The compound described by NaSb2H2OF7 crystallizes in the monoclinic P2_1/c space group. Na(1) is bonded in a 6-coordinate geometry to one O(1), one F(7), two equivalent F(3), and two equivalent F(4) atoms. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a distorted rectangular see-saw-like geometry to one F(1), one F(2), one F(3), and one F(7) atom. In the second Sb site, Sb(2) is bonded in a 4-coordinate geometry to one F(4), one F(5), one F(6), and one F(7) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. O(1) is bonded in a distorted water-like geometry to one Na(1), one H(1), and one H(2) atom. There are seven inequivalent F sites. In the first F site, F(3) is bonded in a distorted trigonal planar geometry to two equivalent Na(1) and one Sb(1) atom. In the second F site, F(4) is bonded in a distorted trigonal planar geometry to two equivalent Na(1) and one Sb(2) atom. In the third F site, F(5) is bonded in a single-bond geometry to one Sb(2) atom. In the fourth F site, F(6) is bonded in a single-bond geometry to one Sb(2) atom. In the fifth F site, F(7) is bonded in a trigonal planar geometry to one Na(1), one Sb(1), and one Sb(2) atom. In the sixth F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the seventh F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. is represented by the CIF card [CIF]
data_NaSb2H2OF7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.572
_cell_length_b   9.747
_cell_length_c   13.700
_cell_angle_alpha   90.000
_cell_angle_beta   97.609
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   737.559
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.243  0.441  0.926  1.0
  Na  Na1  1  0.757  0.941  0.574  1.0
  Na  Na2  1  0.757  0.559  0.074  1.0
  Na  Na3  1  0.243  0.059  0.426  1.0
  Sb  Sb4  1  0.795  0.166  0.973  1.0
  Sb  Sb5  1  0.205  0.666  0.527  1.0
  Sb  Sb6  1  0.205  0.834  0.027  1.0
  Sb  Sb7  1  0.795  0.334  0.473  1.0
  Sb  Sb8  1  0.388  0.200  0.707  1.0
  Sb  Sb9  1  0.612  0.700  0.793  1.0
  Sb  Sb10  1  0.612  0.800  0.293  1.0
  Sb  Sb11  1  0.388  0.300  0.207  1.0
  H  H12  1  0.157  0.919  0.738  1.0
  H  H13  1  0.843  0.419  0.762  1.0
  H  H14  1  0.843  0.081  0.262  1.0
  H  H15  1  0.157  0.581  0.238  1.0
  H  H16  1  0.971  0.031  0.761  1.0
  H  H17  1  0.029  0.531  0.739  1.0
  H  H18  1  0.029  0.969  0.239  1.0
  H  H19  1  0.971  0.469  0.261  1.0
  O  O20  1  0.062  0.998  0.709  1.0
  O  O21  1  0.938  0.498  0.791  1.0
  O  O22  1  0.938  0.002  0.291  1.0
  O  O23  1  0.062  0.502  0.209  1.0
  F  F24  1  0.007  0.178  0.869  1.0
  F  F25  1  0.993  0.678  0.631  1.0
  F  F26  1  0.993  0.822  0.131  1.0
  F  F27  1  0.007  0.322  0.369  1.0
  F  F28  1  0.105  0.109  0.062  1.0
  F  F29  1  0.895  0.609  0.438  1.0
  F  F30  1  0.895  0.891  0.938  1.0
  F  F31  1  0.105  0.391  0.562  1.0
  F  F32  1  0.905  0.356  0.006  1.0
  F  F33  1  0.095  0.856  0.494  1.0
  F  F34  1  0.095  0.644  0.994  1.0
  F  F35  1  0.905  0.144  0.506  1.0
  F  F36  1  0.440  0.103  0.580  1.0
  F  F37  1  0.560  0.603  0.920  1.0
  F  F38  1  0.560  0.897  0.420  1.0
  F  F39  1  0.440  0.397  0.080  1.0
  F  F40  1  0.693  0.295  0.679  1.0
  F  F41  1  0.307  0.795  0.821  1.0
  F  F42  1  0.307  0.705  0.321  1.0
  F  F43  1  0.693  0.205  0.179  1.0
  F  F44  1  0.584  0.046  0.769  1.0
  F  F45  1  0.416  0.546  0.731  1.0
  F  F46  1  0.416  0.954  0.231  1.0
  F  F47  1  0.584  0.454  0.269  1.0
  F  F48  1  0.522  0.281  0.862  1.0
  F  F49  1  0.478  0.781  0.638  1.0
  F  F50  1  0.478  0.719  0.138  1.0
  F  F51  1  0.522  0.219  0.362  1.0
[/CIF]
.
The compound described by NaSb2H2OF7 crystallizes in the monoclinic P2_1/c space group. Na(1) is bonded in a 6-coordinate geometry to one O(1), one F(7), two equivalent F(3), and two equivalent F(4) atoms. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a distorted rectangular see-saw-like geometry to one F(1), one F(2), one F(3), and one F(7) atom. In the second Sb site, Sb(2) is bonded in a 4-coordinate geometry to one F(4), one F(5), one F(6), and one F(7) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. O(1) is bonded in a distorted water-like geometry to one Na(1), one H(1), and one H(2) atom. There are seven inequivalent F sites. In the first F site, F(3) is bonded in a distorted trigonal planar geometry to two equivalent Na(1) and one Sb(1) atom. In the second F site, F(4) is bonded in a distorted trigonal planar geometry to two equivalent Na(1) and one Sb(2) atom. In the third F site, F(5) is bonded in a single-bond geometry to one Sb(2) atom. In the fourth F site, F(6) is bonded in a single-bond geometry to one Sb(2) atom. In the fifth F site, F(7) is bonded in a trigonal planar geometry to one Na(1), one Sb(1), and one Sb(2) atom. In the sixth F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the seventh F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. is represented by the CIF card [CIF]
data_NaSb2H2OF7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.572
_cell_length_b   9.747
_cell_length_c   13.700
_cell_angle_alpha   90.000
_cell_angle_beta   97.609
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   737.559
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.243  0.441  0.926  1.0
  Na  Na1  1  0.757  0.941  0.574  1.0
  Na  Na2  1  0.757  0.559  0.074  1.0
  Na  Na3  1  0.243  0.059  0.426  1.0
  Sb  Sb4  1  0.795  0.166  0.973  1.0
  Sb  Sb5  1  0.205  0.666  0.527  1.0
  Sb  Sb6  1  0.205  0.834  0.027  1.0
  Sb  Sb7  1  0.795  0.334  0.473  1.0
  Sb  Sb8  1  0.388  0.200  0.707  1.0
  Sb  Sb9  1  0.612  0.700  0.793  1.0
  Sb  Sb10  1  0.612  0.800  0.293  1.0
  Sb  Sb11  1  0.388  0.300  0.207  1.0
  H  H12  1  0.157  0.919  0.738  1.0
  H  H13  1  0.843  0.419  0.762  1.0
  H  H14  1  0.843  0.081  0.262  1.0
  H  H15  1  0.157  0.581  0.238  1.0
  H  H16  1  0.971  0.031  0.761  1.0
  H  H17  1  0.029  0.531  0.739  1.0
  H  H18  1  0.029  0.969  0.239  1.0
  H  H19  1  0.971  0.469  0.261  1.0
  O  O20  1  0.062  0.998  0.709  1.0
  O  O21  1  0.938  0.498  0.791  1.0
  O  O22  1  0.938  0.002  0.291  1.0
  O  O23  1  0.062  0.502  0.209  1.0
  F  F24  1  0.007  0.178  0.869  1.0
  F  F25  1  0.993  0.678  0.631  1.0
  F  F26  1  0.993  0.822  0.131  1.0
  F  F27  1  0.007  0.322  0.369  1.0
  F  F28  1  0.105  0.109  0.062  1.0
  F  F29  1  0.895  0.609  0.438  1.0
  F  F30  1  0.895  0.891  0.938  1.0
  F  F31  1  0.105  0.391  0.562  1.0
  F  F32  1  0.905  0.356  0.006  1.0
  F  F33  1  0.095  0.856  0.494  1.0
  F  F34  1  0.095  0.644  0.994  1.0
  F  F35  1  0.905  0.144  0.506  1.0
  F  F36  1  0.440  0.103  0.580  1.0
  F  F37  1  0.560  0.603  0.920  1.0
  F  F38  1  0.560  0.897  0.420  1.0
  F  F39  1  0.440  0.397  0.080  1.0
  F  F40  1  0.693  0.295  0.679  1.0
  F  F41  1  0.307  0.795  0.821  1.0
  F  F42  1  0.307  0.705  0.321  1.0
  F  F43  1  0.693  0.205  0.179  1.0
  F  F44  1  0.584  0.046  0.769  1.0
  F  F45  1  0.416  0.546  0.731  1.0
  F  F46  1  0.416  0.954  0.231  1.0
  F  F47  1  0.584  0.454  0.269  1.0
  F  F48  1  0.522  0.281  0.862  1.0
  F  F49  1  0.478  0.781  0.638  1.0
  F  F50  1  0.478  0.719  0.138  1.0
  F  F51  1  0.522  0.219  0.362  1.0
[/CIF]
.