The material structure described by MgLa2MoZnO6 crystallizes in the triclinic P1 space group. Mg(1) is bonded to one O(1), one O(2), one O(3), and one O(5) atom to form distorted MgO4 tetrahedra that share corners with two equivalent Mo(1)O6 octahedra, corners with two equivalent Zn(1)O4 trigonal pyramids, and  an edgeedge with one Mo(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 25-69°. There are two inequivalent La sites. In the first La site, La(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. In the second La site, La(2) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. Mo(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form MoO6 octahedra that share corners with two equivalent Mg(1)O4 tetrahedra, corners with four equivalent Zn(1)O4 trigonal pyramids, and  an edgeedge with one Mg(1)O4 tetrahedra. Zn(1) is bonded to one O(2), one O(3), one O(4), and one O(6) atom to form distorted ZnO4 trigonal pyramids that share corners with four equivalent Mo(1)O6 octahedra and corners with two equivalent Mg(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 12-81°. There are six inequivalent O sites. In the first O site, O(1) is bonded to one Mg(1), one La(1), one La(2), and one Mo(1) atom to form distorted OLa2MgMo tetrahedra that share corners with four equivalent O(5)La2MgMo tetrahedra and corners with four equivalent O(2)La2MgZnMo trigonal bipyramids. In the second O site, O(2) is bonded to one Mg(1), one La(1), one La(2), one Mo(1), and one Zn(1) atom to form a mixture of distorted corner and edge-sharing OLa2MgZnMo trigonal bipyramids. In the third O site, O(3) is bonded in a 5-coordinate geometry to one Mg(1), one La(1), one La(2), one Mo(1), and one Zn(1) atom. In the fourth O site, O(4) is bonded in a distorted see-saw-like geometry to one La(1), one La(2), one Mo(1), and one Zn(1) atom. In the fifth O site, O(5) is bonded to one Mg(1), one La(1), one La(2), and one Mo(1) atom to form distorted OLa2MgMo tetrahedra that share corners with four equivalent O(1)La2MgMo tetrahedra, corners with two equivalent O(2)La2MgZnMo trigonal bipyramids, and  an edgeedge with one O(2)La2MgZnMo trigonal bipyramid. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to one La(1), one La(2), one Mo(1), and one Zn(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_La2MgZnMoO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.806
_cell_length_b   5.815
_cell_length_c   6.095
_cell_angle_alpha   73.984
_cell_angle_beta   60.594
_cell_angle_gamma   59.934
_symmetry_Int_Tables_number   1
_cell_volume   155.046
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.755  0.811  0.632  1.0
  La  La1  1  0.317  0.171  0.268  1.0
  Mg  Mg2  1  0.736  0.527  0.147  1.0
  Zn  Zn3  1  0.405  0.437  0.689  1.0
  Mo  Mo4  1  0.032  0.987  0.974  1.0
  O  O5  1  0.414  0.815  0.070  1.0
  O  O6  1  0.665  0.219  0.347  1.0
  O  O7  1  0.052  0.384  0.787  1.0
  O  O8  1  0.668  0.168  0.845  1.0
  O  O9  1  0.976  0.620  0.218  1.0
  O  O10  1  0.360  0.800  0.595  1.0
[/CIF]
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The material structure described by MgLa2MoZnO6 crystallizes in the triclinic P1 space group. Mg(1) is bonded to one O(1), one O(2), one O(3), and one O(5) atom to form distorted MgO4 tetrahedra that share corners with two equivalent Mo(1)O6 octahedra, corners with two equivalent Zn(1)O4 trigonal pyramids, and  an edgeedge with one Mo(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 25-69°. There are two inequivalent La sites. In the first La site, La(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. In the second La site, La(2) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. Mo(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form MoO6 octahedra that share corners with two equivalent Mg(1)O4 tetrahedra, corners with four equivalent Zn(1)O4 trigonal pyramids, and  an edgeedge with one Mg(1)O4 tetrahedra. Zn(1) is bonded to one O(2), one O(3), one O(4), and one O(6) atom to form distorted ZnO4 trigonal pyramids that share corners with four equivalent Mo(1)O6 octahedra and corners with two equivalent Mg(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 12-81°. There are six inequivalent O sites. In the first O site, O(1) is bonded to one Mg(1), one La(1), one La(2), and one Mo(1) atom to form distorted OLa2MgMo tetrahedra that share corners with four equivalent O(5)La2MgMo tetrahedra and corners with four equivalent O(2)La2MgZnMo trigonal bipyramids. In the second O site, O(2) is bonded to one Mg(1), one La(1), one La(2), one Mo(1), and one Zn(1) atom to form a mixture of distorted corner and edge-sharing OLa2MgZnMo trigonal bipyramids. In the third O site, O(3) is bonded in a 5-coordinate geometry to one Mg(1), one La(1), one La(2), one Mo(1), and one Zn(1) atom. In the fourth O site, O(4) is bonded in a distorted see-saw-like geometry to one La(1), one La(2), one Mo(1), and one Zn(1) atom. In the fifth O site, O(5) is bonded to one Mg(1), one La(1), one La(2), and one Mo(1) atom to form distorted OLa2MgMo tetrahedra that share corners with four equivalent O(1)La2MgMo tetrahedra, corners with two equivalent O(2)La2MgZnMo trigonal bipyramids, and  an edgeedge with one O(2)La2MgZnMo trigonal bipyramid. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to one La(1), one La(2), one Mo(1), and one Zn(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_La2MgZnMoO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.806
_cell_length_b   5.815
_cell_length_c   6.095
_cell_angle_alpha   73.984
_cell_angle_beta   60.594
_cell_angle_gamma   59.934
_symmetry_Int_Tables_number   1
_cell_volume   155.046
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.755  0.811  0.632  1.0
  La  La1  1  0.317  0.171  0.268  1.0
  Mg  Mg2  1  0.736  0.527  0.147  1.0
  Zn  Zn3  1  0.405  0.437  0.689  1.0
  Mo  Mo4  1  0.032  0.987  0.974  1.0
  O  O5  1  0.414  0.815  0.070  1.0
  O  O6  1  0.665  0.219  0.347  1.0
  O  O7  1  0.052  0.384  0.787  1.0
  O  O8  1  0.668  0.168  0.845  1.0
  O  O9  1  0.976  0.620  0.218  1.0
  O  O10  1  0.360  0.800  0.595  1.0
[/CIF]
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