The compound described by Ge11N11O5 is beta indium sulfide-derived structured and crystallizes in the monoclinic Cm space group. There are nine inequivalent Ge sites. In the first Ge site, Ge(1) is bonded to one N(1), one N(2), one N(4), one N(6), one N(7), and one O(4) atom to form GeN5O octahedra that share  a cornercorner with one Ge(3)N3O tetrahedra, corners with two equivalent Ge(4)N4 tetrahedra, corners with two equivalent Ge(9)N4 tetrahedra,  an edgeedge with one Ge(7)N3O3 octahedra,  an edgeedge with one Ge(5)N5O octahedra, edges with two equivalent Ge(1)N5O octahedra, and edges with two equivalent Ge(8)N5O octahedra. In the second Ge site, Ge(2) is bonded to one N(3), one N(5), one N(8), one O(1), one O(2), and one O(3) atom to form GeN3O3 octahedra that share  a cornercorner with one Ge(4)N4 tetrahedra,  a cornercorner with one Ge(9)N4 tetrahedra, corners with two equivalent Ge(3)N3O tetrahedra,  an edgeedge with one Ge(7)N3O3 octahedra,  an edgeedge with one Ge(5)N5O octahedra, edges with two equivalent Ge(2)N3O3 octahedra, and edges with two equivalent Ge(6)N4O2 octahedra. In the third Ge site, Ge(3) is bonded to one N(4), two equivalent N(5), and one O(2) atom to form GeN3O tetrahedra that share  a cornercorner with one Ge(8)N5O octahedra, corners with two equivalent Ge(6)N4O2 octahedra, corners with two equivalent Ge(1)N5O octahedra, corners with three equivalent Ge(5)N5O octahedra, and corners with four equivalent Ge(2)N3O3 octahedra. The corner-sharing octahedral tilt angles range from 56-61°. In the fourth Ge site, Ge(4) is bonded to one N(2), one N(3), and two equivalent N(1) atoms to form GeN4 tetrahedra that share  a cornercorner with one Ge(6)N4O2 octahedra, corners with two equivalent Ge(2)N3O3 octahedra, corners with two equivalent Ge(8)N5O octahedra, corners with three equivalent Ge(7)N3O3 octahedra, and corners with four equivalent Ge(1)N5O octahedra. The corner-sharing octahedral tilt angles range from 56-59°. In the fifth Ge site, Ge(5) is bonded to one N(7), two equivalent N(5), two equivalent N(6), and one O(2) atom to form GeN5O octahedra that share corners with three equivalent Ge(3)N3O tetrahedra, corners with three equivalent Ge(9)N4 tetrahedra,  an edgeedge with one Ge(6)N4O2 octahedra,  an edgeedge with one Ge(8)N5O octahedra, edges with two equivalent Ge(2)N3O3 octahedra, and edges with two equivalent Ge(1)N5O octahedra. In the sixth Ge site, Ge(6) is bonded to one N(3), one N(8), two equivalent N(5), and two equivalent O(1) atoms to form GeN4O2 octahedra that share  a cornercorner with one Ge(4)N4 tetrahedra,  a cornercorner with one Ge(9)N4 tetrahedra, corners with two equivalent Ge(3)N3O tetrahedra,  an edgeedge with one Ge(7)N3O3 octahedra,  an edgeedge with one Ge(5)N5O octahedra, and edges with four equivalent Ge(2)N3O3 octahedra. In the seventh Ge site, Ge(7) is bonded to one N(2), two equivalent N(1), one O(3), and two equivalent O(1) atoms to form GeN3O3 octahedra that share corners with three equivalent Ge(4)N4 tetrahedra,  an edgeedge with one Ge(6)N4O2 octahedra,  an edgeedge with one Ge(8)N5O octahedra, edges with two equivalent Ge(2)N3O3 octahedra, and edges with two equivalent Ge(1)N5O octahedra. In the eighth Ge site, Ge(8) is bonded to one N(4), two equivalent N(1), two equivalent N(6), and one O(4) atom to form GeN5O octahedra that share  a cornercorner with one Ge(3)N3O tetrahedra, corners with two equivalent Ge(4)N4 tetrahedra, corners with two equivalent Ge(9)N4 tetrahedra,  an edgeedge with one Ge(7)N3O3 octahedra,  an edgeedge with one Ge(5)N5O octahedra, and edges with four equivalent Ge(1)N5O octahedra. In the ninth Ge site, Ge(9) is bonded to one N(7), one N(8), and two equivalent N(6) atoms to form GeN4 tetrahedra that share  a cornercorner with one Ge(6)N4O2 octahedra, corners with two equivalent Ge(2)N3O3 octahedra, corners with two equivalent Ge(8)N5O octahedra, corners with three equivalent Ge(5)N5O octahedra, and corners with four equivalent Ge(1)N5O octahedra. The corner-sharing octahedral tilt angles range from 55-58°. There are eight inequivalent N sites. In the first N site, N(1) is bonded in a distorted rectangular see-saw-like geometry to one Ge(1), one Ge(4), one Ge(7), and one Ge(8) atom. In the second N site, N(2) is bonded in a distorted rectangular see-saw-like geometry to one Ge(4), one Ge(7), and two equivalent Ge(1) atoms. In the third N site, N(3) is bonded to one Ge(4), one Ge(6), and two equivalent Ge(2) atoms to form distorted edge-sharing NGe4 trigonal pyramids. In the fourth N site, N(4) is bonded to one Ge(3), one Ge(8), and two equivalent Ge(1) atoms to form distorted corner-sharing NGe4 trigonal pyramids. In the fifth N site, N(5) is bonded to one Ge(2), one Ge(3), one Ge(5), and one Ge(6) atom to form a mixture of distorted corner and edge-sharing NGe4 trigonal pyramids. In the sixth N site, N(6) is bonded in a rectangular see-saw-like geometry to one Ge(1), one Ge(5), one Ge(8), and one Ge(9) atom. In the seventh N site, N(7) is bonded in a distorted rectangular see-saw-like geometry to one Ge(5), one Ge(9), and two equivalent Ge(1) atoms. In the eighth N site, N(8) is bonded in a distorted rectangular see-saw-like geometry to one Ge(6), one Ge(9), and two equivalent Ge(2) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to one Ge(2), one Ge(6), and one Ge(7) atom. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to one Ge(3), one Ge(5), and two equivalent Ge(2) atoms. In the third O site, O(3) is bonded in a distorted T-shaped geometry to one Ge(7) and two equivalent Ge(2) atoms. In the fourth O site, O(4) is bonded in a distorted trigonal non-coplanar geometry to one Ge(8) and two equivalent Ge(1) atoms. is represented by the CIF file [CIF]
data_Ge11N11O5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.915
_cell_length_b   5.915
_cell_length_c   10.224
_cell_angle_alpha   73.188
_cell_angle_beta   73.188
_cell_angle_gamma   59.712
_symmetry_Int_Tables_number   1
_cell_volume   291.220
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ge  Ge0  1  0.687  0.188  0.438  1.0
  Ge  Ge1  1  0.198  0.685  0.934  1.0
  Ge  Ge2  1  0.685  0.198  0.934  1.0
  Ge  Ge3  1  0.617  0.617  0.126  1.0
  Ge  Ge4  1  0.124  0.124  0.627  1.0
  Ge  Ge5  1  0.943  0.943  0.190  1.0
  Ge  Ge6  1  0.190  0.190  0.939  1.0
  Ge  Ge7  1  0.436  0.436  0.689  1.0
  Ge  Ge8  1  0.687  0.687  0.435  1.0
  Ge  Ge9  1  0.251  0.251  0.250  1.0
  Ge  Ge10  1  0.188  0.687  0.438  1.0
  N  N11  1  0.789  0.324  0.562  1.0
  N  N12  1  0.324  0.324  0.562  1.0
  N  N13  1  0.057  0.057  0.826  1.0
  N  N14  1  0.555  0.555  0.327  1.0
  N  N15  1  0.824  0.288  0.056  1.0
  N  N16  1  0.288  0.824  0.056  1.0
  N  N17  1  0.050  0.584  0.314  1.0
  N  N18  1  0.324  0.789  0.562  1.0
  N  N19  1  0.584  0.050  0.314  1.0
  N  N20  1  0.052  0.052  0.316  1.0
  N  N21  1  0.316  0.316  0.052  1.0
  O  O22  1  0.540  0.102  0.823  1.0
  O  O23  1  0.826  0.826  0.053  1.0
  O  O24  1  0.541  0.541  0.820  1.0
  O  O25  1  0.822  0.822  0.534  1.0
  O  O26  1  0.102  0.540  0.823  1.0
[/CIF]
.
The compound described by Ge11N11O5 is beta indium sulfide-derived structured and crystallizes in the monoclinic Cm space group. There are nine inequivalent Ge sites. In the first Ge site, Ge(1) is bonded to one N(1), one N(2), one N(4), one N(6), one N(7), and one O(4) atom to form GeN5O octahedra that share  a cornercorner with one Ge(3)N3O tetrahedra, corners with two equivalent Ge(4)N4 tetrahedra, corners with two equivalent Ge(9)N4 tetrahedra,  an edgeedge with one Ge(7)N3O3 octahedra,  an edgeedge with one Ge(5)N5O octahedra, edges with two equivalent Ge(1)N5O octahedra, and edges with two equivalent Ge(8)N5O octahedra. In the second Ge site, Ge(2) is bonded to one N(3), one N(5), one N(8), one O(1), one O(2), and one O(3) atom to form GeN3O3 octahedra that share  a cornercorner with one Ge(4)N4 tetrahedra,  a cornercorner with one Ge(9)N4 tetrahedra, corners with two equivalent Ge(3)N3O tetrahedra,  an edgeedge with one Ge(7)N3O3 octahedra,  an edgeedge with one Ge(5)N5O octahedra, edges with two equivalent Ge(2)N3O3 octahedra, and edges with two equivalent Ge(6)N4O2 octahedra. In the third Ge site, Ge(3) is bonded to one N(4), two equivalent N(5), and one O(2) atom to form GeN3O tetrahedra that share  a cornercorner with one Ge(8)N5O octahedra, corners with two equivalent Ge(6)N4O2 octahedra, corners with two equivalent Ge(1)N5O octahedra, corners with three equivalent Ge(5)N5O octahedra, and corners with four equivalent Ge(2)N3O3 octahedra. The corner-sharing octahedral tilt angles range from 56-61°. In the fourth Ge site, Ge(4) is bonded to one N(2), one N(3), and two equivalent N(1) atoms to form GeN4 tetrahedra that share  a cornercorner with one Ge(6)N4O2 octahedra, corners with two equivalent Ge(2)N3O3 octahedra, corners with two equivalent Ge(8)N5O octahedra, corners with three equivalent Ge(7)N3O3 octahedra, and corners with four equivalent Ge(1)N5O octahedra. The corner-sharing octahedral tilt angles range from 56-59°. In the fifth Ge site, Ge(5) is bonded to one N(7), two equivalent N(5), two equivalent N(6), and one O(2) atom to form GeN5O octahedra that share corners with three equivalent Ge(3)N3O tetrahedra, corners with three equivalent Ge(9)N4 tetrahedra,  an edgeedge with one Ge(6)N4O2 octahedra,  an edgeedge with one Ge(8)N5O octahedra, edges with two equivalent Ge(2)N3O3 octahedra, and edges with two equivalent Ge(1)N5O octahedra. In the sixth Ge site, Ge(6) is bonded to one N(3), one N(8), two equivalent N(5), and two equivalent O(1) atoms to form GeN4O2 octahedra that share  a cornercorner with one Ge(4)N4 tetrahedra,  a cornercorner with one Ge(9)N4 tetrahedra, corners with two equivalent Ge(3)N3O tetrahedra,  an edgeedge with one Ge(7)N3O3 octahedra,  an edgeedge with one Ge(5)N5O octahedra, and edges with four equivalent Ge(2)N3O3 octahedra. In the seventh Ge site, Ge(7) is bonded to one N(2), two equivalent N(1), one O(3), and two equivalent O(1) atoms to form GeN3O3 octahedra that share corners with three equivalent Ge(4)N4 tetrahedra,  an edgeedge with one Ge(6)N4O2 octahedra,  an edgeedge with one Ge(8)N5O octahedra, edges with two equivalent Ge(2)N3O3 octahedra, and edges with two equivalent Ge(1)N5O octahedra. In the eighth Ge site, Ge(8) is bonded to one N(4), two equivalent N(1), two equivalent N(6), and one O(4) atom to form GeN5O octahedra that share  a cornercorner with one Ge(3)N3O tetrahedra, corners with two equivalent Ge(4)N4 tetrahedra, corners with two equivalent Ge(9)N4 tetrahedra,  an edgeedge with one Ge(7)N3O3 octahedra,  an edgeedge with one Ge(5)N5O octahedra, and edges with four equivalent Ge(1)N5O octahedra. In the ninth Ge site, Ge(9) is bonded to one N(7), one N(8), and two equivalent N(6) atoms to form GeN4 tetrahedra that share  a cornercorner with one Ge(6)N4O2 octahedra, corners with two equivalent Ge(2)N3O3 octahedra, corners with two equivalent Ge(8)N5O octahedra, corners with three equivalent Ge(5)N5O octahedra, and corners with four equivalent Ge(1)N5O octahedra. The corner-sharing octahedral tilt angles range from 55-58°. There are eight inequivalent N sites. In the first N site, N(1) is bonded in a distorted rectangular see-saw-like geometry to one Ge(1), one Ge(4), one Ge(7), and one Ge(8) atom. In the second N site, N(2) is bonded in a distorted rectangular see-saw-like geometry to one Ge(4), one Ge(7), and two equivalent Ge(1) atoms. In the third N site, N(3) is bonded to one Ge(4), one Ge(6), and two equivalent Ge(2) atoms to form distorted edge-sharing NGe4 trigonal pyramids. In the fourth N site, N(4) is bonded to one Ge(3), one Ge(8), and two equivalent Ge(1) atoms to form distorted corner-sharing NGe4 trigonal pyramids. In the fifth N site, N(5) is bonded to one Ge(2), one Ge(3), one Ge(5), and one Ge(6) atom to form a mixture of distorted corner and edge-sharing NGe4 trigonal pyramids. In the sixth N site, N(6) is bonded in a rectangular see-saw-like geometry to one Ge(1), one Ge(5), one Ge(8), and one Ge(9) atom. In the seventh N site, N(7) is bonded in a distorted rectangular see-saw-like geometry to one Ge(5), one Ge(9), and two equivalent Ge(1) atoms. In the eighth N site, N(8) is bonded in a distorted rectangular see-saw-like geometry to one Ge(6), one Ge(9), and two equivalent Ge(2) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to one Ge(2), one Ge(6), and one Ge(7) atom. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to one Ge(3), one Ge(5), and two equivalent Ge(2) atoms. In the third O site, O(3) is bonded in a distorted T-shaped geometry to one Ge(7) and two equivalent Ge(2) atoms. In the fourth O site, O(4) is bonded in a distorted trigonal non-coplanar geometry to one Ge(8) and two equivalent Ge(1) atoms. is represented by the CIF file [CIF]
data_Ge11N11O5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.915
_cell_length_b   5.915
_cell_length_c   10.224
_cell_angle_alpha   73.188
_cell_angle_beta   73.188
_cell_angle_gamma   59.712
_symmetry_Int_Tables_number   1
_cell_volume   291.220
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ge  Ge0  1  0.687  0.188  0.438  1.0
  Ge  Ge1  1  0.198  0.685  0.934  1.0
  Ge  Ge2  1  0.685  0.198  0.934  1.0
  Ge  Ge3  1  0.617  0.617  0.126  1.0
  Ge  Ge4  1  0.124  0.124  0.627  1.0
  Ge  Ge5  1  0.943  0.943  0.190  1.0
  Ge  Ge6  1  0.190  0.190  0.939  1.0
  Ge  Ge7  1  0.436  0.436  0.689  1.0
  Ge  Ge8  1  0.687  0.687  0.435  1.0
  Ge  Ge9  1  0.251  0.251  0.250  1.0
  Ge  Ge10  1  0.188  0.687  0.438  1.0
  N  N11  1  0.789  0.324  0.562  1.0
  N  N12  1  0.324  0.324  0.562  1.0
  N  N13  1  0.057  0.057  0.826  1.0
  N  N14  1  0.555  0.555  0.327  1.0
  N  N15  1  0.824  0.288  0.056  1.0
  N  N16  1  0.288  0.824  0.056  1.0
  N  N17  1  0.050  0.584  0.314  1.0
  N  N18  1  0.324  0.789  0.562  1.0
  N  N19  1  0.584  0.050  0.314  1.0
  N  N20  1  0.052  0.052  0.316  1.0
  N  N21  1  0.316  0.316  0.052  1.0
  O  O22  1  0.540  0.102  0.823  1.0
  O  O23  1  0.826  0.826  0.053  1.0
  O  O24  1  0.541  0.541  0.820  1.0
  O  O25  1  0.822  0.822  0.534  1.0
  O  O26  1  0.102  0.540  0.823  1.0
[/CIF]
.