The compound described by GeF6(SF3)2 is Indium-derived structured and crystallizes in the orthorhombic Pnnm space group. The structure is zero-dimensional and consists of two GeF6 clusters and four SF3 clusters. In each GeF6 cluster, Ge(1) is bonded in an octahedral geometry to two equivalent F(3) and four equivalent F(1) atoms. There are two inequivalent F sites. In the first F site, F(3) is bonded in a single-bond geometry to one Ge(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one Ge(1) atom. In each SF3 cluster, S(1) is bonded in a 3-coordinate geometry to three equivalent F(2,4) atoms. F(2,4) is bonded in a single-bond geometry to one S(1) atom. is represented by the CIF file [CIF]
data_Ge(SF6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.035
_cell_length_b   7.445
_cell_length_c   9.491
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   426.447
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ge  Ge0  1  0.000  0.500  0.000  1.0
  Ge  Ge1  1  0.500  0.000  0.500  1.0
  S  S2  1  0.500  0.569  0.243  1.0
  S  S3  1  0.500  0.431  0.757  1.0
  S  S4  1  0.000  0.069  0.257  1.0
  S  S5  1  0.000  0.931  0.743  1.0
  F  F6  1  0.211  0.366  0.915  1.0
  F  F7  1  0.211  0.634  0.085  1.0
  F  F8  1  0.289  0.866  0.585  1.0
  F  F9  1  0.289  0.134  0.415  1.0
  F  F10  1  0.789  0.634  0.085  1.0
  F  F11  1  0.789  0.366  0.915  1.0
  F  F12  1  0.811  0.972  0.848  1.0
  F  F13  1  0.811  0.028  0.152  1.0
  F  F14  1  0.689  0.472  0.652  1.0
  F  F15  1  0.689  0.528  0.348  1.0
  F  F16  1  0.189  0.028  0.152  1.0
  F  F17  1  0.189  0.972  0.848  1.0
  F  F18  1  0.311  0.528  0.348  1.0
  F  F19  1  0.311  0.472  0.652  1.0
  F  F20  1  0.000  0.650  0.851  1.0
  F  F21  1  0.000  0.350  0.149  1.0
  F  F22  1  0.500  0.150  0.649  1.0
  F  F23  1  0.500  0.850  0.351  1.0
  F  F24  1  0.500  0.619  0.825  1.0
  F  F25  1  0.500  0.381  0.175  1.0
  F  F26  1  0.000  0.119  0.675  1.0
  F  F27  1  0.000  0.881  0.325  1.0
  F  F28  1  0.711  0.866  0.585  1.0
  F  F29  1  0.711  0.134  0.415  1.0
[/CIF]
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The compound described by GeF6(SF3)2 is Indium-derived structured and crystallizes in the orthorhombic Pnnm space group. The structure is zero-dimensional and consists of two GeF6 clusters and four SF3 clusters. In each GeF6 cluster, Ge(1) is bonded in an octahedral geometry to two equivalent F(3) and four equivalent F(1) atoms. There are two inequivalent F sites. In the first F site, F(3) is bonded in a single-bond geometry to one Ge(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one Ge(1) atom. In each SF3 cluster, S(1) is bonded in a 3-coordinate geometry to three equivalent F(2,4) atoms. F(2,4) is bonded in a single-bond geometry to one S(1) atom. is represented by the CIF file [CIF]
data_Ge(SF6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.035
_cell_length_b   7.445
_cell_length_c   9.491
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   426.447
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ge  Ge0  1  0.000  0.500  0.000  1.0
  Ge  Ge1  1  0.500  0.000  0.500  1.0
  S  S2  1  0.500  0.569  0.243  1.0
  S  S3  1  0.500  0.431  0.757  1.0
  S  S4  1  0.000  0.069  0.257  1.0
  S  S5  1  0.000  0.931  0.743  1.0
  F  F6  1  0.211  0.366  0.915  1.0
  F  F7  1  0.211  0.634  0.085  1.0
  F  F8  1  0.289  0.866  0.585  1.0
  F  F9  1  0.289  0.134  0.415  1.0
  F  F10  1  0.789  0.634  0.085  1.0
  F  F11  1  0.789  0.366  0.915  1.0
  F  F12  1  0.811  0.972  0.848  1.0
  F  F13  1  0.811  0.028  0.152  1.0
  F  F14  1  0.689  0.472  0.652  1.0
  F  F15  1  0.689  0.528  0.348  1.0
  F  F16  1  0.189  0.028  0.152  1.0
  F  F17  1  0.189  0.972  0.848  1.0
  F  F18  1  0.311  0.528  0.348  1.0
  F  F19  1  0.311  0.472  0.652  1.0
  F  F20  1  0.000  0.650  0.851  1.0
  F  F21  1  0.000  0.350  0.149  1.0
  F  F22  1  0.500  0.150  0.649  1.0
  F  F23  1  0.500  0.850  0.351  1.0
  F  F24  1  0.500  0.619  0.825  1.0
  F  F25  1  0.500  0.381  0.175  1.0
  F  F26  1  0.000  0.119  0.675  1.0
  F  F27  1  0.000  0.881  0.325  1.0
  F  F28  1  0.711  0.866  0.585  1.0
  F  F29  1  0.711  0.134  0.415  1.0
[/CIF]
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