The crystal structure described by KPtC2PN2H12(O2Cl)2 crystallizes in the triclinic P-1 space group. K(1) is bonded in a 11-coordinate geometry to one H(10), one H(12), one H(7), one O(1), one O(2), one O(3), two equivalent O(4), one Cl(1), and two equivalent Cl(2) atoms. Pt(1) is bonded in a square co-planar geometry to one N(1), one N(2), one Cl(1), and one Cl(2) atom. There are two inequivalent C sites. In the first C site, C(1) is bonded to one P(1), one N(1), one H(1), and one H(2) atom to form distorted corner-sharing CPH2N tetrahedra. In the second C site, C(2) is bonded to one P(1), one N(2), one H(3), and one H(4) atom to form distorted corner-sharing CPH2N tetrahedra. P(1) is bonded in a distorted tetrahedral geometry to one C(1), one C(2), one O(1), and one O(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 4-coordinate geometry to one Pt(1), one C(1), one H(5), and one H(6) atom. In the second N site, N(2) is bonded in a 4-coordinate geometry to one Pt(1), one C(2), one H(8), and one H(9) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(1) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(1) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one K(1) and one O(4) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one N(2) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one N(2) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one K(1) and one O(3) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one O(3) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one K(1) and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one K(1) and one P(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one K(1) and one P(1) atom. In the third O site, O(3) is bonded in a water-like geometry to one K(1), one H(10), and one H(11) atom. In the fourth O site, O(4) is bonded in a water-like geometry to two equivalent K(1), one H(12), and one H(7) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a water-like geometry to one K(1) and one Pt(1) atom. In the second Cl site, Cl(2) is bonded in a distorted trigonal non-coplanar geometry to two equivalent K(1) and one Pt(1) atom. is represented by the CIF file [CIF]
data_KPH12PtC2N2(ClO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.270
_cell_length_b   8.880
_cell_length_c   8.955
_cell_angle_alpha   86.011
_cell_angle_beta   69.652
_cell_angle_gamma   85.817
_symmetry_Int_Tables_number   1
_cell_volume   614.254
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.423  0.218  0.580  1.0
  K  K1  1  0.577  0.782  0.420  1.0
  P  P2  1  0.182  0.782  0.268  1.0
  P  P3  1  0.818  0.218  0.732  1.0
  H  H4  1  0.206  0.545  0.407  1.0
  H  H5  1  0.794  0.455  0.593  1.0
  H  H6  1  0.381  0.563  0.223  1.0
  H  H7  1  0.619  0.437  0.777  1.0
  H  H8  1  0.402  0.804  0.006  1.0
  H  H9  1  0.598  0.196  0.994  1.0
  H  H10  1  0.240  0.954  0.039  1.0
  H  H11  1  0.760  0.046  0.961  1.0
  H  H12  1  0.023  0.501  0.249  1.0
  H  H13  1  0.977  0.499  0.751  1.0
  H  H14  1  0.185  0.373  0.225  1.0
  H  H15  1  0.815  0.627  0.775  1.0
  H  H16  1  0.139  0.026  0.680  1.0
  H  H17  1  0.861  0.974  0.320  1.0
  H  H18  1  0.043  0.766  0.017  1.0
  H  H19  1  0.957  0.234  0.983  1.0
  H  H20  1  0.207  0.795  0.850  1.0
  H  H21  1  0.793  0.205  0.150  1.0
  H  H22  1  0.143  0.196  0.472  1.0
  H  H23  1  0.857  0.804  0.528  1.0
  H  H24  1  0.258  0.091  0.338  1.0
  H  H25  1  0.742  0.909  0.662  1.0
  H  H26  1  0.228  0.901  0.561  1.0
  H  H27  1  0.772  0.099  0.439  1.0
  Pt  Pt28  1  0.222  0.516  0.956  1.0
  Pt  Pt29  1  0.778  0.484  0.044  1.0
  C  C30  1  0.241  0.580  0.280  1.0
  C  C31  1  0.759  0.420  0.720  1.0
  C  C32  1  0.263  0.831  0.054  1.0
  C  C33  1  0.737  0.169  0.946  1.0
  N  N34  1  0.156  0.485  0.201  1.0
  N  N35  1  0.844  0.515  0.799  1.0
  N  N36  1  0.175  0.749  0.966  1.0
  N  N37  1  0.825  0.251  0.034  1.0
  Cl  Cl38  1  0.267  0.254  0.948  1.0
  Cl  Cl39  1  0.733  0.746  0.052  1.0
  Cl  Cl40  1  0.294  0.549  0.679  1.0
  Cl  Cl41  1  0.706  0.451  0.321  1.0
  O  O42  1  0.280  0.866  0.349  1.0
  O  O43  1  0.720  0.134  0.651  1.0
  O  O44  1  0.985  0.804  0.327  1.0
  O  O45  1  0.015  0.196  0.673  1.0
  O  O46  1  0.240  0.198  0.369  1.0
  O  O47  1  0.760  0.802  0.631  1.0
  O  O48  1  0.230  0.943  0.660  1.0
  O  O49  1  0.770  0.057  0.340  1.0
[/CIF]
.
The crystal structure described by KPtC2PN2H12(O2Cl)2 crystallizes in the triclinic P-1 space group. K(1) is bonded in a 11-coordinate geometry to one H(10), one H(12), one H(7), one O(1), one O(2), one O(3), two equivalent O(4), one Cl(1), and two equivalent Cl(2) atoms. Pt(1) is bonded in a square co-planar geometry to one N(1), one N(2), one Cl(1), and one Cl(2) atom. There are two inequivalent C sites. In the first C site, C(1) is bonded to one P(1), one N(1), one H(1), and one H(2) atom to form distorted corner-sharing CPH2N tetrahedra. In the second C site, C(2) is bonded to one P(1), one N(2), one H(3), and one H(4) atom to form distorted corner-sharing CPH2N tetrahedra. P(1) is bonded in a distorted tetrahedral geometry to one C(1), one C(2), one O(1), and one O(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 4-coordinate geometry to one Pt(1), one C(1), one H(5), and one H(6) atom. In the second N site, N(2) is bonded in a 4-coordinate geometry to one Pt(1), one C(2), one H(8), and one H(9) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(1) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(1) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one K(1) and one O(4) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one N(2) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one N(2) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one K(1) and one O(3) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one O(3) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one K(1) and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one K(1) and one P(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one K(1) and one P(1) atom. In the third O site, O(3) is bonded in a water-like geometry to one K(1), one H(10), and one H(11) atom. In the fourth O site, O(4) is bonded in a water-like geometry to two equivalent K(1), one H(12), and one H(7) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a water-like geometry to one K(1) and one Pt(1) atom. In the second Cl site, Cl(2) is bonded in a distorted trigonal non-coplanar geometry to two equivalent K(1) and one Pt(1) atom. is represented by the CIF file [CIF]
data_KPH12PtC2N2(ClO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.270
_cell_length_b   8.880
_cell_length_c   8.955
_cell_angle_alpha   86.011
_cell_angle_beta   69.652
_cell_angle_gamma   85.817
_symmetry_Int_Tables_number   1
_cell_volume   614.254
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.423  0.218  0.580  1.0
  K  K1  1  0.577  0.782  0.420  1.0
  P  P2  1  0.182  0.782  0.268  1.0
  P  P3  1  0.818  0.218  0.732  1.0
  H  H4  1  0.206  0.545  0.407  1.0
  H  H5  1  0.794  0.455  0.593  1.0
  H  H6  1  0.381  0.563  0.223  1.0
  H  H7  1  0.619  0.437  0.777  1.0
  H  H8  1  0.402  0.804  0.006  1.0
  H  H9  1  0.598  0.196  0.994  1.0
  H  H10  1  0.240  0.954  0.039  1.0
  H  H11  1  0.760  0.046  0.961  1.0
  H  H12  1  0.023  0.501  0.249  1.0
  H  H13  1  0.977  0.499  0.751  1.0
  H  H14  1  0.185  0.373  0.225  1.0
  H  H15  1  0.815  0.627  0.775  1.0
  H  H16  1  0.139  0.026  0.680  1.0
  H  H17  1  0.861  0.974  0.320  1.0
  H  H18  1  0.043  0.766  0.017  1.0
  H  H19  1  0.957  0.234  0.983  1.0
  H  H20  1  0.207  0.795  0.850  1.0
  H  H21  1  0.793  0.205  0.150  1.0
  H  H22  1  0.143  0.196  0.472  1.0
  H  H23  1  0.857  0.804  0.528  1.0
  H  H24  1  0.258  0.091  0.338  1.0
  H  H25  1  0.742  0.909  0.662  1.0
  H  H26  1  0.228  0.901  0.561  1.0
  H  H27  1  0.772  0.099  0.439  1.0
  Pt  Pt28  1  0.222  0.516  0.956  1.0
  Pt  Pt29  1  0.778  0.484  0.044  1.0
  C  C30  1  0.241  0.580  0.280  1.0
  C  C31  1  0.759  0.420  0.720  1.0
  C  C32  1  0.263  0.831  0.054  1.0
  C  C33  1  0.737  0.169  0.946  1.0
  N  N34  1  0.156  0.485  0.201  1.0
  N  N35  1  0.844  0.515  0.799  1.0
  N  N36  1  0.175  0.749  0.966  1.0
  N  N37  1  0.825  0.251  0.034  1.0
  Cl  Cl38  1  0.267  0.254  0.948  1.0
  Cl  Cl39  1  0.733  0.746  0.052  1.0
  Cl  Cl40  1  0.294  0.549  0.679  1.0
  Cl  Cl41  1  0.706  0.451  0.321  1.0
  O  O42  1  0.280  0.866  0.349  1.0
  O  O43  1  0.720  0.134  0.651  1.0
  O  O44  1  0.985  0.804  0.327  1.0
  O  O45  1  0.015  0.196  0.673  1.0
  O  O46  1  0.240  0.198  0.369  1.0
  O  O47  1  0.760  0.802  0.631  1.0
  O  O48  1  0.230  0.943  0.660  1.0
  O  O49  1  0.770  0.057  0.340  1.0
[/CIF]
.