The material structure described by RbZrMnF7 crystallizes in the orthorhombic Cmcm space group. Rb(1) is bonded in a 10-coordinate geometry to two equivalent F(3), four equivalent F(1), and four equivalent F(2) atoms. Zr(1) is bonded to one F(4), two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms to form ZrF7 pentagonal bipyramids that share corners with three equivalent Mn(1)F7 pentagonal bipyramids and edges with two equivalent Mn(1)F7 pentagonal bipyramids. Mn(1) is bonded to one F(4), two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms to form MnF7 pentagonal bipyramids that share corners with three equivalent Zr(1)F7 pentagonal bipyramids and edges with two equivalent Zr(1)F7 pentagonal bipyramids. There are four inequivalent F sites. In the first F site, F(1) is bonded to two equivalent Rb(1), one Zr(1), and one Mn(1) atom to form a mixture of distorted corner, edge, and face-sharing FRb2ZrMn tetrahedra. In the second F site, F(2) is bonded to two equivalent Rb(1), one Zr(1), and one Mn(1) atom to form a mixture of distorted corner, edge, and face-sharing FRb2ZrMn tetrahedra. In the third F site, F(3) is bonded in a linear geometry to one Rb(1), one Zr(1), and one Mn(1) atom. In the fourth F site, F(4) is bonded in a linear geometry to one Zr(1) and one Mn(1) atom. is represented by the CIF card [CIF]
data_RbZrMnF7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.544
_cell_length_b   6.544
_cell_length_c   8.424
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   117.662
_symmetry_Int_Tables_number   1
_cell_volume   319.496
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.500  0.500  0.500  1.0
  Rb  Rb1  1  0.500  0.500  0.000  1.0
  Zr  Zr2  1  0.807  0.193  0.250  1.0
  Zr  Zr3  1  0.193  0.807  0.750  1.0
  Mn  Mn4  1  0.189  0.811  0.250  1.0
  Mn  Mn5  1  0.811  0.189  0.750  1.0
  F  F6  1  0.841  0.554  0.750  1.0
  F  F7  1  0.159  0.446  0.250  1.0
  F  F8  1  0.164  0.467  0.750  1.0
  F  F9  1  0.800  0.200  0.494  1.0
  F  F10  1  0.446  0.159  0.750  1.0
  F  F11  1  0.800  0.200  0.006  1.0
  F  F12  1  0.200  0.800  0.994  1.0
  F  F13  1  0.836  0.533  0.250  1.0
  F  F14  1  0.554  0.841  0.250  1.0
  F  F15  1  0.993  0.007  0.250  1.0
  F  F16  1  0.007  0.993  0.750  1.0
  F  F17  1  0.200  0.800  0.506  1.0
  F  F18  1  0.533  0.836  0.750  1.0
  F  F19  1  0.467  0.164  0.250  1.0
[/CIF]
.
The material structure described by RbZrMnF7 crystallizes in the orthorhombic Cmcm space group. Rb(1) is bonded in a 10-coordinate geometry to two equivalent F(3), four equivalent F(1), and four equivalent F(2) atoms. Zr(1) is bonded to one F(4), two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms to form ZrF7 pentagonal bipyramids that share corners with three equivalent Mn(1)F7 pentagonal bipyramids and edges with two equivalent Mn(1)F7 pentagonal bipyramids. Mn(1) is bonded to one F(4), two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms to form MnF7 pentagonal bipyramids that share corners with three equivalent Zr(1)F7 pentagonal bipyramids and edges with two equivalent Zr(1)F7 pentagonal bipyramids. There are four inequivalent F sites. In the first F site, F(1) is bonded to two equivalent Rb(1), one Zr(1), and one Mn(1) atom to form a mixture of distorted corner, edge, and face-sharing FRb2ZrMn tetrahedra. In the second F site, F(2) is bonded to two equivalent Rb(1), one Zr(1), and one Mn(1) atom to form a mixture of distorted corner, edge, and face-sharing FRb2ZrMn tetrahedra. In the third F site, F(3) is bonded in a linear geometry to one Rb(1), one Zr(1), and one Mn(1) atom. In the fourth F site, F(4) is bonded in a linear geometry to one Zr(1) and one Mn(1) atom. is represented by the CIF card [CIF]
data_RbZrMnF7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.544
_cell_length_b   6.544
_cell_length_c   8.424
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   117.662
_symmetry_Int_Tables_number   1
_cell_volume   319.496
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.500  0.500  0.500  1.0
  Rb  Rb1  1  0.500  0.500  0.000  1.0
  Zr  Zr2  1  0.807  0.193  0.250  1.0
  Zr  Zr3  1  0.193  0.807  0.750  1.0
  Mn  Mn4  1  0.189  0.811  0.250  1.0
  Mn  Mn5  1  0.811  0.189  0.750  1.0
  F  F6  1  0.841  0.554  0.750  1.0
  F  F7  1  0.159  0.446  0.250  1.0
  F  F8  1  0.164  0.467  0.750  1.0
  F  F9  1  0.800  0.200  0.494  1.0
  F  F10  1  0.446  0.159  0.750  1.0
  F  F11  1  0.800  0.200  0.006  1.0
  F  F12  1  0.200  0.800  0.994  1.0
  F  F13  1  0.836  0.533  0.250  1.0
  F  F14  1  0.554  0.841  0.250  1.0
  F  F15  1  0.993  0.007  0.250  1.0
  F  F16  1  0.007  0.993  0.750  1.0
  F  F17  1  0.200  0.800  0.506  1.0
  F  F18  1  0.533  0.836  0.750  1.0
  F  F19  1  0.467  0.164  0.250  1.0
[/CIF]
.