The structure described by LiAg2P3(HO5)2 crystallizes in the triclinic P-1 space group. Li(1) is bonded to one O(1), one O(10), one O(6), and one O(9) atom to form LiO4 tetrahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, and corners with two equivalent Ag(1)O5 trigonal bipyramids. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to one O(1), one O(2), one O(5), one O(6), and one O(8) atom to form distorted AgO5 trigonal bipyramids that share  a cornercorner with one P(2)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra, corners with two equivalent P(1)O4 tetrahedra, and corners with two equivalent P(3)O4 tetrahedra. In the second Ag site, Ag(2) is bonded in a 6-coordinate geometry to one O(10), one O(5), one O(8), one O(9), and two equivalent O(2) atoms. There are three inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form PO4 tetrahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, and corners with two equivalent Ag(1)O5 trigonal bipyramids. In the second P site, P(2) is bonded to one O(4), one O(7), one O(8), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, and  a cornercorner with one Ag(1)O5 trigonal bipyramid. In the third P site, P(3) is bonded to one O(3), one O(5), one O(6), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, and corners with two equivalent Ag(1)O5 trigonal bipyramids. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(10) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(10) atom. There are ten inequivalent O sites. In the first O site, O(9) is bonded in a distorted bent 150 degrees geometry to one Li(1), one Ag(2), and one P(2) atom. In the second O site, O(10) is bonded in a 4-coordinate geometry to one Li(1), one Ag(2), one H(1), and one H(2) atom. In the third O site, O(1) is bonded in a distorted trigonal planar geometry to one Li(1), one Ag(1), and one P(1) atom. In the fourth O site, O(2) is bonded in a 1-coordinate geometry to one Ag(1), two equivalent Ag(2), and one P(1) atom. In the fifth O site, O(3) is bonded in a bent 150 degrees geometry to one P(1) and one P(3) atom. In the sixth O site, O(4) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. In the seventh O site, O(5) is bonded in a distorted single-bond geometry to one Ag(1), one Ag(2), and one P(3) atom. In the eighth O site, O(6) is bonded in a 3-coordinate geometry to one Li(1), one Ag(1), and one P(3) atom. In the ninth O site, O(7) is bonded in a bent 150 degrees geometry to one P(2) and one P(3) atom. In the tenth O site, O(8) is bonded in a distorted single-bond geometry to one Ag(1), one Ag(2), and one P(2) atom. is represented by the CIF file [CIF]
data_LiAg2P3(HO5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.573
_cell_length_b   7.592
_cell_length_c   8.379
_cell_angle_alpha   72.825
_cell_angle_beta   73.961
_cell_angle_gamma   71.832
_symmetry_Int_Tables_number   1
_cell_volume   428.231
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.095  0.290  0.332  1.0
  Li  Li1  1  0.905  0.710  0.668  1.0
  Ag  Ag2  1  0.344  0.564  0.403  1.0
  Ag  Ag3  1  0.656  0.436  0.597  1.0
  Ag  Ag4  1  0.418  0.299  0.985  1.0
  Ag  Ag5  1  0.582  0.701  0.015  1.0
  P  P6  1  0.740  0.243  0.268  1.0
  P  P7  1  0.260  0.757  0.732  1.0
  P  P8  1  0.099  0.714  0.094  1.0
  P  P9  1  0.901  0.286  0.906  1.0
  P  P10  1  0.735  0.829  0.329  1.0
  P  P11  1  0.265  0.171  0.671  1.0
  H  H12  1  0.773  0.989  0.827  1.0
  H  H13  1  0.227  0.011  0.173  1.0
  H  H14  1  0.380  0.993  0.266  1.0
  H  H15  1  0.620  0.007  0.734  1.0
  O  O16  1  0.832  0.269  0.393  1.0
  O  O17  1  0.168  0.731  0.607  1.0
  O  O18  1  0.571  0.392  0.214  1.0
  O  O19  1  0.429  0.608  0.786  1.0
  O  O20  1  0.681  0.047  0.338  1.0
  O  O21  1  0.319  0.953  0.662  1.0
  O  O22  1  0.904  0.212  0.106  1.0
  O  O23  1  0.096  0.788  0.894  1.0
  O  O24  1  0.563  0.795  0.302  1.0
  O  O25  1  0.437  0.205  0.698  1.0
  O  O26  1  0.822  0.706  0.475  1.0
  O  O27  1  0.178  0.294  0.525  1.0
  O  O28  1  0.888  0.829  0.154  1.0
  O  O29  1  0.112  0.171  0.846  1.0
  O  O30  1  0.237  0.792  0.134  1.0
  O  O31  1  0.763  0.208  0.866  1.0
  O  O32  1  0.119  0.506  0.148  1.0
  O  O33  1  0.881  0.494  0.852  1.0
  O  O34  1  0.724  0.910  0.783  1.0
  O  O35  1  0.276  0.090  0.217  1.0
[/CIF]
.
The structure described by LiAg2P3(HO5)2 crystallizes in the triclinic P-1 space group. Li(1) is bonded to one O(1), one O(10), one O(6), and one O(9) atom to form LiO4 tetrahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, and corners with two equivalent Ag(1)O5 trigonal bipyramids. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to one O(1), one O(2), one O(5), one O(6), and one O(8) atom to form distorted AgO5 trigonal bipyramids that share  a cornercorner with one P(2)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra, corners with two equivalent P(1)O4 tetrahedra, and corners with two equivalent P(3)O4 tetrahedra. In the second Ag site, Ag(2) is bonded in a 6-coordinate geometry to one O(10), one O(5), one O(8), one O(9), and two equivalent O(2) atoms. There are three inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form PO4 tetrahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, and corners with two equivalent Ag(1)O5 trigonal bipyramids. In the second P site, P(2) is bonded to one O(4), one O(7), one O(8), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, and  a cornercorner with one Ag(1)O5 trigonal bipyramid. In the third P site, P(3) is bonded to one O(3), one O(5), one O(6), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, and corners with two equivalent Ag(1)O5 trigonal bipyramids. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(10) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(10) atom. There are ten inequivalent O sites. In the first O site, O(9) is bonded in a distorted bent 150 degrees geometry to one Li(1), one Ag(2), and one P(2) atom. In the second O site, O(10) is bonded in a 4-coordinate geometry to one Li(1), one Ag(2), one H(1), and one H(2) atom. In the third O site, O(1) is bonded in a distorted trigonal planar geometry to one Li(1), one Ag(1), and one P(1) atom. In the fourth O site, O(2) is bonded in a 1-coordinate geometry to one Ag(1), two equivalent Ag(2), and one P(1) atom. In the fifth O site, O(3) is bonded in a bent 150 degrees geometry to one P(1) and one P(3) atom. In the sixth O site, O(4) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. In the seventh O site, O(5) is bonded in a distorted single-bond geometry to one Ag(1), one Ag(2), and one P(3) atom. In the eighth O site, O(6) is bonded in a 3-coordinate geometry to one Li(1), one Ag(1), and one P(3) atom. In the ninth O site, O(7) is bonded in a bent 150 degrees geometry to one P(2) and one P(3) atom. In the tenth O site, O(8) is bonded in a distorted single-bond geometry to one Ag(1), one Ag(2), and one P(2) atom. is represented by the CIF file [CIF]
data_LiAg2P3(HO5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.573
_cell_length_b   7.592
_cell_length_c   8.379
_cell_angle_alpha   72.825
_cell_angle_beta   73.961
_cell_angle_gamma   71.832
_symmetry_Int_Tables_number   1
_cell_volume   428.231
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.095  0.290  0.332  1.0
  Li  Li1  1  0.905  0.710  0.668  1.0
  Ag  Ag2  1  0.344  0.564  0.403  1.0
  Ag  Ag3  1  0.656  0.436  0.597  1.0
  Ag  Ag4  1  0.418  0.299  0.985  1.0
  Ag  Ag5  1  0.582  0.701  0.015  1.0
  P  P6  1  0.740  0.243  0.268  1.0
  P  P7  1  0.260  0.757  0.732  1.0
  P  P8  1  0.099  0.714  0.094  1.0
  P  P9  1  0.901  0.286  0.906  1.0
  P  P10  1  0.735  0.829  0.329  1.0
  P  P11  1  0.265  0.171  0.671  1.0
  H  H12  1  0.773  0.989  0.827  1.0
  H  H13  1  0.227  0.011  0.173  1.0
  H  H14  1  0.380  0.993  0.266  1.0
  H  H15  1  0.620  0.007  0.734  1.0
  O  O16  1  0.832  0.269  0.393  1.0
  O  O17  1  0.168  0.731  0.607  1.0
  O  O18  1  0.571  0.392  0.214  1.0
  O  O19  1  0.429  0.608  0.786  1.0
  O  O20  1  0.681  0.047  0.338  1.0
  O  O21  1  0.319  0.953  0.662  1.0
  O  O22  1  0.904  0.212  0.106  1.0
  O  O23  1  0.096  0.788  0.894  1.0
  O  O24  1  0.563  0.795  0.302  1.0
  O  O25  1  0.437  0.205  0.698  1.0
  O  O26  1  0.822  0.706  0.475  1.0
  O  O27  1  0.178  0.294  0.525  1.0
  O  O28  1  0.888  0.829  0.154  1.0
  O  O29  1  0.112  0.171  0.846  1.0
  O  O30  1  0.237  0.792  0.134  1.0
  O  O31  1  0.763  0.208  0.866  1.0
  O  O32  1  0.119  0.506  0.148  1.0
  O  O33  1  0.881  0.494  0.852  1.0
  O  O34  1  0.724  0.910  0.783  1.0
  O  O35  1  0.276  0.090  0.217  1.0
[/CIF]
.