The compound described by K2MoO2(IO3)4 crystallizes in the monoclinic C2/c space group. K(1) is bonded in a 8-coordinate geometry to one O(1), one O(2), two equivalent O(3), two equivalent O(5), and two equivalent O(6) atoms. Mo(1) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent O(4), and two equivalent O(7) atoms. There are seven inequivalent O sites. In the first O site, O(2) is bonded in a 3-coordinate geometry to one K(1) and two equivalent I(1) atoms. In the second O site, O(3) is bonded in a 3-coordinate geometry to two equivalent K(1) and one I(1) atom. In the third O site, O(4) is bonded in a 2-coordinate geometry to one Mo(1) and one I(2) atom. In the fourth O site, O(5) is bonded in a 1-coordinate geometry to two equivalent K(1) and one I(2) atom. In the fifth O site, O(6) is bonded in a 1-coordinate geometry to two equivalent K(1) and one I(2) atom. In the sixth O site, O(7) is bonded in a single-bond geometry to one Mo(1) atom. In the seventh O site, O(1) is bonded in a distorted trigonal planar geometry to one K(1), one Mo(1), and one I(1) atom. There are two inequivalent I sites. In the first I site, I(1) is bonded in a 3-coordinate geometry to one O(1), one O(3), and two equivalent O(2) atoms. In the second I site, I(2) is bonded in a distorted trigonal non-coplanar geometry to one O(4), one O(5), and one O(6) atom. is represented by the CIF card [CIF]
data_K2Mo(I2O7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.295
_cell_length_b   7.295
_cell_length_c   17.819
_cell_angle_alpha   79.362
_cell_angle_beta   79.362
_cell_angle_gamma   51.505
_symmetry_Int_Tables_number   1
_cell_volume   726.389
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.821  0.817  0.462  1.0
  K  K1  1  0.183  0.179  0.038  1.0
  K  K2  1  0.179  0.183  0.538  1.0
  K  K3  1  0.817  0.821  0.962  1.0
  Mo  Mo4  1  0.110  0.890  0.750  1.0
  Mo  Mo5  1  0.890  0.110  0.250  1.0
  I  I6  1  0.381  0.548  0.590  1.0
  I  I7  1  0.452  0.619  0.910  1.0
  I  I8  1  0.619  0.452  0.410  1.0
  I  I9  1  0.548  0.381  0.090  1.0
  I  I10  1  0.273  0.304  0.320  1.0
  I  I11  1  0.696  0.727  0.180  1.0
  I  I12  1  0.727  0.696  0.680  1.0
  I  I13  1  0.304  0.273  0.820  1.0
  O  O14  1  0.199  0.841  0.640  1.0
  O  O15  1  0.159  0.801  0.860  1.0
  O  O16  1  0.801  0.159  0.360  1.0
  O  O17  1  0.841  0.199  0.140  1.0
  O  O18  1  0.375  0.727  0.500  1.0
  O  O19  1  0.273  0.625  1.000  1.0
  O  O20  1  0.625  0.273  0.500  1.0
  O  O21  1  0.727  0.375  0.000  1.0
  O  O22  1  0.128  0.563  0.580  1.0
  O  O23  1  0.437  0.872  0.920  1.0
  O  O24  1  0.872  0.437  0.420  1.0
  O  O25  1  0.563  0.128  0.080  1.0
  O  O26  1  0.502  0.281  0.245  1.0
  O  O27  1  0.719  0.498  0.255  1.0
  O  O28  1  0.498  0.719  0.755  1.0
  O  O29  1  0.281  0.502  0.745  1.0
  O  O30  1  0.266  0.464  0.390  1.0
  O  O31  1  0.536  0.734  0.110  1.0
  O  O32  1  0.734  0.536  0.610  1.0
  O  O33  1  0.464  0.266  0.890  1.0
  O  O34  1  0.439  0.012  0.369  1.0
  O  O35  1  0.988  0.561  0.131  1.0
  O  O36  1  0.561  0.988  0.631  1.0
  O  O37  1  0.012  0.439  0.869  1.0
  O  O38  1  0.046  0.167  0.740  1.0
  O  O39  1  0.833  0.954  0.760  1.0
  O  O40  1  0.954  0.833  0.260  1.0
  O  O41  1  0.167  0.046  0.240  1.0
[/CIF]
.
The compound described by K2MoO2(IO3)4 crystallizes in the monoclinic C2/c space group. K(1) is bonded in a 8-coordinate geometry to one O(1), one O(2), two equivalent O(3), two equivalent O(5), and two equivalent O(6) atoms. Mo(1) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent O(4), and two equivalent O(7) atoms. There are seven inequivalent O sites. In the first O site, O(2) is bonded in a 3-coordinate geometry to one K(1) and two equivalent I(1) atoms. In the second O site, O(3) is bonded in a 3-coordinate geometry to two equivalent K(1) and one I(1) atom. In the third O site, O(4) is bonded in a 2-coordinate geometry to one Mo(1) and one I(2) atom. In the fourth O site, O(5) is bonded in a 1-coordinate geometry to two equivalent K(1) and one I(2) atom. In the fifth O site, O(6) is bonded in a 1-coordinate geometry to two equivalent K(1) and one I(2) atom. In the sixth O site, O(7) is bonded in a single-bond geometry to one Mo(1) atom. In the seventh O site, O(1) is bonded in a distorted trigonal planar geometry to one K(1), one Mo(1), and one I(1) atom. There are two inequivalent I sites. In the first I site, I(1) is bonded in a 3-coordinate geometry to one O(1), one O(3), and two equivalent O(2) atoms. In the second I site, I(2) is bonded in a distorted trigonal non-coplanar geometry to one O(4), one O(5), and one O(6) atom. is represented by the CIF card [CIF]
data_K2Mo(I2O7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.295
_cell_length_b   7.295
_cell_length_c   17.819
_cell_angle_alpha   79.362
_cell_angle_beta   79.362
_cell_angle_gamma   51.505
_symmetry_Int_Tables_number   1
_cell_volume   726.389
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.821  0.817  0.462  1.0
  K  K1  1  0.183  0.179  0.038  1.0
  K  K2  1  0.179  0.183  0.538  1.0
  K  K3  1  0.817  0.821  0.962  1.0
  Mo  Mo4  1  0.110  0.890  0.750  1.0
  Mo  Mo5  1  0.890  0.110  0.250  1.0
  I  I6  1  0.381  0.548  0.590  1.0
  I  I7  1  0.452  0.619  0.910  1.0
  I  I8  1  0.619  0.452  0.410  1.0
  I  I9  1  0.548  0.381  0.090  1.0
  I  I10  1  0.273  0.304  0.320  1.0
  I  I11  1  0.696  0.727  0.180  1.0
  I  I12  1  0.727  0.696  0.680  1.0
  I  I13  1  0.304  0.273  0.820  1.0
  O  O14  1  0.199  0.841  0.640  1.0
  O  O15  1  0.159  0.801  0.860  1.0
  O  O16  1  0.801  0.159  0.360  1.0
  O  O17  1  0.841  0.199  0.140  1.0
  O  O18  1  0.375  0.727  0.500  1.0
  O  O19  1  0.273  0.625  1.000  1.0
  O  O20  1  0.625  0.273  0.500  1.0
  O  O21  1  0.727  0.375  0.000  1.0
  O  O22  1  0.128  0.563  0.580  1.0
  O  O23  1  0.437  0.872  0.920  1.0
  O  O24  1  0.872  0.437  0.420  1.0
  O  O25  1  0.563  0.128  0.080  1.0
  O  O26  1  0.502  0.281  0.245  1.0
  O  O27  1  0.719  0.498  0.255  1.0
  O  O28  1  0.498  0.719  0.755  1.0
  O  O29  1  0.281  0.502  0.745  1.0
  O  O30  1  0.266  0.464  0.390  1.0
  O  O31  1  0.536  0.734  0.110  1.0
  O  O32  1  0.734  0.536  0.610  1.0
  O  O33  1  0.464  0.266  0.890  1.0
  O  O34  1  0.439  0.012  0.369  1.0
  O  O35  1  0.988  0.561  0.131  1.0
  O  O36  1  0.561  0.988  0.631  1.0
  O  O37  1  0.012  0.439  0.869  1.0
  O  O38  1  0.046  0.167  0.740  1.0
  O  O39  1  0.833  0.954  0.760  1.0
  O  O40  1  0.954  0.833  0.260  1.0
  O  O41  1  0.167  0.046  0.240  1.0
[/CIF]
.