The compound described by TbRhSi crystallizes in the orthorhombic Cmcm space group. Tb(1) is bonded in a 11-coordinate geometry to five equivalent Rh(1) and six equivalent Si(1) atoms. Rh(1) is bonded in a 9-coordinate geometry to five equivalent Tb(1) and four equivalent Si(1) atoms. Si(1) is bonded to six equivalent Tb(1), four equivalent Rh(1), and two equivalent Si(1) atoms to form a mixture of distorted edge, face, and corner-sharing SiTb6Si2Rh4 cuboctahedra. is represented by the CIF file [CIF]
data_TbSiRh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.458
_cell_length_b   5.458
_cell_length_c   5.176
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   134.634
_symmetry_Int_Tables_number   1
_cell_volume   109.738
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tb  Tb0  1  0.713  0.287  0.250  1.0
  Tb  Tb1  1  0.287  0.713  0.750  1.0
  Si  Si2  1  0.000  0.000  0.500  1.0
  Si  Si3  1  0.000  0.000  0.000  1.0
  Rh  Rh4  1  0.573  0.427  0.750  1.0
  Rh  Rh5  1  0.427  0.573  0.250  1.0
[/CIF]
.
The compound described by TbRhSi crystallizes in the orthorhombic Cmcm space group. Tb(1) is bonded in a 11-coordinate geometry to five equivalent Rh(1) and six equivalent Si(1) atoms. Rh(1) is bonded in a 9-coordinate geometry to five equivalent Tb(1) and four equivalent Si(1) atoms. Si(1) is bonded to six equivalent Tb(1), four equivalent Rh(1), and two equivalent Si(1) atoms to form a mixture of distorted edge, face, and corner-sharing SiTb6Si2Rh4 cuboctahedra. is represented by the CIF file [CIF]
data_TbSiRh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.458
_cell_length_b   5.458
_cell_length_c   5.176
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   134.634
_symmetry_Int_Tables_number   1
_cell_volume   109.738
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tb  Tb0  1  0.713  0.287  0.250  1.0
  Tb  Tb1  1  0.287  0.713  0.750  1.0
  Si  Si2  1  0.000  0.000  0.500  1.0
  Si  Si3  1  0.000  0.000  0.000  1.0
  Rh  Rh4  1  0.573  0.427  0.750  1.0
  Rh  Rh5  1  0.427  0.573  0.250  1.0
[/CIF]
.