The structure described by EuVO3 is Orthorhombic Perovskite structured and crystallizes in the orthorhombic Pnma space group. Eu(1) is bonded in a 12-coordinate geometry to four equivalent O(1) and eight equivalent O(2) atoms. V(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form corner-sharing VO6 octahedra. The corner-sharing octahedral tilt angles are 18°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to four equivalent Eu(1) and two equivalent V(1) atoms. In the second O site, O(2) is bonded in a 5-coordinate geometry to four equivalent Eu(1) and two equivalent V(1) atoms. is represented by the CIF card [CIF]
data_EuVO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.449
_cell_length_b   5.444
_cell_length_c   7.683
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   227.916
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Eu  Eu0  1  0.997  0.021  0.250  1.0
  Eu  Eu1  1  0.497  0.479  0.750  1.0
  Eu  Eu2  1  0.503  0.521  0.250  1.0
  Eu  Eu3  1  0.003  0.979  0.750  1.0
  V  V4  1  0.500  0.000  0.000  1.0
  V  V5  1  0.500  0.000  0.500  1.0
  V  V6  1  0.000  0.500  0.000  1.0
  V  V7  1  0.000  0.500  0.500  1.0
  O  O8  1  0.556  0.006  0.750  1.0
  O  O9  1  0.224  0.223  0.529  1.0
  O  O10  1  0.224  0.223  0.971  1.0
  O  O11  1  0.724  0.277  0.029  1.0
  O  O12  1  0.724  0.277  0.471  1.0
  O  O13  1  0.056  0.494  0.250  1.0
  O  O14  1  0.944  0.506  0.750  1.0
  O  O15  1  0.276  0.723  0.971  1.0
  O  O16  1  0.276  0.723  0.529  1.0
  O  O17  1  0.776  0.777  0.029  1.0
  O  O18  1  0.776  0.777  0.471  1.0
  O  O19  1  0.444  0.994  0.250  1.0
[/CIF]
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The structure described by EuVO3 is Orthorhombic Perovskite structured and crystallizes in the orthorhombic Pnma space group. Eu(1) is bonded in a 12-coordinate geometry to four equivalent O(1) and eight equivalent O(2) atoms. V(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form corner-sharing VO6 octahedra. The corner-sharing octahedral tilt angles are 18°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to four equivalent Eu(1) and two equivalent V(1) atoms. In the second O site, O(2) is bonded in a 5-coordinate geometry to four equivalent Eu(1) and two equivalent V(1) atoms. is represented by the CIF card [CIF]
data_EuVO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.449
_cell_length_b   5.444
_cell_length_c   7.683
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   227.916
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Eu  Eu0  1  0.997  0.021  0.250  1.0
  Eu  Eu1  1  0.497  0.479  0.750  1.0
  Eu  Eu2  1  0.503  0.521  0.250  1.0
  Eu  Eu3  1  0.003  0.979  0.750  1.0
  V  V4  1  0.500  0.000  0.000  1.0
  V  V5  1  0.500  0.000  0.500  1.0
  V  V6  1  0.000  0.500  0.000  1.0
  V  V7  1  0.000  0.500  0.500  1.0
  O  O8  1  0.556  0.006  0.750  1.0
  O  O9  1  0.224  0.223  0.529  1.0
  O  O10  1  0.224  0.223  0.971  1.0
  O  O11  1  0.724  0.277  0.029  1.0
  O  O12  1  0.724  0.277  0.471  1.0
  O  O13  1  0.056  0.494  0.250  1.0
  O  O14  1  0.944  0.506  0.750  1.0
  O  O15  1  0.276  0.723  0.971  1.0
  O  O16  1  0.276  0.723  0.529  1.0
  O  O17  1  0.776  0.777  0.029  1.0
  O  O18  1  0.776  0.777  0.471  1.0
  O  O19  1  0.444  0.994  0.250  1.0
[/CIF]
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