The material structure described by K2Li3MnO4 is alpha Pu-derived structured and crystallizes in the monoclinic P2_1/c space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 2-coordinate geometry to one O(2), one O(3), and one O(4) atom. In the second K site, K(2) is bonded in a 6-coordinate geometry to one O(2), one O(3), one O(4), and three equivalent O(1) atoms. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form distorted LiO4 tetrahedra that share corners with two equivalent Li(3)O4 tetrahedra, corners with two equivalent Mn(1)O4 tetrahedra,  an edgeedge with one Li(3)O4 tetrahedra, and  an edgeedge with one Mn(1)O4 tetrahedra. In the second Li site, Li(2) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(3), and one O(4) atom. In the third Li site, Li(3) is bonded to one O(3), one O(4), and two equivalent O(2) atoms to form LiO4 tetrahedra that share corners with two equivalent Li(1)O4 tetrahedra, corners with two equivalent Mn(1)O4 tetrahedra,  an edgeedge with one Li(1)O4 tetrahedra,  an edgeedge with one Li(3)O4 tetrahedra, and  an edgeedge with one Mn(1)O4 tetrahedra. Mn(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form MnO4 tetrahedra that share corners with two equivalent Li(1)O4 tetrahedra, corners with two equivalent Li(3)O4 tetrahedra,  an edgeedge with one Li(1)O4 tetrahedra, and  an edgeedge with one Li(3)O4 tetrahedra. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to three equivalent K(2), one Li(1), one Li(2), and one Mn(1) atom. In the second O site, O(2) is bonded in a 7-coordinate geometry to one K(1), one K(2), one Li(1), one Li(2), two equivalent Li(3), and one Mn(1) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one K(1), one K(2), one Li(1), one Li(2), one Li(3), and one Mn(1) atom. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to one K(1), one K(2), one Li(1), one Li(2), one Li(3), and one Mn(1) atom. is represented by the CIF file [CIF]
data_K2Li3MnO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.972
_cell_length_b   5.548
_cell_length_c   10.985
_cell_angle_alpha   71.868
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   519.629
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.227  0.715  0.892  1.0
  K  K1  1  0.490  0.708  0.638  1.0
  K  K2  1  0.273  0.715  0.392  1.0
  K  K3  1  0.990  0.292  0.862  1.0
  K  K4  1  0.010  0.708  0.138  1.0
  K  K5  1  0.727  0.285  0.608  1.0
  K  K6  1  0.510  0.292  0.362  1.0
  K  K7  1  0.773  0.285  0.108  1.0
  Li  Li8  1  0.964  0.905  0.705  1.0
  Li  Li9  1  0.735  0.621  0.800  1.0
  Li  Li10  1  0.536  0.905  0.205  1.0
  Li  Li11  1  0.505  0.379  0.927  1.0
  Li  Li12  1  0.005  0.621  0.573  1.0
  Li  Li13  1  0.235  0.379  0.700  1.0
  Li  Li14  1  0.765  0.621  0.300  1.0
  Li  Li15  1  0.995  0.379  0.427  1.0
  Li  Li16  1  0.495  0.621  0.073  1.0
  Li  Li17  1  0.464  0.095  0.795  1.0
  Li  Li18  1  0.265  0.379  0.200  1.0
  Li  Li19  1  0.036  0.095  0.295  1.0
  Mn  Mn20  1  0.706  0.910  0.942  1.0
  Mn  Mn21  1  0.794  0.910  0.442  1.0
  Mn  Mn22  1  0.206  0.090  0.558  1.0
  Mn  Mn23  1  0.294  0.090  0.058  1.0
  O  O24  1  0.892  0.798  0.888  1.0
  O  O25  1  0.538  0.747  0.882  1.0
  O  O26  1  0.807  0.747  0.623  1.0
  O  O27  1  0.171  0.743  0.654  1.0
  O  O28  1  0.608  0.798  0.388  1.0
  O  O29  1  0.962  0.747  0.382  1.0
  O  O30  1  0.671  0.257  0.846  1.0
  O  O31  1  0.307  0.253  0.877  1.0
  O  O32  1  0.693  0.747  0.123  1.0
  O  O33  1  0.329  0.743  0.154  1.0
  O  O34  1  0.038  0.253  0.618  1.0
  O  O35  1  0.392  0.202  0.612  1.0
  O  O36  1  0.829  0.257  0.346  1.0
  O  O37  1  0.193  0.253  0.377  1.0
  O  O38  1  0.462  0.253  0.118  1.0
  O  O39  1  0.108  0.202  0.112  1.0
[/CIF]
.
The material structure described by K2Li3MnO4 is alpha Pu-derived structured and crystallizes in the monoclinic P2_1/c space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 2-coordinate geometry to one O(2), one O(3), and one O(4) atom. In the second K site, K(2) is bonded in a 6-coordinate geometry to one O(2), one O(3), one O(4), and three equivalent O(1) atoms. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form distorted LiO4 tetrahedra that share corners with two equivalent Li(3)O4 tetrahedra, corners with two equivalent Mn(1)O4 tetrahedra,  an edgeedge with one Li(3)O4 tetrahedra, and  an edgeedge with one Mn(1)O4 tetrahedra. In the second Li site, Li(2) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(3), and one O(4) atom. In the third Li site, Li(3) is bonded to one O(3), one O(4), and two equivalent O(2) atoms to form LiO4 tetrahedra that share corners with two equivalent Li(1)O4 tetrahedra, corners with two equivalent Mn(1)O4 tetrahedra,  an edgeedge with one Li(1)O4 tetrahedra,  an edgeedge with one Li(3)O4 tetrahedra, and  an edgeedge with one Mn(1)O4 tetrahedra. Mn(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form MnO4 tetrahedra that share corners with two equivalent Li(1)O4 tetrahedra, corners with two equivalent Li(3)O4 tetrahedra,  an edgeedge with one Li(1)O4 tetrahedra, and  an edgeedge with one Li(3)O4 tetrahedra. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to three equivalent K(2), one Li(1), one Li(2), and one Mn(1) atom. In the second O site, O(2) is bonded in a 7-coordinate geometry to one K(1), one K(2), one Li(1), one Li(2), two equivalent Li(3), and one Mn(1) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one K(1), one K(2), one Li(1), one Li(2), one Li(3), and one Mn(1) atom. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to one K(1), one K(2), one Li(1), one Li(2), one Li(3), and one Mn(1) atom. is represented by the CIF file [CIF]
data_K2Li3MnO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.972
_cell_length_b   5.548
_cell_length_c   10.985
_cell_angle_alpha   71.868
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   519.629
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.227  0.715  0.892  1.0
  K  K1  1  0.490  0.708  0.638  1.0
  K  K2  1  0.273  0.715  0.392  1.0
  K  K3  1  0.990  0.292  0.862  1.0
  K  K4  1  0.010  0.708  0.138  1.0
  K  K5  1  0.727  0.285  0.608  1.0
  K  K6  1  0.510  0.292  0.362  1.0
  K  K7  1  0.773  0.285  0.108  1.0
  Li  Li8  1  0.964  0.905  0.705  1.0
  Li  Li9  1  0.735  0.621  0.800  1.0
  Li  Li10  1  0.536  0.905  0.205  1.0
  Li  Li11  1  0.505  0.379  0.927  1.0
  Li  Li12  1  0.005  0.621  0.573  1.0
  Li  Li13  1  0.235  0.379  0.700  1.0
  Li  Li14  1  0.765  0.621  0.300  1.0
  Li  Li15  1  0.995  0.379  0.427  1.0
  Li  Li16  1  0.495  0.621  0.073  1.0
  Li  Li17  1  0.464  0.095  0.795  1.0
  Li  Li18  1  0.265  0.379  0.200  1.0
  Li  Li19  1  0.036  0.095  0.295  1.0
  Mn  Mn20  1  0.706  0.910  0.942  1.0
  Mn  Mn21  1  0.794  0.910  0.442  1.0
  Mn  Mn22  1  0.206  0.090  0.558  1.0
  Mn  Mn23  1  0.294  0.090  0.058  1.0
  O  O24  1  0.892  0.798  0.888  1.0
  O  O25  1  0.538  0.747  0.882  1.0
  O  O26  1  0.807  0.747  0.623  1.0
  O  O27  1  0.171  0.743  0.654  1.0
  O  O28  1  0.608  0.798  0.388  1.0
  O  O29  1  0.962  0.747  0.382  1.0
  O  O30  1  0.671  0.257  0.846  1.0
  O  O31  1  0.307  0.253  0.877  1.0
  O  O32  1  0.693  0.747  0.123  1.0
  O  O33  1  0.329  0.743  0.154  1.0
  O  O34  1  0.038  0.253  0.618  1.0
  O  O35  1  0.392  0.202  0.612  1.0
  O  O36  1  0.829  0.257  0.346  1.0
  O  O37  1  0.193  0.253  0.377  1.0
  O  O38  1  0.462  0.253  0.118  1.0
  O  O39  1  0.108  0.202  0.112  1.0
[/CIF]
.