The structure described by C2S2O2FCClF2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four chlorodifluoromethane molecules and four C2S2O2F clusters. In each C2S2O2F cluster, there are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one S(2) and one O(2) atom. In the second C site, C(3) is bonded in a distorted bent 120 degrees geometry to one S(1), one O(1), and one F(1) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one C(3) and one S(2) atom. In the second S site, S(2) is bonded in a water-like geometry to one C(1) and one S(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(3) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. F(1) is bonded in a single-bond geometry to one C(3) atom. is represented by the CIF card [CIF]
data_C3S2ClO2F3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   17.025
_cell_length_b   5.773
_cell_length_c   9.094
_cell_angle_alpha   68.639
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   832.352
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  C  C0  1  0.592  0.752  0.793  1.0
  C  C1  1  0.092  0.248  0.707  1.0
  C  C2  1  0.997  0.820  0.296  1.0
  C  C3  1  0.234  0.550  0.997  1.0
  C  C4  1  0.408  0.248  0.207  1.0
  C  C5  1  0.734  0.450  0.503  1.0
  C  C6  1  0.766  0.450  0.003  1.0
  C  C7  1  0.003  0.180  0.704  1.0
  C  C8  1  0.503  0.820  0.796  1.0
  C  C9  1  0.908  0.752  0.293  1.0
  C  C10  1  0.266  0.550  0.497  1.0
  C  C11  1  0.497  0.180  0.204  1.0
  S  S12  1  0.260  0.238  0.631  1.0
  S  S13  1  0.651  0.858  0.921  1.0
  S  S14  1  0.349  0.142  0.079  1.0
  S  S15  1  0.740  0.762  0.369  1.0
  S  S16  1  0.240  0.238  0.131  1.0
  S  S17  1  0.760  0.762  0.869  1.0
  S  S18  1  0.849  0.858  0.421  1.0
  S  S19  1  0.151  0.142  0.579  1.0
  Cl  Cl20  1  0.987  0.867  0.824  1.0
  Cl  Cl21  1  0.487  0.133  0.676  1.0
  Cl  Cl22  1  0.513  0.867  0.324  1.0
  Cl  Cl23  1  0.013  0.133  0.176  1.0
  O  O24  1  0.220  0.678  0.401  1.0
  O  O25  1  0.780  0.322  0.599  1.0
  O  O26  1  0.115  0.360  0.788  1.0
  O  O27  1  0.385  0.360  0.288  1.0
  O  O28  1  0.280  0.678  0.901  1.0
  O  O29  1  0.885  0.640  0.212  1.0
  O  O30  1  0.720  0.322  0.099  1.0
  O  O31  1  0.615  0.640  0.712  1.0
  F  F32  1  0.838  0.363  0.979  1.0
  F  F33  1  0.338  0.637  0.521  1.0
  F  F34  1  0.981  0.217  0.552  1.0
  F  F35  1  0.481  0.783  0.948  1.0
  F  F36  1  0.041  0.669  0.246  1.0
  F  F37  1  0.662  0.363  0.479  1.0
  F  F38  1  0.519  0.217  0.052  1.0
  F  F39  1  0.959  0.331  0.754  1.0
  F  F40  1  0.541  0.331  0.254  1.0
  F  F41  1  0.162  0.637  0.021  1.0
  F  F42  1  0.459  0.669  0.746  1.0
  F  F43  1  0.019  0.783  0.448  1.0
[/CIF]
.
The structure described by C2S2O2FCClF2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four chlorodifluoromethane molecules and four C2S2O2F clusters. In each C2S2O2F cluster, there are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one S(2) and one O(2) atom. In the second C site, C(3) is bonded in a distorted bent 120 degrees geometry to one S(1), one O(1), and one F(1) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one C(3) and one S(2) atom. In the second S site, S(2) is bonded in a water-like geometry to one C(1) and one S(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(3) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. F(1) is bonded in a single-bond geometry to one C(3) atom. is represented by the CIF card [CIF]
data_C3S2ClO2F3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   17.025
_cell_length_b   5.773
_cell_length_c   9.094
_cell_angle_alpha   68.639
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   832.352
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  C  C0  1  0.592  0.752  0.793  1.0
  C  C1  1  0.092  0.248  0.707  1.0
  C  C2  1  0.997  0.820  0.296  1.0
  C  C3  1  0.234  0.550  0.997  1.0
  C  C4  1  0.408  0.248  0.207  1.0
  C  C5  1  0.734  0.450  0.503  1.0
  C  C6  1  0.766  0.450  0.003  1.0
  C  C7  1  0.003  0.180  0.704  1.0
  C  C8  1  0.503  0.820  0.796  1.0
  C  C9  1  0.908  0.752  0.293  1.0
  C  C10  1  0.266  0.550  0.497  1.0
  C  C11  1  0.497  0.180  0.204  1.0
  S  S12  1  0.260  0.238  0.631  1.0
  S  S13  1  0.651  0.858  0.921  1.0
  S  S14  1  0.349  0.142  0.079  1.0
  S  S15  1  0.740  0.762  0.369  1.0
  S  S16  1  0.240  0.238  0.131  1.0
  S  S17  1  0.760  0.762  0.869  1.0
  S  S18  1  0.849  0.858  0.421  1.0
  S  S19  1  0.151  0.142  0.579  1.0
  Cl  Cl20  1  0.987  0.867  0.824  1.0
  Cl  Cl21  1  0.487  0.133  0.676  1.0
  Cl  Cl22  1  0.513  0.867  0.324  1.0
  Cl  Cl23  1  0.013  0.133  0.176  1.0
  O  O24  1  0.220  0.678  0.401  1.0
  O  O25  1  0.780  0.322  0.599  1.0
  O  O26  1  0.115  0.360  0.788  1.0
  O  O27  1  0.385  0.360  0.288  1.0
  O  O28  1  0.280  0.678  0.901  1.0
  O  O29  1  0.885  0.640  0.212  1.0
  O  O30  1  0.720  0.322  0.099  1.0
  O  O31  1  0.615  0.640  0.712  1.0
  F  F32  1  0.838  0.363  0.979  1.0
  F  F33  1  0.338  0.637  0.521  1.0
  F  F34  1  0.981  0.217  0.552  1.0
  F  F35  1  0.481  0.783  0.948  1.0
  F  F36  1  0.041  0.669  0.246  1.0
  F  F37  1  0.662  0.363  0.479  1.0
  F  F38  1  0.519  0.217  0.052  1.0
  F  F39  1  0.959  0.331  0.754  1.0
  F  F40  1  0.541  0.331  0.254  1.0
  F  F41  1  0.162  0.637  0.021  1.0
  F  F42  1  0.459  0.669  0.746  1.0
  F  F43  1  0.019  0.783  0.448  1.0
[/CIF]
.