The material described by YbO13Cl3 crystallizes in the triclinic P-1 space group. Yb(1) is bonded in a 8-coordinate geometry to one O(11), one O(12), one O(13), one O(2), one O(3), one O(6), one O(7), and one O(8) atom. There are thirteen inequivalent O sites. In the first O site, O(13) is bonded in a single-bond geometry to one Yb(1) atom. In the second O site, O(1) is bonded in a single-bond geometry to one Cl(1) atom. In the third O site, O(2) is bonded in a linear geometry to one Yb(1) and one Cl(1) atom. In the fourth O site, O(3) is bonded in a bent 150 degrees geometry to one Yb(1) and one Cl(1) atom. In the fifth O site, O(4) is bonded in a single-bond geometry to one Cl(1) atom. In the sixth O site, O(5) is bonded in a single-bond geometry to one Cl(2) atom. In the seventh O site, O(6) is bonded in a bent 150 degrees geometry to one Yb(1) and one Cl(2) atom. In the eighth O site, O(7) is bonded in a bent 150 degrees geometry to one Yb(1) and one Cl(2) atom. In the ninth O site, O(8) is bonded in a bent 150 degrees geometry to one Yb(1) and one Cl(2) atom. In the tenth O site, O(9) is bonded in a single-bond geometry to one Cl(3) atom. In the eleventh O site, O(10) is bonded in a single-bond geometry to one Cl(3) atom. In the twelfth O site, O(11) is bonded in a bent 150 degrees geometry to one Yb(1) and one Cl(3) atom. In the thirteenth O site, O(12) is bonded in a bent 150 degrees geometry to one Yb(1) and one Cl(3) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. In the second Cl site, Cl(2) is bonded in a tetrahedral geometry to one O(5), one O(6), one O(7), and one O(8) atom. In the third Cl site, Cl(3) is bonded in a tetrahedral geometry to one O(10), one O(11), one O(12), and one O(9) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_YbCl3O13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.874
_cell_length_b   8.214
_cell_length_c   10.000
_cell_angle_alpha   75.920
_cell_angle_beta   74.935
_cell_angle_gamma   76.749
_symmetry_Int_Tables_number   1
_cell_volume   520.454
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Yb  Yb0  1  0.360  0.336  0.321  1.0
  Yb  Yb1  1  0.640  0.664  0.679  1.0
  Cl  Cl2  1  0.709  0.901  0.305  1.0
  Cl  Cl3  1  0.291  0.099  0.695  1.0
  Cl  Cl4  1  0.200  0.683  0.522  1.0
  Cl  Cl5  1  0.800  0.317  0.478  1.0
  Cl  Cl6  1  0.767  0.334  0.992  1.0
  Cl  Cl7  1  0.233  0.666  0.008  1.0
  O  O8  1  0.624  0.816  0.231  1.0
  O  O9  1  0.376  0.184  0.769  1.0
  O  O10  1  0.566  0.060  0.332  1.0
  O  O11  1  0.434  0.940  0.668  1.0
  O  O12  1  0.732  0.793  0.443  1.0
  O  O13  1  0.268  0.207  0.557  1.0
  O  O14  1  0.906  0.941  0.228  1.0
  O  O15  1  0.094  0.059  0.772  1.0
  O  O16  1  0.185  0.862  0.465  1.0
  O  O17  1  0.815  0.138  0.535  1.0
  O  O18  1  0.228  0.590  0.409  1.0
  O  O19  1  0.772  0.410  0.591  1.0
  O  O20  1  0.012  0.647  0.627  1.0
  O  O21  1  0.988  0.353  0.373  1.0
  O  O22  1  0.370  0.617  0.593  1.0
  O  O23  1  0.630  0.383  0.407  1.0
  O  O24  1  0.973  0.283  0.015  1.0
  O  O25  1  0.027  0.717  0.985  1.0
  O  O26  1  0.692  0.203  0.959  1.0
  O  O27  1  0.308  0.797  0.041  1.0
  O  O28  1  0.766  0.486  0.877  1.0
  O  O29  1  0.234  0.514  0.123  1.0
  O  O30  1  0.633  0.391  0.120  1.0
  O  O31  1  0.367  0.609  0.880  1.0
  O  O32  1  0.730  0.856  0.807  1.0
  O  O33  1  0.270  0.144  0.193  1.0
[/CIF]
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The material described by YbO13Cl3 crystallizes in the triclinic P-1 space group. Yb(1) is bonded in a 8-coordinate geometry to one O(11), one O(12), one O(13), one O(2), one O(3), one O(6), one O(7), and one O(8) atom. There are thirteen inequivalent O sites. In the first O site, O(13) is bonded in a single-bond geometry to one Yb(1) atom. In the second O site, O(1) is bonded in a single-bond geometry to one Cl(1) atom. In the third O site, O(2) is bonded in a linear geometry to one Yb(1) and one Cl(1) atom. In the fourth O site, O(3) is bonded in a bent 150 degrees geometry to one Yb(1) and one Cl(1) atom. In the fifth O site, O(4) is bonded in a single-bond geometry to one Cl(1) atom. In the sixth O site, O(5) is bonded in a single-bond geometry to one Cl(2) atom. In the seventh O site, O(6) is bonded in a bent 150 degrees geometry to one Yb(1) and one Cl(2) atom. In the eighth O site, O(7) is bonded in a bent 150 degrees geometry to one Yb(1) and one Cl(2) atom. In the ninth O site, O(8) is bonded in a bent 150 degrees geometry to one Yb(1) and one Cl(2) atom. In the tenth O site, O(9) is bonded in a single-bond geometry to one Cl(3) atom. In the eleventh O site, O(10) is bonded in a single-bond geometry to one Cl(3) atom. In the twelfth O site, O(11) is bonded in a bent 150 degrees geometry to one Yb(1) and one Cl(3) atom. In the thirteenth O site, O(12) is bonded in a bent 150 degrees geometry to one Yb(1) and one Cl(3) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. In the second Cl site, Cl(2) is bonded in a tetrahedral geometry to one O(5), one O(6), one O(7), and one O(8) atom. In the third Cl site, Cl(3) is bonded in a tetrahedral geometry to one O(10), one O(11), one O(12), and one O(9) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_YbCl3O13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.874
_cell_length_b   8.214
_cell_length_c   10.000
_cell_angle_alpha   75.920
_cell_angle_beta   74.935
_cell_angle_gamma   76.749
_symmetry_Int_Tables_number   1
_cell_volume   520.454
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Yb  Yb0  1  0.360  0.336  0.321  1.0
  Yb  Yb1  1  0.640  0.664  0.679  1.0
  Cl  Cl2  1  0.709  0.901  0.305  1.0
  Cl  Cl3  1  0.291  0.099  0.695  1.0
  Cl  Cl4  1  0.200  0.683  0.522  1.0
  Cl  Cl5  1  0.800  0.317  0.478  1.0
  Cl  Cl6  1  0.767  0.334  0.992  1.0
  Cl  Cl7  1  0.233  0.666  0.008  1.0
  O  O8  1  0.624  0.816  0.231  1.0
  O  O9  1  0.376  0.184  0.769  1.0
  O  O10  1  0.566  0.060  0.332  1.0
  O  O11  1  0.434  0.940  0.668  1.0
  O  O12  1  0.732  0.793  0.443  1.0
  O  O13  1  0.268  0.207  0.557  1.0
  O  O14  1  0.906  0.941  0.228  1.0
  O  O15  1  0.094  0.059  0.772  1.0
  O  O16  1  0.185  0.862  0.465  1.0
  O  O17  1  0.815  0.138  0.535  1.0
  O  O18  1  0.228  0.590  0.409  1.0
  O  O19  1  0.772  0.410  0.591  1.0
  O  O20  1  0.012  0.647  0.627  1.0
  O  O21  1  0.988  0.353  0.373  1.0
  O  O22  1  0.370  0.617  0.593  1.0
  O  O23  1  0.630  0.383  0.407  1.0
  O  O24  1  0.973  0.283  0.015  1.0
  O  O25  1  0.027  0.717  0.985  1.0
  O  O26  1  0.692  0.203  0.959  1.0
  O  O27  1  0.308  0.797  0.041  1.0
  O  O28  1  0.766  0.486  0.877  1.0
  O  O29  1  0.234  0.514  0.123  1.0
  O  O30  1  0.633  0.391  0.120  1.0
  O  O31  1  0.367  0.609  0.880  1.0
  O  O32  1  0.730  0.856  0.807  1.0
  O  O33  1  0.270  0.144  0.193  1.0
[/CIF]
.