The material structure described by KPtN2O5 crystallizes in the monoclinic P2_1/c space group. K(1) is bonded in a 9-coordinate geometry to one O(2), two equivalent O(1), two equivalent O(3), two equivalent O(4), and two equivalent O(5) atoms. Pt(1) is bonded in a square co-planar geometry to one N(1), one N(2), and two equivalent O(2) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Pt(1), one O(3), and one O(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Pt(1), one O(1), and one O(4) atom. There are five inequivalent O sites. In the first O site, O(5) is bonded in a distorted single-bond geometry to two equivalent K(1) and one N(1) atom. In the second O site, O(1) is bonded in a distorted single-bond geometry to two equivalent K(1) and one N(2) atom. In the third O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one K(1) and two equivalent Pt(1) atoms. In the fourth O site, O(3) is bonded in a distorted single-bond geometry to two equivalent K(1) and one N(1) atom. In the fifth O site, O(4) is bonded in a distorted single-bond geometry to two equivalent K(1) and one N(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_KPtN2O5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   15.759
_cell_length_b   5.348
_cell_length_c   8.145
_cell_angle_alpha   61.296
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   602.039
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.657  0.884  0.064  1.0
  K  K1  1  0.343  0.116  0.936  1.0
  K  K2  1  0.157  0.116  0.436  1.0
  K  K3  1  0.843  0.884  0.564  1.0
  Pt  Pt4  1  0.970  0.617  0.127  1.0
  Pt  Pt5  1  0.030  0.383  0.873  1.0
  Pt  Pt6  1  0.470  0.383  0.373  1.0
  Pt  Pt7  1  0.530  0.617  0.627  1.0
  N  N8  1  0.531  0.255  0.205  1.0
  N  N9  1  0.469  0.745  0.795  1.0
  N  N10  1  0.031  0.745  0.295  1.0
  N  N11  1  0.969  0.255  0.705  1.0
  N  N12  1  0.853  0.675  0.204  1.0
  N  N13  1  0.147  0.325  0.796  1.0
  N  N14  1  0.353  0.325  0.296  1.0
  N  N15  1  0.647  0.675  0.704  1.0
  O  O16  1  0.802  0.471  0.266  1.0
  O  O17  1  0.198  0.529  0.734  1.0
  O  O18  1  0.302  0.529  0.234  1.0
  O  O19  1  0.698  0.471  0.766  1.0
  O  O20  1  0.575  0.511  0.440  1.0
  O  O21  1  0.425  0.489  0.560  1.0
  O  O22  1  0.075  0.489  0.060  1.0
  O  O23  1  0.925  0.511  0.940  1.0
  O  O24  1  0.994  0.865  0.373  1.0
  O  O25  1  0.006  0.135  0.627  1.0
  O  O26  1  0.494  0.135  0.127  1.0
  O  O27  1  0.506  0.865  0.873  1.0
  O  O28  1  0.830  0.916  0.178  1.0
  O  O29  1  0.170  0.084  0.822  1.0
  O  O30  1  0.330  0.084  0.322  1.0
  O  O31  1  0.670  0.916  0.678  1.0
  O  O32  1  0.610  0.289  0.189  1.0
  O  O33  1  0.390  0.711  0.811  1.0
  O  O34  1  0.110  0.711  0.311  1.0
  O  O35  1  0.890  0.289  0.689  1.0
[/CIF]
.
The material structure described by KPtN2O5 crystallizes in the monoclinic P2_1/c space group. K(1) is bonded in a 9-coordinate geometry to one O(2), two equivalent O(1), two equivalent O(3), two equivalent O(4), and two equivalent O(5) atoms. Pt(1) is bonded in a square co-planar geometry to one N(1), one N(2), and two equivalent O(2) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Pt(1), one O(3), and one O(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Pt(1), one O(1), and one O(4) atom. There are five inequivalent O sites. In the first O site, O(5) is bonded in a distorted single-bond geometry to two equivalent K(1) and one N(1) atom. In the second O site, O(1) is bonded in a distorted single-bond geometry to two equivalent K(1) and one N(2) atom. In the third O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one K(1) and two equivalent Pt(1) atoms. In the fourth O site, O(3) is bonded in a distorted single-bond geometry to two equivalent K(1) and one N(1) atom. In the fifth O site, O(4) is bonded in a distorted single-bond geometry to two equivalent K(1) and one N(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_KPtN2O5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   15.759
_cell_length_b   5.348
_cell_length_c   8.145
_cell_angle_alpha   61.296
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   602.039
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.657  0.884  0.064  1.0
  K  K1  1  0.343  0.116  0.936  1.0
  K  K2  1  0.157  0.116  0.436  1.0
  K  K3  1  0.843  0.884  0.564  1.0
  Pt  Pt4  1  0.970  0.617  0.127  1.0
  Pt  Pt5  1  0.030  0.383  0.873  1.0
  Pt  Pt6  1  0.470  0.383  0.373  1.0
  Pt  Pt7  1  0.530  0.617  0.627  1.0
  N  N8  1  0.531  0.255  0.205  1.0
  N  N9  1  0.469  0.745  0.795  1.0
  N  N10  1  0.031  0.745  0.295  1.0
  N  N11  1  0.969  0.255  0.705  1.0
  N  N12  1  0.853  0.675  0.204  1.0
  N  N13  1  0.147  0.325  0.796  1.0
  N  N14  1  0.353  0.325  0.296  1.0
  N  N15  1  0.647  0.675  0.704  1.0
  O  O16  1  0.802  0.471  0.266  1.0
  O  O17  1  0.198  0.529  0.734  1.0
  O  O18  1  0.302  0.529  0.234  1.0
  O  O19  1  0.698  0.471  0.766  1.0
  O  O20  1  0.575  0.511  0.440  1.0
  O  O21  1  0.425  0.489  0.560  1.0
  O  O22  1  0.075  0.489  0.060  1.0
  O  O23  1  0.925  0.511  0.940  1.0
  O  O24  1  0.994  0.865  0.373  1.0
  O  O25  1  0.006  0.135  0.627  1.0
  O  O26  1  0.494  0.135  0.127  1.0
  O  O27  1  0.506  0.865  0.873  1.0
  O  O28  1  0.830  0.916  0.178  1.0
  O  O29  1  0.170  0.084  0.822  1.0
  O  O30  1  0.330  0.084  0.322  1.0
  O  O31  1  0.670  0.916  0.678  1.0
  O  O32  1  0.610  0.289  0.189  1.0
  O  O33  1  0.390  0.711  0.811  1.0
  O  O34  1  0.110  0.711  0.311  1.0
  O  O35  1  0.890  0.289  0.689  1.0
[/CIF]
.