The compound described by TmPdIn2 crystallizes in the tetragonal I4mm space group. There are four inequivalent Tm sites. In the first Tm site, Tm(1) is bonded in a 12-coordinate geometry to four equivalent Pd(3), four equivalent In(2), and four equivalent In(3) atoms. In the second Tm site, Tm(2) is bonded in a 13-coordinate geometry to one Pd(1), one Pd(2), two equivalent Pd(3), one In(2), two equivalent In(3), two equivalent In(4), and four equivalent In(1) atoms. In the third Tm site, Tm(3) is bonded in a 10-coordinate geometry to two equivalent Pd(2), two equivalent Pd(3), two equivalent In(2), two equivalent In(3), and four equivalent In(1) atoms. In the fourth Tm site, Tm(4) is bonded in a 12-coordinate geometry to four equivalent Pd(2), four equivalent In(2), and four equivalent In(3) atoms. There are three inequivalent Pd sites. In the first Pd site, Pd(3) is bonded in a 10-coordinate geometry to one Tm(1), two equivalent Tm(2), two equivalent Tm(3), one In(3), two equivalent In(1), and two equivalent In(2) atoms. In the second Pd site, Pd(1) is bonded in a 8-coordinate geometry to two equivalent Tm(2), four equivalent In(1), and four equivalent In(4) atoms. In the third Pd site, Pd(2) is bonded in a 9-coordinate geometry to one Tm(2), one Tm(4), two equivalent Tm(3), one In(2), one In(4), two equivalent In(1), and two equivalent In(3) atoms. There are four inequivalent In sites. In the first In site, In(3) is bonded in a 11-coordinate geometry to one Tm(1), one Tm(4), two equivalent Tm(2), two equivalent Tm(3), one Pd(3), two equivalent Pd(2), and two equivalent In(1) atoms. In the second In site, In(4) is bonded in a 3-coordinate geometry to two equivalent Tm(2), one Pd(2), and two equivalent Pd(1) atoms. In the third In site, In(1) is bonded in a 7-coordinate geometry to two equivalent Tm(2), two equivalent Tm(3), one Pd(1), one Pd(2), one Pd(3), and one In(3) atom. In the fourth In site, In(2) is bonded in a 3-coordinate geometry to one Tm(1), one Tm(2), one Tm(4), two equivalent Tm(3), one Pd(2), and two equivalent Pd(3) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_TmIn2Pd
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.681
_cell_length_b   10.681
_cell_length_c   10.683
_cell_angle_alpha   100.494
_cell_angle_beta   100.494
_cell_angle_gamma   129.480
_symmetry_Int_Tables_number   1
_cell_volume   850.783
_cell_formula_units_Z   10
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tm  Tm0  1  0.475  0.475  0.000  1.0
  Tm  Tm1  1  0.682  0.403  0.279  1.0
  Tm  Tm2  1  0.124  0.403  0.721  1.0
  Tm  Tm3  1  0.403  0.682  0.279  1.0
  Tm  Tm4  1  0.403  0.124  0.721  1.0
  Tm  Tm5  1  0.687  0.687  0.596  1.0
  Tm  Tm6  1  0.091  0.091  0.404  1.0
  Tm  Tm7  1  0.091  0.687  0.000  1.0
  Tm  Tm8  1  0.687  0.091  0.000  1.0
  Tm  Tm9  1  0.001  0.001  0.000  1.0
  In  In10  1  0.282  0.489  0.492  1.0
  In  In11  1  0.997  0.790  0.508  1.0
  In  In12  1  0.790  0.282  0.793  1.0
  In  In13  1  0.282  0.790  0.793  1.0
  In  In14  1  0.489  0.997  0.208  1.0
  In  In15  1  0.997  0.489  0.208  1.0
  In  In16  1  0.790  0.997  0.508  1.0
  In  In17  1  0.489  0.282  0.492  1.0
  In  In18  1  0.893  0.730  0.163  1.0
  In  In19  1  0.568  0.730  0.837  1.0
  In  In20  1  0.730  0.893  0.163  1.0
  In  In21  1  0.730  0.568  0.837  1.0
  In  In22  1  0.367  0.367  0.260  1.0
  In  In23  1  0.107  0.107  0.740  1.0
  In  In24  1  0.107  0.367  0.000  1.0
  In  In25  1  0.367  0.107  0.000  1.0
  In  In26  1  0.261  0.878  0.383  1.0
  In  In27  1  0.495  0.878  0.617  1.0
  In  In28  1  0.878  0.261  0.383  1.0
  In  In29  1  0.878  0.495  0.617  1.0
  Pd  Pd30  1  0.128  0.628  0.500  1.0
  Pd  Pd31  1  0.628  0.128  0.500  1.0
  Pd  Pd32  1  0.250  0.037  0.213  1.0
  Pd  Pd33  1  0.824  0.037  0.787  1.0
  Pd  Pd34  1  0.037  0.250  0.213  1.0
  Pd  Pd35  1  0.037  0.824  0.787  1.0
  Pd  Pd36  1  0.383  0.383  0.678  1.0
  Pd  Pd37  1  0.705  0.705  0.323  1.0
  Pd  Pd38  1  0.705  0.383  1.000  1.0
  Pd  Pd39  1  0.383  0.705  1.000  1.0
[/CIF]
.
The compound described by TmPdIn2 crystallizes in the tetragonal I4mm space group. There are four inequivalent Tm sites. In the first Tm site, Tm(1) is bonded in a 12-coordinate geometry to four equivalent Pd(3), four equivalent In(2), and four equivalent In(3) atoms. In the second Tm site, Tm(2) is bonded in a 13-coordinate geometry to one Pd(1), one Pd(2), two equivalent Pd(3), one In(2), two equivalent In(3), two equivalent In(4), and four equivalent In(1) atoms. In the third Tm site, Tm(3) is bonded in a 10-coordinate geometry to two equivalent Pd(2), two equivalent Pd(3), two equivalent In(2), two equivalent In(3), and four equivalent In(1) atoms. In the fourth Tm site, Tm(4) is bonded in a 12-coordinate geometry to four equivalent Pd(2), four equivalent In(2), and four equivalent In(3) atoms. There are three inequivalent Pd sites. In the first Pd site, Pd(3) is bonded in a 10-coordinate geometry to one Tm(1), two equivalent Tm(2), two equivalent Tm(3), one In(3), two equivalent In(1), and two equivalent In(2) atoms. In the second Pd site, Pd(1) is bonded in a 8-coordinate geometry to two equivalent Tm(2), four equivalent In(1), and four equivalent In(4) atoms. In the third Pd site, Pd(2) is bonded in a 9-coordinate geometry to one Tm(2), one Tm(4), two equivalent Tm(3), one In(2), one In(4), two equivalent In(1), and two equivalent In(3) atoms. There are four inequivalent In sites. In the first In site, In(3) is bonded in a 11-coordinate geometry to one Tm(1), one Tm(4), two equivalent Tm(2), two equivalent Tm(3), one Pd(3), two equivalent Pd(2), and two equivalent In(1) atoms. In the second In site, In(4) is bonded in a 3-coordinate geometry to two equivalent Tm(2), one Pd(2), and two equivalent Pd(1) atoms. In the third In site, In(1) is bonded in a 7-coordinate geometry to two equivalent Tm(2), two equivalent Tm(3), one Pd(1), one Pd(2), one Pd(3), and one In(3) atom. In the fourth In site, In(2) is bonded in a 3-coordinate geometry to one Tm(1), one Tm(2), one Tm(4), two equivalent Tm(3), one Pd(2), and two equivalent Pd(3) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_TmIn2Pd
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.681
_cell_length_b   10.681
_cell_length_c   10.683
_cell_angle_alpha   100.494
_cell_angle_beta   100.494
_cell_angle_gamma   129.480
_symmetry_Int_Tables_number   1
_cell_volume   850.783
_cell_formula_units_Z   10
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tm  Tm0  1  0.475  0.475  0.000  1.0
  Tm  Tm1  1  0.682  0.403  0.279  1.0
  Tm  Tm2  1  0.124  0.403  0.721  1.0
  Tm  Tm3  1  0.403  0.682  0.279  1.0
  Tm  Tm4  1  0.403  0.124  0.721  1.0
  Tm  Tm5  1  0.687  0.687  0.596  1.0
  Tm  Tm6  1  0.091  0.091  0.404  1.0
  Tm  Tm7  1  0.091  0.687  0.000  1.0
  Tm  Tm8  1  0.687  0.091  0.000  1.0
  Tm  Tm9  1  0.001  0.001  0.000  1.0
  In  In10  1  0.282  0.489  0.492  1.0
  In  In11  1  0.997  0.790  0.508  1.0
  In  In12  1  0.790  0.282  0.793  1.0
  In  In13  1  0.282  0.790  0.793  1.0
  In  In14  1  0.489  0.997  0.208  1.0
  In  In15  1  0.997  0.489  0.208  1.0
  In  In16  1  0.790  0.997  0.508  1.0
  In  In17  1  0.489  0.282  0.492  1.0
  In  In18  1  0.893  0.730  0.163  1.0
  In  In19  1  0.568  0.730  0.837  1.0
  In  In20  1  0.730  0.893  0.163  1.0
  In  In21  1  0.730  0.568  0.837  1.0
  In  In22  1  0.367  0.367  0.260  1.0
  In  In23  1  0.107  0.107  0.740  1.0
  In  In24  1  0.107  0.367  0.000  1.0
  In  In25  1  0.367  0.107  0.000  1.0
  In  In26  1  0.261  0.878  0.383  1.0
  In  In27  1  0.495  0.878  0.617  1.0
  In  In28  1  0.878  0.261  0.383  1.0
  In  In29  1  0.878  0.495  0.617  1.0
  Pd  Pd30  1  0.128  0.628  0.500  1.0
  Pd  Pd31  1  0.628  0.128  0.500  1.0
  Pd  Pd32  1  0.250  0.037  0.213  1.0
  Pd  Pd33  1  0.824  0.037  0.787  1.0
  Pd  Pd34  1  0.037  0.250  0.213  1.0
  Pd  Pd35  1  0.037  0.824  0.787  1.0
  Pd  Pd36  1  0.383  0.383  0.678  1.0
  Pd  Pd37  1  0.705  0.705  0.323  1.0
  Pd  Pd38  1  0.705  0.383  1.000  1.0
  Pd  Pd39  1  0.383  0.705  1.000  1.0
[/CIF]
.