The material described by Zn(NH3)4(ClO4)2 is Silicon tetrafluoride-derived structured and crystallizes in the cubic F-43m space group. The structure is zero-dimensional and consists of eight hypochlorous acid;trihydrate molecules and four Zn(NH3)4 clusters. In each Zn(NH3)4 cluster, Zn(1) is bonded in a tetrahedral geometry to four equivalent N(1) atoms. N(1) is bonded in a distorted trigonal non-coplanar geometry to one Zn(1) and three equivalent H(1) atoms. H(1) is bonded in a single-bond geometry to one N(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_ZnH12N4(ClO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.363
_cell_length_b   7.363
_cell_length_c   7.363
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   282.270
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.000  0.000  0.000  1.0
  H  H1  1  0.401  0.791  0.791  1.0
  H  H2  1  0.017  0.791  0.401  1.0
  H  H3  1  0.017  0.401  0.791  1.0
  H  H4  1  0.791  0.791  0.017  1.0
  H  H5  1  0.791  0.017  0.791  1.0
  H  H6  1  0.791  0.401  0.017  1.0
  H  H7  1  0.791  0.017  0.401  1.0
  H  H8  1  0.401  0.017  0.791  1.0
  H  H9  1  0.791  0.791  0.401  1.0
  H  H10  1  0.791  0.401  0.791  1.0
  H  H11  1  0.401  0.791  0.017  1.0
  H  H12  1  0.017  0.791  0.791  1.0
  N  N13  1  0.341  0.886  0.886  1.0
  N  N14  1  0.886  0.341  0.886  1.0
  N  N15  1  0.886  0.886  0.341  1.0
  N  N16  1  0.886  0.886  0.886  1.0
  Cl  Cl17  1  0.250  0.250  0.250  1.0
  Cl  Cl18  1  0.500  0.500  0.500  1.0
  O  O19  1  0.169  0.169  0.493  1.0
  O  O20  1  0.169  0.493  0.169  1.0
  O  O21  1  0.493  0.169  0.169  1.0
  O  O22  1  0.169  0.169  0.169  1.0
  O  O23  1  0.581  0.581  0.581  1.0
  O  O24  1  0.581  0.581  0.256  1.0
  O  O25  1  0.581  0.256  0.581  1.0
  O  O26  1  0.256  0.581  0.581  1.0
[/CIF]
.
The material described by Zn(NH3)4(ClO4)2 is Silicon tetrafluoride-derived structured and crystallizes in the cubic F-43m space group. The structure is zero-dimensional and consists of eight hypochlorous acid;trihydrate molecules and four Zn(NH3)4 clusters. In each Zn(NH3)4 cluster, Zn(1) is bonded in a tetrahedral geometry to four equivalent N(1) atoms. N(1) is bonded in a distorted trigonal non-coplanar geometry to one Zn(1) and three equivalent H(1) atoms. H(1) is bonded in a single-bond geometry to one N(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_ZnH12N4(ClO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.363
_cell_length_b   7.363
_cell_length_c   7.363
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   282.270
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.000  0.000  0.000  1.0
  H  H1  1  0.401  0.791  0.791  1.0
  H  H2  1  0.017  0.791  0.401  1.0
  H  H3  1  0.017  0.401  0.791  1.0
  H  H4  1  0.791  0.791  0.017  1.0
  H  H5  1  0.791  0.017  0.791  1.0
  H  H6  1  0.791  0.401  0.017  1.0
  H  H7  1  0.791  0.017  0.401  1.0
  H  H8  1  0.401  0.017  0.791  1.0
  H  H9  1  0.791  0.791  0.401  1.0
  H  H10  1  0.791  0.401  0.791  1.0
  H  H11  1  0.401  0.791  0.017  1.0
  H  H12  1  0.017  0.791  0.791  1.0
  N  N13  1  0.341  0.886  0.886  1.0
  N  N14  1  0.886  0.341  0.886  1.0
  N  N15  1  0.886  0.886  0.341  1.0
  N  N16  1  0.886  0.886  0.886  1.0
  Cl  Cl17  1  0.250  0.250  0.250  1.0
  Cl  Cl18  1  0.500  0.500  0.500  1.0
  O  O19  1  0.169  0.169  0.493  1.0
  O  O20  1  0.169  0.493  0.169  1.0
  O  O21  1  0.493  0.169  0.169  1.0
  O  O22  1  0.169  0.169  0.169  1.0
  O  O23  1  0.581  0.581  0.581  1.0
  O  O24  1  0.581  0.581  0.256  1.0
  O  O25  1  0.581  0.256  0.581  1.0
  O  O26  1  0.256  0.581  0.581  1.0
[/CIF]
.