The compound described by ZnPbO3 is Ilmenite-like structured and crystallizes in the trigonal R3c space group. Zn(1) is bonded to six equivalent O(1) atoms to form distorted ZnO6 octahedra that share corners with three equivalent Pb(1)O6 octahedra, corners with six equivalent Zn(1)O6 octahedra, edges with three equivalent Pb(1)O6 octahedra, and  a faceface with one Pb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-63°. Pb(1) is bonded to six equivalent O(1) atoms to form distorted PbO6 octahedra that share corners with three equivalent Zn(1)O6 octahedra, corners with six equivalent Pb(1)O6 octahedra, edges with three equivalent Zn(1)O6 octahedra, and  a faceface with one Zn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-63°. O(1) is bonded to two equivalent Zn(1) and two equivalent Pb(1) atoms to form a mixture of distorted edge and corner-sharing OZn2Pb2 trigonal pyramids. is represented by the CIF file [CIF]
data_ZnPbO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.517
_cell_length_b   5.517
_cell_length_c   5.822
_cell_angle_alpha   61.721
_cell_angle_beta   61.721
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   128.458
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.500  0.500  0.500  1.0
  Zn  Zn1  1  0.000  0.000  1.000  1.0
  Pb  Pb2  1  0.782  0.782  0.653  1.0
  Pb  Pb3  1  0.282  0.282  0.153  1.0
  O  O4  1  0.874  0.597  0.333  1.0
  O  O5  1  0.597  0.196  0.333  1.0
  O  O6  1  0.196  0.874  0.333  1.0
  O  O7  1  0.374  0.696  0.833  1.0
  O  O8  1  0.696  0.097  0.833  1.0
  O  O9  1  0.097  0.374  0.833  1.0
[/CIF]
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The compound described by ZnPbO3 is Ilmenite-like structured and crystallizes in the trigonal R3c space group. Zn(1) is bonded to six equivalent O(1) atoms to form distorted ZnO6 octahedra that share corners with three equivalent Pb(1)O6 octahedra, corners with six equivalent Zn(1)O6 octahedra, edges with three equivalent Pb(1)O6 octahedra, and  a faceface with one Pb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-63°. Pb(1) is bonded to six equivalent O(1) atoms to form distorted PbO6 octahedra that share corners with three equivalent Zn(1)O6 octahedra, corners with six equivalent Pb(1)O6 octahedra, edges with three equivalent Zn(1)O6 octahedra, and  a faceface with one Zn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-63°. O(1) is bonded to two equivalent Zn(1) and two equivalent Pb(1) atoms to form a mixture of distorted edge and corner-sharing OZn2Pb2 trigonal pyramids. is represented by the CIF file [CIF]
data_ZnPbO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.517
_cell_length_b   5.517
_cell_length_c   5.822
_cell_angle_alpha   61.721
_cell_angle_beta   61.721
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   128.458
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.500  0.500  0.500  1.0
  Zn  Zn1  1  0.000  0.000  1.000  1.0
  Pb  Pb2  1  0.782  0.782  0.653  1.0
  Pb  Pb3  1  0.282  0.282  0.153  1.0
  O  O4  1  0.874  0.597  0.333  1.0
  O  O5  1  0.597  0.196  0.333  1.0
  O  O6  1  0.196  0.874  0.333  1.0
  O  O7  1  0.374  0.696  0.833  1.0
  O  O8  1  0.696  0.097  0.833  1.0
  O  O9  1  0.097  0.374  0.833  1.0
[/CIF]
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