The structure described by Li4Mn3SbO8 crystallizes in the triclinic P-1 space group. There are six inequivalent Li sites. In the first Li site, Li(1) is bonded to two equivalent O(4), two equivalent O(5), and two equivalent O(8) atoms to form LiO6 octahedra that share corners with six equivalent Sb(1)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, edges with two equivalent Mn(5)O6 octahedra, edges with two equivalent Li(3)O5 square pyramids, and edges with two equivalent Li(6)O5 square pyramids. The corner-sharing octahedral tilt angles range from 2-3°. In the second Li site, Li(2) is bonded to two equivalent O(3), two equivalent O(6), and two equivalent O(7) atoms to form LiO6 octahedra that share corners with six equivalent Sb(1)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with two equivalent Mn(4)O6 octahedra, edges with two equivalent Li(3)O5 square pyramids, and edges with two equivalent Li(6)O5 square pyramids. The corner-sharing octahedral tilt angles range from 2-3°. In the third Li site, Li(3) is bonded to one O(1), one O(5), one O(6), one O(7), and one O(8) atom to form distorted LiO5 square pyramids that share  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(5)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra, corners with three equivalent Mn(4)O6 octahedra, corners with two equivalent Li(6)O5 square pyramids,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra, and edges with two equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-86°. In the fourth Li site, Li(4) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(7) atoms to form LiO6 octahedra that share corners with six equivalent Mn(1)O6 octahedra, corners with two equivalent Li(6)O5 square pyramids, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with two equivalent Mn(4)O6 octahedra, edges with two equivalent Sb(1)O6 octahedra, and edges with two equivalent Li(3)O5 square pyramids. The corner-sharing octahedral tilt angles range from 9-16°. In the fifth Li site, Li(5) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(8) atoms to form LiO6 octahedra that share corners with six equivalent Mn(1)O6 octahedra, corners with two equivalent Li(3)O5 square pyramids, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, edges with two equivalent Mn(5)O6 octahedra, edges with two equivalent Sb(1)O6 octahedra, and edges with two equivalent Li(6)O5 square pyramids. The corner-sharing octahedral tilt angles range from 9-15°. In the sixth Li site, Li(6) is bonded to one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form distorted LiO5 square pyramids that share  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with three equivalent Mn(5)O6 octahedra, corners with two equivalent Li(3)O5 square pyramids,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra, and edges with two equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-86°. There are five inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(7), and one O(8) atom to form MnO6 octahedra that share corners with three equivalent Li(4)O6 octahedra, corners with three equivalent Li(5)O6 octahedra,  a cornercorner with one Li(3)O5 square pyramid,  a cornercorner with one Li(6)O5 square pyramid,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra, edges with two equivalent Sb(1)O6 octahedra,  an edgeedge with one Li(3)O5 square pyramid, and  an edgeedge with one Li(6)O5 square pyramid. The corner-sharing octahedral tilt angles range from 9-16°. In the second Mn site, Mn(2) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(6) atoms to form MnO6 octahedra that share corners with four equivalent Li(6)O5 square pyramids, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Mn(4)O6 octahedra, edges with two equivalent Sb(1)O6 octahedra, and edges with two equivalent Li(3)O5 square pyramids. In the third Mn site, Mn(3) is bonded to two equivalent O(2), two equivalent O(5), and two equivalent O(8) atoms to form MnO6 octahedra that share corners with four equivalent Li(3)O5 square pyramids, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Mn(5)O6 octahedra, edges with two equivalent Sb(1)O6 octahedra, and edges with two equivalent Li(6)O5 square pyramids. In the fourth Mn site, Mn(4) is bonded to two equivalent O(1), two equivalent O(6), and two equivalent O(7) atoms to form MnO6 octahedra that share corners with two equivalent Li(6)O5 square pyramids, corners with six equivalent Li(3)O5 square pyramids, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, and edges with two equivalent Sb(1)O6 octahedra. In the fifth Mn site, Mn(5) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(5) atoms to form MnO6 octahedra that share corners with two equivalent Li(3)O5 square pyramids, corners with six equivalent Li(6)O5 square pyramids, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, and edges with two equivalent Sb(1)O6 octahedra. Sb(1) is bonded to one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom to form SbO6 octahedra that share corners with three equivalent Li(1)O6 octahedra, corners with three equivalent Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Li(3)O5 square pyramids, and edges with two equivalent Li(6)O5 square pyramids. The corner-sharing octahedral tilt angles range from 2-3°. There are eight inequivalent O sites. In the first O site, O(1) is bonded to one Li(3), one Li(4), one Mn(1), one Mn(2), and one Mn(4) atom to form distorted OLi2Mn3 square pyramids that share  a cornercorner with one O(3)Li3Mn2Sb octahedra,  a cornercorner with one O(4)Li3Mn2Sb octahedra,  a cornercorner with one O(5)Li3Mn2Sb octahedra,  a cornercorner with one O(6)Li3Mn2Sb octahedra,  a cornercorner with one O(2)Li2Mn3 square pyramid, corners with three equivalent O(1)Li2Mn3 square pyramids,  an edgeedge with one O(8)Li3Mn2Sb octahedra, edges with two equivalent O(3)Li3Mn2Sb octahedra, edges with two equivalent O(6)Li3Mn2Sb octahedra, and edges with three equivalent O(7)Li3Mn2Sb octahedra. The corner-sharing octahedral tilt angles range from 79-82°. In the second O site, O(2) is bonded to one Li(5), one Li(6), one Mn(1), one Mn(3), and one Mn(5) atom to form distorted OLi2Mn3 square pyramids that share  a cornercorner with one O(5)Li3Mn2Sb octahedra,  a cornercorner with one O(6)Li3Mn2Sb octahedra,  a cornercorner with one O(7)Li3Mn2Sb octahedra,  a cornercorner with one O(8)Li3Mn2Sb octahedra,  a cornercorner with one O(1)Li2Mn3 square pyramid, corners with three equivalent O(2)Li2Mn3 square pyramids,  an edgeedge with one O(3)Li3Mn2Sb octahedra, edges with two equivalent O(5)Li3Mn2Sb octahedra, edges with two equivalent O(8)Li3Mn2Sb octahedra, and edges with three equivalent O(4)Li3Mn2Sb octahedra. The corner-sharing octahedral tilt angles range from 80-83°. In the third O site, O(3) is bonded to one Li(2), one Li(4), one Li(6), one Mn(1), one Mn(2), and one Sb(1) atom to form OLi3Mn2Sb octahedra that share corners with three equivalent O(3)Li3Mn2Sb octahedra, corners with three equivalent O(4)Li3Mn2Sb octahedra,  a cornercorner with one O(1)Li2Mn3 square pyramid,  an edgeedge with one O(5)Li3Mn2Sb octahedra,  an edgeedge with one O(8)Li3Mn2Sb octahedra, edges with three equivalent O(6)Li3Mn2Sb octahedra, edges with three equivalent O(7)Li3Mn2Sb octahedra,  an edgeedge with one O(2)Li2Mn3 square pyramid, and edges with two equivalent O(1)Li2Mn3 square pyramids. The corner-sharing octahedral tilt angles range from 0-11°. In the fourth O site, O(4) is bonded to one Li(1), one Li(5), one Li(6), one Mn(1), one Mn(5), and one Sb(1) atom to form OLi3Mn2Sb octahedra that share corners with three equivalent O(3)Li3Mn2Sb octahedra, corners with three equivalent O(4)Li3Mn2Sb octahedra,  a cornercorner with one O(1)Li2Mn3 square pyramid,  an edgeedge with one O(6)Li3Mn2Sb octahedra,  an edgeedge with one O(7)Li3Mn2Sb octahedra, edges with three equivalent O(5)Li3Mn2Sb octahedra, edges with three equivalent O(8)Li3Mn2Sb octahedra, and edges with three equivalent O(2)Li2Mn3 square pyramids. The corner-sharing octahedral tilt angles range from 0-11°. In the fifth O site, O(5) is bonded to one Li(1), one Li(3), one Li(6), one Mn(3), one Mn(5), and one Sb(1) atom to form OLi3Mn2Sb octahedra that share corners with three equivalent O(5)Li3Mn2Sb octahedra, corners with three equivalent O(6)Li3Mn2Sb octahedra,  a cornercorner with one O(1)Li2Mn3 square pyramid,  a cornercorner with one O(2)Li2Mn3 square pyramid,  an edgeedge with one O(3)Li3Mn2Sb octahedra,  an edgeedge with one O(7)Li3Mn2Sb octahedra, edges with three equivalent O(4)Li3Mn2Sb octahedra, edges with three equivalent O(8)Li3Mn2Sb octahedra, and edges with two equivalent O(2)Li2Mn3 square pyramids. The corner-sharing octahedral tilt angles range from 0-11°. In the sixth O site, O(6) is bonded to one Li(2), one Li(3), one Li(6), one Mn(2), one Mn(4), and one Sb(1) atom to form OLi3Mn2Sb octahedra that share corners with three equivalent O(5)Li3Mn2Sb octahedra, corners with three equivalent O(6)Li3Mn2Sb octahedra,  a cornercorner with one O(1)Li2Mn3 square pyramid,  a cornercorner with one O(2)Li2Mn3 square pyramid,  an edgeedge with one O(4)Li3Mn2Sb octahedra,  an edgeedge with one O(8)Li3Mn2Sb octahedra, edges with three equivalent O(3)Li3Mn2Sb octahedra, edges with three equivalent O(7)Li3Mn2Sb octahedra, and edges with two equivalent O(1)Li2Mn3 square pyramids. The corner-sharing octahedral tilt angles range from 0-11°. In the seventh O site, O(7) is bonded to one Li(2), one Li(3), one Li(4), one Mn(1), one Mn(4), and one Sb(1) atom to form OLi3Mn2Sb octahedra that share corners with three equivalent O(7)Li3Mn2Sb octahedra, corners with three equivalent O(8)Li3Mn2Sb octahedra,  a cornercorner with one O(2)Li2Mn3 square pyramid,  an edgeedge with one O(4)Li3Mn2Sb octahedra,  an edgeedge with one O(5)Li3Mn2Sb octahedra, edges with three equivalent O(3)Li3Mn2Sb octahedra, edges with three equivalent O(6)Li3Mn2Sb octahedra, and edges with three equivalent O(1)Li2Mn3 square pyramids. The corner-sharing octahedral tilt angles range from 0-11°. In the eighth O site, O(8) is bonded to one Li(1), one Li(3), one Li(5), one Mn(1), one Mn(3), and one Sb(1) atom to form OLi3Mn2Sb octahedra that share corners with three equivalent O(7)Li3Mn2Sb octahedra, corners with three equivalent O(8)Li3Mn2Sb octahedra,  a cornercorner with one O(2)Li2Mn3 square pyramid,  an edgeedge with one O(3)Li3Mn2Sb octahedra,  an edgeedge with one O(6)Li3Mn2Sb octahedra, edges with three equivalent O(4)Li3Mn2Sb octahedra, edges with three equivalent O(5)Li3Mn2Sb octahedra,  an edgeedge with one O(1)Li2Mn3 square pyramid, and edges with two equivalent O(2)Li2Mn3 square pyramids. The corner-sharing octahedral tilt angles range from 0-11°. is represented by the CIF card [CIF]
data_Li4Mn3SbO8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.099
_cell_length_b   6.097
_cell_length_c   10.777
_cell_angle_alpha   90.387
_cell_angle_beta   72.853
_cell_angle_gamma   62.070
_symmetry_Int_Tables_number   1
_cell_volume   333.342
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.500  0.750  0.250  1.0
  Li  Li1  1  0.500  0.250  0.750  1.0
  Li  Li2  1  0.527  0.969  0.985  1.0
  Li  Li3  1  0.473  0.531  0.515  1.0
  Li  Li4  1  1.000  0.750  0.750  1.0
  Li  Li5  1  1.000  0.250  0.250  1.0
  Li  Li6  1  0.016  0.487  0.015  1.0
  Li  Li7  1  0.983  0.013  0.485  1.0
  Mn  Mn8  1  0.502  0.498  0.001  1.0
  Mn  Mn9  1  0.499  0.001  0.499  1.0
  Mn  Mn10  1  0.500  0.750  0.750  1.0
  Mn  Mn11  1  0.000  0.750  0.250  1.0
  Mn  Mn12  1  0.000  0.250  0.750  1.0
  Mn  Mn13  1  0.499  0.250  0.250  1.0
  Sb  Sb14  1  0.001  0.499  0.500  1.0
  Sb  Sb15  1  0.999  0.001  1.000  1.0
  O  O16  1  0.280  0.867  0.642  1.0
  O  O17  1  0.225  0.421  0.142  1.0
  O  O18  1  0.775  0.079  0.358  1.0
  O  O19  1  0.720  0.633  0.858  1.0
  O  O20  1  0.235  0.657  0.880  1.0
  O  O21  1  0.225  0.151  0.387  1.0
  O  O22  1  0.764  0.875  0.114  1.0
  O  O23  1  0.761  0.379  0.614  1.0
  O  O24  1  0.766  0.112  0.886  1.0
  O  O25  1  0.779  0.613  0.379  1.0
  O  O26  1  0.774  0.349  0.113  1.0
  O  O27  1  0.765  0.844  0.620  1.0
  O  O28  1  0.238  0.121  0.887  1.0
  O  O29  1  0.236  0.625  0.386  1.0
  O  O30  1  0.221  0.887  0.121  1.0
  O  O31  1  0.235  0.389  0.614  1.0
[/CIF]
.
The structure described by Li4Mn3SbO8 crystallizes in the triclinic P-1 space group. There are six inequivalent Li sites. In the first Li site, Li(1) is bonded to two equivalent O(4), two equivalent O(5), and two equivalent O(8) atoms to form LiO6 octahedra that share corners with six equivalent Sb(1)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, edges with two equivalent Mn(5)O6 octahedra, edges with two equivalent Li(3)O5 square pyramids, and edges with two equivalent Li(6)O5 square pyramids. The corner-sharing octahedral tilt angles range from 2-3°. In the second Li site, Li(2) is bonded to two equivalent O(3), two equivalent O(6), and two equivalent O(7) atoms to form LiO6 octahedra that share corners with six equivalent Sb(1)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with two equivalent Mn(4)O6 octahedra, edges with two equivalent Li(3)O5 square pyramids, and edges with two equivalent Li(6)O5 square pyramids. The corner-sharing octahedral tilt angles range from 2-3°. In the third Li site, Li(3) is bonded to one O(1), one O(5), one O(6), one O(7), and one O(8) atom to form distorted LiO5 square pyramids that share  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(5)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra, corners with three equivalent Mn(4)O6 octahedra, corners with two equivalent Li(6)O5 square pyramids,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra, and edges with two equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-86°. In the fourth Li site, Li(4) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(7) atoms to form LiO6 octahedra that share corners with six equivalent Mn(1)O6 octahedra, corners with two equivalent Li(6)O5 square pyramids, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with two equivalent Mn(4)O6 octahedra, edges with two equivalent Sb(1)O6 octahedra, and edges with two equivalent Li(3)O5 square pyramids. The corner-sharing octahedral tilt angles range from 9-16°. In the fifth Li site, Li(5) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(8) atoms to form LiO6 octahedra that share corners with six equivalent Mn(1)O6 octahedra, corners with two equivalent Li(3)O5 square pyramids, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, edges with two equivalent Mn(5)O6 octahedra, edges with two equivalent Sb(1)O6 octahedra, and edges with two equivalent Li(6)O5 square pyramids. The corner-sharing octahedral tilt angles range from 9-15°. In the sixth Li site, Li(6) is bonded to one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form distorted LiO5 square pyramids that share  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with three equivalent Mn(5)O6 octahedra, corners with two equivalent Li(3)O5 square pyramids,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra, and edges with two equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-86°. There are five inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(7), and one O(8) atom to form MnO6 octahedra that share corners with three equivalent Li(4)O6 octahedra, corners with three equivalent Li(5)O6 octahedra,  a cornercorner with one Li(3)O5 square pyramid,  a cornercorner with one Li(6)O5 square pyramid,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra, edges with two equivalent Sb(1)O6 octahedra,  an edgeedge with one Li(3)O5 square pyramid, and  an edgeedge with one Li(6)O5 square pyramid. The corner-sharing octahedral tilt angles range from 9-16°. In the second Mn site, Mn(2) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(6) atoms to form MnO6 octahedra that share corners with four equivalent Li(6)O5 square pyramids, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Mn(4)O6 octahedra, edges with two equivalent Sb(1)O6 octahedra, and edges with two equivalent Li(3)O5 square pyramids. In the third Mn site, Mn(3) is bonded to two equivalent O(2), two equivalent O(5), and two equivalent O(8) atoms to form MnO6 octahedra that share corners with four equivalent Li(3)O5 square pyramids, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Mn(5)O6 octahedra, edges with two equivalent Sb(1)O6 octahedra, and edges with two equivalent Li(6)O5 square pyramids. In the fourth Mn site, Mn(4) is bonded to two equivalent O(1), two equivalent O(6), and two equivalent O(7) atoms to form MnO6 octahedra that share corners with two equivalent Li(6)O5 square pyramids, corners with six equivalent Li(3)O5 square pyramids, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, and edges with two equivalent Sb(1)O6 octahedra. In the fifth Mn site, Mn(5) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(5) atoms to form MnO6 octahedra that share corners with two equivalent Li(3)O5 square pyramids, corners with six equivalent Li(6)O5 square pyramids, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, and edges with two equivalent Sb(1)O6 octahedra. Sb(1) is bonded to one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom to form SbO6 octahedra that share corners with three equivalent Li(1)O6 octahedra, corners with three equivalent Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Li(3)O5 square pyramids, and edges with two equivalent Li(6)O5 square pyramids. The corner-sharing octahedral tilt angles range from 2-3°. There are eight inequivalent O sites. In the first O site, O(1) is bonded to one Li(3), one Li(4), one Mn(1), one Mn(2), and one Mn(4) atom to form distorted OLi2Mn3 square pyramids that share  a cornercorner with one O(3)Li3Mn2Sb octahedra,  a cornercorner with one O(4)Li3Mn2Sb octahedra,  a cornercorner with one O(5)Li3Mn2Sb octahedra,  a cornercorner with one O(6)Li3Mn2Sb octahedra,  a cornercorner with one O(2)Li2Mn3 square pyramid, corners with three equivalent O(1)Li2Mn3 square pyramids,  an edgeedge with one O(8)Li3Mn2Sb octahedra, edges with two equivalent O(3)Li3Mn2Sb octahedra, edges with two equivalent O(6)Li3Mn2Sb octahedra, and edges with three equivalent O(7)Li3Mn2Sb octahedra. The corner-sharing octahedral tilt angles range from 79-82°. In the second O site, O(2) is bonded to one Li(5), one Li(6), one Mn(1), one Mn(3), and one Mn(5) atom to form distorted OLi2Mn3 square pyramids that share  a cornercorner with one O(5)Li3Mn2Sb octahedra,  a cornercorner with one O(6)Li3Mn2Sb octahedra,  a cornercorner with one O(7)Li3Mn2Sb octahedra,  a cornercorner with one O(8)Li3Mn2Sb octahedra,  a cornercorner with one O(1)Li2Mn3 square pyramid, corners with three equivalent O(2)Li2Mn3 square pyramids,  an edgeedge with one O(3)Li3Mn2Sb octahedra, edges with two equivalent O(5)Li3Mn2Sb octahedra, edges with two equivalent O(8)Li3Mn2Sb octahedra, and edges with three equivalent O(4)Li3Mn2Sb octahedra. The corner-sharing octahedral tilt angles range from 80-83°. In the third O site, O(3) is bonded to one Li(2), one Li(4), one Li(6), one Mn(1), one Mn(2), and one Sb(1) atom to form OLi3Mn2Sb octahedra that share corners with three equivalent O(3)Li3Mn2Sb octahedra, corners with three equivalent O(4)Li3Mn2Sb octahedra,  a cornercorner with one O(1)Li2Mn3 square pyramid,  an edgeedge with one O(5)Li3Mn2Sb octahedra,  an edgeedge with one O(8)Li3Mn2Sb octahedra, edges with three equivalent O(6)Li3Mn2Sb octahedra, edges with three equivalent O(7)Li3Mn2Sb octahedra,  an edgeedge with one O(2)Li2Mn3 square pyramid, and edges with two equivalent O(1)Li2Mn3 square pyramids. The corner-sharing octahedral tilt angles range from 0-11°. In the fourth O site, O(4) is bonded to one Li(1), one Li(5), one Li(6), one Mn(1), one Mn(5), and one Sb(1) atom to form OLi3Mn2Sb octahedra that share corners with three equivalent O(3)Li3Mn2Sb octahedra, corners with three equivalent O(4)Li3Mn2Sb octahedra,  a cornercorner with one O(1)Li2Mn3 square pyramid,  an edgeedge with one O(6)Li3Mn2Sb octahedra,  an edgeedge with one O(7)Li3Mn2Sb octahedra, edges with three equivalent O(5)Li3Mn2Sb octahedra, edges with three equivalent O(8)Li3Mn2Sb octahedra, and edges with three equivalent O(2)Li2Mn3 square pyramids. The corner-sharing octahedral tilt angles range from 0-11°. In the fifth O site, O(5) is bonded to one Li(1), one Li(3), one Li(6), one Mn(3), one Mn(5), and one Sb(1) atom to form OLi3Mn2Sb octahedra that share corners with three equivalent O(5)Li3Mn2Sb octahedra, corners with three equivalent O(6)Li3Mn2Sb octahedra,  a cornercorner with one O(1)Li2Mn3 square pyramid,  a cornercorner with one O(2)Li2Mn3 square pyramid,  an edgeedge with one O(3)Li3Mn2Sb octahedra,  an edgeedge with one O(7)Li3Mn2Sb octahedra, edges with three equivalent O(4)Li3Mn2Sb octahedra, edges with three equivalent O(8)Li3Mn2Sb octahedra, and edges with two equivalent O(2)Li2Mn3 square pyramids. The corner-sharing octahedral tilt angles range from 0-11°. In the sixth O site, O(6) is bonded to one Li(2), one Li(3), one Li(6), one Mn(2), one Mn(4), and one Sb(1) atom to form OLi3Mn2Sb octahedra that share corners with three equivalent O(5)Li3Mn2Sb octahedra, corners with three equivalent O(6)Li3Mn2Sb octahedra,  a cornercorner with one O(1)Li2Mn3 square pyramid,  a cornercorner with one O(2)Li2Mn3 square pyramid,  an edgeedge with one O(4)Li3Mn2Sb octahedra,  an edgeedge with one O(8)Li3Mn2Sb octahedra, edges with three equivalent O(3)Li3Mn2Sb octahedra, edges with three equivalent O(7)Li3Mn2Sb octahedra, and edges with two equivalent O(1)Li2Mn3 square pyramids. The corner-sharing octahedral tilt angles range from 0-11°. In the seventh O site, O(7) is bonded to one Li(2), one Li(3), one Li(4), one Mn(1), one Mn(4), and one Sb(1) atom to form OLi3Mn2Sb octahedra that share corners with three equivalent O(7)Li3Mn2Sb octahedra, corners with three equivalent O(8)Li3Mn2Sb octahedra,  a cornercorner with one O(2)Li2Mn3 square pyramid,  an edgeedge with one O(4)Li3Mn2Sb octahedra,  an edgeedge with one O(5)Li3Mn2Sb octahedra, edges with three equivalent O(3)Li3Mn2Sb octahedra, edges with three equivalent O(6)Li3Mn2Sb octahedra, and edges with three equivalent O(1)Li2Mn3 square pyramids. The corner-sharing octahedral tilt angles range from 0-11°. In the eighth O site, O(8) is bonded to one Li(1), one Li(3), one Li(5), one Mn(1), one Mn(3), and one Sb(1) atom to form OLi3Mn2Sb octahedra that share corners with three equivalent O(7)Li3Mn2Sb octahedra, corners with three equivalent O(8)Li3Mn2Sb octahedra,  a cornercorner with one O(2)Li2Mn3 square pyramid,  an edgeedge with one O(3)Li3Mn2Sb octahedra,  an edgeedge with one O(6)Li3Mn2Sb octahedra, edges with three equivalent O(4)Li3Mn2Sb octahedra, edges with three equivalent O(5)Li3Mn2Sb octahedra,  an edgeedge with one O(1)Li2Mn3 square pyramid, and edges with two equivalent O(2)Li2Mn3 square pyramids. The corner-sharing octahedral tilt angles range from 0-11°. is represented by the CIF card [CIF]
data_Li4Mn3SbO8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.099
_cell_length_b   6.097
_cell_length_c   10.777
_cell_angle_alpha   90.387
_cell_angle_beta   72.853
_cell_angle_gamma   62.070
_symmetry_Int_Tables_number   1
_cell_volume   333.342
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.500  0.750  0.250  1.0
  Li  Li1  1  0.500  0.250  0.750  1.0
  Li  Li2  1  0.527  0.969  0.985  1.0
  Li  Li3  1  0.473  0.531  0.515  1.0
  Li  Li4  1  1.000  0.750  0.750  1.0
  Li  Li5  1  1.000  0.250  0.250  1.0
  Li  Li6  1  0.016  0.487  0.015  1.0
  Li  Li7  1  0.983  0.013  0.485  1.0
  Mn  Mn8  1  0.502  0.498  0.001  1.0
  Mn  Mn9  1  0.499  0.001  0.499  1.0
  Mn  Mn10  1  0.500  0.750  0.750  1.0
  Mn  Mn11  1  0.000  0.750  0.250  1.0
  Mn  Mn12  1  0.000  0.250  0.750  1.0
  Mn  Mn13  1  0.499  0.250  0.250  1.0
  Sb  Sb14  1  0.001  0.499  0.500  1.0
  Sb  Sb15  1  0.999  0.001  1.000  1.0
  O  O16  1  0.280  0.867  0.642  1.0
  O  O17  1  0.225  0.421  0.142  1.0
  O  O18  1  0.775  0.079  0.358  1.0
  O  O19  1  0.720  0.633  0.858  1.0
  O  O20  1  0.235  0.657  0.880  1.0
  O  O21  1  0.225  0.151  0.387  1.0
  O  O22  1  0.764  0.875  0.114  1.0
  O  O23  1  0.761  0.379  0.614  1.0
  O  O24  1  0.766  0.112  0.886  1.0
  O  O25  1  0.779  0.613  0.379  1.0
  O  O26  1  0.774  0.349  0.113  1.0
  O  O27  1  0.765  0.844  0.620  1.0
  O  O28  1  0.238  0.121  0.887  1.0
  O  O29  1  0.236  0.625  0.386  1.0
  O  O30  1  0.221  0.887  0.121  1.0
  O  O31  1  0.235  0.389  0.614  1.0
[/CIF]
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