The crystal structure described by Ce3B2(O2Cl)3 crystallizes in the hexagonal P6_3/m space group. Ce(1) is bonded in a 10-coordinate geometry to six equivalent O(1) and four equivalent Cl(1) atoms. B(1) is bonded in a trigonal planar geometry to three equivalent O(1) atoms. O(1) is bonded in a distorted single-bond geometry to three equivalent Ce(1) and one B(1) atom. Cl(1) is bonded in a distorted see-saw-like geometry to four equivalent Ce(1) atoms. is represented by the CIF file [CIF]
data_Ce3B2(ClO2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.223
_cell_length_b   9.223
_cell_length_c   5.853
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   431.126
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.337  0.386  0.750  1.0
  Ce  Ce1  1  0.050  0.663  0.750  1.0
  Ce  Ce2  1  0.663  0.614  0.250  1.0
  Ce  Ce3  1  0.386  0.050  0.250  1.0
  Ce  Ce4  1  0.614  0.950  0.750  1.0
  Ce  Ce5  1  0.950  0.337  0.250  1.0
  B  B6  1  0.667  0.333  0.513  1.0
  B  B7  1  0.667  0.333  0.987  1.0
  B  B8  1  0.333  0.667  0.013  1.0
  B  B9  1  0.333  0.667  0.487  1.0
  Cl  Cl10  1  0.037  0.798  0.250  1.0
  Cl  Cl11  1  0.239  0.037  0.750  1.0
  Cl  Cl12  1  0.761  0.963  0.250  1.0
  Cl  Cl13  1  0.963  0.202  0.750  1.0
  Cl  Cl14  1  0.798  0.761  0.750  1.0
  Cl  Cl15  1  0.202  0.239  0.250  1.0
  O  O16  1  0.171  0.537  0.501  1.0
  O  O17  1  0.829  0.463  0.001  1.0
  O  O18  1  0.366  0.829  0.501  1.0
  O  O19  1  0.537  0.366  0.001  1.0
  O  O20  1  0.634  0.171  0.001  1.0
  O  O21  1  0.463  0.634  0.999  1.0
  O  O22  1  0.463  0.634  0.501  1.0
  O  O23  1  0.537  0.366  0.499  1.0
  O  O24  1  0.366  0.829  0.999  1.0
  O  O25  1  0.634  0.171  0.499  1.0
  O  O26  1  0.171  0.537  0.999  1.0
  O  O27  1  0.829  0.463  0.499  1.0
[/CIF]
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The crystal structure described by Ce3B2(O2Cl)3 crystallizes in the hexagonal P6_3/m space group. Ce(1) is bonded in a 10-coordinate geometry to six equivalent O(1) and four equivalent Cl(1) atoms. B(1) is bonded in a trigonal planar geometry to three equivalent O(1) atoms. O(1) is bonded in a distorted single-bond geometry to three equivalent Ce(1) and one B(1) atom. Cl(1) is bonded in a distorted see-saw-like geometry to four equivalent Ce(1) atoms. is represented by the CIF file [CIF]
data_Ce3B2(ClO2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.223
_cell_length_b   9.223
_cell_length_c   5.853
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   431.126
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.337  0.386  0.750  1.0
  Ce  Ce1  1  0.050  0.663  0.750  1.0
  Ce  Ce2  1  0.663  0.614  0.250  1.0
  Ce  Ce3  1  0.386  0.050  0.250  1.0
  Ce  Ce4  1  0.614  0.950  0.750  1.0
  Ce  Ce5  1  0.950  0.337  0.250  1.0
  B  B6  1  0.667  0.333  0.513  1.0
  B  B7  1  0.667  0.333  0.987  1.0
  B  B8  1  0.333  0.667  0.013  1.0
  B  B9  1  0.333  0.667  0.487  1.0
  Cl  Cl10  1  0.037  0.798  0.250  1.0
  Cl  Cl11  1  0.239  0.037  0.750  1.0
  Cl  Cl12  1  0.761  0.963  0.250  1.0
  Cl  Cl13  1  0.963  0.202  0.750  1.0
  Cl  Cl14  1  0.798  0.761  0.750  1.0
  Cl  Cl15  1  0.202  0.239  0.250  1.0
  O  O16  1  0.171  0.537  0.501  1.0
  O  O17  1  0.829  0.463  0.001  1.0
  O  O18  1  0.366  0.829  0.501  1.0
  O  O19  1  0.537  0.366  0.001  1.0
  O  O20  1  0.634  0.171  0.001  1.0
  O  O21  1  0.463  0.634  0.999  1.0
  O  O22  1  0.463  0.634  0.501  1.0
  O  O23  1  0.537  0.366  0.499  1.0
  O  O24  1  0.366  0.829  0.999  1.0
  O  O25  1  0.634  0.171  0.499  1.0
  O  O26  1  0.171  0.537  0.999  1.0
  O  O27  1  0.829  0.463  0.499  1.0
[/CIF]
.