The crystal structure described by VSbO4 is Hydrophilite-derived structured and crystallizes in the orthorhombic Cmmm space group. V(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form VO6 octahedra that share corners with eight equivalent Sb(1)O6 octahedra and edges with two equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-51°. Sb(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form SbO6 octahedra that share corners with eight equivalent V(1)O6 octahedra and edges with two equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-51°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to two equivalent V(1) and one Sb(1) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one V(1) and two equivalent Sb(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_VSbO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.155
_cell_length_b   4.675
_cell_length_c   4.676
_cell_angle_alpha   91.339
_cell_angle_beta   89.987
_cell_angle_gamma   89.987
_symmetry_Int_Tables_number   1
_cell_volume   68.945
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  O  O0  1  0.500  0.198  0.198  1.0
  O  O1  1  0.500  0.802  0.802  1.0
  O  O2  1  0.000  0.305  0.695  1.0
  O  O3  1  1.000  0.695  0.305  1.0
  Sb  Sb4  1  0.500  0.500  0.500  1.0
  V  V5  1  0.000  0.000  1.000  1.0
[/CIF]
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The crystal structure described by VSbO4 is Hydrophilite-derived structured and crystallizes in the orthorhombic Cmmm space group. V(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form VO6 octahedra that share corners with eight equivalent Sb(1)O6 octahedra and edges with two equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-51°. Sb(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form SbO6 octahedra that share corners with eight equivalent V(1)O6 octahedra and edges with two equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-51°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to two equivalent V(1) and one Sb(1) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one V(1) and two equivalent Sb(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_VSbO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.155
_cell_length_b   4.675
_cell_length_c   4.676
_cell_angle_alpha   91.339
_cell_angle_beta   89.987
_cell_angle_gamma   89.987
_symmetry_Int_Tables_number   1
_cell_volume   68.945
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  O  O0  1  0.500  0.198  0.198  1.0
  O  O1  1  0.500  0.802  0.802  1.0
  O  O2  1  0.000  0.305  0.695  1.0
  O  O3  1  1.000  0.695  0.305  1.0
  Sb  Sb4  1  0.500  0.500  0.500  1.0
  V  V5  1  0.000  0.000  1.000  1.0
[/CIF]
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