The crystal structure described by LiCo(CO3)2 crystallizes in the monoclinic P2_1/c space group. Li(1) is bonded in a distorted see-saw-like geometry to one O(1), one O(4), one O(5), and one O(6) atom. Co(1) is bonded in a distorted trigonal bipyramidal geometry to one O(2), one O(3), one O(4), one O(5), and one O(6) atom. There are two inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one O(4), one O(5), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Li(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Co(1) and one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Co(1) and one C(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Li(1), one Co(1), and one C(2) atom. In the fifth O site, O(5) is bonded in a distorted trigonal non-coplanar geometry to one Li(1), one Co(1), and one C(2) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Li(1), one Co(1), and one C(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiCo(CO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.832
_cell_length_b   7.399
_cell_length_c   9.060
_cell_angle_alpha   58.035
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   559.208
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.389  0.658  0.837  1.0
  Li  Li1  1  0.111  0.658  0.337  1.0
  Li  Li2  1  0.889  0.342  0.663  1.0
  Li  Li3  1  0.611  0.342  0.163  1.0
  Co  Co4  1  0.860  0.505  0.933  1.0
  Co  Co5  1  0.360  0.495  0.567  1.0
  Co  Co6  1  0.640  0.505  0.433  1.0
  Co  Co7  1  0.140  0.495  0.067  1.0
  C  C8  1  0.010  0.897  0.859  1.0
  C  C9  1  0.490  0.897  0.359  1.0
  C  C10  1  0.616  0.475  0.775  1.0
  C  C11  1  0.116  0.525  0.725  1.0
  C  C12  1  0.884  0.475  0.275  1.0
  C  C13  1  0.384  0.525  0.225  1.0
  C  C14  1  0.510  0.103  0.641  1.0
  C  C15  1  0.990  0.103  0.141  1.0
  O  O16  1  0.503  0.905  0.718  1.0
  O  O17  1  0.906  0.785  0.856  1.0
  O  O18  1  0.119  0.794  0.947  1.0
  O  O19  1  0.997  0.905  0.218  1.0
  O  O20  1  0.594  0.785  0.356  1.0
  O  O21  1  0.381  0.794  0.447  1.0
  O  O22  1  0.665  0.481  0.908  1.0
  O  O23  1  0.986  0.518  0.740  1.0
  O  O24  1  0.200  0.537  0.828  1.0
  O  O25  1  0.700  0.463  0.672  1.0
  O  O26  1  0.486  0.482  0.760  1.0
  O  O27  1  0.165  0.519  0.592  1.0
  O  O28  1  0.835  0.481  0.408  1.0
  O  O29  1  0.514  0.518  0.240  1.0
  O  O30  1  0.300  0.537  0.328  1.0
  O  O31  1  0.800  0.463  0.172  1.0
  O  O32  1  0.014  0.482  0.260  1.0
  O  O33  1  0.335  0.519  0.092  1.0
  O  O34  1  0.619  0.206  0.553  1.0
  O  O35  1  0.406  0.215  0.644  1.0
  O  O36  1  0.003  0.095  0.782  1.0
  O  O37  1  0.881  0.206  0.053  1.0
  O  O38  1  0.094  0.215  0.144  1.0
  O  O39  1  0.497  0.095  0.282  1.0
[/CIF]
.
The crystal structure described by LiCo(CO3)2 crystallizes in the monoclinic P2_1/c space group. Li(1) is bonded in a distorted see-saw-like geometry to one O(1), one O(4), one O(5), and one O(6) atom. Co(1) is bonded in a distorted trigonal bipyramidal geometry to one O(2), one O(3), one O(4), one O(5), and one O(6) atom. There are two inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one O(4), one O(5), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Li(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Co(1) and one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Co(1) and one C(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Li(1), one Co(1), and one C(2) atom. In the fifth O site, O(5) is bonded in a distorted trigonal non-coplanar geometry to one Li(1), one Co(1), and one C(2) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Li(1), one Co(1), and one C(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiCo(CO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.832
_cell_length_b   7.399
_cell_length_c   9.060
_cell_angle_alpha   58.035
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   559.208
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.389  0.658  0.837  1.0
  Li  Li1  1  0.111  0.658  0.337  1.0
  Li  Li2  1  0.889  0.342  0.663  1.0
  Li  Li3  1  0.611  0.342  0.163  1.0
  Co  Co4  1  0.860  0.505  0.933  1.0
  Co  Co5  1  0.360  0.495  0.567  1.0
  Co  Co6  1  0.640  0.505  0.433  1.0
  Co  Co7  1  0.140  0.495  0.067  1.0
  C  C8  1  0.010  0.897  0.859  1.0
  C  C9  1  0.490  0.897  0.359  1.0
  C  C10  1  0.616  0.475  0.775  1.0
  C  C11  1  0.116  0.525  0.725  1.0
  C  C12  1  0.884  0.475  0.275  1.0
  C  C13  1  0.384  0.525  0.225  1.0
  C  C14  1  0.510  0.103  0.641  1.0
  C  C15  1  0.990  0.103  0.141  1.0
  O  O16  1  0.503  0.905  0.718  1.0
  O  O17  1  0.906  0.785  0.856  1.0
  O  O18  1  0.119  0.794  0.947  1.0
  O  O19  1  0.997  0.905  0.218  1.0
  O  O20  1  0.594  0.785  0.356  1.0
  O  O21  1  0.381  0.794  0.447  1.0
  O  O22  1  0.665  0.481  0.908  1.0
  O  O23  1  0.986  0.518  0.740  1.0
  O  O24  1  0.200  0.537  0.828  1.0
  O  O25  1  0.700  0.463  0.672  1.0
  O  O26  1  0.486  0.482  0.760  1.0
  O  O27  1  0.165  0.519  0.592  1.0
  O  O28  1  0.835  0.481  0.408  1.0
  O  O29  1  0.514  0.518  0.240  1.0
  O  O30  1  0.300  0.537  0.328  1.0
  O  O31  1  0.800  0.463  0.172  1.0
  O  O32  1  0.014  0.482  0.260  1.0
  O  O33  1  0.335  0.519  0.092  1.0
  O  O34  1  0.619  0.206  0.553  1.0
  O  O35  1  0.406  0.215  0.644  1.0
  O  O36  1  0.003  0.095  0.782  1.0
  O  O37  1  0.881  0.206  0.053  1.0
  O  O38  1  0.094  0.215  0.144  1.0
  O  O39  1  0.497  0.095  0.282  1.0
[/CIF]
.