The structure described by AgClO3 crystallizes in the monoclinic P2_1/c space group. Ag(1) is bonded in a 4-coordinate geometry to one O(2), two equivalent O(1), and two equivalent O(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to two equivalent Ag(1) and one Cl(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Ag(1) and one Cl(1) atom. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Ag(1) and one Cl(1) atom. Cl(1) is bonded in a trigonal non-coplanar geometry to one O(1), one O(2), and one O(3) atom. is represented by the CIF card [CIF]
data_AgClO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.417
_cell_length_b   6.967
_cell_length_c   8.843
_cell_angle_alpha   67.819
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   309.046
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.263  0.308  0.176  1.0
  Ag  Ag1  1  0.763  0.692  0.324  1.0
  Ag  Ag2  1  0.237  0.308  0.676  1.0
  Ag  Ag3  1  0.737  0.692  0.824  1.0
  Cl  Cl4  1  0.223  0.823  0.025  1.0
  Cl  Cl5  1  0.723  0.177  0.475  1.0
  Cl  Cl6  1  0.277  0.823  0.525  1.0
  Cl  Cl7  1  0.777  0.177  0.975  1.0
  O  O8  1  0.843  0.092  0.154  1.0
  O  O9  1  0.478  0.728  0.043  1.0
  O  O10  1  0.044  0.643  0.107  1.0
  O  O11  1  0.544  0.357  0.393  1.0
  O  O12  1  0.978  0.272  0.457  1.0
  O  O13  1  0.343  0.908  0.346  1.0
  O  O14  1  0.657  0.092  0.654  1.0
  O  O15  1  0.022  0.728  0.543  1.0
  O  O16  1  0.456  0.643  0.607  1.0
  O  O17  1  0.956  0.357  0.893  1.0
  O  O18  1  0.522  0.272  0.957  1.0
  O  O19  1  0.157  0.908  0.846  1.0
[/CIF]
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The structure described by AgClO3 crystallizes in the monoclinic P2_1/c space group. Ag(1) is bonded in a 4-coordinate geometry to one O(2), two equivalent O(1), and two equivalent O(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to two equivalent Ag(1) and one Cl(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Ag(1) and one Cl(1) atom. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Ag(1) and one Cl(1) atom. Cl(1) is bonded in a trigonal non-coplanar geometry to one O(1), one O(2), and one O(3) atom. is represented by the CIF card [CIF]
data_AgClO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.417
_cell_length_b   6.967
_cell_length_c   8.843
_cell_angle_alpha   67.819
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   309.046
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.263  0.308  0.176  1.0
  Ag  Ag1  1  0.763  0.692  0.324  1.0
  Ag  Ag2  1  0.237  0.308  0.676  1.0
  Ag  Ag3  1  0.737  0.692  0.824  1.0
  Cl  Cl4  1  0.223  0.823  0.025  1.0
  Cl  Cl5  1  0.723  0.177  0.475  1.0
  Cl  Cl6  1  0.277  0.823  0.525  1.0
  Cl  Cl7  1  0.777  0.177  0.975  1.0
  O  O8  1  0.843  0.092  0.154  1.0
  O  O9  1  0.478  0.728  0.043  1.0
  O  O10  1  0.044  0.643  0.107  1.0
  O  O11  1  0.544  0.357  0.393  1.0
  O  O12  1  0.978  0.272  0.457  1.0
  O  O13  1  0.343  0.908  0.346  1.0
  O  O14  1  0.657  0.092  0.654  1.0
  O  O15  1  0.022  0.728  0.543  1.0
  O  O16  1  0.456  0.643  0.607  1.0
  O  O17  1  0.956  0.357  0.893  1.0
  O  O18  1  0.522  0.272  0.957  1.0
  O  O19  1  0.157  0.908  0.846  1.0
[/CIF]
.