The material structure described by Sm(MoCo5)2 crystallizes in the orthorhombic Immm space group. Sm(1) is bonded in a 20-coordinate geometry to two equivalent Mo(1), two equivalent Co(4), four equivalent Co(1), four equivalent Co(2), and eight equivalent Co(3) atoms. Mo(1) is bonded in a 14-coordinate geometry to one Sm(1), one Mo(1), two equivalent Co(1), two equivalent Co(2), four equivalent Co(3), and four equivalent Co(4) atoms. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded in a 12-coordinate geometry to two equivalent Sm(1), two equivalent Mo(1), two equivalent Co(2), two equivalent Co(4), and four equivalent Co(3) atoms. In the second Co site, Co(2) is bonded in a 12-coordinate geometry to two equivalent Sm(1), two equivalent Mo(1), two equivalent Co(1), two equivalent Co(4), and four equivalent Co(3) atoms. In the third Co site, Co(3) is bonded to two equivalent Sm(1), two equivalent Mo(1), two equivalent Co(1), two equivalent Co(2), two equivalent Co(3), and two equivalent Co(4) atoms to form a mixture of distorted face, corner, and edge-sharing CoSm2Co8Mo2 cuboctahedra. In the fourth Co site, Co(4) is bonded in a 14-coordinate geometry to one Sm(1), four equivalent Mo(1), one Co(4), two equivalent Co(1), two equivalent Co(2), and four equivalent Co(3) atoms. is represented by the CIF file [CIF]
data_Sm(Co5Mo)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.677
_cell_length_b   6.448
_cell_length_c   6.448
_cell_angle_alpha   97.376
_cell_angle_beta   111.267
_cell_angle_gamma   68.733
_symmetry_Int_Tables_number   1
_cell_volume   168.861
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sm  Sm0  1  0.000  0.000  0.000  1.0
  Co  Co1  1  0.711  0.789  0.211  1.0
  Co  Co2  1  0.289  0.211  0.789  1.0
  Co  Co3  1  0.500  0.774  0.774  1.0
  Co  Co4  1  0.500  0.226  0.226  1.0
  Co  Co5  1  0.500  0.000  0.500  1.0
  Co  Co6  1  0.000  0.000  0.500  1.0
  Co  Co7  1  0.500  0.500  0.000  1.0
  Co  Co8  1  0.000  0.500  0.000  1.0
  Co  Co9  1  0.640  0.360  0.640  1.0
  Co  Co10  1  0.360  0.640  0.360  1.0
  Mo  Mo11  1  0.000  0.359  0.359  1.0
  Mo  Mo12  1  0.000  0.641  0.641  1.0
[/CIF]
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The material structure described by Sm(MoCo5)2 crystallizes in the orthorhombic Immm space group. Sm(1) is bonded in a 20-coordinate geometry to two equivalent Mo(1), two equivalent Co(4), four equivalent Co(1), four equivalent Co(2), and eight equivalent Co(3) atoms. Mo(1) is bonded in a 14-coordinate geometry to one Sm(1), one Mo(1), two equivalent Co(1), two equivalent Co(2), four equivalent Co(3), and four equivalent Co(4) atoms. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded in a 12-coordinate geometry to two equivalent Sm(1), two equivalent Mo(1), two equivalent Co(2), two equivalent Co(4), and four equivalent Co(3) atoms. In the second Co site, Co(2) is bonded in a 12-coordinate geometry to two equivalent Sm(1), two equivalent Mo(1), two equivalent Co(1), two equivalent Co(4), and four equivalent Co(3) atoms. In the third Co site, Co(3) is bonded to two equivalent Sm(1), two equivalent Mo(1), two equivalent Co(1), two equivalent Co(2), two equivalent Co(3), and two equivalent Co(4) atoms to form a mixture of distorted face, corner, and edge-sharing CoSm2Co8Mo2 cuboctahedra. In the fourth Co site, Co(4) is bonded in a 14-coordinate geometry to one Sm(1), four equivalent Mo(1), one Co(4), two equivalent Co(1), two equivalent Co(2), and four equivalent Co(3) atoms. is represented by the CIF file [CIF]
data_Sm(Co5Mo)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.677
_cell_length_b   6.448
_cell_length_c   6.448
_cell_angle_alpha   97.376
_cell_angle_beta   111.267
_cell_angle_gamma   68.733
_symmetry_Int_Tables_number   1
_cell_volume   168.861
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sm  Sm0  1  0.000  0.000  0.000  1.0
  Co  Co1  1  0.711  0.789  0.211  1.0
  Co  Co2  1  0.289  0.211  0.789  1.0
  Co  Co3  1  0.500  0.774  0.774  1.0
  Co  Co4  1  0.500  0.226  0.226  1.0
  Co  Co5  1  0.500  0.000  0.500  1.0
  Co  Co6  1  0.000  0.000  0.500  1.0
  Co  Co7  1  0.500  0.500  0.000  1.0
  Co  Co8  1  0.000  0.500  0.000  1.0
  Co  Co9  1  0.640  0.360  0.640  1.0
  Co  Co10  1  0.360  0.640  0.360  1.0
  Mo  Mo11  1  0.000  0.359  0.359  1.0
  Mo  Mo12  1  0.000  0.641  0.641  1.0
[/CIF]
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