The structure described by LiSr4Mn2(GaO5)2 is Pb (Zr_0.50 Ti_0.48) O_3-derived structured and crystallizes in the triclinic P1 space group. Li(1) is bonded in a 5-coordinate geometry to one O(1), one O(10), one O(5), one O(7), and one O(9) atom. There are four inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 6-coordinate geometry to one O(2), one O(3), one O(4), one O(5), one O(7), and one O(9) atom. In the second Sr site, Sr(2) is bonded in a 7-coordinate geometry to one O(1), one O(10), one O(2), one O(3), one O(4), one O(6), and one O(8) atom. In the third Sr site, Sr(3) is bonded in a 6-coordinate geometry to one O(10), one O(2), one O(3), one O(4), one O(5), and one O(7) atom. In the fourth Sr site, Sr(4) is bonded in a 7-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(6), one O(8), and one O(9) atom. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 3-19°. In the second Mn site, Mn(2) is bonded to one O(1), one O(2), one O(3), one O(4), one O(7), and one O(8) atom to form corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 3-19°. There are two inequivalent Ga sites. In the first Ga site, Ga(1) is bonded in a 4-coordinate geometry to one O(10), one O(5), one O(8), and one O(9) atom. In the second Ga site, Ga(2) is bonded in a 4-coordinate geometry to one O(10), one O(6), one O(7), and one O(9) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Li(1), one Sr(2), one Sr(4), one Mn(1), and one Mn(2) atom. In the second O site, O(2) is bonded to one Sr(1), one Sr(2), one Sr(3), one Sr(4), one Mn(1), and one Mn(2) atom to form a mixture of distorted corner, edge, and face-sharing OSr4Mn2 octahedra. The corner-sharing octahedral tilt angles are 4°. In the third O site, O(3) is bonded to one Sr(1), one Sr(2), one Sr(3), one Sr(4), one Mn(1), and one Mn(2) atom to form a mixture of distorted corner, edge, and face-sharing OSr4Mn2 octahedra. The corner-sharing octahedral tilt angles are 4°. In the fourth O site, O(4) is bonded to one Sr(1), one Sr(2), one Sr(3), one Sr(4), one Mn(1), and one Mn(2) atom to form distorted face-sharing OSr4Mn2 octahedra. In the fifth O site, O(5) is bonded in a 5-coordinate geometry to one Li(1), one Sr(1), one Sr(3), one Mn(1), and one Ga(1) atom. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to one Sr(2), one Sr(4), one Mn(1), and one Ga(2) atom. In the seventh O site, O(7) is bonded in a 5-coordinate geometry to one Li(1), one Sr(1), one Sr(3), one Mn(2), and one Ga(2) atom. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to one Sr(2), one Sr(4), one Mn(2), and one Ga(1) atom. In the ninth O site, O(9) is bonded in a 5-coordinate geometry to one Li(1), one Sr(1), one Sr(4), one Ga(1), and one Ga(2) atom. In the tenth O site, O(10) is bonded in a 5-coordinate geometry to one Li(1), one Sr(2), one Sr(3), one Ga(1), and one Ga(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sr4LiMn2(GaO5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.834
_cell_length_b   5.862
_cell_length_c   8.873
_cell_angle_alpha   72.393
_cell_angle_beta   72.489
_cell_angle_gamma   94.840
_symmetry_Int_Tables_number   1
_cell_volume   270.641
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.058  0.658  0.785  1.0
  Sr  Sr1  1  0.915  0.369  0.215  1.0
  Sr  Sr2  1  0.659  0.056  0.784  1.0
  Sr  Sr3  1  0.370  0.916  0.215  1.0
  Li  Li4  1  0.383  0.382  0.737  1.0
  Mn  Mn5  1  0.493  0.492  0.012  1.0
  Mn  Mn6  1  0.996  0.996  0.012  1.0
  Ga  Ga7  1  0.689  0.690  0.487  1.0
  Ga  Ga8  1  0.324  0.322  0.488  1.0
  O  O9  1  0.266  0.265  0.970  1.0
  O  O10  1  0.249  0.747  0.004  1.0
  O  O11  1  0.749  0.250  0.001  1.0
  O  O12  1  0.739  0.738  0.022  1.0
  O  O13  1  0.672  0.676  0.701  1.0
  O  O14  1  0.313  0.307  0.290  1.0
  O  O15  1  0.128  0.122  0.701  1.0
  O  O16  1  0.897  0.903  0.290  1.0
  O  O17  1  0.341  0.647  0.508  1.0
  O  O18  1  0.652  0.345  0.508  1.0
[/CIF]
.
The structure described by LiSr4Mn2(GaO5)2 is Pb (Zr_0.50 Ti_0.48) O_3-derived structured and crystallizes in the triclinic P1 space group. Li(1) is bonded in a 5-coordinate geometry to one O(1), one O(10), one O(5), one O(7), and one O(9) atom. There are four inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 6-coordinate geometry to one O(2), one O(3), one O(4), one O(5), one O(7), and one O(9) atom. In the second Sr site, Sr(2) is bonded in a 7-coordinate geometry to one O(1), one O(10), one O(2), one O(3), one O(4), one O(6), and one O(8) atom. In the third Sr site, Sr(3) is bonded in a 6-coordinate geometry to one O(10), one O(2), one O(3), one O(4), one O(5), and one O(7) atom. In the fourth Sr site, Sr(4) is bonded in a 7-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(6), one O(8), and one O(9) atom. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 3-19°. In the second Mn site, Mn(2) is bonded to one O(1), one O(2), one O(3), one O(4), one O(7), and one O(8) atom to form corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 3-19°. There are two inequivalent Ga sites. In the first Ga site, Ga(1) is bonded in a 4-coordinate geometry to one O(10), one O(5), one O(8), and one O(9) atom. In the second Ga site, Ga(2) is bonded in a 4-coordinate geometry to one O(10), one O(6), one O(7), and one O(9) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Li(1), one Sr(2), one Sr(4), one Mn(1), and one Mn(2) atom. In the second O site, O(2) is bonded to one Sr(1), one Sr(2), one Sr(3), one Sr(4), one Mn(1), and one Mn(2) atom to form a mixture of distorted corner, edge, and face-sharing OSr4Mn2 octahedra. The corner-sharing octahedral tilt angles are 4°. In the third O site, O(3) is bonded to one Sr(1), one Sr(2), one Sr(3), one Sr(4), one Mn(1), and one Mn(2) atom to form a mixture of distorted corner, edge, and face-sharing OSr4Mn2 octahedra. The corner-sharing octahedral tilt angles are 4°. In the fourth O site, O(4) is bonded to one Sr(1), one Sr(2), one Sr(3), one Sr(4), one Mn(1), and one Mn(2) atom to form distorted face-sharing OSr4Mn2 octahedra. In the fifth O site, O(5) is bonded in a 5-coordinate geometry to one Li(1), one Sr(1), one Sr(3), one Mn(1), and one Ga(1) atom. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to one Sr(2), one Sr(4), one Mn(1), and one Ga(2) atom. In the seventh O site, O(7) is bonded in a 5-coordinate geometry to one Li(1), one Sr(1), one Sr(3), one Mn(2), and one Ga(2) atom. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to one Sr(2), one Sr(4), one Mn(2), and one Ga(1) atom. In the ninth O site, O(9) is bonded in a 5-coordinate geometry to one Li(1), one Sr(1), one Sr(4), one Ga(1), and one Ga(2) atom. In the tenth O site, O(10) is bonded in a 5-coordinate geometry to one Li(1), one Sr(2), one Sr(3), one Ga(1), and one Ga(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sr4LiMn2(GaO5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.834
_cell_length_b   5.862
_cell_length_c   8.873
_cell_angle_alpha   72.393
_cell_angle_beta   72.489
_cell_angle_gamma   94.840
_symmetry_Int_Tables_number   1
_cell_volume   270.641
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.058  0.658  0.785  1.0
  Sr  Sr1  1  0.915  0.369  0.215  1.0
  Sr  Sr2  1  0.659  0.056  0.784  1.0
  Sr  Sr3  1  0.370  0.916  0.215  1.0
  Li  Li4  1  0.383  0.382  0.737  1.0
  Mn  Mn5  1  0.493  0.492  0.012  1.0
  Mn  Mn6  1  0.996  0.996  0.012  1.0
  Ga  Ga7  1  0.689  0.690  0.487  1.0
  Ga  Ga8  1  0.324  0.322  0.488  1.0
  O  O9  1  0.266  0.265  0.970  1.0
  O  O10  1  0.249  0.747  0.004  1.0
  O  O11  1  0.749  0.250  0.001  1.0
  O  O12  1  0.739  0.738  0.022  1.0
  O  O13  1  0.672  0.676  0.701  1.0
  O  O14  1  0.313  0.307  0.290  1.0
  O  O15  1  0.128  0.122  0.701  1.0
  O  O16  1  0.897  0.903  0.290  1.0
  O  O17  1  0.341  0.647  0.508  1.0
  O  O18  1  0.652  0.345  0.508  1.0
[/CIF]
.