The material structure described by RbC2PH6(NO)4 crystallizes in the orthorhombic Fdd2 space group. Rb(1) is bonded in a distorted body-centered cubic geometry to four equivalent O(1) and four equivalent O(2) atoms. C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one O(1) atom. P(1) is bonded in a tetrahedral geometry to two equivalent N(2) and two equivalent O(2) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(1), one H(1), and one H(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(1), one P(1), and one H(3) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to two equivalent Rb(1) and one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to two equivalent Rb(1) and one P(1) atom. is represented by the CIF file [CIF]
data_RbPH6C2(NO)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.900
_cell_length_b   7.900
_cell_length_c   8.390
_cell_angle_alpha   115.463
_cell_angle_beta   115.463
_cell_angle_gamma   94.984
_symmetry_Int_Tables_number   1
_cell_volume   402.460
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.263  0.737  0.500  1.0
  Rb  Rb1  1  0.013  0.987  0.000  1.0
  P  P2  1  0.586  0.414  0.500  1.0
  P  P3  1  0.336  0.664  0.000  1.0
  H  H4  1  0.094  0.112  0.474  1.0
  H  H5  1  0.888  0.906  0.526  1.0
  H  H6  1  0.870  0.388  0.026  1.0
  H  H7  1  0.612  0.130  0.974  1.0
  H  H8  1  0.174  0.372  0.601  1.0
  H  H9  1  0.628  0.826  0.399  1.0
  H  H10  1  0.823  0.521  0.899  1.0
  H  H11  1  0.479  0.177  0.101  1.0
  H  H12  1  0.312  0.419  0.086  1.0
  H  H13  1  0.581  0.688  0.914  1.0
  H  H14  1  0.476  0.082  0.414  1.0
  H  H15  1  0.918  0.524  0.586  1.0
  C  C16  1  0.203  0.249  0.780  1.0
  C  C17  1  0.751  0.797  0.220  1.0
  C  C18  1  0.673  0.219  0.720  1.0
  C  C19  1  0.781  0.327  0.280  1.0
  N  N20  1  0.177  0.246  0.608  1.0
  N  N21  1  0.754  0.823  0.392  1.0
  N  N22  1  0.818  0.388  0.892  1.0
  N  N23  1  0.612  0.182  0.108  1.0
  N  N24  1  0.279  0.430  0.959  1.0
  N  N25  1  0.570  0.721  0.041  1.0
  N  N26  1  0.570  0.221  0.541  1.0
  N  N27  1  0.779  0.430  0.459  1.0
  O  O28  1  0.163  0.088  0.777  1.0
  O  O29  1  0.912  0.837  0.223  1.0
  O  O30  1  0.635  0.061  0.723  1.0
  O  O31  1  0.939  0.365  0.277  1.0
  O  O32  1  0.651  0.606  0.696  1.0
  O  O33  1  0.394  0.349  0.304  1.0
  O  O34  1  0.205  0.660  0.804  1.0
  O  O35  1  0.340  0.795  0.196  1.0
[/CIF]
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The material structure described by RbC2PH6(NO)4 crystallizes in the orthorhombic Fdd2 space group. Rb(1) is bonded in a distorted body-centered cubic geometry to four equivalent O(1) and four equivalent O(2) atoms. C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one O(1) atom. P(1) is bonded in a tetrahedral geometry to two equivalent N(2) and two equivalent O(2) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(1), one H(1), and one H(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(1), one P(1), and one H(3) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to two equivalent Rb(1) and one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to two equivalent Rb(1) and one P(1) atom. is represented by the CIF file [CIF]
data_RbPH6C2(NO)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.900
_cell_length_b   7.900
_cell_length_c   8.390
_cell_angle_alpha   115.463
_cell_angle_beta   115.463
_cell_angle_gamma   94.984
_symmetry_Int_Tables_number   1
_cell_volume   402.460
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.263  0.737  0.500  1.0
  Rb  Rb1  1  0.013  0.987  0.000  1.0
  P  P2  1  0.586  0.414  0.500  1.0
  P  P3  1  0.336  0.664  0.000  1.0
  H  H4  1  0.094  0.112  0.474  1.0
  H  H5  1  0.888  0.906  0.526  1.0
  H  H6  1  0.870  0.388  0.026  1.0
  H  H7  1  0.612  0.130  0.974  1.0
  H  H8  1  0.174  0.372  0.601  1.0
  H  H9  1  0.628  0.826  0.399  1.0
  H  H10  1  0.823  0.521  0.899  1.0
  H  H11  1  0.479  0.177  0.101  1.0
  H  H12  1  0.312  0.419  0.086  1.0
  H  H13  1  0.581  0.688  0.914  1.0
  H  H14  1  0.476  0.082  0.414  1.0
  H  H15  1  0.918  0.524  0.586  1.0
  C  C16  1  0.203  0.249  0.780  1.0
  C  C17  1  0.751  0.797  0.220  1.0
  C  C18  1  0.673  0.219  0.720  1.0
  C  C19  1  0.781  0.327  0.280  1.0
  N  N20  1  0.177  0.246  0.608  1.0
  N  N21  1  0.754  0.823  0.392  1.0
  N  N22  1  0.818  0.388  0.892  1.0
  N  N23  1  0.612  0.182  0.108  1.0
  N  N24  1  0.279  0.430  0.959  1.0
  N  N25  1  0.570  0.721  0.041  1.0
  N  N26  1  0.570  0.221  0.541  1.0
  N  N27  1  0.779  0.430  0.459  1.0
  O  O28  1  0.163  0.088  0.777  1.0
  O  O29  1  0.912  0.837  0.223  1.0
  O  O30  1  0.635  0.061  0.723  1.0
  O  O31  1  0.939  0.365  0.277  1.0
  O  O32  1  0.651  0.606  0.696  1.0
  O  O33  1  0.394  0.349  0.304  1.0
  O  O34  1  0.205  0.660  0.804  1.0
  O  O35  1  0.340  0.795  0.196  1.0
[/CIF]
.