The material described by Cs2PbCu(NO2)6 crystallizes in the cubic Fm-3 space group. The structure consists of four 7439-92-1 atoms inside a Cs2Cu(NO2)6 framework. In the Cs2Cu(NO2)6 framework, Cs(1) is bonded to twelve equivalent O(1) atoms to form edge-sharing CsO12 cuboctahedra. Cu(1) is bonded in an octahedral geometry to six equivalent N(1) atoms. N(1) is bonded in a trigonal planar geometry to one Cu(1) and two equivalent O(1) atoms. O(1) is bonded in a single-bond geometry to two equivalent Cs(1) and one N(1) atom. is represented by the CIF file [CIF]
data_Cs2CuPb(NO2)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.860
_cell_length_b   7.860
_cell_length_c   7.860
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   343.368
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.250  0.250  0.250  1.0
  Cs  Cs1  1  0.750  0.750  0.750  1.0
  Cu  Cu2  1  0.000  0.000  0.000  1.0
  Pb  Pb3  1  0.500  0.500  0.500  1.0
  N  N4  1  0.806  0.194  0.194  1.0
  N  N5  1  0.194  0.806  0.806  1.0
  N  N6  1  0.194  0.194  0.806  1.0
  N  N7  1  0.806  0.806  0.194  1.0
  N  N8  1  0.194  0.806  0.194  1.0
  N  N9  1  0.806  0.194  0.806  1.0
  O  O10  1  0.843  0.157  0.350  1.0
  O  O11  1  0.157  0.843  0.650  1.0
  O  O12  1  0.350  0.650  0.843  1.0
  O  O13  1  0.650  0.350  0.157  1.0
  O  O14  1  0.157  0.350  0.843  1.0
  O  O15  1  0.350  0.157  0.650  1.0
  O  O16  1  0.843  0.650  0.157  1.0
  O  O17  1  0.650  0.843  0.350  1.0
  O  O18  1  0.350  0.843  0.157  1.0
  O  O19  1  0.843  0.350  0.650  1.0
  O  O20  1  0.157  0.650  0.350  1.0
  O  O21  1  0.650  0.157  0.843  1.0
[/CIF]
.
The material described by Cs2PbCu(NO2)6 crystallizes in the cubic Fm-3 space group. The structure consists of four 7439-92-1 atoms inside a Cs2Cu(NO2)6 framework. In the Cs2Cu(NO2)6 framework, Cs(1) is bonded to twelve equivalent O(1) atoms to form edge-sharing CsO12 cuboctahedra. Cu(1) is bonded in an octahedral geometry to six equivalent N(1) atoms. N(1) is bonded in a trigonal planar geometry to one Cu(1) and two equivalent O(1) atoms. O(1) is bonded in a single-bond geometry to two equivalent Cs(1) and one N(1) atom. is represented by the CIF file [CIF]
data_Cs2CuPb(NO2)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.860
_cell_length_b   7.860
_cell_length_c   7.860
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   343.368
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.250  0.250  0.250  1.0
  Cs  Cs1  1  0.750  0.750  0.750  1.0
  Cu  Cu2  1  0.000  0.000  0.000  1.0
  Pb  Pb3  1  0.500  0.500  0.500  1.0
  N  N4  1  0.806  0.194  0.194  1.0
  N  N5  1  0.194  0.806  0.806  1.0
  N  N6  1  0.194  0.194  0.806  1.0
  N  N7  1  0.806  0.806  0.194  1.0
  N  N8  1  0.194  0.806  0.194  1.0
  N  N9  1  0.806  0.194  0.806  1.0
  O  O10  1  0.843  0.157  0.350  1.0
  O  O11  1  0.157  0.843  0.650  1.0
  O  O12  1  0.350  0.650  0.843  1.0
  O  O13  1  0.650  0.350  0.157  1.0
  O  O14  1  0.157  0.350  0.843  1.0
  O  O15  1  0.350  0.157  0.650  1.0
  O  O16  1  0.843  0.650  0.157  1.0
  O  O17  1  0.650  0.843  0.350  1.0
  O  O18  1  0.350  0.843  0.157  1.0
  O  O19  1  0.843  0.350  0.650  1.0
  O  O20  1  0.157  0.650  0.350  1.0
  O  O21  1  0.650  0.157  0.843  1.0
[/CIF]
.