The compound described by OsF6 is beta Np structured and crystallizes in the orthorhombic Pmc2_1 space group. The structure is zero-dimensional and consists of four osmium hexafluoride molecules. Os(1,2) is bonded in an octahedral geometry to one F(3), one F(7), two equivalent F(2), and two equivalent F(5) atoms. There are four inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one Os(1,2) atom. In the second F site, F(3) is bonded in a single-bond geometry to one Os(1,2) atom. In the third F site, F(5) is bonded in a single-bond geometry to one Os(1,2) atom. In the fourth F site, F(7) is bonded in a single-bond geometry to one Os(1,2) atom. is represented by the CIF file [CIF]
data_OsF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.922
_cell_length_b   8.465
_cell_length_c   9.283
_cell_angle_alpha   90.002
_cell_angle_beta   89.994
_cell_angle_gamma   90.001
_symmetry_Int_Tables_number   1
_cell_volume   386.757
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Os  Os0  1  0.588  0.750  0.874  1.0
  Os  Os1  1  0.087  0.250  0.627  1.0
  Os  Os2  1  0.413  0.250  0.127  1.0
  Os  Os3  1  0.912  0.750  0.374  1.0
  F  F4  1  0.260  0.096  0.010  1.0
  F  F5  1  0.753  0.904  0.487  1.0
  F  F6  1  0.747  0.596  0.987  1.0
  F  F7  1  0.240  0.404  0.510  1.0
  F  F8  1  0.602  0.750  0.258  1.0
  F  F9  1  0.108  0.250  0.246  1.0
  F  F10  1  0.392  0.250  0.746  1.0
  F  F11  1  0.898  0.750  0.758  1.0
  F  F12  1  0.071  0.596  0.260  1.0
  F  F13  1  0.566  0.404  0.243  1.0
  F  F14  1  0.934  0.096  0.743  1.0
  F  F15  1  0.429  0.904  0.760  1.0
  F  F16  1  0.934  0.404  0.743  1.0
  F  F17  1  0.429  0.596  0.760  1.0
  F  F18  1  0.071  0.904  0.260  1.0
  F  F19  1  0.566  0.096  0.243  1.0
  F  F20  1  0.222  0.750  0.489  1.0
  F  F21  1  0.716  0.250  0.007  1.0
  F  F22  1  0.784  0.250  0.507  1.0
  F  F23  1  0.278  0.750  0.989  1.0
  F  F24  1  0.753  0.596  0.487  1.0
  F  F25  1  0.260  0.404  0.010  1.0
  F  F26  1  0.240  0.096  0.510  1.0
  F  F27  1  0.747  0.904  0.987  1.0
[/CIF]
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The compound described by OsF6 is beta Np structured and crystallizes in the orthorhombic Pmc2_1 space group. The structure is zero-dimensional and consists of four osmium hexafluoride molecules. Os(1,2) is bonded in an octahedral geometry to one F(3), one F(7), two equivalent F(2), and two equivalent F(5) atoms. There are four inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one Os(1,2) atom. In the second F site, F(3) is bonded in a single-bond geometry to one Os(1,2) atom. In the third F site, F(5) is bonded in a single-bond geometry to one Os(1,2) atom. In the fourth F site, F(7) is bonded in a single-bond geometry to one Os(1,2) atom. is represented by the CIF file [CIF]
data_OsF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.922
_cell_length_b   8.465
_cell_length_c   9.283
_cell_angle_alpha   90.002
_cell_angle_beta   89.994
_cell_angle_gamma   90.001
_symmetry_Int_Tables_number   1
_cell_volume   386.757
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Os  Os0  1  0.588  0.750  0.874  1.0
  Os  Os1  1  0.087  0.250  0.627  1.0
  Os  Os2  1  0.413  0.250  0.127  1.0
  Os  Os3  1  0.912  0.750  0.374  1.0
  F  F4  1  0.260  0.096  0.010  1.0
  F  F5  1  0.753  0.904  0.487  1.0
  F  F6  1  0.747  0.596  0.987  1.0
  F  F7  1  0.240  0.404  0.510  1.0
  F  F8  1  0.602  0.750  0.258  1.0
  F  F9  1  0.108  0.250  0.246  1.0
  F  F10  1  0.392  0.250  0.746  1.0
  F  F11  1  0.898  0.750  0.758  1.0
  F  F12  1  0.071  0.596  0.260  1.0
  F  F13  1  0.566  0.404  0.243  1.0
  F  F14  1  0.934  0.096  0.743  1.0
  F  F15  1  0.429  0.904  0.760  1.0
  F  F16  1  0.934  0.404  0.743  1.0
  F  F17  1  0.429  0.596  0.760  1.0
  F  F18  1  0.071  0.904  0.260  1.0
  F  F19  1  0.566  0.096  0.243  1.0
  F  F20  1  0.222  0.750  0.489  1.0
  F  F21  1  0.716  0.250  0.007  1.0
  F  F22  1  0.784  0.250  0.507  1.0
  F  F23  1  0.278  0.750  0.989  1.0
  F  F24  1  0.753  0.596  0.487  1.0
  F  F25  1  0.260  0.404  0.010  1.0
  F  F26  1  0.240  0.096  0.510  1.0
  F  F27  1  0.747  0.904  0.987  1.0
[/CIF]
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