The structure described by LiLa(PO3)4 crystallizes in the monoclinic C2/c space group. Li(1) is bonded to two equivalent O(3) and two equivalent O(5) atoms to form distorted LiO4 tetrahedra that share corners with two equivalent P(1)O4 tetrahedra and corners with two equivalent P(2)O4 tetrahedra. La(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(3), two equivalent O(5), and two equivalent O(6) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form PO4 tetrahedra that share  a cornercorner with one Li(1)O4 tetrahedra and corners with two equivalent P(2)O4 tetrahedra. In the second P site, P(2) is bonded to one O(2), one O(4), one O(5), and one O(6) atom to form PO4 tetrahedra that share  a cornercorner with one Li(1)O4 tetrahedra and corners with two equivalent P(1)O4 tetrahedra. There are six inequivalent O sites. In the first O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Li(1), one La(1), and one P(1) atom. In the second O site, O(4) is bonded in a distorted bent 120 degrees geometry to one P(1) and one P(2) atom. In the third O site, O(5) is bonded in a 3-coordinate geometry to one Li(1), one La(1), and one P(2) atom. In the fourth O site, O(6) is bonded in a 2-coordinate geometry to one La(1) and one P(2) atom. In the fifth O site, O(1) is bonded in a distorted bent 150 degrees geometry to one La(1) and one P(1) atom. In the sixth O site, O(2) is bonded in a distorted bent 120 degrees geometry to one P(1) and one P(2) atom. is represented by the CIF file [CIF]
data_LiLa(PO3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.146
_cell_length_b   9.146
_cell_length_c   10.009
_cell_angle_alpha   56.799
_cell_angle_beta   56.799
_cell_angle_gamma   46.458
_symmetry_Int_Tables_number   1
_cell_volume   487.341
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.203  0.797  0.250  1.0
  Li  Li1  1  0.797  0.203  0.750  1.0
  La  La2  1  0.702  0.298  0.250  1.0
  La  La3  1  0.298  0.702  0.750  1.0
  P  P4  1  0.084  0.194  0.385  1.0
  P  P5  1  0.806  0.916  0.115  1.0
  P  P6  1  0.916  0.806  0.615  1.0
  P  P7  1  0.194  0.084  0.885  1.0
  P  P8  1  0.193  0.509  0.200  1.0
  P  P9  1  0.491  0.807  0.300  1.0
  P  P10  1  0.807  0.491  0.800  1.0
  P  P11  1  0.509  0.193  0.700  1.0
  O  O12  1  0.901  0.330  0.319  1.0
  O  O13  1  0.670  0.099  0.181  1.0
  O  O14  1  0.099  0.670  0.681  1.0
  O  O15  1  0.330  0.901  0.819  1.0
  O  O16  1  0.160  0.329  0.354  1.0
  O  O17  1  0.671  0.840  0.146  1.0
  O  O18  1  0.840  0.671  0.646  1.0
  O  O19  1  0.329  0.160  0.854  1.0
  O  O20  1  0.939  0.925  0.432  1.0
  O  O21  1  0.075  0.061  0.068  1.0
  O  O22  1  0.061  0.075  0.568  1.0
  O  O23  1  0.925  0.939  0.932  1.0
  O  O24  1  0.280  0.039  0.269  1.0
  O  O25  1  0.961  0.720  0.231  1.0
  O  O26  1  0.720  0.961  0.731  1.0
  O  O27  1  0.039  0.280  0.769  1.0
  O  O28  1  0.327  0.522  0.231  1.0
  O  O29  1  0.478  0.673  0.269  1.0
  O  O30  1  0.673  0.478  0.769  1.0
  O  O31  1  0.522  0.327  0.731  1.0
  O  O32  1  0.485  0.255  0.537  1.0
  O  O33  1  0.745  0.515  0.963  1.0
  O  O34  1  0.515  0.745  0.463  1.0
  O  O35  1  0.255  0.485  0.037  1.0
[/CIF]
.
The structure described by LiLa(PO3)4 crystallizes in the monoclinic C2/c space group. Li(1) is bonded to two equivalent O(3) and two equivalent O(5) atoms to form distorted LiO4 tetrahedra that share corners with two equivalent P(1)O4 tetrahedra and corners with two equivalent P(2)O4 tetrahedra. La(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(3), two equivalent O(5), and two equivalent O(6) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form PO4 tetrahedra that share  a cornercorner with one Li(1)O4 tetrahedra and corners with two equivalent P(2)O4 tetrahedra. In the second P site, P(2) is bonded to one O(2), one O(4), one O(5), and one O(6) atom to form PO4 tetrahedra that share  a cornercorner with one Li(1)O4 tetrahedra and corners with two equivalent P(1)O4 tetrahedra. There are six inequivalent O sites. In the first O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Li(1), one La(1), and one P(1) atom. In the second O site, O(4) is bonded in a distorted bent 120 degrees geometry to one P(1) and one P(2) atom. In the third O site, O(5) is bonded in a 3-coordinate geometry to one Li(1), one La(1), and one P(2) atom. In the fourth O site, O(6) is bonded in a 2-coordinate geometry to one La(1) and one P(2) atom. In the fifth O site, O(1) is bonded in a distorted bent 150 degrees geometry to one La(1) and one P(1) atom. In the sixth O site, O(2) is bonded in a distorted bent 120 degrees geometry to one P(1) and one P(2) atom. is represented by the CIF file [CIF]
data_LiLa(PO3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.146
_cell_length_b   9.146
_cell_length_c   10.009
_cell_angle_alpha   56.799
_cell_angle_beta   56.799
_cell_angle_gamma   46.458
_symmetry_Int_Tables_number   1
_cell_volume   487.341
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.203  0.797  0.250  1.0
  Li  Li1  1  0.797  0.203  0.750  1.0
  La  La2  1  0.702  0.298  0.250  1.0
  La  La3  1  0.298  0.702  0.750  1.0
  P  P4  1  0.084  0.194  0.385  1.0
  P  P5  1  0.806  0.916  0.115  1.0
  P  P6  1  0.916  0.806  0.615  1.0
  P  P7  1  0.194  0.084  0.885  1.0
  P  P8  1  0.193  0.509  0.200  1.0
  P  P9  1  0.491  0.807  0.300  1.0
  P  P10  1  0.807  0.491  0.800  1.0
  P  P11  1  0.509  0.193  0.700  1.0
  O  O12  1  0.901  0.330  0.319  1.0
  O  O13  1  0.670  0.099  0.181  1.0
  O  O14  1  0.099  0.670  0.681  1.0
  O  O15  1  0.330  0.901  0.819  1.0
  O  O16  1  0.160  0.329  0.354  1.0
  O  O17  1  0.671  0.840  0.146  1.0
  O  O18  1  0.840  0.671  0.646  1.0
  O  O19  1  0.329  0.160  0.854  1.0
  O  O20  1  0.939  0.925  0.432  1.0
  O  O21  1  0.075  0.061  0.068  1.0
  O  O22  1  0.061  0.075  0.568  1.0
  O  O23  1  0.925  0.939  0.932  1.0
  O  O24  1  0.280  0.039  0.269  1.0
  O  O25  1  0.961  0.720  0.231  1.0
  O  O26  1  0.720  0.961  0.731  1.0
  O  O27  1  0.039  0.280  0.769  1.0
  O  O28  1  0.327  0.522  0.231  1.0
  O  O29  1  0.478  0.673  0.269  1.0
  O  O30  1  0.673  0.478  0.769  1.0
  O  O31  1  0.522  0.327  0.731  1.0
  O  O32  1  0.485  0.255  0.537  1.0
  O  O33  1  0.745  0.515  0.963  1.0
  O  O34  1  0.515  0.745  0.463  1.0
  O  O35  1  0.255  0.485  0.037  1.0
[/CIF]
.