The structure described by (RhBi4)3Cl2 crystallizes in the orthorhombic Fddd space group. The structure consists of sixteen hydrochloric acid atoms inside a RhBi4 framework. In the RhBi4 framework, there are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a body-centered cubic geometry to two equivalent Bi(1), two equivalent Bi(2), and four equivalent Bi(3) atoms. In the second Rh site, Rh(2) is bonded in a 8-coordinate geometry to four equivalent Bi(1) and four equivalent Bi(2) atoms. There are three inequivalent Bi sites. In the first Bi site, Bi(1) is bonded in a distorted water-like geometry to one Rh(1) and one Rh(2) atom. In the second Bi site, Bi(2) is bonded in a distorted water-like geometry to one Rh(1) and one Rh(2) atom. In the third Bi site, Bi(3) is bonded in a distorted water-like geometry to two equivalent Rh(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Bi12Rh3Cl2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   18.143
_cell_length_b   16.503
_cell_length_c   9.165
_cell_angle_alpha   84.848
_cell_angle_beta   64.945
_cell_angle_gamma   30.207
_symmetry_Int_Tables_number   1
_cell_volume   994.927
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.802  0.303  0.453  1.0
  Bi  Bi1  1  0.442  0.453  0.303  1.0
  Bi  Bi2  1  0.453  0.442  0.802  1.0
  Bi  Bi3  1  0.303  0.802  0.442  1.0
  Bi  Bi4  1  0.448  0.947  0.797  1.0
  Bi  Bi5  1  0.808  0.797  0.947  1.0
  Bi  Bi6  1  0.797  0.808  0.448  1.0
  Bi  Bi7  1  0.947  0.448  0.808  1.0
  Bi  Bi8  1  0.321  0.785  0.786  1.0
  Bi  Bi9  1  0.108  0.786  0.785  1.0
  Bi  Bi10  1  0.786  0.108  0.321  1.0
  Bi  Bi11  1  0.785  0.321  0.108  1.0
  Bi  Bi12  1  0.929  0.465  0.464  1.0
  Bi  Bi13  1  0.142  0.464  0.465  1.0
  Bi  Bi14  1  0.464  0.142  0.929  1.0
  Bi  Bi15  1  0.465  0.929  0.142  1.0
  Bi  Bi16  1  0.857  0.367  0.721  1.0
  Bi  Bi17  1  0.056  0.721  0.367  1.0
  Bi  Bi18  1  0.721  0.056  0.857  1.0
  Bi  Bi19  1  0.367  0.857  0.056  1.0
  Bi  Bi20  1  0.393  0.883  0.529  1.0
  Bi  Bi21  1  0.194  0.529  0.883  1.0
  Bi  Bi22  1  0.529  0.194  0.393  1.0
  Bi  Bi23  1  0.883  0.393  0.194  1.0
  Rh  Rh24  1  0.625  0.625  0.625  1.0
  Rh  Rh25  1  0.125  0.625  0.625  1.0
  Rh  Rh26  1  0.625  0.125  0.625  1.0
  Rh  Rh27  1  0.625  0.625  0.125  1.0
  Rh  Rh28  1  0.500  0.500  0.500  1.0
  Rh  Rh29  1  0.750  0.750  0.750  1.0
  Cl  Cl30  1  0.791  0.209  0.791  1.0
  Cl  Cl31  1  0.209  0.791  0.209  1.0
  Cl  Cl32  1  0.459  0.041  0.459  1.0
  Cl  Cl33  1  0.041  0.459  0.041  1.0
[/CIF]
.
The structure described by (RhBi4)3Cl2 crystallizes in the orthorhombic Fddd space group. The structure consists of sixteen hydrochloric acid atoms inside a RhBi4 framework. In the RhBi4 framework, there are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a body-centered cubic geometry to two equivalent Bi(1), two equivalent Bi(2), and four equivalent Bi(3) atoms. In the second Rh site, Rh(2) is bonded in a 8-coordinate geometry to four equivalent Bi(1) and four equivalent Bi(2) atoms. There are three inequivalent Bi sites. In the first Bi site, Bi(1) is bonded in a distorted water-like geometry to one Rh(1) and one Rh(2) atom. In the second Bi site, Bi(2) is bonded in a distorted water-like geometry to one Rh(1) and one Rh(2) atom. In the third Bi site, Bi(3) is bonded in a distorted water-like geometry to two equivalent Rh(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Bi12Rh3Cl2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   18.143
_cell_length_b   16.503
_cell_length_c   9.165
_cell_angle_alpha   84.848
_cell_angle_beta   64.945
_cell_angle_gamma   30.207
_symmetry_Int_Tables_number   1
_cell_volume   994.927
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.802  0.303  0.453  1.0
  Bi  Bi1  1  0.442  0.453  0.303  1.0
  Bi  Bi2  1  0.453  0.442  0.802  1.0
  Bi  Bi3  1  0.303  0.802  0.442  1.0
  Bi  Bi4  1  0.448  0.947  0.797  1.0
  Bi  Bi5  1  0.808  0.797  0.947  1.0
  Bi  Bi6  1  0.797  0.808  0.448  1.0
  Bi  Bi7  1  0.947  0.448  0.808  1.0
  Bi  Bi8  1  0.321  0.785  0.786  1.0
  Bi  Bi9  1  0.108  0.786  0.785  1.0
  Bi  Bi10  1  0.786  0.108  0.321  1.0
  Bi  Bi11  1  0.785  0.321  0.108  1.0
  Bi  Bi12  1  0.929  0.465  0.464  1.0
  Bi  Bi13  1  0.142  0.464  0.465  1.0
  Bi  Bi14  1  0.464  0.142  0.929  1.0
  Bi  Bi15  1  0.465  0.929  0.142  1.0
  Bi  Bi16  1  0.857  0.367  0.721  1.0
  Bi  Bi17  1  0.056  0.721  0.367  1.0
  Bi  Bi18  1  0.721  0.056  0.857  1.0
  Bi  Bi19  1  0.367  0.857  0.056  1.0
  Bi  Bi20  1  0.393  0.883  0.529  1.0
  Bi  Bi21  1  0.194  0.529  0.883  1.0
  Bi  Bi22  1  0.529  0.194  0.393  1.0
  Bi  Bi23  1  0.883  0.393  0.194  1.0
  Rh  Rh24  1  0.625  0.625  0.625  1.0
  Rh  Rh25  1  0.125  0.625  0.625  1.0
  Rh  Rh26  1  0.625  0.125  0.625  1.0
  Rh  Rh27  1  0.625  0.625  0.125  1.0
  Rh  Rh28  1  0.500  0.500  0.500  1.0
  Rh  Rh29  1  0.750  0.750  0.750  1.0
  Cl  Cl30  1  0.791  0.209  0.791  1.0
  Cl  Cl31  1  0.209  0.791  0.209  1.0
  Cl  Cl32  1  0.459  0.041  0.459  1.0
  Cl  Cl33  1  0.041  0.459  0.041  1.0
[/CIF]
.