The material described by Sb2WO6 crystallizes in the monoclinic P2_1 space group. W(1) is bonded to one O(3), one O(4), two equivalent O(1), and two equivalent O(2) atoms to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 32-38°. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 5-coordinate geometry to one O(3), one O(4), one O(6), and two equivalent O(5) atoms. In the second Sb site, Sb(2) is bonded in a 5-coordinate geometry to one O(3), one O(4), one O(5), and two equivalent O(6) atoms. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to two equivalent W(1) atoms. In the second O site, O(2) is bonded in a bent 150 degrees geometry to two equivalent W(1) atoms. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one W(1), one Sb(1), and one Sb(2) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one W(1), one Sb(1), and one Sb(2) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Sb(2) and two equivalent Sb(1) atoms. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Sb(1) and two equivalent Sb(2) atoms. is represented by the CIF card [CIF]
data_Sb2WO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.975
_cell_length_b   5.558
_cell_length_c   9.254
_cell_angle_alpha   83.529
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   254.216
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.449  0.389  0.168  1.0
  Sb  Sb1  1  0.050  0.887  0.166  1.0
  Sb  Sb2  1  0.949  0.611  0.832  1.0
  Sb  Sb3  1  0.550  0.113  0.834  1.0
  W  W4  1  0.037  0.244  0.509  1.0
  W  W5  1  0.537  0.756  0.491  1.0
  O  O6  1  0.780  0.535  0.442  1.0
  O  O7  1  0.725  0.035  0.441  1.0
  O  O8  1  0.225  0.965  0.559  1.0
  O  O9  1  0.280  0.465  0.558  1.0
  O  O10  1  0.850  0.236  0.687  1.0
  O  O11  1  0.142  0.267  0.311  1.0
  O  O12  1  0.642  0.733  0.689  1.0
  O  O13  1  0.350  0.764  0.313  1.0
  O  O14  1  0.186  0.612  0.060  1.0
  O  O15  1  0.319  0.110  0.064  1.0
  O  O16  1  0.686  0.388  0.940  1.0
  O  O17  1  0.819  0.890  0.936  1.0
[/CIF]
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The material described by Sb2WO6 crystallizes in the monoclinic P2_1 space group. W(1) is bonded to one O(3), one O(4), two equivalent O(1), and two equivalent O(2) atoms to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 32-38°. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 5-coordinate geometry to one O(3), one O(4), one O(6), and two equivalent O(5) atoms. In the second Sb site, Sb(2) is bonded in a 5-coordinate geometry to one O(3), one O(4), one O(5), and two equivalent O(6) atoms. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to two equivalent W(1) atoms. In the second O site, O(2) is bonded in a bent 150 degrees geometry to two equivalent W(1) atoms. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one W(1), one Sb(1), and one Sb(2) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one W(1), one Sb(1), and one Sb(2) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Sb(2) and two equivalent Sb(1) atoms. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Sb(1) and two equivalent Sb(2) atoms. is represented by the CIF card [CIF]
data_Sb2WO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.975
_cell_length_b   5.558
_cell_length_c   9.254
_cell_angle_alpha   83.529
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   254.216
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.449  0.389  0.168  1.0
  Sb  Sb1  1  0.050  0.887  0.166  1.0
  Sb  Sb2  1  0.949  0.611  0.832  1.0
  Sb  Sb3  1  0.550  0.113  0.834  1.0
  W  W4  1  0.037  0.244  0.509  1.0
  W  W5  1  0.537  0.756  0.491  1.0
  O  O6  1  0.780  0.535  0.442  1.0
  O  O7  1  0.725  0.035  0.441  1.0
  O  O8  1  0.225  0.965  0.559  1.0
  O  O9  1  0.280  0.465  0.558  1.0
  O  O10  1  0.850  0.236  0.687  1.0
  O  O11  1  0.142  0.267  0.311  1.0
  O  O12  1  0.642  0.733  0.689  1.0
  O  O13  1  0.350  0.764  0.313  1.0
  O  O14  1  0.186  0.612  0.060  1.0
  O  O15  1  0.319  0.110  0.064  1.0
  O  O16  1  0.686  0.388  0.940  1.0
  O  O17  1  0.819  0.890  0.936  1.0
[/CIF]
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