The material described by K3PtHS2(O3Cl)2 crystallizes in the orthorhombic Cmc2_1 space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 8-coordinate geometry to one O(3), two equivalent O(2), three equivalent O(1), and two equivalent Cl(1) atoms. In the second K site, K(2) is bonded in a 6-coordinate geometry to two equivalent O(2) and four equivalent Cl(1) atoms. Pt(1) is bonded in a square co-planar geometry to two equivalent S(1) and two equivalent Cl(1) atoms. H(1) is bonded in a linear geometry to two equivalent O(3) atoms. S(1) is bonded in a distorted trigonal non-coplanar geometry to one Pt(1), one O(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to three equivalent K(1) and one S(1) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one K(2), two equivalent K(1), and one S(1) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one K(1), one H(1), and one S(1) atom. Cl(1) is bonded to two equivalent K(1), two equivalent K(2), and one Pt(1) atom to form a mixture of distorted corner and face-sharing ClK4Pt square pyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_K3HPtS2(ClO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.324
_cell_length_b   9.324
_cell_length_c   7.150
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   110.307
_symmetry_Int_Tables_number   1
_cell_volume   582.955
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.420  0.860  0.101  1.0
  K  K1  1  0.860  0.420  0.101  1.0
  K  K2  1  0.580  0.140  0.601  1.0
  K  K3  1  0.140  0.580  0.601  1.0
  K  K4  1  0.877  0.877  0.283  1.0
  K  K5  1  0.123  0.123  0.783  1.0
  H  H6  1  0.515  0.515  0.533  1.0
  H  H7  1  0.485  0.485  0.033  1.0
  Pt  Pt8  1  0.755  0.755  0.749  1.0
  Pt  Pt9  1  0.245  0.245  0.249  1.0
  S  S10  1  0.543  0.761  0.598  1.0
  S  S11  1  0.761  0.543  0.598  1.0
  S  S12  1  0.457  0.239  0.098  1.0
  S  S13  1  0.239  0.457  0.098  1.0
  Cl  Cl14  1  0.771  0.990  0.904  1.0
  Cl  Cl15  1  0.990  0.771  0.904  1.0
  Cl  Cl16  1  0.229  0.010  0.404  1.0
  Cl  Cl17  1  0.010  0.229  0.404  1.0
  O  O18  1  0.443  0.820  0.712  1.0
  O  O19  1  0.820  0.443  0.712  1.0
  O  O20  1  0.557  0.180  0.212  1.0
  O  O21  1  0.180  0.557  0.212  1.0
  O  O22  1  0.596  0.858  0.428  1.0
  O  O23  1  0.858  0.596  0.428  1.0
  O  O24  1  0.404  0.142  0.928  1.0
  O  O25  1  0.142  0.404  0.928  1.0
  O  O26  1  0.442  0.599  0.536  1.0
  O  O27  1  0.599  0.442  0.536  1.0
  O  O28  1  0.558  0.401  0.036  1.0
  O  O29  1  0.401  0.558  0.036  1.0
[/CIF]
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The material described by K3PtHS2(O3Cl)2 crystallizes in the orthorhombic Cmc2_1 space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 8-coordinate geometry to one O(3), two equivalent O(2), three equivalent O(1), and two equivalent Cl(1) atoms. In the second K site, K(2) is bonded in a 6-coordinate geometry to two equivalent O(2) and four equivalent Cl(1) atoms. Pt(1) is bonded in a square co-planar geometry to two equivalent S(1) and two equivalent Cl(1) atoms. H(1) is bonded in a linear geometry to two equivalent O(3) atoms. S(1) is bonded in a distorted trigonal non-coplanar geometry to one Pt(1), one O(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to three equivalent K(1) and one S(1) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one K(2), two equivalent K(1), and one S(1) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one K(1), one H(1), and one S(1) atom. Cl(1) is bonded to two equivalent K(1), two equivalent K(2), and one Pt(1) atom to form a mixture of distorted corner and face-sharing ClK4Pt square pyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_K3HPtS2(ClO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.324
_cell_length_b   9.324
_cell_length_c   7.150
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   110.307
_symmetry_Int_Tables_number   1
_cell_volume   582.955
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.420  0.860  0.101  1.0
  K  K1  1  0.860  0.420  0.101  1.0
  K  K2  1  0.580  0.140  0.601  1.0
  K  K3  1  0.140  0.580  0.601  1.0
  K  K4  1  0.877  0.877  0.283  1.0
  K  K5  1  0.123  0.123  0.783  1.0
  H  H6  1  0.515  0.515  0.533  1.0
  H  H7  1  0.485  0.485  0.033  1.0
  Pt  Pt8  1  0.755  0.755  0.749  1.0
  Pt  Pt9  1  0.245  0.245  0.249  1.0
  S  S10  1  0.543  0.761  0.598  1.0
  S  S11  1  0.761  0.543  0.598  1.0
  S  S12  1  0.457  0.239  0.098  1.0
  S  S13  1  0.239  0.457  0.098  1.0
  Cl  Cl14  1  0.771  0.990  0.904  1.0
  Cl  Cl15  1  0.990  0.771  0.904  1.0
  Cl  Cl16  1  0.229  0.010  0.404  1.0
  Cl  Cl17  1  0.010  0.229  0.404  1.0
  O  O18  1  0.443  0.820  0.712  1.0
  O  O19  1  0.820  0.443  0.712  1.0
  O  O20  1  0.557  0.180  0.212  1.0
  O  O21  1  0.180  0.557  0.212  1.0
  O  O22  1  0.596  0.858  0.428  1.0
  O  O23  1  0.858  0.596  0.428  1.0
  O  O24  1  0.404  0.142  0.928  1.0
  O  O25  1  0.142  0.404  0.928  1.0
  O  O26  1  0.442  0.599  0.536  1.0
  O  O27  1  0.599  0.442  0.536  1.0
  O  O28  1  0.558  0.401  0.036  1.0
  O  O29  1  0.401  0.558  0.036  1.0
[/CIF]
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