The structure described by Co(IO3)2 is Hydrophilite-derived structured and crystallizes in the trigonal P-31m space group. Co(1) is bonded to six equivalent O(1) atoms to form CoO6 octahedra that share corners with twelve equivalent I(1)O6 octahedra. The corner-sharing octahedral tilt angles are 52°. O(1) is bonded in a distorted trigonal planar geometry to one Co(1) and two equivalent I(1) atoms. I(1) is bonded to six equivalent O(1) atoms to form IO6 octahedra that share corners with six equivalent Co(1)O6 octahedra and edges with three equivalent I(1)O6 octahedra. The corner-sharing octahedral tilt angles are 52°. is represented by the CIF file [CIF]
data_Co(IO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.505
_cell_length_b   5.505
_cell_length_c   4.540
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   119.159
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.000  0.000  0.000  1.0
  I  I1  1  0.667  0.333  0.500  1.0
  I  I2  1  0.333  0.667  0.500  1.0
  O  O3  1  0.657  0.000  0.744  1.0
  O  O4  1  0.343  0.343  0.744  1.0
  O  O5  1  0.000  0.657  0.744  1.0
  O  O6  1  0.343  0.000  0.256  1.0
  O  O7  1  0.657  0.657  0.256  1.0
  O  O8  1  0.000  0.343  0.256  1.0
[/CIF]
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The structure described by Co(IO3)2 is Hydrophilite-derived structured and crystallizes in the trigonal P-31m space group. Co(1) is bonded to six equivalent O(1) atoms to form CoO6 octahedra that share corners with twelve equivalent I(1)O6 octahedra. The corner-sharing octahedral tilt angles are 52°. O(1) is bonded in a distorted trigonal planar geometry to one Co(1) and two equivalent I(1) atoms. I(1) is bonded to six equivalent O(1) atoms to form IO6 octahedra that share corners with six equivalent Co(1)O6 octahedra and edges with three equivalent I(1)O6 octahedra. The corner-sharing octahedral tilt angles are 52°. is represented by the CIF file [CIF]
data_Co(IO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.505
_cell_length_b   5.505
_cell_length_c   4.540
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   119.159
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.000  0.000  0.000  1.0
  I  I1  1  0.667  0.333  0.500  1.0
  I  I2  1  0.333  0.667  0.500  1.0
  O  O3  1  0.657  0.000  0.744  1.0
  O  O4  1  0.343  0.343  0.744  1.0
  O  O5  1  0.000  0.657  0.744  1.0
  O  O6  1  0.343  0.000  0.256  1.0
  O  O7  1  0.657  0.657  0.256  1.0
  O  O8  1  0.000  0.343  0.256  1.0
[/CIF]
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