The crystal structure described by Ag7O8NO3 crystallizes in the orthorhombic Fmm2 space group. There are four inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 5-coordinate geometry to one O(4), two equivalent O(2), and two equivalent O(3) atoms. In the second Ag site, Ag(2) is bonded in a 6-coordinate geometry to one O(1), one O(4), two equivalent O(2), and two equivalent O(3) atoms. In the third Ag site, Ag(3) is bonded in a square co-planar geometry to two equivalent O(2) and two equivalent O(3) atoms. In the fourth Ag site, Ag(4) is bonded in a body-centered cubic geometry to four equivalent O(2) and four equivalent O(3) atoms. N(1) is bonded in a trigonal planar geometry to one O(4) and two equivalent O(1) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Ag(2) and one N(1) atom. In the second O site, O(2) is bonded to one Ag(1), one Ag(2), one Ag(3), and one Ag(4) atom to form a mixture of corner and edge-sharing OAg4 tetrahedra. In the third O site, O(3) is bonded to one Ag(1), one Ag(2), one Ag(3), and one Ag(4) atom to form a mixture of corner and edge-sharing OAg4 tetrahedra. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to two equivalent Ag(1), two equivalent Ag(2), and one N(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ag7NO11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.085
_cell_length_b   6.958
_cell_length_c   6.926
_cell_angle_alpha   61.365
_cell_angle_beta   59.535
_cell_angle_gamma   59.099
_symmetry_Int_Tables_number   1
_cell_volume   241.207
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.005  0.498  0.995  1.0
  Ag  Ag1  1  0.510  0.004  0.996  1.0
  Ag  Ag2  1  0.004  0.510  0.490  1.0
  Ag  Ag3  1  0.498  0.005  0.502  1.0
  Ag  Ag4  1  0.503  0.503  0.997  1.0
  Ag  Ag5  1  0.505  0.505  0.495  1.0
  Ag  Ag6  1  0.003  0.003  0.497  1.0
  N  N7  1  0.985  0.985  0.015  1.0
  O  O8  1  0.156  0.936  0.064  1.0
  O  O9  1  0.369  0.361  0.353  1.0
  O  O10  1  0.083  0.647  0.639  1.0
  O  O11  1  0.647  0.083  0.631  1.0
  O  O12  1  0.648  0.636  0.075  1.0
  O  O13  1  0.361  0.369  0.917  1.0
  O  O14  1  0.358  0.925  0.364  1.0
  O  O15  1  0.925  0.358  0.352  1.0
  O  O16  1  0.636  0.648  0.642  1.0
  O  O17  1  0.859  0.859  0.141  1.0
  O  O18  1  0.936  0.156  0.844  1.0
[/CIF]
.
The crystal structure described by Ag7O8NO3 crystallizes in the orthorhombic Fmm2 space group. There are four inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 5-coordinate geometry to one O(4), two equivalent O(2), and two equivalent O(3) atoms. In the second Ag site, Ag(2) is bonded in a 6-coordinate geometry to one O(1), one O(4), two equivalent O(2), and two equivalent O(3) atoms. In the third Ag site, Ag(3) is bonded in a square co-planar geometry to two equivalent O(2) and two equivalent O(3) atoms. In the fourth Ag site, Ag(4) is bonded in a body-centered cubic geometry to four equivalent O(2) and four equivalent O(3) atoms. N(1) is bonded in a trigonal planar geometry to one O(4) and two equivalent O(1) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Ag(2) and one N(1) atom. In the second O site, O(2) is bonded to one Ag(1), one Ag(2), one Ag(3), and one Ag(4) atom to form a mixture of corner and edge-sharing OAg4 tetrahedra. In the third O site, O(3) is bonded to one Ag(1), one Ag(2), one Ag(3), and one Ag(4) atom to form a mixture of corner and edge-sharing OAg4 tetrahedra. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to two equivalent Ag(1), two equivalent Ag(2), and one N(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ag7NO11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.085
_cell_length_b   6.958
_cell_length_c   6.926
_cell_angle_alpha   61.365
_cell_angle_beta   59.535
_cell_angle_gamma   59.099
_symmetry_Int_Tables_number   1
_cell_volume   241.207
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.005  0.498  0.995  1.0
  Ag  Ag1  1  0.510  0.004  0.996  1.0
  Ag  Ag2  1  0.004  0.510  0.490  1.0
  Ag  Ag3  1  0.498  0.005  0.502  1.0
  Ag  Ag4  1  0.503  0.503  0.997  1.0
  Ag  Ag5  1  0.505  0.505  0.495  1.0
  Ag  Ag6  1  0.003  0.003  0.497  1.0
  N  N7  1  0.985  0.985  0.015  1.0
  O  O8  1  0.156  0.936  0.064  1.0
  O  O9  1  0.369  0.361  0.353  1.0
  O  O10  1  0.083  0.647  0.639  1.0
  O  O11  1  0.647  0.083  0.631  1.0
  O  O12  1  0.648  0.636  0.075  1.0
  O  O13  1  0.361  0.369  0.917  1.0
  O  O14  1  0.358  0.925  0.364  1.0
  O  O15  1  0.925  0.358  0.352  1.0
  O  O16  1  0.636  0.648  0.642  1.0
  O  O17  1  0.859  0.859  0.141  1.0
  O  O18  1  0.936  0.156  0.844  1.0
[/CIF]
.