The structure described by LiU2TmS3O2 crystallizes in the orthorhombic Imm2 space group. Li(1) is bonded to two equivalent S(2) and two equivalent S(3) atoms to form distorted corner-sharing LiS4 tetrahedra. There are two inequivalent U sites. In the first U site, U(1) is bonded in a 4-coordinate geometry to four equivalent S(2), two equivalent O(1), and two equivalent O(2) atoms. In the second U site, U(2) is bonded in a 8-coordinate geometry to four equivalent S(1), two equivalent O(1), and two equivalent O(2) atoms. Tm(1) is bonded in a 5-coordinate geometry to one S(1) and four equivalent S(3) atoms. There are three inequivalent S sites. In the first S site, S(1) is bonded in a 5-coordinate geometry to four equivalent U(2) and one Tm(1) atom. In the second S site, S(2) is bonded in a distorted water-like geometry to two equivalent Li(1) and four equivalent U(1) atoms. In the third S site, S(3) is bonded to two equivalent Li(1) and four equivalent Tm(1) atoms to form a mixture of distorted corner, edge, and face-sharing SLi2Tm4 pentagonal pyramids. There are two inequivalent O sites. In the first O site, O(1) is bonded to two equivalent U(1) and two equivalent U(2) atoms to form a mixture of corner and edge-sharing OU4 tetrahedra. In the second O site, O(2) is bonded to two equivalent U(1) and two equivalent U(2) atoms to form a mixture of corner and edge-sharing OU4 tetrahedra. is represented by the CIF file [CIF]
data_LiTmU2S3O2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.709
_cell_length_b   3.742
_cell_length_c   12.380
_cell_angle_alpha   98.692
_cell_angle_beta   98.616
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   167.904
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.921  0.421  0.843  1.0
  Tm  Tm1  1  0.030  0.030  0.060  1.0
  U  U2  1  0.301  0.301  0.603  1.0
  U  U3  1  0.690  0.690  0.379  1.0
  S  S4  1  0.135  0.135  0.269  1.0
  S  S5  1  0.862  0.862  0.724  1.0
  S  S6  1  0.498  0.498  0.996  1.0
  O  O7  1  0.246  0.746  0.492  1.0
  O  O8  1  0.746  0.246  0.492  1.0
[/CIF]
.
The structure described by LiU2TmS3O2 crystallizes in the orthorhombic Imm2 space group. Li(1) is bonded to two equivalent S(2) and two equivalent S(3) atoms to form distorted corner-sharing LiS4 tetrahedra. There are two inequivalent U sites. In the first U site, U(1) is bonded in a 4-coordinate geometry to four equivalent S(2), two equivalent O(1), and two equivalent O(2) atoms. In the second U site, U(2) is bonded in a 8-coordinate geometry to four equivalent S(1), two equivalent O(1), and two equivalent O(2) atoms. Tm(1) is bonded in a 5-coordinate geometry to one S(1) and four equivalent S(3) atoms. There are three inequivalent S sites. In the first S site, S(1) is bonded in a 5-coordinate geometry to four equivalent U(2) and one Tm(1) atom. In the second S site, S(2) is bonded in a distorted water-like geometry to two equivalent Li(1) and four equivalent U(1) atoms. In the third S site, S(3) is bonded to two equivalent Li(1) and four equivalent Tm(1) atoms to form a mixture of distorted corner, edge, and face-sharing SLi2Tm4 pentagonal pyramids. There are two inequivalent O sites. In the first O site, O(1) is bonded to two equivalent U(1) and two equivalent U(2) atoms to form a mixture of corner and edge-sharing OU4 tetrahedra. In the second O site, O(2) is bonded to two equivalent U(1) and two equivalent U(2) atoms to form a mixture of corner and edge-sharing OU4 tetrahedra. is represented by the CIF file [CIF]
data_LiTmU2S3O2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.709
_cell_length_b   3.742
_cell_length_c   12.380
_cell_angle_alpha   98.692
_cell_angle_beta   98.616
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   167.904
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.921  0.421  0.843  1.0
  Tm  Tm1  1  0.030  0.030  0.060  1.0
  U  U2  1  0.301  0.301  0.603  1.0
  U  U3  1  0.690  0.690  0.379  1.0
  S  S4  1  0.135  0.135  0.269  1.0
  S  S5  1  0.862  0.862  0.724  1.0
  S  S6  1  0.498  0.498  0.996  1.0
  O  O7  1  0.246  0.746  0.492  1.0
  O  O8  1  0.746  0.246  0.492  1.0
[/CIF]
.