The structure described by (RuN5O8)2(NO3)2O2 is Indium-derived structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of two nitric acid molecules, two water atoms, and two RuN5O8 clusters. In each RuN5O8 cluster, Ru(1) is bonded in a 6-coordinate geometry to one N(1), one N(2), one N(3), one O(11), one O(5), and one O(7) atom. There are five inequivalent N sites. In the first N site, N(1) is bonded in a linear geometry to one Ru(1) and one O(10) atom. In the second N site, N(2) is bonded in a single-bond geometry to one Ru(1) atom. In the third N site, N(3) is bonded in a single-bond geometry to one Ru(1) atom. In the fourth N site, N(5) is bonded in a trigonal planar geometry to one O(4), one O(5), and one O(6) atom. In the fifth N site, N(6) is bonded in a trigonal planar geometry to one O(7), one O(8), and one O(9) atom. There are eight inequivalent O sites. In the first O site, O(10) is bonded in a single-bond geometry to one N(1) atom. In the second O site, O(11) is bonded in a single-bond geometry to one Ru(1) atom. In the third O site, O(4) is bonded in a single-bond geometry to one N(5) atom. In the fourth O site, O(5) is bonded in a bent 120 degrees geometry to one Ru(1) and one N(5) atom. In the fifth O site, O(6) is bonded in a single-bond geometry to one N(5) atom. In the sixth O site, O(7) is bonded in a bent 120 degrees geometry to one Ru(1) and one N(6) atom. In the seventh O site, O(8) is bonded in a single-bond geometry to one N(6) atom. In the eighth O site, O(9) is bonded in a single-bond geometry to one N(6) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ru(NO2)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.924
_cell_length_b   6.819
_cell_length_c   7.083
_cell_angle_alpha   66.684
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   617.563
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ru  Ru0  1  0.664  0.243  0.253  1.0
  Ru  Ru1  1  0.164  0.757  0.747  1.0
  N  N2  1  0.764  0.054  0.449  1.0
  N  N3  1  0.264  0.946  0.551  1.0
  N  N4  1  0.579  0.031  0.540  1.0
  N  N5  1  0.079  0.969  0.460  1.0
  N  N6  1  0.762  0.345  0.105  1.0
  N  N7  1  0.262  0.655  0.895  1.0
  N  N8  1  0.452  0.431  0.661  1.0
  N  N9  1  0.952  0.569  0.339  1.0
  N  N10  1  0.694  0.442  0.569  1.0
  N  N11  1  0.194  0.558  0.431  1.0
  N  N12  1  0.697  0.912  0.081  1.0
  N  N13  1  0.197  0.088  0.919  1.0
  O  O14  1  0.501  0.288  0.794  1.0
  O  O15  1  0.001  0.712  0.206  1.0
  O  O16  1  0.422  0.398  0.509  1.0
  O  O17  1  0.922  0.602  0.491  1.0
  O  O18  1  0.433  0.602  0.681  1.0
  O  O19  1  0.933  0.398  0.319  1.0
  O  O20  1  0.685  0.598  0.614  1.0
  O  O21  1  0.185  0.402  0.386  1.0
  O  O22  1  0.657  0.469  0.384  1.0
  O  O23  1  0.157  0.531  0.616  1.0
  O  O24  1  0.732  0.270  0.677  1.0
  O  O25  1  0.232  0.730  0.323  1.0
  O  O26  1  0.628  0.021  0.134  1.0
  O  O27  1  0.128  0.979  0.866  1.0
  O  O28  1  0.669  0.822  0.971  1.0
  O  O29  1  0.169  0.178  0.029  1.0
  O  O30  1  0.780  0.911  0.143  1.0
  O  O31  1  0.280  0.089  0.857  1.0
  O  O32  1  0.823  0.956  0.558  1.0
  O  O33  1  0.323  0.044  0.442  1.0
  O  O34  1  0.557  0.364  0.138  1.0
  O  O35  1  0.057  0.636  0.862  1.0
  O  O36  1  0.457  0.709  0.106  1.0
  O  O37  1  0.957  0.291  0.894  1.0
[/CIF]
.
The structure described by (RuN5O8)2(NO3)2O2 is Indium-derived structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of two nitric acid molecules, two water atoms, and two RuN5O8 clusters. In each RuN5O8 cluster, Ru(1) is bonded in a 6-coordinate geometry to one N(1), one N(2), one N(3), one O(11), one O(5), and one O(7) atom. There are five inequivalent N sites. In the first N site, N(1) is bonded in a linear geometry to one Ru(1) and one O(10) atom. In the second N site, N(2) is bonded in a single-bond geometry to one Ru(1) atom. In the third N site, N(3) is bonded in a single-bond geometry to one Ru(1) atom. In the fourth N site, N(5) is bonded in a trigonal planar geometry to one O(4), one O(5), and one O(6) atom. In the fifth N site, N(6) is bonded in a trigonal planar geometry to one O(7), one O(8), and one O(9) atom. There are eight inequivalent O sites. In the first O site, O(10) is bonded in a single-bond geometry to one N(1) atom. In the second O site, O(11) is bonded in a single-bond geometry to one Ru(1) atom. In the third O site, O(4) is bonded in a single-bond geometry to one N(5) atom. In the fourth O site, O(5) is bonded in a bent 120 degrees geometry to one Ru(1) and one N(5) atom. In the fifth O site, O(6) is bonded in a single-bond geometry to one N(5) atom. In the sixth O site, O(7) is bonded in a bent 120 degrees geometry to one Ru(1) and one N(6) atom. In the seventh O site, O(8) is bonded in a single-bond geometry to one N(6) atom. In the eighth O site, O(9) is bonded in a single-bond geometry to one N(6) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ru(NO2)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.924
_cell_length_b   6.819
_cell_length_c   7.083
_cell_angle_alpha   66.684
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   617.563
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ru  Ru0  1  0.664  0.243  0.253  1.0
  Ru  Ru1  1  0.164  0.757  0.747  1.0
  N  N2  1  0.764  0.054  0.449  1.0
  N  N3  1  0.264  0.946  0.551  1.0
  N  N4  1  0.579  0.031  0.540  1.0
  N  N5  1  0.079  0.969  0.460  1.0
  N  N6  1  0.762  0.345  0.105  1.0
  N  N7  1  0.262  0.655  0.895  1.0
  N  N8  1  0.452  0.431  0.661  1.0
  N  N9  1  0.952  0.569  0.339  1.0
  N  N10  1  0.694  0.442  0.569  1.0
  N  N11  1  0.194  0.558  0.431  1.0
  N  N12  1  0.697  0.912  0.081  1.0
  N  N13  1  0.197  0.088  0.919  1.0
  O  O14  1  0.501  0.288  0.794  1.0
  O  O15  1  0.001  0.712  0.206  1.0
  O  O16  1  0.422  0.398  0.509  1.0
  O  O17  1  0.922  0.602  0.491  1.0
  O  O18  1  0.433  0.602  0.681  1.0
  O  O19  1  0.933  0.398  0.319  1.0
  O  O20  1  0.685  0.598  0.614  1.0
  O  O21  1  0.185  0.402  0.386  1.0
  O  O22  1  0.657  0.469  0.384  1.0
  O  O23  1  0.157  0.531  0.616  1.0
  O  O24  1  0.732  0.270  0.677  1.0
  O  O25  1  0.232  0.730  0.323  1.0
  O  O26  1  0.628  0.021  0.134  1.0
  O  O27  1  0.128  0.979  0.866  1.0
  O  O28  1  0.669  0.822  0.971  1.0
  O  O29  1  0.169  0.178  0.029  1.0
  O  O30  1  0.780  0.911  0.143  1.0
  O  O31  1  0.280  0.089  0.857  1.0
  O  O32  1  0.823  0.956  0.558  1.0
  O  O33  1  0.323  0.044  0.442  1.0
  O  O34  1  0.557  0.364  0.138  1.0
  O  O35  1  0.057  0.636  0.862  1.0
  O  O36  1  0.457  0.709  0.106  1.0
  O  O37  1  0.957  0.291  0.894  1.0
[/CIF]
.