1) is bonded in a 2-coordinate geometry to one F(4), one F(5), one F(7), and two equivalent F(3) atoms. There are four inequivalent F sites. In the first F site, F(3) is bonded in a bent 120 degrees geometry to two equivalent Sb(1) atoms. In the second F site, F(4) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(5) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(7) is bonded in a single-bond geometry to one Sb(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sb2F13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.352
_cell_length_b   6.861
_cell_length_c   7.702
_cell_angle_alpha   116.266
_cell_angle_beta   94.698
_cell_angle_gamma   95.473
_symmetry_Int_Tables_number   1
_cell_volume   249.996
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.815  0.413  0.715  1.0
  Sb  Sb1  1  0.185  0.587  0.285  1.0
  F  F2  1  0.612  0.422  0.065  1.0
  F  F3  1  0.388  0.578  0.935  1.0
  F  F4  1  0.000  0.000  0.000  1.0
  F  F5  1  0.124  0.643  0.640  1.0
  F  F6  1  0.876  0.357  0.360  1.0
  F  F7  1  0.935  0.173  0.707  1.0
  F  F8  1  0.065  0.827  0.293  1.0
  F  F9  1  0.638  0.784  0.457  1.0
  F  F10  1  0.362  0.216  0.543  1.0
  F  F11  1  0.530  0.130  0.828  1.0
  F  F12  1  0.470  0.870  0.172  1.0
  F  F13  1  0.724  0.593  0.765  1.0
  F  F14  1  0.276  0.407  0.235  1.0
[/CIF]
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The crystal structure described by (SbF4)4(F2)5 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of five hydrofluoric acid atoms and one SbF4 cluster. In the SbF4 cluster, Sb(1) is bonded in a 2-coordinate geometry to one F(4), one F(5), one F(7), and two equivalent F(3) atoms. There are four inequivalent F sites. In the first F site, F(3) is bonded in a bent 120 degrees geometry to two equivalent Sb(1) atoms. In the second F site, F(4) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(5) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(7) is bonded in a single-bond geometry to one Sb(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sb2F13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.352
_cell_length_b   6.861
_cell_length_c   7.702
_cell_angle_alpha   116.266
_cell_angle_beta   94.698
_cell_angle_gamma   95.473
_symmetry_Int_Tables_number   1
_cell_volume   249.996
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.815  0.413  0.715  1.0
  Sb  Sb1  1  0.185  0.587  0.285  1.0
  F  F2  1  0.612  0.422  0.065  1.0
  F  F3  1  0.388  0.578  0.935  1.0
  F  F4  1  0.000  0.000  0.000  1.0
  F  F5  1  0.124  0.643  0.640  1.0
  F  F6  1  0.876  0.357  0.360  1.0
  F  F7  1  0.935  0.173  0.707  1.0
  F  F8  1  0.065  0.827  0.293  1.0
  F  F9  1  0.638  0.784  0.457  1.0
  F  F10  1  0.362  0.216  0.543  1.0
  F  F11  1  0.530  0.130  0.828  1.0
  F  F12  1  0.470  0.870  0.172  1.0
  F  F13  1  0.724  0.593  0.765  1.0
  F  F14  1  0.276  0.407  0.235  1.0
[/CIF]
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