The material described by NV3P crystallizes in the orthorhombic Cmcm space group. There are two inequivalent V sites. In the first V site, V(1) is bonded in a 4-coordinate geometry to two equivalent P(1) and two equivalent N(1) atoms. In the second V site, V(2) is bonded in a 5-coordinate geometry to three equivalent P(1) and two equivalent N(1) atoms. P(1) is bonded in a 8-coordinate geometry to two equivalent V(1) and six equivalent V(2) atoms. N(1) is bonded to two equivalent V(1) and four equivalent V(2) atoms to form a mixture of corner and edge-sharing NV6 octahedra. The corner-sharing octahedral tilt angles are 39°. is represented by the CIF card [CIF]
data_V3PN
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.074
_cell_length_b   5.074
_cell_length_c   7.352
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   144.377
_symmetry_Int_Tables_number   1
_cell_volume   110.270
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.933  0.067  0.250  1.0
  V  V1  1  0.067  0.933  0.750  1.0
  V  V2  1  0.635  0.365  0.449  1.0
  V  V3  1  0.365  0.635  0.551  1.0
  V  V4  1  0.635  0.365  0.051  1.0
  V  V5  1  0.365  0.635  0.949  1.0
  P  P6  1  0.252  0.748  0.250  1.0
  P  P7  1  0.748  0.252  0.750  1.0
  N  N8  1  1.000  0.000  0.500  1.0
  N  N9  1  1.000  0.000  0.000  1.0
[/CIF]
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The material described by NV3P crystallizes in the orthorhombic Cmcm space group. There are two inequivalent V sites. In the first V site, V(1) is bonded in a 4-coordinate geometry to two equivalent P(1) and two equivalent N(1) atoms. In the second V site, V(2) is bonded in a 5-coordinate geometry to three equivalent P(1) and two equivalent N(1) atoms. P(1) is bonded in a 8-coordinate geometry to two equivalent V(1) and six equivalent V(2) atoms. N(1) is bonded to two equivalent V(1) and four equivalent V(2) atoms to form a mixture of corner and edge-sharing NV6 octahedra. The corner-sharing octahedral tilt angles are 39°. is represented by the CIF card [CIF]
data_V3PN
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.074
_cell_length_b   5.074
_cell_length_c   7.352
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   144.377
_symmetry_Int_Tables_number   1
_cell_volume   110.270
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.933  0.067  0.250  1.0
  V  V1  1  0.067  0.933  0.750  1.0
  V  V2  1  0.635  0.365  0.449  1.0
  V  V3  1  0.365  0.635  0.551  1.0
  V  V4  1  0.635  0.365  0.051  1.0
  V  V5  1  0.365  0.635  0.949  1.0
  P  P6  1  0.252  0.748  0.250  1.0
  P  P7  1  0.748  0.252  0.750  1.0
  N  N8  1  1.000  0.000  0.500  1.0
  N  N9  1  1.000  0.000  0.000  1.0
[/CIF]
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