The material described by KSbCl6 crystallizes in the monoclinic C2/c space group. K(1) is bonded in a 12-coordinate geometry to four equivalent Cl(1), four equivalent Cl(2), and four equivalent Cl(3) atoms. Sb(1) is bonded in an octahedral geometry to two equivalent Cl(1), two equivalent Cl(2), and two equivalent Cl(3) atoms. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted single-bond geometry to two equivalent K(1) and one Sb(1) atom. In the second Cl site, Cl(2) is bonded in a distorted single-bond geometry to two equivalent K(1) and one Sb(1) atom. In the third Cl site, Cl(3) is bonded in a distorted single-bond geometry to two equivalent K(1) and one Sb(1) atom. is represented by the CIF card [CIF]
data_KSbCl6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.801
_cell_length_b   6.801
_cell_length_c   11.947
_cell_angle_alpha   81.096
_cell_angle_beta   81.096
_cell_angle_gamma   55.608
_symmetry_Int_Tables_number   1
_cell_volume   448.970
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.918  0.082  0.750  1.0
  K  K1  1  0.082  0.918  0.250  1.0
  Sb  Sb2  1  0.500  0.000  0.500  1.0
  Sb  Sb3  1  0.000  0.500  0.000  1.0
  Cl  Cl4  1  0.467  0.693  0.612  1.0
  Cl  Cl5  1  0.533  0.307  0.388  1.0
  Cl  Cl6  1  0.307  0.533  0.888  1.0
  Cl  Cl7  1  0.693  0.467  0.112  1.0
  Cl  Cl8  1  0.388  0.206  0.667  1.0
  Cl  Cl9  1  0.612  0.794  0.333  1.0
  Cl  Cl10  1  0.794  0.612  0.833  1.0
  Cl  Cl11  1  0.206  0.388  0.167  1.0
  Cl  Cl12  1  0.793  0.912  0.034  1.0
  Cl  Cl13  1  0.207  0.088  0.966  1.0
  Cl  Cl14  1  0.088  0.207  0.466  1.0
  Cl  Cl15  1  0.912  0.793  0.534  1.0
[/CIF]
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The material described by KSbCl6 crystallizes in the monoclinic C2/c space group. K(1) is bonded in a 12-coordinate geometry to four equivalent Cl(1), four equivalent Cl(2), and four equivalent Cl(3) atoms. Sb(1) is bonded in an octahedral geometry to two equivalent Cl(1), two equivalent Cl(2), and two equivalent Cl(3) atoms. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted single-bond geometry to two equivalent K(1) and one Sb(1) atom. In the second Cl site, Cl(2) is bonded in a distorted single-bond geometry to two equivalent K(1) and one Sb(1) atom. In the third Cl site, Cl(3) is bonded in a distorted single-bond geometry to two equivalent K(1) and one Sb(1) atom. is represented by the CIF card [CIF]
data_KSbCl6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.801
_cell_length_b   6.801
_cell_length_c   11.947
_cell_angle_alpha   81.096
_cell_angle_beta   81.096
_cell_angle_gamma   55.608
_symmetry_Int_Tables_number   1
_cell_volume   448.970
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.918  0.082  0.750  1.0
  K  K1  1  0.082  0.918  0.250  1.0
  Sb  Sb2  1  0.500  0.000  0.500  1.0
  Sb  Sb3  1  0.000  0.500  0.000  1.0
  Cl  Cl4  1  0.467  0.693  0.612  1.0
  Cl  Cl5  1  0.533  0.307  0.388  1.0
  Cl  Cl6  1  0.307  0.533  0.888  1.0
  Cl  Cl7  1  0.693  0.467  0.112  1.0
  Cl  Cl8  1  0.388  0.206  0.667  1.0
  Cl  Cl9  1  0.612  0.794  0.333  1.0
  Cl  Cl10  1  0.794  0.612  0.833  1.0
  Cl  Cl11  1  0.206  0.388  0.167  1.0
  Cl  Cl12  1  0.793  0.912  0.034  1.0
  Cl  Cl13  1  0.207  0.088  0.966  1.0
  Cl  Cl14  1  0.088  0.207  0.466  1.0
  Cl  Cl15  1  0.912  0.793  0.534  1.0
[/CIF]
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