The structure described by Ag(OsO3)2 crystallizes in the orthorhombic Ima2 space group. There are two inequivalent Os sites. In the first Os site, Os(1) is bonded to two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms to form corner-sharing OsO6 octahedra. The corner-sharing octahedral tilt angles range from 35-46°. In the second Os site, Os(2) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms to form corner-sharing OsO6 octahedra. The corner-sharing octahedral tilt angles range from 35-46°. Ag(1) is bonded in a distorted hexagonal planar geometry to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to two equivalent Os(2) and two equivalent Ag(1) atoms. In the second O site, O(2) is bonded in a bent 150 degrees geometry to two equivalent Os(1) atoms. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Os(1), one Os(2), and one Ag(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal non-coplanar geometry to one Os(1), one Os(2), and one Ag(1) atom. is represented by the CIF card [CIF]
data_Ag(OsO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.225
_cell_length_b   7.225
_cell_length_c   7.225
_cell_angle_alpha   119.862
_cell_angle_beta   119.652
_cell_angle_gamma   90.421
_symmetry_Int_Tables_number   1
_cell_volume   267.663
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.471  0.931  0.960  1.0
  Ag  Ag1  1  0.529  0.488  0.460  1.0
  Os  Os2  1  0.998  0.509  0.011  1.0
  Os  Os3  1  0.002  0.013  0.511  1.0
  Os  Os4  1  0.500  0.004  0.504  1.0
  Os  Os5  1  0.000  0.004  0.004  1.0
  O  O6  1  0.324  0.072  0.248  1.0
  O  O7  1  0.943  0.699  0.257  1.0
  O  O8  1  0.943  0.063  0.254  1.0
  O  O9  1  0.323  0.681  0.255  1.0
  O  O10  1  0.926  0.681  0.857  1.0
  O  O11  1  0.309  0.063  0.620  1.0
  O  O12  1  0.676  0.924  0.748  1.0
  O  O13  1  0.057  0.314  0.757  1.0
  O  O14  1  0.074  0.931  0.755  1.0
  O  O15  1  0.691  0.311  0.754  1.0
  O  O16  1  0.057  0.311  0.120  1.0
  O  O17  1  0.677  0.931  0.357  1.0
[/CIF]
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The structure described by Ag(OsO3)2 crystallizes in the orthorhombic Ima2 space group. There are two inequivalent Os sites. In the first Os site, Os(1) is bonded to two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms to form corner-sharing OsO6 octahedra. The corner-sharing octahedral tilt angles range from 35-46°. In the second Os site, Os(2) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms to form corner-sharing OsO6 octahedra. The corner-sharing octahedral tilt angles range from 35-46°. Ag(1) is bonded in a distorted hexagonal planar geometry to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to two equivalent Os(2) and two equivalent Ag(1) atoms. In the second O site, O(2) is bonded in a bent 150 degrees geometry to two equivalent Os(1) atoms. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Os(1), one Os(2), and one Ag(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal non-coplanar geometry to one Os(1), one Os(2), and one Ag(1) atom. is represented by the CIF card [CIF]
data_Ag(OsO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.225
_cell_length_b   7.225
_cell_length_c   7.225
_cell_angle_alpha   119.862
_cell_angle_beta   119.652
_cell_angle_gamma   90.421
_symmetry_Int_Tables_number   1
_cell_volume   267.663
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.471  0.931  0.960  1.0
  Ag  Ag1  1  0.529  0.488  0.460  1.0
  Os  Os2  1  0.998  0.509  0.011  1.0
  Os  Os3  1  0.002  0.013  0.511  1.0
  Os  Os4  1  0.500  0.004  0.504  1.0
  Os  Os5  1  0.000  0.004  0.004  1.0
  O  O6  1  0.324  0.072  0.248  1.0
  O  O7  1  0.943  0.699  0.257  1.0
  O  O8  1  0.943  0.063  0.254  1.0
  O  O9  1  0.323  0.681  0.255  1.0
  O  O10  1  0.926  0.681  0.857  1.0
  O  O11  1  0.309  0.063  0.620  1.0
  O  O12  1  0.676  0.924  0.748  1.0
  O  O13  1  0.057  0.314  0.757  1.0
  O  O14  1  0.074  0.931  0.755  1.0
  O  O15  1  0.691  0.311  0.754  1.0
  O  O16  1  0.057  0.311  0.120  1.0
  O  O17  1  0.677  0.931  0.357  1.0
[/CIF]
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