The material structure described by Ga3O5 crystallizes in the orthorhombic Pnma space group. There are three inequivalent Ga sites. In the first Ga site, Ga(1) is bonded to one O(2), one O(4), and two equivalent O(1) atoms to form GaO4 tetrahedra that share corners with four equivalent Ga(2)O6 octahedra and corners with three equivalent Ga(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 51-62°. In the second Ga site, Ga(2) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form GaO6 octahedra that share corners with four equivalent Ga(1)O4 tetrahedra, corners with four equivalent Ga(3)O4 tetrahedra, and edges with two equivalent Ga(2)O6 octahedra. In the third Ga site, Ga(3) is bonded to one O(3), one O(4), and two equivalent O(1) atoms to form GaO4 tetrahedra that share corners with four equivalent Ga(2)O6 octahedra and corners with three equivalent Ga(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 55-61°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Ga(1), one Ga(2), and one Ga(3) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Ga(1) and two equivalent Ga(2) atoms. In the third O site, O(3) is bonded in a trigonal planar geometry to one Ga(3) and two equivalent Ga(2) atoms. In the fourth O site, O(4) is bonded in a water-like geometry to one Ga(1) and one Ga(3) atom. is represented by the CIF card [CIF]
data_Ga3O5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.052
_cell_length_b   8.046
_cell_length_c   8.702
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   423.753
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.250  0.312  0.205  1.0
  Ga  Ga1  1  0.750  0.688  0.795  1.0
  Ga  Ga2  1  0.750  0.812  0.295  1.0
  Ga  Ga3  1  0.250  0.188  0.705  1.0
  Ga  Ga4  1  0.000  0.000  0.000  1.0
  Ga  Ga5  1  0.000  0.500  0.500  1.0
  Ga  Ga6  1  0.500  0.000  0.000  1.0
  Ga  Ga7  1  0.500  0.500  0.500  1.0
  Ga  Ga8  1  0.250  0.696  0.199  1.0
  Ga  Ga9  1  0.750  0.304  0.801  1.0
  Ga  Ga10  1  0.750  0.196  0.301  1.0
  Ga  Ga11  1  0.250  0.804  0.699  1.0
  O  O12  1  0.001  0.324  0.332  1.0
  O  O13  1  0.999  0.676  0.668  1.0
  O  O14  1  0.999  0.824  0.168  1.0
  O  O15  1  0.501  0.676  0.668  1.0
  O  O16  1  0.001  0.176  0.832  1.0
  O  O17  1  0.499  0.324  0.332  1.0
  O  O18  1  0.499  0.176  0.832  1.0
  O  O19  1  0.501  0.824  0.168  1.0
  O  O20  1  0.250  0.114  0.102  1.0
  O  O21  1  0.750  0.886  0.898  1.0
  O  O22  1  0.750  0.614  0.398  1.0
  O  O23  1  0.250  0.386  0.602  1.0
  O  O24  1  0.250  0.619  0.401  1.0
  O  O25  1  0.750  0.381  0.599  1.0
  O  O26  1  0.750  0.119  0.099  1.0
  O  O27  1  0.250  0.881  0.901  1.0
  O  O28  1  0.250  0.501  0.081  1.0
  O  O29  1  0.750  0.499  0.919  1.0
  O  O30  1  0.750  0.001  0.419  1.0
  O  O31  1  0.250  0.999  0.581  1.0
[/CIF]
.
The material structure described by Ga3O5 crystallizes in the orthorhombic Pnma space group. There are three inequivalent Ga sites. In the first Ga site, Ga(1) is bonded to one O(2), one O(4), and two equivalent O(1) atoms to form GaO4 tetrahedra that share corners with four equivalent Ga(2)O6 octahedra and corners with three equivalent Ga(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 51-62°. In the second Ga site, Ga(2) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form GaO6 octahedra that share corners with four equivalent Ga(1)O4 tetrahedra, corners with four equivalent Ga(3)O4 tetrahedra, and edges with two equivalent Ga(2)O6 octahedra. In the third Ga site, Ga(3) is bonded to one O(3), one O(4), and two equivalent O(1) atoms to form GaO4 tetrahedra that share corners with four equivalent Ga(2)O6 octahedra and corners with three equivalent Ga(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 55-61°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Ga(1), one Ga(2), and one Ga(3) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Ga(1) and two equivalent Ga(2) atoms. In the third O site, O(3) is bonded in a trigonal planar geometry to one Ga(3) and two equivalent Ga(2) atoms. In the fourth O site, O(4) is bonded in a water-like geometry to one Ga(1) and one Ga(3) atom. is represented by the CIF card [CIF]
data_Ga3O5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.052
_cell_length_b   8.046
_cell_length_c   8.702
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   423.753
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.250  0.312  0.205  1.0
  Ga  Ga1  1  0.750  0.688  0.795  1.0
  Ga  Ga2  1  0.750  0.812  0.295  1.0
  Ga  Ga3  1  0.250  0.188  0.705  1.0
  Ga  Ga4  1  0.000  0.000  0.000  1.0
  Ga  Ga5  1  0.000  0.500  0.500  1.0
  Ga  Ga6  1  0.500  0.000  0.000  1.0
  Ga  Ga7  1  0.500  0.500  0.500  1.0
  Ga  Ga8  1  0.250  0.696  0.199  1.0
  Ga  Ga9  1  0.750  0.304  0.801  1.0
  Ga  Ga10  1  0.750  0.196  0.301  1.0
  Ga  Ga11  1  0.250  0.804  0.699  1.0
  O  O12  1  0.001  0.324  0.332  1.0
  O  O13  1  0.999  0.676  0.668  1.0
  O  O14  1  0.999  0.824  0.168  1.0
  O  O15  1  0.501  0.676  0.668  1.0
  O  O16  1  0.001  0.176  0.832  1.0
  O  O17  1  0.499  0.324  0.332  1.0
  O  O18  1  0.499  0.176  0.832  1.0
  O  O19  1  0.501  0.824  0.168  1.0
  O  O20  1  0.250  0.114  0.102  1.0
  O  O21  1  0.750  0.886  0.898  1.0
  O  O22  1  0.750  0.614  0.398  1.0
  O  O23  1  0.250  0.386  0.602  1.0
  O  O24  1  0.250  0.619  0.401  1.0
  O  O25  1  0.750  0.381  0.599  1.0
  O  O26  1  0.750  0.119  0.099  1.0
  O  O27  1  0.250  0.881  0.901  1.0
  O  O28  1  0.250  0.501  0.081  1.0
  O  O29  1  0.750  0.499  0.919  1.0
  O  O30  1  0.750  0.001  0.419  1.0
  O  O31  1  0.250  0.999  0.581  1.0
[/CIF]
.