The material described by TiRhAs crystallizes in the orthorhombic Pnma space group. Ti(1) is bonded in a 11-coordinate geometry to six equivalent Rh(1) and five equivalent As(1) atoms. Rh(1) is bonded in a 12-coordinate geometry to six equivalent Ti(1), two equivalent Rh(1), and four equivalent As(1) atoms. As(1) is bonded in a 9-coordinate geometry to five equivalent Ti(1) and four equivalent Rh(1) atoms. is represented by the CIF file [CIF]
data_TiAsRh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.815
_cell_length_b   6.370
_cell_length_c   7.397
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   179.752
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.750  0.032  0.318  1.0
  Ti  Ti1  1  0.250  0.968  0.682  1.0
  Ti  Ti2  1  0.250  0.468  0.818  1.0
  Ti  Ti3  1  0.750  0.532  0.182  1.0
  As  As4  1  0.250  0.251  0.122  1.0
  As  As5  1  0.750  0.749  0.878  1.0
  As  As6  1  0.250  0.751  0.378  1.0
  As  As7  1  0.750  0.249  0.622  1.0
  Rh  Rh8  1  0.750  0.143  0.936  1.0
  Rh  Rh9  1  0.250  0.857  0.064  1.0
  Rh  Rh10  1  0.250  0.357  0.436  1.0
  Rh  Rh11  1  0.750  0.643  0.564  1.0
[/CIF]
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The material described by TiRhAs crystallizes in the orthorhombic Pnma space group. Ti(1) is bonded in a 11-coordinate geometry to six equivalent Rh(1) and five equivalent As(1) atoms. Rh(1) is bonded in a 12-coordinate geometry to six equivalent Ti(1), two equivalent Rh(1), and four equivalent As(1) atoms. As(1) is bonded in a 9-coordinate geometry to five equivalent Ti(1) and four equivalent Rh(1) atoms. is represented by the CIF file [CIF]
data_TiAsRh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.815
_cell_length_b   6.370
_cell_length_c   7.397
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   179.752
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.750  0.032  0.318  1.0
  Ti  Ti1  1  0.250  0.968  0.682  1.0
  Ti  Ti2  1  0.250  0.468  0.818  1.0
  Ti  Ti3  1  0.750  0.532  0.182  1.0
  As  As4  1  0.250  0.251  0.122  1.0
  As  As5  1  0.750  0.749  0.878  1.0
  As  As6  1  0.250  0.751  0.378  1.0
  As  As7  1  0.750  0.249  0.622  1.0
  Rh  Rh8  1  0.750  0.143  0.936  1.0
  Rh  Rh9  1  0.250  0.857  0.064  1.0
  Rh  Rh10  1  0.250  0.357  0.436  1.0
  Rh  Rh11  1  0.750  0.643  0.564  1.0
[/CIF]
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