The structure described by AgVO3 crystallizes in the monoclinic C2/c space group. V(1) is bonded to one O(2), one O(3), and two equivalent O(1) atoms to form VO4 tetrahedra that share corners with three equivalent Ag(2)O6 octahedra and corners with two equivalent V(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 43-52°. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a see-saw-like geometry to two equivalent O(2) and two equivalent O(3) atoms. In the second Ag site, Ag(2) is bonded to two equivalent O(2) and four equivalent O(3) atoms to form AgO6 octahedra that share corners with six equivalent V(1)O4 tetrahedra and edges with two equivalent Ag(2)O6 octahedra. There are three inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to two equivalent V(1) atoms. In the second O site, O(2) is bonded in a 3-coordinate geometry to one V(1), one Ag(1), and one Ag(2) atom. In the third O site, O(3) is bonded in a distorted rectangular see-saw-like geometry to one V(1), one Ag(1), and two equivalent Ag(2) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_VAgO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.306
_cell_length_b   7.306
_cell_length_c   5.803
_cell_angle_alpha   74.509
_cell_angle_beta   74.509
_cell_angle_gamma   85.385
_symmetry_Int_Tables_number   1
_cell_volume   287.631
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.098  0.266  0.766  1.0
  V  V1  1  0.734  0.902  0.734  1.0
  V  V2  1  0.902  0.734  0.234  1.0
  V  V3  1  0.266  0.098  0.266  1.0
  Ag  Ag4  1  0.263  0.737  0.750  1.0
  Ag  Ag5  1  0.737  0.263  0.250  1.0
  Ag  Ag6  1  0.585  0.415  0.750  1.0
  Ag  Ag7  1  0.415  0.585  0.250  1.0
  O  O8  1  0.163  0.095  0.020  1.0
  O  O9  1  0.905  0.837  0.480  1.0
  O  O10  1  0.837  0.905  0.980  1.0
  O  O11  1  0.095  0.163  0.520  1.0
  O  O12  1  0.888  0.369  0.860  1.0
  O  O13  1  0.631  0.112  0.640  1.0
  O  O14  1  0.112  0.631  0.140  1.0
  O  O15  1  0.369  0.888  0.360  1.0
  O  O16  1  0.430  0.269  0.153  1.0
  O  O17  1  0.731  0.570  0.347  1.0
  O  O18  1  0.570  0.731  0.847  1.0
  O  O19  1  0.269  0.430  0.653  1.0
[/CIF]
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The structure described by AgVO3 crystallizes in the monoclinic C2/c space group. V(1) is bonded to one O(2), one O(3), and two equivalent O(1) atoms to form VO4 tetrahedra that share corners with three equivalent Ag(2)O6 octahedra and corners with two equivalent V(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 43-52°. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a see-saw-like geometry to two equivalent O(2) and two equivalent O(3) atoms. In the second Ag site, Ag(2) is bonded to two equivalent O(2) and four equivalent O(3) atoms to form AgO6 octahedra that share corners with six equivalent V(1)O4 tetrahedra and edges with two equivalent Ag(2)O6 octahedra. There are three inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to two equivalent V(1) atoms. In the second O site, O(2) is bonded in a 3-coordinate geometry to one V(1), one Ag(1), and one Ag(2) atom. In the third O site, O(3) is bonded in a distorted rectangular see-saw-like geometry to one V(1), one Ag(1), and two equivalent Ag(2) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_VAgO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.306
_cell_length_b   7.306
_cell_length_c   5.803
_cell_angle_alpha   74.509
_cell_angle_beta   74.509
_cell_angle_gamma   85.385
_symmetry_Int_Tables_number   1
_cell_volume   287.631
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.098  0.266  0.766  1.0
  V  V1  1  0.734  0.902  0.734  1.0
  V  V2  1  0.902  0.734  0.234  1.0
  V  V3  1  0.266  0.098  0.266  1.0
  Ag  Ag4  1  0.263  0.737  0.750  1.0
  Ag  Ag5  1  0.737  0.263  0.250  1.0
  Ag  Ag6  1  0.585  0.415  0.750  1.0
  Ag  Ag7  1  0.415  0.585  0.250  1.0
  O  O8  1  0.163  0.095  0.020  1.0
  O  O9  1  0.905  0.837  0.480  1.0
  O  O10  1  0.837  0.905  0.980  1.0
  O  O11  1  0.095  0.163  0.520  1.0
  O  O12  1  0.888  0.369  0.860  1.0
  O  O13  1  0.631  0.112  0.640  1.0
  O  O14  1  0.112  0.631  0.140  1.0
  O  O15  1  0.369  0.888  0.360  1.0
  O  O16  1  0.430  0.269  0.153  1.0
  O  O17  1  0.731  0.570  0.347  1.0
  O  O18  1  0.570  0.731  0.847  1.0
  O  O19  1  0.269  0.430  0.653  1.0
[/CIF]
.