The compound described by Sb(OCl3)2 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four Sb(OCl3)2 clusters. Sb(1) is bonded in an octahedral geometry to two equivalent Cl(1), two equivalent Cl(2), and two equivalent Cl(3) atoms. O(1) is bonded in a distorted single-bond geometry to one Cl(3) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Sb(1) atom. In the third Cl site, Cl(3) is bonded in a distorted bent 120 degrees geometry to one Sb(1) and one O(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sb(Cl3O)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.177
_cell_length_b   7.177
_cell_length_c   12.858
_cell_angle_alpha   69.416
_cell_angle_beta   69.416
_cell_angle_gamma   53.297
_symmetry_Int_Tables_number   1
_cell_volume   488.201
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.000  0.000  0.000  1.0
  Sb  Sb1  1  0.000  0.000  0.500  1.0
  Cl  Cl2  1  0.187  0.582  0.067  1.0
  Cl  Cl3  1  0.418  0.813  0.433  1.0
  Cl  Cl4  1  0.813  0.418  0.933  1.0
  Cl  Cl5  1  0.582  0.187  0.567  1.0
  Cl  Cl6  1  0.316  0.937  0.839  1.0
  Cl  Cl7  1  0.063  0.684  0.661  1.0
  Cl  Cl8  1  0.684  0.063  0.161  1.0
  Cl  Cl9  1  0.937  0.316  0.339  1.0
  Cl  Cl10  1  0.779  0.984  0.896  1.0
  Cl  Cl11  1  0.016  0.221  0.604  1.0
  Cl  Cl12  1  0.221  0.016  0.104  1.0
  Cl  Cl13  1  0.984  0.779  0.396  1.0
  O  O14  1  0.526  0.630  0.179  1.0
  O  O15  1  0.370  0.474  0.321  1.0
  O  O16  1  0.474  0.370  0.821  1.0
  O  O17  1  0.630  0.526  0.679  1.0
[/CIF]
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The compound described by Sb(OCl3)2 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four Sb(OCl3)2 clusters. Sb(1) is bonded in an octahedral geometry to two equivalent Cl(1), two equivalent Cl(2), and two equivalent Cl(3) atoms. O(1) is bonded in a distorted single-bond geometry to one Cl(3) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Sb(1) atom. In the third Cl site, Cl(3) is bonded in a distorted bent 120 degrees geometry to one Sb(1) and one O(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sb(Cl3O)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.177
_cell_length_b   7.177
_cell_length_c   12.858
_cell_angle_alpha   69.416
_cell_angle_beta   69.416
_cell_angle_gamma   53.297
_symmetry_Int_Tables_number   1
_cell_volume   488.201
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.000  0.000  0.000  1.0
  Sb  Sb1  1  0.000  0.000  0.500  1.0
  Cl  Cl2  1  0.187  0.582  0.067  1.0
  Cl  Cl3  1  0.418  0.813  0.433  1.0
  Cl  Cl4  1  0.813  0.418  0.933  1.0
  Cl  Cl5  1  0.582  0.187  0.567  1.0
  Cl  Cl6  1  0.316  0.937  0.839  1.0
  Cl  Cl7  1  0.063  0.684  0.661  1.0
  Cl  Cl8  1  0.684  0.063  0.161  1.0
  Cl  Cl9  1  0.937  0.316  0.339  1.0
  Cl  Cl10  1  0.779  0.984  0.896  1.0
  Cl  Cl11  1  0.016  0.221  0.604  1.0
  Cl  Cl12  1  0.221  0.016  0.104  1.0
  Cl  Cl13  1  0.984  0.779  0.396  1.0
  O  O14  1  0.526  0.630  0.179  1.0
  O  O15  1  0.370  0.474  0.321  1.0
  O  O16  1  0.474  0.370  0.821  1.0
  O  O17  1  0.630  0.526  0.679  1.0
[/CIF]
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