The structure described by S3N2Cl2 is Indium-like structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of two S3N2Cl2 clusters. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one S(1) and one S(3) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one N(1), one N(2), and one Cl(2) atom. In the second S site, S(2) is bonded in a distorted single-bond geometry to one N(2) atom. In the third S site, S(3) is bonded in a distorted water-like geometry to one N(1) and one Cl(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one S(3) atom. In the second Cl site, Cl(2) is bonded in a distorted single-bond geometry to one S(1) atom. is represented by the CIF card [CIF]
data_S3(NCl)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.154
_cell_length_b   5.701
_cell_length_c   6.667
_cell_angle_alpha   78.376
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   340.830
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  S  S0  1  0.169  0.697  0.608  1.0
  S  S1  1  0.768  0.123  0.787  1.0
  S  S2  1  0.531  0.162  0.767  1.0
  S  S3  1  0.669  0.303  0.392  1.0
  S  S4  1  0.031  0.838  0.233  1.0
  S  S5  1  0.268  0.877  0.213  1.0
  N  N6  1  0.520  0.235  0.527  1.0
  N  N7  1  0.796  0.249  0.550  1.0
  N  N8  1  0.296  0.751  0.450  1.0
  N  N9  1  0.020  0.765  0.473  1.0
  Cl  Cl10  1  0.998  0.510  0.107  1.0
  Cl  Cl11  1  0.498  0.490  0.893  1.0
  Cl  Cl12  1  0.647  0.924  0.192  1.0
  Cl  Cl13  1  0.147  0.076  0.808  1.0
[/CIF]
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The structure described by S3N2Cl2 is Indium-like structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of two S3N2Cl2 clusters. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one S(1) and one S(3) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one N(1), one N(2), and one Cl(2) atom. In the second S site, S(2) is bonded in a distorted single-bond geometry to one N(2) atom. In the third S site, S(3) is bonded in a distorted water-like geometry to one N(1) and one Cl(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one S(3) atom. In the second Cl site, Cl(2) is bonded in a distorted single-bond geometry to one S(1) atom. is represented by the CIF card [CIF]
data_S3(NCl)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.154
_cell_length_b   5.701
_cell_length_c   6.667
_cell_angle_alpha   78.376
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   340.830
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  S  S0  1  0.169  0.697  0.608  1.0
  S  S1  1  0.768  0.123  0.787  1.0
  S  S2  1  0.531  0.162  0.767  1.0
  S  S3  1  0.669  0.303  0.392  1.0
  S  S4  1  0.031  0.838  0.233  1.0
  S  S5  1  0.268  0.877  0.213  1.0
  N  N6  1  0.520  0.235  0.527  1.0
  N  N7  1  0.796  0.249  0.550  1.0
  N  N8  1  0.296  0.751  0.450  1.0
  N  N9  1  0.020  0.765  0.473  1.0
  Cl  Cl10  1  0.998  0.510  0.107  1.0
  Cl  Cl11  1  0.498  0.490  0.893  1.0
  Cl  Cl12  1  0.647  0.924  0.192  1.0
  Cl  Cl13  1  0.147  0.076  0.808  1.0
[/CIF]
.