The compound described by Sr3La(VO4)3 crystallizes in the monoclinic Cm space group. There are six inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 6-coordinate geometry to one O(10), one O(16), two equivalent O(15), and two equivalent O(8) atoms. In the second Sr site, Sr(2) is bonded in a 6-coordinate geometry to one O(11), one O(17), two equivalent O(13), and two equivalent O(9) atoms. In the third Sr site, Sr(3) is bonded in a 6-coordinate geometry to one O(12), one O(18), two equivalent O(14), and two equivalent O(7) atoms. In the fourth Sr site, Sr(4) is bonded in a 10-coordinate geometry to one O(18), one O(2), two equivalent O(11), two equivalent O(14), two equivalent O(8), and two equivalent O(9) atoms. In the fifth Sr site, Sr(5) is bonded in a 10-coordinate geometry to one O(16), one O(3), two equivalent O(12), two equivalent O(15), two equivalent O(7), and two equivalent O(9) atoms. In the sixth Sr site, Sr(6) is bonded in a 10-coordinate geometry to one O(11), one O(6), two equivalent O(14), two equivalent O(15), two equivalent O(18), and two equivalent O(9) atoms. There are two inequivalent La sites. In the first La site, La(1) is bonded in a 10-coordinate geometry to one O(12), one O(4), two equivalent O(13), two equivalent O(15), two equivalent O(16), and two equivalent O(7) atoms. In the second La site, La(2) is bonded in a 10-coordinate geometry to one O(10), one O(5), two equivalent O(13), two equivalent O(14), two equivalent O(17), and two equivalent O(8) atoms. There are six inequivalent V sites. In the first V site, V(1) is bonded in a tetrahedral geometry to one O(16), one O(2), and two equivalent O(13) atoms. In the second V site, V(2) is bonded in a tetrahedral geometry to one O(17), one O(3), and two equivalent O(14) atoms. In the third V site, V(3) is bonded in a tetrahedral geometry to one O(1), one O(18), and two equivalent O(15) atoms. In the fourth V site, V(4) is bonded in a tetrahedral geometry to one O(10), one O(6), and two equivalent O(7) atoms. In the fifth V site, V(5) is bonded in a tetrahedral geometry to one O(11), one O(4), and two equivalent O(8) atoms. In the sixth V site, V(6) is bonded in a tetrahedral geometry to one O(12), one O(5), and two equivalent O(9) atoms. There are eighteen inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one V(3) atom. In the second O site, O(2) is bonded in a linear geometry to one Sr(4) and one V(1) atom. In the third O site, O(3) is bonded in a distorted linear geometry to one Sr(5) and one V(2) atom. In the fourth O site, O(4) is bonded in a distorted linear geometry to one La(1) and one V(5) atom. In the fifth O site, O(5) is bonded in a distorted linear geometry to one La(2) and one V(6) atom. In the sixth O site, O(6) is bonded in a distorted linear geometry to one Sr(6) and one V(4) atom. In the seventh O site, O(7) is bonded in a 4-coordinate geometry to one Sr(3), one Sr(5), one La(1), and one V(4) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one Sr(1), one Sr(4), one La(2), and one V(5) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one Sr(2), one Sr(4), one Sr(5), one Sr(6), and one V(6) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Sr(1), one La(2), and one V(4) atom. In the eleventh O site, O(11) is bonded in a distorted single-bond geometry to one Sr(2), one Sr(6), two equivalent Sr(4), and one V(5) atom. In the twelfth O site, O(12) is bonded in a distorted single-bond geometry to one Sr(3), two equivalent Sr(5), one La(1), and one V(6) atom. In the thirteenth O site, O(13) is bonded in a distorted single-bond geometry to one Sr(2), one La(1), one La(2), and one V(1) atom. In the fourteenth O site, O(14) is bonded in a distorted single-bond geometry to one Sr(3), one Sr(4), one Sr(6), one La(2), and one V(2) atom. In the fifteenth O site, O(15) is bonded in a distorted single-bond geometry to one Sr(1), one Sr(5), one Sr(6), one La(1), and one V(3) atom. In the sixteenth O site, O(16) is bonded in a distorted single-bond geometry to one Sr(1), one Sr(5), two equivalent La(1), and one V(1) atom. In the seventeenth O site, O(17) is bonded in a distorted single-bond geometry to one Sr(2), two equivalent La(2), and one V(2) atom. In the eighteenth O site, O(18) is bonded in a 1-coordinate geometry to one Sr(3), one Sr(4), two equivalent Sr(6), and one V(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sr3LaV3O12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.033
_cell_length_b   11.033
_cell_length_c   9.364
_cell_angle_alpha   84.533
_cell_angle_beta   84.533
_cell_angle_gamma   29.813
_symmetry_Int_Tables_number   1
_cell_volume   563.959
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.004  0.004  0.007  1.0
  Sr  Sr1  1  0.332  0.332  0.662  1.0
  Sr  Sr2  1  0.665  0.665  0.326  1.0
  Sr  Sr3  1  0.800  0.800  0.005  1.0
  Sr  Sr4  1  0.134  0.134  0.668  1.0
  Sr  Sr5  1  0.199  0.199  0.002  1.0
  La  La6  1  0.522  0.522  0.636  1.0
  La  La7  1  0.879  0.879  0.337  1.0
  V  V8  1  0.935  0.935  0.667  1.0
  V  V9  1  0.270  0.270  0.326  1.0
  V  V10  1  0.603  0.603  0.988  1.0
  V  V11  1  0.062  0.062  0.349  1.0
  V  V12  1  0.397  0.397  0.009  1.0
  V  V13  1  0.731  0.731  0.669  1.0
  O  O14  1  0.547  0.547  0.130  1.0
  O  O15  1  0.878  0.878  0.805  1.0
  O  O16  1  0.214  0.214  0.469  1.0
  O  O17  1  0.455  0.455  0.860  1.0
  O  O18  1  0.792  0.792  0.526  1.0
  O  O19  1  0.119  0.119  0.206  1.0
  O  O20  1  0.317  0.831  0.459  1.0
  O  O21  1  0.660  0.141  0.108  1.0
  O  O22  1  0.987  0.490  0.775  1.0
  O  O23  1  0.831  0.317  0.459  1.0
  O  O24  1  0.141  0.660  0.108  1.0
  O  O25  1  0.490  0.987  0.775  1.0
  O  O26  1  0.989  0.989  0.284  1.0
  O  O27  1  0.323  0.323  0.945  1.0
  O  O28  1  0.656  0.656  0.611  1.0
  O  O29  1  0.679  0.179  0.560  1.0
  O  O30  1  0.011  0.512  0.220  1.0
  O  O31  1  0.340  0.848  0.885  1.0
  O  O32  1  0.179  0.679  0.560  1.0
  O  O33  1  0.512  0.011  0.220  1.0
  O  O34  1  0.848  0.340  0.885  1.0
  O  O35  1  0.010  0.010  0.723  1.0
  O  O36  1  0.344  0.344  0.388  1.0
  O  O37  1  0.678  0.678  0.052  1.0
[/CIF]
.
The compound described by Sr3La(VO4)3 crystallizes in the monoclinic Cm space group. There are six inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 6-coordinate geometry to one O(10), one O(16), two equivalent O(15), and two equivalent O(8) atoms. In the second Sr site, Sr(2) is bonded in a 6-coordinate geometry to one O(11), one O(17), two equivalent O(13), and two equivalent O(9) atoms. In the third Sr site, Sr(3) is bonded in a 6-coordinate geometry to one O(12), one O(18), two equivalent O(14), and two equivalent O(7) atoms. In the fourth Sr site, Sr(4) is bonded in a 10-coordinate geometry to one O(18), one O(2), two equivalent O(11), two equivalent O(14), two equivalent O(8), and two equivalent O(9) atoms. In the fifth Sr site, Sr(5) is bonded in a 10-coordinate geometry to one O(16), one O(3), two equivalent O(12), two equivalent O(15), two equivalent O(7), and two equivalent O(9) atoms. In the sixth Sr site, Sr(6) is bonded in a 10-coordinate geometry to one O(11), one O(6), two equivalent O(14), two equivalent O(15), two equivalent O(18), and two equivalent O(9) atoms. There are two inequivalent La sites. In the first La site, La(1) is bonded in a 10-coordinate geometry to one O(12), one O(4), two equivalent O(13), two equivalent O(15), two equivalent O(16), and two equivalent O(7) atoms. In the second La site, La(2) is bonded in a 10-coordinate geometry to one O(10), one O(5), two equivalent O(13), two equivalent O(14), two equivalent O(17), and two equivalent O(8) atoms. There are six inequivalent V sites. In the first V site, V(1) is bonded in a tetrahedral geometry to one O(16), one O(2), and two equivalent O(13) atoms. In the second V site, V(2) is bonded in a tetrahedral geometry to one O(17), one O(3), and two equivalent O(14) atoms. In the third V site, V(3) is bonded in a tetrahedral geometry to one O(1), one O(18), and two equivalent O(15) atoms. In the fourth V site, V(4) is bonded in a tetrahedral geometry to one O(10), one O(6), and two equivalent O(7) atoms. In the fifth V site, V(5) is bonded in a tetrahedral geometry to one O(11), one O(4), and two equivalent O(8) atoms. In the sixth V site, V(6) is bonded in a tetrahedral geometry to one O(12), one O(5), and two equivalent O(9) atoms. There are eighteen inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one V(3) atom. In the second O site, O(2) is bonded in a linear geometry to one Sr(4) and one V(1) atom. In the third O site, O(3) is bonded in a distorted linear geometry to one Sr(5) and one V(2) atom. In the fourth O site, O(4) is bonded in a distorted linear geometry to one La(1) and one V(5) atom. In the fifth O site, O(5) is bonded in a distorted linear geometry to one La(2) and one V(6) atom. In the sixth O site, O(6) is bonded in a distorted linear geometry to one Sr(6) and one V(4) atom. In the seventh O site, O(7) is bonded in a 4-coordinate geometry to one Sr(3), one Sr(5), one La(1), and one V(4) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one Sr(1), one Sr(4), one La(2), and one V(5) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one Sr(2), one Sr(4), one Sr(5), one Sr(6), and one V(6) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Sr(1), one La(2), and one V(4) atom. In the eleventh O site, O(11) is bonded in a distorted single-bond geometry to one Sr(2), one Sr(6), two equivalent Sr(4), and one V(5) atom. In the twelfth O site, O(12) is bonded in a distorted single-bond geometry to one Sr(3), two equivalent Sr(5), one La(1), and one V(6) atom. In the thirteenth O site, O(13) is bonded in a distorted single-bond geometry to one Sr(2), one La(1), one La(2), and one V(1) atom. In the fourteenth O site, O(14) is bonded in a distorted single-bond geometry to one Sr(3), one Sr(4), one Sr(6), one La(2), and one V(2) atom. In the fifteenth O site, O(15) is bonded in a distorted single-bond geometry to one Sr(1), one Sr(5), one Sr(6), one La(1), and one V(3) atom. In the sixteenth O site, O(16) is bonded in a distorted single-bond geometry to one Sr(1), one Sr(5), two equivalent La(1), and one V(1) atom. In the seventeenth O site, O(17) is bonded in a distorted single-bond geometry to one Sr(2), two equivalent La(2), and one V(2) atom. In the eighteenth O site, O(18) is bonded in a 1-coordinate geometry to one Sr(3), one Sr(4), two equivalent Sr(6), and one V(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sr3LaV3O12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.033
_cell_length_b   11.033
_cell_length_c   9.364
_cell_angle_alpha   84.533
_cell_angle_beta   84.533
_cell_angle_gamma   29.813
_symmetry_Int_Tables_number   1
_cell_volume   563.959
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.004  0.004  0.007  1.0
  Sr  Sr1  1  0.332  0.332  0.662  1.0
  Sr  Sr2  1  0.665  0.665  0.326  1.0
  Sr  Sr3  1  0.800  0.800  0.005  1.0
  Sr  Sr4  1  0.134  0.134  0.668  1.0
  Sr  Sr5  1  0.199  0.199  0.002  1.0
  La  La6  1  0.522  0.522  0.636  1.0
  La  La7  1  0.879  0.879  0.337  1.0
  V  V8  1  0.935  0.935  0.667  1.0
  V  V9  1  0.270  0.270  0.326  1.0
  V  V10  1  0.603  0.603  0.988  1.0
  V  V11  1  0.062  0.062  0.349  1.0
  V  V12  1  0.397  0.397  0.009  1.0
  V  V13  1  0.731  0.731  0.669  1.0
  O  O14  1  0.547  0.547  0.130  1.0
  O  O15  1  0.878  0.878  0.805  1.0
  O  O16  1  0.214  0.214  0.469  1.0
  O  O17  1  0.455  0.455  0.860  1.0
  O  O18  1  0.792  0.792  0.526  1.0
  O  O19  1  0.119  0.119  0.206  1.0
  O  O20  1  0.317  0.831  0.459  1.0
  O  O21  1  0.660  0.141  0.108  1.0
  O  O22  1  0.987  0.490  0.775  1.0
  O  O23  1  0.831  0.317  0.459  1.0
  O  O24  1  0.141  0.660  0.108  1.0
  O  O25  1  0.490  0.987  0.775  1.0
  O  O26  1  0.989  0.989  0.284  1.0
  O  O27  1  0.323  0.323  0.945  1.0
  O  O28  1  0.656  0.656  0.611  1.0
  O  O29  1  0.679  0.179  0.560  1.0
  O  O30  1  0.011  0.512  0.220  1.0
  O  O31  1  0.340  0.848  0.885  1.0
  O  O32  1  0.179  0.679  0.560  1.0
  O  O33  1  0.512  0.011  0.220  1.0
  O  O34  1  0.848  0.340  0.885  1.0
  O  O35  1  0.010  0.010  0.723  1.0
  O  O36  1  0.344  0.344  0.388  1.0
  O  O37  1  0.678  0.678  0.052  1.0
[/CIF]
.