The structure described by (YH12(O3Cl)2)2Cl2 crystallizes in the monoclinic P2/c space group. The structure consists of two hydrochloric acid atoms inside a YH12(O3Cl)2 framework. In the YH12(O3Cl)2 framework, Y(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent Cl(2) atoms. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) and one Cl(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(2) and one Cl(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(3) and one Cl(2) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Y(1), one H(1), and one H(2) atom. In the second O site, O(2) is bonded in a water-like geometry to one Y(1), one H(3), and one H(4) atom. In the third O site, O(3) is bonded in a water-like geometry to one Y(1), one H(5), and one H(6) atom. Cl(2) is bonded in a 4-coordinate geometry to one Y(1), one H(1), one H(4), and one H(5) atom. is represented by the CIF card [CIF]
data_YH12(ClO2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.469
_cell_length_b   7.784
_cell_length_c   11.902
_cell_angle_alpha   52.988
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   478.543
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Y  Y0  1  0.844  0.000  0.750  1.0
  Y  Y1  1  0.156  0.000  0.250  1.0
  H  H2  1  0.904  0.758  0.632  1.0
  H  H3  1  0.904  0.242  0.868  1.0
  H  H4  1  0.096  0.242  0.368  1.0
  H  H5  1  0.096  0.758  0.132  1.0
  H  H6  1  0.085  0.678  0.739  1.0
  H  H7  1  0.085  0.322  0.761  1.0
  H  H8  1  0.915  0.322  0.261  1.0
  H  H9  1  0.915  0.678  0.239  1.0
  H  H10  1  0.530  0.799  0.683  1.0
  H  H11  1  0.530  0.201  0.817  1.0
  H  H12  1  0.470  0.201  0.317  1.0
  H  H13  1  0.470  0.799  0.183  1.0
  H  H14  1  0.450  0.032  0.614  1.0
  H  H15  1  0.450  0.968  0.886  1.0
  H  H16  1  0.550  0.968  0.386  1.0
  H  H17  1  0.550  0.032  0.114  1.0
  H  H18  1  0.752  0.534  0.958  1.0
  H  H19  1  0.752  0.466  0.542  1.0
  H  H20  1  0.248  0.466  0.042  1.0
  H  H21  1  0.248  0.534  0.458  1.0
  H  H22  1  0.335  0.633  0.530  1.0
  H  H23  1  0.335  0.367  0.970  1.0
  H  H24  1  0.665  0.367  0.470  1.0
  H  H25  1  0.665  0.633  0.030  1.0
  Cl  Cl26  1  0.372  0.500  0.750  1.0
  Cl  Cl27  1  0.628  0.500  0.250  1.0
  Cl  Cl28  1  0.167  0.202  0.558  1.0
  Cl  Cl29  1  0.167  0.798  0.942  1.0
  Cl  Cl30  1  0.833  0.798  0.442  1.0
  Cl  Cl31  1  0.833  0.202  0.058  1.0
  O  O32  1  0.947  0.741  0.718  1.0
  O  O33  1  0.947  0.259  0.782  1.0
  O  O34  1  0.053  0.259  0.282  1.0
  O  O35  1  0.053  0.741  0.218  1.0
  O  O36  1  0.576  0.944  0.644  1.0
  O  O37  1  0.576  0.056  0.856  1.0
  O  O38  1  0.424  0.056  0.356  1.0
  O  O39  1  0.424  0.944  0.144  1.0
  O  O40  1  0.702  0.669  0.938  1.0
  O  O41  1  0.702  0.331  0.562  1.0
  O  O42  1  0.298  0.331  0.062  1.0
  O  O43  1  0.298  0.669  0.438  1.0
[/CIF]
.
The structure described by (YH12(O3Cl)2)2Cl2 crystallizes in the monoclinic P2/c space group. The structure consists of two hydrochloric acid atoms inside a YH12(O3Cl)2 framework. In the YH12(O3Cl)2 framework, Y(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent Cl(2) atoms. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) and one Cl(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(2) and one Cl(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(3) and one Cl(2) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Y(1), one H(1), and one H(2) atom. In the second O site, O(2) is bonded in a water-like geometry to one Y(1), one H(3), and one H(4) atom. In the third O site, O(3) is bonded in a water-like geometry to one Y(1), one H(5), and one H(6) atom. Cl(2) is bonded in a 4-coordinate geometry to one Y(1), one H(1), one H(4), and one H(5) atom. is represented by the CIF card [CIF]
data_YH12(ClO2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.469
_cell_length_b   7.784
_cell_length_c   11.902
_cell_angle_alpha   52.988
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   478.543
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Y  Y0  1  0.844  0.000  0.750  1.0
  Y  Y1  1  0.156  0.000  0.250  1.0
  H  H2  1  0.904  0.758  0.632  1.0
  H  H3  1  0.904  0.242  0.868  1.0
  H  H4  1  0.096  0.242  0.368  1.0
  H  H5  1  0.096  0.758  0.132  1.0
  H  H6  1  0.085  0.678  0.739  1.0
  H  H7  1  0.085  0.322  0.761  1.0
  H  H8  1  0.915  0.322  0.261  1.0
  H  H9  1  0.915  0.678  0.239  1.0
  H  H10  1  0.530  0.799  0.683  1.0
  H  H11  1  0.530  0.201  0.817  1.0
  H  H12  1  0.470  0.201  0.317  1.0
  H  H13  1  0.470  0.799  0.183  1.0
  H  H14  1  0.450  0.032  0.614  1.0
  H  H15  1  0.450  0.968  0.886  1.0
  H  H16  1  0.550  0.968  0.386  1.0
  H  H17  1  0.550  0.032  0.114  1.0
  H  H18  1  0.752  0.534  0.958  1.0
  H  H19  1  0.752  0.466  0.542  1.0
  H  H20  1  0.248  0.466  0.042  1.0
  H  H21  1  0.248  0.534  0.458  1.0
  H  H22  1  0.335  0.633  0.530  1.0
  H  H23  1  0.335  0.367  0.970  1.0
  H  H24  1  0.665  0.367  0.470  1.0
  H  H25  1  0.665  0.633  0.030  1.0
  Cl  Cl26  1  0.372  0.500  0.750  1.0
  Cl  Cl27  1  0.628  0.500  0.250  1.0
  Cl  Cl28  1  0.167  0.202  0.558  1.0
  Cl  Cl29  1  0.167  0.798  0.942  1.0
  Cl  Cl30  1  0.833  0.798  0.442  1.0
  Cl  Cl31  1  0.833  0.202  0.058  1.0
  O  O32  1  0.947  0.741  0.718  1.0
  O  O33  1  0.947  0.259  0.782  1.0
  O  O34  1  0.053  0.259  0.282  1.0
  O  O35  1  0.053  0.741  0.218  1.0
  O  O36  1  0.576  0.944  0.644  1.0
  O  O37  1  0.576  0.056  0.856  1.0
  O  O38  1  0.424  0.056  0.356  1.0
  O  O39  1  0.424  0.944  0.144  1.0
  O  O40  1  0.702  0.669  0.938  1.0
  O  O41  1  0.702  0.331  0.562  1.0
  O  O42  1  0.298  0.331  0.062  1.0
  O  O43  1  0.298  0.669  0.438  1.0
[/CIF]
.