The structure described by RbSO4F crystallizes in the triclinic P-1 space group. Rb(1) is bonded in a 11-coordinate geometry to one O(4), two equivalent O(3), three equivalent O(1), three equivalent O(2), and two equivalent F(1) atoms. S(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to three equivalent Rb(1) and one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to three equivalent Rb(1) and one S(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one S(1) atom. In the fourth O site, O(4) is bonded in a distorted water-like geometry to one Rb(1), one S(1), and one F(1) atom. F(1) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one O(4) atom. is represented by the CIF card [CIF]
data_RbSO4F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.633
_cell_length_b   5.758
_cell_length_c   7.750
_cell_angle_alpha   100.357
_cell_angle_beta   106.568
_cell_angle_gamma   93.932
_symmetry_Int_Tables_number   1
_cell_volume   235.107
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.110  0.335  0.241  1.0
  Rb  Rb1  1  0.890  0.665  0.759  1.0
  S  S2  1  0.384  0.224  0.788  1.0
  S  S3  1  0.616  0.776  0.212  1.0
  O  O4  1  0.175  0.183  0.858  1.0
  O  O5  1  0.659  0.626  0.348  1.0
  O  O6  1  0.367  0.733  0.079  1.0
  O  O7  1  0.341  0.374  0.652  1.0
  O  O8  1  0.567  0.043  0.314  1.0
  O  O9  1  0.433  0.957  0.686  1.0
  O  O10  1  0.825  0.817  0.142  1.0
  O  O11  1  0.633  0.267  0.921  1.0
  F  F12  1  0.794  0.147  0.474  1.0
  F  F13  1  0.206  0.853  0.526  1.0
[/CIF]
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The structure described by RbSO4F crystallizes in the triclinic P-1 space group. Rb(1) is bonded in a 11-coordinate geometry to one O(4), two equivalent O(3), three equivalent O(1), three equivalent O(2), and two equivalent F(1) atoms. S(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to three equivalent Rb(1) and one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to three equivalent Rb(1) and one S(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one S(1) atom. In the fourth O site, O(4) is bonded in a distorted water-like geometry to one Rb(1), one S(1), and one F(1) atom. F(1) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one O(4) atom. is represented by the CIF card [CIF]
data_RbSO4F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.633
_cell_length_b   5.758
_cell_length_c   7.750
_cell_angle_alpha   100.357
_cell_angle_beta   106.568
_cell_angle_gamma   93.932
_symmetry_Int_Tables_number   1
_cell_volume   235.107
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.110  0.335  0.241  1.0
  Rb  Rb1  1  0.890  0.665  0.759  1.0
  S  S2  1  0.384  0.224  0.788  1.0
  S  S3  1  0.616  0.776  0.212  1.0
  O  O4  1  0.175  0.183  0.858  1.0
  O  O5  1  0.659  0.626  0.348  1.0
  O  O6  1  0.367  0.733  0.079  1.0
  O  O7  1  0.341  0.374  0.652  1.0
  O  O8  1  0.567  0.043  0.314  1.0
  O  O9  1  0.433  0.957  0.686  1.0
  O  O10  1  0.825  0.817  0.142  1.0
  O  O11  1  0.633  0.267  0.921  1.0
  F  F12  1  0.794  0.147  0.474  1.0
  F  F13  1  0.206  0.853  0.526  1.0
[/CIF]
.