The material described by CNCs crystallizes in the monoclinic Cc space group. Cs(1) is bonded to four equivalent C(1) and four equivalent N(1) atoms to form distorted edge-sharing CsC4N4 hexagonal bipyramids. C(1) is bonded in a distorted single-bond geometry to four equivalent Cs(1) and one N(1) atom. N(1) is bonded in a distorted single-bond geometry to four equivalent Cs(1) and one C(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CsCN
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.302
_cell_length_b   4.979
_cell_length_c   8.500
_cell_angle_alpha   31.393
_cell_angle_beta   121.121
_cell_angle_gamma   116.180
_symmetry_Int_Tables_number   1
_cell_volume   194.413
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.458  0.087  0.924  1.0
  Cs  Cs1  1  0.958  0.913  0.010  1.0
  C  C2  1  0.669  0.120  0.378  1.0
  C  C3  1  0.169  0.880  0.499  1.0
  N  N4  1  0.770  0.826  0.606  1.0
  N  N5  1  0.270  0.174  0.431  1.0
[/CIF]
.
The material described by CNCs crystallizes in the monoclinic Cc space group. Cs(1) is bonded to four equivalent C(1) and four equivalent N(1) atoms to form distorted edge-sharing CsC4N4 hexagonal bipyramids. C(1) is bonded in a distorted single-bond geometry to four equivalent Cs(1) and one N(1) atom. N(1) is bonded in a distorted single-bond geometry to four equivalent Cs(1) and one C(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CsCN
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.302
_cell_length_b   4.979
_cell_length_c   8.500
_cell_angle_alpha   31.393
_cell_angle_beta   121.121
_cell_angle_gamma   116.180
_symmetry_Int_Tables_number   1
_cell_volume   194.413
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.458  0.087  0.924  1.0
  Cs  Cs1  1  0.958  0.913  0.010  1.0
  C  C2  1  0.669  0.120  0.378  1.0
  C  C3  1  0.169  0.880  0.499  1.0
  N  N4  1  0.770  0.826  0.606  1.0
  N  N5  1  0.270  0.174  0.431  1.0
[/CIF]
.