The structure described by Dy11Y5O24 crystallizes in the triclinic P1 space group. There are eleven inequivalent Dy sites. In the first Dy site, Dy(1) is bonded in a 1-coordinate geometry to one O(1), one O(11), one O(12), and one O(4) atom. In the second Dy site, Dy(2) is bonded in a square co-planar geometry to one O(18), one O(2), one O(24), and one O(7) atom. In the third Dy site, Dy(3) is bonded in a distorted hexagonal bipyramidal geometry to one O(10), one O(11), one O(13), one O(15), one O(19), one O(20), one O(5), and one O(6) atom. In the fourth Dy site, Dy(4) is bonded in a distorted bent 150 degrees geometry to one O(10), one O(17), one O(18), and one O(9) atom. In the fifth Dy site, Dy(5) is bonded in a distorted square co-planar geometry to one O(1), one O(17), one O(23), and one O(8) atom. In the sixth Dy site, Dy(6) is bonded in a distorted bent 150 degrees geometry to one O(15), one O(16), one O(7), and one O(8) atom. In the seventh Dy site, Dy(7) is bonded in a 4-coordinate geometry to one O(15), one O(19), one O(2), one O(22), and one O(23) atom. In the eighth Dy site, Dy(8) is bonded in a 4-coordinate geometry to one O(11), one O(14), one O(17), and one O(7) atom. In the ninth Dy site, Dy(9) is bonded in a 4-coordinate geometry to one O(10), one O(11), one O(14), and one O(16) atom. In the tenth Dy site, Dy(10) is bonded in a 7-coordinate geometry to one O(1), one O(17), one O(20), one O(21), one O(22), one O(24), and one O(7) atom. In the eleventh Dy site, Dy(11) is bonded in a 1-coordinate geometry to one O(13), one O(14), one O(22), and one O(23) atom. There are five inequivalent Y sites. In the first Y site, Y(1) is bonded in a 8-coordinate geometry to one O(12), one O(14), one O(16), one O(21), one O(22), one O(3), one O(4), and one O(9) atom. In the second Y site, Y(2) is bonded in a 7-coordinate geometry to one O(18), one O(2), one O(23), one O(3), one O(4), one O(6), and one O(8) atom. In the third Y site, Y(3) is bonded in a 4-coordinate geometry to one O(12), one O(13), one O(15), and one O(9) atom. In the fourth Y site, Y(4) is bonded in a 4-coordinate geometry to one O(1), one O(10), one O(24), one O(4), and one O(5) atom. In the fifth Y site, Y(5) is bonded in a 4-coordinate geometry to one O(12), one O(13), one O(18), and one O(8) atom. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Dy(1), one Dy(10), one Dy(5), and one Y(4) atom. In the second O site, O(2) is bonded in a 1-coordinate geometry to one Dy(2), one Dy(7), and one Y(2) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Y(1), one Y(2), and one O(18) atom. In the fourth O site, O(4) is bonded to one Dy(1), one Y(1), one Y(2), and one Y(4) atom to form distorted ODyY3 trigonal pyramids that share  a cornercorner with one O(8)Dy2Y2 trigonal pyramid and  a cornercorner with one O(22)Dy3Y trigonal pyramid. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Dy(3), one Y(4), and one O(10) atom. In the sixth O site, O(6) is bonded in a 1-coordinate geometry to one Dy(3) and one Y(2) atom. In the seventh O site, O(7) is bonded in a 5-coordinate geometry to one Dy(10), one Dy(2), one Dy(6), one Dy(8), and one O(21) atom. In the eighth O site, O(8) is bonded to one Dy(5), one Dy(6), one Y(2), and one Y(5) atom to form distorted ODy2Y2 trigonal pyramids that share  a cornercorner with one O(17)Dy4 trigonal pyramid and  a cornercorner with one O(4)DyY3 trigonal pyramid. In the ninth O site, O(9) is bonded in a distorted T-shaped geometry to one Dy(4), one Y(1), and one Y(3) atom. In the tenth O site, O(10) is bonded in a 5-coordinate geometry to one Dy(3), one Dy(4), one Dy(9), one Y(4), and one O(5) atom. In the eleventh O site, O(11) is bonded in a 4-coordinate geometry to one Dy(1), one Dy(3), one Dy(8), and one Dy(9) atom. In the twelfth O site, O(12) is bonded in a 1-coordinate geometry to one Dy(1), one Y(1), one Y(3), and one Y(5) atom. In the thirteenth O site, O(13) is bonded in a 4-coordinate geometry to one Dy(11), one Dy(3), one Y(3), and one Y(5) atom. In the fourteenth O site, O(14) is bonded in a 1-coordinate geometry to one Dy(11), one Dy(8), one Dy(9), and one Y(1) atom. In the fifteenth O site, O(15) is bonded in a 5-coordinate geometry to one Dy(3), one Dy(6), one Dy(7), one Y(3), and one O(19) atom. In the sixteenth O site, O(16) is bonded in a distorted T-shaped geometry to one Dy(6), one Dy(9), and one Y(1) atom. In the seventeenth O site, O(17) is bonded to one Dy(10), one Dy(4), one Dy(5), and one Dy(8) atom to form distorted ODy4 trigonal pyramids that share  a cornercorner with one O(8)Dy2Y2 trigonal pyramid and  a cornercorner with one O(22)Dy3Y trigonal pyramid. In the eighteenth O site, O(18) is bonded in a 5-coordinate geometry to one Dy(2), one Dy(4), one Y(2), one Y(5), and one O(3) atom. In the nineteenth O site, O(19) is bonded in a 2-coordinate geometry to one Dy(3), one Dy(7), and one O(15) atom. In the twentieth O site, O(20) is bonded in a 1-coordinate geometry to one Dy(10) and one Dy(3) atom. In the twenty-first O site, O(21) is bonded in a distorted single-bond geometry to one Dy(10), one Y(1), and one O(7) atom. In the twenty-second O site, O(22) is bonded to one Dy(10), one Dy(11), one Dy(7), and one Y(1) atom to form distorted ODy3Y trigonal pyramids that share  a cornercorner with one O(17)Dy4 trigonal pyramid and  a cornercorner with one O(4)DyY3 trigonal pyramid. In the twenty-third O site, O(23) is bonded in a 4-coordinate geometry to one Dy(11), one Dy(5), one Dy(7), and one Y(2) atom. In the twenty-fourth O site, O(24) is bonded in a 1-coordinate geometry to one Dy(10), one Dy(2), and one Y(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Dy11Y5O24
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.257
_cell_length_b   9.257
_cell_length_c   9.257
_cell_angle_alpha   109.474
_cell_angle_beta   109.460
_cell_angle_gamma   109.478
_symmetry_Int_Tables_number   1
_cell_volume   610.663
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Dy  Dy0  1  0.533  0.815  0.217  1.0
  Dy  Dy1  1  0.000  0.500  0.000  1.0
  Dy  Dy2  1  0.500  0.500  0.500  1.0
  Dy  Dy3  1  0.033  0.816  0.717  1.0
  Dy  Dy4  1  1.000  1.000  0.500  1.0
  Dy  Dy5  1  0.967  0.185  0.283  1.0
  Dy  Dy6  1  0.315  0.783  0.467  1.0
  Dy  Dy7  1  0.315  0.283  0.967  1.0
  Dy  Dy8  1  0.717  0.467  0.250  1.0
  Dy  Dy9  1  0.783  0.033  0.750  1.0
  Dy  Dy10  1  0.467  0.184  0.783  1.0
  Y  Y11  1  0.500  0.000  1.000  1.0
  Y  Y12  1  0.217  0.967  0.250  1.0
  Y  Y13  1  0.283  0.533  0.750  1.0
  Y  Y14  1  0.685  0.217  0.533  1.0
  Y  Y15  1  0.685  0.717  0.033  1.0
  O  O16  1  0.783  0.053  0.489  1.0
  O  O17  1  0.199  0.688  0.271  1.0
  O  O18  1  0.187  0.927  0.042  1.0
  O  O19  1  0.491  0.032  0.239  1.0
  O  O20  1  0.553  0.314  0.458  1.0
  O  O21  1  0.249  0.207  0.261  1.0
  O  O22  1  0.020  0.250  0.011  1.0
  O  O23  1  0.999  0.010  0.230  1.0
  O  O24  1  0.185  0.717  0.772  1.0
  O  O25  1  0.707  0.479  0.532  1.0
  O  O26  1  0.467  0.499  0.272  1.0
  O  O27  1  0.427  0.698  0.031  1.0
  O  O28  1  0.533  0.501  0.728  1.0
  O  O29  1  0.574  0.303  0.968  1.0
  O  O30  1  0.292  0.520  0.469  1.0
  O  O31  1  0.813  0.282  0.229  1.0
  O  O32  1  0.002  0.991  0.770  1.0
  O  O33  1  0.980  0.750  0.989  1.0
  O  O34  1  0.447  0.687  0.542  1.0
  O  O35  1  0.750  0.792  0.739  1.0
  O  O36  1  0.813  0.073  0.958  1.0
  O  O37  1  0.509  0.967  0.761  1.0
  O  O38  1  0.218  0.947  0.511  1.0
  O  O39  1  0.802  0.313  0.729  1.0
[/CIF]
.
The structure described by Dy11Y5O24 crystallizes in the triclinic P1 space group. There are eleven inequivalent Dy sites. In the first Dy site, Dy(1) is bonded in a 1-coordinate geometry to one O(1), one O(11), one O(12), and one O(4) atom. In the second Dy site, Dy(2) is bonded in a square co-planar geometry to one O(18), one O(2), one O(24), and one O(7) atom. In the third Dy site, Dy(3) is bonded in a distorted hexagonal bipyramidal geometry to one O(10), one O(11), one O(13), one O(15), one O(19), one O(20), one O(5), and one O(6) atom. In the fourth Dy site, Dy(4) is bonded in a distorted bent 150 degrees geometry to one O(10), one O(17), one O(18), and one O(9) atom. In the fifth Dy site, Dy(5) is bonded in a distorted square co-planar geometry to one O(1), one O(17), one O(23), and one O(8) atom. In the sixth Dy site, Dy(6) is bonded in a distorted bent 150 degrees geometry to one O(15), one O(16), one O(7), and one O(8) atom. In the seventh Dy site, Dy(7) is bonded in a 4-coordinate geometry to one O(15), one O(19), one O(2), one O(22), and one O(23) atom. In the eighth Dy site, Dy(8) is bonded in a 4-coordinate geometry to one O(11), one O(14), one O(17), and one O(7) atom. In the ninth Dy site, Dy(9) is bonded in a 4-coordinate geometry to one O(10), one O(11), one O(14), and one O(16) atom. In the tenth Dy site, Dy(10) is bonded in a 7-coordinate geometry to one O(1), one O(17), one O(20), one O(21), one O(22), one O(24), and one O(7) atom. In the eleventh Dy site, Dy(11) is bonded in a 1-coordinate geometry to one O(13), one O(14), one O(22), and one O(23) atom. There are five inequivalent Y sites. In the first Y site, Y(1) is bonded in a 8-coordinate geometry to one O(12), one O(14), one O(16), one O(21), one O(22), one O(3), one O(4), and one O(9) atom. In the second Y site, Y(2) is bonded in a 7-coordinate geometry to one O(18), one O(2), one O(23), one O(3), one O(4), one O(6), and one O(8) atom. In the third Y site, Y(3) is bonded in a 4-coordinate geometry to one O(12), one O(13), one O(15), and one O(9) atom. In the fourth Y site, Y(4) is bonded in a 4-coordinate geometry to one O(1), one O(10), one O(24), one O(4), and one O(5) atom. In the fifth Y site, Y(5) is bonded in a 4-coordinate geometry to one O(12), one O(13), one O(18), and one O(8) atom. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Dy(1), one Dy(10), one Dy(5), and one Y(4) atom. In the second O site, O(2) is bonded in a 1-coordinate geometry to one Dy(2), one Dy(7), and one Y(2) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Y(1), one Y(2), and one O(18) atom. In the fourth O site, O(4) is bonded to one Dy(1), one Y(1), one Y(2), and one Y(4) atom to form distorted ODyY3 trigonal pyramids that share  a cornercorner with one O(8)Dy2Y2 trigonal pyramid and  a cornercorner with one O(22)Dy3Y trigonal pyramid. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Dy(3), one Y(4), and one O(10) atom. In the sixth O site, O(6) is bonded in a 1-coordinate geometry to one Dy(3) and one Y(2) atom. In the seventh O site, O(7) is bonded in a 5-coordinate geometry to one Dy(10), one Dy(2), one Dy(6), one Dy(8), and one O(21) atom. In the eighth O site, O(8) is bonded to one Dy(5), one Dy(6), one Y(2), and one Y(5) atom to form distorted ODy2Y2 trigonal pyramids that share  a cornercorner with one O(17)Dy4 trigonal pyramid and  a cornercorner with one O(4)DyY3 trigonal pyramid. In the ninth O site, O(9) is bonded in a distorted T-shaped geometry to one Dy(4), one Y(1), and one Y(3) atom. In the tenth O site, O(10) is bonded in a 5-coordinate geometry to one Dy(3), one Dy(4), one Dy(9), one Y(4), and one O(5) atom. In the eleventh O site, O(11) is bonded in a 4-coordinate geometry to one Dy(1), one Dy(3), one Dy(8), and one Dy(9) atom. In the twelfth O site, O(12) is bonded in a 1-coordinate geometry to one Dy(1), one Y(1), one Y(3), and one Y(5) atom. In the thirteenth O site, O(13) is bonded in a 4-coordinate geometry to one Dy(11), one Dy(3), one Y(3), and one Y(5) atom. In the fourteenth O site, O(14) is bonded in a 1-coordinate geometry to one Dy(11), one Dy(8), one Dy(9), and one Y(1) atom. In the fifteenth O site, O(15) is bonded in a 5-coordinate geometry to one Dy(3), one Dy(6), one Dy(7), one Y(3), and one O(19) atom. In the sixteenth O site, O(16) is bonded in a distorted T-shaped geometry to one Dy(6), one Dy(9), and one Y(1) atom. In the seventeenth O site, O(17) is bonded to one Dy(10), one Dy(4), one Dy(5), and one Dy(8) atom to form distorted ODy4 trigonal pyramids that share  a cornercorner with one O(8)Dy2Y2 trigonal pyramid and  a cornercorner with one O(22)Dy3Y trigonal pyramid. In the eighteenth O site, O(18) is bonded in a 5-coordinate geometry to one Dy(2), one Dy(4), one Y(2), one Y(5), and one O(3) atom. In the nineteenth O site, O(19) is bonded in a 2-coordinate geometry to one Dy(3), one Dy(7), and one O(15) atom. In the twentieth O site, O(20) is bonded in a 1-coordinate geometry to one Dy(10) and one Dy(3) atom. In the twenty-first O site, O(21) is bonded in a distorted single-bond geometry to one Dy(10), one Y(1), and one O(7) atom. In the twenty-second O site, O(22) is bonded to one Dy(10), one Dy(11), one Dy(7), and one Y(1) atom to form distorted ODy3Y trigonal pyramids that share  a cornercorner with one O(17)Dy4 trigonal pyramid and  a cornercorner with one O(4)DyY3 trigonal pyramid. In the twenty-third O site, O(23) is bonded in a 4-coordinate geometry to one Dy(11), one Dy(5), one Dy(7), and one Y(2) atom. In the twenty-fourth O site, O(24) is bonded in a 1-coordinate geometry to one Dy(10), one Dy(2), and one Y(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Dy11Y5O24
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.257
_cell_length_b   9.257
_cell_length_c   9.257
_cell_angle_alpha   109.474
_cell_angle_beta   109.460
_cell_angle_gamma   109.478
_symmetry_Int_Tables_number   1
_cell_volume   610.663
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Dy  Dy0  1  0.533  0.815  0.217  1.0
  Dy  Dy1  1  0.000  0.500  0.000  1.0
  Dy  Dy2  1  0.500  0.500  0.500  1.0
  Dy  Dy3  1  0.033  0.816  0.717  1.0
  Dy  Dy4  1  1.000  1.000  0.500  1.0
  Dy  Dy5  1  0.967  0.185  0.283  1.0
  Dy  Dy6  1  0.315  0.783  0.467  1.0
  Dy  Dy7  1  0.315  0.283  0.967  1.0
  Dy  Dy8  1  0.717  0.467  0.250  1.0
  Dy  Dy9  1  0.783  0.033  0.750  1.0
  Dy  Dy10  1  0.467  0.184  0.783  1.0
  Y  Y11  1  0.500  0.000  1.000  1.0
  Y  Y12  1  0.217  0.967  0.250  1.0
  Y  Y13  1  0.283  0.533  0.750  1.0
  Y  Y14  1  0.685  0.217  0.533  1.0
  Y  Y15  1  0.685  0.717  0.033  1.0
  O  O16  1  0.783  0.053  0.489  1.0
  O  O17  1  0.199  0.688  0.271  1.0
  O  O18  1  0.187  0.927  0.042  1.0
  O  O19  1  0.491  0.032  0.239  1.0
  O  O20  1  0.553  0.314  0.458  1.0
  O  O21  1  0.249  0.207  0.261  1.0
  O  O22  1  0.020  0.250  0.011  1.0
  O  O23  1  0.999  0.010  0.230  1.0
  O  O24  1  0.185  0.717  0.772  1.0
  O  O25  1  0.707  0.479  0.532  1.0
  O  O26  1  0.467  0.499  0.272  1.0
  O  O27  1  0.427  0.698  0.031  1.0
  O  O28  1  0.533  0.501  0.728  1.0
  O  O29  1  0.574  0.303  0.968  1.0
  O  O30  1  0.292  0.520  0.469  1.0
  O  O31  1  0.813  0.282  0.229  1.0
  O  O32  1  0.002  0.991  0.770  1.0
  O  O33  1  0.980  0.750  0.989  1.0
  O  O34  1  0.447  0.687  0.542  1.0
  O  O35  1  0.750  0.792  0.739  1.0
  O  O36  1  0.813  0.073  0.958  1.0
  O  O37  1  0.509  0.967  0.761  1.0
  O  O38  1  0.218  0.947  0.511  1.0
  O  O39  1  0.802  0.313  0.729  1.0
[/CIF]
.