The structure described by ErC4(NCl3)2C4N2Cl is Indium-derived structured and crystallizes in the orthorhombic P2_12_12 space group. The structure is zero-dimensional and consists of two C4N2Cl clusters and two ErC4(NCl3)2 clusters. In each C4N2Cl cluster, there are two inequivalent C sites. In the first C site, C(1) is bonded in a single-bond geometry to one N(1) atom. In the second C site, C(2) is bonded in a bent 120 degrees geometry to one N(1) and one Cl(4) atom. N(1) is bonded in a linear geometry to one C(1) and one C(2) atom. Cl(4) is bonded in a linear geometry to two equivalent C(2) atoms. In each ErC4(NCl3)2 cluster, Er(1) is bonded in a distorted octahedral geometry to two equivalent Cl(1), two equivalent Cl(2), and two equivalent Cl(3) atoms. There are two inequivalent C sites. In the first C site, C(3) is bonded in a water-like geometry to one N(2) and one Cl(2) atom. In the second C site, C(4) is bonded in a single-bond geometry to one N(2) atom. N(2) is bonded in a linear geometry to one C(3) and one C(4) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in a single-bond geometry to one Er(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Er(1) atom. In the third Cl site, Cl(2) is bonded in a distorted bent 120 degrees geometry to one Er(1) and one C(3) atom. is represented by the CIF card [CIF]
data_ErC8N4Cl7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.491
_cell_length_b   8.946
_cell_length_c   13.852
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1052.309
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Er  Er0  1  0.362  0.500  0.500  1.0
  Er  Er1  1  0.638  0.000  0.000  1.0
  C  C2  1  0.119  0.269  0.676  1.0
  C  C3  1  0.119  0.731  0.324  1.0
  C  C4  1  0.881  0.231  0.176  1.0
  C  C5  1  0.881  0.769  0.824  1.0
  C  C6  1  0.944  0.214  0.535  1.0
  C  C7  1  0.944  0.786  0.465  1.0
  C  C8  1  0.056  0.286  0.035  1.0
  C  C9  1  0.056  0.714  0.965  1.0
  C  C10  1  0.381  0.677  0.156  1.0
  C  C11  1  0.381  0.323  0.844  1.0
  C  C12  1  0.619  0.823  0.656  1.0
  C  C13  1  0.619  0.177  0.344  1.0
  C  C14  1  0.657  0.579  0.173  1.0
  C  C15  1  0.657  0.421  0.827  1.0
  C  C16  1  0.343  0.921  0.673  1.0
  C  C17  1  0.343  0.079  0.327  1.0
  N  N18  1  0.042  0.228  0.604  1.0
  N  N19  1  0.042  0.772  0.396  1.0
  N  N20  1  0.958  0.272  0.104  1.0
  N  N21  1  0.958  0.728  0.896  1.0
  N  N22  1  0.533  0.639  0.157  1.0
  N  N23  1  0.533  0.361  0.843  1.0
  N  N24  1  0.467  0.861  0.657  1.0
  N  N25  1  0.467  0.139  0.343  1.0
  Cl  Cl26  1  0.399  0.268  0.610  1.0
  Cl  Cl27  1  0.399  0.732  0.390  1.0
  Cl  Cl28  1  0.601  0.232  0.110  1.0
  Cl  Cl29  1  0.601  0.768  0.890  1.0
  Cl  Cl30  1  0.644  0.362  0.383  1.0
  Cl  Cl31  1  0.644  0.638  0.617  1.0
  Cl  Cl32  1  0.356  0.138  0.883  1.0
  Cl  Cl33  1  0.356  0.862  0.117  1.0
  Cl  Cl34  1  0.170  0.383  0.391  1.0
  Cl  Cl35  1  0.170  0.617  0.609  1.0
  Cl  Cl36  1  0.830  0.117  0.891  1.0
  Cl  Cl37  1  0.830  0.883  0.109  1.0
  Cl  Cl38  1  0.909  0.000  0.500  1.0
  Cl  Cl39  1  0.091  0.500  0.000  1.0
[/CIF]
.
The structure described by ErC4(NCl3)2C4N2Cl is Indium-derived structured and crystallizes in the orthorhombic P2_12_12 space group. The structure is zero-dimensional and consists of two C4N2Cl clusters and two ErC4(NCl3)2 clusters. In each C4N2Cl cluster, there are two inequivalent C sites. In the first C site, C(1) is bonded in a single-bond geometry to one N(1) atom. In the second C site, C(2) is bonded in a bent 120 degrees geometry to one N(1) and one Cl(4) atom. N(1) is bonded in a linear geometry to one C(1) and one C(2) atom. Cl(4) is bonded in a linear geometry to two equivalent C(2) atoms. In each ErC4(NCl3)2 cluster, Er(1) is bonded in a distorted octahedral geometry to two equivalent Cl(1), two equivalent Cl(2), and two equivalent Cl(3) atoms. There are two inequivalent C sites. In the first C site, C(3) is bonded in a water-like geometry to one N(2) and one Cl(2) atom. In the second C site, C(4) is bonded in a single-bond geometry to one N(2) atom. N(2) is bonded in a linear geometry to one C(3) and one C(4) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in a single-bond geometry to one Er(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Er(1) atom. In the third Cl site, Cl(2) is bonded in a distorted bent 120 degrees geometry to one Er(1) and one C(3) atom. is represented by the CIF card [CIF]
data_ErC8N4Cl7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.491
_cell_length_b   8.946
_cell_length_c   13.852
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1052.309
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Er  Er0  1  0.362  0.500  0.500  1.0
  Er  Er1  1  0.638  0.000  0.000  1.0
  C  C2  1  0.119  0.269  0.676  1.0
  C  C3  1  0.119  0.731  0.324  1.0
  C  C4  1  0.881  0.231  0.176  1.0
  C  C5  1  0.881  0.769  0.824  1.0
  C  C6  1  0.944  0.214  0.535  1.0
  C  C7  1  0.944  0.786  0.465  1.0
  C  C8  1  0.056  0.286  0.035  1.0
  C  C9  1  0.056  0.714  0.965  1.0
  C  C10  1  0.381  0.677  0.156  1.0
  C  C11  1  0.381  0.323  0.844  1.0
  C  C12  1  0.619  0.823  0.656  1.0
  C  C13  1  0.619  0.177  0.344  1.0
  C  C14  1  0.657  0.579  0.173  1.0
  C  C15  1  0.657  0.421  0.827  1.0
  C  C16  1  0.343  0.921  0.673  1.0
  C  C17  1  0.343  0.079  0.327  1.0
  N  N18  1  0.042  0.228  0.604  1.0
  N  N19  1  0.042  0.772  0.396  1.0
  N  N20  1  0.958  0.272  0.104  1.0
  N  N21  1  0.958  0.728  0.896  1.0
  N  N22  1  0.533  0.639  0.157  1.0
  N  N23  1  0.533  0.361  0.843  1.0
  N  N24  1  0.467  0.861  0.657  1.0
  N  N25  1  0.467  0.139  0.343  1.0
  Cl  Cl26  1  0.399  0.268  0.610  1.0
  Cl  Cl27  1  0.399  0.732  0.390  1.0
  Cl  Cl28  1  0.601  0.232  0.110  1.0
  Cl  Cl29  1  0.601  0.768  0.890  1.0
  Cl  Cl30  1  0.644  0.362  0.383  1.0
  Cl  Cl31  1  0.644  0.638  0.617  1.0
  Cl  Cl32  1  0.356  0.138  0.883  1.0
  Cl  Cl33  1  0.356  0.862  0.117  1.0
  Cl  Cl34  1  0.170  0.383  0.391  1.0
  Cl  Cl35  1  0.170  0.617  0.609  1.0
  Cl  Cl36  1  0.830  0.117  0.891  1.0
  Cl  Cl37  1  0.830  0.883  0.109  1.0
  Cl  Cl38  1  0.909  0.000  0.500  1.0
  Cl  Cl39  1  0.091  0.500  0.000  1.0
[/CIF]
.