The compound described by RbLiS is Matlockite structured and crystallizes in the tetragonal P4/nmm space group. Rb(1) is bonded in a 5-coordinate geometry to five equivalent S(1) atoms. Li(1) is bonded to four equivalent S(1) atoms to form a mixture of distorted corner and edge-sharing LiS4 tetrahedra. S(1) is bonded in a 4-coordinate geometry to five equivalent Rb(1) and four equivalent Li(1) atoms. is represented by the CIF card [CIF]
data_RbLiS
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.412
_cell_length_b   4.412
_cell_length_c   7.263
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   141.372
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.250  0.250  0.660  1.0
  Rb  Rb1  1  0.750  0.750  0.340  1.0
  Li  Li2  1  0.250  0.750  0.000  1.0
  Li  Li3  1  0.750  0.250  0.000  1.0
  S  S4  1  0.250  0.250  0.175  1.0
  S  S5  1  0.750  0.750  0.825  1.0
[/CIF]
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The compound described by RbLiS is Matlockite structured and crystallizes in the tetragonal P4/nmm space group. Rb(1) is bonded in a 5-coordinate geometry to five equivalent S(1) atoms. Li(1) is bonded to four equivalent S(1) atoms to form a mixture of distorted corner and edge-sharing LiS4 tetrahedra. S(1) is bonded in a 4-coordinate geometry to five equivalent Rb(1) and four equivalent Li(1) atoms. is represented by the CIF card [CIF]
data_RbLiS
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.412
_cell_length_b   4.412
_cell_length_c   7.263
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   141.372
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.250  0.250  0.660  1.0
  Rb  Rb1  1  0.750  0.750  0.340  1.0
  Li  Li2  1  0.250  0.750  0.000  1.0
  Li  Li3  1  0.750  0.250  0.000  1.0
  S  S4  1  0.250  0.250  0.175  1.0
  S  S5  1  0.750  0.750  0.825  1.0
[/CIF]
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