The material structure described by N2(PNO4F)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four ammonia atoms and four PNO4F clusters. In each PNO4F cluster, P(1) is bonded in a distorted trigonal pyramidal geometry to one O(1), one O(2), one O(3), and one F(1) atom. N(2) is bonded in a bent 120 degrees geometry to one O(3) and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one P(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one P(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one P(1) and one N(2) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one N(2) atom. F(1) is bonded in a single-bond geometry to one P(1) atom. is represented by the CIF card [CIF]
data_PN2O4F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.742
_cell_length_b   8.003
_cell_length_c   15.092
_cell_angle_alpha   90.000
_cell_angle_beta   89.250
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   693.454
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.728  0.073  0.634  1.0
  P  P1  1  0.272  0.573  0.866  1.0
  P  P2  1  0.272  0.927  0.366  1.0
  P  P3  1  0.728  0.427  0.134  1.0
  N  N4  1  0.647  0.328  0.868  1.0
  N  N5  1  0.353  0.828  0.632  1.0
  N  N6  1  0.353  0.672  0.132  1.0
  N  N7  1  0.647  0.172  0.368  1.0
  N  N8  1  0.128  0.326  0.646  1.0
  N  N9  1  0.872  0.826  0.854  1.0
  N  N10  1  0.872  0.674  0.354  1.0
  N  N11  1  0.128  0.174  0.146  1.0
  O  O12  1  0.671  0.048  0.728  1.0
  O  O13  1  0.329  0.548  0.772  1.0
  O  O14  1  0.329  0.952  0.272  1.0
  O  O15  1  0.671  0.452  0.228  1.0
  O  O16  1  0.649  0.193  0.567  1.0
  O  O17  1  0.351  0.693  0.933  1.0
  O  O18  1  0.351  0.807  0.433  1.0
  O  O19  1  0.649  0.307  0.067  1.0
  O  O20  1  0.086  0.178  0.659  1.0
  O  O21  1  0.914  0.678  0.841  1.0
  O  O22  1  0.914  0.822  0.341  1.0
  O  O23  1  0.086  0.322  0.159  1.0
  O  O24  1  0.987  0.941  0.879  1.0
  O  O25  1  0.013  0.441  0.621  1.0
  O  O26  1  0.013  0.059  0.121  1.0
  O  O27  1  0.987  0.559  0.379  1.0
  F  F28  1  0.148  0.418  0.909  1.0
  F  F29  1  0.852  0.918  0.591  1.0
  F  F30  1  0.852  0.582  0.091  1.0
  F  F31  1  0.148  0.082  0.409  1.0
[/CIF]
.
The material structure described by N2(PNO4F)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four ammonia atoms and four PNO4F clusters. In each PNO4F cluster, P(1) is bonded in a distorted trigonal pyramidal geometry to one O(1), one O(2), one O(3), and one F(1) atom. N(2) is bonded in a bent 120 degrees geometry to one O(3) and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one P(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one P(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one P(1) and one N(2) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one N(2) atom. F(1) is bonded in a single-bond geometry to one P(1) atom. is represented by the CIF card [CIF]
data_PN2O4F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.742
_cell_length_b   8.003
_cell_length_c   15.092
_cell_angle_alpha   90.000
_cell_angle_beta   89.250
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   693.454
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.728  0.073  0.634  1.0
  P  P1  1  0.272  0.573  0.866  1.0
  P  P2  1  0.272  0.927  0.366  1.0
  P  P3  1  0.728  0.427  0.134  1.0
  N  N4  1  0.647  0.328  0.868  1.0
  N  N5  1  0.353  0.828  0.632  1.0
  N  N6  1  0.353  0.672  0.132  1.0
  N  N7  1  0.647  0.172  0.368  1.0
  N  N8  1  0.128  0.326  0.646  1.0
  N  N9  1  0.872  0.826  0.854  1.0
  N  N10  1  0.872  0.674  0.354  1.0
  N  N11  1  0.128  0.174  0.146  1.0
  O  O12  1  0.671  0.048  0.728  1.0
  O  O13  1  0.329  0.548  0.772  1.0
  O  O14  1  0.329  0.952  0.272  1.0
  O  O15  1  0.671  0.452  0.228  1.0
  O  O16  1  0.649  0.193  0.567  1.0
  O  O17  1  0.351  0.693  0.933  1.0
  O  O18  1  0.351  0.807  0.433  1.0
  O  O19  1  0.649  0.307  0.067  1.0
  O  O20  1  0.086  0.178  0.659  1.0
  O  O21  1  0.914  0.678  0.841  1.0
  O  O22  1  0.914  0.822  0.341  1.0
  O  O23  1  0.086  0.322  0.159  1.0
  O  O24  1  0.987  0.941  0.879  1.0
  O  O25  1  0.013  0.441  0.621  1.0
  O  O26  1  0.013  0.059  0.121  1.0
  O  O27  1  0.987  0.559  0.379  1.0
  F  F28  1  0.148  0.418  0.909  1.0
  F  F29  1  0.852  0.918  0.591  1.0
  F  F30  1  0.852  0.582  0.091  1.0
  F  F31  1  0.148  0.082  0.409  1.0
[/CIF]
.