The material structure described by Mn(SO6)2(CN)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two hydrogen cyanide molecules and one Mn(SO6)2 cluster. In the Mn(SO6)2 cluster, Mn(1) is bonded to two equivalent O(4), two equivalent O(5), and two equivalent O(6) atoms to form MnO6 octahedra that share corners with two equivalent S(1)O4 tetrahedra. S(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form SO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles are 55°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Mn(1) and one S(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one Mn(1) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one Mn(1) atom. is represented by the CIF file [CIF]
data_MnC2S2(NO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.907
_cell_length_b   7.138
_cell_length_c   7.459
_cell_angle_alpha   76.393
_cell_angle_beta   84.912
_cell_angle_gamma   78.229
_symmetry_Int_Tables_number   1
_cell_volume   349.564
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.000  0.000  0.000  1.0
  C  C1  1  0.508  0.564  0.417  1.0
  C  C2  1  0.492  0.436  0.583  1.0
  S  S3  1  0.212  0.193  0.240  1.0
  S  S4  1  0.788  0.807  0.760  1.0
  N  N5  1  0.479  0.325  0.725  1.0
  N  N6  1  0.521  0.675  0.275  1.0
  O  O7  1  0.388  0.279  0.222  1.0
  O  O8  1  0.612  0.721  0.778  1.0
  O  O9  1  0.233  0.994  0.371  1.0
  O  O10  1  0.767  0.006  0.629  1.0
  O  O11  1  0.037  0.306  0.323  1.0
  O  O12  1  0.963  0.694  0.677  1.0
  O  O13  1  0.172  0.171  0.049  1.0
  O  O14  1  0.828  0.829  0.951  1.0
  O  O15  1  0.814  0.071  0.165  1.0
  O  O16  1  0.186  0.929  0.835  1.0
  O  O17  1  0.924  0.187  0.793  1.0
  O  O18  1  0.076  0.813  0.207  1.0
[/CIF]
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The material structure described by Mn(SO6)2(CN)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two hydrogen cyanide molecules and one Mn(SO6)2 cluster. In the Mn(SO6)2 cluster, Mn(1) is bonded to two equivalent O(4), two equivalent O(5), and two equivalent O(6) atoms to form MnO6 octahedra that share corners with two equivalent S(1)O4 tetrahedra. S(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form SO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles are 55°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Mn(1) and one S(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one Mn(1) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one Mn(1) atom. is represented by the CIF file [CIF]
data_MnC2S2(NO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.907
_cell_length_b   7.138
_cell_length_c   7.459
_cell_angle_alpha   76.393
_cell_angle_beta   84.912
_cell_angle_gamma   78.229
_symmetry_Int_Tables_number   1
_cell_volume   349.564
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.000  0.000  0.000  1.0
  C  C1  1  0.508  0.564  0.417  1.0
  C  C2  1  0.492  0.436  0.583  1.0
  S  S3  1  0.212  0.193  0.240  1.0
  S  S4  1  0.788  0.807  0.760  1.0
  N  N5  1  0.479  0.325  0.725  1.0
  N  N6  1  0.521  0.675  0.275  1.0
  O  O7  1  0.388  0.279  0.222  1.0
  O  O8  1  0.612  0.721  0.778  1.0
  O  O9  1  0.233  0.994  0.371  1.0
  O  O10  1  0.767  0.006  0.629  1.0
  O  O11  1  0.037  0.306  0.323  1.0
  O  O12  1  0.963  0.694  0.677  1.0
  O  O13  1  0.172  0.171  0.049  1.0
  O  O14  1  0.828  0.829  0.951  1.0
  O  O15  1  0.814  0.071  0.165  1.0
  O  O16  1  0.186  0.929  0.835  1.0
  O  O17  1  0.924  0.187  0.793  1.0
  O  O18  1  0.076  0.813  0.207  1.0
[/CIF]
.