The crystal structure described by (SmN2H3O9)2H2(NH2O3)2(H2O2)2O2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 1333-74-0 atoms, two water atoms, two H2O2 clusters, two NH2O3 clusters, and one SmN2H3O9 cluster. In each H2O2 cluster, there are two inequivalent H sites. In the first H site, H(1) is bonded in a 2-coordinate geometry to one O(10) and one O(14) atom. In the second H site, H(2) is bonded in a distorted single-bond geometry to one O(10) and one O(14) atom. There are two inequivalent O sites. In the first O site, O(14) is bonded in a distorted single-bond geometry to one H(1) and one H(2) atom. In the second O site, O(10) is bonded in a 2-coordinate geometry to one H(1) and one H(2) atom. In each NH2O3 cluster, N(3) is bonded in a distorted single-bond geometry to one O(15) and one O(9) atom. There are two inequivalent H sites. In the first H site, H(7) is bonded in a single-bond geometry to one O(13) atom. In the second H site, H(8) is bonded in a distorted single-bond geometry to one O(13) atom. There are three inequivalent O sites. In the first O site, O(9) is bonded in a single-bond geometry to one N(3) and one O(15) atom. In the second O site, O(13) is bonded in a distorted single-bond geometry to one H(7), one H(8), and one O(15) atom. In the third O site, O(15) is bonded in a distorted bent 150 degrees geometry to one N(3), one O(13), and one O(9) atom. In the SmN2H3O9 cluster, Sm(1) is bonded in a distorted single-bond geometry to one H(4), one O(11), one O(6), one O(7), and one O(8) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 1-coordinate geometry to one O(1) and one O(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(4), one O(5), and one O(6) atom. There are three inequivalent H sites. In the first H site, H(4) is bonded in a distorted single-bond geometry to one Sm(1) and one O(11) atom. In the second H site, H(5) is bonded in a 3-coordinate geometry to one H(6), one O(12), and one O(6) atom. In the third H site, H(6) is bonded in a single-bond geometry to one H(5) and one O(12) atom. There are nine inequivalent O sites. In the first O site, O(5) is bonded in a single-bond geometry to one N(2) atom. In the second O site, O(6) is bonded in a 3-coordinate geometry to one Sm(1), one N(2), and one H(5) atom. In the third O site, O(7) is bonded in an L-shaped geometry to one Sm(1) and one O(4) atom. In the fourth O site, O(8) is bonded in a 2-coordinate geometry to one Sm(1) and one O(2) atom. In the fifth O site, O(11) is bonded in a 2-coordinate geometry to one Sm(1) and one H(4) atom. In the sixth O site, O(12) is bonded in a distorted single-bond geometry to one H(5) and one H(6) atom. In the seventh O site, O(1) is bonded in a 1-coordinate geometry to one N(1) atom. In the eighth O site, O(2) is bonded in a single-bond geometry to one N(1) and one O(8) atom. In the ninth O site, O(4) is bonded in a distorted single-bond geometry to one N(2) and one O(7) atom. is represented by the CIF card [CIF]
data_SmH8(NO5)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.806
_cell_length_b   8.827
_cell_length_c   12.030
_cell_angle_alpha   111.299
_cell_angle_beta   91.113
_cell_angle_gamma   110.419
_symmetry_Int_Tables_number   1
_cell_volume   622.135
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sm  Sm0  1  0.205  0.047  0.276  1.0
  Sm  Sm1  1  0.795  0.953  0.724  1.0
  H  H2  1  0.551  0.397  0.485  1.0
  H  H3  1  0.449  0.603  0.515  1.0
  H  H4  1  0.785  0.509  0.504  1.0
  H  H5  1  0.215  0.491  0.496  1.0
  H  H6  1  0.358  0.773  0.272  1.0
  H  H7  1  0.642  0.227  0.728  1.0
  H  H8  1  0.336  0.032  0.131  1.0
  H  H9  1  0.664  0.968  0.869  1.0
  H  H10  1  0.705  0.143  0.350  1.0
  H  H11  1  0.295  0.857  0.650  1.0
  H  H12  1  0.639  0.093  0.272  1.0
  H  H13  1  0.361  0.907  0.728  1.0
  H  H14  1  0.575  0.477  0.936  1.0
  H  H15  1  0.425  0.523  0.064  1.0
  H  H16  1  0.786  0.505  0.007  1.0
  H  H17  1  0.214  0.495  0.993  1.0
  N  N18  1  0.070  0.476  0.173  1.0
  N  N19  1  0.930  0.524  0.827  1.0
  N  N20  1  0.091  0.833  0.500  1.0
  N  N21  1  0.909  0.167  0.500  1.0
  N  N22  1  0.822  0.896  0.185  1.0
  N  N23  1  0.178  0.104  0.815  1.0
  O  O24  1  0.254  0.415  0.234  1.0
  O  O25  1  0.746  0.585  0.766  1.0
  O  O26  1  0.943  0.344  0.162  1.0
  O  O27  1  0.057  0.656  0.838  1.0
  O  O28  1  0.012  0.657  0.126  1.0
  O  O29  1  0.988  0.343  0.874  1.0
  O  O30  1  0.957  0.828  0.427  1.0
  O  O31  1  0.043  0.172  0.573  1.0
  O  O32  1  0.279  0.928  0.477  1.0
  O  O33  1  0.721  0.072  0.523  1.0
  O  O34  1  0.038  0.749  0.589  1.0
  O  O35  1  0.962  0.251  0.411  1.0
  O  O36  1  0.907  0.748  0.297  1.0
  O  O37  1  0.093  0.252  0.703  1.0
  O  O38  1  0.918  0.107  0.116  1.0
  O  O39  1  0.082  0.893  0.884  1.0
  O  O40  1  0.658  0.840  0.147  1.0
  O  O41  1  0.342  0.160  0.853  1.0
  O  O42  1  0.312  0.638  0.455  1.0
  O  O43  1  0.688  0.362  0.545  1.0
  O  O44  1  0.366  0.948  0.216  1.0
  O  O45  1  0.634  0.052  0.784  1.0
  O  O46  1  0.585  0.122  0.305  1.0
  O  O47  1  0.415  0.878  0.695  1.0
  O  O48  1  0.302  0.410  0.073  1.0
  O  O49  1  0.698  0.590  0.927  1.0
  O  O50  1  0.359  0.493  0.385  1.0
  O  O51  1  0.641  0.507  0.615  1.0
  O  O52  1  0.345  0.263  0.978  1.0
  O  O53  1  0.655  0.737  0.022  1.0
[/CIF]
.
The crystal structure described by (SmN2H3O9)2H2(NH2O3)2(H2O2)2O2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 1333-74-0 atoms, two water atoms, two H2O2 clusters, two NH2O3 clusters, and one SmN2H3O9 cluster. In each H2O2 cluster, there are two inequivalent H sites. In the first H site, H(1) is bonded in a 2-coordinate geometry to one O(10) and one O(14) atom. In the second H site, H(2) is bonded in a distorted single-bond geometry to one O(10) and one O(14) atom. There are two inequivalent O sites. In the first O site, O(14) is bonded in a distorted single-bond geometry to one H(1) and one H(2) atom. In the second O site, O(10) is bonded in a 2-coordinate geometry to one H(1) and one H(2) atom. In each NH2O3 cluster, N(3) is bonded in a distorted single-bond geometry to one O(15) and one O(9) atom. There are two inequivalent H sites. In the first H site, H(7) is bonded in a single-bond geometry to one O(13) atom. In the second H site, H(8) is bonded in a distorted single-bond geometry to one O(13) atom. There are three inequivalent O sites. In the first O site, O(9) is bonded in a single-bond geometry to one N(3) and one O(15) atom. In the second O site, O(13) is bonded in a distorted single-bond geometry to one H(7), one H(8), and one O(15) atom. In the third O site, O(15) is bonded in a distorted bent 150 degrees geometry to one N(3), one O(13), and one O(9) atom. In the SmN2H3O9 cluster, Sm(1) is bonded in a distorted single-bond geometry to one H(4), one O(11), one O(6), one O(7), and one O(8) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 1-coordinate geometry to one O(1) and one O(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(4), one O(5), and one O(6) atom. There are three inequivalent H sites. In the first H site, H(4) is bonded in a distorted single-bond geometry to one Sm(1) and one O(11) atom. In the second H site, H(5) is bonded in a 3-coordinate geometry to one H(6), one O(12), and one O(6) atom. In the third H site, H(6) is bonded in a single-bond geometry to one H(5) and one O(12) atom. There are nine inequivalent O sites. In the first O site, O(5) is bonded in a single-bond geometry to one N(2) atom. In the second O site, O(6) is bonded in a 3-coordinate geometry to one Sm(1), one N(2), and one H(5) atom. In the third O site, O(7) is bonded in an L-shaped geometry to one Sm(1) and one O(4) atom. In the fourth O site, O(8) is bonded in a 2-coordinate geometry to one Sm(1) and one O(2) atom. In the fifth O site, O(11) is bonded in a 2-coordinate geometry to one Sm(1) and one H(4) atom. In the sixth O site, O(12) is bonded in a distorted single-bond geometry to one H(5) and one H(6) atom. In the seventh O site, O(1) is bonded in a 1-coordinate geometry to one N(1) atom. In the eighth O site, O(2) is bonded in a single-bond geometry to one N(1) and one O(8) atom. In the ninth O site, O(4) is bonded in a distorted single-bond geometry to one N(2) and one O(7) atom. is represented by the CIF card [CIF]
data_SmH8(NO5)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.806
_cell_length_b   8.827
_cell_length_c   12.030
_cell_angle_alpha   111.299
_cell_angle_beta   91.113
_cell_angle_gamma   110.419
_symmetry_Int_Tables_number   1
_cell_volume   622.135
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sm  Sm0  1  0.205  0.047  0.276  1.0
  Sm  Sm1  1  0.795  0.953  0.724  1.0
  H  H2  1  0.551  0.397  0.485  1.0
  H  H3  1  0.449  0.603  0.515  1.0
  H  H4  1  0.785  0.509  0.504  1.0
  H  H5  1  0.215  0.491  0.496  1.0
  H  H6  1  0.358  0.773  0.272  1.0
  H  H7  1  0.642  0.227  0.728  1.0
  H  H8  1  0.336  0.032  0.131  1.0
  H  H9  1  0.664  0.968  0.869  1.0
  H  H10  1  0.705  0.143  0.350  1.0
  H  H11  1  0.295  0.857  0.650  1.0
  H  H12  1  0.639  0.093  0.272  1.0
  H  H13  1  0.361  0.907  0.728  1.0
  H  H14  1  0.575  0.477  0.936  1.0
  H  H15  1  0.425  0.523  0.064  1.0
  H  H16  1  0.786  0.505  0.007  1.0
  H  H17  1  0.214  0.495  0.993  1.0
  N  N18  1  0.070  0.476  0.173  1.0
  N  N19  1  0.930  0.524  0.827  1.0
  N  N20  1  0.091  0.833  0.500  1.0
  N  N21  1  0.909  0.167  0.500  1.0
  N  N22  1  0.822  0.896  0.185  1.0
  N  N23  1  0.178  0.104  0.815  1.0
  O  O24  1  0.254  0.415  0.234  1.0
  O  O25  1  0.746  0.585  0.766  1.0
  O  O26  1  0.943  0.344  0.162  1.0
  O  O27  1  0.057  0.656  0.838  1.0
  O  O28  1  0.012  0.657  0.126  1.0
  O  O29  1  0.988  0.343  0.874  1.0
  O  O30  1  0.957  0.828  0.427  1.0
  O  O31  1  0.043  0.172  0.573  1.0
  O  O32  1  0.279  0.928  0.477  1.0
  O  O33  1  0.721  0.072  0.523  1.0
  O  O34  1  0.038  0.749  0.589  1.0
  O  O35  1  0.962  0.251  0.411  1.0
  O  O36  1  0.907  0.748  0.297  1.0
  O  O37  1  0.093  0.252  0.703  1.0
  O  O38  1  0.918  0.107  0.116  1.0
  O  O39  1  0.082  0.893  0.884  1.0
  O  O40  1  0.658  0.840  0.147  1.0
  O  O41  1  0.342  0.160  0.853  1.0
  O  O42  1  0.312  0.638  0.455  1.0
  O  O43  1  0.688  0.362  0.545  1.0
  O  O44  1  0.366  0.948  0.216  1.0
  O  O45  1  0.634  0.052  0.784  1.0
  O  O46  1  0.585  0.122  0.305  1.0
  O  O47  1  0.415  0.878  0.695  1.0
  O  O48  1  0.302  0.410  0.073  1.0
  O  O49  1  0.698  0.590  0.927  1.0
  O  O50  1  0.359  0.493  0.385  1.0
  O  O51  1  0.641  0.507  0.615  1.0
  O  O52  1  0.345  0.263  0.978  1.0
  O  O53  1  0.655  0.737  0.022  1.0
[/CIF]
.