The structure described by Ni10ZnP3 crystallizes in the trigonal P-3m1 space group. There are seven inequivalent Ni sites. In the first Ni site, Ni(1) is bonded in a 4-coordinate geometry to one Ni(1) and three equivalent P(1) atoms. In the second Ni site, Ni(2) is bonded in a distorted bent 150 degrees geometry to two equivalent Zn(1) and two equivalent P(1) atoms. In the third Ni site, Ni(3) is bonded in a 4-coordinate geometry to one Zn(2), one P(1), and two equivalent P(2) atoms. In the fourth Ni site, Ni(4) is bonded in a 2-coordinate geometry to one Zn(1), one Zn(2), and two equivalent P(1) atoms. In the fifth Ni site, Ni(5) is bonded in a 4-coordinate geometry to one Zn(1), one P(2), and two equivalent P(1) atoms. In the sixth Ni site, Ni(6) is bonded to one Zn(1) and three equivalent P(2) atoms to form distorted corner-sharing NiZnP3 tetrahedra. In the seventh Ni site, Ni(7) is bonded to one Zn(1) and three equivalent P(1) atoms to form distorted corner-sharing NiZnP3 tetrahedra. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a 14-coordinate geometry to one Ni(6), one Ni(7), three equivalent Ni(4), three equivalent Ni(5), and six equivalent Ni(2) atoms. In the second Zn site, Zn(2) is bonded in a cuboctahedral geometry to six equivalent Ni(3) and six equivalent Ni(4) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded in a 9-coordinate geometry to one Ni(1), one Ni(3), one Ni(7), two equivalent Ni(2), two equivalent Ni(4), and two equivalent Ni(5) atoms. In the second P site, P(2) is bonded in a body-centered cubic geometry to two equivalent Ni(5), two equivalent Ni(6), and four equivalent Ni(3) atoms. is represented by the CIF card [CIF]
data_ZnNi10P3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.649
_cell_length_b   7.649
_cell_length_c   9.344
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   473.471
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.667  0.333  0.360  1.0
  Zn  Zn1  1  0.333  0.667  0.640  1.0
  Zn  Zn2  1  0.000  0.000  0.000  1.0
  Ni  Ni3  1  0.000  0.000  0.621  1.0
  Ni  Ni4  1  0.000  0.341  0.500  1.0
  Ni  Ni5  1  0.659  0.659  0.500  1.0
  Ni  Ni6  1  0.659  0.000  0.500  1.0
  Ni  Ni7  1  0.000  0.659  0.500  1.0
  Ni  Ni8  1  0.341  0.341  0.500  1.0
  Ni  Ni9  1  0.183  0.817  0.066  1.0
  Ni  Ni10  1  0.183  0.365  0.066  1.0
  Ni  Ni11  1  0.635  0.817  0.066  1.0
  Ni  Ni12  1  0.365  0.183  0.934  1.0
  Ni  Ni13  1  0.341  0.000  0.500  1.0
  Ni  Ni14  1  0.817  0.183  0.934  1.0
  Ni  Ni15  1  0.140  0.860  0.795  1.0
  Ni  Ni16  1  0.140  0.280  0.795  1.0
  Ni  Ni17  1  0.720  0.860  0.795  1.0
  Ni  Ni18  1  0.280  0.140  0.205  1.0
  Ni  Ni19  1  0.860  0.720  0.205  1.0
  Ni  Ni20  1  0.860  0.140  0.205  1.0
  Ni  Ni21  1  0.491  0.509  0.241  1.0
  Ni  Ni22  1  0.491  0.983  0.241  1.0
  Ni  Ni23  1  0.017  0.509  0.241  1.0
  Ni  Ni24  1  0.983  0.491  0.759  1.0
  Ni  Ni25  1  0.509  0.017  0.759  1.0
  Ni  Ni26  1  0.509  0.491  0.759  1.0
  Ni  Ni27  1  0.667  0.333  0.097  1.0
  Ni  Ni28  1  0.333  0.667  0.903  1.0
  Ni  Ni29  1  0.667  0.333  0.614  1.0
  Ni  Ni30  1  0.333  0.667  0.386  1.0
  Ni  Ni31  1  0.817  0.635  0.934  1.0
  Ni  Ni32  1  0.000  0.000  0.379  1.0
  P  P33  1  0.835  0.165  0.691  1.0
  P  P34  1  0.835  0.670  0.691  1.0
  P  P35  1  0.330  0.165  0.691  1.0
  P  P36  1  0.165  0.835  0.309  1.0
  P  P37  1  0.500  0.500  0.000  1.0
  P  P38  1  0.000  0.500  0.000  1.0
  P  P39  1  0.500  0.000  0.000  1.0
  P  P40  1  0.670  0.835  0.309  1.0
  P  P41  1  0.165  0.330  0.309  1.0
[/CIF]
.
The structure described by Ni10ZnP3 crystallizes in the trigonal P-3m1 space group. There are seven inequivalent Ni sites. In the first Ni site, Ni(1) is bonded in a 4-coordinate geometry to one Ni(1) and three equivalent P(1) atoms. In the second Ni site, Ni(2) is bonded in a distorted bent 150 degrees geometry to two equivalent Zn(1) and two equivalent P(1) atoms. In the third Ni site, Ni(3) is bonded in a 4-coordinate geometry to one Zn(2), one P(1), and two equivalent P(2) atoms. In the fourth Ni site, Ni(4) is bonded in a 2-coordinate geometry to one Zn(1), one Zn(2), and two equivalent P(1) atoms. In the fifth Ni site, Ni(5) is bonded in a 4-coordinate geometry to one Zn(1), one P(2), and two equivalent P(1) atoms. In the sixth Ni site, Ni(6) is bonded to one Zn(1) and three equivalent P(2) atoms to form distorted corner-sharing NiZnP3 tetrahedra. In the seventh Ni site, Ni(7) is bonded to one Zn(1) and three equivalent P(1) atoms to form distorted corner-sharing NiZnP3 tetrahedra. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a 14-coordinate geometry to one Ni(6), one Ni(7), three equivalent Ni(4), three equivalent Ni(5), and six equivalent Ni(2) atoms. In the second Zn site, Zn(2) is bonded in a cuboctahedral geometry to six equivalent Ni(3) and six equivalent Ni(4) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded in a 9-coordinate geometry to one Ni(1), one Ni(3), one Ni(7), two equivalent Ni(2), two equivalent Ni(4), and two equivalent Ni(5) atoms. In the second P site, P(2) is bonded in a body-centered cubic geometry to two equivalent Ni(5), two equivalent Ni(6), and four equivalent Ni(3) atoms. is represented by the CIF card [CIF]
data_ZnNi10P3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.649
_cell_length_b   7.649
_cell_length_c   9.344
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   473.471
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.667  0.333  0.360  1.0
  Zn  Zn1  1  0.333  0.667  0.640  1.0
  Zn  Zn2  1  0.000  0.000  0.000  1.0
  Ni  Ni3  1  0.000  0.000  0.621  1.0
  Ni  Ni4  1  0.000  0.341  0.500  1.0
  Ni  Ni5  1  0.659  0.659  0.500  1.0
  Ni  Ni6  1  0.659  0.000  0.500  1.0
  Ni  Ni7  1  0.000  0.659  0.500  1.0
  Ni  Ni8  1  0.341  0.341  0.500  1.0
  Ni  Ni9  1  0.183  0.817  0.066  1.0
  Ni  Ni10  1  0.183  0.365  0.066  1.0
  Ni  Ni11  1  0.635  0.817  0.066  1.0
  Ni  Ni12  1  0.365  0.183  0.934  1.0
  Ni  Ni13  1  0.341  0.000  0.500  1.0
  Ni  Ni14  1  0.817  0.183  0.934  1.0
  Ni  Ni15  1  0.140  0.860  0.795  1.0
  Ni  Ni16  1  0.140  0.280  0.795  1.0
  Ni  Ni17  1  0.720  0.860  0.795  1.0
  Ni  Ni18  1  0.280  0.140  0.205  1.0
  Ni  Ni19  1  0.860  0.720  0.205  1.0
  Ni  Ni20  1  0.860  0.140  0.205  1.0
  Ni  Ni21  1  0.491  0.509  0.241  1.0
  Ni  Ni22  1  0.491  0.983  0.241  1.0
  Ni  Ni23  1  0.017  0.509  0.241  1.0
  Ni  Ni24  1  0.983  0.491  0.759  1.0
  Ni  Ni25  1  0.509  0.017  0.759  1.0
  Ni  Ni26  1  0.509  0.491  0.759  1.0
  Ni  Ni27  1  0.667  0.333  0.097  1.0
  Ni  Ni28  1  0.333  0.667  0.903  1.0
  Ni  Ni29  1  0.667  0.333  0.614  1.0
  Ni  Ni30  1  0.333  0.667  0.386  1.0
  Ni  Ni31  1  0.817  0.635  0.934  1.0
  Ni  Ni32  1  0.000  0.000  0.379  1.0
  P  P33  1  0.835  0.165  0.691  1.0
  P  P34  1  0.835  0.670  0.691  1.0
  P  P35  1  0.330  0.165  0.691  1.0
  P  P36  1  0.165  0.835  0.309  1.0
  P  P37  1  0.500  0.500  0.000  1.0
  P  P38  1  0.000  0.500  0.000  1.0
  P  P39  1  0.500  0.000  0.000  1.0
  P  P40  1  0.670  0.835  0.309  1.0
  P  P41  1  0.165  0.330  0.309  1.0
[/CIF]
.