The material structure described by Li(TiTe2)2 crystallizes in the monoclinic C2/m space group. Li(1) is bonded to two equivalent Te(1) and four equivalent Te(2) atoms to form LiTe6 octahedra that share corners with twelve equivalent Ti(1)Te6 octahedra, edges with two equivalent Li(1)Te6 octahedra, and faces with two equivalent Ti(1)Te6 octahedra. The corner-sharing octahedral tilt angles range from 47-48°. Ti(1) is bonded to three equivalent Te(1) and three equivalent Te(2) atoms to form TiTe6 octahedra that share corners with six equivalent Li(1)Te6 octahedra, edges with six equivalent Ti(1)Te6 octahedra, and  a faceface with one Li(1)Te6 octahedra. The corner-sharing octahedral tilt angles range from 47-48°. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a rectangular see-saw-like geometry to one Li(1) and three equivalent Ti(1) atoms. In the second Te site, Te(2) is bonded to two equivalent Li(1) and three equivalent Ti(1) atoms to form a mixture of distorted corner and edge-sharing TeLi2Ti3 trigonal bipyramids. is represented by the CIF file [CIF]
data_Li(TiTe2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.013
_cell_length_b   8.013
_cell_length_c   6.736
_cell_angle_alpha   64.975
_cell_angle_beta   64.975
_cell_angle_gamma   28.089
_symmetry_Int_Tables_number   1
_cell_volume   183.244
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.000  0.000  0.000  1.0
  Ti  Ti1  1  0.750  0.750  0.239  1.0
  Ti  Ti2  1  0.250  0.250  0.761  1.0
  Te  Te3  1  0.128  0.128  0.210  1.0
  Te  Te4  1  0.633  0.633  0.699  1.0
  Te  Te5  1  0.872  0.872  0.790  1.0
  Te  Te6  1  0.367  0.367  0.301  1.0
[/CIF]
.
The material structure described by Li(TiTe2)2 crystallizes in the monoclinic C2/m space group. Li(1) is bonded to two equivalent Te(1) and four equivalent Te(2) atoms to form LiTe6 octahedra that share corners with twelve equivalent Ti(1)Te6 octahedra, edges with two equivalent Li(1)Te6 octahedra, and faces with two equivalent Ti(1)Te6 octahedra. The corner-sharing octahedral tilt angles range from 47-48°. Ti(1) is bonded to three equivalent Te(1) and three equivalent Te(2) atoms to form TiTe6 octahedra that share corners with six equivalent Li(1)Te6 octahedra, edges with six equivalent Ti(1)Te6 octahedra, and  a faceface with one Li(1)Te6 octahedra. The corner-sharing octahedral tilt angles range from 47-48°. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a rectangular see-saw-like geometry to one Li(1) and three equivalent Ti(1) atoms. In the second Te site, Te(2) is bonded to two equivalent Li(1) and three equivalent Ti(1) atoms to form a mixture of distorted corner and edge-sharing TeLi2Ti3 trigonal bipyramids. is represented by the CIF file [CIF]
data_Li(TiTe2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.013
_cell_length_b   8.013
_cell_length_c   6.736
_cell_angle_alpha   64.975
_cell_angle_beta   64.975
_cell_angle_gamma   28.089
_symmetry_Int_Tables_number   1
_cell_volume   183.244
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.000  0.000  0.000  1.0
  Ti  Ti1  1  0.750  0.750  0.239  1.0
  Ti  Ti2  1  0.250  0.250  0.761  1.0
  Te  Te3  1  0.128  0.128  0.210  1.0
  Te  Te4  1  0.633  0.633  0.699  1.0
  Te  Te5  1  0.872  0.872  0.790  1.0
  Te  Te6  1  0.367  0.367  0.301  1.0
[/CIF]
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