The compound described by HoTeO3Cl crystallizes in the orthorhombic Pnma space group. Ho(1) is bonded to one O(1), four equivalent O(2), and two equivalent Cl(1) atoms to form a mixture of distorted edge and corner-sharing HoCl2O5 pentagonal bipyramids. Te(1) is bonded in a distorted T-shaped geometry to one O(1) and two equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Ho(1) and one Te(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent Ho(1) and one Te(1) atom. Cl(1) is bonded in a bent 150 degrees geometry to two equivalent Ho(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_HoTeClO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.011
_cell_length_b   7.392
_cell_length_c   9.138
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   473.572
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ho  Ho0  1  0.250  0.593  0.964  1.0
  Ho  Ho1  1  0.750  0.407  0.036  1.0
  Ho  Ho2  1  0.750  0.907  0.464  1.0
  Ho  Ho3  1  0.250  0.093  0.536  1.0
  Te  Te4  1  0.750  0.817  0.869  1.0
  Te  Te5  1  0.250  0.683  0.369  1.0
  Te  Te6  1  0.750  0.317  0.631  1.0
  Te  Te7  1  0.250  0.183  0.131  1.0
  Cl  Cl8  1  0.250  0.932  0.813  1.0
  Cl  Cl9  1  0.250  0.432  0.687  1.0
  Cl  Cl10  1  0.750  0.568  0.313  1.0
  Cl  Cl11  1  0.750  0.068  0.187  1.0
  O  O12  1  0.250  0.742  0.170  1.0
  O  O13  1  0.750  0.758  0.670  1.0
  O  O14  1  0.566  0.645  0.935  1.0
  O  O15  1  0.934  0.645  0.935  1.0
  O  O16  1  0.434  0.355  0.065  1.0
  O  O17  1  0.066  0.355  0.065  1.0
  O  O18  1  0.434  0.855  0.435  1.0
  O  O19  1  0.566  0.145  0.565  1.0
  O  O20  1  0.934  0.145  0.565  1.0
  O  O21  1  0.750  0.258  0.830  1.0
  O  O22  1  0.250  0.242  0.330  1.0
  O  O23  1  0.066  0.855  0.435  1.0
[/CIF]
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The compound described by HoTeO3Cl crystallizes in the orthorhombic Pnma space group. Ho(1) is bonded to one O(1), four equivalent O(2), and two equivalent Cl(1) atoms to form a mixture of distorted edge and corner-sharing HoCl2O5 pentagonal bipyramids. Te(1) is bonded in a distorted T-shaped geometry to one O(1) and two equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Ho(1) and one Te(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent Ho(1) and one Te(1) atom. Cl(1) is bonded in a bent 150 degrees geometry to two equivalent Ho(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_HoTeClO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.011
_cell_length_b   7.392
_cell_length_c   9.138
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   473.572
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ho  Ho0  1  0.250  0.593  0.964  1.0
  Ho  Ho1  1  0.750  0.407  0.036  1.0
  Ho  Ho2  1  0.750  0.907  0.464  1.0
  Ho  Ho3  1  0.250  0.093  0.536  1.0
  Te  Te4  1  0.750  0.817  0.869  1.0
  Te  Te5  1  0.250  0.683  0.369  1.0
  Te  Te6  1  0.750  0.317  0.631  1.0
  Te  Te7  1  0.250  0.183  0.131  1.0
  Cl  Cl8  1  0.250  0.932  0.813  1.0
  Cl  Cl9  1  0.250  0.432  0.687  1.0
  Cl  Cl10  1  0.750  0.568  0.313  1.0
  Cl  Cl11  1  0.750  0.068  0.187  1.0
  O  O12  1  0.250  0.742  0.170  1.0
  O  O13  1  0.750  0.758  0.670  1.0
  O  O14  1  0.566  0.645  0.935  1.0
  O  O15  1  0.934  0.645  0.935  1.0
  O  O16  1  0.434  0.355  0.065  1.0
  O  O17  1  0.066  0.355  0.065  1.0
  O  O18  1  0.434  0.855  0.435  1.0
  O  O19  1  0.566  0.145  0.565  1.0
  O  O20  1  0.934  0.145  0.565  1.0
  O  O21  1  0.750  0.258  0.830  1.0
  O  O22  1  0.250  0.242  0.330  1.0
  O  O23  1  0.066  0.855  0.435  1.0
[/CIF]
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