The crystal structure described by Li2Ga2GeS6 crystallizes in the orthorhombic Fdd2 space group. Li(1) is bonded in a distorted see-saw-like geometry to one S(1), one S(3), and two equivalent S(2) atoms. Ga(1) is bonded to one S(1), one S(2), and two equivalent S(3) atoms to form GaS4 tetrahedra that share corners with two equivalent Ga(1)S4 tetrahedra and corners with two equivalent Ge(1)S4 tetrahedra. Ge(1) is bonded to two equivalent S(1) and two equivalent S(2) atoms to form GeS4 tetrahedra that share corners with four equivalent Ga(1)S4 tetrahedra. There are three inequivalent S sites. In the first S site, S(1) is bonded in a trigonal non-coplanar geometry to one Li(1), one Ga(1), and one Ge(1) atom. In the second S site, S(2) is bonded to two equivalent Li(1), one Ga(1), and one Ge(1) atom to form corner-sharing SLi2GaGe tetrahedra. In the third S site, S(3) is bonded in a trigonal non-coplanar geometry to one Li(1) and two equivalent Ga(1) atoms. is represented by the CIF file [CIF]
data_Li2Ga2GeS6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.066
_cell_length_b   12.023
_cell_length_c   7.063
_cell_angle_alpha   81.970
_cell_angle_beta   65.667
_cell_angle_gamma   32.363
_symmetry_Int_Tables_number   1
_cell_volume   489.299
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.108  0.988  0.225  1.0
  Li  Li1  1  0.679  0.225  0.988  1.0
  Li  Li2  1  0.262  0.142  0.571  1.0
  Li  Li3  1  0.025  0.571  0.142  1.0
  Ga  Ga4  1  0.719  0.551  0.550  1.0
  Ga  Ga5  1  0.180  0.550  0.551  1.0
  Ga  Ga6  1  0.699  0.531  0.070  1.0
  Ga  Ga7  1  0.700  0.070  0.531  1.0
  Ge  Ge8  1  0.659  0.841  0.841  1.0
  Ge  Ge9  1  0.409  0.591  0.591  1.0
  S  S10  1  0.450  0.902  0.155  1.0
  S  S11  1  0.664  0.792  0.536  1.0
  S  S12  1  0.095  0.757  0.800  1.0
  S  S13  1  0.458  0.586  0.242  1.0
  S  S14  1  0.493  0.155  0.902  1.0
  S  S15  1  0.945  0.318  0.180  1.0
  S  S16  1  0.008  0.536  0.792  1.0
  S  S17  1  0.348  0.800  0.757  1.0
  S  S18  1  0.714  0.242  0.586  1.0
  S  S19  1  0.932  0.305  0.693  1.0
  S  S20  1  0.557  0.180  0.318  1.0
  S  S21  1  0.070  0.693  0.305  1.0
[/CIF]
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The crystal structure described by Li2Ga2GeS6 crystallizes in the orthorhombic Fdd2 space group. Li(1) is bonded in a distorted see-saw-like geometry to one S(1), one S(3), and two equivalent S(2) atoms. Ga(1) is bonded to one S(1), one S(2), and two equivalent S(3) atoms to form GaS4 tetrahedra that share corners with two equivalent Ga(1)S4 tetrahedra and corners with two equivalent Ge(1)S4 tetrahedra. Ge(1) is bonded to two equivalent S(1) and two equivalent S(2) atoms to form GeS4 tetrahedra that share corners with four equivalent Ga(1)S4 tetrahedra. There are three inequivalent S sites. In the first S site, S(1) is bonded in a trigonal non-coplanar geometry to one Li(1), one Ga(1), and one Ge(1) atom. In the second S site, S(2) is bonded to two equivalent Li(1), one Ga(1), and one Ge(1) atom to form corner-sharing SLi2GaGe tetrahedra. In the third S site, S(3) is bonded in a trigonal non-coplanar geometry to one Li(1) and two equivalent Ga(1) atoms. is represented by the CIF file [CIF]
data_Li2Ga2GeS6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.066
_cell_length_b   12.023
_cell_length_c   7.063
_cell_angle_alpha   81.970
_cell_angle_beta   65.667
_cell_angle_gamma   32.363
_symmetry_Int_Tables_number   1
_cell_volume   489.299
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.108  0.988  0.225  1.0
  Li  Li1  1  0.679  0.225  0.988  1.0
  Li  Li2  1  0.262  0.142  0.571  1.0
  Li  Li3  1  0.025  0.571  0.142  1.0
  Ga  Ga4  1  0.719  0.551  0.550  1.0
  Ga  Ga5  1  0.180  0.550  0.551  1.0
  Ga  Ga6  1  0.699  0.531  0.070  1.0
  Ga  Ga7  1  0.700  0.070  0.531  1.0
  Ge  Ge8  1  0.659  0.841  0.841  1.0
  Ge  Ge9  1  0.409  0.591  0.591  1.0
  S  S10  1  0.450  0.902  0.155  1.0
  S  S11  1  0.664  0.792  0.536  1.0
  S  S12  1  0.095  0.757  0.800  1.0
  S  S13  1  0.458  0.586  0.242  1.0
  S  S14  1  0.493  0.155  0.902  1.0
  S  S15  1  0.945  0.318  0.180  1.0
  S  S16  1  0.008  0.536  0.792  1.0
  S  S17  1  0.348  0.800  0.757  1.0
  S  S18  1  0.714  0.242  0.586  1.0
  S  S19  1  0.932  0.305  0.693  1.0
  S  S20  1  0.557  0.180  0.318  1.0
  S  S21  1  0.070  0.693  0.305  1.0
[/CIF]
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