The crystal structure described by MnOF crystallizes in the triclinic P-1 space group. Mn(1) is bonded to three equivalent O(1) and three equivalent F(1) atoms to form a mixture of distorted corner and edge-sharing MnO3F3 octahedra. The corner-sharing octahedral tilt angles range from 22-32°. O(1) is bonded in a T-shaped geometry to three equivalent Mn(1) atoms. F(1) is bonded in a 3-coordinate geometry to three equivalent Mn(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_MnOF
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.792
_cell_length_b   4.351
_cell_length_c   5.530
_cell_angle_alpha   110.998
_cell_angle_beta   109.367
_cell_angle_gamma   90.924
_symmetry_Int_Tables_number   1
_cell_volume   79.410
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.863  0.617  0.231  1.0
  Mn  Mn1  1  0.137  0.383  0.769  1.0
  O  O2  1  0.332  0.630  0.164  1.0
  O  O3  1  0.668  0.370  0.836  1.0
  F  F4  1  0.944  0.187  0.358  1.0
  F  F5  1  0.056  0.813  0.642  1.0
[/CIF]
.
The crystal structure described by MnOF crystallizes in the triclinic P-1 space group. Mn(1) is bonded to three equivalent O(1) and three equivalent F(1) atoms to form a mixture of distorted corner and edge-sharing MnO3F3 octahedra. The corner-sharing octahedral tilt angles range from 22-32°. O(1) is bonded in a T-shaped geometry to three equivalent Mn(1) atoms. F(1) is bonded in a 3-coordinate geometry to three equivalent Mn(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_MnOF
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.792
_cell_length_b   4.351
_cell_length_c   5.530
_cell_angle_alpha   110.998
_cell_angle_beta   109.367
_cell_angle_gamma   90.924
_symmetry_Int_Tables_number   1
_cell_volume   79.410
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.863  0.617  0.231  1.0
  Mn  Mn1  1  0.137  0.383  0.769  1.0
  O  O2  1  0.332  0.630  0.164  1.0
  O  O3  1  0.668  0.370  0.836  1.0
  F  F4  1  0.944  0.187  0.358  1.0
  F  F5  1  0.056  0.813  0.642  1.0
[/CIF]
.