The material described by LiVF4 crystallizes in the monoclinic C2/c space group. Li(1) is bonded in a square co-planar geometry to two equivalent F(1) and two equivalent F(2) atoms. V(1) is bonded to two equivalent F(2) and four equivalent F(1) atoms to form edge-sharing VF6 octahedra. There are two inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one Li(1) and two equivalent V(1) atoms. In the second F site, F(2) is bonded in a bent 120 degrees geometry to one Li(1) and one V(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiVF4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.184
_cell_length_b   6.184
_cell_length_c   5.121
_cell_angle_alpha   71.624
_cell_angle_beta   71.624
_cell_angle_gamma   58.810
_symmetry_Int_Tables_number   1
_cell_volume   156.187
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.000  0.500  0.000  1.0
  Li  Li1  1  0.500  0.000  0.500  1.0
  V  V2  1  0.150  0.850  0.250  1.0
  V  V3  1  0.850  0.150  0.750  1.0
  F  F4  1  0.790  0.008  0.174  1.0
  F  F5  1  0.208  0.543  0.187  1.0
  F  F6  1  0.008  0.790  0.674  1.0
  F  F7  1  0.543  0.208  0.687  1.0
  F  F8  1  0.792  0.457  0.813  1.0
  F  F9  1  0.210  0.992  0.826  1.0
  F  F10  1  0.457  0.792  0.313  1.0
  F  F11  1  0.992  0.210  0.326  1.0
[/CIF]
.
The material described by LiVF4 crystallizes in the monoclinic C2/c space group. Li(1) is bonded in a square co-planar geometry to two equivalent F(1) and two equivalent F(2) atoms. V(1) is bonded to two equivalent F(2) and four equivalent F(1) atoms to form edge-sharing VF6 octahedra. There are two inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one Li(1) and two equivalent V(1) atoms. In the second F site, F(2) is bonded in a bent 120 degrees geometry to one Li(1) and one V(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiVF4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.184
_cell_length_b   6.184
_cell_length_c   5.121
_cell_angle_alpha   71.624
_cell_angle_beta   71.624
_cell_angle_gamma   58.810
_symmetry_Int_Tables_number   1
_cell_volume   156.187
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.000  0.500  0.000  1.0
  Li  Li1  1  0.500  0.000  0.500  1.0
  V  V2  1  0.150  0.850  0.250  1.0
  V  V3  1  0.850  0.150  0.750  1.0
  F  F4  1  0.790  0.008  0.174  1.0
  F  F5  1  0.208  0.543  0.187  1.0
  F  F6  1  0.008  0.790  0.674  1.0
  F  F7  1  0.543  0.208  0.687  1.0
  F  F8  1  0.792  0.457  0.813  1.0
  F  F9  1  0.210  0.992  0.826  1.0
  F  F10  1  0.457  0.792  0.313  1.0
  F  F11  1  0.992  0.210  0.326  1.0
[/CIF]
.