The material structure described by Li3Co(BO2)5 crystallizes in the triclinic P-1 space group. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded in a 4-coordinate geometry to one O(3), one O(5), one O(7), and one O(9) atom. In the second Li site, Li(2) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(10), one O(4), and one O(6) atom. In the third Li site, Li(3) is bonded in a 5-coordinate geometry to one O(4), one O(7), one O(8), and two equivalent O(2) atoms. Co(1) is bonded in a 6-coordinate geometry to one O(1), one O(3), one O(4), one O(6), and two equivalent O(5) atoms. There are five inequivalent B sites. In the first B site, B(1) is bonded in a trigonal planar geometry to one O(1), one O(10), and one O(3) atom. In the second B site, B(2) is bonded in a tetrahedral geometry to one O(2), one O(3), one O(6), and one O(8) atom. In the third B site, B(3) is bonded in a trigonal planar geometry to one O(2), one O(4), and one O(9) atom. In the fourth B site, B(4) is bonded in a trigonal planar geometry to one O(10), one O(5), and one O(8) atom. In the fifth B site, B(5) is bonded in a trigonal planar geometry to one O(6), one O(7), and one O(9) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a 1-coordinate geometry to one Li(2), one Co(1), and one B(1) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to two equivalent Li(3), one B(2), and one B(3) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Li(1), one Co(1), one B(1), and one B(2) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Li(2), one Li(3), one Co(1), and one B(3) atom. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to one Li(1), two equivalent Co(1), and one B(4) atom. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to one Li(2), one Co(1), one B(2), and one B(5) atom. In the seventh O site, O(7) is bonded in a trigonal planar geometry to one Li(1), one Li(3), and one B(5) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one Li(3), one B(2), and one B(4) atom. In the ninth O site, O(9) is bonded in a distorted trigonal planar geometry to one Li(1), one B(3), and one B(5) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Li(2), one B(1), and one B(4) atom. is represented by the CIF card [CIF]
data_Li3Co(BO2)5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.947
_cell_length_b   7.097
_cell_length_c   9.377
_cell_angle_alpha   80.170
_cell_angle_beta   68.946
_cell_angle_gamma   61.830
_symmetry_Int_Tables_number   1
_cell_volume   380.364
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.241  0.493  0.249  1.0
  Li  Li1  1  0.816  0.992  0.163  1.0
  Li  Li2  1  0.020  0.193  0.464  1.0
  Li  Li3  1  0.980  0.807  0.536  1.0
  Li  Li4  1  0.184  0.008  0.837  1.0
  Li  Li5  1  0.759  0.507  0.751  1.0
  Co  Co6  1  0.214  0.523  0.884  1.0
  Co  Co7  1  0.786  0.477  0.116  1.0
  B  B8  1  0.304  0.804  0.074  1.0
  B  B9  1  0.410  0.859  0.290  1.0
  B  B10  1  0.363  0.750  0.568  1.0
  B  B11  1  0.216  0.168  0.132  1.0
  B  B12  1  0.744  0.716  0.397  1.0
  B  B13  1  0.256  0.284  0.603  1.0
  B  B14  1  0.784  0.832  0.868  1.0
  B  B15  1  0.637  0.250  0.432  1.0
  B  B16  1  0.590  0.141  0.710  1.0
  B  B17  1  0.696  0.196  0.926  1.0
  O  O18  1  0.270  0.694  0.995  1.0
  O  O19  1  0.272  0.842  0.448  1.0
  O  O20  1  0.409  0.720  0.188  1.0
  O  O21  1  0.219  0.740  0.706  1.0
  O  O22  1  0.130  0.380  0.099  1.0
  O  O23  1  0.656  0.784  0.273  1.0
  O  O24  1  0.047  0.306  0.622  1.0
  O  O25  1  0.694  0.911  0.750  1.0
  O  O26  1  0.600  0.682  0.540  1.0
  O  O27  1  0.779  0.974  0.958  1.0
  O  O28  1  0.221  0.026  0.042  1.0
  O  O29  1  0.400  0.318  0.460  1.0
  O  O30  1  0.306  0.089  0.250  1.0
  O  O31  1  0.953  0.694  0.378  1.0
  O  O32  1  0.344  0.216  0.727  1.0
  O  O33  1  0.870  0.620  0.901  1.0
  O  O34  1  0.781  0.260  0.294  1.0
  O  O35  1  0.591  0.280  0.812  1.0
  O  O36  1  0.728  0.158  0.552  1.0
  O  O37  1  0.730  0.306  0.005  1.0
[/CIF]
.
The material structure described by Li3Co(BO2)5 crystallizes in the triclinic P-1 space group. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded in a 4-coordinate geometry to one O(3), one O(5), one O(7), and one O(9) atom. In the second Li site, Li(2) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(10), one O(4), and one O(6) atom. In the third Li site, Li(3) is bonded in a 5-coordinate geometry to one O(4), one O(7), one O(8), and two equivalent O(2) atoms. Co(1) is bonded in a 6-coordinate geometry to one O(1), one O(3), one O(4), one O(6), and two equivalent O(5) atoms. There are five inequivalent B sites. In the first B site, B(1) is bonded in a trigonal planar geometry to one O(1), one O(10), and one O(3) atom. In the second B site, B(2) is bonded in a tetrahedral geometry to one O(2), one O(3), one O(6), and one O(8) atom. In the third B site, B(3) is bonded in a trigonal planar geometry to one O(2), one O(4), and one O(9) atom. In the fourth B site, B(4) is bonded in a trigonal planar geometry to one O(10), one O(5), and one O(8) atom. In the fifth B site, B(5) is bonded in a trigonal planar geometry to one O(6), one O(7), and one O(9) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a 1-coordinate geometry to one Li(2), one Co(1), and one B(1) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to two equivalent Li(3), one B(2), and one B(3) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Li(1), one Co(1), one B(1), and one B(2) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Li(2), one Li(3), one Co(1), and one B(3) atom. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to one Li(1), two equivalent Co(1), and one B(4) atom. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to one Li(2), one Co(1), one B(2), and one B(5) atom. In the seventh O site, O(7) is bonded in a trigonal planar geometry to one Li(1), one Li(3), and one B(5) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one Li(3), one B(2), and one B(4) atom. In the ninth O site, O(9) is bonded in a distorted trigonal planar geometry to one Li(1), one B(3), and one B(5) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Li(2), one B(1), and one B(4) atom. is represented by the CIF card [CIF]
data_Li3Co(BO2)5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.947
_cell_length_b   7.097
_cell_length_c   9.377
_cell_angle_alpha   80.170
_cell_angle_beta   68.946
_cell_angle_gamma   61.830
_symmetry_Int_Tables_number   1
_cell_volume   380.364
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.241  0.493  0.249  1.0
  Li  Li1  1  0.816  0.992  0.163  1.0
  Li  Li2  1  0.020  0.193  0.464  1.0
  Li  Li3  1  0.980  0.807  0.536  1.0
  Li  Li4  1  0.184  0.008  0.837  1.0
  Li  Li5  1  0.759  0.507  0.751  1.0
  Co  Co6  1  0.214  0.523  0.884  1.0
  Co  Co7  1  0.786  0.477  0.116  1.0
  B  B8  1  0.304  0.804  0.074  1.0
  B  B9  1  0.410  0.859  0.290  1.0
  B  B10  1  0.363  0.750  0.568  1.0
  B  B11  1  0.216  0.168  0.132  1.0
  B  B12  1  0.744  0.716  0.397  1.0
  B  B13  1  0.256  0.284  0.603  1.0
  B  B14  1  0.784  0.832  0.868  1.0
  B  B15  1  0.637  0.250  0.432  1.0
  B  B16  1  0.590  0.141  0.710  1.0
  B  B17  1  0.696  0.196  0.926  1.0
  O  O18  1  0.270  0.694  0.995  1.0
  O  O19  1  0.272  0.842  0.448  1.0
  O  O20  1  0.409  0.720  0.188  1.0
  O  O21  1  0.219  0.740  0.706  1.0
  O  O22  1  0.130  0.380  0.099  1.0
  O  O23  1  0.656  0.784  0.273  1.0
  O  O24  1  0.047  0.306  0.622  1.0
  O  O25  1  0.694  0.911  0.750  1.0
  O  O26  1  0.600  0.682  0.540  1.0
  O  O27  1  0.779  0.974  0.958  1.0
  O  O28  1  0.221  0.026  0.042  1.0
  O  O29  1  0.400  0.318  0.460  1.0
  O  O30  1  0.306  0.089  0.250  1.0
  O  O31  1  0.953  0.694  0.378  1.0
  O  O32  1  0.344  0.216  0.727  1.0
  O  O33  1  0.870  0.620  0.901  1.0
  O  O34  1  0.781  0.260  0.294  1.0
  O  O35  1  0.591  0.280  0.812  1.0
  O  O36  1  0.728  0.158  0.552  1.0
  O  O37  1  0.730  0.306  0.005  1.0
[/CIF]
.