The crystal structure described by NaTe is Magnesium tetraboride-like structured and crystallizes in the orthorhombic Pbcn space group. There are three inequivalent Na sites. In the first Na site, Na(1) is bonded in a 6-coordinate geometry to one Te(1), two equivalent Te(3), and four equivalent Te(2) atoms. In the second Na site, Na(2) is bonded in a 6-coordinate geometry to one Te(2), one Te(4), two equivalent Te(1), and two equivalent Te(3) atoms. In the third Na site, Na(3) is bonded in a 6-coordinate geometry to one Te(1), one Te(3), two equivalent Te(2), and two equivalent Te(4) atoms. There are four inequivalent Te sites. In the first Te site, Te(3) is bonded in a 7-coordinate geometry to one Na(3), two equivalent Na(1), two equivalent Na(2), one Te(2), and one Te(4) atom. In the second Te site, Te(4) is bonded in a 8-coordinate geometry to two equivalent Na(2), four equivalent Na(3), and two equivalent Te(3) atoms. In the third Te site, Te(1) is bonded in a 8-coordinate geometry to two equivalent Na(1), two equivalent Na(3), and four equivalent Na(2) atoms. In the fourth Te site, Te(2) is bonded in a 8-coordinate geometry to one Na(2), two equivalent Na(3), four equivalent Na(1), and one Te(3) atom. is represented by the CIF card [CIF]
data_NaTe
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.165
_cell_length_b   9.920
_cell_length_c   15.936
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1448.936
_cell_formula_units_Z   24
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.724  0.514  0.810  1.0
  Na  Na1  1  0.224  0.986  0.690  1.0
  Na  Na2  1  0.776  0.514  0.190  1.0
  Na  Na3  1  0.276  0.986  0.310  1.0
  Na  Na4  1  0.276  0.486  0.190  1.0
  Na  Na5  1  0.776  0.014  0.310  1.0
  Na  Na6  1  0.224  0.486  0.810  1.0
  Na  Na7  1  0.724  0.014  0.690  1.0
  Na  Na8  1  0.939  0.681  0.971  1.0
  Na  Na9  1  0.439  0.819  0.529  1.0
  Na  Na10  1  0.561  0.681  0.029  1.0
  Na  Na11  1  0.061  0.819  0.471  1.0
  Na  Na12  1  0.061  0.319  0.029  1.0
  Na  Na13  1  0.561  0.181  0.471  1.0
  Na  Na14  1  0.439  0.319  0.971  1.0
  Na  Na15  1  0.939  0.181  0.529  1.0
  Na  Na16  1  0.757  0.671  0.613  1.0
  Na  Na17  1  0.257  0.829  0.887  1.0
  Na  Na18  1  0.743  0.671  0.387  1.0
  Na  Na19  1  0.243  0.829  0.113  1.0
  Na  Na20  1  0.243  0.329  0.387  1.0
  Na  Na21  1  0.743  0.171  0.113  1.0
  Na  Na22  1  0.257  0.329  0.613  1.0
  Na  Na23  1  0.757  0.171  0.887  1.0
  Te  Te24  1  0.750  0.928  0.500  1.0
  Te  Te25  1  0.250  0.572  0.000  1.0
  Te  Te26  1  0.250  0.072  0.500  1.0
  Te  Te27  1  0.750  0.428  0.000  1.0
  Te  Te28  1  0.510  0.246  0.253  1.0
  Te  Te29  1  0.010  0.254  0.247  1.0
  Te  Te30  1  0.990  0.246  0.747  1.0
  Te  Te31  1  0.490  0.254  0.753  1.0
  Te  Te32  1  0.490  0.754  0.747  1.0
  Te  Te33  1  0.990  0.746  0.753  1.0
  Te  Te34  1  0.010  0.754  0.253  1.0
  Te  Te35  1  0.510  0.746  0.247  1.0
  Te  Te36  1  0.309  0.140  0.133  1.0
  Te  Te37  1  0.809  0.360  0.367  1.0
  Te  Te38  1  0.191  0.140  0.867  1.0
  Te  Te39  1  0.691  0.360  0.633  1.0
  Te  Te40  1  0.691  0.860  0.867  1.0
  Te  Te41  1  0.191  0.640  0.633  1.0
  Te  Te42  1  0.809  0.860  0.133  1.0
  Te  Te43  1  0.309  0.640  0.367  1.0
  Te  Te44  1  0.000  0.500  0.500  1.0
  Te  Te45  1  0.500  0.000  0.000  1.0
  Te  Te46  1  0.500  0.500  0.500  1.0
  Te  Te47  1  0.000  0.000  0.000  1.0
[/CIF]
.
The crystal structure described by NaTe is Magnesium tetraboride-like structured and crystallizes in the orthorhombic Pbcn space group. There are three inequivalent Na sites. In the first Na site, Na(1) is bonded in a 6-coordinate geometry to one Te(1), two equivalent Te(3), and four equivalent Te(2) atoms. In the second Na site, Na(2) is bonded in a 6-coordinate geometry to one Te(2), one Te(4), two equivalent Te(1), and two equivalent Te(3) atoms. In the third Na site, Na(3) is bonded in a 6-coordinate geometry to one Te(1), one Te(3), two equivalent Te(2), and two equivalent Te(4) atoms. There are four inequivalent Te sites. In the first Te site, Te(3) is bonded in a 7-coordinate geometry to one Na(3), two equivalent Na(1), two equivalent Na(2), one Te(2), and one Te(4) atom. In the second Te site, Te(4) is bonded in a 8-coordinate geometry to two equivalent Na(2), four equivalent Na(3), and two equivalent Te(3) atoms. In the third Te site, Te(1) is bonded in a 8-coordinate geometry to two equivalent Na(1), two equivalent Na(3), and four equivalent Na(2) atoms. In the fourth Te site, Te(2) is bonded in a 8-coordinate geometry to one Na(2), two equivalent Na(3), four equivalent Na(1), and one Te(3) atom. is represented by the CIF card [CIF]
data_NaTe
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.165
_cell_length_b   9.920
_cell_length_c   15.936
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1448.936
_cell_formula_units_Z   24
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.724  0.514  0.810  1.0
  Na  Na1  1  0.224  0.986  0.690  1.0
  Na  Na2  1  0.776  0.514  0.190  1.0
  Na  Na3  1  0.276  0.986  0.310  1.0
  Na  Na4  1  0.276  0.486  0.190  1.0
  Na  Na5  1  0.776  0.014  0.310  1.0
  Na  Na6  1  0.224  0.486  0.810  1.0
  Na  Na7  1  0.724  0.014  0.690  1.0
  Na  Na8  1  0.939  0.681  0.971  1.0
  Na  Na9  1  0.439  0.819  0.529  1.0
  Na  Na10  1  0.561  0.681  0.029  1.0
  Na  Na11  1  0.061  0.819  0.471  1.0
  Na  Na12  1  0.061  0.319  0.029  1.0
  Na  Na13  1  0.561  0.181  0.471  1.0
  Na  Na14  1  0.439  0.319  0.971  1.0
  Na  Na15  1  0.939  0.181  0.529  1.0
  Na  Na16  1  0.757  0.671  0.613  1.0
  Na  Na17  1  0.257  0.829  0.887  1.0
  Na  Na18  1  0.743  0.671  0.387  1.0
  Na  Na19  1  0.243  0.829  0.113  1.0
  Na  Na20  1  0.243  0.329  0.387  1.0
  Na  Na21  1  0.743  0.171  0.113  1.0
  Na  Na22  1  0.257  0.329  0.613  1.0
  Na  Na23  1  0.757  0.171  0.887  1.0
  Te  Te24  1  0.750  0.928  0.500  1.0
  Te  Te25  1  0.250  0.572  0.000  1.0
  Te  Te26  1  0.250  0.072  0.500  1.0
  Te  Te27  1  0.750  0.428  0.000  1.0
  Te  Te28  1  0.510  0.246  0.253  1.0
  Te  Te29  1  0.010  0.254  0.247  1.0
  Te  Te30  1  0.990  0.246  0.747  1.0
  Te  Te31  1  0.490  0.254  0.753  1.0
  Te  Te32  1  0.490  0.754  0.747  1.0
  Te  Te33  1  0.990  0.746  0.753  1.0
  Te  Te34  1  0.010  0.754  0.253  1.0
  Te  Te35  1  0.510  0.746  0.247  1.0
  Te  Te36  1  0.309  0.140  0.133  1.0
  Te  Te37  1  0.809  0.360  0.367  1.0
  Te  Te38  1  0.191  0.140  0.867  1.0
  Te  Te39  1  0.691  0.360  0.633  1.0
  Te  Te40  1  0.691  0.860  0.867  1.0
  Te  Te41  1  0.191  0.640  0.633  1.0
  Te  Te42  1  0.809  0.860  0.133  1.0
  Te  Te43  1  0.309  0.640  0.367  1.0
  Te  Te44  1  0.000  0.500  0.500  1.0
  Te  Te45  1  0.500  0.000  0.000  1.0
  Te  Te46  1  0.500  0.500  0.500  1.0
  Te  Te47  1  0.000  0.000  0.000  1.0
[/CIF]
.