The structure described by Co2CuN2 crystallizes in the orthorhombic Pmmn space group. Co(1) is bonded to five equivalent N(1) atoms to form a mixture of edge and corner-sharing CoN5 square pyramids. Cu(1) is bonded in a linear geometry to two equivalent N(1) atoms. N(1) is bonded to five equivalent Co(1) and one Cu(1) atom to form a mixture of edge and corner-sharing NCo5Cu octahedra. The corner-sharing octahedral tilt angles range from 5-6°. is represented by the CIF file [CIF]
data_Co2CuN2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.763
_cell_length_b   2.816
_cell_length_c   6.263
_cell_angle_alpha   77.009
_cell_angle_beta   77.257
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   46.247
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.663  0.663  0.173  1.0
  Co  Co1  1  0.337  0.337  0.827  1.0
  Cu  Cu2  1  1.000  1.000  0.500  1.0
  N  N3  1  0.163  0.163  0.174  1.0
  N  N4  1  0.837  0.837  0.826  1.0
[/CIF]
.
The structure described by Co2CuN2 crystallizes in the orthorhombic Pmmn space group. Co(1) is bonded to five equivalent N(1) atoms to form a mixture of edge and corner-sharing CoN5 square pyramids. Cu(1) is bonded in a linear geometry to two equivalent N(1) atoms. N(1) is bonded to five equivalent Co(1) and one Cu(1) atom to form a mixture of edge and corner-sharing NCo5Cu octahedra. The corner-sharing octahedral tilt angles range from 5-6°. is represented by the CIF file [CIF]
data_Co2CuN2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.763
_cell_length_b   2.816
_cell_length_c   6.263
_cell_angle_alpha   77.009
_cell_angle_beta   77.257
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   46.247
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.663  0.663  0.173  1.0
  Co  Co1  1  0.337  0.337  0.827  1.0
  Cu  Cu2  1  1.000  1.000  0.500  1.0
  N  N3  1  0.163  0.163  0.174  1.0
  N  N4  1  0.837  0.837  0.826  1.0
[/CIF]
.