The structure described by LiAu2Cs7Au3O2 crystallizes in the orthorhombic Imm2 space group. The structure consists of two LiAu2 clusters inside a Cs7Au3O2 framework. In each LiAu2 cluster, Li(1) is bonded in a distorted linear geometry to two equivalent Au(1) atoms. Au(1) is bonded in a single-bond geometry to one Li(1) atom. In the Cs7Au3O2 framework, there are three inequivalent Cs sites. In the first Cs site, Cs(1) is bonded in a distorted single-bond geometry to three equivalent Au(2) and one O(1) atom. In the second Cs site, Cs(2) is bonded in a 2-coordinate geometry to two equivalent Au(2) and two equivalent O(1) atoms. In the third Cs site, Cs(3) is bonded in a distorted linear geometry to two equivalent O(1) atoms. There are two inequivalent Au sites. In the first Au site, Au(2) is bonded in a distorted body-centered cubic geometry to two equivalent Cs(2) and six equivalent Cs(1) atoms. In the second Au site, Au(3) is bonded in a linear geometry to two equivalent O(1) atoms. O(1) is bonded to one Cs(3), two equivalent Cs(1), two equivalent Cs(2), and one Au(3) atom to form corner-sharing OCs5Au octahedra. The corner-sharing octahedral tilt angles range from 1-9°. is represented by the Crystallographic Information File (CIF) [CIF]
data_Cs7LiAu5O2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.421
_cell_length_b   10.133
_cell_length_c   10.562
_cell_angle_alpha   118.664
_cell_angle_beta   107.696
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   565.592
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.831  0.616  0.664  1.0
  Cs  Cs1  1  0.497  0.815  0.000  1.0
  Cs  Cs2  1  0.831  0.049  0.664  1.0
  Cs  Cs3  1  0.166  0.384  0.336  1.0
  Cs  Cs4  1  0.166  0.951  0.336  1.0
  Cs  Cs5  1  0.497  0.185  0.000  1.0
  Cs  Cs6  1  0.039  0.500  0.000  1.0
  Li  Li7  1  0.548  0.500  0.000  1.0
  Au  Au8  1  0.644  0.640  0.280  1.0
  Au  Au9  1  0.312  0.811  0.621  1.0
  Au  Au10  1  0.998  0.000  0.000  1.0
  Au  Au11  1  0.364  0.360  0.720  1.0
  Au  Au12  1  0.690  0.189  0.379  1.0
  O  O13  1  0.001  0.797  0.000  1.0
  O  O14  1  0.001  0.203  0.000  1.0
[/CIF]
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The structure described by LiAu2Cs7Au3O2 crystallizes in the orthorhombic Imm2 space group. The structure consists of two LiAu2 clusters inside a Cs7Au3O2 framework. In each LiAu2 cluster, Li(1) is bonded in a distorted linear geometry to two equivalent Au(1) atoms. Au(1) is bonded in a single-bond geometry to one Li(1) atom. In the Cs7Au3O2 framework, there are three inequivalent Cs sites. In the first Cs site, Cs(1) is bonded in a distorted single-bond geometry to three equivalent Au(2) and one O(1) atom. In the second Cs site, Cs(2) is bonded in a 2-coordinate geometry to two equivalent Au(2) and two equivalent O(1) atoms. In the third Cs site, Cs(3) is bonded in a distorted linear geometry to two equivalent O(1) atoms. There are two inequivalent Au sites. In the first Au site, Au(2) is bonded in a distorted body-centered cubic geometry to two equivalent Cs(2) and six equivalent Cs(1) atoms. In the second Au site, Au(3) is bonded in a linear geometry to two equivalent O(1) atoms. O(1) is bonded to one Cs(3), two equivalent Cs(1), two equivalent Cs(2), and one Au(3) atom to form corner-sharing OCs5Au octahedra. The corner-sharing octahedral tilt angles range from 1-9°. is represented by the Crystallographic Information File (CIF) [CIF]
data_Cs7LiAu5O2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.421
_cell_length_b   10.133
_cell_length_c   10.562
_cell_angle_alpha   118.664
_cell_angle_beta   107.696
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   565.592
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.831  0.616  0.664  1.0
  Cs  Cs1  1  0.497  0.815  0.000  1.0
  Cs  Cs2  1  0.831  0.049  0.664  1.0
  Cs  Cs3  1  0.166  0.384  0.336  1.0
  Cs  Cs4  1  0.166  0.951  0.336  1.0
  Cs  Cs5  1  0.497  0.185  0.000  1.0
  Cs  Cs6  1  0.039  0.500  0.000  1.0
  Li  Li7  1  0.548  0.500  0.000  1.0
  Au  Au8  1  0.644  0.640  0.280  1.0
  Au  Au9  1  0.312  0.811  0.621  1.0
  Au  Au10  1  0.998  0.000  0.000  1.0
  Au  Au11  1  0.364  0.360  0.720  1.0
  Au  Au12  1  0.690  0.189  0.379  1.0
  O  O13  1  0.001  0.797  0.000  1.0
  O  O14  1  0.001  0.203  0.000  1.0
[/CIF]
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