The compound described by PuRh3C is (Cubic) Perovskite structured and crystallizes in the tetragonal P4/mmm space group. Pu(1) is bonded to four equivalent Rh(2) and eight equivalent Rh(1) atoms to form PuRh12 cuboctahedra that share corners with twelve equivalent Pu(1)Rh12 cuboctahedra, faces with six equivalent Pu(1)Rh12 cuboctahedra, and faces with eight equivalent C(1)Rh6 octahedra. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded to four equivalent Pu(1) and two equivalent C(1) atoms to form a mixture of distorted edge, corner, and face-sharing RhPu4C2 octahedra. The corner-sharing octahedral tilt angles range from 0-60°. In the second Rh site, Rh(2) is bonded to four equivalent Pu(1) and two equivalent C(1) atoms to form a mixture of distorted edge, corner, and face-sharing RhPu4C2 octahedra. The corner-sharing octahedral tilt angles range from 0-60°. C(1) is bonded to two equivalent Rh(2) and four equivalent Rh(1) atoms to form CRh6 octahedra that share corners with six equivalent C(1)Rh6 octahedra and faces with eight equivalent Pu(1)Rh12 cuboctahedra. The corner-sharing octahedra are not tilted. is represented by the Crystallographic Information File (CIF) [CIF]
data_PuRh3C
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.184
_cell_length_b   4.208
_cell_length_c   4.184
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   73.671
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pu  Pu0  1  0.000  0.000  0.000  1.0
  Rh  Rh1  1  0.000  0.500  0.500  1.0
  Rh  Rh2  1  0.500  0.500  0.000  1.0
  Rh  Rh3  1  0.500  0.000  0.500  1.0
  C  C4  1  0.500  0.500  0.500  1.0
[/CIF]
.
The compound described by PuRh3C is (Cubic) Perovskite structured and crystallizes in the tetragonal P4/mmm space group. Pu(1) is bonded to four equivalent Rh(2) and eight equivalent Rh(1) atoms to form PuRh12 cuboctahedra that share corners with twelve equivalent Pu(1)Rh12 cuboctahedra, faces with six equivalent Pu(1)Rh12 cuboctahedra, and faces with eight equivalent C(1)Rh6 octahedra. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded to four equivalent Pu(1) and two equivalent C(1) atoms to form a mixture of distorted edge, corner, and face-sharing RhPu4C2 octahedra. The corner-sharing octahedral tilt angles range from 0-60°. In the second Rh site, Rh(2) is bonded to four equivalent Pu(1) and two equivalent C(1) atoms to form a mixture of distorted edge, corner, and face-sharing RhPu4C2 octahedra. The corner-sharing octahedral tilt angles range from 0-60°. C(1) is bonded to two equivalent Rh(2) and four equivalent Rh(1) atoms to form CRh6 octahedra that share corners with six equivalent C(1)Rh6 octahedra and faces with eight equivalent Pu(1)Rh12 cuboctahedra. The corner-sharing octahedra are not tilted. is represented by the Crystallographic Information File (CIF) [CIF]
data_PuRh3C
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.184
_cell_length_b   4.208
_cell_length_c   4.184
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   73.671
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pu  Pu0  1  0.000  0.000  0.000  1.0
  Rh  Rh1  1  0.000  0.500  0.500  1.0
  Rh  Rh2  1  0.500  0.500  0.000  1.0
  Rh  Rh3  1  0.500  0.000  0.500  1.0
  C  C4  1  0.500  0.500  0.500  1.0
[/CIF]
.