The compound described by V6O13 crystallizes in the monoclinic P2_1/c space group. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(4), one O(5), one O(6), and three equivalent O(1) atoms to form a mixture of corner and edge-sharing VO6 octahedra. The corner-sharing octahedral tilt angles range from 0-26°. In the second V site, V(2) is bonded in a 6-coordinate geometry to one O(3), one O(5), two equivalent O(2), and two equivalent O(7) atoms. In the third V site, V(3) is bonded in a 6-coordinate geometry to one O(2), one O(6), one O(7), and three equivalent O(3) atoms. There are seven inequivalent O sites. In the first O site, O(7) is bonded in a 3-coordinate geometry to one V(3) and two equivalent V(2) atoms. In the second O site, O(1) is bonded in a distorted T-shaped geometry to three equivalent V(1) atoms. In the third O site, O(2) is bonded in a distorted T-shaped geometry to one V(3) and two equivalent V(2) atoms. In the fourth O site, O(3) is bonded to one V(2) and three equivalent V(3) atoms to form a mixture of distorted corner and edge-sharing OV4 tetrahedra. In the fifth O site, O(4) is bonded in a linear geometry to two equivalent V(1) atoms. In the sixth O site, O(5) is bonded in a linear geometry to one V(1) and one V(2) atom. In the seventh O site, O(6) is bonded in a linear geometry to one V(1) and one V(3) atom. is represented by the CIF file [CIF]
data_V6O13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.755
_cell_length_b   10.259
_cell_length_c   12.168
_cell_angle_alpha   79.159
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   460.397
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.467  0.004  0.851  1.0
  V  V1  1  0.967  0.996  0.649  1.0
  V  V2  1  0.533  0.996  0.149  1.0
  V  V3  1  0.033  0.004  0.351  1.0
  V  V4  1  0.498  0.636  0.913  1.0
  V  V5  1  0.998  0.364  0.587  1.0
  V  V6  1  0.502  0.364  0.087  1.0
  V  V7  1  0.002  0.636  0.413  1.0
  V  V8  1  0.502  0.634  0.215  1.0
  V  V9  1  0.002  0.366  0.285  1.0
  V  V10  1  0.498  0.366  0.785  1.0
  V  V11  1  0.998  0.634  0.715  1.0
  O  O12  1  0.489  1.000  0.683  1.0
  O  O13  1  0.989  0.000  0.817  1.0
  O  O14  1  0.511  0.000  0.317  1.0
  O  O15  1  0.011  1.000  0.183  1.0
  O  O16  1  0.502  0.614  0.381  1.0
  O  O17  1  0.002  0.386  0.119  1.0
  O  O18  1  0.498  0.386  0.619  1.0
  O  O19  1  0.998  0.614  0.881  1.0
  O  O20  1  0.499  0.588  0.754  1.0
  O  O21  1  0.999  0.412  0.746  1.0
  O  O22  1  0.501  0.412  0.246  1.0
  O  O23  1  0.001  0.588  0.254  1.0
  O  O24  1  0.500  0.000  0.000  1.0
  O  O25  1  0.000  0.000  0.500  1.0
  O  O26  1  0.493  0.802  0.886  1.0
  O  O27  1  0.993  0.198  0.614  1.0
  O  O28  1  0.507  0.198  0.114  1.0
  O  O29  1  0.007  0.802  0.386  1.0
  O  O30  1  0.508  0.802  0.178  1.0
  O  O31  1  0.008  0.198  0.322  1.0
  O  O32  1  0.492  0.198  0.822  1.0
  O  O33  1  0.992  0.802  0.678  1.0
  O  O34  1  0.500  0.591  0.060  1.0
  O  O35  1  0.000  0.409  0.440  1.0
  O  O36  1  0.500  0.409  0.940  1.0
  O  O37  1  1.000  0.591  0.560  1.0
[/CIF]
.
The compound described by V6O13 crystallizes in the monoclinic P2_1/c space group. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(4), one O(5), one O(6), and three equivalent O(1) atoms to form a mixture of corner and edge-sharing VO6 octahedra. The corner-sharing octahedral tilt angles range from 0-26°. In the second V site, V(2) is bonded in a 6-coordinate geometry to one O(3), one O(5), two equivalent O(2), and two equivalent O(7) atoms. In the third V site, V(3) is bonded in a 6-coordinate geometry to one O(2), one O(6), one O(7), and three equivalent O(3) atoms. There are seven inequivalent O sites. In the first O site, O(7) is bonded in a 3-coordinate geometry to one V(3) and two equivalent V(2) atoms. In the second O site, O(1) is bonded in a distorted T-shaped geometry to three equivalent V(1) atoms. In the third O site, O(2) is bonded in a distorted T-shaped geometry to one V(3) and two equivalent V(2) atoms. In the fourth O site, O(3) is bonded to one V(2) and three equivalent V(3) atoms to form a mixture of distorted corner and edge-sharing OV4 tetrahedra. In the fifth O site, O(4) is bonded in a linear geometry to two equivalent V(1) atoms. In the sixth O site, O(5) is bonded in a linear geometry to one V(1) and one V(2) atom. In the seventh O site, O(6) is bonded in a linear geometry to one V(1) and one V(3) atom. is represented by the CIF file [CIF]
data_V6O13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.755
_cell_length_b   10.259
_cell_length_c   12.168
_cell_angle_alpha   79.159
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   460.397
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.467  0.004  0.851  1.0
  V  V1  1  0.967  0.996  0.649  1.0
  V  V2  1  0.533  0.996  0.149  1.0
  V  V3  1  0.033  0.004  0.351  1.0
  V  V4  1  0.498  0.636  0.913  1.0
  V  V5  1  0.998  0.364  0.587  1.0
  V  V6  1  0.502  0.364  0.087  1.0
  V  V7  1  0.002  0.636  0.413  1.0
  V  V8  1  0.502  0.634  0.215  1.0
  V  V9  1  0.002  0.366  0.285  1.0
  V  V10  1  0.498  0.366  0.785  1.0
  V  V11  1  0.998  0.634  0.715  1.0
  O  O12  1  0.489  1.000  0.683  1.0
  O  O13  1  0.989  0.000  0.817  1.0
  O  O14  1  0.511  0.000  0.317  1.0
  O  O15  1  0.011  1.000  0.183  1.0
  O  O16  1  0.502  0.614  0.381  1.0
  O  O17  1  0.002  0.386  0.119  1.0
  O  O18  1  0.498  0.386  0.619  1.0
  O  O19  1  0.998  0.614  0.881  1.0
  O  O20  1  0.499  0.588  0.754  1.0
  O  O21  1  0.999  0.412  0.746  1.0
  O  O22  1  0.501  0.412  0.246  1.0
  O  O23  1  0.001  0.588  0.254  1.0
  O  O24  1  0.500  0.000  0.000  1.0
  O  O25  1  0.000  0.000  0.500  1.0
  O  O26  1  0.493  0.802  0.886  1.0
  O  O27  1  0.993  0.198  0.614  1.0
  O  O28  1  0.507  0.198  0.114  1.0
  O  O29  1  0.007  0.802  0.386  1.0
  O  O30  1  0.508  0.802  0.178  1.0
  O  O31  1  0.008  0.198  0.322  1.0
  O  O32  1  0.492  0.198  0.822  1.0
  O  O33  1  0.992  0.802  0.678  1.0
  O  O34  1  0.500  0.591  0.060  1.0
  O  O35  1  0.000  0.409  0.440  1.0
  O  O36  1  0.500  0.409  0.940  1.0
  O  O37  1  1.000  0.591  0.560  1.0
[/CIF]
.