The structure described by W6AgCCl18 crystallizes in the hexagonal P6_3/m space group. W(1) is bonded to one C(1), one Cl(1), one Cl(2), one Cl(3), and two equivalent Cl(4) atoms to form distorted WCCl5 octahedra that share  a cornercorner with one Ag(1)Cl6 octahedra, corners with two equivalent W(1)CCl5 octahedra, edges with two equivalent W(1)CCl5 octahedra, and  a faceface with one W(1)CCl5 octahedra. The corner-sharing octahedral tilt angles range from 42-50°. Ag(1) is bonded to six equivalent Cl(2) atoms to form AgCl6 octahedra that share corners with six equivalent W(1)CCl5 octahedra. The corner-sharing octahedral tilt angles are 50°. C(1) is bonded in a distorted pentagonal pyramidal geometry to six equivalent W(1) atoms. There are four inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in a distorted L-shaped geometry to two equivalent W(1) atoms. In the second Cl site, Cl(4) is bonded in a 2-coordinate geometry to two equivalent W(1) atoms. In the third Cl site, Cl(1) is bonded in a distorted L-shaped geometry to two equivalent W(1) atoms. In the fourth Cl site, Cl(2) is bonded in a bent 120 degrees geometry to one W(1) and one Ag(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_AgW6CCl18
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.091
_cell_length_b   9.091
_cell_length_c   17.800
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   1273.898
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.000  0.000  0.000  1.0
  Ag  Ag1  1  0.000  0.000  0.500  1.0
  W  W2  1  0.823  0.305  0.835  1.0
  W  W3  1  0.177  0.695  0.165  1.0
  W  W4  1  0.482  0.177  0.835  1.0
  W  W5  1  0.177  0.695  0.335  1.0
  W  W6  1  0.518  0.823  0.165  1.0
  W  W7  1  0.823  0.305  0.665  1.0
  W  W8  1  0.695  0.518  0.835  1.0
  W  W9  1  0.518  0.823  0.335  1.0
  W  W10  1  0.305  0.482  0.165  1.0
  W  W11  1  0.482  0.177  0.665  1.0
  W  W12  1  0.305  0.482  0.335  1.0
  W  W13  1  0.695  0.518  0.665  1.0
  C  C14  1  0.667  0.333  0.750  1.0
  C  C15  1  0.333  0.667  0.250  1.0
  Cl  Cl16  1  0.808  0.085  0.750  1.0
  Cl  Cl17  1  0.192  0.915  0.250  1.0
  Cl  Cl18  1  0.277  0.192  0.750  1.0
  Cl  Cl19  1  0.723  0.808  0.250  1.0
  Cl  Cl20  1  0.915  0.723  0.750  1.0
  Cl  Cl21  1  0.085  0.277  0.250  1.0
  Cl  Cl22  1  0.732  0.773  0.901  1.0
  Cl  Cl23  1  0.268  0.227  0.099  1.0
  Cl  Cl24  1  0.040  0.268  0.901  1.0
  Cl  Cl25  1  0.268  0.227  0.401  1.0
  Cl  Cl26  1  0.960  0.732  0.099  1.0
  Cl  Cl27  1  0.732  0.773  0.599  1.0
  Cl  Cl28  1  0.227  0.960  0.901  1.0
  Cl  Cl29  1  0.960  0.732  0.401  1.0
  Cl  Cl30  1  0.773  0.040  0.099  1.0
  Cl  Cl31  1  0.040  0.268  0.599  1.0
  Cl  Cl32  1  0.773  0.040  0.401  1.0
  Cl  Cl33  1  0.227  0.960  0.599  1.0
  Cl  Cl34  1  0.513  0.572  0.750  1.0
  Cl  Cl35  1  0.487  0.428  0.250  1.0
  Cl  Cl36  1  0.060  0.487  0.750  1.0
  Cl  Cl37  1  0.940  0.513  0.250  1.0
  Cl  Cl38  1  0.428  0.940  0.750  1.0
  Cl  Cl39  1  0.572  0.060  0.250  1.0
  Cl  Cl40  1  0.632  0.107  0.926  1.0
  Cl  Cl41  1  0.368  0.893  0.074  1.0
  Cl  Cl42  1  0.475  0.368  0.926  1.0
  Cl  Cl43  1  0.368  0.893  0.426  1.0
  Cl  Cl44  1  0.525  0.632  0.074  1.0
  Cl  Cl45  1  0.632  0.107  0.574  1.0
  Cl  Cl46  1  0.893  0.525  0.926  1.0
  Cl  Cl47  1  0.525  0.632  0.426  1.0
  Cl  Cl48  1  0.107  0.475  0.074  1.0
  Cl  Cl49  1  0.475  0.368  0.574  1.0
  Cl  Cl50  1  0.107  0.475  0.426  1.0
  Cl  Cl51  1  0.893  0.525  0.574  1.0
[/CIF]
.
The structure described by W6AgCCl18 crystallizes in the hexagonal P6_3/m space group. W(1) is bonded to one C(1), one Cl(1), one Cl(2), one Cl(3), and two equivalent Cl(4) atoms to form distorted WCCl5 octahedra that share  a cornercorner with one Ag(1)Cl6 octahedra, corners with two equivalent W(1)CCl5 octahedra, edges with two equivalent W(1)CCl5 octahedra, and  a faceface with one W(1)CCl5 octahedra. The corner-sharing octahedral tilt angles range from 42-50°. Ag(1) is bonded to six equivalent Cl(2) atoms to form AgCl6 octahedra that share corners with six equivalent W(1)CCl5 octahedra. The corner-sharing octahedral tilt angles are 50°. C(1) is bonded in a distorted pentagonal pyramidal geometry to six equivalent W(1) atoms. There are four inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in a distorted L-shaped geometry to two equivalent W(1) atoms. In the second Cl site, Cl(4) is bonded in a 2-coordinate geometry to two equivalent W(1) atoms. In the third Cl site, Cl(1) is bonded in a distorted L-shaped geometry to two equivalent W(1) atoms. In the fourth Cl site, Cl(2) is bonded in a bent 120 degrees geometry to one W(1) and one Ag(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_AgW6CCl18
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.091
_cell_length_b   9.091
_cell_length_c   17.800
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   1273.898
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.000  0.000  0.000  1.0
  Ag  Ag1  1  0.000  0.000  0.500  1.0
  W  W2  1  0.823  0.305  0.835  1.0
  W  W3  1  0.177  0.695  0.165  1.0
  W  W4  1  0.482  0.177  0.835  1.0
  W  W5  1  0.177  0.695  0.335  1.0
  W  W6  1  0.518  0.823  0.165  1.0
  W  W7  1  0.823  0.305  0.665  1.0
  W  W8  1  0.695  0.518  0.835  1.0
  W  W9  1  0.518  0.823  0.335  1.0
  W  W10  1  0.305  0.482  0.165  1.0
  W  W11  1  0.482  0.177  0.665  1.0
  W  W12  1  0.305  0.482  0.335  1.0
  W  W13  1  0.695  0.518  0.665  1.0
  C  C14  1  0.667  0.333  0.750  1.0
  C  C15  1  0.333  0.667  0.250  1.0
  Cl  Cl16  1  0.808  0.085  0.750  1.0
  Cl  Cl17  1  0.192  0.915  0.250  1.0
  Cl  Cl18  1  0.277  0.192  0.750  1.0
  Cl  Cl19  1  0.723  0.808  0.250  1.0
  Cl  Cl20  1  0.915  0.723  0.750  1.0
  Cl  Cl21  1  0.085  0.277  0.250  1.0
  Cl  Cl22  1  0.732  0.773  0.901  1.0
  Cl  Cl23  1  0.268  0.227  0.099  1.0
  Cl  Cl24  1  0.040  0.268  0.901  1.0
  Cl  Cl25  1  0.268  0.227  0.401  1.0
  Cl  Cl26  1  0.960  0.732  0.099  1.0
  Cl  Cl27  1  0.732  0.773  0.599  1.0
  Cl  Cl28  1  0.227  0.960  0.901  1.0
  Cl  Cl29  1  0.960  0.732  0.401  1.0
  Cl  Cl30  1  0.773  0.040  0.099  1.0
  Cl  Cl31  1  0.040  0.268  0.599  1.0
  Cl  Cl32  1  0.773  0.040  0.401  1.0
  Cl  Cl33  1  0.227  0.960  0.599  1.0
  Cl  Cl34  1  0.513  0.572  0.750  1.0
  Cl  Cl35  1  0.487  0.428  0.250  1.0
  Cl  Cl36  1  0.060  0.487  0.750  1.0
  Cl  Cl37  1  0.940  0.513  0.250  1.0
  Cl  Cl38  1  0.428  0.940  0.750  1.0
  Cl  Cl39  1  0.572  0.060  0.250  1.0
  Cl  Cl40  1  0.632  0.107  0.926  1.0
  Cl  Cl41  1  0.368  0.893  0.074  1.0
  Cl  Cl42  1  0.475  0.368  0.926  1.0
  Cl  Cl43  1  0.368  0.893  0.426  1.0
  Cl  Cl44  1  0.525  0.632  0.074  1.0
  Cl  Cl45  1  0.632  0.107  0.574  1.0
  Cl  Cl46  1  0.893  0.525  0.926  1.0
  Cl  Cl47  1  0.525  0.632  0.426  1.0
  Cl  Cl48  1  0.107  0.475  0.074  1.0
  Cl  Cl49  1  0.475  0.368  0.574  1.0
  Cl  Cl50  1  0.107  0.475  0.426  1.0
  Cl  Cl51  1  0.893  0.525  0.574  1.0
[/CIF]
.