The material structure described by V2O3F is Hydrophilite-derived structured and crystallizes in the orthorhombic Cmcm space group. There are two inequivalent V sites. In the first V site, V(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent F(1) atoms to form edge-sharing VO4F2 octahedra. In the second V site, V(2) is bonded in a 6-coordinate geometry to one O(1), four equivalent O(2), and one F(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one V(2) and two equivalent V(1) atoms. In the second O site, O(2) is bonded in a trigonal planar geometry to one V(1) and two equivalent V(2) atoms. F(1) is bonded in a 3-coordinate geometry to one V(2) and two equivalent V(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_V2O3F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.627
_cell_length_b   4.627
_cell_length_c   5.937
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   94.825
_symmetry_Int_Tables_number   1
_cell_volume   126.641
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.000  0.000  0.000  1.0
  V  V1  1  0.000  0.000  0.500  1.0
  V  V2  1  0.549  0.451  0.250  1.0
  V  V3  1  0.451  0.549  0.750  1.0
  O  O4  1  0.193  0.807  0.750  1.0
  O  O5  1  0.305  0.305  0.000  1.0
  O  O6  1  0.305  0.305  0.500  1.0
  O  O7  1  0.695  0.695  0.000  1.0
  O  O8  1  0.695  0.695  0.500  1.0
  O  O9  1  0.807  0.193  0.250  1.0
  F  F10  1  0.197  0.803  0.250  1.0
  F  F11  1  0.803  0.197  0.750  1.0
[/CIF]
.
The material structure described by V2O3F is Hydrophilite-derived structured and crystallizes in the orthorhombic Cmcm space group. There are two inequivalent V sites. In the first V site, V(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent F(1) atoms to form edge-sharing VO4F2 octahedra. In the second V site, V(2) is bonded in a 6-coordinate geometry to one O(1), four equivalent O(2), and one F(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one V(2) and two equivalent V(1) atoms. In the second O site, O(2) is bonded in a trigonal planar geometry to one V(1) and two equivalent V(2) atoms. F(1) is bonded in a 3-coordinate geometry to one V(2) and two equivalent V(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_V2O3F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.627
_cell_length_b   4.627
_cell_length_c   5.937
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   94.825
_symmetry_Int_Tables_number   1
_cell_volume   126.641
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.000  0.000  0.000  1.0
  V  V1  1  0.000  0.000  0.500  1.0
  V  V2  1  0.549  0.451  0.250  1.0
  V  V3  1  0.451  0.549  0.750  1.0
  O  O4  1  0.193  0.807  0.750  1.0
  O  O5  1  0.305  0.305  0.000  1.0
  O  O6  1  0.305  0.305  0.500  1.0
  O  O7  1  0.695  0.695  0.000  1.0
  O  O8  1  0.695  0.695  0.500  1.0
  O  O9  1  0.807  0.193  0.250  1.0
  F  F10  1  0.197  0.803  0.250  1.0
  F  F11  1  0.803  0.197  0.750  1.0
[/CIF]
.