The compound described by BP5(Pb3O10)2 crystallizes in the tetragonal P-4 space group. B(1) is bonded to four equivalent O(2) atoms to form BO4 tetrahedra that share corners with four equivalent P(2)O4 tetrahedra. There are two inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 5-coordinate geometry to one O(3), one O(4), one O(5), and two equivalent O(1) atoms. In the second Pb site, Pb(2) is bonded in a 4-coordinate geometry to two equivalent O(3) and two equivalent O(5) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded in a tetrahedral geometry to four equivalent O(3) atoms. In the second P site, P(2) is bonded to one O(1), one O(2), one O(4), and one O(5) atom to form PO4 tetrahedra that share  a cornercorner with one B(1)O4 tetrahedra. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Pb(1) and one P(2) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one B(1) and one P(2) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Pb(1), one Pb(2), and one P(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Pb(1) and one P(2) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Pb(1), one Pb(2), and one P(2) atom. is represented by the CIF card [CIF]
data_BP5(Pb3O10)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.055
_cell_length_b   7.055
_cell_length_c   10.113
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   503.399
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.500  0.500  0.500  1.0
  P  P1  1  0.000  0.000  0.000  1.0
  P  P2  1  0.734  0.669  0.304  1.0
  P  P3  1  0.266  0.331  0.304  1.0
  P  P4  1  0.331  0.734  0.696  1.0
  P  P5  1  0.669  0.266  0.696  1.0
  Pb  Pb6  1  0.837  0.771  0.685  1.0
  Pb  Pb7  1  0.163  0.229  0.685  1.0
  Pb  Pb8  1  0.229  0.837  0.315  1.0
  Pb  Pb9  1  0.771  0.163  0.315  1.0
  Pb  Pb10  1  0.000  0.500  0.021  1.0
  Pb  Pb11  1  0.500  0.000  0.979  1.0
  O  O12  1  0.895  0.795  0.361  1.0
  O  O13  1  0.105  0.205  0.361  1.0
  O  O14  1  0.205  0.895  0.639  1.0
  O  O15  1  0.795  0.105  0.639  1.0
  O  O16  1  0.674  0.533  0.424  1.0
  O  O17  1  0.326  0.467  0.424  1.0
  O  O18  1  0.467  0.674  0.576  1.0
  O  O19  1  0.533  0.326  0.576  1.0
  O  O20  1  0.889  0.148  0.085  1.0
  O  O21  1  0.111  0.852  0.085  1.0
  O  O22  1  0.852  0.889  0.915  1.0
  O  O23  1  0.148  0.111  0.915  1.0
  O  O24  1  0.799  0.427  0.749  1.0
  O  O25  1  0.201  0.573  0.749  1.0
  O  O26  1  0.573  0.799  0.251  1.0
  O  O27  1  0.427  0.201  0.251  1.0
  O  O28  1  0.796  0.520  0.201  1.0
  O  O29  1  0.204  0.480  0.201  1.0
  O  O30  1  0.480  0.796  0.799  1.0
  O  O31  1  0.520  0.204  0.799  1.0
[/CIF]
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The compound described by BP5(Pb3O10)2 crystallizes in the tetragonal P-4 space group. B(1) is bonded to four equivalent O(2) atoms to form BO4 tetrahedra that share corners with four equivalent P(2)O4 tetrahedra. There are two inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 5-coordinate geometry to one O(3), one O(4), one O(5), and two equivalent O(1) atoms. In the second Pb site, Pb(2) is bonded in a 4-coordinate geometry to two equivalent O(3) and two equivalent O(5) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded in a tetrahedral geometry to four equivalent O(3) atoms. In the second P site, P(2) is bonded to one O(1), one O(2), one O(4), and one O(5) atom to form PO4 tetrahedra that share  a cornercorner with one B(1)O4 tetrahedra. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Pb(1) and one P(2) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one B(1) and one P(2) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Pb(1), one Pb(2), and one P(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Pb(1) and one P(2) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Pb(1), one Pb(2), and one P(2) atom. is represented by the CIF card [CIF]
data_BP5(Pb3O10)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.055
_cell_length_b   7.055
_cell_length_c   10.113
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   503.399
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.500  0.500  0.500  1.0
  P  P1  1  0.000  0.000  0.000  1.0
  P  P2  1  0.734  0.669  0.304  1.0
  P  P3  1  0.266  0.331  0.304  1.0
  P  P4  1  0.331  0.734  0.696  1.0
  P  P5  1  0.669  0.266  0.696  1.0
  Pb  Pb6  1  0.837  0.771  0.685  1.0
  Pb  Pb7  1  0.163  0.229  0.685  1.0
  Pb  Pb8  1  0.229  0.837  0.315  1.0
  Pb  Pb9  1  0.771  0.163  0.315  1.0
  Pb  Pb10  1  0.000  0.500  0.021  1.0
  Pb  Pb11  1  0.500  0.000  0.979  1.0
  O  O12  1  0.895  0.795  0.361  1.0
  O  O13  1  0.105  0.205  0.361  1.0
  O  O14  1  0.205  0.895  0.639  1.0
  O  O15  1  0.795  0.105  0.639  1.0
  O  O16  1  0.674  0.533  0.424  1.0
  O  O17  1  0.326  0.467  0.424  1.0
  O  O18  1  0.467  0.674  0.576  1.0
  O  O19  1  0.533  0.326  0.576  1.0
  O  O20  1  0.889  0.148  0.085  1.0
  O  O21  1  0.111  0.852  0.085  1.0
  O  O22  1  0.852  0.889  0.915  1.0
  O  O23  1  0.148  0.111  0.915  1.0
  O  O24  1  0.799  0.427  0.749  1.0
  O  O25  1  0.201  0.573  0.749  1.0
  O  O26  1  0.573  0.799  0.251  1.0
  O  O27  1  0.427  0.201  0.251  1.0
  O  O28  1  0.796  0.520  0.201  1.0
  O  O29  1  0.204  0.480  0.201  1.0
  O  O30  1  0.480  0.796  0.799  1.0
  O  O31  1  0.520  0.204  0.799  1.0
[/CIF]
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