The material structure described by Fe3C9TeSO9 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two Fe3C9TeSO9 clusters. There are three inequivalent Fe sites. In the first Fe site, Fe(1) is bonded in a 4-coordinate geometry to one C(1), one C(6), one C(8), one Te(1), and one S(1) atom. In the second Fe site, Fe(2) is bonded in a distorted trigonal pyramidal geometry to one C(2), one C(4), one C(5), one Te(1), and one S(1) atom. In the third Fe site, Fe(3) is bonded in a 5-coordinate geometry to one C(3), one C(7), one C(9), one Te(1), and one S(1) atom. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Fe(1) and one O(3) atom. In the second C site, C(2) is bonded in a linear geometry to one Fe(2) and one O(6) atom. In the third C site, C(3) is bonded in a linear geometry to one Fe(3) and one O(8) atom. In the fourth C site, C(4) is bonded in a linear geometry to one Fe(2) and one O(5) atom. In the fifth C site, C(5) is bonded in a distorted linear geometry to one Fe(2) and one O(7) atom. In the sixth C site, C(6) is bonded in a linear geometry to one Fe(1) and one O(1) atom. In the seventh C site, C(7) is bonded in a distorted linear geometry to one Fe(3) and one O(4) atom. In the eighth C site, C(8) is bonded in a distorted linear geometry to one Fe(1) and one O(2) atom. In the ninth C site, C(9) is bonded in a linear geometry to one Fe(3) and one O(9) atom. Te(1) is bonded in a 3-coordinate geometry to one Fe(1), one Fe(2), and one Fe(3) atom. S(1) is bonded in a distorted T-shaped geometry to one Fe(1), one Fe(2), and one Fe(3) atom. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(6) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(8) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(7) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one C(4) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one C(2) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one C(5) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one C(3) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one C(9) atom. is represented by the CIF card [CIF]
data_Fe3TeC9SO9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.107
_cell_length_b   9.910
_cell_length_c   14.847
_cell_angle_alpha   84.447
_cell_angle_beta   83.613
_cell_angle_gamma   65.874
_symmetry_Int_Tables_number   1
_cell_volume   1080.182
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Fe  Fe0  1  0.353  0.246  0.149  1.0
  Fe  Fe1  1  0.647  0.754  0.851  1.0
  Fe  Fe2  1  0.415  0.298  0.345  1.0
  Fe  Fe3  1  0.585  0.702  0.655  1.0
  Fe  Fe4  1  0.273  0.576  0.233  1.0
  Fe  Fe5  1  0.727  0.424  0.767  1.0
  Te  Te6  1  0.021  0.468  0.250  1.0
  Te  Te7  1  0.979  0.532  0.750  1.0
  C  C8  1  0.299  0.307  0.025  1.0
  C  C9  1  0.701  0.693  0.975  1.0
  C  C10  1  0.650  0.868  0.616  1.0
  C  C11  1  0.350  0.132  0.384  1.0
  C  C12  1  0.064  0.734  0.320  1.0
  C  C13  1  0.936  0.266  0.680  1.0
  C  C14  1  0.304  0.430  0.447  1.0
  C  C15  1  0.696  0.570  0.553  1.0
  C  C16  1  0.683  0.207  0.394  1.0
  C  C17  1  0.317  0.793  0.606  1.0
  C  C18  1  0.788  0.885  0.820  1.0
  C  C19  1  0.212  0.115  0.180  1.0
  C  C20  1  0.448  0.684  0.274  1.0
  C  C21  1  0.552  0.316  0.726  1.0
  C  C22  1  0.609  0.056  0.128  1.0
  C  C23  1  0.391  0.944  0.872  1.0
  C  C24  1  0.199  0.694  0.111  1.0
  C  C25  1  0.801  0.306  0.889  1.0
  S  S26  1  0.537  0.351  0.206  1.0
  S  S27  1  0.463  0.649  0.794  1.0
  O  O28  1  0.864  0.962  0.814  1.0
  O  O29  1  0.136  0.038  0.186  1.0
  O  O30  1  0.758  0.973  0.123  1.0
  O  O31  1  0.242  0.027  0.877  1.0
  O  O32  1  0.720  0.651  0.050  1.0
  O  O33  1  0.280  0.349  0.950  1.0
  O  O34  1  0.524  0.752  0.293  1.0
  O  O35  1  0.476  0.248  0.707  1.0
  O  O36  1  0.245  0.497  0.511  1.0
  O  O37  1  0.755  0.503  0.489  1.0
  O  O38  1  0.684  0.968  0.587  1.0
  O  O39  1  0.316  0.032  0.413  1.0
  O  O40  1  0.167  0.824  0.596  1.0
  O  O41  1  0.833  0.176  0.404  1.0
  O  O42  1  0.950  0.809  0.369  1.0
  O  O43  1  0.050  0.191  0.631  1.0
  O  O44  1  0.161  0.735  0.038  1.0
  O  O45  1  0.839  0.265  0.962  1.0
[/CIF]
.
The material structure described by Fe3C9TeSO9 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two Fe3C9TeSO9 clusters. There are three inequivalent Fe sites. In the first Fe site, Fe(1) is bonded in a 4-coordinate geometry to one C(1), one C(6), one C(8), one Te(1), and one S(1) atom. In the second Fe site, Fe(2) is bonded in a distorted trigonal pyramidal geometry to one C(2), one C(4), one C(5), one Te(1), and one S(1) atom. In the third Fe site, Fe(3) is bonded in a 5-coordinate geometry to one C(3), one C(7), one C(9), one Te(1), and one S(1) atom. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Fe(1) and one O(3) atom. In the second C site, C(2) is bonded in a linear geometry to one Fe(2) and one O(6) atom. In the third C site, C(3) is bonded in a linear geometry to one Fe(3) and one O(8) atom. In the fourth C site, C(4) is bonded in a linear geometry to one Fe(2) and one O(5) atom. In the fifth C site, C(5) is bonded in a distorted linear geometry to one Fe(2) and one O(7) atom. In the sixth C site, C(6) is bonded in a linear geometry to one Fe(1) and one O(1) atom. In the seventh C site, C(7) is bonded in a distorted linear geometry to one Fe(3) and one O(4) atom. In the eighth C site, C(8) is bonded in a distorted linear geometry to one Fe(1) and one O(2) atom. In the ninth C site, C(9) is bonded in a linear geometry to one Fe(3) and one O(9) atom. Te(1) is bonded in a 3-coordinate geometry to one Fe(1), one Fe(2), and one Fe(3) atom. S(1) is bonded in a distorted T-shaped geometry to one Fe(1), one Fe(2), and one Fe(3) atom. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(6) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(8) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(7) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one C(4) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one C(2) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one C(5) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one C(3) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one C(9) atom. is represented by the CIF card [CIF]
data_Fe3TeC9SO9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.107
_cell_length_b   9.910
_cell_length_c   14.847
_cell_angle_alpha   84.447
_cell_angle_beta   83.613
_cell_angle_gamma   65.874
_symmetry_Int_Tables_number   1
_cell_volume   1080.182
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Fe  Fe0  1  0.353  0.246  0.149  1.0
  Fe  Fe1  1  0.647  0.754  0.851  1.0
  Fe  Fe2  1  0.415  0.298  0.345  1.0
  Fe  Fe3  1  0.585  0.702  0.655  1.0
  Fe  Fe4  1  0.273  0.576  0.233  1.0
  Fe  Fe5  1  0.727  0.424  0.767  1.0
  Te  Te6  1  0.021  0.468  0.250  1.0
  Te  Te7  1  0.979  0.532  0.750  1.0
  C  C8  1  0.299  0.307  0.025  1.0
  C  C9  1  0.701  0.693  0.975  1.0
  C  C10  1  0.650  0.868  0.616  1.0
  C  C11  1  0.350  0.132  0.384  1.0
  C  C12  1  0.064  0.734  0.320  1.0
  C  C13  1  0.936  0.266  0.680  1.0
  C  C14  1  0.304  0.430  0.447  1.0
  C  C15  1  0.696  0.570  0.553  1.0
  C  C16  1  0.683  0.207  0.394  1.0
  C  C17  1  0.317  0.793  0.606  1.0
  C  C18  1  0.788  0.885  0.820  1.0
  C  C19  1  0.212  0.115  0.180  1.0
  C  C20  1  0.448  0.684  0.274  1.0
  C  C21  1  0.552  0.316  0.726  1.0
  C  C22  1  0.609  0.056  0.128  1.0
  C  C23  1  0.391  0.944  0.872  1.0
  C  C24  1  0.199  0.694  0.111  1.0
  C  C25  1  0.801  0.306  0.889  1.0
  S  S26  1  0.537  0.351  0.206  1.0
  S  S27  1  0.463  0.649  0.794  1.0
  O  O28  1  0.864  0.962  0.814  1.0
  O  O29  1  0.136  0.038  0.186  1.0
  O  O30  1  0.758  0.973  0.123  1.0
  O  O31  1  0.242  0.027  0.877  1.0
  O  O32  1  0.720  0.651  0.050  1.0
  O  O33  1  0.280  0.349  0.950  1.0
  O  O34  1  0.524  0.752  0.293  1.0
  O  O35  1  0.476  0.248  0.707  1.0
  O  O36  1  0.245  0.497  0.511  1.0
  O  O37  1  0.755  0.503  0.489  1.0
  O  O38  1  0.684  0.968  0.587  1.0
  O  O39  1  0.316  0.032  0.413  1.0
  O  O40  1  0.167  0.824  0.596  1.0
  O  O41  1  0.833  0.176  0.404  1.0
  O  O42  1  0.950  0.809  0.369  1.0
  O  O43  1  0.050  0.191  0.631  1.0
  O  O44  1  0.161  0.735  0.038  1.0
  O  O45  1  0.839  0.265  0.962  1.0
[/CIF]
.