The structure described by GaBr3 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two GaBr3 clusters. Ga(1) is bonded to one Br(1), one Br(2), and two equivalent Br(3) atoms to form edge-sharing GaBr4 tetrahedra. There are three inequivalent Br sites. In the first Br site, Br(2) is bonded in a single-bond geometry to one Ga(1) atom. In the second Br site, Br(1) is bonded in a single-bond geometry to one Ga(1) atom. In the third Br site, Br(3) is bonded in an L-shaped geometry to two equivalent Ga(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_GaBr3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.758
_cell_length_b   9.009
_cell_length_c   11.190
_cell_angle_alpha   107.763
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   552.747
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.002  0.802  0.952  1.0
  Ga  Ga1  1  0.502  0.198  0.548  1.0
  Ga  Ga2  1  0.998  0.198  0.048  1.0
  Ga  Ga3  1  0.498  0.802  0.452  1.0
  Br  Br4  1  0.763  0.672  0.794  1.0
  Br  Br5  1  0.263  0.328  0.706  1.0
  Br  Br6  1  0.237  0.328  0.206  1.0
  Br  Br7  1  0.737  0.672  0.294  1.0
  Br  Br8  1  0.245  0.677  0.049  1.0
  Br  Br9  1  0.745  0.323  0.451  1.0
  Br  Br10  1  0.755  0.323  0.951  1.0
  Br  Br11  1  0.255  0.677  0.549  1.0
  Br  Br12  1  0.780  1.000  0.113  1.0
  Br  Br13  1  0.280  0.000  0.387  1.0
  Br  Br14  1  0.220  0.000  0.887  1.0
  Br  Br15  1  0.720  1.000  0.613  1.0
[/CIF]
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The structure described by GaBr3 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two GaBr3 clusters. Ga(1) is bonded to one Br(1), one Br(2), and two equivalent Br(3) atoms to form edge-sharing GaBr4 tetrahedra. There are three inequivalent Br sites. In the first Br site, Br(2) is bonded in a single-bond geometry to one Ga(1) atom. In the second Br site, Br(1) is bonded in a single-bond geometry to one Ga(1) atom. In the third Br site, Br(3) is bonded in an L-shaped geometry to two equivalent Ga(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_GaBr3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.758
_cell_length_b   9.009
_cell_length_c   11.190
_cell_angle_alpha   107.763
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   552.747
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.002  0.802  0.952  1.0
  Ga  Ga1  1  0.502  0.198  0.548  1.0
  Ga  Ga2  1  0.998  0.198  0.048  1.0
  Ga  Ga3  1  0.498  0.802  0.452  1.0
  Br  Br4  1  0.763  0.672  0.794  1.0
  Br  Br5  1  0.263  0.328  0.706  1.0
  Br  Br6  1  0.237  0.328  0.206  1.0
  Br  Br7  1  0.737  0.672  0.294  1.0
  Br  Br8  1  0.245  0.677  0.049  1.0
  Br  Br9  1  0.745  0.323  0.451  1.0
  Br  Br10  1  0.755  0.323  0.951  1.0
  Br  Br11  1  0.255  0.677  0.549  1.0
  Br  Br12  1  0.780  1.000  0.113  1.0
  Br  Br13  1  0.280  0.000  0.387  1.0
  Br  Br14  1  0.220  0.000  0.887  1.0
  Br  Br15  1  0.720  1.000  0.613  1.0
[/CIF]
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