The compound described by N2SbF3SbF5 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight ammonia atoms, four antimony trifluoride molecules, and four SbF5 clusters. In each SbF5 cluster, Sb(2) is bonded in a trigonal bipyramidal geometry to one F(4), one F(5), one F(6), one F(7), and one F(8) atom. There are five inequivalent F sites. In the first F site, F(5) is bonded in a single-bond geometry to one Sb(2) atom. In the second F site, F(6) is bonded in a single-bond geometry to one Sb(2) atom. In the third F site, F(7) is bonded in a single-bond geometry to one Sb(2) atom. In the fourth F site, F(8) is bonded in a single-bond geometry to one Sb(2) atom. In the fifth F site, F(4) is bonded in a single-bond geometry to one Sb(2) atom. is represented by the CIF card [CIF]
data_SbNF4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.231
_cell_length_b   8.657
_cell_length_c   17.768
_cell_angle_alpha   74.736
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1073.077
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.249  0.679  0.591  1.0
  Sb  Sb1  1  0.749  0.321  0.909  1.0
  Sb  Sb2  1  0.751  0.321  0.409  1.0
  Sb  Sb3  1  0.251  0.679  0.091  1.0
  Sb  Sb4  1  0.697  0.803  0.722  1.0
  Sb  Sb5  1  0.197  0.197  0.778  1.0
  Sb  Sb6  1  0.303  0.197  0.278  1.0
  Sb  Sb7  1  0.803  0.803  0.222  1.0
  N  N8  1  0.264  0.634  0.869  1.0
  N  N9  1  0.764  0.366  0.631  1.0
  N  N10  1  0.736  0.366  0.131  1.0
  N  N11  1  0.236  0.634  0.369  1.0
  N  N12  1  0.236  0.168  0.543  1.0
  N  N13  1  0.736  0.832  0.957  1.0
  N  N14  1  0.764  0.832  0.457  1.0
  N  N15  1  0.264  0.168  0.043  1.0
  F  F16  1  0.197  0.828  0.492  1.0
  F  F17  1  0.697  0.172  0.008  1.0
  F  F18  1  0.803  0.172  0.508  1.0
  F  F19  1  0.303  0.828  0.992  1.0
  F  F20  1  0.133  0.500  0.566  1.0
  F  F21  1  0.633  0.500  0.934  1.0
  F  F22  1  0.867  0.500  0.434  1.0
  F  F23  1  0.367  0.500  0.066  1.0
  F  F24  1  0.493  0.626  0.562  1.0
  F  F25  1  0.993  0.374  0.938  1.0
  F  F26  1  0.507  0.374  0.438  1.0
  F  F27  1  0.007  0.626  0.062  1.0
  F  F28  1  0.524  0.896  0.643  1.0
  F  F29  1  0.024  0.104  0.857  1.0
  F  F30  1  0.476  0.104  0.357  1.0
  F  F31  1  0.976  0.896  0.143  1.0
  F  F32  1  0.595  0.596  0.749  1.0
  F  F33  1  0.095  0.404  0.751  1.0
  F  F34  1  0.405  0.404  0.251  1.0
  F  F35  1  0.905  0.596  0.249  1.0
  F  F36  1  0.894  0.766  0.794  1.0
  F  F37  1  0.394  0.234  0.706  1.0
  F  F38  1  0.106  0.234  0.206  1.0
  F  F39  1  0.606  0.766  0.294  1.0
  F  F40  1  0.572  0.916  0.785  1.0
  F  F41  1  0.072  0.084  0.715  1.0
  F  F42  1  0.428  0.084  0.215  1.0
  F  F43  1  0.928  0.916  0.285  1.0
  F  F44  1  0.873  0.802  0.644  1.0
  F  F45  1  0.373  0.198  0.856  1.0
  F  F46  1  0.127  0.198  0.356  1.0
  F  F47  1  0.627  0.802  0.144  1.0
[/CIF]
.
The compound described by N2SbF3SbF5 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight ammonia atoms, four antimony trifluoride molecules, and four SbF5 clusters. In each SbF5 cluster, Sb(2) is bonded in a trigonal bipyramidal geometry to one F(4), one F(5), one F(6), one F(7), and one F(8) atom. There are five inequivalent F sites. In the first F site, F(5) is bonded in a single-bond geometry to one Sb(2) atom. In the second F site, F(6) is bonded in a single-bond geometry to one Sb(2) atom. In the third F site, F(7) is bonded in a single-bond geometry to one Sb(2) atom. In the fourth F site, F(8) is bonded in a single-bond geometry to one Sb(2) atom. In the fifth F site, F(4) is bonded in a single-bond geometry to one Sb(2) atom. is represented by the CIF card [CIF]
data_SbNF4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.231
_cell_length_b   8.657
_cell_length_c   17.768
_cell_angle_alpha   74.736
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1073.077
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.249  0.679  0.591  1.0
  Sb  Sb1  1  0.749  0.321  0.909  1.0
  Sb  Sb2  1  0.751  0.321  0.409  1.0
  Sb  Sb3  1  0.251  0.679  0.091  1.0
  Sb  Sb4  1  0.697  0.803  0.722  1.0
  Sb  Sb5  1  0.197  0.197  0.778  1.0
  Sb  Sb6  1  0.303  0.197  0.278  1.0
  Sb  Sb7  1  0.803  0.803  0.222  1.0
  N  N8  1  0.264  0.634  0.869  1.0
  N  N9  1  0.764  0.366  0.631  1.0
  N  N10  1  0.736  0.366  0.131  1.0
  N  N11  1  0.236  0.634  0.369  1.0
  N  N12  1  0.236  0.168  0.543  1.0
  N  N13  1  0.736  0.832  0.957  1.0
  N  N14  1  0.764  0.832  0.457  1.0
  N  N15  1  0.264  0.168  0.043  1.0
  F  F16  1  0.197  0.828  0.492  1.0
  F  F17  1  0.697  0.172  0.008  1.0
  F  F18  1  0.803  0.172  0.508  1.0
  F  F19  1  0.303  0.828  0.992  1.0
  F  F20  1  0.133  0.500  0.566  1.0
  F  F21  1  0.633  0.500  0.934  1.0
  F  F22  1  0.867  0.500  0.434  1.0
  F  F23  1  0.367  0.500  0.066  1.0
  F  F24  1  0.493  0.626  0.562  1.0
  F  F25  1  0.993  0.374  0.938  1.0
  F  F26  1  0.507  0.374  0.438  1.0
  F  F27  1  0.007  0.626  0.062  1.0
  F  F28  1  0.524  0.896  0.643  1.0
  F  F29  1  0.024  0.104  0.857  1.0
  F  F30  1  0.476  0.104  0.357  1.0
  F  F31  1  0.976  0.896  0.143  1.0
  F  F32  1  0.595  0.596  0.749  1.0
  F  F33  1  0.095  0.404  0.751  1.0
  F  F34  1  0.405  0.404  0.251  1.0
  F  F35  1  0.905  0.596  0.249  1.0
  F  F36  1  0.894  0.766  0.794  1.0
  F  F37  1  0.394  0.234  0.706  1.0
  F  F38  1  0.106  0.234  0.206  1.0
  F  F39  1  0.606  0.766  0.294  1.0
  F  F40  1  0.572  0.916  0.785  1.0
  F  F41  1  0.072  0.084  0.715  1.0
  F  F42  1  0.428  0.084  0.215  1.0
  F  F43  1  0.928  0.916  0.285  1.0
  F  F44  1  0.873  0.802  0.644  1.0
  F  F45  1  0.373  0.198  0.856  1.0
  F  F46  1  0.127  0.198  0.356  1.0
  F  F47  1  0.627  0.802  0.144  1.0
[/CIF]
.