The crystal structure described by Cu(H2O)6CuH4(SO6)2(H2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 1333-74-0 molecules, one copper hexahydrate molecule, and one CuH4(SO6)2 cluster. In the CuH4(SO6)2 cluster, Cu(2) is bonded in a square co-planar geometry to two equivalent O(8) and two equivalent O(9) atoms. There are two inequivalent H sites. In the first H site, H(7) is bonded in a single-bond geometry to one O(8) atom. In the second H site, H(8) is bonded in a single-bond geometry to one O(8) atom. S(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are six inequivalent O sites. In the first O site, O(8) is bonded in a distorted trigonal planar geometry to one Cu(2), one H(7), and one H(8) atom. In the second O site, O(9) is bonded in a distorted water-like geometry to one Cu(2) and one O(2) atom. In the third O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the fourth O site, O(2) is bonded in a distorted single-bond geometry to one S(1) and one O(9) atom. In the fifth O site, O(3) is bonded in a distorted single-bond geometry to one S(1) atom. In the sixth O site, O(4) is bonded in a single-bond geometry to one S(1) atom. is represented by the CIF card [CIF]
data_CuH10SO9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.431
_cell_length_b   6.454
_cell_length_c   10.965
_cell_angle_alpha   98.478
_cell_angle_beta   87.477
_cell_angle_gamma   109.130
_symmetry_Int_Tables_number   1
_cell_volume   425.237
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cu  Cu0  1  0.000  0.000  0.000  1.0
  Cu  Cu1  1  0.000  0.500  0.500  1.0
  H  H2  1  0.748  0.105  0.857  1.0
  H  H3  1  0.252  0.895  0.143  1.0
  H  H4  1  0.760  0.264  0.984  1.0
  H  H5  1  0.240  0.736  0.016  1.0
  H  H6  1  0.988  0.705  0.819  1.0
  H  H7  1  0.012  0.295  0.181  1.0
  H  H8  1  0.753  0.693  0.794  1.0
  H  H9  1  0.247  0.307  0.206  1.0
  H  H10  1  0.594  0.675  0.619  1.0
  H  H11  1  0.406  0.325  0.381  1.0
  H  H12  1  0.553  0.432  0.639  1.0
  H  H13  1  0.447  0.568  0.361  1.0
  H  H14  1  0.119  0.214  0.607  1.0
  H  H15  1  0.881  0.786  0.393  1.0
  H  H16  1  0.851  0.151  0.613  1.0
  H  H17  1  0.149  0.849  0.387  1.0
  H  H18  1  0.300  0.426  0.886  1.0
  H  H19  1  0.700  0.574  0.114  1.0
  H  H20  1  0.816  0.607  0.090  1.0
  H  H21  1  0.184  0.393  0.910  1.0
  S  S22  1  0.403  0.019  0.720  1.0
  S  S23  1  0.597  0.981  0.280  1.0
  O  O24  1  0.345  0.062  0.848  1.0
  O  O25  1  0.655  0.938  0.152  1.0
  O  O26  1  0.241  0.762  0.689  1.0
  O  O27  1  0.759  0.238  0.311  1.0
  O  O28  1  0.352  0.151  0.635  1.0
  O  O29  1  0.648  0.849  0.365  1.0
  O  O30  1  0.630  0.013  0.703  1.0
  O  O31  1  0.370  0.987  0.297  1.0
  O  O32  1  0.838  0.178  0.932  1.0
  O  O33  1  0.162  0.822  0.068  1.0
  O  O34  1  0.862  0.732  0.864  1.0
  O  O35  1  0.138  0.268  0.136  1.0
  O  O36  1  0.663  0.580  0.652  1.0
  O  O37  1  0.337  0.420  0.348  1.0
  O  O38  1  0.990  0.247  0.581  1.0
  O  O39  1  0.010  0.753  0.419  1.0
  O  O40  1  0.715  0.339  0.433  1.0
  O  O41  1  0.285  0.661  0.567  1.0
[/CIF]
.
The crystal structure described by Cu(H2O)6CuH4(SO6)2(H2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 1333-74-0 molecules, one copper hexahydrate molecule, and one CuH4(SO6)2 cluster. In the CuH4(SO6)2 cluster, Cu(2) is bonded in a square co-planar geometry to two equivalent O(8) and two equivalent O(9) atoms. There are two inequivalent H sites. In the first H site, H(7) is bonded in a single-bond geometry to one O(8) atom. In the second H site, H(8) is bonded in a single-bond geometry to one O(8) atom. S(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are six inequivalent O sites. In the first O site, O(8) is bonded in a distorted trigonal planar geometry to one Cu(2), one H(7), and one H(8) atom. In the second O site, O(9) is bonded in a distorted water-like geometry to one Cu(2) and one O(2) atom. In the third O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the fourth O site, O(2) is bonded in a distorted single-bond geometry to one S(1) and one O(9) atom. In the fifth O site, O(3) is bonded in a distorted single-bond geometry to one S(1) atom. In the sixth O site, O(4) is bonded in a single-bond geometry to one S(1) atom. is represented by the CIF card [CIF]
data_CuH10SO9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.431
_cell_length_b   6.454
_cell_length_c   10.965
_cell_angle_alpha   98.478
_cell_angle_beta   87.477
_cell_angle_gamma   109.130
_symmetry_Int_Tables_number   1
_cell_volume   425.237
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cu  Cu0  1  0.000  0.000  0.000  1.0
  Cu  Cu1  1  0.000  0.500  0.500  1.0
  H  H2  1  0.748  0.105  0.857  1.0
  H  H3  1  0.252  0.895  0.143  1.0
  H  H4  1  0.760  0.264  0.984  1.0
  H  H5  1  0.240  0.736  0.016  1.0
  H  H6  1  0.988  0.705  0.819  1.0
  H  H7  1  0.012  0.295  0.181  1.0
  H  H8  1  0.753  0.693  0.794  1.0
  H  H9  1  0.247  0.307  0.206  1.0
  H  H10  1  0.594  0.675  0.619  1.0
  H  H11  1  0.406  0.325  0.381  1.0
  H  H12  1  0.553  0.432  0.639  1.0
  H  H13  1  0.447  0.568  0.361  1.0
  H  H14  1  0.119  0.214  0.607  1.0
  H  H15  1  0.881  0.786  0.393  1.0
  H  H16  1  0.851  0.151  0.613  1.0
  H  H17  1  0.149  0.849  0.387  1.0
  H  H18  1  0.300  0.426  0.886  1.0
  H  H19  1  0.700  0.574  0.114  1.0
  H  H20  1  0.816  0.607  0.090  1.0
  H  H21  1  0.184  0.393  0.910  1.0
  S  S22  1  0.403  0.019  0.720  1.0
  S  S23  1  0.597  0.981  0.280  1.0
  O  O24  1  0.345  0.062  0.848  1.0
  O  O25  1  0.655  0.938  0.152  1.0
  O  O26  1  0.241  0.762  0.689  1.0
  O  O27  1  0.759  0.238  0.311  1.0
  O  O28  1  0.352  0.151  0.635  1.0
  O  O29  1  0.648  0.849  0.365  1.0
  O  O30  1  0.630  0.013  0.703  1.0
  O  O31  1  0.370  0.987  0.297  1.0
  O  O32  1  0.838  0.178  0.932  1.0
  O  O33  1  0.162  0.822  0.068  1.0
  O  O34  1  0.862  0.732  0.864  1.0
  O  O35  1  0.138  0.268  0.136  1.0
  O  O36  1  0.663  0.580  0.652  1.0
  O  O37  1  0.337  0.420  0.348  1.0
  O  O38  1  0.990  0.247  0.581  1.0
  O  O39  1  0.010  0.753  0.419  1.0
  O  O40  1  0.715  0.339  0.433  1.0
  O  O41  1  0.285  0.661  0.567  1.0
[/CIF]
.