The crystal structure described by (VO2)3VF2 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two bis(oxidanyl)vanadium molecules, two difluorovanadium molecules, and four hydroxy(oxo)vanadium molecules. is represented by the CIF file [CIF]
data_V2O3F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.560
_cell_length_b   5.616
_cell_length_c   9.841
_cell_angle_alpha   101.682
_cell_angle_beta   96.493
_cell_angle_gamma   115.074
_symmetry_Int_Tables_number   1
_cell_volume   265.597
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.762  0.314  0.975  1.0
  V  V1  1  0.000  0.500  0.500  1.0
  V  V2  1  0.127  0.144  0.749  1.0
  V  V3  1  0.873  0.856  0.251  1.0
  V  V4  1  0.389  0.373  0.251  1.0
  V  V5  1  0.238  0.686  0.025  1.0
  V  V6  1  0.500  0.000  0.500  1.0
  V  V7  1  0.611  0.627  0.749  1.0
  O  O8  1  0.020  0.714  0.595  1.0
  O  O9  1  0.739  0.053  0.904  1.0
  O  O10  1  0.980  0.286  0.405  1.0
  O  O11  1  0.475  0.783  0.404  1.0
  O  O12  1  0.424  0.624  0.651  1.0
  O  O13  1  0.576  0.376  0.349  1.0
  O  O14  1  0.826  0.644  0.844  1.0
  O  O15  1  0.762  0.449  0.095  1.0
  O  O16  1  0.261  0.947  0.096  1.0
  O  O17  1  0.525  0.217  0.596  1.0
  O  O18  1  0.238  0.551  0.905  1.0
  O  O19  1  0.174  0.356  0.156  1.0
  F  F20  1  0.074  0.865  0.353  1.0
  F  F21  1  0.678  0.874  0.149  1.0
  F  F22  1  0.926  0.135  0.647  1.0
  F  F23  1  0.322  0.126  0.851  1.0
[/CIF]
.
The crystal structure described by (VO2)3VF2 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two bis(oxidanyl)vanadium molecules, two difluorovanadium molecules, and four hydroxy(oxo)vanadium molecules. is represented by the CIF file [CIF]
data_V2O3F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.560
_cell_length_b   5.616
_cell_length_c   9.841
_cell_angle_alpha   101.682
_cell_angle_beta   96.493
_cell_angle_gamma   115.074
_symmetry_Int_Tables_number   1
_cell_volume   265.597
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.762  0.314  0.975  1.0
  V  V1  1  0.000  0.500  0.500  1.0
  V  V2  1  0.127  0.144  0.749  1.0
  V  V3  1  0.873  0.856  0.251  1.0
  V  V4  1  0.389  0.373  0.251  1.0
  V  V5  1  0.238  0.686  0.025  1.0
  V  V6  1  0.500  0.000  0.500  1.0
  V  V7  1  0.611  0.627  0.749  1.0
  O  O8  1  0.020  0.714  0.595  1.0
  O  O9  1  0.739  0.053  0.904  1.0
  O  O10  1  0.980  0.286  0.405  1.0
  O  O11  1  0.475  0.783  0.404  1.0
  O  O12  1  0.424  0.624  0.651  1.0
  O  O13  1  0.576  0.376  0.349  1.0
  O  O14  1  0.826  0.644  0.844  1.0
  O  O15  1  0.762  0.449  0.095  1.0
  O  O16  1  0.261  0.947  0.096  1.0
  O  O17  1  0.525  0.217  0.596  1.0
  O  O18  1  0.238  0.551  0.905  1.0
  O  O19  1  0.174  0.356  0.156  1.0
  F  F20  1  0.074  0.865  0.353  1.0
  F  F21  1  0.678  0.874  0.149  1.0
  F  F22  1  0.926  0.135  0.647  1.0
  F  F23  1  0.322  0.126  0.851  1.0
[/CIF]
.