The material structure described by XeSbF9 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four XeSbF9 clusters. Xe(1) is bonded in a 4-coordinate geometry to one F(3), one F(4), one F(5), and one F(6) atom. Sb(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(7), one F(8), and one F(9) atom. There are nine inequivalent F sites. In the first F site, F(7) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(8) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(9) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth F site, F(3) is bonded in a distorted bent 150 degrees geometry to one Xe(1) and one Sb(1) atom. In the seventh F site, F(4) is bonded in a single-bond geometry to one Xe(1) atom. In the eighth F site, F(5) is bonded in a single-bond geometry to one Xe(1) atom. In the ninth F site, F(6) is bonded in a single-bond geometry to one Xe(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_SbXeF9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   15.855
_cell_length_b   5.564
_cell_length_c   9.490
_cell_angle_alpha   68.003
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   776.302
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.582  0.457  0.778  1.0
  Sb  Sb1  1  0.082  0.543  0.722  1.0
  Sb  Sb2  1  0.418  0.543  0.222  1.0
  Sb  Sb3  1  0.918  0.457  0.278  1.0
  Xe  Xe4  1  0.363  0.890  0.719  1.0
  Xe  Xe5  1  0.863  0.110  0.781  1.0
  Xe  Xe6  1  0.637  0.110  0.281  1.0
  Xe  Xe7  1  0.137  0.890  0.219  1.0
  F  F8  1  0.635  0.701  0.845  1.0
  F  F9  1  0.135  0.299  0.655  1.0
  F  F10  1  0.365  0.299  0.155  1.0
  F  F11  1  0.865  0.701  0.345  1.0
  F  F12  1  0.521  0.207  0.727  1.0
  F  F13  1  0.021  0.793  0.773  1.0
  F  F14  1  0.479  0.793  0.273  1.0
  F  F15  1  0.979  0.207  0.227  1.0
  F  F16  1  0.029  0.568  0.336  1.0
  F  F17  1  0.529  0.432  0.164  1.0
  F  F18  1  0.971  0.432  0.664  1.0
  F  F19  1  0.471  0.568  0.836  1.0
  F  F20  1  0.130  0.683  0.087  1.0
  F  F21  1  0.630  0.317  0.413  1.0
  F  F22  1  0.870  0.317  0.913  1.0
  F  F23  1  0.370  0.683  0.587  1.0
  F  F24  1  0.221  0.075  0.065  1.0
  F  F25  1  0.721  0.925  0.435  1.0
  F  F26  1  0.779  0.925  0.935  1.0
  F  F27  1  0.279  0.075  0.565  1.0
  F  F28  1  0.172  0.160  0.301  1.0
  F  F29  1  0.672  0.840  0.199  1.0
  F  F30  1  0.828  0.840  0.699  1.0
  F  F31  1  0.328  0.160  0.801  1.0
  F  F32  1  0.937  0.714  0.080  1.0
  F  F33  1  0.437  0.286  0.420  1.0
  F  F34  1  0.063  0.286  0.920  1.0
  F  F35  1  0.563  0.714  0.580  1.0
  F  F36  1  0.813  0.354  0.220  1.0
  F  F37  1  0.313  0.646  0.280  1.0
  F  F38  1  0.187  0.646  0.780  1.0
  F  F39  1  0.687  0.354  0.720  1.0
  F  F40  1  0.910  0.204  0.483  1.0
  F  F41  1  0.410  0.796  0.017  1.0
  F  F42  1  0.090  0.796  0.517  1.0
  F  F43  1  0.590  0.204  0.983  1.0
[/CIF]
.
The material structure described by XeSbF9 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four XeSbF9 clusters. Xe(1) is bonded in a 4-coordinate geometry to one F(3), one F(4), one F(5), and one F(6) atom. Sb(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(7), one F(8), and one F(9) atom. There are nine inequivalent F sites. In the first F site, F(7) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(8) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(9) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth F site, F(3) is bonded in a distorted bent 150 degrees geometry to one Xe(1) and one Sb(1) atom. In the seventh F site, F(4) is bonded in a single-bond geometry to one Xe(1) atom. In the eighth F site, F(5) is bonded in a single-bond geometry to one Xe(1) atom. In the ninth F site, F(6) is bonded in a single-bond geometry to one Xe(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_SbXeF9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   15.855
_cell_length_b   5.564
_cell_length_c   9.490
_cell_angle_alpha   68.003
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   776.302
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.582  0.457  0.778  1.0
  Sb  Sb1  1  0.082  0.543  0.722  1.0
  Sb  Sb2  1  0.418  0.543  0.222  1.0
  Sb  Sb3  1  0.918  0.457  0.278  1.0
  Xe  Xe4  1  0.363  0.890  0.719  1.0
  Xe  Xe5  1  0.863  0.110  0.781  1.0
  Xe  Xe6  1  0.637  0.110  0.281  1.0
  Xe  Xe7  1  0.137  0.890  0.219  1.0
  F  F8  1  0.635  0.701  0.845  1.0
  F  F9  1  0.135  0.299  0.655  1.0
  F  F10  1  0.365  0.299  0.155  1.0
  F  F11  1  0.865  0.701  0.345  1.0
  F  F12  1  0.521  0.207  0.727  1.0
  F  F13  1  0.021  0.793  0.773  1.0
  F  F14  1  0.479  0.793  0.273  1.0
  F  F15  1  0.979  0.207  0.227  1.0
  F  F16  1  0.029  0.568  0.336  1.0
  F  F17  1  0.529  0.432  0.164  1.0
  F  F18  1  0.971  0.432  0.664  1.0
  F  F19  1  0.471  0.568  0.836  1.0
  F  F20  1  0.130  0.683  0.087  1.0
  F  F21  1  0.630  0.317  0.413  1.0
  F  F22  1  0.870  0.317  0.913  1.0
  F  F23  1  0.370  0.683  0.587  1.0
  F  F24  1  0.221  0.075  0.065  1.0
  F  F25  1  0.721  0.925  0.435  1.0
  F  F26  1  0.779  0.925  0.935  1.0
  F  F27  1  0.279  0.075  0.565  1.0
  F  F28  1  0.172  0.160  0.301  1.0
  F  F29  1  0.672  0.840  0.199  1.0
  F  F30  1  0.828  0.840  0.699  1.0
  F  F31  1  0.328  0.160  0.801  1.0
  F  F32  1  0.937  0.714  0.080  1.0
  F  F33  1  0.437  0.286  0.420  1.0
  F  F34  1  0.063  0.286  0.920  1.0
  F  F35  1  0.563  0.714  0.580  1.0
  F  F36  1  0.813  0.354  0.220  1.0
  F  F37  1  0.313  0.646  0.280  1.0
  F  F38  1  0.187  0.646  0.780  1.0
  F  F39  1  0.687  0.354  0.720  1.0
  F  F40  1  0.910  0.204  0.483  1.0
  F  F41  1  0.410  0.796  0.017  1.0
  F  F42  1  0.090  0.796  0.517  1.0
  F  F43  1  0.590  0.204  0.983  1.0
[/CIF]
.