The material structure described by RbSbF6 crystallizes in the trigonal R-3 space group. Rb(1) is bonded to twelve equivalent F(1) atoms to form RbF12 cuboctahedra that share corners with six equivalent Sb(1)F6 octahedra, edges with six equivalent Rb(1)F12 cuboctahedra, and faces with two equivalent Sb(1)F6 octahedra. The corner-sharing octahedral tilt angles are 40°. Sb(1) is bonded to six equivalent F(1) atoms to form SbF6 octahedra that share corners with six equivalent Rb(1)F12 cuboctahedra and faces with two equivalent Rb(1)F12 cuboctahedra. F(1) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one Sb(1) atom. is represented by the CIF card [CIF]
data_RbSbF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.046
_cell_length_b   5.046
_cell_length_c   5.046
_cell_angle_alpha   96.835
_cell_angle_beta   96.835
_cell_angle_gamma   96.835
_symmetry_Int_Tables_number   1
_cell_volume   125.517
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.500  0.500  0.500  1.0
  Sb  Sb1  1  0.000  0.000  0.000  1.0
  F  F2  1  0.203  0.316  0.922  1.0
  F  F3  1  0.316  0.922  0.203  1.0
  F  F4  1  0.078  0.797  0.684  1.0
  F  F5  1  0.684  0.078  0.797  1.0
  F  F6  1  0.797  0.684  0.078  1.0
  F  F7  1  0.922  0.203  0.316  1.0
[/CIF]
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The material structure described by RbSbF6 crystallizes in the trigonal R-3 space group. Rb(1) is bonded to twelve equivalent F(1) atoms to form RbF12 cuboctahedra that share corners with six equivalent Sb(1)F6 octahedra, edges with six equivalent Rb(1)F12 cuboctahedra, and faces with two equivalent Sb(1)F6 octahedra. The corner-sharing octahedral tilt angles are 40°. Sb(1) is bonded to six equivalent F(1) atoms to form SbF6 octahedra that share corners with six equivalent Rb(1)F12 cuboctahedra and faces with two equivalent Rb(1)F12 cuboctahedra. F(1) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one Sb(1) atom. is represented by the CIF card [CIF]
data_RbSbF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.046
_cell_length_b   5.046
_cell_length_c   5.046
_cell_angle_alpha   96.835
_cell_angle_beta   96.835
_cell_angle_gamma   96.835
_symmetry_Int_Tables_number   1
_cell_volume   125.517
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.500  0.500  0.500  1.0
  Sb  Sb1  1  0.000  0.000  0.000  1.0
  F  F2  1  0.203  0.316  0.922  1.0
  F  F3  1  0.316  0.922  0.203  1.0
  F  F4  1  0.078  0.797  0.684  1.0
  F  F5  1  0.684  0.078  0.797  1.0
  F  F6  1  0.797  0.684  0.078  1.0
  F  F7  1  0.922  0.203  0.316  1.0
[/CIF]
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