The crystal structure described by SrBiO2Cl is lead oxide-derived structured and crystallizes in the orthorhombic Cmcm space group. Sr(1) is bonded in a 4-coordinate geometry to four equivalent O(1) and four equivalent Cl(1) atoms. Bi(1) is bonded in a 4-coordinate geometry to four equivalent O(1) atoms. O(1) is bonded to two equivalent Sr(1) and two equivalent Bi(1) atoms to form OSr2Bi2 tetrahedra that share corners with four equivalent O(1)Sr2Bi2 tetrahedra, corners with eight equivalent Cl(1)Sr4 tetrahedra, and edges with four equivalent O(1)Sr2Bi2 tetrahedra. Cl(1) is bonded to four equivalent Sr(1) atoms to form ClSr4 tetrahedra that share corners with four equivalent Cl(1)Sr4 tetrahedra, corners with sixteen equivalent O(1)Sr2Bi2 tetrahedra, and edges with four equivalent Cl(1)Sr4 tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_SrBiClO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.988
_cell_length_b   6.988
_cell_length_c   5.681
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   131.020
_symmetry_Int_Tables_number   1
_cell_volume   209.260
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.892  0.108  0.750  1.0
  Sr  Sr1  1  0.108  0.892  0.250  1.0
  Bi  Bi2  1  0.419  0.581  0.250  1.0
  Bi  Bi3  1  0.581  0.419  0.750  1.0
  Cl  Cl4  1  0.756  0.244  0.250  1.0
  Cl  Cl5  1  0.244  0.756  0.750  1.0
  O  O6  1  0.735  0.735  0.000  1.0
  O  O7  1  0.735  0.735  0.500  1.0
  O  O8  1  0.265  0.265  0.500  1.0
  O  O9  1  0.265  0.265  0.000  1.0
[/CIF]
.
The crystal structure described by SrBiO2Cl is lead oxide-derived structured and crystallizes in the orthorhombic Cmcm space group. Sr(1) is bonded in a 4-coordinate geometry to four equivalent O(1) and four equivalent Cl(1) atoms. Bi(1) is bonded in a 4-coordinate geometry to four equivalent O(1) atoms. O(1) is bonded to two equivalent Sr(1) and two equivalent Bi(1) atoms to form OSr2Bi2 tetrahedra that share corners with four equivalent O(1)Sr2Bi2 tetrahedra, corners with eight equivalent Cl(1)Sr4 tetrahedra, and edges with four equivalent O(1)Sr2Bi2 tetrahedra. Cl(1) is bonded to four equivalent Sr(1) atoms to form ClSr4 tetrahedra that share corners with four equivalent Cl(1)Sr4 tetrahedra, corners with sixteen equivalent O(1)Sr2Bi2 tetrahedra, and edges with four equivalent Cl(1)Sr4 tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_SrBiClO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.988
_cell_length_b   6.988
_cell_length_c   5.681
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   131.020
_symmetry_Int_Tables_number   1
_cell_volume   209.260
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.892  0.108  0.750  1.0
  Sr  Sr1  1  0.108  0.892  0.250  1.0
  Bi  Bi2  1  0.419  0.581  0.250  1.0
  Bi  Bi3  1  0.581  0.419  0.750  1.0
  Cl  Cl4  1  0.756  0.244  0.250  1.0
  Cl  Cl5  1  0.244  0.756  0.750  1.0
  O  O6  1  0.735  0.735  0.000  1.0
  O  O7  1  0.735  0.735  0.500  1.0
  O  O8  1  0.265  0.265  0.500  1.0
  O  O9  1  0.265  0.265  0.000  1.0
[/CIF]
.