The material described by Gd(V)2GdPr2Ti2O12 crystallizes in the orthorhombic Pnnn space group. The structure consists of two 7440-54-2 atoms and four 7440-62-2 atoms inside a GdPr2Ti2O12 framework. In the GdPr2Ti2O12 framework, Gd(1) is bonded in a square co-planar geometry to four equivalent O(2) atoms. There are two inequivalent Pr sites. In the first Pr site, Pr(1) is bonded in a square co-planar geometry to four equivalent O(3) atoms. In the second Pr site, Pr(2) is bonded in a square co-planar geometry to four equivalent O(1) atoms. Ti(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Pr(2) and one Ti(1) atom. In the second O site, O(2) is bonded in a water-like geometry to one Gd(1) and one Ti(1) atom. In the third O site, O(3) is bonded in a water-like geometry to one Pr(1) and one Ti(1) atom. is represented by the CIF card [CIF]
data_PrGdTiVO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.086
_cell_length_b   11.113
_cell_length_c   11.119
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1369.825
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pr  Pr0  1  0.500  0.000  0.500  1.0
  Pr  Pr1  1  0.500  0.500  0.000  1.0
  Pr  Pr2  1  0.000  0.500  0.000  1.0
  Pr  Pr3  1  0.000  0.000  0.500  1.0
  Gd  Gd4  1  0.000  0.500  0.500  1.0
  Gd  Gd5  1  0.500  0.000  0.000  1.0
  Gd  Gd6  1  0.000  0.000  0.000  1.0
  Gd  Gd7  1  0.500  0.500  0.500  1.0
  Ti  Ti8  1  0.750  0.750  0.750  1.0
  Ti  Ti9  1  0.250  0.250  0.750  1.0
  Ti  Ti10  1  0.250  0.750  0.250  1.0
  Ti  Ti11  1  0.750  0.250  0.250  1.0
  V  V12  1  0.250  0.250  0.250  1.0
  V  V13  1  0.750  0.750  0.250  1.0
  V  V14  1  0.750  0.250  0.750  1.0
  V  V15  1  0.250  0.750  0.750  1.0
  O  O16  1  0.984  0.196  0.287  1.0
  O  O17  1  0.016  0.804  0.287  1.0
  O  O18  1  0.016  0.196  0.713  1.0
  O  O19  1  0.984  0.804  0.713  1.0
  O  O20  1  0.295  0.983  0.194  1.0
  O  O21  1  0.295  0.017  0.806  1.0
  O  O22  1  0.705  0.017  0.194  1.0
  O  O23  1  0.705  0.983  0.806  1.0
  O  O24  1  0.199  0.291  0.984  1.0
  O  O25  1  0.801  0.291  0.016  1.0
  O  O26  1  0.199  0.709  0.016  1.0
  O  O27  1  0.801  0.709  0.984  1.0
  O  O28  1  0.516  0.304  0.213  1.0
  O  O29  1  0.484  0.696  0.213  1.0
  O  O30  1  0.484  0.304  0.787  1.0
  O  O31  1  0.516  0.696  0.787  1.0
  O  O32  1  0.205  0.517  0.306  1.0
  O  O33  1  0.205  0.483  0.694  1.0
  O  O34  1  0.795  0.483  0.306  1.0
  O  O35  1  0.795  0.517  0.694  1.0
  O  O36  1  0.301  0.209  0.516  1.0
  O  O37  1  0.699  0.209  0.484  1.0
  O  O38  1  0.301  0.791  0.484  1.0
  O  O39  1  0.699  0.791  0.516  1.0
[/CIF]
.
The material described by Gd(V)2GdPr2Ti2O12 crystallizes in the orthorhombic Pnnn space group. The structure consists of two 7440-54-2 atoms and four 7440-62-2 atoms inside a GdPr2Ti2O12 framework. In the GdPr2Ti2O12 framework, Gd(1) is bonded in a square co-planar geometry to four equivalent O(2) atoms. There are two inequivalent Pr sites. In the first Pr site, Pr(1) is bonded in a square co-planar geometry to four equivalent O(3) atoms. In the second Pr site, Pr(2) is bonded in a square co-planar geometry to four equivalent O(1) atoms. Ti(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Pr(2) and one Ti(1) atom. In the second O site, O(2) is bonded in a water-like geometry to one Gd(1) and one Ti(1) atom. In the third O site, O(3) is bonded in a water-like geometry to one Pr(1) and one Ti(1) atom. is represented by the CIF card [CIF]
data_PrGdTiVO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.086
_cell_length_b   11.113
_cell_length_c   11.119
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1369.825
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pr  Pr0  1  0.500  0.000  0.500  1.0
  Pr  Pr1  1  0.500  0.500  0.000  1.0
  Pr  Pr2  1  0.000  0.500  0.000  1.0
  Pr  Pr3  1  0.000  0.000  0.500  1.0
  Gd  Gd4  1  0.000  0.500  0.500  1.0
  Gd  Gd5  1  0.500  0.000  0.000  1.0
  Gd  Gd6  1  0.000  0.000  0.000  1.0
  Gd  Gd7  1  0.500  0.500  0.500  1.0
  Ti  Ti8  1  0.750  0.750  0.750  1.0
  Ti  Ti9  1  0.250  0.250  0.750  1.0
  Ti  Ti10  1  0.250  0.750  0.250  1.0
  Ti  Ti11  1  0.750  0.250  0.250  1.0
  V  V12  1  0.250  0.250  0.250  1.0
  V  V13  1  0.750  0.750  0.250  1.0
  V  V14  1  0.750  0.250  0.750  1.0
  V  V15  1  0.250  0.750  0.750  1.0
  O  O16  1  0.984  0.196  0.287  1.0
  O  O17  1  0.016  0.804  0.287  1.0
  O  O18  1  0.016  0.196  0.713  1.0
  O  O19  1  0.984  0.804  0.713  1.0
  O  O20  1  0.295  0.983  0.194  1.0
  O  O21  1  0.295  0.017  0.806  1.0
  O  O22  1  0.705  0.017  0.194  1.0
  O  O23  1  0.705  0.983  0.806  1.0
  O  O24  1  0.199  0.291  0.984  1.0
  O  O25  1  0.801  0.291  0.016  1.0
  O  O26  1  0.199  0.709  0.016  1.0
  O  O27  1  0.801  0.709  0.984  1.0
  O  O28  1  0.516  0.304  0.213  1.0
  O  O29  1  0.484  0.696  0.213  1.0
  O  O30  1  0.484  0.304  0.787  1.0
  O  O31  1  0.516  0.696  0.787  1.0
  O  O32  1  0.205  0.517  0.306  1.0
  O  O33  1  0.205  0.483  0.694  1.0
  O  O34  1  0.795  0.483  0.306  1.0
  O  O35  1  0.795  0.517  0.694  1.0
  O  O36  1  0.301  0.209  0.516  1.0
  O  O37  1  0.699  0.209  0.484  1.0
  O  O38  1  0.301  0.791  0.484  1.0
  O  O39  1  0.699  0.791  0.516  1.0
[/CIF]
.