The material structure described by MgV2Mn3O10 crystallizes in the triclinic P1 space group. Mg(1) is bonded to one O(1), one O(3), one O(5), one O(6), one O(7), and one O(8) atom to form distorted MgO6 octahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra, and edges with two equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 13-31°. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(2), one O(3), one O(5), one O(7), and one O(8) atom to form distorted VO6 octahedra that share  a cornercorner with one Mg(1)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra, edges with two equivalent Mg(1)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 13-25°. In the second V site, V(2) is bonded to one O(10), one O(3), one O(4), one O(6), one O(8), and one O(9) atom to form distorted VO6 octahedra that share  a cornercorner with one Mg(1)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  an edgeedge with one Mg(1)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra, and  an edgeedge with one Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 16-19°. There are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(10), one O(2), one O(4), one O(7), and one O(9) atom to form MnO6 octahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  an edgeedge with one Mg(1)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 16-25°. In the second Mn site, Mn(2) is bonded to one O(1), one O(10), one O(2), one O(5), one O(7), and one O(9) atom to form MnO6 octahedra that share  a cornercorner with one Mg(1)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  an edgeedge with one Mg(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 17-31°. In the third Mn site, Mn(3) is bonded in a 5-coordinate geometry to one O(10), one O(2), one O(4), one O(6), and one O(9) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Mg(1), one V(1), one Mn(1), and one Mn(2) atom. In the second O site, O(2) is bonded in a see-saw-like geometry to one V(1), one Mn(1), one Mn(2), and one Mn(3) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Mg(1), one V(1), and one V(2) atom. In the fourth O site, O(4) is bonded in a trigonal non-coplanar geometry to one V(2), one Mn(1), and one Mn(3) atom. In the fifth O site, O(5) is bonded in a distorted T-shaped geometry to one Mg(1), one V(1), and one Mn(2) atom. In the sixth O site, O(6) is bonded in a distorted T-shaped geometry to one Mg(1), one V(2), and one Mn(3) atom. In the seventh O site, O(7) is bonded in a distorted tetrahedral geometry to one Mg(1), one V(1), one Mn(1), and one Mn(2) atom. In the eighth O site, O(8) is bonded in a T-shaped geometry to one Mg(1), one V(1), and one V(2) atom. In the ninth O site, O(9) is bonded in a see-saw-like geometry to one V(2), one Mn(1), one Mn(2), and one Mn(3) atom. In the tenth O site, O(10) is bonded in a distorted see-saw-like geometry to one V(2), one Mn(1), one Mn(2), and one Mn(3) atom. is represented by the CIF file [CIF]
data_MgMn3V2O10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.256
_cell_length_b   5.090
_cell_length_c   8.050
_cell_angle_alpha   113.803
_cell_angle_beta   96.375
_cell_angle_gamma   99.682
_symmetry_Int_Tables_number   1
_cell_volume   190.353
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.740  0.068  0.577  1.0
  Mn  Mn1  1  0.997  0.493  0.997  1.0
  Mn  Mn2  1  0.685  0.868  0.893  1.0
  Mn  Mn3  1  0.319  0.111  0.122  1.0
  V  V4  1  0.131  0.722  0.681  1.0
  V  V5  1  0.891  0.308  0.322  1.0
  O  O6  1  0.979  0.069  0.824  1.0
  O  O7  1  0.332  0.723  0.923  1.0
  O  O8  1  0.092  0.300  0.514  1.0
  O  O9  1  0.170  0.456  0.208  1.0
  O  O10  1  0.433  0.885  0.659  1.0
  O  O11  1  0.595  0.109  0.339  1.0
  O  O12  1  0.815  0.512  0.776  1.0
  O  O13  1  0.878  0.684  0.468  1.0
  O  O14  1  0.659  0.262  0.074  1.0
  O  O15  1  0.982  0.917  0.140  1.0
[/CIF]
.
The material structure described by MgV2Mn3O10 crystallizes in the triclinic P1 space group. Mg(1) is bonded to one O(1), one O(3), one O(5), one O(6), one O(7), and one O(8) atom to form distorted MgO6 octahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra, and edges with two equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 13-31°. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(2), one O(3), one O(5), one O(7), and one O(8) atom to form distorted VO6 octahedra that share  a cornercorner with one Mg(1)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra, edges with two equivalent Mg(1)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 13-25°. In the second V site, V(2) is bonded to one O(10), one O(3), one O(4), one O(6), one O(8), and one O(9) atom to form distorted VO6 octahedra that share  a cornercorner with one Mg(1)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  an edgeedge with one Mg(1)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra, and  an edgeedge with one Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 16-19°. There are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(10), one O(2), one O(4), one O(7), and one O(9) atom to form MnO6 octahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  an edgeedge with one Mg(1)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 16-25°. In the second Mn site, Mn(2) is bonded to one O(1), one O(10), one O(2), one O(5), one O(7), and one O(9) atom to form MnO6 octahedra that share  a cornercorner with one Mg(1)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  an edgeedge with one Mg(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 17-31°. In the third Mn site, Mn(3) is bonded in a 5-coordinate geometry to one O(10), one O(2), one O(4), one O(6), and one O(9) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Mg(1), one V(1), one Mn(1), and one Mn(2) atom. In the second O site, O(2) is bonded in a see-saw-like geometry to one V(1), one Mn(1), one Mn(2), and one Mn(3) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Mg(1), one V(1), and one V(2) atom. In the fourth O site, O(4) is bonded in a trigonal non-coplanar geometry to one V(2), one Mn(1), and one Mn(3) atom. In the fifth O site, O(5) is bonded in a distorted T-shaped geometry to one Mg(1), one V(1), and one Mn(2) atom. In the sixth O site, O(6) is bonded in a distorted T-shaped geometry to one Mg(1), one V(2), and one Mn(3) atom. In the seventh O site, O(7) is bonded in a distorted tetrahedral geometry to one Mg(1), one V(1), one Mn(1), and one Mn(2) atom. In the eighth O site, O(8) is bonded in a T-shaped geometry to one Mg(1), one V(1), and one V(2) atom. In the ninth O site, O(9) is bonded in a see-saw-like geometry to one V(2), one Mn(1), one Mn(2), and one Mn(3) atom. In the tenth O site, O(10) is bonded in a distorted see-saw-like geometry to one V(2), one Mn(1), one Mn(2), and one Mn(3) atom. is represented by the CIF file [CIF]
data_MgMn3V2O10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.256
_cell_length_b   5.090
_cell_length_c   8.050
_cell_angle_alpha   113.803
_cell_angle_beta   96.375
_cell_angle_gamma   99.682
_symmetry_Int_Tables_number   1
_cell_volume   190.353
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.740  0.068  0.577  1.0
  Mn  Mn1  1  0.997  0.493  0.997  1.0
  Mn  Mn2  1  0.685  0.868  0.893  1.0
  Mn  Mn3  1  0.319  0.111  0.122  1.0
  V  V4  1  0.131  0.722  0.681  1.0
  V  V5  1  0.891  0.308  0.322  1.0
  O  O6  1  0.979  0.069  0.824  1.0
  O  O7  1  0.332  0.723  0.923  1.0
  O  O8  1  0.092  0.300  0.514  1.0
  O  O9  1  0.170  0.456  0.208  1.0
  O  O10  1  0.433  0.885  0.659  1.0
  O  O11  1  0.595  0.109  0.339  1.0
  O  O12  1  0.815  0.512  0.776  1.0
  O  O13  1  0.878  0.684  0.468  1.0
  O  O14  1  0.659  0.262  0.074  1.0
  O  O15  1  0.982  0.917  0.140  1.0
[/CIF]
.