The compound described by La5NS4O2 crystallizes in the monoclinic C2/m space group. There are five inequivalent La sites. In the first La site, La(1) is bonded in a 4-coordinate geometry to three equivalent S(1), two equivalent O(1), and two equivalent O(2) atoms. In the second La site, La(2) is bonded in a 8-coordinate geometry to one S(1), two equivalent S(2), two equivalent S(3), one O(2), and two equivalent O(1) atoms. In the third La site, La(3) is bonded in a 7-coordinate geometry to one S(3), one S(4), two equivalent S(1), two equivalent S(2), and one O(2) atom. In the fourth La site, La(4) is bonded in a 6-coordinate geometry to two equivalent N(1), two equivalent S(3), and two equivalent S(4) atoms. In the fifth La site, La(5) is bonded in a 7-coordinate geometry to two equivalent N(1), one S(2), one S(3), and three equivalent S(4) atoms. N(1) is bonded to two equivalent La(4) and two equivalent La(5) atoms to form NLa4 tetrahedra that share corners with two equivalent S(3)La6 octahedra, corners with four equivalent S(4)La6 octahedra, corners with two equivalent N(1)La4 tetrahedra, edges with two equivalent S(3)La6 octahedra, edges with three equivalent S(4)La6 octahedra, and  an edgeedge with one N(1)La4 tetrahedra. The corner-sharing octahedral tilt angles range from 22-47°. There are four inequivalent S sites. In the first S site, S(1) is bonded to one La(2), two equivalent La(3), and three equivalent La(1) atoms to form SLa6 octahedra that share corners with two equivalent S(4)La6 octahedra, corners with three equivalent O(2)La4 tetrahedra, corners with four equivalent O(1)La4 tetrahedra, edges with two equivalent S(3)La6 octahedra, edges with four equivalent S(1)La6 octahedra, edges with two equivalent O(1)La4 tetrahedra, and edges with three equivalent O(2)La4 tetrahedra. The corner-sharing octahedral tilt angles are 51°. In the second S site, S(2) is bonded in a 5-coordinate geometry to one La(5), two equivalent La(2), and two equivalent La(3) atoms. In the third S site, S(3) is bonded to one La(3), one La(5), two equivalent La(2), and two equivalent La(4) atoms to form distorted SLa6 octahedra that share corners with five equivalent S(4)La6 octahedra, corners with two equivalent N(1)La4 tetrahedra, corners with two equivalent O(1)La4 tetrahedra, corners with three equivalent O(2)La4 tetrahedra, edges with two equivalent S(1)La6 octahedra, edges with two equivalent S(3)La6 octahedra,  an edgeedge with one O(1)La4 tetrahedra, edges with two equivalent N(1)La4 tetrahedra, and  a faceface with one S(4)La6 octahedra. The corner-sharing octahedral tilt angles range from 39-57°. In the fourth S site, S(4) is bonded to one La(3), two equivalent La(4), and three equivalent La(5) atoms to form SLa6 octahedra that share corners with two equivalent S(1)La6 octahedra, corners with five equivalent S(3)La6 octahedra,  a cornercorner with one O(2)La4 tetrahedra, corners with four equivalent N(1)La4 tetrahedra, edges with four equivalent S(4)La6 octahedra, edges with three equivalent N(1)La4 tetrahedra, and  a faceface with one S(3)La6 octahedra. The corner-sharing octahedral tilt angles range from 39-57°. There are two inequivalent O sites. In the first O site, O(1) is bonded to two equivalent La(1) and two equivalent La(2) atoms to form OLa4 tetrahedra that share corners with two equivalent S(3)La6 octahedra, corners with four equivalent S(1)La6 octahedra, corners with two equivalent O(1)La4 tetrahedra, corners with two equivalent O(2)La4 tetrahedra,  an edgeedge with one S(3)La6 octahedra, edges with two equivalent S(1)La6 octahedra,  an edgeedge with one O(1)La4 tetrahedra, and edges with two equivalent O(2)La4 tetrahedra. The corner-sharing octahedral tilt angles range from 26-51°. In the second O site, O(2) is bonded to one La(2), one La(3), and two equivalent La(1) atoms to form OLa4 tetrahedra that share  a cornercorner with one S(4)La6 octahedra, corners with three equivalent S(1)La6 octahedra, corners with three equivalent S(3)La6 octahedra, corners with two equivalent O(1)La4 tetrahedra, corners with two equivalent O(2)La4 tetrahedra, edges with three equivalent S(1)La6 octahedra, and edges with two equivalent O(1)La4 tetrahedra. The corner-sharing octahedral tilt angles range from 21-51°. is represented by the CIF file [CIF]
data_La5S4NO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.133
_cell_length_b   8.133
_cell_length_c   16.835
_cell_angle_alpha   79.275
_cell_angle_beta   79.275
_cell_angle_gamma   29.178
_symmetry_Int_Tables_number   1
_cell_volume   532.744
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.124  0.124  0.976  1.0
  La  La1  1  0.876  0.876  0.024  1.0
  La  La2  1  0.482  0.482  0.168  1.0
  La  La3  1  0.518  0.518  0.832  1.0
  La  La4  1  0.232  0.232  0.206  1.0
  La  La5  1  0.768  0.768  0.794  1.0
  La  La6  1  0.421  0.421  0.593  1.0
  La  La7  1  0.579  0.579  0.407  1.0
  La  La8  1  0.141  0.141  0.586  1.0
  La  La9  1  0.859  0.859  0.414  1.0
  S  S10  1  0.323  0.323  0.901  1.0
  S  S11  1  0.677  0.677  0.099  1.0
  S  S12  1  0.160  0.160  0.756  1.0
  S  S13  1  0.840  0.840  0.244  1.0
  S  S14  1  0.046  0.046  0.284  1.0
  S  S15  1  0.954  0.954  0.716  1.0
  S  S16  1  0.213  0.213  0.407  1.0
  S  S17  1  0.787  0.787  0.593  1.0
  N  N18  1  0.427  0.427  0.450  1.0
  N  N19  1  0.573  0.573  0.550  1.0
  O  O20  1  0.002  0.002  0.086  1.0
  O  O21  1  0.998  0.998  0.914  1.0
  O  O22  1  0.361  0.361  0.096  1.0
  O  O23  1  0.639  0.639  0.904  1.0
[/CIF]
.
The compound described by La5NS4O2 crystallizes in the monoclinic C2/m space group. There are five inequivalent La sites. In the first La site, La(1) is bonded in a 4-coordinate geometry to three equivalent S(1), two equivalent O(1), and two equivalent O(2) atoms. In the second La site, La(2) is bonded in a 8-coordinate geometry to one S(1), two equivalent S(2), two equivalent S(3), one O(2), and two equivalent O(1) atoms. In the third La site, La(3) is bonded in a 7-coordinate geometry to one S(3), one S(4), two equivalent S(1), two equivalent S(2), and one O(2) atom. In the fourth La site, La(4) is bonded in a 6-coordinate geometry to two equivalent N(1), two equivalent S(3), and two equivalent S(4) atoms. In the fifth La site, La(5) is bonded in a 7-coordinate geometry to two equivalent N(1), one S(2), one S(3), and three equivalent S(4) atoms. N(1) is bonded to two equivalent La(4) and two equivalent La(5) atoms to form NLa4 tetrahedra that share corners with two equivalent S(3)La6 octahedra, corners with four equivalent S(4)La6 octahedra, corners with two equivalent N(1)La4 tetrahedra, edges with two equivalent S(3)La6 octahedra, edges with three equivalent S(4)La6 octahedra, and  an edgeedge with one N(1)La4 tetrahedra. The corner-sharing octahedral tilt angles range from 22-47°. There are four inequivalent S sites. In the first S site, S(1) is bonded to one La(2), two equivalent La(3), and three equivalent La(1) atoms to form SLa6 octahedra that share corners with two equivalent S(4)La6 octahedra, corners with three equivalent O(2)La4 tetrahedra, corners with four equivalent O(1)La4 tetrahedra, edges with two equivalent S(3)La6 octahedra, edges with four equivalent S(1)La6 octahedra, edges with two equivalent O(1)La4 tetrahedra, and edges with three equivalent O(2)La4 tetrahedra. The corner-sharing octahedral tilt angles are 51°. In the second S site, S(2) is bonded in a 5-coordinate geometry to one La(5), two equivalent La(2), and two equivalent La(3) atoms. In the third S site, S(3) is bonded to one La(3), one La(5), two equivalent La(2), and two equivalent La(4) atoms to form distorted SLa6 octahedra that share corners with five equivalent S(4)La6 octahedra, corners with two equivalent N(1)La4 tetrahedra, corners with two equivalent O(1)La4 tetrahedra, corners with three equivalent O(2)La4 tetrahedra, edges with two equivalent S(1)La6 octahedra, edges with two equivalent S(3)La6 octahedra,  an edgeedge with one O(1)La4 tetrahedra, edges with two equivalent N(1)La4 tetrahedra, and  a faceface with one S(4)La6 octahedra. The corner-sharing octahedral tilt angles range from 39-57°. In the fourth S site, S(4) is bonded to one La(3), two equivalent La(4), and three equivalent La(5) atoms to form SLa6 octahedra that share corners with two equivalent S(1)La6 octahedra, corners with five equivalent S(3)La6 octahedra,  a cornercorner with one O(2)La4 tetrahedra, corners with four equivalent N(1)La4 tetrahedra, edges with four equivalent S(4)La6 octahedra, edges with three equivalent N(1)La4 tetrahedra, and  a faceface with one S(3)La6 octahedra. The corner-sharing octahedral tilt angles range from 39-57°. There are two inequivalent O sites. In the first O site, O(1) is bonded to two equivalent La(1) and two equivalent La(2) atoms to form OLa4 tetrahedra that share corners with two equivalent S(3)La6 octahedra, corners with four equivalent S(1)La6 octahedra, corners with two equivalent O(1)La4 tetrahedra, corners with two equivalent O(2)La4 tetrahedra,  an edgeedge with one S(3)La6 octahedra, edges with two equivalent S(1)La6 octahedra,  an edgeedge with one O(1)La4 tetrahedra, and edges with two equivalent O(2)La4 tetrahedra. The corner-sharing octahedral tilt angles range from 26-51°. In the second O site, O(2) is bonded to one La(2), one La(3), and two equivalent La(1) atoms to form OLa4 tetrahedra that share  a cornercorner with one S(4)La6 octahedra, corners with three equivalent S(1)La6 octahedra, corners with three equivalent S(3)La6 octahedra, corners with two equivalent O(1)La4 tetrahedra, corners with two equivalent O(2)La4 tetrahedra, edges with three equivalent S(1)La6 octahedra, and edges with two equivalent O(1)La4 tetrahedra. The corner-sharing octahedral tilt angles range from 21-51°. is represented by the CIF file [CIF]
data_La5S4NO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.133
_cell_length_b   8.133
_cell_length_c   16.835
_cell_angle_alpha   79.275
_cell_angle_beta   79.275
_cell_angle_gamma   29.178
_symmetry_Int_Tables_number   1
_cell_volume   532.744
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.124  0.124  0.976  1.0
  La  La1  1  0.876  0.876  0.024  1.0
  La  La2  1  0.482  0.482  0.168  1.0
  La  La3  1  0.518  0.518  0.832  1.0
  La  La4  1  0.232  0.232  0.206  1.0
  La  La5  1  0.768  0.768  0.794  1.0
  La  La6  1  0.421  0.421  0.593  1.0
  La  La7  1  0.579  0.579  0.407  1.0
  La  La8  1  0.141  0.141  0.586  1.0
  La  La9  1  0.859  0.859  0.414  1.0
  S  S10  1  0.323  0.323  0.901  1.0
  S  S11  1  0.677  0.677  0.099  1.0
  S  S12  1  0.160  0.160  0.756  1.0
  S  S13  1  0.840  0.840  0.244  1.0
  S  S14  1  0.046  0.046  0.284  1.0
  S  S15  1  0.954  0.954  0.716  1.0
  S  S16  1  0.213  0.213  0.407  1.0
  S  S17  1  0.787  0.787  0.593  1.0
  N  N18  1  0.427  0.427  0.450  1.0
  N  N19  1  0.573  0.573  0.550  1.0
  O  O20  1  0.002  0.002  0.086  1.0
  O  O21  1  0.998  0.998  0.914  1.0
  O  O22  1  0.361  0.361  0.096  1.0
  O  O23  1  0.639  0.639  0.904  1.0
[/CIF]
.