The material described by C2N2S9 is Indium-like structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of two (cyanooctasulfanyl) thiocyanate molecules. There are two inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one N(1) and one S(1) atom. In the second C site, C(2) is bonded in a distorted linear geometry to one N(2) and one S(9) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one C(1) atom. In the second N site, N(2) is bonded in a single-bond geometry to one C(2) atom. There are nine inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one C(1) and one S(2) atom. In the second S site, S(2) is bonded in a water-like geometry to one S(1) and one S(3) atom. In the third S site, S(3) is bonded in a water-like geometry to one S(2) and one S(4) atom. In the fourth S site, S(4) is bonded in a water-like geometry to one S(3) and one S(5) atom. In the fifth S site, S(5) is bonded in a water-like geometry to one S(4) and one S(6) atom. In the sixth S site, S(6) is bonded in a water-like geometry to one S(5) and one S(7) atom. In the seventh S site, S(7) is bonded in a water-like geometry to one S(6) and one S(8) atom. In the eighth S site, S(8) is bonded in a water-like geometry to one S(7) and one S(9) atom. In the ninth S site, S(9) is bonded in a water-like geometry to one C(2) and one S(8) atom. is represented by the CIF card [CIF]
data_C2S9N2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.146
_cell_length_b   9.036
_cell_length_c   13.152
_cell_angle_alpha   77.117
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   712.065
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  C  C0  1  0.329  0.548  0.752  1.0
  C  C1  1  0.829  0.452  0.248  1.0
  C  C2  1  0.935  0.302  0.522  1.0
  C  C3  1  0.435  0.698  0.478  1.0
  S  S4  1  0.055  0.546  0.750  1.0
  S  S5  1  0.555  0.454  0.250  1.0
  S  S6  1  0.983  0.495  0.910  1.0
  S  S7  1  0.483  0.505  0.090  1.0
  S  S8  1  0.002  0.265  0.962  1.0
  S  S9  1  0.502  0.735  0.038  1.0
  S  S10  1  0.702  0.171  0.940  1.0
  S  S11  1  0.202  0.829  0.060  1.0
  S  S12  1  0.694  0.146  0.788  1.0
  S  S13  1  0.194  0.854  0.212  1.0
  S  S14  1  0.838  0.944  0.779  1.0
  S  S15  1  0.338  0.056  0.221  1.0
  S  S16  1  0.167  0.989  0.750  1.0
  S  S17  1  0.667  0.011  0.250  1.0
  S  S18  1  0.215  0.038  0.593  1.0
  S  S19  1  0.715  0.962  0.407  1.0
  S  S20  1  0.204  0.276  0.539  1.0
  S  S21  1  0.704  0.724  0.461  1.0
  N  N22  1  0.520  0.550  0.749  1.0
  N  N23  1  0.020  0.450  0.251  1.0
  N  N24  1  0.747  0.327  0.509  1.0
  N  N25  1  0.247  0.673  0.491  1.0
[/CIF]
.
The material described by C2N2S9 is Indium-like structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of two (cyanooctasulfanyl) thiocyanate molecules. There are two inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one N(1) and one S(1) atom. In the second C site, C(2) is bonded in a distorted linear geometry to one N(2) and one S(9) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one C(1) atom. In the second N site, N(2) is bonded in a single-bond geometry to one C(2) atom. There are nine inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one C(1) and one S(2) atom. In the second S site, S(2) is bonded in a water-like geometry to one S(1) and one S(3) atom. In the third S site, S(3) is bonded in a water-like geometry to one S(2) and one S(4) atom. In the fourth S site, S(4) is bonded in a water-like geometry to one S(3) and one S(5) atom. In the fifth S site, S(5) is bonded in a water-like geometry to one S(4) and one S(6) atom. In the sixth S site, S(6) is bonded in a water-like geometry to one S(5) and one S(7) atom. In the seventh S site, S(7) is bonded in a water-like geometry to one S(6) and one S(8) atom. In the eighth S site, S(8) is bonded in a water-like geometry to one S(7) and one S(9) atom. In the ninth S site, S(9) is bonded in a water-like geometry to one C(2) and one S(8) atom. is represented by the CIF card [CIF]
data_C2S9N2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.146
_cell_length_b   9.036
_cell_length_c   13.152
_cell_angle_alpha   77.117
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   712.065
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  C  C0  1  0.329  0.548  0.752  1.0
  C  C1  1  0.829  0.452  0.248  1.0
  C  C2  1  0.935  0.302  0.522  1.0
  C  C3  1  0.435  0.698  0.478  1.0
  S  S4  1  0.055  0.546  0.750  1.0
  S  S5  1  0.555  0.454  0.250  1.0
  S  S6  1  0.983  0.495  0.910  1.0
  S  S7  1  0.483  0.505  0.090  1.0
  S  S8  1  0.002  0.265  0.962  1.0
  S  S9  1  0.502  0.735  0.038  1.0
  S  S10  1  0.702  0.171  0.940  1.0
  S  S11  1  0.202  0.829  0.060  1.0
  S  S12  1  0.694  0.146  0.788  1.0
  S  S13  1  0.194  0.854  0.212  1.0
  S  S14  1  0.838  0.944  0.779  1.0
  S  S15  1  0.338  0.056  0.221  1.0
  S  S16  1  0.167  0.989  0.750  1.0
  S  S17  1  0.667  0.011  0.250  1.0
  S  S18  1  0.215  0.038  0.593  1.0
  S  S19  1  0.715  0.962  0.407  1.0
  S  S20  1  0.204  0.276  0.539  1.0
  S  S21  1  0.704  0.724  0.461  1.0
  N  N22  1  0.520  0.550  0.749  1.0
  N  N23  1  0.020  0.450  0.251  1.0
  N  N24  1  0.747  0.327  0.509  1.0
  N  N25  1  0.247  0.673  0.491  1.0
[/CIF]
.