The compound described by RhPS crystallizes in the cubic P2_13 space group. Rh(1) is bonded to three equivalent P(1) and three equivalent S(1) atoms to form RhP3S3 octahedra that share corners with twelve equivalent Rh(1)P3S3 octahedra, corners with three equivalent P(1)Rh3S tetrahedra, and corners with three equivalent S(1)PRh3 tetrahedra. The corner-sharing octahedral tilt angles range from 65-66°. P(1) is bonded to three equivalent Rh(1) and one S(1) atom to form distorted PRh3S tetrahedra that share corners with three equivalent Rh(1)P3S3 octahedra, corners with six equivalent P(1)Rh3S tetrahedra, and corners with nine equivalent S(1)PRh3 tetrahedra. The corner-sharing octahedral tilt angles are 76°. S(1) is bonded to three equivalent Rh(1) and one P(1) atom to form SPRh3 tetrahedra that share corners with three equivalent Rh(1)P3S3 octahedra, corners with six equivalent S(1)PRh3 tetrahedra, and corners with nine equivalent P(1)Rh3S tetrahedra. The corner-sharing octahedral tilt angles are 77°. is represented by the CIF card [CIF]
data_PRhS
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.663
_cell_length_b   5.663
_cell_length_c   5.663
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   181.590
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.110  0.890  0.390  1.0
  P  P1  1  0.890  0.390  0.110  1.0
  P  P2  1  0.390  0.110  0.890  1.0
  P  P3  1  0.610  0.610  0.610  1.0
  Rh  Rh4  1  0.506  0.494  0.994  1.0
  Rh  Rh5  1  0.494  0.994  0.506  1.0
  Rh  Rh6  1  0.994  0.506  0.494  1.0
  Rh  Rh7  1  0.006  0.006  0.006  1.0
  S  S8  1  0.890  0.110  0.610  1.0
  S  S9  1  0.110  0.610  0.890  1.0
  S  S10  1  0.610  0.890  0.110  1.0
  S  S11  1  0.390  0.390  0.390  1.0
[/CIF]
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The compound described by RhPS crystallizes in the cubic P2_13 space group. Rh(1) is bonded to three equivalent P(1) and three equivalent S(1) atoms to form RhP3S3 octahedra that share corners with twelve equivalent Rh(1)P3S3 octahedra, corners with three equivalent P(1)Rh3S tetrahedra, and corners with three equivalent S(1)PRh3 tetrahedra. The corner-sharing octahedral tilt angles range from 65-66°. P(1) is bonded to three equivalent Rh(1) and one S(1) atom to form distorted PRh3S tetrahedra that share corners with three equivalent Rh(1)P3S3 octahedra, corners with six equivalent P(1)Rh3S tetrahedra, and corners with nine equivalent S(1)PRh3 tetrahedra. The corner-sharing octahedral tilt angles are 76°. S(1) is bonded to three equivalent Rh(1) and one P(1) atom to form SPRh3 tetrahedra that share corners with three equivalent Rh(1)P3S3 octahedra, corners with six equivalent S(1)PRh3 tetrahedra, and corners with nine equivalent P(1)Rh3S tetrahedra. The corner-sharing octahedral tilt angles are 77°. is represented by the CIF card [CIF]
data_PRhS
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.663
_cell_length_b   5.663
_cell_length_c   5.663
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   181.590
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.110  0.890  0.390  1.0
  P  P1  1  0.890  0.390  0.110  1.0
  P  P2  1  0.390  0.110  0.890  1.0
  P  P3  1  0.610  0.610  0.610  1.0
  Rh  Rh4  1  0.506  0.494  0.994  1.0
  Rh  Rh5  1  0.494  0.994  0.506  1.0
  Rh  Rh6  1  0.994  0.506  0.494  1.0
  Rh  Rh7  1  0.006  0.006  0.006  1.0
  S  S8  1  0.890  0.110  0.610  1.0
  S  S9  1  0.110  0.610  0.890  1.0
  S  S10  1  0.610  0.890  0.110  1.0
  S  S11  1  0.390  0.390  0.390  1.0
[/CIF]
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