The compound described by CeLaCo10 crystallizes in the orthorhombic Pmmm space group. Ce(1) is bonded in a distorted hexagonal planar geometry to two equivalent Co(1), four equivalent Co(2), four equivalent Co(3), and eight equivalent Co(5) atoms. La(1) is bonded in a 18-coordinate geometry to two equivalent Co(2), four equivalent Co(1), four equivalent Co(4), and eight equivalent Co(5) atoms. There are five inequivalent Co sites. In the first Co site, Co(1) is bonded in a 9-coordinate geometry to one Ce(1), two equivalent La(1), two equivalent Co(2), two equivalent Co(4), and four equivalent Co(5) atoms. In the second Co site, Co(2) is bonded in a 12-coordinate geometry to two equivalent Ce(1), one La(1), one Co(2), two equivalent Co(1), two equivalent Co(3), and four equivalent Co(5) atoms. In the third Co site, Co(3) is bonded to four equivalent Ce(1), four equivalent Co(2), and four equivalent Co(5) atoms to form CoCe4Co8 cuboctahedra that share corners with four equivalent Co(3)Ce4Co8 cuboctahedra, corners with four equivalent Co(4)La4Co8 cuboctahedra, corners with eight equivalent Co(5)La2Ce2Co8 cuboctahedra, edges with two equivalent Co(3)Ce4Co8 cuboctahedra, edges with eight equivalent Co(5)La2Ce2Co8 cuboctahedra, faces with two equivalent Co(3)Ce4Co8 cuboctahedra, and faces with eight equivalent Co(5)La2Ce2Co8 cuboctahedra. In the fourth Co site, Co(4) is bonded to four equivalent La(1), four equivalent Co(1), and four equivalent Co(5) atoms to form CoLa4Co8 cuboctahedra that share corners with four equivalent Co(3)Ce4Co8 cuboctahedra, corners with four equivalent Co(4)La4Co8 cuboctahedra, corners with eight equivalent Co(5)La2Ce2Co8 cuboctahedra, edges with two equivalent Co(4)La4Co8 cuboctahedra, edges with eight equivalent Co(5)La2Ce2Co8 cuboctahedra, faces with two equivalent Co(4)La4Co8 cuboctahedra, and faces with eight equivalent Co(5)La2Ce2Co8 cuboctahedra. In the fifth Co site, Co(5) is bonded to two equivalent Ce(1), two equivalent La(1), one Co(3), one Co(4), two equivalent Co(1), two equivalent Co(2), and two equivalent Co(5) atoms to form CoLa2Ce2Co8 cuboctahedra that share corners with two equivalent Co(3)Ce4Co8 cuboctahedra, corners with two equivalent Co(4)La4Co8 cuboctahedra, corners with twelve equivalent Co(5)La2Ce2Co8 cuboctahedra, edges with two equivalent Co(3)Ce4Co8 cuboctahedra, edges with two equivalent Co(4)La4Co8 cuboctahedra, edges with six equivalent Co(5)La2Ce2Co8 cuboctahedra, faces with two equivalent Co(3)Ce4Co8 cuboctahedra, faces with two equivalent Co(4)La4Co8 cuboctahedra, and faces with six equivalent Co(5)La2Ce2Co8 cuboctahedra. is represented by the CIF card [CIF]
data_LaCeCo10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.002
_cell_length_b   4.927
_cell_length_c   8.551
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   168.626
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.000  0.000  0.500  1.0
  Ce  Ce1  1  0.000  0.500  0.000  1.0
  Co  Co2  1  0.000  0.500  0.320  1.0
  Co  Co3  1  0.000  0.000  0.844  1.0
  Co  Co4  1  0.000  0.000  0.156  1.0
  Co  Co5  1  0.000  0.500  0.680  1.0
  Co  Co6  1  0.500  0.000  0.000  1.0
  Co  Co7  1  0.500  0.500  0.500  1.0
  Co  Co8  1  0.500  0.750  0.247  1.0
  Co  Co9  1  0.500  0.250  0.753  1.0
  Co  Co10  1  0.500  0.250  0.247  1.0
  Co  Co11  1  0.500  0.750  0.753  1.0
[/CIF]
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The compound described by CeLaCo10 crystallizes in the orthorhombic Pmmm space group. Ce(1) is bonded in a distorted hexagonal planar geometry to two equivalent Co(1), four equivalent Co(2), four equivalent Co(3), and eight equivalent Co(5) atoms. La(1) is bonded in a 18-coordinate geometry to two equivalent Co(2), four equivalent Co(1), four equivalent Co(4), and eight equivalent Co(5) atoms. There are five inequivalent Co sites. In the first Co site, Co(1) is bonded in a 9-coordinate geometry to one Ce(1), two equivalent La(1), two equivalent Co(2), two equivalent Co(4), and four equivalent Co(5) atoms. In the second Co site, Co(2) is bonded in a 12-coordinate geometry to two equivalent Ce(1), one La(1), one Co(2), two equivalent Co(1), two equivalent Co(3), and four equivalent Co(5) atoms. In the third Co site, Co(3) is bonded to four equivalent Ce(1), four equivalent Co(2), and four equivalent Co(5) atoms to form CoCe4Co8 cuboctahedra that share corners with four equivalent Co(3)Ce4Co8 cuboctahedra, corners with four equivalent Co(4)La4Co8 cuboctahedra, corners with eight equivalent Co(5)La2Ce2Co8 cuboctahedra, edges with two equivalent Co(3)Ce4Co8 cuboctahedra, edges with eight equivalent Co(5)La2Ce2Co8 cuboctahedra, faces with two equivalent Co(3)Ce4Co8 cuboctahedra, and faces with eight equivalent Co(5)La2Ce2Co8 cuboctahedra. In the fourth Co site, Co(4) is bonded to four equivalent La(1), four equivalent Co(1), and four equivalent Co(5) atoms to form CoLa4Co8 cuboctahedra that share corners with four equivalent Co(3)Ce4Co8 cuboctahedra, corners with four equivalent Co(4)La4Co8 cuboctahedra, corners with eight equivalent Co(5)La2Ce2Co8 cuboctahedra, edges with two equivalent Co(4)La4Co8 cuboctahedra, edges with eight equivalent Co(5)La2Ce2Co8 cuboctahedra, faces with two equivalent Co(4)La4Co8 cuboctahedra, and faces with eight equivalent Co(5)La2Ce2Co8 cuboctahedra. In the fifth Co site, Co(5) is bonded to two equivalent Ce(1), two equivalent La(1), one Co(3), one Co(4), two equivalent Co(1), two equivalent Co(2), and two equivalent Co(5) atoms to form CoLa2Ce2Co8 cuboctahedra that share corners with two equivalent Co(3)Ce4Co8 cuboctahedra, corners with two equivalent Co(4)La4Co8 cuboctahedra, corners with twelve equivalent Co(5)La2Ce2Co8 cuboctahedra, edges with two equivalent Co(3)Ce4Co8 cuboctahedra, edges with two equivalent Co(4)La4Co8 cuboctahedra, edges with six equivalent Co(5)La2Ce2Co8 cuboctahedra, faces with two equivalent Co(3)Ce4Co8 cuboctahedra, faces with two equivalent Co(4)La4Co8 cuboctahedra, and faces with six equivalent Co(5)La2Ce2Co8 cuboctahedra. is represented by the CIF card [CIF]
data_LaCeCo10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.002
_cell_length_b   4.927
_cell_length_c   8.551
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   168.626
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.000  0.000  0.500  1.0
  Ce  Ce1  1  0.000  0.500  0.000  1.0
  Co  Co2  1  0.000  0.500  0.320  1.0
  Co  Co3  1  0.000  0.000  0.844  1.0
  Co  Co4  1  0.000  0.000  0.156  1.0
  Co  Co5  1  0.000  0.500  0.680  1.0
  Co  Co6  1  0.500  0.000  0.000  1.0
  Co  Co7  1  0.500  0.500  0.500  1.0
  Co  Co8  1  0.500  0.750  0.247  1.0
  Co  Co9  1  0.500  0.250  0.753  1.0
  Co  Co10  1  0.500  0.250  0.247  1.0
  Co  Co11  1  0.500  0.750  0.753  1.0
[/CIF]
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