The compound described by KSb(PS3)2 crystallizes in the monoclinic P2_1 space group. K(1) is bonded in a 9-coordinate geometry to one S(1), one S(4), two equivalent S(3), two equivalent S(6), and three equivalent S(5) atoms. Sb(1) is bonded in a distorted rectangular see-saw-like geometry to one S(1), one S(2), one S(3), and one S(4) atom. There are two inequivalent P sites. In the first P site, P(1) is bonded in a 4-coordinate geometry to one P(2), one S(1), one S(3), and one S(5) atom. In the second P site, P(2) is bonded in a distorted tetrahedral geometry to one P(1), one S(2), one S(4), and one S(6) atom. There are six inequivalent S sites. In the first S site, S(1) is bonded in a distorted L-shaped geometry to one K(1), one Sb(1), and one P(1) atom. In the second S site, S(2) is bonded in a water-like geometry to one Sb(1) and one P(2) atom. In the third S site, S(3) is bonded in a 4-coordinate geometry to two equivalent K(1), one Sb(1), and one P(1) atom. In the fourth S site, S(4) is bonded in a 3-coordinate geometry to one K(1), one Sb(1), and one P(2) atom. In the fifth S site, S(5) is bonded in a 4-coordinate geometry to three equivalent K(1) and one P(1) atom. In the sixth S site, S(6) is bonded in a distorted single-bond geometry to two equivalent K(1) and one P(2) atom. is represented by the CIF file [CIF]
data_KSb(PS3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.878
_cell_length_b   6.761
_cell_length_c   9.906
_cell_angle_alpha   87.608
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   527.118
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.446  0.695  0.492  1.0
  K  K1  1  0.946  0.305  0.508  1.0
  Sb  Sb2  1  0.737  0.815  0.018  1.0
  Sb  Sb3  1  0.237  0.185  0.982  1.0
  P  P4  1  0.933  0.796  0.302  1.0
  P  P5  1  0.649  0.306  0.829  1.0
  P  P6  1  0.149  0.694  0.171  1.0
  P  P7  1  0.433  0.204  0.698  1.0
  S  S8  1  0.359  0.950  0.807  1.0
  S  S9  1  0.035  0.673  0.982  1.0
  S  S10  1  0.249  0.408  0.731  1.0
  S  S11  1  0.535  0.327  0.018  1.0
  S  S12  1  0.836  0.093  0.830  1.0
  S  S13  1  0.336  0.907  0.170  1.0
  S  S14  1  0.749  0.592  0.269  1.0
  S  S15  1  0.859  0.050  0.193  1.0
  S  S16  1  0.514  0.174  0.512  1.0
  S  S17  1  0.735  0.567  0.753  1.0
  S  S18  1  0.014  0.826  0.488  1.0
  S  S19  1  0.235  0.433  0.247  1.0
[/CIF]
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The compound described by KSb(PS3)2 crystallizes in the monoclinic P2_1 space group. K(1) is bonded in a 9-coordinate geometry to one S(1), one S(4), two equivalent S(3), two equivalent S(6), and three equivalent S(5) atoms. Sb(1) is bonded in a distorted rectangular see-saw-like geometry to one S(1), one S(2), one S(3), and one S(4) atom. There are two inequivalent P sites. In the first P site, P(1) is bonded in a 4-coordinate geometry to one P(2), one S(1), one S(3), and one S(5) atom. In the second P site, P(2) is bonded in a distorted tetrahedral geometry to one P(1), one S(2), one S(4), and one S(6) atom. There are six inequivalent S sites. In the first S site, S(1) is bonded in a distorted L-shaped geometry to one K(1), one Sb(1), and one P(1) atom. In the second S site, S(2) is bonded in a water-like geometry to one Sb(1) and one P(2) atom. In the third S site, S(3) is bonded in a 4-coordinate geometry to two equivalent K(1), one Sb(1), and one P(1) atom. In the fourth S site, S(4) is bonded in a 3-coordinate geometry to one K(1), one Sb(1), and one P(2) atom. In the fifth S site, S(5) is bonded in a 4-coordinate geometry to three equivalent K(1) and one P(1) atom. In the sixth S site, S(6) is bonded in a distorted single-bond geometry to two equivalent K(1) and one P(2) atom. is represented by the CIF file [CIF]
data_KSb(PS3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.878
_cell_length_b   6.761
_cell_length_c   9.906
_cell_angle_alpha   87.608
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   527.118
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.446  0.695  0.492  1.0
  K  K1  1  0.946  0.305  0.508  1.0
  Sb  Sb2  1  0.737  0.815  0.018  1.0
  Sb  Sb3  1  0.237  0.185  0.982  1.0
  P  P4  1  0.933  0.796  0.302  1.0
  P  P5  1  0.649  0.306  0.829  1.0
  P  P6  1  0.149  0.694  0.171  1.0
  P  P7  1  0.433  0.204  0.698  1.0
  S  S8  1  0.359  0.950  0.807  1.0
  S  S9  1  0.035  0.673  0.982  1.0
  S  S10  1  0.249  0.408  0.731  1.0
  S  S11  1  0.535  0.327  0.018  1.0
  S  S12  1  0.836  0.093  0.830  1.0
  S  S13  1  0.336  0.907  0.170  1.0
  S  S14  1  0.749  0.592  0.269  1.0
  S  S15  1  0.859  0.050  0.193  1.0
  S  S16  1  0.514  0.174  0.512  1.0
  S  S17  1  0.735  0.567  0.753  1.0
  S  S18  1  0.014  0.826  0.488  1.0
  S  S19  1  0.235  0.433  0.247  1.0
[/CIF]
.