The structure described by C2SOC2BiSOCl3 is Indium-derived structured and crystallizes in the monoclinic C2 space group. The structure is zero-dimensional and consists of two C2BiSOCl3 clusters and two C2SO clusters. In each C2BiSOCl3 cluster, there are two inequivalent C sites. In the first C site, C(1) is bonded in a bent 150 degrees geometry to one C(2) and one S(1) atom. In the second C site, C(2) is bonded in a bent 150 degrees geometry to one C(1) and one Bi(1) atom. Bi(1) is bonded in a 4-coordinate geometry to one C(2), one O(1), one Cl(2), and one Cl(3) atom. S(1) is bonded in a distorted trigonal non-coplanar geometry to one C(1), one O(1), and one Cl(1) atom. O(1) is bonded in a bent 120 degrees geometry to one Bi(1) and one S(1) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in a single-bond geometry to one Bi(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one S(1) atom. In the third Cl site, Cl(2) is bonded in a distorted single-bond geometry to one Bi(1) atom. In each C2SO cluster, there are two inequivalent C sites. In the first C site, C(3) is bonded in a linear geometry to one C(3) and one C(4) atom. In the second C site, C(4) is bonded in a bent 150 degrees geometry to one C(3) and one S(2) atom. S(2) is bonded in a distorted single-bond geometry to one C(4) and one O(2) atom. O(2) is bonded in a single-bond geometry to one S(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_BiC4S2Cl3O2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.555
_cell_length_b   9.555
_cell_length_c   8.483
_cell_angle_alpha   74.470
_cell_angle_beta   74.470
_cell_angle_gamma   64.937
_symmetry_Int_Tables_number   1
_cell_volume   665.252
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.057  0.540  0.431  1.0
  Bi  Bi1  1  0.460  0.943  0.569  1.0
  C  C2  1  0.264  0.927  0.268  1.0
  C  C3  1  0.073  0.736  0.732  1.0
  C  C4  1  0.334  0.976  0.331  1.0
  C  C5  1  0.024  0.666  0.669  1.0
  C  C6  1  0.711  0.327  0.057  1.0
  C  C7  1  0.673  0.289  0.943  1.0
  C  C8  1  0.759  0.349  0.171  1.0
  C  C9  1  0.651  0.241  0.829  1.0
  S  S10  1  0.230  0.795  0.206  1.0
  S  S11  1  0.205  0.770  0.794  1.0
  S  S12  1  0.877  0.404  0.221  1.0
  S  S13  1  0.596  0.123  0.779  1.0
  Cl  Cl14  1  0.975  0.899  0.216  1.0
  Cl  Cl15  1  0.101  0.025  0.784  1.0
  Cl  Cl16  1  0.690  0.740  0.421  1.0
  Cl  Cl17  1  0.260  0.310  0.579  1.0
  Cl  Cl18  1  0.198  0.462  0.137  1.0
  Cl  Cl19  1  0.538  0.802  0.863  1.0
  O  O20  1  0.243  0.662  0.353  1.0
  O  O21  1  0.338  0.757  0.647  1.0
  O  O22  1  0.890  0.365  0.402  1.0
  O  O23  1  0.635  0.110  0.598  1.0
[/CIF]
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The structure described by C2SOC2BiSOCl3 is Indium-derived structured and crystallizes in the monoclinic C2 space group. The structure is zero-dimensional and consists of two C2BiSOCl3 clusters and two C2SO clusters. In each C2BiSOCl3 cluster, there are two inequivalent C sites. In the first C site, C(1) is bonded in a bent 150 degrees geometry to one C(2) and one S(1) atom. In the second C site, C(2) is bonded in a bent 150 degrees geometry to one C(1) and one Bi(1) atom. Bi(1) is bonded in a 4-coordinate geometry to one C(2), one O(1), one Cl(2), and one Cl(3) atom. S(1) is bonded in a distorted trigonal non-coplanar geometry to one C(1), one O(1), and one Cl(1) atom. O(1) is bonded in a bent 120 degrees geometry to one Bi(1) and one S(1) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in a single-bond geometry to one Bi(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one S(1) atom. In the third Cl site, Cl(2) is bonded in a distorted single-bond geometry to one Bi(1) atom. In each C2SO cluster, there are two inequivalent C sites. In the first C site, C(3) is bonded in a linear geometry to one C(3) and one C(4) atom. In the second C site, C(4) is bonded in a bent 150 degrees geometry to one C(3) and one S(2) atom. S(2) is bonded in a distorted single-bond geometry to one C(4) and one O(2) atom. O(2) is bonded in a single-bond geometry to one S(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_BiC4S2Cl3O2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.555
_cell_length_b   9.555
_cell_length_c   8.483
_cell_angle_alpha   74.470
_cell_angle_beta   74.470
_cell_angle_gamma   64.937
_symmetry_Int_Tables_number   1
_cell_volume   665.252
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.057  0.540  0.431  1.0
  Bi  Bi1  1  0.460  0.943  0.569  1.0
  C  C2  1  0.264  0.927  0.268  1.0
  C  C3  1  0.073  0.736  0.732  1.0
  C  C4  1  0.334  0.976  0.331  1.0
  C  C5  1  0.024  0.666  0.669  1.0
  C  C6  1  0.711  0.327  0.057  1.0
  C  C7  1  0.673  0.289  0.943  1.0
  C  C8  1  0.759  0.349  0.171  1.0
  C  C9  1  0.651  0.241  0.829  1.0
  S  S10  1  0.230  0.795  0.206  1.0
  S  S11  1  0.205  0.770  0.794  1.0
  S  S12  1  0.877  0.404  0.221  1.0
  S  S13  1  0.596  0.123  0.779  1.0
  Cl  Cl14  1  0.975  0.899  0.216  1.0
  Cl  Cl15  1  0.101  0.025  0.784  1.0
  Cl  Cl16  1  0.690  0.740  0.421  1.0
  Cl  Cl17  1  0.260  0.310  0.579  1.0
  Cl  Cl18  1  0.198  0.462  0.137  1.0
  Cl  Cl19  1  0.538  0.802  0.863  1.0
  O  O20  1  0.243  0.662  0.353  1.0
  O  O21  1  0.338  0.757  0.647  1.0
  O  O22  1  0.890  0.365  0.402  1.0
  O  O23  1  0.635  0.110  0.598  1.0
[/CIF]
.