The structure described by Sc7V9O24 is Spinel-like structured and crystallizes in the triclinic P1 space group. There are seven inequivalent Sc sites. In the first Sc site, Sc(1) is bonded to one O(1), one O(11), one O(12), one O(2), one O(21), and one O(5) atom to form distorted ScO6 octahedra that share  a cornercorner with one Sc(2)O6 octahedra,  a cornercorner with one Sc(5)O6 octahedra,  a cornercorner with one Sc(6)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(7)O6 octahedra,  an edgeedge with one Sc(7)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(4)O6 octahedra,  an edgeedge with one V(6)O6 octahedra,  an edgeedge with one V(8)O6 octahedra, and  an edgeedge with one V(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-58°. In the second Sc site, Sc(2) is bonded to one O(10), one O(14), one O(2), one O(20), one O(6), and one O(7) atom to form distorted ScO6 octahedra that share  a cornercorner with one Sc(1)O6 octahedra,  a cornercorner with one Sc(4)O6 octahedra,  a cornercorner with one Sc(5)O6 octahedra,  a cornercorner with one Sc(6)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(9)O6 octahedra,  an edgeedge with one Sc(3)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(4)O6 octahedra,  an edgeedge with one V(5)O6 octahedra,  an edgeedge with one V(6)O6 octahedra, and  an edgeedge with one V(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-56°. In the third Sc site, Sc(3) is bonded to one O(13), one O(14), one O(20), one O(23), one O(24), and one O(3) atom to form distorted ScO6 octahedra that share  a cornercorner with one Sc(7)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra,  a cornercorner with one V(7)O6 octahedra,  a cornercorner with one V(8)O6 octahedra,  an edgeedge with one Sc(2)O6 octahedra,  an edgeedge with one Sc(5)O6 octahedra,  an edgeedge with one Sc(6)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(6)O6 octahedra, and  an edgeedge with one V(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-57°. In the fourth Sc site, Sc(4) is bonded to one O(15), one O(16), one O(19), one O(4), one O(7), and one O(8) atom to form distorted ScO6 octahedra that share  a cornercorner with one Sc(2)O6 octahedra,  a cornercorner with one Sc(5)O6 octahedra,  a cornercorner with one Sc(6)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(6)O6 octahedra,  a cornercorner with one V(9)O6 octahedra,  an edgeedge with one Sc(7)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(4)O6 octahedra,  an edgeedge with one V(7)O6 octahedra, and  an edgeedge with one V(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-57°. In the fifth Sc site, Sc(5) is bonded to one O(14), one O(18), one O(23), one O(4), one O(5), and one O(9) atom to form distorted ScO6 octahedra that share  a cornercorner with one Sc(1)O6 octahedra,  a cornercorner with one Sc(2)O6 octahedra,  a cornercorner with one Sc(4)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(6)O6 octahedra,  an edgeedge with one Sc(3)O6 octahedra,  an edgeedge with one Sc(7)O6 octahedra,  an edgeedge with one V(5)O6 octahedra,  an edgeedge with one V(7)O6 octahedra,  an edgeedge with one V(8)O6 octahedra, and  an edgeedge with one V(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-58°. In the sixth Sc site, Sc(6) is bonded to one O(10), one O(13), one O(17), one O(19), one O(21), and one O(24) atom to form distorted ScO6 octahedra that share  a cornercorner with one Sc(1)O6 octahedra,  a cornercorner with one Sc(2)O6 octahedra,  a cornercorner with one Sc(4)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(7)O6 octahedra,  a cornercorner with one V(9)O6 octahedra,  an edgeedge with one Sc(3)O6 octahedra,  an edgeedge with one Sc(7)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(5)O6 octahedra,  an edgeedge with one V(6)O6 octahedra, and  an edgeedge with one V(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-58°. In the seventh Sc site, Sc(7) is bonded to one O(11), one O(16), one O(18), one O(21), one O(24), and one O(4) atom to form distorted ScO6 octahedra that share  a cornercorner with one Sc(3)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra,  a cornercorner with one V(5)O6 octahedra,  a cornercorner with one V(6)O6 octahedra,  a cornercorner with one V(7)O6 octahedra,  an edgeedge with one Sc(1)O6 octahedra,  an edgeedge with one Sc(4)O6 octahedra,  an edgeedge with one Sc(5)O6 octahedra,  an edgeedge with one Sc(6)O6 octahedra,  an edgeedge with one V(1)O6 octahedra, and  an edgeedge with one V(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-59°. There are nine inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(10), one O(15), one O(22), one O(24), and one O(4) atom to form VO6 octahedra that share  a cornercorner with one Sc(1)O6 octahedra,  a cornercorner with one Sc(2)O6 octahedra,  a cornercorner with one Sc(3)O6 octahedra,  a cornercorner with one Sc(5)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(8)O6 octahedra,  an edgeedge with one Sc(4)O6 octahedra,  an edgeedge with one Sc(6)O6 octahedra,  an edgeedge with one Sc(7)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(4)O6 octahedra, and  an edgeedge with one V(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-58°. In the second V site, V(2) is bonded to one O(1), one O(13), one O(22), one O(3), one O(8), and one O(9) atom to form distorted VO6 octahedra that share  a cornercorner with one Sc(1)O6 octahedra,  a cornercorner with one Sc(4)O6 octahedra,  a cornercorner with one Sc(5)O6 octahedra,  a cornercorner with one Sc(6)O6 octahedra,  a cornercorner with one V(6)O6 octahedra,  a cornercorner with one V(7)O6 octahedra,  an edgeedge with one Sc(3)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(4)O6 octahedra,  an edgeedge with one V(5)O6 octahedra, and  an edgeedge with one V(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-55°. In the third V site, V(3) is bonded to one O(12), one O(16), one O(2), one O(20), one O(22), and one O(8) atom to form distorted VO6 octahedra that share  a cornercorner with one Sc(3)O6 octahedra,  a cornercorner with one Sc(7)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(5)O6 octahedra,  a cornercorner with one V(6)O6 octahedra,  a cornercorner with one V(8)O6 octahedra,  an edgeedge with one Sc(1)O6 octahedra,  an edgeedge with one Sc(2)O6 octahedra,  an edgeedge with one Sc(4)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(7)O6 octahedra, and  an edgeedge with one V(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-57°. In the fourth V site, V(4) is bonded to one O(1), one O(11), one O(15), one O(3), one O(6), and one O(7) atom to form distorted VO6 octahedra that share  a cornercorner with one Sc(3)O6 octahedra,  a cornercorner with one Sc(7)O6 octahedra,  a cornercorner with one V(5)O6 octahedra,  a cornercorner with one V(7)O6 octahedra,  a cornercorner with one V(8)O6 octahedra,  a cornercorner with one V(9)O6 octahedra,  an edgeedge with one Sc(1)O6 octahedra,  an edgeedge with one Sc(2)O6 octahedra,  an edgeedge with one Sc(4)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra, and  an edgeedge with one V(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-55°. In the fifth V site, V(5) is bonded to one O(10), one O(17), one O(18), one O(22), one O(6), and one O(9) atom to form distorted VO6 octahedra that share  a cornercorner with one Sc(7)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra,  a cornercorner with one V(6)O6 octahedra,  a cornercorner with one V(8)O6 octahedra,  a cornercorner with one V(9)O6 octahedra,  an edgeedge with one Sc(2)O6 octahedra,  an edgeedge with one Sc(5)O6 octahedra,  an edgeedge with one Sc(6)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra, and  an edgeedge with one V(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-55°. In the sixth V site, V(6) is bonded to one O(11), one O(13), one O(17), one O(20), one O(5), and one O(7) atom to form VO6 octahedra that share  a cornercorner with one Sc(4)O6 octahedra,  a cornercorner with one Sc(5)O6 octahedra,  a cornercorner with one Sc(7)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(5)O6 octahedra,  an edgeedge with one Sc(1)O6 octahedra,  an edgeedge with one Sc(2)O6 octahedra,  an edgeedge with one Sc(3)O6 octahedra,  an edgeedge with one Sc(6)O6 octahedra,  an edgeedge with one V(4)O6 octahedra, and  an edgeedge with one V(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-59°. In the seventh V site, V(7) is bonded to one O(16), one O(19), one O(2), one O(23), one O(6), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one Sc(1)O6 octahedra,  a cornercorner with one Sc(3)O6 octahedra,  a cornercorner with one Sc(6)O6 octahedra,  a cornercorner with one Sc(7)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(4)O6 octahedra,  an edgeedge with one Sc(2)O6 octahedra,  an edgeedge with one Sc(4)O6 octahedra,  an edgeedge with one Sc(5)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(5)O6 octahedra, and  an edgeedge with one V(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-58°. In the eighth V site, V(8) is bonded to one O(12), one O(15), one O(17), one O(19), one O(23), and one O(5) atom to form distorted VO6 octahedra that share  a cornercorner with one Sc(3)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra,  a cornercorner with one V(5)O6 octahedra,  a cornercorner with one V(9)O6 octahedra,  an edgeedge with one Sc(1)O6 octahedra,  an edgeedge with one Sc(4)O6 octahedra,  an edgeedge with one Sc(5)O6 octahedra,  an edgeedge with one Sc(6)O6 octahedra,  an edgeedge with one V(6)O6 octahedra, and  an edgeedge with one V(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-60°. In the ninth V site, V(9) is bonded to one O(12), one O(14), one O(18), one O(21), one O(3), and one O(8) atom to form VO6 octahedra that share  a cornercorner with one Sc(2)O6 octahedra,  a cornercorner with one Sc(4)O6 octahedra,  a cornercorner with one Sc(6)O6 octahedra,  a cornercorner with one V(4)O6 octahedra,  a cornercorner with one V(5)O6 octahedra,  a cornercorner with one V(8)O6 octahedra,  an edgeedge with one Sc(1)O6 octahedra,  an edgeedge with one Sc(3)O6 octahedra,  an edgeedge with one Sc(5)O6 octahedra,  an edgeedge with one Sc(7)O6 octahedra,  an edgeedge with one V(2)O6 octahedra, and  an edgeedge with one V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-60°. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded to one Sc(1), one V(1), one V(2), and one V(4) atom to form OScV3 trigonal pyramids that share  a cornercorner with one O(10)Sc2V2 tetrahedra,  a cornercorner with one O(9)ScV3 tetrahedra,  a cornercorner with one O(13)Sc2V2 trigonal pyramid,  a cornercorner with one O(2)Sc2V2 trigonal pyramid,  a cornercorner with one O(5)Sc2V2 trigonal pyramid,  a cornercorner with one O(7)Sc2V2 trigonal pyramid,  a cornercorner with one O(21)Sc3V trigonal pyramid,  a cornercorner with one O(24)Sc3V trigonal pyramid,  a cornercorner with one O(4)Sc3V trigonal pyramid,  a cornercorner with one O(12)ScV3 trigonal pyramid,  a cornercorner with one O(6)ScV3 trigonal pyramid,  a cornercorner with one O(8)ScV3 trigonal pyramid,  an edgeedge with one O(11)Sc2V2 trigonal pyramid,  an edgeedge with one O(15)ScV3 trigonal pyramid,  an edgeedge with one O(3)ScV3 trigonal pyramid, and  an edgeedge with one O(22)V4 trigonal pyramid. In the second O site, O(2) is bonded to one Sc(1), one Sc(2), one V(3), and one V(7) atom to form OSc2V2 trigonal pyramids that share  a cornercorner with one O(10)Sc2V2 tetrahedra,  a cornercorner with one O(9)ScV3 tetrahedra,  a cornercorner with one O(11)Sc2V2 trigonal pyramid,  a cornercorner with one O(19)Sc2V2 trigonal pyramid,  a cornercorner with one O(23)Sc2V2 trigonal pyramid,  a cornercorner with one O(5)Sc2V2 trigonal pyramid,  a cornercorner with one O(7)Sc2V2 trigonal pyramid,  a cornercorner with one O(14)Sc3V trigonal pyramid,  a cornercorner with one O(21)Sc3V trigonal pyramid,  a cornercorner with one O(1)ScV3 trigonal pyramid,  a cornercorner with one O(8)ScV3 trigonal pyramid,  a cornercorner with one O(22)V4 trigonal pyramid,  an edgeedge with one O(16)Sc2V2 trigonal pyramid,  an edgeedge with one O(20)Sc2V2 trigonal pyramid,  an edgeedge with one O(12)ScV3 trigonal pyramid, and  an edgeedge with one O(6)ScV3 trigonal pyramid. In the third O site, O(3) is bonded to one Sc(3), one V(2), one V(4), and one V(9) atom to form OScV3 trigonal pyramids that share  a cornercorner with one O(9)ScV3 tetrahedra,  a cornercorner with one O(11)Sc2V2 trigonal pyramid,  a cornercorner with one O(18)Sc2V2 trigonal pyramid,  a cornercorner with one O(20)Sc2V2 trigonal pyramid,  a cornercorner with one O(23)Sc2V2 trigonal pyramid,  a cornercorner with one O(7)Sc2V2 trigonal pyramid,  a cornercorner with one O(21)Sc3V trigonal pyramid,  a cornercorner with one O(24)Sc3V trigonal pyramid,  a cornercorner with one O(12)ScV3 trigonal pyramid,  a cornercorner with one O(15)ScV3 trigonal pyramid,  a cornercorner with one O(6)ScV3 trigonal pyramid,  a cornercorner with one O(22)V4 trigonal pyramid,  an edgeedge with one O(13)Sc2V2 trigonal pyramid,  an edgeedge with one O(14)Sc3V trigonal pyramid,  an edgeedge with one O(1)ScV3 trigonal pyramid, and  an edgeedge with one O(8)ScV3 trigonal pyramid. In the fourth O site, O(4) is bonded to one Sc(4), one Sc(5), one Sc(7), and one V(1) atom to form OSc3V trigonal pyramids that share  a cornercorner with one O(10)Sc2V2 tetrahedra,  a cornercorner with one O(9)ScV3 tetrahedra,  a cornercorner with one O(11)Sc2V2 trigonal pyramid,  a cornercorner with one O(19)Sc2V2 trigonal pyramid,  a cornercorner with one O(23)Sc2V2 trigonal pyramid,  a cornercorner with one O(5)Sc2V2 trigonal pyramid,  a cornercorner with one O(7)Sc2V2 trigonal pyramid,  a cornercorner with one O(14)Sc3V trigonal pyramid,  a cornercorner with one O(21)Sc3V trigonal pyramid,  a cornercorner with one O(1)ScV3 trigonal pyramid,  a cornercorner with one O(8)ScV3 trigonal pyramid,  a cornercorner with one O(22)V4 trigonal pyramid,  an edgeedge with one O(16)Sc2V2 trigonal pyramid,  an edgeedge with one O(18)Sc2V2 trigonal pyramid,  an edgeedge with one O(24)Sc3V trigonal pyramid, and  an edgeedge with one O(15)ScV3 trigonal pyramid. In the fifth O site, O(5) is bonded to one Sc(1), one Sc(5), one V(6), and one V(8) atom to form OSc2V2 trigonal pyramids that share  a cornercorner with one O(9)ScV3 tetrahedra,  a cornercorner with one O(13)Sc2V2 trigonal pyramid,  a cornercorner with one O(18)Sc2V2 trigonal pyramid,  a cornercorner with one O(19)Sc2V2 trigonal pyramid,  a cornercorner with one O(2)Sc2V2 trigonal pyramid,  a cornercorner with one O(20)Sc2V2 trigonal pyramid,  a cornercorner with one O(7)Sc2V2 trigonal pyramid,  a cornercorner with one O(14)Sc3V trigonal pyramid,  a cornercorner with one O(21)Sc3V trigonal pyramid,  a cornercorner with one O(4)Sc3V trigonal pyramid,  a cornercorner with one O(1)ScV3 trigonal pyramid,  a cornercorner with one O(15)ScV3 trigonal pyramid,  an edgeedge with one O(11)Sc2V2 trigonal pyramid,  an edgeedge with one O(23)Sc2V2 trigonal pyramid,  an edgeedge with one O(12)ScV3 trigonal pyramid, and  an edgeedge with one O(17)ScV3 trigonal pyramid. In the sixth O site, O(6) is bonded to one Sc(2), one V(4), one V(5), and one V(7) atom to form OScV3 trigonal pyramids that share  a cornercorner with one O(11)Sc2V2 trigonal pyramid,  a cornercorner with one O(16)Sc2V2 trigonal pyramid,  a cornercorner with one O(18)Sc2V2 trigonal pyramid,  a cornercorner with one O(19)Sc2V2 trigonal pyramid,  a cornercorner with one O(20)Sc2V2 trigonal pyramid,  a cornercorner with one O(23)Sc2V2 trigonal pyramid,  a cornercorner with one O(14)Sc3V trigonal pyramid,  a cornercorner with one O(1)ScV3 trigonal pyramid,  a cornercorner with one O(15)ScV3 trigonal pyramid,  a cornercorner with one O(17)ScV3 trigonal pyramid,  a cornercorner with one O(3)ScV3 trigonal pyramid,  a cornercorner with one O(22)V4 trigonal pyramid,  an edgeedge with one O(10)Sc2V2 tetrahedra,  an edgeedge with one O(9)ScV3 tetrahedra,  an edgeedge with one O(2)Sc2V2 trigonal pyramid, and  an edgeedge with one O(7)Sc2V2 trigonal pyramid. In the seventh O site, O(7) is bonded to one Sc(2), one Sc(4), one V(4), and one V(6) atom to form OSc2V2 trigonal pyramids that share  a cornercorner with one O(10)Sc2V2 tetrahedra,  a cornercorner with one O(13)Sc2V2 trigonal pyramid,  a cornercorner with one O(16)Sc2V2 trigonal pyramid,  a cornercorner with one O(19)Sc2V2 trigonal pyramid,  a cornercorner with one O(2)Sc2V2 trigonal pyramid,  a cornercorner with one O(5)Sc2V2 trigonal pyramid,  a cornercorner with one O(14)Sc3V trigonal pyramid,  a cornercorner with one O(4)Sc3V trigonal pyramid,  a cornercorner with one O(1)ScV3 trigonal pyramid,  a cornercorner with one O(17)ScV3 trigonal pyramid,  a cornercorner with one O(3)ScV3 trigonal pyramid,  a cornercorner with one O(8)ScV3 trigonal pyramid,  an edgeedge with one O(11)Sc2V2 trigonal pyramid,  an edgeedge with one O(20)Sc2V2 trigonal pyramid,  an edgeedge with one O(15)ScV3 trigonal pyramid, and  an edgeedge with one O(6)ScV3 trigonal pyramid. In the eighth O site, O(8) is bonded to one Sc(4), one V(2), one V(3), and one V(9) atom to form OScV3 trigonal pyramids that share  a cornercorner with one O(9)ScV3 tetrahedra,  a cornercorner with one O(13)Sc2V2 trigonal pyramid,  a cornercorner with one O(18)Sc2V2 trigonal pyramid,  a cornercorner with one O(19)Sc2V2 trigonal pyramid,  a cornercorner with one O(2)Sc2V2 trigonal pyramid,  a cornercorner with one O(20)Sc2V2 trigonal pyramid,  a cornercorner with one O(7)Sc2V2 trigonal pyramid,  a cornercorner with one O(14)Sc3V trigonal pyramid,  a cornercorner with one O(21)Sc3V trigonal pyramid,  a cornercorner with one O(4)Sc3V trigonal pyramid,  a cornercorner with one O(1)ScV3 trigonal pyramid,  a cornercorner with one O(15)ScV3 trigonal pyramid,  an edgeedge with one O(16)Sc2V2 trigonal pyramid,  an edgeedge with one O(12)ScV3 trigonal pyramid,  an edgeedge with one O(3)ScV3 trigonal pyramid, and  an edgeedge with one O(22)V4 trigonal pyramid. In the ninth O site, O(9) is bonded to one Sc(5), one V(2), one V(5), and one V(7) atom to form OScV3 tetrahedra that share  a cornercorner with one O(10)Sc2V2 tetrahedra,  a cornercorner with one O(13)Sc2V2 trigonal pyramid,  a cornercorner with one O(16)Sc2V2 trigonal pyramid,  a cornercorner with one O(19)Sc2V2 trigonal pyramid,  a cornercorner with one O(2)Sc2V2 trigonal pyramid,  a cornercorner with one O(5)Sc2V2 trigonal pyramid,  a cornercorner with one O(14)Sc3V trigonal pyramid,  a cornercorner with one O(4)Sc3V trigonal pyramid,  a cornercorner with one O(1)ScV3 trigonal pyramid,  a cornercorner with one O(17)ScV3 trigonal pyramid,  a cornercorner with one O(3)ScV3 trigonal pyramid,  a cornercorner with one O(8)ScV3 trigonal pyramid,  an edgeedge with one O(18)Sc2V2 trigonal pyramid,  an edgeedge with one O(23)Sc2V2 trigonal pyramid,  an edgeedge with one O(6)ScV3 trigonal pyramid, and  an edgeedge with one O(22)V4 trigonal pyramid. In the tenth O site, O(10) is bonded to one Sc(2), one Sc(6), one V(1), and one V(5) atom to form OSc2V2 tetrahedra that share  a cornercorner with one O(9)ScV3 tetrahedra,  a cornercorner with one O(13)Sc2V2 trigonal pyramid,  a cornercorner with one O(18)Sc2V2 trigonal pyramid,  a cornercorner with one O(19)Sc2V2 trigonal pyramid,  a cornercorner with one O(2)Sc2V2 trigonal pyramid,  a cornercorner with one O(20)Sc2V2 trigonal pyramid,  a cornercorner with one O(7)Sc2V2 trigonal pyramid,  a cornercorner with one O(14)Sc3V trigonal pyramid,  a cornercorner with one O(21)Sc3V trigonal pyramid,  a cornercorner with one O(4)Sc3V trigonal pyramid,  a cornercorner with one O(1)ScV3 trigonal pyramid,  a cornercorner with one O(15)ScV3 trigonal pyramid,  an edgeedge with one O(24)Sc3V trigonal pyramid,  an edgeedge with one O(17)ScV3 trigonal pyramid,  an edgeedge with one O(6)ScV3 trigonal pyramid, and  an edgeedge with one O(22)V4 trigonal pyramid. In the eleventh O site, O(11) is bonded to one Sc(1), one Sc(7), one V(4), and one V(6) atom to form OSc2V2 trigonal pyramids that share  a cornercorner with one O(13)Sc2V2 trigonal pyramid,  a cornercorner with one O(16)Sc2V2 trigonal pyramid,  a cornercorner with one O(18)Sc2V2 trigonal pyramid,  a cornercorner with one O(2)Sc2V2 trigonal pyramid,  a cornercorner with one O(20)Sc2V2 trigonal pyramid,  a cornercorner with one O(24)Sc3V trigonal pyramid,  a cornercorner with one O(4)Sc3V trigonal pyramid,  a cornercorner with one O(12)ScV3 trigonal pyramid,  a cornercorner with one O(15)ScV3 trigonal pyramid,  a cornercorner with one O(17)ScV3 trigonal pyramid,  a cornercorner with one O(3)ScV3 trigonal pyramid,  a cornercorner with one O(6)ScV3 trigonal pyramid,  an edgeedge with one O(5)Sc2V2 trigonal pyramid,  an edgeedge with one O(7)Sc2V2 trigonal pyramid,  an edgeedge with one O(21)Sc3V trigonal pyramid, and  an edgeedge with one O(1)ScV3 trigonal pyramid. In the twelfth O site, O(12) is bonded to one Sc(1), one V(3), one V(8), and one V(9) atom to form OScV3 trigonal pyramids that share  a cornercorner with one O(11)Sc2V2 trigonal pyramid,  a cornercorner with one O(16)Sc2V2 trigonal pyramid,  a cornercorner with one O(18)Sc2V2 trigonal pyramid,  a cornercorner with one O(19)Sc2V2 trigonal pyramid,  a cornercorner with one O(20)Sc2V2 trigonal pyramid,  a cornercorner with one O(23)Sc2V2 trigonal pyramid,  a cornercorner with one O(14)Sc3V trigonal pyramid,  a cornercorner with one O(1)ScV3 trigonal pyramid,  a cornercorner with one O(15)ScV3 trigonal pyramid,  a cornercorner with one O(17)ScV3 trigonal pyramid,  a cornercorner with one O(3)ScV3 trigonal pyramid,  a cornercorner with one O(22)V4 trigonal pyramid,  an edgeedge with one O(2)Sc2V2 trigonal pyramid,  an edgeedge with one O(5)Sc2V2 trigonal pyramid,  an edgeedge with one O(21)Sc3V trigonal pyramid, and  an edgeedge with one O(8)ScV3 trigonal pyramid. In the thirteenth O site, O(13) is bonded to one Sc(3), one Sc(6), one V(2), and one V(6) atom to form OSc2V2 trigonal pyramids that share  a cornercorner with one O(10)Sc2V2 tetrahedra,  a cornercorner with one O(9)ScV3 tetrahedra,  a cornercorner with one O(11)Sc2V2 trigonal pyramid,  a cornercorner with one O(19)Sc2V2 trigonal pyramid,  a cornercorner with one O(23)Sc2V2 trigonal pyramid,  a cornercorner with one O(5)Sc2V2 trigonal pyramid,  a cornercorner with one O(7)Sc2V2 trigonal pyramid,  a cornercorner with one O(14)Sc3V trigonal pyramid,  a cornercorner with one O(21)Sc3V trigonal pyramid,  a cornercorner with one O(1)ScV3 trigonal pyramid,  a cornercorner with one O(8)ScV3 trigonal pyramid,  a cornercorner with one O(22)V4 trigonal pyramid,  an edgeedge with one O(20)Sc2V2 trigonal pyramid,  an edgeedge with one O(24)Sc3V trigonal pyramid,  an edgeedge with one O(17)ScV3 trigonal pyramid, and  an edgeedge with one O(3)ScV3 trigonal pyramid. In the fourteenth O site, O(14) is bonded to one Sc(2), one Sc(3), one Sc(5), and one V(9) atom to form OSc3V trigonal pyramids that share  a cornercorner with one O(10)Sc2V2 tetrahedra,  a cornercorner with one O(9)ScV3 tetrahedra,  a cornercorner with one O(13)Sc2V2 trigonal pyramid,  a cornercorner with one O(2)Sc2V2 trigonal pyramid,  a cornercorner with one O(5)Sc2V2 trigonal pyramid,  a cornercorner with one O(7)Sc2V2 trigonal pyramid,  a cornercorner with one O(21)Sc3V trigonal pyramid,  a cornercorner with one O(24)Sc3V trigonal pyramid,  a cornercorner with one O(4)Sc3V trigonal pyramid,  a cornercorner with one O(12)ScV3 trigonal pyramid,  a cornercorner with one O(6)ScV3 trigonal pyramid,  a cornercorner with one O(8)ScV3 trigonal pyramid,  an edgeedge with one O(18)Sc2V2 trigonal pyramid,  an edgeedge with one O(20)Sc2V2 trigonal pyramid,  an edgeedge with one O(23)Sc2V2 trigonal pyramid, and  an edgeedge with one O(3)ScV3 trigonal pyramid. In the fifteenth O site, O(15) is bonded to one Sc(4), one V(1), one V(4), and one V(8) atom to form OScV3 trigonal pyramids that share  a cornercorner with one O(10)Sc2V2 tetrahedra,  a cornercorner with one O(11)Sc2V2 trigonal pyramid,  a cornercorner with one O(16)Sc2V2 trigonal pyramid,  a cornercorner with one O(23)Sc2V2 trigonal pyramid,  a cornercorner with one O(5)Sc2V2 trigonal pyramid,  a cornercorner with one O(24)Sc3V trigonal pyramid,  a cornercorner with one O(12)ScV3 trigonal pyramid,  a cornercorner with one O(17)ScV3 trigonal pyramid,  a cornercorner with one O(3)ScV3 trigonal pyramid,  a cornercorner with one O(6)ScV3 trigonal pyramid,  a cornercorner with one O(8)ScV3 trigonal pyramid,  a cornercorner with one O(22)V4 trigonal pyramid,  an edgeedge with one O(19)Sc2V2 trigonal pyramid,  an edgeedge with one O(7)Sc2V2 trigonal pyramid,  an edgeedge with one O(4)Sc3V trigonal pyramid, and  an edgeedge with one O(1)ScV3 trigonal pyramid. In the sixteenth O site, O(16) is bonded to one Sc(4), one Sc(7), one V(3), and one V(7) atom to form OSc2V2 trigonal pyramids that share  a cornercorner with one O(9)ScV3 tetrahedra,  a cornercorner with one O(11)Sc2V2 trigonal pyramid,  a cornercorner with one O(18)Sc2V2 trigonal pyramid,  a cornercorner with one O(20)Sc2V2 trigonal pyramid,  a cornercorner with one O(23)Sc2V2 trigonal pyramid,  a cornercorner with one O(7)Sc2V2 trigonal pyramid,  a cornercorner with one O(21)Sc3V trigonal pyramid,  a cornercorner with one O(24)Sc3V trigonal pyramid,  a cornercorner with one O(12)ScV3 trigonal pyramid,  a cornercorner with one O(15)ScV3 trigonal pyramid,  a cornercorner with one O(6)ScV3 trigonal pyramid,  a cornercorner with one O(22)V4 trigonal pyramid,  an edgeedge with one O(19)Sc2V2 trigonal pyramid,  an edgeedge with one O(2)Sc2V2 trigonal pyramid,  an edgeedge with one O(4)Sc3V trigonal pyramid, and  an edgeedge with one O(8)ScV3 trigonal pyramid. In the seventeenth O site, O(17) is bonded to one Sc(6), one V(5), one V(6), and one V(8) atom to form OScV3 trigonal pyramids that share  a cornercorner with one O(9)ScV3 tetrahedra,  a cornercorner with one O(11)Sc2V2 trigonal pyramid,  a cornercorner with one O(18)Sc2V2 trigonal pyramid,  a cornercorner with one O(20)Sc2V2 trigonal pyramid,  a cornercorner with one O(23)Sc2V2 trigonal pyramid,  a cornercorner with one O(7)Sc2V2 trigonal pyramid,  a cornercorner with one O(21)Sc3V trigonal pyramid,  a cornercorner with one O(24)Sc3V trigonal pyramid,  a cornercorner with one O(12)ScV3 trigonal pyramid,  a cornercorner with one O(15)ScV3 trigonal pyramid,  a cornercorner with one O(6)ScV3 trigonal pyramid,  a cornercorner with one O(22)V4 trigonal pyramid,  an edgeedge with one O(10)Sc2V2 tetrahedra,  an edgeedge with one O(13)Sc2V2 trigonal pyramid,  an edgeedge with one O(19)Sc2V2 trigonal pyramid, and  an edgeedge with one O(5)Sc2V2 trigonal pyramid. In the eighteenth O site, O(18) is bonded to one Sc(5), one Sc(7), one V(5), and one V(9) atom to form OSc2V2 trigonal pyramids that share  a cornercorner with one O(10)Sc2V2 tetrahedra,  a cornercorner with one O(11)Sc2V2 trigonal pyramid,  a cornercorner with one O(16)Sc2V2 trigonal pyramid,  a cornercorner with one O(23)Sc2V2 trigonal pyramid,  a cornercorner with one O(5)Sc2V2 trigonal pyramid,  a cornercorner with one O(24)Sc3V trigonal pyramid,  a cornercorner with one O(12)ScV3 trigonal pyramid,  a cornercorner with one O(17)ScV3 trigonal pyramid,  a cornercorner with one O(3)ScV3 trigonal pyramid,  a cornercorner with one O(6)ScV3 trigonal pyramid,  a cornercorner with one O(8)ScV3 trigonal pyramid,  a cornercorner with one O(22)V4 trigonal pyramid,  an edgeedge with one O(9)ScV3 tetrahedra,  an edgeedge with one O(14)Sc3V trigonal pyramid,  an edgeedge with one O(21)Sc3V trigonal pyramid, and  an edgeedge with one O(4)Sc3V trigonal pyramid. In the nineteenth O site, O(19) is bonded to one Sc(4), one Sc(6), one V(7), and one V(8) atom to form OSc2V2 trigonal pyramids that share  a cornercorner with one O(10)Sc2V2 tetrahedra,  a cornercorner with one O(9)ScV3 tetrahedra,  a cornercorner with one O(13)Sc2V2 trigonal pyramid,  a cornercorner with one O(2)Sc2V2 trigonal pyramid,  a cornercorner with one O(5)Sc2V2 trigonal pyramid,  a cornercorner with one O(7)Sc2V2 trigonal pyramid,  a cornercorner with one O(21)Sc3V trigonal pyramid,  a cornercorner with one O(24)Sc3V trigonal pyramid,  a cornercorner with one O(4)Sc3V trigonal pyramid,  a cornercorner with one O(12)ScV3 trigonal pyramid,  a cornercorner with one O(6)ScV3 trigonal pyramid,  a cornercorner with one O(8)ScV3 trigonal pyramid,  an edgeedge with one O(16)Sc2V2 trigonal pyramid,  an edgeedge with one O(23)Sc2V2 trigonal pyramid,  an edgeedge with one O(15)ScV3 trigonal pyramid, and  an edgeedge with one O(17)ScV3 trigonal pyramid. In the twentieth O site, O(20) is bonded to one Sc(2), one Sc(3), one V(3), and one V(6) atom to form OSc2V2 trigonal pyramids that share  a cornercorner with one O(10)Sc2V2 tetrahedra,  a cornercorner with one O(11)Sc2V2 trigonal pyramid,  a cornercorner with one O(16)Sc2V2 trigonal pyramid,  a cornercorner with one O(23)Sc2V2 trigonal pyramid,  a cornercorner with one O(5)Sc2V2 trigonal pyramid,  a cornercorner with one O(24)Sc3V trigonal pyramid,  a cornercorner with one O(12)ScV3 trigonal pyramid,  a cornercorner with one O(17)ScV3 trigonal pyramid,  a cornercorner with one O(3)ScV3 trigonal pyramid,  a cornercorner with one O(6)ScV3 trigonal pyramid,  a cornercorner with one O(8)ScV3 trigonal pyramid,  a cornercorner with one O(22)V4 trigonal pyramid,  an edgeedge with one O(13)Sc2V2 trigonal pyramid,  an edgeedge with one O(2)Sc2V2 trigonal pyramid,  an edgeedge with one O(7)Sc2V2 trigonal pyramid, and  an edgeedge with one O(14)Sc3V trigonal pyramid. In the twenty-first O site, O(21) is bonded to one Sc(1), one Sc(6), one Sc(7), and one V(9) atom to form OSc3V trigonal pyramids that share  a cornercorner with one O(10)Sc2V2 tetrahedra,  a cornercorner with one O(13)Sc2V2 trigonal pyramid,  a cornercorner with one O(16)Sc2V2 trigonal pyramid,  a cornercorner with one O(19)Sc2V2 trigonal pyramid,  a cornercorner with one O(2)Sc2V2 trigonal pyramid,  a cornercorner with one O(5)Sc2V2 trigonal pyramid,  a cornercorner with one O(14)Sc3V trigonal pyramid,  a cornercorner with one O(4)Sc3V trigonal pyramid,  a cornercorner with one O(1)ScV3 trigonal pyramid,  a cornercorner with one O(17)ScV3 trigonal pyramid,  a cornercorner with one O(3)ScV3 trigonal pyramid,  a cornercorner with one O(8)ScV3 trigonal pyramid,  an edgeedge with one O(11)Sc2V2 trigonal pyramid,  an edgeedge with one O(18)Sc2V2 trigonal pyramid,  an edgeedge with one O(24)Sc3V trigonal pyramid, and  an edgeedge with one O(12)ScV3 trigonal pyramid. In the twenty-second O site, O(22) is bonded to one V(1), one V(2), one V(3), and one V(5) atom to form OV4 trigonal pyramids that share  a cornercorner with one O(13)Sc2V2 trigonal pyramid,  a cornercorner with one O(16)Sc2V2 trigonal pyramid,  a cornercorner with one O(18)Sc2V2 trigonal pyramid,  a cornercorner with one O(2)Sc2V2 trigonal pyramid,  a cornercorner with one O(20)Sc2V2 trigonal pyramid,  a cornercorner with one O(24)Sc3V trigonal pyramid,  a cornercorner with one O(4)Sc3V trigonal pyramid,  a cornercorner with one O(12)ScV3 trigonal pyramid,  a cornercorner with one O(15)ScV3 trigonal pyramid,  a cornercorner with one O(17)ScV3 trigonal pyramid,  a cornercorner with one O(3)ScV3 trigonal pyramid,  a cornercorner with one O(6)ScV3 trigonal pyramid,  an edgeedge with one O(10)Sc2V2 tetrahedra,  an edgeedge with one O(9)ScV3 tetrahedra,  an edgeedge with one O(1)ScV3 trigonal pyramid, and  an edgeedge with one O(8)ScV3 trigonal pyramid. In the twenty-third O site, O(23) is bonded to one Sc(3), one Sc(5), one V(7), and one V(8) atom to form OSc2V2 trigonal pyramids that share  a cornercorner with one O(13)Sc2V2 trigonal pyramid,  a cornercorner with one O(16)Sc2V2 trigonal pyramid,  a cornercorner with one O(18)Sc2V2 trigonal pyramid,  a cornercorner with one O(2)Sc2V2 trigonal pyramid,  a cornercorner with one O(20)Sc2V2 trigonal pyramid,  a cornercorner with one O(24)Sc3V trigonal pyramid,  a cornercorner with one O(4)Sc3V trigonal pyramid,  a cornercorner with one O(12)ScV3 trigonal pyramid,  a cornercorner with one O(15)ScV3 trigonal pyramid,  a cornercorner with one O(17)ScV3 trigonal pyramid,  a cornercorner with one O(3)ScV3 trigonal pyramid,  a cornercorner with one O(6)ScV3 trigonal pyramid,  an edgeedge with one O(9)ScV3 tetrahedra,  an edgeedge with one O(19)Sc2V2 trigonal pyramid,  an edgeedge with one O(5)Sc2V2 trigonal pyramid, and  an edgeedge with one O(14)Sc3V trigonal pyramid. In the twenty-fourth O site, O(24) is bonded to one Sc(3), one Sc(6), one Sc(7), and one V(1) atom to form OSc3V trigonal pyramids that share  a cornercorner with one O(11)Sc2V2 trigonal pyramid,  a cornercorner with one O(16)Sc2V2 trigonal pyramid,  a cornercorner with one O(18)Sc2V2 trigonal pyramid,  a cornercorner with one O(19)Sc2V2 trigonal pyramid,  a cornercorner with one O(20)Sc2V2 trigonal pyramid,  a cornercorner with one O(23)Sc2V2 trigonal pyramid,  a cornercorner with one O(14)Sc3V trigonal pyramid,  a cornercorner with one O(1)ScV3 trigonal pyramid,  a cornercorner with one O(15)ScV3 trigonal pyramid,  a cornercorner with one O(17)ScV3 trigonal pyramid,  a cornercorner with one O(3)ScV3 trigonal pyramid,  a cornercorner with one O(22)V4 trigonal pyramid,  an edgeedge with one O(10)Sc2V2 tetrahedra,  an edgeedge with one O(13)Sc2V2 trigonal pyramid,  an edgeedge with one O(21)Sc3V trigonal pyramid, and  an edgeedge with one O(4)Sc3V trigonal pyramid. is represented by the CIF file [CIF]
data_Sc7V9O24
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.271
_cell_length_b   8.349
_cell_length_c   8.344
_cell_angle_alpha   109.274
_cell_angle_beta   109.639
_cell_angle_gamma   109.723
_symmetry_Int_Tables_number   1
_cell_volume   442.308
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sc  Sc0  1  0.748  0.284  0.534  1.0
  Sc  Sc1  1  0.541  0.750  0.289  1.0
  Sc  Sc2  1  0.250  0.714  0.463  1.0
  Sc  Sc3  1  0.250  0.216  0.965  1.0
  Sc  Sc4  1  0.212  0.966  0.252  1.0
  Sc  Sc5  1  0.289  0.535  0.750  1.0
  Sc  Sc6  1  0.033  0.751  0.788  1.0
  V  V7  1  0.508  0.004  0.996  1.0
  V  V8  1  0.959  0.248  0.209  1.0
  V  V9  1  0.782  0.033  0.753  1.0
  V  V10  1  0.716  0.467  0.247  1.0
  V  V11  1  0.750  0.788  0.039  1.0
  V  V12  1  0.501  0.500  0.501  1.0
  V  V13  1  0.999  0.999  0.501  1.0
  V  V14  1  0.469  0.253  0.719  1.0
  V  V15  1  0.991  0.496  1.000  1.0
  O  O16  1  0.735  0.225  0.262  1.0
  O  O17  1  0.775  0.039  0.496  1.0
  O  O18  1  0.957  0.506  0.230  1.0
  O  O19  1  0.285  0.011  0.049  1.0
  O  O20  1  0.462  0.237  0.459  1.0
  O  O21  1  0.791  0.731  0.272  1.0
  O  O22  1  0.457  0.464  0.232  1.0
  O  O23  1  0.037  0.276  0.013  1.0
  O  O24  1  0.992  0.041  0.261  1.0
  O  O25  1  0.505  0.770  0.039  1.0
  O  O26  1  0.768  0.544  0.524  1.0
  O  O27  1  0.719  0.249  0.768  1.0
  O  O28  1  0.223  0.445  0.455  1.0
  O  O29  1  0.272  0.737  0.225  1.0
  O  O30  1  0.519  0.248  0.968  1.0
  O  O31  1  0.980  0.956  0.730  1.0
  O  O32  1  0.553  0.534  0.775  1.0
  O  O33  1  0.946  0.720  0.992  1.0
  O  O34  1  0.220  0.266  0.729  1.0
  O  O35  1  0.542  0.769  0.550  1.0
  O  O36  1  0.036  0.491  0.774  1.0
  O  O37  1  0.719  0.987  0.943  1.0
  O  O38  1  0.240  0.974  0.518  1.0
  O  O39  1  0.267  0.777  0.731  1.0
[/CIF]
.
The structure described by Sc7V9O24 is Spinel-like structured and crystallizes in the triclinic P1 space group. There are seven inequivalent Sc sites. In the first Sc site, Sc(1) is bonded to one O(1), one O(11), one O(12), one O(2), one O(21), and one O(5) atom to form distorted ScO6 octahedra that share  a cornercorner with one Sc(2)O6 octahedra,  a cornercorner with one Sc(5)O6 octahedra,  a cornercorner with one Sc(6)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(7)O6 octahedra,  an edgeedge with one Sc(7)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(4)O6 octahedra,  an edgeedge with one V(6)O6 octahedra,  an edgeedge with one V(8)O6 octahedra, and  an edgeedge with one V(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-58°. In the second Sc site, Sc(2) is bonded to one O(10), one O(14), one O(2), one O(20), one O(6), and one O(7) atom to form distorted ScO6 octahedra that share  a cornercorner with one Sc(1)O6 octahedra,  a cornercorner with one Sc(4)O6 octahedra,  a cornercorner with one Sc(5)O6 octahedra,  a cornercorner with one Sc(6)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(9)O6 octahedra,  an edgeedge with one Sc(3)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(4)O6 octahedra,  an edgeedge with one V(5)O6 octahedra,  an edgeedge with one V(6)O6 octahedra, and  an edgeedge with one V(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-56°. In the third Sc site, Sc(3) is bonded to one O(13), one O(14), one O(20), one O(23), one O(24), and one O(3) atom to form distorted ScO6 octahedra that share  a cornercorner with one Sc(7)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra,  a cornercorner with one V(7)O6 octahedra,  a cornercorner with one V(8)O6 octahedra,  an edgeedge with one Sc(2)O6 octahedra,  an edgeedge with one Sc(5)O6 octahedra,  an edgeedge with one Sc(6)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(6)O6 octahedra, and  an edgeedge with one V(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-57°. In the fourth Sc site, Sc(4) is bonded to one O(15), one O(16), one O(19), one O(4), one O(7), and one O(8) atom to form distorted ScO6 octahedra that share  a cornercorner with one Sc(2)O6 octahedra,  a cornercorner with one Sc(5)O6 octahedra,  a cornercorner with one Sc(6)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(6)O6 octahedra,  a cornercorner with one V(9)O6 octahedra,  an edgeedge with one Sc(7)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(4)O6 octahedra,  an edgeedge with one V(7)O6 octahedra, and  an edgeedge with one V(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-57°. In the fifth Sc site, Sc(5) is bonded to one O(14), one O(18), one O(23), one O(4), one O(5), and one O(9) atom to form distorted ScO6 octahedra that share  a cornercorner with one Sc(1)O6 octahedra,  a cornercorner with one Sc(2)O6 octahedra,  a cornercorner with one Sc(4)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(6)O6 octahedra,  an edgeedge with one Sc(3)O6 octahedra,  an edgeedge with one Sc(7)O6 octahedra,  an edgeedge with one V(5)O6 octahedra,  an edgeedge with one V(7)O6 octahedra,  an edgeedge with one V(8)O6 octahedra, and  an edgeedge with one V(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-58°. In the sixth Sc site, Sc(6) is bonded to one O(10), one O(13), one O(17), one O(19), one O(21), and one O(24) atom to form distorted ScO6 octahedra that share  a cornercorner with one Sc(1)O6 octahedra,  a cornercorner with one Sc(2)O6 octahedra,  a cornercorner with one Sc(4)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(7)O6 octahedra,  a cornercorner with one V(9)O6 octahedra,  an edgeedge with one Sc(3)O6 octahedra,  an edgeedge with one Sc(7)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(5)O6 octahedra,  an edgeedge with one V(6)O6 octahedra, and  an edgeedge with one V(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-58°. In the seventh Sc site, Sc(7) is bonded to one O(11), one O(16), one O(18), one O(21), one O(24), and one O(4) atom to form distorted ScO6 octahedra that share  a cornercorner with one Sc(3)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra,  a cornercorner with one V(5)O6 octahedra,  a cornercorner with one V(6)O6 octahedra,  a cornercorner with one V(7)O6 octahedra,  an edgeedge with one Sc(1)O6 octahedra,  an edgeedge with one Sc(4)O6 octahedra,  an edgeedge with one Sc(5)O6 octahedra,  an edgeedge with one Sc(6)O6 octahedra,  an edgeedge with one V(1)O6 octahedra, and  an edgeedge with one V(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-59°. There are nine inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(10), one O(15), one O(22), one O(24), and one O(4) atom to form VO6 octahedra that share  a cornercorner with one Sc(1)O6 octahedra,  a cornercorner with one Sc(2)O6 octahedra,  a cornercorner with one Sc(3)O6 octahedra,  a cornercorner with one Sc(5)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(8)O6 octahedra,  an edgeedge with one Sc(4)O6 octahedra,  an edgeedge with one Sc(6)O6 octahedra,  an edgeedge with one Sc(7)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(4)O6 octahedra, and  an edgeedge with one V(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-58°. In the second V site, V(2) is bonded to one O(1), one O(13), one O(22), one O(3), one O(8), and one O(9) atom to form distorted VO6 octahedra that share  a cornercorner with one Sc(1)O6 octahedra,  a cornercorner with one Sc(4)O6 octahedra,  a cornercorner with one Sc(5)O6 octahedra,  a cornercorner with one Sc(6)O6 octahedra,  a cornercorner with one V(6)O6 octahedra,  a cornercorner with one V(7)O6 octahedra,  an edgeedge with one Sc(3)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(4)O6 octahedra,  an edgeedge with one V(5)O6 octahedra, and  an edgeedge with one V(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-55°. In the third V site, V(3) is bonded to one O(12), one O(16), one O(2), one O(20), one O(22), and one O(8) atom to form distorted VO6 octahedra that share  a cornercorner with one Sc(3)O6 octahedra,  a cornercorner with one Sc(7)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(5)O6 octahedra,  a cornercorner with one V(6)O6 octahedra,  a cornercorner with one V(8)O6 octahedra,  an edgeedge with one Sc(1)O6 octahedra,  an edgeedge with one Sc(2)O6 octahedra,  an edgeedge with one Sc(4)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(7)O6 octahedra, and  an edgeedge with one V(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-57°. In the fourth V site, V(4) is bonded to one O(1), one O(11), one O(15), one O(3), one O(6), and one O(7) atom to form distorted VO6 octahedra that share  a cornercorner with one Sc(3)O6 octahedra,  a cornercorner with one Sc(7)O6 octahedra,  a cornercorner with one V(5)O6 octahedra,  a cornercorner with one V(7)O6 octahedra,  a cornercorner with one V(8)O6 octahedra,  a cornercorner with one V(9)O6 octahedra,  an edgeedge with one Sc(1)O6 octahedra,  an edgeedge with one Sc(2)O6 octahedra,  an edgeedge with one Sc(4)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra, and  an edgeedge with one V(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-55°. In the fifth V site, V(5) is bonded to one O(10), one O(17), one O(18), one O(22), one O(6), and one O(9) atom to form distorted VO6 octahedra that share  a cornercorner with one Sc(7)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra,  a cornercorner with one V(6)O6 octahedra,  a cornercorner with one V(8)O6 octahedra,  a cornercorner with one V(9)O6 octahedra,  an edgeedge with one Sc(2)O6 octahedra,  an edgeedge with one Sc(5)O6 octahedra,  an edgeedge with one Sc(6)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra, and  an edgeedge with one V(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-55°. In the sixth V site, V(6) is bonded to one O(11), one O(13), one O(17), one O(20), one O(5), and one O(7) atom to form VO6 octahedra that share  a cornercorner with one Sc(4)O6 octahedra,  a cornercorner with one Sc(5)O6 octahedra,  a cornercorner with one Sc(7)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(5)O6 octahedra,  an edgeedge with one Sc(1)O6 octahedra,  an edgeedge with one Sc(2)O6 octahedra,  an edgeedge with one Sc(3)O6 octahedra,  an edgeedge with one Sc(6)O6 octahedra,  an edgeedge with one V(4)O6 octahedra, and  an edgeedge with one V(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-59°. In the seventh V site, V(7) is bonded to one O(16), one O(19), one O(2), one O(23), one O(6), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one Sc(1)O6 octahedra,  a cornercorner with one Sc(3)O6 octahedra,  a cornercorner with one Sc(6)O6 octahedra,  a cornercorner with one Sc(7)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(4)O6 octahedra,  an edgeedge with one Sc(2)O6 octahedra,  an edgeedge with one Sc(4)O6 octahedra,  an edgeedge with one Sc(5)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(5)O6 octahedra, and  an edgeedge with one V(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-58°. In the eighth V site, V(8) is bonded to one O(12), one O(15), one O(17), one O(19), one O(23), and one O(5) atom to form distorted VO6 octahedra that share  a cornercorner with one Sc(3)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra,  a cornercorner with one V(5)O6 octahedra,  a cornercorner with one V(9)O6 octahedra,  an edgeedge with one Sc(1)O6 octahedra,  an edgeedge with one Sc(4)O6 octahedra,  an edgeedge with one Sc(5)O6 octahedra,  an edgeedge with one Sc(6)O6 octahedra,  an edgeedge with one V(6)O6 octahedra, and  an edgeedge with one V(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-60°. In the ninth V site, V(9) is bonded to one O(12), one O(14), one O(18), one O(21), one O(3), and one O(8) atom to form VO6 octahedra that share  a cornercorner with one Sc(2)O6 octahedra,  a cornercorner with one Sc(4)O6 octahedra,  a cornercorner with one Sc(6)O6 octahedra,  a cornercorner with one V(4)O6 octahedra,  a cornercorner with one V(5)O6 octahedra,  a cornercorner with one V(8)O6 octahedra,  an edgeedge with one Sc(1)O6 octahedra,  an edgeedge with one Sc(3)O6 octahedra,  an edgeedge with one Sc(5)O6 octahedra,  an edgeedge with one Sc(7)O6 octahedra,  an edgeedge with one V(2)O6 octahedra, and  an edgeedge with one V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-60°. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded to one Sc(1), one V(1), one V(2), and one V(4) atom to form OScV3 trigonal pyramids that share  a cornercorner with one O(10)Sc2V2 tetrahedra,  a cornercorner with one O(9)ScV3 tetrahedra,  a cornercorner with one O(13)Sc2V2 trigonal pyramid,  a cornercorner with one O(2)Sc2V2 trigonal pyramid,  a cornercorner with one O(5)Sc2V2 trigonal pyramid,  a cornercorner with one O(7)Sc2V2 trigonal pyramid,  a cornercorner with one O(21)Sc3V trigonal pyramid,  a cornercorner with one O(24)Sc3V trigonal pyramid,  a cornercorner with one O(4)Sc3V trigonal pyramid,  a cornercorner with one O(12)ScV3 trigonal pyramid,  a cornercorner with one O(6)ScV3 trigonal pyramid,  a cornercorner with one O(8)ScV3 trigonal pyramid,  an edgeedge with one O(11)Sc2V2 trigonal pyramid,  an edgeedge with one O(15)ScV3 trigonal pyramid,  an edgeedge with one O(3)ScV3 trigonal pyramid, and  an edgeedge with one O(22)V4 trigonal pyramid. In the second O site, O(2) is bonded to one Sc(1), one Sc(2), one V(3), and one V(7) atom to form OSc2V2 trigonal pyramids that share  a cornercorner with one O(10)Sc2V2 tetrahedra,  a cornercorner with one O(9)ScV3 tetrahedra,  a cornercorner with one O(11)Sc2V2 trigonal pyramid,  a cornercorner with one O(19)Sc2V2 trigonal pyramid,  a cornercorner with one O(23)Sc2V2 trigonal pyramid,  a cornercorner with one O(5)Sc2V2 trigonal pyramid,  a cornercorner with one O(7)Sc2V2 trigonal pyramid,  a cornercorner with one O(14)Sc3V trigonal pyramid,  a cornercorner with one O(21)Sc3V trigonal pyramid,  a cornercorner with one O(1)ScV3 trigonal pyramid,  a cornercorner with one O(8)ScV3 trigonal pyramid,  a cornercorner with one O(22)V4 trigonal pyramid,  an edgeedge with one O(16)Sc2V2 trigonal pyramid,  an edgeedge with one O(20)Sc2V2 trigonal pyramid,  an edgeedge with one O(12)ScV3 trigonal pyramid, and  an edgeedge with one O(6)ScV3 trigonal pyramid. In the third O site, O(3) is bonded to one Sc(3), one V(2), one V(4), and one V(9) atom to form OScV3 trigonal pyramids that share  a cornercorner with one O(9)ScV3 tetrahedra,  a cornercorner with one O(11)Sc2V2 trigonal pyramid,  a cornercorner with one O(18)Sc2V2 trigonal pyramid,  a cornercorner with one O(20)Sc2V2 trigonal pyramid,  a cornercorner with one O(23)Sc2V2 trigonal pyramid,  a cornercorner with one O(7)Sc2V2 trigonal pyramid,  a cornercorner with one O(21)Sc3V trigonal pyramid,  a cornercorner with one O(24)Sc3V trigonal pyramid,  a cornercorner with one O(12)ScV3 trigonal pyramid,  a cornercorner with one O(15)ScV3 trigonal pyramid,  a cornercorner with one O(6)ScV3 trigonal pyramid,  a cornercorner with one O(22)V4 trigonal pyramid,  an edgeedge with one O(13)Sc2V2 trigonal pyramid,  an edgeedge with one O(14)Sc3V trigonal pyramid,  an edgeedge with one O(1)ScV3 trigonal pyramid, and  an edgeedge with one O(8)ScV3 trigonal pyramid. In the fourth O site, O(4) is bonded to one Sc(4), one Sc(5), one Sc(7), and one V(1) atom to form OSc3V trigonal pyramids that share  a cornercorner with one O(10)Sc2V2 tetrahedra,  a cornercorner with one O(9)ScV3 tetrahedra,  a cornercorner with one O(11)Sc2V2 trigonal pyramid,  a cornercorner with one O(19)Sc2V2 trigonal pyramid,  a cornercorner with one O(23)Sc2V2 trigonal pyramid,  a cornercorner with one O(5)Sc2V2 trigonal pyramid,  a cornercorner with one O(7)Sc2V2 trigonal pyramid,  a cornercorner with one O(14)Sc3V trigonal pyramid,  a cornercorner with one O(21)Sc3V trigonal pyramid,  a cornercorner with one O(1)ScV3 trigonal pyramid,  a cornercorner with one O(8)ScV3 trigonal pyramid,  a cornercorner with one O(22)V4 trigonal pyramid,  an edgeedge with one O(16)Sc2V2 trigonal pyramid,  an edgeedge with one O(18)Sc2V2 trigonal pyramid,  an edgeedge with one O(24)Sc3V trigonal pyramid, and  an edgeedge with one O(15)ScV3 trigonal pyramid. In the fifth O site, O(5) is bonded to one Sc(1), one Sc(5), one V(6), and one V(8) atom to form OSc2V2 trigonal pyramids that share  a cornercorner with one O(9)ScV3 tetrahedra,  a cornercorner with one O(13)Sc2V2 trigonal pyramid,  a cornercorner with one O(18)Sc2V2 trigonal pyramid,  a cornercorner with one O(19)Sc2V2 trigonal pyramid,  a cornercorner with one O(2)Sc2V2 trigonal pyramid,  a cornercorner with one O(20)Sc2V2 trigonal pyramid,  a cornercorner with one O(7)Sc2V2 trigonal pyramid,  a cornercorner with one O(14)Sc3V trigonal pyramid,  a cornercorner with one O(21)Sc3V trigonal pyramid,  a cornercorner with one O(4)Sc3V trigonal pyramid,  a cornercorner with one O(1)ScV3 trigonal pyramid,  a cornercorner with one O(15)ScV3 trigonal pyramid,  an edgeedge with one O(11)Sc2V2 trigonal pyramid,  an edgeedge with one O(23)Sc2V2 trigonal pyramid,  an edgeedge with one O(12)ScV3 trigonal pyramid, and  an edgeedge with one O(17)ScV3 trigonal pyramid. In the sixth O site, O(6) is bonded to one Sc(2), one V(4), one V(5), and one V(7) atom to form OScV3 trigonal pyramids that share  a cornercorner with one O(11)Sc2V2 trigonal pyramid,  a cornercorner with one O(16)Sc2V2 trigonal pyramid,  a cornercorner with one O(18)Sc2V2 trigonal pyramid,  a cornercorner with one O(19)Sc2V2 trigonal pyramid,  a cornercorner with one O(20)Sc2V2 trigonal pyramid,  a cornercorner with one O(23)Sc2V2 trigonal pyramid,  a cornercorner with one O(14)Sc3V trigonal pyramid,  a cornercorner with one O(1)ScV3 trigonal pyramid,  a cornercorner with one O(15)ScV3 trigonal pyramid,  a cornercorner with one O(17)ScV3 trigonal pyramid,  a cornercorner with one O(3)ScV3 trigonal pyramid,  a cornercorner with one O(22)V4 trigonal pyramid,  an edgeedge with one O(10)Sc2V2 tetrahedra,  an edgeedge with one O(9)ScV3 tetrahedra,  an edgeedge with one O(2)Sc2V2 trigonal pyramid, and  an edgeedge with one O(7)Sc2V2 trigonal pyramid. In the seventh O site, O(7) is bonded to one Sc(2), one Sc(4), one V(4), and one V(6) atom to form OSc2V2 trigonal pyramids that share  a cornercorner with one O(10)Sc2V2 tetrahedra,  a cornercorner with one O(13)Sc2V2 trigonal pyramid,  a cornercorner with one O(16)Sc2V2 trigonal pyramid,  a cornercorner with one O(19)Sc2V2 trigonal pyramid,  a cornercorner with one O(2)Sc2V2 trigonal pyramid,  a cornercorner with one O(5)Sc2V2 trigonal pyramid,  a cornercorner with one O(14)Sc3V trigonal pyramid,  a cornercorner with one O(4)Sc3V trigonal pyramid,  a cornercorner with one O(1)ScV3 trigonal pyramid,  a cornercorner with one O(17)ScV3 trigonal pyramid,  a cornercorner with one O(3)ScV3 trigonal pyramid,  a cornercorner with one O(8)ScV3 trigonal pyramid,  an edgeedge with one O(11)Sc2V2 trigonal pyramid,  an edgeedge with one O(20)Sc2V2 trigonal pyramid,  an edgeedge with one O(15)ScV3 trigonal pyramid, and  an edgeedge with one O(6)ScV3 trigonal pyramid. In the eighth O site, O(8) is bonded to one Sc(4), one V(2), one V(3), and one V(9) atom to form OScV3 trigonal pyramids that share  a cornercorner with one O(9)ScV3 tetrahedra,  a cornercorner with one O(13)Sc2V2 trigonal pyramid,  a cornercorner with one O(18)Sc2V2 trigonal pyramid,  a cornercorner with one O(19)Sc2V2 trigonal pyramid,  a cornercorner with one O(2)Sc2V2 trigonal pyramid,  a cornercorner with one O(20)Sc2V2 trigonal pyramid,  a cornercorner with one O(7)Sc2V2 trigonal pyramid,  a cornercorner with one O(14)Sc3V trigonal pyramid,  a cornercorner with one O(21)Sc3V trigonal pyramid,  a cornercorner with one O(4)Sc3V trigonal pyramid,  a cornercorner with one O(1)ScV3 trigonal pyramid,  a cornercorner with one O(15)ScV3 trigonal pyramid,  an edgeedge with one O(16)Sc2V2 trigonal pyramid,  an edgeedge with one O(12)ScV3 trigonal pyramid,  an edgeedge with one O(3)ScV3 trigonal pyramid, and  an edgeedge with one O(22)V4 trigonal pyramid. In the ninth O site, O(9) is bonded to one Sc(5), one V(2), one V(5), and one V(7) atom to form OScV3 tetrahedra that share  a cornercorner with one O(10)Sc2V2 tetrahedra,  a cornercorner with one O(13)Sc2V2 trigonal pyramid,  a cornercorner with one O(16)Sc2V2 trigonal pyramid,  a cornercorner with one O(19)Sc2V2 trigonal pyramid,  a cornercorner with one O(2)Sc2V2 trigonal pyramid,  a cornercorner with one O(5)Sc2V2 trigonal pyramid,  a cornercorner with one O(14)Sc3V trigonal pyramid,  a cornercorner with one O(4)Sc3V trigonal pyramid,  a cornercorner with one O(1)ScV3 trigonal pyramid,  a cornercorner with one O(17)ScV3 trigonal pyramid,  a cornercorner with one O(3)ScV3 trigonal pyramid,  a cornercorner with one O(8)ScV3 trigonal pyramid,  an edgeedge with one O(18)Sc2V2 trigonal pyramid,  an edgeedge with one O(23)Sc2V2 trigonal pyramid,  an edgeedge with one O(6)ScV3 trigonal pyramid, and  an edgeedge with one O(22)V4 trigonal pyramid. In the tenth O site, O(10) is bonded to one Sc(2), one Sc(6), one V(1), and one V(5) atom to form OSc2V2 tetrahedra that share  a cornercorner with one O(9)ScV3 tetrahedra,  a cornercorner with one O(13)Sc2V2 trigonal pyramid,  a cornercorner with one O(18)Sc2V2 trigonal pyramid,  a cornercorner with one O(19)Sc2V2 trigonal pyramid,  a cornercorner with one O(2)Sc2V2 trigonal pyramid,  a cornercorner with one O(20)Sc2V2 trigonal pyramid,  a cornercorner with one O(7)Sc2V2 trigonal pyramid,  a cornercorner with one O(14)Sc3V trigonal pyramid,  a cornercorner with one O(21)Sc3V trigonal pyramid,  a cornercorner with one O(4)Sc3V trigonal pyramid,  a cornercorner with one O(1)ScV3 trigonal pyramid,  a cornercorner with one O(15)ScV3 trigonal pyramid,  an edgeedge with one O(24)Sc3V trigonal pyramid,  an edgeedge with one O(17)ScV3 trigonal pyramid,  an edgeedge with one O(6)ScV3 trigonal pyramid, and  an edgeedge with one O(22)V4 trigonal pyramid. In the eleventh O site, O(11) is bonded to one Sc(1), one Sc(7), one V(4), and one V(6) atom to form OSc2V2 trigonal pyramids that share  a cornercorner with one O(13)Sc2V2 trigonal pyramid,  a cornercorner with one O(16)Sc2V2 trigonal pyramid,  a cornercorner with one O(18)Sc2V2 trigonal pyramid,  a cornercorner with one O(2)Sc2V2 trigonal pyramid,  a cornercorner with one O(20)Sc2V2 trigonal pyramid,  a cornercorner with one O(24)Sc3V trigonal pyramid,  a cornercorner with one O(4)Sc3V trigonal pyramid,  a cornercorner with one O(12)ScV3 trigonal pyramid,  a cornercorner with one O(15)ScV3 trigonal pyramid,  a cornercorner with one O(17)ScV3 trigonal pyramid,  a cornercorner with one O(3)ScV3 trigonal pyramid,  a cornercorner with one O(6)ScV3 trigonal pyramid,  an edgeedge with one O(5)Sc2V2 trigonal pyramid,  an edgeedge with one O(7)Sc2V2 trigonal pyramid,  an edgeedge with one O(21)Sc3V trigonal pyramid, and  an edgeedge with one O(1)ScV3 trigonal pyramid. In the twelfth O site, O(12) is bonded to one Sc(1), one V(3), one V(8), and one V(9) atom to form OScV3 trigonal pyramids that share  a cornercorner with one O(11)Sc2V2 trigonal pyramid,  a cornercorner with one O(16)Sc2V2 trigonal pyramid,  a cornercorner with one O(18)Sc2V2 trigonal pyramid,  a cornercorner with one O(19)Sc2V2 trigonal pyramid,  a cornercorner with one O(20)Sc2V2 trigonal pyramid,  a cornercorner with one O(23)Sc2V2 trigonal pyramid,  a cornercorner with one O(14)Sc3V trigonal pyramid,  a cornercorner with one O(1)ScV3 trigonal pyramid,  a cornercorner with one O(15)ScV3 trigonal pyramid,  a cornercorner with one O(17)ScV3 trigonal pyramid,  a cornercorner with one O(3)ScV3 trigonal pyramid,  a cornercorner with one O(22)V4 trigonal pyramid,  an edgeedge with one O(2)Sc2V2 trigonal pyramid,  an edgeedge with one O(5)Sc2V2 trigonal pyramid,  an edgeedge with one O(21)Sc3V trigonal pyramid, and  an edgeedge with one O(8)ScV3 trigonal pyramid. In the thirteenth O site, O(13) is bonded to one Sc(3), one Sc(6), one V(2), and one V(6) atom to form OSc2V2 trigonal pyramids that share  a cornercorner with one O(10)Sc2V2 tetrahedra,  a cornercorner with one O(9)ScV3 tetrahedra,  a cornercorner with one O(11)Sc2V2 trigonal pyramid,  a cornercorner with one O(19)Sc2V2 trigonal pyramid,  a cornercorner with one O(23)Sc2V2 trigonal pyramid,  a cornercorner with one O(5)Sc2V2 trigonal pyramid,  a cornercorner with one O(7)Sc2V2 trigonal pyramid,  a cornercorner with one O(14)Sc3V trigonal pyramid,  a cornercorner with one O(21)Sc3V trigonal pyramid,  a cornercorner with one O(1)ScV3 trigonal pyramid,  a cornercorner with one O(8)ScV3 trigonal pyramid,  a cornercorner with one O(22)V4 trigonal pyramid,  an edgeedge with one O(20)Sc2V2 trigonal pyramid,  an edgeedge with one O(24)Sc3V trigonal pyramid,  an edgeedge with one O(17)ScV3 trigonal pyramid, and  an edgeedge with one O(3)ScV3 trigonal pyramid. In the fourteenth O site, O(14) is bonded to one Sc(2), one Sc(3), one Sc(5), and one V(9) atom to form OSc3V trigonal pyramids that share  a cornercorner with one O(10)Sc2V2 tetrahedra,  a cornercorner with one O(9)ScV3 tetrahedra,  a cornercorner with one O(13)Sc2V2 trigonal pyramid,  a cornercorner with one O(2)Sc2V2 trigonal pyramid,  a cornercorner with one O(5)Sc2V2 trigonal pyramid,  a cornercorner with one O(7)Sc2V2 trigonal pyramid,  a cornercorner with one O(21)Sc3V trigonal pyramid,  a cornercorner with one O(24)Sc3V trigonal pyramid,  a cornercorner with one O(4)Sc3V trigonal pyramid,  a cornercorner with one O(12)ScV3 trigonal pyramid,  a cornercorner with one O(6)ScV3 trigonal pyramid,  a cornercorner with one O(8)ScV3 trigonal pyramid,  an edgeedge with one O(18)Sc2V2 trigonal pyramid,  an edgeedge with one O(20)Sc2V2 trigonal pyramid,  an edgeedge with one O(23)Sc2V2 trigonal pyramid, and  an edgeedge with one O(3)ScV3 trigonal pyramid. In the fifteenth O site, O(15) is bonded to one Sc(4), one V(1), one V(4), and one V(8) atom to form OScV3 trigonal pyramids that share  a cornercorner with one O(10)Sc2V2 tetrahedra,  a cornercorner with one O(11)Sc2V2 trigonal pyramid,  a cornercorner with one O(16)Sc2V2 trigonal pyramid,  a cornercorner with one O(23)Sc2V2 trigonal pyramid,  a cornercorner with one O(5)Sc2V2 trigonal pyramid,  a cornercorner with one O(24)Sc3V trigonal pyramid,  a cornercorner with one O(12)ScV3 trigonal pyramid,  a cornercorner with one O(17)ScV3 trigonal pyramid,  a cornercorner with one O(3)ScV3 trigonal pyramid,  a cornercorner with one O(6)ScV3 trigonal pyramid,  a cornercorner with one O(8)ScV3 trigonal pyramid,  a cornercorner with one O(22)V4 trigonal pyramid,  an edgeedge with one O(19)Sc2V2 trigonal pyramid,  an edgeedge with one O(7)Sc2V2 trigonal pyramid,  an edgeedge with one O(4)Sc3V trigonal pyramid, and  an edgeedge with one O(1)ScV3 trigonal pyramid. In the sixteenth O site, O(16) is bonded to one Sc(4), one Sc(7), one V(3), and one V(7) atom to form OSc2V2 trigonal pyramids that share  a cornercorner with one O(9)ScV3 tetrahedra,  a cornercorner with one O(11)Sc2V2 trigonal pyramid,  a cornercorner with one O(18)Sc2V2 trigonal pyramid,  a cornercorner with one O(20)Sc2V2 trigonal pyramid,  a cornercorner with one O(23)Sc2V2 trigonal pyramid,  a cornercorner with one O(7)Sc2V2 trigonal pyramid,  a cornercorner with one O(21)Sc3V trigonal pyramid,  a cornercorner with one O(24)Sc3V trigonal pyramid,  a cornercorner with one O(12)ScV3 trigonal pyramid,  a cornercorner with one O(15)ScV3 trigonal pyramid,  a cornercorner with one O(6)ScV3 trigonal pyramid,  a cornercorner with one O(22)V4 trigonal pyramid,  an edgeedge with one O(19)Sc2V2 trigonal pyramid,  an edgeedge with one O(2)Sc2V2 trigonal pyramid,  an edgeedge with one O(4)Sc3V trigonal pyramid, and  an edgeedge with one O(8)ScV3 trigonal pyramid. In the seventeenth O site, O(17) is bonded to one Sc(6), one V(5), one V(6), and one V(8) atom to form OScV3 trigonal pyramids that share  a cornercorner with one O(9)ScV3 tetrahedra,  a cornercorner with one O(11)Sc2V2 trigonal pyramid,  a cornercorner with one O(18)Sc2V2 trigonal pyramid,  a cornercorner with one O(20)Sc2V2 trigonal pyramid,  a cornercorner with one O(23)Sc2V2 trigonal pyramid,  a cornercorner with one O(7)Sc2V2 trigonal pyramid,  a cornercorner with one O(21)Sc3V trigonal pyramid,  a cornercorner with one O(24)Sc3V trigonal pyramid,  a cornercorner with one O(12)ScV3 trigonal pyramid,  a cornercorner with one O(15)ScV3 trigonal pyramid,  a cornercorner with one O(6)ScV3 trigonal pyramid,  a cornercorner with one O(22)V4 trigonal pyramid,  an edgeedge with one O(10)Sc2V2 tetrahedra,  an edgeedge with one O(13)Sc2V2 trigonal pyramid,  an edgeedge with one O(19)Sc2V2 trigonal pyramid, and  an edgeedge with one O(5)Sc2V2 trigonal pyramid. In the eighteenth O site, O(18) is bonded to one Sc(5), one Sc(7), one V(5), and one V(9) atom to form OSc2V2 trigonal pyramids that share  a cornercorner with one O(10)Sc2V2 tetrahedra,  a cornercorner with one O(11)Sc2V2 trigonal pyramid,  a cornercorner with one O(16)Sc2V2 trigonal pyramid,  a cornercorner with one O(23)Sc2V2 trigonal pyramid,  a cornercorner with one O(5)Sc2V2 trigonal pyramid,  a cornercorner with one O(24)Sc3V trigonal pyramid,  a cornercorner with one O(12)ScV3 trigonal pyramid,  a cornercorner with one O(17)ScV3 trigonal pyramid,  a cornercorner with one O(3)ScV3 trigonal pyramid,  a cornercorner with one O(6)ScV3 trigonal pyramid,  a cornercorner with one O(8)ScV3 trigonal pyramid,  a cornercorner with one O(22)V4 trigonal pyramid,  an edgeedge with one O(9)ScV3 tetrahedra,  an edgeedge with one O(14)Sc3V trigonal pyramid,  an edgeedge with one O(21)Sc3V trigonal pyramid, and  an edgeedge with one O(4)Sc3V trigonal pyramid. In the nineteenth O site, O(19) is bonded to one Sc(4), one Sc(6), one V(7), and one V(8) atom to form OSc2V2 trigonal pyramids that share  a cornercorner with one O(10)Sc2V2 tetrahedra,  a cornercorner with one O(9)ScV3 tetrahedra,  a cornercorner with one O(13)Sc2V2 trigonal pyramid,  a cornercorner with one O(2)Sc2V2 trigonal pyramid,  a cornercorner with one O(5)Sc2V2 trigonal pyramid,  a cornercorner with one O(7)Sc2V2 trigonal pyramid,  a cornercorner with one O(21)Sc3V trigonal pyramid,  a cornercorner with one O(24)Sc3V trigonal pyramid,  a cornercorner with one O(4)Sc3V trigonal pyramid,  a cornercorner with one O(12)ScV3 trigonal pyramid,  a cornercorner with one O(6)ScV3 trigonal pyramid,  a cornercorner with one O(8)ScV3 trigonal pyramid,  an edgeedge with one O(16)Sc2V2 trigonal pyramid,  an edgeedge with one O(23)Sc2V2 trigonal pyramid,  an edgeedge with one O(15)ScV3 trigonal pyramid, and  an edgeedge with one O(17)ScV3 trigonal pyramid. In the twentieth O site, O(20) is bonded to one Sc(2), one Sc(3), one V(3), and one V(6) atom to form OSc2V2 trigonal pyramids that share  a cornercorner with one O(10)Sc2V2 tetrahedra,  a cornercorner with one O(11)Sc2V2 trigonal pyramid,  a cornercorner with one O(16)Sc2V2 trigonal pyramid,  a cornercorner with one O(23)Sc2V2 trigonal pyramid,  a cornercorner with one O(5)Sc2V2 trigonal pyramid,  a cornercorner with one O(24)Sc3V trigonal pyramid,  a cornercorner with one O(12)ScV3 trigonal pyramid,  a cornercorner with one O(17)ScV3 trigonal pyramid,  a cornercorner with one O(3)ScV3 trigonal pyramid,  a cornercorner with one O(6)ScV3 trigonal pyramid,  a cornercorner with one O(8)ScV3 trigonal pyramid,  a cornercorner with one O(22)V4 trigonal pyramid,  an edgeedge with one O(13)Sc2V2 trigonal pyramid,  an edgeedge with one O(2)Sc2V2 trigonal pyramid,  an edgeedge with one O(7)Sc2V2 trigonal pyramid, and  an edgeedge with one O(14)Sc3V trigonal pyramid. In the twenty-first O site, O(21) is bonded to one Sc(1), one Sc(6), one Sc(7), and one V(9) atom to form OSc3V trigonal pyramids that share  a cornercorner with one O(10)Sc2V2 tetrahedra,  a cornercorner with one O(13)Sc2V2 trigonal pyramid,  a cornercorner with one O(16)Sc2V2 trigonal pyramid,  a cornercorner with one O(19)Sc2V2 trigonal pyramid,  a cornercorner with one O(2)Sc2V2 trigonal pyramid,  a cornercorner with one O(5)Sc2V2 trigonal pyramid,  a cornercorner with one O(14)Sc3V trigonal pyramid,  a cornercorner with one O(4)Sc3V trigonal pyramid,  a cornercorner with one O(1)ScV3 trigonal pyramid,  a cornercorner with one O(17)ScV3 trigonal pyramid,  a cornercorner with one O(3)ScV3 trigonal pyramid,  a cornercorner with one O(8)ScV3 trigonal pyramid,  an edgeedge with one O(11)Sc2V2 trigonal pyramid,  an edgeedge with one O(18)Sc2V2 trigonal pyramid,  an edgeedge with one O(24)Sc3V trigonal pyramid, and  an edgeedge with one O(12)ScV3 trigonal pyramid. In the twenty-second O site, O(22) is bonded to one V(1), one V(2), one V(3), and one V(5) atom to form OV4 trigonal pyramids that share  a cornercorner with one O(13)Sc2V2 trigonal pyramid,  a cornercorner with one O(16)Sc2V2 trigonal pyramid,  a cornercorner with one O(18)Sc2V2 trigonal pyramid,  a cornercorner with one O(2)Sc2V2 trigonal pyramid,  a cornercorner with one O(20)Sc2V2 trigonal pyramid,  a cornercorner with one O(24)Sc3V trigonal pyramid,  a cornercorner with one O(4)Sc3V trigonal pyramid,  a cornercorner with one O(12)ScV3 trigonal pyramid,  a cornercorner with one O(15)ScV3 trigonal pyramid,  a cornercorner with one O(17)ScV3 trigonal pyramid,  a cornercorner with one O(3)ScV3 trigonal pyramid,  a cornercorner with one O(6)ScV3 trigonal pyramid,  an edgeedge with one O(10)Sc2V2 tetrahedra,  an edgeedge with one O(9)ScV3 tetrahedra,  an edgeedge with one O(1)ScV3 trigonal pyramid, and  an edgeedge with one O(8)ScV3 trigonal pyramid. In the twenty-third O site, O(23) is bonded to one Sc(3), one Sc(5), one V(7), and one V(8) atom to form OSc2V2 trigonal pyramids that share  a cornercorner with one O(13)Sc2V2 trigonal pyramid,  a cornercorner with one O(16)Sc2V2 trigonal pyramid,  a cornercorner with one O(18)Sc2V2 trigonal pyramid,  a cornercorner with one O(2)Sc2V2 trigonal pyramid,  a cornercorner with one O(20)Sc2V2 trigonal pyramid,  a cornercorner with one O(24)Sc3V trigonal pyramid,  a cornercorner with one O(4)Sc3V trigonal pyramid,  a cornercorner with one O(12)ScV3 trigonal pyramid,  a cornercorner with one O(15)ScV3 trigonal pyramid,  a cornercorner with one O(17)ScV3 trigonal pyramid,  a cornercorner with one O(3)ScV3 trigonal pyramid,  a cornercorner with one O(6)ScV3 trigonal pyramid,  an edgeedge with one O(9)ScV3 tetrahedra,  an edgeedge with one O(19)Sc2V2 trigonal pyramid,  an edgeedge with one O(5)Sc2V2 trigonal pyramid, and  an edgeedge with one O(14)Sc3V trigonal pyramid. In the twenty-fourth O site, O(24) is bonded to one Sc(3), one Sc(6), one Sc(7), and one V(1) atom to form OSc3V trigonal pyramids that share  a cornercorner with one O(11)Sc2V2 trigonal pyramid,  a cornercorner with one O(16)Sc2V2 trigonal pyramid,  a cornercorner with one O(18)Sc2V2 trigonal pyramid,  a cornercorner with one O(19)Sc2V2 trigonal pyramid,  a cornercorner with one O(20)Sc2V2 trigonal pyramid,  a cornercorner with one O(23)Sc2V2 trigonal pyramid,  a cornercorner with one O(14)Sc3V trigonal pyramid,  a cornercorner with one O(1)ScV3 trigonal pyramid,  a cornercorner with one O(15)ScV3 trigonal pyramid,  a cornercorner with one O(17)ScV3 trigonal pyramid,  a cornercorner with one O(3)ScV3 trigonal pyramid,  a cornercorner with one O(22)V4 trigonal pyramid,  an edgeedge with one O(10)Sc2V2 tetrahedra,  an edgeedge with one O(13)Sc2V2 trigonal pyramid,  an edgeedge with one O(21)Sc3V trigonal pyramid, and  an edgeedge with one O(4)Sc3V trigonal pyramid. is represented by the CIF file [CIF]
data_Sc7V9O24
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.271
_cell_length_b   8.349
_cell_length_c   8.344
_cell_angle_alpha   109.274
_cell_angle_beta   109.639
_cell_angle_gamma   109.723
_symmetry_Int_Tables_number   1
_cell_volume   442.308
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sc  Sc0  1  0.748  0.284  0.534  1.0
  Sc  Sc1  1  0.541  0.750  0.289  1.0
  Sc  Sc2  1  0.250  0.714  0.463  1.0
  Sc  Sc3  1  0.250  0.216  0.965  1.0
  Sc  Sc4  1  0.212  0.966  0.252  1.0
  Sc  Sc5  1  0.289  0.535  0.750  1.0
  Sc  Sc6  1  0.033  0.751  0.788  1.0
  V  V7  1  0.508  0.004  0.996  1.0
  V  V8  1  0.959  0.248  0.209  1.0
  V  V9  1  0.782  0.033  0.753  1.0
  V  V10  1  0.716  0.467  0.247  1.0
  V  V11  1  0.750  0.788  0.039  1.0
  V  V12  1  0.501  0.500  0.501  1.0
  V  V13  1  0.999  0.999  0.501  1.0
  V  V14  1  0.469  0.253  0.719  1.0
  V  V15  1  0.991  0.496  1.000  1.0
  O  O16  1  0.735  0.225  0.262  1.0
  O  O17  1  0.775  0.039  0.496  1.0
  O  O18  1  0.957  0.506  0.230  1.0
  O  O19  1  0.285  0.011  0.049  1.0
  O  O20  1  0.462  0.237  0.459  1.0
  O  O21  1  0.791  0.731  0.272  1.0
  O  O22  1  0.457  0.464  0.232  1.0
  O  O23  1  0.037  0.276  0.013  1.0
  O  O24  1  0.992  0.041  0.261  1.0
  O  O25  1  0.505  0.770  0.039  1.0
  O  O26  1  0.768  0.544  0.524  1.0
  O  O27  1  0.719  0.249  0.768  1.0
  O  O28  1  0.223  0.445  0.455  1.0
  O  O29  1  0.272  0.737  0.225  1.0
  O  O30  1  0.519  0.248  0.968  1.0
  O  O31  1  0.980  0.956  0.730  1.0
  O  O32  1  0.553  0.534  0.775  1.0
  O  O33  1  0.946  0.720  0.992  1.0
  O  O34  1  0.220  0.266  0.729  1.0
  O  O35  1  0.542  0.769  0.550  1.0
  O  O36  1  0.036  0.491  0.774  1.0
  O  O37  1  0.719  0.987  0.943  1.0
  O  O38  1  0.240  0.974  0.518  1.0
  O  O39  1  0.267  0.777  0.731  1.0
[/CIF]
.