The compound described by (SbCl6)2(O2)3 is Modderite structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four trioxidane molecules and four SbCl6 clusters. In each SbCl6 cluster, Sb(1) is bonded in an octahedral geometry to one Cl(1), one Cl(2), one Cl(3), one Cl(4), one Cl(5), and one Cl(6) atom. There are six inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Sb(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth Cl site, Cl(5) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth Cl site, Cl(6) is bonded in a single-bond geometry to one Sb(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sb(Cl2O)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.390
_cell_length_b   7.116
_cell_length_c   12.954
_cell_angle_alpha   86.006
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1139.390
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.632  0.701  0.696  1.0
  Sb  Sb1  1  0.132  0.299  0.804  1.0
  Sb  Sb2  1  0.368  0.299  0.304  1.0
  Sb  Sb3  1  0.868  0.701  0.196  1.0
  Cl  Cl4  1  0.688  0.775  0.520  1.0
  Cl  Cl5  1  0.188  0.225  0.980  1.0
  Cl  Cl6  1  0.312  0.225  0.480  1.0
  Cl  Cl7  1  0.812  0.775  0.020  1.0
  Cl  Cl8  1  0.541  0.424  0.645  1.0
  Cl  Cl9  1  0.041  0.576  0.855  1.0
  Cl  Cl10  1  0.459  0.576  0.355  1.0
  Cl  Cl11  1  0.959  0.424  0.145  1.0
  Cl  Cl12  1  0.472  0.885  0.664  1.0
  Cl  Cl13  1  0.972  0.115  0.836  1.0
  Cl  Cl14  1  0.528  0.115  0.336  1.0
  Cl  Cl15  1  0.028  0.885  0.164  1.0
  Cl  Cl16  1  0.576  0.623  0.872  1.0
  Cl  Cl17  1  0.076  0.377  0.628  1.0
  Cl  Cl18  1  0.424  0.377  0.128  1.0
  Cl  Cl19  1  0.924  0.623  0.372  1.0
  Cl  Cl20  1  0.727  0.972  0.750  1.0
  Cl  Cl21  1  0.227  0.028  0.750  1.0
  Cl  Cl22  1  0.273  0.028  0.250  1.0
  Cl  Cl23  1  0.773  0.972  0.250  1.0
  Cl  Cl24  1  0.794  0.519  0.725  1.0
  Cl  Cl25  1  0.294  0.481  0.775  1.0
  Cl  Cl26  1  0.206  0.481  0.275  1.0
  Cl  Cl27  1  0.706  0.519  0.225  1.0
  O  O28  1  0.542  0.153  0.905  1.0
  O  O29  1  0.042  0.847  0.595  1.0
  O  O30  1  0.458  0.847  0.095  1.0
  O  O31  1  0.958  0.153  0.405  1.0
  O  O32  1  0.610  0.153  0.980  1.0
  O  O33  1  0.110  0.847  0.520  1.0
  O  O34  1  0.390  0.847  0.020  1.0
  O  O35  1  0.890  0.153  0.480  1.0
  O  O36  1  0.703  0.224  0.962  1.0
  O  O37  1  0.203  0.776  0.538  1.0
  O  O38  1  0.297  0.776  0.038  1.0
  O  O39  1  0.797  0.224  0.462  1.0
[/CIF]
.
The compound described by (SbCl6)2(O2)3 is Modderite structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four trioxidane molecules and four SbCl6 clusters. In each SbCl6 cluster, Sb(1) is bonded in an octahedral geometry to one Cl(1), one Cl(2), one Cl(3), one Cl(4), one Cl(5), and one Cl(6) atom. There are six inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Sb(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth Cl site, Cl(5) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth Cl site, Cl(6) is bonded in a single-bond geometry to one Sb(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sb(Cl2O)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.390
_cell_length_b   7.116
_cell_length_c   12.954
_cell_angle_alpha   86.006
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1139.390
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.632  0.701  0.696  1.0
  Sb  Sb1  1  0.132  0.299  0.804  1.0
  Sb  Sb2  1  0.368  0.299  0.304  1.0
  Sb  Sb3  1  0.868  0.701  0.196  1.0
  Cl  Cl4  1  0.688  0.775  0.520  1.0
  Cl  Cl5  1  0.188  0.225  0.980  1.0
  Cl  Cl6  1  0.312  0.225  0.480  1.0
  Cl  Cl7  1  0.812  0.775  0.020  1.0
  Cl  Cl8  1  0.541  0.424  0.645  1.0
  Cl  Cl9  1  0.041  0.576  0.855  1.0
  Cl  Cl10  1  0.459  0.576  0.355  1.0
  Cl  Cl11  1  0.959  0.424  0.145  1.0
  Cl  Cl12  1  0.472  0.885  0.664  1.0
  Cl  Cl13  1  0.972  0.115  0.836  1.0
  Cl  Cl14  1  0.528  0.115  0.336  1.0
  Cl  Cl15  1  0.028  0.885  0.164  1.0
  Cl  Cl16  1  0.576  0.623  0.872  1.0
  Cl  Cl17  1  0.076  0.377  0.628  1.0
  Cl  Cl18  1  0.424  0.377  0.128  1.0
  Cl  Cl19  1  0.924  0.623  0.372  1.0
  Cl  Cl20  1  0.727  0.972  0.750  1.0
  Cl  Cl21  1  0.227  0.028  0.750  1.0
  Cl  Cl22  1  0.273  0.028  0.250  1.0
  Cl  Cl23  1  0.773  0.972  0.250  1.0
  Cl  Cl24  1  0.794  0.519  0.725  1.0
  Cl  Cl25  1  0.294  0.481  0.775  1.0
  Cl  Cl26  1  0.206  0.481  0.275  1.0
  Cl  Cl27  1  0.706  0.519  0.225  1.0
  O  O28  1  0.542  0.153  0.905  1.0
  O  O29  1  0.042  0.847  0.595  1.0
  O  O30  1  0.458  0.847  0.095  1.0
  O  O31  1  0.958  0.153  0.405  1.0
  O  O32  1  0.610  0.153  0.980  1.0
  O  O33  1  0.110  0.847  0.520  1.0
  O  O34  1  0.390  0.847  0.020  1.0
  O  O35  1  0.890  0.153  0.480  1.0
  O  O36  1  0.703  0.224  0.962  1.0
  O  O37  1  0.203  0.776  0.538  1.0
  O  O38  1  0.297  0.776  0.038  1.0
  O  O39  1  0.797  0.224  0.462  1.0
[/CIF]
.