The material structure described by W2H(CO)10W2C8H(NO5)2 is Indium-like structured and crystallizes in the monoclinic C2 space group. The structure is zero-dimensional and consists of two W2C8H(NO5)2 clusters and two W2H(CO)10 clusters. In each W2C8H(NO5)2 cluster, W(1) is bonded to one C(1), one C(3), one C(5), one C(7), one N(1), and one H(1) atom to form corner-sharing WHC4N octahedra. The corner-sharing octahedral tilt angles are 51°. There are four inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one W(1) and one O(7) atom. In the second C site, C(3) is bonded in a distorted single-bond geometry to one W(1) and one O(3) atom. In the third C site, C(5) is bonded in a distorted single-bond geometry to one W(1) and one O(1) atom. In the fourth C site, C(7) is bonded in a distorted single-bond geometry to one W(1) and one O(9) atom. N(1) is bonded in a linear geometry to one W(1) and one O(5) atom. H(1) is bonded in a bent 120 degrees geometry to two equivalent W(1) atoms. There are five inequivalent O sites. In the first O site, O(7) is bonded in a single-bond geometry to one C(1) atom. In the second O site, O(9) is bonded in a single-bond geometry to one C(7) atom. In the third O site, O(1) is bonded in a single-bond geometry to one C(5) atom. In the fourth O site, O(3) is bonded in a single-bond geometry to one C(3) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one N(1) atom. In each W2H(CO)10 cluster, W(2) is bonded to one C(2), one C(4), one C(6), one C(8), one C(9), and one H(2) atom to form corner-sharing WHC5 octahedra. The corner-sharing octahedral tilt angles are 53°. There are five inequivalent C sites. In the first C site, C(2) is bonded in a distorted single-bond geometry to one W(2) and one O(8) atom. In the second C site, C(4) is bonded in a distorted single-bond geometry to one W(2) and one O(4) atom. In the third C site, C(6) is bonded in a distorted single-bond geometry to one W(2) and one O(2) atom. In the fourth C site, C(8) is bonded in a distorted linear geometry to one W(2) and one O(10) atom. In the fifth C site, C(9) is bonded in a distorted linear geometry to one W(2) and one O(6) atom. H(2) is bonded in a bent 120 degrees geometry to two equivalent W(2) atoms. There are five inequivalent O sites. In the first O site, O(8) is bonded in a single-bond geometry to one C(2) atom. In the second O site, O(4) is bonded in a single-bond geometry to one C(4) atom. In the third O site, O(10) is bonded in a single-bond geometry to one C(8) atom. In the fourth O site, O(2) is bonded in a single-bond geometry to one C(6) atom. In the fifth O site, O(6) is bonded in a single-bond geometry to one C(9) atom. is represented by the CIF file [CIF]
data_HW2C9NO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.266
_cell_length_b   8.266
_cell_length_c   16.178
_cell_angle_alpha   79.123
_cell_angle_beta   79.123
_cell_angle_gamma   49.853
_symmetry_Int_Tables_number   1
_cell_volume   826.556
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.670  0.330  0.000  1.0
  H  H1  1  0.335  0.665  0.500  1.0
  W  W2  1  0.728  0.148  0.106  1.0
  W  W3  1  0.852  0.272  0.894  1.0
  W  W4  1  0.272  0.847  0.397  1.0
  W  W5  1  0.153  0.728  0.603  1.0
  C  C6  1  0.735  0.932  0.052  1.0
  C  C7  1  0.068  0.265  0.948  1.0
  C  C8  1  0.264  0.066  0.449  1.0
  C  C9  1  0.934  0.736  0.551  1.0
  C  C10  1  0.059  0.947  0.097  1.0
  C  C11  1  0.053  0.941  0.903  1.0
  C  C12  1  0.943  0.051  0.404  1.0
  C  C13  1  0.949  0.057  0.596  1.0
  C  C14  1  0.394  0.356  0.113  1.0
  C  C15  1  0.644  0.606  0.887  1.0
  C  C16  1  0.603  0.644  0.389  1.0
  C  C17  1  0.356  0.397  0.611  1.0
  C  C18  1  0.723  0.372  0.154  1.0
  C  C19  1  0.628  0.277  0.846  1.0
  C  C20  1  0.278  0.630  0.348  1.0
  C  C21  1  0.370  0.722  0.652  1.0
  C  C22  1  0.278  0.981  0.281  1.0
  C  C23  1  0.019  0.722  0.719  1.0
  N  N24  1  0.722  0.022  0.216  1.0
  N  N25  1  0.978  0.278  0.784  1.0
  O  O26  1  0.211  0.468  0.118  1.0
  O  O27  1  0.532  0.789  0.882  1.0
  O  O28  1  0.788  0.534  0.381  1.0
  O  O29  1  0.466  0.212  0.619  1.0
  O  O30  1  0.243  0.833  0.094  1.0
  O  O31  1  0.167  0.757  0.906  1.0
  O  O32  1  0.758  0.167  0.405  1.0
  O  O33  1  0.833  0.242  0.595  1.0
  O  O34  1  0.715  0.947  0.284  1.0
  O  O35  1  0.053  0.285  0.716  1.0
  O  O36  1  0.285  0.057  0.212  1.0
  O  O37  1  0.943  0.715  0.788  1.0
  O  O38  1  0.738  0.811  0.024  1.0
  O  O39  1  0.189  0.262  0.976  1.0
  O  O40  1  0.262  0.188  0.475  1.0
  O  O41  1  0.812  0.738  0.525  1.0
  O  O42  1  0.721  0.491  0.181  1.0
  O  O43  1  0.509  0.279  0.819  1.0
  O  O44  1  0.279  0.510  0.318  1.0
  O  O45  1  0.490  0.721  0.682  1.0
[/CIF]
.
The material structure described by W2H(CO)10W2C8H(NO5)2 is Indium-like structured and crystallizes in the monoclinic C2 space group. The structure is zero-dimensional and consists of two W2C8H(NO5)2 clusters and two W2H(CO)10 clusters. In each W2C8H(NO5)2 cluster, W(1) is bonded to one C(1), one C(3), one C(5), one C(7), one N(1), and one H(1) atom to form corner-sharing WHC4N octahedra. The corner-sharing octahedral tilt angles are 51°. There are four inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one W(1) and one O(7) atom. In the second C site, C(3) is bonded in a distorted single-bond geometry to one W(1) and one O(3) atom. In the third C site, C(5) is bonded in a distorted single-bond geometry to one W(1) and one O(1) atom. In the fourth C site, C(7) is bonded in a distorted single-bond geometry to one W(1) and one O(9) atom. N(1) is bonded in a linear geometry to one W(1) and one O(5) atom. H(1) is bonded in a bent 120 degrees geometry to two equivalent W(1) atoms. There are five inequivalent O sites. In the first O site, O(7) is bonded in a single-bond geometry to one C(1) atom. In the second O site, O(9) is bonded in a single-bond geometry to one C(7) atom. In the third O site, O(1) is bonded in a single-bond geometry to one C(5) atom. In the fourth O site, O(3) is bonded in a single-bond geometry to one C(3) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one N(1) atom. In each W2H(CO)10 cluster, W(2) is bonded to one C(2), one C(4), one C(6), one C(8), one C(9), and one H(2) atom to form corner-sharing WHC5 octahedra. The corner-sharing octahedral tilt angles are 53°. There are five inequivalent C sites. In the first C site, C(2) is bonded in a distorted single-bond geometry to one W(2) and one O(8) atom. In the second C site, C(4) is bonded in a distorted single-bond geometry to one W(2) and one O(4) atom. In the third C site, C(6) is bonded in a distorted single-bond geometry to one W(2) and one O(2) atom. In the fourth C site, C(8) is bonded in a distorted linear geometry to one W(2) and one O(10) atom. In the fifth C site, C(9) is bonded in a distorted linear geometry to one W(2) and one O(6) atom. H(2) is bonded in a bent 120 degrees geometry to two equivalent W(2) atoms. There are five inequivalent O sites. In the first O site, O(8) is bonded in a single-bond geometry to one C(2) atom. In the second O site, O(4) is bonded in a single-bond geometry to one C(4) atom. In the third O site, O(10) is bonded in a single-bond geometry to one C(8) atom. In the fourth O site, O(2) is bonded in a single-bond geometry to one C(6) atom. In the fifth O site, O(6) is bonded in a single-bond geometry to one C(9) atom. is represented by the CIF file [CIF]
data_HW2C9NO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.266
_cell_length_b   8.266
_cell_length_c   16.178
_cell_angle_alpha   79.123
_cell_angle_beta   79.123
_cell_angle_gamma   49.853
_symmetry_Int_Tables_number   1
_cell_volume   826.556
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.670  0.330  0.000  1.0
  H  H1  1  0.335  0.665  0.500  1.0
  W  W2  1  0.728  0.148  0.106  1.0
  W  W3  1  0.852  0.272  0.894  1.0
  W  W4  1  0.272  0.847  0.397  1.0
  W  W5  1  0.153  0.728  0.603  1.0
  C  C6  1  0.735  0.932  0.052  1.0
  C  C7  1  0.068  0.265  0.948  1.0
  C  C8  1  0.264  0.066  0.449  1.0
  C  C9  1  0.934  0.736  0.551  1.0
  C  C10  1  0.059  0.947  0.097  1.0
  C  C11  1  0.053  0.941  0.903  1.0
  C  C12  1  0.943  0.051  0.404  1.0
  C  C13  1  0.949  0.057  0.596  1.0
  C  C14  1  0.394  0.356  0.113  1.0
  C  C15  1  0.644  0.606  0.887  1.0
  C  C16  1  0.603  0.644  0.389  1.0
  C  C17  1  0.356  0.397  0.611  1.0
  C  C18  1  0.723  0.372  0.154  1.0
  C  C19  1  0.628  0.277  0.846  1.0
  C  C20  1  0.278  0.630  0.348  1.0
  C  C21  1  0.370  0.722  0.652  1.0
  C  C22  1  0.278  0.981  0.281  1.0
  C  C23  1  0.019  0.722  0.719  1.0
  N  N24  1  0.722  0.022  0.216  1.0
  N  N25  1  0.978  0.278  0.784  1.0
  O  O26  1  0.211  0.468  0.118  1.0
  O  O27  1  0.532  0.789  0.882  1.0
  O  O28  1  0.788  0.534  0.381  1.0
  O  O29  1  0.466  0.212  0.619  1.0
  O  O30  1  0.243  0.833  0.094  1.0
  O  O31  1  0.167  0.757  0.906  1.0
  O  O32  1  0.758  0.167  0.405  1.0
  O  O33  1  0.833  0.242  0.595  1.0
  O  O34  1  0.715  0.947  0.284  1.0
  O  O35  1  0.053  0.285  0.716  1.0
  O  O36  1  0.285  0.057  0.212  1.0
  O  O37  1  0.943  0.715  0.788  1.0
  O  O38  1  0.738  0.811  0.024  1.0
  O  O39  1  0.189  0.262  0.976  1.0
  O  O40  1  0.262  0.188  0.475  1.0
  O  O41  1  0.812  0.738  0.525  1.0
  O  O42  1  0.721  0.491  0.181  1.0
  O  O43  1  0.509  0.279  0.819  1.0
  O  O44  1  0.279  0.510  0.318  1.0
  O  O45  1  0.490  0.721  0.682  1.0
[/CIF]
.