The crystal structure described by MgP3(OBr3)3POBr3 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one phosphorus oxybromide molecule and one MgP3(OBr3)3 cluster. In the MgP3(OBr3)3 cluster, Mg(1) is bonded to one O(2), one Br(10), one Br(12), and one Br(6) atom to form distorted MgBr3O tetrahedra that share  a cornercorner with one P(2)Br3O tetrahedra and  a cornercorner with one P(3)Br3O tetrahedra. There are three inequivalent P sites. In the first P site, P(1) is bonded in a distorted single-bond geometry to one O(3), one Br(12), and one Br(5) atom. In the second P site, P(2) is bonded to one O(1), one Br(1), one Br(6), and one Br(7) atom to form distorted PBr3O tetrahedra that share  a cornercorner with one Mg(1)Br3O tetrahedra. In the third P site, P(3) is bonded to one O(2), one Br(4), one Br(8), and one Br(9) atom to form PBr3O tetrahedra that share  a cornercorner with one Mg(1)Br3O tetrahedra. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one P(2) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Mg(1) and one P(3) atom. In the third O site, O(3) is bonded in a single-bond geometry to one P(1) atom. There are nine inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one P(2) atom. In the second Br site, Br(4) is bonded in a single-bond geometry to one P(3) atom. In the third Br site, Br(5) is bonded in a single-bond geometry to one P(1) atom. In the fourth Br site, Br(6) is bonded in a water-like geometry to one Mg(1) and one P(2) atom. In the fifth Br site, Br(7) is bonded in a single-bond geometry to one P(2) atom. In the sixth Br site, Br(8) is bonded in a single-bond geometry to one P(3) atom. In the seventh Br site, Br(9) is bonded in a single-bond geometry to one P(3) atom. In the eighth Br site, Br(10) is bonded in a single-bond geometry to one Mg(1) atom. In the ninth Br site, Br(12) is bonded in a bent 120 degrees geometry to one Mg(1) and one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_MgP4(Br3O)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.579
_cell_length_b   11.121
_cell_length_c   9.850
_cell_angle_alpha   88.169
_cell_angle_beta   79.119
_cell_angle_gamma   82.439
_symmetry_Int_Tables_number   1
_cell_volume   808.160
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.862  0.416  0.967  1.0
  P  P1  1  0.438  0.261  0.278  1.0
  P  P2  1  0.620  0.685  0.730  1.0
  P  P3  1  0.808  0.188  0.772  1.0
  P  P4  1  0.105  0.814  0.241  1.0
  Br  Br5  1  0.768  0.626  0.526  1.0
  Br  Br6  1  0.890  0.969  0.272  1.0
  Br  Br7  1  0.269  0.834  0.400  1.0
  Br  Br8  1  0.648  0.084  0.929  1.0
  Br  Br9  1  0.266  0.374  0.461  1.0
  Br  Br10  1  0.841  0.654  0.864  1.0
  Br  Br11  1  0.436  0.552  0.813  1.0
  Br  Br12  1  0.694  0.189  0.585  1.0
  Br  Br13  1  0.078  0.086  0.728  1.0
  Br  Br14  1  0.180  0.373  0.979  1.0
  Br  Br15  1  0.283  0.854  0.044  1.0
  Br  Br16  1  0.622  0.452  0.177  1.0
  O  O17  1  0.540  0.813  0.738  1.0
  O  O18  1  0.811  0.314  0.823  1.0
  O  O19  1  0.574  0.174  0.336  1.0
  O  O20  1  0.038  0.695  0.243  1.0
[/CIF]
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The crystal structure described by MgP3(OBr3)3POBr3 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one phosphorus oxybromide molecule and one MgP3(OBr3)3 cluster. In the MgP3(OBr3)3 cluster, Mg(1) is bonded to one O(2), one Br(10), one Br(12), and one Br(6) atom to form distorted MgBr3O tetrahedra that share  a cornercorner with one P(2)Br3O tetrahedra and  a cornercorner with one P(3)Br3O tetrahedra. There are three inequivalent P sites. In the first P site, P(1) is bonded in a distorted single-bond geometry to one O(3), one Br(12), and one Br(5) atom. In the second P site, P(2) is bonded to one O(1), one Br(1), one Br(6), and one Br(7) atom to form distorted PBr3O tetrahedra that share  a cornercorner with one Mg(1)Br3O tetrahedra. In the third P site, P(3) is bonded to one O(2), one Br(4), one Br(8), and one Br(9) atom to form PBr3O tetrahedra that share  a cornercorner with one Mg(1)Br3O tetrahedra. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one P(2) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Mg(1) and one P(3) atom. In the third O site, O(3) is bonded in a single-bond geometry to one P(1) atom. There are nine inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one P(2) atom. In the second Br site, Br(4) is bonded in a single-bond geometry to one P(3) atom. In the third Br site, Br(5) is bonded in a single-bond geometry to one P(1) atom. In the fourth Br site, Br(6) is bonded in a water-like geometry to one Mg(1) and one P(2) atom. In the fifth Br site, Br(7) is bonded in a single-bond geometry to one P(2) atom. In the sixth Br site, Br(8) is bonded in a single-bond geometry to one P(3) atom. In the seventh Br site, Br(9) is bonded in a single-bond geometry to one P(3) atom. In the eighth Br site, Br(10) is bonded in a single-bond geometry to one Mg(1) atom. In the ninth Br site, Br(12) is bonded in a bent 120 degrees geometry to one Mg(1) and one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_MgP4(Br3O)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.579
_cell_length_b   11.121
_cell_length_c   9.850
_cell_angle_alpha   88.169
_cell_angle_beta   79.119
_cell_angle_gamma   82.439
_symmetry_Int_Tables_number   1
_cell_volume   808.160
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.862  0.416  0.967  1.0
  P  P1  1  0.438  0.261  0.278  1.0
  P  P2  1  0.620  0.685  0.730  1.0
  P  P3  1  0.808  0.188  0.772  1.0
  P  P4  1  0.105  0.814  0.241  1.0
  Br  Br5  1  0.768  0.626  0.526  1.0
  Br  Br6  1  0.890  0.969  0.272  1.0
  Br  Br7  1  0.269  0.834  0.400  1.0
  Br  Br8  1  0.648  0.084  0.929  1.0
  Br  Br9  1  0.266  0.374  0.461  1.0
  Br  Br10  1  0.841  0.654  0.864  1.0
  Br  Br11  1  0.436  0.552  0.813  1.0
  Br  Br12  1  0.694  0.189  0.585  1.0
  Br  Br13  1  0.078  0.086  0.728  1.0
  Br  Br14  1  0.180  0.373  0.979  1.0
  Br  Br15  1  0.283  0.854  0.044  1.0
  Br  Br16  1  0.622  0.452  0.177  1.0
  O  O17  1  0.540  0.813  0.738  1.0
  O  O18  1  0.811  0.314  0.823  1.0
  O  O19  1  0.574  0.174  0.336  1.0
  O  O20  1  0.038  0.695  0.243  1.0
[/CIF]
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