The material described by Rb2Mo2C4H4O15 crystallizes in the monoclinic P2_1/c space group. Rb(1) is bonded in a 7-coordinate geometry to one O(2), one O(4), one O(6), two equivalent O(1), and two equivalent O(3) atoms. Mo(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(5), one O(6), one O(7), and one O(8) atom. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(4) and one O(6) atom. In the second C site, C(2) is bonded in a bent 120 degrees geometry to one O(3) and one O(7) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(5) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(5) atom. There are eight inequivalent O sites. In the first O site, O(6) is bonded in a 1-coordinate geometry to one Rb(1), one Mo(1), and one C(1) atom. In the second O site, O(7) is bonded in a bent 120 degrees geometry to one Mo(1) and one C(2) atom. In the third O site, O(8) is bonded in a linear geometry to two equivalent Mo(1) atoms. In the fourth O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one Mo(1) atom. In the fifth O site, O(2) is bonded in a distorted single-bond geometry to one Rb(1) and one Mo(1) atom. In the sixth O site, O(3) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one C(2) atom. In the seventh O site, O(4) is bonded in a distorted single-bond geometry to one Rb(1) and one C(1) atom. In the eighth O site, O(5) is bonded in a water-like geometry to one Mo(1), one H(1), and one H(2) atom. is represented by the CIF card [CIF]
data_Rb2Mo2H4C4O15
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   14.533
_cell_length_b   7.030
_cell_length_c   7.809
_cell_angle_alpha   85.522
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   795.482
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.637  0.127  0.192  1.0
  Rb  Rb1  1  0.137  0.373  0.808  1.0
  Rb  Rb2  1  0.363  0.873  0.808  1.0
  Rb  Rb3  1  0.863  0.627  0.192  1.0
  Mo  Mo4  1  0.393  0.384  0.106  1.0
  Mo  Mo5  1  0.893  0.116  0.894  1.0
  Mo  Mo6  1  0.107  0.884  0.106  1.0
  Mo  Mo7  1  0.607  0.616  0.894  1.0
  H  H8  1  0.435  0.726  0.290  1.0
  H  H9  1  0.175  0.226  0.260  1.0
  H  H10  1  0.825  0.774  0.740  1.0
  H  H11  1  0.325  0.726  0.260  1.0
  H  H12  1  0.675  0.274  0.740  1.0
  H  H13  1  0.065  0.226  0.290  1.0
  H  H14  1  0.565  0.274  0.710  1.0
  H  H15  1  0.935  0.774  0.710  1.0
  C  C16  1  0.070  0.760  0.480  1.0
  C  C17  1  0.176  0.748  0.457  1.0
  C  C18  1  0.570  0.740  0.520  1.0
  C  C19  1  0.324  0.248  0.457  1.0
  C  C20  1  0.676  0.752  0.543  1.0
  C  C21  1  0.930  0.240  0.520  1.0
  C  C22  1  0.824  0.252  0.543  1.0
  C  C23  1  0.430  0.260  0.480  1.0
  O  O24  1  0.305  0.469  0.970  1.0
  O  O25  1  0.090  0.650  0.057  1.0
  O  O26  1  0.727  0.815  0.426  1.0
  O  O27  1  0.590  0.850  0.943  1.0
  O  O28  1  0.466  0.200  0.618  1.0
  O  O29  1  0.273  0.185  0.574  1.0
  O  O30  1  0.884  0.821  0.782  1.0
  O  O31  1  0.910  0.350  0.943  1.0
  O  O32  1  0.227  0.685  0.574  1.0
  O  O33  1  0.410  0.150  0.057  1.0
  O  O34  1  0.973  0.167  0.655  1.0
  O  O35  1  0.704  0.691  0.698  1.0
  O  O36  1  0.204  0.809  0.302  1.0
  O  O37  1  0.805  0.031  0.030  1.0
  O  O38  1  0.966  0.300  0.382  1.0
  O  O39  1  0.027  0.833  0.345  1.0
  O  O40  1  0.034  0.700  0.618  1.0
  O  O41  1  0.527  0.667  0.655  1.0
  O  O42  1  0.116  0.179  0.218  1.0
  O  O43  1  0.796  0.191  0.698  1.0
  O  O44  1  0.000  0.000  0.000  1.0
  O  O45  1  0.616  0.321  0.782  1.0
  O  O46  1  0.773  0.315  0.426  1.0
  O  O47  1  0.473  0.333  0.345  1.0
  O  O48  1  0.534  0.800  0.382  1.0
  O  O49  1  0.195  0.969  0.970  1.0
  O  O50  1  0.296  0.309  0.302  1.0
  O  O51  1  0.384  0.679  0.218  1.0
  O  O52  1  0.695  0.531  0.030  1.0
  O  O53  1  0.500  0.500  0.000  1.0
[/CIF]
.
The material described by Rb2Mo2C4H4O15 crystallizes in the monoclinic P2_1/c space group. Rb(1) is bonded in a 7-coordinate geometry to one O(2), one O(4), one O(6), two equivalent O(1), and two equivalent O(3) atoms. Mo(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(5), one O(6), one O(7), and one O(8) atom. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(4) and one O(6) atom. In the second C site, C(2) is bonded in a bent 120 degrees geometry to one O(3) and one O(7) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(5) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(5) atom. There are eight inequivalent O sites. In the first O site, O(6) is bonded in a 1-coordinate geometry to one Rb(1), one Mo(1), and one C(1) atom. In the second O site, O(7) is bonded in a bent 120 degrees geometry to one Mo(1) and one C(2) atom. In the third O site, O(8) is bonded in a linear geometry to two equivalent Mo(1) atoms. In the fourth O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one Mo(1) atom. In the fifth O site, O(2) is bonded in a distorted single-bond geometry to one Rb(1) and one Mo(1) atom. In the sixth O site, O(3) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one C(2) atom. In the seventh O site, O(4) is bonded in a distorted single-bond geometry to one Rb(1) and one C(1) atom. In the eighth O site, O(5) is bonded in a water-like geometry to one Mo(1), one H(1), and one H(2) atom. is represented by the CIF card [CIF]
data_Rb2Mo2H4C4O15
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   14.533
_cell_length_b   7.030
_cell_length_c   7.809
_cell_angle_alpha   85.522
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   795.482
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.637  0.127  0.192  1.0
  Rb  Rb1  1  0.137  0.373  0.808  1.0
  Rb  Rb2  1  0.363  0.873  0.808  1.0
  Rb  Rb3  1  0.863  0.627  0.192  1.0
  Mo  Mo4  1  0.393  0.384  0.106  1.0
  Mo  Mo5  1  0.893  0.116  0.894  1.0
  Mo  Mo6  1  0.107  0.884  0.106  1.0
  Mo  Mo7  1  0.607  0.616  0.894  1.0
  H  H8  1  0.435  0.726  0.290  1.0
  H  H9  1  0.175  0.226  0.260  1.0
  H  H10  1  0.825  0.774  0.740  1.0
  H  H11  1  0.325  0.726  0.260  1.0
  H  H12  1  0.675  0.274  0.740  1.0
  H  H13  1  0.065  0.226  0.290  1.0
  H  H14  1  0.565  0.274  0.710  1.0
  H  H15  1  0.935  0.774  0.710  1.0
  C  C16  1  0.070  0.760  0.480  1.0
  C  C17  1  0.176  0.748  0.457  1.0
  C  C18  1  0.570  0.740  0.520  1.0
  C  C19  1  0.324  0.248  0.457  1.0
  C  C20  1  0.676  0.752  0.543  1.0
  C  C21  1  0.930  0.240  0.520  1.0
  C  C22  1  0.824  0.252  0.543  1.0
  C  C23  1  0.430  0.260  0.480  1.0
  O  O24  1  0.305  0.469  0.970  1.0
  O  O25  1  0.090  0.650  0.057  1.0
  O  O26  1  0.727  0.815  0.426  1.0
  O  O27  1  0.590  0.850  0.943  1.0
  O  O28  1  0.466  0.200  0.618  1.0
  O  O29  1  0.273  0.185  0.574  1.0
  O  O30  1  0.884  0.821  0.782  1.0
  O  O31  1  0.910  0.350  0.943  1.0
  O  O32  1  0.227  0.685  0.574  1.0
  O  O33  1  0.410  0.150  0.057  1.0
  O  O34  1  0.973  0.167  0.655  1.0
  O  O35  1  0.704  0.691  0.698  1.0
  O  O36  1  0.204  0.809  0.302  1.0
  O  O37  1  0.805  0.031  0.030  1.0
  O  O38  1  0.966  0.300  0.382  1.0
  O  O39  1  0.027  0.833  0.345  1.0
  O  O40  1  0.034  0.700  0.618  1.0
  O  O41  1  0.527  0.667  0.655  1.0
  O  O42  1  0.116  0.179  0.218  1.0
  O  O43  1  0.796  0.191  0.698  1.0
  O  O44  1  0.000  0.000  0.000  1.0
  O  O45  1  0.616  0.321  0.782  1.0
  O  O46  1  0.773  0.315  0.426  1.0
  O  O47  1  0.473  0.333  0.345  1.0
  O  O48  1  0.534  0.800  0.382  1.0
  O  O49  1  0.195  0.969  0.970  1.0
  O  O50  1  0.296  0.309  0.302  1.0
  O  O51  1  0.384  0.679  0.218  1.0
  O  O52  1  0.695  0.531  0.030  1.0
  O  O53  1  0.500  0.500  0.000  1.0
[/CIF]
.