The compound described by MoO2 is Hydrophilite-like structured and crystallizes in the tetragonal I4/m space group. Mo(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form a mixture of edge and corner-sharing MoO6 octahedra. The corner-sharing octahedral tilt angles are 51°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to three equivalent Mo(1) atoms. In the second O site, O(2) is bonded in a trigonal non-coplanar geometry to three equivalent Mo(1) atoms. is represented by the CIF file [CIF]
data_MoO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.687
_cell_length_b   7.687
_cell_length_c   7.687
_cell_angle_alpha   92.584
_cell_angle_beta   92.584
_cell_angle_gamma   155.483
_symmetry_Int_Tables_number   1
_cell_volume   184.168
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mo  Mo0  1  0.343  0.842  0.185  1.0
  Mo  Mo1  1  0.842  0.657  0.499  1.0
  Mo  Mo2  1  0.158  0.343  0.501  1.0
  Mo  Mo3  1  0.657  0.158  0.815  1.0
  O  O4  1  0.162  0.534  0.695  1.0
  O  O5  1  0.534  0.838  0.372  1.0
  O  O6  1  0.466  0.162  0.628  1.0
  O  O7  1  0.838  0.466  0.305  1.0
  O  O8  1  0.839  0.215  0.054  1.0
  O  O9  1  0.215  0.161  0.377  1.0
  O  O10  1  0.161  0.785  0.946  1.0
  O  O11  1  0.785  0.839  0.623  1.0
[/CIF]
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The compound described by MoO2 is Hydrophilite-like structured and crystallizes in the tetragonal I4/m space group. Mo(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form a mixture of edge and corner-sharing MoO6 octahedra. The corner-sharing octahedral tilt angles are 51°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to three equivalent Mo(1) atoms. In the second O site, O(2) is bonded in a trigonal non-coplanar geometry to three equivalent Mo(1) atoms. is represented by the CIF file [CIF]
data_MoO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.687
_cell_length_b   7.687
_cell_length_c   7.687
_cell_angle_alpha   92.584
_cell_angle_beta   92.584
_cell_angle_gamma   155.483
_symmetry_Int_Tables_number   1
_cell_volume   184.168
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mo  Mo0  1  0.343  0.842  0.185  1.0
  Mo  Mo1  1  0.842  0.657  0.499  1.0
  Mo  Mo2  1  0.158  0.343  0.501  1.0
  Mo  Mo3  1  0.657  0.158  0.815  1.0
  O  O4  1  0.162  0.534  0.695  1.0
  O  O5  1  0.534  0.838  0.372  1.0
  O  O6  1  0.466  0.162  0.628  1.0
  O  O7  1  0.838  0.466  0.305  1.0
  O  O8  1  0.839  0.215  0.054  1.0
  O  O9  1  0.215  0.161  0.377  1.0
  O  O10  1  0.161  0.785  0.946  1.0
  O  O11  1  0.785  0.839  0.623  1.0
[/CIF]
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