The material structure described by Pu4CeCo3 crystallizes in the orthorhombic Ibam space group. There are two inequivalent Pu sites. In the first Pu site, Pu(1) is bonded in a 2-coordinate geometry to one Pu(2) and four equivalent Co(2) atoms. In the second Pu site, Pu(2) is bonded in a 9-coordinate geometry to one Pu(1), two equivalent Ce(1), two equivalent Co(1), and four equivalent Co(2) atoms. Ce(1) is bonded in a 4-coordinate geometry to four equivalent Pu(2) and four equivalent Co(2) atoms. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded in a 4-coordinate geometry to four equivalent Pu(2) atoms. In the second Co site, Co(2) is bonded in a 10-coordinate geometry to four equivalent Pu(1), four equivalent Pu(2), and two equivalent Ce(1) atoms. is represented by the CIF file [CIF]
data_CePu4Co3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.927
_cell_length_b   7.927
_cell_length_c   7.927
_cell_angle_alpha   137.572
_cell_angle_beta   107.025
_cell_angle_gamma   88.228
_symmetry_Int_Tables_number   1
_cell_volume   307.764
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.500  0.750  0.250  1.0
  Ce  Ce1  1  0.500  0.250  0.750  1.0
  Pu  Pu2  1  0.676  0.770  0.906  1.0
  Pu  Pu3  1  0.134  0.920  0.214  1.0
  Pu  Pu4  1  0.866  0.080  0.786  1.0
  Pu  Pu5  1  0.324  0.230  0.094  1.0
  Pu  Pu6  1  0.294  0.580  0.714  1.0
  Pu  Pu7  1  0.706  0.420  0.286  1.0
  Pu  Pu8  1  0.864  0.270  0.594  1.0
  Pu  Pu9  1  0.136  0.730  0.406  1.0
  Co  Co10  1  0.000  0.250  0.250  1.0
  Co  Co11  1  0.000  0.750  0.750  1.0
  Co  Co12  1  0.175  0.333  0.842  1.0
  Co  Co13  1  0.492  0.833  0.658  1.0
  Co  Co14  1  0.508  0.167  0.342  1.0
  Co  Co15  1  0.825  0.667  0.158  1.0
[/CIF]
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The material structure described by Pu4CeCo3 crystallizes in the orthorhombic Ibam space group. There are two inequivalent Pu sites. In the first Pu site, Pu(1) is bonded in a 2-coordinate geometry to one Pu(2) and four equivalent Co(2) atoms. In the second Pu site, Pu(2) is bonded in a 9-coordinate geometry to one Pu(1), two equivalent Ce(1), two equivalent Co(1), and four equivalent Co(2) atoms. Ce(1) is bonded in a 4-coordinate geometry to four equivalent Pu(2) and four equivalent Co(2) atoms. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded in a 4-coordinate geometry to four equivalent Pu(2) atoms. In the second Co site, Co(2) is bonded in a 10-coordinate geometry to four equivalent Pu(1), four equivalent Pu(2), and two equivalent Ce(1) atoms. is represented by the CIF file [CIF]
data_CePu4Co3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.927
_cell_length_b   7.927
_cell_length_c   7.927
_cell_angle_alpha   137.572
_cell_angle_beta   107.025
_cell_angle_gamma   88.228
_symmetry_Int_Tables_number   1
_cell_volume   307.764
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.500  0.750  0.250  1.0
  Ce  Ce1  1  0.500  0.250  0.750  1.0
  Pu  Pu2  1  0.676  0.770  0.906  1.0
  Pu  Pu3  1  0.134  0.920  0.214  1.0
  Pu  Pu4  1  0.866  0.080  0.786  1.0
  Pu  Pu5  1  0.324  0.230  0.094  1.0
  Pu  Pu6  1  0.294  0.580  0.714  1.0
  Pu  Pu7  1  0.706  0.420  0.286  1.0
  Pu  Pu8  1  0.864  0.270  0.594  1.0
  Pu  Pu9  1  0.136  0.730  0.406  1.0
  Co  Co10  1  0.000  0.250  0.250  1.0
  Co  Co11  1  0.000  0.750  0.750  1.0
  Co  Co12  1  0.175  0.333  0.842  1.0
  Co  Co13  1  0.492  0.833  0.658  1.0
  Co  Co14  1  0.508  0.167  0.342  1.0
  Co  Co15  1  0.825  0.667  0.158  1.0
[/CIF]
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