The compound described by Sb4N2Te3 crystallizes in the orthorhombic Pnma space group. There are three inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 2-coordinate geometry to two equivalent N(1) and four equivalent Te(2) atoms. In the second Sb site, Sb(2) is bonded in a 2-coordinate geometry to two equivalent N(1) and one Te(1) atom. In the third Sb site, Sb(3) is bonded in a distorted L-shaped geometry to two equivalent N(1), one Te(1), and two equivalent Te(2) atoms. N(1) is bonded to one Sb(1), one Sb(2), and two equivalent Sb(3) atoms to form edge-sharing NSb4 tetrahedra. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a 3-coordinate geometry to one Sb(2) and two equivalent Sb(3) atoms. In the second Te site, Te(2) is bonded in a distorted rectangular see-saw-like geometry to two equivalent Sb(1) and two equivalent Sb(3) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sb4Te3N2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.608
_cell_length_b   10.790
_cell_length_c   11.462
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   940.912
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.590  0.250  0.828  1.0
  Sb  Sb1  1  0.090  0.250  0.672  1.0
  Sb  Sb2  1  0.410  0.750  0.172  1.0
  Sb  Sb3  1  0.910  0.750  0.328  1.0
  Sb  Sb4  1  0.764  0.250  0.475  1.0
  Sb  Sb5  1  0.264  0.250  0.025  1.0
  Sb  Sb6  1  0.236  0.750  0.525  1.0
  Sb  Sb7  1  0.736  0.750  0.975  1.0
  Sb  Sb8  1  0.651  0.450  0.100  1.0
  Sb  Sb9  1  0.151  0.050  0.400  1.0
  Sb  Sb10  1  0.349  0.950  0.900  1.0
  Sb  Sb11  1  0.849  0.550  0.600  1.0
  Sb  Sb12  1  0.349  0.550  0.900  1.0
  Sb  Sb13  1  0.849  0.950  0.600  1.0
  Sb  Sb14  1  0.651  0.050  0.100  1.0
  Sb  Sb15  1  0.151  0.450  0.400  1.0
  Te  Te16  1  0.944  0.250  0.261  1.0
  Te  Te17  1  0.444  0.250  0.239  1.0
  Te  Te18  1  0.056  0.750  0.739  1.0
  Te  Te19  1  0.556  0.750  0.761  1.0
  Te  Te20  1  0.615  0.555  0.358  1.0
  Te  Te21  1  0.115  0.945  0.142  1.0
  Te  Te22  1  0.385  0.055  0.642  1.0
  Te  Te23  1  0.885  0.445  0.858  1.0
  Te  Te24  1  0.385  0.445  0.642  1.0
  Te  Te25  1  0.885  0.055  0.858  1.0
  Te  Te26  1  0.615  0.945  0.358  1.0
  Te  Te27  1  0.115  0.555  0.142  1.0
  N  N28  1  0.540  0.623  0.041  1.0
  N  N29  1  0.040  0.877  0.459  1.0
  N  N30  1  0.460  0.123  0.959  1.0
  N  N31  1  0.960  0.377  0.541  1.0
  N  N32  1  0.460  0.377  0.959  1.0
  N  N33  1  0.960  0.123  0.541  1.0
  N  N34  1  0.540  0.877  0.041  1.0
  N  N35  1  0.040  0.623  0.459  1.0
[/CIF]
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The compound described by Sb4N2Te3 crystallizes in the orthorhombic Pnma space group. There are three inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 2-coordinate geometry to two equivalent N(1) and four equivalent Te(2) atoms. In the second Sb site, Sb(2) is bonded in a 2-coordinate geometry to two equivalent N(1) and one Te(1) atom. In the third Sb site, Sb(3) is bonded in a distorted L-shaped geometry to two equivalent N(1), one Te(1), and two equivalent Te(2) atoms. N(1) is bonded to one Sb(1), one Sb(2), and two equivalent Sb(3) atoms to form edge-sharing NSb4 tetrahedra. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a 3-coordinate geometry to one Sb(2) and two equivalent Sb(3) atoms. In the second Te site, Te(2) is bonded in a distorted rectangular see-saw-like geometry to two equivalent Sb(1) and two equivalent Sb(3) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sb4Te3N2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.608
_cell_length_b   10.790
_cell_length_c   11.462
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   940.912
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.590  0.250  0.828  1.0
  Sb  Sb1  1  0.090  0.250  0.672  1.0
  Sb  Sb2  1  0.410  0.750  0.172  1.0
  Sb  Sb3  1  0.910  0.750  0.328  1.0
  Sb  Sb4  1  0.764  0.250  0.475  1.0
  Sb  Sb5  1  0.264  0.250  0.025  1.0
  Sb  Sb6  1  0.236  0.750  0.525  1.0
  Sb  Sb7  1  0.736  0.750  0.975  1.0
  Sb  Sb8  1  0.651  0.450  0.100  1.0
  Sb  Sb9  1  0.151  0.050  0.400  1.0
  Sb  Sb10  1  0.349  0.950  0.900  1.0
  Sb  Sb11  1  0.849  0.550  0.600  1.0
  Sb  Sb12  1  0.349  0.550  0.900  1.0
  Sb  Sb13  1  0.849  0.950  0.600  1.0
  Sb  Sb14  1  0.651  0.050  0.100  1.0
  Sb  Sb15  1  0.151  0.450  0.400  1.0
  Te  Te16  1  0.944  0.250  0.261  1.0
  Te  Te17  1  0.444  0.250  0.239  1.0
  Te  Te18  1  0.056  0.750  0.739  1.0
  Te  Te19  1  0.556  0.750  0.761  1.0
  Te  Te20  1  0.615  0.555  0.358  1.0
  Te  Te21  1  0.115  0.945  0.142  1.0
  Te  Te22  1  0.385  0.055  0.642  1.0
  Te  Te23  1  0.885  0.445  0.858  1.0
  Te  Te24  1  0.385  0.445  0.642  1.0
  Te  Te25  1  0.885  0.055  0.858  1.0
  Te  Te26  1  0.615  0.945  0.358  1.0
  Te  Te27  1  0.115  0.555  0.142  1.0
  N  N28  1  0.540  0.623  0.041  1.0
  N  N29  1  0.040  0.877  0.459  1.0
  N  N30  1  0.460  0.123  0.959  1.0
  N  N31  1  0.960  0.377  0.541  1.0
  N  N32  1  0.460  0.377  0.959  1.0
  N  N33  1  0.960  0.123  0.541  1.0
  N  N34  1  0.540  0.877  0.041  1.0
  N  N35  1  0.040  0.623  0.459  1.0
[/CIF]
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