The crystal structure described by LiMn(PO3)4 crystallizes in the monoclinic C2/c space group. Li(1) is bonded in a distorted see-saw-like geometry to two equivalent O(1) and two equivalent O(3) atoms. Mn(1) is bonded to two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms to form distorted MnO6 octahedra that share corners with two equivalent P(1)O4 tetrahedra and corners with four equivalent P(2)O4 tetrahedra. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), one O(5), and one O(6) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra and corners with two equivalent P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 51°. In the second P site, P(2) is bonded to one O(3), one O(4), one O(5), and one O(6) atom to form PO4 tetrahedra that share corners with two equivalent Mn(1)O6 octahedra and corners with two equivalent P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 11-41°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Li(1) and one P(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Mn(1) and one P(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Li(1), one Mn(1), and one P(2) atom. In the fourth O site, O(4) is bonded in a distorted linear geometry to one Mn(1) and one P(2) atom. In the fifth O site, O(5) is bonded in a linear geometry to one P(1) and one P(2) atom. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one P(1) and one P(2) atom. is represented by the CIF card [CIF]
data_LiMn(PO3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.989
_cell_length_b   6.989
_cell_length_c   10.003
_cell_angle_alpha   89.040
_cell_angle_beta   89.040
_cell_angle_gamma   107.486
_symmetry_Int_Tables_number   1
_cell_volume   465.906
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.148  0.852  0.250  1.0
  Li  Li1  1  0.852  0.148  0.750  1.0
  Mn  Mn2  1  0.883  0.117  0.250  1.0
  Mn  Mn3  1  0.117  0.883  0.750  1.0
  P  P4  1  0.285  0.666  0.978  1.0
  P  P5  1  0.666  0.285  0.478  1.0
  P  P6  1  0.270  0.216  0.040  1.0
  P  P7  1  0.784  0.730  0.460  1.0
  P  P8  1  0.216  0.270  0.540  1.0
  P  P9  1  0.730  0.784  0.960  1.0
  P  P10  1  0.334  0.715  0.522  1.0
  P  P11  1  0.715  0.334  0.022  1.0
  O  O12  1  0.267  0.774  0.101  1.0
  O  O13  1  0.662  0.142  0.363  1.0
  O  O14  1  0.147  0.133  0.167  1.0
  O  O15  1  0.774  0.267  0.601  1.0
  O  O16  1  0.770  0.903  0.083  1.0
  O  O17  1  0.142  0.662  0.863  1.0
  O  O18  1  0.563  0.740  0.488  1.0
  O  O19  1  0.495  0.255  0.091  1.0
  O  O20  1  0.745  0.505  0.409  1.0
  O  O21  1  0.260  0.437  0.012  1.0
  O  O22  1  0.133  0.147  0.667  1.0
  O  O23  1  0.097  0.230  0.417  1.0
  O  O24  1  0.903  0.770  0.583  1.0
  O  O25  1  0.867  0.853  0.333  1.0
  O  O26  1  0.740  0.563  0.988  1.0
  O  O27  1  0.255  0.495  0.591  1.0
  O  O28  1  0.505  0.745  0.909  1.0
  O  O29  1  0.437  0.260  0.512  1.0
  O  O30  1  0.858  0.338  0.137  1.0
  O  O31  1  0.230  0.097  0.917  1.0
  O  O32  1  0.226  0.733  0.399  1.0
  O  O33  1  0.853  0.867  0.833  1.0
  O  O34  1  0.338  0.858  0.637  1.0
  O  O35  1  0.733  0.226  0.899  1.0
[/CIF]
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The crystal structure described by LiMn(PO3)4 crystallizes in the monoclinic C2/c space group. Li(1) is bonded in a distorted see-saw-like geometry to two equivalent O(1) and two equivalent O(3) atoms. Mn(1) is bonded to two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms to form distorted MnO6 octahedra that share corners with two equivalent P(1)O4 tetrahedra and corners with four equivalent P(2)O4 tetrahedra. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), one O(5), and one O(6) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra and corners with two equivalent P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 51°. In the second P site, P(2) is bonded to one O(3), one O(4), one O(5), and one O(6) atom to form PO4 tetrahedra that share corners with two equivalent Mn(1)O6 octahedra and corners with two equivalent P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 11-41°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Li(1) and one P(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Mn(1) and one P(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Li(1), one Mn(1), and one P(2) atom. In the fourth O site, O(4) is bonded in a distorted linear geometry to one Mn(1) and one P(2) atom. In the fifth O site, O(5) is bonded in a linear geometry to one P(1) and one P(2) atom. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one P(1) and one P(2) atom. is represented by the CIF card [CIF]
data_LiMn(PO3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.989
_cell_length_b   6.989
_cell_length_c   10.003
_cell_angle_alpha   89.040
_cell_angle_beta   89.040
_cell_angle_gamma   107.486
_symmetry_Int_Tables_number   1
_cell_volume   465.906
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.148  0.852  0.250  1.0
  Li  Li1  1  0.852  0.148  0.750  1.0
  Mn  Mn2  1  0.883  0.117  0.250  1.0
  Mn  Mn3  1  0.117  0.883  0.750  1.0
  P  P4  1  0.285  0.666  0.978  1.0
  P  P5  1  0.666  0.285  0.478  1.0
  P  P6  1  0.270  0.216  0.040  1.0
  P  P7  1  0.784  0.730  0.460  1.0
  P  P8  1  0.216  0.270  0.540  1.0
  P  P9  1  0.730  0.784  0.960  1.0
  P  P10  1  0.334  0.715  0.522  1.0
  P  P11  1  0.715  0.334  0.022  1.0
  O  O12  1  0.267  0.774  0.101  1.0
  O  O13  1  0.662  0.142  0.363  1.0
  O  O14  1  0.147  0.133  0.167  1.0
  O  O15  1  0.774  0.267  0.601  1.0
  O  O16  1  0.770  0.903  0.083  1.0
  O  O17  1  0.142  0.662  0.863  1.0
  O  O18  1  0.563  0.740  0.488  1.0
  O  O19  1  0.495  0.255  0.091  1.0
  O  O20  1  0.745  0.505  0.409  1.0
  O  O21  1  0.260  0.437  0.012  1.0
  O  O22  1  0.133  0.147  0.667  1.0
  O  O23  1  0.097  0.230  0.417  1.0
  O  O24  1  0.903  0.770  0.583  1.0
  O  O25  1  0.867  0.853  0.333  1.0
  O  O26  1  0.740  0.563  0.988  1.0
  O  O27  1  0.255  0.495  0.591  1.0
  O  O28  1  0.505  0.745  0.909  1.0
  O  O29  1  0.437  0.260  0.512  1.0
  O  O30  1  0.858  0.338  0.137  1.0
  O  O31  1  0.230  0.097  0.917  1.0
  O  O32  1  0.226  0.733  0.399  1.0
  O  O33  1  0.853  0.867  0.833  1.0
  O  O34  1  0.338  0.858  0.637  1.0
  O  O35  1  0.733  0.226  0.899  1.0
[/CIF]
.