The crystal structure described by P4(S2O)3 is Indium-like structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two P4(S2O)3 clusters. There are three inequivalent P sites. In the first P site, P(1) is bonded to one S(1), one S(3), one O(1), and one O(2) atom to form distorted corner-sharing PS2O2 tetrahedra. In the second P site, P(2) is bonded in a trigonal non-coplanar geometry to one S(4) and two equivalent S(3) atoms. In the third P site, P(3) is bonded to one S(2), one S(4), and two equivalent O(1) atoms to form distorted corner-sharing PS2O2 tetrahedra. There are four inequivalent S sites. In the first S site, S(1) is bonded in a single-bond geometry to one P(1) atom. In the second S site, S(2) is bonded in a single-bond geometry to one P(3) atom. In the third S site, S(3) is bonded in a water-like geometry to one P(1) and one P(2) atom. In the fourth S site, S(4) is bonded in a water-like geometry to one P(2) and one P(3) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one P(1) and one P(3) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to two equivalent P(1) atoms. is represented by the CIF file [CIF]
data_P4(S2O)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.459
_cell_length_b   6.680
_cell_length_c   7.319
_cell_angle_alpha   75.568
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   589.918
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.868  0.180  0.181  1.0
  P  P1  1  0.250  0.205  0.960  1.0
  P  P2  1  0.368  0.820  0.819  1.0
  P  P3  1  0.132  0.820  0.819  1.0
  P  P4  1  0.632  0.180  0.181  1.0
  P  P5  1  0.250  0.703  0.178  1.0
  P  P6  1  0.750  0.795  0.040  1.0
  P  P7  1  0.750  0.297  0.822  1.0
  S  S8  1  0.980  0.289  0.300  1.0
  S  S9  1  0.480  0.711  0.700  1.0
  S  S10  1  0.020  0.711  0.700  1.0
  S  S11  1  0.520  0.289  0.300  1.0
  S  S12  1  0.750  0.518  0.605  1.0
  S  S13  1  0.250  0.482  0.395  1.0
  S  S14  1  0.886  0.871  0.185  1.0
  S  S15  1  0.614  0.871  0.185  1.0
  S  S16  1  0.114  0.129  0.815  1.0
  S  S17  1  0.250  0.993  0.231  1.0
  S  S18  1  0.750  0.007  0.769  1.0
  S  S19  1  0.386  0.129  0.815  1.0
  O  O20  1  0.650  0.298  0.963  1.0
  O  O21  1  0.250  0.802  0.733  1.0
  O  O22  1  0.850  0.298  0.963  1.0
  O  O23  1  0.350  0.702  0.037  1.0
  O  O24  1  0.150  0.702  0.037  1.0
  O  O25  1  0.750  0.198  0.267  1.0
[/CIF]
.
The crystal structure described by P4(S2O)3 is Indium-like structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two P4(S2O)3 clusters. There are three inequivalent P sites. In the first P site, P(1) is bonded to one S(1), one S(3), one O(1), and one O(2) atom to form distorted corner-sharing PS2O2 tetrahedra. In the second P site, P(2) is bonded in a trigonal non-coplanar geometry to one S(4) and two equivalent S(3) atoms. In the third P site, P(3) is bonded to one S(2), one S(4), and two equivalent O(1) atoms to form distorted corner-sharing PS2O2 tetrahedra. There are four inequivalent S sites. In the first S site, S(1) is bonded in a single-bond geometry to one P(1) atom. In the second S site, S(2) is bonded in a single-bond geometry to one P(3) atom. In the third S site, S(3) is bonded in a water-like geometry to one P(1) and one P(2) atom. In the fourth S site, S(4) is bonded in a water-like geometry to one P(2) and one P(3) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one P(1) and one P(3) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to two equivalent P(1) atoms. is represented by the CIF file [CIF]
data_P4(S2O)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.459
_cell_length_b   6.680
_cell_length_c   7.319
_cell_angle_alpha   75.568
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   589.918
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.868  0.180  0.181  1.0
  P  P1  1  0.250  0.205  0.960  1.0
  P  P2  1  0.368  0.820  0.819  1.0
  P  P3  1  0.132  0.820  0.819  1.0
  P  P4  1  0.632  0.180  0.181  1.0
  P  P5  1  0.250  0.703  0.178  1.0
  P  P6  1  0.750  0.795  0.040  1.0
  P  P7  1  0.750  0.297  0.822  1.0
  S  S8  1  0.980  0.289  0.300  1.0
  S  S9  1  0.480  0.711  0.700  1.0
  S  S10  1  0.020  0.711  0.700  1.0
  S  S11  1  0.520  0.289  0.300  1.0
  S  S12  1  0.750  0.518  0.605  1.0
  S  S13  1  0.250  0.482  0.395  1.0
  S  S14  1  0.886  0.871  0.185  1.0
  S  S15  1  0.614  0.871  0.185  1.0
  S  S16  1  0.114  0.129  0.815  1.0
  S  S17  1  0.250  0.993  0.231  1.0
  S  S18  1  0.750  0.007  0.769  1.0
  S  S19  1  0.386  0.129  0.815  1.0
  O  O20  1  0.650  0.298  0.963  1.0
  O  O21  1  0.250  0.802  0.733  1.0
  O  O22  1  0.850  0.298  0.963  1.0
  O  O23  1  0.350  0.702  0.037  1.0
  O  O24  1  0.150  0.702  0.037  1.0
  O  O25  1  0.750  0.198  0.267  1.0
[/CIF]
.