The compound described by Li2In crystallizes in the orthorhombic Cmcm space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded to four equivalent Li(2) and four equivalent In(1) atoms to form a mixture of distorted edge and face-sharing LiLi4In4 tetrahedra. In the second Li site, Li(2) is bonded in a distorted water-like geometry to two equivalent Li(2), four equivalent Li(1), and seven equivalent In(1) atoms. In(1) is bonded in a 6-coordinate geometry to four equivalent Li(1) and seven equivalent Li(2) atoms. is represented by the CIF card [CIF]
data_Li2In
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.680
_cell_length_b   4.693
_cell_length_c   5.550
_cell_angle_alpha   115.011
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   110.467
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.750  0.757  0.515  1.0
  Li  Li1  1  0.250  0.243  0.485  1.0
  Li  Li2  1  0.750  0.411  0.821  1.0
  Li  Li3  1  0.250  0.589  0.179  1.0
  In  In4  1  0.750  0.087  0.175  1.0
  In  In5  1  0.250  0.913  0.825  1.0
[/CIF]
.
The compound described by Li2In crystallizes in the orthorhombic Cmcm space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded to four equivalent Li(2) and four equivalent In(1) atoms to form a mixture of distorted edge and face-sharing LiLi4In4 tetrahedra. In the second Li site, Li(2) is bonded in a distorted water-like geometry to two equivalent Li(2), four equivalent Li(1), and seven equivalent In(1) atoms. In(1) is bonded in a 6-coordinate geometry to four equivalent Li(1) and seven equivalent Li(2) atoms. is represented by the CIF card [CIF]
data_Li2In
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.680
_cell_length_b   4.693
_cell_length_c   5.550
_cell_angle_alpha   115.011
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   110.467
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.750  0.757  0.515  1.0
  Li  Li1  1  0.250  0.243  0.485  1.0
  Li  Li2  1  0.750  0.411  0.821  1.0
  Li  Li3  1  0.250  0.589  0.179  1.0
  In  In4  1  0.750  0.087  0.175  1.0
  In  In5  1  0.250  0.913  0.825  1.0
[/CIF]
.