The structure described by SBSCs crystallizes in the orthorhombic Immm space group. Cs(1) is bonded in a 9-coordinate geometry to four equivalent S(2) and five equivalent S(1) atoms. B(1) is bonded in a distorted trigonal planar geometry to one S(1) and two equivalent S(2) atoms. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted single-bond geometry to five equivalent Cs(1) and one B(1) atom. In the second S site, S(2) is bonded in a distorted L-shaped geometry to four equivalent Cs(1) and two equivalent B(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_CsBS2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.559
_cell_length_b   6.188
_cell_length_c   9.715
_cell_angle_alpha   71.423
_cell_angle_beta   76.433
_cell_angle_gamma   90.005
_symmetry_Int_Tables_number   1
_cell_volume   251.711
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.141  0.141  0.718  1.0
  Cs  Cs1  1  0.859  0.859  0.282  1.0
  B  B2  1  0.567  0.567  0.865  1.0
  B  B3  1  0.433  0.433  0.135  1.0
  S  S4  1  0.664  0.665  0.671  1.0
  S  S5  1  0.336  0.335  0.329  1.0
  S  S6  1  0.500  0.270  0.000  1.0
  S  S7  1  0.500  0.730  1.000  1.0
[/CIF]
.
The structure described by SBSCs crystallizes in the orthorhombic Immm space group. Cs(1) is bonded in a 9-coordinate geometry to four equivalent S(2) and five equivalent S(1) atoms. B(1) is bonded in a distorted trigonal planar geometry to one S(1) and two equivalent S(2) atoms. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted single-bond geometry to five equivalent Cs(1) and one B(1) atom. In the second S site, S(2) is bonded in a distorted L-shaped geometry to four equivalent Cs(1) and two equivalent B(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_CsBS2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.559
_cell_length_b   6.188
_cell_length_c   9.715
_cell_angle_alpha   71.423
_cell_angle_beta   76.433
_cell_angle_gamma   90.005
_symmetry_Int_Tables_number   1
_cell_volume   251.711
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.141  0.141  0.718  1.0
  Cs  Cs1  1  0.859  0.859  0.282  1.0
  B  B2  1  0.567  0.567  0.865  1.0
  B  B3  1  0.433  0.433  0.135  1.0
  S  S4  1  0.664  0.665  0.671  1.0
  S  S5  1  0.336  0.335  0.329  1.0
  S  S6  1  0.500  0.270  0.000  1.0
  S  S7  1  0.500  0.730  1.000  1.0
[/CIF]
.