The structure described by Hf5(RhIn2)2 crystallizes in the orthorhombic Pbam space group. There are three inequivalent Hf sites. In the first Hf site, Hf(1) is bonded in a 4-coordinate geometry to four equivalent Rh(1), two equivalent In(1), and four equivalent In(2) atoms. In the second Hf site, Hf(2) is bonded in a 2-coordinate geometry to two equivalent Rh(1), two equivalent In(2), and four equivalent In(1) atoms. In the third Hf site, Hf(3) is bonded in a 8-coordinate geometry to four equivalent In(1) and four equivalent In(2) atoms. Rh(1) is bonded in a 9-coordinate geometry to two equivalent Hf(2), four equivalent Hf(1), one In(1), and two equivalent In(2) atoms. There are two inequivalent In sites. In the first In site, In(1) is bonded in a 12-coordinate geometry to two equivalent Hf(1), two equivalent Hf(3), four equivalent Hf(2), one Rh(1), one In(2), and two equivalent In(1) atoms. In the second In site, In(2) is bonded in a 13-coordinate geometry to two equivalent Hf(2), two equivalent Hf(3), four equivalent Hf(1), two equivalent Rh(1), one In(1), and two equivalent In(2) atoms. is represented by the CIF card [CIF]
data_Hf5(In2Rh)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.354
_cell_length_b   7.553
_cell_length_c   17.365
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   439.945
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Hf  Hf0  1  0.000  0.265  0.223  1.0
  Hf  Hf1  1  0.000  0.641  0.081  1.0
  Hf  Hf2  1  0.000  0.765  0.277  1.0
  Hf  Hf3  1  0.000  0.859  0.581  1.0
  Hf  Hf4  1  0.000  0.235  0.723  1.0
  Hf  Hf5  1  0.000  0.735  0.777  1.0
  Hf  Hf6  1  0.000  0.141  0.419  1.0
  Hf  Hf7  1  0.000  0.000  0.000  1.0
  Hf  Hf8  1  0.000  0.359  0.919  1.0
  Hf  Hf9  1  0.000  0.500  0.500  1.0
  In  In10  1  0.500  0.803  0.433  1.0
  In  In11  1  0.500  0.697  0.933  1.0
  In  In12  1  0.500  0.056  0.851  1.0
  In  In13  1  0.500  0.556  0.649  1.0
  In  In14  1  0.500  0.197  0.567  1.0
  In  In15  1  0.500  0.944  0.149  1.0
  In  In16  1  0.500  0.444  0.351  1.0
  In  In17  1  0.500  0.303  0.067  1.0
  Rh  Rh18  1  0.500  0.445  0.807  1.0
  Rh  Rh19  1  0.500  0.555  0.193  1.0
  Rh  Rh20  1  0.500  0.945  0.693  1.0
  Rh  Rh21  1  0.500  0.055  0.307  1.0
[/CIF]
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The structure described by Hf5(RhIn2)2 crystallizes in the orthorhombic Pbam space group. There are three inequivalent Hf sites. In the first Hf site, Hf(1) is bonded in a 4-coordinate geometry to four equivalent Rh(1), two equivalent In(1), and four equivalent In(2) atoms. In the second Hf site, Hf(2) is bonded in a 2-coordinate geometry to two equivalent Rh(1), two equivalent In(2), and four equivalent In(1) atoms. In the third Hf site, Hf(3) is bonded in a 8-coordinate geometry to four equivalent In(1) and four equivalent In(2) atoms. Rh(1) is bonded in a 9-coordinate geometry to two equivalent Hf(2), four equivalent Hf(1), one In(1), and two equivalent In(2) atoms. There are two inequivalent In sites. In the first In site, In(1) is bonded in a 12-coordinate geometry to two equivalent Hf(1), two equivalent Hf(3), four equivalent Hf(2), one Rh(1), one In(2), and two equivalent In(1) atoms. In the second In site, In(2) is bonded in a 13-coordinate geometry to two equivalent Hf(2), two equivalent Hf(3), four equivalent Hf(1), two equivalent Rh(1), one In(1), and two equivalent In(2) atoms. is represented by the CIF card [CIF]
data_Hf5(In2Rh)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.354
_cell_length_b   7.553
_cell_length_c   17.365
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   439.945
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Hf  Hf0  1  0.000  0.265  0.223  1.0
  Hf  Hf1  1  0.000  0.641  0.081  1.0
  Hf  Hf2  1  0.000  0.765  0.277  1.0
  Hf  Hf3  1  0.000  0.859  0.581  1.0
  Hf  Hf4  1  0.000  0.235  0.723  1.0
  Hf  Hf5  1  0.000  0.735  0.777  1.0
  Hf  Hf6  1  0.000  0.141  0.419  1.0
  Hf  Hf7  1  0.000  0.000  0.000  1.0
  Hf  Hf8  1  0.000  0.359  0.919  1.0
  Hf  Hf9  1  0.000  0.500  0.500  1.0
  In  In10  1  0.500  0.803  0.433  1.0
  In  In11  1  0.500  0.697  0.933  1.0
  In  In12  1  0.500  0.056  0.851  1.0
  In  In13  1  0.500  0.556  0.649  1.0
  In  In14  1  0.500  0.197  0.567  1.0
  In  In15  1  0.500  0.944  0.149  1.0
  In  In16  1  0.500  0.444  0.351  1.0
  In  In17  1  0.500  0.303  0.067  1.0
  Rh  Rh18  1  0.500  0.445  0.807  1.0
  Rh  Rh19  1  0.500  0.555  0.193  1.0
  Rh  Rh20  1  0.500  0.945  0.693  1.0
  Rh  Rh21  1  0.500  0.055  0.307  1.0
[/CIF]
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