The compound described by RbB3Te2O9 crystallizes in the monoclinic P2/c space group. Rb(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(4), and two equivalent O(5) atoms. There are two inequivalent B sites. In the first B site, B(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. In the second B site, B(2) is bonded in a trigonal planar geometry to one O(5) and two equivalent O(4) atoms. Te(1) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(3), one O(4), and one O(5) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Rb(1), one B(1), and one Te(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Rb(1), one B(1), and one Te(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one B(1) and one Te(1) atom. In the fourth O site, O(4) is bonded in a distorted water-like geometry to one Rb(1), one B(2), and one Te(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to two equivalent Rb(1), one B(2), and two equivalent Te(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_RbB3Te2O9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.695
_cell_length_b   6.246
_cell_length_c   13.564
_cell_angle_alpha   75.697
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   467.564
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.676  0.000  0.750  1.0
  Rb  Rb1  1  0.324  0.000  0.250  1.0
  B  B2  1  0.157  0.801  0.942  1.0
  B  B3  1  0.843  0.801  0.442  1.0
  B  B4  1  0.161  0.500  0.750  1.0
  B  B5  1  0.839  0.500  0.250  1.0
  B  B6  1  0.157  0.199  0.558  1.0
  B  B7  1  0.843  0.199  0.058  1.0
  Te  Te8  1  0.295  0.703  0.565  1.0
  Te  Te9  1  0.705  0.703  0.065  1.0
  Te  Te10  1  0.295  0.297  0.935  1.0
  Te  Te11  1  0.705  0.297  0.435  1.0
  O  O12  1  0.300  0.979  0.905  1.0
  O  O13  1  0.700  0.979  0.405  1.0
  O  O14  1  0.914  0.836  0.950  1.0
  O  O15  1  0.086  0.836  0.450  1.0
  O  O16  1  0.742  0.596  0.470  1.0
  O  O17  1  0.258  0.596  0.970  1.0
  O  O18  1  0.036  0.620  0.665  1.0
  O  O19  1  0.964  0.620  0.165  1.0
  O  O20  1  0.398  0.500  0.750  1.0
  O  O21  1  0.602  0.500  0.250  1.0
  O  O22  1  0.036  0.380  0.835  1.0
  O  O23  1  0.964  0.380  0.335  1.0
  O  O24  1  0.742  0.404  0.030  1.0
  O  O25  1  0.258  0.404  0.530  1.0
  O  O26  1  0.914  0.164  0.550  1.0
  O  O27  1  0.086  0.164  0.050  1.0
  O  O28  1  0.300  0.021  0.595  1.0
  O  O29  1  0.700  0.021  0.095  1.0
[/CIF]
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The compound described by RbB3Te2O9 crystallizes in the monoclinic P2/c space group. Rb(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(4), and two equivalent O(5) atoms. There are two inequivalent B sites. In the first B site, B(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. In the second B site, B(2) is bonded in a trigonal planar geometry to one O(5) and two equivalent O(4) atoms. Te(1) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(3), one O(4), and one O(5) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Rb(1), one B(1), and one Te(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Rb(1), one B(1), and one Te(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one B(1) and one Te(1) atom. In the fourth O site, O(4) is bonded in a distorted water-like geometry to one Rb(1), one B(2), and one Te(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to two equivalent Rb(1), one B(2), and two equivalent Te(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_RbB3Te2O9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.695
_cell_length_b   6.246
_cell_length_c   13.564
_cell_angle_alpha   75.697
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   467.564
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.676  0.000  0.750  1.0
  Rb  Rb1  1  0.324  0.000  0.250  1.0
  B  B2  1  0.157  0.801  0.942  1.0
  B  B3  1  0.843  0.801  0.442  1.0
  B  B4  1  0.161  0.500  0.750  1.0
  B  B5  1  0.839  0.500  0.250  1.0
  B  B6  1  0.157  0.199  0.558  1.0
  B  B7  1  0.843  0.199  0.058  1.0
  Te  Te8  1  0.295  0.703  0.565  1.0
  Te  Te9  1  0.705  0.703  0.065  1.0
  Te  Te10  1  0.295  0.297  0.935  1.0
  Te  Te11  1  0.705  0.297  0.435  1.0
  O  O12  1  0.300  0.979  0.905  1.0
  O  O13  1  0.700  0.979  0.405  1.0
  O  O14  1  0.914  0.836  0.950  1.0
  O  O15  1  0.086  0.836  0.450  1.0
  O  O16  1  0.742  0.596  0.470  1.0
  O  O17  1  0.258  0.596  0.970  1.0
  O  O18  1  0.036  0.620  0.665  1.0
  O  O19  1  0.964  0.620  0.165  1.0
  O  O20  1  0.398  0.500  0.750  1.0
  O  O21  1  0.602  0.500  0.250  1.0
  O  O22  1  0.036  0.380  0.835  1.0
  O  O23  1  0.964  0.380  0.335  1.0
  O  O24  1  0.742  0.404  0.030  1.0
  O  O25  1  0.258  0.404  0.530  1.0
  O  O26  1  0.914  0.164  0.550  1.0
  O  O27  1  0.086  0.164  0.050  1.0
  O  O28  1  0.300  0.021  0.595  1.0
  O  O29  1  0.700  0.021  0.095  1.0
[/CIF]
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