The compound described by WSCl4 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two WSCl4 clusters. W(1) is bonded in a distorted trigonal bipyramidal geometry to one S(1), one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. S(1) is bonded in a single-bond geometry to one W(1) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one W(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one W(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one W(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one W(1) atom. is represented by the CIF card [CIF]
data_WSCl4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.692
_cell_length_b   7.578
_cell_length_c   7.685
_cell_angle_alpha   77.325
_cell_angle_beta   82.866
_cell_angle_gamma   78.030
_symmetry_Int_Tables_number   1
_cell_volume   370.656
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  W  W0  1  0.852  0.753  0.808  1.0
  W  W1  1  0.148  0.247  0.192  1.0
  S  S2  1  0.641  0.000  0.774  1.0
  S  S3  1  0.359  1.000  0.226  1.0
  Cl  Cl4  1  0.146  0.840  0.856  1.0
  Cl  Cl5  1  0.995  0.736  0.525  1.0
  Cl  Cl6  1  0.816  0.648  0.116  1.0
  Cl  Cl7  1  0.662  0.543  0.784  1.0
  Cl  Cl8  1  0.338  0.457  0.216  1.0
  Cl  Cl9  1  0.184  0.352  0.884  1.0
  Cl  Cl10  1  0.005  0.264  0.475  1.0
  Cl  Cl11  1  0.854  0.160  0.144  1.0
[/CIF]
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The compound described by WSCl4 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two WSCl4 clusters. W(1) is bonded in a distorted trigonal bipyramidal geometry to one S(1), one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. S(1) is bonded in a single-bond geometry to one W(1) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one W(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one W(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one W(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one W(1) atom. is represented by the CIF card [CIF]
data_WSCl4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.692
_cell_length_b   7.578
_cell_length_c   7.685
_cell_angle_alpha   77.325
_cell_angle_beta   82.866
_cell_angle_gamma   78.030
_symmetry_Int_Tables_number   1
_cell_volume   370.656
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  W  W0  1  0.852  0.753  0.808  1.0
  W  W1  1  0.148  0.247  0.192  1.0
  S  S2  1  0.641  0.000  0.774  1.0
  S  S3  1  0.359  1.000  0.226  1.0
  Cl  Cl4  1  0.146  0.840  0.856  1.0
  Cl  Cl5  1  0.995  0.736  0.525  1.0
  Cl  Cl6  1  0.816  0.648  0.116  1.0
  Cl  Cl7  1  0.662  0.543  0.784  1.0
  Cl  Cl8  1  0.338  0.457  0.216  1.0
  Cl  Cl9  1  0.184  0.352  0.884  1.0
  Cl  Cl10  1  0.005  0.264  0.475  1.0
  Cl  Cl11  1  0.854  0.160  0.144  1.0
[/CIF]
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