The material structure described by Dy2WO6 crystallizes in the orthorhombic P2_12_12_1 space group. There are two inequivalent Dy sites. In the first Dy site, Dy(1) is bonded in a 7-coordinate geometry to one O(2), one O(3), one O(4), one O(5), one O(6), and two equivalent O(1) atoms. In the second Dy site, Dy(2) is bonded to one O(2), one O(3), one O(4), two equivalent O(5), and two equivalent O(6) atoms to form distorted DyO7 hexagonal pyramids that share corners with three equivalent W(1)O6 octahedra, edges with two equivalent Dy(2)O7 hexagonal pyramids, and edges with two equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 38-46°. W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form WO6 octahedra that share corners with three equivalent Dy(2)O7 hexagonal pyramids and edges with two equivalent Dy(2)O7 hexagonal pyramids. There are six inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to two equivalent Dy(1) and one W(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Dy(1), one Dy(2), and one W(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Dy(1), one Dy(2), and one W(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal non-coplanar geometry to one Dy(1), one Dy(2), and one W(1) atom. In the fifth O site, O(5) is bonded to one Dy(1), two equivalent Dy(2), and one W(1) atom to form a mixture of distorted corner and edge-sharing ODy3W tetrahedra. In the sixth O site, O(6) is bonded to one Dy(1), two equivalent Dy(2), and one W(1) atom to form a mixture of corner and edge-sharing ODy3W tetrahedra. is represented by the CIF card [CIF]
data_Dy2WO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.219
_cell_length_b   9.050
_cell_length_c   9.888
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   467.050
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Dy  Dy0  1  0.019  0.397  0.034  1.0
  Dy  Dy1  1  0.038  0.280  0.628  1.0
  Dy  Dy2  1  0.462  0.720  0.128  1.0
  Dy  Dy3  1  0.481  0.603  0.534  1.0
  Dy  Dy4  1  0.519  0.103  0.966  1.0
  Dy  Dy5  1  0.538  0.220  0.372  1.0
  Dy  Dy6  1  0.962  0.780  0.872  1.0
  Dy  Dy7  1  0.981  0.897  0.466  1.0
  W  W8  1  0.039  0.005  0.153  1.0
  W  W9  1  0.461  0.995  0.653  1.0
  W  W10  1  0.539  0.495  0.847  1.0
  W  W11  1  0.961  0.505  0.347  1.0
  O  O12  1  0.083  0.656  0.470  1.0
  O  O13  1  0.176  0.547  0.203  1.0
  O  O14  1  0.181  0.863  0.681  1.0
  O  O15  1  0.193  0.860  0.264  1.0
  O  O16  1  0.231  0.386  0.432  1.0
  O  O17  1  0.252  0.090  0.506  1.0
  O  O18  1  0.248  0.910  0.006  1.0
  O  O19  1  0.269  0.614  0.932  1.0
  O  O20  1  0.307  0.140  0.764  1.0
  O  O21  1  0.319  0.137  0.181  1.0
  O  O22  1  0.324  0.453  0.703  1.0
  O  O23  1  0.417  0.344  0.970  1.0
  O  O24  1  0.583  0.844  0.530  1.0
  O  O25  1  0.676  0.953  0.797  1.0
  O  O26  1  0.681  0.637  0.319  1.0
  O  O27  1  0.693  0.640  0.736  1.0
  O  O28  1  0.731  0.114  0.568  1.0
  O  O29  1  0.752  0.410  0.494  1.0
  O  O30  1  0.748  0.590  0.994  1.0
  O  O31  1  0.769  0.886  0.068  1.0
  O  O32  1  0.807  0.360  0.236  1.0
  O  O33  1  0.819  0.363  0.819  1.0
  O  O34  1  0.824  0.047  0.297  1.0
  O  O35  1  0.917  0.156  0.030  1.0
[/CIF]
.
The material structure described by Dy2WO6 crystallizes in the orthorhombic P2_12_12_1 space group. There are two inequivalent Dy sites. In the first Dy site, Dy(1) is bonded in a 7-coordinate geometry to one O(2), one O(3), one O(4), one O(5), one O(6), and two equivalent O(1) atoms. In the second Dy site, Dy(2) is bonded to one O(2), one O(3), one O(4), two equivalent O(5), and two equivalent O(6) atoms to form distorted DyO7 hexagonal pyramids that share corners with three equivalent W(1)O6 octahedra, edges with two equivalent Dy(2)O7 hexagonal pyramids, and edges with two equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 38-46°. W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form WO6 octahedra that share corners with three equivalent Dy(2)O7 hexagonal pyramids and edges with two equivalent Dy(2)O7 hexagonal pyramids. There are six inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to two equivalent Dy(1) and one W(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Dy(1), one Dy(2), and one W(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Dy(1), one Dy(2), and one W(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal non-coplanar geometry to one Dy(1), one Dy(2), and one W(1) atom. In the fifth O site, O(5) is bonded to one Dy(1), two equivalent Dy(2), and one W(1) atom to form a mixture of distorted corner and edge-sharing ODy3W tetrahedra. In the sixth O site, O(6) is bonded to one Dy(1), two equivalent Dy(2), and one W(1) atom to form a mixture of corner and edge-sharing ODy3W tetrahedra. is represented by the CIF card [CIF]
data_Dy2WO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.219
_cell_length_b   9.050
_cell_length_c   9.888
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   467.050
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Dy  Dy0  1  0.019  0.397  0.034  1.0
  Dy  Dy1  1  0.038  0.280  0.628  1.0
  Dy  Dy2  1  0.462  0.720  0.128  1.0
  Dy  Dy3  1  0.481  0.603  0.534  1.0
  Dy  Dy4  1  0.519  0.103  0.966  1.0
  Dy  Dy5  1  0.538  0.220  0.372  1.0
  Dy  Dy6  1  0.962  0.780  0.872  1.0
  Dy  Dy7  1  0.981  0.897  0.466  1.0
  W  W8  1  0.039  0.005  0.153  1.0
  W  W9  1  0.461  0.995  0.653  1.0
  W  W10  1  0.539  0.495  0.847  1.0
  W  W11  1  0.961  0.505  0.347  1.0
  O  O12  1  0.083  0.656  0.470  1.0
  O  O13  1  0.176  0.547  0.203  1.0
  O  O14  1  0.181  0.863  0.681  1.0
  O  O15  1  0.193  0.860  0.264  1.0
  O  O16  1  0.231  0.386  0.432  1.0
  O  O17  1  0.252  0.090  0.506  1.0
  O  O18  1  0.248  0.910  0.006  1.0
  O  O19  1  0.269  0.614  0.932  1.0
  O  O20  1  0.307  0.140  0.764  1.0
  O  O21  1  0.319  0.137  0.181  1.0
  O  O22  1  0.324  0.453  0.703  1.0
  O  O23  1  0.417  0.344  0.970  1.0
  O  O24  1  0.583  0.844  0.530  1.0
  O  O25  1  0.676  0.953  0.797  1.0
  O  O26  1  0.681  0.637  0.319  1.0
  O  O27  1  0.693  0.640  0.736  1.0
  O  O28  1  0.731  0.114  0.568  1.0
  O  O29  1  0.752  0.410  0.494  1.0
  O  O30  1  0.748  0.590  0.994  1.0
  O  O31  1  0.769  0.886  0.068  1.0
  O  O32  1  0.807  0.360  0.236  1.0
  O  O33  1  0.819  0.363  0.819  1.0
  O  O34  1  0.824  0.047  0.297  1.0
  O  O35  1  0.917  0.156  0.030  1.0
[/CIF]
.