The compound described by KHo(CO3)2 crystallizes in the monoclinic C2/c space group. K(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(3), and four equivalent O(2) atoms. Ho(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), and four equivalent O(3) atoms. C(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one K(1), one Ho(1), and one C(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent K(1), one Ho(1), and one C(1) atom. In the third O site, O(3) is bonded in a 1-coordinate geometry to one K(1), two equivalent Ho(1), and one C(1) atom. is represented by the CIF card [CIF]
data_KHo(CO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.325
_cell_length_b   6.325
_cell_length_c   6.857
_cell_angle_alpha   77.206
_cell_angle_beta   77.206
_cell_angle_gamma   97.850
_symmetry_Int_Tables_number   1
_cell_volume   255.881
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.878  0.122  0.250  1.0
  K  K1  1  0.122  0.878  0.750  1.0
  Ho  Ho2  1  0.407  0.593  0.250  1.0
  Ho  Ho3  1  0.593  0.407  0.750  1.0
  C  C4  1  0.604  0.857  0.747  1.0
  C  C5  1  0.143  0.396  0.753  1.0
  C  C6  1  0.396  0.143  0.253  1.0
  C  C7  1  0.857  0.604  0.247  1.0
  O  O8  1  0.059  0.591  0.226  1.0
  O  O9  1  0.409  0.941  0.274  1.0
  O  O10  1  0.941  0.409  0.774  1.0
  O  O11  1  0.591  0.059  0.726  1.0
  O  O12  1  0.791  0.744  0.119  1.0
  O  O13  1  0.256  0.209  0.381  1.0
  O  O14  1  0.209  0.256  0.881  1.0
  O  O15  1  0.744  0.791  0.619  1.0
  O  O16  1  0.701  0.465  0.397  1.0
  O  O17  1  0.535  0.299  0.103  1.0
  O  O18  1  0.299  0.535  0.603  1.0
  O  O19  1  0.465  0.701  0.897  1.0
[/CIF]
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The compound described by KHo(CO3)2 crystallizes in the monoclinic C2/c space group. K(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(3), and four equivalent O(2) atoms. Ho(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), and four equivalent O(3) atoms. C(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one K(1), one Ho(1), and one C(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent K(1), one Ho(1), and one C(1) atom. In the third O site, O(3) is bonded in a 1-coordinate geometry to one K(1), two equivalent Ho(1), and one C(1) atom. is represented by the CIF card [CIF]
data_KHo(CO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.325
_cell_length_b   6.325
_cell_length_c   6.857
_cell_angle_alpha   77.206
_cell_angle_beta   77.206
_cell_angle_gamma   97.850
_symmetry_Int_Tables_number   1
_cell_volume   255.881
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.878  0.122  0.250  1.0
  K  K1  1  0.122  0.878  0.750  1.0
  Ho  Ho2  1  0.407  0.593  0.250  1.0
  Ho  Ho3  1  0.593  0.407  0.750  1.0
  C  C4  1  0.604  0.857  0.747  1.0
  C  C5  1  0.143  0.396  0.753  1.0
  C  C6  1  0.396  0.143  0.253  1.0
  C  C7  1  0.857  0.604  0.247  1.0
  O  O8  1  0.059  0.591  0.226  1.0
  O  O9  1  0.409  0.941  0.274  1.0
  O  O10  1  0.941  0.409  0.774  1.0
  O  O11  1  0.591  0.059  0.726  1.0
  O  O12  1  0.791  0.744  0.119  1.0
  O  O13  1  0.256  0.209  0.381  1.0
  O  O14  1  0.209  0.256  0.881  1.0
  O  O15  1  0.744  0.791  0.619  1.0
  O  O16  1  0.701  0.465  0.397  1.0
  O  O17  1  0.535  0.299  0.103  1.0
  O  O18  1  0.299  0.535  0.603  1.0
  O  O19  1  0.465  0.701  0.897  1.0
[/CIF]
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