The structure described by Cd(BF4)(BiF6) crystallizes in the monoclinic P2_1/c space group. Cd(1) is bonded in a 8-coordinate geometry to one F(1), one F(10), one F(2), one F(3), one F(4), one F(6), one F(7), and one F(8) atom. B(1) is bonded in a tetrahedral geometry to one F(1), one F(2), one F(3), and one F(4) atom. Bi(1) is bonded in an octahedral geometry to one F(10), one F(5), one F(6), one F(7), one F(8), and one F(9) atom. There are ten inequivalent F sites. In the first F site, F(6) is bonded in a bent 150 degrees geometry to one Cd(1) and one Bi(1) atom. In the second F site, F(7) is bonded in a distorted linear geometry to one Cd(1) and one Bi(1) atom. In the third F site, F(8) is bonded in a bent 150 degrees geometry to one Cd(1) and one Bi(1) atom. In the fourth F site, F(1) is bonded in a distorted single-bond geometry to one Cd(1) and one B(1) atom. In the fifth F site, F(9) is bonded in a single-bond geometry to one Bi(1) atom. In the sixth F site, F(2) is bonded in a distorted bent 150 degrees geometry to one Cd(1) and one B(1) atom. In the seventh F site, F(10) is bonded in a bent 150 degrees geometry to one Cd(1) and one Bi(1) atom. In the eighth F site, F(3) is bonded in a distorted single-bond geometry to one Cd(1) and one B(1) atom. In the ninth F site, F(4) is bonded in a distorted single-bond geometry to one Cd(1) and one B(1) atom. In the tenth F site, F(5) is bonded in a single-bond geometry to one Bi(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CdBiBF10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.620
_cell_length_b   8.574
_cell_length_c   9.235
_cell_angle_alpha   85.708
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   759.585
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.479  0.174  0.216  1.0
  Cd  Cd1  1  0.979  0.826  0.284  1.0
  Cd  Cd2  1  0.521  0.826  0.784  1.0
  Cd  Cd3  1  0.021  0.174  0.716  1.0
  Bi  Bi4  1  0.066  0.336  0.263  1.0
  Bi  Bi5  1  0.566  0.664  0.237  1.0
  Bi  Bi6  1  0.934  0.664  0.737  1.0
  Bi  Bi7  1  0.434  0.336  0.763  1.0
  B  B8  1  0.269  0.941  0.504  1.0
  B  B9  1  0.769  0.059  0.996  1.0
  B  B10  1  0.731  0.059  0.496  1.0
  B  B11  1  0.231  0.941  0.004  1.0
  F  F12  1  0.191  0.042  0.587  1.0
  F  F13  1  0.691  0.958  0.913  1.0
  F  F14  1  0.809  0.958  0.413  1.0
  F  F15  1  0.309  0.042  0.087  1.0
  F  F16  1  0.358  0.848  0.597  1.0
  F  F17  1  0.858  0.152  0.903  1.0
  F  F18  1  0.642  0.152  0.403  1.0
  F  F19  1  0.142  0.848  0.097  1.0
  F  F20  1  0.178  0.842  0.433  1.0
  F  F21  1  0.678  0.158  0.067  1.0
  F  F22  1  0.822  0.158  0.567  1.0
  F  F23  1  0.322  0.842  0.933  1.0
  F  F24  1  0.351  0.030  0.401  1.0
  F  F25  1  0.851  0.970  0.099  1.0
  F  F26  1  0.649  0.970  0.599  1.0
  F  F27  1  0.149  0.030  0.901  1.0
  F  F28  1  0.078  0.345  0.045  1.0
  F  F29  1  0.578  0.655  0.455  1.0
  F  F30  1  0.922  0.655  0.955  1.0
  F  F31  1  0.422  0.345  0.545  1.0
  F  F32  1  0.072  0.323  0.487  1.0
  F  F33  1  0.572  0.677  0.013  1.0
  F  F34  1  0.928  0.677  0.513  1.0
  F  F35  1  0.428  0.323  0.987  1.0
  F  F36  1  0.056  0.093  0.279  1.0
  F  F37  1  0.556  0.907  0.221  1.0
  F  F38  1  0.944  0.907  0.721  1.0
  F  F39  1  0.444  0.093  0.779  1.0
  F  F40  1  0.071  0.577  0.263  1.0
  F  F41  1  0.571  0.423  0.237  1.0
  F  F42  1  0.929  0.423  0.737  1.0
  F  F43  1  0.429  0.577  0.763  1.0
  F  F44  1  0.858  0.343  0.263  1.0
  F  F45  1  0.358  0.657  0.237  1.0
  F  F46  1  0.142  0.657  0.737  1.0
  F  F47  1  0.642  0.343  0.763  1.0
  F  F48  1  0.281  0.321  0.265  1.0
  F  F49  1  0.781  0.679  0.235  1.0
  F  F50  1  0.719  0.679  0.735  1.0
  F  F51  1  0.219  0.321  0.765  1.0
[/CIF]
.
The structure described by Cd(BF4)(BiF6) crystallizes in the monoclinic P2_1/c space group. Cd(1) is bonded in a 8-coordinate geometry to one F(1), one F(10), one F(2), one F(3), one F(4), one F(6), one F(7), and one F(8) atom. B(1) is bonded in a tetrahedral geometry to one F(1), one F(2), one F(3), and one F(4) atom. Bi(1) is bonded in an octahedral geometry to one F(10), one F(5), one F(6), one F(7), one F(8), and one F(9) atom. There are ten inequivalent F sites. In the first F site, F(6) is bonded in a bent 150 degrees geometry to one Cd(1) and one Bi(1) atom. In the second F site, F(7) is bonded in a distorted linear geometry to one Cd(1) and one Bi(1) atom. In the third F site, F(8) is bonded in a bent 150 degrees geometry to one Cd(1) and one Bi(1) atom. In the fourth F site, F(1) is bonded in a distorted single-bond geometry to one Cd(1) and one B(1) atom. In the fifth F site, F(9) is bonded in a single-bond geometry to one Bi(1) atom. In the sixth F site, F(2) is bonded in a distorted bent 150 degrees geometry to one Cd(1) and one B(1) atom. In the seventh F site, F(10) is bonded in a bent 150 degrees geometry to one Cd(1) and one Bi(1) atom. In the eighth F site, F(3) is bonded in a distorted single-bond geometry to one Cd(1) and one B(1) atom. In the ninth F site, F(4) is bonded in a distorted single-bond geometry to one Cd(1) and one B(1) atom. In the tenth F site, F(5) is bonded in a single-bond geometry to one Bi(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CdBiBF10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.620
_cell_length_b   8.574
_cell_length_c   9.235
_cell_angle_alpha   85.708
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   759.585
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.479  0.174  0.216  1.0
  Cd  Cd1  1  0.979  0.826  0.284  1.0
  Cd  Cd2  1  0.521  0.826  0.784  1.0
  Cd  Cd3  1  0.021  0.174  0.716  1.0
  Bi  Bi4  1  0.066  0.336  0.263  1.0
  Bi  Bi5  1  0.566  0.664  0.237  1.0
  Bi  Bi6  1  0.934  0.664  0.737  1.0
  Bi  Bi7  1  0.434  0.336  0.763  1.0
  B  B8  1  0.269  0.941  0.504  1.0
  B  B9  1  0.769  0.059  0.996  1.0
  B  B10  1  0.731  0.059  0.496  1.0
  B  B11  1  0.231  0.941  0.004  1.0
  F  F12  1  0.191  0.042  0.587  1.0
  F  F13  1  0.691  0.958  0.913  1.0
  F  F14  1  0.809  0.958  0.413  1.0
  F  F15  1  0.309  0.042  0.087  1.0
  F  F16  1  0.358  0.848  0.597  1.0
  F  F17  1  0.858  0.152  0.903  1.0
  F  F18  1  0.642  0.152  0.403  1.0
  F  F19  1  0.142  0.848  0.097  1.0
  F  F20  1  0.178  0.842  0.433  1.0
  F  F21  1  0.678  0.158  0.067  1.0
  F  F22  1  0.822  0.158  0.567  1.0
  F  F23  1  0.322  0.842  0.933  1.0
  F  F24  1  0.351  0.030  0.401  1.0
  F  F25  1  0.851  0.970  0.099  1.0
  F  F26  1  0.649  0.970  0.599  1.0
  F  F27  1  0.149  0.030  0.901  1.0
  F  F28  1  0.078  0.345  0.045  1.0
  F  F29  1  0.578  0.655  0.455  1.0
  F  F30  1  0.922  0.655  0.955  1.0
  F  F31  1  0.422  0.345  0.545  1.0
  F  F32  1  0.072  0.323  0.487  1.0
  F  F33  1  0.572  0.677  0.013  1.0
  F  F34  1  0.928  0.677  0.513  1.0
  F  F35  1  0.428  0.323  0.987  1.0
  F  F36  1  0.056  0.093  0.279  1.0
  F  F37  1  0.556  0.907  0.221  1.0
  F  F38  1  0.944  0.907  0.721  1.0
  F  F39  1  0.444  0.093  0.779  1.0
  F  F40  1  0.071  0.577  0.263  1.0
  F  F41  1  0.571  0.423  0.237  1.0
  F  F42  1  0.929  0.423  0.737  1.0
  F  F43  1  0.429  0.577  0.763  1.0
  F  F44  1  0.858  0.343  0.263  1.0
  F  F45  1  0.358  0.657  0.237  1.0
  F  F46  1  0.142  0.657  0.737  1.0
  F  F47  1  0.642  0.343  0.763  1.0
  F  F48  1  0.281  0.321  0.265  1.0
  F  F49  1  0.781  0.679  0.235  1.0
  F  F50  1  0.719  0.679  0.735  1.0
  F  F51  1  0.219  0.321  0.765  1.0
[/CIF]
.