The material structure described by Nd(CO3)3 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two Nd(CO3)3 clusters. Nd(1) is bonded in a 7-coordinate geometry to one O(1), one O(3), one O(4), one O(5), one O(7), one O(8), and one O(9) atom. There are three inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one O(1) and one O(2) atom. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. In the third C site, C(3) is bonded in a linear geometry to one O(5) and one O(6) atom. There are nine inequivalent O sites. In the first O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Nd(1) and one C(3) atom. In the second O site, O(6) is bonded in a single-bond geometry to one C(3) atom. In the third O site, O(7) is bonded in a single-bond geometry to one Nd(1) atom. In the fourth O site, O(8) is bonded in a 2-coordinate geometry to one Nd(1) and one O(9) atom. In the fifth O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Nd(1) and one C(1) atom. In the sixth O site, O(9) is bonded in a 2-coordinate geometry to one Nd(1) and one O(8) atom. In the seventh O site, O(2) is bonded in a single-bond geometry to one C(1) atom. In the eighth O site, O(3) is bonded in a bent 120 degrees geometry to one Nd(1) and one C(2) atom. In the ninth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Nd(1) and one C(2) atom. is represented by the CIF file [CIF]
data_Nd(CO3)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.223
_cell_length_b   11.390
_cell_length_c   12.043
_cell_angle_alpha   69.275
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1183.207
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Nd  Nd0  1  0.513  0.283  0.825  1.0
  Nd  Nd1  1  0.013  0.217  0.175  1.0
  Nd  Nd2  1  0.487  0.717  0.175  1.0
  Nd  Nd3  1  0.987  0.783  0.825  1.0
  C  C4  1  0.400  0.363  0.512  1.0
  C  C5  1  0.900  0.137  0.488  1.0
  C  C6  1  0.600  0.637  0.488  1.0
  C  C7  1  0.100  0.863  0.512  1.0
  C  C8  1  0.422  0.997  0.975  1.0
  C  C9  1  0.922  0.503  0.025  1.0
  C  C10  1  0.578  0.003  0.025  1.0
  C  C11  1  0.078  0.497  0.975  1.0
  C  C12  1  0.460  0.369  0.102  1.0
  C  C13  1  0.960  0.131  0.898  1.0
  C  C14  1  0.540  0.631  0.898  1.0
  C  C15  1  0.040  0.869  0.102  1.0
  O  O16  1  0.417  0.287  0.608  1.0
  O  O17  1  0.917  0.213  0.392  1.0
  O  O18  1  0.583  0.713  0.392  1.0
  O  O19  1  0.083  0.787  0.608  1.0
  O  O20  1  0.384  0.438  0.417  1.0
  O  O21  1  0.884  0.062  0.583  1.0
  O  O22  1  0.616  0.562  0.583  1.0
  O  O23  1  0.116  0.938  0.417  1.0
  O  O24  1  0.375  0.098  0.897  1.0
  O  O25  1  0.875  0.402  0.103  1.0
  O  O26  1  0.625  0.902  0.103  1.0
  O  O27  1  0.125  0.598  0.897  1.0
  O  O28  1  0.643  0.107  0.983  1.0
  O  O29  1  0.143  0.393  0.017  1.0
  O  O30  1  0.357  0.893  0.017  1.0
  O  O31  1  0.857  0.607  0.983  1.0
  O  O32  1  0.500  0.316  0.040  1.0
  O  O33  1  1.000  0.184  0.960  1.0
  O  O34  1  0.500  0.684  0.960  1.0
  O  O35  1  0.000  0.816  0.040  1.0
  O  O36  1  0.576  0.576  0.837  1.0
  O  O37  1  0.076  0.924  0.163  1.0
  O  O38  1  0.424  0.424  0.163  1.0
  O  O39  1  0.924  0.076  0.837  1.0
  O  O40  1  0.356  0.441  0.769  1.0
  O  O41  1  0.856  0.059  0.231  1.0
  O  O42  1  0.644  0.559  0.231  1.0
  O  O43  1  0.144  0.941  0.769  1.0
  O  O44  1  0.711  0.298  0.696  1.0
  O  O45  1  0.211  0.202  0.304  1.0
  O  O46  1  0.289  0.702  0.304  1.0
  O  O47  1  0.789  0.798  0.696  1.0
  O  O48  1  0.763  0.331  0.785  1.0
  O  O49  1  0.263  0.169  0.215  1.0
  O  O50  1  0.237  0.669  0.215  1.0
  O  O51  1  0.737  0.831  0.785  1.0
[/CIF]
.
The material structure described by Nd(CO3)3 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two Nd(CO3)3 clusters. Nd(1) is bonded in a 7-coordinate geometry to one O(1), one O(3), one O(4), one O(5), one O(7), one O(8), and one O(9) atom. There are three inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one O(1) and one O(2) atom. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. In the third C site, C(3) is bonded in a linear geometry to one O(5) and one O(6) atom. There are nine inequivalent O sites. In the first O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Nd(1) and one C(3) atom. In the second O site, O(6) is bonded in a single-bond geometry to one C(3) atom. In the third O site, O(7) is bonded in a single-bond geometry to one Nd(1) atom. In the fourth O site, O(8) is bonded in a 2-coordinate geometry to one Nd(1) and one O(9) atom. In the fifth O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Nd(1) and one C(1) atom. In the sixth O site, O(9) is bonded in a 2-coordinate geometry to one Nd(1) and one O(8) atom. In the seventh O site, O(2) is bonded in a single-bond geometry to one C(1) atom. In the eighth O site, O(3) is bonded in a bent 120 degrees geometry to one Nd(1) and one C(2) atom. In the ninth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Nd(1) and one C(2) atom. is represented by the CIF file [CIF]
data_Nd(CO3)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.223
_cell_length_b   11.390
_cell_length_c   12.043
_cell_angle_alpha   69.275
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1183.207
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Nd  Nd0  1  0.513  0.283  0.825  1.0
  Nd  Nd1  1  0.013  0.217  0.175  1.0
  Nd  Nd2  1  0.487  0.717  0.175  1.0
  Nd  Nd3  1  0.987  0.783  0.825  1.0
  C  C4  1  0.400  0.363  0.512  1.0
  C  C5  1  0.900  0.137  0.488  1.0
  C  C6  1  0.600  0.637  0.488  1.0
  C  C7  1  0.100  0.863  0.512  1.0
  C  C8  1  0.422  0.997  0.975  1.0
  C  C9  1  0.922  0.503  0.025  1.0
  C  C10  1  0.578  0.003  0.025  1.0
  C  C11  1  0.078  0.497  0.975  1.0
  C  C12  1  0.460  0.369  0.102  1.0
  C  C13  1  0.960  0.131  0.898  1.0
  C  C14  1  0.540  0.631  0.898  1.0
  C  C15  1  0.040  0.869  0.102  1.0
  O  O16  1  0.417  0.287  0.608  1.0
  O  O17  1  0.917  0.213  0.392  1.0
  O  O18  1  0.583  0.713  0.392  1.0
  O  O19  1  0.083  0.787  0.608  1.0
  O  O20  1  0.384  0.438  0.417  1.0
  O  O21  1  0.884  0.062  0.583  1.0
  O  O22  1  0.616  0.562  0.583  1.0
  O  O23  1  0.116  0.938  0.417  1.0
  O  O24  1  0.375  0.098  0.897  1.0
  O  O25  1  0.875  0.402  0.103  1.0
  O  O26  1  0.625  0.902  0.103  1.0
  O  O27  1  0.125  0.598  0.897  1.0
  O  O28  1  0.643  0.107  0.983  1.0
  O  O29  1  0.143  0.393  0.017  1.0
  O  O30  1  0.357  0.893  0.017  1.0
  O  O31  1  0.857  0.607  0.983  1.0
  O  O32  1  0.500  0.316  0.040  1.0
  O  O33  1  1.000  0.184  0.960  1.0
  O  O34  1  0.500  0.684  0.960  1.0
  O  O35  1  0.000  0.816  0.040  1.0
  O  O36  1  0.576  0.576  0.837  1.0
  O  O37  1  0.076  0.924  0.163  1.0
  O  O38  1  0.424  0.424  0.163  1.0
  O  O39  1  0.924  0.076  0.837  1.0
  O  O40  1  0.356  0.441  0.769  1.0
  O  O41  1  0.856  0.059  0.231  1.0
  O  O42  1  0.644  0.559  0.231  1.0
  O  O43  1  0.144  0.941  0.769  1.0
  O  O44  1  0.711  0.298  0.696  1.0
  O  O45  1  0.211  0.202  0.304  1.0
  O  O46  1  0.289  0.702  0.304  1.0
  O  O47  1  0.789  0.798  0.696  1.0
  O  O48  1  0.763  0.331  0.785  1.0
  O  O49  1  0.263  0.169  0.215  1.0
  O  O50  1  0.237  0.669  0.215  1.0
  O  O51  1  0.737  0.831  0.785  1.0
[/CIF]
.