The compound described by ClO2 is Indium-like structured and crystallizes in the orthorhombic Pbca space group. The structure is zero-dimensional and consists of eight hydroxychloride hydrate molecules. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Cl(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Cl(1) atom. Cl(1) is bonded in a bent 120 degrees geometry to one O(1) and one O(2) atom. is represented by the CIF card [CIF]
data_ClO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.467
_cell_length_b   6.526
_cell_length_c   10.586
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   377.686
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cl  Cl0  1  0.834  0.005  0.386  1.0
  Cl  Cl1  1  0.334  0.995  0.114  1.0
  Cl  Cl2  1  0.666  0.505  0.614  1.0
  Cl  Cl3  1  0.166  0.495  0.886  1.0
  Cl  Cl4  1  0.166  0.995  0.614  1.0
  Cl  Cl5  1  0.666  0.005  0.886  1.0
  Cl  Cl6  1  0.334  0.495  0.386  1.0
  Cl  Cl7  1  0.834  0.505  0.114  1.0
  O  O8  1  0.786  0.100  0.511  1.0
  O  O9  1  0.286  0.900  0.989  1.0
  O  O10  1  0.714  0.600  0.489  1.0
  O  O11  1  0.214  0.400  0.011  1.0
  O  O12  1  0.214  0.900  0.489  1.0
  O  O13  1  0.714  0.100  0.011  1.0
  O  O14  1  0.286  0.400  0.511  1.0
  O  O15  1  0.786  0.600  0.989  1.0
  O  O16  1  0.925  0.646  0.211  1.0
  O  O17  1  0.425  0.354  0.289  1.0
  O  O18  1  0.575  0.146  0.789  1.0
  O  O19  1  0.075  0.854  0.711  1.0
  O  O20  1  0.075  0.354  0.789  1.0
  O  O21  1  0.575  0.646  0.711  1.0
  O  O22  1  0.425  0.854  0.211  1.0
  O  O23  1  0.925  0.146  0.289  1.0
[/CIF]
.
The compound described by ClO2 is Indium-like structured and crystallizes in the orthorhombic Pbca space group. The structure is zero-dimensional and consists of eight hydroxychloride hydrate molecules. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Cl(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Cl(1) atom. Cl(1) is bonded in a bent 120 degrees geometry to one O(1) and one O(2) atom. is represented by the CIF card [CIF]
data_ClO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.467
_cell_length_b   6.526
_cell_length_c   10.586
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   377.686
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cl  Cl0  1  0.834  0.005  0.386  1.0
  Cl  Cl1  1  0.334  0.995  0.114  1.0
  Cl  Cl2  1  0.666  0.505  0.614  1.0
  Cl  Cl3  1  0.166  0.495  0.886  1.0
  Cl  Cl4  1  0.166  0.995  0.614  1.0
  Cl  Cl5  1  0.666  0.005  0.886  1.0
  Cl  Cl6  1  0.334  0.495  0.386  1.0
  Cl  Cl7  1  0.834  0.505  0.114  1.0
  O  O8  1  0.786  0.100  0.511  1.0
  O  O9  1  0.286  0.900  0.989  1.0
  O  O10  1  0.714  0.600  0.489  1.0
  O  O11  1  0.214  0.400  0.011  1.0
  O  O12  1  0.214  0.900  0.489  1.0
  O  O13  1  0.714  0.100  0.011  1.0
  O  O14  1  0.286  0.400  0.511  1.0
  O  O15  1  0.786  0.600  0.989  1.0
  O  O16  1  0.925  0.646  0.211  1.0
  O  O17  1  0.425  0.354  0.289  1.0
  O  O18  1  0.575  0.146  0.789  1.0
  O  O19  1  0.075  0.854  0.711  1.0
  O  O20  1  0.075  0.354  0.789  1.0
  O  O21  1  0.575  0.646  0.711  1.0
  O  O22  1  0.425  0.854  0.211  1.0
  O  O23  1  0.925  0.146  0.289  1.0
[/CIF]
.