The compound described by Rb2MnS2 crystallizes in the orthorhombic Ibam space group. Rb(1) is bonded in a 5-coordinate geometry to six equivalent S(1) atoms. Mn(1) is bonded to four equivalent S(1) atoms to form distorted edge-sharing MnS4 tetrahedra. S(1) is bonded in a 8-coordinate geometry to six equivalent Rb(1) and two equivalent Mn(1) atoms. is represented by the CIF card [CIF]
data_Rb2MnS2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.390
_cell_length_b   7.090
_cell_length_c   8.163
_cell_angle_alpha   115.729
_cell_angle_beta   113.040
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   300.046
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.648  0.809  0.296  1.0
  Rb  Rb1  1  0.352  0.191  0.704  1.0
  Rb  Rb2  1  0.852  0.513  0.704  1.0
  Rb  Rb3  1  0.148  0.487  0.296  1.0
  Mn  Mn4  1  0.250  0.000  0.000  1.0
  Mn  Mn5  1  0.750  0.000  0.000  1.0
  S  S6  1  0.401  0.716  0.801  1.0
  S  S7  1  0.599  0.284  0.199  1.0
  S  S8  1  0.099  0.915  0.199  1.0
  S  S9  1  0.901  0.085  0.801  1.0
[/CIF]
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The compound described by Rb2MnS2 crystallizes in the orthorhombic Ibam space group. Rb(1) is bonded in a 5-coordinate geometry to six equivalent S(1) atoms. Mn(1) is bonded to four equivalent S(1) atoms to form distorted edge-sharing MnS4 tetrahedra. S(1) is bonded in a 8-coordinate geometry to six equivalent Rb(1) and two equivalent Mn(1) atoms. is represented by the CIF card [CIF]
data_Rb2MnS2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.390
_cell_length_b   7.090
_cell_length_c   8.163
_cell_angle_alpha   115.729
_cell_angle_beta   113.040
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   300.046
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.648  0.809  0.296  1.0
  Rb  Rb1  1  0.352  0.191  0.704  1.0
  Rb  Rb2  1  0.852  0.513  0.704  1.0
  Rb  Rb3  1  0.148  0.487  0.296  1.0
  Mn  Mn4  1  0.250  0.000  0.000  1.0
  Mn  Mn5  1  0.750  0.000  0.000  1.0
  S  S6  1  0.401  0.716  0.801  1.0
  S  S7  1  0.599  0.284  0.199  1.0
  S  S8  1  0.099  0.915  0.199  1.0
  S  S9  1  0.901  0.085  0.801  1.0
[/CIF]
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