The material structure described by Ag6Mo10O33 crystallizes in the triclinic P-1 space group. There are five inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 6-coordinate geometry to one O(10), one O(15), one O(16), one O(17), and two equivalent O(13) atoms. In the second Mo site, Mo(2) is bonded in a 6-coordinate geometry to one O(11), one O(14), one O(16), one O(17), and two equivalent O(12) atoms. In the third Mo site, Mo(3) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(5), one O(6), and one O(9) atom. In the fourth Mo site, Mo(4) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(7), and one O(8) atom. In the fifth Mo site, Mo(5) is bonded in a 6-coordinate geometry to one O(12), one O(13), one O(16), one O(17), one O(8), and one O(9) atom. There are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a distorted trigonal bipyramidal geometry to one O(12), one O(13), one O(3), one O(6), and one O(7) atom. In the second Ag site, Ag(2) is bonded in a 6-coordinate geometry to one O(10), one O(11), one O(14), one O(2), one O(4), and one O(6) atom. In the third Ag site, Ag(3) is bonded in a 5-coordinate geometry to one O(10), one O(15), one O(4), one O(5), and one O(7) atom. There are seventeen inequivalent O sites. In the first O site, O(1) is bonded in a square co-planar geometry to two equivalent Mo(3) and two equivalent Mo(4) atoms. In the second O site, O(2) is bonded in a trigonal non-coplanar geometry to one Mo(3), one Mo(4), and one Ag(2) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Mo(3), one Mo(4), and one Ag(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Mo(4), one Ag(2), and one Ag(3) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Mo(3) and one Ag(3) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Mo(3), one Ag(1), and one Ag(2) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one Mo(4), one Ag(1), and one Ag(3) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one Mo(4) and one Mo(5) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one Mo(3) and one Mo(5) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Mo(1), one Ag(2), and one Ag(3) atom. In the eleventh O site, O(11) is bonded in a bent 150 degrees geometry to one Mo(2) and one Ag(2) atom. In the twelfth O site, O(12) is bonded to one Mo(5), two equivalent Mo(2), and one Ag(1) atom to form a mixture of corner and edge-sharing OAgMo3 tetrahedra. In the thirteenth O site, O(13) is bonded to one Mo(5), two equivalent Mo(1), and one Ag(1) atom to form a mixture of corner and edge-sharing OAgMo3 tetrahedra. In the fourteenth O site, O(14) is bonded in a single-bond geometry to one Mo(2) and one Ag(2) atom. In the fifteenth O site, O(15) is bonded in a bent 150 degrees geometry to one Mo(1) and one Ag(3) atom. In the sixteenth O site, O(16) is bonded in a 3-coordinate geometry to one Mo(1), one Mo(2), and one Mo(5) atom. In the seventeenth O site, O(17) is bonded in a 3-coordinate geometry to one Mo(1), one Mo(2), and one Mo(5) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ag6Mo10O33
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.667
_cell_length_b   8.442
_cell_length_c   11.470
_cell_angle_alpha   82.425
_cell_angle_beta   77.375
_cell_angle_gamma   73.866
_symmetry_Int_Tables_number   1
_cell_volume   693.933
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.347  0.005  0.248  1.0
  Ag  Ag1  1  0.653  0.995  0.752  1.0
  Ag  Ag2  1  0.162  0.478  0.211  1.0
  Ag  Ag3  1  0.838  0.522  0.789  1.0
  Ag  Ag4  1  0.555  0.524  0.238  1.0
  Ag  Ag5  1  0.445  0.476  0.762  1.0
  Mo  Mo6  1  0.431  0.226  0.489  1.0
  Mo  Mo7  1  0.569  0.774  0.511  1.0
  Mo  Mo8  1  0.928  0.231  0.490  1.0
  Mo  Mo9  1  0.072  0.769  0.510  1.0
  Mo  Mo10  1  0.856  0.802  0.030  1.0
  Mo  Mo11  1  0.144  0.198  0.970  1.0
  Mo  Mo12  1  0.703  0.203  0.015  1.0
  Mo  Mo13  1  0.297  0.797  0.985  1.0
  Mo  Mo14  1  0.817  1.000  0.318  1.0
  Mo  Mo15  1  0.183  0.000  0.682  1.0
  O  O16  1  0.000  0.000  0.000  1.0
  O  O17  1  0.113  0.670  0.024  1.0
  O  O18  1  0.887  0.330  0.976  1.0
  O  O19  1  0.651  0.994  0.079  1.0
  O  O20  1  0.349  0.006  0.921  1.0
  O  O21  1  0.510  0.348  0.085  1.0
  O  O22  1  0.490  0.652  0.915  1.0
  O  O23  1  0.754  0.649  0.112  1.0
  O  O24  1  0.246  0.351  0.888  1.0
  O  O25  1  0.172  0.203  0.117  1.0
  O  O26  1  0.828  0.797  0.883  1.0
  O  O27  1  0.337  0.796  0.130  1.0
  O  O28  1  0.663  0.204  0.870  1.0
  O  O29  1  0.781  0.171  0.212  1.0
  O  O30  1  0.219  0.829  0.788  1.0
  O  O31  1  0.902  0.832  0.227  1.0
  O  O32  1  0.098  0.168  0.773  1.0
  O  O33  1  0.402  0.335  0.349  1.0
  O  O34  1  0.598  0.665  0.651  1.0
  O  O35  1  0.962  0.373  0.368  1.0
  O  O36  1  0.038  0.627  0.632  1.0
  O  O37  1  0.031  0.008  0.379  1.0
  O  O38  1  0.969  0.992  0.621  1.0
  O  O39  1  0.554  0.987  0.379  1.0
  O  O40  1  0.446  0.013  0.621  1.0
  O  O41  1  0.184  0.653  0.388  1.0
  O  O42  1  0.816  0.347  0.612  1.0
  O  O43  1  0.610  0.625  0.411  1.0
  O  O44  1  0.390  0.375  0.589  1.0
  O  O45  1  0.704  0.174  0.466  1.0
  O  O46  1  0.296  0.826  0.534  1.0
  O  O47  1  0.815  0.824  0.482  1.0
  O  O48  1  0.185  0.176  0.518  1.0
[/CIF]
.
The material structure described by Ag6Mo10O33 crystallizes in the triclinic P-1 space group. There are five inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 6-coordinate geometry to one O(10), one O(15), one O(16), one O(17), and two equivalent O(13) atoms. In the second Mo site, Mo(2) is bonded in a 6-coordinate geometry to one O(11), one O(14), one O(16), one O(17), and two equivalent O(12) atoms. In the third Mo site, Mo(3) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(5), one O(6), and one O(9) atom. In the fourth Mo site, Mo(4) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(7), and one O(8) atom. In the fifth Mo site, Mo(5) is bonded in a 6-coordinate geometry to one O(12), one O(13), one O(16), one O(17), one O(8), and one O(9) atom. There are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a distorted trigonal bipyramidal geometry to one O(12), one O(13), one O(3), one O(6), and one O(7) atom. In the second Ag site, Ag(2) is bonded in a 6-coordinate geometry to one O(10), one O(11), one O(14), one O(2), one O(4), and one O(6) atom. In the third Ag site, Ag(3) is bonded in a 5-coordinate geometry to one O(10), one O(15), one O(4), one O(5), and one O(7) atom. There are seventeen inequivalent O sites. In the first O site, O(1) is bonded in a square co-planar geometry to two equivalent Mo(3) and two equivalent Mo(4) atoms. In the second O site, O(2) is bonded in a trigonal non-coplanar geometry to one Mo(3), one Mo(4), and one Ag(2) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Mo(3), one Mo(4), and one Ag(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Mo(4), one Ag(2), and one Ag(3) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Mo(3) and one Ag(3) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Mo(3), one Ag(1), and one Ag(2) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one Mo(4), one Ag(1), and one Ag(3) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one Mo(4) and one Mo(5) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one Mo(3) and one Mo(5) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Mo(1), one Ag(2), and one Ag(3) atom. In the eleventh O site, O(11) is bonded in a bent 150 degrees geometry to one Mo(2) and one Ag(2) atom. In the twelfth O site, O(12) is bonded to one Mo(5), two equivalent Mo(2), and one Ag(1) atom to form a mixture of corner and edge-sharing OAgMo3 tetrahedra. In the thirteenth O site, O(13) is bonded to one Mo(5), two equivalent Mo(1), and one Ag(1) atom to form a mixture of corner and edge-sharing OAgMo3 tetrahedra. In the fourteenth O site, O(14) is bonded in a single-bond geometry to one Mo(2) and one Ag(2) atom. In the fifteenth O site, O(15) is bonded in a bent 150 degrees geometry to one Mo(1) and one Ag(3) atom. In the sixteenth O site, O(16) is bonded in a 3-coordinate geometry to one Mo(1), one Mo(2), and one Mo(5) atom. In the seventeenth O site, O(17) is bonded in a 3-coordinate geometry to one Mo(1), one Mo(2), and one Mo(5) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ag6Mo10O33
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.667
_cell_length_b   8.442
_cell_length_c   11.470
_cell_angle_alpha   82.425
_cell_angle_beta   77.375
_cell_angle_gamma   73.866
_symmetry_Int_Tables_number   1
_cell_volume   693.933
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.347  0.005  0.248  1.0
  Ag  Ag1  1  0.653  0.995  0.752  1.0
  Ag  Ag2  1  0.162  0.478  0.211  1.0
  Ag  Ag3  1  0.838  0.522  0.789  1.0
  Ag  Ag4  1  0.555  0.524  0.238  1.0
  Ag  Ag5  1  0.445  0.476  0.762  1.0
  Mo  Mo6  1  0.431  0.226  0.489  1.0
  Mo  Mo7  1  0.569  0.774  0.511  1.0
  Mo  Mo8  1  0.928  0.231  0.490  1.0
  Mo  Mo9  1  0.072  0.769  0.510  1.0
  Mo  Mo10  1  0.856  0.802  0.030  1.0
  Mo  Mo11  1  0.144  0.198  0.970  1.0
  Mo  Mo12  1  0.703  0.203  0.015  1.0
  Mo  Mo13  1  0.297  0.797  0.985  1.0
  Mo  Mo14  1  0.817  1.000  0.318  1.0
  Mo  Mo15  1  0.183  0.000  0.682  1.0
  O  O16  1  0.000  0.000  0.000  1.0
  O  O17  1  0.113  0.670  0.024  1.0
  O  O18  1  0.887  0.330  0.976  1.0
  O  O19  1  0.651  0.994  0.079  1.0
  O  O20  1  0.349  0.006  0.921  1.0
  O  O21  1  0.510  0.348  0.085  1.0
  O  O22  1  0.490  0.652  0.915  1.0
  O  O23  1  0.754  0.649  0.112  1.0
  O  O24  1  0.246  0.351  0.888  1.0
  O  O25  1  0.172  0.203  0.117  1.0
  O  O26  1  0.828  0.797  0.883  1.0
  O  O27  1  0.337  0.796  0.130  1.0
  O  O28  1  0.663  0.204  0.870  1.0
  O  O29  1  0.781  0.171  0.212  1.0
  O  O30  1  0.219  0.829  0.788  1.0
  O  O31  1  0.902  0.832  0.227  1.0
  O  O32  1  0.098  0.168  0.773  1.0
  O  O33  1  0.402  0.335  0.349  1.0
  O  O34  1  0.598  0.665  0.651  1.0
  O  O35  1  0.962  0.373  0.368  1.0
  O  O36  1  0.038  0.627  0.632  1.0
  O  O37  1  0.031  0.008  0.379  1.0
  O  O38  1  0.969  0.992  0.621  1.0
  O  O39  1  0.554  0.987  0.379  1.0
  O  O40  1  0.446  0.013  0.621  1.0
  O  O41  1  0.184  0.653  0.388  1.0
  O  O42  1  0.816  0.347  0.612  1.0
  O  O43  1  0.610  0.625  0.411  1.0
  O  O44  1  0.390  0.375  0.589  1.0
  O  O45  1  0.704  0.174  0.466  1.0
  O  O46  1  0.296  0.826  0.534  1.0
  O  O47  1  0.815  0.824  0.482  1.0
  O  O48  1  0.185  0.176  0.518  1.0
[/CIF]
.