The material described by K2HoWPO8 crystallizes in the orthorhombic Ibca space group. K(1) is bonded in a 8-coordinate geometry to one O(2), two equivalent O(1), two equivalent O(4), and three equivalent O(3) atoms. Ho(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(4), and four equivalent O(2) atoms. W(1) is bonded in a tetrahedral geometry to two equivalent O(3) and two equivalent O(4) atoms. P(1) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent O(2) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent K(1), one Ho(1), and one P(1) atom. In the second O site, O(2) is bonded in a 1-coordinate geometry to one K(1), two equivalent Ho(1), and one P(1) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to three equivalent K(1) and one W(1) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to two equivalent K(1), one Ho(1), and one W(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_K2HoPWO8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.237
_cell_length_b   12.237
_cell_length_c   12.237
_cell_angle_alpha   146.987
_cell_angle_beta   119.901
_cell_angle_gamma   70.303
_symmetry_Int_Tables_number   1
_cell_volume   852.558
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.578  0.187  0.451  1.0
  K  K1  1  0.235  0.126  0.049  1.0
  K  K2  1  0.922  0.374  0.609  1.0
  K  K3  1  0.078  0.626  0.391  1.0
  K  K4  1  0.422  0.813  0.549  1.0
  K  K5  1  0.735  0.687  0.109  1.0
  K  K6  1  0.265  0.313  0.891  1.0
  K  K7  1  0.765  0.874  0.951  1.0
  Ho  Ho8  1  0.174  0.250  0.424  1.0
  Ho  Ho9  1  0.826  0.750  0.576  1.0
  Ho  Ho10  1  0.326  0.750  0.076  1.0
  Ho  Ho11  1  0.674  0.250  0.924  1.0
  P  P12  1  0.430  0.250  0.680  1.0
  P  P13  1  0.070  0.750  0.820  1.0
  P  P14  1  0.570  0.750  0.320  1.0
  P  P15  1  0.930  0.250  0.180  1.0
  W  W16  1  0.914  0.164  0.750  1.0
  W  W17  1  0.086  0.836  0.250  1.0
  W  W18  1  0.414  0.664  0.750  1.0
  W  W19  1  0.586  0.336  0.250  1.0
  O  O20  1  0.445  0.171  0.738  1.0
  O  O21  1  0.555  0.829  0.262  1.0
  O  O22  1  0.356  0.084  0.426  1.0
  O  O23  1  0.151  0.843  0.425  1.0
  O  O24  1  0.168  0.675  0.069  1.0
  O  O25  1  0.158  0.931  0.074  1.0
  O  O26  1  0.651  0.226  0.308  1.0
  O  O27  1  0.055  0.794  0.727  1.0
  O  O28  1  0.067  0.294  0.238  1.0
  O  O29  1  0.658  0.584  0.228  1.0
  O  O30  1  0.418  0.343  0.192  1.0
  O  O31  1  0.849  0.157  0.575  1.0
  O  O32  1  0.342  0.416  0.772  1.0
  O  O33  1  0.349  0.774  0.692  1.0
  O  O34  1  0.933  0.706  0.762  1.0
  O  O35  1  0.567  0.329  0.773  1.0
  O  O36  1  0.832  0.325  0.931  1.0
  O  O37  1  0.842  0.069  0.926  1.0
  O  O38  1  0.644  0.916  0.574  1.0
  O  O39  1  0.894  0.901  0.569  1.0
  O  O40  1  0.394  0.825  0.992  1.0
  O  O41  1  0.332  0.401  0.508  1.0
  O  O42  1  0.668  0.599  0.492  1.0
  O  O43  1  0.106  0.099  0.431  1.0
  O  O44  1  0.606  0.175  0.008  1.0
  O  O45  1  0.945  0.206  0.273  1.0
  O  O46  1  0.582  0.657  0.808  1.0
  O  O47  1  0.918  0.726  0.075  1.0
  O  O48  1  0.144  0.569  0.728  1.0
  O  O49  1  0.856  0.431  0.272  1.0
  O  O50  1  0.433  0.671  0.227  1.0
  O  O51  1  0.082  0.274  0.925  1.0
[/CIF]
.
The material described by K2HoWPO8 crystallizes in the orthorhombic Ibca space group. K(1) is bonded in a 8-coordinate geometry to one O(2), two equivalent O(1), two equivalent O(4), and three equivalent O(3) atoms. Ho(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(4), and four equivalent O(2) atoms. W(1) is bonded in a tetrahedral geometry to two equivalent O(3) and two equivalent O(4) atoms. P(1) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent O(2) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent K(1), one Ho(1), and one P(1) atom. In the second O site, O(2) is bonded in a 1-coordinate geometry to one K(1), two equivalent Ho(1), and one P(1) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to three equivalent K(1) and one W(1) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to two equivalent K(1), one Ho(1), and one W(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_K2HoPWO8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.237
_cell_length_b   12.237
_cell_length_c   12.237
_cell_angle_alpha   146.987
_cell_angle_beta   119.901
_cell_angle_gamma   70.303
_symmetry_Int_Tables_number   1
_cell_volume   852.558
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.578  0.187  0.451  1.0
  K  K1  1  0.235  0.126  0.049  1.0
  K  K2  1  0.922  0.374  0.609  1.0
  K  K3  1  0.078  0.626  0.391  1.0
  K  K4  1  0.422  0.813  0.549  1.0
  K  K5  1  0.735  0.687  0.109  1.0
  K  K6  1  0.265  0.313  0.891  1.0
  K  K7  1  0.765  0.874  0.951  1.0
  Ho  Ho8  1  0.174  0.250  0.424  1.0
  Ho  Ho9  1  0.826  0.750  0.576  1.0
  Ho  Ho10  1  0.326  0.750  0.076  1.0
  Ho  Ho11  1  0.674  0.250  0.924  1.0
  P  P12  1  0.430  0.250  0.680  1.0
  P  P13  1  0.070  0.750  0.820  1.0
  P  P14  1  0.570  0.750  0.320  1.0
  P  P15  1  0.930  0.250  0.180  1.0
  W  W16  1  0.914  0.164  0.750  1.0
  W  W17  1  0.086  0.836  0.250  1.0
  W  W18  1  0.414  0.664  0.750  1.0
  W  W19  1  0.586  0.336  0.250  1.0
  O  O20  1  0.445  0.171  0.738  1.0
  O  O21  1  0.555  0.829  0.262  1.0
  O  O22  1  0.356  0.084  0.426  1.0
  O  O23  1  0.151  0.843  0.425  1.0
  O  O24  1  0.168  0.675  0.069  1.0
  O  O25  1  0.158  0.931  0.074  1.0
  O  O26  1  0.651  0.226  0.308  1.0
  O  O27  1  0.055  0.794  0.727  1.0
  O  O28  1  0.067  0.294  0.238  1.0
  O  O29  1  0.658  0.584  0.228  1.0
  O  O30  1  0.418  0.343  0.192  1.0
  O  O31  1  0.849  0.157  0.575  1.0
  O  O32  1  0.342  0.416  0.772  1.0
  O  O33  1  0.349  0.774  0.692  1.0
  O  O34  1  0.933  0.706  0.762  1.0
  O  O35  1  0.567  0.329  0.773  1.0
  O  O36  1  0.832  0.325  0.931  1.0
  O  O37  1  0.842  0.069  0.926  1.0
  O  O38  1  0.644  0.916  0.574  1.0
  O  O39  1  0.894  0.901  0.569  1.0
  O  O40  1  0.394  0.825  0.992  1.0
  O  O41  1  0.332  0.401  0.508  1.0
  O  O42  1  0.668  0.599  0.492  1.0
  O  O43  1  0.106  0.099  0.431  1.0
  O  O44  1  0.606  0.175  0.008  1.0
  O  O45  1  0.945  0.206  0.273  1.0
  O  O46  1  0.582  0.657  0.808  1.0
  O  O47  1  0.918  0.726  0.075  1.0
  O  O48  1  0.144  0.569  0.728  1.0
  O  O49  1  0.856  0.431  0.272  1.0
  O  O50  1  0.433  0.671  0.227  1.0
  O  O51  1  0.082  0.274  0.925  1.0
[/CIF]
.