The material structure described by Gd3NTe2O crystallizes in the orthorhombic Pnma space group. There are three inequivalent Gd sites. In the first Gd site, Gd(1) is bonded in a 4-coordinate geometry to one N(1), two equivalent Te(1), two equivalent Te(2), and three equivalent O(1) atoms. In the second Gd site, Gd(2) is bonded in a 3-coordinate geometry to two equivalent N(1), one Te(2), three equivalent Te(1), and one O(1) atom. In the third Gd site, Gd(3) is bonded in a distorted single-bond geometry to one N(1), two equivalent Te(1), and three equivalent Te(2) atoms. N(1) is bonded to one Gd(1), one Gd(3), and two equivalent Gd(2) atoms to form NGd4 tetrahedra that share  a cornercorner with one O(1)Gd4 tetrahedra, corners with two equivalent N(1)Gd4 tetrahedra, and edges with two equivalent O(1)Gd4 tetrahedra. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a 7-coordinate geometry to two equivalent Gd(1), two equivalent Gd(3), and three equivalent Gd(2) atoms. In the second Te site, Te(2) is bonded in a 6-coordinate geometry to one Gd(2), two equivalent Gd(1), and three equivalent Gd(3) atoms. O(1) is bonded to one Gd(2) and three equivalent Gd(1) atoms to form OGd4 tetrahedra that share  a cornercorner with one N(1)Gd4 tetrahedra, corners with two equivalent O(1)Gd4 tetrahedra, edges with two equivalent N(1)Gd4 tetrahedra, and edges with two equivalent O(1)Gd4 tetrahedra. is represented by the CIF card [CIF]
data_Gd3Te2NO
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.554
_cell_length_b   4.117
_cell_length_c   12.207
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   681.130
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Gd  Gd0  1  0.522  0.250  0.621  1.0
  Gd  Gd1  1  0.022  0.250  0.879  1.0
  Gd  Gd2  1  0.478  0.750  0.379  1.0
  Gd  Gd3  1  0.978  0.750  0.121  1.0
  Gd  Gd4  1  0.689  0.250  0.351  1.0
  Gd  Gd5  1  0.189  0.250  0.149  1.0
  Gd  Gd6  1  0.311  0.750  0.649  1.0
  Gd  Gd7  1  0.811  0.750  0.851  1.0
  Gd  Gd8  1  0.895  0.250  0.614  1.0
  Gd  Gd9  1  0.395  0.250  0.886  1.0
  Gd  Gd10  1  0.105  0.750  0.386  1.0
  Gd  Gd11  1  0.605  0.750  0.114  1.0
  Te  Te12  1  0.772  0.250  0.072  1.0
  Te  Te13  1  0.272  0.250  0.428  1.0
  Te  Te14  1  0.228  0.750  0.928  1.0
  Te  Te15  1  0.728  0.750  0.572  1.0
  Te  Te16  1  0.934  0.250  0.348  1.0
  Te  Te17  1  0.434  0.250  0.152  1.0
  Te  Te18  1  0.066  0.750  0.652  1.0
  Te  Te19  1  0.566  0.750  0.848  1.0
  N  N20  1  0.870  0.250  0.789  1.0
  N  N21  1  0.370  0.250  0.711  1.0
  N  N22  1  0.130  0.750  0.211  1.0
  N  N23  1  0.630  0.750  0.289  1.0
  O  O24  1  0.541  0.250  0.433  1.0
  O  O25  1  0.041  0.250  0.067  1.0
  O  O26  1  0.459  0.750  0.567  1.0
  O  O27  1  0.959  0.750  0.933  1.0
[/CIF]
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The material structure described by Gd3NTe2O crystallizes in the orthorhombic Pnma space group. There are three inequivalent Gd sites. In the first Gd site, Gd(1) is bonded in a 4-coordinate geometry to one N(1), two equivalent Te(1), two equivalent Te(2), and three equivalent O(1) atoms. In the second Gd site, Gd(2) is bonded in a 3-coordinate geometry to two equivalent N(1), one Te(2), three equivalent Te(1), and one O(1) atom. In the third Gd site, Gd(3) is bonded in a distorted single-bond geometry to one N(1), two equivalent Te(1), and three equivalent Te(2) atoms. N(1) is bonded to one Gd(1), one Gd(3), and two equivalent Gd(2) atoms to form NGd4 tetrahedra that share  a cornercorner with one O(1)Gd4 tetrahedra, corners with two equivalent N(1)Gd4 tetrahedra, and edges with two equivalent O(1)Gd4 tetrahedra. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a 7-coordinate geometry to two equivalent Gd(1), two equivalent Gd(3), and three equivalent Gd(2) atoms. In the second Te site, Te(2) is bonded in a 6-coordinate geometry to one Gd(2), two equivalent Gd(1), and three equivalent Gd(3) atoms. O(1) is bonded to one Gd(2) and three equivalent Gd(1) atoms to form OGd4 tetrahedra that share  a cornercorner with one N(1)Gd4 tetrahedra, corners with two equivalent O(1)Gd4 tetrahedra, edges with two equivalent N(1)Gd4 tetrahedra, and edges with two equivalent O(1)Gd4 tetrahedra. is represented by the CIF card [CIF]
data_Gd3Te2NO
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.554
_cell_length_b   4.117
_cell_length_c   12.207
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   681.130
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Gd  Gd0  1  0.522  0.250  0.621  1.0
  Gd  Gd1  1  0.022  0.250  0.879  1.0
  Gd  Gd2  1  0.478  0.750  0.379  1.0
  Gd  Gd3  1  0.978  0.750  0.121  1.0
  Gd  Gd4  1  0.689  0.250  0.351  1.0
  Gd  Gd5  1  0.189  0.250  0.149  1.0
  Gd  Gd6  1  0.311  0.750  0.649  1.0
  Gd  Gd7  1  0.811  0.750  0.851  1.0
  Gd  Gd8  1  0.895  0.250  0.614  1.0
  Gd  Gd9  1  0.395  0.250  0.886  1.0
  Gd  Gd10  1  0.105  0.750  0.386  1.0
  Gd  Gd11  1  0.605  0.750  0.114  1.0
  Te  Te12  1  0.772  0.250  0.072  1.0
  Te  Te13  1  0.272  0.250  0.428  1.0
  Te  Te14  1  0.228  0.750  0.928  1.0
  Te  Te15  1  0.728  0.750  0.572  1.0
  Te  Te16  1  0.934  0.250  0.348  1.0
  Te  Te17  1  0.434  0.250  0.152  1.0
  Te  Te18  1  0.066  0.750  0.652  1.0
  Te  Te19  1  0.566  0.750  0.848  1.0
  N  N20  1  0.870  0.250  0.789  1.0
  N  N21  1  0.370  0.250  0.711  1.0
  N  N22  1  0.130  0.750  0.211  1.0
  N  N23  1  0.630  0.750  0.289  1.0
  O  O24  1  0.541  0.250  0.433  1.0
  O  O25  1  0.041  0.250  0.067  1.0
  O  O26  1  0.459  0.750  0.567  1.0
  O  O27  1  0.959  0.750  0.933  1.0
[/CIF]
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