The structure described by SbOBr crystallizes in the monoclinic P2_1/c space group. There are three inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a distorted rectangular see-saw-like geometry to one O(2), one O(3), and two equivalent O(1) atoms. In the second Sb site, Sb(2) is bonded in a 2-coordinate geometry to one O(2), one O(3), one Br(1), and one Br(3) atom. In the third Sb site, Sb(3) is bonded in a 4-coordinate geometry to one O(1), one O(3), one Br(2), and one Br(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Sb(3) and two equivalent Sb(1) atoms. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Sb(1) and one Sb(2) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Sb(1), one Sb(2), and one Sb(3) atom. There are three inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one Sb(2) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one Sb(3) atom. In the third Br site, Br(3) is bonded in a distorted bent 120 degrees geometry to one Sb(2) and one Sb(3) atom. is represented by the CIF card [CIF]
data_SbBrO
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.364
_cell_length_b   8.347
_cell_length_c   9.715
_cell_angle_alpha   76.192
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   894.912
_cell_formula_units_Z   12
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.531  0.292  0.071  1.0
  Sb  Sb1  1  0.255  0.892  0.110  1.0
  Sb  Sb2  1  0.172  0.476  0.242  1.0
  Sb  Sb3  1  0.672  0.524  0.258  1.0
  Sb  Sb4  1  0.755  0.108  0.390  1.0
  Sb  Sb5  1  0.031  0.708  0.429  1.0
  Sb  Sb6  1  0.969  0.292  0.571  1.0
  Sb  Sb7  1  0.245  0.892  0.610  1.0
  Sb  Sb8  1  0.328  0.476  0.742  1.0
  Sb  Sb9  1  0.828  0.524  0.758  1.0
  Sb  Sb10  1  0.745  0.108  0.890  1.0
  Sb  Sb11  1  0.469  0.708  0.929  1.0
  Br  Br12  1  0.900  0.127  0.080  1.0
  Br  Br13  1  0.864  0.607  0.119  1.0
  Br  Br14  1  0.607  0.894  0.155  1.0
  Br  Br15  1  0.107  0.106  0.345  1.0
  Br  Br16  1  0.364  0.393  0.381  1.0
  Br  Br17  1  0.400  0.873  0.420  1.0
  Br  Br18  1  0.600  0.127  0.580  1.0
  Br  Br19  1  0.636  0.607  0.619  1.0
  Br  Br20  1  0.893  0.894  0.655  1.0
  Br  Br21  1  0.393  0.106  0.845  1.0
  Br  Br22  1  0.136  0.393  0.881  1.0
  Br  Br23  1  0.100  0.873  0.920  1.0
  O  O24  1  0.570  0.529  0.087  1.0
  O  O25  1  0.343  0.704  0.068  1.0
  O  O26  1  0.668  0.285  0.244  1.0
  O  O27  1  0.168  0.715  0.256  1.0
  O  O28  1  0.843  0.296  0.432  1.0
  O  O29  1  0.070  0.471  0.413  1.0
  O  O30  1  0.930  0.529  0.587  1.0
  O  O31  1  0.157  0.704  0.568  1.0
  O  O32  1  0.832  0.285  0.744  1.0
  O  O33  1  0.332  0.715  0.756  1.0
  O  O34  1  0.657  0.296  0.932  1.0
  O  O35  1  0.430  0.471  0.913  1.0
[/CIF]
.
The structure described by SbOBr crystallizes in the monoclinic P2_1/c space group. There are three inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a distorted rectangular see-saw-like geometry to one O(2), one O(3), and two equivalent O(1) atoms. In the second Sb site, Sb(2) is bonded in a 2-coordinate geometry to one O(2), one O(3), one Br(1), and one Br(3) atom. In the third Sb site, Sb(3) is bonded in a 4-coordinate geometry to one O(1), one O(3), one Br(2), and one Br(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Sb(3) and two equivalent Sb(1) atoms. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Sb(1) and one Sb(2) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Sb(1), one Sb(2), and one Sb(3) atom. There are three inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one Sb(2) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one Sb(3) atom. In the third Br site, Br(3) is bonded in a distorted bent 120 degrees geometry to one Sb(2) and one Sb(3) atom. is represented by the CIF card [CIF]
data_SbBrO
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.364
_cell_length_b   8.347
_cell_length_c   9.715
_cell_angle_alpha   76.192
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   894.912
_cell_formula_units_Z   12
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.531  0.292  0.071  1.0
  Sb  Sb1  1  0.255  0.892  0.110  1.0
  Sb  Sb2  1  0.172  0.476  0.242  1.0
  Sb  Sb3  1  0.672  0.524  0.258  1.0
  Sb  Sb4  1  0.755  0.108  0.390  1.0
  Sb  Sb5  1  0.031  0.708  0.429  1.0
  Sb  Sb6  1  0.969  0.292  0.571  1.0
  Sb  Sb7  1  0.245  0.892  0.610  1.0
  Sb  Sb8  1  0.328  0.476  0.742  1.0
  Sb  Sb9  1  0.828  0.524  0.758  1.0
  Sb  Sb10  1  0.745  0.108  0.890  1.0
  Sb  Sb11  1  0.469  0.708  0.929  1.0
  Br  Br12  1  0.900  0.127  0.080  1.0
  Br  Br13  1  0.864  0.607  0.119  1.0
  Br  Br14  1  0.607  0.894  0.155  1.0
  Br  Br15  1  0.107  0.106  0.345  1.0
  Br  Br16  1  0.364  0.393  0.381  1.0
  Br  Br17  1  0.400  0.873  0.420  1.0
  Br  Br18  1  0.600  0.127  0.580  1.0
  Br  Br19  1  0.636  0.607  0.619  1.0
  Br  Br20  1  0.893  0.894  0.655  1.0
  Br  Br21  1  0.393  0.106  0.845  1.0
  Br  Br22  1  0.136  0.393  0.881  1.0
  Br  Br23  1  0.100  0.873  0.920  1.0
  O  O24  1  0.570  0.529  0.087  1.0
  O  O25  1  0.343  0.704  0.068  1.0
  O  O26  1  0.668  0.285  0.244  1.0
  O  O27  1  0.168  0.715  0.256  1.0
  O  O28  1  0.843  0.296  0.432  1.0
  O  O29  1  0.070  0.471  0.413  1.0
  O  O30  1  0.930  0.529  0.587  1.0
  O  O31  1  0.157  0.704  0.568  1.0
  O  O32  1  0.832  0.285  0.744  1.0
  O  O33  1  0.332  0.715  0.756  1.0
  O  O34  1  0.657  0.296  0.932  1.0
  O  O35  1  0.430  0.471  0.913  1.0
[/CIF]
.