The material described by CaMn9CdO10 crystallizes in the triclinic P1 space group. Ca(1) is bonded to one O(10), one O(2), one O(3), one O(4), one O(7), and one O(9) atom to form CaO6 octahedra that share  a cornercorner with one Mn(1)O5 trigonal bipyramid, corners with two equivalent Mn(6)O5 trigonal bipyramids, corners with two equivalent Mn(7)O5 trigonal bipyramids, corners with two equivalent Mn(8)O5 trigonal bipyramids,  an edgeedge with one Mn(5)O4 tetrahedra,  an edgeedge with one Mn(1)O5 trigonal bipyramid,  an edgeedge with one Mn(7)O5 trigonal bipyramid, and  an edgeedge with one Mn(8)O5 trigonal bipyramid. There are nine inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(10), one O(3), one O(5), one O(8), and one O(9) atom to form distorted MnO5 trigonal bipyramids that share  a cornercorner with one Ca(1)O6 octahedra, corners with two equivalent Mn(5)O4 tetrahedra,  a cornercorner with one Mn(6)O5 trigonal bipyramid,  a cornercorner with one Mn(7)O5 trigonal bipyramid,  a cornercorner with one Mn(8)O5 trigonal bipyramid,  an edgeedge with one Ca(1)O6 octahedra,  an edgeedge with one Mn(6)O5 trigonal bipyramid, and  an edgeedge with one Mn(8)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles are 69°. In the second Mn site, Mn(2) is bonded in a distorted see-saw-like geometry to one O(1), one O(3), one O(5), and one O(6) atom. In the third Mn site, Mn(3) is bonded in a see-saw-like geometry to one O(5), one O(6), one O(7), and one O(8) atom. In the fourth Mn site, Mn(4) is bonded in a 4-coordinate geometry to one O(10), one O(6), one O(7), and one O(9) atom. In the fifth Mn site, Mn(5) is bonded to one O(1), one O(2), one O(3), and one O(8) atom to form MnO4 tetrahedra that share  a cornercorner with one Mn(6)O5 trigonal bipyramid,  a cornercorner with one Mn(7)O5 trigonal bipyramid, corners with two equivalent Mn(1)O5 trigonal bipyramids, corners with two equivalent Mn(8)O5 trigonal bipyramids,  an edgeedge with one Ca(1)O6 octahedra, and  an edgeedge with one Mn(6)O5 trigonal bipyramid. In the sixth Mn site, Mn(6) is bonded to one O(1), one O(2), one O(5), one O(8), and one O(9) atom to form MnO5 trigonal bipyramids that share corners with two equivalent Ca(1)O6 octahedra,  a cornercorner with one Mn(5)O4 tetrahedra,  a cornercorner with one Mn(1)O5 trigonal bipyramid, corners with two equivalent Mn(8)O5 trigonal bipyramids,  an edgeedge with one Mn(5)O4 tetrahedra,  an edgeedge with one Mn(1)O5 trigonal bipyramid, and  an edgeedge with one Mn(7)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles are 65°. In the seventh Mn site, Mn(7) is bonded to one O(2), one O(4), one O(6), one O(7), and one O(9) atom to form distorted MnO5 trigonal bipyramids that share corners with two equivalent Ca(1)O6 octahedra,  a cornercorner with one Mn(5)O4 tetrahedra,  a cornercorner with one Mn(1)O5 trigonal bipyramid,  an edgeedge with one Ca(1)O6 octahedra,  an edgeedge with one Mn(6)O5 trigonal bipyramid, and  an edgeedge with one Mn(8)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 45-51°. In the eighth Mn site, Mn(8) is bonded to one O(10), one O(2), one O(3), one O(4), and one O(5) atom to form distorted MnO5 trigonal bipyramids that share corners with two equivalent Ca(1)O6 octahedra, corners with two equivalent Mn(5)O4 tetrahedra,  a cornercorner with one Mn(1)O5 trigonal bipyramid, corners with two equivalent Mn(6)O5 trigonal bipyramids,  an edgeedge with one Ca(1)O6 octahedra,  an edgeedge with one Mn(1)O5 trigonal bipyramid, and  an edgeedge with one Mn(7)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 43-53°. In the ninth Mn site, Mn(9) is bonded in a distorted see-saw-like geometry to one O(1), one O(10), one O(4), and one O(6) atom. Cd(1) is bonded in a 3-coordinate geometry to one O(1), one O(4), and one O(8) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded to one Mn(2), one Mn(5), one Mn(6), one Mn(9), and one Cd(1) atom to form distorted OMn4Cd square pyramids that share  a cornercorner with one O(10)CaMn4 trigonal bipyramid,  a cornercorner with one O(9)CaMn4 trigonal bipyramid,  a cornercorner with one O(8)Mn4Cd trigonal bipyramid, corners with two equivalent O(3)CaMn4 trigonal bipyramids, corners with two equivalent O(5)Mn5 trigonal bipyramids,  an edgeedge with one O(4)CaMn3Cd trigonal bipyramid,  an edgeedge with one O(2)CaMn4 trigonal bipyramid,  an edgeedge with one O(8)Mn4Cd trigonal bipyramid, and  an edgeedge with one O(6)Mn5 trigonal bipyramid. In the second O site, O(2) is bonded to one Ca(1), one Mn(5), one Mn(6), one Mn(7), and one Mn(8) atom to form OCaMn4 trigonal bipyramids that share  a cornercorner with one O(4)CaMn3Cd trigonal bipyramid,  a cornercorner with one O(3)CaMn4 trigonal bipyramid,  a cornercorner with one O(9)CaMn4 trigonal bipyramid,  a cornercorner with one O(6)Mn5 trigonal bipyramid, corners with two equivalent O(10)CaMn4 trigonal bipyramids, corners with two equivalent O(8)Mn4Cd trigonal bipyramids, corners with two equivalent O(5)Mn5 trigonal bipyramids,  an edgeedge with one O(1)Mn4Cd square pyramid,  an edgeedge with one O(4)CaMn3Cd trigonal bipyramid,  an edgeedge with one O(3)CaMn4 trigonal bipyramid, and  an edgeedge with one O(9)CaMn4 trigonal bipyramid. In the third O site, O(3) is bonded to one Ca(1), one Mn(1), one Mn(2), one Mn(5), and one Mn(8) atom to form distorted OCaMn4 trigonal bipyramids that share corners with two equivalent O(1)Mn4Cd square pyramids,  a cornercorner with one O(10)CaMn4 trigonal bipyramid,  a cornercorner with one O(2)CaMn4 trigonal bipyramid,  a cornercorner with one O(5)Mn5 trigonal bipyramid,  a cornercorner with one O(6)Mn5 trigonal bipyramid, corners with two equivalent O(9)CaMn4 trigonal bipyramids, corners with two equivalent O(8)Mn4Cd trigonal bipyramids,  an edgeedge with one O(4)CaMn3Cd trigonal bipyramid,  an edgeedge with one O(10)CaMn4 trigonal bipyramid,  an edgeedge with one O(2)CaMn4 trigonal bipyramid, and  an edgeedge with one O(5)Mn5 trigonal bipyramid. In the fourth O site, O(4) is bonded to one Ca(1), one Mn(7), one Mn(8), one Mn(9), and one Cd(1) atom to form OCaMn3Cd trigonal bipyramids that share  a cornercorner with one O(10)CaMn4 trigonal bipyramid,  a cornercorner with one O(2)CaMn4 trigonal bipyramid,  a cornercorner with one O(8)Mn4Cd trigonal bipyramid,  a cornercorner with one O(5)Mn5 trigonal bipyramid, corners with two equivalent O(9)CaMn4 trigonal bipyramids, corners with two equivalent O(6)Mn5 trigonal bipyramids,  an edgeedge with one O(1)Mn4Cd square pyramid,  an edgeedge with one O(10)CaMn4 trigonal bipyramid,  an edgeedge with one O(2)CaMn4 trigonal bipyramid, and  an edgeedge with one O(3)CaMn4 trigonal bipyramid. In the fifth O site, O(5) is bonded to one Mn(1), one Mn(2), one Mn(3), one Mn(6), and one Mn(8) atom to form distorted OMn5 trigonal bipyramids that share corners with two equivalent O(1)Mn4Cd square pyramids,  a cornercorner with one O(4)CaMn3Cd trigonal bipyramid,  a cornercorner with one O(3)CaMn4 trigonal bipyramid,  a cornercorner with one O(8)Mn4Cd trigonal bipyramid, corners with two equivalent O(2)CaMn4 trigonal bipyramids, corners with two equivalent O(9)CaMn4 trigonal bipyramids,  an edgeedge with one O(10)CaMn4 trigonal bipyramid,  an edgeedge with one O(3)CaMn4 trigonal bipyramid,  an edgeedge with one O(8)Mn4Cd trigonal bipyramid, and  an edgeedge with one O(6)Mn5 trigonal bipyramid. In the sixth O site, O(6) is bonded to one Mn(2), one Mn(3), one Mn(4), one Mn(7), and one Mn(9) atom to form distorted OMn5 trigonal bipyramids that share  a cornercorner with one O(2)CaMn4 trigonal bipyramid,  a cornercorner with one O(3)CaMn4 trigonal bipyramid,  a cornercorner with one O(8)Mn4Cd trigonal bipyramid, corners with two equivalent O(4)CaMn3Cd trigonal bipyramids, corners with two equivalent O(10)CaMn4 trigonal bipyramids,  an edgeedge with one O(1)Mn4Cd square pyramid,  an edgeedge with one O(9)CaMn4 trigonal bipyramid, and  an edgeedge with one O(5)Mn5 trigonal bipyramid. In the seventh O site, O(7) is bonded in a distorted see-saw-like geometry to one Ca(1), one Mn(3), one Mn(4), and one Mn(7) atom. In the eighth O site, O(8) is bonded to one Mn(1), one Mn(3), one Mn(5), one Mn(6), and one Cd(1) atom to form OMn4Cd trigonal bipyramids that share  a cornercorner with one O(1)Mn4Cd square pyramid,  a cornercorner with one O(4)CaMn3Cd trigonal bipyramid,  a cornercorner with one O(10)CaMn4 trigonal bipyramid,  a cornercorner with one O(5)Mn5 trigonal bipyramid,  a cornercorner with one O(6)Mn5 trigonal bipyramid, corners with two equivalent O(2)CaMn4 trigonal bipyramids, corners with two equivalent O(3)CaMn4 trigonal bipyramids,  an edgeedge with one O(1)Mn4Cd square pyramid,  an edgeedge with one O(9)CaMn4 trigonal bipyramid, and  an edgeedge with one O(5)Mn5 trigonal bipyramid. In the ninth O site, O(9) is bonded to one Ca(1), one Mn(1), one Mn(4), one Mn(6), and one Mn(7) atom to form distorted OCaMn4 trigonal bipyramids that share  a cornercorner with one O(1)Mn4Cd square pyramid,  a cornercorner with one O(10)CaMn4 trigonal bipyramid,  a cornercorner with one O(2)CaMn4 trigonal bipyramid, corners with two equivalent O(4)CaMn3Cd trigonal bipyramids, corners with two equivalent O(3)CaMn4 trigonal bipyramids, corners with two equivalent O(5)Mn5 trigonal bipyramids,  an edgeedge with one O(10)CaMn4 trigonal bipyramid,  an edgeedge with one O(2)CaMn4 trigonal bipyramid,  an edgeedge with one O(8)Mn4Cd trigonal bipyramid, and  an edgeedge with one O(6)Mn5 trigonal bipyramid. In the tenth O site, O(10) is bonded to one Ca(1), one Mn(1), one Mn(4), one Mn(8), and one Mn(9) atom to form OCaMn4 trigonal bipyramids that share  a cornercorner with one O(1)Mn4Cd square pyramid,  a cornercorner with one O(4)CaMn3Cd trigonal bipyramid,  a cornercorner with one O(3)CaMn4 trigonal bipyramid,  a cornercorner with one O(9)CaMn4 trigonal bipyramid,  a cornercorner with one O(8)Mn4Cd trigonal bipyramid, corners with two equivalent O(2)CaMn4 trigonal bipyramids, corners with two equivalent O(6)Mn5 trigonal bipyramids,  an edgeedge with one O(4)CaMn3Cd trigonal bipyramid,  an edgeedge with one O(3)CaMn4 trigonal bipyramid,  an edgeedge with one O(9)CaMn4 trigonal bipyramid, and  an edgeedge with one O(5)Mn5 trigonal bipyramid. is represented by the CIF card [CIF]
data_CaMn9CdO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.286
_cell_length_b   9.314
_cell_length_c   6.564
_cell_angle_alpha   64.001
_cell_angle_beta   121.301
_cell_angle_gamma   92.072
_symmetry_Int_Tables_number   1
_cell_volume   285.834
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ca  Ca0  1  0.731  0.512  0.232  1.0
  Mn  Mn1  1  0.387  0.322  0.378  1.0
  Mn  Mn2  1  0.958  0.044  0.012  1.0
  Mn  Mn3  1  0.475  0.960  0.524  1.0
  Mn  Mn4  1  0.105  0.680  0.110  1.0
  Mn  Mn5  1  0.951  0.144  0.447  1.0
  Mn  Mn6  1  0.455  0.235  0.904  1.0
  Mn  Mn7  1  0.519  0.598  0.654  1.0
  Mn  Mn8  1  0.983  0.393  0.842  1.0
  Mn  Mn9  1  0.018  0.760  0.574  1.0
  Cd  Cd10  1  0.420  0.879  0.026  1.0
  O  O11  1  0.775  0.007  0.241  1.0
  O  O12  1  0.763  0.361  0.029  1.0
  O  O13  1  0.801  0.245  0.603  1.0
  O  O14  1  0.744  0.620  0.489  1.0
  O  O15  1  0.278  0.173  0.131  1.0
  O  O16  1  0.209  0.816  0.367  1.0
  O  O17  1  0.709  0.740  0.875  1.0
  O  O18  1  0.355  0.112  0.643  1.0
  O  O19  1  0.235  0.462  0.493  1.0
  O  O20  1  0.258  0.539  0.997  1.0
[/CIF]
.
The material described by CaMn9CdO10 crystallizes in the triclinic P1 space group. Ca(1) is bonded to one O(10), one O(2), one O(3), one O(4), one O(7), and one O(9) atom to form CaO6 octahedra that share  a cornercorner with one Mn(1)O5 trigonal bipyramid, corners with two equivalent Mn(6)O5 trigonal bipyramids, corners with two equivalent Mn(7)O5 trigonal bipyramids, corners with two equivalent Mn(8)O5 trigonal bipyramids,  an edgeedge with one Mn(5)O4 tetrahedra,  an edgeedge with one Mn(1)O5 trigonal bipyramid,  an edgeedge with one Mn(7)O5 trigonal bipyramid, and  an edgeedge with one Mn(8)O5 trigonal bipyramid. There are nine inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(10), one O(3), one O(5), one O(8), and one O(9) atom to form distorted MnO5 trigonal bipyramids that share  a cornercorner with one Ca(1)O6 octahedra, corners with two equivalent Mn(5)O4 tetrahedra,  a cornercorner with one Mn(6)O5 trigonal bipyramid,  a cornercorner with one Mn(7)O5 trigonal bipyramid,  a cornercorner with one Mn(8)O5 trigonal bipyramid,  an edgeedge with one Ca(1)O6 octahedra,  an edgeedge with one Mn(6)O5 trigonal bipyramid, and  an edgeedge with one Mn(8)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles are 69°. In the second Mn site, Mn(2) is bonded in a distorted see-saw-like geometry to one O(1), one O(3), one O(5), and one O(6) atom. In the third Mn site, Mn(3) is bonded in a see-saw-like geometry to one O(5), one O(6), one O(7), and one O(8) atom. In the fourth Mn site, Mn(4) is bonded in a 4-coordinate geometry to one O(10), one O(6), one O(7), and one O(9) atom. In the fifth Mn site, Mn(5) is bonded to one O(1), one O(2), one O(3), and one O(8) atom to form MnO4 tetrahedra that share  a cornercorner with one Mn(6)O5 trigonal bipyramid,  a cornercorner with one Mn(7)O5 trigonal bipyramid, corners with two equivalent Mn(1)O5 trigonal bipyramids, corners with two equivalent Mn(8)O5 trigonal bipyramids,  an edgeedge with one Ca(1)O6 octahedra, and  an edgeedge with one Mn(6)O5 trigonal bipyramid. In the sixth Mn site, Mn(6) is bonded to one O(1), one O(2), one O(5), one O(8), and one O(9) atom to form MnO5 trigonal bipyramids that share corners with two equivalent Ca(1)O6 octahedra,  a cornercorner with one Mn(5)O4 tetrahedra,  a cornercorner with one Mn(1)O5 trigonal bipyramid, corners with two equivalent Mn(8)O5 trigonal bipyramids,  an edgeedge with one Mn(5)O4 tetrahedra,  an edgeedge with one Mn(1)O5 trigonal bipyramid, and  an edgeedge with one Mn(7)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles are 65°. In the seventh Mn site, Mn(7) is bonded to one O(2), one O(4), one O(6), one O(7), and one O(9) atom to form distorted MnO5 trigonal bipyramids that share corners with two equivalent Ca(1)O6 octahedra,  a cornercorner with one Mn(5)O4 tetrahedra,  a cornercorner with one Mn(1)O5 trigonal bipyramid,  an edgeedge with one Ca(1)O6 octahedra,  an edgeedge with one Mn(6)O5 trigonal bipyramid, and  an edgeedge with one Mn(8)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 45-51°. In the eighth Mn site, Mn(8) is bonded to one O(10), one O(2), one O(3), one O(4), and one O(5) atom to form distorted MnO5 trigonal bipyramids that share corners with two equivalent Ca(1)O6 octahedra, corners with two equivalent Mn(5)O4 tetrahedra,  a cornercorner with one Mn(1)O5 trigonal bipyramid, corners with two equivalent Mn(6)O5 trigonal bipyramids,  an edgeedge with one Ca(1)O6 octahedra,  an edgeedge with one Mn(1)O5 trigonal bipyramid, and  an edgeedge with one Mn(7)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 43-53°. In the ninth Mn site, Mn(9) is bonded in a distorted see-saw-like geometry to one O(1), one O(10), one O(4), and one O(6) atom. Cd(1) is bonded in a 3-coordinate geometry to one O(1), one O(4), and one O(8) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded to one Mn(2), one Mn(5), one Mn(6), one Mn(9), and one Cd(1) atom to form distorted OMn4Cd square pyramids that share  a cornercorner with one O(10)CaMn4 trigonal bipyramid,  a cornercorner with one O(9)CaMn4 trigonal bipyramid,  a cornercorner with one O(8)Mn4Cd trigonal bipyramid, corners with two equivalent O(3)CaMn4 trigonal bipyramids, corners with two equivalent O(5)Mn5 trigonal bipyramids,  an edgeedge with one O(4)CaMn3Cd trigonal bipyramid,  an edgeedge with one O(2)CaMn4 trigonal bipyramid,  an edgeedge with one O(8)Mn4Cd trigonal bipyramid, and  an edgeedge with one O(6)Mn5 trigonal bipyramid. In the second O site, O(2) is bonded to one Ca(1), one Mn(5), one Mn(6), one Mn(7), and one Mn(8) atom to form OCaMn4 trigonal bipyramids that share  a cornercorner with one O(4)CaMn3Cd trigonal bipyramid,  a cornercorner with one O(3)CaMn4 trigonal bipyramid,  a cornercorner with one O(9)CaMn4 trigonal bipyramid,  a cornercorner with one O(6)Mn5 trigonal bipyramid, corners with two equivalent O(10)CaMn4 trigonal bipyramids, corners with two equivalent O(8)Mn4Cd trigonal bipyramids, corners with two equivalent O(5)Mn5 trigonal bipyramids,  an edgeedge with one O(1)Mn4Cd square pyramid,  an edgeedge with one O(4)CaMn3Cd trigonal bipyramid,  an edgeedge with one O(3)CaMn4 trigonal bipyramid, and  an edgeedge with one O(9)CaMn4 trigonal bipyramid. In the third O site, O(3) is bonded to one Ca(1), one Mn(1), one Mn(2), one Mn(5), and one Mn(8) atom to form distorted OCaMn4 trigonal bipyramids that share corners with two equivalent O(1)Mn4Cd square pyramids,  a cornercorner with one O(10)CaMn4 trigonal bipyramid,  a cornercorner with one O(2)CaMn4 trigonal bipyramid,  a cornercorner with one O(5)Mn5 trigonal bipyramid,  a cornercorner with one O(6)Mn5 trigonal bipyramid, corners with two equivalent O(9)CaMn4 trigonal bipyramids, corners with two equivalent O(8)Mn4Cd trigonal bipyramids,  an edgeedge with one O(4)CaMn3Cd trigonal bipyramid,  an edgeedge with one O(10)CaMn4 trigonal bipyramid,  an edgeedge with one O(2)CaMn4 trigonal bipyramid, and  an edgeedge with one O(5)Mn5 trigonal bipyramid. In the fourth O site, O(4) is bonded to one Ca(1), one Mn(7), one Mn(8), one Mn(9), and one Cd(1) atom to form OCaMn3Cd trigonal bipyramids that share  a cornercorner with one O(10)CaMn4 trigonal bipyramid,  a cornercorner with one O(2)CaMn4 trigonal bipyramid,  a cornercorner with one O(8)Mn4Cd trigonal bipyramid,  a cornercorner with one O(5)Mn5 trigonal bipyramid, corners with two equivalent O(9)CaMn4 trigonal bipyramids, corners with two equivalent O(6)Mn5 trigonal bipyramids,  an edgeedge with one O(1)Mn4Cd square pyramid,  an edgeedge with one O(10)CaMn4 trigonal bipyramid,  an edgeedge with one O(2)CaMn4 trigonal bipyramid, and  an edgeedge with one O(3)CaMn4 trigonal bipyramid. In the fifth O site, O(5) is bonded to one Mn(1), one Mn(2), one Mn(3), one Mn(6), and one Mn(8) atom to form distorted OMn5 trigonal bipyramids that share corners with two equivalent O(1)Mn4Cd square pyramids,  a cornercorner with one O(4)CaMn3Cd trigonal bipyramid,  a cornercorner with one O(3)CaMn4 trigonal bipyramid,  a cornercorner with one O(8)Mn4Cd trigonal bipyramid, corners with two equivalent O(2)CaMn4 trigonal bipyramids, corners with two equivalent O(9)CaMn4 trigonal bipyramids,  an edgeedge with one O(10)CaMn4 trigonal bipyramid,  an edgeedge with one O(3)CaMn4 trigonal bipyramid,  an edgeedge with one O(8)Mn4Cd trigonal bipyramid, and  an edgeedge with one O(6)Mn5 trigonal bipyramid. In the sixth O site, O(6) is bonded to one Mn(2), one Mn(3), one Mn(4), one Mn(7), and one Mn(9) atom to form distorted OMn5 trigonal bipyramids that share  a cornercorner with one O(2)CaMn4 trigonal bipyramid,  a cornercorner with one O(3)CaMn4 trigonal bipyramid,  a cornercorner with one O(8)Mn4Cd trigonal bipyramid, corners with two equivalent O(4)CaMn3Cd trigonal bipyramids, corners with two equivalent O(10)CaMn4 trigonal bipyramids,  an edgeedge with one O(1)Mn4Cd square pyramid,  an edgeedge with one O(9)CaMn4 trigonal bipyramid, and  an edgeedge with one O(5)Mn5 trigonal bipyramid. In the seventh O site, O(7) is bonded in a distorted see-saw-like geometry to one Ca(1), one Mn(3), one Mn(4), and one Mn(7) atom. In the eighth O site, O(8) is bonded to one Mn(1), one Mn(3), one Mn(5), one Mn(6), and one Cd(1) atom to form OMn4Cd trigonal bipyramids that share  a cornercorner with one O(1)Mn4Cd square pyramid,  a cornercorner with one O(4)CaMn3Cd trigonal bipyramid,  a cornercorner with one O(10)CaMn4 trigonal bipyramid,  a cornercorner with one O(5)Mn5 trigonal bipyramid,  a cornercorner with one O(6)Mn5 trigonal bipyramid, corners with two equivalent O(2)CaMn4 trigonal bipyramids, corners with two equivalent O(3)CaMn4 trigonal bipyramids,  an edgeedge with one O(1)Mn4Cd square pyramid,  an edgeedge with one O(9)CaMn4 trigonal bipyramid, and  an edgeedge with one O(5)Mn5 trigonal bipyramid. In the ninth O site, O(9) is bonded to one Ca(1), one Mn(1), one Mn(4), one Mn(6), and one Mn(7) atom to form distorted OCaMn4 trigonal bipyramids that share  a cornercorner with one O(1)Mn4Cd square pyramid,  a cornercorner with one O(10)CaMn4 trigonal bipyramid,  a cornercorner with one O(2)CaMn4 trigonal bipyramid, corners with two equivalent O(4)CaMn3Cd trigonal bipyramids, corners with two equivalent O(3)CaMn4 trigonal bipyramids, corners with two equivalent O(5)Mn5 trigonal bipyramids,  an edgeedge with one O(10)CaMn4 trigonal bipyramid,  an edgeedge with one O(2)CaMn4 trigonal bipyramid,  an edgeedge with one O(8)Mn4Cd trigonal bipyramid, and  an edgeedge with one O(6)Mn5 trigonal bipyramid. In the tenth O site, O(10) is bonded to one Ca(1), one Mn(1), one Mn(4), one Mn(8), and one Mn(9) atom to form OCaMn4 trigonal bipyramids that share  a cornercorner with one O(1)Mn4Cd square pyramid,  a cornercorner with one O(4)CaMn3Cd trigonal bipyramid,  a cornercorner with one O(3)CaMn4 trigonal bipyramid,  a cornercorner with one O(9)CaMn4 trigonal bipyramid,  a cornercorner with one O(8)Mn4Cd trigonal bipyramid, corners with two equivalent O(2)CaMn4 trigonal bipyramids, corners with two equivalent O(6)Mn5 trigonal bipyramids,  an edgeedge with one O(4)CaMn3Cd trigonal bipyramid,  an edgeedge with one O(3)CaMn4 trigonal bipyramid,  an edgeedge with one O(9)CaMn4 trigonal bipyramid, and  an edgeedge with one O(5)Mn5 trigonal bipyramid. is represented by the CIF card [CIF]
data_CaMn9CdO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.286
_cell_length_b   9.314
_cell_length_c   6.564
_cell_angle_alpha   64.001
_cell_angle_beta   121.301
_cell_angle_gamma   92.072
_symmetry_Int_Tables_number   1
_cell_volume   285.834
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ca  Ca0  1  0.731  0.512  0.232  1.0
  Mn  Mn1  1  0.387  0.322  0.378  1.0
  Mn  Mn2  1  0.958  0.044  0.012  1.0
  Mn  Mn3  1  0.475  0.960  0.524  1.0
  Mn  Mn4  1  0.105  0.680  0.110  1.0
  Mn  Mn5  1  0.951  0.144  0.447  1.0
  Mn  Mn6  1  0.455  0.235  0.904  1.0
  Mn  Mn7  1  0.519  0.598  0.654  1.0
  Mn  Mn8  1  0.983  0.393  0.842  1.0
  Mn  Mn9  1  0.018  0.760  0.574  1.0
  Cd  Cd10  1  0.420  0.879  0.026  1.0
  O  O11  1  0.775  0.007  0.241  1.0
  O  O12  1  0.763  0.361  0.029  1.0
  O  O13  1  0.801  0.245  0.603  1.0
  O  O14  1  0.744  0.620  0.489  1.0
  O  O15  1  0.278  0.173  0.131  1.0
  O  O16  1  0.209  0.816  0.367  1.0
  O  O17  1  0.709  0.740  0.875  1.0
  O  O18  1  0.355  0.112  0.643  1.0
  O  O19  1  0.235  0.462  0.493  1.0
  O  O20  1  0.258  0.539  0.997  1.0
[/CIF]
.