The structure described by SrLaVO4 crystallizes in the orthorhombic Ima2 space group. There are two inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 9-coordinate geometry to one O(1), one O(3), two equivalent O(5), two equivalent O(6), and three equivalent O(4) atoms. In the second Sr site, Sr(2) is bonded in a 9-coordinate geometry to one O(2), one O(4), two equivalent O(5), two equivalent O(7), and three equivalent O(3) atoms. There are two inequivalent La sites. In the first La site, La(1) is bonded in a 8-coordinate geometry to one O(1), one O(3), two equivalent O(2), two equivalent O(5), and two equivalent O(6) atoms. In the second La site, La(2) is bonded in a 8-coordinate geometry to one O(2), one O(4), two equivalent O(1), two equivalent O(5), and two equivalent O(7) atoms. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(3), two equivalent O(5), and two equivalent O(7) atoms to form corner-sharing VO6 octahedra. The corner-sharing octahedral tilt angles range from 5-16°. In the second V site, V(2) is bonded to one O(2), one O(4), two equivalent O(5), and two equivalent O(6) atoms to form corner-sharing VO6 octahedra. The corner-sharing octahedral tilt angles range from 5-16°. There are seven inequivalent O sites. In the first O site, O(5) is bonded to one Sr(1), one Sr(2), one La(1), one La(2), one V(1), and one V(2) atom to form a mixture of distorted corner, edge, and face-sharing OSr2La2V2 octahedra. The corner-sharing octahedral tilt angles are 5°. In the second O site, O(6) is bonded in a 6-coordinate geometry to two equivalent Sr(1), two equivalent La(1), and two equivalent V(2) atoms. In the third O site, O(7) is bonded to two equivalent Sr(2), two equivalent La(2), and two equivalent V(1) atoms to form a mixture of distorted corner, edge, and face-sharing OSr2La2V2 octahedra. The corner-sharing octahedral tilt angles are 5°. In the fourth O site, O(1) is bonded in a 5-coordinate geometry to one Sr(1), one La(1), two equivalent La(2), and one V(1) atom. In the fifth O site, O(2) is bonded in a 5-coordinate geometry to one Sr(2), one La(2), two equivalent La(1), and one V(2) atom. In the sixth O site, O(3) is bonded in a 6-coordinate geometry to one Sr(1), three equivalent Sr(2), one La(1), and one V(1) atom. In the seventh O site, O(4) is bonded in a 6-coordinate geometry to one Sr(2), three equivalent Sr(1), one La(2), and one V(2) atom. is represented by the CIF card [CIF]
data_SrLaVO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.548
_cell_length_b   5.676
_cell_length_c   6.856
_cell_angle_alpha   89.998
_cell_angle_beta   113.870
_cell_angle_gamma   90.002
_symmetry_Int_Tables_number   1
_cell_volume   197.430
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.857  0.519  0.714  1.0
  La  La1  1  0.357  0.981  0.714  1.0
  O  O2  1  0.834  0.945  0.668  1.0
  O  O3  1  0.335  0.555  0.668  1.0
  O  O4  1  0.673  0.464  0.346  1.0
  O  O5  1  0.173  0.036  0.346  1.0
  O  O6  1  0.759  0.750  0.019  1.0
  O  O7  1  0.230  0.250  0.961  1.0
  O  O8  1  0.259  0.750  0.018  1.0
  O  O9  1  0.731  0.250  0.961  1.0
  Sr  Sr10  1  0.643  0.011  0.286  1.0
  Sr  Sr11  1  0.143  0.489  0.287  1.0
  V  V12  1  0.503  0.501  0.005  1.0
  V  V13  1  0.003  0.999  0.005  1.0
[/CIF]
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The structure described by SrLaVO4 crystallizes in the orthorhombic Ima2 space group. There are two inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 9-coordinate geometry to one O(1), one O(3), two equivalent O(5), two equivalent O(6), and three equivalent O(4) atoms. In the second Sr site, Sr(2) is bonded in a 9-coordinate geometry to one O(2), one O(4), two equivalent O(5), two equivalent O(7), and three equivalent O(3) atoms. There are two inequivalent La sites. In the first La site, La(1) is bonded in a 8-coordinate geometry to one O(1), one O(3), two equivalent O(2), two equivalent O(5), and two equivalent O(6) atoms. In the second La site, La(2) is bonded in a 8-coordinate geometry to one O(2), one O(4), two equivalent O(1), two equivalent O(5), and two equivalent O(7) atoms. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(3), two equivalent O(5), and two equivalent O(7) atoms to form corner-sharing VO6 octahedra. The corner-sharing octahedral tilt angles range from 5-16°. In the second V site, V(2) is bonded to one O(2), one O(4), two equivalent O(5), and two equivalent O(6) atoms to form corner-sharing VO6 octahedra. The corner-sharing octahedral tilt angles range from 5-16°. There are seven inequivalent O sites. In the first O site, O(5) is bonded to one Sr(1), one Sr(2), one La(1), one La(2), one V(1), and one V(2) atom to form a mixture of distorted corner, edge, and face-sharing OSr2La2V2 octahedra. The corner-sharing octahedral tilt angles are 5°. In the second O site, O(6) is bonded in a 6-coordinate geometry to two equivalent Sr(1), two equivalent La(1), and two equivalent V(2) atoms. In the third O site, O(7) is bonded to two equivalent Sr(2), two equivalent La(2), and two equivalent V(1) atoms to form a mixture of distorted corner, edge, and face-sharing OSr2La2V2 octahedra. The corner-sharing octahedral tilt angles are 5°. In the fourth O site, O(1) is bonded in a 5-coordinate geometry to one Sr(1), one La(1), two equivalent La(2), and one V(1) atom. In the fifth O site, O(2) is bonded in a 5-coordinate geometry to one Sr(2), one La(2), two equivalent La(1), and one V(2) atom. In the sixth O site, O(3) is bonded in a 6-coordinate geometry to one Sr(1), three equivalent Sr(2), one La(1), and one V(1) atom. In the seventh O site, O(4) is bonded in a 6-coordinate geometry to one Sr(2), three equivalent Sr(1), one La(2), and one V(2) atom. is represented by the CIF card [CIF]
data_SrLaVO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.548
_cell_length_b   5.676
_cell_length_c   6.856
_cell_angle_alpha   89.998
_cell_angle_beta   113.870
_cell_angle_gamma   90.002
_symmetry_Int_Tables_number   1
_cell_volume   197.430
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.857  0.519  0.714  1.0
  La  La1  1  0.357  0.981  0.714  1.0
  O  O2  1  0.834  0.945  0.668  1.0
  O  O3  1  0.335  0.555  0.668  1.0
  O  O4  1  0.673  0.464  0.346  1.0
  O  O5  1  0.173  0.036  0.346  1.0
  O  O6  1  0.759  0.750  0.019  1.0
  O  O7  1  0.230  0.250  0.961  1.0
  O  O8  1  0.259  0.750  0.018  1.0
  O  O9  1  0.731  0.250  0.961  1.0
  Sr  Sr10  1  0.643  0.011  0.286  1.0
  Sr  Sr11  1  0.143  0.489  0.287  1.0
  V  V12  1  0.503  0.501  0.005  1.0
  V  V13  1  0.003  0.999  0.005  1.0
[/CIF]
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