The structure described by Ho3SOF5 crystallizes in the monoclinic Pm space group. There are six inequivalent Ho sites. In the first Ho site, Ho(1) is bonded in a 9-coordinate geometry to two equivalent S(2), one O(1), one O(2), one F(1), two equivalent F(6), and two equivalent F(9) atoms. In the second Ho site, Ho(2) is bonded in a 9-coordinate geometry to two equivalent S(2), one O(2), one F(2), one F(7), two equivalent F(10), and two equivalent F(4) atoms. In the third Ho site, Ho(3) is bonded in a 9-coordinate geometry to two equivalent S(2), one O(1), one F(3), one F(7), two equivalent F(5), and two equivalent F(8) atoms. In the fourth Ho site, Ho(4) is bonded in a 7-coordinate geometry to two equivalent S(1), two equivalent O(2), one F(4), one F(8), one F(9), and two equivalent F(3) atoms. In the fifth Ho site, Ho(5) is bonded in a 7-coordinate geometry to two equivalent S(1), one F(10), one F(5), one F(9), two equivalent F(1), and two equivalent F(7) atoms. In the sixth Ho site, Ho(6) is bonded in a 7-coordinate geometry to two equivalent S(1), two equivalent O(1), one F(10), one F(6), one F(8), and two equivalent F(2) atoms. There are two inequivalent S sites. In the first S site, S(1) is bonded to two equivalent Ho(4), two equivalent Ho(5), and two equivalent Ho(6) atoms to form distorted SHo6 pentagonal pyramids that share corners with two equivalent O(1)Ho4 tetrahedra, corners with two equivalent O(2)Ho4 tetrahedra, corners with two equivalent F(7)Ho4 tetrahedra,  an edgeedge with one O(1)Ho4 tetrahedra,  an edgeedge with one O(2)Ho4 tetrahedra,  an edgeedge with one F(7)Ho4 tetrahedra, edges with two equivalent F(10)Ho4 tetrahedra, edges with two equivalent F(8)Ho4 tetrahedra, edges with two equivalent F(9)Ho4 tetrahedra, and faces with two equivalent S(1)Ho6 pentagonal pyramids. In the second S site, S(2) is bonded to two equivalent Ho(1), two equivalent Ho(2), and two equivalent Ho(3) atoms to form distorted SHo6 pentagonal pyramids that share corners with two equivalent F(10)Ho4 tetrahedra, corners with two equivalent F(8)Ho4 tetrahedra, corners with two equivalent F(9)Ho4 tetrahedra,  an edgeedge with one F(10)Ho4 tetrahedra,  an edgeedge with one F(8)Ho4 tetrahedra,  an edgeedge with one F(9)Ho4 tetrahedra, edges with two equivalent O(1)Ho4 tetrahedra, edges with two equivalent O(2)Ho4 tetrahedra, edges with two equivalent F(7)Ho4 tetrahedra, and faces with two equivalent S(2)Ho6 pentagonal pyramids. There are two inequivalent O sites. In the first O site, O(1) is bonded to one Ho(1), one Ho(3), and two equivalent Ho(6) atoms to form OHo4 tetrahedra that share corners with two equivalent S(1)Ho6 pentagonal pyramids,  a cornercorner with one O(2)Ho4 tetrahedra,  a cornercorner with one F(7)Ho4 tetrahedra, corners with two equivalent O(1)Ho4 tetrahedra, corners with two equivalent F(10)Ho4 tetrahedra, corners with two equivalent F(9)Ho4 tetrahedra,  an edgeedge with one S(1)Ho6 pentagonal pyramid, edges with two equivalent S(2)Ho6 pentagonal pyramids, and edges with two equivalent F(8)Ho4 tetrahedra. In the second O site, O(2) is bonded to one Ho(1), one Ho(2), and two equivalent Ho(4) atoms to form OHo4 tetrahedra that share corners with two equivalent S(1)Ho6 pentagonal pyramids,  a cornercorner with one O(1)Ho4 tetrahedra,  a cornercorner with one F(7)Ho4 tetrahedra, corners with two equivalent O(2)Ho4 tetrahedra, corners with two equivalent F(10)Ho4 tetrahedra, corners with two equivalent F(8)Ho4 tetrahedra,  an edgeedge with one S(1)Ho6 pentagonal pyramid, edges with two equivalent S(2)Ho6 pentagonal pyramids, and edges with two equivalent F(9)Ho4 tetrahedra. There are ten inequivalent F sites. In the first F site, F(1) is bonded in a trigonal non-coplanar geometry to one Ho(1) and two equivalent Ho(5) atoms. In the second F site, F(2) is bonded in a trigonal non-coplanar geometry to one Ho(2) and two equivalent Ho(6) atoms. In the third F site, F(3) is bonded in a trigonal non-coplanar geometry to one Ho(3) and two equivalent Ho(4) atoms. In the fourth F site, F(4) is bonded in a trigonal non-coplanar geometry to one Ho(4) and two equivalent Ho(2) atoms. In the fifth F site, F(5) is bonded in a trigonal non-coplanar geometry to one Ho(5) and two equivalent Ho(3) atoms. In the sixth F site, F(6) is bonded in a trigonal non-coplanar geometry to one Ho(6) and two equivalent Ho(1) atoms. In the seventh F site, F(7) is bonded to one Ho(2), one Ho(3), and two equivalent Ho(5) atoms to form FHo4 tetrahedra that share corners with two equivalent S(1)Ho6 pentagonal pyramids,  a cornercorner with one O(1)Ho4 tetrahedra,  a cornercorner with one O(2)Ho4 tetrahedra, corners with two equivalent F(7)Ho4 tetrahedra, corners with two equivalent F(8)Ho4 tetrahedra, corners with two equivalent F(9)Ho4 tetrahedra,  an edgeedge with one S(1)Ho6 pentagonal pyramid, edges with two equivalent S(2)Ho6 pentagonal pyramids, and edges with two equivalent F(10)Ho4 tetrahedra. In the eighth F site, F(8) is bonded to one Ho(4), one Ho(6), and two equivalent Ho(3) atoms to form FHo4 tetrahedra that share corners with two equivalent S(2)Ho6 pentagonal pyramids,  a cornercorner with one F(10)Ho4 tetrahedra,  a cornercorner with one F(9)Ho4 tetrahedra, corners with two equivalent O(2)Ho4 tetrahedra, corners with two equivalent F(7)Ho4 tetrahedra, corners with two equivalent F(8)Ho4 tetrahedra,  an edgeedge with one S(2)Ho6 pentagonal pyramid, edges with two equivalent S(1)Ho6 pentagonal pyramids, and edges with two equivalent O(1)Ho4 tetrahedra. In the ninth F site, F(9) is bonded to one Ho(4), one Ho(5), and two equivalent Ho(1) atoms to form FHo4 tetrahedra that share corners with two equivalent S(2)Ho6 pentagonal pyramids,  a cornercorner with one F(10)Ho4 tetrahedra,  a cornercorner with one F(8)Ho4 tetrahedra, corners with two equivalent O(1)Ho4 tetrahedra, corners with two equivalent F(7)Ho4 tetrahedra, corners with two equivalent F(9)Ho4 tetrahedra,  an edgeedge with one S(2)Ho6 pentagonal pyramid, edges with two equivalent S(1)Ho6 pentagonal pyramids, and edges with two equivalent O(2)Ho4 tetrahedra. In the tenth F site, F(10) is bonded to one Ho(5), one Ho(6), and two equivalent Ho(2) atoms to form FHo4 tetrahedra that share corners with two equivalent S(2)Ho6 pentagonal pyramids,  a cornercorner with one F(8)Ho4 tetrahedra,  a cornercorner with one F(9)Ho4 tetrahedra, corners with two equivalent O(1)Ho4 tetrahedra, corners with two equivalent O(2)Ho4 tetrahedra, corners with two equivalent F(10)Ho4 tetrahedra,  an edgeedge with one S(2)Ho6 pentagonal pyramid, edges with two equivalent S(1)Ho6 pentagonal pyramids, and edges with two equivalent F(7)Ho4 tetrahedra. is represented by the CIF card [CIF]
data_Ho3SOF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.674
_cell_length_b   9.372
_cell_length_c   9.424
_cell_angle_alpha   60.438
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   282.290
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ho  Ho0  1  0.000  0.416  0.867  1.0
  Ho  Ho1  1  0.000  0.867  0.730  1.0
  Ho  Ho2  1  0.000  0.702  0.414  1.0
  Ho  Ho3  1  0.500  0.596  0.104  1.0
  Ho  Ho4  1  0.500  0.122  0.284  1.0
  Ho  Ho5  1  0.500  0.296  0.599  1.0
  S  S6  1  0.000  0.329  0.333  1.0
  S  S7  1  0.500  0.673  0.661  1.0
  O  O8  1  0.000  0.436  0.614  1.0
  O  O9  1  0.000  0.616  0.949  1.0
  F  F10  1  0.000  0.157  0.118  1.0
  F  F11  1  0.000  0.110  0.729  1.0
  F  F12  1  0.000  0.728  0.161  1.0
  F  F13  1  0.500  0.854  0.882  1.0
  F  F14  1  0.500  0.882  0.279  1.0
  F  F15  1  0.500  0.270  0.852  1.0
  F  F16  1  0.000  0.953  0.432  1.0
  F  F17  1  0.500  0.571  0.375  1.0
  F  F18  1  0.500  0.377  0.049  1.0
  F  F19  1  0.500  0.045  0.567  1.0
[/CIF]
.
The structure described by Ho3SOF5 crystallizes in the monoclinic Pm space group. There are six inequivalent Ho sites. In the first Ho site, Ho(1) is bonded in a 9-coordinate geometry to two equivalent S(2), one O(1), one O(2), one F(1), two equivalent F(6), and two equivalent F(9) atoms. In the second Ho site, Ho(2) is bonded in a 9-coordinate geometry to two equivalent S(2), one O(2), one F(2), one F(7), two equivalent F(10), and two equivalent F(4) atoms. In the third Ho site, Ho(3) is bonded in a 9-coordinate geometry to two equivalent S(2), one O(1), one F(3), one F(7), two equivalent F(5), and two equivalent F(8) atoms. In the fourth Ho site, Ho(4) is bonded in a 7-coordinate geometry to two equivalent S(1), two equivalent O(2), one F(4), one F(8), one F(9), and two equivalent F(3) atoms. In the fifth Ho site, Ho(5) is bonded in a 7-coordinate geometry to two equivalent S(1), one F(10), one F(5), one F(9), two equivalent F(1), and two equivalent F(7) atoms. In the sixth Ho site, Ho(6) is bonded in a 7-coordinate geometry to two equivalent S(1), two equivalent O(1), one F(10), one F(6), one F(8), and two equivalent F(2) atoms. There are two inequivalent S sites. In the first S site, S(1) is bonded to two equivalent Ho(4), two equivalent Ho(5), and two equivalent Ho(6) atoms to form distorted SHo6 pentagonal pyramids that share corners with two equivalent O(1)Ho4 tetrahedra, corners with two equivalent O(2)Ho4 tetrahedra, corners with two equivalent F(7)Ho4 tetrahedra,  an edgeedge with one O(1)Ho4 tetrahedra,  an edgeedge with one O(2)Ho4 tetrahedra,  an edgeedge with one F(7)Ho4 tetrahedra, edges with two equivalent F(10)Ho4 tetrahedra, edges with two equivalent F(8)Ho4 tetrahedra, edges with two equivalent F(9)Ho4 tetrahedra, and faces with two equivalent S(1)Ho6 pentagonal pyramids. In the second S site, S(2) is bonded to two equivalent Ho(1), two equivalent Ho(2), and two equivalent Ho(3) atoms to form distorted SHo6 pentagonal pyramids that share corners with two equivalent F(10)Ho4 tetrahedra, corners with two equivalent F(8)Ho4 tetrahedra, corners with two equivalent F(9)Ho4 tetrahedra,  an edgeedge with one F(10)Ho4 tetrahedra,  an edgeedge with one F(8)Ho4 tetrahedra,  an edgeedge with one F(9)Ho4 tetrahedra, edges with two equivalent O(1)Ho4 tetrahedra, edges with two equivalent O(2)Ho4 tetrahedra, edges with two equivalent F(7)Ho4 tetrahedra, and faces with two equivalent S(2)Ho6 pentagonal pyramids. There are two inequivalent O sites. In the first O site, O(1) is bonded to one Ho(1), one Ho(3), and two equivalent Ho(6) atoms to form OHo4 tetrahedra that share corners with two equivalent S(1)Ho6 pentagonal pyramids,  a cornercorner with one O(2)Ho4 tetrahedra,  a cornercorner with one F(7)Ho4 tetrahedra, corners with two equivalent O(1)Ho4 tetrahedra, corners with two equivalent F(10)Ho4 tetrahedra, corners with two equivalent F(9)Ho4 tetrahedra,  an edgeedge with one S(1)Ho6 pentagonal pyramid, edges with two equivalent S(2)Ho6 pentagonal pyramids, and edges with two equivalent F(8)Ho4 tetrahedra. In the second O site, O(2) is bonded to one Ho(1), one Ho(2), and two equivalent Ho(4) atoms to form OHo4 tetrahedra that share corners with two equivalent S(1)Ho6 pentagonal pyramids,  a cornercorner with one O(1)Ho4 tetrahedra,  a cornercorner with one F(7)Ho4 tetrahedra, corners with two equivalent O(2)Ho4 tetrahedra, corners with two equivalent F(10)Ho4 tetrahedra, corners with two equivalent F(8)Ho4 tetrahedra,  an edgeedge with one S(1)Ho6 pentagonal pyramid, edges with two equivalent S(2)Ho6 pentagonal pyramids, and edges with two equivalent F(9)Ho4 tetrahedra. There are ten inequivalent F sites. In the first F site, F(1) is bonded in a trigonal non-coplanar geometry to one Ho(1) and two equivalent Ho(5) atoms. In the second F site, F(2) is bonded in a trigonal non-coplanar geometry to one Ho(2) and two equivalent Ho(6) atoms. In the third F site, F(3) is bonded in a trigonal non-coplanar geometry to one Ho(3) and two equivalent Ho(4) atoms. In the fourth F site, F(4) is bonded in a trigonal non-coplanar geometry to one Ho(4) and two equivalent Ho(2) atoms. In the fifth F site, F(5) is bonded in a trigonal non-coplanar geometry to one Ho(5) and two equivalent Ho(3) atoms. In the sixth F site, F(6) is bonded in a trigonal non-coplanar geometry to one Ho(6) and two equivalent Ho(1) atoms. In the seventh F site, F(7) is bonded to one Ho(2), one Ho(3), and two equivalent Ho(5) atoms to form FHo4 tetrahedra that share corners with two equivalent S(1)Ho6 pentagonal pyramids,  a cornercorner with one O(1)Ho4 tetrahedra,  a cornercorner with one O(2)Ho4 tetrahedra, corners with two equivalent F(7)Ho4 tetrahedra, corners with two equivalent F(8)Ho4 tetrahedra, corners with two equivalent F(9)Ho4 tetrahedra,  an edgeedge with one S(1)Ho6 pentagonal pyramid, edges with two equivalent S(2)Ho6 pentagonal pyramids, and edges with two equivalent F(10)Ho4 tetrahedra. In the eighth F site, F(8) is bonded to one Ho(4), one Ho(6), and two equivalent Ho(3) atoms to form FHo4 tetrahedra that share corners with two equivalent S(2)Ho6 pentagonal pyramids,  a cornercorner with one F(10)Ho4 tetrahedra,  a cornercorner with one F(9)Ho4 tetrahedra, corners with two equivalent O(2)Ho4 tetrahedra, corners with two equivalent F(7)Ho4 tetrahedra, corners with two equivalent F(8)Ho4 tetrahedra,  an edgeedge with one S(2)Ho6 pentagonal pyramid, edges with two equivalent S(1)Ho6 pentagonal pyramids, and edges with two equivalent O(1)Ho4 tetrahedra. In the ninth F site, F(9) is bonded to one Ho(4), one Ho(5), and two equivalent Ho(1) atoms to form FHo4 tetrahedra that share corners with two equivalent S(2)Ho6 pentagonal pyramids,  a cornercorner with one F(10)Ho4 tetrahedra,  a cornercorner with one F(8)Ho4 tetrahedra, corners with two equivalent O(1)Ho4 tetrahedra, corners with two equivalent F(7)Ho4 tetrahedra, corners with two equivalent F(9)Ho4 tetrahedra,  an edgeedge with one S(2)Ho6 pentagonal pyramid, edges with two equivalent S(1)Ho6 pentagonal pyramids, and edges with two equivalent O(2)Ho4 tetrahedra. In the tenth F site, F(10) is bonded to one Ho(5), one Ho(6), and two equivalent Ho(2) atoms to form FHo4 tetrahedra that share corners with two equivalent S(2)Ho6 pentagonal pyramids,  a cornercorner with one F(8)Ho4 tetrahedra,  a cornercorner with one F(9)Ho4 tetrahedra, corners with two equivalent O(1)Ho4 tetrahedra, corners with two equivalent O(2)Ho4 tetrahedra, corners with two equivalent F(10)Ho4 tetrahedra,  an edgeedge with one S(2)Ho6 pentagonal pyramid, edges with two equivalent S(1)Ho6 pentagonal pyramids, and edges with two equivalent F(7)Ho4 tetrahedra. is represented by the CIF card [CIF]
data_Ho3SOF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.674
_cell_length_b   9.372
_cell_length_c   9.424
_cell_angle_alpha   60.438
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   282.290
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ho  Ho0  1  0.000  0.416  0.867  1.0
  Ho  Ho1  1  0.000  0.867  0.730  1.0
  Ho  Ho2  1  0.000  0.702  0.414  1.0
  Ho  Ho3  1  0.500  0.596  0.104  1.0
  Ho  Ho4  1  0.500  0.122  0.284  1.0
  Ho  Ho5  1  0.500  0.296  0.599  1.0
  S  S6  1  0.000  0.329  0.333  1.0
  S  S7  1  0.500  0.673  0.661  1.0
  O  O8  1  0.000  0.436  0.614  1.0
  O  O9  1  0.000  0.616  0.949  1.0
  F  F10  1  0.000  0.157  0.118  1.0
  F  F11  1  0.000  0.110  0.729  1.0
  F  F12  1  0.000  0.728  0.161  1.0
  F  F13  1  0.500  0.854  0.882  1.0
  F  F14  1  0.500  0.882  0.279  1.0
  F  F15  1  0.500  0.270  0.852  1.0
  F  F16  1  0.000  0.953  0.432  1.0
  F  F17  1  0.500  0.571  0.375  1.0
  F  F18  1  0.500  0.377  0.049  1.0
  F  F19  1  0.500  0.045  0.567  1.0
[/CIF]
.