The material described by Dy(MoCo5)2 crystallizes in the orthorhombic Immm space group. Dy(1) is bonded in a 20-coordinate geometry to two equivalent Mo(1), two equivalent Co(4), four equivalent Co(1), four equivalent Co(2), and eight equivalent Co(3) atoms. Mo(1) is bonded in a 14-coordinate geometry to one Dy(1), one Mo(1), two equivalent Co(1), two equivalent Co(2), four equivalent Co(3), and four equivalent Co(4) atoms. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded to two equivalent Dy(1), two equivalent Mo(1), two equivalent Co(2), two equivalent Co(4), and four equivalent Co(3) atoms to form a mixture of distorted corner, face, and edge-sharing CoDy2Co8Mo2 cuboctahedra. In the second Co site, Co(2) is bonded in a 12-coordinate geometry to two equivalent Dy(1), two equivalent Mo(1), two equivalent Co(1), two equivalent Co(4), and four equivalent Co(3) atoms. In the third Co site, Co(3) is bonded to two equivalent Dy(1), two equivalent Mo(1), two equivalent Co(1), two equivalent Co(2), two equivalent Co(3), and two equivalent Co(4) atoms to form a mixture of distorted corner, face, and edge-sharing CoDy2Co8Mo2 cuboctahedra. In the fourth Co site, Co(4) is bonded in a 14-coordinate geometry to one Dy(1), four equivalent Mo(1), one Co(4), two equivalent Co(1), two equivalent Co(2), and four equivalent Co(3) atoms. is represented by the CIF card [CIF]
data_Dy(Co5Mo)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.681
_cell_length_b   6.420
_cell_length_c   6.420
_cell_angle_alpha   97.555
_cell_angle_beta   111.380
_cell_angle_gamma   68.620
_symmetry_Int_Tables_number   1
_cell_volume   167.272
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Dy  Dy0  1  0.000  0.000  0.000  1.0
  Co  Co1  1  0.710  0.790  0.210  1.0
  Co  Co2  1  0.290  0.210  0.790  1.0
  Co  Co3  1  0.500  0.778  0.778  1.0
  Co  Co4  1  0.500  0.222  0.222  1.0
  Co  Co5  1  0.500  0.000  0.500  1.0
  Co  Co6  1  0.000  0.000  0.500  1.0
  Co  Co7  1  0.500  0.500  0.000  1.0
  Co  Co8  1  0.000  0.500  0.000  1.0
  Co  Co9  1  0.641  0.359  0.641  1.0
  Co  Co10  1  0.359  0.641  0.359  1.0
  Mo  Mo11  1  0.000  0.359  0.359  1.0
  Mo  Mo12  1  0.000  0.641  0.641  1.0
[/CIF]
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The material described by Dy(MoCo5)2 crystallizes in the orthorhombic Immm space group. Dy(1) is bonded in a 20-coordinate geometry to two equivalent Mo(1), two equivalent Co(4), four equivalent Co(1), four equivalent Co(2), and eight equivalent Co(3) atoms. Mo(1) is bonded in a 14-coordinate geometry to one Dy(1), one Mo(1), two equivalent Co(1), two equivalent Co(2), four equivalent Co(3), and four equivalent Co(4) atoms. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded to two equivalent Dy(1), two equivalent Mo(1), two equivalent Co(2), two equivalent Co(4), and four equivalent Co(3) atoms to form a mixture of distorted corner, face, and edge-sharing CoDy2Co8Mo2 cuboctahedra. In the second Co site, Co(2) is bonded in a 12-coordinate geometry to two equivalent Dy(1), two equivalent Mo(1), two equivalent Co(1), two equivalent Co(4), and four equivalent Co(3) atoms. In the third Co site, Co(3) is bonded to two equivalent Dy(1), two equivalent Mo(1), two equivalent Co(1), two equivalent Co(2), two equivalent Co(3), and two equivalent Co(4) atoms to form a mixture of distorted corner, face, and edge-sharing CoDy2Co8Mo2 cuboctahedra. In the fourth Co site, Co(4) is bonded in a 14-coordinate geometry to one Dy(1), four equivalent Mo(1), one Co(4), two equivalent Co(1), two equivalent Co(2), and four equivalent Co(3) atoms. is represented by the CIF card [CIF]
data_Dy(Co5Mo)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.681
_cell_length_b   6.420
_cell_length_c   6.420
_cell_angle_alpha   97.555
_cell_angle_beta   111.380
_cell_angle_gamma   68.620
_symmetry_Int_Tables_number   1
_cell_volume   167.272
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Dy  Dy0  1  0.000  0.000  0.000  1.0
  Co  Co1  1  0.710  0.790  0.210  1.0
  Co  Co2  1  0.290  0.210  0.790  1.0
  Co  Co3  1  0.500  0.778  0.778  1.0
  Co  Co4  1  0.500  0.222  0.222  1.0
  Co  Co5  1  0.500  0.000  0.500  1.0
  Co  Co6  1  0.000  0.000  0.500  1.0
  Co  Co7  1  0.500  0.500  0.000  1.0
  Co  Co8  1  0.000  0.500  0.000  1.0
  Co  Co9  1  0.641  0.359  0.641  1.0
  Co  Co10  1  0.359  0.641  0.359  1.0
  Mo  Mo11  1  0.000  0.359  0.359  1.0
  Mo  Mo12  1  0.000  0.641  0.641  1.0
[/CIF]
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