The material described by WGa2O6 crystallizes in the monoclinic P2/c space group. W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form distorted WO6 octahedra that share corners with four equivalent Ga(2)O6 octahedra and  an edgeedge with one Ga(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 39-53°. There are three inequivalent Ga sites. In the first Ga site, Ga(1) is bonded in a 4-coordinate geometry to two equivalent O(1) and two equivalent O(3) atoms. In the second Ga site, Ga(2) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form GaO6 octahedra that share corners with four equivalent W(1)O6 octahedra and  an edgeedge with one W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 39-53°. In the third Ga site, Ga(3) is bonded in a 4-coordinate geometry to two equivalent O(3), two equivalent O(4), and two equivalent O(6) atoms. There are six inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one W(1), one Ga(1), and one Ga(2) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one W(1) and one Ga(2) atom. In the third O site, O(3) is bonded in a distorted rectangular see-saw-like geometry to one W(1), one Ga(1), one Ga(2), and one Ga(3) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one W(1), one Ga(2), and one Ga(3) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one W(1) and one Ga(2) atom. In the sixth O site, O(6) is bonded in a trigonal non-coplanar geometry to one W(1), one Ga(2), and one Ga(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ga2WO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.803
_cell_length_b   7.229
_cell_length_c   11.518
_cell_angle_alpha   86.094
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   399.019
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.790  0.000  0.750  1.0
  Ga  Ga1  1  0.210  0.000  0.250  1.0
  Ga  Ga2  1  0.242  0.757  0.618  1.0
  Ga  Ga3  1  0.758  0.757  0.118  1.0
  Ga  Ga4  1  0.712  0.500  0.750  1.0
  Ga  Ga5  1  0.288  0.500  0.250  1.0
  Ga  Ga6  1  0.242  0.243  0.882  1.0
  Ga  Ga7  1  0.758  0.243  0.382  1.0
  W  W8  1  0.266  0.744  0.896  1.0
  W  W9  1  0.734  0.744  0.396  1.0
  W  W10  1  0.266  0.256  0.604  1.0
  W  W11  1  0.734  0.256  0.104  1.0
  O  O12  1  0.072  0.987  0.871  1.0
  O  O13  1  0.564  0.833  0.973  1.0
  O  O14  1  0.928  0.987  0.371  1.0
  O  O15  1  0.508  0.812  0.740  1.0
  O  O16  1  0.436  0.833  0.473  1.0
  O  O17  1  0.004  0.683  0.762  1.0
  O  O18  1  0.492  0.812  0.240  1.0
  O  O19  1  0.944  0.670  0.521  1.0
  O  O20  1  0.437  0.497  0.873  1.0
  O  O21  1  0.996  0.683  0.262  1.0
  O  O22  1  0.437  0.503  0.627  1.0
  O  O23  1  0.944  0.330  0.979  1.0
  O  O24  1  0.056  0.670  0.021  1.0
  O  O25  1  0.563  0.497  0.373  1.0
  O  O26  1  0.004  0.317  0.738  1.0
  O  O27  1  0.563  0.503  0.127  1.0
  O  O28  1  0.056  0.330  0.479  1.0
  O  O29  1  0.508  0.188  0.760  1.0
  O  O30  1  0.996  0.317  0.238  1.0
  O  O31  1  0.564  0.167  0.527  1.0
  O  O32  1  0.492  0.188  0.260  1.0
  O  O33  1  0.072  0.013  0.629  1.0
  O  O34  1  0.436  0.167  0.027  1.0
  O  O35  1  0.928  0.013  0.129  1.0
[/CIF]
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The material described by WGa2O6 crystallizes in the monoclinic P2/c space group. W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form distorted WO6 octahedra that share corners with four equivalent Ga(2)O6 octahedra and  an edgeedge with one Ga(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 39-53°. There are three inequivalent Ga sites. In the first Ga site, Ga(1) is bonded in a 4-coordinate geometry to two equivalent O(1) and two equivalent O(3) atoms. In the second Ga site, Ga(2) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form GaO6 octahedra that share corners with four equivalent W(1)O6 octahedra and  an edgeedge with one W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 39-53°. In the third Ga site, Ga(3) is bonded in a 4-coordinate geometry to two equivalent O(3), two equivalent O(4), and two equivalent O(6) atoms. There are six inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one W(1), one Ga(1), and one Ga(2) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one W(1) and one Ga(2) atom. In the third O site, O(3) is bonded in a distorted rectangular see-saw-like geometry to one W(1), one Ga(1), one Ga(2), and one Ga(3) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one W(1), one Ga(2), and one Ga(3) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one W(1) and one Ga(2) atom. In the sixth O site, O(6) is bonded in a trigonal non-coplanar geometry to one W(1), one Ga(2), and one Ga(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ga2WO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.803
_cell_length_b   7.229
_cell_length_c   11.518
_cell_angle_alpha   86.094
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   399.019
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.790  0.000  0.750  1.0
  Ga  Ga1  1  0.210  0.000  0.250  1.0
  Ga  Ga2  1  0.242  0.757  0.618  1.0
  Ga  Ga3  1  0.758  0.757  0.118  1.0
  Ga  Ga4  1  0.712  0.500  0.750  1.0
  Ga  Ga5  1  0.288  0.500  0.250  1.0
  Ga  Ga6  1  0.242  0.243  0.882  1.0
  Ga  Ga7  1  0.758  0.243  0.382  1.0
  W  W8  1  0.266  0.744  0.896  1.0
  W  W9  1  0.734  0.744  0.396  1.0
  W  W10  1  0.266  0.256  0.604  1.0
  W  W11  1  0.734  0.256  0.104  1.0
  O  O12  1  0.072  0.987  0.871  1.0
  O  O13  1  0.564  0.833  0.973  1.0
  O  O14  1  0.928  0.987  0.371  1.0
  O  O15  1  0.508  0.812  0.740  1.0
  O  O16  1  0.436  0.833  0.473  1.0
  O  O17  1  0.004  0.683  0.762  1.0
  O  O18  1  0.492  0.812  0.240  1.0
  O  O19  1  0.944  0.670  0.521  1.0
  O  O20  1  0.437  0.497  0.873  1.0
  O  O21  1  0.996  0.683  0.262  1.0
  O  O22  1  0.437  0.503  0.627  1.0
  O  O23  1  0.944  0.330  0.979  1.0
  O  O24  1  0.056  0.670  0.021  1.0
  O  O25  1  0.563  0.497  0.373  1.0
  O  O26  1  0.004  0.317  0.738  1.0
  O  O27  1  0.563  0.503  0.127  1.0
  O  O28  1  0.056  0.330  0.479  1.0
  O  O29  1  0.508  0.188  0.760  1.0
  O  O30  1  0.996  0.317  0.238  1.0
  O  O31  1  0.564  0.167  0.527  1.0
  O  O32  1  0.492  0.188  0.260  1.0
  O  O33  1  0.072  0.013  0.629  1.0
  O  O34  1  0.436  0.167  0.027  1.0
  O  O35  1  0.928  0.013  0.129  1.0
[/CIF]
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