The material structure described by Sr4LaMn5O13 crystallizes in the monoclinic Cm space group. There are four inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 11-coordinate geometry to one O(1), one O(10), one O(15), one O(16), one O(2), one O(21), one O(22), one O(3), one O(4), one O(7), and one O(9) atom. In the second Sr site, Sr(2) is bonded in a 11-coordinate geometry to one O(1), one O(11), one O(12), one O(13), one O(14), one O(2), one O(21), one O(22), one O(5), one O(6), and one O(8) atom. In the third Sr site, Sr(3) is bonded in a distorted q6 geometry to one O(10), one O(13), one O(14), one O(17), one O(18), one O(21), one O(7), one O(8), and one O(9) atom. In the fourth Sr site, Sr(4) is bonded in a distorted q6 geometry to one O(11), one O(12), one O(15), one O(16), one O(19), one O(20), one O(22), one O(7), and one O(8) atom. La(1) is bonded in a 12-coordinate geometry to one O(17), one O(18), one O(19), one O(20), one O(21), one O(22), one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom. There are ten inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a rectangular see-saw-like geometry to one O(12), one O(14), one O(15), and one O(9) atom. In the second Mn site, Mn(2) is bonded in a rectangular see-saw-like geometry to one O(10), one O(11), one O(13), and one O(16) atom. In the third Mn site, Mn(3) is bonded to one O(1), one O(13), one O(17), one O(3), and two equivalent O(21) atoms to form MnO6 octahedra that share  a cornercorner with one Mn(7)O6 octahedra, corners with two equivalent Mn(6)O6 octahedra,  a cornercorner with one Mn(10)O5 square pyramid, and  a cornercorner with one Mn(8)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 1-6°. In the fourth Mn site, Mn(4) is bonded to one O(16), one O(2), one O(20), one O(6), and two equivalent O(22) atoms to form MnO6 octahedra that share  a cornercorner with one Mn(6)O6 octahedra, corners with two equivalent Mn(7)O6 octahedra,  a cornercorner with one Mn(5)O5 square pyramid, and  a cornercorner with one Mn(9)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 1-7°. In the fifth Mn site, Mn(5) is bonded to one O(12), one O(18), one O(6), and two equivalent O(8) atoms to form MnO5 square pyramids that share  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Mn(6)O6 octahedra, and corners with two equivalent Mn(10)O5 square pyramids. The corner-sharing octahedral tilt angles range from 9-11°. In the sixth Mn site, Mn(6) is bonded to one O(14), one O(18), one O(2), one O(4), and two equivalent O(21) atoms to form MnO6 octahedra that share  a cornercorner with one Mn(4)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra,  a cornercorner with one Mn(5)O5 square pyramid, and  a cornercorner with one Mn(9)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 1-6°. In the seventh Mn site, Mn(7) is bonded to one O(1), one O(15), one O(19), one O(5), and two equivalent O(22) atoms to form MnO6 octahedra that share  a cornercorner with one Mn(3)O6 octahedra, corners with two equivalent Mn(4)O6 octahedra,  a cornercorner with one Mn(10)O5 square pyramid, and  a cornercorner with one Mn(8)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 1-7°. In the eighth Mn site, Mn(8) is bonded to one O(19), one O(3), one O(9), and two equivalent O(7) atoms to form MnO5 trigonal bipyramids that share  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(7)O6 octahedra, and corners with two equivalent Mn(9)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 9-15°. In the ninth Mn site, Mn(9) is bonded to one O(10), one O(20), one O(4), and two equivalent O(7) atoms to form MnO5 trigonal bipyramids that share  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Mn(6)O6 octahedra, and corners with two equivalent Mn(8)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 2-11°. In the tenth Mn site, Mn(10) is bonded to one O(11), one O(17), one O(5), and two equivalent O(8) atoms to form MnO5 square pyramids that share  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(7)O6 octahedra, and corners with two equivalent Mn(5)O5 square pyramids. The corner-sharing octahedral tilt angles range from 6-13°. There are twenty-two inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Sr(1), two equivalent Sr(2), one Mn(3), and one Mn(7) atom to form distorted OSr4Mn2 octahedra that share corners with two equivalent O(4)Sr2La2Mn2 octahedra, corners with two equivalent O(6)Sr2La2Mn2 octahedra, corners with two equivalent O(10)Sr4Mn2 octahedra, corners with two equivalent O(12)Sr4Mn2 octahedra, corners with two equivalent O(14)Sr4Mn2 octahedra, corners with two equivalent O(16)Sr4Mn2 octahedra,  an edgeedge with one O(11)Sr4Mn2 octahedra,  an edgeedge with one O(9)Sr4Mn2 octahedra, edges with two equivalent O(2)Sr4Mn2 octahedra,  a faceface with one O(5)Sr2La2Mn2 octahedra,  a faceface with one O(13)Sr4Mn2 octahedra, and  a faceface with one O(15)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 3-61°. In the second O site, O(2) is bonded to two equivalent Sr(1), two equivalent Sr(2), one Mn(4), and one Mn(6) atom to form distorted OSr4Mn2 octahedra that share  a cornercorner with one O(20)Sr2La2Mn2 octahedra, corners with two equivalent O(5)Sr2La2Mn2 octahedra, corners with two equivalent O(11)Sr4Mn2 octahedra, corners with two equivalent O(13)Sr4Mn2 octahedra, corners with two equivalent O(15)Sr4Mn2 octahedra, corners with two equivalent O(9)Sr4Mn2 octahedra,  an edgeedge with one O(10)Sr4Mn2 octahedra,  an edgeedge with one O(12)Sr4Mn2 octahedra, edges with two equivalent O(1)Sr4Mn2 octahedra,  a faceface with one O(4)Sr2La2Mn2 octahedra,  a faceface with one O(6)Sr2La2Mn2 octahedra,  a faceface with one O(14)Sr4Mn2 octahedra, and  a faceface with one O(16)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 1-64°. In the third O site, O(3) is bonded in a 6-coordinate geometry to two equivalent Sr(1), two equivalent La(1), one Mn(3), and one Mn(8) atom. In the fourth O site, O(4) is bonded to two equivalent Sr(1), two equivalent La(1), one Mn(6), and one Mn(9) atom to form distorted OSr2La2Mn2 octahedra that share  a cornercorner with one O(14)Sr4Mn2 octahedra, corners with two equivalent O(5)Sr2La2Mn2 octahedra, corners with two equivalent O(1)Sr4Mn2 octahedra, corners with two equivalent O(15)Sr4Mn2 octahedra, corners with two equivalent O(9)Sr4Mn2 octahedra,  an edgeedge with one O(6)Sr2La2Mn2 octahedra,  an edgeedge with one O(16)Sr4Mn2 octahedra,  a faceface with one O(20)Sr2La2Mn2 octahedra,  a faceface with one O(10)Sr4Mn2 octahedra, and  a faceface with one O(2)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-63°. In the fifth O site, O(5) is bonded to two equivalent Sr(2), two equivalent La(1), one Mn(10), and one Mn(7) atom to form distorted OSr2La2Mn2 octahedra that share  a cornercorner with one O(15)Sr4Mn2 octahedra, corners with two equivalent O(20)Sr2La2Mn2 octahedra, corners with two equivalent O(4)Sr2La2Mn2 octahedra, corners with two equivalent O(12)Sr4Mn2 octahedra, corners with two equivalent O(14)Sr4Mn2 octahedra, corners with two equivalent O(2)Sr4Mn2 octahedra,  an edgeedge with one O(13)Sr4Mn2 octahedra, edges with two equivalent O(6)Sr2La2Mn2 octahedra,  a faceface with one O(1)Sr4Mn2 octahedra, and  a faceface with one O(11)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-64°. In the sixth O site, O(6) is bonded to two equivalent Sr(2), two equivalent La(1), one Mn(4), and one Mn(5) atom to form distorted OSr2La2Mn2 octahedra that share  a cornercorner with one O(16)Sr4Mn2 octahedra, corners with two equivalent O(1)Sr4Mn2 octahedra, corners with two equivalent O(11)Sr4Mn2 octahedra, corners with two equivalent O(13)Sr4Mn2 octahedra,  an edgeedge with one O(4)Sr2La2Mn2 octahedra,  an edgeedge with one O(14)Sr4Mn2 octahedra, edges with two equivalent O(5)Sr2La2Mn2 octahedra,  a faceface with one O(20)Sr2La2Mn2 octahedra,  a faceface with one O(12)Sr4Mn2 octahedra, and  a faceface with one O(2)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 2-63°. In the seventh O site, O(7) is bonded in a 4-coordinate geometry to one Sr(1), one Sr(3), one Sr(4), one La(1), one Mn(8), and one Mn(9) atom. In the eighth O site, O(8) is bonded in a 2-coordinate geometry to one Sr(2), one Sr(3), one Sr(4), one La(1), one Mn(10), and one Mn(5) atom. In the ninth O site, O(9) is bonded to two equivalent Sr(1), two equivalent Sr(3), one Mn(1), and one Mn(8) atom to form distorted OSr4Mn2 octahedra that share  a cornercorner with one O(12)Sr4Mn2 octahedra, corners with two equivalent O(4)Sr2La2Mn2 octahedra, corners with two equivalent O(13)Sr4Mn2 octahedra, corners with two equivalent O(16)Sr4Mn2 octahedra, corners with two equivalent O(2)Sr4Mn2 octahedra,  an edgeedge with one O(1)Sr4Mn2 octahedra, edges with two equivalent O(10)Sr4Mn2 octahedra,  a faceface with one O(14)Sr4Mn2 octahedra, and  a faceface with one O(15)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 1-68°. In the tenth O site, O(10) is bonded to two equivalent Sr(1), two equivalent Sr(3), one Mn(2), and one Mn(9) atom to form distorted OSr4Mn2 octahedra that share  a cornercorner with one O(20)Sr2La2Mn2 octahedra,  a cornercorner with one O(11)Sr4Mn2 octahedra, corners with two equivalent O(1)Sr4Mn2 octahedra, corners with two equivalent O(14)Sr4Mn2 octahedra, corners with two equivalent O(15)Sr4Mn2 octahedra,  an edgeedge with one O(2)Sr4Mn2 octahedra, edges with two equivalent O(9)Sr4Mn2 octahedra,  a faceface with one O(4)Sr2La2Mn2 octahedra,  a faceface with one O(13)Sr4Mn2 octahedra, and  a faceface with one O(16)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-67°. In the eleventh O site, O(11) is bonded to two equivalent Sr(2), two equivalent Sr(4), one Mn(10), and one Mn(2) atom to form distorted OSr4Mn2 octahedra that share  a cornercorner with one O(10)Sr4Mn2 octahedra, corners with two equivalent O(6)Sr2La2Mn2 octahedra, corners with two equivalent O(14)Sr4Mn2 octahedra, corners with two equivalent O(15)Sr4Mn2 octahedra, corners with two equivalent O(2)Sr4Mn2 octahedra,  an edgeedge with one O(20)Sr2La2Mn2 octahedra,  an edgeedge with one O(1)Sr4Mn2 octahedra, edges with two equivalent O(12)Sr4Mn2 octahedra,  a faceface with one O(5)Sr2La2Mn2 octahedra,  a faceface with one O(13)Sr4Mn2 octahedra, and  a faceface with one O(16)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-67°. In the twelfth O site, O(12) is bonded to two equivalent Sr(2), two equivalent Sr(4), one Mn(1), and one Mn(5) atom to form distorted OSr4Mn2 octahedra that share  a cornercorner with one O(9)Sr4Mn2 octahedra, corners with two equivalent O(20)Sr2La2Mn2 octahedra, corners with two equivalent O(5)Sr2La2Mn2 octahedra, corners with two equivalent O(1)Sr4Mn2 octahedra, corners with two equivalent O(13)Sr4Mn2 octahedra, corners with two equivalent O(16)Sr4Mn2 octahedra,  an edgeedge with one O(2)Sr4Mn2 octahedra, edges with two equivalent O(11)Sr4Mn2 octahedra,  a faceface with one O(6)Sr2La2Mn2 octahedra,  a faceface with one O(14)Sr4Mn2 octahedra, and  a faceface with one O(15)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 1-70°. In the thirteenth O site, O(13) is bonded to two equivalent Sr(2), two equivalent Sr(3), one Mn(2), and one Mn(3) atom to form distorted OSr4Mn2 octahedra that share  a cornercorner with one O(16)Sr4Mn2 octahedra, corners with two equivalent O(6)Sr2La2Mn2 octahedra, corners with two equivalent O(12)Sr4Mn2 octahedra, corners with two equivalent O(2)Sr4Mn2 octahedra, corners with two equivalent O(9)Sr4Mn2 octahedra,  an edgeedge with one O(5)Sr2La2Mn2 octahedra, edges with two equivalent O(14)Sr4Mn2 octahedra,  a faceface with one O(1)Sr4Mn2 octahedra,  a faceface with one O(10)Sr4Mn2 octahedra, and  a faceface with one O(11)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 1-70°. In the fourteenth O site, O(14) is bonded to two equivalent Sr(2), two equivalent Sr(3), one Mn(1), and one Mn(6) atom to form distorted OSr4Mn2 octahedra that share  a cornercorner with one O(4)Sr2La2Mn2 octahedra,  a cornercorner with one O(15)Sr4Mn2 octahedra, corners with two equivalent O(5)Sr2La2Mn2 octahedra, corners with two equivalent O(1)Sr4Mn2 octahedra, corners with two equivalent O(10)Sr4Mn2 octahedra, corners with two equivalent O(11)Sr4Mn2 octahedra,  an edgeedge with one O(6)Sr2La2Mn2 octahedra, edges with two equivalent O(13)Sr4Mn2 octahedra,  a faceface with one O(12)Sr4Mn2 octahedra,  a faceface with one O(2)Sr4Mn2 octahedra, and  a faceface with one O(9)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-67°. In the fifteenth O site, O(15) is bonded to two equivalent Sr(1), two equivalent Sr(4), one Mn(1), and one Mn(7) atom to form distorted OSr4Mn2 octahedra that share  a cornercorner with one O(5)Sr2La2Mn2 octahedra,  a cornercorner with one O(14)Sr4Mn2 octahedra, corners with two equivalent O(20)Sr2La2Mn2 octahedra, corners with two equivalent O(4)Sr2La2Mn2 octahedra, corners with two equivalent O(10)Sr4Mn2 octahedra, corners with two equivalent O(11)Sr4Mn2 octahedra, corners with two equivalent O(2)Sr4Mn2 octahedra, edges with two equivalent O(16)Sr4Mn2 octahedra,  a faceface with one O(1)Sr4Mn2 octahedra,  a faceface with one O(12)Sr4Mn2 octahedra, and  a faceface with one O(9)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-67°. In the sixteenth O site, O(16) is bonded to two equivalent Sr(1), two equivalent Sr(4), one Mn(2), and one Mn(4) atom to form distorted OSr4Mn2 octahedra that share  a cornercorner with one O(6)Sr2La2Mn2 octahedra,  a cornercorner with one O(13)Sr4Mn2 octahedra, corners with two equivalent O(1)Sr4Mn2 octahedra, corners with two equivalent O(12)Sr4Mn2 octahedra, corners with two equivalent O(9)Sr4Mn2 octahedra,  an edgeedge with one O(4)Sr2La2Mn2 octahedra, edges with two equivalent O(15)Sr4Mn2 octahedra,  a faceface with one O(20)Sr2La2Mn2 octahedra,  a faceface with one O(10)Sr4Mn2 octahedra,  a faceface with one O(11)Sr4Mn2 octahedra, and  a faceface with one O(2)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 1-68°. In the seventeenth O site, O(17) is bonded in a 6-coordinate geometry to two equivalent Sr(3), two equivalent La(1), one Mn(10), and one Mn(3) atom. In the eighteenth O site, O(18) is bonded in a 6-coordinate geometry to two equivalent Sr(3), two equivalent La(1), one Mn(5), and one Mn(6) atom. In the nineteenth O site, O(19) is bonded in a 6-coordinate geometry to two equivalent Sr(4), two equivalent La(1), one Mn(7), and one Mn(8) atom. In the twentieth O site, O(20) is bonded to two equivalent Sr(4), two equivalent La(1), one Mn(4), and one Mn(9) atom to form distorted OSr2La2Mn2 octahedra that share  a cornercorner with one O(10)Sr4Mn2 octahedra,  a cornercorner with one O(2)Sr4Mn2 octahedra, corners with two equivalent O(5)Sr2La2Mn2 octahedra, corners with two equivalent O(12)Sr4Mn2 octahedra, corners with two equivalent O(15)Sr4Mn2 octahedra,  an edgeedge with one O(11)Sr4Mn2 octahedra,  a faceface with one O(4)Sr2La2Mn2 octahedra,  a faceface with one O(6)Sr2La2Mn2 octahedra, and  a faceface with one O(16)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 1-60°. In the twenty-first O site, O(21) is bonded in a distorted linear geometry to one Sr(1), one Sr(2), one Sr(3), one La(1), one Mn(3), and one Mn(6) atom. In the twenty-second O site, O(22) is bonded in a distorted linear geometry to one Sr(1), one Sr(2), one Sr(4), one La(1), one Mn(4), and one Mn(7) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sr4LaMn5O13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.629
_cell_length_b   9.670
_cell_length_c   8.873
_cell_angle_alpha   90.207
_cell_angle_beta   90.001
_cell_angle_gamma   66.772
_symmetry_Int_Tables_number   1
_cell_volume   601.536
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.093  0.317  0.901  1.0
  Sr  Sr1  1  0.590  0.317  0.901  1.0
  Sr  Sr2  1  0.908  0.687  0.100  1.0
  Sr  Sr3  1  0.405  0.687  0.099  1.0
  Sr  Sr4  1  0.806  0.889  0.708  1.0
  Sr  Sr5  1  0.306  0.889  0.708  1.0
  Sr  Sr6  1  0.195  0.111  0.293  1.0
  Sr  Sr7  1  0.694  0.111  0.293  1.0
  La  La8  1  0.002  0.500  0.501  1.0
  La  La9  1  0.498  0.500  0.501  1.0
  Mn  Mn10  1  0.499  0.001  0.999  1.0
  Mn  Mn11  1  0.997  0.006  0.003  1.0
  Mn  Mn12  1  0.197  0.606  0.799  1.0
  Mn  Mn13  1  0.801  0.397  0.204  1.0
  Mn  Mn14  1  0.598  0.803  0.391  1.0
  Mn  Mn15  1  0.697  0.606  0.801  1.0
  Mn  Mn16  1  0.303  0.393  0.200  1.0
  Mn  Mn17  1  0.405  0.190  0.603  1.0
  Mn  Mn18  1  0.902  0.197  0.606  1.0
  Mn  Mn19  1  0.099  0.802  0.393  1.0
  O  O20  1  0.246  0.507  0.990  1.0
  O  O21  1  0.753  0.495  0.018  1.0
  O  O22  1  0.296  0.407  0.672  1.0
  O  O23  1  0.792  0.416  0.687  1.0
  O  O24  1  0.210  0.581  0.317  1.0
  O  O25  1  0.707  0.585  0.315  1.0
  O  O26  1  0.171  0.150  0.581  1.0
  O  O27  1  0.680  0.150  0.581  1.0
  O  O28  1  0.838  0.827  0.405  1.0
  O  O29  1  0.335  0.827  0.405  1.0
  O  O30  1  0.457  0.086  0.801  1.0
  O  O31  1  0.951  0.099  0.804  1.0
  O  O32  1  0.043  0.914  0.203  1.0
  O  O33  1  0.541  0.918  0.201  1.0
  O  O34  1  0.092  0.816  0.913  1.0
  O  O35  1  0.599  0.803  0.916  1.0
  O  O36  1  0.400  0.200  0.084  1.0
  O  O37  1  0.899  0.201  0.097  1.0
  O  O38  1  0.141  0.718  0.595  1.0
  O  O39  1  0.636  0.729  0.588  1.0
  O  O40  1  0.365  0.270  0.406  1.0
  O  O41  1  0.854  0.292  0.407  1.0
  O  O42  1  0.949  0.602  0.790  1.0
  O  O43  1  0.449  0.602  0.790  1.0
  O  O44  1  0.048  0.399  0.214  1.0
  O  O45  1  0.553  0.399  0.214  1.0
[/CIF]
.
The material structure described by Sr4LaMn5O13 crystallizes in the monoclinic Cm space group. There are four inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 11-coordinate geometry to one O(1), one O(10), one O(15), one O(16), one O(2), one O(21), one O(22), one O(3), one O(4), one O(7), and one O(9) atom. In the second Sr site, Sr(2) is bonded in a 11-coordinate geometry to one O(1), one O(11), one O(12), one O(13), one O(14), one O(2), one O(21), one O(22), one O(5), one O(6), and one O(8) atom. In the third Sr site, Sr(3) is bonded in a distorted q6 geometry to one O(10), one O(13), one O(14), one O(17), one O(18), one O(21), one O(7), one O(8), and one O(9) atom. In the fourth Sr site, Sr(4) is bonded in a distorted q6 geometry to one O(11), one O(12), one O(15), one O(16), one O(19), one O(20), one O(22), one O(7), and one O(8) atom. La(1) is bonded in a 12-coordinate geometry to one O(17), one O(18), one O(19), one O(20), one O(21), one O(22), one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom. There are ten inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a rectangular see-saw-like geometry to one O(12), one O(14), one O(15), and one O(9) atom. In the second Mn site, Mn(2) is bonded in a rectangular see-saw-like geometry to one O(10), one O(11), one O(13), and one O(16) atom. In the third Mn site, Mn(3) is bonded to one O(1), one O(13), one O(17), one O(3), and two equivalent O(21) atoms to form MnO6 octahedra that share  a cornercorner with one Mn(7)O6 octahedra, corners with two equivalent Mn(6)O6 octahedra,  a cornercorner with one Mn(10)O5 square pyramid, and  a cornercorner with one Mn(8)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 1-6°. In the fourth Mn site, Mn(4) is bonded to one O(16), one O(2), one O(20), one O(6), and two equivalent O(22) atoms to form MnO6 octahedra that share  a cornercorner with one Mn(6)O6 octahedra, corners with two equivalent Mn(7)O6 octahedra,  a cornercorner with one Mn(5)O5 square pyramid, and  a cornercorner with one Mn(9)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 1-7°. In the fifth Mn site, Mn(5) is bonded to one O(12), one O(18), one O(6), and two equivalent O(8) atoms to form MnO5 square pyramids that share  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Mn(6)O6 octahedra, and corners with two equivalent Mn(10)O5 square pyramids. The corner-sharing octahedral tilt angles range from 9-11°. In the sixth Mn site, Mn(6) is bonded to one O(14), one O(18), one O(2), one O(4), and two equivalent O(21) atoms to form MnO6 octahedra that share  a cornercorner with one Mn(4)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra,  a cornercorner with one Mn(5)O5 square pyramid, and  a cornercorner with one Mn(9)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 1-6°. In the seventh Mn site, Mn(7) is bonded to one O(1), one O(15), one O(19), one O(5), and two equivalent O(22) atoms to form MnO6 octahedra that share  a cornercorner with one Mn(3)O6 octahedra, corners with two equivalent Mn(4)O6 octahedra,  a cornercorner with one Mn(10)O5 square pyramid, and  a cornercorner with one Mn(8)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 1-7°. In the eighth Mn site, Mn(8) is bonded to one O(19), one O(3), one O(9), and two equivalent O(7) atoms to form MnO5 trigonal bipyramids that share  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(7)O6 octahedra, and corners with two equivalent Mn(9)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 9-15°. In the ninth Mn site, Mn(9) is bonded to one O(10), one O(20), one O(4), and two equivalent O(7) atoms to form MnO5 trigonal bipyramids that share  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Mn(6)O6 octahedra, and corners with two equivalent Mn(8)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 2-11°. In the tenth Mn site, Mn(10) is bonded to one O(11), one O(17), one O(5), and two equivalent O(8) atoms to form MnO5 square pyramids that share  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(7)O6 octahedra, and corners with two equivalent Mn(5)O5 square pyramids. The corner-sharing octahedral tilt angles range from 6-13°. There are twenty-two inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Sr(1), two equivalent Sr(2), one Mn(3), and one Mn(7) atom to form distorted OSr4Mn2 octahedra that share corners with two equivalent O(4)Sr2La2Mn2 octahedra, corners with two equivalent O(6)Sr2La2Mn2 octahedra, corners with two equivalent O(10)Sr4Mn2 octahedra, corners with two equivalent O(12)Sr4Mn2 octahedra, corners with two equivalent O(14)Sr4Mn2 octahedra, corners with two equivalent O(16)Sr4Mn2 octahedra,  an edgeedge with one O(11)Sr4Mn2 octahedra,  an edgeedge with one O(9)Sr4Mn2 octahedra, edges with two equivalent O(2)Sr4Mn2 octahedra,  a faceface with one O(5)Sr2La2Mn2 octahedra,  a faceface with one O(13)Sr4Mn2 octahedra, and  a faceface with one O(15)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 3-61°. In the second O site, O(2) is bonded to two equivalent Sr(1), two equivalent Sr(2), one Mn(4), and one Mn(6) atom to form distorted OSr4Mn2 octahedra that share  a cornercorner with one O(20)Sr2La2Mn2 octahedra, corners with two equivalent O(5)Sr2La2Mn2 octahedra, corners with two equivalent O(11)Sr4Mn2 octahedra, corners with two equivalent O(13)Sr4Mn2 octahedra, corners with two equivalent O(15)Sr4Mn2 octahedra, corners with two equivalent O(9)Sr4Mn2 octahedra,  an edgeedge with one O(10)Sr4Mn2 octahedra,  an edgeedge with one O(12)Sr4Mn2 octahedra, edges with two equivalent O(1)Sr4Mn2 octahedra,  a faceface with one O(4)Sr2La2Mn2 octahedra,  a faceface with one O(6)Sr2La2Mn2 octahedra,  a faceface with one O(14)Sr4Mn2 octahedra, and  a faceface with one O(16)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 1-64°. In the third O site, O(3) is bonded in a 6-coordinate geometry to two equivalent Sr(1), two equivalent La(1), one Mn(3), and one Mn(8) atom. In the fourth O site, O(4) is bonded to two equivalent Sr(1), two equivalent La(1), one Mn(6), and one Mn(9) atom to form distorted OSr2La2Mn2 octahedra that share  a cornercorner with one O(14)Sr4Mn2 octahedra, corners with two equivalent O(5)Sr2La2Mn2 octahedra, corners with two equivalent O(1)Sr4Mn2 octahedra, corners with two equivalent O(15)Sr4Mn2 octahedra, corners with two equivalent O(9)Sr4Mn2 octahedra,  an edgeedge with one O(6)Sr2La2Mn2 octahedra,  an edgeedge with one O(16)Sr4Mn2 octahedra,  a faceface with one O(20)Sr2La2Mn2 octahedra,  a faceface with one O(10)Sr4Mn2 octahedra, and  a faceface with one O(2)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-63°. In the fifth O site, O(5) is bonded to two equivalent Sr(2), two equivalent La(1), one Mn(10), and one Mn(7) atom to form distorted OSr2La2Mn2 octahedra that share  a cornercorner with one O(15)Sr4Mn2 octahedra, corners with two equivalent O(20)Sr2La2Mn2 octahedra, corners with two equivalent O(4)Sr2La2Mn2 octahedra, corners with two equivalent O(12)Sr4Mn2 octahedra, corners with two equivalent O(14)Sr4Mn2 octahedra, corners with two equivalent O(2)Sr4Mn2 octahedra,  an edgeedge with one O(13)Sr4Mn2 octahedra, edges with two equivalent O(6)Sr2La2Mn2 octahedra,  a faceface with one O(1)Sr4Mn2 octahedra, and  a faceface with one O(11)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-64°. In the sixth O site, O(6) is bonded to two equivalent Sr(2), two equivalent La(1), one Mn(4), and one Mn(5) atom to form distorted OSr2La2Mn2 octahedra that share  a cornercorner with one O(16)Sr4Mn2 octahedra, corners with two equivalent O(1)Sr4Mn2 octahedra, corners with two equivalent O(11)Sr4Mn2 octahedra, corners with two equivalent O(13)Sr4Mn2 octahedra,  an edgeedge with one O(4)Sr2La2Mn2 octahedra,  an edgeedge with one O(14)Sr4Mn2 octahedra, edges with two equivalent O(5)Sr2La2Mn2 octahedra,  a faceface with one O(20)Sr2La2Mn2 octahedra,  a faceface with one O(12)Sr4Mn2 octahedra, and  a faceface with one O(2)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 2-63°. In the seventh O site, O(7) is bonded in a 4-coordinate geometry to one Sr(1), one Sr(3), one Sr(4), one La(1), one Mn(8), and one Mn(9) atom. In the eighth O site, O(8) is bonded in a 2-coordinate geometry to one Sr(2), one Sr(3), one Sr(4), one La(1), one Mn(10), and one Mn(5) atom. In the ninth O site, O(9) is bonded to two equivalent Sr(1), two equivalent Sr(3), one Mn(1), and one Mn(8) atom to form distorted OSr4Mn2 octahedra that share  a cornercorner with one O(12)Sr4Mn2 octahedra, corners with two equivalent O(4)Sr2La2Mn2 octahedra, corners with two equivalent O(13)Sr4Mn2 octahedra, corners with two equivalent O(16)Sr4Mn2 octahedra, corners with two equivalent O(2)Sr4Mn2 octahedra,  an edgeedge with one O(1)Sr4Mn2 octahedra, edges with two equivalent O(10)Sr4Mn2 octahedra,  a faceface with one O(14)Sr4Mn2 octahedra, and  a faceface with one O(15)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 1-68°. In the tenth O site, O(10) is bonded to two equivalent Sr(1), two equivalent Sr(3), one Mn(2), and one Mn(9) atom to form distorted OSr4Mn2 octahedra that share  a cornercorner with one O(20)Sr2La2Mn2 octahedra,  a cornercorner with one O(11)Sr4Mn2 octahedra, corners with two equivalent O(1)Sr4Mn2 octahedra, corners with two equivalent O(14)Sr4Mn2 octahedra, corners with two equivalent O(15)Sr4Mn2 octahedra,  an edgeedge with one O(2)Sr4Mn2 octahedra, edges with two equivalent O(9)Sr4Mn2 octahedra,  a faceface with one O(4)Sr2La2Mn2 octahedra,  a faceface with one O(13)Sr4Mn2 octahedra, and  a faceface with one O(16)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-67°. In the eleventh O site, O(11) is bonded to two equivalent Sr(2), two equivalent Sr(4), one Mn(10), and one Mn(2) atom to form distorted OSr4Mn2 octahedra that share  a cornercorner with one O(10)Sr4Mn2 octahedra, corners with two equivalent O(6)Sr2La2Mn2 octahedra, corners with two equivalent O(14)Sr4Mn2 octahedra, corners with two equivalent O(15)Sr4Mn2 octahedra, corners with two equivalent O(2)Sr4Mn2 octahedra,  an edgeedge with one O(20)Sr2La2Mn2 octahedra,  an edgeedge with one O(1)Sr4Mn2 octahedra, edges with two equivalent O(12)Sr4Mn2 octahedra,  a faceface with one O(5)Sr2La2Mn2 octahedra,  a faceface with one O(13)Sr4Mn2 octahedra, and  a faceface with one O(16)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-67°. In the twelfth O site, O(12) is bonded to two equivalent Sr(2), two equivalent Sr(4), one Mn(1), and one Mn(5) atom to form distorted OSr4Mn2 octahedra that share  a cornercorner with one O(9)Sr4Mn2 octahedra, corners with two equivalent O(20)Sr2La2Mn2 octahedra, corners with two equivalent O(5)Sr2La2Mn2 octahedra, corners with two equivalent O(1)Sr4Mn2 octahedra, corners with two equivalent O(13)Sr4Mn2 octahedra, corners with two equivalent O(16)Sr4Mn2 octahedra,  an edgeedge with one O(2)Sr4Mn2 octahedra, edges with two equivalent O(11)Sr4Mn2 octahedra,  a faceface with one O(6)Sr2La2Mn2 octahedra,  a faceface with one O(14)Sr4Mn2 octahedra, and  a faceface with one O(15)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 1-70°. In the thirteenth O site, O(13) is bonded to two equivalent Sr(2), two equivalent Sr(3), one Mn(2), and one Mn(3) atom to form distorted OSr4Mn2 octahedra that share  a cornercorner with one O(16)Sr4Mn2 octahedra, corners with two equivalent O(6)Sr2La2Mn2 octahedra, corners with two equivalent O(12)Sr4Mn2 octahedra, corners with two equivalent O(2)Sr4Mn2 octahedra, corners with two equivalent O(9)Sr4Mn2 octahedra,  an edgeedge with one O(5)Sr2La2Mn2 octahedra, edges with two equivalent O(14)Sr4Mn2 octahedra,  a faceface with one O(1)Sr4Mn2 octahedra,  a faceface with one O(10)Sr4Mn2 octahedra, and  a faceface with one O(11)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 1-70°. In the fourteenth O site, O(14) is bonded to two equivalent Sr(2), two equivalent Sr(3), one Mn(1), and one Mn(6) atom to form distorted OSr4Mn2 octahedra that share  a cornercorner with one O(4)Sr2La2Mn2 octahedra,  a cornercorner with one O(15)Sr4Mn2 octahedra, corners with two equivalent O(5)Sr2La2Mn2 octahedra, corners with two equivalent O(1)Sr4Mn2 octahedra, corners with two equivalent O(10)Sr4Mn2 octahedra, corners with two equivalent O(11)Sr4Mn2 octahedra,  an edgeedge with one O(6)Sr2La2Mn2 octahedra, edges with two equivalent O(13)Sr4Mn2 octahedra,  a faceface with one O(12)Sr4Mn2 octahedra,  a faceface with one O(2)Sr4Mn2 octahedra, and  a faceface with one O(9)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-67°. In the fifteenth O site, O(15) is bonded to two equivalent Sr(1), two equivalent Sr(4), one Mn(1), and one Mn(7) atom to form distorted OSr4Mn2 octahedra that share  a cornercorner with one O(5)Sr2La2Mn2 octahedra,  a cornercorner with one O(14)Sr4Mn2 octahedra, corners with two equivalent O(20)Sr2La2Mn2 octahedra, corners with two equivalent O(4)Sr2La2Mn2 octahedra, corners with two equivalent O(10)Sr4Mn2 octahedra, corners with two equivalent O(11)Sr4Mn2 octahedra, corners with two equivalent O(2)Sr4Mn2 octahedra, edges with two equivalent O(16)Sr4Mn2 octahedra,  a faceface with one O(1)Sr4Mn2 octahedra,  a faceface with one O(12)Sr4Mn2 octahedra, and  a faceface with one O(9)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-67°. In the sixteenth O site, O(16) is bonded to two equivalent Sr(1), two equivalent Sr(4), one Mn(2), and one Mn(4) atom to form distorted OSr4Mn2 octahedra that share  a cornercorner with one O(6)Sr2La2Mn2 octahedra,  a cornercorner with one O(13)Sr4Mn2 octahedra, corners with two equivalent O(1)Sr4Mn2 octahedra, corners with two equivalent O(12)Sr4Mn2 octahedra, corners with two equivalent O(9)Sr4Mn2 octahedra,  an edgeedge with one O(4)Sr2La2Mn2 octahedra, edges with two equivalent O(15)Sr4Mn2 octahedra,  a faceface with one O(20)Sr2La2Mn2 octahedra,  a faceface with one O(10)Sr4Mn2 octahedra,  a faceface with one O(11)Sr4Mn2 octahedra, and  a faceface with one O(2)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 1-68°. In the seventeenth O site, O(17) is bonded in a 6-coordinate geometry to two equivalent Sr(3), two equivalent La(1), one Mn(10), and one Mn(3) atom. In the eighteenth O site, O(18) is bonded in a 6-coordinate geometry to two equivalent Sr(3), two equivalent La(1), one Mn(5), and one Mn(6) atom. In the nineteenth O site, O(19) is bonded in a 6-coordinate geometry to two equivalent Sr(4), two equivalent La(1), one Mn(7), and one Mn(8) atom. In the twentieth O site, O(20) is bonded to two equivalent Sr(4), two equivalent La(1), one Mn(4), and one Mn(9) atom to form distorted OSr2La2Mn2 octahedra that share  a cornercorner with one O(10)Sr4Mn2 octahedra,  a cornercorner with one O(2)Sr4Mn2 octahedra, corners with two equivalent O(5)Sr2La2Mn2 octahedra, corners with two equivalent O(12)Sr4Mn2 octahedra, corners with two equivalent O(15)Sr4Mn2 octahedra,  an edgeedge with one O(11)Sr4Mn2 octahedra,  a faceface with one O(4)Sr2La2Mn2 octahedra,  a faceface with one O(6)Sr2La2Mn2 octahedra, and  a faceface with one O(16)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 1-60°. In the twenty-first O site, O(21) is bonded in a distorted linear geometry to one Sr(1), one Sr(2), one Sr(3), one La(1), one Mn(3), and one Mn(6) atom. In the twenty-second O site, O(22) is bonded in a distorted linear geometry to one Sr(1), one Sr(2), one Sr(4), one La(1), one Mn(4), and one Mn(7) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sr4LaMn5O13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.629
_cell_length_b   9.670
_cell_length_c   8.873
_cell_angle_alpha   90.207
_cell_angle_beta   90.001
_cell_angle_gamma   66.772
_symmetry_Int_Tables_number   1
_cell_volume   601.536
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.093  0.317  0.901  1.0
  Sr  Sr1  1  0.590  0.317  0.901  1.0
  Sr  Sr2  1  0.908  0.687  0.100  1.0
  Sr  Sr3  1  0.405  0.687  0.099  1.0
  Sr  Sr4  1  0.806  0.889  0.708  1.0
  Sr  Sr5  1  0.306  0.889  0.708  1.0
  Sr  Sr6  1  0.195  0.111  0.293  1.0
  Sr  Sr7  1  0.694  0.111  0.293  1.0
  La  La8  1  0.002  0.500  0.501  1.0
  La  La9  1  0.498  0.500  0.501  1.0
  Mn  Mn10  1  0.499  0.001  0.999  1.0
  Mn  Mn11  1  0.997  0.006  0.003  1.0
  Mn  Mn12  1  0.197  0.606  0.799  1.0
  Mn  Mn13  1  0.801  0.397  0.204  1.0
  Mn  Mn14  1  0.598  0.803  0.391  1.0
  Mn  Mn15  1  0.697  0.606  0.801  1.0
  Mn  Mn16  1  0.303  0.393  0.200  1.0
  Mn  Mn17  1  0.405  0.190  0.603  1.0
  Mn  Mn18  1  0.902  0.197  0.606  1.0
  Mn  Mn19  1  0.099  0.802  0.393  1.0
  O  O20  1  0.246  0.507  0.990  1.0
  O  O21  1  0.753  0.495  0.018  1.0
  O  O22  1  0.296  0.407  0.672  1.0
  O  O23  1  0.792  0.416  0.687  1.0
  O  O24  1  0.210  0.581  0.317  1.0
  O  O25  1  0.707  0.585  0.315  1.0
  O  O26  1  0.171  0.150  0.581  1.0
  O  O27  1  0.680  0.150  0.581  1.0
  O  O28  1  0.838  0.827  0.405  1.0
  O  O29  1  0.335  0.827  0.405  1.0
  O  O30  1  0.457  0.086  0.801  1.0
  O  O31  1  0.951  0.099  0.804  1.0
  O  O32  1  0.043  0.914  0.203  1.0
  O  O33  1  0.541  0.918  0.201  1.0
  O  O34  1  0.092  0.816  0.913  1.0
  O  O35  1  0.599  0.803  0.916  1.0
  O  O36  1  0.400  0.200  0.084  1.0
  O  O37  1  0.899  0.201  0.097  1.0
  O  O38  1  0.141  0.718  0.595  1.0
  O  O39  1  0.636  0.729  0.588  1.0
  O  O40  1  0.365  0.270  0.406  1.0
  O  O41  1  0.854  0.292  0.407  1.0
  O  O42  1  0.949  0.602  0.790  1.0
  O  O43  1  0.449  0.602  0.790  1.0
  O  O44  1  0.048  0.399  0.214  1.0
  O  O45  1  0.553  0.399  0.214  1.0
[/CIF]
.