The compound described by C3NC3SbNCl3ClC1C2NSbCl5 is Indium-derived structured and crystallizes in the monoclinic Pc space group. The structure is zero-dimensional and consists of two methyleneaziridine molecules, two C3SbNCl3 clusters, two ClC1C2N clusters, and two SbCl5 clusters. In each C3SbNCl3 cluster, there are three inequivalent C sites. In the first C site, C(4) is bonded in a bent 150 degrees geometry to one C(5) and one Cl(3) atom. In the second C site, C(5) is bonded in a distorted linear geometry to one C(4) and one N(2) atom. In the third C site, C(6) is bonded in a single-bond geometry to one N(2) atom. Sb(1) is bonded in a distorted T-shaped geometry to one Cl(1), one Cl(2), and one Cl(3) atom. N(2) is bonded in a linear geometry to one C(5) and one C(6) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in a distorted L-shaped geometry to one C(4) and one Sb(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Sb(1) atom. In the third Cl site, Cl(2) is bonded in a single-bond geometry to one Sb(1) atom. In each ClC1C2N cluster, there are three inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one C(2) and one N(1) atom. In the second C site, C(2) is bonded in a linear geometry to one C(1) and one Cl(4) atom. In the third C site, C(3) is bonded in a single-bond geometry to one N(1) atom. N(1) is bonded in a linear geometry to one C(1) and one C(3) atom. Cl(4) is bonded in a single-bond geometry to one C(2) atom. In each SbCl5 cluster, Sb(2) is bonded in a trigonal bipyramidal geometry to one Cl(5), one Cl(6), one Cl(7), one Cl(8), and one Cl(9) atom. There are five inequivalent Cl sites. In the first Cl site, Cl(5) is bonded in a single-bond geometry to one Sb(2) atom. In the second Cl site, Cl(6) is bonded in a single-bond geometry to one Sb(2) atom. In the third Cl site, Cl(7) is bonded in a single-bond geometry to one Sb(2) atom. In the fourth Cl site, Cl(8) is bonded in a single-bond geometry to one Sb(2) atom. In the fifth Cl site, Cl(9) is bonded in a single-bond geometry to one Sb(2) atom. is represented by the CIF card [CIF]
data_Sb2C9(NCl3)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.892
_cell_length_b   11.247
_cell_length_c   14.902
_cell_angle_alpha   87.512
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1488.998
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.788  0.973  0.502  1.0
  Sb  Sb1  1  0.212  0.973  0.002  1.0
  Sb  Sb2  1  0.670  0.292  0.166  1.0
  Sb  Sb3  1  0.330  0.292  0.666  1.0
  C  C4  1  0.838  0.482  0.467  1.0
  C  C5  1  0.162  0.482  0.967  1.0
  C  C6  1  0.871  0.476  0.388  1.0
  C  C7  1  0.129  0.476  0.888  1.0
  C  C8  1  0.800  0.508  0.631  1.0
  C  C9  1  0.200  0.508  0.131  1.0
  C  C10  1  0.594  0.024  0.922  1.0
  C  C11  1  0.406  0.024  0.422  1.0
  C  C12  1  0.672  0.076  0.865  1.0
  C  C13  1  0.328  0.076  0.365  1.0
  C  C14  1  0.839  0.212  0.772  1.0
  C  C15  1  0.161  0.212  0.272  1.0
  C  C16  1  0.660  0.795  0.194  1.0
  C  C17  1  0.340  0.795  0.694  1.0
  C  C18  1  0.780  0.817  0.122  1.0
  C  C19  1  0.220  0.817  0.622  1.0
  C  C20  1  0.586  0.722  0.250  1.0
  C  C21  1  0.414  0.722  0.750  1.0
  N  N22  1  0.813  0.493  0.552  1.0
  N  N23  1  0.187  0.493  0.052  1.0
  N  N24  1  0.760  0.147  0.817  1.0
  N  N25  1  0.240  0.147  0.317  1.0
  N  N26  1  0.709  0.904  0.155  1.0
  N  N27  1  0.291  0.904  0.655  1.0
  Cl  Cl28  1  0.974  0.878  0.419  1.0
  Cl  Cl29  1  0.026  0.878  0.919  1.0
  Cl  Cl30  1  0.817  0.864  0.639  1.0
  Cl  Cl31  1  0.183  0.864  0.139  1.0
  Cl  Cl32  1  0.579  0.857  0.446  1.0
  Cl  Cl33  1  0.421  0.857  0.946  1.0
  Cl  Cl34  1  0.930  0.473  0.286  1.0
  Cl  Cl35  1  0.070  0.473  0.786  1.0
  Cl  Cl36  1  0.528  0.412  0.260  1.0
  Cl  Cl37  1  0.472  0.412  0.760  1.0
  Cl  Cl38  1  0.696  0.458  0.065  1.0
  Cl  Cl39  1  0.304  0.458  0.565  1.0
  Cl  Cl40  1  0.524  0.185  0.604  1.0
  Cl  Cl41  1  0.476  0.185  0.104  1.0
  Cl  Cl42  1  0.877  0.207  0.091  1.0
  Cl  Cl43  1  0.123  0.207  0.591  1.0
  Cl  Cl44  1  0.741  0.173  0.295  1.0
  Cl  Cl45  1  0.259  0.173  0.795  1.0
[/CIF]
.
The compound described by C3NC3SbNCl3ClC1C2NSbCl5 is Indium-derived structured and crystallizes in the monoclinic Pc space group. The structure is zero-dimensional and consists of two methyleneaziridine molecules, two C3SbNCl3 clusters, two ClC1C2N clusters, and two SbCl5 clusters. In each C3SbNCl3 cluster, there are three inequivalent C sites. In the first C site, C(4) is bonded in a bent 150 degrees geometry to one C(5) and one Cl(3) atom. In the second C site, C(5) is bonded in a distorted linear geometry to one C(4) and one N(2) atom. In the third C site, C(6) is bonded in a single-bond geometry to one N(2) atom. Sb(1) is bonded in a distorted T-shaped geometry to one Cl(1), one Cl(2), and one Cl(3) atom. N(2) is bonded in a linear geometry to one C(5) and one C(6) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in a distorted L-shaped geometry to one C(4) and one Sb(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Sb(1) atom. In the third Cl site, Cl(2) is bonded in a single-bond geometry to one Sb(1) atom. In each ClC1C2N cluster, there are three inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one C(2) and one N(1) atom. In the second C site, C(2) is bonded in a linear geometry to one C(1) and one Cl(4) atom. In the third C site, C(3) is bonded in a single-bond geometry to one N(1) atom. N(1) is bonded in a linear geometry to one C(1) and one C(3) atom. Cl(4) is bonded in a single-bond geometry to one C(2) atom. In each SbCl5 cluster, Sb(2) is bonded in a trigonal bipyramidal geometry to one Cl(5), one Cl(6), one Cl(7), one Cl(8), and one Cl(9) atom. There are five inequivalent Cl sites. In the first Cl site, Cl(5) is bonded in a single-bond geometry to one Sb(2) atom. In the second Cl site, Cl(6) is bonded in a single-bond geometry to one Sb(2) atom. In the third Cl site, Cl(7) is bonded in a single-bond geometry to one Sb(2) atom. In the fourth Cl site, Cl(8) is bonded in a single-bond geometry to one Sb(2) atom. In the fifth Cl site, Cl(9) is bonded in a single-bond geometry to one Sb(2) atom. is represented by the CIF card [CIF]
data_Sb2C9(NCl3)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.892
_cell_length_b   11.247
_cell_length_c   14.902
_cell_angle_alpha   87.512
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1488.998
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.788  0.973  0.502  1.0
  Sb  Sb1  1  0.212  0.973  0.002  1.0
  Sb  Sb2  1  0.670  0.292  0.166  1.0
  Sb  Sb3  1  0.330  0.292  0.666  1.0
  C  C4  1  0.838  0.482  0.467  1.0
  C  C5  1  0.162  0.482  0.967  1.0
  C  C6  1  0.871  0.476  0.388  1.0
  C  C7  1  0.129  0.476  0.888  1.0
  C  C8  1  0.800  0.508  0.631  1.0
  C  C9  1  0.200  0.508  0.131  1.0
  C  C10  1  0.594  0.024  0.922  1.0
  C  C11  1  0.406  0.024  0.422  1.0
  C  C12  1  0.672  0.076  0.865  1.0
  C  C13  1  0.328  0.076  0.365  1.0
  C  C14  1  0.839  0.212  0.772  1.0
  C  C15  1  0.161  0.212  0.272  1.0
  C  C16  1  0.660  0.795  0.194  1.0
  C  C17  1  0.340  0.795  0.694  1.0
  C  C18  1  0.780  0.817  0.122  1.0
  C  C19  1  0.220  0.817  0.622  1.0
  C  C20  1  0.586  0.722  0.250  1.0
  C  C21  1  0.414  0.722  0.750  1.0
  N  N22  1  0.813  0.493  0.552  1.0
  N  N23  1  0.187  0.493  0.052  1.0
  N  N24  1  0.760  0.147  0.817  1.0
  N  N25  1  0.240  0.147  0.317  1.0
  N  N26  1  0.709  0.904  0.155  1.0
  N  N27  1  0.291  0.904  0.655  1.0
  Cl  Cl28  1  0.974  0.878  0.419  1.0
  Cl  Cl29  1  0.026  0.878  0.919  1.0
  Cl  Cl30  1  0.817  0.864  0.639  1.0
  Cl  Cl31  1  0.183  0.864  0.139  1.0
  Cl  Cl32  1  0.579  0.857  0.446  1.0
  Cl  Cl33  1  0.421  0.857  0.946  1.0
  Cl  Cl34  1  0.930  0.473  0.286  1.0
  Cl  Cl35  1  0.070  0.473  0.786  1.0
  Cl  Cl36  1  0.528  0.412  0.260  1.0
  Cl  Cl37  1  0.472  0.412  0.760  1.0
  Cl  Cl38  1  0.696  0.458  0.065  1.0
  Cl  Cl39  1  0.304  0.458  0.565  1.0
  Cl  Cl40  1  0.524  0.185  0.604  1.0
  Cl  Cl41  1  0.476  0.185  0.104  1.0
  Cl  Cl42  1  0.877  0.207  0.091  1.0
  Cl  Cl43  1  0.123  0.207  0.591  1.0
  Cl  Cl44  1  0.741  0.173  0.295  1.0
  Cl  Cl45  1  0.259  0.173  0.795  1.0
[/CIF]
.