The compound described by ZnPb(O11I3)2O2 crystallizes in the triclinic P-1 space group. The structure consists of two water atoms inside a ZnPb(O11I3)2 framework. In the ZnPb(O11I3)2 framework, Zn(1) is bonded in a distorted octahedral geometry to two equivalent O(1), two equivalent O(10), and two equivalent O(11) atoms. Pb(1) is bonded in an octahedral geometry to two equivalent O(3), two equivalent O(4), and two equivalent O(7) atoms. There are eleven inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one I(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one I(1) and one I(2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Pb(1) and one I(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Pb(1) and one I(2) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one I(2) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one I(2) atom. In the seventh O site, O(7) is bonded in a 2-coordinate geometry to one Pb(1) and one I(3) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one I(3) atom. In the ninth O site, O(9) is bonded in a distorted bent 150 degrees geometry to one I(1) and one I(3) atom. In the tenth O site, O(10) is bonded in a single-bond geometry to one Zn(1) atom. In the eleventh O site, O(11) is bonded in a single-bond geometry to one Zn(1) atom. There are three inequivalent I sites. In the first I site, I(1) is bonded in a 3-coordinate geometry to one O(1), one O(2), one O(3), and one O(9) atom. In the second I site, I(2) is bonded in a distorted see-saw-like geometry to one O(2), one O(4), one O(5), and one O(6) atom. In the third I site, I(3) is bonded in a 3-coordinate geometry to one O(7), one O(8), and one O(9) atom. is represented by the CIF card [CIF]
data_ZnPb(IO4)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.076
_cell_length_b   7.121
_cell_length_c   10.876
_cell_angle_alpha   95.444
_cell_angle_beta   108.808
_cell_angle_gamma   92.748
_symmetry_Int_Tables_number   1
_cell_volume   514.643
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.000  0.000  0.500  1.0
  Pb  Pb1  1  0.000  0.000  0.000  1.0
  I  I2  1  0.365  0.939  0.329  1.0
  I  I3  1  0.635  0.061  0.671  1.0
  I  I4  1  0.168  0.459  0.199  1.0
  I  I5  1  0.832  0.541  0.801  1.0
  I  I6  1  0.494  0.261  0.003  1.0
  I  I7  1  0.506  0.739  0.997  1.0
  O  O8  1  0.712  0.967  0.530  1.0
  O  O9  1  0.288  0.033  0.470  1.0
  O  O10  1  0.635  0.309  0.637  1.0
  O  O11  1  0.365  0.691  0.363  1.0
  O  O12  1  0.891  0.086  0.795  1.0
  O  O13  1  0.109  0.914  0.205  1.0
  O  O14  1  0.967  0.285  0.067  1.0
  O  O15  1  0.033  0.715  0.933  1.0
  O  O16  1  0.364  0.299  0.243  1.0
  O  O17  1  0.636  0.701  0.757  1.0
  O  O18  1  0.035  0.429  0.319  1.0
  O  O19  1  0.965  0.571  0.681  1.0
  O  O20  1  0.694  0.952  0.018  1.0
  O  O21  1  0.306  0.048  0.982  1.0
  O  O22  1  0.696  0.563  0.022  1.0
  O  O23  1  0.304  0.437  0.978  1.0
  O  O24  1  0.493  0.769  0.161  1.0
  O  O25  1  0.507  0.231  0.839  1.0
  O  O26  1  0.862  0.205  0.402  1.0
  O  O27  1  0.138  0.795  0.598  1.0
  O  O28  1  0.919  0.707  0.403  1.0
  O  O29  1  0.081  0.293  0.597  1.0
  O  O30  1  0.780  0.489  0.473  1.0
  O  O31  1  0.220  0.511  0.527  1.0
[/CIF]
.
The compound described by ZnPb(O11I3)2O2 crystallizes in the triclinic P-1 space group. The structure consists of two water atoms inside a ZnPb(O11I3)2 framework. In the ZnPb(O11I3)2 framework, Zn(1) is bonded in a distorted octahedral geometry to two equivalent O(1), two equivalent O(10), and two equivalent O(11) atoms. Pb(1) is bonded in an octahedral geometry to two equivalent O(3), two equivalent O(4), and two equivalent O(7) atoms. There are eleven inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one I(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one I(1) and one I(2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Pb(1) and one I(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Pb(1) and one I(2) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one I(2) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one I(2) atom. In the seventh O site, O(7) is bonded in a 2-coordinate geometry to one Pb(1) and one I(3) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one I(3) atom. In the ninth O site, O(9) is bonded in a distorted bent 150 degrees geometry to one I(1) and one I(3) atom. In the tenth O site, O(10) is bonded in a single-bond geometry to one Zn(1) atom. In the eleventh O site, O(11) is bonded in a single-bond geometry to one Zn(1) atom. There are three inequivalent I sites. In the first I site, I(1) is bonded in a 3-coordinate geometry to one O(1), one O(2), one O(3), and one O(9) atom. In the second I site, I(2) is bonded in a distorted see-saw-like geometry to one O(2), one O(4), one O(5), and one O(6) atom. In the third I site, I(3) is bonded in a 3-coordinate geometry to one O(7), one O(8), and one O(9) atom. is represented by the CIF card [CIF]
data_ZnPb(IO4)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.076
_cell_length_b   7.121
_cell_length_c   10.876
_cell_angle_alpha   95.444
_cell_angle_beta   108.808
_cell_angle_gamma   92.748
_symmetry_Int_Tables_number   1
_cell_volume   514.643
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.000  0.000  0.500  1.0
  Pb  Pb1  1  0.000  0.000  0.000  1.0
  I  I2  1  0.365  0.939  0.329  1.0
  I  I3  1  0.635  0.061  0.671  1.0
  I  I4  1  0.168  0.459  0.199  1.0
  I  I5  1  0.832  0.541  0.801  1.0
  I  I6  1  0.494  0.261  0.003  1.0
  I  I7  1  0.506  0.739  0.997  1.0
  O  O8  1  0.712  0.967  0.530  1.0
  O  O9  1  0.288  0.033  0.470  1.0
  O  O10  1  0.635  0.309  0.637  1.0
  O  O11  1  0.365  0.691  0.363  1.0
  O  O12  1  0.891  0.086  0.795  1.0
  O  O13  1  0.109  0.914  0.205  1.0
  O  O14  1  0.967  0.285  0.067  1.0
  O  O15  1  0.033  0.715  0.933  1.0
  O  O16  1  0.364  0.299  0.243  1.0
  O  O17  1  0.636  0.701  0.757  1.0
  O  O18  1  0.035  0.429  0.319  1.0
  O  O19  1  0.965  0.571  0.681  1.0
  O  O20  1  0.694  0.952  0.018  1.0
  O  O21  1  0.306  0.048  0.982  1.0
  O  O22  1  0.696  0.563  0.022  1.0
  O  O23  1  0.304  0.437  0.978  1.0
  O  O24  1  0.493  0.769  0.161  1.0
  O  O25  1  0.507  0.231  0.839  1.0
  O  O26  1  0.862  0.205  0.402  1.0
  O  O27  1  0.138  0.795  0.598  1.0
  O  O28  1  0.919  0.707  0.403  1.0
  O  O29  1  0.081  0.293  0.597  1.0
  O  O30  1  0.780  0.489  0.473  1.0
  O  O31  1  0.220  0.511  0.527  1.0
[/CIF]
.