The material structure described by Ce2Fe3Rh crystallizes in the trigonal R-3m space group. Ce(1) is bonded in a 12-coordinate geometry to nine equivalent Fe(1) and three equivalent Rh(1) atoms. Fe(1) is bonded to six equivalent Ce(1), four equivalent Fe(1), and two equivalent Rh(1) atoms to form FeCe6Fe4Rh2 cuboctahedra that share corners with four equivalent Rh(1)Ce6Fe6 cuboctahedra, corners with fourteen equivalent Fe(1)Ce6Fe4Rh2 cuboctahedra, edges with six equivalent Fe(1)Ce6Fe4Rh2 cuboctahedra, faces with six equivalent Rh(1)Ce6Fe6 cuboctahedra, and faces with twelve equivalent Fe(1)Ce6Fe4Rh2 cuboctahedra. Rh(1) is bonded to six equivalent Ce(1) and six equivalent Fe(1) atoms to form RhCe6Fe6 cuboctahedra that share corners with six equivalent Rh(1)Ce6Fe6 cuboctahedra, corners with twelve equivalent Fe(1)Ce6Fe4Rh2 cuboctahedra, edges with six equivalent Rh(1)Ce6Fe6 cuboctahedra, and faces with eighteen equivalent Fe(1)Ce6Fe4Rh2 cuboctahedra. is represented by the CIF card [CIF]
data_Ce2Fe3Rh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.280
_cell_length_b   5.280
_cell_length_c   5.280
_cell_angle_alpha   56.323
_cell_angle_beta   56.323
_cell_angle_gamma   56.323
_symmetry_Int_Tables_number   1
_cell_volume   95.213
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.121  0.121  0.121  1.0
  Ce  Ce1  1  0.879  0.879  0.879  1.0
  Fe  Fe2  1  0.500  0.000  0.500  1.0
  Fe  Fe3  1  0.000  0.500  0.500  1.0
  Fe  Fe4  1  0.500  0.500  0.000  1.0
  Rh  Rh5  1  0.500  0.500  0.500  1.0
[/CIF]
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The material structure described by Ce2Fe3Rh crystallizes in the trigonal R-3m space group. Ce(1) is bonded in a 12-coordinate geometry to nine equivalent Fe(1) and three equivalent Rh(1) atoms. Fe(1) is bonded to six equivalent Ce(1), four equivalent Fe(1), and two equivalent Rh(1) atoms to form FeCe6Fe4Rh2 cuboctahedra that share corners with four equivalent Rh(1)Ce6Fe6 cuboctahedra, corners with fourteen equivalent Fe(1)Ce6Fe4Rh2 cuboctahedra, edges with six equivalent Fe(1)Ce6Fe4Rh2 cuboctahedra, faces with six equivalent Rh(1)Ce6Fe6 cuboctahedra, and faces with twelve equivalent Fe(1)Ce6Fe4Rh2 cuboctahedra. Rh(1) is bonded to six equivalent Ce(1) and six equivalent Fe(1) atoms to form RhCe6Fe6 cuboctahedra that share corners with six equivalent Rh(1)Ce6Fe6 cuboctahedra, corners with twelve equivalent Fe(1)Ce6Fe4Rh2 cuboctahedra, edges with six equivalent Rh(1)Ce6Fe6 cuboctahedra, and faces with eighteen equivalent Fe(1)Ce6Fe4Rh2 cuboctahedra. is represented by the CIF card [CIF]
data_Ce2Fe3Rh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.280
_cell_length_b   5.280
_cell_length_c   5.280
_cell_angle_alpha   56.323
_cell_angle_beta   56.323
_cell_angle_gamma   56.323
_symmetry_Int_Tables_number   1
_cell_volume   95.213
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.121  0.121  0.121  1.0
  Ce  Ce1  1  0.879  0.879  0.879  1.0
  Fe  Fe2  1  0.500  0.000  0.500  1.0
  Fe  Fe3  1  0.000  0.500  0.500  1.0
  Fe  Fe4  1  0.500  0.500  0.000  1.0
  Rh  Rh5  1  0.500  0.500  0.500  1.0
[/CIF]
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