The crystal structure described by NaHF2 crystallizes in the monoclinic C2 space group. Na(1) is bonded in a 6-coordinate geometry to six equivalent F(1) atoms. H(1) is bonded in a linear geometry to two equivalent F(1) atoms. F(1) is bonded in a distorted single-bond geometry to three equivalent Na(1) and one H(1) atom. is represented by the CIF file [CIF]
data_NaHF2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.822
_cell_length_b   3.822
_cell_length_c   3.244
_cell_angle_alpha   83.941
_cell_angle_beta   83.941
_cell_angle_gamma   96.948
_symmetry_Int_Tables_number   1
_cell_volume   46.452
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.737  0.263  0.500  1.0
  H  H1  1  0.098  0.902  0.000  1.0
  F  F2  1  0.283  0.123  0.109  1.0
  F  F3  1  0.877  0.717  0.891  1.0
[/CIF]
.
The crystal structure described by NaHF2 crystallizes in the monoclinic C2 space group. Na(1) is bonded in a 6-coordinate geometry to six equivalent F(1) atoms. H(1) is bonded in a linear geometry to two equivalent F(1) atoms. F(1) is bonded in a distorted single-bond geometry to three equivalent Na(1) and one H(1) atom. is represented by the CIF file [CIF]
data_NaHF2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.822
_cell_length_b   3.822
_cell_length_c   3.244
_cell_angle_alpha   83.941
_cell_angle_beta   83.941
_cell_angle_gamma   96.948
_symmetry_Int_Tables_number   1
_cell_volume   46.452
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.737  0.263  0.500  1.0
  H  H1  1  0.098  0.902  0.000  1.0
  F  F2  1  0.283  0.123  0.109  1.0
  F  F3  1  0.877  0.717  0.891  1.0
[/CIF]
.