The material described by BPNBr2Cl3 is Indium-like structured and crystallizes in the orthorhombic Cmce space group. The structure is zero-dimensional and consists of four BPNBr2Cl3 clusters. B(1) is bonded to two equivalent N(1) and two equivalent Br(1) atoms to form BBr2N2 tetrahedra that share corners with two equivalent P(1)NCl3 tetrahedra and  an edgeedge with one B(1)Br2N2 tetrahedra. P(1) is bonded to one N(1), one Cl(2), and two equivalent Cl(1) atoms to form PNCl3 tetrahedra that share corners with two equivalent B(1)Br2N2 tetrahedra. N(1) is bonded in a distorted T-shaped geometry to two equivalent B(1) and one P(1) atom. Br(1) is bonded in a single-bond geometry to one B(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one P(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_BPBr2NCl3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.305
_cell_length_b   9.305
_cell_length_c   10.492
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   95.082
_symmetry_Int_Tables_number   1
_cell_volume   904.901
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.420  0.580  0.000  1.0
  B  B1  1  0.080  0.920  0.500  1.0
  B  B2  1  0.580  0.420  0.000  1.0
  B  B3  1  0.920  0.080  0.500  1.0
  P  P4  1  0.999  0.999  0.247  1.0
  P  P5  1  0.001  0.001  0.753  1.0
  P  P6  1  0.499  0.499  0.253  1.0
  P  P7  1  0.501  0.501  0.747  1.0
  Br  Br8  1  0.966  0.297  0.480  1.0
  Br  Br9  1  0.534  0.203  0.980  1.0
  Br  Br10  1  0.203  0.534  0.980  1.0
  Br  Br11  1  0.466  0.797  0.020  1.0
  Br  Br12  1  0.797  0.466  0.020  1.0
  Br  Br13  1  0.034  0.703  0.520  1.0
  Br  Br14  1  0.703  0.034  0.520  1.0
  Br  Br15  1  0.297  0.966  0.480  1.0
  N  N16  1  0.489  0.489  0.104  1.0
  N  N17  1  0.011  0.011  0.604  1.0
  N  N18  1  0.511  0.511  0.896  1.0
  N  N19  1  0.989  0.989  0.396  1.0
  Cl  Cl20  1  0.686  0.452  0.671  1.0
  Cl  Cl21  1  0.353  0.353  0.675  1.0
  Cl  Cl22  1  0.952  0.186  0.829  1.0
  Cl  Cl23  1  0.647  0.647  0.325  1.0
  Cl  Cl24  1  0.048  0.814  0.171  1.0
  Cl  Cl25  1  0.314  0.548  0.329  1.0
  Cl  Cl26  1  0.186  0.952  0.829  1.0
  Cl  Cl27  1  0.814  0.048  0.171  1.0
  Cl  Cl28  1  0.147  0.147  0.175  1.0
  Cl  Cl29  1  0.452  0.686  0.671  1.0
  Cl  Cl30  1  0.853  0.853  0.825  1.0
  Cl  Cl31  1  0.548  0.314  0.329  1.0
[/CIF]
.
The material described by BPNBr2Cl3 is Indium-like structured and crystallizes in the orthorhombic Cmce space group. The structure is zero-dimensional and consists of four BPNBr2Cl3 clusters. B(1) is bonded to two equivalent N(1) and two equivalent Br(1) atoms to form BBr2N2 tetrahedra that share corners with two equivalent P(1)NCl3 tetrahedra and  an edgeedge with one B(1)Br2N2 tetrahedra. P(1) is bonded to one N(1), one Cl(2), and two equivalent Cl(1) atoms to form PNCl3 tetrahedra that share corners with two equivalent B(1)Br2N2 tetrahedra. N(1) is bonded in a distorted T-shaped geometry to two equivalent B(1) and one P(1) atom. Br(1) is bonded in a single-bond geometry to one B(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one P(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_BPBr2NCl3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.305
_cell_length_b   9.305
_cell_length_c   10.492
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   95.082
_symmetry_Int_Tables_number   1
_cell_volume   904.901
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.420  0.580  0.000  1.0
  B  B1  1  0.080  0.920  0.500  1.0
  B  B2  1  0.580  0.420  0.000  1.0
  B  B3  1  0.920  0.080  0.500  1.0
  P  P4  1  0.999  0.999  0.247  1.0
  P  P5  1  0.001  0.001  0.753  1.0
  P  P6  1  0.499  0.499  0.253  1.0
  P  P7  1  0.501  0.501  0.747  1.0
  Br  Br8  1  0.966  0.297  0.480  1.0
  Br  Br9  1  0.534  0.203  0.980  1.0
  Br  Br10  1  0.203  0.534  0.980  1.0
  Br  Br11  1  0.466  0.797  0.020  1.0
  Br  Br12  1  0.797  0.466  0.020  1.0
  Br  Br13  1  0.034  0.703  0.520  1.0
  Br  Br14  1  0.703  0.034  0.520  1.0
  Br  Br15  1  0.297  0.966  0.480  1.0
  N  N16  1  0.489  0.489  0.104  1.0
  N  N17  1  0.011  0.011  0.604  1.0
  N  N18  1  0.511  0.511  0.896  1.0
  N  N19  1  0.989  0.989  0.396  1.0
  Cl  Cl20  1  0.686  0.452  0.671  1.0
  Cl  Cl21  1  0.353  0.353  0.675  1.0
  Cl  Cl22  1  0.952  0.186  0.829  1.0
  Cl  Cl23  1  0.647  0.647  0.325  1.0
  Cl  Cl24  1  0.048  0.814  0.171  1.0
  Cl  Cl25  1  0.314  0.548  0.329  1.0
  Cl  Cl26  1  0.186  0.952  0.829  1.0
  Cl  Cl27  1  0.814  0.048  0.171  1.0
  Cl  Cl28  1  0.147  0.147  0.175  1.0
  Cl  Cl29  1  0.452  0.686  0.671  1.0
  Cl  Cl30  1  0.853  0.853  0.825  1.0
  Cl  Cl31  1  0.548  0.314  0.329  1.0
[/CIF]
.