The material structure described by WCl6Te3I is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four tungsten(vi) chloride molecules and two Te3I clusters. In each Te3I cluster, there are three inequivalent Te sites. In the first Te site, Te(1) is bonded in a water-like geometry to one Te(2) and one Te(3) atom. In the second Te site, Te(2) is bonded in a water-like geometry to one Te(1) and one Te(3) atom. In the third Te site, Te(3) is bonded in a distorted single-bond geometry to one Te(1), one Te(2), and one I(1) atom. I(1) is bonded in a single-bond geometry to one Te(3) atom. is represented by the CIF card [CIF]
data_Te3WICl6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.006
_cell_length_b   11.853
_cell_length_c   12.041
_cell_angle_alpha   68.322
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1459.636
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.188  0.112  0.044  1.0
  Te  Te1  1  0.210  0.940  0.952  1.0
  Te  Te2  1  0.710  0.060  0.548  1.0
  Te  Te3  1  0.812  0.888  0.956  1.0
  Te  Te4  1  0.510  0.011  0.718  1.0
  Te  Te5  1  0.990  0.011  0.218  1.0
  Te  Te6  1  0.790  0.060  0.048  1.0
  Te  Te7  1  0.290  0.940  0.452  1.0
  Te  Te8  1  0.010  0.989  0.782  1.0
  Te  Te9  1  0.312  0.112  0.544  1.0
  Te  Te10  1  0.688  0.888  0.456  1.0
  Te  Te11  1  0.490  0.989  0.282  1.0
  W  W12  1  0.005  0.639  0.714  1.0
  W  W13  1  0.495  0.639  0.214  1.0
  W  W14  1  0.995  0.361  0.286  1.0
  W  W15  1  0.505  0.361  0.786  1.0
  I  I16  1  0.970  0.227  0.740  1.0
  I  I17  1  0.530  0.227  0.240  1.0
  I  I18  1  0.030  0.773  0.260  1.0
  I  I19  1  0.470  0.773  0.760  1.0
  Cl  Cl20  1  0.614  0.558  0.104  1.0
  Cl  Cl21  1  0.670  0.691  0.296  1.0
  Cl  Cl22  1  0.482  0.454  0.369  1.0
  Cl  Cl23  1  0.005  0.163  0.437  1.0
  Cl  Cl24  1  0.505  0.837  0.063  1.0
  Cl  Cl25  1  0.018  0.454  0.869  1.0
  Cl  Cl26  1  0.330  0.309  0.704  1.0
  Cl  Cl27  1  0.386  0.442  0.896  1.0
  Cl  Cl28  1  0.680  0.391  0.876  1.0
  Cl  Cl29  1  0.830  0.691  0.796  1.0
  Cl  Cl30  1  0.320  0.609  0.124  1.0
  Cl  Cl31  1  0.114  0.442  0.396  1.0
  Cl  Cl32  1  0.180  0.609  0.624  1.0
  Cl  Cl33  1  0.878  0.274  0.168  1.0
  Cl  Cl34  1  0.495  0.163  0.937  1.0
  Cl  Cl35  1  0.886  0.558  0.604  1.0
  Cl  Cl36  1  0.820  0.391  0.376  1.0
  Cl  Cl37  1  0.121  0.726  0.832  1.0
  Cl  Cl38  1  0.518  0.546  0.631  1.0
  Cl  Cl39  1  0.995  0.837  0.563  1.0
  Cl  Cl40  1  0.379  0.726  0.332  1.0
  Cl  Cl41  1  0.622  0.274  0.668  1.0
  Cl  Cl42  1  0.170  0.309  0.204  1.0
  Cl  Cl43  1  0.982  0.546  0.131  1.0
[/CIF]
.
The material structure described by WCl6Te3I is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four tungsten(vi) chloride molecules and two Te3I clusters. In each Te3I cluster, there are three inequivalent Te sites. In the first Te site, Te(1) is bonded in a water-like geometry to one Te(2) and one Te(3) atom. In the second Te site, Te(2) is bonded in a water-like geometry to one Te(1) and one Te(3) atom. In the third Te site, Te(3) is bonded in a distorted single-bond geometry to one Te(1), one Te(2), and one I(1) atom. I(1) is bonded in a single-bond geometry to one Te(3) atom. is represented by the CIF card [CIF]
data_Te3WICl6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.006
_cell_length_b   11.853
_cell_length_c   12.041
_cell_angle_alpha   68.322
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1459.636
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.188  0.112  0.044  1.0
  Te  Te1  1  0.210  0.940  0.952  1.0
  Te  Te2  1  0.710  0.060  0.548  1.0
  Te  Te3  1  0.812  0.888  0.956  1.0
  Te  Te4  1  0.510  0.011  0.718  1.0
  Te  Te5  1  0.990  0.011  0.218  1.0
  Te  Te6  1  0.790  0.060  0.048  1.0
  Te  Te7  1  0.290  0.940  0.452  1.0
  Te  Te8  1  0.010  0.989  0.782  1.0
  Te  Te9  1  0.312  0.112  0.544  1.0
  Te  Te10  1  0.688  0.888  0.456  1.0
  Te  Te11  1  0.490  0.989  0.282  1.0
  W  W12  1  0.005  0.639  0.714  1.0
  W  W13  1  0.495  0.639  0.214  1.0
  W  W14  1  0.995  0.361  0.286  1.0
  W  W15  1  0.505  0.361  0.786  1.0
  I  I16  1  0.970  0.227  0.740  1.0
  I  I17  1  0.530  0.227  0.240  1.0
  I  I18  1  0.030  0.773  0.260  1.0
  I  I19  1  0.470  0.773  0.760  1.0
  Cl  Cl20  1  0.614  0.558  0.104  1.0
  Cl  Cl21  1  0.670  0.691  0.296  1.0
  Cl  Cl22  1  0.482  0.454  0.369  1.0
  Cl  Cl23  1  0.005  0.163  0.437  1.0
  Cl  Cl24  1  0.505  0.837  0.063  1.0
  Cl  Cl25  1  0.018  0.454  0.869  1.0
  Cl  Cl26  1  0.330  0.309  0.704  1.0
  Cl  Cl27  1  0.386  0.442  0.896  1.0
  Cl  Cl28  1  0.680  0.391  0.876  1.0
  Cl  Cl29  1  0.830  0.691  0.796  1.0
  Cl  Cl30  1  0.320  0.609  0.124  1.0
  Cl  Cl31  1  0.114  0.442  0.396  1.0
  Cl  Cl32  1  0.180  0.609  0.624  1.0
  Cl  Cl33  1  0.878  0.274  0.168  1.0
  Cl  Cl34  1  0.495  0.163  0.937  1.0
  Cl  Cl35  1  0.886  0.558  0.604  1.0
  Cl  Cl36  1  0.820  0.391  0.376  1.0
  Cl  Cl37  1  0.121  0.726  0.832  1.0
  Cl  Cl38  1  0.518  0.546  0.631  1.0
  Cl  Cl39  1  0.995  0.837  0.563  1.0
  Cl  Cl40  1  0.379  0.726  0.332  1.0
  Cl  Cl41  1  0.622  0.274  0.668  1.0
  Cl  Cl42  1  0.170  0.309  0.204  1.0
  Cl  Cl43  1  0.982  0.546  0.131  1.0
[/CIF]
.