The material structure described by V2CdO8O2 crystallizes in the monoclinic Cc space group. The structure consists of four hydrogen peroxide molecules inside a V2CdO8 framework. In the V2CdO8 framework, there are two inequivalent V sites. In the first V site, V(1) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(3), and two equivalent O(4) atoms. In the second V site, V(2) is bonded in a 5-coordinate geometry to one O(4), one O(5), one O(6), and two equivalent O(3) atoms. Cd(1) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(2), one O(5), one O(6), and one O(9) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one V(1) and one Cd(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one V(1) and one Cd(1) atom. In the third O site, O(3) is bonded in a trigonal non-coplanar geometry to one V(1) and two equivalent V(2) atoms. In the fourth O site, O(4) is bonded in a trigonal non-coplanar geometry to one V(2) and two equivalent V(1) atoms. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one V(2) and one Cd(1) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one V(2) and one Cd(1) atom. In the seventh O site, O(9) is bonded in a distorted bent 120 degrees geometry to one Cd(1) and one O(10) atom. In the eighth O site, O(10) is bonded in a single-bond geometry to one O(9) atom. is represented by the CIF card [CIF]
data_V2CdO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.989
_cell_length_b   8.493
_cell_length_c   8.493
_cell_angle_alpha   74.796
_cell_angle_beta   71.460
_cell_angle_gamma   71.460
_symmetry_Int_Tables_number   1
_cell_volume   445.816
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.541  0.390  0.324  1.0
  V  V1  1  0.041  0.324  0.390  1.0
  V  V2  1  0.943  0.114  0.176  1.0
  V  V3  1  0.443  0.176  0.114  1.0
  Cd  Cd4  1  0.747  0.748  0.252  1.0
  Cd  Cd5  1  0.247  0.252  0.748  1.0
  O  O6  1  0.569  0.583  0.224  1.0
  O  O7  1  0.069  0.224  0.583  1.0
  O  O8  1  0.914  0.529  0.401  1.0
  O  O9  1  0.414  0.401  0.529  1.0
  O  O10  1  0.668  0.231  0.154  1.0
  O  O11  1  0.168  0.154  0.231  1.0
  O  O12  1  0.813  0.266  0.355  1.0
  O  O13  1  0.313  0.355  0.266  1.0
  O  O14  1  0.564  0.968  0.116  1.0
  O  O15  1  0.064  0.116  0.968  1.0
  O  O16  1  0.931  0.915  0.266  1.0
  O  O17  1  0.431  0.266  0.915  1.0
  O  O18  1  0.107  0.693  0.965  1.0
  O  O19  1  0.607  0.965  0.693  1.0
  O  O20  1  0.787  0.936  0.704  1.0
  O  O21  1  0.287  0.704  0.936  1.0
  O  O22  1  0.397  0.784  0.534  1.0
  O  O23  1  0.897  0.534  0.784  1.0
  O  O24  1  0.721  0.544  0.776  1.0
  O  O25  1  0.221  0.776  0.544  1.0
[/CIF]
.
The material structure described by V2CdO8O2 crystallizes in the monoclinic Cc space group. The structure consists of four hydrogen peroxide molecules inside a V2CdO8 framework. In the V2CdO8 framework, there are two inequivalent V sites. In the first V site, V(1) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(3), and two equivalent O(4) atoms. In the second V site, V(2) is bonded in a 5-coordinate geometry to one O(4), one O(5), one O(6), and two equivalent O(3) atoms. Cd(1) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(2), one O(5), one O(6), and one O(9) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one V(1) and one Cd(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one V(1) and one Cd(1) atom. In the third O site, O(3) is bonded in a trigonal non-coplanar geometry to one V(1) and two equivalent V(2) atoms. In the fourth O site, O(4) is bonded in a trigonal non-coplanar geometry to one V(2) and two equivalent V(1) atoms. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one V(2) and one Cd(1) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one V(2) and one Cd(1) atom. In the seventh O site, O(9) is bonded in a distorted bent 120 degrees geometry to one Cd(1) and one O(10) atom. In the eighth O site, O(10) is bonded in a single-bond geometry to one O(9) atom. is represented by the CIF card [CIF]
data_V2CdO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.989
_cell_length_b   8.493
_cell_length_c   8.493
_cell_angle_alpha   74.796
_cell_angle_beta   71.460
_cell_angle_gamma   71.460
_symmetry_Int_Tables_number   1
_cell_volume   445.816
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.541  0.390  0.324  1.0
  V  V1  1  0.041  0.324  0.390  1.0
  V  V2  1  0.943  0.114  0.176  1.0
  V  V3  1  0.443  0.176  0.114  1.0
  Cd  Cd4  1  0.747  0.748  0.252  1.0
  Cd  Cd5  1  0.247  0.252  0.748  1.0
  O  O6  1  0.569  0.583  0.224  1.0
  O  O7  1  0.069  0.224  0.583  1.0
  O  O8  1  0.914  0.529  0.401  1.0
  O  O9  1  0.414  0.401  0.529  1.0
  O  O10  1  0.668  0.231  0.154  1.0
  O  O11  1  0.168  0.154  0.231  1.0
  O  O12  1  0.813  0.266  0.355  1.0
  O  O13  1  0.313  0.355  0.266  1.0
  O  O14  1  0.564  0.968  0.116  1.0
  O  O15  1  0.064  0.116  0.968  1.0
  O  O16  1  0.931  0.915  0.266  1.0
  O  O17  1  0.431  0.266  0.915  1.0
  O  O18  1  0.107  0.693  0.965  1.0
  O  O19  1  0.607  0.965  0.693  1.0
  O  O20  1  0.787  0.936  0.704  1.0
  O  O21  1  0.287  0.704  0.936  1.0
  O  O22  1  0.397  0.784  0.534  1.0
  O  O23  1  0.897  0.534  0.784  1.0
  O  O24  1  0.721  0.544  0.776  1.0
  O  O25  1  0.221  0.776  0.544  1.0
[/CIF]
.