The structure described by CsUGa(PO5)2 crystallizes in the triclinic P-1 space group. Cs(1) is bonded in a 8-coordinate geometry to one O(2), one O(4), one O(5), one O(8), two equivalent O(1), and two equivalent O(6) atoms. U(1) is bonded in a 7-coordinate geometry to one O(1), one O(2), one O(3), one O(5), one O(6), and two equivalent O(7) atoms. Ga(1) is bonded to one O(10), one O(4), one O(8), and one O(9) atom to form GaO4 tetrahedra that share corners with two equivalent P(1)O4 tetrahedra and corners with two equivalent P(2)O4 tetrahedra. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(4), one O(6), one O(7), and one O(9) atom to form PO4 tetrahedra that share corners with two equivalent Ga(1)O4 tetrahedra. In the second P site, P(2) is bonded to one O(10), one O(2), one O(3), and one O(8) atom to form PO4 tetrahedra that share corners with two equivalent Ga(1)O4 tetrahedra. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to two equivalent Cs(1) and one U(1) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Cs(1), one U(1), and one P(2) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one U(1) and one P(2) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Cs(1), one Ga(1), and one P(1) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Cs(1) and one U(1) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to two equivalent Cs(1), one U(1), and one P(1) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to two equivalent U(1) and one P(1) atom. In the eighth O site, O(8) is bonded in a 2-coordinate geometry to one Cs(1), one Ga(1), and one P(2) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one Ga(1) and one P(1) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Ga(1) and one P(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CsUGa(PO5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.942
_cell_length_b   8.645
_cell_length_c   9.096
_cell_angle_alpha   113.790
_cell_angle_beta   109.924
_cell_angle_gamma   83.577
_symmetry_Int_Tables_number   1
_cell_volume   537.056
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.333  0.304  0.484  1.0
  Cs  Cs1  1  0.667  0.696  0.516  1.0
  U  U2  1  0.785  0.079  0.334  1.0
  U  U3  1  0.215  0.921  0.666  1.0
  Ga  Ga4  1  0.755  0.422  0.988  1.0
  Ga  Ga5  1  0.245  0.578  0.012  1.0
  P  P6  1  0.957  0.325  0.716  1.0
  P  P7  1  0.043  0.675  0.284  1.0
  P  P8  1  0.473  0.264  0.056  1.0
  P  P9  1  0.527  0.736  0.944  1.0
  O  O10  1  0.367  0.992  0.594  1.0
  O  O11  1  0.556  0.227  0.218  1.0
  O  O12  1  0.320  0.136  0.927  1.0
  O  O13  1  0.887  0.541  0.213  1.0
  O  O14  1  0.055  0.846  0.727  1.0
  O  O15  1  0.200  0.646  0.424  1.0
  O  O16  1  0.976  0.852  0.376  1.0
  O  O17  1  0.402  0.448  0.116  1.0
  O  O18  1  0.908  0.323  0.866  1.0
  O  O19  1  0.800  0.354  0.576  1.0
  O  O20  1  0.680  0.864  0.073  1.0
  O  O21  1  0.024  0.148  0.624  1.0
  O  O22  1  0.945  0.154  0.273  1.0
  O  O23  1  0.444  0.773  0.782  1.0
  O  O24  1  0.092  0.677  0.134  1.0
  O  O25  1  0.617  0.256  0.973  1.0
  O  O26  1  0.383  0.744  0.027  1.0
  O  O27  1  0.113  0.459  0.787  1.0
  O  O28  1  0.598  0.552  0.884  1.0
  O  O29  1  0.633  0.008  0.406  1.0
[/CIF]
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The structure described by CsUGa(PO5)2 crystallizes in the triclinic P-1 space group. Cs(1) is bonded in a 8-coordinate geometry to one O(2), one O(4), one O(5), one O(8), two equivalent O(1), and two equivalent O(6) atoms. U(1) is bonded in a 7-coordinate geometry to one O(1), one O(2), one O(3), one O(5), one O(6), and two equivalent O(7) atoms. Ga(1) is bonded to one O(10), one O(4), one O(8), and one O(9) atom to form GaO4 tetrahedra that share corners with two equivalent P(1)O4 tetrahedra and corners with two equivalent P(2)O4 tetrahedra. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(4), one O(6), one O(7), and one O(9) atom to form PO4 tetrahedra that share corners with two equivalent Ga(1)O4 tetrahedra. In the second P site, P(2) is bonded to one O(10), one O(2), one O(3), and one O(8) atom to form PO4 tetrahedra that share corners with two equivalent Ga(1)O4 tetrahedra. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to two equivalent Cs(1) and one U(1) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Cs(1), one U(1), and one P(2) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one U(1) and one P(2) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Cs(1), one Ga(1), and one P(1) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Cs(1) and one U(1) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to two equivalent Cs(1), one U(1), and one P(1) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to two equivalent U(1) and one P(1) atom. In the eighth O site, O(8) is bonded in a 2-coordinate geometry to one Cs(1), one Ga(1), and one P(2) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one Ga(1) and one P(1) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Ga(1) and one P(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CsUGa(PO5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.942
_cell_length_b   8.645
_cell_length_c   9.096
_cell_angle_alpha   113.790
_cell_angle_beta   109.924
_cell_angle_gamma   83.577
_symmetry_Int_Tables_number   1
_cell_volume   537.056
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.333  0.304  0.484  1.0
  Cs  Cs1  1  0.667  0.696  0.516  1.0
  U  U2  1  0.785  0.079  0.334  1.0
  U  U3  1  0.215  0.921  0.666  1.0
  Ga  Ga4  1  0.755  0.422  0.988  1.0
  Ga  Ga5  1  0.245  0.578  0.012  1.0
  P  P6  1  0.957  0.325  0.716  1.0
  P  P7  1  0.043  0.675  0.284  1.0
  P  P8  1  0.473  0.264  0.056  1.0
  P  P9  1  0.527  0.736  0.944  1.0
  O  O10  1  0.367  0.992  0.594  1.0
  O  O11  1  0.556  0.227  0.218  1.0
  O  O12  1  0.320  0.136  0.927  1.0
  O  O13  1  0.887  0.541  0.213  1.0
  O  O14  1  0.055  0.846  0.727  1.0
  O  O15  1  0.200  0.646  0.424  1.0
  O  O16  1  0.976  0.852  0.376  1.0
  O  O17  1  0.402  0.448  0.116  1.0
  O  O18  1  0.908  0.323  0.866  1.0
  O  O19  1  0.800  0.354  0.576  1.0
  O  O20  1  0.680  0.864  0.073  1.0
  O  O21  1  0.024  0.148  0.624  1.0
  O  O22  1  0.945  0.154  0.273  1.0
  O  O23  1  0.444  0.773  0.782  1.0
  O  O24  1  0.092  0.677  0.134  1.0
  O  O25  1  0.617  0.256  0.973  1.0
  O  O26  1  0.383  0.744  0.027  1.0
  O  O27  1  0.113  0.459  0.787  1.0
  O  O28  1  0.598  0.552  0.884  1.0
  O  O29  1  0.633  0.008  0.406  1.0
[/CIF]
.