The structure described by LiLa8Cu3O16 is (La,Ba)CuO4-derived structured and crystallizes in the triclinic P1 space group. Li(1) is bonded to one O(10), one O(3), one O(4), one O(5), one O(8), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Cu(2)O6 octahedra,  a cornercorner with one Cu(3)O6 octahedra, and corners with two equivalent Cu(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-3°. There are eight inequivalent La sites. In the first La site, La(1) is bonded in a 9-coordinate geometry to one O(1), one O(12), one O(13), one O(14), one O(15), one O(3), one O(4), one O(5), and one O(8) atom. In the second La site, La(2) is bonded in a 9-coordinate geometry to one O(11), one O(13), one O(16), one O(2), one O(4), one O(5), one O(6), one O(7), and one O(9) atom. In the third La site, La(3) is bonded in a 9-coordinate geometry to one O(1), one O(10), one O(11), one O(13), one O(14), one O(15), one O(2), one O(3), and one O(8) atom. In the fourth La site, La(4) is bonded in a 9-coordinate geometry to one O(10), one O(12), one O(13), one O(14), one O(15), one O(16), one O(6), one O(8), and one O(9) atom. In the fifth La site, La(5) is bonded in a 9-coordinate geometry to one O(11), one O(13), one O(14), one O(15), one O(16), one O(4), one O(7), one O(8), and one O(9) atom. In the sixth La site, La(6) is bonded in a 9-coordinate geometry to one O(10), one O(12), one O(16), one O(2), one O(5), one O(6), one O(7), one O(8), and one O(9) atom. In the seventh La site, La(7) is bonded in a 9-coordinate geometry to one O(1), one O(12), one O(15), one O(2), one O(3), one O(4), one O(5), one O(6), and one O(7) atom. In the eighth La site, La(8) is bonded in a 9-coordinate geometry to one O(1), one O(10), one O(11), one O(14), one O(2), one O(3), one O(5), one O(6), and one O(7) atom. There are three inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to one O(1), one O(10), one O(13), one O(16), one O(2), and one O(4) atom to form CuO6 octahedra that share  a cornercorner with one Cu(2)O6 octahedra,  a cornercorner with one Cu(3)O6 octahedra, and corners with two equivalent Li(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-3°. In the second Cu site, Cu(2) is bonded to one O(11), one O(12), one O(14), one O(16), one O(3), and one O(6) atom to form CuO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Cu(1)O6 octahedra, and corners with two equivalent Cu(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-2°. In the third Cu site, Cu(3) is bonded to one O(1), one O(11), one O(12), one O(15), one O(7), and one O(9) atom to form CuO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Cu(1)O6 octahedra, and corners with two equivalent Cu(2)O6 octahedra. The corner-sharing octahedral tilt angles are 1°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded to one La(1), one La(3), one La(7), one La(8), one Cu(1), and one Cu(3) atom to form distorted OLa4Cu2 octahedra that share  a cornercorner with one O(16)La4Cu2 octahedra,  a cornercorner with one O(9)LiLa4Cu octahedra, corners with two equivalent O(8)LiLa5 octahedra, edges with two equivalent O(3)LiLa4Cu octahedra,  a faceface with one O(11)La4Cu2 octahedra,  a faceface with one O(12)La4Cu2 octahedra,  a faceface with one O(10)LiLa4Cu octahedra, and  a faceface with one O(4)LiLa4Cu octahedra. The corner-sharing octahedral tilt angles range from 0-49°. In the second O site, O(2) is bonded in a 6-coordinate geometry to one La(2), one La(3), one La(6), one La(7), one La(8), and one Cu(1) atom. In the third O site, O(3) is bonded to one Li(1), one La(1), one La(3), one La(7), one La(8), and one Cu(2) atom to form distorted OLiLa4Cu octahedra that share  a cornercorner with one O(16)La4Cu2 octahedra,  a cornercorner with one O(9)LiLa4Cu octahedra, edges with two equivalent O(1)La4Cu2 octahedra,  a faceface with one O(11)La4Cu2 octahedra,  a faceface with one O(12)La4Cu2 octahedra,  a faceface with one O(10)LiLa4Cu octahedra,  a faceface with one O(4)LiLa4Cu octahedra, and  a faceface with one O(8)LiLa5 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the fourth O site, O(4) is bonded to one Li(1), one La(1), one La(2), one La(5), one La(7), and one Cu(1) atom to form distorted OLiLa4Cu octahedra that share corners with two equivalent O(10)LiLa4Cu octahedra,  an edgeedge with one O(11)La4Cu2 octahedra,  an edgeedge with one O(12)La4Cu2 octahedra,  a faceface with one O(1)La4Cu2 octahedra,  a faceface with one O(16)La4Cu2 octahedra,  a faceface with one O(3)LiLa4Cu octahedra,  a faceface with one O(9)LiLa4Cu octahedra, and  a faceface with one O(8)LiLa5 octahedra. The corner-sharing octahedra are not tilted. In the fifth O site, O(5) is bonded in a 6-coordinate geometry to one Li(1), one La(1), one La(2), one La(6), one La(7), and one La(8) atom. In the sixth O site, O(6) is bonded in a 6-coordinate geometry to one La(2), one La(4), one La(6), one La(7), one La(8), and one Cu(2) atom. In the seventh O site, O(7) is bonded in a 6-coordinate geometry to one La(2), one La(5), one La(6), one La(7), one La(8), and one Cu(3) atom. In the eighth O site, O(8) is bonded to one Li(1), one La(1), one La(3), one La(4), one La(5), and one La(6) atom to form distorted OLiLa5 octahedra that share  a cornercorner with one O(10)LiLa4Cu octahedra,  a cornercorner with one O(9)LiLa4Cu octahedra, corners with two equivalent O(1)La4Cu2 octahedra, corners with two equivalent O(11)La4Cu2 octahedra, corners with three equivalent O(12)La4Cu2 octahedra, corners with three equivalent O(16)La4Cu2 octahedra,  a faceface with one O(10)LiLa4Cu octahedra,  a faceface with one O(3)LiLa4Cu octahedra,  a faceface with one O(4)LiLa4Cu octahedra, and  a faceface with one O(9)LiLa4Cu octahedra. The corner-sharing octahedral tilt angles range from 45-50°. In the ninth O site, O(9) is bonded to one Li(1), one La(2), one La(4), one La(5), one La(6), and one Cu(3) atom to form distorted OLiLa4Cu octahedra that share  a cornercorner with one O(1)La4Cu2 octahedra,  a cornercorner with one O(3)LiLa4Cu octahedra,  a cornercorner with one O(8)LiLa5 octahedra, edges with two equivalent O(16)La4Cu2 octahedra,  a faceface with one O(11)La4Cu2 octahedra,  a faceface with one O(12)La4Cu2 octahedra,  a faceface with one O(10)LiLa4Cu octahedra,  a faceface with one O(4)LiLa4Cu octahedra, and  a faceface with one O(8)LiLa5 octahedra. The corner-sharing octahedral tilt angles range from 0-45°. In the tenth O site, O(10) is bonded to one Li(1), one La(3), one La(4), one La(6), one La(8), and one Cu(1) atom to form distorted OLiLa4Cu octahedra that share  a cornercorner with one O(8)LiLa5 octahedra, corners with two equivalent O(4)LiLa4Cu octahedra,  an edgeedge with one O(11)La4Cu2 octahedra,  an edgeedge with one O(12)La4Cu2 octahedra,  a faceface with one O(1)La4Cu2 octahedra,  a faceface with one O(16)La4Cu2 octahedra,  a faceface with one O(3)LiLa4Cu octahedra,  a faceface with one O(9)LiLa4Cu octahedra, and  a faceface with one O(8)LiLa5 octahedra. The corner-sharing octahedral tilt angles range from 0-47°. In the eleventh O site, O(11) is bonded to one La(2), one La(3), one La(5), one La(8), one Cu(2), and one Cu(3) atom to form distorted OLa4Cu2 octahedra that share corners with two equivalent O(12)La4Cu2 octahedra, corners with two equivalent O(8)LiLa5 octahedra,  an edgeedge with one O(10)LiLa4Cu octahedra,  an edgeedge with one O(4)LiLa4Cu octahedra,  a faceface with one O(1)La4Cu2 octahedra,  a faceface with one O(16)La4Cu2 octahedra,  a faceface with one O(3)LiLa4Cu octahedra, and  a faceface with one O(9)LiLa4Cu octahedra. The corner-sharing octahedral tilt angles range from 1-50°. In the twelfth O site, O(12) is bonded to one La(1), one La(4), one La(6), one La(7), one Cu(2), and one Cu(3) atom to form distorted OLa4Cu2 octahedra that share corners with two equivalent O(11)La4Cu2 octahedra, corners with three equivalent O(8)LiLa5 octahedra,  an edgeedge with one O(10)LiLa4Cu octahedra,  an edgeedge with one O(4)LiLa4Cu octahedra,  a faceface with one O(1)La4Cu2 octahedra,  a faceface with one O(16)La4Cu2 octahedra,  a faceface with one O(3)LiLa4Cu octahedra, and  a faceface with one O(9)LiLa4Cu octahedra. The corner-sharing octahedral tilt angles range from 1-50°. In the thirteenth O site, O(13) is bonded in a 6-coordinate geometry to one La(1), one La(2), one La(3), one La(4), one La(5), and one Cu(1) atom. In the fourteenth O site, O(14) is bonded in a 6-coordinate geometry to one La(1), one La(3), one La(4), one La(5), one La(8), and one Cu(2) atom. In the fifteenth O site, O(15) is bonded in a 6-coordinate geometry to one La(1), one La(3), one La(4), one La(5), one La(7), and one Cu(3) atom. In the sixteenth O site, O(16) is bonded to one La(2), one La(4), one La(5), one La(6), one Cu(1), and one Cu(2) atom to form distorted OLa4Cu2 octahedra that share  a cornercorner with one O(1)La4Cu2 octahedra,  a cornercorner with one O(3)LiLa4Cu octahedra, corners with three equivalent O(8)LiLa5 octahedra, edges with two equivalent O(9)LiLa4Cu octahedra,  a faceface with one O(11)La4Cu2 octahedra,  a faceface with one O(12)La4Cu2 octahedra,  a faceface with one O(10)LiLa4Cu octahedra, and  a faceface with one O(4)LiLa4Cu octahedra. The corner-sharing octahedral tilt angles range from 0-49°. is represented by the CIF card [CIF]
data_LiLa8Cu3O16
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.459
_cell_length_b   7.572
_cell_length_c   8.881
_cell_angle_alpha   102.353
_cell_angle_beta   118.487
_cell_angle_gamma   116.440
_symmetry_Int_Tables_number   1
_cell_volume   376.272
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.500  0.750  0.999  1.0
  La  La1  1  0.046  0.207  0.725  1.0
  La  La2  1  0.954  0.799  0.278  1.0
  La  La3  1  0.050  0.705  0.724  1.0
  La  La4  1  0.537  0.945  0.722  1.0
  La  La5  1  0.541  0.457  0.723  1.0
  La  La6  1  0.958  0.297  0.277  1.0
  La  La7  1  0.464  0.557  0.278  1.0
  La  La8  1  0.460  0.045  0.277  1.0
  Cu  Cu9  1  0.500  0.250  1.000  1.0
  Cu  Cu10  1  0.000  0.500  0.999  1.0
  Cu  Cu11  1  0.000  0.000  0.003  1.0
  O  O12  1  0.251  0.127  0.004  1.0
  O  O13  1  0.783  0.487  0.372  1.0
  O  O14  1  0.246  0.622  0.996  1.0
  O  O15  1  0.494  0.490  0.993  1.0
  O  O16  1  0.767  0.969  0.365  1.0
  O  O17  1  0.269  0.719  0.366  1.0
  O  O18  1  0.269  0.221  0.371  1.0
  O  O19  1  0.230  0.528  0.638  1.0
  O  O20  1  0.753  0.878  0.003  1.0
  O  O21  1  0.505  0.010  0.007  1.0
  O  O22  1  0.004  0.752  0.004  1.0
  O  O23  1  0.004  0.252  0.003  1.0
  O  O24  1  0.214  0.008  0.631  1.0
  O  O25  1  0.719  0.258  0.629  1.0
  O  O26  1  0.717  0.761  0.632  1.0
  O  O27  1  0.748  0.373  0.995  1.0
[/CIF]
.
The structure described by LiLa8Cu3O16 is (La,Ba)CuO4-derived structured and crystallizes in the triclinic P1 space group. Li(1) is bonded to one O(10), one O(3), one O(4), one O(5), one O(8), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Cu(2)O6 octahedra,  a cornercorner with one Cu(3)O6 octahedra, and corners with two equivalent Cu(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-3°. There are eight inequivalent La sites. In the first La site, La(1) is bonded in a 9-coordinate geometry to one O(1), one O(12), one O(13), one O(14), one O(15), one O(3), one O(4), one O(5), and one O(8) atom. In the second La site, La(2) is bonded in a 9-coordinate geometry to one O(11), one O(13), one O(16), one O(2), one O(4), one O(5), one O(6), one O(7), and one O(9) atom. In the third La site, La(3) is bonded in a 9-coordinate geometry to one O(1), one O(10), one O(11), one O(13), one O(14), one O(15), one O(2), one O(3), and one O(8) atom. In the fourth La site, La(4) is bonded in a 9-coordinate geometry to one O(10), one O(12), one O(13), one O(14), one O(15), one O(16), one O(6), one O(8), and one O(9) atom. In the fifth La site, La(5) is bonded in a 9-coordinate geometry to one O(11), one O(13), one O(14), one O(15), one O(16), one O(4), one O(7), one O(8), and one O(9) atom. In the sixth La site, La(6) is bonded in a 9-coordinate geometry to one O(10), one O(12), one O(16), one O(2), one O(5), one O(6), one O(7), one O(8), and one O(9) atom. In the seventh La site, La(7) is bonded in a 9-coordinate geometry to one O(1), one O(12), one O(15), one O(2), one O(3), one O(4), one O(5), one O(6), and one O(7) atom. In the eighth La site, La(8) is bonded in a 9-coordinate geometry to one O(1), one O(10), one O(11), one O(14), one O(2), one O(3), one O(5), one O(6), and one O(7) atom. There are three inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to one O(1), one O(10), one O(13), one O(16), one O(2), and one O(4) atom to form CuO6 octahedra that share  a cornercorner with one Cu(2)O6 octahedra,  a cornercorner with one Cu(3)O6 octahedra, and corners with two equivalent Li(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-3°. In the second Cu site, Cu(2) is bonded to one O(11), one O(12), one O(14), one O(16), one O(3), and one O(6) atom to form CuO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Cu(1)O6 octahedra, and corners with two equivalent Cu(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-2°. In the third Cu site, Cu(3) is bonded to one O(1), one O(11), one O(12), one O(15), one O(7), and one O(9) atom to form CuO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Cu(1)O6 octahedra, and corners with two equivalent Cu(2)O6 octahedra. The corner-sharing octahedral tilt angles are 1°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded to one La(1), one La(3), one La(7), one La(8), one Cu(1), and one Cu(3) atom to form distorted OLa4Cu2 octahedra that share  a cornercorner with one O(16)La4Cu2 octahedra,  a cornercorner with one O(9)LiLa4Cu octahedra, corners with two equivalent O(8)LiLa5 octahedra, edges with two equivalent O(3)LiLa4Cu octahedra,  a faceface with one O(11)La4Cu2 octahedra,  a faceface with one O(12)La4Cu2 octahedra,  a faceface with one O(10)LiLa4Cu octahedra, and  a faceface with one O(4)LiLa4Cu octahedra. The corner-sharing octahedral tilt angles range from 0-49°. In the second O site, O(2) is bonded in a 6-coordinate geometry to one La(2), one La(3), one La(6), one La(7), one La(8), and one Cu(1) atom. In the third O site, O(3) is bonded to one Li(1), one La(1), one La(3), one La(7), one La(8), and one Cu(2) atom to form distorted OLiLa4Cu octahedra that share  a cornercorner with one O(16)La4Cu2 octahedra,  a cornercorner with one O(9)LiLa4Cu octahedra, edges with two equivalent O(1)La4Cu2 octahedra,  a faceface with one O(11)La4Cu2 octahedra,  a faceface with one O(12)La4Cu2 octahedra,  a faceface with one O(10)LiLa4Cu octahedra,  a faceface with one O(4)LiLa4Cu octahedra, and  a faceface with one O(8)LiLa5 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the fourth O site, O(4) is bonded to one Li(1), one La(1), one La(2), one La(5), one La(7), and one Cu(1) atom to form distorted OLiLa4Cu octahedra that share corners with two equivalent O(10)LiLa4Cu octahedra,  an edgeedge with one O(11)La4Cu2 octahedra,  an edgeedge with one O(12)La4Cu2 octahedra,  a faceface with one O(1)La4Cu2 octahedra,  a faceface with one O(16)La4Cu2 octahedra,  a faceface with one O(3)LiLa4Cu octahedra,  a faceface with one O(9)LiLa4Cu octahedra, and  a faceface with one O(8)LiLa5 octahedra. The corner-sharing octahedra are not tilted. In the fifth O site, O(5) is bonded in a 6-coordinate geometry to one Li(1), one La(1), one La(2), one La(6), one La(7), and one La(8) atom. In the sixth O site, O(6) is bonded in a 6-coordinate geometry to one La(2), one La(4), one La(6), one La(7), one La(8), and one Cu(2) atom. In the seventh O site, O(7) is bonded in a 6-coordinate geometry to one La(2), one La(5), one La(6), one La(7), one La(8), and one Cu(3) atom. In the eighth O site, O(8) is bonded to one Li(1), one La(1), one La(3), one La(4), one La(5), and one La(6) atom to form distorted OLiLa5 octahedra that share  a cornercorner with one O(10)LiLa4Cu octahedra,  a cornercorner with one O(9)LiLa4Cu octahedra, corners with two equivalent O(1)La4Cu2 octahedra, corners with two equivalent O(11)La4Cu2 octahedra, corners with three equivalent O(12)La4Cu2 octahedra, corners with three equivalent O(16)La4Cu2 octahedra,  a faceface with one O(10)LiLa4Cu octahedra,  a faceface with one O(3)LiLa4Cu octahedra,  a faceface with one O(4)LiLa4Cu octahedra, and  a faceface with one O(9)LiLa4Cu octahedra. The corner-sharing octahedral tilt angles range from 45-50°. In the ninth O site, O(9) is bonded to one Li(1), one La(2), one La(4), one La(5), one La(6), and one Cu(3) atom to form distorted OLiLa4Cu octahedra that share  a cornercorner with one O(1)La4Cu2 octahedra,  a cornercorner with one O(3)LiLa4Cu octahedra,  a cornercorner with one O(8)LiLa5 octahedra, edges with two equivalent O(16)La4Cu2 octahedra,  a faceface with one O(11)La4Cu2 octahedra,  a faceface with one O(12)La4Cu2 octahedra,  a faceface with one O(10)LiLa4Cu octahedra,  a faceface with one O(4)LiLa4Cu octahedra, and  a faceface with one O(8)LiLa5 octahedra. The corner-sharing octahedral tilt angles range from 0-45°. In the tenth O site, O(10) is bonded to one Li(1), one La(3), one La(4), one La(6), one La(8), and one Cu(1) atom to form distorted OLiLa4Cu octahedra that share  a cornercorner with one O(8)LiLa5 octahedra, corners with two equivalent O(4)LiLa4Cu octahedra,  an edgeedge with one O(11)La4Cu2 octahedra,  an edgeedge with one O(12)La4Cu2 octahedra,  a faceface with one O(1)La4Cu2 octahedra,  a faceface with one O(16)La4Cu2 octahedra,  a faceface with one O(3)LiLa4Cu octahedra,  a faceface with one O(9)LiLa4Cu octahedra, and  a faceface with one O(8)LiLa5 octahedra. The corner-sharing octahedral tilt angles range from 0-47°. In the eleventh O site, O(11) is bonded to one La(2), one La(3), one La(5), one La(8), one Cu(2), and one Cu(3) atom to form distorted OLa4Cu2 octahedra that share corners with two equivalent O(12)La4Cu2 octahedra, corners with two equivalent O(8)LiLa5 octahedra,  an edgeedge with one O(10)LiLa4Cu octahedra,  an edgeedge with one O(4)LiLa4Cu octahedra,  a faceface with one O(1)La4Cu2 octahedra,  a faceface with one O(16)La4Cu2 octahedra,  a faceface with one O(3)LiLa4Cu octahedra, and  a faceface with one O(9)LiLa4Cu octahedra. The corner-sharing octahedral tilt angles range from 1-50°. In the twelfth O site, O(12) is bonded to one La(1), one La(4), one La(6), one La(7), one Cu(2), and one Cu(3) atom to form distorted OLa4Cu2 octahedra that share corners with two equivalent O(11)La4Cu2 octahedra, corners with three equivalent O(8)LiLa5 octahedra,  an edgeedge with one O(10)LiLa4Cu octahedra,  an edgeedge with one O(4)LiLa4Cu octahedra,  a faceface with one O(1)La4Cu2 octahedra,  a faceface with one O(16)La4Cu2 octahedra,  a faceface with one O(3)LiLa4Cu octahedra, and  a faceface with one O(9)LiLa4Cu octahedra. The corner-sharing octahedral tilt angles range from 1-50°. In the thirteenth O site, O(13) is bonded in a 6-coordinate geometry to one La(1), one La(2), one La(3), one La(4), one La(5), and one Cu(1) atom. In the fourteenth O site, O(14) is bonded in a 6-coordinate geometry to one La(1), one La(3), one La(4), one La(5), one La(8), and one Cu(2) atom. In the fifteenth O site, O(15) is bonded in a 6-coordinate geometry to one La(1), one La(3), one La(4), one La(5), one La(7), and one Cu(3) atom. In the sixteenth O site, O(16) is bonded to one La(2), one La(4), one La(5), one La(6), one Cu(1), and one Cu(2) atom to form distorted OLa4Cu2 octahedra that share  a cornercorner with one O(1)La4Cu2 octahedra,  a cornercorner with one O(3)LiLa4Cu octahedra, corners with three equivalent O(8)LiLa5 octahedra, edges with two equivalent O(9)LiLa4Cu octahedra,  a faceface with one O(11)La4Cu2 octahedra,  a faceface with one O(12)La4Cu2 octahedra,  a faceface with one O(10)LiLa4Cu octahedra, and  a faceface with one O(4)LiLa4Cu octahedra. The corner-sharing octahedral tilt angles range from 0-49°. is represented by the CIF card [CIF]
data_LiLa8Cu3O16
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.459
_cell_length_b   7.572
_cell_length_c   8.881
_cell_angle_alpha   102.353
_cell_angle_beta   118.487
_cell_angle_gamma   116.440
_symmetry_Int_Tables_number   1
_cell_volume   376.272
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.500  0.750  0.999  1.0
  La  La1  1  0.046  0.207  0.725  1.0
  La  La2  1  0.954  0.799  0.278  1.0
  La  La3  1  0.050  0.705  0.724  1.0
  La  La4  1  0.537  0.945  0.722  1.0
  La  La5  1  0.541  0.457  0.723  1.0
  La  La6  1  0.958  0.297  0.277  1.0
  La  La7  1  0.464  0.557  0.278  1.0
  La  La8  1  0.460  0.045  0.277  1.0
  Cu  Cu9  1  0.500  0.250  1.000  1.0
  Cu  Cu10  1  0.000  0.500  0.999  1.0
  Cu  Cu11  1  0.000  0.000  0.003  1.0
  O  O12  1  0.251  0.127  0.004  1.0
  O  O13  1  0.783  0.487  0.372  1.0
  O  O14  1  0.246  0.622  0.996  1.0
  O  O15  1  0.494  0.490  0.993  1.0
  O  O16  1  0.767  0.969  0.365  1.0
  O  O17  1  0.269  0.719  0.366  1.0
  O  O18  1  0.269  0.221  0.371  1.0
  O  O19  1  0.230  0.528  0.638  1.0
  O  O20  1  0.753  0.878  0.003  1.0
  O  O21  1  0.505  0.010  0.007  1.0
  O  O22  1  0.004  0.752  0.004  1.0
  O  O23  1  0.004  0.252  0.003  1.0
  O  O24  1  0.214  0.008  0.631  1.0
  O  O25  1  0.719  0.258  0.629  1.0
  O  O26  1  0.717  0.761  0.632  1.0
  O  O27  1  0.748  0.373  0.995  1.0
[/CIF]
.