The structure described by FeN2S2O5C4N is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two ch2=chch2nc molecules and one FeN2S2O5 cluster. In the FeN2S2O5 cluster, Fe(1) is bonded to one N(1), one N(2), and two equivalent S(1) atoms to form distorted edge-sharing FeS2N2 tetrahedra. There are two inequivalent N sites. In the first N site, N(1) is bonded in a linear geometry to one Fe(1) and one O(4) atom. In the second N site, N(2) is bonded in a linear geometry to one Fe(1) and one O(5) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a 3-coordinate geometry to two equivalent Fe(1) and one S(2) atom. In the second S site, S(2) is bonded in a distorted trigonal planar geometry to one S(1), one O(1), one O(2), and one O(3) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(2) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one N(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one N(2) atom. is represented by the CIF card [CIF]
data_FeC4S2N3O5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.452
_cell_length_b   8.681
_cell_length_c   12.954
_cell_angle_alpha   62.019
_cell_angle_beta   84.636
_cell_angle_gamma   86.234
_symmetry_Int_Tables_number   1
_cell_volume   637.682
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Fe  Fe0  1  0.928  0.354  0.976  1.0
  Fe  Fe1  1  0.072  0.646  0.024  1.0
  C  C2  1  0.633  0.284  0.691  1.0
  C  C3  1  0.367  0.716  0.309  1.0
  C  C4  1  0.656  0.205  0.628  1.0
  C  C5  1  0.344  0.795  0.372  1.0
  C  C6  1  0.638  0.268  0.796  1.0
  C  C7  1  0.362  0.732  0.204  1.0
  C  C8  1  0.740  0.986  0.561  1.0
  C  C9  1  0.260  0.014  0.439  1.0
  S  S10  1  0.947  0.655  0.855  1.0
  S  S11  1  0.053  0.345  0.145  1.0
  S  S12  1  0.232  0.653  0.736  1.0
  S  S13  1  0.768  0.347  0.264  1.0
  N  N14  1  0.660  0.276  0.012  1.0
  N  N15  1  0.340  0.724  0.988  1.0
  N  N16  1  0.061  0.218  0.913  1.0
  N  N17  1  0.939  0.782  0.087  1.0
  N  N18  1  0.693  0.108  0.582  1.0
  N  N19  1  0.307  0.892  0.418  1.0
  O  O20  1  0.140  0.604  0.657  1.0
  O  O21  1  0.860  0.396  0.343  1.0
  O  O22  1  0.300  0.832  0.686  1.0
  O  O23  1  0.700  0.168  0.314  1.0
  O  O24  1  0.368  0.520  0.819  1.0
  O  O25  1  0.632  0.480  0.181  1.0
  O  O26  1  0.486  0.243  0.040  1.0
  O  O27  1  0.514  0.757  0.960  1.0
  O  O28  1  0.153  0.137  0.872  1.0
  O  O29  1  0.847  0.863  0.128  1.0
[/CIF]
.
The structure described by FeN2S2O5C4N is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two ch2=chch2nc molecules and one FeN2S2O5 cluster. In the FeN2S2O5 cluster, Fe(1) is bonded to one N(1), one N(2), and two equivalent S(1) atoms to form distorted edge-sharing FeS2N2 tetrahedra. There are two inequivalent N sites. In the first N site, N(1) is bonded in a linear geometry to one Fe(1) and one O(4) atom. In the second N site, N(2) is bonded in a linear geometry to one Fe(1) and one O(5) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a 3-coordinate geometry to two equivalent Fe(1) and one S(2) atom. In the second S site, S(2) is bonded in a distorted trigonal planar geometry to one S(1), one O(1), one O(2), and one O(3) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(2) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one N(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one N(2) atom. is represented by the CIF card [CIF]
data_FeC4S2N3O5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.452
_cell_length_b   8.681
_cell_length_c   12.954
_cell_angle_alpha   62.019
_cell_angle_beta   84.636
_cell_angle_gamma   86.234
_symmetry_Int_Tables_number   1
_cell_volume   637.682
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Fe  Fe0  1  0.928  0.354  0.976  1.0
  Fe  Fe1  1  0.072  0.646  0.024  1.0
  C  C2  1  0.633  0.284  0.691  1.0
  C  C3  1  0.367  0.716  0.309  1.0
  C  C4  1  0.656  0.205  0.628  1.0
  C  C5  1  0.344  0.795  0.372  1.0
  C  C6  1  0.638  0.268  0.796  1.0
  C  C7  1  0.362  0.732  0.204  1.0
  C  C8  1  0.740  0.986  0.561  1.0
  C  C9  1  0.260  0.014  0.439  1.0
  S  S10  1  0.947  0.655  0.855  1.0
  S  S11  1  0.053  0.345  0.145  1.0
  S  S12  1  0.232  0.653  0.736  1.0
  S  S13  1  0.768  0.347  0.264  1.0
  N  N14  1  0.660  0.276  0.012  1.0
  N  N15  1  0.340  0.724  0.988  1.0
  N  N16  1  0.061  0.218  0.913  1.0
  N  N17  1  0.939  0.782  0.087  1.0
  N  N18  1  0.693  0.108  0.582  1.0
  N  N19  1  0.307  0.892  0.418  1.0
  O  O20  1  0.140  0.604  0.657  1.0
  O  O21  1  0.860  0.396  0.343  1.0
  O  O22  1  0.300  0.832  0.686  1.0
  O  O23  1  0.700  0.168  0.314  1.0
  O  O24  1  0.368  0.520  0.819  1.0
  O  O25  1  0.632  0.480  0.181  1.0
  O  O26  1  0.486  0.243  0.040  1.0
  O  O27  1  0.514  0.757  0.960  1.0
  O  O28  1  0.153  0.137  0.872  1.0
  O  O29  1  0.847  0.863  0.128  1.0
[/CIF]
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