The material described by CoH8Se2(O4Cl)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two CoH8Se2(O4Cl)2 clusters. Co(1) is bonded in an octahedral geometry to two equivalent O(2), two equivalent O(4), and two equivalent Cl(1) atoms. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(4) atom. Se(1) is bonded in a distorted T-shaped geometry to one O(1), one O(2), and one O(3) atom. There are four inequivalent O sites. In the first O site, O(3) is bonded in a distorted water-like geometry to one H(2) and one Se(1) atom. In the second O site, O(4) is bonded in a distorted water-like geometry to one Co(1), one H(3), and one H(4) atom. In the third O site, O(1) is bonded in a distorted single-bond geometry to one H(1) and one Se(1) atom. In the fourth O site, O(2) is bonded in a bent 120 degrees geometry to one Co(1) and one Se(1) atom. Cl(1) is bonded in a single-bond geometry to one Co(1) atom. is represented by the CIF file [CIF]
data_CoH8Se2(ClO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.174
_cell_length_b   6.560
_cell_length_c   14.971
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   93.151
_symmetry_Int_Tables_number   1
_cell_volume   507.412
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.000  0.500  0.000  1.0
  Co  Co1  1  0.000  0.000  0.500  1.0
  H  H2  1  0.083  0.214  0.697  1.0
  H  H3  1  0.917  0.286  0.197  1.0
  H  H4  1  0.917  0.786  0.303  1.0
  H  H5  1  0.083  0.714  0.803  1.0
  H  H6  1  0.707  0.334  0.770  1.0
  H  H7  1  0.293  0.166  0.270  1.0
  H  H8  1  0.293  0.666  0.230  1.0
  H  H9  1  0.707  0.834  0.730  1.0
  H  H10  1  0.423  0.340  0.079  1.0
  H  H11  1  0.577  0.160  0.579  1.0
  H  H12  1  0.577  0.660  0.921  1.0
  H  H13  1  0.423  0.840  0.421  1.0
  H  H14  1  0.227  0.152  0.056  1.0
  H  H15  1  0.773  0.348  0.556  1.0
  H  H16  1  0.773  0.848  0.944  1.0
  H  H17  1  0.227  0.652  0.444  1.0
  Se  Se18  1  0.293  0.292  0.831  1.0
  Se  Se19  1  0.707  0.208  0.331  1.0
  Se  Se20  1  0.707  0.708  0.169  1.0
  Se  Se21  1  0.293  0.792  0.669  1.0
  Cl  Cl22  1  0.763  0.196  0.942  1.0
  Cl  Cl23  1  0.237  0.304  0.442  1.0
  Cl  Cl24  1  0.237  0.804  0.058  1.0
  Cl  Cl25  1  0.763  0.696  0.558  1.0
  O  O26  1  0.046  0.313  0.745  1.0
  O  O27  1  0.954  0.187  0.245  1.0
  O  O28  1  0.954  0.687  0.255  1.0
  O  O29  1  0.046  0.813  0.755  1.0
  O  O30  1  0.237  0.515  0.884  1.0
  O  O31  1  0.763  0.985  0.384  1.0
  O  O32  1  0.763  0.485  0.116  1.0
  O  O33  1  0.237  0.015  0.616  1.0
  O  O34  1  0.535  0.386  0.755  1.0
  O  O35  1  0.465  0.114  0.255  1.0
  O  O36  1  0.465  0.614  0.245  1.0
  O  O37  1  0.535  0.886  0.745  1.0
  O  O38  1  0.240  0.301  0.068  1.0
  O  O39  1  0.760  0.199  0.568  1.0
  O  O40  1  0.760  0.699  0.932  1.0
  O  O41  1  0.240  0.801  0.432  1.0
[/CIF]
.
The material described by CoH8Se2(O4Cl)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two CoH8Se2(O4Cl)2 clusters. Co(1) is bonded in an octahedral geometry to two equivalent O(2), two equivalent O(4), and two equivalent Cl(1) atoms. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(4) atom. Se(1) is bonded in a distorted T-shaped geometry to one O(1), one O(2), and one O(3) atom. There are four inequivalent O sites. In the first O site, O(3) is bonded in a distorted water-like geometry to one H(2) and one Se(1) atom. In the second O site, O(4) is bonded in a distorted water-like geometry to one Co(1), one H(3), and one H(4) atom. In the third O site, O(1) is bonded in a distorted single-bond geometry to one H(1) and one Se(1) atom. In the fourth O site, O(2) is bonded in a bent 120 degrees geometry to one Co(1) and one Se(1) atom. Cl(1) is bonded in a single-bond geometry to one Co(1) atom. is represented by the CIF file [CIF]
data_CoH8Se2(ClO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.174
_cell_length_b   6.560
_cell_length_c   14.971
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   93.151
_symmetry_Int_Tables_number   1
_cell_volume   507.412
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.000  0.500  0.000  1.0
  Co  Co1  1  0.000  0.000  0.500  1.0
  H  H2  1  0.083  0.214  0.697  1.0
  H  H3  1  0.917  0.286  0.197  1.0
  H  H4  1  0.917  0.786  0.303  1.0
  H  H5  1  0.083  0.714  0.803  1.0
  H  H6  1  0.707  0.334  0.770  1.0
  H  H7  1  0.293  0.166  0.270  1.0
  H  H8  1  0.293  0.666  0.230  1.0
  H  H9  1  0.707  0.834  0.730  1.0
  H  H10  1  0.423  0.340  0.079  1.0
  H  H11  1  0.577  0.160  0.579  1.0
  H  H12  1  0.577  0.660  0.921  1.0
  H  H13  1  0.423  0.840  0.421  1.0
  H  H14  1  0.227  0.152  0.056  1.0
  H  H15  1  0.773  0.348  0.556  1.0
  H  H16  1  0.773  0.848  0.944  1.0
  H  H17  1  0.227  0.652  0.444  1.0
  Se  Se18  1  0.293  0.292  0.831  1.0
  Se  Se19  1  0.707  0.208  0.331  1.0
  Se  Se20  1  0.707  0.708  0.169  1.0
  Se  Se21  1  0.293  0.792  0.669  1.0
  Cl  Cl22  1  0.763  0.196  0.942  1.0
  Cl  Cl23  1  0.237  0.304  0.442  1.0
  Cl  Cl24  1  0.237  0.804  0.058  1.0
  Cl  Cl25  1  0.763  0.696  0.558  1.0
  O  O26  1  0.046  0.313  0.745  1.0
  O  O27  1  0.954  0.187  0.245  1.0
  O  O28  1  0.954  0.687  0.255  1.0
  O  O29  1  0.046  0.813  0.755  1.0
  O  O30  1  0.237  0.515  0.884  1.0
  O  O31  1  0.763  0.985  0.384  1.0
  O  O32  1  0.763  0.485  0.116  1.0
  O  O33  1  0.237  0.015  0.616  1.0
  O  O34  1  0.535  0.386  0.755  1.0
  O  O35  1  0.465  0.114  0.255  1.0
  O  O36  1  0.465  0.614  0.245  1.0
  O  O37  1  0.535  0.886  0.745  1.0
  O  O38  1  0.240  0.301  0.068  1.0
  O  O39  1  0.760  0.199  0.568  1.0
  O  O40  1  0.760  0.699  0.932  1.0
  O  O41  1  0.240  0.801  0.432  1.0
[/CIF]
.