The material structure described by V2CuP2O13O2 crystallizes in the triclinic P-1 space group. The structure consists of two 7782-44-7 molecules inside a V2CuP2O13 framework. In the V2CuP2O13 framework, there are two inequivalent V sites. In the first V site, V(1) is bonded in a 6-coordinate geometry to one O(10), one O(11), one O(12), one O(13), one O(5), and one O(6) atom. In the second V site, V(2) is bonded to one O(14), one O(2), one O(3), one O(4), and one O(7) atom to form distorted VO5 trigonal bipyramids that share  a cornercorner with one P(1)O4 tetrahedra and corners with three equivalent P(2)O4 tetrahedra. Cu(1) is bonded in a distorted rectangular see-saw-like geometry to one O(8), one O(9), and two equivalent O(10) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(11), one O(12), one O(6), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one V(2)O5 trigonal bipyramid. In the second P site, P(2) is bonded to one O(13), one O(14), one O(3), and one O(4) atom to form PO4 tetrahedra that share corners with three equivalent V(2)O5 trigonal bipyramids. There are thirteen inequivalent O sites. In the first O site, O(12) is bonded in a 2-coordinate geometry to one V(1) and one P(1) atom. In the second O site, O(13) is bonded in a distorted bent 120 degrees geometry to one V(1) and one P(2) atom. In the third O site, O(14) is bonded in a bent 120 degrees geometry to one V(2) and one P(2) atom. In the fourth O site, O(2) is bonded in a single-bond geometry to one V(2) atom. In the fifth O site, O(3) is bonded in a bent 120 degrees geometry to one V(2) and one P(2) atom. In the sixth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one V(2) and one P(2) atom. In the seventh O site, O(5) is bonded in a single-bond geometry to one V(1) atom. In the eighth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one V(1) and one P(1) atom. In the ninth O site, O(7) is bonded in a distorted bent 120 degrees geometry to one V(2) and one P(1) atom. In the tenth O site, O(8) is bonded in a single-bond geometry to one Cu(1) atom. In the eleventh O site, O(9) is bonded in a single-bond geometry to one Cu(1) atom. In the twelfth O site, O(10) is bonded in a distorted trigonal non-coplanar geometry to one V(1) and two equivalent Cu(1) atoms. In the thirteenth O site, O(11) is bonded in a distorted bent 120 degrees geometry to one V(1) and one P(1) atom. is represented by the CIF card [CIF]
data_V2CuP2O15
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.278
_cell_length_b   7.602
_cell_length_c   12.597
_cell_angle_alpha   104.233
_cell_angle_beta   90.945
_cell_angle_gamma   96.436
_symmetry_Int_Tables_number   1
_cell_volume   578.460
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.238  0.409  0.613  1.0
  V  V1  1  0.762  0.591  0.387  1.0
  V  V2  1  0.758  0.565  0.885  1.0
  V  V3  1  0.242  0.435  0.115  1.0
  Cu  Cu4  1  0.891  0.008  0.592  1.0
  Cu  Cu5  1  0.109  0.992  0.408  1.0
  P  P6  1  0.747  0.495  0.624  1.0
  P  P7  1  0.253  0.505  0.376  1.0
  P  P8  1  0.247  0.493  0.874  1.0
  P  P9  1  0.753  0.507  0.126  1.0
  O  O10  1  0.745  0.955  0.920  1.0
  O  O11  1  0.255  0.045  0.080  1.0
  O  O12  1  0.727  0.348  0.856  1.0
  O  O13  1  0.273  0.652  0.144  1.0
  O  O14  1  0.066  0.620  0.891  1.0
  O  O15  1  0.934  0.380  0.109  1.0
  O  O16  1  0.464  0.619  0.894  1.0
  O  O17  1  0.536  0.381  0.106  1.0
  O  O18  1  0.263  0.628  0.646  1.0
  O  O19  1  0.737  0.372  0.354  1.0
  O  O20  1  0.532  0.367  0.602  1.0
  O  O21  1  0.468  0.633  0.398  1.0
  O  O22  1  0.761  0.616  0.743  1.0
  O  O23  1  0.239  0.384  0.257  1.0
  O  O24  1  0.637  0.964  0.648  1.0
  O  O25  1  0.363  0.036  0.352  1.0
  O  O26  1  0.925  0.051  0.736  1.0
  O  O27  1  0.075  0.949  0.264  1.0
  O  O28  1  0.162  0.085  0.554  1.0
  O  O29  1  0.838  0.915  0.446  1.0
  O  O30  1  0.227  0.375  0.453  1.0
  O  O31  1  0.773  0.625  0.547  1.0
  O  O32  1  0.925  0.365  0.606  1.0
  O  O33  1  0.075  0.635  0.394  1.0
  O  O34  1  0.234  0.365  0.757  1.0
  O  O35  1  0.766  0.635  0.243  1.0
  O  O36  1  0.772  0.629  0.043  1.0
  O  O37  1  0.228  0.371  0.957  1.0
  O  O38  1  0.589  0.991  0.874  1.0
  O  O39  1  0.411  0.009  0.126  1.0
[/CIF]
.
The material structure described by V2CuP2O13O2 crystallizes in the triclinic P-1 space group. The structure consists of two 7782-44-7 molecules inside a V2CuP2O13 framework. In the V2CuP2O13 framework, there are two inequivalent V sites. In the first V site, V(1) is bonded in a 6-coordinate geometry to one O(10), one O(11), one O(12), one O(13), one O(5), and one O(6) atom. In the second V site, V(2) is bonded to one O(14), one O(2), one O(3), one O(4), and one O(7) atom to form distorted VO5 trigonal bipyramids that share  a cornercorner with one P(1)O4 tetrahedra and corners with three equivalent P(2)O4 tetrahedra. Cu(1) is bonded in a distorted rectangular see-saw-like geometry to one O(8), one O(9), and two equivalent O(10) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(11), one O(12), one O(6), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one V(2)O5 trigonal bipyramid. In the second P site, P(2) is bonded to one O(13), one O(14), one O(3), and one O(4) atom to form PO4 tetrahedra that share corners with three equivalent V(2)O5 trigonal bipyramids. There are thirteen inequivalent O sites. In the first O site, O(12) is bonded in a 2-coordinate geometry to one V(1) and one P(1) atom. In the second O site, O(13) is bonded in a distorted bent 120 degrees geometry to one V(1) and one P(2) atom. In the third O site, O(14) is bonded in a bent 120 degrees geometry to one V(2) and one P(2) atom. In the fourth O site, O(2) is bonded in a single-bond geometry to one V(2) atom. In the fifth O site, O(3) is bonded in a bent 120 degrees geometry to one V(2) and one P(2) atom. In the sixth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one V(2) and one P(2) atom. In the seventh O site, O(5) is bonded in a single-bond geometry to one V(1) atom. In the eighth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one V(1) and one P(1) atom. In the ninth O site, O(7) is bonded in a distorted bent 120 degrees geometry to one V(2) and one P(1) atom. In the tenth O site, O(8) is bonded in a single-bond geometry to one Cu(1) atom. In the eleventh O site, O(9) is bonded in a single-bond geometry to one Cu(1) atom. In the twelfth O site, O(10) is bonded in a distorted trigonal non-coplanar geometry to one V(1) and two equivalent Cu(1) atoms. In the thirteenth O site, O(11) is bonded in a distorted bent 120 degrees geometry to one V(1) and one P(1) atom. is represented by the CIF card [CIF]
data_V2CuP2O15
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.278
_cell_length_b   7.602
_cell_length_c   12.597
_cell_angle_alpha   104.233
_cell_angle_beta   90.945
_cell_angle_gamma   96.436
_symmetry_Int_Tables_number   1
_cell_volume   578.460
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.238  0.409  0.613  1.0
  V  V1  1  0.762  0.591  0.387  1.0
  V  V2  1  0.758  0.565  0.885  1.0
  V  V3  1  0.242  0.435  0.115  1.0
  Cu  Cu4  1  0.891  0.008  0.592  1.0
  Cu  Cu5  1  0.109  0.992  0.408  1.0
  P  P6  1  0.747  0.495  0.624  1.0
  P  P7  1  0.253  0.505  0.376  1.0
  P  P8  1  0.247  0.493  0.874  1.0
  P  P9  1  0.753  0.507  0.126  1.0
  O  O10  1  0.745  0.955  0.920  1.0
  O  O11  1  0.255  0.045  0.080  1.0
  O  O12  1  0.727  0.348  0.856  1.0
  O  O13  1  0.273  0.652  0.144  1.0
  O  O14  1  0.066  0.620  0.891  1.0
  O  O15  1  0.934  0.380  0.109  1.0
  O  O16  1  0.464  0.619  0.894  1.0
  O  O17  1  0.536  0.381  0.106  1.0
  O  O18  1  0.263  0.628  0.646  1.0
  O  O19  1  0.737  0.372  0.354  1.0
  O  O20  1  0.532  0.367  0.602  1.0
  O  O21  1  0.468  0.633  0.398  1.0
  O  O22  1  0.761  0.616  0.743  1.0
  O  O23  1  0.239  0.384  0.257  1.0
  O  O24  1  0.637  0.964  0.648  1.0
  O  O25  1  0.363  0.036  0.352  1.0
  O  O26  1  0.925  0.051  0.736  1.0
  O  O27  1  0.075  0.949  0.264  1.0
  O  O28  1  0.162  0.085  0.554  1.0
  O  O29  1  0.838  0.915  0.446  1.0
  O  O30  1  0.227  0.375  0.453  1.0
  O  O31  1  0.773  0.625  0.547  1.0
  O  O32  1  0.925  0.365  0.606  1.0
  O  O33  1  0.075  0.635  0.394  1.0
  O  O34  1  0.234  0.365  0.757  1.0
  O  O35  1  0.766  0.635  0.243  1.0
  O  O36  1  0.772  0.629  0.043  1.0
  O  O37  1  0.228  0.371  0.957  1.0
  O  O38  1  0.589  0.991  0.874  1.0
  O  O39  1  0.411  0.009  0.126  1.0
[/CIF]
.