The structure described by VO6FVO4FN2O2 is Indium-derived structured and crystallizes in the orthorhombic P222_1 space group. The structure is zero-dimensional and consists of four ammonia atoms, four water atoms, two VO4F clusters, and two VO6F clusters. In each VO4F cluster, V(2) is bonded in a 5-coordinate geometry to two equivalent O(3), two equivalent O(5), and one F(2) atom. There are two inequivalent O sites. In the first O site, O(3) is bonded in a distorted single-bond geometry to one V(2) and one O(5) atom. In the second O site, O(5) is bonded in a distorted single-bond geometry to one V(2) and one O(3) atom. F(2) is bonded in a single-bond geometry to one V(2) atom. In each VO6F cluster, V(1) is bonded in a distorted pentagonal bipyramidal geometry to two equivalent O(1), two equivalent O(2), two equivalent O(6), and one F(1) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one V(1) and one O(2) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one V(1) and one O(1) atom. In the third O site, O(6) is bonded in a 2-coordinate geometry to one V(1) and one O(6) atom. F(1) is bonded in a single-bond geometry to one V(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_VNO6F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.079
_cell_length_b   9.464
_cell_length_c   11.181
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   854.840
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.500  0.500  0.250  1.0
  V  V1  1  0.000  0.500  0.750  1.0
  V  V2  1  0.500  0.000  0.680  1.0
  V  V3  1  0.000  0.000  0.320  1.0
  N  N4  1  0.750  0.741  0.000  1.0
  N  N5  1  0.250  0.259  0.000  1.0
  N  N6  1  0.250  0.772  0.500  1.0
  N  N7  1  0.750  0.228  0.500  1.0
  O  O8  1  0.365  0.678  0.225  1.0
  O  O9  1  0.635  0.322  0.225  1.0
  O  O10  1  0.865  0.322  0.775  1.0
  O  O11  1  0.135  0.678  0.775  1.0
  O  O12  1  0.512  0.710  0.271  1.0
  O  O13  1  0.488  0.290  0.271  1.0
  O  O14  1  0.012  0.290  0.729  1.0
  O  O15  1  0.988  0.710  0.729  1.0
  O  O16  1  0.048  0.834  0.233  1.0
  O  O17  1  0.952  0.166  0.233  1.0
  O  O18  1  0.548  0.166  0.767  1.0
  O  O19  1  0.452  0.834  0.767  1.0
  O  O20  1  0.500  0.000  0.267  1.0
  O  O21  1  0.000  0.000  0.733  1.0
  O  O22  1  0.877  0.863  0.235  1.0
  O  O23  1  0.123  0.137  0.235  1.0
  O  O24  1  0.377  0.137  0.765  1.0
  O  O25  1  0.623  0.863  0.765  1.0
  O  O26  1  0.582  0.497  0.422  1.0
  O  O27  1  0.418  0.503  0.422  1.0
  O  O28  1  0.082  0.503  0.578  1.0
  O  O29  1  0.918  0.497  0.578  1.0
  O  O30  1  0.000  0.500  0.189  1.0
  O  O31  1  0.500  0.500  0.811  1.0
  F  F32  1  0.500  0.500  0.089  1.0
  F  F33  1  0.000  0.500  0.911  1.0
  F  F34  1  0.500  0.000  0.521  1.0
  F  F35  1  0.000  0.000  0.479  1.0
[/CIF]
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The structure described by VO6FVO4FN2O2 is Indium-derived structured and crystallizes in the orthorhombic P222_1 space group. The structure is zero-dimensional and consists of four ammonia atoms, four water atoms, two VO4F clusters, and two VO6F clusters. In each VO4F cluster, V(2) is bonded in a 5-coordinate geometry to two equivalent O(3), two equivalent O(5), and one F(2) atom. There are two inequivalent O sites. In the first O site, O(3) is bonded in a distorted single-bond geometry to one V(2) and one O(5) atom. In the second O site, O(5) is bonded in a distorted single-bond geometry to one V(2) and one O(3) atom. F(2) is bonded in a single-bond geometry to one V(2) atom. In each VO6F cluster, V(1) is bonded in a distorted pentagonal bipyramidal geometry to two equivalent O(1), two equivalent O(2), two equivalent O(6), and one F(1) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one V(1) and one O(2) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one V(1) and one O(1) atom. In the third O site, O(6) is bonded in a 2-coordinate geometry to one V(1) and one O(6) atom. F(1) is bonded in a single-bond geometry to one V(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_VNO6F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.079
_cell_length_b   9.464
_cell_length_c   11.181
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   854.840
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.500  0.500  0.250  1.0
  V  V1  1  0.000  0.500  0.750  1.0
  V  V2  1  0.500  0.000  0.680  1.0
  V  V3  1  0.000  0.000  0.320  1.0
  N  N4  1  0.750  0.741  0.000  1.0
  N  N5  1  0.250  0.259  0.000  1.0
  N  N6  1  0.250  0.772  0.500  1.0
  N  N7  1  0.750  0.228  0.500  1.0
  O  O8  1  0.365  0.678  0.225  1.0
  O  O9  1  0.635  0.322  0.225  1.0
  O  O10  1  0.865  0.322  0.775  1.0
  O  O11  1  0.135  0.678  0.775  1.0
  O  O12  1  0.512  0.710  0.271  1.0
  O  O13  1  0.488  0.290  0.271  1.0
  O  O14  1  0.012  0.290  0.729  1.0
  O  O15  1  0.988  0.710  0.729  1.0
  O  O16  1  0.048  0.834  0.233  1.0
  O  O17  1  0.952  0.166  0.233  1.0
  O  O18  1  0.548  0.166  0.767  1.0
  O  O19  1  0.452  0.834  0.767  1.0
  O  O20  1  0.500  0.000  0.267  1.0
  O  O21  1  0.000  0.000  0.733  1.0
  O  O22  1  0.877  0.863  0.235  1.0
  O  O23  1  0.123  0.137  0.235  1.0
  O  O24  1  0.377  0.137  0.765  1.0
  O  O25  1  0.623  0.863  0.765  1.0
  O  O26  1  0.582  0.497  0.422  1.0
  O  O27  1  0.418  0.503  0.422  1.0
  O  O28  1  0.082  0.503  0.578  1.0
  O  O29  1  0.918  0.497  0.578  1.0
  O  O30  1  0.000  0.500  0.189  1.0
  O  O31  1  0.500  0.500  0.811  1.0
  F  F32  1  0.500  0.500  0.089  1.0
  F  F33  1  0.000  0.500  0.911  1.0
  F  F34  1  0.500  0.000  0.521  1.0
  F  F35  1  0.000  0.000  0.479  1.0
[/CIF]
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