The material structure described by Cr3Mn3(TeO8)2 is Rutile-derived structured and crystallizes in the monoclinic Cm space group. There are two inequivalent Cr sites. In the first Cr site, Cr(1) is bonded to one O(11), one O(2), one O(3), one O(4), one O(6), and one O(7) atom to form CrO6 octahedra that share corners with two equivalent Te(2)O6 octahedra,  an edgeedge with one Te(1)O6 octahedra, edges with two equivalent Cr(1)O6 octahedra, and edges with two equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles are 50°. In the second Cr site, Cr(2) is bonded to one O(10), one O(5), two equivalent O(1), and two equivalent O(9) atoms to form CrO6 octahedra that share corners with two equivalent Te(1)O6 octahedra,  an edgeedge with one Te(2)O6 octahedra, and edges with four equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles are 49°. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(3), one O(4), two equivalent O(11), and two equivalent O(6) atoms to form MnO6 octahedra that share corners with two equivalent Te(2)O6 octahedra,  an edgeedge with one Te(1)O6 octahedra, and edges with four equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles are 49°. In the second Mn site, Mn(2) is bonded to one O(1), one O(10), one O(12), one O(5), one O(8), and one O(9) atom to form MnO6 octahedra that share corners with two equivalent Te(1)O6 octahedra,  an edgeedge with one Te(2)O6 octahedra, edges with two equivalent Cr(2)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-51°. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(2), one O(8), two equivalent O(1), and two equivalent O(6) atoms to form TeO6 octahedra that share corners with two equivalent Cr(2)O6 octahedra, corners with four equivalent Mn(2)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra, and edges with two equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-51°. In the second Te site, Te(2) is bonded to one O(12), one O(7), two equivalent O(11), and two equivalent O(9) atoms to form TeO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra, corners with four equivalent Cr(1)O6 octahedra,  an edgeedge with one Cr(2)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-50°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Cr(2), one Mn(2), and one Te(1) atom. In the second O site, O(2) is bonded in a distorted T-shaped geometry to two equivalent Cr(1) and one Te(1) atom. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Cr(1) and one Mn(1) atom. In the fourth O site, O(4) is bonded in a trigonal non-coplanar geometry to two equivalent Cr(1) and one Mn(1) atom. In the fifth O site, O(5) is bonded in a trigonal non-coplanar geometry to one Cr(2) and two equivalent Mn(2) atoms. In the sixth O site, O(6) is bonded in a distorted T-shaped geometry to one Cr(1), one Mn(1), and one Te(1) atom. In the seventh O site, O(7) is bonded in a distorted trigonal planar geometry to two equivalent Cr(1) and one Te(2) atom. In the eighth O site, O(8) is bonded in a distorted trigonal planar geometry to two equivalent Mn(2) and one Te(1) atom. In the ninth O site, O(9) is bonded in a distorted T-shaped geometry to one Cr(2), one Mn(2), and one Te(2) atom. In the tenth O site, O(10) is bonded in a distorted trigonal non-coplanar geometry to one Cr(2) and two equivalent Mn(2) atoms. In the eleventh O site, O(11) is bonded in a distorted trigonal planar geometry to one Cr(1), one Mn(1), and one Te(2) atom. In the twelfth O site, O(12) is bonded in a distorted T-shaped geometry to two equivalent Mn(2) and one Te(2) atom. is represented by the CIF card [CIF]
data_Mn3Cr3(TeO8)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.956
_cell_length_b   5.956
_cell_length_c   9.216
_cell_angle_alpha   89.765
_cell_angle_beta   89.765
_cell_angle_gamma   60.128
_symmetry_Int_Tables_number   1
_cell_volume   283.473
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.831  0.831  0.211  1.0
  Mn  Mn1  1  0.665  0.168  0.710  1.0
  Mn  Mn2  1  0.168  0.665  0.710  1.0
  Cr  Cr3  1  0.831  0.338  0.211  1.0
  Cr  Cr4  1  0.338  0.831  0.211  1.0
  Cr  Cr5  1  0.170  0.170  0.711  1.0
  Te  Te6  1  0.665  0.665  0.487  1.0
  Te  Te7  1  0.332  0.332  0.989  1.0
  O  O8  1  0.829  0.344  0.596  1.0
  O  O9  1  0.521  0.521  0.346  1.0
  O  O10  1  0.672  0.672  0.109  1.0
  O  O11  1  0.996  0.996  0.303  1.0
  O  O12  1  0.996  0.996  0.802  1.0
  O  O13  1  0.344  0.829  0.596  1.0
  O  O14  1  0.958  0.525  0.343  1.0
  O  O15  1  0.525  0.958  0.343  1.0
  O  O16  1  0.171  0.171  0.096  1.0
  O  O17  1  0.824  0.824  0.598  1.0
  O  O18  1  0.478  0.043  0.845  1.0
  O  O19  1  0.043  0.478  0.845  1.0
  O  O20  1  0.340  0.340  0.612  1.0
  O  O21  1  0.655  0.170  0.098  1.0
  O  O22  1  0.480  0.480  0.849  1.0
  O  O23  1  0.170  0.655  0.098  1.0
[/CIF]
.
The material structure described by Cr3Mn3(TeO8)2 is Rutile-derived structured and crystallizes in the monoclinic Cm space group. There are two inequivalent Cr sites. In the first Cr site, Cr(1) is bonded to one O(11), one O(2), one O(3), one O(4), one O(6), and one O(7) atom to form CrO6 octahedra that share corners with two equivalent Te(2)O6 octahedra,  an edgeedge with one Te(1)O6 octahedra, edges with two equivalent Cr(1)O6 octahedra, and edges with two equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles are 50°. In the second Cr site, Cr(2) is bonded to one O(10), one O(5), two equivalent O(1), and two equivalent O(9) atoms to form CrO6 octahedra that share corners with two equivalent Te(1)O6 octahedra,  an edgeedge with one Te(2)O6 octahedra, and edges with four equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles are 49°. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(3), one O(4), two equivalent O(11), and two equivalent O(6) atoms to form MnO6 octahedra that share corners with two equivalent Te(2)O6 octahedra,  an edgeedge with one Te(1)O6 octahedra, and edges with four equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles are 49°. In the second Mn site, Mn(2) is bonded to one O(1), one O(10), one O(12), one O(5), one O(8), and one O(9) atom to form MnO6 octahedra that share corners with two equivalent Te(1)O6 octahedra,  an edgeedge with one Te(2)O6 octahedra, edges with two equivalent Cr(2)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-51°. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(2), one O(8), two equivalent O(1), and two equivalent O(6) atoms to form TeO6 octahedra that share corners with two equivalent Cr(2)O6 octahedra, corners with four equivalent Mn(2)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra, and edges with two equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-51°. In the second Te site, Te(2) is bonded to one O(12), one O(7), two equivalent O(11), and two equivalent O(9) atoms to form TeO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra, corners with four equivalent Cr(1)O6 octahedra,  an edgeedge with one Cr(2)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-50°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Cr(2), one Mn(2), and one Te(1) atom. In the second O site, O(2) is bonded in a distorted T-shaped geometry to two equivalent Cr(1) and one Te(1) atom. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Cr(1) and one Mn(1) atom. In the fourth O site, O(4) is bonded in a trigonal non-coplanar geometry to two equivalent Cr(1) and one Mn(1) atom. In the fifth O site, O(5) is bonded in a trigonal non-coplanar geometry to one Cr(2) and two equivalent Mn(2) atoms. In the sixth O site, O(6) is bonded in a distorted T-shaped geometry to one Cr(1), one Mn(1), and one Te(1) atom. In the seventh O site, O(7) is bonded in a distorted trigonal planar geometry to two equivalent Cr(1) and one Te(2) atom. In the eighth O site, O(8) is bonded in a distorted trigonal planar geometry to two equivalent Mn(2) and one Te(1) atom. In the ninth O site, O(9) is bonded in a distorted T-shaped geometry to one Cr(2), one Mn(2), and one Te(2) atom. In the tenth O site, O(10) is bonded in a distorted trigonal non-coplanar geometry to one Cr(2) and two equivalent Mn(2) atoms. In the eleventh O site, O(11) is bonded in a distorted trigonal planar geometry to one Cr(1), one Mn(1), and one Te(2) atom. In the twelfth O site, O(12) is bonded in a distorted T-shaped geometry to two equivalent Mn(2) and one Te(2) atom. is represented by the CIF card [CIF]
data_Mn3Cr3(TeO8)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.956
_cell_length_b   5.956
_cell_length_c   9.216
_cell_angle_alpha   89.765
_cell_angle_beta   89.765
_cell_angle_gamma   60.128
_symmetry_Int_Tables_number   1
_cell_volume   283.473
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.831  0.831  0.211  1.0
  Mn  Mn1  1  0.665  0.168  0.710  1.0
  Mn  Mn2  1  0.168  0.665  0.710  1.0
  Cr  Cr3  1  0.831  0.338  0.211  1.0
  Cr  Cr4  1  0.338  0.831  0.211  1.0
  Cr  Cr5  1  0.170  0.170  0.711  1.0
  Te  Te6  1  0.665  0.665  0.487  1.0
  Te  Te7  1  0.332  0.332  0.989  1.0
  O  O8  1  0.829  0.344  0.596  1.0
  O  O9  1  0.521  0.521  0.346  1.0
  O  O10  1  0.672  0.672  0.109  1.0
  O  O11  1  0.996  0.996  0.303  1.0
  O  O12  1  0.996  0.996  0.802  1.0
  O  O13  1  0.344  0.829  0.596  1.0
  O  O14  1  0.958  0.525  0.343  1.0
  O  O15  1  0.525  0.958  0.343  1.0
  O  O16  1  0.171  0.171  0.096  1.0
  O  O17  1  0.824  0.824  0.598  1.0
  O  O18  1  0.478  0.043  0.845  1.0
  O  O19  1  0.043  0.478  0.845  1.0
  O  O20  1  0.340  0.340  0.612  1.0
  O  O21  1  0.655  0.170  0.098  1.0
  O  O22  1  0.480  0.480  0.849  1.0
  O  O23  1  0.170  0.655  0.098  1.0
[/CIF]
.