The structure described by Os3Bi(CO)9 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two Os3Bi(CO)9 clusters. There are three inequivalent Os sites. In the first Os site, Os(1) is bonded in a 3-coordinate geometry to one C(1), one C(2), one C(3), and one Bi(1) atom. In the second Os site, Os(2) is bonded in a 3-coordinate geometry to one C(4), one C(5), one C(6), and one Bi(1) atom. In the third Os site, Os(3) is bonded in a 3-coordinate geometry to one C(7), one C(8), one C(9), and one Bi(1) atom. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one Os(1) and one O(1) atom. In the second C site, C(2) is bonded in a linear geometry to one Os(1) and one O(2) atom. In the third C site, C(3) is bonded in a distorted linear geometry to one Os(1) and one O(3) atom. In the fourth C site, C(4) is bonded in a linear geometry to one Os(2) and one O(4) atom. In the fifth C site, C(5) is bonded in a linear geometry to one Os(2) and one O(5) atom. In the sixth C site, C(6) is bonded in a distorted linear geometry to one Os(2) and one O(6,8) atom. In the seventh C site, C(7) is bonded in a linear geometry to one Os(3) and one O(7) atom. In the eighth C site, C(8) is bonded in a linear geometry to one Os(3) and one O(6,8) atom. In the ninth C site, C(9) is bonded in a linear geometry to one Os(3) and one O(9) atom. Bi(1) is bonded in a 3-coordinate geometry to one Os(1), one Os(2), and one Os(3) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one C(5) atom. In the sixth O site, O(6,8) is bonded in a single-bond geometry to one C(6) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one C(7) atom. In the eighth O site, O(9) is bonded in a single-bond geometry to one C(9) atom. is represented by the CIF card [CIF]
data_BiOs3(CO)9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.647
_cell_length_b   9.567
_cell_length_c   13.058
_cell_angle_alpha   91.272
_cell_angle_beta   105.286
_cell_angle_gamma   105.004
_symmetry_Int_Tables_number   1
_cell_volume   885.928
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.499  0.207  0.582  1.0
  Bi  Bi1  1  0.501  0.793  0.418  1.0
  Os  Os2  1  0.687  0.247  0.825  1.0
  Os  Os3  1  0.313  0.753  0.175  1.0
  Os  Os4  1  0.533  0.446  0.721  1.0
  Os  Os5  1  0.467  0.554  0.279  1.0
  Os  Os6  1  0.325  0.105  0.741  1.0
  Os  Os7  1  0.675  0.895  0.259  1.0
  C  C8  1  0.900  0.368  0.791  1.0
  C  C9  1  0.100  0.632  0.209  1.0
  C  C10  1  0.818  0.273  0.972  1.0
  C  C11  1  0.182  0.727  0.028  1.0
  C  C12  1  0.715  0.056  0.808  1.0
  C  C13  1  0.285  0.944  0.192  1.0
  C  C14  1  0.699  0.604  0.685  1.0
  C  C15  1  0.301  0.396  0.315  1.0
  C  C16  1  0.331  0.484  0.615  1.0
  C  C17  1  0.669  0.516  0.385  1.0
  C  C18  1  0.514  0.547  0.845  1.0
  C  C19  1  0.486  0.453  0.155  1.0
  C  C20  1  0.094  0.112  0.645  1.0
  C  C21  1  0.906  0.888  0.355  1.0
  C  C22  1  0.262  0.102  0.873  1.0
  C  C23  1  0.738  0.898  0.127  1.0
  C  C24  1  0.265  0.902  0.712  1.0
  C  C25  1  0.735  0.098  0.288  1.0
  O  O26  1  0.031  0.428  0.764  1.0
  O  O27  1  0.969  0.572  0.236  1.0
  O  O28  1  0.900  0.289  0.062  1.0
  O  O29  1  0.100  0.711  0.938  1.0
  O  O30  1  0.742  0.945  0.790  1.0
  O  O31  1  0.258  0.055  0.210  1.0
  O  O32  1  0.809  0.699  0.663  1.0
  O  O33  1  0.191  0.301  0.337  1.0
  O  O34  1  0.209  0.509  0.550  1.0
  O  O35  1  0.791  0.491  0.450  1.0
  O  O36  1  0.494  0.616  0.913  1.0
  O  O37  1  0.506  0.384  0.087  1.0
  O  O38  1  0.952  0.119  0.587  1.0
  O  O39  1  0.048  0.881  0.413  1.0
  O  O40  1  0.204  0.094  0.948  1.0
  O  O41  1  0.796  0.906  0.052  1.0
  O  O42  1  0.244  0.778  0.697  1.0
  O  O43  1  0.756  0.222  0.303  1.0
[/CIF]
.
The structure described by Os3Bi(CO)9 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two Os3Bi(CO)9 clusters. There are three inequivalent Os sites. In the first Os site, Os(1) is bonded in a 3-coordinate geometry to one C(1), one C(2), one C(3), and one Bi(1) atom. In the second Os site, Os(2) is bonded in a 3-coordinate geometry to one C(4), one C(5), one C(6), and one Bi(1) atom. In the third Os site, Os(3) is bonded in a 3-coordinate geometry to one C(7), one C(8), one C(9), and one Bi(1) atom. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one Os(1) and one O(1) atom. In the second C site, C(2) is bonded in a linear geometry to one Os(1) and one O(2) atom. In the third C site, C(3) is bonded in a distorted linear geometry to one Os(1) and one O(3) atom. In the fourth C site, C(4) is bonded in a linear geometry to one Os(2) and one O(4) atom. In the fifth C site, C(5) is bonded in a linear geometry to one Os(2) and one O(5) atom. In the sixth C site, C(6) is bonded in a distorted linear geometry to one Os(2) and one O(6,8) atom. In the seventh C site, C(7) is bonded in a linear geometry to one Os(3) and one O(7) atom. In the eighth C site, C(8) is bonded in a linear geometry to one Os(3) and one O(6,8) atom. In the ninth C site, C(9) is bonded in a linear geometry to one Os(3) and one O(9) atom. Bi(1) is bonded in a 3-coordinate geometry to one Os(1), one Os(2), and one Os(3) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one C(5) atom. In the sixth O site, O(6,8) is bonded in a single-bond geometry to one C(6) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one C(7) atom. In the eighth O site, O(9) is bonded in a single-bond geometry to one C(9) atom. is represented by the CIF card [CIF]
data_BiOs3(CO)9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.647
_cell_length_b   9.567
_cell_length_c   13.058
_cell_angle_alpha   91.272
_cell_angle_beta   105.286
_cell_angle_gamma   105.004
_symmetry_Int_Tables_number   1
_cell_volume   885.928
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.499  0.207  0.582  1.0
  Bi  Bi1  1  0.501  0.793  0.418  1.0
  Os  Os2  1  0.687  0.247  0.825  1.0
  Os  Os3  1  0.313  0.753  0.175  1.0
  Os  Os4  1  0.533  0.446  0.721  1.0
  Os  Os5  1  0.467  0.554  0.279  1.0
  Os  Os6  1  0.325  0.105  0.741  1.0
  Os  Os7  1  0.675  0.895  0.259  1.0
  C  C8  1  0.900  0.368  0.791  1.0
  C  C9  1  0.100  0.632  0.209  1.0
  C  C10  1  0.818  0.273  0.972  1.0
  C  C11  1  0.182  0.727  0.028  1.0
  C  C12  1  0.715  0.056  0.808  1.0
  C  C13  1  0.285  0.944  0.192  1.0
  C  C14  1  0.699  0.604  0.685  1.0
  C  C15  1  0.301  0.396  0.315  1.0
  C  C16  1  0.331  0.484  0.615  1.0
  C  C17  1  0.669  0.516  0.385  1.0
  C  C18  1  0.514  0.547  0.845  1.0
  C  C19  1  0.486  0.453  0.155  1.0
  C  C20  1  0.094  0.112  0.645  1.0
  C  C21  1  0.906  0.888  0.355  1.0
  C  C22  1  0.262  0.102  0.873  1.0
  C  C23  1  0.738  0.898  0.127  1.0
  C  C24  1  0.265  0.902  0.712  1.0
  C  C25  1  0.735  0.098  0.288  1.0
  O  O26  1  0.031  0.428  0.764  1.0
  O  O27  1  0.969  0.572  0.236  1.0
  O  O28  1  0.900  0.289  0.062  1.0
  O  O29  1  0.100  0.711  0.938  1.0
  O  O30  1  0.742  0.945  0.790  1.0
  O  O31  1  0.258  0.055  0.210  1.0
  O  O32  1  0.809  0.699  0.663  1.0
  O  O33  1  0.191  0.301  0.337  1.0
  O  O34  1  0.209  0.509  0.550  1.0
  O  O35  1  0.791  0.491  0.450  1.0
  O  O36  1  0.494  0.616  0.913  1.0
  O  O37  1  0.506  0.384  0.087  1.0
  O  O38  1  0.952  0.119  0.587  1.0
  O  O39  1  0.048  0.881  0.413  1.0
  O  O40  1  0.204  0.094  0.948  1.0
  O  O41  1  0.796  0.906  0.052  1.0
  O  O42  1  0.244  0.778  0.697  1.0
  O  O43  1  0.756  0.222  0.303  1.0
[/CIF]
.