The compound described by VGeO4 is Rutile-derived structured and crystallizes in the orthorhombic Pbcn space group. V(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form VO6 octahedra that share corners with six equivalent Ge(1)O6 octahedra,  an edgeedge with one Ge(1)O6 octahedra, and edges with two equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-52°. Ge(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form GeO6 octahedra that share corners with four equivalent Ge(1)O6 octahedra, corners with six equivalent V(1)O6 octahedra, and  an edgeedge with one V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-52°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one V(1) and two equivalent Ge(1) atoms. In the second O site, O(2) is bonded in a distorted T-shaped geometry to two equivalent V(1) and one Ge(1) atom. is represented by the CIF card [CIF]
data_VGeO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.299
_cell_length_b   4.697
_cell_length_c   11.159
_cell_angle_alpha   90.000
_cell_angle_beta   89.999
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   225.343
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.500  0.750  0.056  1.0
  V  V1  1  0.000  0.250  0.444  1.0
  V  V2  1  1.000  0.750  0.556  1.0
  V  V3  1  0.500  0.250  0.944  1.0
  Ge  Ge4  1  0.000  0.750  0.815  1.0
  Ge  Ge5  1  0.500  0.250  0.685  1.0
  Ge  Ge6  1  0.500  0.750  0.315  1.0
  Ge  Ge7  1  1.000  0.250  0.185  1.0
  O  O8  1  0.227  0.078  0.312  1.0
  O  O9  1  0.273  0.578  0.188  1.0
  O  O10  1  0.273  0.078  0.812  1.0
  O  O11  1  0.227  0.578  0.688  1.0
  O  O12  1  0.773  0.422  0.312  1.0
  O  O13  1  0.727  0.922  0.188  1.0
  O  O14  1  0.727  0.422  0.812  1.0
  O  O15  1  0.773  0.922  0.688  1.0
  O  O16  1  0.256  0.590  0.438  1.0
  O  O17  1  0.244  0.090  0.061  1.0
  O  O18  1  0.256  0.090  0.562  1.0
  O  O19  1  0.244  0.590  0.938  1.0
  O  O20  1  0.756  0.410  0.061  1.0
  O  O21  1  0.744  0.910  0.438  1.0
  O  O22  1  0.756  0.910  0.938  1.0
  O  O23  1  0.744  0.410  0.562  1.0
[/CIF]
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The compound described by VGeO4 is Rutile-derived structured and crystallizes in the orthorhombic Pbcn space group. V(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form VO6 octahedra that share corners with six equivalent Ge(1)O6 octahedra,  an edgeedge with one Ge(1)O6 octahedra, and edges with two equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-52°. Ge(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form GeO6 octahedra that share corners with four equivalent Ge(1)O6 octahedra, corners with six equivalent V(1)O6 octahedra, and  an edgeedge with one V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-52°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one V(1) and two equivalent Ge(1) atoms. In the second O site, O(2) is bonded in a distorted T-shaped geometry to two equivalent V(1) and one Ge(1) atom. is represented by the CIF card [CIF]
data_VGeO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.299
_cell_length_b   4.697
_cell_length_c   11.159
_cell_angle_alpha   90.000
_cell_angle_beta   89.999
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   225.343
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.500  0.750  0.056  1.0
  V  V1  1  0.000  0.250  0.444  1.0
  V  V2  1  1.000  0.750  0.556  1.0
  V  V3  1  0.500  0.250  0.944  1.0
  Ge  Ge4  1  0.000  0.750  0.815  1.0
  Ge  Ge5  1  0.500  0.250  0.685  1.0
  Ge  Ge6  1  0.500  0.750  0.315  1.0
  Ge  Ge7  1  1.000  0.250  0.185  1.0
  O  O8  1  0.227  0.078  0.312  1.0
  O  O9  1  0.273  0.578  0.188  1.0
  O  O10  1  0.273  0.078  0.812  1.0
  O  O11  1  0.227  0.578  0.688  1.0
  O  O12  1  0.773  0.422  0.312  1.0
  O  O13  1  0.727  0.922  0.188  1.0
  O  O14  1  0.727  0.422  0.812  1.0
  O  O15  1  0.773  0.922  0.688  1.0
  O  O16  1  0.256  0.590  0.438  1.0
  O  O17  1  0.244  0.090  0.061  1.0
  O  O18  1  0.256  0.090  0.562  1.0
  O  O19  1  0.244  0.590  0.938  1.0
  O  O20  1  0.756  0.410  0.061  1.0
  O  O21  1  0.744  0.910  0.438  1.0
  O  O22  1  0.756  0.910  0.938  1.0
  O  O23  1  0.744  0.410  0.562  1.0
[/CIF]
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