The material structure described by Co(IO3)2 crystallizes in the trigonal P3 space group. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded in an octahedral geometry to one O(2), one O(3), one O(4), one O(6), one O(7), and one O(8) atom. In the second Co site, Co(2) is bonded in an octahedral geometry to three equivalent O(1) and three equivalent O(5) atoms. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Co(2) and one I(1) atom. In the second O site, O(2) is bonded in a water-like geometry to one Co(1) and one I(1) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Co(1) and one I(2) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Co(1) and one I(1) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Co(2) and one I(3) atom. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Co(1) and one I(3) atom. In the seventh O site, O(7) is bonded in a distorted bent 150 degrees geometry to one Co(1) and one I(3) atom. In the eighth O site, O(8) is bonded in a water-like geometry to one Co(1) and one I(4) atom. There are four inequivalent I sites. In the first I site, I(1) is bonded in a 3-coordinate geometry to one O(1), one O(2), and one O(4) atom. In the second I site, I(2) is bonded in a trigonal non-coplanar geometry to three equivalent O(3) atoms. In the third I site, I(3) is bonded in a 3-coordinate geometry to one O(5), one O(6), and one O(7) atom. In the fourth I site, I(4) is bonded in a 3-coordinate geometry to three equivalent O(8) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Co(IO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.093
_cell_length_b   11.093
_cell_length_c   5.139
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   547.701
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.337  0.175  0.066  1.0
  Co  Co1  1  0.333  0.667  0.573  1.0
  Co  Co2  1  0.839  0.663  0.066  1.0
  Co  Co3  1  0.825  0.161  0.066  1.0
  I  I4  1  0.499  0.514  0.997  1.0
  I  I5  1  0.486  0.985  0.997  1.0
  I  I6  1  0.667  0.333  0.459  1.0
  I  I7  1  0.015  0.501  0.997  1.0
  I  I8  1  0.679  0.833  0.486  1.0
  I  I9  1  0.154  0.321  0.486  1.0
  I  I10  1  0.000  0.000  0.011  1.0
  I  I11  1  0.167  0.846  0.486  1.0
  O  O12  1  0.480  0.638  0.783  1.0
  O  O13  1  0.375  0.348  0.837  1.0
  O  O14  1  0.512  0.319  0.297  1.0
  O  O15  1  0.661  0.536  0.854  1.0
  O  O16  1  0.464  0.125  0.854  1.0
  O  O17  1  0.362  0.842  0.783  1.0
  O  O18  1  0.807  0.488  0.297  1.0
  O  O19  1  0.681  0.193  0.297  1.0
  O  O20  1  0.510  0.797  0.348  1.0
  O  O21  1  0.652  0.027  0.837  1.0
  O  O22  1  0.973  0.625  0.837  1.0
  O  O23  1  0.875  0.339  0.854  1.0
  O  O24  1  0.795  0.988  0.289  1.0
  O  O25  1  0.700  0.704  0.297  1.0
  O  O26  1  0.004  0.300  0.297  1.0
  O  O27  1  0.158  0.520  0.783  1.0
  O  O28  1  0.952  0.115  0.834  1.0
  O  O29  1  0.885  0.837  0.834  1.0
  O  O30  1  0.286  0.490  0.348  1.0
  O  O31  1  0.193  0.205  0.289  1.0
  O  O32  1  0.012  0.807  0.289  1.0
  O  O33  1  0.163  0.048  0.834  1.0
  O  O34  1  0.296  0.996  0.297  1.0
  O  O35  1  0.203  0.714  0.348  1.0
[/CIF]
.
The material structure described by Co(IO3)2 crystallizes in the trigonal P3 space group. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded in an octahedral geometry to one O(2), one O(3), one O(4), one O(6), one O(7), and one O(8) atom. In the second Co site, Co(2) is bonded in an octahedral geometry to three equivalent O(1) and three equivalent O(5) atoms. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Co(2) and one I(1) atom. In the second O site, O(2) is bonded in a water-like geometry to one Co(1) and one I(1) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Co(1) and one I(2) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Co(1) and one I(1) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Co(2) and one I(3) atom. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Co(1) and one I(3) atom. In the seventh O site, O(7) is bonded in a distorted bent 150 degrees geometry to one Co(1) and one I(3) atom. In the eighth O site, O(8) is bonded in a water-like geometry to one Co(1) and one I(4) atom. There are four inequivalent I sites. In the first I site, I(1) is bonded in a 3-coordinate geometry to one O(1), one O(2), and one O(4) atom. In the second I site, I(2) is bonded in a trigonal non-coplanar geometry to three equivalent O(3) atoms. In the third I site, I(3) is bonded in a 3-coordinate geometry to one O(5), one O(6), and one O(7) atom. In the fourth I site, I(4) is bonded in a 3-coordinate geometry to three equivalent O(8) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Co(IO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.093
_cell_length_b   11.093
_cell_length_c   5.139
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   547.701
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.337  0.175  0.066  1.0
  Co  Co1  1  0.333  0.667  0.573  1.0
  Co  Co2  1  0.839  0.663  0.066  1.0
  Co  Co3  1  0.825  0.161  0.066  1.0
  I  I4  1  0.499  0.514  0.997  1.0
  I  I5  1  0.486  0.985  0.997  1.0
  I  I6  1  0.667  0.333  0.459  1.0
  I  I7  1  0.015  0.501  0.997  1.0
  I  I8  1  0.679  0.833  0.486  1.0
  I  I9  1  0.154  0.321  0.486  1.0
  I  I10  1  0.000  0.000  0.011  1.0
  I  I11  1  0.167  0.846  0.486  1.0
  O  O12  1  0.480  0.638  0.783  1.0
  O  O13  1  0.375  0.348  0.837  1.0
  O  O14  1  0.512  0.319  0.297  1.0
  O  O15  1  0.661  0.536  0.854  1.0
  O  O16  1  0.464  0.125  0.854  1.0
  O  O17  1  0.362  0.842  0.783  1.0
  O  O18  1  0.807  0.488  0.297  1.0
  O  O19  1  0.681  0.193  0.297  1.0
  O  O20  1  0.510  0.797  0.348  1.0
  O  O21  1  0.652  0.027  0.837  1.0
  O  O22  1  0.973  0.625  0.837  1.0
  O  O23  1  0.875  0.339  0.854  1.0
  O  O24  1  0.795  0.988  0.289  1.0
  O  O25  1  0.700  0.704  0.297  1.0
  O  O26  1  0.004  0.300  0.297  1.0
  O  O27  1  0.158  0.520  0.783  1.0
  O  O28  1  0.952  0.115  0.834  1.0
  O  O29  1  0.885  0.837  0.834  1.0
  O  O30  1  0.286  0.490  0.348  1.0
  O  O31  1  0.193  0.205  0.289  1.0
  O  O32  1  0.012  0.807  0.289  1.0
  O  O33  1  0.163  0.048  0.834  1.0
  O  O34  1  0.296  0.996  0.297  1.0
  O  O35  1  0.203  0.714  0.348  1.0
[/CIF]
.