The structure described by KLiHoF5 crystallizes in the monoclinic P2_1/c space group. K(1) is bonded in a 9-coordinate geometry to one F(4), two equivalent F(1), two equivalent F(2), two equivalent F(3), and two equivalent F(5) atoms. Li(1) is bonded to one F(4), one F(5), and two equivalent F(1) atoms to form distorted corner-sharing LiF4 tetrahedra. Ho(1) is bonded in a 8-coordinate geometry to one F(1), one F(5), two equivalent F(2), two equivalent F(3), and two equivalent F(4) atoms. There are five inequivalent F sites. In the first F site, F(1) is bonded in a 4-coordinate geometry to two equivalent K(1), two equivalent Li(1), and one Ho(1) atom. In the second F site, F(2) is bonded in a 4-coordinate geometry to two equivalent K(1) and two equivalent Ho(1) atoms. In the third F site, F(3) is bonded to two equivalent K(1) and two equivalent Ho(1) atoms to form distorted FK2Ho2 tetrahedra that share corners with four equivalent F(5)K2LiHo tetrahedra,  an edgeedge with one F(5)K2LiHo tetrahedra, and edges with two equivalent F(3)K2Ho2 tetrahedra. In the fourth F site, F(4) is bonded in a 3-coordinate geometry to one K(1), one Li(1), and two equivalent Ho(1) atoms. In the fifth F site, F(5) is bonded to two equivalent K(1), one Li(1), and one Ho(1) atom to form distorted FK2LiHo tetrahedra that share corners with two equivalent F(5)K2LiHo tetrahedra, corners with four equivalent F(3)K2Ho2 tetrahedra, and  an edgeedge with one F(3)K2Ho2 tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_KLiHoF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.515
_cell_length_b   6.359
_cell_length_c   11.903
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   113.834
_symmetry_Int_Tables_number   1
_cell_volume   451.078
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.947  0.963  0.350  1.0
  K  K1  1  0.053  0.037  0.650  1.0
  K  K2  1  0.053  0.537  0.850  1.0
  K  K3  1  0.947  0.463  0.150  1.0
  Li  Li4  1  0.558  0.962  0.746  1.0
  Li  Li5  1  0.442  0.038  0.254  1.0
  Li  Li6  1  0.442  0.538  0.246  1.0
  Li  Li7  1  0.558  0.462  0.754  1.0
  Ho  Ho8  1  0.682  0.821  0.998  1.0
  Ho  Ho9  1  0.318  0.179  0.002  1.0
  Ho  Ho10  1  0.318  0.679  0.498  1.0
  Ho  Ho11  1  0.682  0.321  0.502  1.0
  F  F12  1  0.721  0.778  0.806  1.0
  F  F13  1  0.279  0.222  0.194  1.0
  F  F14  1  0.279  0.722  0.306  1.0
  F  F15  1  0.721  0.278  0.694  1.0
  F  F16  1  0.664  0.952  0.531  1.0
  F  F17  1  0.336  0.048  0.469  1.0
  F  F18  1  0.336  0.548  0.031  1.0
  F  F19  1  0.664  0.452  0.969  1.0
  F  F20  1  0.956  0.673  0.507  1.0
  F  F21  1  0.044  0.327  0.493  1.0
  F  F22  1  0.044  0.827  0.007  1.0
  F  F23  1  0.956  0.173  0.993  1.0
  F  F24  1  0.464  0.966  0.896  1.0
  F  F25  1  0.536  0.034  0.104  1.0
  F  F26  1  0.536  0.534  0.396  1.0
  F  F27  1  0.464  0.466  0.604  1.0
  F  F28  1  0.287  0.778  0.674  1.0
  F  F29  1  0.713  0.222  0.326  1.0
  F  F30  1  0.713  0.722  0.174  1.0
  F  F31  1  0.287  0.278  0.826  1.0
[/CIF]
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The structure described by KLiHoF5 crystallizes in the monoclinic P2_1/c space group. K(1) is bonded in a 9-coordinate geometry to one F(4), two equivalent F(1), two equivalent F(2), two equivalent F(3), and two equivalent F(5) atoms. Li(1) is bonded to one F(4), one F(5), and two equivalent F(1) atoms to form distorted corner-sharing LiF4 tetrahedra. Ho(1) is bonded in a 8-coordinate geometry to one F(1), one F(5), two equivalent F(2), two equivalent F(3), and two equivalent F(4) atoms. There are five inequivalent F sites. In the first F site, F(1) is bonded in a 4-coordinate geometry to two equivalent K(1), two equivalent Li(1), and one Ho(1) atom. In the second F site, F(2) is bonded in a 4-coordinate geometry to two equivalent K(1) and two equivalent Ho(1) atoms. In the third F site, F(3) is bonded to two equivalent K(1) and two equivalent Ho(1) atoms to form distorted FK2Ho2 tetrahedra that share corners with four equivalent F(5)K2LiHo tetrahedra,  an edgeedge with one F(5)K2LiHo tetrahedra, and edges with two equivalent F(3)K2Ho2 tetrahedra. In the fourth F site, F(4) is bonded in a 3-coordinate geometry to one K(1), one Li(1), and two equivalent Ho(1) atoms. In the fifth F site, F(5) is bonded to two equivalent K(1), one Li(1), and one Ho(1) atom to form distorted FK2LiHo tetrahedra that share corners with two equivalent F(5)K2LiHo tetrahedra, corners with four equivalent F(3)K2Ho2 tetrahedra, and  an edgeedge with one F(3)K2Ho2 tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_KLiHoF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.515
_cell_length_b   6.359
_cell_length_c   11.903
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   113.834
_symmetry_Int_Tables_number   1
_cell_volume   451.078
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.947  0.963  0.350  1.0
  K  K1  1  0.053  0.037  0.650  1.0
  K  K2  1  0.053  0.537  0.850  1.0
  K  K3  1  0.947  0.463  0.150  1.0
  Li  Li4  1  0.558  0.962  0.746  1.0
  Li  Li5  1  0.442  0.038  0.254  1.0
  Li  Li6  1  0.442  0.538  0.246  1.0
  Li  Li7  1  0.558  0.462  0.754  1.0
  Ho  Ho8  1  0.682  0.821  0.998  1.0
  Ho  Ho9  1  0.318  0.179  0.002  1.0
  Ho  Ho10  1  0.318  0.679  0.498  1.0
  Ho  Ho11  1  0.682  0.321  0.502  1.0
  F  F12  1  0.721  0.778  0.806  1.0
  F  F13  1  0.279  0.222  0.194  1.0
  F  F14  1  0.279  0.722  0.306  1.0
  F  F15  1  0.721  0.278  0.694  1.0
  F  F16  1  0.664  0.952  0.531  1.0
  F  F17  1  0.336  0.048  0.469  1.0
  F  F18  1  0.336  0.548  0.031  1.0
  F  F19  1  0.664  0.452  0.969  1.0
  F  F20  1  0.956  0.673  0.507  1.0
  F  F21  1  0.044  0.327  0.493  1.0
  F  F22  1  0.044  0.827  0.007  1.0
  F  F23  1  0.956  0.173  0.993  1.0
  F  F24  1  0.464  0.966  0.896  1.0
  F  F25  1  0.536  0.034  0.104  1.0
  F  F26  1  0.536  0.534  0.396  1.0
  F  F27  1  0.464  0.466  0.604  1.0
  F  F28  1  0.287  0.778  0.674  1.0
  F  F29  1  0.713  0.222  0.326  1.0
  F  F30  1  0.713  0.722  0.174  1.0
  F  F31  1  0.287  0.278  0.826  1.0
[/CIF]
.