The material described by WPd3 is beta Cu3Ti-like structured and crystallizes in the tetragonal I4/mmm space group. W(1) is bonded to four equivalent Pd(2) and eight equivalent Pd(1) atoms to form WPd12 cuboctahedra that share corners with four equivalent W(1)Pd12 cuboctahedra, corners with eight equivalent Pd(2)Pd8W4 cuboctahedra, edges with eight equivalent W(1)Pd12 cuboctahedra, edges with sixteen equivalent Pd(1)Pd8W4 cuboctahedra, faces with four equivalent W(1)Pd12 cuboctahedra, faces with six equivalent Pd(2)Pd8W4 cuboctahedra, and faces with eight equivalent Pd(1)Pd8W4 cuboctahedra. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded to four equivalent W(1), four equivalent Pd(1), and four equivalent Pd(2) atoms to form PdPd8W4 cuboctahedra that share corners with twelve equivalent Pd(1)Pd8W4 cuboctahedra, edges with eight equivalent W(1)Pd12 cuboctahedra, edges with eight equivalent Pd(1)Pd8W4 cuboctahedra, edges with eight equivalent Pd(2)Pd8W4 cuboctahedra, faces with four equivalent W(1)Pd12 cuboctahedra, faces with four equivalent Pd(2)Pd8W4 cuboctahedra, and faces with ten equivalent Pd(1)Pd8W4 cuboctahedra. In the second Pd site, Pd(2) is bonded to four equivalent W(1) and eight equivalent Pd(1) atoms to form PdPd8W4 cuboctahedra that share corners with four equivalent Pd(2)Pd8W4 cuboctahedra, corners with eight equivalent W(1)Pd12 cuboctahedra, edges with eight equivalent Pd(2)Pd8W4 cuboctahedra, edges with sixteen equivalent Pd(1)Pd8W4 cuboctahedra, faces with four equivalent Pd(2)Pd8W4 cuboctahedra, faces with six equivalent W(1)Pd12 cuboctahedra, and faces with eight equivalent Pd(1)Pd8W4 cuboctahedra. is represented by the CIF card [CIF]
data_Pd3W
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.837
_cell_length_b   4.837
_cell_length_c   4.837
_cell_angle_alpha   133.052
_cell_angle_beta   133.052
_cell_angle_gamma   68.573
_symmetry_Int_Tables_number   1
_cell_volume   59.353
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pd  Pd0  1  0.750  0.250  0.500  1.0
  Pd  Pd1  1  0.250  0.750  0.500  1.0
  Pd  Pd2  1  0.500  0.500  0.000  1.0
  W  W3  1  0.000  0.000  0.000  1.0
[/CIF]
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The material described by WPd3 is beta Cu3Ti-like structured and crystallizes in the tetragonal I4/mmm space group. W(1) is bonded to four equivalent Pd(2) and eight equivalent Pd(1) atoms to form WPd12 cuboctahedra that share corners with four equivalent W(1)Pd12 cuboctahedra, corners with eight equivalent Pd(2)Pd8W4 cuboctahedra, edges with eight equivalent W(1)Pd12 cuboctahedra, edges with sixteen equivalent Pd(1)Pd8W4 cuboctahedra, faces with four equivalent W(1)Pd12 cuboctahedra, faces with six equivalent Pd(2)Pd8W4 cuboctahedra, and faces with eight equivalent Pd(1)Pd8W4 cuboctahedra. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded to four equivalent W(1), four equivalent Pd(1), and four equivalent Pd(2) atoms to form PdPd8W4 cuboctahedra that share corners with twelve equivalent Pd(1)Pd8W4 cuboctahedra, edges with eight equivalent W(1)Pd12 cuboctahedra, edges with eight equivalent Pd(1)Pd8W4 cuboctahedra, edges with eight equivalent Pd(2)Pd8W4 cuboctahedra, faces with four equivalent W(1)Pd12 cuboctahedra, faces with four equivalent Pd(2)Pd8W4 cuboctahedra, and faces with ten equivalent Pd(1)Pd8W4 cuboctahedra. In the second Pd site, Pd(2) is bonded to four equivalent W(1) and eight equivalent Pd(1) atoms to form PdPd8W4 cuboctahedra that share corners with four equivalent Pd(2)Pd8W4 cuboctahedra, corners with eight equivalent W(1)Pd12 cuboctahedra, edges with eight equivalent Pd(2)Pd8W4 cuboctahedra, edges with sixteen equivalent Pd(1)Pd8W4 cuboctahedra, faces with four equivalent Pd(2)Pd8W4 cuboctahedra, faces with six equivalent W(1)Pd12 cuboctahedra, and faces with eight equivalent Pd(1)Pd8W4 cuboctahedra. is represented by the CIF card [CIF]
data_Pd3W
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.837
_cell_length_b   4.837
_cell_length_c   4.837
_cell_angle_alpha   133.052
_cell_angle_beta   133.052
_cell_angle_gamma   68.573
_symmetry_Int_Tables_number   1
_cell_volume   59.353
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pd  Pd0  1  0.750  0.250  0.500  1.0
  Pd  Pd1  1  0.250  0.750  0.500  1.0
  Pd  Pd2  1  0.500  0.500  0.000  1.0
  W  W3  1  0.000  0.000  0.000  1.0
[/CIF]
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