The compound described by C2AsN(OF3)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four C2AsN(OF3)2 clusters. There are two inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one O(2), and one F(4) atom. In the second C site, C(2) is bonded in a linear geometry to one N(1) and one O(1) atom. As(1) is bonded in an octahedral geometry to one O(2), one F(1), one F(2), one F(3), one F(5), and one F(6) atom. N(1) is bonded in a bent 120 degrees geometry to one C(1) and one C(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(2) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one C(1) and one As(1) atom. There are six inequivalent F sites. In the first F site, F(6) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(4) is bonded in a single-bond geometry to one C(1) atom. In the sixth F site, F(5) is bonded in a single-bond geometry to one As(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_AsC2N(OF3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.418
_cell_length_b   8.824
_cell_length_c   15.396
_cell_angle_alpha   79.610
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   723.949
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.761  0.793  0.902  1.0
  As  As1  1  0.739  0.793  0.402  1.0
  As  As2  1  0.239  0.207  0.098  1.0
  As  As3  1  0.261  0.207  0.598  1.0
  C  C4  1  0.351  0.863  0.642  1.0
  C  C5  1  0.851  0.137  0.858  1.0
  C  C6  1  0.649  0.137  0.358  1.0
  C  C7  1  0.149  0.863  0.142  1.0
  C  C8  1  0.412  0.650  0.167  1.0
  C  C9  1  0.912  0.350  0.333  1.0
  C  C10  1  0.588  0.350  0.833  1.0
  C  C11  1  0.088  0.650  0.667  1.0
  N  N12  1  0.208  0.713  0.159  1.0
  N  N13  1  0.708  0.287  0.341  1.0
  N  N14  1  0.292  0.713  0.659  1.0
  N  N15  1  0.792  0.287  0.841  1.0
  O  O16  1  0.589  0.574  0.177  1.0
  O  O17  1  0.702  0.029  0.876  1.0
  O  O18  1  0.911  0.574  0.677  1.0
  O  O19  1  0.798  0.029  0.376  1.0
  O  O20  1  0.202  0.971  0.624  1.0
  O  O21  1  0.411  0.426  0.823  1.0
  O  O22  1  0.089  0.426  0.323  1.0
  O  O23  1  0.298  0.971  0.124  1.0
  F  F24  1  0.428  0.202  0.007  1.0
  F  F25  1  0.945  0.821  0.806  1.0
  F  F26  1  0.503  0.209  0.164  1.0
  F  F27  1  0.997  0.209  0.664  1.0
  F  F28  1  0.591  0.887  0.644  1.0
  F  F29  1  0.445  0.179  0.694  1.0
  F  F30  1  0.204  0.406  0.078  1.0
  F  F31  1  0.072  0.202  0.507  1.0
  F  F32  1  0.555  0.821  0.306  1.0
  F  F33  1  0.409  0.113  0.356  1.0
  F  F34  1  0.296  0.406  0.578  1.0
  F  F35  1  0.572  0.798  0.993  1.0
  F  F36  1  0.019  0.827  0.964  1.0
  F  F37  1  0.519  0.173  0.536  1.0
  F  F38  1  0.055  0.179  0.194  1.0
  F  F39  1  0.497  0.791  0.836  1.0
  F  F40  1  0.704  0.594  0.422  1.0
  F  F41  1  0.481  0.827  0.464  1.0
  F  F42  1  0.981  0.173  0.036  1.0
  F  F43  1  0.003  0.791  0.336  1.0
  F  F44  1  0.796  0.594  0.922  1.0
  F  F45  1  0.928  0.798  0.493  1.0
  F  F46  1  0.909  0.887  0.144  1.0
  F  F47  1  0.091  0.113  0.856  1.0
[/CIF]
.
The compound described by C2AsN(OF3)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four C2AsN(OF3)2 clusters. There are two inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one O(2), and one F(4) atom. In the second C site, C(2) is bonded in a linear geometry to one N(1) and one O(1) atom. As(1) is bonded in an octahedral geometry to one O(2), one F(1), one F(2), one F(3), one F(5), and one F(6) atom. N(1) is bonded in a bent 120 degrees geometry to one C(1) and one C(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(2) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one C(1) and one As(1) atom. There are six inequivalent F sites. In the first F site, F(6) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(4) is bonded in a single-bond geometry to one C(1) atom. In the sixth F site, F(5) is bonded in a single-bond geometry to one As(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_AsC2N(OF3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.418
_cell_length_b   8.824
_cell_length_c   15.396
_cell_angle_alpha   79.610
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   723.949
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.761  0.793  0.902  1.0
  As  As1  1  0.739  0.793  0.402  1.0
  As  As2  1  0.239  0.207  0.098  1.0
  As  As3  1  0.261  0.207  0.598  1.0
  C  C4  1  0.351  0.863  0.642  1.0
  C  C5  1  0.851  0.137  0.858  1.0
  C  C6  1  0.649  0.137  0.358  1.0
  C  C7  1  0.149  0.863  0.142  1.0
  C  C8  1  0.412  0.650  0.167  1.0
  C  C9  1  0.912  0.350  0.333  1.0
  C  C10  1  0.588  0.350  0.833  1.0
  C  C11  1  0.088  0.650  0.667  1.0
  N  N12  1  0.208  0.713  0.159  1.0
  N  N13  1  0.708  0.287  0.341  1.0
  N  N14  1  0.292  0.713  0.659  1.0
  N  N15  1  0.792  0.287  0.841  1.0
  O  O16  1  0.589  0.574  0.177  1.0
  O  O17  1  0.702  0.029  0.876  1.0
  O  O18  1  0.911  0.574  0.677  1.0
  O  O19  1  0.798  0.029  0.376  1.0
  O  O20  1  0.202  0.971  0.624  1.0
  O  O21  1  0.411  0.426  0.823  1.0
  O  O22  1  0.089  0.426  0.323  1.0
  O  O23  1  0.298  0.971  0.124  1.0
  F  F24  1  0.428  0.202  0.007  1.0
  F  F25  1  0.945  0.821  0.806  1.0
  F  F26  1  0.503  0.209  0.164  1.0
  F  F27  1  0.997  0.209  0.664  1.0
  F  F28  1  0.591  0.887  0.644  1.0
  F  F29  1  0.445  0.179  0.694  1.0
  F  F30  1  0.204  0.406  0.078  1.0
  F  F31  1  0.072  0.202  0.507  1.0
  F  F32  1  0.555  0.821  0.306  1.0
  F  F33  1  0.409  0.113  0.356  1.0
  F  F34  1  0.296  0.406  0.578  1.0
  F  F35  1  0.572  0.798  0.993  1.0
  F  F36  1  0.019  0.827  0.964  1.0
  F  F37  1  0.519  0.173  0.536  1.0
  F  F38  1  0.055  0.179  0.194  1.0
  F  F39  1  0.497  0.791  0.836  1.0
  F  F40  1  0.704  0.594  0.422  1.0
  F  F41  1  0.481  0.827  0.464  1.0
  F  F42  1  0.981  0.173  0.036  1.0
  F  F43  1  0.003  0.791  0.336  1.0
  F  F44  1  0.796  0.594  0.922  1.0
  F  F45  1  0.928  0.798  0.493  1.0
  F  F46  1  0.909  0.887  0.144  1.0
  F  F47  1  0.091  0.113  0.856  1.0
[/CIF]
.