The compound described by V2Cu3Pb(O4Cl)2 crystallizes in the orthorhombic Ibam space group. V(1) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent O(2) atoms. There are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a square co-planar geometry to four equivalent O(2) atoms. In the second Cu site, Cu(2) is bonded in a trigonal planar geometry to two equivalent O(1) and one Cl(1) atom. Pb(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent Cl(1) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one V(1), one Cu(2), and one Pb(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one V(1) and one Cu(1) atom. Cl(1) is bonded in a distorted single-bond geometry to one Cu(2) and two equivalent Pb(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_V2Cu3Pb(ClO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.837
_cell_length_b   8.837
_cell_length_c   8.837
_cell_angle_alpha   113.350
_cell_angle_beta   109.712
_cell_angle_gamma   105.448
_symmetry_Int_Tables_number   1
_cell_volume   528.698
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.812  0.062  0.250  1.0
  V  V1  1  0.812  0.562  0.750  1.0
  V  V2  1  0.188  0.938  0.750  1.0
  V  V3  1  0.188  0.438  0.250  1.0
  Cu  Cu4  1  0.000  0.000  0.000  1.0
  Cu  Cu5  1  0.444  0.743  0.700  1.0
  Cu  Cu6  1  0.556  0.257  0.300  1.0
  Cu  Cu7  1  0.957  0.757  0.200  1.0
  Cu  Cu8  1  0.000  0.500  0.500  1.0
  Cu  Cu9  1  0.043  0.243  0.800  1.0
  Pb  Pb10  1  0.500  0.750  0.250  1.0
  Pb  Pb11  1  0.500  0.250  0.750  1.0
  Cl  Cl12  1  0.743  0.082  0.661  1.0
  Cl  Cl13  1  0.420  0.582  0.839  1.0
  Cl  Cl14  1  0.257  0.918  0.339  1.0
  Cl  Cl15  1  0.580  0.418  0.161  1.0
  O  O16  1  0.396  0.625  0.445  1.0
  O  O17  1  0.818  0.038  0.046  1.0
  O  O18  1  0.818  0.772  0.780  1.0
  O  O19  1  0.604  0.375  0.555  1.0
  O  O20  1  0.180  0.451  0.055  1.0
  O  O21  1  0.182  0.962  0.954  1.0
  O  O22  1  0.604  0.049  0.229  1.0
  O  O23  1  0.992  0.538  0.720  1.0
  O  O24  1  0.180  0.125  0.729  1.0
  O  O25  1  0.008  0.728  0.546  1.0
  O  O26  1  0.820  0.549  0.945  1.0
  O  O27  1  0.820  0.875  0.271  1.0
  O  O28  1  0.992  0.272  0.454  1.0
  O  O29  1  0.396  0.951  0.771  1.0
  O  O30  1  0.182  0.228  0.220  1.0
  O  O31  1  0.008  0.462  0.280  1.0
[/CIF]
.
The compound described by V2Cu3Pb(O4Cl)2 crystallizes in the orthorhombic Ibam space group. V(1) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent O(2) atoms. There are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a square co-planar geometry to four equivalent O(2) atoms. In the second Cu site, Cu(2) is bonded in a trigonal planar geometry to two equivalent O(1) and one Cl(1) atom. Pb(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent Cl(1) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one V(1), one Cu(2), and one Pb(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one V(1) and one Cu(1) atom. Cl(1) is bonded in a distorted single-bond geometry to one Cu(2) and two equivalent Pb(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_V2Cu3Pb(ClO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.837
_cell_length_b   8.837
_cell_length_c   8.837
_cell_angle_alpha   113.350
_cell_angle_beta   109.712
_cell_angle_gamma   105.448
_symmetry_Int_Tables_number   1
_cell_volume   528.698
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.812  0.062  0.250  1.0
  V  V1  1  0.812  0.562  0.750  1.0
  V  V2  1  0.188  0.938  0.750  1.0
  V  V3  1  0.188  0.438  0.250  1.0
  Cu  Cu4  1  0.000  0.000  0.000  1.0
  Cu  Cu5  1  0.444  0.743  0.700  1.0
  Cu  Cu6  1  0.556  0.257  0.300  1.0
  Cu  Cu7  1  0.957  0.757  0.200  1.0
  Cu  Cu8  1  0.000  0.500  0.500  1.0
  Cu  Cu9  1  0.043  0.243  0.800  1.0
  Pb  Pb10  1  0.500  0.750  0.250  1.0
  Pb  Pb11  1  0.500  0.250  0.750  1.0
  Cl  Cl12  1  0.743  0.082  0.661  1.0
  Cl  Cl13  1  0.420  0.582  0.839  1.0
  Cl  Cl14  1  0.257  0.918  0.339  1.0
  Cl  Cl15  1  0.580  0.418  0.161  1.0
  O  O16  1  0.396  0.625  0.445  1.0
  O  O17  1  0.818  0.038  0.046  1.0
  O  O18  1  0.818  0.772  0.780  1.0
  O  O19  1  0.604  0.375  0.555  1.0
  O  O20  1  0.180  0.451  0.055  1.0
  O  O21  1  0.182  0.962  0.954  1.0
  O  O22  1  0.604  0.049  0.229  1.0
  O  O23  1  0.992  0.538  0.720  1.0
  O  O24  1  0.180  0.125  0.729  1.0
  O  O25  1  0.008  0.728  0.546  1.0
  O  O26  1  0.820  0.549  0.945  1.0
  O  O27  1  0.820  0.875  0.271  1.0
  O  O28  1  0.992  0.272  0.454  1.0
  O  O29  1  0.396  0.951  0.771  1.0
  O  O30  1  0.182  0.228  0.220  1.0
  O  O31  1  0.008  0.462  0.280  1.0
[/CIF]
.