The structure described by RbP(OF)2 crystallizes in the orthorhombic Pnma space group. Rb(1) is bonded in a 12-coordinate geometry to six equivalent O(1), two equivalent F(2), and four equivalent F(1) atoms. P(1) is bonded in a tetrahedral geometry to two equivalent O(1), one F(1), and one F(2) atom. O(1) is bonded in a distorted single-bond geometry to three equivalent Rb(1) and one P(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to four equivalent Rb(1) and one P(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to two equivalent Rb(1) and one P(1) atom. is represented by the CIF file [CIF]
data_RbP(OF)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.569
_cell_length_b   7.650
_cell_length_c   7.884
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   396.199
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.250  0.356  0.635  1.0
  Rb  Rb1  1  0.750  0.856  0.865  1.0
  Rb  Rb2  1  0.750  0.644  0.365  1.0
  Rb  Rb3  1  0.250  0.144  0.135  1.0
  P  P4  1  0.750  0.316  0.884  1.0
  P  P5  1  0.250  0.684  0.116  1.0
  P  P6  1  0.250  0.816  0.616  1.0
  P  P7  1  0.750  0.184  0.384  1.0
  O  O8  1  0.946  0.277  0.383  1.0
  O  O9  1  0.446  0.777  0.117  1.0
  O  O10  1  0.554  0.223  0.883  1.0
  O  O11  1  0.946  0.223  0.883  1.0
  O  O12  1  0.554  0.277  0.383  1.0
  O  O13  1  0.446  0.723  0.617  1.0
  O  O14  1  0.054  0.777  0.117  1.0
  O  O15  1  0.054  0.723  0.617  1.0
  F  F16  1  0.750  0.453  0.734  1.0
  F  F17  1  0.750  0.045  0.532  1.0
  F  F18  1  0.250  0.953  0.766  1.0
  F  F19  1  0.250  0.547  0.266  1.0
  F  F20  1  0.750  0.047  0.234  1.0
  F  F21  1  0.250  0.955  0.468  1.0
  F  F22  1  0.750  0.455  0.032  1.0
  F  F23  1  0.250  0.545  0.968  1.0
[/CIF]
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The structure described by RbP(OF)2 crystallizes in the orthorhombic Pnma space group. Rb(1) is bonded in a 12-coordinate geometry to six equivalent O(1), two equivalent F(2), and four equivalent F(1) atoms. P(1) is bonded in a tetrahedral geometry to two equivalent O(1), one F(1), and one F(2) atom. O(1) is bonded in a distorted single-bond geometry to three equivalent Rb(1) and one P(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to four equivalent Rb(1) and one P(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to two equivalent Rb(1) and one P(1) atom. is represented by the CIF file [CIF]
data_RbP(OF)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.569
_cell_length_b   7.650
_cell_length_c   7.884
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   396.199
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.250  0.356  0.635  1.0
  Rb  Rb1  1  0.750  0.856  0.865  1.0
  Rb  Rb2  1  0.750  0.644  0.365  1.0
  Rb  Rb3  1  0.250  0.144  0.135  1.0
  P  P4  1  0.750  0.316  0.884  1.0
  P  P5  1  0.250  0.684  0.116  1.0
  P  P6  1  0.250  0.816  0.616  1.0
  P  P7  1  0.750  0.184  0.384  1.0
  O  O8  1  0.946  0.277  0.383  1.0
  O  O9  1  0.446  0.777  0.117  1.0
  O  O10  1  0.554  0.223  0.883  1.0
  O  O11  1  0.946  0.223  0.883  1.0
  O  O12  1  0.554  0.277  0.383  1.0
  O  O13  1  0.446  0.723  0.617  1.0
  O  O14  1  0.054  0.777  0.117  1.0
  O  O15  1  0.054  0.723  0.617  1.0
  F  F16  1  0.750  0.453  0.734  1.0
  F  F17  1  0.750  0.045  0.532  1.0
  F  F18  1  0.250  0.953  0.766  1.0
  F  F19  1  0.250  0.547  0.266  1.0
  F  F20  1  0.750  0.047  0.234  1.0
  F  F21  1  0.250  0.955  0.468  1.0
  F  F22  1  0.750  0.455  0.032  1.0
  F  F23  1  0.250  0.545  0.968  1.0
[/CIF]
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