The material structure described by CNH3F3Sb2F11 is Indium-derived structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two trifluoromethylazanium molecules and two Sb2F11 clusters. In each Sb2F11 cluster, there are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one F(1), one F(3), one F(7), one F(8), and two equivalent F(2) atoms to form corner-sharing SbF6 octahedra. The corner-sharing octahedral tilt angles are 38°. In the second Sb site, Sb(2) is bonded to one F(3), one F(4), two equivalent F(5), and two equivalent F(6) atoms to form corner-sharing SbF6 octahedra. The corner-sharing octahedral tilt angles are 38°. There are eight inequivalent F sites. In the first F site, F(7) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(8) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(3) is bonded in a bent 150 degrees geometry to one Sb(1) and one Sb(2) atom. In the sixth F site, F(4) is bonded in a single-bond geometry to one Sb(2) atom. In the seventh F site, F(5) is bonded in a single-bond geometry to one Sb(2) atom. In the eighth F site, F(6) is bonded in a single-bond geometry to one Sb(2) atom. is represented by the CIF file [CIF]
data_Sb2H3CNF14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.821
_cell_length_b   7.845
_cell_length_c   10.160
_cell_angle_alpha   90.000
_cell_angle_beta   98.439
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   616.646
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.250  0.250  0.474  1.0
  Sb  Sb1  1  0.750  0.750  0.526  1.0
  Sb  Sb2  1  0.498  0.250  0.167  1.0
  Sb  Sb3  1  0.502  0.750  0.833  1.0
  H  H4  1  0.828  0.250  0.681  1.0
  H  H5  1  0.172  0.750  0.319  1.0
  H  H6  1  0.723  0.359  0.789  1.0
  H  H7  1  0.277  0.859  0.211  1.0
  H  H8  1  0.277  0.641  0.211  1.0
  H  H9  1  0.723  0.141  0.789  1.0
  C  C10  1  0.958  0.250  0.875  1.0
  C  C11  1  0.042  0.750  0.125  1.0
  N  N12  1  0.796  0.250  0.776  1.0
  N  N13  1  0.204  0.750  0.224  1.0
  F  F14  1  0.094  0.250  0.312  1.0
  F  F15  1  0.906  0.750  0.688  1.0
  F  F16  1  0.263  0.008  0.460  1.0
  F  F17  1  0.737  0.508  0.540  1.0
  F  F18  1  0.737  0.992  0.540  1.0
  F  F19  1  0.263  0.492  0.460  1.0
  F  F20  1  0.452  0.250  0.361  1.0
  F  F21  1  0.548  0.750  0.639  1.0
  F  F22  1  0.532  0.250  0.986  1.0
  F  F23  1  0.468  0.750  0.014  1.0
  F  F24  1  0.661  0.077  0.221  1.0
  F  F25  1  0.339  0.577  0.779  1.0
  F  F26  1  0.339  0.923  0.779  1.0
  F  F27  1  0.661  0.423  0.221  1.0
  F  F28  1  0.320  0.422  0.138  1.0
  F  F29  1  0.680  0.922  0.862  1.0
  F  F30  1  0.680  0.578  0.862  1.0
  F  F31  1  0.320  0.078  0.138  1.0
  F  F32  1  0.074  0.250  0.586  1.0
  F  F33  1  0.926  0.750  0.414  1.0
  F  F34  1  0.435  0.250  0.618  1.0
  F  F35  1  0.565  0.750  0.382  1.0
  F  F36  1  0.048  0.110  0.856  1.0
  F  F37  1  0.952  0.610  0.144  1.0
  F  F38  1  0.952  0.890  0.144  1.0
  F  F39  1  0.048  0.390  0.856  1.0
  F  F40  1  0.914  0.250  0.998  1.0
  F  F41  1  0.086  0.750  0.002  1.0
[/CIF]
.
The material structure described by CNH3F3Sb2F11 is Indium-derived structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two trifluoromethylazanium molecules and two Sb2F11 clusters. In each Sb2F11 cluster, there are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one F(1), one F(3), one F(7), one F(8), and two equivalent F(2) atoms to form corner-sharing SbF6 octahedra. The corner-sharing octahedral tilt angles are 38°. In the second Sb site, Sb(2) is bonded to one F(3), one F(4), two equivalent F(5), and two equivalent F(6) atoms to form corner-sharing SbF6 octahedra. The corner-sharing octahedral tilt angles are 38°. There are eight inequivalent F sites. In the first F site, F(7) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(8) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(3) is bonded in a bent 150 degrees geometry to one Sb(1) and one Sb(2) atom. In the sixth F site, F(4) is bonded in a single-bond geometry to one Sb(2) atom. In the seventh F site, F(5) is bonded in a single-bond geometry to one Sb(2) atom. In the eighth F site, F(6) is bonded in a single-bond geometry to one Sb(2) atom. is represented by the CIF file [CIF]
data_Sb2H3CNF14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.821
_cell_length_b   7.845
_cell_length_c   10.160
_cell_angle_alpha   90.000
_cell_angle_beta   98.439
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   616.646
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.250  0.250  0.474  1.0
  Sb  Sb1  1  0.750  0.750  0.526  1.0
  Sb  Sb2  1  0.498  0.250  0.167  1.0
  Sb  Sb3  1  0.502  0.750  0.833  1.0
  H  H4  1  0.828  0.250  0.681  1.0
  H  H5  1  0.172  0.750  0.319  1.0
  H  H6  1  0.723  0.359  0.789  1.0
  H  H7  1  0.277  0.859  0.211  1.0
  H  H8  1  0.277  0.641  0.211  1.0
  H  H9  1  0.723  0.141  0.789  1.0
  C  C10  1  0.958  0.250  0.875  1.0
  C  C11  1  0.042  0.750  0.125  1.0
  N  N12  1  0.796  0.250  0.776  1.0
  N  N13  1  0.204  0.750  0.224  1.0
  F  F14  1  0.094  0.250  0.312  1.0
  F  F15  1  0.906  0.750  0.688  1.0
  F  F16  1  0.263  0.008  0.460  1.0
  F  F17  1  0.737  0.508  0.540  1.0
  F  F18  1  0.737  0.992  0.540  1.0
  F  F19  1  0.263  0.492  0.460  1.0
  F  F20  1  0.452  0.250  0.361  1.0
  F  F21  1  0.548  0.750  0.639  1.0
  F  F22  1  0.532  0.250  0.986  1.0
  F  F23  1  0.468  0.750  0.014  1.0
  F  F24  1  0.661  0.077  0.221  1.0
  F  F25  1  0.339  0.577  0.779  1.0
  F  F26  1  0.339  0.923  0.779  1.0
  F  F27  1  0.661  0.423  0.221  1.0
  F  F28  1  0.320  0.422  0.138  1.0
  F  F29  1  0.680  0.922  0.862  1.0
  F  F30  1  0.680  0.578  0.862  1.0
  F  F31  1  0.320  0.078  0.138  1.0
  F  F32  1  0.074  0.250  0.586  1.0
  F  F33  1  0.926  0.750  0.414  1.0
  F  F34  1  0.435  0.250  0.618  1.0
  F  F35  1  0.565  0.750  0.382  1.0
  F  F36  1  0.048  0.110  0.856  1.0
  F  F37  1  0.952  0.610  0.144  1.0
  F  F38  1  0.952  0.890  0.144  1.0
  F  F39  1  0.048  0.390  0.856  1.0
  F  F40  1  0.914  0.250  0.998  1.0
  F  F41  1  0.086  0.750  0.002  1.0
[/CIF]
.