The material structure described by Re2C9S3O8 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one Re2C9S3O8 cluster. There are two inequivalent Re sites. In the first Re site, Re(1) is bonded to one C(3), one C(4), one C(5), one C(8), and two equivalent S(2) atoms to form edge-sharing ReC4S2 octahedra. In the second Re site, Re(2) is bonded in a distorted octahedral geometry to one C(1), one C(2), one C(6), one C(9), one S(1), and one S(3) atom. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Re(2) and one O(6) atom. In the second C site, C(2) is bonded in a linear geometry to one Re(2) and one O(1) atom. In the third C site, C(3) is bonded in a linear geometry to one Re(1) and one O(3) atom. In the fourth C site, C(4) is bonded in a linear geometry to one Re(1) and one O(7) atom. In the fifth C site, C(5) is bonded in a linear geometry to one Re(1) and one O(2) atom. In the sixth C site, C(6) is bonded in a linear geometry to one Re(2) and one O(5) atom. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one S(1), one S(2), and one S(3) atom. In the eighth C site, C(8) is bonded in a linear geometry to one Re(1) and one O(8) atom. In the ninth C site, C(9) is bonded in a linear geometry to one Re(2) and one O(4) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in an L-shaped geometry to one Re(2) and one C(7) atom. In the second S site, S(2) is bonded in a trigonal non-coplanar geometry to two equivalent Re(1) and one C(7) atom. In the third S site, S(3) is bonded in an L-shaped geometry to one Re(2) and one C(7) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(5) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(9) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one C(1) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one C(4) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one C(8) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Re2C9S3O8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.240
_cell_length_b   8.687
_cell_length_c   14.136
_cell_angle_alpha   83.678
_cell_angle_beta   79.465
_cell_angle_gamma   75.300
_symmetry_Int_Tables_number   1
_cell_volume   843.524
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.816  0.184  0.948  1.0
  Re  Re1  1  0.107  0.675  0.643  1.0
  Re  Re2  1  0.893  0.325  0.357  1.0
  Re  Re3  1  0.184  0.816  0.052  1.0
  C  C4  1  0.718  0.522  0.405  1.0
  C  C5  1  0.880  0.577  0.668  1.0
  C  C6  1  0.615  0.223  0.868  1.0
  C  C7  1  0.632  0.154  0.069  1.0
  C  C8  1  0.014  0.206  0.831  1.0
  C  C9  1  0.317  0.796  0.622  1.0
  C  C10  1  0.986  0.794  0.169  1.0
  C  C11  1  0.120  0.423  0.332  1.0
  C  C12  1  0.385  0.777  0.132  1.0
  C  C13  1  0.013  0.191  0.164  1.0
  C  C14  1  0.754  0.412  0.959  1.0
  C  C15  1  0.683  0.204  0.378  1.0
  C  C16  1  0.368  0.846  0.931  1.0
  C  C17  1  0.987  0.809  0.836  1.0
  C  C18  1  0.962  0.240  0.482  1.0
  C  C19  1  0.282  0.478  0.595  1.0
  C  C20  1  0.038  0.760  0.518  1.0
  C  C21  1  0.246  0.588  0.041  1.0
  S  S22  1  0.861  0.373  0.180  1.0
  S  S23  1  0.908  0.881  0.951  1.0
  S  S24  1  0.092  0.119  0.049  1.0
  S  S25  1  0.139  0.627  0.820  1.0
  S  S26  1  0.096  0.092  0.263  1.0
  S  S27  1  0.904  0.908  0.737  1.0
  O  O28  1  0.255  0.477  0.316  1.0
  O  O29  1  0.745  0.523  0.684  1.0
  O  O30  1  0.125  0.224  0.763  1.0
  O  O31  1  0.491  0.257  0.822  1.0
  O  O32  1  0.015  0.184  0.554  1.0
  O  O33  1  0.575  0.124  0.394  1.0
  O  O34  1  0.384  0.360  0.566  1.0
  O  O35  1  0.531  0.136  0.141  1.0
  O  O36  1  0.616  0.640  0.434  1.0
  O  O37  1  0.985  0.816  0.446  1.0
  O  O38  1  0.425  0.876  0.606  1.0
  O  O39  1  0.875  0.776  0.237  1.0
  O  O40  1  0.509  0.743  0.178  1.0
  O  O41  1  0.709  0.551  0.962  1.0
  O  O42  1  0.291  0.449  0.038  1.0
  O  O43  1  0.469  0.864  0.859  1.0
[/CIF]
.
The material structure described by Re2C9S3O8 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one Re2C9S3O8 cluster. There are two inequivalent Re sites. In the first Re site, Re(1) is bonded to one C(3), one C(4), one C(5), one C(8), and two equivalent S(2) atoms to form edge-sharing ReC4S2 octahedra. In the second Re site, Re(2) is bonded in a distorted octahedral geometry to one C(1), one C(2), one C(6), one C(9), one S(1), and one S(3) atom. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Re(2) and one O(6) atom. In the second C site, C(2) is bonded in a linear geometry to one Re(2) and one O(1) atom. In the third C site, C(3) is bonded in a linear geometry to one Re(1) and one O(3) atom. In the fourth C site, C(4) is bonded in a linear geometry to one Re(1) and one O(7) atom. In the fifth C site, C(5) is bonded in a linear geometry to one Re(1) and one O(2) atom. In the sixth C site, C(6) is bonded in a linear geometry to one Re(2) and one O(5) atom. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one S(1), one S(2), and one S(3) atom. In the eighth C site, C(8) is bonded in a linear geometry to one Re(1) and one O(8) atom. In the ninth C site, C(9) is bonded in a linear geometry to one Re(2) and one O(4) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in an L-shaped geometry to one Re(2) and one C(7) atom. In the second S site, S(2) is bonded in a trigonal non-coplanar geometry to two equivalent Re(1) and one C(7) atom. In the third S site, S(3) is bonded in an L-shaped geometry to one Re(2) and one C(7) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(5) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(9) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one C(1) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one C(4) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one C(8) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Re2C9S3O8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.240
_cell_length_b   8.687
_cell_length_c   14.136
_cell_angle_alpha   83.678
_cell_angle_beta   79.465
_cell_angle_gamma   75.300
_symmetry_Int_Tables_number   1
_cell_volume   843.524
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.816  0.184  0.948  1.0
  Re  Re1  1  0.107  0.675  0.643  1.0
  Re  Re2  1  0.893  0.325  0.357  1.0
  Re  Re3  1  0.184  0.816  0.052  1.0
  C  C4  1  0.718  0.522  0.405  1.0
  C  C5  1  0.880  0.577  0.668  1.0
  C  C6  1  0.615  0.223  0.868  1.0
  C  C7  1  0.632  0.154  0.069  1.0
  C  C8  1  0.014  0.206  0.831  1.0
  C  C9  1  0.317  0.796  0.622  1.0
  C  C10  1  0.986  0.794  0.169  1.0
  C  C11  1  0.120  0.423  0.332  1.0
  C  C12  1  0.385  0.777  0.132  1.0
  C  C13  1  0.013  0.191  0.164  1.0
  C  C14  1  0.754  0.412  0.959  1.0
  C  C15  1  0.683  0.204  0.378  1.0
  C  C16  1  0.368  0.846  0.931  1.0
  C  C17  1  0.987  0.809  0.836  1.0
  C  C18  1  0.962  0.240  0.482  1.0
  C  C19  1  0.282  0.478  0.595  1.0
  C  C20  1  0.038  0.760  0.518  1.0
  C  C21  1  0.246  0.588  0.041  1.0
  S  S22  1  0.861  0.373  0.180  1.0
  S  S23  1  0.908  0.881  0.951  1.0
  S  S24  1  0.092  0.119  0.049  1.0
  S  S25  1  0.139  0.627  0.820  1.0
  S  S26  1  0.096  0.092  0.263  1.0
  S  S27  1  0.904  0.908  0.737  1.0
  O  O28  1  0.255  0.477  0.316  1.0
  O  O29  1  0.745  0.523  0.684  1.0
  O  O30  1  0.125  0.224  0.763  1.0
  O  O31  1  0.491  0.257  0.822  1.0
  O  O32  1  0.015  0.184  0.554  1.0
  O  O33  1  0.575  0.124  0.394  1.0
  O  O34  1  0.384  0.360  0.566  1.0
  O  O35  1  0.531  0.136  0.141  1.0
  O  O36  1  0.616  0.640  0.434  1.0
  O  O37  1  0.985  0.816  0.446  1.0
  O  O38  1  0.425  0.876  0.606  1.0
  O  O39  1  0.875  0.776  0.237  1.0
  O  O40  1  0.509  0.743  0.178  1.0
  O  O41  1  0.709  0.551  0.962  1.0
  O  O42  1  0.291  0.449  0.038  1.0
  O  O43  1  0.469  0.864  0.859  1.0
[/CIF]
.