The crystal structure described by RbAg3S2 crystallizes in the monoclinic C2/m space group. Rb(1) is bonded in a 6-coordinate geometry to one Ag(1), one Ag(2), two equivalent S(1), and two equivalent S(2) atoms. There are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 3-coordinate geometry to one Rb(1), one S(2), and two equivalent S(1) atoms. In the second Ag site, Ag(2) is bonded in a 2-coordinate geometry to one Rb(1), one S(2), and two equivalent S(1) atoms. In the third Ag site, Ag(3) is bonded in a 2-coordinate geometry to one S(1) and two equivalent S(2) atoms. There are two inequivalent S sites. In the first S site, S(1) is bonded in a 7-coordinate geometry to two equivalent Rb(1), one Ag(3), two equivalent Ag(1), and two equivalent Ag(2) atoms. In the second S site, S(2) is bonded in a 6-coordinate geometry to two equivalent Rb(1), one Ag(1), one Ag(2), and two equivalent Ag(3) atoms. is represented by the CIF file [CIF]
data_RbAg3S2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.430
_cell_length_b   9.430
_cell_length_c   9.961
_cell_angle_alpha   63.252
_cell_angle_beta   63.252
_cell_angle_gamma   26.687
_symmetry_Int_Tables_number   1
_cell_volume   352.721
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.854  0.854  0.189  1.0
  Rb  Rb1  1  0.146  0.146  0.811  1.0
  Ag  Ag2  1  0.091  0.091  0.509  1.0
  Ag  Ag3  1  0.947  0.947  0.773  1.0
  Ag  Ag4  1  0.909  0.909  0.491  1.0
  Ag  Ag5  1  0.636  0.636  0.274  1.0
  Ag  Ag6  1  0.364  0.364  0.726  1.0
  Ag  Ag7  1  0.053  0.053  0.227  1.0
  S  S8  1  0.527  0.527  0.725  1.0
  S  S9  1  0.204  0.204  0.249  1.0
  S  S10  1  0.796  0.796  0.751  1.0
  S  S11  1  0.473  0.473  0.275  1.0
[/CIF]
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The crystal structure described by RbAg3S2 crystallizes in the monoclinic C2/m space group. Rb(1) is bonded in a 6-coordinate geometry to one Ag(1), one Ag(2), two equivalent S(1), and two equivalent S(2) atoms. There are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 3-coordinate geometry to one Rb(1), one S(2), and two equivalent S(1) atoms. In the second Ag site, Ag(2) is bonded in a 2-coordinate geometry to one Rb(1), one S(2), and two equivalent S(1) atoms. In the third Ag site, Ag(3) is bonded in a 2-coordinate geometry to one S(1) and two equivalent S(2) atoms. There are two inequivalent S sites. In the first S site, S(1) is bonded in a 7-coordinate geometry to two equivalent Rb(1), one Ag(3), two equivalent Ag(1), and two equivalent Ag(2) atoms. In the second S site, S(2) is bonded in a 6-coordinate geometry to two equivalent Rb(1), one Ag(1), one Ag(2), and two equivalent Ag(3) atoms. is represented by the CIF file [CIF]
data_RbAg3S2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.430
_cell_length_b   9.430
_cell_length_c   9.961
_cell_angle_alpha   63.252
_cell_angle_beta   63.252
_cell_angle_gamma   26.687
_symmetry_Int_Tables_number   1
_cell_volume   352.721
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.854  0.854  0.189  1.0
  Rb  Rb1  1  0.146  0.146  0.811  1.0
  Ag  Ag2  1  0.091  0.091  0.509  1.0
  Ag  Ag3  1  0.947  0.947  0.773  1.0
  Ag  Ag4  1  0.909  0.909  0.491  1.0
  Ag  Ag5  1  0.636  0.636  0.274  1.0
  Ag  Ag6  1  0.364  0.364  0.726  1.0
  Ag  Ag7  1  0.053  0.053  0.227  1.0
  S  S8  1  0.527  0.527  0.725  1.0
  S  S9  1  0.204  0.204  0.249  1.0
  S  S10  1  0.796  0.796  0.751  1.0
  S  S11  1  0.473  0.473  0.275  1.0
[/CIF]
.