The crystal structure described by NaLi5Mn2P2(CO7)2 crystallizes in the triclinic P1 space group. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded in a 6-coordinate geometry to one O(1), one O(10), one O(2), one O(24), one O(25), and one O(9) atom. In the second Na site, Na(2) is bonded in a 7-coordinate geometry to one O(13), one O(14), one O(2), one O(3), one O(6), one O(7), and one O(9) atom. There are ten inequivalent Li sites. In the first Li site, Li(1) is bonded in a 5-coordinate geometry to one O(1), one O(23), one O(26), one O(7), and one O(8) atom. In the second Li site, Li(2) is bonded in a 5-coordinate geometry to one O(1), one O(11), one O(12), one O(5), and one O(9) atom. In the third Li site, Li(3) is bonded in a 5-coordinate geometry to one O(1), one O(10), one O(11), one O(12), and one O(5) atom. In the fourth Li site, Li(4) is bonded in a 4-coordinate geometry to one O(13), one O(14), one O(2), one O(6), and one O(8) atom. In the fifth Li site, Li(5) is bonded in a 6-coordinate geometry to one O(15), one O(16), one O(21), one O(23), one O(26), and one O(27) atom. In the sixth Li site, Li(6) is bonded in a 6-coordinate geometry to one O(15), one O(16), one O(22), one O(23), one O(26), and one O(27) atom. In the seventh Li site, Li(7) is bonded in a 4-coordinate geometry to one O(17), one O(18), one O(19), one O(24), and one O(28) atom. In the eighth Li site, Li(8) is bonded in a 6-coordinate geometry to one O(17), one O(18), one O(20), one O(24), one O(25), and one O(28) atom. In the ninth Li site, Li(9) is bonded in a 5-coordinate geometry to one O(19), one O(20), one O(27), one O(4), and one O(5) atom. In the tenth Li site, Li(10) is bonded in a 5-coordinate geometry to one O(21), one O(22), one O(28), one O(3), and one O(6) atom. There are four inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a 6-coordinate geometry to one O(14), one O(16), one O(3), one O(5), one O(7), and one O(8) atom. In the second Mn site, Mn(2) is bonded in a 6-coordinate geometry to one O(10), one O(12), one O(18), one O(4), one O(6), and one O(9) atom. In the third Mn site, Mn(3) is bonded to one O(11), one O(17), one O(19), one O(20), one O(23), and one O(25) atom to form distorted MnO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, and corners with two equivalent P(3)O4 tetrahedra. In the fourth Mn site, Mn(4) is bonded in a 6-coordinate geometry to one O(13), one O(15), one O(21), one O(22), one O(24), and one O(26) atom. There are four inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one O(27), one O(3), and one O(5) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one O(28), one O(4), and one O(6) atom. In the third C site, C(3) is bonded in a trigonal planar geometry to one O(1), one O(23), and one O(25) atom. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one O(2), one O(24), and one O(26) atom. There are four inequivalent P sites. In the first P site, P(1) is bonded to one O(11), one O(15), one O(7), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles are 68°. In the second P site, P(2) is bonded to one O(10), one O(13), one O(17), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles are 58°. In the third P site, P(3) is bonded to one O(12), one O(16), one O(19), and one O(20) atom to form PO4 tetrahedra that share corners with two equivalent Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles are 49°. In the fourth P site, P(4) is bonded in a tetrahedral geometry to one O(14), one O(18), one O(21), and one O(22) atom. There are twenty-eight inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Na(1), one Li(1), one Li(2), one Li(3), and one C(3) atom. In the second O site, O(2) is bonded to one Na(1), one Na(2), one Li(4), and one C(4) atom to form distorted ONa2LiC trigonal pyramids that share  a cornercorner with one O(8)Li2MnP trigonal pyramid,  a cornercorner with one O(10)NaLiMnP trigonal pyramid, and  an edgeedge with one O(13)NaLiMnP tetrahedra. In the third O site, O(3) is bonded in a 2-coordinate geometry to one Na(2), one Li(10), one Mn(1), and one C(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Li(9), one Mn(2), and one C(2) atom. In the fifth O site, O(5) is bonded to one Li(2), one Li(3), one Li(9), one Mn(1), and one C(1) atom to form distorted OLi3MnC trigonal bipyramids that share  a cornercorner with one O(16)Li2MnP tetrahedra, corners with two equivalent O(11)Li2MnP tetrahedra,  a cornercorner with one O(19)Li2MnP trigonal pyramid,  a cornercorner with one O(20)Li2MnP trigonal pyramid,  a cornercorner with one O(8)Li2MnP trigonal pyramid,  a cornercorner with one O(10)NaLiMnP trigonal pyramid, and  an edgeedge with one O(27)Li3C tetrahedra. In the sixth O site, O(6) is bonded in a 5-coordinate geometry to one Na(2), one Li(10), one Li(4), one Mn(2), and one C(2) atom. In the seventh O site, O(7) is bonded in a 4-coordinate geometry to one Na(2), one Li(1), one Mn(1), and one P(1) atom. In the eighth O site, O(8) is bonded to one Li(1), one Li(4), one Mn(1), and one P(1) atom to form distorted OLi2MnP trigonal pyramids that share  a cornercorner with one O(11)Li2MnP tetrahedra,  a cornercorner with one O(16)Li2MnP tetrahedra,  a cornercorner with one O(13)NaLiMnP tetrahedra,  a cornercorner with one O(23)Li3MnC trigonal bipyramid,  a cornercorner with one O(5)Li3MnC trigonal bipyramid, and  a cornercorner with one O(2)Na2LiC trigonal pyramid. In the ninth O site, O(9) is bonded in a 4-coordinate geometry to one Na(1), one Na(2), one Li(2), one Mn(2), and one P(2) atom. In the tenth O site, O(10) is bonded to one Na(1), one Li(3), one Mn(2), and one P(2) atom to form distorted ONaLiMnP trigonal pyramids that share  a cornercorner with one O(11)Li2MnP tetrahedra,  a cornercorner with one O(18)Li2MnP tetrahedra,  a cornercorner with one O(13)NaLiMnP tetrahedra,  a cornercorner with one O(5)Li3MnC trigonal bipyramid, and  a cornercorner with one O(2)Na2LiC trigonal pyramid. In the eleventh O site, O(11) is bonded to one Li(2), one Li(3), one Mn(3), and one P(1) atom to form OLi2MnP tetrahedra that share  a cornercorner with one O(23)Li3MnC trigonal bipyramid, corners with two equivalent O(5)Li3MnC trigonal bipyramids,  a cornercorner with one O(19)Li2MnP trigonal pyramid,  a cornercorner with one O(20)Li2MnP trigonal pyramid,  a cornercorner with one O(8)Li2MnP trigonal pyramid, and  a cornercorner with one O(10)NaLiMnP trigonal pyramid. In the twelfth O site, O(12) is bonded in a 4-coordinate geometry to one Li(2), one Li(3), one Mn(2), and one P(3) atom. In the thirteenth O site, O(13) is bonded to one Na(2), one Li(4), one Mn(4), and one P(2) atom to form distorted ONaLiMnP tetrahedra that share  a cornercorner with one O(21)Li2MnP trigonal pyramid,  a cornercorner with one O(8)Li2MnP trigonal pyramid,  a cornercorner with one O(10)NaLiMnP trigonal pyramid, and  an edgeedge with one O(2)Na2LiC trigonal pyramid. In the fourteenth O site, O(14) is bonded in a 4-coordinate geometry to one Na(2), one Li(4), one Mn(1), and one P(4) atom. In the fifteenth O site, O(15) is bonded in a 4-coordinate geometry to one Li(5), one Li(6), one Mn(4), and one P(1) atom. In the sixteenth O site, O(16) is bonded to one Li(5), one Li(6), one Mn(1), and one P(3) atom to form OLi2MnP tetrahedra that share  a cornercorner with one O(5)Li3MnC trigonal bipyramid, corners with two equivalent O(23)Li3MnC trigonal bipyramids,  a cornercorner with one O(19)Li2MnP trigonal pyramid,  a cornercorner with one O(20)Li2MnP trigonal pyramid,  a cornercorner with one O(21)Li2MnP trigonal pyramid,  a cornercorner with one O(8)Li2MnP trigonal pyramid, and  an edgeedge with one O(27)Li3C tetrahedra. In the seventeenth O site, O(17) is bonded in a 4-coordinate geometry to one Li(7), one Li(8), one Mn(3), and one P(2) atom. In the eighteenth O site, O(18) is bonded to one Li(7), one Li(8), one Mn(2), and one P(4) atom to form OLi2MnP tetrahedra that share  a cornercorner with one O(19)Li2MnP trigonal pyramid,  a cornercorner with one O(20)Li2MnP trigonal pyramid,  a cornercorner with one O(21)Li2MnP trigonal pyramid,  a cornercorner with one O(10)NaLiMnP trigonal pyramid, and  an edgeedge with one O(28)Li3C tetrahedra. In the nineteenth O site, O(19) is bonded to one Li(7), one Li(9), one Mn(3), and one P(3) atom to form distorted OLi2MnP trigonal pyramids that share  a cornercorner with one O(11)Li2MnP tetrahedra,  a cornercorner with one O(16)Li2MnP tetrahedra,  a cornercorner with one O(18)Li2MnP tetrahedra,  a cornercorner with one O(27)Li3C tetrahedra,  a cornercorner with one O(28)Li3C tetrahedra,  a cornercorner with one O(23)Li3MnC trigonal bipyramid,  a cornercorner with one O(5)Li3MnC trigonal bipyramid,  a cornercorner with one O(20)Li2MnP trigonal pyramid, and  an edgeedge with one O(20)Li2MnP trigonal pyramid. In the twentieth O site, O(20) is bonded to one Li(8), one Li(9), one Mn(3), and one P(3) atom to form distorted OLi2MnP trigonal pyramids that share  a cornercorner with one O(11)Li2MnP tetrahedra,  a cornercorner with one O(16)Li2MnP tetrahedra,  a cornercorner with one O(18)Li2MnP tetrahedra,  a cornercorner with one O(27)Li3C tetrahedra,  a cornercorner with one O(28)Li3C tetrahedra,  a cornercorner with one O(23)Li3MnC trigonal bipyramid,  a cornercorner with one O(5)Li3MnC trigonal bipyramid,  a cornercorner with one O(19)Li2MnP trigonal pyramid, and  an edgeedge with one O(19)Li2MnP trigonal pyramid. In the twenty-first O site, O(21) is bonded to one Li(10), one Li(5), one Mn(4), and one P(4) atom to form distorted OLi2MnP trigonal pyramids that share  a cornercorner with one O(16)Li2MnP tetrahedra,  a cornercorner with one O(18)Li2MnP tetrahedra,  a cornercorner with one O(27)Li3C tetrahedra,  a cornercorner with one O(28)Li3C tetrahedra,  a cornercorner with one O(13)NaLiMnP tetrahedra, and  a cornercorner with one O(23)Li3MnC trigonal bipyramid. In the twenty-second O site, O(22) is bonded in a 4-coordinate geometry to one Li(10), one Li(6), one Mn(4), and one P(4) atom. In the twenty-third O site, O(23) is bonded to one Li(1), one Li(5), one Li(6), one Mn(3), and one C(3) atom to form distorted OLi3MnC trigonal bipyramids that share  a cornercorner with one O(11)Li2MnP tetrahedra, corners with two equivalent O(16)Li2MnP tetrahedra, corners with two equivalent O(27)Li3C tetrahedra,  a cornercorner with one O(19)Li2MnP trigonal pyramid,  a cornercorner with one O(20)Li2MnP trigonal pyramid,  a cornercorner with one O(21)Li2MnP trigonal pyramid, and  a cornercorner with one O(8)Li2MnP trigonal pyramid. In the twenty-fourth O site, O(24) is bonded in a 5-coordinate geometry to one Na(1), one Li(7), one Li(8), one Mn(4), and one C(4) atom. In the twenty-fifth O site, O(25) is bonded in a 3-coordinate geometry to one Na(1), one Li(8), one Mn(3), and one C(3) atom. In the twenty-sixth O site, O(26) is bonded in a 2-coordinate geometry to one Li(1), one Li(5), one Li(6), one Mn(4), and one C(4) atom. In the twenty-seventh O site, O(27) is bonded to one Li(5), one Li(6), one Li(9), and one C(1) atom to form distorted OLi3C tetrahedra that share corners with two equivalent O(23)Li3MnC trigonal bipyramids,  a cornercorner with one O(19)Li2MnP trigonal pyramid,  a cornercorner with one O(20)Li2MnP trigonal pyramid,  a cornercorner with one O(21)Li2MnP trigonal pyramid,  an edgeedge with one O(16)Li2MnP tetrahedra, and  an edgeedge with one O(5)Li3MnC trigonal bipyramid. In the twenty-eighth O site, O(28) is bonded to one Li(10), one Li(7), one Li(8), and one C(2) atom to form a mixture of distorted edge and corner-sharing OLi3C tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_NaLi5Mn2P2(CO7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.633
_cell_length_b   8.654
_cell_length_c   9.987
_cell_angle_alpha   91.563
_cell_angle_beta   90.013
_cell_angle_gamma   90.436
_symmetry_Int_Tables_number   1
_cell_volume   573.039
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.255  0.085  0.622  1.0
  Na  Na1  1  0.998  0.251  0.877  1.0
  Li  Li2  1  0.255  0.078  0.125  1.0
  Li  Li3  1  0.019  0.264  0.380  1.0
  Li  Li4  1  0.480  0.265  0.382  1.0
  Li  Li5  1  0.481  0.267  0.887  1.0
  Li  Li6  1  0.517  0.739  0.117  1.0
  Li  Li7  1  0.983  0.740  0.116  1.0
  Li  Li8  1  0.519  0.734  0.615  1.0
  Li  Li9  1  0.981  0.735  0.616  1.0
  Li  Li10  1  0.749  0.917  0.373  1.0
  Li  Li11  1  0.742  0.914  0.876  1.0
  Mn  Mn12  1  0.746  0.356  0.116  1.0
  Mn  Mn13  1  0.749  0.358  0.610  1.0
  Mn  Mn14  1  0.251  0.646  0.385  1.0
  Mn  Mn15  1  0.249  0.646  0.890  1.0
  P  P16  1  0.250  0.405  0.151  1.0
  P  P17  1  0.255  0.415  0.646  1.0
  P  P18  1  0.750  0.593  0.352  1.0
  P  P19  1  0.745  0.596  0.855  1.0
  C  C20  1  0.749  0.042  0.135  1.0
  C  C21  1  0.748  0.042  0.633  1.0
  C  C22  1  0.250  0.952  0.360  1.0
  C  C23  1  0.259  0.954  0.870  1.0
  O  O24  1  0.248  0.102  0.347  1.0
  O  O25  1  0.278  0.101  0.852  1.0
  O  O26  1  0.750  0.088  0.013  1.0
  O  O27  1  0.749  0.089  0.511  1.0
  O  O28  1  0.746  0.141  0.235  1.0
  O  O29  1  0.745  0.142  0.732  1.0
  O  O30  1  0.061  0.312  0.104  1.0
  O  O31  1  0.431  0.309  0.097  1.0
  O  O32  1  0.065  0.322  0.598  1.0
  O  O33  1  0.435  0.323  0.587  1.0
  O  O34  1  0.255  0.414  0.308  1.0
  O  O35  1  0.751  0.422  0.397  1.0
  O  O36  1  0.267  0.419  0.802  1.0
  O  O37  1  0.732  0.428  0.904  1.0
  O  O38  1  0.252  0.575  0.102  1.0
  O  O39  1  0.750  0.588  0.195  1.0
  O  O40  1  0.251  0.586  0.600  1.0
  O  O41  1  0.749  0.587  0.698  1.0
  O  O42  1  0.567  0.687  0.405  1.0
  O  O43  1  0.935  0.688  0.405  1.0
  O  O44  1  0.566  0.697  0.904  1.0
  O  O45  1  0.934  0.685  0.908  1.0
  O  O46  1  0.251  0.862  0.253  1.0
  O  O47  1  0.248  0.858  0.767  1.0
  O  O48  1  0.252  0.890  0.477  1.0
  O  O49  1  0.249  0.901  0.991  1.0
  O  O50  1  0.751  0.895  0.160  1.0
  O  O51  1  0.750  0.895  0.659  1.0
[/CIF]
.
The crystal structure described by NaLi5Mn2P2(CO7)2 crystallizes in the triclinic P1 space group. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded in a 6-coordinate geometry to one O(1), one O(10), one O(2), one O(24), one O(25), and one O(9) atom. In the second Na site, Na(2) is bonded in a 7-coordinate geometry to one O(13), one O(14), one O(2), one O(3), one O(6), one O(7), and one O(9) atom. There are ten inequivalent Li sites. In the first Li site, Li(1) is bonded in a 5-coordinate geometry to one O(1), one O(23), one O(26), one O(7), and one O(8) atom. In the second Li site, Li(2) is bonded in a 5-coordinate geometry to one O(1), one O(11), one O(12), one O(5), and one O(9) atom. In the third Li site, Li(3) is bonded in a 5-coordinate geometry to one O(1), one O(10), one O(11), one O(12), and one O(5) atom. In the fourth Li site, Li(4) is bonded in a 4-coordinate geometry to one O(13), one O(14), one O(2), one O(6), and one O(8) atom. In the fifth Li site, Li(5) is bonded in a 6-coordinate geometry to one O(15), one O(16), one O(21), one O(23), one O(26), and one O(27) atom. In the sixth Li site, Li(6) is bonded in a 6-coordinate geometry to one O(15), one O(16), one O(22), one O(23), one O(26), and one O(27) atom. In the seventh Li site, Li(7) is bonded in a 4-coordinate geometry to one O(17), one O(18), one O(19), one O(24), and one O(28) atom. In the eighth Li site, Li(8) is bonded in a 6-coordinate geometry to one O(17), one O(18), one O(20), one O(24), one O(25), and one O(28) atom. In the ninth Li site, Li(9) is bonded in a 5-coordinate geometry to one O(19), one O(20), one O(27), one O(4), and one O(5) atom. In the tenth Li site, Li(10) is bonded in a 5-coordinate geometry to one O(21), one O(22), one O(28), one O(3), and one O(6) atom. There are four inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a 6-coordinate geometry to one O(14), one O(16), one O(3), one O(5), one O(7), and one O(8) atom. In the second Mn site, Mn(2) is bonded in a 6-coordinate geometry to one O(10), one O(12), one O(18), one O(4), one O(6), and one O(9) atom. In the third Mn site, Mn(3) is bonded to one O(11), one O(17), one O(19), one O(20), one O(23), and one O(25) atom to form distorted MnO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, and corners with two equivalent P(3)O4 tetrahedra. In the fourth Mn site, Mn(4) is bonded in a 6-coordinate geometry to one O(13), one O(15), one O(21), one O(22), one O(24), and one O(26) atom. There are four inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one O(27), one O(3), and one O(5) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one O(28), one O(4), and one O(6) atom. In the third C site, C(3) is bonded in a trigonal planar geometry to one O(1), one O(23), and one O(25) atom. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one O(2), one O(24), and one O(26) atom. There are four inequivalent P sites. In the first P site, P(1) is bonded to one O(11), one O(15), one O(7), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles are 68°. In the second P site, P(2) is bonded to one O(10), one O(13), one O(17), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles are 58°. In the third P site, P(3) is bonded to one O(12), one O(16), one O(19), and one O(20) atom to form PO4 tetrahedra that share corners with two equivalent Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles are 49°. In the fourth P site, P(4) is bonded in a tetrahedral geometry to one O(14), one O(18), one O(21), and one O(22) atom. There are twenty-eight inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Na(1), one Li(1), one Li(2), one Li(3), and one C(3) atom. In the second O site, O(2) is bonded to one Na(1), one Na(2), one Li(4), and one C(4) atom to form distorted ONa2LiC trigonal pyramids that share  a cornercorner with one O(8)Li2MnP trigonal pyramid,  a cornercorner with one O(10)NaLiMnP trigonal pyramid, and  an edgeedge with one O(13)NaLiMnP tetrahedra. In the third O site, O(3) is bonded in a 2-coordinate geometry to one Na(2), one Li(10), one Mn(1), and one C(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Li(9), one Mn(2), and one C(2) atom. In the fifth O site, O(5) is bonded to one Li(2), one Li(3), one Li(9), one Mn(1), and one C(1) atom to form distorted OLi3MnC trigonal bipyramids that share  a cornercorner with one O(16)Li2MnP tetrahedra, corners with two equivalent O(11)Li2MnP tetrahedra,  a cornercorner with one O(19)Li2MnP trigonal pyramid,  a cornercorner with one O(20)Li2MnP trigonal pyramid,  a cornercorner with one O(8)Li2MnP trigonal pyramid,  a cornercorner with one O(10)NaLiMnP trigonal pyramid, and  an edgeedge with one O(27)Li3C tetrahedra. In the sixth O site, O(6) is bonded in a 5-coordinate geometry to one Na(2), one Li(10), one Li(4), one Mn(2), and one C(2) atom. In the seventh O site, O(7) is bonded in a 4-coordinate geometry to one Na(2), one Li(1), one Mn(1), and one P(1) atom. In the eighth O site, O(8) is bonded to one Li(1), one Li(4), one Mn(1), and one P(1) atom to form distorted OLi2MnP trigonal pyramids that share  a cornercorner with one O(11)Li2MnP tetrahedra,  a cornercorner with one O(16)Li2MnP tetrahedra,  a cornercorner with one O(13)NaLiMnP tetrahedra,  a cornercorner with one O(23)Li3MnC trigonal bipyramid,  a cornercorner with one O(5)Li3MnC trigonal bipyramid, and  a cornercorner with one O(2)Na2LiC trigonal pyramid. In the ninth O site, O(9) is bonded in a 4-coordinate geometry to one Na(1), one Na(2), one Li(2), one Mn(2), and one P(2) atom. In the tenth O site, O(10) is bonded to one Na(1), one Li(3), one Mn(2), and one P(2) atom to form distorted ONaLiMnP trigonal pyramids that share  a cornercorner with one O(11)Li2MnP tetrahedra,  a cornercorner with one O(18)Li2MnP tetrahedra,  a cornercorner with one O(13)NaLiMnP tetrahedra,  a cornercorner with one O(5)Li3MnC trigonal bipyramid, and  a cornercorner with one O(2)Na2LiC trigonal pyramid. In the eleventh O site, O(11) is bonded to one Li(2), one Li(3), one Mn(3), and one P(1) atom to form OLi2MnP tetrahedra that share  a cornercorner with one O(23)Li3MnC trigonal bipyramid, corners with two equivalent O(5)Li3MnC trigonal bipyramids,  a cornercorner with one O(19)Li2MnP trigonal pyramid,  a cornercorner with one O(20)Li2MnP trigonal pyramid,  a cornercorner with one O(8)Li2MnP trigonal pyramid, and  a cornercorner with one O(10)NaLiMnP trigonal pyramid. In the twelfth O site, O(12) is bonded in a 4-coordinate geometry to one Li(2), one Li(3), one Mn(2), and one P(3) atom. In the thirteenth O site, O(13) is bonded to one Na(2), one Li(4), one Mn(4), and one P(2) atom to form distorted ONaLiMnP tetrahedra that share  a cornercorner with one O(21)Li2MnP trigonal pyramid,  a cornercorner with one O(8)Li2MnP trigonal pyramid,  a cornercorner with one O(10)NaLiMnP trigonal pyramid, and  an edgeedge with one O(2)Na2LiC trigonal pyramid. In the fourteenth O site, O(14) is bonded in a 4-coordinate geometry to one Na(2), one Li(4), one Mn(1), and one P(4) atom. In the fifteenth O site, O(15) is bonded in a 4-coordinate geometry to one Li(5), one Li(6), one Mn(4), and one P(1) atom. In the sixteenth O site, O(16) is bonded to one Li(5), one Li(6), one Mn(1), and one P(3) atom to form OLi2MnP tetrahedra that share  a cornercorner with one O(5)Li3MnC trigonal bipyramid, corners with two equivalent O(23)Li3MnC trigonal bipyramids,  a cornercorner with one O(19)Li2MnP trigonal pyramid,  a cornercorner with one O(20)Li2MnP trigonal pyramid,  a cornercorner with one O(21)Li2MnP trigonal pyramid,  a cornercorner with one O(8)Li2MnP trigonal pyramid, and  an edgeedge with one O(27)Li3C tetrahedra. In the seventeenth O site, O(17) is bonded in a 4-coordinate geometry to one Li(7), one Li(8), one Mn(3), and one P(2) atom. In the eighteenth O site, O(18) is bonded to one Li(7), one Li(8), one Mn(2), and one P(4) atom to form OLi2MnP tetrahedra that share  a cornercorner with one O(19)Li2MnP trigonal pyramid,  a cornercorner with one O(20)Li2MnP trigonal pyramid,  a cornercorner with one O(21)Li2MnP trigonal pyramid,  a cornercorner with one O(10)NaLiMnP trigonal pyramid, and  an edgeedge with one O(28)Li3C tetrahedra. In the nineteenth O site, O(19) is bonded to one Li(7), one Li(9), one Mn(3), and one P(3) atom to form distorted OLi2MnP trigonal pyramids that share  a cornercorner with one O(11)Li2MnP tetrahedra,  a cornercorner with one O(16)Li2MnP tetrahedra,  a cornercorner with one O(18)Li2MnP tetrahedra,  a cornercorner with one O(27)Li3C tetrahedra,  a cornercorner with one O(28)Li3C tetrahedra,  a cornercorner with one O(23)Li3MnC trigonal bipyramid,  a cornercorner with one O(5)Li3MnC trigonal bipyramid,  a cornercorner with one O(20)Li2MnP trigonal pyramid, and  an edgeedge with one O(20)Li2MnP trigonal pyramid. In the twentieth O site, O(20) is bonded to one Li(8), one Li(9), one Mn(3), and one P(3) atom to form distorted OLi2MnP trigonal pyramids that share  a cornercorner with one O(11)Li2MnP tetrahedra,  a cornercorner with one O(16)Li2MnP tetrahedra,  a cornercorner with one O(18)Li2MnP tetrahedra,  a cornercorner with one O(27)Li3C tetrahedra,  a cornercorner with one O(28)Li3C tetrahedra,  a cornercorner with one O(23)Li3MnC trigonal bipyramid,  a cornercorner with one O(5)Li3MnC trigonal bipyramid,  a cornercorner with one O(19)Li2MnP trigonal pyramid, and  an edgeedge with one O(19)Li2MnP trigonal pyramid. In the twenty-first O site, O(21) is bonded to one Li(10), one Li(5), one Mn(4), and one P(4) atom to form distorted OLi2MnP trigonal pyramids that share  a cornercorner with one O(16)Li2MnP tetrahedra,  a cornercorner with one O(18)Li2MnP tetrahedra,  a cornercorner with one O(27)Li3C tetrahedra,  a cornercorner with one O(28)Li3C tetrahedra,  a cornercorner with one O(13)NaLiMnP tetrahedra, and  a cornercorner with one O(23)Li3MnC trigonal bipyramid. In the twenty-second O site, O(22) is bonded in a 4-coordinate geometry to one Li(10), one Li(6), one Mn(4), and one P(4) atom. In the twenty-third O site, O(23) is bonded to one Li(1), one Li(5), one Li(6), one Mn(3), and one C(3) atom to form distorted OLi3MnC trigonal bipyramids that share  a cornercorner with one O(11)Li2MnP tetrahedra, corners with two equivalent O(16)Li2MnP tetrahedra, corners with two equivalent O(27)Li3C tetrahedra,  a cornercorner with one O(19)Li2MnP trigonal pyramid,  a cornercorner with one O(20)Li2MnP trigonal pyramid,  a cornercorner with one O(21)Li2MnP trigonal pyramid, and  a cornercorner with one O(8)Li2MnP trigonal pyramid. In the twenty-fourth O site, O(24) is bonded in a 5-coordinate geometry to one Na(1), one Li(7), one Li(8), one Mn(4), and one C(4) atom. In the twenty-fifth O site, O(25) is bonded in a 3-coordinate geometry to one Na(1), one Li(8), one Mn(3), and one C(3) atom. In the twenty-sixth O site, O(26) is bonded in a 2-coordinate geometry to one Li(1), one Li(5), one Li(6), one Mn(4), and one C(4) atom. In the twenty-seventh O site, O(27) is bonded to one Li(5), one Li(6), one Li(9), and one C(1) atom to form distorted OLi3C tetrahedra that share corners with two equivalent O(23)Li3MnC trigonal bipyramids,  a cornercorner with one O(19)Li2MnP trigonal pyramid,  a cornercorner with one O(20)Li2MnP trigonal pyramid,  a cornercorner with one O(21)Li2MnP trigonal pyramid,  an edgeedge with one O(16)Li2MnP tetrahedra, and  an edgeedge with one O(5)Li3MnC trigonal bipyramid. In the twenty-eighth O site, O(28) is bonded to one Li(10), one Li(7), one Li(8), and one C(2) atom to form a mixture of distorted edge and corner-sharing OLi3C tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_NaLi5Mn2P2(CO7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.633
_cell_length_b   8.654
_cell_length_c   9.987
_cell_angle_alpha   91.563
_cell_angle_beta   90.013
_cell_angle_gamma   90.436
_symmetry_Int_Tables_number   1
_cell_volume   573.039
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.255  0.085  0.622  1.0
  Na  Na1  1  0.998  0.251  0.877  1.0
  Li  Li2  1  0.255  0.078  0.125  1.0
  Li  Li3  1  0.019  0.264  0.380  1.0
  Li  Li4  1  0.480  0.265  0.382  1.0
  Li  Li5  1  0.481  0.267  0.887  1.0
  Li  Li6  1  0.517  0.739  0.117  1.0
  Li  Li7  1  0.983  0.740  0.116  1.0
  Li  Li8  1  0.519  0.734  0.615  1.0
  Li  Li9  1  0.981  0.735  0.616  1.0
  Li  Li10  1  0.749  0.917  0.373  1.0
  Li  Li11  1  0.742  0.914  0.876  1.0
  Mn  Mn12  1  0.746  0.356  0.116  1.0
  Mn  Mn13  1  0.749  0.358  0.610  1.0
  Mn  Mn14  1  0.251  0.646  0.385  1.0
  Mn  Mn15  1  0.249  0.646  0.890  1.0
  P  P16  1  0.250  0.405  0.151  1.0
  P  P17  1  0.255  0.415  0.646  1.0
  P  P18  1  0.750  0.593  0.352  1.0
  P  P19  1  0.745  0.596  0.855  1.0
  C  C20  1  0.749  0.042  0.135  1.0
  C  C21  1  0.748  0.042  0.633  1.0
  C  C22  1  0.250  0.952  0.360  1.0
  C  C23  1  0.259  0.954  0.870  1.0
  O  O24  1  0.248  0.102  0.347  1.0
  O  O25  1  0.278  0.101  0.852  1.0
  O  O26  1  0.750  0.088  0.013  1.0
  O  O27  1  0.749  0.089  0.511  1.0
  O  O28  1  0.746  0.141  0.235  1.0
  O  O29  1  0.745  0.142  0.732  1.0
  O  O30  1  0.061  0.312  0.104  1.0
  O  O31  1  0.431  0.309  0.097  1.0
  O  O32  1  0.065  0.322  0.598  1.0
  O  O33  1  0.435  0.323  0.587  1.0
  O  O34  1  0.255  0.414  0.308  1.0
  O  O35  1  0.751  0.422  0.397  1.0
  O  O36  1  0.267  0.419  0.802  1.0
  O  O37  1  0.732  0.428  0.904  1.0
  O  O38  1  0.252  0.575  0.102  1.0
  O  O39  1  0.750  0.588  0.195  1.0
  O  O40  1  0.251  0.586  0.600  1.0
  O  O41  1  0.749  0.587  0.698  1.0
  O  O42  1  0.567  0.687  0.405  1.0
  O  O43  1  0.935  0.688  0.405  1.0
  O  O44  1  0.566  0.697  0.904  1.0
  O  O45  1  0.934  0.685  0.908  1.0
  O  O46  1  0.251  0.862  0.253  1.0
  O  O47  1  0.248  0.858  0.767  1.0
  O  O48  1  0.252  0.890  0.477  1.0
  O  O49  1  0.249  0.901  0.991  1.0
  O  O50  1  0.751  0.895  0.160  1.0
  O  O51  1  0.750  0.895  0.659  1.0
[/CIF]
.