The material structure described by Sr6Ca2Fe3Co5O24 is (Cubic) Perovskite-derived structured and crystallizes in the monoclinic P2 space group. There are three inequivalent Sr sites. In the first Sr site, Sr(1) is bonded to one O(1), one O(10), one O(13), one O(14), one O(15), one O(16), one O(2), one O(3), one O(4), one O(5), one O(6), and one O(9) atom to form SrO12 cuboctahedra that share corners with four equivalent Sr(1)O12 cuboctahedra, corners with eight equivalent Sr(3)O12 cuboctahedra, faces with two equivalent Ca(1)O12 cuboctahedra, faces with four equivalent Sr(2)O12 cuboctahedra,  a faceface with one Fe(1)O6 octahedra,  a faceface with one Fe(2)O6 octahedra,  a faceface with one Fe(3)O6 octahedra,  a faceface with one Co(1)O6 octahedra,  a faceface with one Co(2)O6 octahedra,  a faceface with one Co(3)O6 octahedra,  a faceface with one Co(4)O6 octahedra, and  a faceface with one Co(5)O6 octahedra. In the second Sr site, Sr(2) is bonded to one O(1), one O(10), one O(13), one O(14), one O(15), one O(16), one O(2), one O(3), one O(4), one O(5), one O(6), and one O(9) atom to form SrO12 cuboctahedra that share corners with four equivalent Sr(2)O12 cuboctahedra, corners with eight equivalent Ca(1)O12 cuboctahedra, faces with two equivalent Sr(3)O12 cuboctahedra, faces with four equivalent Sr(1)O12 cuboctahedra,  a faceface with one Fe(1)O6 octahedra,  a faceface with one Fe(2)O6 octahedra,  a faceface with one Fe(3)O6 octahedra,  a faceface with one Co(1)O6 octahedra,  a faceface with one Co(2)O6 octahedra,  a faceface with one Co(3)O6 octahedra,  a faceface with one Co(4)O6 octahedra, and  a faceface with one Co(5)O6 octahedra. In the third Sr site, Sr(3) is bonded to one O(1), one O(11), one O(12), one O(13), one O(14), one O(15), one O(16), one O(2), one O(3), one O(4), one O(7), and one O(8) atom to form SrO12 cuboctahedra that share corners with four equivalent Sr(3)O12 cuboctahedra, corners with eight equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Sr(2)O12 cuboctahedra, faces with four equivalent Ca(1)O12 cuboctahedra,  a faceface with one Fe(1)O6 octahedra,  a faceface with one Fe(2)O6 octahedra,  a faceface with one Fe(3)O6 octahedra,  a faceface with one Co(1)O6 octahedra,  a faceface with one Co(2)O6 octahedra,  a faceface with one Co(3)O6 octahedra,  a faceface with one Co(4)O6 octahedra, and  a faceface with one Co(5)O6 octahedra. Ca(1) is bonded to one O(1), one O(11), one O(12), one O(13), one O(14), one O(15), one O(16), one O(2), one O(3), one O(4), one O(7), and one O(8) atom to form CaO12 cuboctahedra that share corners with four equivalent Ca(1)O12 cuboctahedra, corners with eight equivalent Sr(2)O12 cuboctahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with four equivalent Sr(3)O12 cuboctahedra,  a faceface with one Fe(1)O6 octahedra,  a faceface with one Fe(2)O6 octahedra,  a faceface with one Fe(3)O6 octahedra,  a faceface with one Co(1)O6 octahedra,  a faceface with one Co(2)O6 octahedra,  a faceface with one Co(3)O6 octahedra,  a faceface with one Co(4)O6 octahedra, and  a faceface with one Co(5)O6 octahedra. There are three inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to one O(5), one O(7), two equivalent O(1), and two equivalent O(13) atoms to form FeO6 octahedra that share corners with two equivalent Fe(2)O6 octahedra, corners with two equivalent Fe(3)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Sr(2)O12 cuboctahedra, faces with two equivalent Sr(3)O12 cuboctahedra, and faces with two equivalent Ca(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the second Fe site, Fe(2) is bonded to one O(6), one O(8), two equivalent O(13), and two equivalent O(2) atoms to form FeO6 octahedra that share corners with two equivalent Fe(1)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Co(3)O6 octahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Sr(2)O12 cuboctahedra, faces with two equivalent Sr(3)O12 cuboctahedra, and faces with two equivalent Ca(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the third Fe site, Fe(3) is bonded to one O(5), one O(7), two equivalent O(14), and two equivalent O(3) atoms to form FeO6 octahedra that share corners with two equivalent Fe(1)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Co(4)O6 octahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Sr(2)O12 cuboctahedra, faces with two equivalent Sr(3)O12 cuboctahedra, and faces with two equivalent Ca(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. There are five inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(6), one O(8), two equivalent O(14), and two equivalent O(4) atoms to form CoO6 octahedra that share corners with two equivalent Fe(2)O6 octahedra, corners with two equivalent Fe(3)O6 octahedra, corners with two equivalent Co(5)O6 octahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Sr(2)O12 cuboctahedra, faces with two equivalent Sr(3)O12 cuboctahedra, and faces with two equivalent Ca(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the second Co site, Co(2) is bonded to one O(11), one O(9), two equivalent O(1), and two equivalent O(15) atoms to form CoO6 octahedra that share corners with two equivalent Fe(1)O6 octahedra, corners with two equivalent Co(3)O6 octahedra, corners with two equivalent Co(4)O6 octahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Sr(2)O12 cuboctahedra, faces with two equivalent Sr(3)O12 cuboctahedra, and faces with two equivalent Ca(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the third Co site, Co(3) is bonded to one O(10), one O(12), two equivalent O(15), and two equivalent O(2) atoms to form CoO6 octahedra that share corners with two equivalent Fe(2)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Co(5)O6 octahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Sr(2)O12 cuboctahedra, faces with two equivalent Sr(3)O12 cuboctahedra, and faces with two equivalent Ca(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the fourth Co site, Co(4) is bonded to one O(11), one O(9), two equivalent O(16), and two equivalent O(3) atoms to form CoO6 octahedra that share corners with two equivalent Fe(3)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Co(5)O6 octahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Sr(2)O12 cuboctahedra, faces with two equivalent Sr(3)O12 cuboctahedra, and faces with two equivalent Ca(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the fifth Co site, Co(5) is bonded to one O(10), one O(12), two equivalent O(16), and two equivalent O(4) atoms to form CoO6 octahedra that share corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Co(3)O6 octahedra, corners with two equivalent Co(4)O6 octahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Sr(2)O12 cuboctahedra, faces with two equivalent Sr(3)O12 cuboctahedra, and faces with two equivalent Ca(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to one Sr(1), one Sr(2), one Sr(3), one Ca(1), one Fe(1), and one Co(2) atom. In the second O site, O(2) is bonded in a distorted linear geometry to one Sr(1), one Sr(2), one Sr(3), one Ca(1), one Fe(2), and one Co(3) atom. In the third O site, O(3) is bonded in a distorted linear geometry to one Sr(1), one Sr(2), one Sr(3), one Ca(1), one Fe(3), and one Co(4) atom. In the fourth O site, O(4) is bonded in a distorted linear geometry to one Sr(1), one Sr(2), one Sr(3), one Ca(1), one Co(1), and one Co(5) atom. In the fifth O site, O(5) is bonded to two equivalent Sr(1), two equivalent Sr(2), one Fe(1), and one Fe(3) atom to form distorted OSr4Fe2 octahedra that share corners with four equivalent O(15)Sr3CaCo2 octahedra, corners with four equivalent O(16)Sr3CaCo2 octahedra, corners with four equivalent O(10)Sr4Co2 octahedra, edges with two equivalent O(9)Sr4Co2 octahedra, edges with two equivalent O(6)Sr4FeCo octahedra, and faces with two equivalent O(13)Sr3CaFe2 octahedra. The corner-sharing octahedral tilt angles range from 2-62°. In the sixth O site, O(6) is bonded to two equivalent Sr(1), two equivalent Sr(2), one Fe(2), and one Co(1) atom to form distorted OSr4FeCo octahedra that share corners with four equivalent O(15)Sr3CaCo2 octahedra, corners with four equivalent O(16)Sr3CaCo2 octahedra, corners with four equivalent O(9)Sr4Co2 octahedra, edges with two equivalent O(10)Sr4Co2 octahedra, edges with two equivalent O(5)Sr4Fe2 octahedra, and faces with two equivalent O(13)Sr3CaFe2 octahedra. The corner-sharing octahedral tilt angles range from 1-60°. In the seventh O site, O(7) is bonded in a distorted linear geometry to two equivalent Sr(3), two equivalent Ca(1), one Fe(1), and one Fe(3) atom. In the eighth O site, O(8) is bonded in a distorted linear geometry to two equivalent Sr(3), two equivalent Ca(1), one Fe(2), and one Co(1) atom. In the ninth O site, O(9) is bonded to two equivalent Sr(1), two equivalent Sr(2), one Co(2), and one Co(4) atom to form distorted OSr4Co2 octahedra that share corners with two equivalent O(11)Sr2Ca2Co2 octahedra, corners with four equivalent O(13)Sr3CaFe2 octahedra, corners with four equivalent O(6)Sr4FeCo octahedra, edges with two equivalent O(10)Sr4Co2 octahedra, edges with two equivalent O(5)Sr4Fe2 octahedra, faces with two equivalent O(15)Sr3CaCo2 octahedra, and faces with two equivalent O(16)Sr3CaCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-61°. In the tenth O site, O(10) is bonded to two equivalent Sr(1), two equivalent Sr(2), one Co(3), and one Co(5) atom to form distorted OSr4Co2 octahedra that share corners with two equivalent O(12)Sr2Ca2Co2 octahedra, corners with four equivalent O(13)Sr3CaFe2 octahedra, corners with four equivalent O(5)Sr4Fe2 octahedra, edges with two equivalent O(9)Sr4Co2 octahedra, edges with two equivalent O(6)Sr4FeCo octahedra, faces with two equivalent O(15)Sr3CaCo2 octahedra, and faces with two equivalent O(16)Sr3CaCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-62°. In the eleventh O site, O(11) is bonded to two equivalent Sr(3), two equivalent Ca(1), one Co(2), and one Co(4) atom to form distorted OSr2Ca2Co2 octahedra that share corners with two equivalent O(9)Sr4Co2 octahedra, corners with four equivalent O(13)Sr3CaFe2 octahedra, edges with two equivalent O(12)Sr2Ca2Co2 octahedra, faces with two equivalent O(15)Sr3CaCo2 octahedra, and faces with two equivalent O(16)Sr3CaCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-60°. In the twelfth O site, O(12) is bonded to two equivalent Sr(3), two equivalent Ca(1), one Co(3), and one Co(5) atom to form distorted OSr2Ca2Co2 octahedra that share corners with two equivalent O(10)Sr4Co2 octahedra, corners with four equivalent O(13)Sr3CaFe2 octahedra, edges with two equivalent O(11)Sr2Ca2Co2 octahedra, faces with two equivalent O(15)Sr3CaCo2 octahedra, and faces with two equivalent O(16)Sr3CaCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-61°. In the thirteenth O site, O(13) is bonded to one Sr(1), one Sr(2), one Sr(3), one Ca(1), one Fe(1), and one Fe(2) atom to form distorted OSr3CaFe2 octahedra that share corners with two equivalent O(11)Sr2Ca2Co2 octahedra, corners with two equivalent O(12)Sr2Ca2Co2 octahedra, corners with two equivalent O(13)Sr3CaFe2 octahedra, corners with two equivalent O(10)Sr4Co2 octahedra, corners with two equivalent O(9)Sr4Co2 octahedra, corners with four equivalent O(16)Sr3CaCo2 octahedra, edges with two equivalent O(15)Sr3CaCo2 octahedra,  a faceface with one O(5)Sr4Fe2 octahedra, and  a faceface with one O(6)Sr4FeCo octahedra. The corner-sharing octahedral tilt angles range from 1-62°. In the fourteenth O site, O(14) is bonded in a distorted linear geometry to one Sr(1), one Sr(2), one Sr(3), one Ca(1), one Fe(3), and one Co(1) atom. In the fifteenth O site, O(15) is bonded to one Sr(1), one Sr(2), one Sr(3), one Ca(1), one Co(2), and one Co(3) atom to form distorted OSr3CaCo2 octahedra that share corners with two equivalent O(15)Sr3CaCo2 octahedra, corners with two equivalent O(5)Sr4Fe2 octahedra, corners with two equivalent O(6)Sr4FeCo octahedra, edges with two equivalent O(16)Sr3CaCo2 octahedra, edges with two equivalent O(13)Sr3CaFe2 octahedra,  a faceface with one O(11)Sr2Ca2Co2 octahedra,  a faceface with one O(12)Sr2Ca2Co2 octahedra,  a faceface with one O(10)Sr4Co2 octahedra, and  a faceface with one O(9)Sr4Co2 octahedra. The corner-sharing octahedral tilt angles range from 1-61°. In the sixteenth O site, O(16) is bonded to one Sr(1), one Sr(2), one Sr(3), one Ca(1), one Co(4), and one Co(5) atom to form distorted OSr3CaCo2 octahedra that share corners with two equivalent O(16)Sr3CaCo2 octahedra, corners with two equivalent O(5)Sr4Fe2 octahedra, corners with two equivalent O(6)Sr4FeCo octahedra, corners with four equivalent O(13)Sr3CaFe2 octahedra, edges with two equivalent O(15)Sr3CaCo2 octahedra,  a faceface with one O(11)Sr2Ca2Co2 octahedra,  a faceface with one O(12)Sr2Ca2Co2 octahedra,  a faceface with one O(10)Sr4Co2 octahedra, and  a faceface with one O(9)Sr4Co2 octahedra. The corner-sharing octahedral tilt angles range from 1-62°. is represented by the CIF file [CIF]
data_Sr6Ca2Fe3Co5O24
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.746
_cell_length_b   7.690
_cell_length_c   7.756
_cell_angle_alpha   89.975
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   462.048
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.250  0.747  0.750  1.0
  Sr  Sr1  1  0.250  0.747  0.249  1.0
  Sr  Sr2  1  0.750  0.747  0.249  1.0
  Sr  Sr3  1  0.250  0.253  0.751  1.0
  Sr  Sr4  1  0.250  0.253  0.250  1.0
  Sr  Sr5  1  0.750  0.253  0.751  1.0
  Ca  Ca6  1  0.751  0.747  0.751  1.0
  Ca  Ca7  1  0.751  0.253  0.249  1.0
  Fe  Fe8  1  0.999  0.000  0.000  1.0
  Fe  Fe9  1  0.998  0.000  0.500  1.0
  Fe  Fe10  1  0.501  0.000  0.000  1.0
  Co  Co11  1  0.501  0.000  0.500  1.0
  Co  Co12  1  0.999  0.500  0.000  1.0
  Co  Co13  1  0.999  0.500  0.500  1.0
  Co  Co14  1  0.502  0.500  0.000  1.0
  Co  Co15  1  0.502  0.500  0.500  1.0
  O  O16  1  0.997  0.739  0.998  1.0
  O  O17  1  0.997  0.748  0.502  1.0
  O  O18  1  0.503  0.748  0.998  1.0
  O  O19  1  0.503  0.739  0.502  1.0
  O  O20  1  0.997  0.261  0.002  1.0
  O  O21  1  0.997  0.252  0.498  1.0
  O  O22  1  0.503  0.252  0.002  1.0
  O  O23  1  0.503  0.261  0.498  1.0
  O  O24  1  0.248  0.000  0.000  1.0
  O  O25  1  0.257  0.000  0.500  1.0
  O  O26  1  0.752  0.000  0.000  1.0
  O  O27  1  0.743  0.000  0.500  1.0
  O  O28  1  0.251  0.500  0.000  1.0
  O  O29  1  0.238  0.500  0.500  1.0
  O  O30  1  0.749  0.500  0.000  1.0
  O  O31  1  0.761  0.500  0.500  1.0
  O  O32  1  0.997  0.998  0.752  1.0
  O  O33  1  0.997  0.002  0.248  1.0
  O  O34  1  0.503  0.997  0.743  1.0
  O  O35  1  0.503  0.003  0.257  1.0
  O  O36  1  0.996  0.503  0.749  1.0
  O  O37  1  0.996  0.497  0.251  1.0
  O  O38  1  0.503  0.502  0.761  1.0
  O  O39  1  0.503  0.498  0.239  1.0
[/CIF]
.
The material structure described by Sr6Ca2Fe3Co5O24 is (Cubic) Perovskite-derived structured and crystallizes in the monoclinic P2 space group. There are three inequivalent Sr sites. In the first Sr site, Sr(1) is bonded to one O(1), one O(10), one O(13), one O(14), one O(15), one O(16), one O(2), one O(3), one O(4), one O(5), one O(6), and one O(9) atom to form SrO12 cuboctahedra that share corners with four equivalent Sr(1)O12 cuboctahedra, corners with eight equivalent Sr(3)O12 cuboctahedra, faces with two equivalent Ca(1)O12 cuboctahedra, faces with four equivalent Sr(2)O12 cuboctahedra,  a faceface with one Fe(1)O6 octahedra,  a faceface with one Fe(2)O6 octahedra,  a faceface with one Fe(3)O6 octahedra,  a faceface with one Co(1)O6 octahedra,  a faceface with one Co(2)O6 octahedra,  a faceface with one Co(3)O6 octahedra,  a faceface with one Co(4)O6 octahedra, and  a faceface with one Co(5)O6 octahedra. In the second Sr site, Sr(2) is bonded to one O(1), one O(10), one O(13), one O(14), one O(15), one O(16), one O(2), one O(3), one O(4), one O(5), one O(6), and one O(9) atom to form SrO12 cuboctahedra that share corners with four equivalent Sr(2)O12 cuboctahedra, corners with eight equivalent Ca(1)O12 cuboctahedra, faces with two equivalent Sr(3)O12 cuboctahedra, faces with four equivalent Sr(1)O12 cuboctahedra,  a faceface with one Fe(1)O6 octahedra,  a faceface with one Fe(2)O6 octahedra,  a faceface with one Fe(3)O6 octahedra,  a faceface with one Co(1)O6 octahedra,  a faceface with one Co(2)O6 octahedra,  a faceface with one Co(3)O6 octahedra,  a faceface with one Co(4)O6 octahedra, and  a faceface with one Co(5)O6 octahedra. In the third Sr site, Sr(3) is bonded to one O(1), one O(11), one O(12), one O(13), one O(14), one O(15), one O(16), one O(2), one O(3), one O(4), one O(7), and one O(8) atom to form SrO12 cuboctahedra that share corners with four equivalent Sr(3)O12 cuboctahedra, corners with eight equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Sr(2)O12 cuboctahedra, faces with four equivalent Ca(1)O12 cuboctahedra,  a faceface with one Fe(1)O6 octahedra,  a faceface with one Fe(2)O6 octahedra,  a faceface with one Fe(3)O6 octahedra,  a faceface with one Co(1)O6 octahedra,  a faceface with one Co(2)O6 octahedra,  a faceface with one Co(3)O6 octahedra,  a faceface with one Co(4)O6 octahedra, and  a faceface with one Co(5)O6 octahedra. Ca(1) is bonded to one O(1), one O(11), one O(12), one O(13), one O(14), one O(15), one O(16), one O(2), one O(3), one O(4), one O(7), and one O(8) atom to form CaO12 cuboctahedra that share corners with four equivalent Ca(1)O12 cuboctahedra, corners with eight equivalent Sr(2)O12 cuboctahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with four equivalent Sr(3)O12 cuboctahedra,  a faceface with one Fe(1)O6 octahedra,  a faceface with one Fe(2)O6 octahedra,  a faceface with one Fe(3)O6 octahedra,  a faceface with one Co(1)O6 octahedra,  a faceface with one Co(2)O6 octahedra,  a faceface with one Co(3)O6 octahedra,  a faceface with one Co(4)O6 octahedra, and  a faceface with one Co(5)O6 octahedra. There are three inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to one O(5), one O(7), two equivalent O(1), and two equivalent O(13) atoms to form FeO6 octahedra that share corners with two equivalent Fe(2)O6 octahedra, corners with two equivalent Fe(3)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Sr(2)O12 cuboctahedra, faces with two equivalent Sr(3)O12 cuboctahedra, and faces with two equivalent Ca(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the second Fe site, Fe(2) is bonded to one O(6), one O(8), two equivalent O(13), and two equivalent O(2) atoms to form FeO6 octahedra that share corners with two equivalent Fe(1)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Co(3)O6 octahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Sr(2)O12 cuboctahedra, faces with two equivalent Sr(3)O12 cuboctahedra, and faces with two equivalent Ca(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the third Fe site, Fe(3) is bonded to one O(5), one O(7), two equivalent O(14), and two equivalent O(3) atoms to form FeO6 octahedra that share corners with two equivalent Fe(1)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Co(4)O6 octahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Sr(2)O12 cuboctahedra, faces with two equivalent Sr(3)O12 cuboctahedra, and faces with two equivalent Ca(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. There are five inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(6), one O(8), two equivalent O(14), and two equivalent O(4) atoms to form CoO6 octahedra that share corners with two equivalent Fe(2)O6 octahedra, corners with two equivalent Fe(3)O6 octahedra, corners with two equivalent Co(5)O6 octahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Sr(2)O12 cuboctahedra, faces with two equivalent Sr(3)O12 cuboctahedra, and faces with two equivalent Ca(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the second Co site, Co(2) is bonded to one O(11), one O(9), two equivalent O(1), and two equivalent O(15) atoms to form CoO6 octahedra that share corners with two equivalent Fe(1)O6 octahedra, corners with two equivalent Co(3)O6 octahedra, corners with two equivalent Co(4)O6 octahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Sr(2)O12 cuboctahedra, faces with two equivalent Sr(3)O12 cuboctahedra, and faces with two equivalent Ca(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the third Co site, Co(3) is bonded to one O(10), one O(12), two equivalent O(15), and two equivalent O(2) atoms to form CoO6 octahedra that share corners with two equivalent Fe(2)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Co(5)O6 octahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Sr(2)O12 cuboctahedra, faces with two equivalent Sr(3)O12 cuboctahedra, and faces with two equivalent Ca(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the fourth Co site, Co(4) is bonded to one O(11), one O(9), two equivalent O(16), and two equivalent O(3) atoms to form CoO6 octahedra that share corners with two equivalent Fe(3)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Co(5)O6 octahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Sr(2)O12 cuboctahedra, faces with two equivalent Sr(3)O12 cuboctahedra, and faces with two equivalent Ca(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the fifth Co site, Co(5) is bonded to one O(10), one O(12), two equivalent O(16), and two equivalent O(4) atoms to form CoO6 octahedra that share corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Co(3)O6 octahedra, corners with two equivalent Co(4)O6 octahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Sr(2)O12 cuboctahedra, faces with two equivalent Sr(3)O12 cuboctahedra, and faces with two equivalent Ca(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to one Sr(1), one Sr(2), one Sr(3), one Ca(1), one Fe(1), and one Co(2) atom. In the second O site, O(2) is bonded in a distorted linear geometry to one Sr(1), one Sr(2), one Sr(3), one Ca(1), one Fe(2), and one Co(3) atom. In the third O site, O(3) is bonded in a distorted linear geometry to one Sr(1), one Sr(2), one Sr(3), one Ca(1), one Fe(3), and one Co(4) atom. In the fourth O site, O(4) is bonded in a distorted linear geometry to one Sr(1), one Sr(2), one Sr(3), one Ca(1), one Co(1), and one Co(5) atom. In the fifth O site, O(5) is bonded to two equivalent Sr(1), two equivalent Sr(2), one Fe(1), and one Fe(3) atom to form distorted OSr4Fe2 octahedra that share corners with four equivalent O(15)Sr3CaCo2 octahedra, corners with four equivalent O(16)Sr3CaCo2 octahedra, corners with four equivalent O(10)Sr4Co2 octahedra, edges with two equivalent O(9)Sr4Co2 octahedra, edges with two equivalent O(6)Sr4FeCo octahedra, and faces with two equivalent O(13)Sr3CaFe2 octahedra. The corner-sharing octahedral tilt angles range from 2-62°. In the sixth O site, O(6) is bonded to two equivalent Sr(1), two equivalent Sr(2), one Fe(2), and one Co(1) atom to form distorted OSr4FeCo octahedra that share corners with four equivalent O(15)Sr3CaCo2 octahedra, corners with four equivalent O(16)Sr3CaCo2 octahedra, corners with four equivalent O(9)Sr4Co2 octahedra, edges with two equivalent O(10)Sr4Co2 octahedra, edges with two equivalent O(5)Sr4Fe2 octahedra, and faces with two equivalent O(13)Sr3CaFe2 octahedra. The corner-sharing octahedral tilt angles range from 1-60°. In the seventh O site, O(7) is bonded in a distorted linear geometry to two equivalent Sr(3), two equivalent Ca(1), one Fe(1), and one Fe(3) atom. In the eighth O site, O(8) is bonded in a distorted linear geometry to two equivalent Sr(3), two equivalent Ca(1), one Fe(2), and one Co(1) atom. In the ninth O site, O(9) is bonded to two equivalent Sr(1), two equivalent Sr(2), one Co(2), and one Co(4) atom to form distorted OSr4Co2 octahedra that share corners with two equivalent O(11)Sr2Ca2Co2 octahedra, corners with four equivalent O(13)Sr3CaFe2 octahedra, corners with four equivalent O(6)Sr4FeCo octahedra, edges with two equivalent O(10)Sr4Co2 octahedra, edges with two equivalent O(5)Sr4Fe2 octahedra, faces with two equivalent O(15)Sr3CaCo2 octahedra, and faces with two equivalent O(16)Sr3CaCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-61°. In the tenth O site, O(10) is bonded to two equivalent Sr(1), two equivalent Sr(2), one Co(3), and one Co(5) atom to form distorted OSr4Co2 octahedra that share corners with two equivalent O(12)Sr2Ca2Co2 octahedra, corners with four equivalent O(13)Sr3CaFe2 octahedra, corners with four equivalent O(5)Sr4Fe2 octahedra, edges with two equivalent O(9)Sr4Co2 octahedra, edges with two equivalent O(6)Sr4FeCo octahedra, faces with two equivalent O(15)Sr3CaCo2 octahedra, and faces with two equivalent O(16)Sr3CaCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-62°. In the eleventh O site, O(11) is bonded to two equivalent Sr(3), two equivalent Ca(1), one Co(2), and one Co(4) atom to form distorted OSr2Ca2Co2 octahedra that share corners with two equivalent O(9)Sr4Co2 octahedra, corners with four equivalent O(13)Sr3CaFe2 octahedra, edges with two equivalent O(12)Sr2Ca2Co2 octahedra, faces with two equivalent O(15)Sr3CaCo2 octahedra, and faces with two equivalent O(16)Sr3CaCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-60°. In the twelfth O site, O(12) is bonded to two equivalent Sr(3), two equivalent Ca(1), one Co(3), and one Co(5) atom to form distorted OSr2Ca2Co2 octahedra that share corners with two equivalent O(10)Sr4Co2 octahedra, corners with four equivalent O(13)Sr3CaFe2 octahedra, edges with two equivalent O(11)Sr2Ca2Co2 octahedra, faces with two equivalent O(15)Sr3CaCo2 octahedra, and faces with two equivalent O(16)Sr3CaCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-61°. In the thirteenth O site, O(13) is bonded to one Sr(1), one Sr(2), one Sr(3), one Ca(1), one Fe(1), and one Fe(2) atom to form distorted OSr3CaFe2 octahedra that share corners with two equivalent O(11)Sr2Ca2Co2 octahedra, corners with two equivalent O(12)Sr2Ca2Co2 octahedra, corners with two equivalent O(13)Sr3CaFe2 octahedra, corners with two equivalent O(10)Sr4Co2 octahedra, corners with two equivalent O(9)Sr4Co2 octahedra, corners with four equivalent O(16)Sr3CaCo2 octahedra, edges with two equivalent O(15)Sr3CaCo2 octahedra,  a faceface with one O(5)Sr4Fe2 octahedra, and  a faceface with one O(6)Sr4FeCo octahedra. The corner-sharing octahedral tilt angles range from 1-62°. In the fourteenth O site, O(14) is bonded in a distorted linear geometry to one Sr(1), one Sr(2), one Sr(3), one Ca(1), one Fe(3), and one Co(1) atom. In the fifteenth O site, O(15) is bonded to one Sr(1), one Sr(2), one Sr(3), one Ca(1), one Co(2), and one Co(3) atom to form distorted OSr3CaCo2 octahedra that share corners with two equivalent O(15)Sr3CaCo2 octahedra, corners with two equivalent O(5)Sr4Fe2 octahedra, corners with two equivalent O(6)Sr4FeCo octahedra, edges with two equivalent O(16)Sr3CaCo2 octahedra, edges with two equivalent O(13)Sr3CaFe2 octahedra,  a faceface with one O(11)Sr2Ca2Co2 octahedra,  a faceface with one O(12)Sr2Ca2Co2 octahedra,  a faceface with one O(10)Sr4Co2 octahedra, and  a faceface with one O(9)Sr4Co2 octahedra. The corner-sharing octahedral tilt angles range from 1-61°. In the sixteenth O site, O(16) is bonded to one Sr(1), one Sr(2), one Sr(3), one Ca(1), one Co(4), and one Co(5) atom to form distorted OSr3CaCo2 octahedra that share corners with two equivalent O(16)Sr3CaCo2 octahedra, corners with two equivalent O(5)Sr4Fe2 octahedra, corners with two equivalent O(6)Sr4FeCo octahedra, corners with four equivalent O(13)Sr3CaFe2 octahedra, edges with two equivalent O(15)Sr3CaCo2 octahedra,  a faceface with one O(11)Sr2Ca2Co2 octahedra,  a faceface with one O(12)Sr2Ca2Co2 octahedra,  a faceface with one O(10)Sr4Co2 octahedra, and  a faceface with one O(9)Sr4Co2 octahedra. The corner-sharing octahedral tilt angles range from 1-62°. is represented by the CIF file [CIF]
data_Sr6Ca2Fe3Co5O24
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.746
_cell_length_b   7.690
_cell_length_c   7.756
_cell_angle_alpha   89.975
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   462.048
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.250  0.747  0.750  1.0
  Sr  Sr1  1  0.250  0.747  0.249  1.0
  Sr  Sr2  1  0.750  0.747  0.249  1.0
  Sr  Sr3  1  0.250  0.253  0.751  1.0
  Sr  Sr4  1  0.250  0.253  0.250  1.0
  Sr  Sr5  1  0.750  0.253  0.751  1.0
  Ca  Ca6  1  0.751  0.747  0.751  1.0
  Ca  Ca7  1  0.751  0.253  0.249  1.0
  Fe  Fe8  1  0.999  0.000  0.000  1.0
  Fe  Fe9  1  0.998  0.000  0.500  1.0
  Fe  Fe10  1  0.501  0.000  0.000  1.0
  Co  Co11  1  0.501  0.000  0.500  1.0
  Co  Co12  1  0.999  0.500  0.000  1.0
  Co  Co13  1  0.999  0.500  0.500  1.0
  Co  Co14  1  0.502  0.500  0.000  1.0
  Co  Co15  1  0.502  0.500  0.500  1.0
  O  O16  1  0.997  0.739  0.998  1.0
  O  O17  1  0.997  0.748  0.502  1.0
  O  O18  1  0.503  0.748  0.998  1.0
  O  O19  1  0.503  0.739  0.502  1.0
  O  O20  1  0.997  0.261  0.002  1.0
  O  O21  1  0.997  0.252  0.498  1.0
  O  O22  1  0.503  0.252  0.002  1.0
  O  O23  1  0.503  0.261  0.498  1.0
  O  O24  1  0.248  0.000  0.000  1.0
  O  O25  1  0.257  0.000  0.500  1.0
  O  O26  1  0.752  0.000  0.000  1.0
  O  O27  1  0.743  0.000  0.500  1.0
  O  O28  1  0.251  0.500  0.000  1.0
  O  O29  1  0.238  0.500  0.500  1.0
  O  O30  1  0.749  0.500  0.000  1.0
  O  O31  1  0.761  0.500  0.500  1.0
  O  O32  1  0.997  0.998  0.752  1.0
  O  O33  1  0.997  0.002  0.248  1.0
  O  O34  1  0.503  0.997  0.743  1.0
  O  O35  1  0.503  0.003  0.257  1.0
  O  O36  1  0.996  0.503  0.749  1.0
  O  O37  1  0.996  0.497  0.251  1.0
  O  O38  1  0.503  0.502  0.761  1.0
  O  O39  1  0.503  0.498  0.239  1.0
[/CIF]
.