The compound described by K2PtS6 crystallizes in the monoclinic C2/m space group. K(1) is bonded in a 6-coordinate geometry to two equivalent S(1) and four equivalent S(2) atoms. Pt(1) is bonded in a distorted hexagonal planar geometry to two equivalent S(1) and four equivalent S(2) atoms. There are two inequivalent S sites. In the first S site, S(1) is bonded in a 3-coordinate geometry to two equivalent K(1) and one Pt(1) atom. In the second S site, S(2) is bonded in a 4-coordinate geometry to two equivalent K(1), one Pt(1), and one S(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_K2PtS6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.533
_cell_length_b   7.533
_cell_length_c   5.246
_cell_angle_alpha   89.595
_cell_angle_beta   89.595
_cell_angle_gamma   60.201
_symmetry_Int_Tables_number   1
_cell_volume   258.328
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.674  0.674  0.394  1.0
  K  K1  1  0.326  0.326  0.606  1.0
  Pt  Pt2  1  0.000  0.000  0.000  1.0
  S  S3  1  0.821  0.821  0.897  1.0
  S  S4  1  0.358  0.790  0.917  1.0
  S  S5  1  0.790  0.358  0.917  1.0
  S  S6  1  0.179  0.179  0.103  1.0
  S  S7  1  0.642  0.210  0.083  1.0
  S  S8  1  0.210  0.642  0.083  1.0
[/CIF]
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The compound described by K2PtS6 crystallizes in the monoclinic C2/m space group. K(1) is bonded in a 6-coordinate geometry to two equivalent S(1) and four equivalent S(2) atoms. Pt(1) is bonded in a distorted hexagonal planar geometry to two equivalent S(1) and four equivalent S(2) atoms. There are two inequivalent S sites. In the first S site, S(1) is bonded in a 3-coordinate geometry to two equivalent K(1) and one Pt(1) atom. In the second S site, S(2) is bonded in a 4-coordinate geometry to two equivalent K(1), one Pt(1), and one S(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_K2PtS6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.533
_cell_length_b   7.533
_cell_length_c   5.246
_cell_angle_alpha   89.595
_cell_angle_beta   89.595
_cell_angle_gamma   60.201
_symmetry_Int_Tables_number   1
_cell_volume   258.328
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.674  0.674  0.394  1.0
  K  K1  1  0.326  0.326  0.606  1.0
  Pt  Pt2  1  0.000  0.000  0.000  1.0
  S  S3  1  0.821  0.821  0.897  1.0
  S  S4  1  0.358  0.790  0.917  1.0
  S  S5  1  0.790  0.358  0.917  1.0
  S  S6  1  0.179  0.179  0.103  1.0
  S  S7  1  0.642  0.210  0.083  1.0
  S  S8  1  0.210  0.642  0.083  1.0
[/CIF]
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