The material structure described by V6O13 crystallizes in the monoclinic P2_1/m space group. There are six inequivalent V sites. In the first V site, V(1) is bonded in a 6-coordinate geometry to one O(3), one O(5), one O(7), and three equivalent O(9) atoms. In the second V site, V(2) is bonded in a 6-coordinate geometry to one O(4), one O(6), one O(8), and three equivalent O(10) atoms. In the third V site, V(3) is bonded in a 6-coordinate geometry to one O(10), one O(2), one O(5), one O(6), and two equivalent O(8) atoms. In the fourth V site, V(4) is bonded in a 6-coordinate geometry to one O(1), one O(5), one O(6), one O(9), and two equivalent O(7) atoms. In the fifth V site, V(5) is bonded to one O(11), one O(2), one O(4), and three equivalent O(12) atoms to form a mixture of corner and edge-sharing VO6 octahedra. The corner-sharing octahedral tilt angles range from 1-27°. In the sixth V site, V(6) is bonded to one O(1), one O(11), one O(3), and three equivalent O(13) atoms to form a mixture of corner and edge-sharing VO6 octahedra. The corner-sharing octahedral tilt angles range from 1-21°. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded in a linear geometry to one V(4) and one V(6) atom. In the second O site, O(2) is bonded in a linear geometry to one V(3) and one V(5) atom. In the third O site, O(3) is bonded in a linear geometry to one V(1) and one V(6) atom. In the fourth O site, O(4) is bonded in a linear geometry to one V(2) and one V(5) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one V(1), one V(3), and one V(4) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one V(2), one V(3), and one V(4) atom. In the seventh O site, O(7) is bonded in a distorted T-shaped geometry to one V(1) and two equivalent V(4) atoms. In the eighth O site, O(8) is bonded in a distorted T-shaped geometry to one V(2) and two equivalent V(3) atoms. In the ninth O site, O(9) is bonded to one V(4) and three equivalent V(1) atoms to form a mixture of distorted corner and edge-sharing OV4 tetrahedra. In the tenth O site, O(10) is bonded to one V(3) and three equivalent V(2) atoms to form a mixture of distorted corner and edge-sharing OV4 tetrahedra. In the eleventh O site, O(11) is bonded in a linear geometry to one V(5) and one V(6) atom. In the twelfth O site, O(12) is bonded in a distorted T-shaped geometry to three equivalent V(5) atoms. In the thirteenth O site, O(13) is bonded in a distorted T-shaped geometry to three equivalent V(6) atoms. is represented by the CIF file [CIF]
data_V6O13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.743
_cell_length_b   6.361
_cell_length_c   10.300
_cell_angle_alpha   100.363
_cell_angle_beta   90.000
_cell_angle_gamma   107.110
_symmetry_Int_Tables_number   1
_cell_volume   230.229
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  O  O0  1  0.386  0.273  0.198  1.0
  O  O1  1  0.614  0.727  0.802  1.0
  O  O2  1  0.677  0.854  0.198  1.0
  O  O3  1  0.323  0.146  0.802  1.0
  O  O4  1  0.560  0.621  0.409  1.0
  O  O5  1  0.440  0.379  0.591  1.0
  O  O6  1  0.880  0.260  0.385  1.0
  O  O7  1  0.120  0.740  0.615  1.0
  O  O8  1  0.747  0.993  0.590  1.0
  O  O9  1  0.253  0.007  0.410  1.0
  O  O10  1  0.500  0.500  0.000  1.0
  O  O11  1  0.819  0.138  1.000  1.0
  O  O12  1  0.181  0.862  0.000  1.0
  V  V13  1  0.714  0.927  0.365  1.0
  V  V14  1  0.286  0.073  0.635  1.0
  V  V15  1  0.413  0.326  0.364  1.0
  V  V16  1  0.587  0.674  0.636  1.0
  V  V17  1  0.351  0.203  0.999  1.0
  V  V18  1  0.649  0.797  0.001  1.0
[/CIF]
.
The material structure described by V6O13 crystallizes in the monoclinic P2_1/m space group. There are six inequivalent V sites. In the first V site, V(1) is bonded in a 6-coordinate geometry to one O(3), one O(5), one O(7), and three equivalent O(9) atoms. In the second V site, V(2) is bonded in a 6-coordinate geometry to one O(4), one O(6), one O(8), and three equivalent O(10) atoms. In the third V site, V(3) is bonded in a 6-coordinate geometry to one O(10), one O(2), one O(5), one O(6), and two equivalent O(8) atoms. In the fourth V site, V(4) is bonded in a 6-coordinate geometry to one O(1), one O(5), one O(6), one O(9), and two equivalent O(7) atoms. In the fifth V site, V(5) is bonded to one O(11), one O(2), one O(4), and three equivalent O(12) atoms to form a mixture of corner and edge-sharing VO6 octahedra. The corner-sharing octahedral tilt angles range from 1-27°. In the sixth V site, V(6) is bonded to one O(1), one O(11), one O(3), and three equivalent O(13) atoms to form a mixture of corner and edge-sharing VO6 octahedra. The corner-sharing octahedral tilt angles range from 1-21°. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded in a linear geometry to one V(4) and one V(6) atom. In the second O site, O(2) is bonded in a linear geometry to one V(3) and one V(5) atom. In the third O site, O(3) is bonded in a linear geometry to one V(1) and one V(6) atom. In the fourth O site, O(4) is bonded in a linear geometry to one V(2) and one V(5) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one V(1), one V(3), and one V(4) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one V(2), one V(3), and one V(4) atom. In the seventh O site, O(7) is bonded in a distorted T-shaped geometry to one V(1) and two equivalent V(4) atoms. In the eighth O site, O(8) is bonded in a distorted T-shaped geometry to one V(2) and two equivalent V(3) atoms. In the ninth O site, O(9) is bonded to one V(4) and three equivalent V(1) atoms to form a mixture of distorted corner and edge-sharing OV4 tetrahedra. In the tenth O site, O(10) is bonded to one V(3) and three equivalent V(2) atoms to form a mixture of distorted corner and edge-sharing OV4 tetrahedra. In the eleventh O site, O(11) is bonded in a linear geometry to one V(5) and one V(6) atom. In the twelfth O site, O(12) is bonded in a distorted T-shaped geometry to three equivalent V(5) atoms. In the thirteenth O site, O(13) is bonded in a distorted T-shaped geometry to three equivalent V(6) atoms. is represented by the CIF file [CIF]
data_V6O13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.743
_cell_length_b   6.361
_cell_length_c   10.300
_cell_angle_alpha   100.363
_cell_angle_beta   90.000
_cell_angle_gamma   107.110
_symmetry_Int_Tables_number   1
_cell_volume   230.229
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  O  O0  1  0.386  0.273  0.198  1.0
  O  O1  1  0.614  0.727  0.802  1.0
  O  O2  1  0.677  0.854  0.198  1.0
  O  O3  1  0.323  0.146  0.802  1.0
  O  O4  1  0.560  0.621  0.409  1.0
  O  O5  1  0.440  0.379  0.591  1.0
  O  O6  1  0.880  0.260  0.385  1.0
  O  O7  1  0.120  0.740  0.615  1.0
  O  O8  1  0.747  0.993  0.590  1.0
  O  O9  1  0.253  0.007  0.410  1.0
  O  O10  1  0.500  0.500  0.000  1.0
  O  O11  1  0.819  0.138  1.000  1.0
  O  O12  1  0.181  0.862  0.000  1.0
  V  V13  1  0.714  0.927  0.365  1.0
  V  V14  1  0.286  0.073  0.635  1.0
  V  V15  1  0.413  0.326  0.364  1.0
  V  V16  1  0.587  0.674  0.636  1.0
  V  V17  1  0.351  0.203  0.999  1.0
  V  V18  1  0.649  0.797  0.001  1.0
[/CIF]
.