The material structure described by CsSb(SO4)2 crystallizes in the orthorhombic P2_12_12_1 space group. Cs(1) is bonded in a 13-coordinate geometry to one O(2), two equivalent O(1), two equivalent O(3), two equivalent O(4), two equivalent O(5), two equivalent O(6), and two equivalent O(8) atoms. Sb(1) is bonded in a 4-coordinate geometry to one O(3), one O(4), one O(7), and one O(8) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. In the second S site, S(2) is bonded in a tetrahedral geometry to one O(5), one O(6), one O(7), and one O(8) atom. There are eight inequivalent O sites. In the first O site, O(5) is bonded in a single-bond geometry to two equivalent Cs(1) and one S(2) atom. In the second O site, O(6) is bonded in a single-bond geometry to two equivalent Cs(1) and one S(2) atom. In the third O site, O(7) is bonded in a bent 120 degrees geometry to one Sb(1) and one S(2) atom. In the fourth O site, O(8) is bonded in a distorted bent 120 degrees geometry to two equivalent Cs(1), one Sb(1), and one S(2) atom. In the fifth O site, O(1) is bonded in a single-bond geometry to two equivalent Cs(1) and one S(1) atom. In the sixth O site, O(2) is bonded in a single-bond geometry to one Cs(1) and one S(1) atom. In the seventh O site, O(3) is bonded in a 2-coordinate geometry to two equivalent Cs(1), one Sb(1), and one S(1) atom. In the eighth O site, O(4) is bonded in a distorted bent 120 degrees geometry to two equivalent Cs(1), one Sb(1), and one S(1) atom. is represented by the CIF file [CIF]
data_CsSb(SO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.336
_cell_length_b   9.824
_cell_length_c   15.454
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   810.205
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.763  0.338  0.761  1.0
  Cs  Cs1  1  0.737  0.662  0.261  1.0
  Cs  Cs2  1  0.263  0.162  0.239  1.0
  Cs  Cs3  1  0.237  0.838  0.739  1.0
  Sb  Sb4  1  0.794  0.987  0.979  1.0
  Sb  Sb5  1  0.706  0.013  0.479  1.0
  Sb  Sb6  1  0.294  0.513  0.021  1.0
  Sb  Sb7  1  0.206  0.487  0.521  1.0
  S  S8  1  0.737  0.655  0.584  1.0
  S  S9  1  0.763  0.345  0.084  1.0
  S  S10  1  0.237  0.845  0.416  1.0
  S  S11  1  0.263  0.155  0.916  1.0
  S  S12  1  0.728  0.672  0.902  1.0
  S  S13  1  0.772  0.328  0.402  1.0
  S  S14  1  0.228  0.828  0.098  1.0
  S  S15  1  0.272  0.172  0.598  1.0
  O  O16  1  0.740  0.781  0.633  1.0
  O  O17  1  0.760  0.219  0.133  1.0
  O  O18  1  0.240  0.719  0.367  1.0
  O  O19  1  0.260  0.281  0.867  1.0
  O  O20  1  0.743  0.332  0.990  1.0
  O  O21  1  0.757  0.668  0.490  1.0
  O  O22  1  0.243  0.168  0.010  1.0
  O  O23  1  0.257  0.832  0.510  1.0
  O  O24  1  0.510  0.571  0.609  1.0
  O  O25  1  0.990  0.429  0.109  1.0
  O  O26  1  0.010  0.929  0.391  1.0
  O  O27  1  0.490  0.071  0.891  1.0
  O  O28  1  0.968  0.569  0.616  1.0
  O  O29  1  0.532  0.431  0.116  1.0
  O  O30  1  0.468  0.931  0.384  1.0
  O  O31  1  0.032  0.069  0.884  1.0
  O  O32  1  0.986  0.624  0.892  1.0
  O  O33  1  0.514  0.376  0.392  1.0
  O  O34  1  0.486  0.876  0.108  1.0
  O  O35  1  0.014  0.124  0.608  1.0
  O  O36  1  0.554  0.620  0.838  1.0
  O  O37  1  0.946  0.380  0.338  1.0
  O  O38  1  0.054  0.880  0.162  1.0
  O  O39  1  0.446  0.120  0.662  1.0
  O  O40  1  0.637  0.645  0.993  1.0
  O  O41  1  0.863  0.355  0.493  1.0
  O  O42  1  0.137  0.855  0.007  1.0
  O  O43  1  0.363  0.145  0.507  1.0
  O  O44  1  0.725  0.831  0.891  1.0
  O  O45  1  0.775  0.169  0.391  1.0
  O  O46  1  0.225  0.669  0.109  1.0
  O  O47  1  0.275  0.331  0.609  1.0
[/CIF]
.
The material structure described by CsSb(SO4)2 crystallizes in the orthorhombic P2_12_12_1 space group. Cs(1) is bonded in a 13-coordinate geometry to one O(2), two equivalent O(1), two equivalent O(3), two equivalent O(4), two equivalent O(5), two equivalent O(6), and two equivalent O(8) atoms. Sb(1) is bonded in a 4-coordinate geometry to one O(3), one O(4), one O(7), and one O(8) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. In the second S site, S(2) is bonded in a tetrahedral geometry to one O(5), one O(6), one O(7), and one O(8) atom. There are eight inequivalent O sites. In the first O site, O(5) is bonded in a single-bond geometry to two equivalent Cs(1) and one S(2) atom. In the second O site, O(6) is bonded in a single-bond geometry to two equivalent Cs(1) and one S(2) atom. In the third O site, O(7) is bonded in a bent 120 degrees geometry to one Sb(1) and one S(2) atom. In the fourth O site, O(8) is bonded in a distorted bent 120 degrees geometry to two equivalent Cs(1), one Sb(1), and one S(2) atom. In the fifth O site, O(1) is bonded in a single-bond geometry to two equivalent Cs(1) and one S(1) atom. In the sixth O site, O(2) is bonded in a single-bond geometry to one Cs(1) and one S(1) atom. In the seventh O site, O(3) is bonded in a 2-coordinate geometry to two equivalent Cs(1), one Sb(1), and one S(1) atom. In the eighth O site, O(4) is bonded in a distorted bent 120 degrees geometry to two equivalent Cs(1), one Sb(1), and one S(1) atom. is represented by the CIF file [CIF]
data_CsSb(SO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.336
_cell_length_b   9.824
_cell_length_c   15.454
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   810.205
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.763  0.338  0.761  1.0
  Cs  Cs1  1  0.737  0.662  0.261  1.0
  Cs  Cs2  1  0.263  0.162  0.239  1.0
  Cs  Cs3  1  0.237  0.838  0.739  1.0
  Sb  Sb4  1  0.794  0.987  0.979  1.0
  Sb  Sb5  1  0.706  0.013  0.479  1.0
  Sb  Sb6  1  0.294  0.513  0.021  1.0
  Sb  Sb7  1  0.206  0.487  0.521  1.0
  S  S8  1  0.737  0.655  0.584  1.0
  S  S9  1  0.763  0.345  0.084  1.0
  S  S10  1  0.237  0.845  0.416  1.0
  S  S11  1  0.263  0.155  0.916  1.0
  S  S12  1  0.728  0.672  0.902  1.0
  S  S13  1  0.772  0.328  0.402  1.0
  S  S14  1  0.228  0.828  0.098  1.0
  S  S15  1  0.272  0.172  0.598  1.0
  O  O16  1  0.740  0.781  0.633  1.0
  O  O17  1  0.760  0.219  0.133  1.0
  O  O18  1  0.240  0.719  0.367  1.0
  O  O19  1  0.260  0.281  0.867  1.0
  O  O20  1  0.743  0.332  0.990  1.0
  O  O21  1  0.757  0.668  0.490  1.0
  O  O22  1  0.243  0.168  0.010  1.0
  O  O23  1  0.257  0.832  0.510  1.0
  O  O24  1  0.510  0.571  0.609  1.0
  O  O25  1  0.990  0.429  0.109  1.0
  O  O26  1  0.010  0.929  0.391  1.0
  O  O27  1  0.490  0.071  0.891  1.0
  O  O28  1  0.968  0.569  0.616  1.0
  O  O29  1  0.532  0.431  0.116  1.0
  O  O30  1  0.468  0.931  0.384  1.0
  O  O31  1  0.032  0.069  0.884  1.0
  O  O32  1  0.986  0.624  0.892  1.0
  O  O33  1  0.514  0.376  0.392  1.0
  O  O34  1  0.486  0.876  0.108  1.0
  O  O35  1  0.014  0.124  0.608  1.0
  O  O36  1  0.554  0.620  0.838  1.0
  O  O37  1  0.946  0.380  0.338  1.0
  O  O38  1  0.054  0.880  0.162  1.0
  O  O39  1  0.446  0.120  0.662  1.0
  O  O40  1  0.637  0.645  0.993  1.0
  O  O41  1  0.863  0.355  0.493  1.0
  O  O42  1  0.137  0.855  0.007  1.0
  O  O43  1  0.363  0.145  0.507  1.0
  O  O44  1  0.725  0.831  0.891  1.0
  O  O45  1  0.775  0.169  0.391  1.0
  O  O46  1  0.225  0.669  0.109  1.0
  O  O47  1  0.275  0.331  0.609  1.0
[/CIF]
.