The compound described by WOF4 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one WOF4 cluster. W(1) is bonded in a 6-coordinate geometry to one O(1), one F(1), one F(3), one F(4), and two equivalent F(2) atoms. O(1) is bonded in a single-bond geometry to one W(1) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one W(1) atom. In the second F site, F(2) is bonded in a distorted water-like geometry to two equivalent W(1) atoms. In the third F site, F(3) is bonded in a single-bond geometry to one W(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one W(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_WOF4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.352
_cell_length_b   6.276
_cell_length_c   6.528
_cell_angle_alpha   102.251
_cell_angle_beta   95.160
_cell_angle_gamma   107.935
_symmetry_Int_Tables_number   1
_cell_volume   201.012
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  W  W0  1  0.914  0.782  0.748  1.0
  W  W1  1  0.086  0.218  0.252  1.0
  O  O2  1  0.995  0.257  0.500  1.0
  O  O3  1  0.005  0.743  0.500  1.0
  F  F4  1  0.845  0.319  0.104  1.0
  F  F5  1  0.843  0.901  0.110  1.0
  F  F6  1  0.639  0.505  0.731  1.0
  F  F7  1  0.343  0.075  0.294  1.0
  F  F8  1  0.657  0.925  0.706  1.0
  F  F9  1  0.361  0.495  0.269  1.0
  F  F10  1  0.157  0.099  0.890  1.0
  F  F11  1  0.155  0.681  0.896  1.0
[/CIF]
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The compound described by WOF4 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one WOF4 cluster. W(1) is bonded in a 6-coordinate geometry to one O(1), one F(1), one F(3), one F(4), and two equivalent F(2) atoms. O(1) is bonded in a single-bond geometry to one W(1) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one W(1) atom. In the second F site, F(2) is bonded in a distorted water-like geometry to two equivalent W(1) atoms. In the third F site, F(3) is bonded in a single-bond geometry to one W(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one W(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_WOF4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.352
_cell_length_b   6.276
_cell_length_c   6.528
_cell_angle_alpha   102.251
_cell_angle_beta   95.160
_cell_angle_gamma   107.935
_symmetry_Int_Tables_number   1
_cell_volume   201.012
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  W  W0  1  0.914  0.782  0.748  1.0
  W  W1  1  0.086  0.218  0.252  1.0
  O  O2  1  0.995  0.257  0.500  1.0
  O  O3  1  0.005  0.743  0.500  1.0
  F  F4  1  0.845  0.319  0.104  1.0
  F  F5  1  0.843  0.901  0.110  1.0
  F  F6  1  0.639  0.505  0.731  1.0
  F  F7  1  0.343  0.075  0.294  1.0
  F  F8  1  0.657  0.925  0.706  1.0
  F  F9  1  0.361  0.495  0.269  1.0
  F  F10  1  0.157  0.099  0.890  1.0
  F  F11  1  0.155  0.681  0.896  1.0
[/CIF]
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