The material structure described by (Na2Cu(S2O3)2)4(CuN4)2N2 crystallizes in the tetragonal I4/m space group. The structure consists of two ammonia atoms and two azanide;copper molecules inside a Na2Cu(S2O3)2 framework. In the Na2Cu(S2O3)2 framework, Na(1) is bonded in a 5-coordinate geometry to one O(2) and four equivalent O(1) atoms. Cu(1) is bonded to four equivalent S(1) atoms to form edge-sharing CuS4 tetrahedra. There are two inequivalent S sites. In the first S site, S(1) is bonded in a 3-coordinate geometry to two equivalent Cu(1) and one S(2) atom. In the second S site, S(2) is bonded in a trigonal non-coplanar geometry to one S(1), one O(2), and two equivalent O(1) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to two equivalent Na(1) and one S(2) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Na(1) and one S(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Na4Cu3S8N5O12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.162
_cell_length_b   10.162
_cell_length_c   10.162
_cell_angle_alpha   94.815
_cell_angle_beta   94.815
_cell_angle_gamma   146.316
_symmetry_Int_Tables_number   1
_cell_volume   557.088
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.674  0.213  0.887  1.0
  Na  Na1  1  0.326  0.787  0.113  1.0
  Na  Na2  1  0.213  0.326  0.539  1.0
  Na  Na3  1  0.787  0.674  0.461  1.0
  Cu  Cu4  1  0.250  0.750  0.500  1.0
  Cu  Cu5  1  0.750  0.250  0.500  1.0
  Cu  Cu6  1  0.000  0.000  0.000  1.0
  S  S7  1  0.073  0.603  0.676  1.0
  S  S8  1  0.927  0.397  0.324  1.0
  S  S9  1  0.603  0.927  0.530  1.0
  S  S10  1  0.397  0.073  0.470  1.0
  S  S11  1  0.230  0.587  0.817  1.0
  S  S12  1  0.770  0.413  0.183  1.0
  S  S13  1  0.587  0.770  0.357  1.0
  S  S14  1  0.413  0.230  0.643  1.0
  N  N15  1  0.960  0.131  0.091  1.0
  N  N16  1  0.040  0.869  0.909  1.0
  N  N17  1  0.131  0.040  0.171  1.0
  N  N18  1  0.869  0.960  0.829  1.0
  N  N19  1  0.500  0.500  0.000  1.0
  O  O20  1  0.465  0.846  0.899  1.0
  O  O21  1  0.947  0.567  0.101  1.0
  O  O22  1  0.846  0.947  0.380  1.0
  O  O23  1  0.567  0.465  0.620  1.0
  O  O24  1  0.535  0.154  0.101  1.0
  O  O25  1  0.053  0.433  0.899  1.0
  O  O26  1  0.154  0.053  0.620  1.0
  O  O27  1  0.433  0.535  0.380  1.0
  O  O28  1  0.253  0.484  0.738  1.0
  O  O29  1  0.747  0.516  0.262  1.0
  O  O30  1  0.484  0.747  0.231  1.0
  O  O31  1  0.516  0.253  0.769  1.0
[/CIF]
.
The material structure described by (Na2Cu(S2O3)2)4(CuN4)2N2 crystallizes in the tetragonal I4/m space group. The structure consists of two ammonia atoms and two azanide;copper molecules inside a Na2Cu(S2O3)2 framework. In the Na2Cu(S2O3)2 framework, Na(1) is bonded in a 5-coordinate geometry to one O(2) and four equivalent O(1) atoms. Cu(1) is bonded to four equivalent S(1) atoms to form edge-sharing CuS4 tetrahedra. There are two inequivalent S sites. In the first S site, S(1) is bonded in a 3-coordinate geometry to two equivalent Cu(1) and one S(2) atom. In the second S site, S(2) is bonded in a trigonal non-coplanar geometry to one S(1), one O(2), and two equivalent O(1) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to two equivalent Na(1) and one S(2) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Na(1) and one S(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Na4Cu3S8N5O12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.162
_cell_length_b   10.162
_cell_length_c   10.162
_cell_angle_alpha   94.815
_cell_angle_beta   94.815
_cell_angle_gamma   146.316
_symmetry_Int_Tables_number   1
_cell_volume   557.088
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.674  0.213  0.887  1.0
  Na  Na1  1  0.326  0.787  0.113  1.0
  Na  Na2  1  0.213  0.326  0.539  1.0
  Na  Na3  1  0.787  0.674  0.461  1.0
  Cu  Cu4  1  0.250  0.750  0.500  1.0
  Cu  Cu5  1  0.750  0.250  0.500  1.0
  Cu  Cu6  1  0.000  0.000  0.000  1.0
  S  S7  1  0.073  0.603  0.676  1.0
  S  S8  1  0.927  0.397  0.324  1.0
  S  S9  1  0.603  0.927  0.530  1.0
  S  S10  1  0.397  0.073  0.470  1.0
  S  S11  1  0.230  0.587  0.817  1.0
  S  S12  1  0.770  0.413  0.183  1.0
  S  S13  1  0.587  0.770  0.357  1.0
  S  S14  1  0.413  0.230  0.643  1.0
  N  N15  1  0.960  0.131  0.091  1.0
  N  N16  1  0.040  0.869  0.909  1.0
  N  N17  1  0.131  0.040  0.171  1.0
  N  N18  1  0.869  0.960  0.829  1.0
  N  N19  1  0.500  0.500  0.000  1.0
  O  O20  1  0.465  0.846  0.899  1.0
  O  O21  1  0.947  0.567  0.101  1.0
  O  O22  1  0.846  0.947  0.380  1.0
  O  O23  1  0.567  0.465  0.620  1.0
  O  O24  1  0.535  0.154  0.101  1.0
  O  O25  1  0.053  0.433  0.899  1.0
  O  O26  1  0.154  0.053  0.620  1.0
  O  O27  1  0.433  0.535  0.380  1.0
  O  O28  1  0.253  0.484  0.738  1.0
  O  O29  1  0.747  0.516  0.262  1.0
  O  O30  1  0.484  0.747  0.231  1.0
  O  O31  1  0.516  0.253  0.769  1.0
[/CIF]
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