The compound described by Sr5W3O14 crystallizes in the orthorhombic Pbca space group. There are three inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a distorted body-centered cubic geometry to two equivalent O(4), two equivalent O(5), two equivalent O(6), and two equivalent O(7) atoms. In the second Sr site, Sr(2) is bonded in a 7-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), one O(6), and one O(7) atom. In the third Sr site, Sr(3) is bonded in a 8-coordinate geometry to one O(2), one O(3), one O(4), one O(5), one O(6), one O(7), and two equivalent O(1) atoms. There are two inequivalent W sites. In the first W site, W(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 27-31°. In the second W site, W(2) is bonded to one O(2), one O(3), one O(4), one O(5), one O(6), and one O(7) atom to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 27-31°. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Sr(2), two equivalent Sr(3), and one W(1) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one Sr(2), one Sr(3), one W(1), and one W(2) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Sr(2), one Sr(3), one W(1), and one W(2) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Sr(1), one Sr(2), one Sr(3), and one W(2) atom. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to one Sr(1), one Sr(2), one Sr(3), and one W(2) atom. In the sixth O site, O(6) is bonded to one Sr(1), one Sr(2), one Sr(3), and one W(2) atom to form distorted corner-sharing OSr3W tetrahedra. In the seventh O site, O(7) is bonded in a distorted rectangular see-saw-like geometry to one Sr(1), one Sr(2), one Sr(3), and one W(2) atom. is represented by the CIF file [CIF]
data_Sr5W3O14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.684
_cell_length_b   7.684
_cell_length_c   11.065
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.474
_symmetry_Int_Tables_number   1
_cell_volume   653.322
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  O  O0  1  0.455  0.455  0.667  1.0
  O  O1  1  0.045  0.045  0.167  1.0
  O  O2  1  0.748  0.496  0.544  1.0
  O  O3  1  0.004  0.752  0.044  1.0
  O  O4  1  0.248  0.996  0.956  1.0
  O  O5  1  0.504  0.252  0.456  1.0
  O  O6  1  0.828  0.532  0.875  1.0
  O  O7  1  0.968  0.672  0.375  1.0
  O  O8  1  0.328  0.032  0.625  1.0
  O  O9  1  0.468  0.172  0.125  1.0
  O  O10  1  0.029  0.696  0.610  1.0
  O  O11  1  0.804  0.471  0.110  1.0
  O  O12  1  0.529  0.196  0.890  1.0
  O  O13  1  0.304  0.971  0.390  1.0
  O  O14  1  0.971  0.304  0.390  1.0
  O  O15  1  0.196  0.529  0.890  1.0
  O  O16  1  0.471  0.804  0.110  1.0
  O  O17  1  0.696  0.029  0.610  1.0
  O  O18  1  0.172  0.468  0.125  1.0
  O  O19  1  0.032  0.328  0.625  1.0
  O  O20  1  0.672  0.968  0.375  1.0
  O  O21  1  0.532  0.828  0.875  1.0
  O  O22  1  0.996  0.248  0.956  1.0
  O  O23  1  0.252  0.504  0.456  1.0
  O  O24  1  0.496  0.748  0.544  1.0
  O  O25  1  0.752  0.004  0.044  1.0
  O  O26  1  0.955  0.955  0.833  1.0
  O  O27  1  0.545  0.545  0.333  1.0
  Sr  Sr28  1  0.000  0.000  0.500  1.0
  Sr  Sr29  1  0.500  0.500  0.000  1.0
  Sr  Sr30  1  0.251  0.251  0.776  1.0
  Sr  Sr31  1  0.249  0.249  0.276  1.0
  Sr  Sr32  1  0.764  0.264  0.750  1.0
  Sr  Sr33  1  0.236  0.736  0.250  1.0
  Sr  Sr34  1  0.736  0.236  0.250  1.0
  Sr  Sr35  1  0.264  0.764  0.750  1.0
  Sr  Sr36  1  0.751  0.751  0.724  1.0
  Sr  Sr37  1  0.749  0.749  0.224  1.0
  W  W38  1  0.000  0.000  0.000  1.0
  W  W39  1  0.500  0.500  0.500  1.0
  W  W40  1  0.000  0.500  0.000  1.0
  W  W41  1  0.000  0.500  0.500  1.0
  W  W42  1  0.500  1.000  0.000  1.0
  W  W43  1  0.500  0.000  0.500  1.0
[/CIF]
.
The compound described by Sr5W3O14 crystallizes in the orthorhombic Pbca space group. There are three inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a distorted body-centered cubic geometry to two equivalent O(4), two equivalent O(5), two equivalent O(6), and two equivalent O(7) atoms. In the second Sr site, Sr(2) is bonded in a 7-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), one O(6), and one O(7) atom. In the third Sr site, Sr(3) is bonded in a 8-coordinate geometry to one O(2), one O(3), one O(4), one O(5), one O(6), one O(7), and two equivalent O(1) atoms. There are two inequivalent W sites. In the first W site, W(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 27-31°. In the second W site, W(2) is bonded to one O(2), one O(3), one O(4), one O(5), one O(6), and one O(7) atom to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 27-31°. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Sr(2), two equivalent Sr(3), and one W(1) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one Sr(2), one Sr(3), one W(1), and one W(2) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Sr(2), one Sr(3), one W(1), and one W(2) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Sr(1), one Sr(2), one Sr(3), and one W(2) atom. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to one Sr(1), one Sr(2), one Sr(3), and one W(2) atom. In the sixth O site, O(6) is bonded to one Sr(1), one Sr(2), one Sr(3), and one W(2) atom to form distorted corner-sharing OSr3W tetrahedra. In the seventh O site, O(7) is bonded in a distorted rectangular see-saw-like geometry to one Sr(1), one Sr(2), one Sr(3), and one W(2) atom. is represented by the CIF file [CIF]
data_Sr5W3O14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.684
_cell_length_b   7.684
_cell_length_c   11.065
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.474
_symmetry_Int_Tables_number   1
_cell_volume   653.322
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  O  O0  1  0.455  0.455  0.667  1.0
  O  O1  1  0.045  0.045  0.167  1.0
  O  O2  1  0.748  0.496  0.544  1.0
  O  O3  1  0.004  0.752  0.044  1.0
  O  O4  1  0.248  0.996  0.956  1.0
  O  O5  1  0.504  0.252  0.456  1.0
  O  O6  1  0.828  0.532  0.875  1.0
  O  O7  1  0.968  0.672  0.375  1.0
  O  O8  1  0.328  0.032  0.625  1.0
  O  O9  1  0.468  0.172  0.125  1.0
  O  O10  1  0.029  0.696  0.610  1.0
  O  O11  1  0.804  0.471  0.110  1.0
  O  O12  1  0.529  0.196  0.890  1.0
  O  O13  1  0.304  0.971  0.390  1.0
  O  O14  1  0.971  0.304  0.390  1.0
  O  O15  1  0.196  0.529  0.890  1.0
  O  O16  1  0.471  0.804  0.110  1.0
  O  O17  1  0.696  0.029  0.610  1.0
  O  O18  1  0.172  0.468  0.125  1.0
  O  O19  1  0.032  0.328  0.625  1.0
  O  O20  1  0.672  0.968  0.375  1.0
  O  O21  1  0.532  0.828  0.875  1.0
  O  O22  1  0.996  0.248  0.956  1.0
  O  O23  1  0.252  0.504  0.456  1.0
  O  O24  1  0.496  0.748  0.544  1.0
  O  O25  1  0.752  0.004  0.044  1.0
  O  O26  1  0.955  0.955  0.833  1.0
  O  O27  1  0.545  0.545  0.333  1.0
  Sr  Sr28  1  0.000  0.000  0.500  1.0
  Sr  Sr29  1  0.500  0.500  0.000  1.0
  Sr  Sr30  1  0.251  0.251  0.776  1.0
  Sr  Sr31  1  0.249  0.249  0.276  1.0
  Sr  Sr32  1  0.764  0.264  0.750  1.0
  Sr  Sr33  1  0.236  0.736  0.250  1.0
  Sr  Sr34  1  0.736  0.236  0.250  1.0
  Sr  Sr35  1  0.264  0.764  0.750  1.0
  Sr  Sr36  1  0.751  0.751  0.724  1.0
  Sr  Sr37  1  0.749  0.749  0.224  1.0
  W  W38  1  0.000  0.000  0.000  1.0
  W  W39  1  0.500  0.500  0.500  1.0
  W  W40  1  0.000  0.500  0.000  1.0
  W  W41  1  0.000  0.500  0.500  1.0
  W  W42  1  0.500  1.000  0.000  1.0
  W  W43  1  0.500  0.000  0.500  1.0
[/CIF]
.