The compound described by MgTi4Cd2O10 crystallizes in the orthorhombic Amm2 space group. Mg(1) is bonded in a distorted bent 120 degrees geometry to two equivalent Cd(2) and two equivalent O(4) atoms. There are two inequivalent Ti sites. In the first Ti site, Ti(1) is bonded in a 5-coordinate geometry to one O(1), one O(4), one O(6), and two equivalent O(5) atoms. In the second Ti site, Ti(2) is bonded to one O(1), one O(3), one O(6), and two equivalent O(2) atoms to form corner-sharing TiO5 trigonal bipyramids. There are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. In the second Cd site, Cd(2) is bonded in a 8-coordinate geometry to two equivalent Mg(1), two equivalent O(4), two equivalent O(5), and two equivalent O(6) atoms. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Ti(1), one Ti(2), and one Cd(1) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to two equivalent Ti(2) and one Cd(1) atom. In the third O site, O(3) is bonded to two equivalent Ti(2) and two equivalent Cd(1) atoms to form distorted corner-sharing OTi2Cd2 tetrahedra. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to two equivalent Mg(1), two equivalent Ti(1), and two equivalent Cd(2) atoms. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to two equivalent Ti(1) and one Cd(2) atom. In the sixth O site, O(6) is bonded in a distorted water-like geometry to one Ti(1), one Ti(2), and one Cd(2) atom. is represented by the CIF file [CIF]
data_MgTi4Cd2O10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.877
_cell_length_b   5.877
_cell_length_c   11.492
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   34.297
_symmetry_Int_Tables_number   1
_cell_volume   223.630
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.504  0.504  0.750  1.0
  Ti  Ti1  1  0.115  0.115  0.552  1.0
  Ti  Ti2  1  0.115  0.115  0.948  1.0
  Ti  Ti3  1  0.898  0.898  0.084  1.0
  Ti  Ti4  1  0.898  0.898  0.416  1.0
  Cd  Cd5  1  0.204  0.204  0.250  1.0
  Cd  Cd6  1  0.796  0.796  0.750  1.0
  O  O7  1  0.061  0.061  0.113  1.0
  O  O8  1  0.061  0.061  0.387  1.0
  O  O9  1  0.330  0.330  0.068  1.0
  O  O10  1  0.330  0.330  0.432  1.0
  O  O11  1  0.836  0.836  0.250  1.0
  O  O12  1  0.105  0.105  0.750  1.0
  O  O13  1  0.675  0.675  0.564  1.0
  O  O14  1  0.955  0.955  0.577  1.0
  O  O15  1  0.675  0.675  0.936  1.0
  O  O16  1  0.955  0.955  0.923  1.0
[/CIF]
.
The compound described by MgTi4Cd2O10 crystallizes in the orthorhombic Amm2 space group. Mg(1) is bonded in a distorted bent 120 degrees geometry to two equivalent Cd(2) and two equivalent O(4) atoms. There are two inequivalent Ti sites. In the first Ti site, Ti(1) is bonded in a 5-coordinate geometry to one O(1), one O(4), one O(6), and two equivalent O(5) atoms. In the second Ti site, Ti(2) is bonded to one O(1), one O(3), one O(6), and two equivalent O(2) atoms to form corner-sharing TiO5 trigonal bipyramids. There are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. In the second Cd site, Cd(2) is bonded in a 8-coordinate geometry to two equivalent Mg(1), two equivalent O(4), two equivalent O(5), and two equivalent O(6) atoms. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Ti(1), one Ti(2), and one Cd(1) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to two equivalent Ti(2) and one Cd(1) atom. In the third O site, O(3) is bonded to two equivalent Ti(2) and two equivalent Cd(1) atoms to form distorted corner-sharing OTi2Cd2 tetrahedra. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to two equivalent Mg(1), two equivalent Ti(1), and two equivalent Cd(2) atoms. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to two equivalent Ti(1) and one Cd(2) atom. In the sixth O site, O(6) is bonded in a distorted water-like geometry to one Ti(1), one Ti(2), and one Cd(2) atom. is represented by the CIF file [CIF]
data_MgTi4Cd2O10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.877
_cell_length_b   5.877
_cell_length_c   11.492
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   34.297
_symmetry_Int_Tables_number   1
_cell_volume   223.630
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.504  0.504  0.750  1.0
  Ti  Ti1  1  0.115  0.115  0.552  1.0
  Ti  Ti2  1  0.115  0.115  0.948  1.0
  Ti  Ti3  1  0.898  0.898  0.084  1.0
  Ti  Ti4  1  0.898  0.898  0.416  1.0
  Cd  Cd5  1  0.204  0.204  0.250  1.0
  Cd  Cd6  1  0.796  0.796  0.750  1.0
  O  O7  1  0.061  0.061  0.113  1.0
  O  O8  1  0.061  0.061  0.387  1.0
  O  O9  1  0.330  0.330  0.068  1.0
  O  O10  1  0.330  0.330  0.432  1.0
  O  O11  1  0.836  0.836  0.250  1.0
  O  O12  1  0.105  0.105  0.750  1.0
  O  O13  1  0.675  0.675  0.564  1.0
  O  O14  1  0.955  0.955  0.577  1.0
  O  O15  1  0.675  0.675  0.936  1.0
  O  O16  1  0.955  0.955  0.923  1.0
[/CIF]
.