The material structure described by Mn3In2Sb3O14 crystallizes in the triclinic P1 space group. There are six inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(11), one O(21), one O(23), one O(25), one O(27), one O(3), and one O(9) atom to form distorted MnO8 hexagonal bipyramids that share  an edgeedge with one Sb(3)O6 octahedra,  an edgeedge with one Sb(4)O6 octahedra,  an edgeedge with one Sb(5)O6 octahedra,  an edgeedge with one Sb(6)O6 octahedra, and edges with two equivalent Sb(1)O6 octahedra. In the second Mn site, Mn(2) is bonded to one O(10), one O(12), one O(2), one O(22), one O(24), one O(26), one O(28), and one O(4) atom to form distorted MnO8 hexagonal bipyramids that share  an edgeedge with one Sb(3)O6 octahedra,  an edgeedge with one Sb(4)O6 octahedra,  an edgeedge with one Sb(5)O6 octahedra,  an edgeedge with one Sb(6)O6 octahedra, and edges with two equivalent Sb(2)O6 octahedra. In the third Mn site, Mn(3) is bonded in a distorted body-centered cubic geometry to one O(1), one O(12), one O(14), one O(16), one O(17), one O(19), one O(4), and one O(9) atom. In the fourth Mn site, Mn(4) is bonded in a body-centered cubic geometry to one O(10), one O(11), one O(13), one O(15), one O(18), one O(2), one O(20), and one O(3) atom. In the fifth Mn site, Mn(5) is bonded to one O(14), one O(16), one O(17), one O(19), one O(6), and one O(7) atom to form MnO6 octahedra that share  a cornercorner with one Sb(1)O6 octahedra,  a cornercorner with one Sb(2)O6 octahedra, corners with two equivalent Sb(4)O6 octahedra, and corners with two equivalent Sb(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-55°. In the sixth Mn site, Mn(6) is bonded to one O(13), one O(15), one O(18), one O(20), one O(5), and one O(8) atom to form MnO6 octahedra that share  a cornercorner with one Sb(1)O6 octahedra,  a cornercorner with one Sb(2)O6 octahedra, corners with two equivalent Sb(3)O6 octahedra, and corners with two equivalent Sb(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-55°. There are four inequivalent In sites. In the first In site, In(1) is bonded in a distorted body-centered cubic geometry to one O(1), one O(16), one O(20), one O(21), one O(25), one O(3), one O(5), and one O(7) atom. In the second In site, In(2) is bonded in a distorted body-centered cubic geometry to one O(15), one O(19), one O(2), one O(22), one O(26), one O(4), one O(6), and one O(8) atom. In the third In site, In(3) is bonded in a distorted body-centered cubic geometry to one O(1), one O(14), one O(18), one O(23), one O(27), one O(3), one O(5), and one O(7) atom. In the fourth In site, In(4) is bonded in a distorted body-centered cubic geometry to one O(13), one O(17), one O(2), one O(24), one O(28), one O(4), one O(6), and one O(8) atom. There are six inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(21), one O(23), one O(25), one O(27), one O(5), and one O(7) atom to form SbO6 octahedra that share  a cornercorner with one Mn(5)O6 octahedra,  a cornercorner with one Mn(6)O6 octahedra,  a cornercorner with one Sb(3)O6 octahedra,  a cornercorner with one Sb(4)O6 octahedra,  a cornercorner with one Sb(5)O6 octahedra,  a cornercorner with one Sb(6)O6 octahedra, and edges with two equivalent Mn(1)O8 hexagonal bipyramids. The corner-sharing octahedral tilt angles range from 47-55°. In the second Sb site, Sb(2) is bonded to one O(22), one O(24), one O(26), one O(28), one O(6), and one O(8) atom to form SbO6 octahedra that share  a cornercorner with one Mn(5)O6 octahedra,  a cornercorner with one Mn(6)O6 octahedra,  a cornercorner with one Sb(3)O6 octahedra,  a cornercorner with one Sb(4)O6 octahedra,  a cornercorner with one Sb(5)O6 octahedra,  a cornercorner with one Sb(6)O6 octahedra, and edges with two equivalent Mn(2)O8 hexagonal bipyramids. The corner-sharing octahedral tilt angles range from 47-55°. In the third Sb site, Sb(3) is bonded to one O(10), one O(11), one O(13), one O(18), one O(23), and one O(28) atom to form SbO6 octahedra that share  a cornercorner with one Sb(1)O6 octahedra,  a cornercorner with one Sb(2)O6 octahedra, corners with two equivalent Mn(6)O6 octahedra, corners with two equivalent Sb(5)O6 octahedra,  an edgeedge with one Mn(1)O8 hexagonal bipyramid, and  an edgeedge with one Mn(2)O8 hexagonal bipyramid. The corner-sharing octahedral tilt angles range from 47-50°. In the fourth Sb site, Sb(4) is bonded to one O(12), one O(14), one O(17), one O(24), one O(27), and one O(9) atom to form SbO6 octahedra that share  a cornercorner with one Sb(1)O6 octahedra,  a cornercorner with one Sb(2)O6 octahedra, corners with two equivalent Mn(5)O6 octahedra, corners with two equivalent Sb(6)O6 octahedra,  an edgeedge with one Mn(1)O8 hexagonal bipyramid, and  an edgeedge with one Mn(2)O8 hexagonal bipyramid. The corner-sharing octahedral tilt angles range from 47-50°. In the fifth Sb site, Sb(5) is bonded to one O(10), one O(11), one O(15), one O(20), one O(21), and one O(26) atom to form SbO6 octahedra that share  a cornercorner with one Sb(1)O6 octahedra,  a cornercorner with one Sb(2)O6 octahedra, corners with two equivalent Mn(6)O6 octahedra, corners with two equivalent Sb(3)O6 octahedra,  an edgeedge with one Mn(1)O8 hexagonal bipyramid, and  an edgeedge with one Mn(2)O8 hexagonal bipyramid. The corner-sharing octahedral tilt angles range from 47-50°. In the sixth Sb site, Sb(6) is bonded to one O(12), one O(16), one O(19), one O(22), one O(25), and one O(9) atom to form SbO6 octahedra that share  a cornercorner with one Sb(1)O6 octahedra,  a cornercorner with one Sb(2)O6 octahedra, corners with two equivalent Mn(5)O6 octahedra, corners with two equivalent Sb(4)O6 octahedra,  an edgeedge with one Mn(1)O8 hexagonal bipyramid, and  an edgeedge with one Mn(2)O8 hexagonal bipyramid. The corner-sharing octahedral tilt angles range from 47-50°. There are twenty-eight inequivalent O sites. In the first O site, O(1) is bonded to one Mn(1), one Mn(3), one In(1), and one In(3) atom to form OMn2In2 tetrahedra that share  a cornercorner with one O(4)Mn2In2 tetrahedra, corners with two equivalent O(7)MnIn2Sb tetrahedra, corners with three equivalent O(3)Mn2In2 tetrahedra, and  an edgeedge with one O(5)MnIn2Sb tetrahedra. In the second O site, O(2) is bonded to one Mn(2), one Mn(4), one In(2), and one In(4) atom to form OMn2In2 tetrahedra that share  a cornercorner with one O(3)Mn2In2 tetrahedra, corners with two equivalent O(8)MnIn2Sb tetrahedra, corners with three equivalent O(4)Mn2In2 tetrahedra, and  an edgeedge with one O(6)MnIn2Sb tetrahedra. In the third O site, O(3) is bonded to one Mn(1), one Mn(4), one In(1), and one In(3) atom to form OMn2In2 tetrahedra that share  a cornercorner with one O(2)Mn2In2 tetrahedra, corners with two equivalent O(5)MnIn2Sb tetrahedra, corners with three equivalent O(1)Mn2In2 tetrahedra, and  an edgeedge with one O(7)MnIn2Sb tetrahedra. In the fourth O site, O(4) is bonded to one Mn(2), one Mn(3), one In(2), and one In(4) atom to form OMn2In2 tetrahedra that share  a cornercorner with one O(1)Mn2In2 tetrahedra, corners with two equivalent O(6)MnIn2Sb tetrahedra, corners with three equivalent O(2)Mn2In2 tetrahedra, and  an edgeedge with one O(8)MnIn2Sb tetrahedra. In the fifth O site, O(5) is bonded to one Mn(6), one In(1), one In(3), and one Sb(1) atom to form distorted OMnIn2Sb tetrahedra that share  a cornercorner with one O(8)MnIn2Sb tetrahedra, corners with two equivalent O(3)Mn2In2 tetrahedra, corners with three equivalent O(7)MnIn2Sb tetrahedra, and  an edgeedge with one O(1)Mn2In2 tetrahedra. In the sixth O site, O(6) is bonded to one Mn(5), one In(2), one In(4), and one Sb(2) atom to form distorted OMnIn2Sb tetrahedra that share  a cornercorner with one O(7)MnIn2Sb tetrahedra, corners with two equivalent O(4)Mn2In2 tetrahedra, corners with three equivalent O(8)MnIn2Sb tetrahedra, and  an edgeedge with one O(2)Mn2In2 tetrahedra. In the seventh O site, O(7) is bonded to one Mn(5), one In(1), one In(3), and one Sb(1) atom to form distorted OMnIn2Sb tetrahedra that share  a cornercorner with one O(6)MnIn2Sb tetrahedra, corners with two equivalent O(1)Mn2In2 tetrahedra, corners with three equivalent O(5)MnIn2Sb tetrahedra, and  an edgeedge with one O(3)Mn2In2 tetrahedra. In the eighth O site, O(8) is bonded to one Mn(6), one In(2), one In(4), and one Sb(2) atom to form distorted OMnIn2Sb tetrahedra that share  a cornercorner with one O(5)MnIn2Sb tetrahedra, corners with two equivalent O(2)Mn2In2 tetrahedra, corners with three equivalent O(6)MnIn2Sb tetrahedra, and  an edgeedge with one O(4)Mn2In2 tetrahedra. In the ninth O site, O(9) is bonded in a 4-coordinate geometry to one Mn(1), one Mn(3), one Sb(4), and one Sb(6) atom. In the tenth O site, O(10) is bonded in a 4-coordinate geometry to one Mn(2), one Mn(4), one Sb(3), and one Sb(5) atom. In the eleventh O site, O(11) is bonded in a 4-coordinate geometry to one Mn(1), one Mn(4), one Sb(3), and one Sb(5) atom. In the twelfth O site, O(12) is bonded in a 4-coordinate geometry to one Mn(2), one Mn(3), one Sb(4), and one Sb(6) atom. In the thirteenth O site, O(13) is bonded in a 4-coordinate geometry to one Mn(4), one Mn(6), one In(4), and one Sb(3) atom. In the fourteenth O site, O(14) is bonded in a 4-coordinate geometry to one Mn(3), one Mn(5), one In(3), and one Sb(4) atom. In the fifteenth O site, O(15) is bonded in a 4-coordinate geometry to one Mn(4), one Mn(6), one In(2), and one Sb(5) atom. In the sixteenth O site, O(16) is bonded in a 4-coordinate geometry to one Mn(3), one Mn(5), one In(1), and one Sb(6) atom. In the seventeenth O site, O(17) is bonded in a 4-coordinate geometry to one Mn(3), one Mn(5), one In(4), and one Sb(4) atom. In the eighteenth O site, O(18) is bonded in a 4-coordinate geometry to one Mn(4), one Mn(6), one In(3), and one Sb(3) atom. In the nineteenth O site, O(19) is bonded in a 4-coordinate geometry to one Mn(3), one Mn(5), one In(2), and one Sb(6) atom. In the twentieth O site, O(20) is bonded in a 4-coordinate geometry to one Mn(4), one Mn(6), one In(1), and one Sb(5) atom. In the twenty-first O site, O(21) is bonded in a 4-coordinate geometry to one Mn(1), one In(1), one Sb(1), and one Sb(5) atom. In the twenty-second O site, O(22) is bonded in a 4-coordinate geometry to one Mn(2), one In(2), one Sb(2), and one Sb(6) atom. In the twenty-third O site, O(23) is bonded in a 4-coordinate geometry to one Mn(1), one In(3), one Sb(1), and one Sb(3) atom. In the twenty-fourth O site, O(24) is bonded in a 4-coordinate geometry to one Mn(2), one In(4), one Sb(2), and one Sb(4) atom. In the twenty-fifth O site, O(25) is bonded in a 4-coordinate geometry to one Mn(1), one In(1), one Sb(1), and one Sb(6) atom. In the twenty-sixth O site, O(26) is bonded in a 4-coordinate geometry to one Mn(2), one In(2), one Sb(2), and one Sb(5) atom. In the twenty-seventh O site, O(27) is bonded in a 4-coordinate geometry to one Mn(1), one In(3), one Sb(1), and one Sb(4) atom. In the twenty-eighth O site, O(28) is bonded in a 4-coordinate geometry to one Mn(2), one In(4), one Sb(2), and one Sb(3) atom. is represented by the CIF file [CIF]
data_Mn3In2Sb3O14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.136
_cell_length_b   7.136
_cell_length_c   7.345
_cell_angle_alpha   118.937
_cell_angle_beta   90.446
_cell_angle_gamma   119.554
_symmetry_Int_Tables_number   1
_cell_volume   269.418
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.500  0.500  1.000  1.0
  In  In1  1  1.000  0.000  0.000  1.0
  Mn  Mn2  1  0.000  0.500  0.000  1.0
  Mn  Mn3  1  0.999  0.999  0.500  1.0
  Mn  Mn4  1  0.500  0.500  0.500  1.0
  O  O5  1  0.127  0.254  0.880  1.0
  O  O6  1  0.872  0.746  0.120  1.0
  O  O7  1  0.404  0.236  0.143  1.0
  O  O8  1  0.596  0.764  0.857  1.0
  O  O9  1  0.831  0.235  0.567  1.0
  O  O10  1  0.169  0.765  0.434  1.0
  O  O11  1  0.829  0.662  0.588  1.0
  O  O12  1  0.426  0.259  0.588  1.0
  O  O13  1  0.171  0.338  0.412  1.0
  O  O14  1  0.574  0.741  0.413  1.0
  O  O15  1  0.408  0.844  0.176  1.0
  O  O16  1  0.832  0.269  0.177  1.0
  O  O17  1  0.592  0.156  0.824  1.0
  O  O18  1  0.168  0.731  0.823  1.0
  Sb  Sb19  1  0.500  0.000  0.000  1.0
  Sb  Sb20  1  0.000  0.500  0.500  1.0
  Sb  Sb21  1  0.500  0.000  0.500  1.0
[/CIF]
.
The material structure described by Mn3In2Sb3O14 crystallizes in the triclinic P1 space group. There are six inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(11), one O(21), one O(23), one O(25), one O(27), one O(3), and one O(9) atom to form distorted MnO8 hexagonal bipyramids that share  an edgeedge with one Sb(3)O6 octahedra,  an edgeedge with one Sb(4)O6 octahedra,  an edgeedge with one Sb(5)O6 octahedra,  an edgeedge with one Sb(6)O6 octahedra, and edges with two equivalent Sb(1)O6 octahedra. In the second Mn site, Mn(2) is bonded to one O(10), one O(12), one O(2), one O(22), one O(24), one O(26), one O(28), and one O(4) atom to form distorted MnO8 hexagonal bipyramids that share  an edgeedge with one Sb(3)O6 octahedra,  an edgeedge with one Sb(4)O6 octahedra,  an edgeedge with one Sb(5)O6 octahedra,  an edgeedge with one Sb(6)O6 octahedra, and edges with two equivalent Sb(2)O6 octahedra. In the third Mn site, Mn(3) is bonded in a distorted body-centered cubic geometry to one O(1), one O(12), one O(14), one O(16), one O(17), one O(19), one O(4), and one O(9) atom. In the fourth Mn site, Mn(4) is bonded in a body-centered cubic geometry to one O(10), one O(11), one O(13), one O(15), one O(18), one O(2), one O(20), and one O(3) atom. In the fifth Mn site, Mn(5) is bonded to one O(14), one O(16), one O(17), one O(19), one O(6), and one O(7) atom to form MnO6 octahedra that share  a cornercorner with one Sb(1)O6 octahedra,  a cornercorner with one Sb(2)O6 octahedra, corners with two equivalent Sb(4)O6 octahedra, and corners with two equivalent Sb(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-55°. In the sixth Mn site, Mn(6) is bonded to one O(13), one O(15), one O(18), one O(20), one O(5), and one O(8) atom to form MnO6 octahedra that share  a cornercorner with one Sb(1)O6 octahedra,  a cornercorner with one Sb(2)O6 octahedra, corners with two equivalent Sb(3)O6 octahedra, and corners with two equivalent Sb(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-55°. There are four inequivalent In sites. In the first In site, In(1) is bonded in a distorted body-centered cubic geometry to one O(1), one O(16), one O(20), one O(21), one O(25), one O(3), one O(5), and one O(7) atom. In the second In site, In(2) is bonded in a distorted body-centered cubic geometry to one O(15), one O(19), one O(2), one O(22), one O(26), one O(4), one O(6), and one O(8) atom. In the third In site, In(3) is bonded in a distorted body-centered cubic geometry to one O(1), one O(14), one O(18), one O(23), one O(27), one O(3), one O(5), and one O(7) atom. In the fourth In site, In(4) is bonded in a distorted body-centered cubic geometry to one O(13), one O(17), one O(2), one O(24), one O(28), one O(4), one O(6), and one O(8) atom. There are six inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(21), one O(23), one O(25), one O(27), one O(5), and one O(7) atom to form SbO6 octahedra that share  a cornercorner with one Mn(5)O6 octahedra,  a cornercorner with one Mn(6)O6 octahedra,  a cornercorner with one Sb(3)O6 octahedra,  a cornercorner with one Sb(4)O6 octahedra,  a cornercorner with one Sb(5)O6 octahedra,  a cornercorner with one Sb(6)O6 octahedra, and edges with two equivalent Mn(1)O8 hexagonal bipyramids. The corner-sharing octahedral tilt angles range from 47-55°. In the second Sb site, Sb(2) is bonded to one O(22), one O(24), one O(26), one O(28), one O(6), and one O(8) atom to form SbO6 octahedra that share  a cornercorner with one Mn(5)O6 octahedra,  a cornercorner with one Mn(6)O6 octahedra,  a cornercorner with one Sb(3)O6 octahedra,  a cornercorner with one Sb(4)O6 octahedra,  a cornercorner with one Sb(5)O6 octahedra,  a cornercorner with one Sb(6)O6 octahedra, and edges with two equivalent Mn(2)O8 hexagonal bipyramids. The corner-sharing octahedral tilt angles range from 47-55°. In the third Sb site, Sb(3) is bonded to one O(10), one O(11), one O(13), one O(18), one O(23), and one O(28) atom to form SbO6 octahedra that share  a cornercorner with one Sb(1)O6 octahedra,  a cornercorner with one Sb(2)O6 octahedra, corners with two equivalent Mn(6)O6 octahedra, corners with two equivalent Sb(5)O6 octahedra,  an edgeedge with one Mn(1)O8 hexagonal bipyramid, and  an edgeedge with one Mn(2)O8 hexagonal bipyramid. The corner-sharing octahedral tilt angles range from 47-50°. In the fourth Sb site, Sb(4) is bonded to one O(12), one O(14), one O(17), one O(24), one O(27), and one O(9) atom to form SbO6 octahedra that share  a cornercorner with one Sb(1)O6 octahedra,  a cornercorner with one Sb(2)O6 octahedra, corners with two equivalent Mn(5)O6 octahedra, corners with two equivalent Sb(6)O6 octahedra,  an edgeedge with one Mn(1)O8 hexagonal bipyramid, and  an edgeedge with one Mn(2)O8 hexagonal bipyramid. The corner-sharing octahedral tilt angles range from 47-50°. In the fifth Sb site, Sb(5) is bonded to one O(10), one O(11), one O(15), one O(20), one O(21), and one O(26) atom to form SbO6 octahedra that share  a cornercorner with one Sb(1)O6 octahedra,  a cornercorner with one Sb(2)O6 octahedra, corners with two equivalent Mn(6)O6 octahedra, corners with two equivalent Sb(3)O6 octahedra,  an edgeedge with one Mn(1)O8 hexagonal bipyramid, and  an edgeedge with one Mn(2)O8 hexagonal bipyramid. The corner-sharing octahedral tilt angles range from 47-50°. In the sixth Sb site, Sb(6) is bonded to one O(12), one O(16), one O(19), one O(22), one O(25), and one O(9) atom to form SbO6 octahedra that share  a cornercorner with one Sb(1)O6 octahedra,  a cornercorner with one Sb(2)O6 octahedra, corners with two equivalent Mn(5)O6 octahedra, corners with two equivalent Sb(4)O6 octahedra,  an edgeedge with one Mn(1)O8 hexagonal bipyramid, and  an edgeedge with one Mn(2)O8 hexagonal bipyramid. The corner-sharing octahedral tilt angles range from 47-50°. There are twenty-eight inequivalent O sites. In the first O site, O(1) is bonded to one Mn(1), one Mn(3), one In(1), and one In(3) atom to form OMn2In2 tetrahedra that share  a cornercorner with one O(4)Mn2In2 tetrahedra, corners with two equivalent O(7)MnIn2Sb tetrahedra, corners with three equivalent O(3)Mn2In2 tetrahedra, and  an edgeedge with one O(5)MnIn2Sb tetrahedra. In the second O site, O(2) is bonded to one Mn(2), one Mn(4), one In(2), and one In(4) atom to form OMn2In2 tetrahedra that share  a cornercorner with one O(3)Mn2In2 tetrahedra, corners with two equivalent O(8)MnIn2Sb tetrahedra, corners with three equivalent O(4)Mn2In2 tetrahedra, and  an edgeedge with one O(6)MnIn2Sb tetrahedra. In the third O site, O(3) is bonded to one Mn(1), one Mn(4), one In(1), and one In(3) atom to form OMn2In2 tetrahedra that share  a cornercorner with one O(2)Mn2In2 tetrahedra, corners with two equivalent O(5)MnIn2Sb tetrahedra, corners with three equivalent O(1)Mn2In2 tetrahedra, and  an edgeedge with one O(7)MnIn2Sb tetrahedra. In the fourth O site, O(4) is bonded to one Mn(2), one Mn(3), one In(2), and one In(4) atom to form OMn2In2 tetrahedra that share  a cornercorner with one O(1)Mn2In2 tetrahedra, corners with two equivalent O(6)MnIn2Sb tetrahedra, corners with three equivalent O(2)Mn2In2 tetrahedra, and  an edgeedge with one O(8)MnIn2Sb tetrahedra. In the fifth O site, O(5) is bonded to one Mn(6), one In(1), one In(3), and one Sb(1) atom to form distorted OMnIn2Sb tetrahedra that share  a cornercorner with one O(8)MnIn2Sb tetrahedra, corners with two equivalent O(3)Mn2In2 tetrahedra, corners with three equivalent O(7)MnIn2Sb tetrahedra, and  an edgeedge with one O(1)Mn2In2 tetrahedra. In the sixth O site, O(6) is bonded to one Mn(5), one In(2), one In(4), and one Sb(2) atom to form distorted OMnIn2Sb tetrahedra that share  a cornercorner with one O(7)MnIn2Sb tetrahedra, corners with two equivalent O(4)Mn2In2 tetrahedra, corners with three equivalent O(8)MnIn2Sb tetrahedra, and  an edgeedge with one O(2)Mn2In2 tetrahedra. In the seventh O site, O(7) is bonded to one Mn(5), one In(1), one In(3), and one Sb(1) atom to form distorted OMnIn2Sb tetrahedra that share  a cornercorner with one O(6)MnIn2Sb tetrahedra, corners with two equivalent O(1)Mn2In2 tetrahedra, corners with three equivalent O(5)MnIn2Sb tetrahedra, and  an edgeedge with one O(3)Mn2In2 tetrahedra. In the eighth O site, O(8) is bonded to one Mn(6), one In(2), one In(4), and one Sb(2) atom to form distorted OMnIn2Sb tetrahedra that share  a cornercorner with one O(5)MnIn2Sb tetrahedra, corners with two equivalent O(2)Mn2In2 tetrahedra, corners with three equivalent O(6)MnIn2Sb tetrahedra, and  an edgeedge with one O(4)Mn2In2 tetrahedra. In the ninth O site, O(9) is bonded in a 4-coordinate geometry to one Mn(1), one Mn(3), one Sb(4), and one Sb(6) atom. In the tenth O site, O(10) is bonded in a 4-coordinate geometry to one Mn(2), one Mn(4), one Sb(3), and one Sb(5) atom. In the eleventh O site, O(11) is bonded in a 4-coordinate geometry to one Mn(1), one Mn(4), one Sb(3), and one Sb(5) atom. In the twelfth O site, O(12) is bonded in a 4-coordinate geometry to one Mn(2), one Mn(3), one Sb(4), and one Sb(6) atom. In the thirteenth O site, O(13) is bonded in a 4-coordinate geometry to one Mn(4), one Mn(6), one In(4), and one Sb(3) atom. In the fourteenth O site, O(14) is bonded in a 4-coordinate geometry to one Mn(3), one Mn(5), one In(3), and one Sb(4) atom. In the fifteenth O site, O(15) is bonded in a 4-coordinate geometry to one Mn(4), one Mn(6), one In(2), and one Sb(5) atom. In the sixteenth O site, O(16) is bonded in a 4-coordinate geometry to one Mn(3), one Mn(5), one In(1), and one Sb(6) atom. In the seventeenth O site, O(17) is bonded in a 4-coordinate geometry to one Mn(3), one Mn(5), one In(4), and one Sb(4) atom. In the eighteenth O site, O(18) is bonded in a 4-coordinate geometry to one Mn(4), one Mn(6), one In(3), and one Sb(3) atom. In the nineteenth O site, O(19) is bonded in a 4-coordinate geometry to one Mn(3), one Mn(5), one In(2), and one Sb(6) atom. In the twentieth O site, O(20) is bonded in a 4-coordinate geometry to one Mn(4), one Mn(6), one In(1), and one Sb(5) atom. In the twenty-first O site, O(21) is bonded in a 4-coordinate geometry to one Mn(1), one In(1), one Sb(1), and one Sb(5) atom. In the twenty-second O site, O(22) is bonded in a 4-coordinate geometry to one Mn(2), one In(2), one Sb(2), and one Sb(6) atom. In the twenty-third O site, O(23) is bonded in a 4-coordinate geometry to one Mn(1), one In(3), one Sb(1), and one Sb(3) atom. In the twenty-fourth O site, O(24) is bonded in a 4-coordinate geometry to one Mn(2), one In(4), one Sb(2), and one Sb(4) atom. In the twenty-fifth O site, O(25) is bonded in a 4-coordinate geometry to one Mn(1), one In(1), one Sb(1), and one Sb(6) atom. In the twenty-sixth O site, O(26) is bonded in a 4-coordinate geometry to one Mn(2), one In(2), one Sb(2), and one Sb(5) atom. In the twenty-seventh O site, O(27) is bonded in a 4-coordinate geometry to one Mn(1), one In(3), one Sb(1), and one Sb(4) atom. In the twenty-eighth O site, O(28) is bonded in a 4-coordinate geometry to one Mn(2), one In(4), one Sb(2), and one Sb(3) atom. is represented by the CIF file [CIF]
data_Mn3In2Sb3O14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.136
_cell_length_b   7.136
_cell_length_c   7.345
_cell_angle_alpha   118.937
_cell_angle_beta   90.446
_cell_angle_gamma   119.554
_symmetry_Int_Tables_number   1
_cell_volume   269.418
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.500  0.500  1.000  1.0
  In  In1  1  1.000  0.000  0.000  1.0
  Mn  Mn2  1  0.000  0.500  0.000  1.0
  Mn  Mn3  1  0.999  0.999  0.500  1.0
  Mn  Mn4  1  0.500  0.500  0.500  1.0
  O  O5  1  0.127  0.254  0.880  1.0
  O  O6  1  0.872  0.746  0.120  1.0
  O  O7  1  0.404  0.236  0.143  1.0
  O  O8  1  0.596  0.764  0.857  1.0
  O  O9  1  0.831  0.235  0.567  1.0
  O  O10  1  0.169  0.765  0.434  1.0
  O  O11  1  0.829  0.662  0.588  1.0
  O  O12  1  0.426  0.259  0.588  1.0
  O  O13  1  0.171  0.338  0.412  1.0
  O  O14  1  0.574  0.741  0.413  1.0
  O  O15  1  0.408  0.844  0.176  1.0
  O  O16  1  0.832  0.269  0.177  1.0
  O  O17  1  0.592  0.156  0.824  1.0
  O  O18  1  0.168  0.731  0.823  1.0
  Sb  Sb19  1  0.500  0.000  0.000  1.0
  Sb  Sb20  1  0.000  0.500  0.500  1.0
  Sb  Sb21  1  0.500  0.000  0.500  1.0
[/CIF]
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