The material structure described by PCl4ICl4 is Indium-derived structured and crystallizes in the orthorhombic Imma space group. The structure is zero-dimensional and consists of eight [pcl4]+1 molecules and eight ICl4 clusters. In each ICl4 cluster, I(1) is bonded in a rectangular see-saw-like geometry to two equivalent Cl(5) and two equivalent Cl(6) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(5) is bonded in a single-bond geometry to one I(1) atom. In the second Cl site, Cl(6) is bonded in a single-bond geometry to one I(1) atom. is represented by the CIF card [CIF]
data_PICl8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.019
_cell_length_b   12.018
_cell_length_c   12.019
_cell_angle_alpha   118.563
_cell_angle_beta   117.461
_cell_angle_gamma   93.482
_symmetry_Int_Tables_number   1
_cell_volume   1261.815
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.246  0.746  1.000  1.0
  P  P1  1  0.254  0.254  0.500  1.0
  P  P2  1  0.746  0.746  0.500  1.0
  P  P3  1  0.754  0.254  1.000  1.0
  I  I4  1  0.750  0.690  0.940  1.0
  I  I5  1  0.750  0.179  0.429  1.0
  I  I6  1  0.250  0.821  0.571  1.0
  I  I7  1  0.250  0.310  0.060  1.0
  Cl  Cl8  1  0.226  0.404  0.484  1.0
  Cl  Cl9  1  0.750  0.975  0.225  1.0
  Cl  Cl10  1  0.394  0.714  0.979  1.0
  Cl  Cl11  1  0.106  0.085  0.320  1.0
  Cl  Cl12  1  0.403  0.973  0.570  1.0
  Cl  Cl13  1  0.765  0.085  0.979  1.0
  Cl  Cl14  1  0.097  0.667  0.570  1.0
  Cl  Cl15  1  0.250  0.025  0.775  1.0
  Cl  Cl16  1  0.579  0.758  0.484  1.0
  Cl  Cl17  1  0.097  0.156  0.059  1.0
  Cl  Cl18  1  0.235  0.915  0.021  1.0
  Cl  Cl19  1  0.549  0.693  0.742  1.0
  Cl  Cl20  1  0.250  0.614  0.364  1.0
  Cl  Cl21  1  0.774  0.596  0.516  1.0
  Cl  Cl22  1  0.597  0.538  0.941  1.0
  Cl  Cl23  1  0.951  0.693  0.144  1.0
  Cl  Cl24  1  0.726  0.242  0.821  1.0
  Cl  Cl25  1  0.903  0.333  0.430  1.0
  Cl  Cl26  1  0.903  0.844  0.941  1.0
  Cl  Cl27  1  0.265  0.286  0.680  1.0
  Cl  Cl28  1  0.049  0.307  0.856  1.0
  Cl  Cl29  1  0.421  0.242  0.516  1.0
  Cl  Cl30  1  0.735  0.714  0.320  1.0
  Cl  Cl31  1  0.079  0.596  0.821  1.0
  Cl  Cl32  1  0.750  0.386  0.636  1.0
  Cl  Cl33  1  0.274  0.758  0.179  1.0
  Cl  Cl34  1  0.403  0.462  0.059  1.0
  Cl  Cl35  1  0.606  0.286  0.021  1.0
  Cl  Cl36  1  0.921  0.404  0.179  1.0
  Cl  Cl37  1  0.894  0.915  0.680  1.0
  Cl  Cl38  1  0.597  0.027  0.430  1.0
  Cl  Cl39  1  0.451  0.307  0.258  1.0
[/CIF]
.
The material structure described by PCl4ICl4 is Indium-derived structured and crystallizes in the orthorhombic Imma space group. The structure is zero-dimensional and consists of eight [pcl4]+1 molecules and eight ICl4 clusters. In each ICl4 cluster, I(1) is bonded in a rectangular see-saw-like geometry to two equivalent Cl(5) and two equivalent Cl(6) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(5) is bonded in a single-bond geometry to one I(1) atom. In the second Cl site, Cl(6) is bonded in a single-bond geometry to one I(1) atom. is represented by the CIF card [CIF]
data_PICl8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.019
_cell_length_b   12.018
_cell_length_c   12.019
_cell_angle_alpha   118.563
_cell_angle_beta   117.461
_cell_angle_gamma   93.482
_symmetry_Int_Tables_number   1
_cell_volume   1261.815
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.246  0.746  1.000  1.0
  P  P1  1  0.254  0.254  0.500  1.0
  P  P2  1  0.746  0.746  0.500  1.0
  P  P3  1  0.754  0.254  1.000  1.0
  I  I4  1  0.750  0.690  0.940  1.0
  I  I5  1  0.750  0.179  0.429  1.0
  I  I6  1  0.250  0.821  0.571  1.0
  I  I7  1  0.250  0.310  0.060  1.0
  Cl  Cl8  1  0.226  0.404  0.484  1.0
  Cl  Cl9  1  0.750  0.975  0.225  1.0
  Cl  Cl10  1  0.394  0.714  0.979  1.0
  Cl  Cl11  1  0.106  0.085  0.320  1.0
  Cl  Cl12  1  0.403  0.973  0.570  1.0
  Cl  Cl13  1  0.765  0.085  0.979  1.0
  Cl  Cl14  1  0.097  0.667  0.570  1.0
  Cl  Cl15  1  0.250  0.025  0.775  1.0
  Cl  Cl16  1  0.579  0.758  0.484  1.0
  Cl  Cl17  1  0.097  0.156  0.059  1.0
  Cl  Cl18  1  0.235  0.915  0.021  1.0
  Cl  Cl19  1  0.549  0.693  0.742  1.0
  Cl  Cl20  1  0.250  0.614  0.364  1.0
  Cl  Cl21  1  0.774  0.596  0.516  1.0
  Cl  Cl22  1  0.597  0.538  0.941  1.0
  Cl  Cl23  1  0.951  0.693  0.144  1.0
  Cl  Cl24  1  0.726  0.242  0.821  1.0
  Cl  Cl25  1  0.903  0.333  0.430  1.0
  Cl  Cl26  1  0.903  0.844  0.941  1.0
  Cl  Cl27  1  0.265  0.286  0.680  1.0
  Cl  Cl28  1  0.049  0.307  0.856  1.0
  Cl  Cl29  1  0.421  0.242  0.516  1.0
  Cl  Cl30  1  0.735  0.714  0.320  1.0
  Cl  Cl31  1  0.079  0.596  0.821  1.0
  Cl  Cl32  1  0.750  0.386  0.636  1.0
  Cl  Cl33  1  0.274  0.758  0.179  1.0
  Cl  Cl34  1  0.403  0.462  0.059  1.0
  Cl  Cl35  1  0.606  0.286  0.021  1.0
  Cl  Cl36  1  0.921  0.404  0.179  1.0
  Cl  Cl37  1  0.894  0.915  0.680  1.0
  Cl  Cl38  1  0.597  0.027  0.430  1.0
  Cl  Cl39  1  0.451  0.307  0.258  1.0
[/CIF]
.