The material described by (AgPO3)12O2 crystallizes in the trigonal R3 space group. The structure consists of three water atoms inside a AgPO3 framework. In the AgPO3 framework, Ag(1,2) is bonded in a 6-coordinate geometry to one O(2), one O(6), two equivalent O(1), and two equivalent O(5) atoms. P(1,2) is bonded to one O(1), one O(3), one O(4), and one O(5) atom to form corner-sharing PO4 tetrahedra. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 1-coordinate geometry to three equivalent Ag(1,2) and one P(1,2) atom. In the second O site, O(2) is bonded in a 1-coordinate geometry to three equivalent Ag(1,2) and one P(1,2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to two equivalent P(1,2) atoms. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to two equivalent P(1,2) atoms. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to three equivalent Ag(1,2) and one P(1,2) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to three equivalent Ag(1,2) and one P(1,2) atom. is represented by the CIF card [CIF]
data_Ag6P6O19
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.957
_cell_length_b   8.957
_cell_length_c   8.957
_cell_angle_alpha   114.071
_cell_angle_beta   114.071
_cell_angle_gamma   114.071
_symmetry_Int_Tables_number   1
_cell_volume   434.219
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.842  0.379  0.519  1.0
  Ag  Ag1  1  0.379  0.519  0.842  1.0
  Ag  Ag2  1  0.519  0.842  0.379  1.0
  Ag  Ag3  1  0.158  0.621  0.481  1.0
  Ag  Ag4  1  0.621  0.481  0.158  1.0
  Ag  Ag5  1  0.481  0.158  0.621  1.0
  P  P6  1  0.024  0.268  0.898  1.0
  P  P7  1  0.268  0.898  0.024  1.0
  P  P8  1  0.898  0.024  0.268  1.0
  P  P9  1  0.976  0.732  0.102  1.0
  P  P10  1  0.732  0.102  0.976  1.0
  P  P11  1  0.102  0.976  0.732  1.0
  O  O12  1  0.460  0.059  0.275  1.0
  O  O13  1  0.059  0.275  0.460  1.0
  O  O14  1  0.275  0.460  0.059  1.0
  O  O15  1  0.540  0.941  0.725  1.0
  O  O16  1  0.941  0.725  0.540  1.0
  O  O17  1  0.725  0.540  0.941  1.0
  O  O18  1  0.972  0.254  0.047  1.0
  O  O19  1  0.254  0.047  0.972  1.0
  O  O20  1  0.047  0.972  0.254  1.0
  O  O21  1  0.028  0.746  0.953  1.0
  O  O22  1  0.746  0.953  0.028  1.0
  O  O23  1  0.953  0.028  0.746  1.0
  O  O24  1  0.863  0.259  0.737  1.0
  O  O25  1  0.259  0.737  0.863  1.0
  O  O26  1  0.737  0.863  0.259  1.0
  O  O27  1  0.137  0.741  0.263  1.0
  O  O28  1  0.741  0.263  0.137  1.0
  O  O29  1  0.263  0.137  0.741  1.0
  O  O30  1  0.479  0.479  0.479  1.0
[/CIF]
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The material described by (AgPO3)12O2 crystallizes in the trigonal R3 space group. The structure consists of three water atoms inside a AgPO3 framework. In the AgPO3 framework, Ag(1,2) is bonded in a 6-coordinate geometry to one O(2), one O(6), two equivalent O(1), and two equivalent O(5) atoms. P(1,2) is bonded to one O(1), one O(3), one O(4), and one O(5) atom to form corner-sharing PO4 tetrahedra. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 1-coordinate geometry to three equivalent Ag(1,2) and one P(1,2) atom. In the second O site, O(2) is bonded in a 1-coordinate geometry to three equivalent Ag(1,2) and one P(1,2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to two equivalent P(1,2) atoms. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to two equivalent P(1,2) atoms. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to three equivalent Ag(1,2) and one P(1,2) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to three equivalent Ag(1,2) and one P(1,2) atom. is represented by the CIF card [CIF]
data_Ag6P6O19
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.957
_cell_length_b   8.957
_cell_length_c   8.957
_cell_angle_alpha   114.071
_cell_angle_beta   114.071
_cell_angle_gamma   114.071
_symmetry_Int_Tables_number   1
_cell_volume   434.219
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.842  0.379  0.519  1.0
  Ag  Ag1  1  0.379  0.519  0.842  1.0
  Ag  Ag2  1  0.519  0.842  0.379  1.0
  Ag  Ag3  1  0.158  0.621  0.481  1.0
  Ag  Ag4  1  0.621  0.481  0.158  1.0
  Ag  Ag5  1  0.481  0.158  0.621  1.0
  P  P6  1  0.024  0.268  0.898  1.0
  P  P7  1  0.268  0.898  0.024  1.0
  P  P8  1  0.898  0.024  0.268  1.0
  P  P9  1  0.976  0.732  0.102  1.0
  P  P10  1  0.732  0.102  0.976  1.0
  P  P11  1  0.102  0.976  0.732  1.0
  O  O12  1  0.460  0.059  0.275  1.0
  O  O13  1  0.059  0.275  0.460  1.0
  O  O14  1  0.275  0.460  0.059  1.0
  O  O15  1  0.540  0.941  0.725  1.0
  O  O16  1  0.941  0.725  0.540  1.0
  O  O17  1  0.725  0.540  0.941  1.0
  O  O18  1  0.972  0.254  0.047  1.0
  O  O19  1  0.254  0.047  0.972  1.0
  O  O20  1  0.047  0.972  0.254  1.0
  O  O21  1  0.028  0.746  0.953  1.0
  O  O22  1  0.746  0.953  0.028  1.0
  O  O23  1  0.953  0.028  0.746  1.0
  O  O24  1  0.863  0.259  0.737  1.0
  O  O25  1  0.259  0.737  0.863  1.0
  O  O26  1  0.737  0.863  0.259  1.0
  O  O27  1  0.137  0.741  0.263  1.0
  O  O28  1  0.741  0.263  0.137  1.0
  O  O29  1  0.263  0.137  0.741  1.0
  O  O30  1  0.479  0.479  0.479  1.0
[/CIF]
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