The compound described by La6Pd13Zn4 crystallizes in the cubic Im-3m space group. La(1) is bonded in a 9-coordinate geometry to one Pd(2) and eight equivalent Pd(1) atoms. There are two inequivalent Pd sites. In the first Pd site, Pd(2) is bonded in an octahedral geometry to six equivalent La(1) atoms. In the second Pd site, Pd(1) is bonded in a 10-coordinate geometry to four equivalent La(1), four equivalent Pd(1), and two equivalent Zn(1) atoms. Zn(1) is bonded in a distorted hexagonal planar geometry to six equivalent Pd(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_La6Zn4Pd13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.475
_cell_length_b   8.475
_cell_length_c   8.475
_cell_angle_alpha   109.471
_cell_angle_beta   109.471
_cell_angle_gamma   109.471
_symmetry_Int_Tables_number   1
_cell_volume   468.513
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.696  0.696  0.000  1.0
  La  La1  1  0.304  0.000  0.304  1.0
  La  La2  1  0.000  0.304  0.304  1.0
  La  La3  1  0.304  0.304  0.000  1.0
  La  La4  1  0.696  0.000  0.696  1.0
  La  La5  1  0.000  0.696  0.696  1.0
  Zn  Zn6  1  0.000  0.000  0.500  1.0
  Zn  Zn7  1  0.000  0.500  0.000  1.0
  Zn  Zn8  1  0.500  0.000  0.000  1.0
  Zn  Zn9  1  0.500  0.500  0.500  1.0
  Pd  Pd10  1  0.330  0.330  0.660  1.0
  Pd  Pd11  1  0.670  0.000  0.330  1.0
  Pd  Pd12  1  0.000  0.670  0.330  1.0
  Pd  Pd13  1  0.670  0.330  0.000  1.0
  Pd  Pd14  1  0.330  0.660  0.330  1.0
  Pd  Pd15  1  0.000  0.330  0.670  1.0
  Pd  Pd16  1  0.330  0.670  0.000  1.0
  Pd  Pd17  1  0.330  0.000  0.670  1.0
  Pd  Pd18  1  0.660  0.330  0.330  1.0
  Pd  Pd19  1  0.670  0.670  0.340  1.0
  Pd  Pd20  1  0.670  0.340  0.670  1.0
  Pd  Pd21  1  0.340  0.670  0.670  1.0
  Pd  Pd22  1  0.000  0.000  0.000  1.0
[/CIF]
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The compound described by La6Pd13Zn4 crystallizes in the cubic Im-3m space group. La(1) is bonded in a 9-coordinate geometry to one Pd(2) and eight equivalent Pd(1) atoms. There are two inequivalent Pd sites. In the first Pd site, Pd(2) is bonded in an octahedral geometry to six equivalent La(1) atoms. In the second Pd site, Pd(1) is bonded in a 10-coordinate geometry to four equivalent La(1), four equivalent Pd(1), and two equivalent Zn(1) atoms. Zn(1) is bonded in a distorted hexagonal planar geometry to six equivalent Pd(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_La6Zn4Pd13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.475
_cell_length_b   8.475
_cell_length_c   8.475
_cell_angle_alpha   109.471
_cell_angle_beta   109.471
_cell_angle_gamma   109.471
_symmetry_Int_Tables_number   1
_cell_volume   468.513
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.696  0.696  0.000  1.0
  La  La1  1  0.304  0.000  0.304  1.0
  La  La2  1  0.000  0.304  0.304  1.0
  La  La3  1  0.304  0.304  0.000  1.0
  La  La4  1  0.696  0.000  0.696  1.0
  La  La5  1  0.000  0.696  0.696  1.0
  Zn  Zn6  1  0.000  0.000  0.500  1.0
  Zn  Zn7  1  0.000  0.500  0.000  1.0
  Zn  Zn8  1  0.500  0.000  0.000  1.0
  Zn  Zn9  1  0.500  0.500  0.500  1.0
  Pd  Pd10  1  0.330  0.330  0.660  1.0
  Pd  Pd11  1  0.670  0.000  0.330  1.0
  Pd  Pd12  1  0.000  0.670  0.330  1.0
  Pd  Pd13  1  0.670  0.330  0.000  1.0
  Pd  Pd14  1  0.330  0.660  0.330  1.0
  Pd  Pd15  1  0.000  0.330  0.670  1.0
  Pd  Pd16  1  0.330  0.670  0.000  1.0
  Pd  Pd17  1  0.330  0.000  0.670  1.0
  Pd  Pd18  1  0.660  0.330  0.330  1.0
  Pd  Pd19  1  0.670  0.670  0.340  1.0
  Pd  Pd20  1  0.670  0.340  0.670  1.0
  Pd  Pd21  1  0.340  0.670  0.670  1.0
  Pd  Pd22  1  0.000  0.000  0.000  1.0
[/CIF]
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