The material structure described by Li4Cr3Mn3(SbO8)2 is Spinel-derived structured and crystallizes in the monoclinic Cm space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(12), one O(3), and two equivalent O(9) atoms to form LiO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra, corners with two equivalent Cr(1)O6 octahedra, corners with two equivalent Cr(2)O6 octahedra, corners with three equivalent Sb(2)O6 octahedra, and corners with four equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 57-62°. In the second Li site, Li(2) is bonded to one O(5), one O(7), and two equivalent O(11) atoms to form distorted LiO4 trigonal pyramids that share  a cornercorner with one Cr(2)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with three equivalent Sb(2)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra, and edges with two equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 60-65°. In the third Li site, Li(3) is bonded to one O(4), one O(8), and two equivalent O(1) atoms to form distorted LiO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra, corners with two equivalent Cr(1)O6 octahedra, corners with three equivalent Sb(1)O6 octahedra,  an edgeedge with one Cr(2)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 61-64°. In the fourth Li site, Li(4) is bonded to one O(10), one O(2), and two equivalent O(6) atoms to form LiO4 tetrahedra that share  a cornercorner with one Cr(2)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with three equivalent Sb(1)O6 octahedra, and corners with four equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 57-63°. There are two inequivalent Cr sites. In the first Cr site, Cr(1) is bonded to one O(11), one O(2), one O(3), one O(4), one O(6), and one O(7) atom to form CrO6 octahedra that share corners with two equivalent Sb(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Sb(1)O6 octahedra, edges with two equivalent Cr(1)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and  an edgeedge with one Li(2)O4 trigonal pyramid. The corner-sharing octahedral tilt angles are 50°. In the second Cr site, Cr(2) is bonded to one O(10), one O(5), two equivalent O(1), and two equivalent O(9) atoms to form CrO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 trigonal pyramid,  an edgeedge with one Sb(2)O6 octahedra, edges with four equivalent Mn(2)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles are 49°. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(3), one O(4), two equivalent O(11), and two equivalent O(6) atoms to form MnO6 octahedra that share corners with two equivalent Sb(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Sb(1)O6 octahedra, edges with four equivalent Cr(1)O6 octahedra, and  an edgeedge with one Li(2)O4 trigonal pyramid. The corner-sharing octahedral tilt angles are 53°. In the second Mn site, Mn(2) is bonded to one O(1), one O(10), one O(12), one O(5), one O(8), and one O(9) atom to form MnO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 trigonal pyramid,  an edgeedge with one Sb(2)O6 octahedra, edges with two equivalent Cr(2)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 51-52°. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(2), one O(8), two equivalent O(1), and two equivalent O(6) atoms to form SbO6 octahedra that share corners with two equivalent Cr(2)O6 octahedra, corners with four equivalent Mn(2)O6 octahedra, corners with three equivalent Li(3)O4 tetrahedra, corners with three equivalent Li(4)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra, and edges with two equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-52°. In the second Sb site, Sb(2) is bonded to one O(12), one O(7), two equivalent O(11), and two equivalent O(9) atoms to form SbO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra, corners with four equivalent Cr(1)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra, corners with three equivalent Li(2)O4 trigonal pyramids,  an edgeedge with one Cr(2)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-53°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Li(3), one Cr(2), one Mn(2), and one Sb(1) atom. In the second O site, O(2) is bonded to one Li(4), two equivalent Cr(1), and one Sb(1) atom to form distorted OLiCr2Sb trigonal pyramids that share  a cornercorner with one O(10)LiMn2Cr tetrahedra, corners with two equivalent O(4)LiMnCr2 tetrahedra, and  an edgeedge with one O(3)LiMnCr2 tetrahedra. In the third O site, O(3) is bonded to one Li(1), two equivalent Cr(1), and one Mn(1) atom to form distorted OLiMnCr2 tetrahedra that share  a cornercorner with one O(12)LiMn2Sb tetrahedra, corners with three equivalent O(4)LiMnCr2 tetrahedra, and  an edgeedge with one O(2)LiCr2Sb trigonal pyramid. In the fourth O site, O(4) is bonded to one Li(3), two equivalent Cr(1), and one Mn(1) atom to form OLiMnCr2 tetrahedra that share corners with three equivalent O(3)LiMnCr2 tetrahedra and corners with two equivalent O(2)LiCr2Sb trigonal pyramids. In the fifth O site, O(5) is bonded to one Li(2), one Cr(2), and two equivalent Mn(2) atoms to form OLiMn2Cr tetrahedra that share corners with two equivalent O(12)LiMn2Sb tetrahedra and corners with three equivalent O(10)LiMn2Cr tetrahedra. In the sixth O site, O(6) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), one Cr(1), one Mn(1), and one Sb(1) atom. In the seventh O site, O(7) is bonded in a rectangular see-saw-like geometry to one Li(2), two equivalent Cr(1), and one Sb(2) atom. In the eighth O site, O(8) is bonded in a rectangular see-saw-like geometry to one Li(3), two equivalent Mn(2), and one Sb(1) atom. In the ninth O site, O(9) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Cr(2), one Mn(2), and one Sb(2) atom. In the tenth O site, O(10) is bonded to one Li(4), one Cr(2), and two equivalent Mn(2) atoms to form distorted OLiMn2Cr tetrahedra that share corners with three equivalent O(5)LiMn2Cr tetrahedra,  a cornercorner with one O(2)LiCr2Sb trigonal pyramid, and  an edgeedge with one O(12)LiMn2Sb tetrahedra. In the eleventh O site, O(11) is bonded in a rectangular see-saw-like geometry to one Li(2), one Cr(1), one Mn(1), and one Sb(2) atom. In the twelfth O site, O(12) is bonded to one Li(1), two equivalent Mn(2), and one Sb(2) atom to form distorted OLiMn2Sb tetrahedra that share  a cornercorner with one O(3)LiMnCr2 tetrahedra, corners with two equivalent O(5)LiMn2Cr tetrahedra, and  an edgeedge with one O(10)LiMn2Cr tetrahedra. is represented by the CIF card [CIF]
data_Li4Mn3Cr3(SbO8)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.993
_cell_length_b   5.993
_cell_length_c   9.757
_cell_angle_alpha   88.606
_cell_angle_beta   88.606
_cell_angle_gamma   59.431
_symmetry_Int_Tables_number   1
_cell_volume   301.609
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.663  0.663  0.093  1.0
  Li  Li1  1  0.001  0.001  0.011  1.0
  Li  Li2  1  0.004  0.004  0.511  1.0
  Li  Li3  1  0.334  0.334  0.599  1.0
  Mn  Mn4  1  0.832  0.832  0.789  1.0
  Mn  Mn5  1  0.170  0.663  0.287  1.0
  Mn  Mn6  1  0.663  0.170  0.287  1.0
  Cr  Cr7  1  0.340  0.831  0.786  1.0
  Cr  Cr8  1  0.831  0.340  0.786  1.0
  Cr  Cr9  1  0.171  0.171  0.285  1.0
  Sb  Sb10  1  0.669  0.669  0.515  1.0
  Sb  Sb11  1  0.329  0.329  0.013  1.0
  O  O12  1  0.338  0.840  0.408  1.0
  O  O13  1  0.519  0.519  0.660  1.0
  O  O14  1  0.670  0.670  0.886  1.0
  O  O15  1  0.997  0.997  0.697  1.0
  O  O16  1  1.000  1.000  0.199  1.0
  O  O17  1  0.840  0.338  0.408  1.0
  O  O18  1  0.511  0.966  0.653  1.0
  O  O19  1  0.966  0.511  0.653  1.0
  O  O20  1  0.165  0.165  0.901  1.0
  O  O21  1  0.839  0.839  0.408  1.0
  O  O22  1  0.028  0.471  0.150  1.0
  O  O23  1  0.471  0.028  0.150  1.0
  O  O24  1  0.335  0.335  0.385  1.0
  O  O25  1  0.169  0.669  0.908  1.0
  O  O26  1  0.478  0.478  0.152  1.0
  O  O27  1  0.669  0.169  0.908  1.0
[/CIF]
.
The material structure described by Li4Cr3Mn3(SbO8)2 is Spinel-derived structured and crystallizes in the monoclinic Cm space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(12), one O(3), and two equivalent O(9) atoms to form LiO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra, corners with two equivalent Cr(1)O6 octahedra, corners with two equivalent Cr(2)O6 octahedra, corners with three equivalent Sb(2)O6 octahedra, and corners with four equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 57-62°. In the second Li site, Li(2) is bonded to one O(5), one O(7), and two equivalent O(11) atoms to form distorted LiO4 trigonal pyramids that share  a cornercorner with one Cr(2)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with three equivalent Sb(2)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra, and edges with two equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 60-65°. In the third Li site, Li(3) is bonded to one O(4), one O(8), and two equivalent O(1) atoms to form distorted LiO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra, corners with two equivalent Cr(1)O6 octahedra, corners with three equivalent Sb(1)O6 octahedra,  an edgeedge with one Cr(2)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 61-64°. In the fourth Li site, Li(4) is bonded to one O(10), one O(2), and two equivalent O(6) atoms to form LiO4 tetrahedra that share  a cornercorner with one Cr(2)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with three equivalent Sb(1)O6 octahedra, and corners with four equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 57-63°. There are two inequivalent Cr sites. In the first Cr site, Cr(1) is bonded to one O(11), one O(2), one O(3), one O(4), one O(6), and one O(7) atom to form CrO6 octahedra that share corners with two equivalent Sb(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Sb(1)O6 octahedra, edges with two equivalent Cr(1)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and  an edgeedge with one Li(2)O4 trigonal pyramid. The corner-sharing octahedral tilt angles are 50°. In the second Cr site, Cr(2) is bonded to one O(10), one O(5), two equivalent O(1), and two equivalent O(9) atoms to form CrO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 trigonal pyramid,  an edgeedge with one Sb(2)O6 octahedra, edges with four equivalent Mn(2)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles are 49°. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(3), one O(4), two equivalent O(11), and two equivalent O(6) atoms to form MnO6 octahedra that share corners with two equivalent Sb(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Sb(1)O6 octahedra, edges with four equivalent Cr(1)O6 octahedra, and  an edgeedge with one Li(2)O4 trigonal pyramid. The corner-sharing octahedral tilt angles are 53°. In the second Mn site, Mn(2) is bonded to one O(1), one O(10), one O(12), one O(5), one O(8), and one O(9) atom to form MnO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 trigonal pyramid,  an edgeedge with one Sb(2)O6 octahedra, edges with two equivalent Cr(2)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 51-52°. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(2), one O(8), two equivalent O(1), and two equivalent O(6) atoms to form SbO6 octahedra that share corners with two equivalent Cr(2)O6 octahedra, corners with four equivalent Mn(2)O6 octahedra, corners with three equivalent Li(3)O4 tetrahedra, corners with three equivalent Li(4)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra, and edges with two equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-52°. In the second Sb site, Sb(2) is bonded to one O(12), one O(7), two equivalent O(11), and two equivalent O(9) atoms to form SbO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra, corners with four equivalent Cr(1)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra, corners with three equivalent Li(2)O4 trigonal pyramids,  an edgeedge with one Cr(2)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-53°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Li(3), one Cr(2), one Mn(2), and one Sb(1) atom. In the second O site, O(2) is bonded to one Li(4), two equivalent Cr(1), and one Sb(1) atom to form distorted OLiCr2Sb trigonal pyramids that share  a cornercorner with one O(10)LiMn2Cr tetrahedra, corners with two equivalent O(4)LiMnCr2 tetrahedra, and  an edgeedge with one O(3)LiMnCr2 tetrahedra. In the third O site, O(3) is bonded to one Li(1), two equivalent Cr(1), and one Mn(1) atom to form distorted OLiMnCr2 tetrahedra that share  a cornercorner with one O(12)LiMn2Sb tetrahedra, corners with three equivalent O(4)LiMnCr2 tetrahedra, and  an edgeedge with one O(2)LiCr2Sb trigonal pyramid. In the fourth O site, O(4) is bonded to one Li(3), two equivalent Cr(1), and one Mn(1) atom to form OLiMnCr2 tetrahedra that share corners with three equivalent O(3)LiMnCr2 tetrahedra and corners with two equivalent O(2)LiCr2Sb trigonal pyramids. In the fifth O site, O(5) is bonded to one Li(2), one Cr(2), and two equivalent Mn(2) atoms to form OLiMn2Cr tetrahedra that share corners with two equivalent O(12)LiMn2Sb tetrahedra and corners with three equivalent O(10)LiMn2Cr tetrahedra. In the sixth O site, O(6) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), one Cr(1), one Mn(1), and one Sb(1) atom. In the seventh O site, O(7) is bonded in a rectangular see-saw-like geometry to one Li(2), two equivalent Cr(1), and one Sb(2) atom. In the eighth O site, O(8) is bonded in a rectangular see-saw-like geometry to one Li(3), two equivalent Mn(2), and one Sb(1) atom. In the ninth O site, O(9) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Cr(2), one Mn(2), and one Sb(2) atom. In the tenth O site, O(10) is bonded to one Li(4), one Cr(2), and two equivalent Mn(2) atoms to form distorted OLiMn2Cr tetrahedra that share corners with three equivalent O(5)LiMn2Cr tetrahedra,  a cornercorner with one O(2)LiCr2Sb trigonal pyramid, and  an edgeedge with one O(12)LiMn2Sb tetrahedra. In the eleventh O site, O(11) is bonded in a rectangular see-saw-like geometry to one Li(2), one Cr(1), one Mn(1), and one Sb(2) atom. In the twelfth O site, O(12) is bonded to one Li(1), two equivalent Mn(2), and one Sb(2) atom to form distorted OLiMn2Sb tetrahedra that share  a cornercorner with one O(3)LiMnCr2 tetrahedra, corners with two equivalent O(5)LiMn2Cr tetrahedra, and  an edgeedge with one O(10)LiMn2Cr tetrahedra. is represented by the CIF card [CIF]
data_Li4Mn3Cr3(SbO8)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.993
_cell_length_b   5.993
_cell_length_c   9.757
_cell_angle_alpha   88.606
_cell_angle_beta   88.606
_cell_angle_gamma   59.431
_symmetry_Int_Tables_number   1
_cell_volume   301.609
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.663  0.663  0.093  1.0
  Li  Li1  1  0.001  0.001  0.011  1.0
  Li  Li2  1  0.004  0.004  0.511  1.0
  Li  Li3  1  0.334  0.334  0.599  1.0
  Mn  Mn4  1  0.832  0.832  0.789  1.0
  Mn  Mn5  1  0.170  0.663  0.287  1.0
  Mn  Mn6  1  0.663  0.170  0.287  1.0
  Cr  Cr7  1  0.340  0.831  0.786  1.0
  Cr  Cr8  1  0.831  0.340  0.786  1.0
  Cr  Cr9  1  0.171  0.171  0.285  1.0
  Sb  Sb10  1  0.669  0.669  0.515  1.0
  Sb  Sb11  1  0.329  0.329  0.013  1.0
  O  O12  1  0.338  0.840  0.408  1.0
  O  O13  1  0.519  0.519  0.660  1.0
  O  O14  1  0.670  0.670  0.886  1.0
  O  O15  1  0.997  0.997  0.697  1.0
  O  O16  1  1.000  1.000  0.199  1.0
  O  O17  1  0.840  0.338  0.408  1.0
  O  O18  1  0.511  0.966  0.653  1.0
  O  O19  1  0.966  0.511  0.653  1.0
  O  O20  1  0.165  0.165  0.901  1.0
  O  O21  1  0.839  0.839  0.408  1.0
  O  O22  1  0.028  0.471  0.150  1.0
  O  O23  1  0.471  0.028  0.150  1.0
  O  O24  1  0.335  0.335  0.385  1.0
  O  O25  1  0.169  0.669  0.908  1.0
  O  O26  1  0.478  0.478  0.152  1.0
  O  O27  1  0.669  0.169  0.908  1.0
[/CIF]
.