The structure described by Ag3In(PO4)2 crystallizes in the monoclinic C2/m space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 3-coordinate geometry to one O(1) and two equivalent O(3) atoms. In the second Ag site, Ag(2) is bonded in a distorted linear geometry to two equivalent O(1) and four equivalent O(3) atoms. In(1) is bonded to two equivalent O(2) and four equivalent O(3) atoms to form InO6 octahedra that share corners with six equivalent P(1)O4 tetrahedra. P(1) is bonded to one O(1), one O(2), and two equivalent O(3) atoms to form PO4 tetrahedra that share corners with three equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 40-47°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Ag(1), one Ag(2), and one P(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one In(1) and one P(1) atom. In the third O site, O(3) is bonded in a 1-coordinate geometry to one Ag(1), one Ag(2), one In(1), and one P(1) atom. is represented by the CIF file [CIF]
data_InAg3(PO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.235
_cell_length_b   5.235
_cell_length_c   7.457
_cell_angle_alpha   86.461
_cell_angle_beta   86.461
_cell_angle_gamma   64.796
_symmetry_Int_Tables_number   1
_cell_volume   184.427
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.000  0.000  0.000  1.0
  Ag  Ag1  1  0.332  0.332  0.679  1.0
  Ag  Ag2  1  0.668  0.668  0.321  1.0
  Ag  Ag3  1  0.000  0.000  0.500  1.0
  P  P4  1  0.661  0.661  0.791  1.0
  P  P5  1  0.339  0.339  0.209  1.0
  O  O6  1  0.244  0.244  0.393  1.0
  O  O7  1  0.763  0.763  0.950  1.0
  O  O8  1  0.670  0.221  0.203  1.0
  O  O9  1  0.779  0.330  0.797  1.0
  O  O10  1  0.237  0.237  0.050  1.0
  O  O11  1  0.221  0.670  0.203  1.0
  O  O12  1  0.330  0.779  0.797  1.0
  O  O13  1  0.756  0.756  0.607  1.0
[/CIF]
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The structure described by Ag3In(PO4)2 crystallizes in the monoclinic C2/m space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 3-coordinate geometry to one O(1) and two equivalent O(3) atoms. In the second Ag site, Ag(2) is bonded in a distorted linear geometry to two equivalent O(1) and four equivalent O(3) atoms. In(1) is bonded to two equivalent O(2) and four equivalent O(3) atoms to form InO6 octahedra that share corners with six equivalent P(1)O4 tetrahedra. P(1) is bonded to one O(1), one O(2), and two equivalent O(3) atoms to form PO4 tetrahedra that share corners with three equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 40-47°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Ag(1), one Ag(2), and one P(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one In(1) and one P(1) atom. In the third O site, O(3) is bonded in a 1-coordinate geometry to one Ag(1), one Ag(2), one In(1), and one P(1) atom. is represented by the CIF file [CIF]
data_InAg3(PO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.235
_cell_length_b   5.235
_cell_length_c   7.457
_cell_angle_alpha   86.461
_cell_angle_beta   86.461
_cell_angle_gamma   64.796
_symmetry_Int_Tables_number   1
_cell_volume   184.427
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.000  0.000  0.000  1.0
  Ag  Ag1  1  0.332  0.332  0.679  1.0
  Ag  Ag2  1  0.668  0.668  0.321  1.0
  Ag  Ag3  1  0.000  0.000  0.500  1.0
  P  P4  1  0.661  0.661  0.791  1.0
  P  P5  1  0.339  0.339  0.209  1.0
  O  O6  1  0.244  0.244  0.393  1.0
  O  O7  1  0.763  0.763  0.950  1.0
  O  O8  1  0.670  0.221  0.203  1.0
  O  O9  1  0.779  0.330  0.797  1.0
  O  O10  1  0.237  0.237  0.050  1.0
  O  O11  1  0.221  0.670  0.203  1.0
  O  O12  1  0.330  0.779  0.797  1.0
  O  O13  1  0.756  0.756  0.607  1.0
[/CIF]
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