The compound described by Ba2SnS4O11 crystallizes in the triclinic P-1 space group. There are two inequivalent Ba sites. In the first Ba site, Ba(1) is bonded in a 7-coordinate geometry to one O(1), one O(3), one O(5), one O(7), one O(8), and two equivalent O(2) atoms. In the second Ba site, Ba(2) is bonded in a 10-coordinate geometry to one O(3), one O(4), two equivalent O(10), two equivalent O(11), two equivalent O(6), and two equivalent O(9) atoms. Sn(1) is bonded in an L-shaped geometry to one O(11) and one O(4) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one O(2) and one O(8) atom. In the second S site, S(2) is bonded in a trigonal non-coplanar geometry to one O(10), one O(3), and one O(7) atom. In the third S site, S(3) is bonded in a trigonal non-coplanar geometry to one O(4), one O(6), and one O(9) atom. In the fourth S site, S(4) is bonded in a water-like geometry to one O(1) and one O(5) atom. There are eleven inequivalent O sites. In the first O site, O(10) is bonded in a distorted single-bond geometry to two equivalent Ba(2) and one S(2) atom. In the second O site, O(11) is bonded in a 3-coordinate geometry to two equivalent Ba(2) and one Sn(1) atom. In the third O site, O(1) is bonded in a distorted water-like geometry to one Ba(1) and one S(4) atom. In the fourth O site, O(2) is bonded in a distorted single-bond geometry to two equivalent Ba(1) and one S(1) atom. In the fifth O site, O(3) is bonded in a 2-coordinate geometry to one Ba(1), one Ba(2), and one S(2) atom. In the sixth O site, O(4) is bonded in a 2-coordinate geometry to one Ba(2), one Sn(1), and one S(3) atom. In the seventh O site, O(5) is bonded in a distorted single-bond geometry to one Ba(1) and one S(4) atom. In the eighth O site, O(6) is bonded in a distorted single-bond geometry to two equivalent Ba(2) and one S(3) atom. In the ninth O site, O(7) is bonded in a linear geometry to one Ba(1) and one S(2) atom. In the tenth O site, O(8) is bonded in a distorted linear geometry to one Ba(1) and one S(1) atom. In the eleventh O site, O(9) is bonded in a distorted single-bond geometry to two equivalent Ba(2) and one S(3) atom. is represented by the CIF file [CIF]
data_Ba2SnS4O11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.299
_cell_length_b   5.874
_cell_length_c   17.294
_cell_angle_alpha   102.144
_cell_angle_beta   91.879
_cell_angle_gamma   108.014
_symmetry_Int_Tables_number   1
_cell_volume   685.499
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.959  0.658  0.373  1.0
  Ba  Ba1  1  0.041  0.342  0.627  1.0
  Ba  Ba2  1  0.805  0.472  0.077  1.0
  Ba  Ba3  1  0.195  0.528  0.923  1.0
  Sn  Sn4  1  0.360  0.850  0.174  1.0
  Sn  Sn5  1  0.640  0.150  0.826  1.0
  S  S6  1  0.304  0.390  0.451  1.0
  S  S7  1  0.696  0.610  0.549  1.0
  S  S8  1  0.993  0.071  0.209  1.0
  S  S9  1  0.007  0.929  0.791  1.0
  S  S10  1  0.286  0.242  0.081  1.0
  S  S11  1  0.714  0.758  0.919  1.0
  S  S12  1  0.478  0.634  0.345  1.0
  S  S13  1  0.522  0.366  0.655  1.0
  O  O14  1  0.576  0.472  0.298  1.0
  O  O15  1  0.424  0.528  0.702  1.0
  O  O16  1  0.216  0.573  0.495  1.0
  O  O17  1  0.784  0.427  0.505  1.0
  O  O18  1  0.014  0.859  0.247  1.0
  O  O19  1  0.986  0.141  0.753  1.0
  O  O20  1  0.402  0.477  0.145  1.0
  O  O21  1  0.598  0.523  0.855  1.0
  O  O22  1  0.609  0.811  0.414  1.0
  O  O23  1  0.391  0.189  0.586  1.0
  O  O24  1  0.101  0.260  0.051  1.0
  O  O25  1  0.899  0.740  0.949  1.0
  O  O26  1  0.977  0.277  0.276  1.0
  O  O27  1  0.023  0.723  0.724  1.0
  O  O28  1  0.840  0.861  0.570  1.0
  O  O29  1  0.160  0.139  0.430  1.0
  O  O30  1  0.414  0.217  0.016  1.0
  O  O31  1  0.586  0.783  0.984  1.0
  O  O32  1  0.799  0.962  0.157  1.0
  O  O33  1  0.201  0.038  0.843  1.0
  O  O34  1  0.184  0.749  0.076  1.0
  O  O35  1  0.816  0.251  0.924  1.0
[/CIF]
.
The compound described by Ba2SnS4O11 crystallizes in the triclinic P-1 space group. There are two inequivalent Ba sites. In the first Ba site, Ba(1) is bonded in a 7-coordinate geometry to one O(1), one O(3), one O(5), one O(7), one O(8), and two equivalent O(2) atoms. In the second Ba site, Ba(2) is bonded in a 10-coordinate geometry to one O(3), one O(4), two equivalent O(10), two equivalent O(11), two equivalent O(6), and two equivalent O(9) atoms. Sn(1) is bonded in an L-shaped geometry to one O(11) and one O(4) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one O(2) and one O(8) atom. In the second S site, S(2) is bonded in a trigonal non-coplanar geometry to one O(10), one O(3), and one O(7) atom. In the third S site, S(3) is bonded in a trigonal non-coplanar geometry to one O(4), one O(6), and one O(9) atom. In the fourth S site, S(4) is bonded in a water-like geometry to one O(1) and one O(5) atom. There are eleven inequivalent O sites. In the first O site, O(10) is bonded in a distorted single-bond geometry to two equivalent Ba(2) and one S(2) atom. In the second O site, O(11) is bonded in a 3-coordinate geometry to two equivalent Ba(2) and one Sn(1) atom. In the third O site, O(1) is bonded in a distorted water-like geometry to one Ba(1) and one S(4) atom. In the fourth O site, O(2) is bonded in a distorted single-bond geometry to two equivalent Ba(1) and one S(1) atom. In the fifth O site, O(3) is bonded in a 2-coordinate geometry to one Ba(1), one Ba(2), and one S(2) atom. In the sixth O site, O(4) is bonded in a 2-coordinate geometry to one Ba(2), one Sn(1), and one S(3) atom. In the seventh O site, O(5) is bonded in a distorted single-bond geometry to one Ba(1) and one S(4) atom. In the eighth O site, O(6) is bonded in a distorted single-bond geometry to two equivalent Ba(2) and one S(3) atom. In the ninth O site, O(7) is bonded in a linear geometry to one Ba(1) and one S(2) atom. In the tenth O site, O(8) is bonded in a distorted linear geometry to one Ba(1) and one S(1) atom. In the eleventh O site, O(9) is bonded in a distorted single-bond geometry to two equivalent Ba(2) and one S(3) atom. is represented by the CIF file [CIF]
data_Ba2SnS4O11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.299
_cell_length_b   5.874
_cell_length_c   17.294
_cell_angle_alpha   102.144
_cell_angle_beta   91.879
_cell_angle_gamma   108.014
_symmetry_Int_Tables_number   1
_cell_volume   685.499
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.959  0.658  0.373  1.0
  Ba  Ba1  1  0.041  0.342  0.627  1.0
  Ba  Ba2  1  0.805  0.472  0.077  1.0
  Ba  Ba3  1  0.195  0.528  0.923  1.0
  Sn  Sn4  1  0.360  0.850  0.174  1.0
  Sn  Sn5  1  0.640  0.150  0.826  1.0
  S  S6  1  0.304  0.390  0.451  1.0
  S  S7  1  0.696  0.610  0.549  1.0
  S  S8  1  0.993  0.071  0.209  1.0
  S  S9  1  0.007  0.929  0.791  1.0
  S  S10  1  0.286  0.242  0.081  1.0
  S  S11  1  0.714  0.758  0.919  1.0
  S  S12  1  0.478  0.634  0.345  1.0
  S  S13  1  0.522  0.366  0.655  1.0
  O  O14  1  0.576  0.472  0.298  1.0
  O  O15  1  0.424  0.528  0.702  1.0
  O  O16  1  0.216  0.573  0.495  1.0
  O  O17  1  0.784  0.427  0.505  1.0
  O  O18  1  0.014  0.859  0.247  1.0
  O  O19  1  0.986  0.141  0.753  1.0
  O  O20  1  0.402  0.477  0.145  1.0
  O  O21  1  0.598  0.523  0.855  1.0
  O  O22  1  0.609  0.811  0.414  1.0
  O  O23  1  0.391  0.189  0.586  1.0
  O  O24  1  0.101  0.260  0.051  1.0
  O  O25  1  0.899  0.740  0.949  1.0
  O  O26  1  0.977  0.277  0.276  1.0
  O  O27  1  0.023  0.723  0.724  1.0
  O  O28  1  0.840  0.861  0.570  1.0
  O  O29  1  0.160  0.139  0.430  1.0
  O  O30  1  0.414  0.217  0.016  1.0
  O  O31  1  0.586  0.783  0.984  1.0
  O  O32  1  0.799  0.962  0.157  1.0
  O  O33  1  0.201  0.038  0.843  1.0
  O  O34  1  0.184  0.749  0.076  1.0
  O  O35  1  0.816  0.251  0.924  1.0
[/CIF]
.