The material structure described by Mn(C2O)2(CO2)2 is Indium-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of four carbon dioxide molecules and two Mn(C2O)2 clusters. In each Mn(C2O)2 cluster, Mn(1) is bonded in a distorted rectangular see-saw-like geometry to four equivalent C(2) atoms. C(2) is bonded in an L-shaped geometry to one Mn(1) and one O(2) atom. O(2) is bonded in a bent 120 degrees geometry to two equivalent C(2) atoms. is represented by the CIF card [CIF]
data_Mn(CO)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.419
_cell_length_b   6.979
_cell_length_c   13.226
_cell_angle_alpha   75.955
_cell_angle_beta   68.921
_cell_angle_gamma   47.564
_symmetry_Int_Tables_number   1
_cell_volume   598.691
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.000  0.000  0.000  1.0
  C  C1  1  0.687  0.000  0.504  1.0
  C  C2  1  0.313  0.000  0.496  1.0
  C  C3  1  0.684  0.231  0.003  1.0
  C  C4  1  0.316  0.769  0.997  1.0
  C  C5  1  0.915  0.769  0.003  1.0
  C  C6  1  0.085  0.231  0.997  1.0
  O  O7  1  0.572  0.229  0.504  1.0
  O  O8  1  0.428  0.771  0.496  1.0
  O  O9  1  0.734  0.000  0.998  1.0
  O  O10  1  0.199  0.229  0.496  1.0
  O  O11  1  0.266  0.000  0.002  1.0
  O  O12  1  0.801  0.771  0.504  1.0
[/CIF]
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The material structure described by Mn(C2O)2(CO2)2 is Indium-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of four carbon dioxide molecules and two Mn(C2O)2 clusters. In each Mn(C2O)2 cluster, Mn(1) is bonded in a distorted rectangular see-saw-like geometry to four equivalent C(2) atoms. C(2) is bonded in an L-shaped geometry to one Mn(1) and one O(2) atom. O(2) is bonded in a bent 120 degrees geometry to two equivalent C(2) atoms. is represented by the CIF card [CIF]
data_Mn(CO)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.419
_cell_length_b   6.979
_cell_length_c   13.226
_cell_angle_alpha   75.955
_cell_angle_beta   68.921
_cell_angle_gamma   47.564
_symmetry_Int_Tables_number   1
_cell_volume   598.691
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.000  0.000  0.000  1.0
  C  C1  1  0.687  0.000  0.504  1.0
  C  C2  1  0.313  0.000  0.496  1.0
  C  C3  1  0.684  0.231  0.003  1.0
  C  C4  1  0.316  0.769  0.997  1.0
  C  C5  1  0.915  0.769  0.003  1.0
  C  C6  1  0.085  0.231  0.997  1.0
  O  O7  1  0.572  0.229  0.504  1.0
  O  O8  1  0.428  0.771  0.496  1.0
  O  O9  1  0.734  0.000  0.998  1.0
  O  O10  1  0.199  0.229  0.496  1.0
  O  O11  1  0.266  0.000  0.002  1.0
  O  O12  1  0.801  0.771  0.504  1.0
[/CIF]
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