The material described by SbTe6(OF5)6Te2Cl6F is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one SbTe6(OF5)6 cluster and one Te2Cl6F cluster. In the SbTe6(OF5)6 cluster, Sb(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form SbO6 octahedra that share corners with two equivalent Te(1)OF5 octahedra, corners with two equivalent Te(2)OF5 octahedra, and corners with two equivalent Te(4)OF5 octahedra. The corner-sharing octahedral tilt angles range from 39-40°. There are three inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(1), one F(10), one F(12), one F(2), one F(3), and one F(7) atom to form TeOF5 octahedra that share  a cornercorner with one Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles are 40°. In the second Te site, Te(2) is bonded to one O(2), one F(15), one F(16), one F(4), one F(5), and one F(6) atom to form TeOF5 octahedra that share  a cornercorner with one Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles are 39°. In the third Te site, Te(4) is bonded to one O(3), one F(1), one F(11), one F(14), one F(8), and one F(9) atom to form TeOF5 octahedra that share  a cornercorner with one Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles are 40°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Sb(1) and one Te(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Sb(1) and one Te(2) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Sb(1) and one Te(4) atom. There are fifteen inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Te(4) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Te(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Te(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Te(2) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one Te(2) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one Te(2) atom. In the seventh F site, F(7) is bonded in a single-bond geometry to one Te(1) atom. In the eighth F site, F(8) is bonded in a single-bond geometry to one Te(4) atom. In the ninth F site, F(9) is bonded in a single-bond geometry to one Te(4) atom. In the tenth F site, F(10) is bonded in a single-bond geometry to one Te(1) atom. In the eleventh F site, F(11) is bonded in a single-bond geometry to one Te(4) atom. In the twelfth F site, F(12) is bonded in a single-bond geometry to one Te(1) atom. In the thirteenth F site, F(14) is bonded in a single-bond geometry to one Te(4) atom. In the fourteenth F site, F(15) is bonded in a single-bond geometry to one Te(2) atom. In the fifteenth F site, F(16) is bonded in a single-bond geometry to one Te(2) atom. In the Te2Cl6F cluster, Te(3) is bonded in a rectangular see-saw-like geometry to one Cl(1), one Cl(2), one Cl(3), and one F(13) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Te(3) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Te(3) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Te(3) atom. F(13) is bonded in a linear geometry to two equivalent Te(3) atoms. is represented by the CIF card [CIF]
data_SbTe8Cl6O6F31
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.366
_cell_length_b   10.664
_cell_length_c   10.815
_cell_angle_alpha   83.505
_cell_angle_beta   86.183
_cell_angle_gamma   75.657
_symmetry_Int_Tables_number   1
_cell_volume   1039.008
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.000  0.000  0.500  1.0
  Te  Te1  1  0.275  0.723  0.393  1.0
  Te  Te2  1  0.725  0.277  0.607  1.0
  Te  Te3  1  0.239  0.199  0.343  1.0
  Te  Te4  1  0.761  0.801  0.657  1.0
  Te  Te5  1  0.662  0.514  0.138  1.0
  Te  Te6  1  0.338  0.486  0.862  1.0
  Te  Te7  1  0.831  0.026  0.200  1.0
  Te  Te8  1  0.169  0.974  0.800  1.0
  Cl  Cl9  1  0.159  0.451  0.737  1.0
  Cl  Cl10  1  0.841  0.549  0.263  1.0
  Cl  Cl11  1  0.165  0.578  0.009  1.0
  Cl  Cl12  1  0.835  0.422  0.991  1.0
  Cl  Cl13  1  0.603  0.730  0.057  1.0
  Cl  Cl14  1  0.397  0.270  0.943  1.0
  O  O15  1  0.806  0.127  0.526  1.0
  O  O16  1  0.194  0.873  0.474  1.0
  O  O17  1  0.066  0.142  0.394  1.0
  O  O18  1  0.934  0.858  0.606  1.0
  O  O19  1  0.083  0.050  0.647  1.0
  O  O20  1  0.917  0.950  0.353  1.0
  F  F21  1  0.764  0.197  0.248  1.0
  F  F22  1  0.236  0.803  0.752  1.0
  F  F23  1  0.545  0.228  0.629  1.0
  F  F24  1  0.455  0.772  0.371  1.0
  F  F25  1  0.657  0.372  0.456  1.0
  F  F26  1  0.343  0.628  0.544  1.0
  F  F27  1  0.182  0.337  0.443  1.0
  F  F28  1  0.818  0.663  0.557  1.0
  F  F29  1  0.401  0.267  0.286  1.0
  F  F30  1  0.599  0.733  0.714  1.0
  F  F31  1  0.355  0.098  0.469  1.0
  F  F32  1  0.645  0.902  0.531  1.0
  F  F33  1  0.221  0.802  0.234  1.0
  F  F34  1  0.779  0.198  0.766  1.0
  F  F35  1  0.002  0.070  0.131  1.0
  F  F36  1  0.998  0.930  0.869  1.0
  F  F37  1  0.109  0.138  0.859  1.0
  F  F38  1  0.891  0.862  0.141  1.0
  F  F39  1  0.106  0.658  0.411  1.0
  F  F40  1  0.894  0.342  0.589  1.0
  F  F41  1  0.742  0.090  0.048  1.0
  F  F42  1  0.258  0.910  0.952  1.0
  F  F43  1  0.370  0.573  0.313  1.0
  F  F44  1  0.630  0.427  0.687  1.0
  F  F45  1  0.500  0.500  0.000  1.0
  F  F46  1  0.349  0.011  0.742  1.0
  F  F47  1  0.651  0.989  0.258  1.0
  F  F48  1  0.132  0.304  0.212  1.0
  F  F49  1  0.868  0.696  0.788  1.0
  F  F50  1  0.308  0.069  0.236  1.0
  F  F51  1  0.692  0.931  0.764  1.0
[/CIF]
.
The material described by SbTe6(OF5)6Te2Cl6F is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one SbTe6(OF5)6 cluster and one Te2Cl6F cluster. In the SbTe6(OF5)6 cluster, Sb(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form SbO6 octahedra that share corners with two equivalent Te(1)OF5 octahedra, corners with two equivalent Te(2)OF5 octahedra, and corners with two equivalent Te(4)OF5 octahedra. The corner-sharing octahedral tilt angles range from 39-40°. There are three inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(1), one F(10), one F(12), one F(2), one F(3), and one F(7) atom to form TeOF5 octahedra that share  a cornercorner with one Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles are 40°. In the second Te site, Te(2) is bonded to one O(2), one F(15), one F(16), one F(4), one F(5), and one F(6) atom to form TeOF5 octahedra that share  a cornercorner with one Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles are 39°. In the third Te site, Te(4) is bonded to one O(3), one F(1), one F(11), one F(14), one F(8), and one F(9) atom to form TeOF5 octahedra that share  a cornercorner with one Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles are 40°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Sb(1) and one Te(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Sb(1) and one Te(2) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Sb(1) and one Te(4) atom. There are fifteen inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Te(4) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Te(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Te(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Te(2) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one Te(2) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one Te(2) atom. In the seventh F site, F(7) is bonded in a single-bond geometry to one Te(1) atom. In the eighth F site, F(8) is bonded in a single-bond geometry to one Te(4) atom. In the ninth F site, F(9) is bonded in a single-bond geometry to one Te(4) atom. In the tenth F site, F(10) is bonded in a single-bond geometry to one Te(1) atom. In the eleventh F site, F(11) is bonded in a single-bond geometry to one Te(4) atom. In the twelfth F site, F(12) is bonded in a single-bond geometry to one Te(1) atom. In the thirteenth F site, F(14) is bonded in a single-bond geometry to one Te(4) atom. In the fourteenth F site, F(15) is bonded in a single-bond geometry to one Te(2) atom. In the fifteenth F site, F(16) is bonded in a single-bond geometry to one Te(2) atom. In the Te2Cl6F cluster, Te(3) is bonded in a rectangular see-saw-like geometry to one Cl(1), one Cl(2), one Cl(3), and one F(13) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Te(3) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Te(3) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Te(3) atom. F(13) is bonded in a linear geometry to two equivalent Te(3) atoms. is represented by the CIF card [CIF]
data_SbTe8Cl6O6F31
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.366
_cell_length_b   10.664
_cell_length_c   10.815
_cell_angle_alpha   83.505
_cell_angle_beta   86.183
_cell_angle_gamma   75.657
_symmetry_Int_Tables_number   1
_cell_volume   1039.008
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.000  0.000  0.500  1.0
  Te  Te1  1  0.275  0.723  0.393  1.0
  Te  Te2  1  0.725  0.277  0.607  1.0
  Te  Te3  1  0.239  0.199  0.343  1.0
  Te  Te4  1  0.761  0.801  0.657  1.0
  Te  Te5  1  0.662  0.514  0.138  1.0
  Te  Te6  1  0.338  0.486  0.862  1.0
  Te  Te7  1  0.831  0.026  0.200  1.0
  Te  Te8  1  0.169  0.974  0.800  1.0
  Cl  Cl9  1  0.159  0.451  0.737  1.0
  Cl  Cl10  1  0.841  0.549  0.263  1.0
  Cl  Cl11  1  0.165  0.578  0.009  1.0
  Cl  Cl12  1  0.835  0.422  0.991  1.0
  Cl  Cl13  1  0.603  0.730  0.057  1.0
  Cl  Cl14  1  0.397  0.270  0.943  1.0
  O  O15  1  0.806  0.127  0.526  1.0
  O  O16  1  0.194  0.873  0.474  1.0
  O  O17  1  0.066  0.142  0.394  1.0
  O  O18  1  0.934  0.858  0.606  1.0
  O  O19  1  0.083  0.050  0.647  1.0
  O  O20  1  0.917  0.950  0.353  1.0
  F  F21  1  0.764  0.197  0.248  1.0
  F  F22  1  0.236  0.803  0.752  1.0
  F  F23  1  0.545  0.228  0.629  1.0
  F  F24  1  0.455  0.772  0.371  1.0
  F  F25  1  0.657  0.372  0.456  1.0
  F  F26  1  0.343  0.628  0.544  1.0
  F  F27  1  0.182  0.337  0.443  1.0
  F  F28  1  0.818  0.663  0.557  1.0
  F  F29  1  0.401  0.267  0.286  1.0
  F  F30  1  0.599  0.733  0.714  1.0
  F  F31  1  0.355  0.098  0.469  1.0
  F  F32  1  0.645  0.902  0.531  1.0
  F  F33  1  0.221  0.802  0.234  1.0
  F  F34  1  0.779  0.198  0.766  1.0
  F  F35  1  0.002  0.070  0.131  1.0
  F  F36  1  0.998  0.930  0.869  1.0
  F  F37  1  0.109  0.138  0.859  1.0
  F  F38  1  0.891  0.862  0.141  1.0
  F  F39  1  0.106  0.658  0.411  1.0
  F  F40  1  0.894  0.342  0.589  1.0
  F  F41  1  0.742  0.090  0.048  1.0
  F  F42  1  0.258  0.910  0.952  1.0
  F  F43  1  0.370  0.573  0.313  1.0
  F  F44  1  0.630  0.427  0.687  1.0
  F  F45  1  0.500  0.500  0.000  1.0
  F  F46  1  0.349  0.011  0.742  1.0
  F  F47  1  0.651  0.989  0.258  1.0
  F  F48  1  0.132  0.304  0.212  1.0
  F  F49  1  0.868  0.696  0.788  1.0
  F  F50  1  0.308  0.069  0.236  1.0
  F  F51  1  0.692  0.931  0.764  1.0
[/CIF]
.