The crystal structure described by LiSbWO6 crystallizes in the orthorhombic Imma space group. Li(1) is bonded in a hexagonal planar geometry to two equivalent O(2) and four equivalent O(1) atoms. W(1) is bonded to two equivalent O(3) and four equivalent O(1) atoms to form WO6 octahedra that share corners with two equivalent W(1)O6 octahedra and corners with four equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 34-43°. Sb(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form SbO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra and corners with four equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 43-52°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Li(1), one W(1), and one Sb(1) atom. In the second O site, O(2) is bonded to two equivalent Li(1) and two equivalent Sb(1) atoms to form distorted corner-sharing OLi2Sb2 tetrahedra. In the third O site, O(3) is bonded in a bent 150 degrees geometry to two equivalent W(1) atoms. is represented by the CIF file [CIF]
data_LiSbWO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.317
_cell_length_b   7.317
_cell_length_c   7.317
_cell_angle_alpha   120.975
_cell_angle_beta   119.011
_cell_angle_gamma   90.021
_symmetry_Int_Tables_number   1
_cell_volume   276.905
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.500  0.500  0.000  1.0
  Li  Li1  1  0.000  0.500  0.500  1.0
  Sb  Sb2  1  0.000  0.000  0.500  1.0
  Sb  Sb3  1  0.000  0.500  0.000  1.0
  W  W4  1  0.500  0.000  0.500  1.0
  W  W5  1  0.000  0.000  0.000  1.0
  O  O6  1  0.321  0.072  0.638  1.0
  O  O7  1  0.916  0.666  0.250  1.0
  O  O8  1  0.084  0.334  0.750  1.0
  O  O9  1  0.679  0.928  0.362  1.0
  O  O10  1  0.679  0.316  0.750  1.0
  O  O11  1  0.066  0.928  0.750  1.0
  O  O12  1  0.934  0.072  0.250  1.0
  O  O13  1  0.321  0.684  0.250  1.0
  O  O14  1  0.695  0.945  0.750  1.0
  O  O15  1  0.066  0.316  0.138  1.0
  O  O16  1  0.934  0.684  0.862  1.0
  O  O17  1  0.305  0.055  0.250  1.0
[/CIF]
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The crystal structure described by LiSbWO6 crystallizes in the orthorhombic Imma space group. Li(1) is bonded in a hexagonal planar geometry to two equivalent O(2) and four equivalent O(1) atoms. W(1) is bonded to two equivalent O(3) and four equivalent O(1) atoms to form WO6 octahedra that share corners with two equivalent W(1)O6 octahedra and corners with four equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 34-43°. Sb(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form SbO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra and corners with four equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 43-52°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Li(1), one W(1), and one Sb(1) atom. In the second O site, O(2) is bonded to two equivalent Li(1) and two equivalent Sb(1) atoms to form distorted corner-sharing OLi2Sb2 tetrahedra. In the third O site, O(3) is bonded in a bent 150 degrees geometry to two equivalent W(1) atoms. is represented by the CIF file [CIF]
data_LiSbWO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.317
_cell_length_b   7.317
_cell_length_c   7.317
_cell_angle_alpha   120.975
_cell_angle_beta   119.011
_cell_angle_gamma   90.021
_symmetry_Int_Tables_number   1
_cell_volume   276.905
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.500  0.500  0.000  1.0
  Li  Li1  1  0.000  0.500  0.500  1.0
  Sb  Sb2  1  0.000  0.000  0.500  1.0
  Sb  Sb3  1  0.000  0.500  0.000  1.0
  W  W4  1  0.500  0.000  0.500  1.0
  W  W5  1  0.000  0.000  0.000  1.0
  O  O6  1  0.321  0.072  0.638  1.0
  O  O7  1  0.916  0.666  0.250  1.0
  O  O8  1  0.084  0.334  0.750  1.0
  O  O9  1  0.679  0.928  0.362  1.0
  O  O10  1  0.679  0.316  0.750  1.0
  O  O11  1  0.066  0.928  0.750  1.0
  O  O12  1  0.934  0.072  0.250  1.0
  O  O13  1  0.321  0.684  0.250  1.0
  O  O14  1  0.695  0.945  0.750  1.0
  O  O15  1  0.066  0.316  0.138  1.0
  O  O16  1  0.934  0.684  0.862  1.0
  O  O17  1  0.305  0.055  0.250  1.0
[/CIF]
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