The crystal structure described by PrOs2CP crystallizes in the orthorhombic Cmcm space group. Pr(1) is bonded in a 4-coordinate geometry to four equivalent C(1) and three equivalent P(1) atoms. Os(1) is bonded in a distorted single-bond geometry to one C(1) and three equivalent P(1) atoms. C(1) is bonded to four equivalent Pr(1) and two equivalent Os(1) atoms to form a mixture of corner and edge-sharing CPr4Os2 octahedra. The corner-sharing octahedral tilt angles are 22°. P(1) is bonded in a 9-coordinate geometry to three equivalent Pr(1) and six equivalent Os(1) atoms. is represented by the CIF file [CIF]
data_PrPOs2C
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.874
_cell_length_b   5.874
_cell_length_c   7.147
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   140.539
_symmetry_Int_Tables_number   1
_cell_volume   156.751
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pr  Pr0  1  0.546  0.454  0.250  1.0
  Pr  Pr1  1  0.454  0.546  0.750  1.0
  P  P2  1  0.270  0.730  0.250  1.0
  P  P3  1  0.730  0.270  0.750  1.0
  Os  Os4  1  0.832  0.168  0.054  1.0
  Os  Os5  1  0.168  0.832  0.946  1.0
  Os  Os6  1  0.168  0.832  0.554  1.0
  Os  Os7  1  0.832  0.168  0.446  1.0
  C  C8  1  0.000  0.000  0.000  1.0
  C  C9  1  0.000  0.000  0.500  1.0
[/CIF]
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The crystal structure described by PrOs2CP crystallizes in the orthorhombic Cmcm space group. Pr(1) is bonded in a 4-coordinate geometry to four equivalent C(1) and three equivalent P(1) atoms. Os(1) is bonded in a distorted single-bond geometry to one C(1) and three equivalent P(1) atoms. C(1) is bonded to four equivalent Pr(1) and two equivalent Os(1) atoms to form a mixture of corner and edge-sharing CPr4Os2 octahedra. The corner-sharing octahedral tilt angles are 22°. P(1) is bonded in a 9-coordinate geometry to three equivalent Pr(1) and six equivalent Os(1) atoms. is represented by the CIF file [CIF]
data_PrPOs2C
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.874
_cell_length_b   5.874
_cell_length_c   7.147
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   140.539
_symmetry_Int_Tables_number   1
_cell_volume   156.751
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pr  Pr0  1  0.546  0.454  0.250  1.0
  Pr  Pr1  1  0.454  0.546  0.750  1.0
  P  P2  1  0.270  0.730  0.250  1.0
  P  P3  1  0.730  0.270  0.750  1.0
  Os  Os4  1  0.832  0.168  0.054  1.0
  Os  Os5  1  0.168  0.832  0.946  1.0
  Os  Os6  1  0.168  0.832  0.554  1.0
  Os  Os7  1  0.832  0.168  0.446  1.0
  C  C8  1  0.000  0.000  0.000  1.0
  C  C9  1  0.000  0.000  0.500  1.0
[/CIF]
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