The structure described by Li5Mn2Fe3O10 is Caswellsilverite-derived structured and crystallizes in the triclinic P1 space group. There are ten inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(13), one O(15), one O(17), one O(19), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  a cornercorner with one Li(9)O6 octahedra,  a cornercorner with one Fe(1)O6 octahedra,  a cornercorner with one Fe(4)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Fe(2)O6 octahedra,  an edgeedge with one Fe(6)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and edges with two equivalent Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-16°. In the second Li site, Li(2) is bonded to one O(10), one O(12), one O(14), one O(16), one O(18), and one O(20) atom to form LiO6 octahedra that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  a cornercorner with one Fe(1)O6 octahedra,  a cornercorner with one Fe(4)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Fe(3)O6 octahedra,  an edgeedge with one Fe(5)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, and edges with two equivalent Mn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-17°. In the third Li site, Li(3) is bonded to one O(11), one O(13), one O(17), one O(19), one O(3), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Fe(2)O6 octahedra,  a cornercorner with one Fe(5)O6 octahedra,  a cornercorner with one Fe(6)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Fe(4)O6 octahedra,  an edgeedge with one Fe(6)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Li(9)O6 octahedra, and edges with two equivalent Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-16°. In the fourth Li site, Li(4) is bonded to one O(10), one O(12), one O(14), one O(18), one O(20), and one O(4) atom to form distorted LiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Fe(2)O6 octahedra,  a cornercorner with one Fe(3)O6 octahedra,  a cornercorner with one Fe(5)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Fe(1)O6 octahedra,  an edgeedge with one Fe(3)O6 octahedra, edges with two equivalent Li(10)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, and edges with two equivalent Mn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-12°. In the fifth Li site, Li(5) is bonded to one O(1), one O(11), one O(15), one O(17), one O(19), and one O(9) atom to form distorted LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Fe(2)O6 octahedra,  a cornercorner with one Fe(3)O6 octahedra,  a cornercorner with one Fe(6)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Fe(1)O6 octahedra,  an edgeedge with one Fe(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(7)O6 octahedra, and edges with two equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-11°. In the sixth Li site, Li(6) is bonded to one O(10), one O(12), one O(16), one O(18), one O(2), and one O(20) atom to form LiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Fe(3)O6 octahedra,  a cornercorner with one Fe(5)O6 octahedra,  a cornercorner with one Fe(6)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Fe(4)O6 octahedra,  an edgeedge with one Fe(5)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(8)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-17°. In the seventh Li site, Li(7) is bonded to one O(1), one O(15), one O(17), one O(5), one O(8), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Fe(2)O6 octahedra,  a cornercorner with one Fe(3)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Fe(3)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Fe(1)O6 octahedra, and edges with two equivalent Fe(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-10°. In the eighth Li site, Li(8) is bonded to one O(10), one O(16), one O(18), one O(2), one O(6), and one O(7) atom to form distorted LiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Fe(5)O6 octahedra,  a cornercorner with one Fe(6)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Fe(6)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with two equivalent Fe(4)O6 octahedra, and edges with two equivalent Fe(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-17°. In the ninth Li site, Li(9) is bonded to one O(11), one O(13), one O(19), one O(3), one O(6), and one O(7) atom to form distorted LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Fe(5)O6 octahedra,  a cornercorner with one Fe(6)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Fe(5)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, edges with two equivalent Fe(4)O6 octahedra, and edges with two equivalent Fe(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-16°. In the tenth Li site, Li(10) is bonded to one O(12), one O(14), one O(20), one O(4), one O(5), and one O(8) atom to form LiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Fe(2)O6 octahedra,  a cornercorner with one Fe(3)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Fe(2)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Mn(4)O6 octahedra, edges with two equivalent Fe(1)O6 octahedra, and edges with two equivalent Fe(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-14°. There are four inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(11), one O(15), one O(17), one O(5), and one O(9) atom to form MnO6 octahedra that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  a cornercorner with one Li(9)O6 octahedra,  a cornercorner with one Fe(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Fe(1)O6 octahedra,  an edgeedge with one Fe(3)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Li(7)O6 octahedra, and edges with two equivalent Fe(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-16°. In the second Mn site, Mn(2) is bonded to one O(10), one O(12), one O(16), one O(18), one O(2), and one O(6) atom to form MnO6 octahedra that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  a cornercorner with one Li(9)O6 octahedra,  a cornercorner with one Fe(4)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Fe(4)O6 octahedra,  an edgeedge with one Fe(6)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, edges with two equivalent Li(8)O6 octahedra, and edges with two equivalent Fe(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-13°. In the third Mn site, Mn(3) is bonded to one O(11), one O(13), one O(19), one O(3), one O(7), and one O(9) atom to form MnO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  a cornercorner with one Li(9)O6 octahedra,  a cornercorner with one Fe(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Fe(4)O6 octahedra,  an edgeedge with one Fe(5)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(9)O6 octahedra, and edges with two equivalent Fe(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-12°. In the fourth Mn site, Mn(4) is bonded to one O(10), one O(12), one O(14), one O(20), one O(4), and one O(8) atom to form MnO6 octahedra that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  a cornercorner with one Fe(1)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Fe(1)O6 octahedra,  an edgeedge with one Fe(2)O6 octahedra, edges with two equivalent Li(10)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, and edges with two equivalent Fe(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-17°. There are six inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to one O(1), one O(14), one O(15), one O(4), one O(5), and one O(8) atom to form FeO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Fe(2)O6 octahedra,  a cornercorner with one Fe(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra, edges with two equivalent Li(10)O6 octahedra, edges with two equivalent Li(7)O6 octahedra, edges with two equivalent Fe(2)O6 octahedra, and edges with two equivalent Fe(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-9°. In the second Fe site, Fe(2) is bonded to one O(1), one O(15), one O(17), one O(4), one O(5), and one O(8) atom to form FeO6 octahedra that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  a cornercorner with one Fe(1)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra, edges with two equivalent Li(7)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Fe(1)O6 octahedra, and edges with two equivalent Fe(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-9°. In the third Fe site, Fe(3) is bonded to one O(1), one O(14), one O(20), one O(4), one O(5), and one O(8) atom to form FeO6 octahedra that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  a cornercorner with one Fe(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra, edges with two equivalent Li(10)O6 octahedra, edges with two equivalent Mn(4)O6 octahedra, edges with two equivalent Fe(1)O6 octahedra, and edges with two equivalent Fe(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-14°. In the fourth Fe site, Fe(4) is bonded to one O(13), one O(16), one O(2), one O(3), one O(6), and one O(7) atom to form FeO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Fe(5)O6 octahedra,  a cornercorner with one Fe(6)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra, edges with two equivalent Li(8)O6 octahedra, edges with two equivalent Li(9)O6 octahedra, edges with two equivalent Fe(5)O6 octahedra, and edges with two equivalent Fe(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-10°. In the fifth Fe site, Fe(5) is bonded to one O(16), one O(18), one O(2), one O(3), one O(6), and one O(7) atom to form FeO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  a cornercorner with one Li(9)O6 octahedra,  a cornercorner with one Fe(4)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra, edges with two equivalent Li(8)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with two equivalent Fe(4)O6 octahedra, and edges with two equivalent Fe(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-12°. In the sixth Fe site, Fe(6) is bonded to one O(13), one O(19), one O(2), one O(3), one O(6), and one O(7) atom to form FeO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  a cornercorner with one Li(9)O6 octahedra,  a cornercorner with one Fe(4)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra, edges with two equivalent Li(9)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, edges with two equivalent Fe(4)O6 octahedra, and edges with two equivalent Fe(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-12°. There are twenty inequivalent O sites. In the first O site, O(1) is bonded to one Li(5), one Li(7), one Mn(1), one Fe(1), one Fe(2), and one Fe(3) atom to form OLi2MnFe3 octahedra that share  a cornercorner with one O(4)Li2MnFe3 octahedra,  a cornercorner with one O(5)Li2MnFe3 octahedra,  a cornercorner with one O(15)Li3MnFe2 octahedra,  a cornercorner with one O(9)Li4Mn2 octahedra,  a cornercorner with one O(19)Li4MnFe octahedra,  a cornercorner with one O(20)Li4MnFe octahedra,  an edgeedge with one O(4)Li2MnFe3 octahedra,  an edgeedge with one O(14)Li3MnFe2 octahedra,  an edgeedge with one O(11)Li4Mn2 octahedra,  an edgeedge with one O(9)Li4Mn2 octahedra, edges with two equivalent O(5)Li2MnFe3 octahedra, edges with two equivalent O(8)Li2MnFe3 octahedra, edges with two equivalent O(15)Li3MnFe2 octahedra, and edges with two equivalent O(17)Li4MnFe octahedra. The corner-sharing octahedral tilt angles range from 2-11°. In the second O site, O(2) is bonded to one Li(6), one Li(8), one Mn(2), one Fe(4), one Fe(5), and one Fe(6) atom to form OLi2MnFe3 octahedra that share  a cornercorner with one O(3)Li2MnFe3 octahedra,  a cornercorner with one O(6)Li2MnFe3 octahedra,  a cornercorner with one O(16)Li3MnFe2 octahedra,  a cornercorner with one O(10)Li4Mn2 octahedra,  a cornercorner with one O(19)Li4MnFe octahedra,  a cornercorner with one O(20)Li4MnFe octahedra,  an edgeedge with one O(3)Li2MnFe3 octahedra,  an edgeedge with one O(13)Li3MnFe2 octahedra,  an edgeedge with one O(10)Li4Mn2 octahedra,  an edgeedge with one O(12)Li4Mn2 octahedra, edges with two equivalent O(6)Li2MnFe3 octahedra, edges with two equivalent O(7)Li2MnFe3 octahedra, edges with two equivalent O(16)Li3MnFe2 octahedra, and edges with two equivalent O(18)Li4MnFe octahedra. The corner-sharing octahedral tilt angles range from 0-15°. In the third O site, O(3) is bonded to one Li(3), one Li(9), one Mn(3), one Fe(4), one Fe(5), and one Fe(6) atom to form OLi2MnFe3 octahedra that share  a cornercorner with one O(2)Li2MnFe3 octahedra,  a cornercorner with one O(7)Li2MnFe3 octahedra,  a cornercorner with one O(13)Li3MnFe2 octahedra,  a cornercorner with one O(11)Li4Mn2 octahedra,  a cornercorner with one O(17)Li4MnFe octahedra,  a cornercorner with one O(18)Li4MnFe octahedra,  an edgeedge with one O(2)Li2MnFe3 octahedra,  an edgeedge with one O(16)Li3MnFe2 octahedra,  an edgeedge with one O(11)Li4Mn2 octahedra,  an edgeedge with one O(9)Li4Mn2 octahedra, edges with two equivalent O(6)Li2MnFe3 octahedra, edges with two equivalent O(7)Li2MnFe3 octahedra, edges with two equivalent O(13)Li3MnFe2 octahedra, and edges with two equivalent O(19)Li4MnFe octahedra. The corner-sharing octahedral tilt angles range from 0-14°. In the fourth O site, O(4) is bonded to one Li(10), one Li(4), one Mn(4), one Fe(1), one Fe(2), and one Fe(3) atom to form OLi2MnFe3 octahedra that share  a cornercorner with one O(1)Li2MnFe3 octahedra,  a cornercorner with one O(8)Li2MnFe3 octahedra,  a cornercorner with one O(14)Li3MnFe2 octahedra,  a cornercorner with one O(12)Li4Mn2 octahedra,  a cornercorner with one O(17)Li4MnFe octahedra,  a cornercorner with one O(18)Li4MnFe octahedra,  an edgeedge with one O(1)Li2MnFe3 octahedra,  an edgeedge with one O(15)Li3MnFe2 octahedra,  an edgeedge with one O(10)Li4Mn2 octahedra,  an edgeedge with one O(12)Li4Mn2 octahedra, edges with two equivalent O(5)Li2MnFe3 octahedra, edges with two equivalent O(8)Li2MnFe3 octahedra, edges with two equivalent O(14)Li3MnFe2 octahedra, and edges with two equivalent O(20)Li4MnFe octahedra. The corner-sharing octahedral tilt angles range from 1-16°. In the fifth O site, O(5) is bonded to one Li(10), one Li(7), one Mn(1), one Fe(1), one Fe(2), and one Fe(3) atom to form OLi2MnFe3 octahedra that share  a cornercorner with one O(1)Li2MnFe3 octahedra,  a cornercorner with one O(8)Li2MnFe3 octahedra,  a cornercorner with one O(14)Li3MnFe2 octahedra,  a cornercorner with one O(11)Li4Mn2 octahedra,  a cornercorner with one O(12)Li4Mn2 octahedra,  a cornercorner with one O(17)Li4MnFe octahedra,  an edgeedge with one O(14)Li3MnFe2 octahedra,  an edgeedge with one O(9)Li4Mn2 octahedra,  an edgeedge with one O(17)Li4MnFe octahedra,  an edgeedge with one O(20)Li4MnFe octahedra, edges with two equivalent O(1)Li2MnFe3 octahedra, edges with two equivalent O(4)Li2MnFe3 octahedra, edges with two equivalent O(8)Li2MnFe3 octahedra, and edges with two equivalent O(15)Li3MnFe2 octahedra. The corner-sharing octahedral tilt angles range from 3-9°. In the sixth O site, O(6) is bonded to one Li(8), one Li(9), one Mn(2), one Fe(4), one Fe(5), and one Fe(6) atom to form OLi2MnFe3 octahedra that share  a cornercorner with one O(2)Li2MnFe3 octahedra,  a cornercorner with one O(7)Li2MnFe3 octahedra,  a cornercorner with one O(13)Li3MnFe2 octahedra,  a cornercorner with one O(11)Li4Mn2 octahedra,  a cornercorner with one O(12)Li4Mn2 octahedra,  a cornercorner with one O(18)Li4MnFe octahedra,  an edgeedge with one O(13)Li3MnFe2 octahedra,  an edgeedge with one O(10)Li4Mn2 octahedra,  an edgeedge with one O(18)Li4MnFe octahedra,  an edgeedge with one O(19)Li4MnFe octahedra, edges with two equivalent O(2)Li2MnFe3 octahedra, edges with two equivalent O(3)Li2MnFe3 octahedra, edges with two equivalent O(7)Li2MnFe3 octahedra, and edges with two equivalent O(16)Li3MnFe2 octahedra. The corner-sharing octahedral tilt angles range from 0-10°. In the seventh O site, O(7) is bonded to one Li(8), one Li(9), one Mn(3), one Fe(4), one Fe(5), and one Fe(6) atom to form OLi2MnFe3 octahedra that share  a cornercorner with one O(3)Li2MnFe3 octahedra,  a cornercorner with one O(6)Li2MnFe3 octahedra,  a cornercorner with one O(16)Li3MnFe2 octahedra,  a cornercorner with one O(10)Li4Mn2 octahedra,  a cornercorner with one O(9)Li4Mn2 octahedra,  a cornercorner with one O(19)Li4MnFe octahedra,  an edgeedge with one O(16)Li3MnFe2 octahedra,  an edgeedge with one O(11)Li4Mn2 octahedra,  an edgeedge with one O(18)Li4MnFe octahedra,  an edgeedge with one O(19)Li4MnFe octahedra, edges with two equivalent O(2)Li2MnFe3 octahedra, edges with two equivalent O(3)Li2MnFe3 octahedra, edges with two equivalent O(6)Li2MnFe3 octahedra, and edges with two equivalent O(13)Li3MnFe2 octahedra. The corner-sharing octahedral tilt angles range from 0-11°. In the eighth O site, O(8) is bonded to one Li(10), one Li(7), one Mn(4), one Fe(1), one Fe(2), and one Fe(3) atom to form OLi2MnFe3 octahedra that share  a cornercorner with one O(4)Li2MnFe3 octahedra,  a cornercorner with one O(5)Li2MnFe3 octahedra,  a cornercorner with one O(15)Li3MnFe2 octahedra,  a cornercorner with one O(10)Li4Mn2 octahedra,  a cornercorner with one O(9)Li4Mn2 octahedra,  a cornercorner with one O(20)Li4MnFe octahedra,  an edgeedge with one O(15)Li3MnFe2 octahedra,  an edgeedge with one O(12)Li4Mn2 octahedra,  an edgeedge with one O(17)Li4MnFe octahedra,  an edgeedge with one O(20)Li4MnFe octahedra, edges with two equivalent O(1)Li2MnFe3 octahedra, edges with two equivalent O(4)Li2MnFe3 octahedra, edges with two equivalent O(5)Li2MnFe3 octahedra, and edges with two equivalent O(14)Li3MnFe2 octahedra. The corner-sharing octahedral tilt angles range from 3-9°. In the ninth O site, O(9) is bonded to one Li(1), one Li(3), one Li(5), one Li(7), one Mn(1), and one Mn(3) atom to form OLi4Mn2 octahedra that share  a cornercorner with one O(1)Li2MnFe3 octahedra,  a cornercorner with one O(7)Li2MnFe3 octahedra,  a cornercorner with one O(8)Li2MnFe3 octahedra,  a cornercorner with one O(13)Li3MnFe2 octahedra,  a cornercorner with one O(11)Li4Mn2 octahedra,  a cornercorner with one O(17)Li4MnFe octahedra,  an edgeedge with one O(1)Li2MnFe3 octahedra,  an edgeedge with one O(3)Li2MnFe3 octahedra,  an edgeedge with one O(5)Li2MnFe3 octahedra,  an edgeedge with one O(13)Li3MnFe2 octahedra, edges with two equivalent O(15)Li3MnFe2 octahedra, edges with two equivalent O(11)Li4Mn2 octahedra, edges with two equivalent O(17)Li4MnFe octahedra, and edges with two equivalent O(19)Li4MnFe octahedra. The corner-sharing octahedral tilt angles range from 2-12°. In the tenth O site, O(10) is bonded to one Li(2), one Li(4), one Li(6), one Li(8), one Mn(2), and one Mn(4) atom to form distorted OLi4Mn2 octahedra that share  a cornercorner with one O(2)Li2MnFe3 octahedra,  a cornercorner with one O(7)Li2MnFe3 octahedra,  a cornercorner with one O(8)Li2MnFe3 octahedra,  a cornercorner with one O(14)Li3MnFe2 octahedra,  a cornercorner with one O(12)Li4Mn2 octahedra,  a cornercorner with one O(18)Li4MnFe octahedra,  an edgeedge with one O(2)Li2MnFe3 octahedra,  an edgeedge with one O(4)Li2MnFe3 octahedra,  an edgeedge with one O(6)Li2MnFe3 octahedra,  an edgeedge with one O(14)Li3MnFe2 octahedra, edges with two equivalent O(16)Li3MnFe2 octahedra, edges with two equivalent O(12)Li4Mn2 octahedra, edges with two equivalent O(18)Li4MnFe octahedra, and edges with two equivalent O(20)Li4MnFe octahedra. The corner-sharing octahedral tilt angles range from 5-13°. In the eleventh O site, O(11) is bonded to one Li(1), one Li(3), one Li(5), one Li(9), one Mn(1), and one Mn(3) atom to form distorted OLi4Mn2 octahedra that share  a cornercorner with one O(3)Li2MnFe3 octahedra,  a cornercorner with one O(5)Li2MnFe3 octahedra,  a cornercorner with one O(6)Li2MnFe3 octahedra,  a cornercorner with one O(15)Li3MnFe2 octahedra,  a cornercorner with one O(9)Li4Mn2 octahedra,  a cornercorner with one O(19)Li4MnFe octahedra,  an edgeedge with one O(1)Li2MnFe3 octahedra,  an edgeedge with one O(3)Li2MnFe3 octahedra,  an edgeedge with one O(7)Li2MnFe3 octahedra,  an edgeedge with one O(15)Li3MnFe2 octahedra, edges with two equivalent O(13)Li3MnFe2 octahedra, edges with two equivalent O(9)Li4Mn2 octahedra, edges with two equivalent O(17)Li4MnFe octahedra, and edges with two equivalent O(19)Li4MnFe octahedra. The corner-sharing octahedral tilt angles range from 5-12°. In the twelfth O site, O(12) is bonded to one Li(10), one Li(2), one Li(4), one Li(6), one Mn(2), and one Mn(4) atom to form OLi4Mn2 octahedra that share  a cornercorner with one O(4)Li2MnFe3 octahedra,  a cornercorner with one O(5)Li2MnFe3 octahedra,  a cornercorner with one O(6)Li2MnFe3 octahedra,  a cornercorner with one O(16)Li3MnFe2 octahedra,  a cornercorner with one O(10)Li4Mn2 octahedra,  a cornercorner with one O(20)Li4MnFe octahedra,  an edgeedge with one O(2)Li2MnFe3 octahedra,  an edgeedge with one O(4)Li2MnFe3 octahedra,  an edgeedge with one O(8)Li2MnFe3 octahedra,  an edgeedge with one O(16)Li3MnFe2 octahedra, edges with two equivalent O(14)Li3MnFe2 octahedra, edges with two equivalent O(10)Li4Mn2 octahedra, edges with two equivalent O(18)Li4MnFe octahedra, and edges with two equivalent O(20)Li4MnFe octahedra. The corner-sharing octahedral tilt angles range from 1-13°. In the thirteenth O site, O(13) is bonded to one Li(1), one Li(3), one Li(9), one Mn(3), one Fe(4), and one Fe(6) atom to form OLi3MnFe2 octahedra that share  a cornercorner with one O(3)Li2MnFe3 octahedra,  a cornercorner with one O(6)Li2MnFe3 octahedra,  a cornercorner with one O(15)Li3MnFe2 octahedra,  a cornercorner with one O(16)Li3MnFe2 octahedra,  a cornercorner with one O(9)Li4Mn2 octahedra,  a cornercorner with one O(19)Li4MnFe octahedra,  an edgeedge with one O(2)Li2MnFe3 octahedra,  an edgeedge with one O(6)Li2MnFe3 octahedra,  an edgeedge with one O(9)Li4Mn2 octahedra,  an edgeedge with one O(17)Li4MnFe octahedra, edges with two equivalent O(3)Li2MnFe3 octahedra, edges with two equivalent O(7)Li2MnFe3 octahedra, edges with two equivalent O(11)Li4Mn2 octahedra, and edges with two equivalent O(19)Li4MnFe octahedra. The corner-sharing octahedral tilt angles range from 0-14°. In the fourteenth O site, O(14) is bonded to one Li(10), one Li(2), one Li(4), one Mn(4), one Fe(1), and one Fe(3) atom to form OLi3MnFe2 octahedra that share  a cornercorner with one O(4)Li2MnFe3 octahedra,  a cornercorner with one O(5)Li2MnFe3 octahedra,  a cornercorner with one O(15)Li3MnFe2 octahedra,  a cornercorner with one O(16)Li3MnFe2 octahedra,  a cornercorner with one O(10)Li4Mn2 octahedra,  a cornercorner with one O(20)Li4MnFe octahedra,  an edgeedge with one O(1)Li2MnFe3 octahedra,  an edgeedge with one O(5)Li2MnFe3 octahedra,  an edgeedge with one O(10)Li4Mn2 octahedra,  an edgeedge with one O(18)Li4MnFe octahedra, edges with two equivalent O(4)Li2MnFe3 octahedra, edges with two equivalent O(8)Li2MnFe3 octahedra, edges with two equivalent O(12)Li4Mn2 octahedra, and edges with two equivalent O(20)Li4MnFe octahedra. The corner-sharing octahedral tilt angles range from 2-16°. In the fifteenth O site, O(15) is bonded to one Li(1), one Li(5), one Li(7), one Mn(1), one Fe(1), and one Fe(2) atom to form OLi3MnFe2 octahedra that share  a cornercorner with one O(1)Li2MnFe3 octahedra,  a cornercorner with one O(8)Li2MnFe3 octahedra,  a cornercorner with one O(13)Li3MnFe2 octahedra,  a cornercorner with one O(14)Li3MnFe2 octahedra,  a cornercorner with one O(11)Li4Mn2 octahedra,  a cornercorner with one O(17)Li4MnFe octahedra,  an edgeedge with one O(4)Li2MnFe3 octahedra,  an edgeedge with one O(8)Li2MnFe3 octahedra,  an edgeedge with one O(11)Li4Mn2 octahedra,  an edgeedge with one O(19)Li4MnFe octahedra, edges with two equivalent O(1)Li2MnFe3 octahedra, edges with two equivalent O(5)Li2MnFe3 octahedra, edges with two equivalent O(9)Li4Mn2 octahedra, and edges with two equivalent O(17)Li4MnFe octahedra. The corner-sharing octahedral tilt angles range from 1-11°. In the sixteenth O site, O(16) is bonded to one Li(2), one Li(6), one Li(8), one Mn(2), one Fe(4), and one Fe(5) atom to form OLi3MnFe2 octahedra that share  a cornercorner with one O(2)Li2MnFe3 octahedra,  a cornercorner with one O(7)Li2MnFe3 octahedra,  a cornercorner with one O(13)Li3MnFe2 octahedra,  a cornercorner with one O(14)Li3MnFe2 octahedra,  a cornercorner with one O(12)Li4Mn2 octahedra,  a cornercorner with one O(18)Li4MnFe octahedra,  an edgeedge with one O(3)Li2MnFe3 octahedra,  an edgeedge with one O(7)Li2MnFe3 octahedra,  an edgeedge with one O(12)Li4Mn2 octahedra,  an edgeedge with one O(20)Li4MnFe octahedra, edges with two equivalent O(2)Li2MnFe3 octahedra, edges with two equivalent O(6)Li2MnFe3 octahedra, edges with two equivalent O(10)Li4Mn2 octahedra, and edges with two equivalent O(18)Li4MnFe octahedra. The corner-sharing octahedral tilt angles range from 0-15°. In the seventeenth O site, O(17) is bonded to one Li(1), one Li(3), one Li(5), one Li(7), one Mn(1), and one Fe(2) atom to form OLi4MnFe octahedra that share  a cornercorner with one O(3)Li2MnFe3 octahedra,  a cornercorner with one O(4)Li2MnFe3 octahedra,  a cornercorner with one O(5)Li2MnFe3 octahedra,  a cornercorner with one O(15)Li3MnFe2 octahedra,  a cornercorner with one O(9)Li4Mn2 octahedra,  a cornercorner with one O(19)Li4MnFe octahedra,  an edgeedge with one O(5)Li2MnFe3 octahedra,  an edgeedge with one O(8)Li2MnFe3 octahedra,  an edgeedge with one O(13)Li3MnFe2 octahedra,  an edgeedge with one O(19)Li4MnFe octahedra, edges with two equivalent O(1)Li2MnFe3 octahedra, edges with two equivalent O(15)Li3MnFe2 octahedra, edges with two equivalent O(11)Li4Mn2 octahedra, and edges with two equivalent O(9)Li4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 1-7°. In the eighteenth O site, O(18) is bonded to one Li(2), one Li(4), one Li(6), one Li(8), one Mn(2), and one Fe(5) atom to form OLi4MnFe octahedra that share  a cornercorner with one O(3)Li2MnFe3 octahedra,  a cornercorner with one O(4)Li2MnFe3 octahedra,  a cornercorner with one O(6)Li2MnFe3 octahedra,  a cornercorner with one O(16)Li3MnFe2 octahedra,  a cornercorner with one O(10)Li4Mn2 octahedra,  a cornercorner with one O(20)Li4MnFe octahedra,  an edgeedge with one O(6)Li2MnFe3 octahedra,  an edgeedge with one O(7)Li2MnFe3 octahedra,  an edgeedge with one O(14)Li3MnFe2 octahedra,  an edgeedge with one O(20)Li4MnFe octahedra, edges with two equivalent O(2)Li2MnFe3 octahedra, edges with two equivalent O(16)Li3MnFe2 octahedra, edges with two equivalent O(10)Li4Mn2 octahedra, and edges with two equivalent O(12)Li4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 2-13°. In the nineteenth O site, O(19) is bonded to one Li(1), one Li(3), one Li(5), one Li(9), one Mn(3), and one Fe(6) atom to form OLi4MnFe octahedra that share  a cornercorner with one O(1)Li2MnFe3 octahedra,  a cornercorner with one O(2)Li2MnFe3 octahedra,  a cornercorner with one O(7)Li2MnFe3 octahedra,  a cornercorner with one O(13)Li3MnFe2 octahedra,  a cornercorner with one O(11)Li4Mn2 octahedra,  a cornercorner with one O(17)Li4MnFe octahedra,  an edgeedge with one O(6)Li2MnFe3 octahedra,  an edgeedge with one O(7)Li2MnFe3 octahedra,  an edgeedge with one O(15)Li3MnFe2 octahedra,  an edgeedge with one O(17)Li4MnFe octahedra, edges with two equivalent O(3)Li2MnFe3 octahedra, edges with two equivalent O(13)Li3MnFe2 octahedra, edges with two equivalent O(11)Li4Mn2 octahedra, and edges with two equivalent O(9)Li4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 1-12°. In the twentieth O site, O(20) is bonded to one Li(10), one Li(2), one Li(4), one Li(6), one Mn(4), and one Fe(3) atom to form OLi4MnFe octahedra that share  a cornercorner with one O(1)Li2MnFe3 octahedra,  a cornercorner with one O(2)Li2MnFe3 octahedra,  a cornercorner with one O(8)Li2MnFe3 octahedra,  a cornercorner with one O(14)Li3MnFe2 octahedra,  a cornercorner with one O(12)Li4Mn2 octahedra,  a cornercorner with one O(18)Li4MnFe octahedra,  an edgeedge with one O(5)Li2MnFe3 octahedra,  an edgeedge with one O(8)Li2MnFe3 octahedra,  an edgeedge with one O(16)Li3MnFe2 octahedra,  an edgeedge with one O(18)Li4MnFe octahedra, edges with two equivalent O(4)Li2MnFe3 octahedra, edges with two equivalent O(14)Li3MnFe2 octahedra, edges with two equivalent O(10)Li4Mn2 octahedra, and edges with two equivalent O(12)Li4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 2-9°. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li5Mn2Fe3O10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.234
_cell_length_b   14.329
_cell_length_c   5.139
_cell_angle_alpha   86.977
_cell_angle_beta   100.755
_cell_angle_gamma   92.392
_symmetry_Int_Tables_number   1
_cell_volume   377.913
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.241  0.251  0.248  1.0
  Li  Li1  1  0.754  0.748  0.754  1.0
  Li  Li2  1  0.693  0.208  0.005  1.0
  Li  Li3  1  0.191  0.701  0.518  1.0
  Li  Li4  1  0.810  0.300  0.485  1.0
  Li  Li5  1  0.310  0.791  0.997  1.0
  Li  Li6  1  0.894  0.389  0.988  1.0
  Li  Li7  1  0.412  0.886  0.491  1.0
  Li  Li8  1  0.589  0.114  0.511  1.0
  Li  Li9  1  0.108  0.615  0.004  1.0
  Mn  Mn10  1  0.347  0.346  0.753  1.0
  Mn  Mn11  1  0.868  0.846  0.249  1.0
  Mn  Mn12  1  0.132  0.154  0.752  1.0
  Mn  Mn13  1  0.654  0.653  0.249  1.0
  Fe  Fe14  1  0.003  0.502  0.502  1.0
  Fe  Fe15  1  0.446  0.447  0.245  1.0
  Fe  Fe16  1  0.551  0.554  0.753  1.0
  Fe  Fe17  1  0.500  0.000  0.000  1.0
  Fe  Fe18  1  0.955  0.945  0.746  1.0
  Fe  Fe19  1  0.044  0.055  0.254  1.0
  O  O20  1  0.681  0.428  0.608  1.0
  O  O21  1  0.155  0.927  0.126  1.0
  O  O22  1  0.845  0.074  0.875  1.0
  O  O23  1  0.308  0.567  0.366  1.0
  O  O24  1  0.224  0.463  0.868  1.0
  O  O25  1  0.751  0.967  0.373  1.0
  O  O26  1  0.249  0.034  0.628  1.0
  O  O27  1  0.760  0.528  0.150  1.0
  O  O28  1  0.013  0.262  0.865  1.0
  O  O29  1  0.579  0.778  0.356  1.0
  O  O30  1  0.423  0.222  0.647  1.0
  O  O31  1  0.987  0.738  0.134  1.0
  O  O32  1  0.342  0.120  0.108  1.0
  O  O33  1  0.873  0.623  0.603  1.0
  O  O34  1  0.144  0.379  0.393  1.0
  O  O35  1  0.658  0.881  0.893  1.0
  O  O36  1  0.558  0.330  0.107  1.0
  O  O37  1  0.078  0.833  0.600  1.0
  O  O38  1  0.923  0.168  0.399  1.0
  O  O39  1  0.443  0.673  0.897  1.0
[/CIF]
.
The structure described by Li5Mn2Fe3O10 is Caswellsilverite-derived structured and crystallizes in the triclinic P1 space group. There are ten inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(13), one O(15), one O(17), one O(19), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  a cornercorner with one Li(9)O6 octahedra,  a cornercorner with one Fe(1)O6 octahedra,  a cornercorner with one Fe(4)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Fe(2)O6 octahedra,  an edgeedge with one Fe(6)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and edges with two equivalent Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-16°. In the second Li site, Li(2) is bonded to one O(10), one O(12), one O(14), one O(16), one O(18), and one O(20) atom to form LiO6 octahedra that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  a cornercorner with one Fe(1)O6 octahedra,  a cornercorner with one Fe(4)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Fe(3)O6 octahedra,  an edgeedge with one Fe(5)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, and edges with two equivalent Mn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-17°. In the third Li site, Li(3) is bonded to one O(11), one O(13), one O(17), one O(19), one O(3), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Fe(2)O6 octahedra,  a cornercorner with one Fe(5)O6 octahedra,  a cornercorner with one Fe(6)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Fe(4)O6 octahedra,  an edgeedge with one Fe(6)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Li(9)O6 octahedra, and edges with two equivalent Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-16°. In the fourth Li site, Li(4) is bonded to one O(10), one O(12), one O(14), one O(18), one O(20), and one O(4) atom to form distorted LiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Fe(2)O6 octahedra,  a cornercorner with one Fe(3)O6 octahedra,  a cornercorner with one Fe(5)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Fe(1)O6 octahedra,  an edgeedge with one Fe(3)O6 octahedra, edges with two equivalent Li(10)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, and edges with two equivalent Mn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-12°. In the fifth Li site, Li(5) is bonded to one O(1), one O(11), one O(15), one O(17), one O(19), and one O(9) atom to form distorted LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Fe(2)O6 octahedra,  a cornercorner with one Fe(3)O6 octahedra,  a cornercorner with one Fe(6)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Fe(1)O6 octahedra,  an edgeedge with one Fe(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(7)O6 octahedra, and edges with two equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-11°. In the sixth Li site, Li(6) is bonded to one O(10), one O(12), one O(16), one O(18), one O(2), and one O(20) atom to form LiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Fe(3)O6 octahedra,  a cornercorner with one Fe(5)O6 octahedra,  a cornercorner with one Fe(6)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Fe(4)O6 octahedra,  an edgeedge with one Fe(5)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(8)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-17°. In the seventh Li site, Li(7) is bonded to one O(1), one O(15), one O(17), one O(5), one O(8), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Fe(2)O6 octahedra,  a cornercorner with one Fe(3)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Fe(3)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Fe(1)O6 octahedra, and edges with two equivalent Fe(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-10°. In the eighth Li site, Li(8) is bonded to one O(10), one O(16), one O(18), one O(2), one O(6), and one O(7) atom to form distorted LiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Fe(5)O6 octahedra,  a cornercorner with one Fe(6)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Fe(6)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with two equivalent Fe(4)O6 octahedra, and edges with two equivalent Fe(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-17°. In the ninth Li site, Li(9) is bonded to one O(11), one O(13), one O(19), one O(3), one O(6), and one O(7) atom to form distorted LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Fe(5)O6 octahedra,  a cornercorner with one Fe(6)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Fe(5)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, edges with two equivalent Fe(4)O6 octahedra, and edges with two equivalent Fe(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-16°. In the tenth Li site, Li(10) is bonded to one O(12), one O(14), one O(20), one O(4), one O(5), and one O(8) atom to form LiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Fe(2)O6 octahedra,  a cornercorner with one Fe(3)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Fe(2)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Mn(4)O6 octahedra, edges with two equivalent Fe(1)O6 octahedra, and edges with two equivalent Fe(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-14°. There are four inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(11), one O(15), one O(17), one O(5), and one O(9) atom to form MnO6 octahedra that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  a cornercorner with one Li(9)O6 octahedra,  a cornercorner with one Fe(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Fe(1)O6 octahedra,  an edgeedge with one Fe(3)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Li(7)O6 octahedra, and edges with two equivalent Fe(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-16°. In the second Mn site, Mn(2) is bonded to one O(10), one O(12), one O(16), one O(18), one O(2), and one O(6) atom to form MnO6 octahedra that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  a cornercorner with one Li(9)O6 octahedra,  a cornercorner with one Fe(4)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Fe(4)O6 octahedra,  an edgeedge with one Fe(6)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, edges with two equivalent Li(8)O6 octahedra, and edges with two equivalent Fe(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-13°. In the third Mn site, Mn(3) is bonded to one O(11), one O(13), one O(19), one O(3), one O(7), and one O(9) atom to form MnO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  a cornercorner with one Li(9)O6 octahedra,  a cornercorner with one Fe(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Fe(4)O6 octahedra,  an edgeedge with one Fe(5)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(9)O6 octahedra, and edges with two equivalent Fe(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-12°. In the fourth Mn site, Mn(4) is bonded to one O(10), one O(12), one O(14), one O(20), one O(4), and one O(8) atom to form MnO6 octahedra that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  a cornercorner with one Fe(1)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Fe(1)O6 octahedra,  an edgeedge with one Fe(2)O6 octahedra, edges with two equivalent Li(10)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, and edges with two equivalent Fe(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-17°. There are six inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to one O(1), one O(14), one O(15), one O(4), one O(5), and one O(8) atom to form FeO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Fe(2)O6 octahedra,  a cornercorner with one Fe(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra, edges with two equivalent Li(10)O6 octahedra, edges with two equivalent Li(7)O6 octahedra, edges with two equivalent Fe(2)O6 octahedra, and edges with two equivalent Fe(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-9°. In the second Fe site, Fe(2) is bonded to one O(1), one O(15), one O(17), one O(4), one O(5), and one O(8) atom to form FeO6 octahedra that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  a cornercorner with one Fe(1)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra, edges with two equivalent Li(7)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Fe(1)O6 octahedra, and edges with two equivalent Fe(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-9°. In the third Fe site, Fe(3) is bonded to one O(1), one O(14), one O(20), one O(4), one O(5), and one O(8) atom to form FeO6 octahedra that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  a cornercorner with one Fe(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra, edges with two equivalent Li(10)O6 octahedra, edges with two equivalent Mn(4)O6 octahedra, edges with two equivalent Fe(1)O6 octahedra, and edges with two equivalent Fe(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-14°. In the fourth Fe site, Fe(4) is bonded to one O(13), one O(16), one O(2), one O(3), one O(6), and one O(7) atom to form FeO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Fe(5)O6 octahedra,  a cornercorner with one Fe(6)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra, edges with two equivalent Li(8)O6 octahedra, edges with two equivalent Li(9)O6 octahedra, edges with two equivalent Fe(5)O6 octahedra, and edges with two equivalent Fe(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-10°. In the fifth Fe site, Fe(5) is bonded to one O(16), one O(18), one O(2), one O(3), one O(6), and one O(7) atom to form FeO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  a cornercorner with one Li(9)O6 octahedra,  a cornercorner with one Fe(4)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra, edges with two equivalent Li(8)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with two equivalent Fe(4)O6 octahedra, and edges with two equivalent Fe(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-12°. In the sixth Fe site, Fe(6) is bonded to one O(13), one O(19), one O(2), one O(3), one O(6), and one O(7) atom to form FeO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  a cornercorner with one Li(9)O6 octahedra,  a cornercorner with one Fe(4)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra, edges with two equivalent Li(9)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, edges with two equivalent Fe(4)O6 octahedra, and edges with two equivalent Fe(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-12°. There are twenty inequivalent O sites. In the first O site, O(1) is bonded to one Li(5), one Li(7), one Mn(1), one Fe(1), one Fe(2), and one Fe(3) atom to form OLi2MnFe3 octahedra that share  a cornercorner with one O(4)Li2MnFe3 octahedra,  a cornercorner with one O(5)Li2MnFe3 octahedra,  a cornercorner with one O(15)Li3MnFe2 octahedra,  a cornercorner with one O(9)Li4Mn2 octahedra,  a cornercorner with one O(19)Li4MnFe octahedra,  a cornercorner with one O(20)Li4MnFe octahedra,  an edgeedge with one O(4)Li2MnFe3 octahedra,  an edgeedge with one O(14)Li3MnFe2 octahedra,  an edgeedge with one O(11)Li4Mn2 octahedra,  an edgeedge with one O(9)Li4Mn2 octahedra, edges with two equivalent O(5)Li2MnFe3 octahedra, edges with two equivalent O(8)Li2MnFe3 octahedra, edges with two equivalent O(15)Li3MnFe2 octahedra, and edges with two equivalent O(17)Li4MnFe octahedra. The corner-sharing octahedral tilt angles range from 2-11°. In the second O site, O(2) is bonded to one Li(6), one Li(8), one Mn(2), one Fe(4), one Fe(5), and one Fe(6) atom to form OLi2MnFe3 octahedra that share  a cornercorner with one O(3)Li2MnFe3 octahedra,  a cornercorner with one O(6)Li2MnFe3 octahedra,  a cornercorner with one O(16)Li3MnFe2 octahedra,  a cornercorner with one O(10)Li4Mn2 octahedra,  a cornercorner with one O(19)Li4MnFe octahedra,  a cornercorner with one O(20)Li4MnFe octahedra,  an edgeedge with one O(3)Li2MnFe3 octahedra,  an edgeedge with one O(13)Li3MnFe2 octahedra,  an edgeedge with one O(10)Li4Mn2 octahedra,  an edgeedge with one O(12)Li4Mn2 octahedra, edges with two equivalent O(6)Li2MnFe3 octahedra, edges with two equivalent O(7)Li2MnFe3 octahedra, edges with two equivalent O(16)Li3MnFe2 octahedra, and edges with two equivalent O(18)Li4MnFe octahedra. The corner-sharing octahedral tilt angles range from 0-15°. In the third O site, O(3) is bonded to one Li(3), one Li(9), one Mn(3), one Fe(4), one Fe(5), and one Fe(6) atom to form OLi2MnFe3 octahedra that share  a cornercorner with one O(2)Li2MnFe3 octahedra,  a cornercorner with one O(7)Li2MnFe3 octahedra,  a cornercorner with one O(13)Li3MnFe2 octahedra,  a cornercorner with one O(11)Li4Mn2 octahedra,  a cornercorner with one O(17)Li4MnFe octahedra,  a cornercorner with one O(18)Li4MnFe octahedra,  an edgeedge with one O(2)Li2MnFe3 octahedra,  an edgeedge with one O(16)Li3MnFe2 octahedra,  an edgeedge with one O(11)Li4Mn2 octahedra,  an edgeedge with one O(9)Li4Mn2 octahedra, edges with two equivalent O(6)Li2MnFe3 octahedra, edges with two equivalent O(7)Li2MnFe3 octahedra, edges with two equivalent O(13)Li3MnFe2 octahedra, and edges with two equivalent O(19)Li4MnFe octahedra. The corner-sharing octahedral tilt angles range from 0-14°. In the fourth O site, O(4) is bonded to one Li(10), one Li(4), one Mn(4), one Fe(1), one Fe(2), and one Fe(3) atom to form OLi2MnFe3 octahedra that share  a cornercorner with one O(1)Li2MnFe3 octahedra,  a cornercorner with one O(8)Li2MnFe3 octahedra,  a cornercorner with one O(14)Li3MnFe2 octahedra,  a cornercorner with one O(12)Li4Mn2 octahedra,  a cornercorner with one O(17)Li4MnFe octahedra,  a cornercorner with one O(18)Li4MnFe octahedra,  an edgeedge with one O(1)Li2MnFe3 octahedra,  an edgeedge with one O(15)Li3MnFe2 octahedra,  an edgeedge with one O(10)Li4Mn2 octahedra,  an edgeedge with one O(12)Li4Mn2 octahedra, edges with two equivalent O(5)Li2MnFe3 octahedra, edges with two equivalent O(8)Li2MnFe3 octahedra, edges with two equivalent O(14)Li3MnFe2 octahedra, and edges with two equivalent O(20)Li4MnFe octahedra. The corner-sharing octahedral tilt angles range from 1-16°. In the fifth O site, O(5) is bonded to one Li(10), one Li(7), one Mn(1), one Fe(1), one Fe(2), and one Fe(3) atom to form OLi2MnFe3 octahedra that share  a cornercorner with one O(1)Li2MnFe3 octahedra,  a cornercorner with one O(8)Li2MnFe3 octahedra,  a cornercorner with one O(14)Li3MnFe2 octahedra,  a cornercorner with one O(11)Li4Mn2 octahedra,  a cornercorner with one O(12)Li4Mn2 octahedra,  a cornercorner with one O(17)Li4MnFe octahedra,  an edgeedge with one O(14)Li3MnFe2 octahedra,  an edgeedge with one O(9)Li4Mn2 octahedra,  an edgeedge with one O(17)Li4MnFe octahedra,  an edgeedge with one O(20)Li4MnFe octahedra, edges with two equivalent O(1)Li2MnFe3 octahedra, edges with two equivalent O(4)Li2MnFe3 octahedra, edges with two equivalent O(8)Li2MnFe3 octahedra, and edges with two equivalent O(15)Li3MnFe2 octahedra. The corner-sharing octahedral tilt angles range from 3-9°. In the sixth O site, O(6) is bonded to one Li(8), one Li(9), one Mn(2), one Fe(4), one Fe(5), and one Fe(6) atom to form OLi2MnFe3 octahedra that share  a cornercorner with one O(2)Li2MnFe3 octahedra,  a cornercorner with one O(7)Li2MnFe3 octahedra,  a cornercorner with one O(13)Li3MnFe2 octahedra,  a cornercorner with one O(11)Li4Mn2 octahedra,  a cornercorner with one O(12)Li4Mn2 octahedra,  a cornercorner with one O(18)Li4MnFe octahedra,  an edgeedge with one O(13)Li3MnFe2 octahedra,  an edgeedge with one O(10)Li4Mn2 octahedra,  an edgeedge with one O(18)Li4MnFe octahedra,  an edgeedge with one O(19)Li4MnFe octahedra, edges with two equivalent O(2)Li2MnFe3 octahedra, edges with two equivalent O(3)Li2MnFe3 octahedra, edges with two equivalent O(7)Li2MnFe3 octahedra, and edges with two equivalent O(16)Li3MnFe2 octahedra. The corner-sharing octahedral tilt angles range from 0-10°. In the seventh O site, O(7) is bonded to one Li(8), one Li(9), one Mn(3), one Fe(4), one Fe(5), and one Fe(6) atom to form OLi2MnFe3 octahedra that share  a cornercorner with one O(3)Li2MnFe3 octahedra,  a cornercorner with one O(6)Li2MnFe3 octahedra,  a cornercorner with one O(16)Li3MnFe2 octahedra,  a cornercorner with one O(10)Li4Mn2 octahedra,  a cornercorner with one O(9)Li4Mn2 octahedra,  a cornercorner with one O(19)Li4MnFe octahedra,  an edgeedge with one O(16)Li3MnFe2 octahedra,  an edgeedge with one O(11)Li4Mn2 octahedra,  an edgeedge with one O(18)Li4MnFe octahedra,  an edgeedge with one O(19)Li4MnFe octahedra, edges with two equivalent O(2)Li2MnFe3 octahedra, edges with two equivalent O(3)Li2MnFe3 octahedra, edges with two equivalent O(6)Li2MnFe3 octahedra, and edges with two equivalent O(13)Li3MnFe2 octahedra. The corner-sharing octahedral tilt angles range from 0-11°. In the eighth O site, O(8) is bonded to one Li(10), one Li(7), one Mn(4), one Fe(1), one Fe(2), and one Fe(3) atom to form OLi2MnFe3 octahedra that share  a cornercorner with one O(4)Li2MnFe3 octahedra,  a cornercorner with one O(5)Li2MnFe3 octahedra,  a cornercorner with one O(15)Li3MnFe2 octahedra,  a cornercorner with one O(10)Li4Mn2 octahedra,  a cornercorner with one O(9)Li4Mn2 octahedra,  a cornercorner with one O(20)Li4MnFe octahedra,  an edgeedge with one O(15)Li3MnFe2 octahedra,  an edgeedge with one O(12)Li4Mn2 octahedra,  an edgeedge with one O(17)Li4MnFe octahedra,  an edgeedge with one O(20)Li4MnFe octahedra, edges with two equivalent O(1)Li2MnFe3 octahedra, edges with two equivalent O(4)Li2MnFe3 octahedra, edges with two equivalent O(5)Li2MnFe3 octahedra, and edges with two equivalent O(14)Li3MnFe2 octahedra. The corner-sharing octahedral tilt angles range from 3-9°. In the ninth O site, O(9) is bonded to one Li(1), one Li(3), one Li(5), one Li(7), one Mn(1), and one Mn(3) atom to form OLi4Mn2 octahedra that share  a cornercorner with one O(1)Li2MnFe3 octahedra,  a cornercorner with one O(7)Li2MnFe3 octahedra,  a cornercorner with one O(8)Li2MnFe3 octahedra,  a cornercorner with one O(13)Li3MnFe2 octahedra,  a cornercorner with one O(11)Li4Mn2 octahedra,  a cornercorner with one O(17)Li4MnFe octahedra,  an edgeedge with one O(1)Li2MnFe3 octahedra,  an edgeedge with one O(3)Li2MnFe3 octahedra,  an edgeedge with one O(5)Li2MnFe3 octahedra,  an edgeedge with one O(13)Li3MnFe2 octahedra, edges with two equivalent O(15)Li3MnFe2 octahedra, edges with two equivalent O(11)Li4Mn2 octahedra, edges with two equivalent O(17)Li4MnFe octahedra, and edges with two equivalent O(19)Li4MnFe octahedra. The corner-sharing octahedral tilt angles range from 2-12°. In the tenth O site, O(10) is bonded to one Li(2), one Li(4), one Li(6), one Li(8), one Mn(2), and one Mn(4) atom to form distorted OLi4Mn2 octahedra that share  a cornercorner with one O(2)Li2MnFe3 octahedra,  a cornercorner with one O(7)Li2MnFe3 octahedra,  a cornercorner with one O(8)Li2MnFe3 octahedra,  a cornercorner with one O(14)Li3MnFe2 octahedra,  a cornercorner with one O(12)Li4Mn2 octahedra,  a cornercorner with one O(18)Li4MnFe octahedra,  an edgeedge with one O(2)Li2MnFe3 octahedra,  an edgeedge with one O(4)Li2MnFe3 octahedra,  an edgeedge with one O(6)Li2MnFe3 octahedra,  an edgeedge with one O(14)Li3MnFe2 octahedra, edges with two equivalent O(16)Li3MnFe2 octahedra, edges with two equivalent O(12)Li4Mn2 octahedra, edges with two equivalent O(18)Li4MnFe octahedra, and edges with two equivalent O(20)Li4MnFe octahedra. The corner-sharing octahedral tilt angles range from 5-13°. In the eleventh O site, O(11) is bonded to one Li(1), one Li(3), one Li(5), one Li(9), one Mn(1), and one Mn(3) atom to form distorted OLi4Mn2 octahedra that share  a cornercorner with one O(3)Li2MnFe3 octahedra,  a cornercorner with one O(5)Li2MnFe3 octahedra,  a cornercorner with one O(6)Li2MnFe3 octahedra,  a cornercorner with one O(15)Li3MnFe2 octahedra,  a cornercorner with one O(9)Li4Mn2 octahedra,  a cornercorner with one O(19)Li4MnFe octahedra,  an edgeedge with one O(1)Li2MnFe3 octahedra,  an edgeedge with one O(3)Li2MnFe3 octahedra,  an edgeedge with one O(7)Li2MnFe3 octahedra,  an edgeedge with one O(15)Li3MnFe2 octahedra, edges with two equivalent O(13)Li3MnFe2 octahedra, edges with two equivalent O(9)Li4Mn2 octahedra, edges with two equivalent O(17)Li4MnFe octahedra, and edges with two equivalent O(19)Li4MnFe octahedra. The corner-sharing octahedral tilt angles range from 5-12°. In the twelfth O site, O(12) is bonded to one Li(10), one Li(2), one Li(4), one Li(6), one Mn(2), and one Mn(4) atom to form OLi4Mn2 octahedra that share  a cornercorner with one O(4)Li2MnFe3 octahedra,  a cornercorner with one O(5)Li2MnFe3 octahedra,  a cornercorner with one O(6)Li2MnFe3 octahedra,  a cornercorner with one O(16)Li3MnFe2 octahedra,  a cornercorner with one O(10)Li4Mn2 octahedra,  a cornercorner with one O(20)Li4MnFe octahedra,  an edgeedge with one O(2)Li2MnFe3 octahedra,  an edgeedge with one O(4)Li2MnFe3 octahedra,  an edgeedge with one O(8)Li2MnFe3 octahedra,  an edgeedge with one O(16)Li3MnFe2 octahedra, edges with two equivalent O(14)Li3MnFe2 octahedra, edges with two equivalent O(10)Li4Mn2 octahedra, edges with two equivalent O(18)Li4MnFe octahedra, and edges with two equivalent O(20)Li4MnFe octahedra. The corner-sharing octahedral tilt angles range from 1-13°. In the thirteenth O site, O(13) is bonded to one Li(1), one Li(3), one Li(9), one Mn(3), one Fe(4), and one Fe(6) atom to form OLi3MnFe2 octahedra that share  a cornercorner with one O(3)Li2MnFe3 octahedra,  a cornercorner with one O(6)Li2MnFe3 octahedra,  a cornercorner with one O(15)Li3MnFe2 octahedra,  a cornercorner with one O(16)Li3MnFe2 octahedra,  a cornercorner with one O(9)Li4Mn2 octahedra,  a cornercorner with one O(19)Li4MnFe octahedra,  an edgeedge with one O(2)Li2MnFe3 octahedra,  an edgeedge with one O(6)Li2MnFe3 octahedra,  an edgeedge with one O(9)Li4Mn2 octahedra,  an edgeedge with one O(17)Li4MnFe octahedra, edges with two equivalent O(3)Li2MnFe3 octahedra, edges with two equivalent O(7)Li2MnFe3 octahedra, edges with two equivalent O(11)Li4Mn2 octahedra, and edges with two equivalent O(19)Li4MnFe octahedra. The corner-sharing octahedral tilt angles range from 0-14°. In the fourteenth O site, O(14) is bonded to one Li(10), one Li(2), one Li(4), one Mn(4), one Fe(1), and one Fe(3) atom to form OLi3MnFe2 octahedra that share  a cornercorner with one O(4)Li2MnFe3 octahedra,  a cornercorner with one O(5)Li2MnFe3 octahedra,  a cornercorner with one O(15)Li3MnFe2 octahedra,  a cornercorner with one O(16)Li3MnFe2 octahedra,  a cornercorner with one O(10)Li4Mn2 octahedra,  a cornercorner with one O(20)Li4MnFe octahedra,  an edgeedge with one O(1)Li2MnFe3 octahedra,  an edgeedge with one O(5)Li2MnFe3 octahedra,  an edgeedge with one O(10)Li4Mn2 octahedra,  an edgeedge with one O(18)Li4MnFe octahedra, edges with two equivalent O(4)Li2MnFe3 octahedra, edges with two equivalent O(8)Li2MnFe3 octahedra, edges with two equivalent O(12)Li4Mn2 octahedra, and edges with two equivalent O(20)Li4MnFe octahedra. The corner-sharing octahedral tilt angles range from 2-16°. In the fifteenth O site, O(15) is bonded to one Li(1), one Li(5), one Li(7), one Mn(1), one Fe(1), and one Fe(2) atom to form OLi3MnFe2 octahedra that share  a cornercorner with one O(1)Li2MnFe3 octahedra,  a cornercorner with one O(8)Li2MnFe3 octahedra,  a cornercorner with one O(13)Li3MnFe2 octahedra,  a cornercorner with one O(14)Li3MnFe2 octahedra,  a cornercorner with one O(11)Li4Mn2 octahedra,  a cornercorner with one O(17)Li4MnFe octahedra,  an edgeedge with one O(4)Li2MnFe3 octahedra,  an edgeedge with one O(8)Li2MnFe3 octahedra,  an edgeedge with one O(11)Li4Mn2 octahedra,  an edgeedge with one O(19)Li4MnFe octahedra, edges with two equivalent O(1)Li2MnFe3 octahedra, edges with two equivalent O(5)Li2MnFe3 octahedra, edges with two equivalent O(9)Li4Mn2 octahedra, and edges with two equivalent O(17)Li4MnFe octahedra. The corner-sharing octahedral tilt angles range from 1-11°. In the sixteenth O site, O(16) is bonded to one Li(2), one Li(6), one Li(8), one Mn(2), one Fe(4), and one Fe(5) atom to form OLi3MnFe2 octahedra that share  a cornercorner with one O(2)Li2MnFe3 octahedra,  a cornercorner with one O(7)Li2MnFe3 octahedra,  a cornercorner with one O(13)Li3MnFe2 octahedra,  a cornercorner with one O(14)Li3MnFe2 octahedra,  a cornercorner with one O(12)Li4Mn2 octahedra,  a cornercorner with one O(18)Li4MnFe octahedra,  an edgeedge with one O(3)Li2MnFe3 octahedra,  an edgeedge with one O(7)Li2MnFe3 octahedra,  an edgeedge with one O(12)Li4Mn2 octahedra,  an edgeedge with one O(20)Li4MnFe octahedra, edges with two equivalent O(2)Li2MnFe3 octahedra, edges with two equivalent O(6)Li2MnFe3 octahedra, edges with two equivalent O(10)Li4Mn2 octahedra, and edges with two equivalent O(18)Li4MnFe octahedra. The corner-sharing octahedral tilt angles range from 0-15°. In the seventeenth O site, O(17) is bonded to one Li(1), one Li(3), one Li(5), one Li(7), one Mn(1), and one Fe(2) atom to form OLi4MnFe octahedra that share  a cornercorner with one O(3)Li2MnFe3 octahedra,  a cornercorner with one O(4)Li2MnFe3 octahedra,  a cornercorner with one O(5)Li2MnFe3 octahedra,  a cornercorner with one O(15)Li3MnFe2 octahedra,  a cornercorner with one O(9)Li4Mn2 octahedra,  a cornercorner with one O(19)Li4MnFe octahedra,  an edgeedge with one O(5)Li2MnFe3 octahedra,  an edgeedge with one O(8)Li2MnFe3 octahedra,  an edgeedge with one O(13)Li3MnFe2 octahedra,  an edgeedge with one O(19)Li4MnFe octahedra, edges with two equivalent O(1)Li2MnFe3 octahedra, edges with two equivalent O(15)Li3MnFe2 octahedra, edges with two equivalent O(11)Li4Mn2 octahedra, and edges with two equivalent O(9)Li4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 1-7°. In the eighteenth O site, O(18) is bonded to one Li(2), one Li(4), one Li(6), one Li(8), one Mn(2), and one Fe(5) atom to form OLi4MnFe octahedra that share  a cornercorner with one O(3)Li2MnFe3 octahedra,  a cornercorner with one O(4)Li2MnFe3 octahedra,  a cornercorner with one O(6)Li2MnFe3 octahedra,  a cornercorner with one O(16)Li3MnFe2 octahedra,  a cornercorner with one O(10)Li4Mn2 octahedra,  a cornercorner with one O(20)Li4MnFe octahedra,  an edgeedge with one O(6)Li2MnFe3 octahedra,  an edgeedge with one O(7)Li2MnFe3 octahedra,  an edgeedge with one O(14)Li3MnFe2 octahedra,  an edgeedge with one O(20)Li4MnFe octahedra, edges with two equivalent O(2)Li2MnFe3 octahedra, edges with two equivalent O(16)Li3MnFe2 octahedra, edges with two equivalent O(10)Li4Mn2 octahedra, and edges with two equivalent O(12)Li4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 2-13°. In the nineteenth O site, O(19) is bonded to one Li(1), one Li(3), one Li(5), one Li(9), one Mn(3), and one Fe(6) atom to form OLi4MnFe octahedra that share  a cornercorner with one O(1)Li2MnFe3 octahedra,  a cornercorner with one O(2)Li2MnFe3 octahedra,  a cornercorner with one O(7)Li2MnFe3 octahedra,  a cornercorner with one O(13)Li3MnFe2 octahedra,  a cornercorner with one O(11)Li4Mn2 octahedra,  a cornercorner with one O(17)Li4MnFe octahedra,  an edgeedge with one O(6)Li2MnFe3 octahedra,  an edgeedge with one O(7)Li2MnFe3 octahedra,  an edgeedge with one O(15)Li3MnFe2 octahedra,  an edgeedge with one O(17)Li4MnFe octahedra, edges with two equivalent O(3)Li2MnFe3 octahedra, edges with two equivalent O(13)Li3MnFe2 octahedra, edges with two equivalent O(11)Li4Mn2 octahedra, and edges with two equivalent O(9)Li4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 1-12°. In the twentieth O site, O(20) is bonded to one Li(10), one Li(2), one Li(4), one Li(6), one Mn(4), and one Fe(3) atom to form OLi4MnFe octahedra that share  a cornercorner with one O(1)Li2MnFe3 octahedra,  a cornercorner with one O(2)Li2MnFe3 octahedra,  a cornercorner with one O(8)Li2MnFe3 octahedra,  a cornercorner with one O(14)Li3MnFe2 octahedra,  a cornercorner with one O(12)Li4Mn2 octahedra,  a cornercorner with one O(18)Li4MnFe octahedra,  an edgeedge with one O(5)Li2MnFe3 octahedra,  an edgeedge with one O(8)Li2MnFe3 octahedra,  an edgeedge with one O(16)Li3MnFe2 octahedra,  an edgeedge with one O(18)Li4MnFe octahedra, edges with two equivalent O(4)Li2MnFe3 octahedra, edges with two equivalent O(14)Li3MnFe2 octahedra, edges with two equivalent O(10)Li4Mn2 octahedra, and edges with two equivalent O(12)Li4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 2-9°. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li5Mn2Fe3O10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.234
_cell_length_b   14.329
_cell_length_c   5.139
_cell_angle_alpha   86.977
_cell_angle_beta   100.755
_cell_angle_gamma   92.392
_symmetry_Int_Tables_number   1
_cell_volume   377.913
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.241  0.251  0.248  1.0
  Li  Li1  1  0.754  0.748  0.754  1.0
  Li  Li2  1  0.693  0.208  0.005  1.0
  Li  Li3  1  0.191  0.701  0.518  1.0
  Li  Li4  1  0.810  0.300  0.485  1.0
  Li  Li5  1  0.310  0.791  0.997  1.0
  Li  Li6  1  0.894  0.389  0.988  1.0
  Li  Li7  1  0.412  0.886  0.491  1.0
  Li  Li8  1  0.589  0.114  0.511  1.0
  Li  Li9  1  0.108  0.615  0.004  1.0
  Mn  Mn10  1  0.347  0.346  0.753  1.0
  Mn  Mn11  1  0.868  0.846  0.249  1.0
  Mn  Mn12  1  0.132  0.154  0.752  1.0
  Mn  Mn13  1  0.654  0.653  0.249  1.0
  Fe  Fe14  1  0.003  0.502  0.502  1.0
  Fe  Fe15  1  0.446  0.447  0.245  1.0
  Fe  Fe16  1  0.551  0.554  0.753  1.0
  Fe  Fe17  1  0.500  0.000  0.000  1.0
  Fe  Fe18  1  0.955  0.945  0.746  1.0
  Fe  Fe19  1  0.044  0.055  0.254  1.0
  O  O20  1  0.681  0.428  0.608  1.0
  O  O21  1  0.155  0.927  0.126  1.0
  O  O22  1  0.845  0.074  0.875  1.0
  O  O23  1  0.308  0.567  0.366  1.0
  O  O24  1  0.224  0.463  0.868  1.0
  O  O25  1  0.751  0.967  0.373  1.0
  O  O26  1  0.249  0.034  0.628  1.0
  O  O27  1  0.760  0.528  0.150  1.0
  O  O28  1  0.013  0.262  0.865  1.0
  O  O29  1  0.579  0.778  0.356  1.0
  O  O30  1  0.423  0.222  0.647  1.0
  O  O31  1  0.987  0.738  0.134  1.0
  O  O32  1  0.342  0.120  0.108  1.0
  O  O33  1  0.873  0.623  0.603  1.0
  O  O34  1  0.144  0.379  0.393  1.0
  O  O35  1  0.658  0.881  0.893  1.0
  O  O36  1  0.558  0.330  0.107  1.0
  O  O37  1  0.078  0.833  0.600  1.0
  O  O38  1  0.923  0.168  0.399  1.0
  O  O39  1  0.443  0.673  0.897  1.0
[/CIF]
.