The compound described by (NbCl6)2N2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four ammonia atoms and four NbCl6 clusters. In each NbCl6 cluster, Nb(1) is bonded in an octahedral geometry to two equivalent Cl(1), two equivalent Cl(2), and two equivalent Cl(3) atoms. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Nb(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Nb(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Nb(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_NbNCl6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.001
_cell_length_b   7.001
_cell_length_c   12.520
_cell_angle_alpha   79.054
_cell_angle_beta   79.054
_cell_angle_gamma   55.261
_symmetry_Int_Tables_number   1
_cell_volume   492.601
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Nb  Nb0  1  0.500  0.000  0.500  1.0
  Nb  Nb1  1  0.000  0.500  0.000  1.0
  N  N2  1  0.881  0.119  0.750  1.0
  N  N3  1  0.119  0.881  0.250  1.0
  Cl  Cl4  1  0.465  0.700  0.603  1.0
  Cl  Cl5  1  0.535  0.300  0.397  1.0
  Cl  Cl6  1  0.300  0.535  0.897  1.0
  Cl  Cl7  1  0.700  0.465  0.103  1.0
  Cl  Cl8  1  0.370  0.200  0.659  1.0
  Cl  Cl9  1  0.630  0.800  0.341  1.0
  Cl  Cl10  1  0.800  0.630  0.841  1.0
  Cl  Cl11  1  0.200  0.370  0.159  1.0
  Cl  Cl12  1  0.794  0.895  0.041  1.0
  Cl  Cl13  1  0.206  0.105  0.959  1.0
  Cl  Cl14  1  0.105  0.206  0.459  1.0
  Cl  Cl15  1  0.895  0.794  0.541  1.0
[/CIF]
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The compound described by (NbCl6)2N2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four ammonia atoms and four NbCl6 clusters. In each NbCl6 cluster, Nb(1) is bonded in an octahedral geometry to two equivalent Cl(1), two equivalent Cl(2), and two equivalent Cl(3) atoms. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Nb(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Nb(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Nb(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_NbNCl6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.001
_cell_length_b   7.001
_cell_length_c   12.520
_cell_angle_alpha   79.054
_cell_angle_beta   79.054
_cell_angle_gamma   55.261
_symmetry_Int_Tables_number   1
_cell_volume   492.601
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Nb  Nb0  1  0.500  0.000  0.500  1.0
  Nb  Nb1  1  0.000  0.500  0.000  1.0
  N  N2  1  0.881  0.119  0.750  1.0
  N  N3  1  0.119  0.881  0.250  1.0
  Cl  Cl4  1  0.465  0.700  0.603  1.0
  Cl  Cl5  1  0.535  0.300  0.397  1.0
  Cl  Cl6  1  0.300  0.535  0.897  1.0
  Cl  Cl7  1  0.700  0.465  0.103  1.0
  Cl  Cl8  1  0.370  0.200  0.659  1.0
  Cl  Cl9  1  0.630  0.800  0.341  1.0
  Cl  Cl10  1  0.800  0.630  0.841  1.0
  Cl  Cl11  1  0.200  0.370  0.159  1.0
  Cl  Cl12  1  0.794  0.895  0.041  1.0
  Cl  Cl13  1  0.206  0.105  0.959  1.0
  Cl  Cl14  1  0.105  0.206  0.459  1.0
  Cl  Cl15  1  0.895  0.794  0.541  1.0
[/CIF]
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