The crystal structure described by TcAgO2 crystallizes in the tetragonal I4_1/amd space group. Tc(1) is bonded in a distorted rectangular see-saw-like geometry to four equivalent O(1) atoms. Ag(1) is bonded to six equivalent O(1) atoms to form edge-sharing AgO6 octahedra. O(1) is bonded in a 5-coordinate geometry to two equivalent Tc(1) and three equivalent Ag(1) atoms. is represented by the CIF card [CIF]
data_TcAgO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.339
_cell_length_b   7.339
_cell_length_c   7.339
_cell_angle_alpha   131.352
_cell_angle_beta   131.352
_cell_angle_gamma   71.255
_symmetry_Int_Tables_number   1
_cell_volume   218.074
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tc  Tc0  1  0.375  0.125  0.250  1.0
  Tc  Tc1  1  0.875  0.125  0.750  1.0
  Tc  Tc2  1  0.875  0.125  0.250  1.0
  Tc  Tc3  1  0.875  0.625  0.750  1.0
  Ag  Ag4  1  0.875  0.625  0.250  1.0
  Ag  Ag5  1  0.375  0.625  0.750  1.0
  Ag  Ag6  1  0.375  0.625  0.250  1.0
  Ag  Ag7  1  0.375  0.125  0.750  1.0
  O  O8  1  0.178  0.376  0.198  1.0
  O  O9  1  0.178  0.979  0.802  1.0
  O  O10  1  0.126  0.428  0.698  1.0
  O  O11  1  0.572  0.874  0.302  1.0
  O  O12  1  0.729  0.428  0.302  1.0
  O  O13  1  0.572  0.271  0.698  1.0
  O  O14  1  0.624  0.822  0.802  1.0
  O  O15  1  0.021  0.822  0.198  1.0
[/CIF]
.
The crystal structure described by TcAgO2 crystallizes in the tetragonal I4_1/amd space group. Tc(1) is bonded in a distorted rectangular see-saw-like geometry to four equivalent O(1) atoms. Ag(1) is bonded to six equivalent O(1) atoms to form edge-sharing AgO6 octahedra. O(1) is bonded in a 5-coordinate geometry to two equivalent Tc(1) and three equivalent Ag(1) atoms. is represented by the CIF card [CIF]
data_TcAgO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.339
_cell_length_b   7.339
_cell_length_c   7.339
_cell_angle_alpha   131.352
_cell_angle_beta   131.352
_cell_angle_gamma   71.255
_symmetry_Int_Tables_number   1
_cell_volume   218.074
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tc  Tc0  1  0.375  0.125  0.250  1.0
  Tc  Tc1  1  0.875  0.125  0.750  1.0
  Tc  Tc2  1  0.875  0.125  0.250  1.0
  Tc  Tc3  1  0.875  0.625  0.750  1.0
  Ag  Ag4  1  0.875  0.625  0.250  1.0
  Ag  Ag5  1  0.375  0.625  0.750  1.0
  Ag  Ag6  1  0.375  0.625  0.250  1.0
  Ag  Ag7  1  0.375  0.125  0.750  1.0
  O  O8  1  0.178  0.376  0.198  1.0
  O  O9  1  0.178  0.979  0.802  1.0
  O  O10  1  0.126  0.428  0.698  1.0
  O  O11  1  0.572  0.874  0.302  1.0
  O  O12  1  0.729  0.428  0.302  1.0
  O  O13  1  0.572  0.271  0.698  1.0
  O  O14  1  0.624  0.822  0.802  1.0
  O  O15  1  0.021  0.822  0.198  1.0
[/CIF]
.