The crystal structure described by CsMnH4O2Cl3 crystallizes in the orthorhombic Pcca space group. Cs(1) is bonded in a 8-coordinate geometry to two equivalent Cl(1) and six equivalent Cl(2) atoms. Mn(1) is bonded to two equivalent O(1), two equivalent Cl(1), and two equivalent Cl(2) atoms to form corner-sharing MnCl4O2 octahedra. The corner-sharing octahedral tilt angles are 54°. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. O(1) is bonded in a distorted water-like geometry to one Mn(1), one H(1), and one H(2) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted bent 120 degrees geometry to two equivalent Cs(1) and two equivalent Mn(1) atoms. In the second Cl site, Cl(2) is bonded in a distorted single-bond geometry to three equivalent Cs(1) and one Mn(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CsMnH4Cl3O2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.287
_cell_length_b   9.010
_cell_length_c   11.425
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   750.114
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.000  0.750  0.648  1.0
  Cs  Cs1  1  0.000  0.250  0.852  1.0
  Cs  Cs2  1  0.000  0.250  0.352  1.0
  Cs  Cs3  1  0.000  0.750  0.148  1.0
  Mn  Mn4  1  0.528  0.500  0.750  1.0
  Mn  Mn5  1  0.472  0.000  0.750  1.0
  Mn  Mn6  1  0.472  0.500  0.250  1.0
  Mn  Mn7  1  0.528  0.000  0.250  1.0
  H  H8  1  0.308  0.522  0.948  1.0
  H  H9  1  0.692  0.978  0.948  1.0
  H  H10  1  0.692  0.022  0.552  1.0
  H  H11  1  0.308  0.478  0.552  1.0
  H  H12  1  0.692  0.478  0.052  1.0
  H  H13  1  0.308  0.022  0.052  1.0
  H  H14  1  0.308  0.978  0.448  1.0
  H  H15  1  0.692  0.522  0.448  1.0
  H  H16  1  0.301  0.678  0.885  1.0
  H  H17  1  0.699  0.822  0.885  1.0
  H  H18  1  0.699  0.178  0.615  1.0
  H  H19  1  0.301  0.322  0.615  1.0
  H  H20  1  0.699  0.322  0.115  1.0
  H  H21  1  0.301  0.178  0.115  1.0
  H  H22  1  0.301  0.822  0.385  1.0
  H  H23  1  0.699  0.678  0.385  1.0
  Cl  Cl24  1  0.500  0.750  0.650  1.0
  Cl  Cl25  1  0.500  0.250  0.850  1.0
  Cl  Cl26  1  0.500  0.250  0.350  1.0
  Cl  Cl27  1  0.500  0.750  0.150  1.0
  Cl  Cl28  1  0.773  0.590  0.891  1.0
  Cl  Cl29  1  0.227  0.910  0.891  1.0
  Cl  Cl30  1  0.227  0.090  0.609  1.0
  Cl  Cl31  1  0.773  0.410  0.609  1.0
  Cl  Cl32  1  0.227  0.410  0.109  1.0
  Cl  Cl33  1  0.773  0.090  0.109  1.0
  Cl  Cl34  1  0.773  0.910  0.391  1.0
  Cl  Cl35  1  0.227  0.590  0.391  1.0
  O  O36  1  0.314  0.571  0.871  1.0
  O  O37  1  0.686  0.929  0.871  1.0
  O  O38  1  0.686  0.071  0.629  1.0
  O  O39  1  0.314  0.429  0.629  1.0
  O  O40  1  0.686  0.429  0.129  1.0
  O  O41  1  0.314  0.071  0.129  1.0
  O  O42  1  0.314  0.929  0.371  1.0
  O  O43  1  0.686  0.571  0.371  1.0
[/CIF]
.
The crystal structure described by CsMnH4O2Cl3 crystallizes in the orthorhombic Pcca space group. Cs(1) is bonded in a 8-coordinate geometry to two equivalent Cl(1) and six equivalent Cl(2) atoms. Mn(1) is bonded to two equivalent O(1), two equivalent Cl(1), and two equivalent Cl(2) atoms to form corner-sharing MnCl4O2 octahedra. The corner-sharing octahedral tilt angles are 54°. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. O(1) is bonded in a distorted water-like geometry to one Mn(1), one H(1), and one H(2) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted bent 120 degrees geometry to two equivalent Cs(1) and two equivalent Mn(1) atoms. In the second Cl site, Cl(2) is bonded in a distorted single-bond geometry to three equivalent Cs(1) and one Mn(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CsMnH4Cl3O2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.287
_cell_length_b   9.010
_cell_length_c   11.425
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   750.114
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.000  0.750  0.648  1.0
  Cs  Cs1  1  0.000  0.250  0.852  1.0
  Cs  Cs2  1  0.000  0.250  0.352  1.0
  Cs  Cs3  1  0.000  0.750  0.148  1.0
  Mn  Mn4  1  0.528  0.500  0.750  1.0
  Mn  Mn5  1  0.472  0.000  0.750  1.0
  Mn  Mn6  1  0.472  0.500  0.250  1.0
  Mn  Mn7  1  0.528  0.000  0.250  1.0
  H  H8  1  0.308  0.522  0.948  1.0
  H  H9  1  0.692  0.978  0.948  1.0
  H  H10  1  0.692  0.022  0.552  1.0
  H  H11  1  0.308  0.478  0.552  1.0
  H  H12  1  0.692  0.478  0.052  1.0
  H  H13  1  0.308  0.022  0.052  1.0
  H  H14  1  0.308  0.978  0.448  1.0
  H  H15  1  0.692  0.522  0.448  1.0
  H  H16  1  0.301  0.678  0.885  1.0
  H  H17  1  0.699  0.822  0.885  1.0
  H  H18  1  0.699  0.178  0.615  1.0
  H  H19  1  0.301  0.322  0.615  1.0
  H  H20  1  0.699  0.322  0.115  1.0
  H  H21  1  0.301  0.178  0.115  1.0
  H  H22  1  0.301  0.822  0.385  1.0
  H  H23  1  0.699  0.678  0.385  1.0
  Cl  Cl24  1  0.500  0.750  0.650  1.0
  Cl  Cl25  1  0.500  0.250  0.850  1.0
  Cl  Cl26  1  0.500  0.250  0.350  1.0
  Cl  Cl27  1  0.500  0.750  0.150  1.0
  Cl  Cl28  1  0.773  0.590  0.891  1.0
  Cl  Cl29  1  0.227  0.910  0.891  1.0
  Cl  Cl30  1  0.227  0.090  0.609  1.0
  Cl  Cl31  1  0.773  0.410  0.609  1.0
  Cl  Cl32  1  0.227  0.410  0.109  1.0
  Cl  Cl33  1  0.773  0.090  0.109  1.0
  Cl  Cl34  1  0.773  0.910  0.391  1.0
  Cl  Cl35  1  0.227  0.590  0.391  1.0
  O  O36  1  0.314  0.571  0.871  1.0
  O  O37  1  0.686  0.929  0.871  1.0
  O  O38  1  0.686  0.071  0.629  1.0
  O  O39  1  0.314  0.429  0.629  1.0
  O  O40  1  0.686  0.429  0.129  1.0
  O  O41  1  0.314  0.071  0.129  1.0
  O  O42  1  0.314  0.929  0.371  1.0
  O  O43  1  0.686  0.571  0.371  1.0
[/CIF]
.