The crystal structure described by RbGeCl3 is Orthorhombic Perovskite structured and crystallizes in the orthorhombic Pna2_1 space group. Rb(1) is bonded in a 8-coordinate geometry to two equivalent Cl(3), three equivalent Cl(1), and three equivalent Cl(2) atoms. Ge(1) is bonded in a distorted T-shaped geometry to one Cl(1), one Cl(2), and one Cl(3) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a 4-coordinate geometry to three equivalent Rb(1) and one Ge(1) atom. In the second Cl site, Cl(2) is bonded in a 4-coordinate geometry to three equivalent Rb(1) and one Ge(1) atom. In the third Cl site, Cl(3) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Rb(1) and one Ge(1) atom. is represented by the CIF card [CIF]
data_RbGeCl3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.299
_cell_length_b   7.990
_cell_length_c   10.844
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   632.456
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.971  0.416  0.751  1.0
  Rb  Rb1  1  0.471  0.084  0.251  1.0
  Rb  Rb2  1  0.529  0.916  0.751  1.0
  Rb  Rb3  1  0.029  0.584  0.251  1.0
  Ge  Ge4  1  0.485  0.473  0.519  1.0
  Ge  Ge5  1  0.515  0.527  0.019  1.0
  Ge  Ge6  1  0.015  0.973  0.519  1.0
  Ge  Ge7  1  0.985  0.027  0.019  1.0
  Cl  Cl8  1  0.344  0.778  0.048  1.0
  Cl  Cl9  1  0.156  0.278  0.048  1.0
  Cl  Cl10  1  0.844  0.722  0.548  1.0
  Cl  Cl11  1  0.289  0.830  0.467  1.0
  Cl  Cl12  1  0.211  0.330  0.467  1.0
  Cl  Cl13  1  0.789  0.670  0.967  1.0
  Cl  Cl14  1  0.417  0.506  0.730  1.0
  Cl  Cl15  1  0.711  0.170  0.967  1.0
  Cl  Cl16  1  0.917  0.994  0.230  1.0
  Cl  Cl17  1  0.583  0.494  0.230  1.0
  Cl  Cl18  1  0.083  0.006  0.730  1.0
  Cl  Cl19  1  0.656  0.222  0.548  1.0
[/CIF]
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The crystal structure described by RbGeCl3 is Orthorhombic Perovskite structured and crystallizes in the orthorhombic Pna2_1 space group. Rb(1) is bonded in a 8-coordinate geometry to two equivalent Cl(3), three equivalent Cl(1), and three equivalent Cl(2) atoms. Ge(1) is bonded in a distorted T-shaped geometry to one Cl(1), one Cl(2), and one Cl(3) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a 4-coordinate geometry to three equivalent Rb(1) and one Ge(1) atom. In the second Cl site, Cl(2) is bonded in a 4-coordinate geometry to three equivalent Rb(1) and one Ge(1) atom. In the third Cl site, Cl(3) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Rb(1) and one Ge(1) atom. is represented by the CIF card [CIF]
data_RbGeCl3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.299
_cell_length_b   7.990
_cell_length_c   10.844
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   632.456
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.971  0.416  0.751  1.0
  Rb  Rb1  1  0.471  0.084  0.251  1.0
  Rb  Rb2  1  0.529  0.916  0.751  1.0
  Rb  Rb3  1  0.029  0.584  0.251  1.0
  Ge  Ge4  1  0.485  0.473  0.519  1.0
  Ge  Ge5  1  0.515  0.527  0.019  1.0
  Ge  Ge6  1  0.015  0.973  0.519  1.0
  Ge  Ge7  1  0.985  0.027  0.019  1.0
  Cl  Cl8  1  0.344  0.778  0.048  1.0
  Cl  Cl9  1  0.156  0.278  0.048  1.0
  Cl  Cl10  1  0.844  0.722  0.548  1.0
  Cl  Cl11  1  0.289  0.830  0.467  1.0
  Cl  Cl12  1  0.211  0.330  0.467  1.0
  Cl  Cl13  1  0.789  0.670  0.967  1.0
  Cl  Cl14  1  0.417  0.506  0.730  1.0
  Cl  Cl15  1  0.711  0.170  0.967  1.0
  Cl  Cl16  1  0.917  0.994  0.230  1.0
  Cl  Cl17  1  0.583  0.494  0.230  1.0
  Cl  Cl18  1  0.083  0.006  0.730  1.0
  Cl  Cl19  1  0.656  0.222  0.548  1.0
[/CIF]
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