The structure described by Ni2C5(OCl2)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two Ni2C5(OCl2)2 clusters. In one of the Ni2C5(OCl2)2 clusters, there are two inequivalent Ni sites. In the first Ni site, Ni(1) is bonded in a distorted square co-planar geometry to one C(2), one C(4), one C(9), and one Cl(6) atom. In the second Ni site, Ni(3) is bonded in a distorted square co-planar geometry to one C(2), one C(6), one C(9), and one Cl(6) atom. There are five inequivalent C sites. In the first C site, C(1) is bonded in a 3-coordinate geometry to one C(2), one C(9), and one Cl(2) atom. In the second C site, C(2) is bonded in a distorted rectangular see-saw-like geometry to one Ni(1), one Ni(3), one C(1), and one Cl(1) atom. In the third C site, C(4) is bonded in a linear geometry to one Ni(1) and one O(3) atom. In the fourth C site, C(6) is bonded in a linear geometry to one Ni(3) and one O(4) atom. In the fifth C site, C(9) is bonded in a distorted rectangular see-saw-like geometry to one Ni(1), one Ni(3), one C(1), and one Cl(3) atom. There are two inequivalent O sites. In the first O site, O(3) is bonded in a single-bond geometry to one C(4) atom. In the second O site, O(4) is bonded in a single-bond geometry to one C(6) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(6) is bonded in a bent 120 degrees geometry to one Ni(1) and one Ni(3) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one C(2) atom. In the third Cl site, Cl(2) is bonded in a single-bond geometry to one C(1) atom. In the fourth Cl site, Cl(3) is bonded in a single-bond geometry to one C(9) atom. In one of the Ni2C5(OCl2)2 clusters, there are two inequivalent Ni sites. In the first Ni site, Ni(2) is bonded in a distorted square co-planar geometry to one C(3), one C(5), one C(7), and one Cl(7) atom. In the second Ni site, Ni(4) is bonded in a distorted square co-planar geometry to one C(5), one C(7), one C(8), and one Cl(7) atom. There are five inequivalent C sites. In the first C site, C(3) is bonded in a linear geometry to one Ni(2) and one O(2) atom. In the second C site, C(5) is bonded in a distorted rectangular see-saw-like geometry to one Ni(2), one Ni(4), one C(10), and one Cl(5) atom. In the third C site, C(7) is bonded in a distorted rectangular see-saw-like geometry to one Ni(2), one Ni(4), one C(10), and one Cl(4) atom. In the fourth C site, C(8) is bonded in a linear geometry to one Ni(4) and one O(1) atom. In the fifth C site, C(10) is bonded in a 3-coordinate geometry to one C(5), one C(7), and one Cl(8) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(8) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(3) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(5) is bonded in a single-bond geometry to one C(5) atom. In the second Cl site, Cl(7) is bonded in a bent 120 degrees geometry to one Ni(2) and one Ni(4) atom. In the third Cl site, Cl(8) is bonded in a single-bond geometry to one C(10) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one C(7) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ni2C5(Cl2O)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.460
_cell_length_b   10.854
_cell_length_c   14.512
_cell_angle_alpha   91.052
_cell_angle_beta   90.371
_cell_angle_gamma   103.589
_symmetry_Int_Tables_number   1
_cell_volume   1141.970
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ni  Ni0  1  0.910  0.816  0.912  1.0
  Ni  Ni1  1  0.760  0.585  0.455  1.0
  Ni  Ni2  1  0.213  0.885  0.000  1.0
  Ni  Ni3  1  0.090  0.184  0.088  1.0
  Ni  Ni4  1  0.240  0.415  0.545  1.0
  Ni  Ni5  1  0.911  0.288  0.515  1.0
  Ni  Ni6  1  0.787  0.115  1.000  1.0
  Ni  Ni7  1  0.089  0.712  0.485  1.0
  C  C8  1  0.809  0.144  0.160  1.0
  C  C9  1  0.865  0.244  0.096  1.0
  C  C10  1  0.370  0.405  0.648  1.0
  C  C11  1  0.751  0.665  0.921  1.0
  C  C12  1  0.630  0.595  0.352  1.0
  C  C13  1  0.097  0.375  0.429  1.0
  C  C14  1  0.265  0.783  0.088  1.0
  C  C15  1  0.249  0.335  0.079  1.0
  C  C16  1  0.141  0.234  0.525  1.0
  C  C17  1  0.222  0.813  0.401  1.0
  C  C18  1  0.778  0.187  0.599  1.0
  C  C19  1  0.735  0.217  0.912  1.0
  C  C20  1  0.869  0.047  0.112  1.0
  C  C21  1  0.191  0.856  0.840  1.0
  C  C22  1  0.859  0.766  0.475  1.0
  C  C23  1  0.903  0.625  0.571  1.0
  C  C24  1  0.131  0.953  0.888  1.0
  C  C25  1  0.844  0.739  0.571  1.0
  C  C26  1  0.135  0.756  0.904  1.0
  C  C27  1  0.156  0.261  0.429  1.0
  Cl  Cl28  1  0.177  0.608  0.890  1.0
  Cl  Cl29  1  0.701  0.144  0.264  1.0
  Cl  Cl30  1  0.842  0.896  0.151  1.0
  Cl  Cl31  1  0.803  0.895  0.427  1.0
  Cl  Cl32  1  0.916  0.539  0.667  1.0
  Cl  Cl33  1  0.084  0.461  0.333  1.0
  Cl  Cl34  1  0.299  0.856  0.736  1.0
  Cl  Cl35  1  0.301  0.067  0.083  1.0
  Cl  Cl36  1  0.699  0.933  0.917  1.0
  Cl  Cl37  1  0.158  0.104  0.849  1.0
  Cl  Cl38  1  0.679  0.373  0.468  1.0
  Cl  Cl39  1  0.197  0.105  0.573  1.0
  Cl  Cl40  1  0.321  0.627  0.532  1.0
  Cl  Cl41  1  0.823  0.392  0.110  1.0
  Cl  Cl42  1  0.227  0.179  0.339  1.0
  Cl  Cl43  1  0.773  0.821  0.661  1.0
  O  O44  1  0.309  0.875  0.346  1.0
  O  O45  1  0.545  0.604  0.287  1.0
  O  O46  1  0.351  0.432  0.077  1.0
  O  O47  1  0.711  0.285  0.856  1.0
  O  O48  1  0.289  0.715  0.144  1.0
  O  O49  1  0.691  0.125  0.654  1.0
  O  O50  1  0.455  0.396  0.713  1.0
  O  O51  1  0.649  0.568  0.923  1.0
[/CIF]
.
The structure described by Ni2C5(OCl2)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two Ni2C5(OCl2)2 clusters. In one of the Ni2C5(OCl2)2 clusters, there are two inequivalent Ni sites. In the first Ni site, Ni(1) is bonded in a distorted square co-planar geometry to one C(2), one C(4), one C(9), and one Cl(6) atom. In the second Ni site, Ni(3) is bonded in a distorted square co-planar geometry to one C(2), one C(6), one C(9), and one Cl(6) atom. There are five inequivalent C sites. In the first C site, C(1) is bonded in a 3-coordinate geometry to one C(2), one C(9), and one Cl(2) atom. In the second C site, C(2) is bonded in a distorted rectangular see-saw-like geometry to one Ni(1), one Ni(3), one C(1), and one Cl(1) atom. In the third C site, C(4) is bonded in a linear geometry to one Ni(1) and one O(3) atom. In the fourth C site, C(6) is bonded in a linear geometry to one Ni(3) and one O(4) atom. In the fifth C site, C(9) is bonded in a distorted rectangular see-saw-like geometry to one Ni(1), one Ni(3), one C(1), and one Cl(3) atom. There are two inequivalent O sites. In the first O site, O(3) is bonded in a single-bond geometry to one C(4) atom. In the second O site, O(4) is bonded in a single-bond geometry to one C(6) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(6) is bonded in a bent 120 degrees geometry to one Ni(1) and one Ni(3) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one C(2) atom. In the third Cl site, Cl(2) is bonded in a single-bond geometry to one C(1) atom. In the fourth Cl site, Cl(3) is bonded in a single-bond geometry to one C(9) atom. In one of the Ni2C5(OCl2)2 clusters, there are two inequivalent Ni sites. In the first Ni site, Ni(2) is bonded in a distorted square co-planar geometry to one C(3), one C(5), one C(7), and one Cl(7) atom. In the second Ni site, Ni(4) is bonded in a distorted square co-planar geometry to one C(5), one C(7), one C(8), and one Cl(7) atom. There are five inequivalent C sites. In the first C site, C(3) is bonded in a linear geometry to one Ni(2) and one O(2) atom. In the second C site, C(5) is bonded in a distorted rectangular see-saw-like geometry to one Ni(2), one Ni(4), one C(10), and one Cl(5) atom. In the third C site, C(7) is bonded in a distorted rectangular see-saw-like geometry to one Ni(2), one Ni(4), one C(10), and one Cl(4) atom. In the fourth C site, C(8) is bonded in a linear geometry to one Ni(4) and one O(1) atom. In the fifth C site, C(10) is bonded in a 3-coordinate geometry to one C(5), one C(7), and one Cl(8) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(8) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(3) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(5) is bonded in a single-bond geometry to one C(5) atom. In the second Cl site, Cl(7) is bonded in a bent 120 degrees geometry to one Ni(2) and one Ni(4) atom. In the third Cl site, Cl(8) is bonded in a single-bond geometry to one C(10) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one C(7) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ni2C5(Cl2O)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.460
_cell_length_b   10.854
_cell_length_c   14.512
_cell_angle_alpha   91.052
_cell_angle_beta   90.371
_cell_angle_gamma   103.589
_symmetry_Int_Tables_number   1
_cell_volume   1141.970
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ni  Ni0  1  0.910  0.816  0.912  1.0
  Ni  Ni1  1  0.760  0.585  0.455  1.0
  Ni  Ni2  1  0.213  0.885  0.000  1.0
  Ni  Ni3  1  0.090  0.184  0.088  1.0
  Ni  Ni4  1  0.240  0.415  0.545  1.0
  Ni  Ni5  1  0.911  0.288  0.515  1.0
  Ni  Ni6  1  0.787  0.115  1.000  1.0
  Ni  Ni7  1  0.089  0.712  0.485  1.0
  C  C8  1  0.809  0.144  0.160  1.0
  C  C9  1  0.865  0.244  0.096  1.0
  C  C10  1  0.370  0.405  0.648  1.0
  C  C11  1  0.751  0.665  0.921  1.0
  C  C12  1  0.630  0.595  0.352  1.0
  C  C13  1  0.097  0.375  0.429  1.0
  C  C14  1  0.265  0.783  0.088  1.0
  C  C15  1  0.249  0.335  0.079  1.0
  C  C16  1  0.141  0.234  0.525  1.0
  C  C17  1  0.222  0.813  0.401  1.0
  C  C18  1  0.778  0.187  0.599  1.0
  C  C19  1  0.735  0.217  0.912  1.0
  C  C20  1  0.869  0.047  0.112  1.0
  C  C21  1  0.191  0.856  0.840  1.0
  C  C22  1  0.859  0.766  0.475  1.0
  C  C23  1  0.903  0.625  0.571  1.0
  C  C24  1  0.131  0.953  0.888  1.0
  C  C25  1  0.844  0.739  0.571  1.0
  C  C26  1  0.135  0.756  0.904  1.0
  C  C27  1  0.156  0.261  0.429  1.0
  Cl  Cl28  1  0.177  0.608  0.890  1.0
  Cl  Cl29  1  0.701  0.144  0.264  1.0
  Cl  Cl30  1  0.842  0.896  0.151  1.0
  Cl  Cl31  1  0.803  0.895  0.427  1.0
  Cl  Cl32  1  0.916  0.539  0.667  1.0
  Cl  Cl33  1  0.084  0.461  0.333  1.0
  Cl  Cl34  1  0.299  0.856  0.736  1.0
  Cl  Cl35  1  0.301  0.067  0.083  1.0
  Cl  Cl36  1  0.699  0.933  0.917  1.0
  Cl  Cl37  1  0.158  0.104  0.849  1.0
  Cl  Cl38  1  0.679  0.373  0.468  1.0
  Cl  Cl39  1  0.197  0.105  0.573  1.0
  Cl  Cl40  1  0.321  0.627  0.532  1.0
  Cl  Cl41  1  0.823  0.392  0.110  1.0
  Cl  Cl42  1  0.227  0.179  0.339  1.0
  Cl  Cl43  1  0.773  0.821  0.661  1.0
  O  O44  1  0.309  0.875  0.346  1.0
  O  O45  1  0.545  0.604  0.287  1.0
  O  O46  1  0.351  0.432  0.077  1.0
  O  O47  1  0.711  0.285  0.856  1.0
  O  O48  1  0.289  0.715  0.144  1.0
  O  O49  1  0.691  0.125  0.654  1.0
  O  O50  1  0.455  0.396  0.713  1.0
  O  O51  1  0.649  0.568  0.923  1.0
[/CIF]
.