The compound described by (B5O6(OH)4)2N2(H2O)4 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four ammonia atoms, eight water molecules, and four B5O6(OH)4 clusters. In each B5O6(OH)4 cluster, there are three inequivalent B sites. In the first B site, B(1) is bonded in a tetrahedral geometry to two equivalent O(4) and two equivalent O(5) atoms. In the second B site, B(2) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(4) atom. In the third B site, B(3) is bonded in a trigonal planar geometry to one O(2), one O(3), and one O(5) atom. There are two inequivalent H sites. In the first H site, H(4) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(3) is bonded in a distorted single-bond geometry to one O(3) atom. There are five inequivalent O sites. In the first O site, O(3) is bonded in a distorted water-like geometry to one B(3) and one H(3) atom. In the second O site, O(4) is bonded in a bent 120 degrees geometry to one B(1) and one B(2) atom. In the third O site, O(5) is bonded in a bent 120 degrees geometry to one B(1) and one B(3) atom. In the fourth O site, O(2) is bonded in a bent 120 degrees geometry to one B(2) and one B(3) atom. In the fifth O site, O(1) is bonded in a bent 120 degrees geometry to one B(2) and one H(4) atom. is represented by the CIF file [CIF]
data_B5H8NO12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.315
_cell_length_b   7.315
_cell_length_c   11.533
_cell_angle_alpha   88.316
_cell_angle_beta   88.316
_cell_angle_gamma   72.886
_symmetry_Int_Tables_number   1
_cell_volume   589.470
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.778  0.222  0.750  1.0
  B  B1  1  0.222  0.778  0.250  1.0
  B  B2  1  0.628  0.268  0.554  1.0
  B  B3  1  0.732  0.372  0.946  1.0
  B  B4  1  0.372  0.732  0.446  1.0
  B  B5  1  0.268  0.628  0.054  1.0
  B  B6  1  0.962  0.243  0.566  1.0
  B  B7  1  0.757  0.038  0.934  1.0
  B  B8  1  0.038  0.757  0.434  1.0
  B  B9  1  0.243  0.962  0.066  1.0
  H  H10  1  0.198  0.132  0.743  1.0
  H  H11  1  0.868  0.802  0.757  1.0
  H  H12  1  0.802  0.868  0.257  1.0
  H  H13  1  0.132  0.198  0.243  1.0
  H  H14  1  0.418  0.122  0.741  1.0
  H  H15  1  0.878  0.582  0.759  1.0
  H  H16  1  0.582  0.878  0.259  1.0
  H  H17  1  0.122  0.418  0.241  1.0
  H  H18  1  0.110  0.281  0.425  1.0
  H  H19  1  0.719  0.890  0.075  1.0
  H  H20  1  0.890  0.719  0.575  1.0
  H  H21  1  0.281  0.110  0.925  1.0
  H  H22  1  0.360  0.267  0.515  1.0
  H  H23  1  0.733  0.640  0.985  1.0
  H  H24  1  0.640  0.733  0.485  1.0
  H  H25  1  0.267  0.360  0.015  1.0
  N  N26  1  0.321  0.679  0.750  1.0
  N  N27  1  0.679  0.321  0.250  1.0
  O  O28  1  0.482  0.279  0.482  1.0
  O  O29  1  0.721  0.518  0.018  1.0
  O  O30  1  0.518  0.721  0.518  1.0
  O  O31  1  0.279  0.482  0.982  1.0
  O  O32  1  0.801  0.269  0.501  1.0
  O  O33  1  0.731  0.199  0.999  1.0
  O  O34  1  0.199  0.731  0.499  1.0
  O  O35  1  0.269  0.801  0.001  1.0
  O  O36  1  0.128  0.252  0.511  1.0
  O  O37  1  0.748  0.872  0.989  1.0
  O  O38  1  0.872  0.748  0.489  1.0
  O  O39  1  0.252  0.128  0.011  1.0
  O  O40  1  0.613  0.251  0.674  1.0
  O  O41  1  0.749  0.387  0.826  1.0
  O  O42  1  0.387  0.749  0.326  1.0
  O  O43  1  0.251  0.613  0.174  1.0
  O  O44  1  0.959  0.207  0.684  1.0
  O  O45  1  0.793  0.041  0.816  1.0
  O  O46  1  0.041  0.793  0.316  1.0
  O  O47  1  0.207  0.959  0.184  1.0
  O  O48  1  0.320  0.077  0.783  1.0
  O  O49  1  0.923  0.680  0.717  1.0
  O  O50  1  0.680  0.923  0.217  1.0
  O  O51  1  0.077  0.320  0.283  1.0
[/CIF]
.
The compound described by (B5O6(OH)4)2N2(H2O)4 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four ammonia atoms, eight water molecules, and four B5O6(OH)4 clusters. In each B5O6(OH)4 cluster, there are three inequivalent B sites. In the first B site, B(1) is bonded in a tetrahedral geometry to two equivalent O(4) and two equivalent O(5) atoms. In the second B site, B(2) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(4) atom. In the third B site, B(3) is bonded in a trigonal planar geometry to one O(2), one O(3), and one O(5) atom. There are two inequivalent H sites. In the first H site, H(4) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(3) is bonded in a distorted single-bond geometry to one O(3) atom. There are five inequivalent O sites. In the first O site, O(3) is bonded in a distorted water-like geometry to one B(3) and one H(3) atom. In the second O site, O(4) is bonded in a bent 120 degrees geometry to one B(1) and one B(2) atom. In the third O site, O(5) is bonded in a bent 120 degrees geometry to one B(1) and one B(3) atom. In the fourth O site, O(2) is bonded in a bent 120 degrees geometry to one B(2) and one B(3) atom. In the fifth O site, O(1) is bonded in a bent 120 degrees geometry to one B(2) and one H(4) atom. is represented by the CIF file [CIF]
data_B5H8NO12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.315
_cell_length_b   7.315
_cell_length_c   11.533
_cell_angle_alpha   88.316
_cell_angle_beta   88.316
_cell_angle_gamma   72.886
_symmetry_Int_Tables_number   1
_cell_volume   589.470
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.778  0.222  0.750  1.0
  B  B1  1  0.222  0.778  0.250  1.0
  B  B2  1  0.628  0.268  0.554  1.0
  B  B3  1  0.732  0.372  0.946  1.0
  B  B4  1  0.372  0.732  0.446  1.0
  B  B5  1  0.268  0.628  0.054  1.0
  B  B6  1  0.962  0.243  0.566  1.0
  B  B7  1  0.757  0.038  0.934  1.0
  B  B8  1  0.038  0.757  0.434  1.0
  B  B9  1  0.243  0.962  0.066  1.0
  H  H10  1  0.198  0.132  0.743  1.0
  H  H11  1  0.868  0.802  0.757  1.0
  H  H12  1  0.802  0.868  0.257  1.0
  H  H13  1  0.132  0.198  0.243  1.0
  H  H14  1  0.418  0.122  0.741  1.0
  H  H15  1  0.878  0.582  0.759  1.0
  H  H16  1  0.582  0.878  0.259  1.0
  H  H17  1  0.122  0.418  0.241  1.0
  H  H18  1  0.110  0.281  0.425  1.0
  H  H19  1  0.719  0.890  0.075  1.0
  H  H20  1  0.890  0.719  0.575  1.0
  H  H21  1  0.281  0.110  0.925  1.0
  H  H22  1  0.360  0.267  0.515  1.0
  H  H23  1  0.733  0.640  0.985  1.0
  H  H24  1  0.640  0.733  0.485  1.0
  H  H25  1  0.267  0.360  0.015  1.0
  N  N26  1  0.321  0.679  0.750  1.0
  N  N27  1  0.679  0.321  0.250  1.0
  O  O28  1  0.482  0.279  0.482  1.0
  O  O29  1  0.721  0.518  0.018  1.0
  O  O30  1  0.518  0.721  0.518  1.0
  O  O31  1  0.279  0.482  0.982  1.0
  O  O32  1  0.801  0.269  0.501  1.0
  O  O33  1  0.731  0.199  0.999  1.0
  O  O34  1  0.199  0.731  0.499  1.0
  O  O35  1  0.269  0.801  0.001  1.0
  O  O36  1  0.128  0.252  0.511  1.0
  O  O37  1  0.748  0.872  0.989  1.0
  O  O38  1  0.872  0.748  0.489  1.0
  O  O39  1  0.252  0.128  0.011  1.0
  O  O40  1  0.613  0.251  0.674  1.0
  O  O41  1  0.749  0.387  0.826  1.0
  O  O42  1  0.387  0.749  0.326  1.0
  O  O43  1  0.251  0.613  0.174  1.0
  O  O44  1  0.959  0.207  0.684  1.0
  O  O45  1  0.793  0.041  0.816  1.0
  O  O46  1  0.041  0.793  0.316  1.0
  O  O47  1  0.207  0.959  0.184  1.0
  O  O48  1  0.320  0.077  0.783  1.0
  O  O49  1  0.923  0.680  0.717  1.0
  O  O50  1  0.680  0.923  0.217  1.0
  O  O51  1  0.077  0.320  0.283  1.0
[/CIF]
.