The crystal structure described by Li2I(OH) crystallizes in the orthorhombic Pnma space group. Li(1) is bonded in a distorted water-like geometry to two equivalent O(1) and two equivalent I(1) atoms. H(1) is bonded in a single-bond geometry to one O(1) atom. O(1) is bonded in a distorted single-bond geometry to four equivalent Li(1) and one H(1) atom. I(1) is bonded in a 4-coordinate geometry to four equivalent Li(1) atoms. is represented by the CIF file [CIF]
data_Li2HIO
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.651
_cell_length_b   6.675
_cell_length_c   10.492
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   395.759
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.000  0.561  0.889  1.0
  Li  Li1  1  0.500  0.939  0.389  1.0
  Li  Li2  1  0.500  0.439  0.111  1.0
  Li  Li3  1  1.000  0.061  0.611  1.0
  Li  Li4  1  1.000  0.439  0.111  1.0
  Li  Li5  1  0.500  0.061  0.611  1.0
  Li  Li6  1  0.500  0.561  0.889  1.0
  Li  Li7  1  0.000  0.939  0.389  1.0
  H  H8  1  0.250  0.774  0.544  1.0
  H  H9  1  0.250  0.726  0.044  1.0
  H  H10  1  0.750  0.226  0.456  1.0
  H  H11  1  0.750  0.274  0.956  1.0
  I  I12  1  0.250  0.416  0.675  1.0
  I  I13  1  0.250  0.084  0.175  1.0
  I  I14  1  0.750  0.584  0.325  1.0
  I  I15  1  0.750  0.916  0.825  1.0
  O  O16  1  0.250  0.916  0.519  1.0
  O  O17  1  0.250  0.584  0.019  1.0
  O  O18  1  0.750  0.084  0.481  1.0
  O  O19  1  0.750  0.416  0.981  1.0
[/CIF]
.
The crystal structure described by Li2I(OH) crystallizes in the orthorhombic Pnma space group. Li(1) is bonded in a distorted water-like geometry to two equivalent O(1) and two equivalent I(1) atoms. H(1) is bonded in a single-bond geometry to one O(1) atom. O(1) is bonded in a distorted single-bond geometry to four equivalent Li(1) and one H(1) atom. I(1) is bonded in a 4-coordinate geometry to four equivalent Li(1) atoms. is represented by the CIF file [CIF]
data_Li2HIO
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.651
_cell_length_b   6.675
_cell_length_c   10.492
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   395.759
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.000  0.561  0.889  1.0
  Li  Li1  1  0.500  0.939  0.389  1.0
  Li  Li2  1  0.500  0.439  0.111  1.0
  Li  Li3  1  1.000  0.061  0.611  1.0
  Li  Li4  1  1.000  0.439  0.111  1.0
  Li  Li5  1  0.500  0.061  0.611  1.0
  Li  Li6  1  0.500  0.561  0.889  1.0
  Li  Li7  1  0.000  0.939  0.389  1.0
  H  H8  1  0.250  0.774  0.544  1.0
  H  H9  1  0.250  0.726  0.044  1.0
  H  H10  1  0.750  0.226  0.456  1.0
  H  H11  1  0.750  0.274  0.956  1.0
  I  I12  1  0.250  0.416  0.675  1.0
  I  I13  1  0.250  0.084  0.175  1.0
  I  I14  1  0.750  0.584  0.325  1.0
  I  I15  1  0.750  0.916  0.825  1.0
  O  O16  1  0.250  0.916  0.519  1.0
  O  O17  1  0.250  0.584  0.019  1.0
  O  O18  1  0.750  0.084  0.481  1.0
  O  O19  1  0.750  0.416  0.981  1.0
[/CIF]
.