The material structure described by Co3Cd(PO3)8 crystallizes in the monoclinic C2 space group. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(10), one O(11), one O(12), one O(3), one O(4), and one O(9) atom to form CoO6 octahedra that share  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra,  an edgeedge with one Co(2)O6 octahedra, and  an edgeedge with one Cd(1)O6 octahedra. In the second Co site, Co(2) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(9) atoms to form CoO6 octahedra that share corners with two equivalent P(2)O4 tetrahedra, corners with two equivalent P(3)O4 tetrahedra, corners with two equivalent P(4)O4 tetrahedra, and edges with two equivalent Co(1)O6 octahedra. Cd(1) is bonded to two equivalent O(1), two equivalent O(10), and two equivalent O(3) atoms to form CdO6 octahedra that share corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(3)O4 tetrahedra, corners with two equivalent P(4)O4 tetrahedra, and edges with two equivalent Co(1)O6 octahedra. There are four inequivalent P sites. In the first P site, P(1) is bonded to one O(11), one O(3), one O(6), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one Cd(1)O6 octahedra, corners with two equivalent Co(1)O6 octahedra,  a cornercorner with one P(3)O4 tetrahedra, and  a cornercorner with one P(4)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 19-57°. In the second P site, P(2) is bonded to one O(12), one O(4), one O(5), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Co(2)O6 octahedra, corners with two equivalent Co(1)O6 octahedra,  a cornercorner with one P(3)O4 tetrahedra, and  a cornercorner with one P(4)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 21-59°. In the third P site, P(3) is bonded to one O(1), one O(5), one O(7), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Cd(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra, and  a cornercorner with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 31-56°. In the fourth P site, P(4) is bonded to one O(10), one O(2), one O(6), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Cd(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra, and  a cornercorner with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 27-58°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Cd(1) and one P(3) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Co(2) and one P(4) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Co(1), one Cd(1), and one P(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Co(1), one Co(2), and one P(2) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one P(2) and one P(3) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one P(1) and one P(4) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one P(1) and one P(3) atom. In the eighth O site, O(8) is bonded in a distorted bent 150 degrees geometry to one P(2) and one P(4) atom. In the ninth O site, O(9) is bonded in a distorted trigonal planar geometry to one Co(1), one Co(2), and one P(3) atom. In the tenth O site, O(10) is bonded in a distorted trigonal planar geometry to one Co(1), one Cd(1), and one P(4) atom. In the eleventh O site, O(11) is bonded in a distorted bent 150 degrees geometry to one Co(1) and one P(1) atom. In the twelfth O site, O(12) is bonded in a bent 150 degrees geometry to one Co(1) and one P(2) atom. is represented by the CIF card [CIF]
data_CdCo3(PO3)8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.395
_cell_length_b   7.395
_cell_length_c   10.041
_cell_angle_alpha   67.322
_cell_angle_beta   67.322
_cell_angle_gamma   70.559
_symmetry_Int_Tables_number   1
_cell_volume   456.395
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.550  0.450  0.000  1.0
  Co  Co1  1  0.006  0.500  0.747  1.0
  Co  Co2  1  0.500  0.994  0.253  1.0
  Co  Co3  1  0.456  0.544  0.500  1.0
  P  P4  1  0.185  0.195  0.056  1.0
  P  P5  1  0.805  0.815  0.944  1.0
  P  P6  1  0.807  0.800  0.453  1.0
  P  P7  1  0.200  0.193  0.547  1.0
  P  P8  1  0.219  0.759  0.231  1.0
  P  P9  1  0.241  0.781  0.769  1.0
  P  P10  1  0.772  0.236  0.282  1.0
  P  P11  1  0.764  0.228  0.718  1.0
  O  O12  1  0.319  0.584  0.173  1.0
  O  O13  1  0.416  0.681  0.827  1.0
  O  O14  1  0.664  0.411  0.342  1.0
  O  O15  1  0.589  0.336  0.658  1.0
  O  O16  1  0.372  0.207  0.077  1.0
  O  O17  1  0.793  0.628  0.923  1.0
  O  O18  1  0.622  0.781  0.432  1.0
  O  O19  1  0.219  0.378  0.568  1.0
  O  O20  1  0.989  0.742  0.314  1.0
  O  O21  1  0.258  0.011  0.686  1.0
  O  O22  1  0.000  0.260  0.194  1.0
  O  O23  1  0.740  1.000  0.806  1.0
  O  O24  1  0.193  0.961  0.092  1.0
  O  O25  1  0.039  0.807  0.908  1.0
  O  O26  1  0.795  0.035  0.421  1.0
  O  O27  1  0.965  0.205  0.579  1.0
  O  O28  1  0.310  0.792  0.331  1.0
  O  O29  1  0.208  0.690  0.669  1.0
  O  O30  1  0.692  0.193  0.181  1.0
  O  O31  1  0.807  0.308  0.819  1.0
  O  O32  1  0.147  0.306  0.908  1.0
  O  O33  1  0.694  0.853  0.092  1.0
  O  O34  1  0.850  0.689  0.599  1.0
  O  O35  1  0.311  0.150  0.401  1.0
[/CIF]
.
The material structure described by Co3Cd(PO3)8 crystallizes in the monoclinic C2 space group. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(10), one O(11), one O(12), one O(3), one O(4), and one O(9) atom to form CoO6 octahedra that share  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra,  an edgeedge with one Co(2)O6 octahedra, and  an edgeedge with one Cd(1)O6 octahedra. In the second Co site, Co(2) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(9) atoms to form CoO6 octahedra that share corners with two equivalent P(2)O4 tetrahedra, corners with two equivalent P(3)O4 tetrahedra, corners with two equivalent P(4)O4 tetrahedra, and edges with two equivalent Co(1)O6 octahedra. Cd(1) is bonded to two equivalent O(1), two equivalent O(10), and two equivalent O(3) atoms to form CdO6 octahedra that share corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(3)O4 tetrahedra, corners with two equivalent P(4)O4 tetrahedra, and edges with two equivalent Co(1)O6 octahedra. There are four inequivalent P sites. In the first P site, P(1) is bonded to one O(11), one O(3), one O(6), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one Cd(1)O6 octahedra, corners with two equivalent Co(1)O6 octahedra,  a cornercorner with one P(3)O4 tetrahedra, and  a cornercorner with one P(4)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 19-57°. In the second P site, P(2) is bonded to one O(12), one O(4), one O(5), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Co(2)O6 octahedra, corners with two equivalent Co(1)O6 octahedra,  a cornercorner with one P(3)O4 tetrahedra, and  a cornercorner with one P(4)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 21-59°. In the third P site, P(3) is bonded to one O(1), one O(5), one O(7), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Cd(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra, and  a cornercorner with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 31-56°. In the fourth P site, P(4) is bonded to one O(10), one O(2), one O(6), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Cd(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra, and  a cornercorner with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 27-58°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Cd(1) and one P(3) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Co(2) and one P(4) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Co(1), one Cd(1), and one P(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Co(1), one Co(2), and one P(2) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one P(2) and one P(3) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one P(1) and one P(4) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one P(1) and one P(3) atom. In the eighth O site, O(8) is bonded in a distorted bent 150 degrees geometry to one P(2) and one P(4) atom. In the ninth O site, O(9) is bonded in a distorted trigonal planar geometry to one Co(1), one Co(2), and one P(3) atom. In the tenth O site, O(10) is bonded in a distorted trigonal planar geometry to one Co(1), one Cd(1), and one P(4) atom. In the eleventh O site, O(11) is bonded in a distorted bent 150 degrees geometry to one Co(1) and one P(1) atom. In the twelfth O site, O(12) is bonded in a bent 150 degrees geometry to one Co(1) and one P(2) atom. is represented by the CIF card [CIF]
data_CdCo3(PO3)8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.395
_cell_length_b   7.395
_cell_length_c   10.041
_cell_angle_alpha   67.322
_cell_angle_beta   67.322
_cell_angle_gamma   70.559
_symmetry_Int_Tables_number   1
_cell_volume   456.395
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.550  0.450  0.000  1.0
  Co  Co1  1  0.006  0.500  0.747  1.0
  Co  Co2  1  0.500  0.994  0.253  1.0
  Co  Co3  1  0.456  0.544  0.500  1.0
  P  P4  1  0.185  0.195  0.056  1.0
  P  P5  1  0.805  0.815  0.944  1.0
  P  P6  1  0.807  0.800  0.453  1.0
  P  P7  1  0.200  0.193  0.547  1.0
  P  P8  1  0.219  0.759  0.231  1.0
  P  P9  1  0.241  0.781  0.769  1.0
  P  P10  1  0.772  0.236  0.282  1.0
  P  P11  1  0.764  0.228  0.718  1.0
  O  O12  1  0.319  0.584  0.173  1.0
  O  O13  1  0.416  0.681  0.827  1.0
  O  O14  1  0.664  0.411  0.342  1.0
  O  O15  1  0.589  0.336  0.658  1.0
  O  O16  1  0.372  0.207  0.077  1.0
  O  O17  1  0.793  0.628  0.923  1.0
  O  O18  1  0.622  0.781  0.432  1.0
  O  O19  1  0.219  0.378  0.568  1.0
  O  O20  1  0.989  0.742  0.314  1.0
  O  O21  1  0.258  0.011  0.686  1.0
  O  O22  1  0.000  0.260  0.194  1.0
  O  O23  1  0.740  1.000  0.806  1.0
  O  O24  1  0.193  0.961  0.092  1.0
  O  O25  1  0.039  0.807  0.908  1.0
  O  O26  1  0.795  0.035  0.421  1.0
  O  O27  1  0.965  0.205  0.579  1.0
  O  O28  1  0.310  0.792  0.331  1.0
  O  O29  1  0.208  0.690  0.669  1.0
  O  O30  1  0.692  0.193  0.181  1.0
  O  O31  1  0.807  0.308  0.819  1.0
  O  O32  1  0.147  0.306  0.908  1.0
  O  O33  1  0.694  0.853  0.092  1.0
  O  O34  1  0.850  0.689  0.599  1.0
  O  O35  1  0.311  0.150  0.401  1.0
[/CIF]
.