The material structure described by LiMn2P3O10 crystallizes in the monoclinic C2/c space group. Li(1) is bonded to two equivalent O(3) and two equivalent O(4) atoms to form distorted LiO4 trigonal pyramids that share corners with four equivalent P(1)O4 tetrahedra and edges with two equivalent Mn(1)O4 tetrahedra. Mn(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form distorted MnO4 tetrahedra that share  a cornercorner with one P(2)O4 tetrahedra, corners with three equivalent P(1)O4 tetrahedra, and  an edgeedge with one Li(1)O4 trigonal pyramid. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(2), one O(3), one O(4), and one O(5) atom to form PO4 tetrahedra that share  a cornercorner with one P(2)O4 tetrahedra, corners with three equivalent Mn(1)O4 tetrahedra, and corners with two equivalent Li(1)O4 trigonal pyramids. In the second P site, P(2) is bonded to two equivalent O(1) and two equivalent O(5) atoms to form PO4 tetrahedra that share corners with two equivalent Mn(1)O4 tetrahedra and corners with two equivalent P(1)O4 tetrahedra. There are five inequivalent O sites. In the first O site, O(4) is bonded in a distorted trigonal planar geometry to one Li(1), one Mn(1), and one P(1) atom. In the second O site, O(5) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. In the third O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one P(2) atom. In the fourth O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one P(1) atom. In the fifth O site, O(3) is bonded in a 3-coordinate geometry to one Li(1), one Mn(1), and one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiMn2P3O10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.034
_cell_length_b   9.034
_cell_length_c   11.935
_cell_angle_alpha   43.974
_cell_angle_beta   43.974
_cell_angle_gamma   57.534
_symmetry_Int_Tables_number   1
_cell_volume   469.195
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.839  0.161  0.250  1.0
  Li  Li1  1  0.161  0.839  0.750  1.0
  Mn  Mn2  1  0.206  0.663  0.585  1.0
  Mn  Mn3  1  0.663  0.206  0.085  1.0
  Mn  Mn4  1  0.337  0.794  0.915  1.0
  Mn  Mn5  1  0.794  0.337  0.415  1.0
  P  P6  1  0.253  0.358  0.072  1.0
  P  P7  1  0.670  0.330  0.750  1.0
  P  P8  1  0.358  0.253  0.572  1.0
  P  P9  1  0.642  0.747  0.428  1.0
  P  P10  1  0.747  0.642  0.928  1.0
  P  P11  1  0.330  0.670  0.250  1.0
  O  O12  1  0.745  0.225  0.659  1.0
  O  O13  1  0.728  0.645  0.328  1.0
  O  O14  1  0.225  0.745  0.159  1.0
  O  O15  1  0.043  0.255  0.213  1.0
  O  O16  1  0.255  0.775  0.341  1.0
  O  O17  1  0.272  0.355  0.672  1.0
  O  O18  1  0.775  0.255  0.841  1.0
  O  O19  1  0.957  0.745  0.787  1.0
  O  O20  1  0.355  0.272  0.172  1.0
  O  O21  1  0.777  0.397  0.043  1.0
  O  O22  1  0.586  0.698  0.090  1.0
  O  O23  1  0.745  0.957  0.287  1.0
  O  O24  1  0.397  0.777  0.543  1.0
  O  O25  1  0.302  0.414  0.410  1.0
  O  O26  1  0.698  0.586  0.590  1.0
  O  O27  1  0.603  0.223  0.457  1.0
  O  O28  1  0.255  0.043  0.713  1.0
  O  O29  1  0.414  0.302  0.910  1.0
  O  O30  1  0.223  0.603  0.957  1.0
  O  O31  1  0.645  0.728  0.828  1.0
[/CIF]
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The material structure described by LiMn2P3O10 crystallizes in the monoclinic C2/c space group. Li(1) is bonded to two equivalent O(3) and two equivalent O(4) atoms to form distorted LiO4 trigonal pyramids that share corners with four equivalent P(1)O4 tetrahedra and edges with two equivalent Mn(1)O4 tetrahedra. Mn(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form distorted MnO4 tetrahedra that share  a cornercorner with one P(2)O4 tetrahedra, corners with three equivalent P(1)O4 tetrahedra, and  an edgeedge with one Li(1)O4 trigonal pyramid. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(2), one O(3), one O(4), and one O(5) atom to form PO4 tetrahedra that share  a cornercorner with one P(2)O4 tetrahedra, corners with three equivalent Mn(1)O4 tetrahedra, and corners with two equivalent Li(1)O4 trigonal pyramids. In the second P site, P(2) is bonded to two equivalent O(1) and two equivalent O(5) atoms to form PO4 tetrahedra that share corners with two equivalent Mn(1)O4 tetrahedra and corners with two equivalent P(1)O4 tetrahedra. There are five inequivalent O sites. In the first O site, O(4) is bonded in a distorted trigonal planar geometry to one Li(1), one Mn(1), and one P(1) atom. In the second O site, O(5) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. In the third O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one P(2) atom. In the fourth O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one P(1) atom. In the fifth O site, O(3) is bonded in a 3-coordinate geometry to one Li(1), one Mn(1), and one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiMn2P3O10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.034
_cell_length_b   9.034
_cell_length_c   11.935
_cell_angle_alpha   43.974
_cell_angle_beta   43.974
_cell_angle_gamma   57.534
_symmetry_Int_Tables_number   1
_cell_volume   469.195
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.839  0.161  0.250  1.0
  Li  Li1  1  0.161  0.839  0.750  1.0
  Mn  Mn2  1  0.206  0.663  0.585  1.0
  Mn  Mn3  1  0.663  0.206  0.085  1.0
  Mn  Mn4  1  0.337  0.794  0.915  1.0
  Mn  Mn5  1  0.794  0.337  0.415  1.0
  P  P6  1  0.253  0.358  0.072  1.0
  P  P7  1  0.670  0.330  0.750  1.0
  P  P8  1  0.358  0.253  0.572  1.0
  P  P9  1  0.642  0.747  0.428  1.0
  P  P10  1  0.747  0.642  0.928  1.0
  P  P11  1  0.330  0.670  0.250  1.0
  O  O12  1  0.745  0.225  0.659  1.0
  O  O13  1  0.728  0.645  0.328  1.0
  O  O14  1  0.225  0.745  0.159  1.0
  O  O15  1  0.043  0.255  0.213  1.0
  O  O16  1  0.255  0.775  0.341  1.0
  O  O17  1  0.272  0.355  0.672  1.0
  O  O18  1  0.775  0.255  0.841  1.0
  O  O19  1  0.957  0.745  0.787  1.0
  O  O20  1  0.355  0.272  0.172  1.0
  O  O21  1  0.777  0.397  0.043  1.0
  O  O22  1  0.586  0.698  0.090  1.0
  O  O23  1  0.745  0.957  0.287  1.0
  O  O24  1  0.397  0.777  0.543  1.0
  O  O25  1  0.302  0.414  0.410  1.0
  O  O26  1  0.698  0.586  0.590  1.0
  O  O27  1  0.603  0.223  0.457  1.0
  O  O28  1  0.255  0.043  0.713  1.0
  O  O29  1  0.414  0.302  0.910  1.0
  O  O30  1  0.223  0.603  0.957  1.0
  O  O31  1  0.645  0.728  0.828  1.0
[/CIF]
.