The crystal structure described by Os(CO)6(SbF6)2 is Fluorite structured and crystallizes in the tetragonal P4/mnc space group. The structure is zero-dimensional and consists of two Os(CO)6 clusters and four SbF6 clusters. In each Os(CO)6 cluster, Os(1) is bonded in an octahedral geometry to two equivalent C(2) and four equivalent C(1) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one Os(1) and one O(1) atom. In the second C site, C(2) is bonded in a distorted linear geometry to one Os(1) and one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(2) atom. In each SbF6 cluster, Sb(1) is bonded in an octahedral geometry to two equivalent F(1) and four equivalent F(2) atoms. There are two inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. is represented by the CIF file [CIF]
data_Sb2OsC6(OF2)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.446
_cell_length_b   8.446
_cell_length_c   12.666
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   903.427
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.000  0.500  0.750  1.0
  Sb  Sb1  1  0.500  0.000  0.750  1.0
  Sb  Sb2  1  0.500  0.000  0.250  1.0
  Sb  Sb3  1  0.000  0.500  0.250  1.0
  Os  Os4  1  0.500  0.500  0.500  1.0
  Os  Os5  1  0.000  0.000  0.000  1.0
  C  C6  1  0.629  0.701  0.500  1.0
  C  C7  1  0.371  0.299  0.500  1.0
  C  C8  1  0.000  0.000  0.159  1.0
  C  C9  1  0.500  0.500  0.341  1.0
  C  C10  1  0.000  0.000  0.841  1.0
  C  C11  1  0.500  0.500  0.659  1.0
  C  C12  1  0.201  0.129  0.000  1.0
  C  C13  1  0.871  0.201  0.000  1.0
  C  C14  1  0.129  0.799  0.000  1.0
  C  C15  1  0.701  0.371  0.500  1.0
  C  C16  1  0.299  0.629  0.500  1.0
  C  C17  1  0.799  0.871  0.000  1.0
  O  O18  1  0.300  0.185  0.500  1.0
  O  O19  1  0.700  0.815  0.500  1.0
  O  O20  1  0.000  0.000  0.249  1.0
  O  O21  1  0.500  0.500  0.251  1.0
  O  O22  1  0.000  0.000  0.751  1.0
  O  O23  1  0.500  0.500  0.749  1.0
  O  O24  1  0.315  0.200  0.000  1.0
  O  O25  1  0.800  0.315  0.000  1.0
  O  O26  1  0.200  0.685  0.000  1.0
  O  O27  1  0.815  0.300  0.500  1.0
  O  O28  1  0.185  0.700  0.500  1.0
  O  O29  1  0.685  0.800  0.000  1.0
  F  F30  1  0.340  0.160  0.750  1.0
  F  F31  1  0.840  0.340  0.750  1.0
  F  F32  1  0.660  0.840  0.750  1.0
  F  F33  1  0.381  0.893  0.858  1.0
  F  F34  1  0.660  0.840  0.250  1.0
  F  F35  1  0.160  0.660  0.250  1.0
  F  F36  1  0.619  0.107  0.142  1.0
  F  F37  1  0.893  0.619  0.142  1.0
  F  F38  1  0.107  0.381  0.142  1.0
  F  F39  1  0.119  0.393  0.358  1.0
  F  F40  1  0.881  0.607  0.358  1.0
  F  F41  1  0.381  0.893  0.142  1.0
  F  F42  1  0.607  0.119  0.358  1.0
  F  F43  1  0.393  0.881  0.358  1.0
  F  F44  1  0.840  0.340  0.250  1.0
  F  F45  1  0.107  0.381  0.858  1.0
  F  F46  1  0.893  0.619  0.858  1.0
  F  F47  1  0.881  0.607  0.642  1.0
  F  F48  1  0.119  0.393  0.642  1.0
  F  F49  1  0.619  0.107  0.858  1.0
  F  F50  1  0.393  0.881  0.642  1.0
  F  F51  1  0.607  0.119  0.642  1.0
  F  F52  1  0.340  0.160  0.250  1.0
  F  F53  1  0.160  0.660  0.750  1.0
[/CIF]
.
The crystal structure described by Os(CO)6(SbF6)2 is Fluorite structured and crystallizes in the tetragonal P4/mnc space group. The structure is zero-dimensional and consists of two Os(CO)6 clusters and four SbF6 clusters. In each Os(CO)6 cluster, Os(1) is bonded in an octahedral geometry to two equivalent C(2) and four equivalent C(1) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one Os(1) and one O(1) atom. In the second C site, C(2) is bonded in a distorted linear geometry to one Os(1) and one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(2) atom. In each SbF6 cluster, Sb(1) is bonded in an octahedral geometry to two equivalent F(1) and four equivalent F(2) atoms. There are two inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. is represented by the CIF file [CIF]
data_Sb2OsC6(OF2)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.446
_cell_length_b   8.446
_cell_length_c   12.666
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   903.427
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.000  0.500  0.750  1.0
  Sb  Sb1  1  0.500  0.000  0.750  1.0
  Sb  Sb2  1  0.500  0.000  0.250  1.0
  Sb  Sb3  1  0.000  0.500  0.250  1.0
  Os  Os4  1  0.500  0.500  0.500  1.0
  Os  Os5  1  0.000  0.000  0.000  1.0
  C  C6  1  0.629  0.701  0.500  1.0
  C  C7  1  0.371  0.299  0.500  1.0
  C  C8  1  0.000  0.000  0.159  1.0
  C  C9  1  0.500  0.500  0.341  1.0
  C  C10  1  0.000  0.000  0.841  1.0
  C  C11  1  0.500  0.500  0.659  1.0
  C  C12  1  0.201  0.129  0.000  1.0
  C  C13  1  0.871  0.201  0.000  1.0
  C  C14  1  0.129  0.799  0.000  1.0
  C  C15  1  0.701  0.371  0.500  1.0
  C  C16  1  0.299  0.629  0.500  1.0
  C  C17  1  0.799  0.871  0.000  1.0
  O  O18  1  0.300  0.185  0.500  1.0
  O  O19  1  0.700  0.815  0.500  1.0
  O  O20  1  0.000  0.000  0.249  1.0
  O  O21  1  0.500  0.500  0.251  1.0
  O  O22  1  0.000  0.000  0.751  1.0
  O  O23  1  0.500  0.500  0.749  1.0
  O  O24  1  0.315  0.200  0.000  1.0
  O  O25  1  0.800  0.315  0.000  1.0
  O  O26  1  0.200  0.685  0.000  1.0
  O  O27  1  0.815  0.300  0.500  1.0
  O  O28  1  0.185  0.700  0.500  1.0
  O  O29  1  0.685  0.800  0.000  1.0
  F  F30  1  0.340  0.160  0.750  1.0
  F  F31  1  0.840  0.340  0.750  1.0
  F  F32  1  0.660  0.840  0.750  1.0
  F  F33  1  0.381  0.893  0.858  1.0
  F  F34  1  0.660  0.840  0.250  1.0
  F  F35  1  0.160  0.660  0.250  1.0
  F  F36  1  0.619  0.107  0.142  1.0
  F  F37  1  0.893  0.619  0.142  1.0
  F  F38  1  0.107  0.381  0.142  1.0
  F  F39  1  0.119  0.393  0.358  1.0
  F  F40  1  0.881  0.607  0.358  1.0
  F  F41  1  0.381  0.893  0.142  1.0
  F  F42  1  0.607  0.119  0.358  1.0
  F  F43  1  0.393  0.881  0.358  1.0
  F  F44  1  0.840  0.340  0.250  1.0
  F  F45  1  0.107  0.381  0.858  1.0
  F  F46  1  0.893  0.619  0.858  1.0
  F  F47  1  0.881  0.607  0.642  1.0
  F  F48  1  0.119  0.393  0.642  1.0
  F  F49  1  0.619  0.107  0.858  1.0
  F  F50  1  0.393  0.881  0.642  1.0
  F  F51  1  0.607  0.119  0.642  1.0
  F  F52  1  0.340  0.160  0.250  1.0
  F  F53  1  0.160  0.660  0.750  1.0
[/CIF]
.