The crystal structure described by CsPH4(NO)2 crystallizes in the tetragonal P4_32_12 space group. Cs(1) is bonded in a 14-coordinate geometry to four equivalent H(1), four equivalent H(2), and six equivalent O(1) atoms. P(1) is bonded in a tetrahedral geometry to two equivalent N(1) and two equivalent O(1) atoms. N(1) is bonded in a trigonal non-coplanar geometry to one P(1), one H(1), and one H(2) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to two equivalent Cs(1) and one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to two equivalent Cs(1) and one N(1) atom. O(1) is bonded in a single-bond geometry to three equivalent Cs(1) and one P(1) atom. is represented by the CIF card [CIF]
data_CsPH4(NO)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.656
_cell_length_b   5.656
_cell_length_c   15.722
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   503.005
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.150  0.850  0.250  1.0
  Cs  Cs1  1  0.350  0.350  0.500  1.0
  Cs  Cs2  1  0.650  0.650  0.000  1.0
  Cs  Cs3  1  0.850  0.150  0.750  1.0
  P  P4  1  0.111  0.111  0.000  1.0
  P  P5  1  0.389  0.611  0.750  1.0
  P  P6  1  0.611  0.389  0.250  1.0
  P  P7  1  0.889  0.889  0.500  1.0
  H  H8  1  0.991  0.367  0.311  1.0
  H  H9  1  0.133  0.491  0.061  1.0
  H  H10  1  0.213  0.791  0.864  1.0
  H  H11  1  0.209  0.787  0.636  1.0
  H  H12  1  0.291  0.287  0.114  1.0
  H  H13  1  0.287  0.291  0.886  1.0
  H  H14  1  0.367  0.991  0.689  1.0
  H  H15  1  0.509  0.867  0.439  1.0
  H  H16  1  0.491  0.133  0.939  1.0
  H  H17  1  0.633  0.009  0.189  1.0
  H  H18  1  0.713  0.709  0.386  1.0
  H  H19  1  0.709  0.713  0.614  1.0
  H  H20  1  0.791  0.213  0.136  1.0
  H  H21  1  0.787  0.209  0.364  1.0
  H  H22  1  0.867  0.509  0.561  1.0
  H  H23  1  0.009  0.633  0.811  1.0
  N  N24  1  0.142  0.316  0.078  1.0
  N  N25  1  0.184  0.642  0.828  1.0
  N  N26  1  0.316  0.142  0.922  1.0
  N  N27  1  0.358  0.816  0.672  1.0
  N  N28  1  0.642  0.184  0.172  1.0
  N  N29  1  0.684  0.858  0.422  1.0
  N  N30  1  0.816  0.358  0.328  1.0
  N  N31  1  0.858  0.684  0.578  1.0
  O  O32  1  0.125  0.845  0.457  1.0
  O  O33  1  0.155  0.875  0.043  1.0
  O  O34  1  0.345  0.375  0.707  1.0
  O  O35  1  0.375  0.345  0.293  1.0
  O  O36  1  0.625  0.655  0.793  1.0
  O  O37  1  0.655  0.625  0.207  1.0
  O  O38  1  0.845  0.125  0.543  1.0
  O  O39  1  0.875  0.155  0.957  1.0
[/CIF]
.
The crystal structure described by CsPH4(NO)2 crystallizes in the tetragonal P4_32_12 space group. Cs(1) is bonded in a 14-coordinate geometry to four equivalent H(1), four equivalent H(2), and six equivalent O(1) atoms. P(1) is bonded in a tetrahedral geometry to two equivalent N(1) and two equivalent O(1) atoms. N(1) is bonded in a trigonal non-coplanar geometry to one P(1), one H(1), and one H(2) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to two equivalent Cs(1) and one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to two equivalent Cs(1) and one N(1) atom. O(1) is bonded in a single-bond geometry to three equivalent Cs(1) and one P(1) atom. is represented by the CIF card [CIF]
data_CsPH4(NO)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.656
_cell_length_b   5.656
_cell_length_c   15.722
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   503.005
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.150  0.850  0.250  1.0
  Cs  Cs1  1  0.350  0.350  0.500  1.0
  Cs  Cs2  1  0.650  0.650  0.000  1.0
  Cs  Cs3  1  0.850  0.150  0.750  1.0
  P  P4  1  0.111  0.111  0.000  1.0
  P  P5  1  0.389  0.611  0.750  1.0
  P  P6  1  0.611  0.389  0.250  1.0
  P  P7  1  0.889  0.889  0.500  1.0
  H  H8  1  0.991  0.367  0.311  1.0
  H  H9  1  0.133  0.491  0.061  1.0
  H  H10  1  0.213  0.791  0.864  1.0
  H  H11  1  0.209  0.787  0.636  1.0
  H  H12  1  0.291  0.287  0.114  1.0
  H  H13  1  0.287  0.291  0.886  1.0
  H  H14  1  0.367  0.991  0.689  1.0
  H  H15  1  0.509  0.867  0.439  1.0
  H  H16  1  0.491  0.133  0.939  1.0
  H  H17  1  0.633  0.009  0.189  1.0
  H  H18  1  0.713  0.709  0.386  1.0
  H  H19  1  0.709  0.713  0.614  1.0
  H  H20  1  0.791  0.213  0.136  1.0
  H  H21  1  0.787  0.209  0.364  1.0
  H  H22  1  0.867  0.509  0.561  1.0
  H  H23  1  0.009  0.633  0.811  1.0
  N  N24  1  0.142  0.316  0.078  1.0
  N  N25  1  0.184  0.642  0.828  1.0
  N  N26  1  0.316  0.142  0.922  1.0
  N  N27  1  0.358  0.816  0.672  1.0
  N  N28  1  0.642  0.184  0.172  1.0
  N  N29  1  0.684  0.858  0.422  1.0
  N  N30  1  0.816  0.358  0.328  1.0
  N  N31  1  0.858  0.684  0.578  1.0
  O  O32  1  0.125  0.845  0.457  1.0
  O  O33  1  0.155  0.875  0.043  1.0
  O  O34  1  0.345  0.375  0.707  1.0
  O  O35  1  0.375  0.345  0.293  1.0
  O  O36  1  0.625  0.655  0.793  1.0
  O  O37  1  0.655  0.625  0.207  1.0
  O  O38  1  0.845  0.125  0.543  1.0
  O  O39  1  0.875  0.155  0.957  1.0
[/CIF]
.