The compound described by LiAg2F4 crystallizes in the tetragonal I-4 space group. Li(1) is bonded to four equivalent F(1) atoms to form distorted LiF4 tetrahedra that share corners with four equivalent Ag(2)F4 trigonal pyramids. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to four equivalent F(1) atoms. In the second Ag site, Ag(2) is bonded to four equivalent F(1) atoms to form distorted AgF4 trigonal pyramids that share corners with four equivalent Li(1)F4 tetrahedra. F(1) is bonded in a trigonal planar geometry to one Li(1), one Ag(1), and one Ag(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiAg2F4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.186
_cell_length_b   6.186
_cell_length_c   6.186
_cell_angle_alpha   130.305
_cell_angle_beta   130.305
_cell_angle_gamma   72.919
_symmetry_Int_Tables_number   1
_cell_volume   134.461
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.000  0.000  0.000  1.0
  Ag  Ag1  1  0.250  0.750  0.500  1.0
  Ag  Ag2  1  0.500  0.500  0.000  1.0
  F  F3  1  0.648  0.104  0.924  1.0
  F  F4  1  0.896  0.820  0.545  1.0
  F  F5  1  0.180  0.725  0.076  1.0
  F  F6  1  0.275  0.352  0.455  1.0
[/CIF]
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The compound described by LiAg2F4 crystallizes in the tetragonal I-4 space group. Li(1) is bonded to four equivalent F(1) atoms to form distorted LiF4 tetrahedra that share corners with four equivalent Ag(2)F4 trigonal pyramids. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to four equivalent F(1) atoms. In the second Ag site, Ag(2) is bonded to four equivalent F(1) atoms to form distorted AgF4 trigonal pyramids that share corners with four equivalent Li(1)F4 tetrahedra. F(1) is bonded in a trigonal planar geometry to one Li(1), one Ag(1), and one Ag(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiAg2F4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.186
_cell_length_b   6.186
_cell_length_c   6.186
_cell_angle_alpha   130.305
_cell_angle_beta   130.305
_cell_angle_gamma   72.919
_symmetry_Int_Tables_number   1
_cell_volume   134.461
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.000  0.000  0.000  1.0
  Ag  Ag1  1  0.250  0.750  0.500  1.0
  Ag  Ag2  1  0.500  0.500  0.000  1.0
  F  F3  1  0.648  0.104  0.924  1.0
  F  F4  1  0.896  0.820  0.545  1.0
  F  F5  1  0.180  0.725  0.076  1.0
  F  F6  1  0.275  0.352  0.455  1.0
[/CIF]
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