The structure described by RbAuN12 crystallizes in the monoclinic C2/c space group. Rb(1) is bonded in a distorted q6 geometry to two equivalent N(6), four equivalent N(1), and four equivalent N(5) atoms. Au(1) is bonded in a rectangular see-saw-like geometry to two equivalent N(4) and two equivalent N(6) atoms. There are six inequivalent N sites. In the first N site, N(1) is bonded in a 3-coordinate geometry to two equivalent Rb(1) and one N(3) atom. In the second N site, N(2) is bonded in a linear geometry to one N(5) and one N(6) atom. In the third N site, N(3) is bonded in a linear geometry to one N(1) and one N(4) atom. In the fourth N site, N(4) is bonded in a bent 120 degrees geometry to one Au(1) and one N(3) atom. In the fifth N site, N(5) is bonded in a 3-coordinate geometry to two equivalent Rb(1) and one N(2) atom. In the sixth N site, N(6) is bonded in a distorted trigonal planar geometry to one Rb(1), one Au(1), and one N(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_RbAuN12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.649
_cell_length_b   7.649
_cell_length_c   8.386
_cell_angle_alpha   89.180
_cell_angle_beta   89.180
_cell_angle_gamma   90.928
_symmetry_Int_Tables_number   1
_cell_volume   490.515
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.085  0.915  0.250  1.0
  Rb  Rb1  1  0.915  0.085  0.750  1.0
  Au  Au2  1  0.507  0.493  0.750  1.0
  Au  Au3  1  0.493  0.507  0.250  1.0
  N  N4  1  0.913  0.276  0.086  1.0
  N  N5  1  0.404  0.166  0.892  1.0
  N  N6  1  0.166  0.404  0.392  1.0
  N  N7  1  0.390  0.827  0.633  1.0
  N  N8  1  0.753  0.519  0.180  1.0
  N  N9  1  0.247  0.481  0.820  1.0
  N  N10  1  0.827  0.390  0.133  1.0
  N  N11  1  0.711  0.906  0.041  1.0
  N  N12  1  0.173  0.610  0.867  1.0
  N  N13  1  0.289  0.094  0.959  1.0
  N  N14  1  0.519  0.753  0.680  1.0
  N  N15  1  0.232  0.529  0.322  1.0
  N  N16  1  0.834  0.596  0.608  1.0
  N  N17  1  0.094  0.289  0.459  1.0
  N  N18  1  0.906  0.711  0.541  1.0
  N  N19  1  0.596  0.834  0.108  1.0
  N  N20  1  0.087  0.724  0.914  1.0
  N  N21  1  0.768  0.471  0.678  1.0
  N  N22  1  0.276  0.913  0.586  1.0
  N  N23  1  0.471  0.768  0.178  1.0
  N  N24  1  0.529  0.232  0.822  1.0
  N  N25  1  0.481  0.247  0.320  1.0
  N  N26  1  0.610  0.173  0.367  1.0
  N  N27  1  0.724  0.087  0.414  1.0
[/CIF]
.
The structure described by RbAuN12 crystallizes in the monoclinic C2/c space group. Rb(1) is bonded in a distorted q6 geometry to two equivalent N(6), four equivalent N(1), and four equivalent N(5) atoms. Au(1) is bonded in a rectangular see-saw-like geometry to two equivalent N(4) and two equivalent N(6) atoms. There are six inequivalent N sites. In the first N site, N(1) is bonded in a 3-coordinate geometry to two equivalent Rb(1) and one N(3) atom. In the second N site, N(2) is bonded in a linear geometry to one N(5) and one N(6) atom. In the third N site, N(3) is bonded in a linear geometry to one N(1) and one N(4) atom. In the fourth N site, N(4) is bonded in a bent 120 degrees geometry to one Au(1) and one N(3) atom. In the fifth N site, N(5) is bonded in a 3-coordinate geometry to two equivalent Rb(1) and one N(2) atom. In the sixth N site, N(6) is bonded in a distorted trigonal planar geometry to one Rb(1), one Au(1), and one N(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_RbAuN12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.649
_cell_length_b   7.649
_cell_length_c   8.386
_cell_angle_alpha   89.180
_cell_angle_beta   89.180
_cell_angle_gamma   90.928
_symmetry_Int_Tables_number   1
_cell_volume   490.515
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.085  0.915  0.250  1.0
  Rb  Rb1  1  0.915  0.085  0.750  1.0
  Au  Au2  1  0.507  0.493  0.750  1.0
  Au  Au3  1  0.493  0.507  0.250  1.0
  N  N4  1  0.913  0.276  0.086  1.0
  N  N5  1  0.404  0.166  0.892  1.0
  N  N6  1  0.166  0.404  0.392  1.0
  N  N7  1  0.390  0.827  0.633  1.0
  N  N8  1  0.753  0.519  0.180  1.0
  N  N9  1  0.247  0.481  0.820  1.0
  N  N10  1  0.827  0.390  0.133  1.0
  N  N11  1  0.711  0.906  0.041  1.0
  N  N12  1  0.173  0.610  0.867  1.0
  N  N13  1  0.289  0.094  0.959  1.0
  N  N14  1  0.519  0.753  0.680  1.0
  N  N15  1  0.232  0.529  0.322  1.0
  N  N16  1  0.834  0.596  0.608  1.0
  N  N17  1  0.094  0.289  0.459  1.0
  N  N18  1  0.906  0.711  0.541  1.0
  N  N19  1  0.596  0.834  0.108  1.0
  N  N20  1  0.087  0.724  0.914  1.0
  N  N21  1  0.768  0.471  0.678  1.0
  N  N22  1  0.276  0.913  0.586  1.0
  N  N23  1  0.471  0.768  0.178  1.0
  N  N24  1  0.529  0.232  0.822  1.0
  N  N25  1  0.481  0.247  0.320  1.0
  N  N26  1  0.610  0.173  0.367  1.0
  N  N27  1  0.724  0.087  0.414  1.0
[/CIF]
.