The structure described by Li4Nb2WMnO12 is beta indium sulfide-derived structured and crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded in a 6-coordinate geometry to one O(1), one O(11), one O(4), one O(7), one O(8), and one O(9) atom. In the second Li site, Li(2) is bonded in a 6-coordinate geometry to one O(10), one O(12), one O(2), one O(3), one O(5), and one O(6) atom. In the third Li site, Li(3) is bonded in a trigonal planar geometry to one O(5), one O(6), and one O(9) atom. In the fourth Li site, Li(4) is bonded in a 6-coordinate geometry to one O(1), one O(11), one O(12), one O(3), one O(4), and one O(7) atom. There are two inequivalent Nb sites. In the first Nb site, Nb(1) is bonded to one O(1), one O(11), one O(12), one O(2), one O(4), and one O(9) atom to form NbO6 octahedra that share corners with two equivalent W(1)O6 octahedra and corners with four equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 31-40°. In the second Nb site, Nb(2) is bonded to one O(10), one O(3), one O(5), one O(6), one O(7), and one O(8) atom to form NbO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra and corners with four equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 35-43°. W(1) is bonded to one O(10), one O(11), one O(2), one O(3), one O(5), and one O(8) atom to form WO6 octahedra that share corners with two equivalent Nb(1)O6 octahedra and corners with four equivalent Nb(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 37-43°. Mn(1) is bonded to one O(1), one O(12), one O(4), one O(6), one O(7), and one O(9) atom to form MnO6 octahedra that share corners with two equivalent Nb(2)O6 octahedra and corners with four equivalent Nb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 31-36°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted see-saw-like geometry to one Li(1), one Li(4), one Nb(1), and one Mn(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Li(2), one Nb(1), and one W(1) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Li(2), one Li(4), one Nb(2), and one W(1) atom. In the fourth O site, O(4) is bonded in a distorted see-saw-like geometry to one Li(1), one Li(4), one Nb(1), and one Mn(1) atom. In the fifth O site, O(5) is bonded to one Li(2), one Li(3), one Nb(2), and one W(1) atom to form a mixture of distorted corner and edge-sharing OLi2NbW trigonal pyramids. In the sixth O site, O(6) is bonded to one Li(2), one Li(3), one Nb(2), and one Mn(1) atom to form OLi2MnNb tetrahedra that share  a cornercorner with one O(5)Li2NbW trigonal pyramid, corners with two equivalent O(9)Li2MnNb trigonal pyramids, and  an edgeedge with one O(5)Li2NbW trigonal pyramid. In the seventh O site, O(7) is bonded in a distorted see-saw-like geometry to one Li(1), one Li(4), one Nb(2), and one Mn(1) atom. In the eighth O site, O(8) is bonded in a distorted trigonal planar geometry to one Li(1), one Nb(2), and one W(1) atom. In the ninth O site, O(9) is bonded to one Li(1), one Li(3), one Nb(1), and one Mn(1) atom to form OLi2MnNb trigonal pyramids that share corners with two equivalent O(6)Li2MnNb tetrahedra and  a cornercorner with one O(5)Li2NbW trigonal pyramid. In the tenth O site, O(10) is bonded in a distorted trigonal planar geometry to one Li(2), one Nb(2), and one W(1) atom. In the eleventh O site, O(11) is bonded in a 4-coordinate geometry to one Li(1), one Li(4), one Nb(1), and one W(1) atom. In the twelfth O site, O(12) is bonded in a distorted see-saw-like geometry to one Li(2), one Li(4), one Nb(1), and one Mn(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li4MnNb2WO12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.463
_cell_length_b   10.937
_cell_length_c   9.636
_cell_angle_alpha   28.177
_cell_angle_beta   51.107
_cell_angle_gamma   56.344
_symmetry_Int_Tables_number   1
_cell_volume   211.597
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.254  0.998  0.312  1.0
  Li  Li1  1  0.324  0.499  0.271  1.0
  Li  Li2  1  0.774  0.006  0.732  1.0
  Li  Li3  1  0.768  0.496  0.813  1.0
  Mn  Mn4  1  0.002  0.500  0.999  1.0
  Nb  Nb5  1  0.488  0.004  0.506  1.0
  Nb  Nb6  1  0.525  0.498  0.502  1.0
  W  W7  1  0.003  0.003  0.005  1.0
  O  O8  1  0.352  0.300  0.136  1.0
  O  O9  1  0.225  0.124  0.634  1.0
  O  O10  1  0.114  0.313  0.744  1.0
  O  O11  1  0.857  0.206  0.231  1.0
  O  O12  1  0.369  0.819  0.113  1.0
  O  O13  1  0.730  0.390  0.355  1.0
  O  O14  1  0.243  0.614  0.632  1.0
  O  O15  1  0.624  0.172  0.885  1.0
  O  O16  1  0.137  0.804  0.740  1.0
  O  O17  1  0.887  0.691  0.239  1.0
  O  O18  1  0.752  0.873  0.367  1.0
  O  O19  1  0.643  0.690  0.858  1.0
[/CIF]
.
The structure described by Li4Nb2WMnO12 is beta indium sulfide-derived structured and crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded in a 6-coordinate geometry to one O(1), one O(11), one O(4), one O(7), one O(8), and one O(9) atom. In the second Li site, Li(2) is bonded in a 6-coordinate geometry to one O(10), one O(12), one O(2), one O(3), one O(5), and one O(6) atom. In the third Li site, Li(3) is bonded in a trigonal planar geometry to one O(5), one O(6), and one O(9) atom. In the fourth Li site, Li(4) is bonded in a 6-coordinate geometry to one O(1), one O(11), one O(12), one O(3), one O(4), and one O(7) atom. There are two inequivalent Nb sites. In the first Nb site, Nb(1) is bonded to one O(1), one O(11), one O(12), one O(2), one O(4), and one O(9) atom to form NbO6 octahedra that share corners with two equivalent W(1)O6 octahedra and corners with four equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 31-40°. In the second Nb site, Nb(2) is bonded to one O(10), one O(3), one O(5), one O(6), one O(7), and one O(8) atom to form NbO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra and corners with four equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 35-43°. W(1) is bonded to one O(10), one O(11), one O(2), one O(3), one O(5), and one O(8) atom to form WO6 octahedra that share corners with two equivalent Nb(1)O6 octahedra and corners with four equivalent Nb(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 37-43°. Mn(1) is bonded to one O(1), one O(12), one O(4), one O(6), one O(7), and one O(9) atom to form MnO6 octahedra that share corners with two equivalent Nb(2)O6 octahedra and corners with four equivalent Nb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 31-36°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted see-saw-like geometry to one Li(1), one Li(4), one Nb(1), and one Mn(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Li(2), one Nb(1), and one W(1) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Li(2), one Li(4), one Nb(2), and one W(1) atom. In the fourth O site, O(4) is bonded in a distorted see-saw-like geometry to one Li(1), one Li(4), one Nb(1), and one Mn(1) atom. In the fifth O site, O(5) is bonded to one Li(2), one Li(3), one Nb(2), and one W(1) atom to form a mixture of distorted corner and edge-sharing OLi2NbW trigonal pyramids. In the sixth O site, O(6) is bonded to one Li(2), one Li(3), one Nb(2), and one Mn(1) atom to form OLi2MnNb tetrahedra that share  a cornercorner with one O(5)Li2NbW trigonal pyramid, corners with two equivalent O(9)Li2MnNb trigonal pyramids, and  an edgeedge with one O(5)Li2NbW trigonal pyramid. In the seventh O site, O(7) is bonded in a distorted see-saw-like geometry to one Li(1), one Li(4), one Nb(2), and one Mn(1) atom. In the eighth O site, O(8) is bonded in a distorted trigonal planar geometry to one Li(1), one Nb(2), and one W(1) atom. In the ninth O site, O(9) is bonded to one Li(1), one Li(3), one Nb(1), and one Mn(1) atom to form OLi2MnNb trigonal pyramids that share corners with two equivalent O(6)Li2MnNb tetrahedra and  a cornercorner with one O(5)Li2NbW trigonal pyramid. In the tenth O site, O(10) is bonded in a distorted trigonal planar geometry to one Li(2), one Nb(2), and one W(1) atom. In the eleventh O site, O(11) is bonded in a 4-coordinate geometry to one Li(1), one Li(4), one Nb(1), and one W(1) atom. In the twelfth O site, O(12) is bonded in a distorted see-saw-like geometry to one Li(2), one Li(4), one Nb(1), and one Mn(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li4MnNb2WO12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.463
_cell_length_b   10.937
_cell_length_c   9.636
_cell_angle_alpha   28.177
_cell_angle_beta   51.107
_cell_angle_gamma   56.344
_symmetry_Int_Tables_number   1
_cell_volume   211.597
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.254  0.998  0.312  1.0
  Li  Li1  1  0.324  0.499  0.271  1.0
  Li  Li2  1  0.774  0.006  0.732  1.0
  Li  Li3  1  0.768  0.496  0.813  1.0
  Mn  Mn4  1  0.002  0.500  0.999  1.0
  Nb  Nb5  1  0.488  0.004  0.506  1.0
  Nb  Nb6  1  0.525  0.498  0.502  1.0
  W  W7  1  0.003  0.003  0.005  1.0
  O  O8  1  0.352  0.300  0.136  1.0
  O  O9  1  0.225  0.124  0.634  1.0
  O  O10  1  0.114  0.313  0.744  1.0
  O  O11  1  0.857  0.206  0.231  1.0
  O  O12  1  0.369  0.819  0.113  1.0
  O  O13  1  0.730  0.390  0.355  1.0
  O  O14  1  0.243  0.614  0.632  1.0
  O  O15  1  0.624  0.172  0.885  1.0
  O  O16  1  0.137  0.804  0.740  1.0
  O  O17  1  0.887  0.691  0.239  1.0
  O  O18  1  0.752  0.873  0.367  1.0
  O  O19  1  0.643  0.690  0.858  1.0
[/CIF]
.