The material structure described by Ag4C(NO3)3 crystallizes in the triclinic P-1 space group. There are four inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to one C(1), one O(7), one O(8), and one O(9) atom. In the second Ag site, Ag(2) is bonded in a 3-coordinate geometry to one C(1), one O(1), and one O(4) atom. In the third Ag site, Ag(3) is bonded in a 3-coordinate geometry to one C(1), one O(2), and one O(5) atom. In the fourth Ag site, Ag(4) is bonded in a 3-coordinate geometry to one C(1), one O(3), and one O(6) atom. C(1) is bonded in a 5-coordinate geometry to one Ag(1), one Ag(2), one Ag(3), one Ag(4), and one C(1) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(3), one O(4), and one O(7) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(1), one O(5), and one O(8) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one O(2), one O(6), and one O(9) atom. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Ag(2) and one N(2) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Ag(3) and one N(3) atom. In the third O site, O(3) is bonded in a 1-coordinate geometry to one Ag(4) and one N(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Ag(2) and one N(1) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Ag(3) and one N(2) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Ag(4) and one N(3) atom. In the seventh O site, O(7) is bonded in a distorted water-like geometry to one Ag(1) and one N(1) atom. In the eighth O site, O(8) is bonded in a distorted water-like geometry to one Ag(1) and one N(2) atom. In the ninth O site, O(9) is bonded in a distorted water-like geometry to one Ag(1) and one N(3) atom. is represented by the CIF card [CIF]
data_Ag4C(NO3)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.999
_cell_length_b   8.078
_cell_length_c   8.125
_cell_angle_alpha   106.855
_cell_angle_beta   104.959
_cell_angle_gamma   104.954
_symmetry_Int_Tables_number   1
_cell_volume   452.895
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.742  0.748  0.743  1.0
  Ag  Ag1  1  0.258  0.252  0.257  1.0
  Ag  Ag2  1  0.244  0.861  0.141  1.0
  Ag  Ag3  1  0.131  0.243  0.859  1.0
  Ag  Ag4  1  0.859  0.133  0.235  1.0
  Ag  Ag5  1  0.756  0.139  0.859  1.0
  Ag  Ag6  1  0.869  0.757  0.141  1.0
  Ag  Ag7  1  0.141  0.867  0.765  1.0
  C  C8  1  0.022  0.967  0.064  1.0
  C  C9  1  0.978  0.033  0.936  1.0
  N  N10  1  0.159  0.606  0.369  1.0
  N  N11  1  0.370  0.160  0.612  1.0
  N  N12  1  0.610  0.369  0.158  1.0
  N  N13  1  0.841  0.394  0.631  1.0
  N  N14  1  0.630  0.840  0.388  1.0
  N  N15  1  0.390  0.631  0.842  1.0
  O  O16  1  0.553  0.871  0.248  1.0
  O  O17  1  0.248  0.554  0.873  1.0
  O  O18  1  0.872  0.250  0.554  1.0
  O  O19  1  0.447  0.129  0.752  1.0
  O  O20  1  0.752  0.446  0.127  1.0
  O  O21  1  0.128  0.750  0.446  1.0
  O  O22  1  0.168  0.574  0.210  1.0
  O  O23  1  0.210  0.167  0.583  1.0
  O  O24  1  0.583  0.209  0.165  1.0
  O  O25  1  0.832  0.426  0.790  1.0
  O  O26  1  0.790  0.833  0.417  1.0
  O  O27  1  0.417  0.791  0.835  1.0
  O  O28  1  0.179  0.495  0.448  1.0
  O  O29  1  0.451  0.180  0.500  1.0
  O  O30  1  0.496  0.448  0.181  1.0
  O  O31  1  0.821  0.505  0.552  1.0
  O  O32  1  0.549  0.820  0.500  1.0
  O  O33  1  0.504  0.552  0.819  1.0
[/CIF]
.
The material structure described by Ag4C(NO3)3 crystallizes in the triclinic P-1 space group. There are four inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to one C(1), one O(7), one O(8), and one O(9) atom. In the second Ag site, Ag(2) is bonded in a 3-coordinate geometry to one C(1), one O(1), and one O(4) atom. In the third Ag site, Ag(3) is bonded in a 3-coordinate geometry to one C(1), one O(2), and one O(5) atom. In the fourth Ag site, Ag(4) is bonded in a 3-coordinate geometry to one C(1), one O(3), and one O(6) atom. C(1) is bonded in a 5-coordinate geometry to one Ag(1), one Ag(2), one Ag(3), one Ag(4), and one C(1) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(3), one O(4), and one O(7) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(1), one O(5), and one O(8) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one O(2), one O(6), and one O(9) atom. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Ag(2) and one N(2) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Ag(3) and one N(3) atom. In the third O site, O(3) is bonded in a 1-coordinate geometry to one Ag(4) and one N(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Ag(2) and one N(1) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Ag(3) and one N(2) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Ag(4) and one N(3) atom. In the seventh O site, O(7) is bonded in a distorted water-like geometry to one Ag(1) and one N(1) atom. In the eighth O site, O(8) is bonded in a distorted water-like geometry to one Ag(1) and one N(2) atom. In the ninth O site, O(9) is bonded in a distorted water-like geometry to one Ag(1) and one N(3) atom. is represented by the CIF card [CIF]
data_Ag4C(NO3)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.999
_cell_length_b   8.078
_cell_length_c   8.125
_cell_angle_alpha   106.855
_cell_angle_beta   104.959
_cell_angle_gamma   104.954
_symmetry_Int_Tables_number   1
_cell_volume   452.895
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.742  0.748  0.743  1.0
  Ag  Ag1  1  0.258  0.252  0.257  1.0
  Ag  Ag2  1  0.244  0.861  0.141  1.0
  Ag  Ag3  1  0.131  0.243  0.859  1.0
  Ag  Ag4  1  0.859  0.133  0.235  1.0
  Ag  Ag5  1  0.756  0.139  0.859  1.0
  Ag  Ag6  1  0.869  0.757  0.141  1.0
  Ag  Ag7  1  0.141  0.867  0.765  1.0
  C  C8  1  0.022  0.967  0.064  1.0
  C  C9  1  0.978  0.033  0.936  1.0
  N  N10  1  0.159  0.606  0.369  1.0
  N  N11  1  0.370  0.160  0.612  1.0
  N  N12  1  0.610  0.369  0.158  1.0
  N  N13  1  0.841  0.394  0.631  1.0
  N  N14  1  0.630  0.840  0.388  1.0
  N  N15  1  0.390  0.631  0.842  1.0
  O  O16  1  0.553  0.871  0.248  1.0
  O  O17  1  0.248  0.554  0.873  1.0
  O  O18  1  0.872  0.250  0.554  1.0
  O  O19  1  0.447  0.129  0.752  1.0
  O  O20  1  0.752  0.446  0.127  1.0
  O  O21  1  0.128  0.750  0.446  1.0
  O  O22  1  0.168  0.574  0.210  1.0
  O  O23  1  0.210  0.167  0.583  1.0
  O  O24  1  0.583  0.209  0.165  1.0
  O  O25  1  0.832  0.426  0.790  1.0
  O  O26  1  0.790  0.833  0.417  1.0
  O  O27  1  0.417  0.791  0.835  1.0
  O  O28  1  0.179  0.495  0.448  1.0
  O  O29  1  0.451  0.180  0.500  1.0
  O  O30  1  0.496  0.448  0.181  1.0
  O  O31  1  0.821  0.505  0.552  1.0
  O  O32  1  0.549  0.820  0.500  1.0
  O  O33  1  0.504  0.552  0.819  1.0
[/CIF]
.