The compound described by MgWMn2FeO6 crystallizes in the triclinic P1 space group. Mg(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form MgO6 octahedra that share corners with three equivalent Mn(1)O6 octahedra, corners with three equivalent Fe(1)O6 octahedra, edges with three equivalent W(1)O6 octahedra,  a faceface with one Mn(1)O6 octahedra, and  a faceface with one Fe(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 34-48°. W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form WO6 octahedra that share corners with three equivalent Mn(1)O6 octahedra, corners with six equivalent Fe(1)O6 octahedra, edges with three equivalent Mg(1)O6 octahedra, and  a faceface with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 33-54°. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form MnO6 octahedra that share corners with three equivalent Mg(1)O6 octahedra, corners with three equivalent W(1)O6 octahedra, edges with three equivalent Fe(1)O6 octahedra,  a faceface with one Mg(1)O6 octahedra, and  a faceface with one W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 34-54°. In the second Mn site, Mn(2) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. Fe(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form distorted FeO6 octahedra that share corners with three equivalent Mg(1)O6 octahedra, corners with six equivalent W(1)O6 octahedra, edges with three equivalent Mn(1)O6 octahedra, and  a faceface with one Mg(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 33-54°. There are six inequivalent O sites. In the first O site, O(1) is bonded to one Mg(1), one W(1), one Mn(1), one Mn(2), and one Fe(1) atom to form a mixture of distorted corner and edge-sharing OMgMn2FeW trigonal bipyramids. In the second O site, O(2) is bonded in a 5-coordinate geometry to one Mg(1), one W(1), one Mn(1), one Mn(2), and one Fe(1) atom. In the third O site, O(3) is bonded in a 5-coordinate geometry to one Mg(1), one W(1), one Mn(1), one Mn(2), and one Fe(1) atom. In the fourth O site, O(4) is bonded to one Mg(1), one W(1), one Mn(1), one Mn(2), and one Fe(1) atom to form a mixture of distorted corner and edge-sharing OMgMn2FeW trigonal bipyramids. In the fifth O site, O(5) is bonded to one Mg(1), one W(1), one Mn(1), one Mn(2), and one Fe(1) atom to form a mixture of distorted corner and edge-sharing OMgMn2FeW trigonal bipyramids. In the sixth O site, O(6) is bonded in a 5-coordinate geometry to one Mg(1), one W(1), one Mn(1), one Mn(2), and one Fe(1) atom. is represented by the CIF file [CIF]
data_MgMn2FeWO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.393
_cell_length_b   5.378
_cell_length_c   6.106
_cell_angle_alpha   61.943
_cell_angle_beta   64.893
_cell_angle_gamma   59.549
_symmetry_Int_Tables_number   1
_cell_volume   130.642
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.646  0.646  0.063  1.0
  Mn  Mn1  1  0.813  0.814  0.557  1.0
  Mn  Mn2  1  0.278  0.273  0.164  1.0
  Fe  Fe3  1  0.467  0.480  0.590  1.0
  W  W4  1  0.003  0.993  0.006  1.0
  O  O5  1  0.249  0.849  0.289  1.0
  O  O6  1  0.877  0.621  0.272  1.0
  O  O7  1  0.633  0.220  0.262  1.0
  O  O8  1  0.049  0.405  0.833  1.0
  O  O9  1  0.392  0.731  0.821  1.0
  O  O10  1  0.708  0.068  0.810  1.0
[/CIF]
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The compound described by MgWMn2FeO6 crystallizes in the triclinic P1 space group. Mg(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form MgO6 octahedra that share corners with three equivalent Mn(1)O6 octahedra, corners with three equivalent Fe(1)O6 octahedra, edges with three equivalent W(1)O6 octahedra,  a faceface with one Mn(1)O6 octahedra, and  a faceface with one Fe(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 34-48°. W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form WO6 octahedra that share corners with three equivalent Mn(1)O6 octahedra, corners with six equivalent Fe(1)O6 octahedra, edges with three equivalent Mg(1)O6 octahedra, and  a faceface with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 33-54°. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form MnO6 octahedra that share corners with three equivalent Mg(1)O6 octahedra, corners with three equivalent W(1)O6 octahedra, edges with three equivalent Fe(1)O6 octahedra,  a faceface with one Mg(1)O6 octahedra, and  a faceface with one W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 34-54°. In the second Mn site, Mn(2) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. Fe(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form distorted FeO6 octahedra that share corners with three equivalent Mg(1)O6 octahedra, corners with six equivalent W(1)O6 octahedra, edges with three equivalent Mn(1)O6 octahedra, and  a faceface with one Mg(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 33-54°. There are six inequivalent O sites. In the first O site, O(1) is bonded to one Mg(1), one W(1), one Mn(1), one Mn(2), and one Fe(1) atom to form a mixture of distorted corner and edge-sharing OMgMn2FeW trigonal bipyramids. In the second O site, O(2) is bonded in a 5-coordinate geometry to one Mg(1), one W(1), one Mn(1), one Mn(2), and one Fe(1) atom. In the third O site, O(3) is bonded in a 5-coordinate geometry to one Mg(1), one W(1), one Mn(1), one Mn(2), and one Fe(1) atom. In the fourth O site, O(4) is bonded to one Mg(1), one W(1), one Mn(1), one Mn(2), and one Fe(1) atom to form a mixture of distorted corner and edge-sharing OMgMn2FeW trigonal bipyramids. In the fifth O site, O(5) is bonded to one Mg(1), one W(1), one Mn(1), one Mn(2), and one Fe(1) atom to form a mixture of distorted corner and edge-sharing OMgMn2FeW trigonal bipyramids. In the sixth O site, O(6) is bonded in a 5-coordinate geometry to one Mg(1), one W(1), one Mn(1), one Mn(2), and one Fe(1) atom. is represented by the CIF file [CIF]
data_MgMn2FeWO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.393
_cell_length_b   5.378
_cell_length_c   6.106
_cell_angle_alpha   61.943
_cell_angle_beta   64.893
_cell_angle_gamma   59.549
_symmetry_Int_Tables_number   1
_cell_volume   130.642
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.646  0.646  0.063  1.0
  Mn  Mn1  1  0.813  0.814  0.557  1.0
  Mn  Mn2  1  0.278  0.273  0.164  1.0
  Fe  Fe3  1  0.467  0.480  0.590  1.0
  W  W4  1  0.003  0.993  0.006  1.0
  O  O5  1  0.249  0.849  0.289  1.0
  O  O6  1  0.877  0.621  0.272  1.0
  O  O7  1  0.633  0.220  0.262  1.0
  O  O8  1  0.049  0.405  0.833  1.0
  O  O9  1  0.392  0.731  0.821  1.0
  O  O10  1  0.708  0.068  0.810  1.0
[/CIF]
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