The material structure described by Tm2MnS4 crystallizes in the tetragonal I-42d space group. Tm(1) is bonded in a 8-coordinate geometry to eight equivalent S(1) atoms. Mn(1) is bonded in a 4-coordinate geometry to eight equivalent S(1) atoms. S(1) is bonded in a 6-coordinate geometry to four equivalent Tm(1) and two equivalent Mn(1) atoms. is represented by the CIF file [CIF]
data_Tm2MnS4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.105
_cell_length_b   7.105
_cell_length_c   7.105
_cell_angle_alpha   110.620
_cell_angle_beta   110.620
_cell_angle_gamma   107.198
_symmetry_Int_Tables_number   1
_cell_volume   275.801
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tm  Tm0  1  0.875  0.488  0.113  1.0
  Tm  Tm1  1  0.238  0.125  0.613  1.0
  Tm  Tm2  1  0.375  0.762  0.887  1.0
  Tm  Tm3  1  0.512  0.625  0.387  1.0
  Mn  Mn4  1  0.750  0.250  0.500  1.0
  Mn  Mn5  1  0.000  0.000  0.000  1.0
  S  S6  1  0.634  0.001  0.766  1.0
  S  S7  1  0.618  0.485  0.734  1.0
  S  S8  1  0.515  0.249  0.134  1.0
  S  S9  1  0.132  0.366  0.366  1.0
  S  S10  1  0.751  0.884  0.266  1.0
  S  S11  1  0.116  0.382  0.866  1.0
  S  S12  1  0.999  0.765  0.634  1.0
  S  S13  1  0.235  0.868  0.234  1.0
[/CIF]
.
The material structure described by Tm2MnS4 crystallizes in the tetragonal I-42d space group. Tm(1) is bonded in a 8-coordinate geometry to eight equivalent S(1) atoms. Mn(1) is bonded in a 4-coordinate geometry to eight equivalent S(1) atoms. S(1) is bonded in a 6-coordinate geometry to four equivalent Tm(1) and two equivalent Mn(1) atoms. is represented by the CIF file [CIF]
data_Tm2MnS4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.105
_cell_length_b   7.105
_cell_length_c   7.105
_cell_angle_alpha   110.620
_cell_angle_beta   110.620
_cell_angle_gamma   107.198
_symmetry_Int_Tables_number   1
_cell_volume   275.801
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tm  Tm0  1  0.875  0.488  0.113  1.0
  Tm  Tm1  1  0.238  0.125  0.613  1.0
  Tm  Tm2  1  0.375  0.762  0.887  1.0
  Tm  Tm3  1  0.512  0.625  0.387  1.0
  Mn  Mn4  1  0.750  0.250  0.500  1.0
  Mn  Mn5  1  0.000  0.000  0.000  1.0
  S  S6  1  0.634  0.001  0.766  1.0
  S  S7  1  0.618  0.485  0.734  1.0
  S  S8  1  0.515  0.249  0.134  1.0
  S  S9  1  0.132  0.366  0.366  1.0
  S  S10  1  0.751  0.884  0.266  1.0
  S  S11  1  0.116  0.382  0.866  1.0
  S  S12  1  0.999  0.765  0.634  1.0
  S  S13  1  0.235  0.868  0.234  1.0
[/CIF]
.