The material described by RhCl6(NH4)4NO3 is Silicon tetrafluoride-derived structured and crystallizes in the trigonal R32 space group. The structure is zero-dimensional and consists of twelve ammonium molecules, three hexachlororhodium molecules, and three nitric acid molecules. is represented by the CIF card [CIF]
data_H16RhN5(Cl2O)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.338
_cell_length_b   9.338
_cell_length_c   9.338
_cell_angle_alpha   43.554
_cell_angle_beta   43.554
_cell_angle_gamma   43.554
_symmetry_Int_Tables_number   1
_cell_volume   350.788
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.337  0.337  0.337  1.0
  H  H1  1  0.663  0.663  0.663  1.0
  H  H2  1  0.468  0.753  0.610  1.0
  H  H3  1  0.610  0.468  0.753  1.0
  H  H4  1  0.753  0.610  0.468  1.0
  H  H5  1  0.874  0.874  0.874  1.0
  H  H6  1  0.017  0.252  0.272  1.0
  H  H7  1  0.272  0.017  0.252  1.0
  H  H8  1  0.252  0.272  0.017  1.0
  H  H9  1  0.748  0.983  0.728  1.0
  H  H10  1  0.728  0.748  0.983  1.0
  H  H11  1  0.983  0.728  0.748  1.0
  H  H12  1  0.126  0.126  0.126  1.0
  H  H13  1  0.247  0.532  0.390  1.0
  H  H14  1  0.390  0.247  0.532  1.0
  H  H15  1  0.532  0.390  0.247  1.0
  Rh  Rh16  1  0.000  0.000  0.000  1.0
  N  N17  1  0.622  0.622  0.622  1.0
  N  N18  1  0.167  0.167  0.167  1.0
  N  N19  1  0.500  0.500  0.500  1.0
  N  N20  1  0.833  0.833  0.833  1.0
  N  N21  1  0.378  0.378  0.378  1.0
  Cl  Cl22  1  0.115  0.089  0.625  1.0
  Cl  Cl23  1  0.089  0.625  0.115  1.0
  Cl  Cl24  1  0.625  0.115  0.089  1.0
  Cl  Cl25  1  0.375  0.911  0.885  1.0
  Cl  Cl26  1  0.911  0.885  0.375  1.0
  Cl  Cl27  1  0.885  0.375  0.911  1.0
  O  O28  1  0.684  0.316  0.500  1.0
  O  O29  1  0.500  0.684  0.316  1.0
  O  O30  1  0.316  0.500  0.684  1.0
[/CIF]
.
The material described by RhCl6(NH4)4NO3 is Silicon tetrafluoride-derived structured and crystallizes in the trigonal R32 space group. The structure is zero-dimensional and consists of twelve ammonium molecules, three hexachlororhodium molecules, and three nitric acid molecules. is represented by the CIF card [CIF]
data_H16RhN5(Cl2O)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.338
_cell_length_b   9.338
_cell_length_c   9.338
_cell_angle_alpha   43.554
_cell_angle_beta   43.554
_cell_angle_gamma   43.554
_symmetry_Int_Tables_number   1
_cell_volume   350.788
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.337  0.337  0.337  1.0
  H  H1  1  0.663  0.663  0.663  1.0
  H  H2  1  0.468  0.753  0.610  1.0
  H  H3  1  0.610  0.468  0.753  1.0
  H  H4  1  0.753  0.610  0.468  1.0
  H  H5  1  0.874  0.874  0.874  1.0
  H  H6  1  0.017  0.252  0.272  1.0
  H  H7  1  0.272  0.017  0.252  1.0
  H  H8  1  0.252  0.272  0.017  1.0
  H  H9  1  0.748  0.983  0.728  1.0
  H  H10  1  0.728  0.748  0.983  1.0
  H  H11  1  0.983  0.728  0.748  1.0
  H  H12  1  0.126  0.126  0.126  1.0
  H  H13  1  0.247  0.532  0.390  1.0
  H  H14  1  0.390  0.247  0.532  1.0
  H  H15  1  0.532  0.390  0.247  1.0
  Rh  Rh16  1  0.000  0.000  0.000  1.0
  N  N17  1  0.622  0.622  0.622  1.0
  N  N18  1  0.167  0.167  0.167  1.0
  N  N19  1  0.500  0.500  0.500  1.0
  N  N20  1  0.833  0.833  0.833  1.0
  N  N21  1  0.378  0.378  0.378  1.0
  Cl  Cl22  1  0.115  0.089  0.625  1.0
  Cl  Cl23  1  0.089  0.625  0.115  1.0
  Cl  Cl24  1  0.625  0.115  0.089  1.0
  Cl  Cl25  1  0.375  0.911  0.885  1.0
  Cl  Cl26  1  0.911  0.885  0.375  1.0
  Cl  Cl27  1  0.885  0.375  0.911  1.0
  O  O28  1  0.684  0.316  0.500  1.0
  O  O29  1  0.500  0.684  0.316  1.0
  O  O30  1  0.316  0.500  0.684  1.0
[/CIF]
.