The structure described by XeIrSbF12 is Indium-like structured and crystallizes in the monoclinic Cc space group. The structure is zero-dimensional and consists of four XeIrSbF12 clusters. Xe(1) is bonded in a linear geometry to one F(11) and one F(12) atom. Ir(1) is bonded to one F(10), one F(11), one F(6), one F(7), one F(8), and one F(9) atom to form IrF6 octahedra that share  a cornercorner with one Sb(1)F6 octahedra. The corner-sharing octahedral tilt angles are 40°. Sb(1) is bonded to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom to form SbF6 octahedra that share  a cornercorner with one Ir(1)F6 octahedra. The corner-sharing octahedral tilt angles are 40°. There are twelve inequivalent F sites. In the first F site, F(11) is bonded in a bent 120 degrees geometry to one Xe(1) and one Ir(1) atom. In the second F site, F(12) is bonded in a single-bond geometry to one Xe(1) atom. In the third F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth F site, F(4) is bonded in a single-bond geometry to one Sb(1) atom. In the seventh F site, F(5) is bonded in a single-bond geometry to one Sb(1) atom. In the eighth F site, F(6) is bonded in a bent 150 degrees geometry to one Ir(1) and one Sb(1) atom. In the ninth F site, F(7) is bonded in a single-bond geometry to one Ir(1) atom. In the tenth F site, F(8) is bonded in a single-bond geometry to one Ir(1) atom. In the eleventh F site, F(9) is bonded in a single-bond geometry to one Ir(1) atom. In the twelfth F site, F(10) is bonded in a single-bond geometry to one Ir(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_SbIrXeF12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.261
_cell_length_b   11.261
_cell_length_c   8.253
_cell_angle_alpha   89.964
_cell_angle_beta   89.964
_cell_angle_gamma   148.189
_symmetry_Int_Tables_number   1
_cell_volume   551.696
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.285  0.451  0.030  1.0
  Sb  Sb1  1  0.451  0.285  0.530  1.0
  Ir  Ir2  1  0.378  0.871  0.965  1.0
  Ir  Ir3  1  0.871  0.378  0.465  1.0
  Xe  Xe4  1  0.967  0.777  0.030  1.0
  Xe  Xe5  1  0.777  0.967  0.530  1.0
  F  F6  1  0.352  0.343  0.045  1.0
  F  F7  1  0.343  0.352  0.545  1.0
  F  F8  1  0.517  0.678  0.876  1.0
  F  F9  1  0.678  0.517  0.376  1.0
  F  F10  1  0.041  0.239  0.179  1.0
  F  F11  1  0.239  0.041  0.679  1.0
  F  F12  1  0.077  0.254  0.857  1.0
  F  F13  1  0.254  0.077  0.357  1.0
  F  F14  1  0.477  0.660  0.203  1.0
  F  F15  1  0.660  0.477  0.703  1.0
  F  F16  1  0.215  0.577  0.008  1.0
  F  F17  1  0.577  0.215  0.508  1.0
  F  F18  1  0.394  0.843  0.745  1.0
  F  F19  1  0.843  0.394  0.245  1.0
  F  F20  1  0.340  0.878  0.183  1.0
  F  F21  1  0.878  0.340  0.683  1.0
  F  F22  1  0.658  0.036  0.007  1.0
  F  F23  1  0.036  0.658  0.507  1.0
  F  F24  1  0.520  0.138  0.924  1.0
  F  F25  1  0.138  0.520  0.424  1.0
  F  F26  1  0.077  0.691  0.924  1.0
  F  F27  1  0.691  0.077  0.424  1.0
  F  F28  1  0.860  0.839  0.125  1.0
  F  F29  1  0.839  0.860  0.625  1.0
[/CIF]
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The structure described by XeIrSbF12 is Indium-like structured and crystallizes in the monoclinic Cc space group. The structure is zero-dimensional and consists of four XeIrSbF12 clusters. Xe(1) is bonded in a linear geometry to one F(11) and one F(12) atom. Ir(1) is bonded to one F(10), one F(11), one F(6), one F(7), one F(8), and one F(9) atom to form IrF6 octahedra that share  a cornercorner with one Sb(1)F6 octahedra. The corner-sharing octahedral tilt angles are 40°. Sb(1) is bonded to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom to form SbF6 octahedra that share  a cornercorner with one Ir(1)F6 octahedra. The corner-sharing octahedral tilt angles are 40°. There are twelve inequivalent F sites. In the first F site, F(11) is bonded in a bent 120 degrees geometry to one Xe(1) and one Ir(1) atom. In the second F site, F(12) is bonded in a single-bond geometry to one Xe(1) atom. In the third F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth F site, F(4) is bonded in a single-bond geometry to one Sb(1) atom. In the seventh F site, F(5) is bonded in a single-bond geometry to one Sb(1) atom. In the eighth F site, F(6) is bonded in a bent 150 degrees geometry to one Ir(1) and one Sb(1) atom. In the ninth F site, F(7) is bonded in a single-bond geometry to one Ir(1) atom. In the tenth F site, F(8) is bonded in a single-bond geometry to one Ir(1) atom. In the eleventh F site, F(9) is bonded in a single-bond geometry to one Ir(1) atom. In the twelfth F site, F(10) is bonded in a single-bond geometry to one Ir(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_SbIrXeF12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.261
_cell_length_b   11.261
_cell_length_c   8.253
_cell_angle_alpha   89.964
_cell_angle_beta   89.964
_cell_angle_gamma   148.189
_symmetry_Int_Tables_number   1
_cell_volume   551.696
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.285  0.451  0.030  1.0
  Sb  Sb1  1  0.451  0.285  0.530  1.0
  Ir  Ir2  1  0.378  0.871  0.965  1.0
  Ir  Ir3  1  0.871  0.378  0.465  1.0
  Xe  Xe4  1  0.967  0.777  0.030  1.0
  Xe  Xe5  1  0.777  0.967  0.530  1.0
  F  F6  1  0.352  0.343  0.045  1.0
  F  F7  1  0.343  0.352  0.545  1.0
  F  F8  1  0.517  0.678  0.876  1.0
  F  F9  1  0.678  0.517  0.376  1.0
  F  F10  1  0.041  0.239  0.179  1.0
  F  F11  1  0.239  0.041  0.679  1.0
  F  F12  1  0.077  0.254  0.857  1.0
  F  F13  1  0.254  0.077  0.357  1.0
  F  F14  1  0.477  0.660  0.203  1.0
  F  F15  1  0.660  0.477  0.703  1.0
  F  F16  1  0.215  0.577  0.008  1.0
  F  F17  1  0.577  0.215  0.508  1.0
  F  F18  1  0.394  0.843  0.745  1.0
  F  F19  1  0.843  0.394  0.245  1.0
  F  F20  1  0.340  0.878  0.183  1.0
  F  F21  1  0.878  0.340  0.683  1.0
  F  F22  1  0.658  0.036  0.007  1.0
  F  F23  1  0.036  0.658  0.507  1.0
  F  F24  1  0.520  0.138  0.924  1.0
  F  F25  1  0.138  0.520  0.424  1.0
  F  F26  1  0.077  0.691  0.924  1.0
  F  F27  1  0.691  0.077  0.424  1.0
  F  F28  1  0.860  0.839  0.125  1.0
  F  F29  1  0.839  0.860  0.625  1.0
[/CIF]
.