The crystal structure described by K3GeNH2O3 crystallizes in the triclinic P-1 space group. There are three inequivalent K sites. In the first K site, K(1) is bonded in a 5-coordinate geometry to one O(3), two equivalent O(1), and two equivalent O(2) atoms. In the second K site, K(2) is bonded in a 7-coordinate geometry to one N(1), one H(1), one H(2), one O(2), one O(3), and two equivalent O(1) atoms. In the third K site, K(3) is bonded in a 7-coordinate geometry to one N(1), one H(2), one O(1), two equivalent O(2), and two equivalent O(3) atoms. Ge(1) is bonded in a tetrahedral geometry to one N(1), one O(1), one O(2), and one O(3) atom. N(1) is bonded in a 2-coordinate geometry to one K(2), one K(3), one Ge(1), one H(1), and one H(2) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one K(2) and one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one K(2), one K(3), and one N(1) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 6-coordinate geometry to one K(3), two equivalent K(1), two equivalent K(2), and one Ge(1) atom. In the second O site, O(2) is bonded in a 1-coordinate geometry to one K(2), two equivalent K(1), two equivalent K(3), and one Ge(1) atom. In the third O site, O(3) is bonded in a 5-coordinate geometry to one K(1), one K(2), two equivalent K(3), and one Ge(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_K3GeH2NO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.468
_cell_length_b   6.777
_cell_length_c   7.297
_cell_angle_alpha   96.291
_cell_angle_beta   101.423
_cell_angle_gamma   91.607
_symmetry_Int_Tables_number   1
_cell_volume   311.248
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.762  0.091  0.029  1.0
  K  K1  1  0.238  0.909  0.971  1.0
  K  K2  1  0.654  0.199  0.483  1.0
  K  K3  1  0.346  0.801  0.517  1.0
  K  K4  1  0.717  0.523  0.870  1.0
  K  K5  1  0.283  0.477  0.130  1.0
  Ge  Ge6  1  0.786  0.702  0.303  1.0
  Ge  Ge7  1  0.214  0.298  0.697  1.0
  H  H8  1  0.886  0.890  0.625  1.0
  H  H9  1  0.114  0.110  0.375  1.0
  H  H10  1  0.968  0.664  0.631  1.0
  H  H11  1  0.032  0.336  0.369  1.0
  N  N12  1  0.840  0.743  0.577  1.0
  N  N13  1  0.160  0.257  0.423  1.0
  O  O14  1  0.566  0.850  0.237  1.0
  O  O15  1  0.434  0.150  0.763  1.0
  O  O16  1  0.996  0.220  0.792  1.0
  O  O17  1  0.004  0.780  0.208  1.0
  O  O18  1  0.723  0.445  0.239  1.0
  O  O19  1  0.277  0.555  0.761  1.0
[/CIF]
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The crystal structure described by K3GeNH2O3 crystallizes in the triclinic P-1 space group. There are three inequivalent K sites. In the first K site, K(1) is bonded in a 5-coordinate geometry to one O(3), two equivalent O(1), and two equivalent O(2) atoms. In the second K site, K(2) is bonded in a 7-coordinate geometry to one N(1), one H(1), one H(2), one O(2), one O(3), and two equivalent O(1) atoms. In the third K site, K(3) is bonded in a 7-coordinate geometry to one N(1), one H(2), one O(1), two equivalent O(2), and two equivalent O(3) atoms. Ge(1) is bonded in a tetrahedral geometry to one N(1), one O(1), one O(2), and one O(3) atom. N(1) is bonded in a 2-coordinate geometry to one K(2), one K(3), one Ge(1), one H(1), and one H(2) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one K(2) and one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one K(2), one K(3), and one N(1) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 6-coordinate geometry to one K(3), two equivalent K(1), two equivalent K(2), and one Ge(1) atom. In the second O site, O(2) is bonded in a 1-coordinate geometry to one K(2), two equivalent K(1), two equivalent K(3), and one Ge(1) atom. In the third O site, O(3) is bonded in a 5-coordinate geometry to one K(1), one K(2), two equivalent K(3), and one Ge(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_K3GeH2NO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.468
_cell_length_b   6.777
_cell_length_c   7.297
_cell_angle_alpha   96.291
_cell_angle_beta   101.423
_cell_angle_gamma   91.607
_symmetry_Int_Tables_number   1
_cell_volume   311.248
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.762  0.091  0.029  1.0
  K  K1  1  0.238  0.909  0.971  1.0
  K  K2  1  0.654  0.199  0.483  1.0
  K  K3  1  0.346  0.801  0.517  1.0
  K  K4  1  0.717  0.523  0.870  1.0
  K  K5  1  0.283  0.477  0.130  1.0
  Ge  Ge6  1  0.786  0.702  0.303  1.0
  Ge  Ge7  1  0.214  0.298  0.697  1.0
  H  H8  1  0.886  0.890  0.625  1.0
  H  H9  1  0.114  0.110  0.375  1.0
  H  H10  1  0.968  0.664  0.631  1.0
  H  H11  1  0.032  0.336  0.369  1.0
  N  N12  1  0.840  0.743  0.577  1.0
  N  N13  1  0.160  0.257  0.423  1.0
  O  O14  1  0.566  0.850  0.237  1.0
  O  O15  1  0.434  0.150  0.763  1.0
  O  O16  1  0.996  0.220  0.792  1.0
  O  O17  1  0.004  0.780  0.208  1.0
  O  O18  1  0.723  0.445  0.239  1.0
  O  O19  1  0.277  0.555  0.761  1.0
[/CIF]
.