The crystal structure described by Na5Ti16O32 is beta indium sulfide-derived structured and crystallizes in the triclinic P1 space group. There are five inequivalent Na sites. In the first Na site, Na(1) is bonded in a distorted rectangular see-saw-like geometry to one O(25), one O(5), one O(7), and one O(8) atom. In the second Na site, Na(2) is bonded in a rectangular see-saw-like geometry to one O(10), one O(12), one O(24), and one O(9) atom. In the third Na site, Na(3) is bonded in a rectangular see-saw-like geometry to one O(10), one O(22), one O(23), and one O(24) atom. In the fourth Na site, Na(4) is bonded in a rectangular see-saw-like geometry to one O(25), one O(26), one O(27), and one O(7) atom. In the fifth Na site, Na(5) is bonded in a rectangular see-saw-like geometry to one O(25), one O(26), one O(28), and one O(8) atom. There are sixteen inequivalent Ti sites. In the first Ti site, Ti(1) is bonded to one O(1), one O(27), one O(3), one O(31), one O(32), and one O(4) atom to form a mixture of corner and edge-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles range from 29-53°. In the second Ti site, Ti(2) is bonded to one O(2), one O(28), one O(3), one O(31), one O(32), and one O(4) atom to form a mixture of corner and edge-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles range from 23-51°. In the third Ti site, Ti(3) is bonded to one O(11), one O(12), one O(15), one O(3), one O(7), and one O(8) atom to form a mixture of corner and edge-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles range from 20-53°. In the fourth Ti site, Ti(4) is bonded to one O(11), one O(12), one O(16), one O(4), one O(7), and one O(8) atom to form a mixture of corner and edge-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles range from 27-52°. In the fifth Ti site, Ti(5) is bonded to one O(1), one O(10), one O(13), one O(5), one O(6), and one O(9) atom to form a mixture of distorted corner and edge-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles range from 29-52°. In the sixth Ti site, Ti(6) is bonded to one O(10), one O(14), one O(2), one O(5), one O(6), and one O(9) atom to form a mixture of corner and edge-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles range from 23-53°. In the seventh Ti site, Ti(7) is bonded to one O(13), one O(14), one O(16), one O(17), one O(18), and one O(22) atom to form a mixture of corner and edge-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles range from 27-53°. In the eighth Ti site, Ti(8) is bonded to one O(13), one O(14), one O(15), one O(17), one O(18), and one O(21) atom to form a mixture of corner and edge-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles range from 20-52°. In the ninth Ti site, Ti(9) is bonded to one O(11), one O(15), one O(16), one O(17), one O(19), and one O(20) atom to form a mixture of corner and edge-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles range from 22-54°. In the tenth Ti site, Ti(10) is bonded to one O(12), one O(15), one O(16), one O(18), one O(19), and one O(20) atom to form a mixture of corner and edge-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles range from 23-53°. In the eleventh Ti site, Ti(11) is bonded to one O(19), one O(23), one O(24), one O(27), one O(28), and one O(32) atom to form a mixture of corner and edge-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles range from 23-54°. In the twelfth Ti site, Ti(12) is bonded to one O(20), one O(23), one O(24), one O(27), one O(28), and one O(31) atom to form a mixture of distorted corner and edge-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles range from 29-52°. In the thirteenth Ti site, Ti(13) is bonded to one O(17), one O(21), one O(22), one O(25), one O(26), and one O(29) atom to form a mixture of corner and edge-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles range from 22-52°. In the fourteenth Ti site, Ti(14) is bonded to one O(18), one O(21), one O(22), one O(25), one O(26), and one O(30) atom to form a mixture of corner and edge-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles range from 23-52°. In the fifteenth Ti site, Ti(15) is bonded to one O(1), one O(2), one O(29), one O(30), one O(31), and one O(5) atom to form a mixture of corner and edge-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles range from 29-52°. In the sixteenth Ti site, Ti(16) is bonded to one O(1), one O(2), one O(29), one O(30), one O(32), and one O(6) atom to form a mixture of corner and edge-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles range from 23-51°. There are thirty-two inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Ti(1), one Ti(15), one Ti(16), and one Ti(5) atom. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to one Ti(15), one Ti(16), one Ti(2), and one Ti(6) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Ti(1), one Ti(2), and one Ti(3) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Ti(1), one Ti(2), and one Ti(4) atom. In the fifth O site, O(5) is bonded to one Na(1), one Ti(15), one Ti(5), and one Ti(6) atom to form distorted corner-sharing ONaTi3 tetrahedra. In the sixth O site, O(6) is bonded in a distorted trigonal non-coplanar geometry to one Ti(16), one Ti(5), and one Ti(6) atom. In the seventh O site, O(7) is bonded in a distorted see-saw-like geometry to one Na(1), one Na(4), one Ti(3), and one Ti(4) atom. In the eighth O site, O(8) is bonded in a distorted see-saw-like geometry to one Na(1), one Na(5), one Ti(3), and one Ti(4) atom. In the ninth O site, O(9) is bonded in a distorted T-shaped geometry to one Na(2), one Ti(5), and one Ti(6) atom. In the tenth O site, O(10) is bonded in a distorted see-saw-like geometry to one Na(2), one Na(3), one Ti(5), and one Ti(6) atom. In the eleventh O site, O(11) is bonded in a trigonal non-coplanar geometry to one Ti(3), one Ti(4), and one Ti(9) atom. In the twelfth O site, O(12) is bonded in a distorted tetrahedral geometry to one Na(2), one Ti(10), one Ti(3), and one Ti(4) atom. In the thirteenth O site, O(13) is bonded in a distorted trigonal planar geometry to one Ti(5), one Ti(7), and one Ti(8) atom. In the fourteenth O site, O(14) is bonded in a distorted trigonal planar geometry to one Ti(6), one Ti(7), and one Ti(8) atom. In the fifteenth O site, O(15) is bonded in a rectangular see-saw-like geometry to one Ti(10), one Ti(3), one Ti(8), and one Ti(9) atom. In the sixteenth O site, O(16) is bonded in a rectangular see-saw-like geometry to one Ti(10), one Ti(4), one Ti(7), and one Ti(9) atom. In the seventeenth O site, O(17) is bonded in a rectangular see-saw-like geometry to one Ti(13), one Ti(7), one Ti(8), and one Ti(9) atom. In the eighteenth O site, O(18) is bonded in a rectangular see-saw-like geometry to one Ti(10), one Ti(14), one Ti(7), and one Ti(8) atom. In the nineteenth O site, O(19) is bonded in a trigonal planar geometry to one Ti(10), one Ti(11), and one Ti(9) atom. In the twentieth O site, O(20) is bonded in a distorted trigonal planar geometry to one Ti(10), one Ti(12), and one Ti(9) atom. In the twenty-first O site, O(21) is bonded in a trigonal non-coplanar geometry to one Ti(13), one Ti(14), and one Ti(8) atom. In the twenty-second O site, O(22) is bonded in a tetrahedral geometry to one Na(3), one Ti(13), one Ti(14), and one Ti(7) atom. In the twenty-third O site, O(23) is bonded in a distorted T-shaped geometry to one Na(3), one Ti(11), and one Ti(12) atom. In the twenty-fourth O site, O(24) is bonded in a 4-coordinate geometry to one Na(2), one Na(3), one Ti(11), and one Ti(12) atom. In the twenty-fifth O site, O(25) is bonded in a 5-coordinate geometry to one Na(1), one Na(4), one Na(5), one Ti(13), and one Ti(14) atom. In the twenty-sixth O site, O(26) is bonded in a distorted rectangular see-saw-like geometry to one Na(4), one Na(5), one Ti(13), and one Ti(14) atom. In the twenty-seventh O site, O(27) is bonded to one Na(4), one Ti(1), one Ti(11), and one Ti(12) atom to form distorted ONaTi3 tetrahedra that share corners with two equivalent O(28)NaTi3 tetrahedra and  an edgeedge with one O(31)Ti4 trigonal pyramid. In the twenty-eighth O site, O(28) is bonded to one Na(5), one Ti(11), one Ti(12), and one Ti(2) atom to form distorted ONaTi3 tetrahedra that share corners with two equivalent O(27)NaTi3 tetrahedra and  an edgeedge with one O(31)Ti4 trigonal pyramid. In the twenty-ninth O site, O(29) is bonded in a distorted trigonal planar geometry to one Ti(13), one Ti(15), and one Ti(16) atom. In the thirtieth O site, O(30) is bonded in a distorted trigonal planar geometry to one Ti(14), one Ti(15), and one Ti(16) atom. In the thirty-first O site, O(31) is bonded to one Ti(1), one Ti(12), one Ti(15), and one Ti(2) atom to form a mixture of corner and edge-sharing OTi4 trigonal pyramids. In the thirty-second O site, O(32) is bonded in a rectangular see-saw-like geometry to one Ti(1), one Ti(11), one Ti(16), and one Ti(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Na5Ti16O32
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.949
_cell_length_b   9.630
_cell_length_c   11.389
_cell_angle_alpha   90.556
_cell_angle_beta   90.040
_cell_angle_gamma   90.064
_symmetry_Int_Tables_number   1
_cell_volume   652.406
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.627  0.117  0.419  1.0
  Na  Na1  1  0.390  0.395  0.924  1.0
  Na  Na2  1  0.109  0.604  0.076  1.0
  Na  Na3  1  0.881  0.894  0.575  1.0
  Na  Na4  1  0.369  0.895  0.575  1.0
  Ti  Ti5  1  0.879  0.020  0.877  1.0
  Ti  Ti6  1  0.372  0.016  0.879  1.0
  Ti  Ti7  1  0.626  0.239  0.670  1.0
  Ti  Ti8  1  0.124  0.231  0.655  1.0
  Ti  Ti9  1  0.875  0.270  0.154  1.0
  Ti  Ti10  1  0.375  0.262  0.170  1.0
  Ti  Ti11  1  0.120  0.481  0.380  1.0
  Ti  Ti12  1  0.630  0.486  0.379  1.0
  Ti  Ti13  1  0.871  0.515  0.624  1.0
  Ti  Ti14  1  0.379  0.517  0.621  1.0
  Ti  Ti15  1  0.124  0.739  0.831  1.0
  Ti  Ti16  1  0.625  0.731  0.845  1.0
  Ti  Ti17  1  0.875  0.763  0.335  1.0
  Ti  Ti18  1  0.375  0.763  0.335  1.0
  Ti  Ti19  1  0.625  0.980  0.121  1.0
  Ti  Ti20  1  0.125  0.986  0.123  1.0
  O  O21  1  0.875  0.100  0.041  1.0
  O  O22  1  0.375  0.100  0.040  1.0
  O  O23  1  0.623  0.127  0.811  1.0
  O  O24  1  0.127  0.125  0.806  1.0
  O  O25  1  0.626  0.136  0.228  1.0
  O  O26  1  0.124  0.140  0.228  1.0
  O  O27  1  0.868  0.138  0.593  1.0
  O  O28  1  0.381  0.140  0.592  1.0
  O  O29  1  0.619  0.351  0.091  1.0
  O  O30  1  0.132  0.358  0.092  1.0
  O  O31  1  0.877  0.361  0.727  1.0
  O  O32  1  0.374  0.363  0.728  1.0
  O  O33  1  0.872  0.374  0.307  1.0
  O  O34  1  0.378  0.374  0.312  1.0
  O  O35  1  0.625  0.397  0.539  1.0
  O  O36  1  0.125  0.398  0.539  1.0
  O  O37  1  0.876  0.602  0.462  1.0
  O  O38  1  0.375  0.602  0.461  1.0
  O  O39  1  0.125  0.631  0.686  1.0
  O  O40  1  0.626  0.629  0.691  1.0
  O  O41  1  0.625  0.640  0.273  1.0
  O  O42  1  0.125  0.636  0.271  1.0
  O  O43  1  0.881  0.648  0.908  1.0
  O  O44  1  0.368  0.643  0.907  1.0
  O  O45  1  0.625  0.859  0.414  1.0
  O  O46  1  0.125  0.849  0.415  1.0
  O  O47  1  0.874  0.864  0.769  1.0
  O  O48  1  0.376  0.862  0.769  1.0
  O  O49  1  0.877  0.874  0.191  1.0
  O  O50  1  0.372  0.874  0.192  1.0
  O  O51  1  0.625  0.899  0.958  1.0
  O  O52  1  0.124  0.899  0.958  1.0
[/CIF]
.
The crystal structure described by Na5Ti16O32 is beta indium sulfide-derived structured and crystallizes in the triclinic P1 space group. There are five inequivalent Na sites. In the first Na site, Na(1) is bonded in a distorted rectangular see-saw-like geometry to one O(25), one O(5), one O(7), and one O(8) atom. In the second Na site, Na(2) is bonded in a rectangular see-saw-like geometry to one O(10), one O(12), one O(24), and one O(9) atom. In the third Na site, Na(3) is bonded in a rectangular see-saw-like geometry to one O(10), one O(22), one O(23), and one O(24) atom. In the fourth Na site, Na(4) is bonded in a rectangular see-saw-like geometry to one O(25), one O(26), one O(27), and one O(7) atom. In the fifth Na site, Na(5) is bonded in a rectangular see-saw-like geometry to one O(25), one O(26), one O(28), and one O(8) atom. There are sixteen inequivalent Ti sites. In the first Ti site, Ti(1) is bonded to one O(1), one O(27), one O(3), one O(31), one O(32), and one O(4) atom to form a mixture of corner and edge-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles range from 29-53°. In the second Ti site, Ti(2) is bonded to one O(2), one O(28), one O(3), one O(31), one O(32), and one O(4) atom to form a mixture of corner and edge-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles range from 23-51°. In the third Ti site, Ti(3) is bonded to one O(11), one O(12), one O(15), one O(3), one O(7), and one O(8) atom to form a mixture of corner and edge-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles range from 20-53°. In the fourth Ti site, Ti(4) is bonded to one O(11), one O(12), one O(16), one O(4), one O(7), and one O(8) atom to form a mixture of corner and edge-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles range from 27-52°. In the fifth Ti site, Ti(5) is bonded to one O(1), one O(10), one O(13), one O(5), one O(6), and one O(9) atom to form a mixture of distorted corner and edge-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles range from 29-52°. In the sixth Ti site, Ti(6) is bonded to one O(10), one O(14), one O(2), one O(5), one O(6), and one O(9) atom to form a mixture of corner and edge-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles range from 23-53°. In the seventh Ti site, Ti(7) is bonded to one O(13), one O(14), one O(16), one O(17), one O(18), and one O(22) atom to form a mixture of corner and edge-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles range from 27-53°. In the eighth Ti site, Ti(8) is bonded to one O(13), one O(14), one O(15), one O(17), one O(18), and one O(21) atom to form a mixture of corner and edge-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles range from 20-52°. In the ninth Ti site, Ti(9) is bonded to one O(11), one O(15), one O(16), one O(17), one O(19), and one O(20) atom to form a mixture of corner and edge-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles range from 22-54°. In the tenth Ti site, Ti(10) is bonded to one O(12), one O(15), one O(16), one O(18), one O(19), and one O(20) atom to form a mixture of corner and edge-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles range from 23-53°. In the eleventh Ti site, Ti(11) is bonded to one O(19), one O(23), one O(24), one O(27), one O(28), and one O(32) atom to form a mixture of corner and edge-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles range from 23-54°. In the twelfth Ti site, Ti(12) is bonded to one O(20), one O(23), one O(24), one O(27), one O(28), and one O(31) atom to form a mixture of distorted corner and edge-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles range from 29-52°. In the thirteenth Ti site, Ti(13) is bonded to one O(17), one O(21), one O(22), one O(25), one O(26), and one O(29) atom to form a mixture of corner and edge-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles range from 22-52°. In the fourteenth Ti site, Ti(14) is bonded to one O(18), one O(21), one O(22), one O(25), one O(26), and one O(30) atom to form a mixture of corner and edge-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles range from 23-52°. In the fifteenth Ti site, Ti(15) is bonded to one O(1), one O(2), one O(29), one O(30), one O(31), and one O(5) atom to form a mixture of corner and edge-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles range from 29-52°. In the sixteenth Ti site, Ti(16) is bonded to one O(1), one O(2), one O(29), one O(30), one O(32), and one O(6) atom to form a mixture of corner and edge-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles range from 23-51°. There are thirty-two inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Ti(1), one Ti(15), one Ti(16), and one Ti(5) atom. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to one Ti(15), one Ti(16), one Ti(2), and one Ti(6) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Ti(1), one Ti(2), and one Ti(3) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Ti(1), one Ti(2), and one Ti(4) atom. In the fifth O site, O(5) is bonded to one Na(1), one Ti(15), one Ti(5), and one Ti(6) atom to form distorted corner-sharing ONaTi3 tetrahedra. In the sixth O site, O(6) is bonded in a distorted trigonal non-coplanar geometry to one Ti(16), one Ti(5), and one Ti(6) atom. In the seventh O site, O(7) is bonded in a distorted see-saw-like geometry to one Na(1), one Na(4), one Ti(3), and one Ti(4) atom. In the eighth O site, O(8) is bonded in a distorted see-saw-like geometry to one Na(1), one Na(5), one Ti(3), and one Ti(4) atom. In the ninth O site, O(9) is bonded in a distorted T-shaped geometry to one Na(2), one Ti(5), and one Ti(6) atom. In the tenth O site, O(10) is bonded in a distorted see-saw-like geometry to one Na(2), one Na(3), one Ti(5), and one Ti(6) atom. In the eleventh O site, O(11) is bonded in a trigonal non-coplanar geometry to one Ti(3), one Ti(4), and one Ti(9) atom. In the twelfth O site, O(12) is bonded in a distorted tetrahedral geometry to one Na(2), one Ti(10), one Ti(3), and one Ti(4) atom. In the thirteenth O site, O(13) is bonded in a distorted trigonal planar geometry to one Ti(5), one Ti(7), and one Ti(8) atom. In the fourteenth O site, O(14) is bonded in a distorted trigonal planar geometry to one Ti(6), one Ti(7), and one Ti(8) atom. In the fifteenth O site, O(15) is bonded in a rectangular see-saw-like geometry to one Ti(10), one Ti(3), one Ti(8), and one Ti(9) atom. In the sixteenth O site, O(16) is bonded in a rectangular see-saw-like geometry to one Ti(10), one Ti(4), one Ti(7), and one Ti(9) atom. In the seventeenth O site, O(17) is bonded in a rectangular see-saw-like geometry to one Ti(13), one Ti(7), one Ti(8), and one Ti(9) atom. In the eighteenth O site, O(18) is bonded in a rectangular see-saw-like geometry to one Ti(10), one Ti(14), one Ti(7), and one Ti(8) atom. In the nineteenth O site, O(19) is bonded in a trigonal planar geometry to one Ti(10), one Ti(11), and one Ti(9) atom. In the twentieth O site, O(20) is bonded in a distorted trigonal planar geometry to one Ti(10), one Ti(12), and one Ti(9) atom. In the twenty-first O site, O(21) is bonded in a trigonal non-coplanar geometry to one Ti(13), one Ti(14), and one Ti(8) atom. In the twenty-second O site, O(22) is bonded in a tetrahedral geometry to one Na(3), one Ti(13), one Ti(14), and one Ti(7) atom. In the twenty-third O site, O(23) is bonded in a distorted T-shaped geometry to one Na(3), one Ti(11), and one Ti(12) atom. In the twenty-fourth O site, O(24) is bonded in a 4-coordinate geometry to one Na(2), one Na(3), one Ti(11), and one Ti(12) atom. In the twenty-fifth O site, O(25) is bonded in a 5-coordinate geometry to one Na(1), one Na(4), one Na(5), one Ti(13), and one Ti(14) atom. In the twenty-sixth O site, O(26) is bonded in a distorted rectangular see-saw-like geometry to one Na(4), one Na(5), one Ti(13), and one Ti(14) atom. In the twenty-seventh O site, O(27) is bonded to one Na(4), one Ti(1), one Ti(11), and one Ti(12) atom to form distorted ONaTi3 tetrahedra that share corners with two equivalent O(28)NaTi3 tetrahedra and  an edgeedge with one O(31)Ti4 trigonal pyramid. In the twenty-eighth O site, O(28) is bonded to one Na(5), one Ti(11), one Ti(12), and one Ti(2) atom to form distorted ONaTi3 tetrahedra that share corners with two equivalent O(27)NaTi3 tetrahedra and  an edgeedge with one O(31)Ti4 trigonal pyramid. In the twenty-ninth O site, O(29) is bonded in a distorted trigonal planar geometry to one Ti(13), one Ti(15), and one Ti(16) atom. In the thirtieth O site, O(30) is bonded in a distorted trigonal planar geometry to one Ti(14), one Ti(15), and one Ti(16) atom. In the thirty-first O site, O(31) is bonded to one Ti(1), one Ti(12), one Ti(15), and one Ti(2) atom to form a mixture of corner and edge-sharing OTi4 trigonal pyramids. In the thirty-second O site, O(32) is bonded in a rectangular see-saw-like geometry to one Ti(1), one Ti(11), one Ti(16), and one Ti(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Na5Ti16O32
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.949
_cell_length_b   9.630
_cell_length_c   11.389
_cell_angle_alpha   90.556
_cell_angle_beta   90.040
_cell_angle_gamma   90.064
_symmetry_Int_Tables_number   1
_cell_volume   652.406
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.627  0.117  0.419  1.0
  Na  Na1  1  0.390  0.395  0.924  1.0
  Na  Na2  1  0.109  0.604  0.076  1.0
  Na  Na3  1  0.881  0.894  0.575  1.0
  Na  Na4  1  0.369  0.895  0.575  1.0
  Ti  Ti5  1  0.879  0.020  0.877  1.0
  Ti  Ti6  1  0.372  0.016  0.879  1.0
  Ti  Ti7  1  0.626  0.239  0.670  1.0
  Ti  Ti8  1  0.124  0.231  0.655  1.0
  Ti  Ti9  1  0.875  0.270  0.154  1.0
  Ti  Ti10  1  0.375  0.262  0.170  1.0
  Ti  Ti11  1  0.120  0.481  0.380  1.0
  Ti  Ti12  1  0.630  0.486  0.379  1.0
  Ti  Ti13  1  0.871  0.515  0.624  1.0
  Ti  Ti14  1  0.379  0.517  0.621  1.0
  Ti  Ti15  1  0.124  0.739  0.831  1.0
  Ti  Ti16  1  0.625  0.731  0.845  1.0
  Ti  Ti17  1  0.875  0.763  0.335  1.0
  Ti  Ti18  1  0.375  0.763  0.335  1.0
  Ti  Ti19  1  0.625  0.980  0.121  1.0
  Ti  Ti20  1  0.125  0.986  0.123  1.0
  O  O21  1  0.875  0.100  0.041  1.0
  O  O22  1  0.375  0.100  0.040  1.0
  O  O23  1  0.623  0.127  0.811  1.0
  O  O24  1  0.127  0.125  0.806  1.0
  O  O25  1  0.626  0.136  0.228  1.0
  O  O26  1  0.124  0.140  0.228  1.0
  O  O27  1  0.868  0.138  0.593  1.0
  O  O28  1  0.381  0.140  0.592  1.0
  O  O29  1  0.619  0.351  0.091  1.0
  O  O30  1  0.132  0.358  0.092  1.0
  O  O31  1  0.877  0.361  0.727  1.0
  O  O32  1  0.374  0.363  0.728  1.0
  O  O33  1  0.872  0.374  0.307  1.0
  O  O34  1  0.378  0.374  0.312  1.0
  O  O35  1  0.625  0.397  0.539  1.0
  O  O36  1  0.125  0.398  0.539  1.0
  O  O37  1  0.876  0.602  0.462  1.0
  O  O38  1  0.375  0.602  0.461  1.0
  O  O39  1  0.125  0.631  0.686  1.0
  O  O40  1  0.626  0.629  0.691  1.0
  O  O41  1  0.625  0.640  0.273  1.0
  O  O42  1  0.125  0.636  0.271  1.0
  O  O43  1  0.881  0.648  0.908  1.0
  O  O44  1  0.368  0.643  0.907  1.0
  O  O45  1  0.625  0.859  0.414  1.0
  O  O46  1  0.125  0.849  0.415  1.0
  O  O47  1  0.874  0.864  0.769  1.0
  O  O48  1  0.376  0.862  0.769  1.0
  O  O49  1  0.877  0.874  0.191  1.0
  O  O50  1  0.372  0.874  0.192  1.0
  O  O51  1  0.625  0.899  0.958  1.0
  O  O52  1  0.124  0.899  0.958  1.0
[/CIF]
.