The compound described by NiNH12O9NO3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two nitric acid molecules and two NiNH12O9 clusters. In each NiNH12O9 cluster, Ni(1) is bonded in an octahedral geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. N(1) is bonded in a trigonal planar geometry to one O(7), one O(8), and one O(9) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(2) and one O(9) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(3) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one O(4) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one O(4) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one O(5) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one O(5) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one O(6) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one O(6) atom. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Ni(1), one H(1), and one H(2) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one Ni(1), one H(3), and one H(4) atom. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one Ni(1), one H(5), and one H(6) atom. In the fourth O site, O(4) is bonded in a distorted water-like geometry to one Ni(1), one H(7), and one H(8) atom. In the fifth O site, O(5) is bonded in a distorted water-like geometry to one Ni(1), one H(10), and one H(9) atom. In the sixth O site, O(6) is bonded in a distorted water-like geometry to one Ni(1), one H(11), and one H(12) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one N(1) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one N(1) atom. In the ninth O site, O(9) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_NiH12(NO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.888
_cell_length_b   7.680
_cell_length_c   11.868
_cell_angle_alpha   105.485
_cell_angle_beta   98.562
_cell_angle_gamma   101.680
_symmetry_Int_Tables_number   1
_cell_volume   494.617
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ni  Ni0  1  0.324  0.855  0.768  1.0
  Ni  Ni1  1  0.676  0.145  0.232  1.0
  H  H2  1  0.300  0.515  0.626  1.0
  H  H3  1  0.700  0.485  0.374  1.0
  H  H4  1  0.342  0.659  0.555  1.0
  H  H5  1  0.658  0.341  0.445  1.0
  H  H6  1  0.792  0.899  0.813  1.0
  H  H7  1  0.208  0.101  0.187  1.0
  H  H8  1  0.736  0.095  0.866  1.0
  H  H9  1  0.264  0.905  0.134  1.0
  H  H10  1  0.281  0.066  0.979  1.0
  H  H11  1  0.719  0.934  0.021  1.0
  H  H12  1  0.339  0.191  0.893  1.0
  H  H13  1  0.661  0.809  0.107  1.0
  H  H14  1  0.529  0.055  0.641  1.0
  H  H15  1  0.471  0.945  0.359  1.0
  H  H16  1  0.280  0.106  0.640  1.0
  H  H17  1  0.720  0.894  0.360  1.0
  H  H18  1  0.891  0.624  0.665  1.0
  H  H19  1  0.109  0.376  0.335  1.0
  H  H20  1  0.911  0.797  0.617  1.0
  H  H21  1  0.089  0.203  0.383  1.0
  H  H22  1  0.351  0.582  0.869  1.0
  H  H23  1  0.649  0.418  0.131  1.0
  H  H24  1  0.105  0.641  0.880  1.0
  H  H25  1  0.895  0.359  0.120  1.0
  N  N26  1  0.705  0.443  0.873  1.0
  N  N27  1  0.295  0.557  0.127  1.0
  N  N28  1  0.916  0.239  0.608  1.0
  N  N29  1  0.084  0.761  0.392  1.0
  O  O30  1  0.391  0.642  0.634  1.0
  O  O31  1  0.609  0.358  0.366  1.0
  O  O32  1  0.683  0.959  0.856  1.0
  O  O33  1  0.317  0.041  0.144  1.0
  O  O34  1  0.251  0.067  0.895  1.0
  O  O35  1  0.749  0.933  0.105  1.0
  O  O36  1  0.364  0.010  0.650  1.0
  O  O37  1  0.636  0.990  0.350  1.0
  O  O38  1  0.954  0.761  0.689  1.0
  O  O39  1  0.046  0.239  0.311  1.0
  O  O40  1  0.271  0.685  0.873  1.0
  O  O41  1  0.729  0.315  0.127  1.0
  O  O42  1  0.799  0.607  0.876  1.0
  O  O43  1  0.201  0.393  0.124  1.0
  O  O44  1  0.480  0.395  0.867  1.0
  O  O45  1  0.520  0.605  0.133  1.0
  O  O46  1  0.829  0.328  0.875  1.0
  O  O47  1  0.171  0.672  0.125  1.0
  O  O48  1  0.793  0.355  0.600  1.0
  O  O49  1  0.207  0.645  0.400  1.0
  O  O50  1  0.828  0.088  0.625  1.0
  O  O51  1  0.172  0.912  0.375  1.0
  O  O52  1  0.132  0.275  0.596  1.0
  O  O53  1  0.868  0.725  0.404  1.0
[/CIF]
.
The compound described by NiNH12O9NO3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two nitric acid molecules and two NiNH12O9 clusters. In each NiNH12O9 cluster, Ni(1) is bonded in an octahedral geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. N(1) is bonded in a trigonal planar geometry to one O(7), one O(8), and one O(9) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(2) and one O(9) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(3) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one O(4) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one O(4) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one O(5) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one O(5) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one O(6) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one O(6) atom. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Ni(1), one H(1), and one H(2) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one Ni(1), one H(3), and one H(4) atom. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one Ni(1), one H(5), and one H(6) atom. In the fourth O site, O(4) is bonded in a distorted water-like geometry to one Ni(1), one H(7), and one H(8) atom. In the fifth O site, O(5) is bonded in a distorted water-like geometry to one Ni(1), one H(10), and one H(9) atom. In the sixth O site, O(6) is bonded in a distorted water-like geometry to one Ni(1), one H(11), and one H(12) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one N(1) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one N(1) atom. In the ninth O site, O(9) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_NiH12(NO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.888
_cell_length_b   7.680
_cell_length_c   11.868
_cell_angle_alpha   105.485
_cell_angle_beta   98.562
_cell_angle_gamma   101.680
_symmetry_Int_Tables_number   1
_cell_volume   494.617
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ni  Ni0  1  0.324  0.855  0.768  1.0
  Ni  Ni1  1  0.676  0.145  0.232  1.0
  H  H2  1  0.300  0.515  0.626  1.0
  H  H3  1  0.700  0.485  0.374  1.0
  H  H4  1  0.342  0.659  0.555  1.0
  H  H5  1  0.658  0.341  0.445  1.0
  H  H6  1  0.792  0.899  0.813  1.0
  H  H7  1  0.208  0.101  0.187  1.0
  H  H8  1  0.736  0.095  0.866  1.0
  H  H9  1  0.264  0.905  0.134  1.0
  H  H10  1  0.281  0.066  0.979  1.0
  H  H11  1  0.719  0.934  0.021  1.0
  H  H12  1  0.339  0.191  0.893  1.0
  H  H13  1  0.661  0.809  0.107  1.0
  H  H14  1  0.529  0.055  0.641  1.0
  H  H15  1  0.471  0.945  0.359  1.0
  H  H16  1  0.280  0.106  0.640  1.0
  H  H17  1  0.720  0.894  0.360  1.0
  H  H18  1  0.891  0.624  0.665  1.0
  H  H19  1  0.109  0.376  0.335  1.0
  H  H20  1  0.911  0.797  0.617  1.0
  H  H21  1  0.089  0.203  0.383  1.0
  H  H22  1  0.351  0.582  0.869  1.0
  H  H23  1  0.649  0.418  0.131  1.0
  H  H24  1  0.105  0.641  0.880  1.0
  H  H25  1  0.895  0.359  0.120  1.0
  N  N26  1  0.705  0.443  0.873  1.0
  N  N27  1  0.295  0.557  0.127  1.0
  N  N28  1  0.916  0.239  0.608  1.0
  N  N29  1  0.084  0.761  0.392  1.0
  O  O30  1  0.391  0.642  0.634  1.0
  O  O31  1  0.609  0.358  0.366  1.0
  O  O32  1  0.683  0.959  0.856  1.0
  O  O33  1  0.317  0.041  0.144  1.0
  O  O34  1  0.251  0.067  0.895  1.0
  O  O35  1  0.749  0.933  0.105  1.0
  O  O36  1  0.364  0.010  0.650  1.0
  O  O37  1  0.636  0.990  0.350  1.0
  O  O38  1  0.954  0.761  0.689  1.0
  O  O39  1  0.046  0.239  0.311  1.0
  O  O40  1  0.271  0.685  0.873  1.0
  O  O41  1  0.729  0.315  0.127  1.0
  O  O42  1  0.799  0.607  0.876  1.0
  O  O43  1  0.201  0.393  0.124  1.0
  O  O44  1  0.480  0.395  0.867  1.0
  O  O45  1  0.520  0.605  0.133  1.0
  O  O46  1  0.829  0.328  0.875  1.0
  O  O47  1  0.171  0.672  0.125  1.0
  O  O48  1  0.793  0.355  0.600  1.0
  O  O49  1  0.207  0.645  0.400  1.0
  O  O50  1  0.828  0.088  0.625  1.0
  O  O51  1  0.172  0.912  0.375  1.0
  O  O52  1  0.132  0.275  0.596  1.0
  O  O53  1  0.868  0.725  0.404  1.0
[/CIF]
.