The material structure described by N2Se3AsF6 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four AsF6 clusters and four N2Se3 clusters. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to one F(1), one F(10), one F(12), one F(2), one F(4), and one F(5) atom. There are six inequivalent F sites. In the first F site, F(10) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(12) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(4) is bonded in a single-bond geometry to one As(1) atom. In the sixth F site, F(5) is bonded in a single-bond geometry to one As(1) atom. In each N2Se3 cluster, there are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one Se(2) and one Se(5) atom. In the second N site, N(3) is bonded in a bent 120 degrees geometry to one Se(1) and one Se(5) atom. There are three inequivalent Se sites. In the first Se site, Se(1) is bonded in a single-bond geometry to one N(3) atom. In the second Se site, Se(2) is bonded in a single-bond geometry to one N(1) atom. In the third Se site, Se(5) is bonded in a water-like geometry to one N(1) and one N(3) atom. is represented by the CIF file [CIF]
data_AsSe3(NF3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.496
_cell_length_b   10.631
_cell_length_c   10.735
_cell_angle_alpha   82.435
_cell_angle_beta   69.847
_cell_angle_gamma   82.398
_symmetry_Int_Tables_number   1
_cell_volume   898.390
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.206  0.676  0.626  1.0
  As  As1  1  0.792  0.146  0.863  1.0
  As  As2  1  0.794  0.324  0.374  1.0
  As  As3  1  0.208  0.854  0.137  1.0
  Se  Se4  1  0.664  0.997  0.314  1.0
  Se  Se5  1  0.710  0.921  0.529  1.0
  Se  Se6  1  0.727  0.479  0.016  1.0
  Se  Se7  1  0.355  0.433  0.180  1.0
  Se  Se8  1  0.336  0.003  0.686  1.0
  Se  Se9  1  0.707  0.705  0.367  1.0
  Se  Se10  1  0.273  0.521  0.984  1.0
  Se  Se11  1  0.270  0.230  0.041  1.0
  Se  Se12  1  0.290  0.079  0.471  1.0
  Se  Se13  1  0.730  0.770  0.959  1.0
  Se  Se14  1  0.293  0.295  0.633  1.0
  Se  Se15  1  0.645  0.567  0.820  1.0
  N  N16  1  0.272  0.242  0.493  1.0
  N  N17  1  0.764  0.627  0.053  1.0
  N  N18  1  0.321  0.157  0.736  1.0
  N  N19  1  0.679  0.843  0.264  1.0
  N  N20  1  0.328  0.274  0.169  1.0
  N  N21  1  0.236  0.373  0.947  1.0
  N  N22  1  0.728  0.758  0.507  1.0
  N  N23  1  0.672  0.726  0.831  1.0
  F  F24  1  0.239  0.603  0.480  1.0
  F  F25  1  0.031  0.774  0.607  1.0
  F  F26  1  0.910  0.202  0.700  1.0
  F  F27  1  0.090  0.798  0.300  1.0
  F  F28  1  0.925  0.443  0.276  1.0
  F  F29  1  0.660  0.202  0.469  1.0
  F  F30  1  0.075  0.557  0.724  1.0
  F  F31  1  0.071  0.996  0.146  1.0
  F  F32  1  0.338  0.928  0.200  1.0
  F  F33  1  0.084  0.777  0.072  1.0
  F  F34  1  0.662  0.072  0.800  1.0
  F  F35  1  0.351  0.710  0.124  1.0
  F  F36  1  0.969  0.226  0.393  1.0
  F  F37  1  0.340  0.798  0.531  1.0
  F  F38  1  0.761  0.397  0.520  1.0
  F  F39  1  0.613  0.419  0.353  1.0
  F  F40  1  0.649  0.290  0.876  1.0
  F  F41  1  0.667  0.093  0.028  1.0
  F  F42  1  0.387  0.581  0.647  1.0
  F  F43  1  0.333  0.907  0.972  1.0
  F  F44  1  0.916  0.223  0.928  1.0
  F  F45  1  0.929  0.004  0.854  1.0
  F  F46  1  0.182  0.747  0.774  1.0
  F  F47  1  0.818  0.253  0.226  1.0
[/CIF]
.
The material structure described by N2Se3AsF6 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four AsF6 clusters and four N2Se3 clusters. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to one F(1), one F(10), one F(12), one F(2), one F(4), and one F(5) atom. There are six inequivalent F sites. In the first F site, F(10) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(12) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(4) is bonded in a single-bond geometry to one As(1) atom. In the sixth F site, F(5) is bonded in a single-bond geometry to one As(1) atom. In each N2Se3 cluster, there are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one Se(2) and one Se(5) atom. In the second N site, N(3) is bonded in a bent 120 degrees geometry to one Se(1) and one Se(5) atom. There are three inequivalent Se sites. In the first Se site, Se(1) is bonded in a single-bond geometry to one N(3) atom. In the second Se site, Se(2) is bonded in a single-bond geometry to one N(1) atom. In the third Se site, Se(5) is bonded in a water-like geometry to one N(1) and one N(3) atom. is represented by the CIF file [CIF]
data_AsSe3(NF3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.496
_cell_length_b   10.631
_cell_length_c   10.735
_cell_angle_alpha   82.435
_cell_angle_beta   69.847
_cell_angle_gamma   82.398
_symmetry_Int_Tables_number   1
_cell_volume   898.390
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.206  0.676  0.626  1.0
  As  As1  1  0.792  0.146  0.863  1.0
  As  As2  1  0.794  0.324  0.374  1.0
  As  As3  1  0.208  0.854  0.137  1.0
  Se  Se4  1  0.664  0.997  0.314  1.0
  Se  Se5  1  0.710  0.921  0.529  1.0
  Se  Se6  1  0.727  0.479  0.016  1.0
  Se  Se7  1  0.355  0.433  0.180  1.0
  Se  Se8  1  0.336  0.003  0.686  1.0
  Se  Se9  1  0.707  0.705  0.367  1.0
  Se  Se10  1  0.273  0.521  0.984  1.0
  Se  Se11  1  0.270  0.230  0.041  1.0
  Se  Se12  1  0.290  0.079  0.471  1.0
  Se  Se13  1  0.730  0.770  0.959  1.0
  Se  Se14  1  0.293  0.295  0.633  1.0
  Se  Se15  1  0.645  0.567  0.820  1.0
  N  N16  1  0.272  0.242  0.493  1.0
  N  N17  1  0.764  0.627  0.053  1.0
  N  N18  1  0.321  0.157  0.736  1.0
  N  N19  1  0.679  0.843  0.264  1.0
  N  N20  1  0.328  0.274  0.169  1.0
  N  N21  1  0.236  0.373  0.947  1.0
  N  N22  1  0.728  0.758  0.507  1.0
  N  N23  1  0.672  0.726  0.831  1.0
  F  F24  1  0.239  0.603  0.480  1.0
  F  F25  1  0.031  0.774  0.607  1.0
  F  F26  1  0.910  0.202  0.700  1.0
  F  F27  1  0.090  0.798  0.300  1.0
  F  F28  1  0.925  0.443  0.276  1.0
  F  F29  1  0.660  0.202  0.469  1.0
  F  F30  1  0.075  0.557  0.724  1.0
  F  F31  1  0.071  0.996  0.146  1.0
  F  F32  1  0.338  0.928  0.200  1.0
  F  F33  1  0.084  0.777  0.072  1.0
  F  F34  1  0.662  0.072  0.800  1.0
  F  F35  1  0.351  0.710  0.124  1.0
  F  F36  1  0.969  0.226  0.393  1.0
  F  F37  1  0.340  0.798  0.531  1.0
  F  F38  1  0.761  0.397  0.520  1.0
  F  F39  1  0.613  0.419  0.353  1.0
  F  F40  1  0.649  0.290  0.876  1.0
  F  F41  1  0.667  0.093  0.028  1.0
  F  F42  1  0.387  0.581  0.647  1.0
  F  F43  1  0.333  0.907  0.972  1.0
  F  F44  1  0.916  0.223  0.928  1.0
  F  F45  1  0.929  0.004  0.854  1.0
  F  F46  1  0.182  0.747  0.774  1.0
  F  F47  1  0.818  0.253  0.226  1.0
[/CIF]
.