The compound described by CsOsC3(OCl)3 crystallizes in the monoclinic P2_1/c space group. Cs(1) is bonded in a 8-coordinate geometry to one O(2), two equivalent Cl(1), two equivalent Cl(3), and three equivalent Cl(2) atoms. Os(1) is bonded in an octahedral geometry to one C(1), one C(2), one C(3), one Cl(1), one Cl(2), and one Cl(3) atom. There are three inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Os(1) and one O(1) atom. In the second C site, C(2) is bonded in a linear geometry to one Os(1) and one O(2) atom. In the third C site, C(3) is bonded in a linear geometry to one Os(1) and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Cs(1) and one C(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(3) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a trigonal non-coplanar geometry to two equivalent Cs(1) and one Os(1) atom. In the second Cl site, Cl(2) is bonded in a 4-coordinate geometry to three equivalent Cs(1) and one Os(1) atom. In the third Cl site, Cl(3) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Cs(1) and one Os(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CsOsC3(ClO)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.334
_cell_length_b   10.155
_cell_length_c   11.382
_cell_angle_alpha   88.890
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1078.723
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.248  0.881  0.043  1.0
  Cs  Cs1  1  0.748  0.119  0.457  1.0
  Cs  Cs2  1  0.752  0.119  0.957  1.0
  Cs  Cs3  1  0.252  0.881  0.543  1.0
  Os  Os4  1  0.120  0.296  0.710  1.0
  Os  Os5  1  0.620  0.704  0.790  1.0
  Os  Os6  1  0.880  0.704  0.290  1.0
  Os  Os7  1  0.380  0.296  0.210  1.0
  C  C8  1  0.120  0.368  0.862  1.0
  C  C9  1  0.620  0.632  0.638  1.0
  C  C10  1  0.880  0.632  0.138  1.0
  C  C11  1  0.380  0.368  0.362  1.0
  C  C12  1  0.129  0.464  0.636  1.0
  C  C13  1  0.629  0.536  0.864  1.0
  C  C14  1  0.871  0.536  0.364  1.0
  C  C15  1  0.371  0.464  0.136  1.0
  C  C16  1  0.321  0.276  0.709  1.0
  C  C17  1  0.821  0.724  0.791  1.0
  C  C18  1  0.679  0.724  0.291  1.0
  C  C19  1  0.179  0.276  0.209  1.0
  Cl  Cl20  1  0.109  0.198  0.514  1.0
  Cl  Cl21  1  0.609  0.802  0.986  1.0
  Cl  Cl22  1  0.891  0.802  0.486  1.0
  Cl  Cl23  1  0.391  0.198  0.014  1.0
  Cl  Cl24  1  0.087  0.071  0.792  1.0
  Cl  Cl25  1  0.587  0.929  0.708  1.0
  Cl  Cl26  1  0.913  0.929  0.208  1.0
  Cl  Cl27  1  0.413  0.071  0.292  1.0
  Cl  Cl28  1  0.857  0.314  0.705  1.0
  Cl  Cl29  1  0.357  0.686  0.795  1.0
  Cl  Cl30  1  0.143  0.686  0.295  1.0
  Cl  Cl31  1  0.643  0.314  0.205  1.0
  O  O32  1  0.116  0.412  0.955  1.0
  O  O33  1  0.616  0.588  0.545  1.0
  O  O34  1  0.884  0.588  0.045  1.0
  O  O35  1  0.384  0.412  0.455  1.0
  O  O36  1  0.132  0.566  0.588  1.0
  O  O37  1  0.632  0.434  0.912  1.0
  O  O38  1  0.868  0.434  0.412  1.0
  O  O39  1  0.368  0.566  0.088  1.0
  O  O40  1  0.445  0.263  0.706  1.0
  O  O41  1  0.945  0.737  0.794  1.0
  O  O42  1  0.555  0.737  0.294  1.0
  O  O43  1  0.055  0.263  0.206  1.0
[/CIF]
.
The compound described by CsOsC3(OCl)3 crystallizes in the monoclinic P2_1/c space group. Cs(1) is bonded in a 8-coordinate geometry to one O(2), two equivalent Cl(1), two equivalent Cl(3), and three equivalent Cl(2) atoms. Os(1) is bonded in an octahedral geometry to one C(1), one C(2), one C(3), one Cl(1), one Cl(2), and one Cl(3) atom. There are three inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Os(1) and one O(1) atom. In the second C site, C(2) is bonded in a linear geometry to one Os(1) and one O(2) atom. In the third C site, C(3) is bonded in a linear geometry to one Os(1) and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Cs(1) and one C(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(3) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a trigonal non-coplanar geometry to two equivalent Cs(1) and one Os(1) atom. In the second Cl site, Cl(2) is bonded in a 4-coordinate geometry to three equivalent Cs(1) and one Os(1) atom. In the third Cl site, Cl(3) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Cs(1) and one Os(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CsOsC3(ClO)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.334
_cell_length_b   10.155
_cell_length_c   11.382
_cell_angle_alpha   88.890
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1078.723
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.248  0.881  0.043  1.0
  Cs  Cs1  1  0.748  0.119  0.457  1.0
  Cs  Cs2  1  0.752  0.119  0.957  1.0
  Cs  Cs3  1  0.252  0.881  0.543  1.0
  Os  Os4  1  0.120  0.296  0.710  1.0
  Os  Os5  1  0.620  0.704  0.790  1.0
  Os  Os6  1  0.880  0.704  0.290  1.0
  Os  Os7  1  0.380  0.296  0.210  1.0
  C  C8  1  0.120  0.368  0.862  1.0
  C  C9  1  0.620  0.632  0.638  1.0
  C  C10  1  0.880  0.632  0.138  1.0
  C  C11  1  0.380  0.368  0.362  1.0
  C  C12  1  0.129  0.464  0.636  1.0
  C  C13  1  0.629  0.536  0.864  1.0
  C  C14  1  0.871  0.536  0.364  1.0
  C  C15  1  0.371  0.464  0.136  1.0
  C  C16  1  0.321  0.276  0.709  1.0
  C  C17  1  0.821  0.724  0.791  1.0
  C  C18  1  0.679  0.724  0.291  1.0
  C  C19  1  0.179  0.276  0.209  1.0
  Cl  Cl20  1  0.109  0.198  0.514  1.0
  Cl  Cl21  1  0.609  0.802  0.986  1.0
  Cl  Cl22  1  0.891  0.802  0.486  1.0
  Cl  Cl23  1  0.391  0.198  0.014  1.0
  Cl  Cl24  1  0.087  0.071  0.792  1.0
  Cl  Cl25  1  0.587  0.929  0.708  1.0
  Cl  Cl26  1  0.913  0.929  0.208  1.0
  Cl  Cl27  1  0.413  0.071  0.292  1.0
  Cl  Cl28  1  0.857  0.314  0.705  1.0
  Cl  Cl29  1  0.357  0.686  0.795  1.0
  Cl  Cl30  1  0.143  0.686  0.295  1.0
  Cl  Cl31  1  0.643  0.314  0.205  1.0
  O  O32  1  0.116  0.412  0.955  1.0
  O  O33  1  0.616  0.588  0.545  1.0
  O  O34  1  0.884  0.588  0.045  1.0
  O  O35  1  0.384  0.412  0.455  1.0
  O  O36  1  0.132  0.566  0.588  1.0
  O  O37  1  0.632  0.434  0.912  1.0
  O  O38  1  0.868  0.434  0.412  1.0
  O  O39  1  0.368  0.566  0.088  1.0
  O  O40  1  0.445  0.263  0.706  1.0
  O  O41  1  0.945  0.737  0.794  1.0
  O  O42  1  0.555  0.737  0.294  1.0
  O  O43  1  0.055  0.263  0.206  1.0
[/CIF]
.