The material structure described by RbOsN2 crystallizes in the orthorhombic Pbcm space group. There are two inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 8-coordinate geometry to two equivalent N(1), two equivalent N(3), and four equivalent N(2) atoms. In the second Rb site, Rb(2) is bonded in a 7-coordinate geometry to one N(1), two equivalent N(3), and four equivalent N(2) atoms. There are two inequivalent Os sites. In the first Os site, Os(1) is bonded to two equivalent N(2) and two equivalent N(3) atoms to form corner-sharing OsN4 tetrahedra. In the second Os site, Os(2) is bonded to two equivalent N(1) and two equivalent N(2) atoms to form corner-sharing OsN4 tetrahedra. There are three inequivalent N sites. In the first N site, N(1) is bonded in a 5-coordinate geometry to one Rb(2), two equivalent Rb(1), and two equivalent Os(2) atoms. In the second N site, N(2) is bonded in a distorted linear geometry to two equivalent Rb(1), two equivalent Rb(2), one Os(1), and one Os(2) atom. In the third N site, N(3) is bonded in a distorted linear geometry to two equivalent Rb(1), two equivalent Rb(2), and two equivalent Os(1) atoms. is represented by the CIF card [CIF]
data_RbOsN2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.307
_cell_length_b   7.824
_cell_length_c   12.399
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   611.837
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.250  0.131  0.000  1.0
  Rb  Rb1  1  0.750  0.869  0.500  1.0
  Rb  Rb2  1  0.750  0.869  0.000  1.0
  Rb  Rb3  1  0.250  0.131  0.500  1.0
  Rb  Rb4  1  0.409  0.384  0.750  1.0
  Rb  Rb5  1  0.909  0.616  0.750  1.0
  Rb  Rb6  1  0.591  0.616  0.250  1.0
  Rb  Rb7  1  0.091  0.384  0.250  1.0
  Os  Os8  1  0.750  0.369  0.000  1.0
  Os  Os9  1  0.250  0.631  0.500  1.0
  Os  Os10  1  0.250  0.631  0.000  1.0
  Os  Os11  1  0.750  0.369  0.500  1.0
  Os  Os12  1  0.852  0.116  0.750  1.0
  Os  Os13  1  0.352  0.884  0.750  1.0
  Os  Os14  1  0.148  0.884  0.250  1.0
  Os  Os15  1  0.648  0.116  0.250  1.0
  N  N16  1  0.143  0.056  0.750  1.0
  N  N17  1  0.643  0.944  0.750  1.0
  N  N18  1  0.857  0.944  0.250  1.0
  N  N19  1  0.357  0.056  0.250  1.0
  N  N20  1  0.794  0.237  0.623  1.0
  N  N21  1  0.294  0.763  0.877  1.0
  N  N22  1  0.206  0.763  0.123  1.0
  N  N23  1  0.706  0.237  0.377  1.0
  N  N24  1  0.206  0.763  0.377  1.0
  N  N25  1  0.706  0.237  0.123  1.0
  N  N26  1  0.794  0.237  0.877  1.0
  N  N27  1  0.294  0.763  0.623  1.0
  N  N28  1  0.500  0.500  0.500  1.0
  N  N29  1  0.000  0.500  0.000  1.0
  N  N30  1  0.500  0.500  0.000  1.0
  N  N31  1  0.000  0.500  0.500  1.0
[/CIF]
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The material structure described by RbOsN2 crystallizes in the orthorhombic Pbcm space group. There are two inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 8-coordinate geometry to two equivalent N(1), two equivalent N(3), and four equivalent N(2) atoms. In the second Rb site, Rb(2) is bonded in a 7-coordinate geometry to one N(1), two equivalent N(3), and four equivalent N(2) atoms. There are two inequivalent Os sites. In the first Os site, Os(1) is bonded to two equivalent N(2) and two equivalent N(3) atoms to form corner-sharing OsN4 tetrahedra. In the second Os site, Os(2) is bonded to two equivalent N(1) and two equivalent N(2) atoms to form corner-sharing OsN4 tetrahedra. There are three inequivalent N sites. In the first N site, N(1) is bonded in a 5-coordinate geometry to one Rb(2), two equivalent Rb(1), and two equivalent Os(2) atoms. In the second N site, N(2) is bonded in a distorted linear geometry to two equivalent Rb(1), two equivalent Rb(2), one Os(1), and one Os(2) atom. In the third N site, N(3) is bonded in a distorted linear geometry to two equivalent Rb(1), two equivalent Rb(2), and two equivalent Os(1) atoms. is represented by the CIF card [CIF]
data_RbOsN2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.307
_cell_length_b   7.824
_cell_length_c   12.399
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   611.837
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.250  0.131  0.000  1.0
  Rb  Rb1  1  0.750  0.869  0.500  1.0
  Rb  Rb2  1  0.750  0.869  0.000  1.0
  Rb  Rb3  1  0.250  0.131  0.500  1.0
  Rb  Rb4  1  0.409  0.384  0.750  1.0
  Rb  Rb5  1  0.909  0.616  0.750  1.0
  Rb  Rb6  1  0.591  0.616  0.250  1.0
  Rb  Rb7  1  0.091  0.384  0.250  1.0
  Os  Os8  1  0.750  0.369  0.000  1.0
  Os  Os9  1  0.250  0.631  0.500  1.0
  Os  Os10  1  0.250  0.631  0.000  1.0
  Os  Os11  1  0.750  0.369  0.500  1.0
  Os  Os12  1  0.852  0.116  0.750  1.0
  Os  Os13  1  0.352  0.884  0.750  1.0
  Os  Os14  1  0.148  0.884  0.250  1.0
  Os  Os15  1  0.648  0.116  0.250  1.0
  N  N16  1  0.143  0.056  0.750  1.0
  N  N17  1  0.643  0.944  0.750  1.0
  N  N18  1  0.857  0.944  0.250  1.0
  N  N19  1  0.357  0.056  0.250  1.0
  N  N20  1  0.794  0.237  0.623  1.0
  N  N21  1  0.294  0.763  0.877  1.0
  N  N22  1  0.206  0.763  0.123  1.0
  N  N23  1  0.706  0.237  0.377  1.0
  N  N24  1  0.206  0.763  0.377  1.0
  N  N25  1  0.706  0.237  0.123  1.0
  N  N26  1  0.794  0.237  0.877  1.0
  N  N27  1  0.294  0.763  0.623  1.0
  N  N28  1  0.500  0.500  0.500  1.0
  N  N29  1  0.000  0.500  0.000  1.0
  N  N30  1  0.500  0.500  0.000  1.0
  N  N31  1  0.000  0.500  0.500  1.0
[/CIF]
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