The material described by Mg6VC crystallizes in the orthorhombic Amm2 space group. There are four inequivalent Mg sites. In the first Mg site, Mg(1) is bonded in a single-bond geometry to two equivalent Mg(4), two equivalent V(1), and one C(1) atom. In the second Mg site, Mg(2) is bonded in a 2-coordinate geometry to one Mg(4), two equivalent V(1), and two equivalent C(1) atoms. In the third Mg site, Mg(3) is bonded in a 2-coordinate geometry to two equivalent Mg(4) and two equivalent V(1) atoms. In the fourth Mg site, Mg(4) is bonded in a 8-coordinate geometry to two equivalent Mg(2), two equivalent Mg(3), and four equivalent Mg(1) atoms. V(1) is bonded in a 12-coordinate geometry to two equivalent Mg(3), four equivalent Mg(1), four equivalent Mg(2), and two equivalent C(1) atoms. C(1) is bonded in a 6-coordinate geometry to two equivalent Mg(1), four equivalent Mg(2), and two equivalent V(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mg6VC
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.539
_cell_length_b   5.776
_cell_length_c   6.548
_cell_angle_alpha   116.168
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   154.084
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  C  C0  1  0.500  0.598  0.197  1.0
  Mg  Mg1  1  0.500  0.686  0.885  1.0
  Mg  Mg2  1  0.500  0.198  0.885  1.0
  Mg  Mg3  1  0.000  0.835  0.189  1.0
  Mg  Mg4  1  0.000  0.354  0.189  1.0
  Mg  Mg5  1  0.000  0.328  0.655  1.0
  Mg  Mg6  1  0.000  0.820  0.639  1.0
  V  V7  1  0.500  0.181  0.362  1.0
[/CIF]
.
The material described by Mg6VC crystallizes in the orthorhombic Amm2 space group. There are four inequivalent Mg sites. In the first Mg site, Mg(1) is bonded in a single-bond geometry to two equivalent Mg(4), two equivalent V(1), and one C(1) atom. In the second Mg site, Mg(2) is bonded in a 2-coordinate geometry to one Mg(4), two equivalent V(1), and two equivalent C(1) atoms. In the third Mg site, Mg(3) is bonded in a 2-coordinate geometry to two equivalent Mg(4) and two equivalent V(1) atoms. In the fourth Mg site, Mg(4) is bonded in a 8-coordinate geometry to two equivalent Mg(2), two equivalent Mg(3), and four equivalent Mg(1) atoms. V(1) is bonded in a 12-coordinate geometry to two equivalent Mg(3), four equivalent Mg(1), four equivalent Mg(2), and two equivalent C(1) atoms. C(1) is bonded in a 6-coordinate geometry to two equivalent Mg(1), four equivalent Mg(2), and two equivalent V(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mg6VC
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.539
_cell_length_b   5.776
_cell_length_c   6.548
_cell_angle_alpha   116.168
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   154.084
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  C  C0  1  0.500  0.598  0.197  1.0
  Mg  Mg1  1  0.500  0.686  0.885  1.0
  Mg  Mg2  1  0.500  0.198  0.885  1.0
  Mg  Mg3  1  0.000  0.835  0.189  1.0
  Mg  Mg4  1  0.000  0.354  0.189  1.0
  Mg  Mg5  1  0.000  0.328  0.655  1.0
  Mg  Mg6  1  0.000  0.820  0.639  1.0
  V  V7  1  0.500  0.181  0.362  1.0
[/CIF]
.