The compound described by VMnN2 is Enargite-like structured and crystallizes in the orthorhombic Pna2_1 space group. V(1) is bonded to two equivalent N(1) and two equivalent N(2) atoms to form VN4 tetrahedra that share corners with four equivalent V(1)N4 tetrahedra and corners with eight equivalent Mn(1)N4 tetrahedra. Mn(1) is bonded to two equivalent N(1) and two equivalent N(2) atoms to form MnN4 tetrahedra that share corners with four equivalent Mn(1)N4 tetrahedra and corners with eight equivalent V(1)N4 tetrahedra. There are two inequivalent N sites. In the first N site, N(1) is bonded to two equivalent V(1) and two equivalent Mn(1) atoms to form corner-sharing NMn2V2 tetrahedra. In the second N site, N(2) is bonded to two equivalent V(1) and two equivalent Mn(1) atoms to form corner-sharing NMn2V2 tetrahedra. is represented by the CIF card [CIF]
data_MnVN2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.264
_cell_length_b   6.046
_cell_length_c   5.359
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   170.557
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.591  0.872  0.003  1.0
  Mn  Mn1  1  0.409  0.128  0.503  1.0
  Mn  Mn2  1  0.909  0.372  0.503  1.0
  Mn  Mn3  1  0.091  0.628  0.003  1.0
  V  V4  1  0.582  0.373  0.005  1.0
  V  V5  1  0.418  0.627  0.505  1.0
  V  V6  1  0.918  0.873  0.505  1.0
  V  V7  1  0.082  0.127  0.005  1.0
  N  N8  1  0.585  0.876  0.360  1.0
  N  N9  1  0.415  0.124  0.860  1.0
  N  N10  1  0.915  0.376  0.860  1.0
  N  N11  1  0.085  0.624  0.360  1.0
  N  N12  1  0.579  0.378  0.354  1.0
  N  N13  1  0.421  0.622  0.854  1.0
  N  N14  1  0.921  0.878  0.854  1.0
  N  N15  1  0.079  0.122  0.354  1.0
[/CIF]
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The compound described by VMnN2 is Enargite-like structured and crystallizes in the orthorhombic Pna2_1 space group. V(1) is bonded to two equivalent N(1) and two equivalent N(2) atoms to form VN4 tetrahedra that share corners with four equivalent V(1)N4 tetrahedra and corners with eight equivalent Mn(1)N4 tetrahedra. Mn(1) is bonded to two equivalent N(1) and two equivalent N(2) atoms to form MnN4 tetrahedra that share corners with four equivalent Mn(1)N4 tetrahedra and corners with eight equivalent V(1)N4 tetrahedra. There are two inequivalent N sites. In the first N site, N(1) is bonded to two equivalent V(1) and two equivalent Mn(1) atoms to form corner-sharing NMn2V2 tetrahedra. In the second N site, N(2) is bonded to two equivalent V(1) and two equivalent Mn(1) atoms to form corner-sharing NMn2V2 tetrahedra. is represented by the CIF card [CIF]
data_MnVN2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.264
_cell_length_b   6.046
_cell_length_c   5.359
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   170.557
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.591  0.872  0.003  1.0
  Mn  Mn1  1  0.409  0.128  0.503  1.0
  Mn  Mn2  1  0.909  0.372  0.503  1.0
  Mn  Mn3  1  0.091  0.628  0.003  1.0
  V  V4  1  0.582  0.373  0.005  1.0
  V  V5  1  0.418  0.627  0.505  1.0
  V  V6  1  0.918  0.873  0.505  1.0
  V  V7  1  0.082  0.127  0.005  1.0
  N  N8  1  0.585  0.876  0.360  1.0
  N  N9  1  0.415  0.124  0.860  1.0
  N  N10  1  0.915  0.376  0.860  1.0
  N  N11  1  0.085  0.624  0.360  1.0
  N  N12  1  0.579  0.378  0.354  1.0
  N  N13  1  0.421  0.622  0.854  1.0
  N  N14  1  0.921  0.878  0.854  1.0
  N  N15  1  0.079  0.122  0.354  1.0
[/CIF]
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