The material described by CN2H4S is Indium-like structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four thiourea molecules. C(1) is bonded in a distorted trigonal planar geometry to two equivalent N(1) and one S(1) atom. N(1) is bonded in a trigonal planar geometry to one C(1), one H(1), and one H(2) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. S(1) is bonded in a single-bond geometry to one C(1) atom. is represented by the CIF card [CIF]
data_H4CSN2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.750
_cell_length_b   7.925
_cell_length_c   8.660
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   394.589
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.805  0.093  0.487  1.0
  H  H1  1  0.305  0.407  0.513  1.0
  H  H2  1  0.695  0.593  0.013  1.0
  H  H3  1  0.195  0.907  0.987  1.0
  H  H4  1  0.195  0.907  0.513  1.0
  H  H5  1  0.695  0.593  0.487  1.0
  H  H6  1  0.305  0.407  0.987  1.0
  H  H7  1  0.805  0.093  0.013  1.0
  H  H8  1  0.595  0.206  0.379  1.0
  H  H9  1  0.595  0.206  0.121  1.0
  H  H10  1  0.905  0.706  0.121  1.0
  H  H11  1  0.405  0.794  0.879  1.0
  H  H12  1  0.405  0.794  0.621  1.0
  H  H13  1  0.905  0.706  0.379  1.0
  H  H14  1  0.095  0.294  0.879  1.0
  H  H15  1  0.095  0.294  0.621  1.0
  C  C16  1  0.660  0.582  0.250  1.0
  C  C17  1  0.840  0.082  0.250  1.0
  C  C18  1  0.340  0.418  0.750  1.0
  C  C19  1  0.160  0.918  0.750  1.0
  S  S20  1  0.908  0.034  0.750  1.0
  S  S21  1  0.408  0.466  0.250  1.0
  S  S22  1  0.592  0.534  0.750  1.0
  S  S23  1  0.092  0.966  0.250  1.0
  N  N24  1  0.738  0.129  0.382  1.0
  N  N25  1  0.762  0.629  0.382  1.0
  N  N26  1  0.238  0.371  0.882  1.0
  N  N27  1  0.738  0.129  0.118  1.0
  N  N28  1  0.262  0.871  0.618  1.0
  N  N29  1  0.262  0.871  0.882  1.0
  N  N30  1  0.762  0.629  0.118  1.0
  N  N31  1  0.238  0.371  0.618  1.0
[/CIF]
.
The material described by CN2H4S is Indium-like structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four thiourea molecules. C(1) is bonded in a distorted trigonal planar geometry to two equivalent N(1) and one S(1) atom. N(1) is bonded in a trigonal planar geometry to one C(1), one H(1), and one H(2) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. S(1) is bonded in a single-bond geometry to one C(1) atom. is represented by the CIF card [CIF]
data_H4CSN2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.750
_cell_length_b   7.925
_cell_length_c   8.660
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   394.589
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.805  0.093  0.487  1.0
  H  H1  1  0.305  0.407  0.513  1.0
  H  H2  1  0.695  0.593  0.013  1.0
  H  H3  1  0.195  0.907  0.987  1.0
  H  H4  1  0.195  0.907  0.513  1.0
  H  H5  1  0.695  0.593  0.487  1.0
  H  H6  1  0.305  0.407  0.987  1.0
  H  H7  1  0.805  0.093  0.013  1.0
  H  H8  1  0.595  0.206  0.379  1.0
  H  H9  1  0.595  0.206  0.121  1.0
  H  H10  1  0.905  0.706  0.121  1.0
  H  H11  1  0.405  0.794  0.879  1.0
  H  H12  1  0.405  0.794  0.621  1.0
  H  H13  1  0.905  0.706  0.379  1.0
  H  H14  1  0.095  0.294  0.879  1.0
  H  H15  1  0.095  0.294  0.621  1.0
  C  C16  1  0.660  0.582  0.250  1.0
  C  C17  1  0.840  0.082  0.250  1.0
  C  C18  1  0.340  0.418  0.750  1.0
  C  C19  1  0.160  0.918  0.750  1.0
  S  S20  1  0.908  0.034  0.750  1.0
  S  S21  1  0.408  0.466  0.250  1.0
  S  S22  1  0.592  0.534  0.750  1.0
  S  S23  1  0.092  0.966  0.250  1.0
  N  N24  1  0.738  0.129  0.382  1.0
  N  N25  1  0.762  0.629  0.382  1.0
  N  N26  1  0.238  0.371  0.882  1.0
  N  N27  1  0.738  0.129  0.118  1.0
  N  N28  1  0.262  0.871  0.618  1.0
  N  N29  1  0.262  0.871  0.882  1.0
  N  N30  1  0.762  0.629  0.118  1.0
  N  N31  1  0.238  0.371  0.618  1.0
[/CIF]
.