The crystal structure described by WMnZn2O6 crystallizes in the monoclinic Pc space group. W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form WO6 octahedra that share corners with six equivalent Mn(1)O6 octahedra, corners with four equivalent Zn(1)O4 tetrahedra, and corners with four equivalent Zn(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 42-54°. Mn(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form MnO6 octahedra that share corners with six equivalent W(1)O6 octahedra, corners with four equivalent Zn(1)O4 tetrahedra, and corners with four equivalent Zn(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 42-54°. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(2), one O(4), one O(5), and one O(6) atom to form distorted ZnO4 tetrahedra that share corners with four equivalent W(1)O6 octahedra, corners with four equivalent Mn(1)O6 octahedra, and corners with two equivalent Zn(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 55-87°. In the second Zn site, Zn(2) is bonded to one O(1), one O(3), one O(5), and one O(6) atom to form distorted ZnO4 tetrahedra that share corners with four equivalent W(1)O6 octahedra, corners with four equivalent Mn(1)O6 octahedra, and corners with two equivalent Zn(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 55-87°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one W(1), one Mn(1), and one Zn(2) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one W(1), one Mn(1), and one Zn(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one W(1), one Mn(1), and one Zn(2) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one W(1), one Mn(1), and one Zn(1) atom. In the fifth O site, O(5) is bonded to one W(1), one Mn(1), one Zn(1), and one Zn(2) atom to form distorted corner-sharing OMnZn2W tetrahedra. In the sixth O site, O(6) is bonded to one W(1), one Mn(1), one Zn(1), and one Zn(2) atom to form distorted corner-sharing OMnZn2W tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_MnZn2WO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.319
_cell_length_b   7.981
_cell_length_c   5.333
_cell_angle_alpha   88.433
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   226.283
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.500  0.500  0.000  1.0
  Mn  Mn1  1  0.999  1.000  0.501  1.0
  Zn  Zn2  1  0.025  0.260  0.016  1.0
  Zn  Zn3  1  0.525  0.240  0.484  1.0
  Zn  Zn4  1  0.975  0.740  0.984  1.0
  Zn  Zn5  1  0.475  0.760  0.516  1.0
  W  W6  1  0.000  0.500  0.500  1.0
  W  W7  1  0.500  1.000  1.000  1.0
  O  O8  1  0.311  0.414  0.641  1.0
  O  O9  1  0.811  0.086  0.859  1.0
  O  O10  1  0.689  0.586  0.359  1.0
  O  O11  1  0.189  0.914  0.141  1.0
  O  O12  1  0.160  0.554  0.181  1.0
  O  O13  1  0.660  0.946  0.319  1.0
  O  O14  1  0.840  0.446  0.819  1.0
  O  O15  1  0.340  0.054  0.681  1.0
  O  O16  1  0.397  0.228  0.118  1.0
  O  O17  1  0.897  0.272  0.382  1.0
  O  O18  1  0.103  0.728  0.618  1.0
  O  O19  1  0.603  0.772  0.882  1.0
[/CIF]
.
The crystal structure described by WMnZn2O6 crystallizes in the monoclinic Pc space group. W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form WO6 octahedra that share corners with six equivalent Mn(1)O6 octahedra, corners with four equivalent Zn(1)O4 tetrahedra, and corners with four equivalent Zn(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 42-54°. Mn(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form MnO6 octahedra that share corners with six equivalent W(1)O6 octahedra, corners with four equivalent Zn(1)O4 tetrahedra, and corners with four equivalent Zn(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 42-54°. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(2), one O(4), one O(5), and one O(6) atom to form distorted ZnO4 tetrahedra that share corners with four equivalent W(1)O6 octahedra, corners with four equivalent Mn(1)O6 octahedra, and corners with two equivalent Zn(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 55-87°. In the second Zn site, Zn(2) is bonded to one O(1), one O(3), one O(5), and one O(6) atom to form distorted ZnO4 tetrahedra that share corners with four equivalent W(1)O6 octahedra, corners with four equivalent Mn(1)O6 octahedra, and corners with two equivalent Zn(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 55-87°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one W(1), one Mn(1), and one Zn(2) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one W(1), one Mn(1), and one Zn(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one W(1), one Mn(1), and one Zn(2) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one W(1), one Mn(1), and one Zn(1) atom. In the fifth O site, O(5) is bonded to one W(1), one Mn(1), one Zn(1), and one Zn(2) atom to form distorted corner-sharing OMnZn2W tetrahedra. In the sixth O site, O(6) is bonded to one W(1), one Mn(1), one Zn(1), and one Zn(2) atom to form distorted corner-sharing OMnZn2W tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_MnZn2WO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.319
_cell_length_b   7.981
_cell_length_c   5.333
_cell_angle_alpha   88.433
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   226.283
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.500  0.500  0.000  1.0
  Mn  Mn1  1  0.999  1.000  0.501  1.0
  Zn  Zn2  1  0.025  0.260  0.016  1.0
  Zn  Zn3  1  0.525  0.240  0.484  1.0
  Zn  Zn4  1  0.975  0.740  0.984  1.0
  Zn  Zn5  1  0.475  0.760  0.516  1.0
  W  W6  1  0.000  0.500  0.500  1.0
  W  W7  1  0.500  1.000  1.000  1.0
  O  O8  1  0.311  0.414  0.641  1.0
  O  O9  1  0.811  0.086  0.859  1.0
  O  O10  1  0.689  0.586  0.359  1.0
  O  O11  1  0.189  0.914  0.141  1.0
  O  O12  1  0.160  0.554  0.181  1.0
  O  O13  1  0.660  0.946  0.319  1.0
  O  O14  1  0.840  0.446  0.819  1.0
  O  O15  1  0.340  0.054  0.681  1.0
  O  O16  1  0.397  0.228  0.118  1.0
  O  O17  1  0.897  0.272  0.382  1.0
  O  O18  1  0.103  0.728  0.618  1.0
  O  O19  1  0.603  0.772  0.882  1.0
[/CIF]
.