The compound described by VP2O4Cl7 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one VP2O4Cl7 cluster. V(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one Cl(1), and one Cl(6) atom. There are two inequivalent P sites. In the first P site, P(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one Cl(3), and one Cl(5) atom. In the second P site, P(2) is bonded in a tetrahedral geometry to one O(3), one Cl(2), one Cl(4), and one Cl(7) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one V(1) and one P(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one V(1) and one P(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one V(1) and one P(2) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one V(1) atom. There are seven inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one V(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one P(2) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one P(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one P(2) atom. In the fifth Cl site, Cl(5) is bonded in a single-bond geometry to one P(1) atom. In the sixth Cl site, Cl(6) is bonded in a single-bond geometry to one V(1) atom. In the seventh Cl site, Cl(7) is bonded in a single-bond geometry to one P(2) atom. is represented by the CIF file [CIF]
data_VP2Cl7O4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.413
_cell_length_b   8.569
_cell_length_c   10.748
_cell_angle_alpha   92.052
_cell_angle_beta   103.311
_cell_angle_gamma   105.714
_symmetry_Int_Tables_number   1
_cell_volume   721.827
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.398  0.348  0.192  1.0
  V  V1  1  0.602  0.652  0.808  1.0
  P  P2  1  0.335  0.646  0.002  1.0
  P  P3  1  0.207  0.254  0.685  1.0
  P  P4  1  0.793  0.746  0.315  1.0
  P  P5  1  0.665  0.354  0.998  1.0
  Cl  Cl6  1  0.575  0.251  0.337  1.0
  Cl  Cl7  1  0.993  0.687  0.419  1.0
  Cl  Cl8  1  0.641  0.169  0.869  1.0
  Cl  Cl9  1  0.007  0.313  0.581  1.0
  Cl  Cl10  1  0.359  0.831  0.131  1.0
  Cl  Cl11  1  0.283  0.133  0.558  1.0
  Cl  Cl12  1  0.115  0.630  0.875  1.0
  Cl  Cl13  1  0.885  0.370  0.125  1.0
  Cl  Cl14  1  0.324  0.481  0.341  1.0
  Cl  Cl15  1  0.893  0.915  0.209  1.0
  Cl  Cl16  1  0.676  0.519  0.659  1.0
  Cl  Cl17  1  0.717  0.867  0.442  1.0
  Cl  Cl18  1  0.107  0.085  0.791  1.0
  Cl  Cl19  1  0.425  0.749  0.663  1.0
  O  O20  1  0.688  0.511  0.936  1.0
  O  O21  1  0.481  0.697  0.939  1.0
  O  O22  1  0.658  0.606  0.237  1.0
  O  O23  1  0.764  0.810  0.847  1.0
  O  O24  1  0.236  0.190  0.153  1.0
  O  O25  1  0.342  0.394  0.763  1.0
  O  O26  1  0.312  0.489  0.064  1.0
  O  O27  1  0.519  0.303  0.061  1.0
[/CIF]
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The compound described by VP2O4Cl7 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one VP2O4Cl7 cluster. V(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one Cl(1), and one Cl(6) atom. There are two inequivalent P sites. In the first P site, P(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one Cl(3), and one Cl(5) atom. In the second P site, P(2) is bonded in a tetrahedral geometry to one O(3), one Cl(2), one Cl(4), and one Cl(7) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one V(1) and one P(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one V(1) and one P(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one V(1) and one P(2) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one V(1) atom. There are seven inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one V(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one P(2) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one P(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one P(2) atom. In the fifth Cl site, Cl(5) is bonded in a single-bond geometry to one P(1) atom. In the sixth Cl site, Cl(6) is bonded in a single-bond geometry to one V(1) atom. In the seventh Cl site, Cl(7) is bonded in a single-bond geometry to one P(2) atom. is represented by the CIF file [CIF]
data_VP2Cl7O4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.413
_cell_length_b   8.569
_cell_length_c   10.748
_cell_angle_alpha   92.052
_cell_angle_beta   103.311
_cell_angle_gamma   105.714
_symmetry_Int_Tables_number   1
_cell_volume   721.827
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.398  0.348  0.192  1.0
  V  V1  1  0.602  0.652  0.808  1.0
  P  P2  1  0.335  0.646  0.002  1.0
  P  P3  1  0.207  0.254  0.685  1.0
  P  P4  1  0.793  0.746  0.315  1.0
  P  P5  1  0.665  0.354  0.998  1.0
  Cl  Cl6  1  0.575  0.251  0.337  1.0
  Cl  Cl7  1  0.993  0.687  0.419  1.0
  Cl  Cl8  1  0.641  0.169  0.869  1.0
  Cl  Cl9  1  0.007  0.313  0.581  1.0
  Cl  Cl10  1  0.359  0.831  0.131  1.0
  Cl  Cl11  1  0.283  0.133  0.558  1.0
  Cl  Cl12  1  0.115  0.630  0.875  1.0
  Cl  Cl13  1  0.885  0.370  0.125  1.0
  Cl  Cl14  1  0.324  0.481  0.341  1.0
  Cl  Cl15  1  0.893  0.915  0.209  1.0
  Cl  Cl16  1  0.676  0.519  0.659  1.0
  Cl  Cl17  1  0.717  0.867  0.442  1.0
  Cl  Cl18  1  0.107  0.085  0.791  1.0
  Cl  Cl19  1  0.425  0.749  0.663  1.0
  O  O20  1  0.688  0.511  0.936  1.0
  O  O21  1  0.481  0.697  0.939  1.0
  O  O22  1  0.658  0.606  0.237  1.0
  O  O23  1  0.764  0.810  0.847  1.0
  O  O24  1  0.236  0.190  0.153  1.0
  O  O25  1  0.342  0.394  0.763  1.0
  O  O26  1  0.312  0.489  0.064  1.0
  O  O27  1  0.519  0.303  0.061  1.0
[/CIF]
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