The material structure described by VHO2 crystallizes in the orthorhombic Pnma space group. V(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form a mixture of corner and edge-sharing VO6 octahedra. The corner-sharing octahedral tilt angles are 55°. H(1) is bonded in a single-bond geometry to one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to three equivalent V(1) atoms. In the second O site, O(2) is bonded in a distorted single-bond geometry to three equivalent V(1) and one H(1) atom. is represented by the CIF card [CIF]
data_VHO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.081
_cell_length_b   4.592
_cell_length_c   9.843
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   139.256
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.000  0.302  0.655  1.0
  V  V1  1  0.000  0.698  0.155  1.0
  V  V2  1  0.500  0.198  0.363  1.0
  V  V3  1  0.500  0.802  0.863  1.0
  H  H4  1  0.000  0.649  0.423  1.0
  H  H5  1  0.000  0.351  0.923  1.0
  H  H6  1  0.500  0.851  0.595  1.0
  H  H7  1  0.500  0.149  0.095  1.0
  O  O8  1  0.000  0.958  0.307  1.0
  O  O9  1  0.000  0.042  0.807  1.0
  O  O10  1  0.500  0.542  0.712  1.0
  O  O11  1  0.500  0.458  0.212  1.0
  O  O12  1  0.000  0.446  0.454  1.0
  O  O13  1  0.000  0.554  0.954  1.0
  O  O14  1  0.500  0.054  0.564  1.0
  O  O15  1  0.500  0.946  0.064  1.0
[/CIF]
.
The material structure described by VHO2 crystallizes in the orthorhombic Pnma space group. V(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form a mixture of corner and edge-sharing VO6 octahedra. The corner-sharing octahedral tilt angles are 55°. H(1) is bonded in a single-bond geometry to one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to three equivalent V(1) atoms. In the second O site, O(2) is bonded in a distorted single-bond geometry to three equivalent V(1) and one H(1) atom. is represented by the CIF card [CIF]
data_VHO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.081
_cell_length_b   4.592
_cell_length_c   9.843
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   139.256
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.000  0.302  0.655  1.0
  V  V1  1  0.000  0.698  0.155  1.0
  V  V2  1  0.500  0.198  0.363  1.0
  V  V3  1  0.500  0.802  0.863  1.0
  H  H4  1  0.000  0.649  0.423  1.0
  H  H5  1  0.000  0.351  0.923  1.0
  H  H6  1  0.500  0.851  0.595  1.0
  H  H7  1  0.500  0.149  0.095  1.0
  O  O8  1  0.000  0.958  0.307  1.0
  O  O9  1  0.000  0.042  0.807  1.0
  O  O10  1  0.500  0.542  0.712  1.0
  O  O11  1  0.500  0.458  0.212  1.0
  O  O12  1  0.000  0.446  0.454  1.0
  O  O13  1  0.000  0.554  0.954  1.0
  O  O14  1  0.500  0.054  0.564  1.0
  O  O15  1  0.500  0.946  0.064  1.0
[/CIF]
.