The material structure described by Mn10CoN8 crystallizes in the monoclinic C2/m space group. There are five inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one N(3) atom. In the second Mn site, Mn(2) is bonded in a rectangular see-saw-like geometry to one N(1), one N(2), and two equivalent N(4) atoms. In the third Mn site, Mn(3) is bonded in a see-saw-like geometry to one N(3), one N(4), and two equivalent N(2) atoms. In the fourth Mn site, Mn(4) is bonded in a see-saw-like geometry to one N(3), one N(4), and two equivalent N(1) atoms. In the fifth Mn site, Mn(5) is bonded in a see-saw-like geometry to one N(1), one N(2), and two equivalent N(3) atoms. Co(1) is bonded in a linear geometry to two equivalent N(4) atoms. There are four inequivalent N sites. In the first N site, N(1) is bonded to one Mn(1), one Mn(2), one Mn(5), and two equivalent Mn(4) atoms to form NMn5 trigonal bipyramids that share  a cornercorner with one N(3)Mn5 trigonal bipyramid, corners with two equivalent N(1)Mn5 trigonal bipyramids, corners with three equivalent N(2)Mn5 trigonal bipyramids, edges with two equivalent N(4)Mn4Co square pyramids, and edges with two equivalent N(3)Mn5 trigonal bipyramids. In the second N site, N(2) is bonded to one Mn(1), one Mn(2), one Mn(5), and two equivalent Mn(3) atoms to form NMn5 trigonal bipyramids that share  a cornercorner with one N(3)Mn5 trigonal bipyramid, corners with two equivalent N(2)Mn5 trigonal bipyramids, corners with three equivalent N(1)Mn5 trigonal bipyramids, edges with two equivalent N(4)Mn4Co square pyramids, and edges with two equivalent N(3)Mn5 trigonal bipyramids. In the third N site, N(3) is bonded to one Mn(1), one Mn(3), one Mn(4), and two equivalent Mn(5) atoms to form NMn5 trigonal bipyramids that share corners with two equivalent N(4)Mn4Co square pyramids,  a cornercorner with one N(1)Mn5 trigonal bipyramid,  a cornercorner with one N(2)Mn5 trigonal bipyramid, corners with two equivalent N(3)Mn5 trigonal bipyramids, edges with two equivalent N(1)Mn5 trigonal bipyramids, and edges with two equivalent N(2)Mn5 trigonal bipyramids. In the fourth N site, N(4) is bonded to one Mn(3), one Mn(4), two equivalent Mn(2), and one Co(1) atom to form NMn4Co square pyramids that share corners with three equivalent N(4)Mn4Co square pyramids, corners with two equivalent N(3)Mn5 trigonal bipyramids, edges with two equivalent N(1)Mn5 trigonal bipyramids, and edges with two equivalent N(2)Mn5 trigonal bipyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mn10CoN8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.624
_cell_length_b   3.944
_cell_length_c   6.747
_cell_angle_alpha   90.000
_cell_angle_beta   66.085
_cell_angle_gamma   76.780
_symmetry_Int_Tables_number   1
_cell_volume   203.131
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.366  0.817  0.813  1.0
  Mn  Mn1  1  0.634  0.183  0.187  1.0
  Mn  Mn2  1  0.996  0.002  0.762  1.0
  Mn  Mn3  1  0.004  0.998  0.238  1.0
  Mn  Mn4  1  0.749  0.626  0.374  1.0
  Mn  Mn5  1  0.251  0.374  0.626  1.0
  Mn  Mn6  1  0.741  0.630  0.881  1.0
  Mn  Mn7  1  0.259  0.370  0.119  1.0
  Mn  Mn8  1  0.391  0.804  0.306  1.0
  Mn  Mn9  1  0.609  0.196  0.694  1.0
  Co  Co10  1  0.000  0.500  0.500  1.0
  N  N11  1  0.266  0.867  0.108  1.0
  N  N12  1  0.734  0.133  0.892  1.0
  N  N13  1  0.256  0.872  0.632  1.0
  N  N14  1  0.744  0.128  0.368  1.0
  N  N15  1  0.605  0.697  0.696  1.0
  N  N16  1  0.395  0.303  0.304  1.0
  N  N17  1  0.005  0.498  0.226  1.0
  N  N18  1  0.995  0.502  0.774  1.0
[/CIF]
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The material structure described by Mn10CoN8 crystallizes in the monoclinic C2/m space group. There are five inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one N(3) atom. In the second Mn site, Mn(2) is bonded in a rectangular see-saw-like geometry to one N(1), one N(2), and two equivalent N(4) atoms. In the third Mn site, Mn(3) is bonded in a see-saw-like geometry to one N(3), one N(4), and two equivalent N(2) atoms. In the fourth Mn site, Mn(4) is bonded in a see-saw-like geometry to one N(3), one N(4), and two equivalent N(1) atoms. In the fifth Mn site, Mn(5) is bonded in a see-saw-like geometry to one N(1), one N(2), and two equivalent N(3) atoms. Co(1) is bonded in a linear geometry to two equivalent N(4) atoms. There are four inequivalent N sites. In the first N site, N(1) is bonded to one Mn(1), one Mn(2), one Mn(5), and two equivalent Mn(4) atoms to form NMn5 trigonal bipyramids that share  a cornercorner with one N(3)Mn5 trigonal bipyramid, corners with two equivalent N(1)Mn5 trigonal bipyramids, corners with three equivalent N(2)Mn5 trigonal bipyramids, edges with two equivalent N(4)Mn4Co square pyramids, and edges with two equivalent N(3)Mn5 trigonal bipyramids. In the second N site, N(2) is bonded to one Mn(1), one Mn(2), one Mn(5), and two equivalent Mn(3) atoms to form NMn5 trigonal bipyramids that share  a cornercorner with one N(3)Mn5 trigonal bipyramid, corners with two equivalent N(2)Mn5 trigonal bipyramids, corners with three equivalent N(1)Mn5 trigonal bipyramids, edges with two equivalent N(4)Mn4Co square pyramids, and edges with two equivalent N(3)Mn5 trigonal bipyramids. In the third N site, N(3) is bonded to one Mn(1), one Mn(3), one Mn(4), and two equivalent Mn(5) atoms to form NMn5 trigonal bipyramids that share corners with two equivalent N(4)Mn4Co square pyramids,  a cornercorner with one N(1)Mn5 trigonal bipyramid,  a cornercorner with one N(2)Mn5 trigonal bipyramid, corners with two equivalent N(3)Mn5 trigonal bipyramids, edges with two equivalent N(1)Mn5 trigonal bipyramids, and edges with two equivalent N(2)Mn5 trigonal bipyramids. In the fourth N site, N(4) is bonded to one Mn(3), one Mn(4), two equivalent Mn(2), and one Co(1) atom to form NMn4Co square pyramids that share corners with three equivalent N(4)Mn4Co square pyramids, corners with two equivalent N(3)Mn5 trigonal bipyramids, edges with two equivalent N(1)Mn5 trigonal bipyramids, and edges with two equivalent N(2)Mn5 trigonal bipyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mn10CoN8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.624
_cell_length_b   3.944
_cell_length_c   6.747
_cell_angle_alpha   90.000
_cell_angle_beta   66.085
_cell_angle_gamma   76.780
_symmetry_Int_Tables_number   1
_cell_volume   203.131
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.366  0.817  0.813  1.0
  Mn  Mn1  1  0.634  0.183  0.187  1.0
  Mn  Mn2  1  0.996  0.002  0.762  1.0
  Mn  Mn3  1  0.004  0.998  0.238  1.0
  Mn  Mn4  1  0.749  0.626  0.374  1.0
  Mn  Mn5  1  0.251  0.374  0.626  1.0
  Mn  Mn6  1  0.741  0.630  0.881  1.0
  Mn  Mn7  1  0.259  0.370  0.119  1.0
  Mn  Mn8  1  0.391  0.804  0.306  1.0
  Mn  Mn9  1  0.609  0.196  0.694  1.0
  Co  Co10  1  0.000  0.500  0.500  1.0
  N  N11  1  0.266  0.867  0.108  1.0
  N  N12  1  0.734  0.133  0.892  1.0
  N  N13  1  0.256  0.872  0.632  1.0
  N  N14  1  0.744  0.128  0.368  1.0
  N  N15  1  0.605  0.697  0.696  1.0
  N  N16  1  0.395  0.303  0.304  1.0
  N  N17  1  0.005  0.498  0.226  1.0
  N  N18  1  0.995  0.502  0.774  1.0
[/CIF]
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