The material described by Rb2BaPt2(CN)8 crystallizes in the tetragonal P4/mmm space group. Rb(1) is bonded in a 16-coordinate geometry to eight equivalent C(1) and eight equivalent N(1) atoms. Ba(1) is bonded in a body-centered cubic geometry to eight equivalent N(1) atoms. Pt(1) is bonded in a rectangular see-saw-like geometry to four equivalent C(1) atoms. C(1) is bonded in a distorted linear geometry to two equivalent Rb(1), one Pt(1), and one N(1) atom. N(1) is bonded in a distorted single-bond geometry to two equivalent Rb(1), one Ba(1), and one C(1) atom. is represented by the CIF file [CIF]
data_Rb2BaPt2(CN)8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.863
_cell_length_b   7.863
_cell_length_c   7.028
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   434.543
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.500  0.000  0.500  1.0
  Rb  Rb1  1  0.000  0.500  0.500  1.0
  Ba  Ba2  1  0.500  0.500  0.000  1.0
  Pt  Pt3  1  0.000  0.000  0.757  1.0
  Pt  Pt4  1  0.000  0.000  0.243  1.0
  C  C5  1  0.179  0.179  0.760  1.0
  C  C6  1  0.821  0.821  0.240  1.0
  C  C7  1  0.821  0.179  0.760  1.0
  C  C8  1  0.179  0.821  0.760  1.0
  C  C9  1  0.179  0.179  0.240  1.0
  C  C10  1  0.821  0.821  0.760  1.0
  C  C11  1  0.821  0.179  0.240  1.0
  C  C12  1  0.179  0.821  0.240  1.0
  N  N13  1  0.285  0.715  0.763  1.0
  N  N14  1  0.285  0.285  0.237  1.0
  N  N15  1  0.285  0.285  0.763  1.0
  N  N16  1  0.715  0.715  0.237  1.0
  N  N17  1  0.715  0.285  0.763  1.0
  N  N18  1  0.715  0.715  0.763  1.0
  N  N19  1  0.285  0.715  0.237  1.0
  N  N20  1  0.715  0.285  0.237  1.0
[/CIF]
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The material described by Rb2BaPt2(CN)8 crystallizes in the tetragonal P4/mmm space group. Rb(1) is bonded in a 16-coordinate geometry to eight equivalent C(1) and eight equivalent N(1) atoms. Ba(1) is bonded in a body-centered cubic geometry to eight equivalent N(1) atoms. Pt(1) is bonded in a rectangular see-saw-like geometry to four equivalent C(1) atoms. C(1) is bonded in a distorted linear geometry to two equivalent Rb(1), one Pt(1), and one N(1) atom. N(1) is bonded in a distorted single-bond geometry to two equivalent Rb(1), one Ba(1), and one C(1) atom. is represented by the CIF file [CIF]
data_Rb2BaPt2(CN)8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.863
_cell_length_b   7.863
_cell_length_c   7.028
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   434.543
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.500  0.000  0.500  1.0
  Rb  Rb1  1  0.000  0.500  0.500  1.0
  Ba  Ba2  1  0.500  0.500  0.000  1.0
  Pt  Pt3  1  0.000  0.000  0.757  1.0
  Pt  Pt4  1  0.000  0.000  0.243  1.0
  C  C5  1  0.179  0.179  0.760  1.0
  C  C6  1  0.821  0.821  0.240  1.0
  C  C7  1  0.821  0.179  0.760  1.0
  C  C8  1  0.179  0.821  0.760  1.0
  C  C9  1  0.179  0.179  0.240  1.0
  C  C10  1  0.821  0.821  0.760  1.0
  C  C11  1  0.821  0.179  0.240  1.0
  C  C12  1  0.179  0.821  0.240  1.0
  N  N13  1  0.285  0.715  0.763  1.0
  N  N14  1  0.285  0.285  0.237  1.0
  N  N15  1  0.285  0.285  0.763  1.0
  N  N16  1  0.715  0.715  0.237  1.0
  N  N17  1  0.715  0.285  0.763  1.0
  N  N18  1  0.715  0.715  0.763  1.0
  N  N19  1  0.285  0.715  0.237  1.0
  N  N20  1  0.715  0.285  0.237  1.0
[/CIF]
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