The compound described by Ag2ZnC4(NS)4 crystallizes in the monoclinic C2/c space group. Ag(1) is bonded to two equivalent S(1) and two equivalent S(2) atoms to form corner-sharing AgS4 tetrahedra. Zn(1) is bonded in a tetrahedral geometry to two equivalent N(1) and two equivalent N(2) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one N(2) and one S(1) atom. In the second C site, C(2) is bonded in a linear geometry to one N(1) and one S(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 150 degrees geometry to one Zn(1) and one C(2) atom. In the second N site, N(2) is bonded in a linear geometry to one Zn(1) and one C(1) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a trigonal non-coplanar geometry to two equivalent Ag(1) and one C(1) atom. In the second S site, S(2) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Ag(1) and one C(2) atom. is represented by the CIF file [CIF]
data_ZnAg2C4(SN)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.680
_cell_length_b   10.680
_cell_length_c   8.298
_cell_angle_alpha   84.196
_cell_angle_beta   84.196
_cell_angle_gamma   43.618
_symmetry_Int_Tables_number   1
_cell_volume   649.008
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.333  0.667  0.250  1.0
  Zn  Zn1  1  0.667  0.333  0.750  1.0
  Ag  Ag2  1  0.704  0.892  0.264  1.0
  Ag  Ag3  1  0.296  0.108  0.736  1.0
  Ag  Ag4  1  0.108  0.296  0.236  1.0
  Ag  Ag5  1  0.892  0.704  0.764  1.0
  C  C6  1  0.404  0.341  0.168  1.0
  C  C7  1  0.850  0.985  0.958  1.0
  C  C8  1  0.150  0.015  0.042  1.0
  C  C9  1  0.015  0.150  0.542  1.0
  C  C10  1  0.341  0.404  0.668  1.0
  C  C11  1  0.659  0.596  0.332  1.0
  C  C12  1  0.985  0.850  0.458  1.0
  C  C13  1  0.596  0.659  0.832  1.0
  S  S14  1  0.410  0.188  0.132  1.0
  S  S15  1  0.053  0.218  0.977  1.0
  S  S16  1  0.188  0.410  0.632  1.0
  S  S17  1  0.812  0.590  0.368  1.0
  S  S18  1  0.590  0.812  0.868  1.0
  S  S19  1  0.782  0.947  0.523  1.0
  S  S20  1  0.218  0.053  0.477  1.0
  S  S21  1  0.947  0.782  0.023  1.0
  N  N22  1  0.220  0.869  0.087  1.0
  N  N23  1  0.398  0.452  0.187  1.0
  N  N24  1  0.131  0.780  0.413  1.0
  N  N25  1  0.869  0.220  0.587  1.0
  N  N26  1  0.452  0.398  0.687  1.0
  N  N27  1  0.780  0.131  0.913  1.0
  N  N28  1  0.602  0.548  0.813  1.0
  N  N29  1  0.548  0.602  0.313  1.0
[/CIF]
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The compound described by Ag2ZnC4(NS)4 crystallizes in the monoclinic C2/c space group. Ag(1) is bonded to two equivalent S(1) and two equivalent S(2) atoms to form corner-sharing AgS4 tetrahedra. Zn(1) is bonded in a tetrahedral geometry to two equivalent N(1) and two equivalent N(2) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one N(2) and one S(1) atom. In the second C site, C(2) is bonded in a linear geometry to one N(1) and one S(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 150 degrees geometry to one Zn(1) and one C(2) atom. In the second N site, N(2) is bonded in a linear geometry to one Zn(1) and one C(1) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a trigonal non-coplanar geometry to two equivalent Ag(1) and one C(1) atom. In the second S site, S(2) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Ag(1) and one C(2) atom. is represented by the CIF file [CIF]
data_ZnAg2C4(SN)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.680
_cell_length_b   10.680
_cell_length_c   8.298
_cell_angle_alpha   84.196
_cell_angle_beta   84.196
_cell_angle_gamma   43.618
_symmetry_Int_Tables_number   1
_cell_volume   649.008
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.333  0.667  0.250  1.0
  Zn  Zn1  1  0.667  0.333  0.750  1.0
  Ag  Ag2  1  0.704  0.892  0.264  1.0
  Ag  Ag3  1  0.296  0.108  0.736  1.0
  Ag  Ag4  1  0.108  0.296  0.236  1.0
  Ag  Ag5  1  0.892  0.704  0.764  1.0
  C  C6  1  0.404  0.341  0.168  1.0
  C  C7  1  0.850  0.985  0.958  1.0
  C  C8  1  0.150  0.015  0.042  1.0
  C  C9  1  0.015  0.150  0.542  1.0
  C  C10  1  0.341  0.404  0.668  1.0
  C  C11  1  0.659  0.596  0.332  1.0
  C  C12  1  0.985  0.850  0.458  1.0
  C  C13  1  0.596  0.659  0.832  1.0
  S  S14  1  0.410  0.188  0.132  1.0
  S  S15  1  0.053  0.218  0.977  1.0
  S  S16  1  0.188  0.410  0.632  1.0
  S  S17  1  0.812  0.590  0.368  1.0
  S  S18  1  0.590  0.812  0.868  1.0
  S  S19  1  0.782  0.947  0.523  1.0
  S  S20  1  0.218  0.053  0.477  1.0
  S  S21  1  0.947  0.782  0.023  1.0
  N  N22  1  0.220  0.869  0.087  1.0
  N  N23  1  0.398  0.452  0.187  1.0
  N  N24  1  0.131  0.780  0.413  1.0
  N  N25  1  0.869  0.220  0.587  1.0
  N  N26  1  0.452  0.398  0.687  1.0
  N  N27  1  0.780  0.131  0.913  1.0
  N  N28  1  0.602  0.548  0.813  1.0
  N  N29  1  0.548  0.602  0.313  1.0
[/CIF]
.