The structure described by V3O5F is Hydrophilite-derived structured and crystallizes in the triclinic P-1 space group. There are four inequivalent V sites. In the first V site, V(1) is bonded to two equivalent O(4), two equivalent O(5), and two equivalent F(1) atoms to form VO4F2 octahedra that share corners with four equivalent V(3)O4F2 octahedra, corners with four equivalent V(4)O5F octahedra, and edges with two equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-53°. In the second V site, V(2) is bonded to one O(1), one O(2), one O(4), one O(5), and two equivalent O(3) atoms to form VO6 octahedra that share corners with two equivalent V(3)O4F2 octahedra, corners with six equivalent V(4)O5F octahedra,  an edgeedge with one V(1)O4F2 octahedra, and  an edgeedge with one V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-54°. In the third V site, V(3) is bonded to two equivalent O(1), two equivalent O(4), and two equivalent F(1) atoms to form VO4F2 octahedra that share corners with four equivalent V(1)O4F2 octahedra, corners with four equivalent V(2)O6 octahedra, and edges with two equivalent V(4)O5F octahedra. The corner-sharing octahedral tilt angles range from 50-53°. In the fourth V site, V(4) is bonded to one O(1), one O(3), one O(5), two equivalent O(2), and one F(1) atom to form VO5F octahedra that share corners with two equivalent V(1)O4F2 octahedra, corners with six equivalent V(2)O6 octahedra,  an edgeedge with one V(3)O4F2 octahedra, and  an edgeedge with one V(4)O5F octahedra. The corner-sharing octahedral tilt angles range from 45-54°. There are five inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one V(2), one V(3), and one V(4) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one V(2) and two equivalent V(4) atoms. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one V(4) and two equivalent V(2) atoms. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one V(1), one V(2), and one V(3) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one V(1), one V(2), and one V(4) atom. F(1) is bonded in a distorted trigonal planar geometry to one V(1), one V(3), and one V(4) atom. is represented by the CIF file [CIF]
data_V3O5F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.584
_cell_length_b   5.503
_cell_length_c   7.653
_cell_angle_alpha   87.085
_cell_angle_beta   89.080
_cell_angle_gamma   88.644
_symmetry_Int_Tables_number   1
_cell_volume   192.741
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.500  0.500  0.500  1.0
  V  V1  1  0.492  0.160  0.828  1.0
  V  V2  1  0.508  0.840  0.172  1.0
  V  V3  1  0.000  0.000  0.500  1.0
  V  V4  1  0.982  0.331  0.150  1.0
  V  V5  1  0.018  0.669  0.850  1.0
  O  O6  1  0.798  0.033  0.262  1.0
  O  O7  1  0.798  0.371  0.933  1.0
  O  O8  1  0.702  0.869  0.930  1.0
  O  O9  1  0.688  0.200  0.602  1.0
  O  O10  1  0.708  0.530  0.267  1.0
  O  O11  1  0.312  0.800  0.398  1.0
  O  O12  1  0.298  0.131  0.070  1.0
  O  O13  1  0.292  0.470  0.733  1.0
  O  O14  1  0.202  0.629  0.067  1.0
  O  O15  1  0.202  0.967  0.738  1.0
  F  F16  1  0.809  0.697  0.608  1.0
  F  F17  1  0.191  0.303  0.392  1.0
[/CIF]
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The structure described by V3O5F is Hydrophilite-derived structured and crystallizes in the triclinic P-1 space group. There are four inequivalent V sites. In the first V site, V(1) is bonded to two equivalent O(4), two equivalent O(5), and two equivalent F(1) atoms to form VO4F2 octahedra that share corners with four equivalent V(3)O4F2 octahedra, corners with four equivalent V(4)O5F octahedra, and edges with two equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-53°. In the second V site, V(2) is bonded to one O(1), one O(2), one O(4), one O(5), and two equivalent O(3) atoms to form VO6 octahedra that share corners with two equivalent V(3)O4F2 octahedra, corners with six equivalent V(4)O5F octahedra,  an edgeedge with one V(1)O4F2 octahedra, and  an edgeedge with one V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-54°. In the third V site, V(3) is bonded to two equivalent O(1), two equivalent O(4), and two equivalent F(1) atoms to form VO4F2 octahedra that share corners with four equivalent V(1)O4F2 octahedra, corners with four equivalent V(2)O6 octahedra, and edges with two equivalent V(4)O5F octahedra. The corner-sharing octahedral tilt angles range from 50-53°. In the fourth V site, V(4) is bonded to one O(1), one O(3), one O(5), two equivalent O(2), and one F(1) atom to form VO5F octahedra that share corners with two equivalent V(1)O4F2 octahedra, corners with six equivalent V(2)O6 octahedra,  an edgeedge with one V(3)O4F2 octahedra, and  an edgeedge with one V(4)O5F octahedra. The corner-sharing octahedral tilt angles range from 45-54°. There are five inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one V(2), one V(3), and one V(4) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one V(2) and two equivalent V(4) atoms. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one V(4) and two equivalent V(2) atoms. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one V(1), one V(2), and one V(3) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one V(1), one V(2), and one V(4) atom. F(1) is bonded in a distorted trigonal planar geometry to one V(1), one V(3), and one V(4) atom. is represented by the CIF file [CIF]
data_V3O5F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.584
_cell_length_b   5.503
_cell_length_c   7.653
_cell_angle_alpha   87.085
_cell_angle_beta   89.080
_cell_angle_gamma   88.644
_symmetry_Int_Tables_number   1
_cell_volume   192.741
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.500  0.500  0.500  1.0
  V  V1  1  0.492  0.160  0.828  1.0
  V  V2  1  0.508  0.840  0.172  1.0
  V  V3  1  0.000  0.000  0.500  1.0
  V  V4  1  0.982  0.331  0.150  1.0
  V  V5  1  0.018  0.669  0.850  1.0
  O  O6  1  0.798  0.033  0.262  1.0
  O  O7  1  0.798  0.371  0.933  1.0
  O  O8  1  0.702  0.869  0.930  1.0
  O  O9  1  0.688  0.200  0.602  1.0
  O  O10  1  0.708  0.530  0.267  1.0
  O  O11  1  0.312  0.800  0.398  1.0
  O  O12  1  0.298  0.131  0.070  1.0
  O  O13  1  0.292  0.470  0.733  1.0
  O  O14  1  0.202  0.629  0.067  1.0
  O  O15  1  0.202  0.967  0.738  1.0
  F  F16  1  0.809  0.697  0.608  1.0
  F  F17  1  0.191  0.303  0.392  1.0
[/CIF]
.