The material structure described by LiCrPO4 crystallizes in the orthorhombic Fdd2 space group. Li(1) is bonded in a 6-coordinate geometry to two equivalent O(1) and four equivalent O(2) atoms. Cr(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent O(1) and two equivalent O(2) atoms. P(1) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Li(1), one Cr(1), and one P(1) atom. In the second O site, O(2) is bonded to two equivalent Li(1), one Cr(1), and one P(1) atom to form a mixture of distorted corner and edge-sharing OLi2CrP trigonal pyramids. is represented by the CIF file [CIF]
data_LiCrPO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.393
_cell_length_b   6.284
_cell_length_c   5.584
_cell_angle_alpha   76.812
_cell_angle_beta   55.849
_cell_angle_gamma   47.339
_symmetry_Int_Tables_number   1
_cell_volume   152.831
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.935  0.565  0.935  1.0
  Li  Li1  1  0.685  0.315  0.685  1.0
  Cr  Cr2  1  0.027  0.973  0.027  1.0
  Cr  Cr3  1  0.277  0.223  0.277  1.0
  P  P4  1  0.633  0.867  0.633  1.0
  P  P5  1  0.383  0.617  0.383  1.0
  O  O6  1  0.352  0.488  0.216  1.0
  O  O7  1  0.216  0.944  0.352  1.0
  O  O8  1  0.306  0.034  0.762  1.0
  O  O9  1  0.762  0.898  0.306  1.0
  O  O10  1  0.240  0.616  0.721  1.0
  O  O11  1  0.827  0.529  0.634  1.0
  O  O12  1  0.634  0.009  0.827  1.0
  O  O13  1  0.721  0.423  0.240  1.0
[/CIF]
.
The material structure described by LiCrPO4 crystallizes in the orthorhombic Fdd2 space group. Li(1) is bonded in a 6-coordinate geometry to two equivalent O(1) and four equivalent O(2) atoms. Cr(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent O(1) and two equivalent O(2) atoms. P(1) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Li(1), one Cr(1), and one P(1) atom. In the second O site, O(2) is bonded to two equivalent Li(1), one Cr(1), and one P(1) atom to form a mixture of distorted corner and edge-sharing OLi2CrP trigonal pyramids. is represented by the CIF file [CIF]
data_LiCrPO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.393
_cell_length_b   6.284
_cell_length_c   5.584
_cell_angle_alpha   76.812
_cell_angle_beta   55.849
_cell_angle_gamma   47.339
_symmetry_Int_Tables_number   1
_cell_volume   152.831
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.935  0.565  0.935  1.0
  Li  Li1  1  0.685  0.315  0.685  1.0
  Cr  Cr2  1  0.027  0.973  0.027  1.0
  Cr  Cr3  1  0.277  0.223  0.277  1.0
  P  P4  1  0.633  0.867  0.633  1.0
  P  P5  1  0.383  0.617  0.383  1.0
  O  O6  1  0.352  0.488  0.216  1.0
  O  O7  1  0.216  0.944  0.352  1.0
  O  O8  1  0.306  0.034  0.762  1.0
  O  O9  1  0.762  0.898  0.306  1.0
  O  O10  1  0.240  0.616  0.721  1.0
  O  O11  1  0.827  0.529  0.634  1.0
  O  O12  1  0.634  0.009  0.827  1.0
  O  O13  1  0.721  0.423  0.240  1.0
[/CIF]
.