The compound described by CaLa2Co2Sb2(PbO6)2 crystallizes in the triclinic P1 space group. Ca(1) is bonded in a 5-coordinate geometry to one O(1), one O(11), one O(5), one O(7), and one O(9) atom. There are two inequivalent La sites. In the first La site, La(1) is bonded in a 8-coordinate geometry to one O(10), one O(11), one O(2), one O(3), one O(6), one O(7), one O(8), and one O(9) atom. In the second La site, La(2) is bonded in a 7-coordinate geometry to one O(1), one O(10), one O(12), one O(4), one O(5), one O(6), and one O(8) atom. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded in a 5-coordinate geometry to one O(11), one O(2), one O(5), one O(7), and one O(9) atom. In the second Co site, Co(2) is bonded to one O(1), one O(10), one O(12), one O(3), one O(6), and one O(8) atom to form distorted CoO6 octahedra that share corners with four equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 17-37°. There are two inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 3-coordinate geometry to one O(1), one O(4), and one O(8) atom. In the second Pb site, Pb(2) is bonded in a 4-coordinate geometry to one O(10), one O(11), one O(2), and one O(6) atom. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(10), one O(12), one O(2), one O(4), one O(6), and one O(8) atom to form SbO6 octahedra that share corners with four equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 17-37°. In the second Sb site, Sb(2) is bonded in a rectangular see-saw-like geometry to one O(11), one O(3), one O(7), and one O(9) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded to one Ca(1), one La(2), one Co(2), and one Pb(1) atom to form distorted corner-sharing OCaLaCoPb tetrahedra. In the second O site, O(2) is bonded in a 4-coordinate geometry to one La(1), one Co(1), one Pb(2), and one Sb(1) atom. In the third O site, O(3) is bonded in a distorted T-shaped geometry to one La(1), one Co(2), and one Sb(2) atom. In the fourth O site, O(4) is bonded in a distorted trigonal non-coplanar geometry to one La(2), one Pb(1), and one Sb(1) atom. In the fifth O site, O(5) is bonded in a distorted trigonal non-coplanar geometry to one Ca(1), one La(2), and one Co(1) atom. In the sixth O site, O(6) is bonded in a 5-coordinate geometry to one La(1), one La(2), one Co(2), one Pb(2), and one Sb(1) atom. In the seventh O site, O(7) is bonded in a 2-coordinate geometry to one Ca(1), one La(1), one Co(1), and one Sb(2) atom. In the eighth O site, O(8) is bonded in a 5-coordinate geometry to one La(1), one La(2), one Co(2), one Pb(1), and one Sb(1) atom. In the ninth O site, O(9) is bonded in a distorted rectangular see-saw-like geometry to one Ca(1), one La(1), one Co(1), and one Sb(2) atom. In the tenth O site, O(10) is bonded in a 5-coordinate geometry to one La(1), one La(2), one Co(2), one Pb(2), and one Sb(1) atom. In the eleventh O site, O(11) is bonded to one Ca(1), one La(1), one Co(1), one Pb(2), and one Sb(2) atom to form distorted corner-sharing OCaLaCoSbPb trigonal bipyramids. In the twelfth O site, O(12) is bonded in a distorted trigonal non-coplanar geometry to one La(2), one Co(2), and one Sb(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CaLa2Co2Sb2(PbO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.825
_cell_length_b   5.987
_cell_length_c   9.795
_cell_angle_alpha   76.198
_cell_angle_beta   93.243
_cell_angle_gamma   94.343
_symmetry_Int_Tables_number   1
_cell_volume   330.508
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ca  Ca0  1  0.487  0.702  0.414  1.0
  La  La1  1  0.515  0.483  0.780  1.0
  La  La2  1  0.001  0.926  0.167  1.0
  Co  Co3  1  0.007  0.576  0.563  1.0
  Co  Co4  1  0.511  0.936  0.985  1.0
  Sb  Sb5  1  0.028  0.477  0.979  1.0
  Sb  Sb6  1  0.464  0.125  0.565  1.0
  Pb  Pb7  1  0.559  0.315  0.193  1.0
  Pb  Pb8  1  0.952  0.997  0.759  1.0
  O  O9  1  0.588  0.934  0.195  1.0
  O  O10  1  0.095  0.595  0.774  1.0
  O  O11  1  0.446  0.055  0.775  1.0
  O  O12  1  0.958  0.338  0.179  1.0
  O  O13  1  0.099  0.788  0.387  1.0
  O  O14  1  0.753  0.683  0.956  1.0
  O  O15  1  0.731  0.354  0.570  1.0
  O  O16  1  0.302  0.273  0.003  1.0
  O  O17  1  0.292  0.418  0.574  1.0
  O  O18  1  0.808  0.219  0.933  1.0
  O  O19  1  0.670  0.820  0.605  1.0
  O  O20  1  0.221  0.738  0.029  1.0
[/CIF]
.
The compound described by CaLa2Co2Sb2(PbO6)2 crystallizes in the triclinic P1 space group. Ca(1) is bonded in a 5-coordinate geometry to one O(1), one O(11), one O(5), one O(7), and one O(9) atom. There are two inequivalent La sites. In the first La site, La(1) is bonded in a 8-coordinate geometry to one O(10), one O(11), one O(2), one O(3), one O(6), one O(7), one O(8), and one O(9) atom. In the second La site, La(2) is bonded in a 7-coordinate geometry to one O(1), one O(10), one O(12), one O(4), one O(5), one O(6), and one O(8) atom. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded in a 5-coordinate geometry to one O(11), one O(2), one O(5), one O(7), and one O(9) atom. In the second Co site, Co(2) is bonded to one O(1), one O(10), one O(12), one O(3), one O(6), and one O(8) atom to form distorted CoO6 octahedra that share corners with four equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 17-37°. There are two inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 3-coordinate geometry to one O(1), one O(4), and one O(8) atom. In the second Pb site, Pb(2) is bonded in a 4-coordinate geometry to one O(10), one O(11), one O(2), and one O(6) atom. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(10), one O(12), one O(2), one O(4), one O(6), and one O(8) atom to form SbO6 octahedra that share corners with four equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 17-37°. In the second Sb site, Sb(2) is bonded in a rectangular see-saw-like geometry to one O(11), one O(3), one O(7), and one O(9) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded to one Ca(1), one La(2), one Co(2), and one Pb(1) atom to form distorted corner-sharing OCaLaCoPb tetrahedra. In the second O site, O(2) is bonded in a 4-coordinate geometry to one La(1), one Co(1), one Pb(2), and one Sb(1) atom. In the third O site, O(3) is bonded in a distorted T-shaped geometry to one La(1), one Co(2), and one Sb(2) atom. In the fourth O site, O(4) is bonded in a distorted trigonal non-coplanar geometry to one La(2), one Pb(1), and one Sb(1) atom. In the fifth O site, O(5) is bonded in a distorted trigonal non-coplanar geometry to one Ca(1), one La(2), and one Co(1) atom. In the sixth O site, O(6) is bonded in a 5-coordinate geometry to one La(1), one La(2), one Co(2), one Pb(2), and one Sb(1) atom. In the seventh O site, O(7) is bonded in a 2-coordinate geometry to one Ca(1), one La(1), one Co(1), and one Sb(2) atom. In the eighth O site, O(8) is bonded in a 5-coordinate geometry to one La(1), one La(2), one Co(2), one Pb(1), and one Sb(1) atom. In the ninth O site, O(9) is bonded in a distorted rectangular see-saw-like geometry to one Ca(1), one La(1), one Co(1), and one Sb(2) atom. In the tenth O site, O(10) is bonded in a 5-coordinate geometry to one La(1), one La(2), one Co(2), one Pb(2), and one Sb(1) atom. In the eleventh O site, O(11) is bonded to one Ca(1), one La(1), one Co(1), one Pb(2), and one Sb(2) atom to form distorted corner-sharing OCaLaCoSbPb trigonal bipyramids. In the twelfth O site, O(12) is bonded in a distorted trigonal non-coplanar geometry to one La(2), one Co(2), and one Sb(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CaLa2Co2Sb2(PbO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.825
_cell_length_b   5.987
_cell_length_c   9.795
_cell_angle_alpha   76.198
_cell_angle_beta   93.243
_cell_angle_gamma   94.343
_symmetry_Int_Tables_number   1
_cell_volume   330.508
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ca  Ca0  1  0.487  0.702  0.414  1.0
  La  La1  1  0.515  0.483  0.780  1.0
  La  La2  1  0.001  0.926  0.167  1.0
  Co  Co3  1  0.007  0.576  0.563  1.0
  Co  Co4  1  0.511  0.936  0.985  1.0
  Sb  Sb5  1  0.028  0.477  0.979  1.0
  Sb  Sb6  1  0.464  0.125  0.565  1.0
  Pb  Pb7  1  0.559  0.315  0.193  1.0
  Pb  Pb8  1  0.952  0.997  0.759  1.0
  O  O9  1  0.588  0.934  0.195  1.0
  O  O10  1  0.095  0.595  0.774  1.0
  O  O11  1  0.446  0.055  0.775  1.0
  O  O12  1  0.958  0.338  0.179  1.0
  O  O13  1  0.099  0.788  0.387  1.0
  O  O14  1  0.753  0.683  0.956  1.0
  O  O15  1  0.731  0.354  0.570  1.0
  O  O16  1  0.302  0.273  0.003  1.0
  O  O17  1  0.292  0.418  0.574  1.0
  O  O18  1  0.808  0.219  0.933  1.0
  O  O19  1  0.670  0.820  0.605  1.0
  O  O20  1  0.221  0.738  0.029  1.0
[/CIF]
.