The structure described by Li2VMnP2(O4F)2 crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded in a 4-coordinate geometry to one O(11), one O(13), one O(3), and one F(4) atom. In the second Li site, Li(2) is bonded in a 4-coordinate geometry to one O(11), one O(3), one O(5), and one F(2) atom. In the third Li site, Li(3) is bonded in a 4-coordinate geometry to one O(12), one O(14), one O(6), and one F(3) atom. In the fourth Li site, Li(4) is bonded in a 4-coordinate geometry to one O(14), one O(4), one O(6), and one F(1) atom. There are two inequivalent V sites. In the first V site, V(1) is bonded in a linear geometry to one O(1) and one O(16) atom. In the second V site, V(2) is bonded in a 10-coordinate geometry to two equivalent Mn(2), one O(10), one O(15), one O(2), one O(3), one O(6), one O(7), one F(1), and one F(2) atom. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a linear geometry to one O(8) and one O(9) atom. In the second Mn site, Mn(2) is bonded in a 10-coordinate geometry to two equivalent V(2), one O(10), one O(11), one O(14), one O(15), one O(2), one O(7), one F(3), and one F(4) atom. There are four inequivalent P sites. In the first P site, P(1) is bonded in a distorted single-bond geometry to one O(1), one O(2), one O(3), and one O(5) atom. In the second P site, P(2) is bonded in a distorted single-bond geometry to one O(4), one O(6), and one O(7) atom. In the third P site, P(3) is bonded in a distorted single-bond geometry to one O(10), one O(11), one O(13), and one O(9) atom. In the fourth P site, P(4) is bonded in a 1-coordinate geometry to one O(12), one O(14), one O(15), and one O(16) atom. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one V(1), one P(1), one O(13), and one O(5) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one V(2), one Mn(2), and one P(1) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Li(1), one Li(2), one V(2), and one P(1) atom. In the fourth O site, O(4) is bonded in a 1-coordinate geometry to one Li(4), one P(2), and one O(16) atom. In the fifth O site, O(5) is bonded in a 1-coordinate geometry to one Li(2), one P(1), one O(1), and one O(9) atom. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to one Li(3), one Li(4), one V(2), and one P(2) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one V(2), one Mn(2), and one P(2) atom. In the eighth O site, O(8) is bonded in a 1-coordinate geometry to one Mn(1) atom. In the ninth O site, O(9) is bonded in a 4-coordinate geometry to one Mn(1), one P(3), one O(13), and one O(5) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one V(2), one Mn(2), and one P(3) atom. In the eleventh O site, O(11) is bonded in a 4-coordinate geometry to one Li(1), one Li(2), one Mn(2), and one P(3) atom. In the twelfth O site, O(12) is bonded in a 2-coordinate geometry to one Li(3), one P(4), and one O(16) atom. In the thirteenth O site, O(13) is bonded in a 1-coordinate geometry to one Li(1), one P(3), one O(1), and one O(9) atom. In the fourteenth O site, O(14) is bonded in a 4-coordinate geometry to one Li(3), one Li(4), one Mn(2), and one P(4) atom. In the fifteenth O site, O(15) is bonded in a 3-coordinate geometry to one V(2), one Mn(2), and one P(4) atom. In the sixteenth O site, O(16) is bonded in a 4-coordinate geometry to one V(1), one P(4), one O(12), and one O(4) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a water-like geometry to one Li(4) and one V(2) atom. In the second F site, F(2) is bonded in a water-like geometry to one Li(2) and one V(2) atom. In the third F site, F(3) is bonded in a water-like geometry to one Li(3) and one Mn(2) atom. In the fourth F site, F(4) is bonded in a distorted water-like geometry to one Li(1) and one Mn(2) atom. is represented by the CIF file [CIF]
data_Li2MnVP2(O4F)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.430
_cell_length_b   5.352
_cell_length_c   7.479
_cell_angle_alpha   108.951
_cell_angle_beta   105.735
_cell_angle_gamma   97.533
_symmetry_Int_Tables_number   1
_cell_volume   368.905
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.813  0.041  0.430  1.0
  Li  Li1  1  0.811  0.540  0.428  1.0
  Li  Li2  1  0.188  0.460  0.574  1.0
  Li  Li3  1  0.188  0.958  0.570  1.0
  Mn  Mn4  1  0.999  0.499  0.001  1.0
  Mn  Mn5  1  0.500  0.749  0.500  1.0
  V  V6  1  0.003  0.002  0.001  1.0
  V  V7  1  0.498  0.250  0.498  1.0
  P  P8  1  0.762  0.221  0.119  1.0
  P  P9  1  0.235  0.279  0.878  1.0
  P  P10  1  0.763  0.722  0.119  1.0
  P  P11  1  0.240  0.778  0.882  1.0
  O  O12  1  0.914  0.143  0.162  1.0
  O  O13  1  0.613  0.182  0.826  1.0
  O  O14  1  0.657  0.177  0.316  1.0
  O  O15  1  0.115  0.121  0.780  1.0
  O  O16  1  0.883  0.380  0.218  1.0
  O  O17  1  0.340  0.323  0.682  1.0
  O  O18  1  0.383  0.318  0.171  1.0
  O  O19  1  0.081  0.357  0.834  1.0
  O  O20  1  0.912  0.640  0.160  1.0
  O  O21  1  0.614  0.684  0.826  1.0
  O  O22  1  0.661  0.680  0.321  1.0
  O  O23  1  0.115  0.620  0.783  1.0
  O  O24  1  0.888  0.880  0.218  1.0
  O  O25  1  0.343  0.822  0.682  1.0
  O  O26  1  0.389  0.816  0.177  1.0
  O  O27  1  0.092  0.860  0.844  1.0
  F  F28  1  0.264  0.068  0.337  1.0
  F  F29  1  0.725  0.430  0.650  1.0
  F  F30  1  0.265  0.560  0.342  1.0
  F  F31  1  0.747  0.940  0.672  1.0
[/CIF]
.
The structure described by Li2VMnP2(O4F)2 crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded in a 4-coordinate geometry to one O(11), one O(13), one O(3), and one F(4) atom. In the second Li site, Li(2) is bonded in a 4-coordinate geometry to one O(11), one O(3), one O(5), and one F(2) atom. In the third Li site, Li(3) is bonded in a 4-coordinate geometry to one O(12), one O(14), one O(6), and one F(3) atom. In the fourth Li site, Li(4) is bonded in a 4-coordinate geometry to one O(14), one O(4), one O(6), and one F(1) atom. There are two inequivalent V sites. In the first V site, V(1) is bonded in a linear geometry to one O(1) and one O(16) atom. In the second V site, V(2) is bonded in a 10-coordinate geometry to two equivalent Mn(2), one O(10), one O(15), one O(2), one O(3), one O(6), one O(7), one F(1), and one F(2) atom. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a linear geometry to one O(8) and one O(9) atom. In the second Mn site, Mn(2) is bonded in a 10-coordinate geometry to two equivalent V(2), one O(10), one O(11), one O(14), one O(15), one O(2), one O(7), one F(3), and one F(4) atom. There are four inequivalent P sites. In the first P site, P(1) is bonded in a distorted single-bond geometry to one O(1), one O(2), one O(3), and one O(5) atom. In the second P site, P(2) is bonded in a distorted single-bond geometry to one O(4), one O(6), and one O(7) atom. In the third P site, P(3) is bonded in a distorted single-bond geometry to one O(10), one O(11), one O(13), and one O(9) atom. In the fourth P site, P(4) is bonded in a 1-coordinate geometry to one O(12), one O(14), one O(15), and one O(16) atom. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one V(1), one P(1), one O(13), and one O(5) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one V(2), one Mn(2), and one P(1) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Li(1), one Li(2), one V(2), and one P(1) atom. In the fourth O site, O(4) is bonded in a 1-coordinate geometry to one Li(4), one P(2), and one O(16) atom. In the fifth O site, O(5) is bonded in a 1-coordinate geometry to one Li(2), one P(1), one O(1), and one O(9) atom. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to one Li(3), one Li(4), one V(2), and one P(2) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one V(2), one Mn(2), and one P(2) atom. In the eighth O site, O(8) is bonded in a 1-coordinate geometry to one Mn(1) atom. In the ninth O site, O(9) is bonded in a 4-coordinate geometry to one Mn(1), one P(3), one O(13), and one O(5) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one V(2), one Mn(2), and one P(3) atom. In the eleventh O site, O(11) is bonded in a 4-coordinate geometry to one Li(1), one Li(2), one Mn(2), and one P(3) atom. In the twelfth O site, O(12) is bonded in a 2-coordinate geometry to one Li(3), one P(4), and one O(16) atom. In the thirteenth O site, O(13) is bonded in a 1-coordinate geometry to one Li(1), one P(3), one O(1), and one O(9) atom. In the fourteenth O site, O(14) is bonded in a 4-coordinate geometry to one Li(3), one Li(4), one Mn(2), and one P(4) atom. In the fifteenth O site, O(15) is bonded in a 3-coordinate geometry to one V(2), one Mn(2), and one P(4) atom. In the sixteenth O site, O(16) is bonded in a 4-coordinate geometry to one V(1), one P(4), one O(12), and one O(4) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a water-like geometry to one Li(4) and one V(2) atom. In the second F site, F(2) is bonded in a water-like geometry to one Li(2) and one V(2) atom. In the third F site, F(3) is bonded in a water-like geometry to one Li(3) and one Mn(2) atom. In the fourth F site, F(4) is bonded in a distorted water-like geometry to one Li(1) and one Mn(2) atom. is represented by the CIF file [CIF]
data_Li2MnVP2(O4F)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.430
_cell_length_b   5.352
_cell_length_c   7.479
_cell_angle_alpha   108.951
_cell_angle_beta   105.735
_cell_angle_gamma   97.533
_symmetry_Int_Tables_number   1
_cell_volume   368.905
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.813  0.041  0.430  1.0
  Li  Li1  1  0.811  0.540  0.428  1.0
  Li  Li2  1  0.188  0.460  0.574  1.0
  Li  Li3  1  0.188  0.958  0.570  1.0
  Mn  Mn4  1  0.999  0.499  0.001  1.0
  Mn  Mn5  1  0.500  0.749  0.500  1.0
  V  V6  1  0.003  0.002  0.001  1.0
  V  V7  1  0.498  0.250  0.498  1.0
  P  P8  1  0.762  0.221  0.119  1.0
  P  P9  1  0.235  0.279  0.878  1.0
  P  P10  1  0.763  0.722  0.119  1.0
  P  P11  1  0.240  0.778  0.882  1.0
  O  O12  1  0.914  0.143  0.162  1.0
  O  O13  1  0.613  0.182  0.826  1.0
  O  O14  1  0.657  0.177  0.316  1.0
  O  O15  1  0.115  0.121  0.780  1.0
  O  O16  1  0.883  0.380  0.218  1.0
  O  O17  1  0.340  0.323  0.682  1.0
  O  O18  1  0.383  0.318  0.171  1.0
  O  O19  1  0.081  0.357  0.834  1.0
  O  O20  1  0.912  0.640  0.160  1.0
  O  O21  1  0.614  0.684  0.826  1.0
  O  O22  1  0.661  0.680  0.321  1.0
  O  O23  1  0.115  0.620  0.783  1.0
  O  O24  1  0.888  0.880  0.218  1.0
  O  O25  1  0.343  0.822  0.682  1.0
  O  O26  1  0.389  0.816  0.177  1.0
  O  O27  1  0.092  0.860  0.844  1.0
  F  F28  1  0.264  0.068  0.337  1.0
  F  F29  1  0.725  0.430  0.650  1.0
  F  F30  1  0.265  0.560  0.342  1.0
  F  F31  1  0.747  0.940  0.672  1.0
[/CIF]
.