The compound described by SbOCl crystallizes in the monoclinic P2_1/c space group. There are three inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a distorted rectangular see-saw-like geometry to one O(2), one O(3), and two equivalent O(1) atoms. In the second Sb site, Sb(2) is bonded in a distorted rectangular see-saw-like geometry to one O(2), one O(3), one Cl(1), and one Cl(3) atom. In the third Sb site, Sb(3) is bonded in a 3-coordinate geometry to one O(1), one O(2), one Cl(2), and one Cl(3) atom. There are three inequivalent O sites. In the first O site, O(3) is bonded in a bent 120 degrees geometry to one Sb(1) and one Sb(2) atom. In the second O site, O(1) is bonded in a distorted trigonal planar geometry to one Sb(3) and two equivalent Sb(1) atoms. In the third O site, O(2) is bonded in a distorted trigonal planar geometry to one Sb(1), one Sb(2), and one Sb(3) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Sb(2) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Sb(3) atom. In the third Cl site, Cl(3) is bonded in a distorted bent 120 degrees geometry to one Sb(2) and one Sb(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_SbClO
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.933
_cell_length_b   8.013
_cell_length_c   9.600
_cell_angle_alpha   75.735
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   815.156
_cell_formula_units_Z   12
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.025  0.718  0.422  1.0
  Sb  Sb1  1  0.525  0.282  0.078  1.0
  Sb  Sb2  1  0.975  0.282  0.578  1.0
  Sb  Sb3  1  0.475  0.718  0.922  1.0
  Sb  Sb4  1  0.245  0.915  0.090  1.0
  Sb  Sb5  1  0.745  0.085  0.410  1.0
  Sb  Sb6  1  0.755  0.085  0.910  1.0
  Sb  Sb7  1  0.255  0.915  0.590  1.0
  Sb  Sb8  1  0.172  0.477  0.234  1.0
  Sb  Sb9  1  0.672  0.523  0.266  1.0
  Sb  Sb10  1  0.828  0.523  0.766  1.0
  Sb  Sb11  1  0.328  0.477  0.734  1.0
  Cl  Cl12  1  0.402  0.885  0.411  1.0
  Cl  Cl13  1  0.902  0.115  0.089  1.0
  Cl  Cl14  1  0.598  0.115  0.589  1.0
  Cl  Cl15  1  0.098  0.885  0.911  1.0
  Cl  Cl16  1  0.357  0.404  0.372  1.0
  Cl  Cl17  1  0.857  0.596  0.128  1.0
  Cl  Cl18  1  0.643  0.596  0.628  1.0
  Cl  Cl19  1  0.143  0.404  0.872  1.0
  Cl  Cl20  1  0.109  0.106  0.348  1.0
  Cl  Cl21  1  0.609  0.894  0.152  1.0
  Cl  Cl22  1  0.891  0.894  0.652  1.0
  Cl  Cl23  1  0.391  0.106  0.848  1.0
  O  O24  1  0.069  0.471  0.409  1.0
  O  O25  1  0.569  0.529  0.091  1.0
  O  O26  1  0.931  0.529  0.591  1.0
  O  O27  1  0.431  0.471  0.909  1.0
  O  O28  1  0.160  0.727  0.242  1.0
  O  O29  1  0.660  0.273  0.258  1.0
  O  O30  1  0.840  0.273  0.758  1.0
  O  O31  1  0.340  0.727  0.742  1.0
  O  O32  1  0.340  0.717  0.058  1.0
  O  O33  1  0.840  0.283  0.442  1.0
  O  O34  1  0.660  0.283  0.942  1.0
  O  O35  1  0.160  0.717  0.558  1.0
[/CIF]
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The compound described by SbOCl crystallizes in the monoclinic P2_1/c space group. There are three inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a distorted rectangular see-saw-like geometry to one O(2), one O(3), and two equivalent O(1) atoms. In the second Sb site, Sb(2) is bonded in a distorted rectangular see-saw-like geometry to one O(2), one O(3), one Cl(1), and one Cl(3) atom. In the third Sb site, Sb(3) is bonded in a 3-coordinate geometry to one O(1), one O(2), one Cl(2), and one Cl(3) atom. There are three inequivalent O sites. In the first O site, O(3) is bonded in a bent 120 degrees geometry to one Sb(1) and one Sb(2) atom. In the second O site, O(1) is bonded in a distorted trigonal planar geometry to one Sb(3) and two equivalent Sb(1) atoms. In the third O site, O(2) is bonded in a distorted trigonal planar geometry to one Sb(1), one Sb(2), and one Sb(3) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Sb(2) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Sb(3) atom. In the third Cl site, Cl(3) is bonded in a distorted bent 120 degrees geometry to one Sb(2) and one Sb(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_SbClO
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.933
_cell_length_b   8.013
_cell_length_c   9.600
_cell_angle_alpha   75.735
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   815.156
_cell_formula_units_Z   12
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.025  0.718  0.422  1.0
  Sb  Sb1  1  0.525  0.282  0.078  1.0
  Sb  Sb2  1  0.975  0.282  0.578  1.0
  Sb  Sb3  1  0.475  0.718  0.922  1.0
  Sb  Sb4  1  0.245  0.915  0.090  1.0
  Sb  Sb5  1  0.745  0.085  0.410  1.0
  Sb  Sb6  1  0.755  0.085  0.910  1.0
  Sb  Sb7  1  0.255  0.915  0.590  1.0
  Sb  Sb8  1  0.172  0.477  0.234  1.0
  Sb  Sb9  1  0.672  0.523  0.266  1.0
  Sb  Sb10  1  0.828  0.523  0.766  1.0
  Sb  Sb11  1  0.328  0.477  0.734  1.0
  Cl  Cl12  1  0.402  0.885  0.411  1.0
  Cl  Cl13  1  0.902  0.115  0.089  1.0
  Cl  Cl14  1  0.598  0.115  0.589  1.0
  Cl  Cl15  1  0.098  0.885  0.911  1.0
  Cl  Cl16  1  0.357  0.404  0.372  1.0
  Cl  Cl17  1  0.857  0.596  0.128  1.0
  Cl  Cl18  1  0.643  0.596  0.628  1.0
  Cl  Cl19  1  0.143  0.404  0.872  1.0
  Cl  Cl20  1  0.109  0.106  0.348  1.0
  Cl  Cl21  1  0.609  0.894  0.152  1.0
  Cl  Cl22  1  0.891  0.894  0.652  1.0
  Cl  Cl23  1  0.391  0.106  0.848  1.0
  O  O24  1  0.069  0.471  0.409  1.0
  O  O25  1  0.569  0.529  0.091  1.0
  O  O26  1  0.931  0.529  0.591  1.0
  O  O27  1  0.431  0.471  0.909  1.0
  O  O28  1  0.160  0.727  0.242  1.0
  O  O29  1  0.660  0.273  0.258  1.0
  O  O30  1  0.840  0.273  0.758  1.0
  O  O31  1  0.340  0.727  0.742  1.0
  O  O32  1  0.340  0.717  0.058  1.0
  O  O33  1  0.840  0.283  0.442  1.0
  O  O34  1  0.660  0.283  0.942  1.0
  O  O35  1  0.160  0.717  0.558  1.0
[/CIF]
.