The compound described by Ce3Pd4Sn6 crystallizes in the orthorhombic Pnma space group. There are three inequivalent Ce sites. In the first Ce site, Ce(1) is bonded in a 15-coordinate geometry to two equivalent Pd(1), two equivalent Pd(2), two equivalent Pd(3), one Sn(5), one Sn(6), two equivalent Sn(3), two equivalent Sn(4), and three equivalent Sn(2) atoms. In the second Ce site, Ce(2) is bonded in a 15-coordinate geometry to two equivalent Pd(2), two equivalent Pd(3), two equivalent Pd(4), one Sn(1), one Sn(2), one Sn(6), two equivalent Sn(3), two equivalent Sn(4), and two equivalent Sn(5) atoms. In the third Ce site, Ce(3) is bonded in a 15-coordinate geometry to one Pd(3), two equivalent Pd(1), three equivalent Pd(4), one Sn(3), one Sn(5), two equivalent Sn(4), two equivalent Sn(6), and three equivalent Sn(1) atoms. There are four inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 9-coordinate geometry to two equivalent Ce(1), two equivalent Ce(3), one Sn(2), one Sn(4), one Sn(6), and two equivalent Sn(5) atoms. In the second Pd site, Pd(2) is bonded in a 9-coordinate geometry to two equivalent Ce(1), two equivalent Ce(2), one Sn(3), one Sn(5), and three equivalent Sn(2) atoms. In the third Pd site, Pd(3) is bonded in a 5-coordinate geometry to one Ce(3), two equivalent Ce(1), two equivalent Ce(2), one Sn(3), one Sn(4), one Sn(5), and two equivalent Sn(6) atoms. In the fourth Pd site, Pd(4) is bonded in a 10-coordinate geometry to two equivalent Ce(2), three equivalent Ce(3), one Sn(3), one Sn(4), and three equivalent Sn(1) atoms. There are six inequivalent Sn sites. In the first Sn site, Sn(6) is bonded in a 3-coordinate geometry to one Ce(1), one Ce(2), two equivalent Ce(3), one Pd(1), two equivalent Pd(3), and one Sn(1) atom. In the second Sn site, Sn(1) is bonded in a 8-coordinate geometry to one Ce(2), three equivalent Ce(3), three equivalent Pd(4), and one Sn(6) atom. In the third Sn site, Sn(2) is bonded in a 4-coordinate geometry to one Ce(2), three equivalent Ce(1), one Pd(1), and three equivalent Pd(2) atoms. In the fourth Sn site, Sn(3) is bonded in a distorted trigonal planar geometry to one Ce(3), two equivalent Ce(1), two equivalent Ce(2), one Pd(2), one Pd(3), and one Pd(4) atom. In the fifth Sn site, Sn(4) is bonded in a 9-coordinate geometry to two equivalent Ce(1), two equivalent Ce(2), two equivalent Ce(3), one Pd(1), one Pd(3), and one Pd(4) atom. In the sixth Sn site, Sn(5) is bonded in a 8-coordinate geometry to one Ce(1), one Ce(3), two equivalent Ce(2), one Pd(2), one Pd(3), and two equivalent Pd(1) atoms. is represented by the CIF card [CIF]
data_Ce3(Sn3Pd2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.655
_cell_length_b   16.851
_cell_length_c   15.691
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1230.666
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.750  0.357  0.382  1.0
  Ce  Ce1  1  0.250  0.643  0.618  1.0
  Ce  Ce2  1  0.250  0.143  0.882  1.0
  Ce  Ce3  1  0.750  0.857  0.118  1.0
  Ce  Ce4  1  0.750  0.616  0.248  1.0
  Ce  Ce5  1  0.250  0.384  0.752  1.0
  Ce  Ce6  1  0.250  0.884  0.748  1.0
  Ce  Ce7  1  0.750  0.116  0.252  1.0
  Ce  Ce8  1  0.750  0.649  0.983  1.0
  Ce  Ce9  1  0.250  0.351  0.017  1.0
  Ce  Ce10  1  0.250  0.851  0.483  1.0
  Ce  Ce11  1  0.750  0.149  0.517  1.0
  Sn  Sn12  1  0.750  0.974  0.420  1.0
  Sn  Sn13  1  0.250  0.026  0.580  1.0
  Sn  Sn14  1  0.250  0.526  0.920  1.0
  Sn  Sn15  1  0.750  0.474  0.080  1.0
  Sn  Sn16  1  0.750  0.551  0.459  1.0
  Sn  Sn17  1  0.250  0.449  0.541  1.0
  Sn  Sn18  1  0.250  0.949  0.959  1.0
  Sn  Sn19  1  0.750  0.051  0.041  1.0
  Sn  Sn20  1  0.750  0.555  0.769  1.0
  Sn  Sn21  1  0.250  0.445  0.231  1.0
  Sn  Sn22  1  0.250  0.945  0.269  1.0
  Sn  Sn23  1  0.750  0.055  0.731  1.0
  Sn  Sn24  1  0.750  0.794  0.620  1.0
  Sn  Sn25  1  0.250  0.206  0.380  1.0
  Sn  Sn26  1  0.250  0.706  0.120  1.0
  Sn  Sn27  1  0.750  0.294  0.880  1.0
  Sn  Sn28  1  0.750  0.828  0.894  1.0
  Sn  Sn29  1  0.250  0.172  0.106  1.0
  Sn  Sn30  1  0.250  0.672  0.394  1.0
  Sn  Sn31  1  0.750  0.328  0.606  1.0
  Sn  Sn32  1  0.750  0.811  0.336  1.0
  Sn  Sn33  1  0.250  0.189  0.664  1.0
  Sn  Sn34  1  0.250  0.689  0.836  1.0
  Sn  Sn35  1  0.750  0.311  0.164  1.0
  Pd  Pd36  1  0.750  0.709  0.475  1.0
  Pd  Pd37  1  0.250  0.291  0.525  1.0
  Pd  Pd38  1  0.250  0.791  0.975  1.0
  Pd  Pd39  1  0.750  0.209  0.025  1.0
  Pd  Pd40  1  0.750  0.990  0.880  1.0
  Pd  Pd41  1  0.250  0.010  0.120  1.0
  Pd  Pd42  1  0.250  0.510  0.380  1.0
  Pd  Pd43  1  0.750  0.490  0.620  1.0
  Pd  Pd44  1  0.750  0.717  0.766  1.0
  Pd  Pd45  1  0.250  0.283  0.234  1.0
  Pd  Pd46  1  0.250  0.783  0.266  1.0
  Pd  Pd47  1  0.750  0.217  0.734  1.0
  Pd  Pd48  1  0.750  0.952  0.599  1.0
  Pd  Pd49  1  0.250  0.048  0.401  1.0
  Pd  Pd50  1  0.250  0.548  0.099  1.0
  Pd  Pd51  1  0.750  0.452  0.901  1.0
[/CIF]
.
The compound described by Ce3Pd4Sn6 crystallizes in the orthorhombic Pnma space group. There are three inequivalent Ce sites. In the first Ce site, Ce(1) is bonded in a 15-coordinate geometry to two equivalent Pd(1), two equivalent Pd(2), two equivalent Pd(3), one Sn(5), one Sn(6), two equivalent Sn(3), two equivalent Sn(4), and three equivalent Sn(2) atoms. In the second Ce site, Ce(2) is bonded in a 15-coordinate geometry to two equivalent Pd(2), two equivalent Pd(3), two equivalent Pd(4), one Sn(1), one Sn(2), one Sn(6), two equivalent Sn(3), two equivalent Sn(4), and two equivalent Sn(5) atoms. In the third Ce site, Ce(3) is bonded in a 15-coordinate geometry to one Pd(3), two equivalent Pd(1), three equivalent Pd(4), one Sn(3), one Sn(5), two equivalent Sn(4), two equivalent Sn(6), and three equivalent Sn(1) atoms. There are four inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 9-coordinate geometry to two equivalent Ce(1), two equivalent Ce(3), one Sn(2), one Sn(4), one Sn(6), and two equivalent Sn(5) atoms. In the second Pd site, Pd(2) is bonded in a 9-coordinate geometry to two equivalent Ce(1), two equivalent Ce(2), one Sn(3), one Sn(5), and three equivalent Sn(2) atoms. In the third Pd site, Pd(3) is bonded in a 5-coordinate geometry to one Ce(3), two equivalent Ce(1), two equivalent Ce(2), one Sn(3), one Sn(4), one Sn(5), and two equivalent Sn(6) atoms. In the fourth Pd site, Pd(4) is bonded in a 10-coordinate geometry to two equivalent Ce(2), three equivalent Ce(3), one Sn(3), one Sn(4), and three equivalent Sn(1) atoms. There are six inequivalent Sn sites. In the first Sn site, Sn(6) is bonded in a 3-coordinate geometry to one Ce(1), one Ce(2), two equivalent Ce(3), one Pd(1), two equivalent Pd(3), and one Sn(1) atom. In the second Sn site, Sn(1) is bonded in a 8-coordinate geometry to one Ce(2), three equivalent Ce(3), three equivalent Pd(4), and one Sn(6) atom. In the third Sn site, Sn(2) is bonded in a 4-coordinate geometry to one Ce(2), three equivalent Ce(1), one Pd(1), and three equivalent Pd(2) atoms. In the fourth Sn site, Sn(3) is bonded in a distorted trigonal planar geometry to one Ce(3), two equivalent Ce(1), two equivalent Ce(2), one Pd(2), one Pd(3), and one Pd(4) atom. In the fifth Sn site, Sn(4) is bonded in a 9-coordinate geometry to two equivalent Ce(1), two equivalent Ce(2), two equivalent Ce(3), one Pd(1), one Pd(3), and one Pd(4) atom. In the sixth Sn site, Sn(5) is bonded in a 8-coordinate geometry to one Ce(1), one Ce(3), two equivalent Ce(2), one Pd(2), one Pd(3), and two equivalent Pd(1) atoms. is represented by the CIF card [CIF]
data_Ce3(Sn3Pd2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.655
_cell_length_b   16.851
_cell_length_c   15.691
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1230.666
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.750  0.357  0.382  1.0
  Ce  Ce1  1  0.250  0.643  0.618  1.0
  Ce  Ce2  1  0.250  0.143  0.882  1.0
  Ce  Ce3  1  0.750  0.857  0.118  1.0
  Ce  Ce4  1  0.750  0.616  0.248  1.0
  Ce  Ce5  1  0.250  0.384  0.752  1.0
  Ce  Ce6  1  0.250  0.884  0.748  1.0
  Ce  Ce7  1  0.750  0.116  0.252  1.0
  Ce  Ce8  1  0.750  0.649  0.983  1.0
  Ce  Ce9  1  0.250  0.351  0.017  1.0
  Ce  Ce10  1  0.250  0.851  0.483  1.0
  Ce  Ce11  1  0.750  0.149  0.517  1.0
  Sn  Sn12  1  0.750  0.974  0.420  1.0
  Sn  Sn13  1  0.250  0.026  0.580  1.0
  Sn  Sn14  1  0.250  0.526  0.920  1.0
  Sn  Sn15  1  0.750  0.474  0.080  1.0
  Sn  Sn16  1  0.750  0.551  0.459  1.0
  Sn  Sn17  1  0.250  0.449  0.541  1.0
  Sn  Sn18  1  0.250  0.949  0.959  1.0
  Sn  Sn19  1  0.750  0.051  0.041  1.0
  Sn  Sn20  1  0.750  0.555  0.769  1.0
  Sn  Sn21  1  0.250  0.445  0.231  1.0
  Sn  Sn22  1  0.250  0.945  0.269  1.0
  Sn  Sn23  1  0.750  0.055  0.731  1.0
  Sn  Sn24  1  0.750  0.794  0.620  1.0
  Sn  Sn25  1  0.250  0.206  0.380  1.0
  Sn  Sn26  1  0.250  0.706  0.120  1.0
  Sn  Sn27  1  0.750  0.294  0.880  1.0
  Sn  Sn28  1  0.750  0.828  0.894  1.0
  Sn  Sn29  1  0.250  0.172  0.106  1.0
  Sn  Sn30  1  0.250  0.672  0.394  1.0
  Sn  Sn31  1  0.750  0.328  0.606  1.0
  Sn  Sn32  1  0.750  0.811  0.336  1.0
  Sn  Sn33  1  0.250  0.189  0.664  1.0
  Sn  Sn34  1  0.250  0.689  0.836  1.0
  Sn  Sn35  1  0.750  0.311  0.164  1.0
  Pd  Pd36  1  0.750  0.709  0.475  1.0
  Pd  Pd37  1  0.250  0.291  0.525  1.0
  Pd  Pd38  1  0.250  0.791  0.975  1.0
  Pd  Pd39  1  0.750  0.209  0.025  1.0
  Pd  Pd40  1  0.750  0.990  0.880  1.0
  Pd  Pd41  1  0.250  0.010  0.120  1.0
  Pd  Pd42  1  0.250  0.510  0.380  1.0
  Pd  Pd43  1  0.750  0.490  0.620  1.0
  Pd  Pd44  1  0.750  0.717  0.766  1.0
  Pd  Pd45  1  0.250  0.283  0.234  1.0
  Pd  Pd46  1  0.250  0.783  0.266  1.0
  Pd  Pd47  1  0.750  0.217  0.734  1.0
  Pd  Pd48  1  0.750  0.952  0.599  1.0
  Pd  Pd49  1  0.250  0.048  0.401  1.0
  Pd  Pd50  1  0.250  0.548  0.099  1.0
  Pd  Pd51  1  0.750  0.452  0.901  1.0
[/CIF]
.