The material described by AgCO2 crystallizes in the monoclinic P2_1/c space group. Ag(1) is bonded in a 4-coordinate geometry to two equivalent O(1) and two equivalent O(2) atoms. C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to two equivalent Ag(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent Ag(1) and one C(1) atom. is represented by the CIF card [CIF]
data_AgCO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.946
_cell_length_b   4.010
_cell_length_c   9.977
_cell_angle_alpha   70.867
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   224.739
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.993  0.855  0.651  1.0
  Ag  Ag1  1  0.493  0.145  0.849  1.0
  Ag  Ag2  1  0.007  0.145  0.349  1.0
  Ag  Ag3  1  0.507  0.855  0.151  1.0
  C  C4  1  0.889  0.396  0.999  1.0
  C  C5  1  0.111  0.604  0.001  1.0
  C  C6  1  0.611  0.396  0.499  1.0
  C  C7  1  0.389  0.604  0.501  1.0
  O  O8  1  0.327  0.826  0.384  1.0
  O  O9  1  0.173  0.826  0.884  1.0
  O  O10  1  0.827  0.174  0.116  1.0
  O  O11  1  0.673  0.174  0.616  1.0
  O  O12  1  0.710  0.466  0.380  1.0
  O  O13  1  0.210  0.534  0.120  1.0
  O  O14  1  0.290  0.534  0.620  1.0
  O  O15  1  0.790  0.466  0.880  1.0
[/CIF]
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The material described by AgCO2 crystallizes in the monoclinic P2_1/c space group. Ag(1) is bonded in a 4-coordinate geometry to two equivalent O(1) and two equivalent O(2) atoms. C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to two equivalent Ag(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent Ag(1) and one C(1) atom. is represented by the CIF card [CIF]
data_AgCO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.946
_cell_length_b   4.010
_cell_length_c   9.977
_cell_angle_alpha   70.867
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   224.739
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.993  0.855  0.651  1.0
  Ag  Ag1  1  0.493  0.145  0.849  1.0
  Ag  Ag2  1  0.007  0.145  0.349  1.0
  Ag  Ag3  1  0.507  0.855  0.151  1.0
  C  C4  1  0.889  0.396  0.999  1.0
  C  C5  1  0.111  0.604  0.001  1.0
  C  C6  1  0.611  0.396  0.499  1.0
  C  C7  1  0.389  0.604  0.501  1.0
  O  O8  1  0.327  0.826  0.384  1.0
  O  O9  1  0.173  0.826  0.884  1.0
  O  O10  1  0.827  0.174  0.116  1.0
  O  O11  1  0.673  0.174  0.616  1.0
  O  O12  1  0.710  0.466  0.380  1.0
  O  O13  1  0.210  0.534  0.120  1.0
  O  O14  1  0.290  0.534  0.620  1.0
  O  O15  1  0.790  0.466  0.880  1.0
[/CIF]
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