The compound described by LiCo(WO4)2 crystallizes in the triclinic P1 space group. Li(1) is bonded in a 6-coordinate geometry to one O(1), one O(3), one O(4), one O(5), one O(7), and one O(8) atom. There are two inequivalent W sites. In the first W site, W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(8) atom to form distorted WO6 octahedra that share corners with four equivalent Co(1)O6 octahedra and edges with two equivalent W(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 37-55°. In the second W site, W(2) is bonded to one O(2), one O(4), one O(5), one O(6), one O(7), and one O(8) atom to form distorted WO6 octahedra that share corners with four equivalent Co(1)O6 octahedra and edges with two equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 38-56°. Co(1) is bonded to one O(1), one O(2), one O(3), one O(6), one O(7), and one O(8) atom to form CoO6 octahedra that share corners with four equivalent W(1)O6 octahedra and corners with four equivalent W(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 37-56°. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to one Li(1), one W(1), and one Co(1) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one W(1), one W(2), and one Co(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Li(1), one W(1), and one Co(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Li(1), one W(1), and one W(2) atom. In the fifth O site, O(5) is bonded in a distorted T-shaped geometry to one Li(1), one W(1), and one W(2) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one W(2) and one Co(1) atom. In the seventh O site, O(7) is bonded in a trigonal planar geometry to one Li(1), one W(2), and one Co(1) atom. In the eighth O site, O(8) is bonded in a distorted trigonal pyramidal geometry to one Li(1), one W(1), one W(2), and one Co(1) atom. is represented by the CIF card [CIF]
data_LiCo(WO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.983
_cell_length_b   5.609
_cell_length_c   5.869
_cell_angle_alpha   110.098
_cell_angle_beta   89.172
_cell_angle_gamma   114.319
_symmetry_Int_Tables_number   1
_cell_volume   138.802
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.037  0.061  0.713  1.0
  Co  Co1  1  0.506  0.004  0.017  1.0
  W  W2  1  0.732  0.476  0.667  1.0
  W  W3  1  0.268  0.521  0.337  1.0
  O  O4  1  0.712  0.778  0.924  1.0
  O  O5  1  0.824  0.285  0.330  1.0
  O  O6  1  0.762  0.252  0.819  1.0
  O  O7  1  0.324  0.284  0.549  1.0
  O  O8  1  0.671  0.715  0.463  1.0
  O  O9  1  0.256  0.746  0.185  1.0
  O  O10  1  0.293  0.227  0.068  1.0
  O  O11  1  0.169  0.724  0.672  1.0
[/CIF]
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The compound described by LiCo(WO4)2 crystallizes in the triclinic P1 space group. Li(1) is bonded in a 6-coordinate geometry to one O(1), one O(3), one O(4), one O(5), one O(7), and one O(8) atom. There are two inequivalent W sites. In the first W site, W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(8) atom to form distorted WO6 octahedra that share corners with four equivalent Co(1)O6 octahedra and edges with two equivalent W(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 37-55°. In the second W site, W(2) is bonded to one O(2), one O(4), one O(5), one O(6), one O(7), and one O(8) atom to form distorted WO6 octahedra that share corners with four equivalent Co(1)O6 octahedra and edges with two equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 38-56°. Co(1) is bonded to one O(1), one O(2), one O(3), one O(6), one O(7), and one O(8) atom to form CoO6 octahedra that share corners with four equivalent W(1)O6 octahedra and corners with four equivalent W(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 37-56°. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to one Li(1), one W(1), and one Co(1) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one W(1), one W(2), and one Co(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Li(1), one W(1), and one Co(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Li(1), one W(1), and one W(2) atom. In the fifth O site, O(5) is bonded in a distorted T-shaped geometry to one Li(1), one W(1), and one W(2) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one W(2) and one Co(1) atom. In the seventh O site, O(7) is bonded in a trigonal planar geometry to one Li(1), one W(2), and one Co(1) atom. In the eighth O site, O(8) is bonded in a distorted trigonal pyramidal geometry to one Li(1), one W(1), one W(2), and one Co(1) atom. is represented by the CIF card [CIF]
data_LiCo(WO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.983
_cell_length_b   5.609
_cell_length_c   5.869
_cell_angle_alpha   110.098
_cell_angle_beta   89.172
_cell_angle_gamma   114.319
_symmetry_Int_Tables_number   1
_cell_volume   138.802
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.037  0.061  0.713  1.0
  Co  Co1  1  0.506  0.004  0.017  1.0
  W  W2  1  0.732  0.476  0.667  1.0
  W  W3  1  0.268  0.521  0.337  1.0
  O  O4  1  0.712  0.778  0.924  1.0
  O  O5  1  0.824  0.285  0.330  1.0
  O  O6  1  0.762  0.252  0.819  1.0
  O  O7  1  0.324  0.284  0.549  1.0
  O  O8  1  0.671  0.715  0.463  1.0
  O  O9  1  0.256  0.746  0.185  1.0
  O  O10  1  0.293  0.227  0.068  1.0
  O  O11  1  0.169  0.724  0.672  1.0
[/CIF]
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