The structure described by Li2U(MoO5)2 crystallizes in the triclinic P-1 space group. Li(1) is bonded in a 6-coordinate geometry to one O(2), one O(3), two equivalent O(1), and two equivalent O(5) atoms. U(1) is bonded in a distorted square co-planar geometry to two equivalent O(3) and two equivalent O(4) atoms. Mo(1) is bonded in a 1-coordinate geometry to one O(1), one O(2), one O(4), and one O(5) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a 1-coordinate geometry to two equivalent Li(1) and one Mo(1) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Li(1) and one Mo(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Li(1) and one U(1) atom. In the fourth O site, O(4) is bonded in a linear geometry to one U(1) and one Mo(1) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to two equivalent Li(1) and one Mo(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li2U(MoO5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.509
_cell_length_b   5.935
_cell_length_c   8.386
_cell_angle_alpha   108.212
_cell_angle_beta   100.095
_cell_angle_gamma   104.706
_symmetry_Int_Tables_number   1
_cell_volume   242.033
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.053  0.791  0.425  1.0
  Li  Li1  1  0.947  0.209  0.575  1.0
  U  U2  1  0.000  0.000  0.000  1.0
  Mo  Mo3  1  0.617  0.349  0.300  1.0
  Mo  Mo4  1  0.383  0.651  0.700  1.0
  O  O5  1  0.229  0.589  0.550  1.0
  O  O6  1  0.646  0.640  0.153  1.0
  O  O7  1  0.852  0.095  0.840  1.0
  O  O8  1  0.797  0.194  0.171  1.0
  O  O9  1  0.726  0.846  0.582  1.0
  O  O10  1  0.203  0.806  0.829  1.0
  O  O11  1  0.354  0.360  0.847  1.0
  O  O12  1  0.274  0.154  0.418  1.0
  O  O13  1  0.771  0.411  0.450  1.0
  O  O14  1  0.148  0.905  0.160  1.0
[/CIF]
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The structure described by Li2U(MoO5)2 crystallizes in the triclinic P-1 space group. Li(1) is bonded in a 6-coordinate geometry to one O(2), one O(3), two equivalent O(1), and two equivalent O(5) atoms. U(1) is bonded in a distorted square co-planar geometry to two equivalent O(3) and two equivalent O(4) atoms. Mo(1) is bonded in a 1-coordinate geometry to one O(1), one O(2), one O(4), and one O(5) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a 1-coordinate geometry to two equivalent Li(1) and one Mo(1) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Li(1) and one Mo(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Li(1) and one U(1) atom. In the fourth O site, O(4) is bonded in a linear geometry to one U(1) and one Mo(1) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to two equivalent Li(1) and one Mo(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li2U(MoO5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.509
_cell_length_b   5.935
_cell_length_c   8.386
_cell_angle_alpha   108.212
_cell_angle_beta   100.095
_cell_angle_gamma   104.706
_symmetry_Int_Tables_number   1
_cell_volume   242.033
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.053  0.791  0.425  1.0
  Li  Li1  1  0.947  0.209  0.575  1.0
  U  U2  1  0.000  0.000  0.000  1.0
  Mo  Mo3  1  0.617  0.349  0.300  1.0
  Mo  Mo4  1  0.383  0.651  0.700  1.0
  O  O5  1  0.229  0.589  0.550  1.0
  O  O6  1  0.646  0.640  0.153  1.0
  O  O7  1  0.852  0.095  0.840  1.0
  O  O8  1  0.797  0.194  0.171  1.0
  O  O9  1  0.726  0.846  0.582  1.0
  O  O10  1  0.203  0.806  0.829  1.0
  O  O11  1  0.354  0.360  0.847  1.0
  O  O12  1  0.274  0.154  0.418  1.0
  O  O13  1  0.771  0.411  0.450  1.0
  O  O14  1  0.148  0.905  0.160  1.0
[/CIF]
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