The structure described by MgLa2TiCoO6 crystallizes in the triclinic P-1 space group. Mg(1) is bonded in a square co-planar geometry to two equivalent O(2) and two equivalent O(3) atoms. La(1) is bonded in a 7-coordinate geometry to two equivalent O(2), two equivalent O(3), and three equivalent O(1) atoms. Ti(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. Co(1) is bonded in a square co-planar geometry to two equivalent O(2) and two equivalent O(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to three equivalent La(1) and one Ti(1) atom. In the second O site, O(2) is bonded to one Mg(1), two equivalent La(1), one Ti(1), and one Co(1) atom to form a mixture of distorted corner and edge-sharing OLa2MgTiCo trigonal bipyramids. In the third O site, O(3) is bonded in a 5-coordinate geometry to one Mg(1), two equivalent La(1), one Ti(1), and one Co(1) atom. is represented by the CIF card [CIF]
data_La2MgTiCoO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.076
_cell_length_b   5.575
_cell_length_c   6.531
_cell_angle_alpha   66.032
_cell_angle_beta   44.537
_cell_angle_gamma   69.398
_symmetry_Int_Tables_number   1
_cell_volume   187.564
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.028  0.875  0.762  1.0
  La  La1  1  0.972  0.125  0.238  1.0
  Mg  Mg2  1  0.500  0.500  0.000  1.0
  Ti  Ti3  1  0.000  0.500  0.500  1.0
  Co  Co4  1  0.500  0.000  0.000  1.0
  O  O5  1  0.032  0.284  0.817  1.0
  O  O6  1  0.241  0.731  0.295  1.0
  O  O7  1  0.968  0.716  0.183  1.0
  O  O8  1  0.759  0.269  0.705  1.0
  O  O9  1  0.248  0.257  0.232  1.0
  O  O10  1  0.752  0.743  0.768  1.0
[/CIF]
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The structure described by MgLa2TiCoO6 crystallizes in the triclinic P-1 space group. Mg(1) is bonded in a square co-planar geometry to two equivalent O(2) and two equivalent O(3) atoms. La(1) is bonded in a 7-coordinate geometry to two equivalent O(2), two equivalent O(3), and three equivalent O(1) atoms. Ti(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. Co(1) is bonded in a square co-planar geometry to two equivalent O(2) and two equivalent O(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to three equivalent La(1) and one Ti(1) atom. In the second O site, O(2) is bonded to one Mg(1), two equivalent La(1), one Ti(1), and one Co(1) atom to form a mixture of distorted corner and edge-sharing OLa2MgTiCo trigonal bipyramids. In the third O site, O(3) is bonded in a 5-coordinate geometry to one Mg(1), two equivalent La(1), one Ti(1), and one Co(1) atom. is represented by the CIF card [CIF]
data_La2MgTiCoO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.076
_cell_length_b   5.575
_cell_length_c   6.531
_cell_angle_alpha   66.032
_cell_angle_beta   44.537
_cell_angle_gamma   69.398
_symmetry_Int_Tables_number   1
_cell_volume   187.564
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.028  0.875  0.762  1.0
  La  La1  1  0.972  0.125  0.238  1.0
  Mg  Mg2  1  0.500  0.500  0.000  1.0
  Ti  Ti3  1  0.000  0.500  0.500  1.0
  Co  Co4  1  0.500  0.000  0.000  1.0
  O  O5  1  0.032  0.284  0.817  1.0
  O  O6  1  0.241  0.731  0.295  1.0
  O  O7  1  0.968  0.716  0.183  1.0
  O  O8  1  0.759  0.269  0.705  1.0
  O  O9  1  0.248  0.257  0.232  1.0
  O  O10  1  0.752  0.743  0.768  1.0
[/CIF]
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