The material structure described by Ga(W3O10)4 is Tungsten structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two Ga(W3O10)4 clusters. There are seven inequivalent W sites. In the first W site, W(1) is bonded in a 6-coordinate geometry to one O(1), one O(10), one O(13), one O(14), one O(16), and one O(22) atom. In the second W site, W(2) is bonded in a 6-coordinate geometry to one O(2), one O(22), two equivalent O(14), and two equivalent O(17) atoms. In the third W site, W(3) is bonded in a 6-coordinate geometry to one O(16), one O(19), one O(21), one O(23), one O(3), and one O(8) atom. In the fourth W site, W(4) is bonded in a 6-coordinate geometry to one O(23), one O(4), two equivalent O(18), and two equivalent O(19) atoms. In the fifth W site, W(5) is bonded in a 6-coordinate geometry to one O(10), one O(20), one O(24), one O(5), one O(8), and one O(9) atom. In the sixth W site, W(6) is bonded in a 6-coordinate geometry to one O(12), one O(15), one O(17), one O(20), one O(24), and one O(6) atom. In the seventh W site, W(7) is bonded in a 6-coordinate geometry to one O(11), one O(15), one O(18), one O(24), one O(7), and one O(9) atom. Ga(1) is bonded in a tetrahedral geometry to one O(22), one O(23), and two equivalent O(24) atoms. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one W(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one W(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one W(3) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one W(4) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one W(5) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one W(6) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one W(7) atom. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one W(3) and one W(5) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one W(5) and one W(7) atom. In the tenth O site, O(10) is bonded in a bent 150 degrees geometry to one W(1) and one W(5) atom. In the eleventh O site, O(11) is bonded in a bent 150 degrees geometry to two equivalent W(7) atoms. In the twelfth O site, O(12) is bonded in a bent 150 degrees geometry to two equivalent W(6) atoms. In the thirteenth O site, O(13) is bonded in a bent 120 degrees geometry to two equivalent W(1) atoms. In the fourteenth O site, O(14) is bonded in a bent 120 degrees geometry to one W(1) and one W(2) atom. In the fifteenth O site, O(15) is bonded in a bent 120 degrees geometry to one W(6) and one W(7) atom. In the sixteenth O site, O(16) is bonded in a bent 150 degrees geometry to one W(1) and one W(3) atom. In the seventeenth O site, O(17) is bonded in a bent 150 degrees geometry to one W(2) and one W(6) atom. In the eighteenth O site, O(18) is bonded in a bent 150 degrees geometry to one W(4) and one W(7) atom. In the nineteenth O site, O(19) is bonded in a bent 120 degrees geometry to one W(3) and one W(4) atom. In the twentieth O site, O(20) is bonded in a bent 120 degrees geometry to one W(5) and one W(6) atom. In the twenty-first O site, O(21) is bonded in a bent 120 degrees geometry to two equivalent W(3) atoms. In the twenty-second O site, O(22) is bonded in a distorted single-bond geometry to one W(2), two equivalent W(1), and one Ga(1) atom. In the twenty-third O site, O(23) is bonded in a distorted single-bond geometry to one W(4), two equivalent W(3), and one Ga(1) atom. In the twenty-fourth O site, O(24) is bonded in a distorted single-bond geometry to one W(5), one W(6), one W(7), and one Ga(1) atom. is represented by the CIF card [CIF]
data_Ga(W3O10)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   15.541
_cell_length_b   15.541
_cell_length_c   15.482
_cell_angle_alpha   70.527
_cell_angle_beta   70.527
_cell_angle_gamma   109.456
_symmetry_Int_Tables_number   1
_cell_volume   2878.721
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.306  0.306  0.558  1.0
  W  W1  1  0.161  0.022  0.708  1.0
  W  W2  1  0.022  0.161  0.708  1.0
  W  W3  1  0.156  0.156  0.847  1.0
  W  W4  1  0.307  0.172  0.408  1.0
  W  W5  1  0.172  0.307  0.408  1.0
  W  W6  1  0.442  0.442  0.273  1.0
  W  W7  1  0.458  0.172  0.557  1.0
  W  W8  1  0.172  0.458  0.557  1.0
  W  W9  1  0.455  0.305  0.695  1.0
  W  W10  1  0.305  0.455  0.695  1.0
  W  W11  1  0.592  0.443  0.422  1.0
  W  W12  1  0.443  0.592  0.422  1.0
  O  O13  1  0.107  0.887  0.758  1.0
  O  O14  1  0.887  0.107  0.758  1.0
  O  O15  1  0.106  0.106  0.982  1.0
  O  O16  1  0.308  0.087  0.358  1.0
  O  O17  1  0.087  0.308  0.358  1.0
  O  O18  1  0.527  0.527  0.137  1.0
  O  O19  1  0.512  0.091  0.553  1.0
  O  O20  1  0.091  0.512  0.553  1.0
  O  O21  1  0.506  0.307  0.779  1.0
  O  O22  1  0.307  0.506  0.779  1.0
  O  O23  1  0.726  0.529  0.337  1.0
  O  O24  1  0.529  0.726  0.337  1.0
  O  O25  1  0.410  0.180  0.455  1.0
  O  O26  1  0.180  0.410  0.455  1.0
  O  O27  1  0.586  0.308  0.448  1.0
  O  O28  1  0.308  0.586  0.448  1.0
  O  O29  1  0.309  0.072  0.663  1.0
  O  O30  1  0.072  0.309  0.663  1.0
  O  O31  1  0.538  0.538  0.431  1.0
  O  O32  1  0.408  0.408  0.686  1.0
  O  O33  1  0.033  0.033  0.727  1.0
  O  O34  1  0.139  0.028  0.838  1.0
  O  O35  1  0.028  0.139  0.838  1.0
  O  O36  1  0.584  0.416  0.559  1.0
  O  O37  1  0.416  0.584  0.559  1.0
  O  O38  1  0.206  0.076  0.559  1.0
  O  O39  1  0.076  0.206  0.559  1.0
  O  O40  1  0.306  0.203  0.792  1.0
  O  O41  1  0.203  0.306  0.792  1.0
  O  O42  1  0.538  0.435  0.326  1.0
  O  O43  1  0.435  0.538  0.326  1.0
  O  O44  1  0.417  0.307  0.278  1.0
  O  O45  1  0.307  0.417  0.278  1.0
  O  O46  1  0.478  0.198  0.667  1.0
  O  O47  1  0.198  0.478  0.667  1.0
  O  O48  1  0.198  0.198  0.389  1.0
  O  O49  1  0.189  0.189  0.675  1.0
  O  O50  1  0.309  0.309  0.439  1.0
  O  O51  1  0.422  0.304  0.560  1.0
  O  O52  1  0.304  0.422  0.560  1.0
[/CIF]
.
The material structure described by Ga(W3O10)4 is Tungsten structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two Ga(W3O10)4 clusters. There are seven inequivalent W sites. In the first W site, W(1) is bonded in a 6-coordinate geometry to one O(1), one O(10), one O(13), one O(14), one O(16), and one O(22) atom. In the second W site, W(2) is bonded in a 6-coordinate geometry to one O(2), one O(22), two equivalent O(14), and two equivalent O(17) atoms. In the third W site, W(3) is bonded in a 6-coordinate geometry to one O(16), one O(19), one O(21), one O(23), one O(3), and one O(8) atom. In the fourth W site, W(4) is bonded in a 6-coordinate geometry to one O(23), one O(4), two equivalent O(18), and two equivalent O(19) atoms. In the fifth W site, W(5) is bonded in a 6-coordinate geometry to one O(10), one O(20), one O(24), one O(5), one O(8), and one O(9) atom. In the sixth W site, W(6) is bonded in a 6-coordinate geometry to one O(12), one O(15), one O(17), one O(20), one O(24), and one O(6) atom. In the seventh W site, W(7) is bonded in a 6-coordinate geometry to one O(11), one O(15), one O(18), one O(24), one O(7), and one O(9) atom. Ga(1) is bonded in a tetrahedral geometry to one O(22), one O(23), and two equivalent O(24) atoms. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one W(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one W(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one W(3) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one W(4) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one W(5) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one W(6) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one W(7) atom. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one W(3) and one W(5) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one W(5) and one W(7) atom. In the tenth O site, O(10) is bonded in a bent 150 degrees geometry to one W(1) and one W(5) atom. In the eleventh O site, O(11) is bonded in a bent 150 degrees geometry to two equivalent W(7) atoms. In the twelfth O site, O(12) is bonded in a bent 150 degrees geometry to two equivalent W(6) atoms. In the thirteenth O site, O(13) is bonded in a bent 120 degrees geometry to two equivalent W(1) atoms. In the fourteenth O site, O(14) is bonded in a bent 120 degrees geometry to one W(1) and one W(2) atom. In the fifteenth O site, O(15) is bonded in a bent 120 degrees geometry to one W(6) and one W(7) atom. In the sixteenth O site, O(16) is bonded in a bent 150 degrees geometry to one W(1) and one W(3) atom. In the seventeenth O site, O(17) is bonded in a bent 150 degrees geometry to one W(2) and one W(6) atom. In the eighteenth O site, O(18) is bonded in a bent 150 degrees geometry to one W(4) and one W(7) atom. In the nineteenth O site, O(19) is bonded in a bent 120 degrees geometry to one W(3) and one W(4) atom. In the twentieth O site, O(20) is bonded in a bent 120 degrees geometry to one W(5) and one W(6) atom. In the twenty-first O site, O(21) is bonded in a bent 120 degrees geometry to two equivalent W(3) atoms. In the twenty-second O site, O(22) is bonded in a distorted single-bond geometry to one W(2), two equivalent W(1), and one Ga(1) atom. In the twenty-third O site, O(23) is bonded in a distorted single-bond geometry to one W(4), two equivalent W(3), and one Ga(1) atom. In the twenty-fourth O site, O(24) is bonded in a distorted single-bond geometry to one W(5), one W(6), one W(7), and one Ga(1) atom. is represented by the CIF card [CIF]
data_Ga(W3O10)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   15.541
_cell_length_b   15.541
_cell_length_c   15.482
_cell_angle_alpha   70.527
_cell_angle_beta   70.527
_cell_angle_gamma   109.456
_symmetry_Int_Tables_number   1
_cell_volume   2878.721
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.306  0.306  0.558  1.0
  W  W1  1  0.161  0.022  0.708  1.0
  W  W2  1  0.022  0.161  0.708  1.0
  W  W3  1  0.156  0.156  0.847  1.0
  W  W4  1  0.307  0.172  0.408  1.0
  W  W5  1  0.172  0.307  0.408  1.0
  W  W6  1  0.442  0.442  0.273  1.0
  W  W7  1  0.458  0.172  0.557  1.0
  W  W8  1  0.172  0.458  0.557  1.0
  W  W9  1  0.455  0.305  0.695  1.0
  W  W10  1  0.305  0.455  0.695  1.0
  W  W11  1  0.592  0.443  0.422  1.0
  W  W12  1  0.443  0.592  0.422  1.0
  O  O13  1  0.107  0.887  0.758  1.0
  O  O14  1  0.887  0.107  0.758  1.0
  O  O15  1  0.106  0.106  0.982  1.0
  O  O16  1  0.308  0.087  0.358  1.0
  O  O17  1  0.087  0.308  0.358  1.0
  O  O18  1  0.527  0.527  0.137  1.0
  O  O19  1  0.512  0.091  0.553  1.0
  O  O20  1  0.091  0.512  0.553  1.0
  O  O21  1  0.506  0.307  0.779  1.0
  O  O22  1  0.307  0.506  0.779  1.0
  O  O23  1  0.726  0.529  0.337  1.0
  O  O24  1  0.529  0.726  0.337  1.0
  O  O25  1  0.410  0.180  0.455  1.0
  O  O26  1  0.180  0.410  0.455  1.0
  O  O27  1  0.586  0.308  0.448  1.0
  O  O28  1  0.308  0.586  0.448  1.0
  O  O29  1  0.309  0.072  0.663  1.0
  O  O30  1  0.072  0.309  0.663  1.0
  O  O31  1  0.538  0.538  0.431  1.0
  O  O32  1  0.408  0.408  0.686  1.0
  O  O33  1  0.033  0.033  0.727  1.0
  O  O34  1  0.139  0.028  0.838  1.0
  O  O35  1  0.028  0.139  0.838  1.0
  O  O36  1  0.584  0.416  0.559  1.0
  O  O37  1  0.416  0.584  0.559  1.0
  O  O38  1  0.206  0.076  0.559  1.0
  O  O39  1  0.076  0.206  0.559  1.0
  O  O40  1  0.306  0.203  0.792  1.0
  O  O41  1  0.203  0.306  0.792  1.0
  O  O42  1  0.538  0.435  0.326  1.0
  O  O43  1  0.435  0.538  0.326  1.0
  O  O44  1  0.417  0.307  0.278  1.0
  O  O45  1  0.307  0.417  0.278  1.0
  O  O46  1  0.478  0.198  0.667  1.0
  O  O47  1  0.198  0.478  0.667  1.0
  O  O48  1  0.198  0.198  0.389  1.0
  O  O49  1  0.189  0.189  0.675  1.0
  O  O50  1  0.309  0.309  0.439  1.0
  O  O51  1  0.422  0.304  0.560  1.0
  O  O52  1  0.304  0.422  0.560  1.0
[/CIF]
.