The structure described by Sn5(S2Cl)2 crystallizes in the triclinic P-1 space group. There are five inequivalent Sn sites. In the first Sn site, Sn(1) is bonded in a distorted trigonal pyramidal geometry to one S(1), one S(2), one S(3), and one S(4) atom. In the second Sn site, Sn(2) is bonded in a 3-coordinate geometry to one S(2) and two equivalent S(3) atoms. In the third Sn site, Sn(3) is bonded in a 3-coordinate geometry to one S(4) and two equivalent S(1) atoms. In the fourth Sn site, Sn(4) is bonded in a 4-coordinate geometry to one S(1), one S(4), one Cl(1), and one Cl(2) atom. In the fifth Sn site, Sn(5) is bonded in a 4-coordinate geometry to one S(2), one S(3), one Cl(1), and one Cl(2) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a distorted rectangular see-saw-like geometry to one Sn(1), one Sn(4), and two equivalent Sn(3) atoms. In the second S site, S(2) is bonded in a 3-coordinate geometry to one Sn(1), one Sn(2), and one Sn(5) atom. In the third S site, S(3) is bonded in a distorted rectangular see-saw-like geometry to one Sn(1), one Sn(5), and two equivalent Sn(2) atoms. In the fourth S site, S(4) is bonded in a 3-coordinate geometry to one Sn(1), one Sn(3), and one Sn(4) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted L-shaped geometry to one Sn(4) and one Sn(5) atom. In the second Cl site, Cl(2) is bonded in a distorted L-shaped geometry to one Sn(4) and one Sn(5) atom. is represented by the CIF file [CIF]
data_Sn5(S2Cl)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.317
_cell_length_b   9.223
_cell_length_c   10.590
_cell_angle_alpha   67.573
_cell_angle_beta   69.992
_cell_angle_gamma   66.743
_symmetry_Int_Tables_number   1
_cell_volume   591.284
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn0  1  0.162  0.748  0.746  1.0
  Sn  Sn1  1  0.838  0.252  0.254  1.0
  Sn  Sn2  1  0.246  0.133  0.432  1.0
  Sn  Sn3  1  0.306  0.367  0.067  1.0
  Sn  Sn4  1  0.754  0.867  0.568  1.0
  Sn  Sn5  1  0.694  0.633  0.933  1.0
  Sn  Sn6  1  0.095  0.712  0.257  1.0
  Sn  Sn7  1  0.905  0.288  0.743  1.0
  Sn  Sn8  1  0.564  0.789  0.242  1.0
  Sn  Sn9  1  0.436  0.211  0.758  1.0
  S  S10  1  0.499  0.492  0.186  1.0
  S  S11  1  0.777  0.142  0.562  1.0
  S  S12  1  0.674  0.012  0.315  1.0
  S  S13  1  0.981  0.357  0.940  1.0
  S  S14  1  0.501  0.508  0.814  1.0
  S  S15  1  0.223  0.858  0.438  1.0
  S  S16  1  0.326  0.988  0.685  1.0
  S  S17  1  0.019  0.643  0.060  1.0
  Cl  Cl18  1  0.243  0.946  0.065  1.0
  Cl  Cl19  1  0.757  0.054  0.935  1.0
  Cl  Cl20  1  0.754  0.553  0.434  1.0
  Cl  Cl21  1  0.246  0.447  0.566  1.0
[/CIF]
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The structure described by Sn5(S2Cl)2 crystallizes in the triclinic P-1 space group. There are five inequivalent Sn sites. In the first Sn site, Sn(1) is bonded in a distorted trigonal pyramidal geometry to one S(1), one S(2), one S(3), and one S(4) atom. In the second Sn site, Sn(2) is bonded in a 3-coordinate geometry to one S(2) and two equivalent S(3) atoms. In the third Sn site, Sn(3) is bonded in a 3-coordinate geometry to one S(4) and two equivalent S(1) atoms. In the fourth Sn site, Sn(4) is bonded in a 4-coordinate geometry to one S(1), one S(4), one Cl(1), and one Cl(2) atom. In the fifth Sn site, Sn(5) is bonded in a 4-coordinate geometry to one S(2), one S(3), one Cl(1), and one Cl(2) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a distorted rectangular see-saw-like geometry to one Sn(1), one Sn(4), and two equivalent Sn(3) atoms. In the second S site, S(2) is bonded in a 3-coordinate geometry to one Sn(1), one Sn(2), and one Sn(5) atom. In the third S site, S(3) is bonded in a distorted rectangular see-saw-like geometry to one Sn(1), one Sn(5), and two equivalent Sn(2) atoms. In the fourth S site, S(4) is bonded in a 3-coordinate geometry to one Sn(1), one Sn(3), and one Sn(4) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted L-shaped geometry to one Sn(4) and one Sn(5) atom. In the second Cl site, Cl(2) is bonded in a distorted L-shaped geometry to one Sn(4) and one Sn(5) atom. is represented by the CIF file [CIF]
data_Sn5(S2Cl)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.317
_cell_length_b   9.223
_cell_length_c   10.590
_cell_angle_alpha   67.573
_cell_angle_beta   69.992
_cell_angle_gamma   66.743
_symmetry_Int_Tables_number   1
_cell_volume   591.284
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn0  1  0.162  0.748  0.746  1.0
  Sn  Sn1  1  0.838  0.252  0.254  1.0
  Sn  Sn2  1  0.246  0.133  0.432  1.0
  Sn  Sn3  1  0.306  0.367  0.067  1.0
  Sn  Sn4  1  0.754  0.867  0.568  1.0
  Sn  Sn5  1  0.694  0.633  0.933  1.0
  Sn  Sn6  1  0.095  0.712  0.257  1.0
  Sn  Sn7  1  0.905  0.288  0.743  1.0
  Sn  Sn8  1  0.564  0.789  0.242  1.0
  Sn  Sn9  1  0.436  0.211  0.758  1.0
  S  S10  1  0.499  0.492  0.186  1.0
  S  S11  1  0.777  0.142  0.562  1.0
  S  S12  1  0.674  0.012  0.315  1.0
  S  S13  1  0.981  0.357  0.940  1.0
  S  S14  1  0.501  0.508  0.814  1.0
  S  S15  1  0.223  0.858  0.438  1.0
  S  S16  1  0.326  0.988  0.685  1.0
  S  S17  1  0.019  0.643  0.060  1.0
  Cl  Cl18  1  0.243  0.946  0.065  1.0
  Cl  Cl19  1  0.757  0.054  0.935  1.0
  Cl  Cl20  1  0.754  0.553  0.434  1.0
  Cl  Cl21  1  0.246  0.447  0.566  1.0
[/CIF]
.