The crystal structure described by (PrN3O14)2O2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one hydrogen peroxide molecule and two PrN3O14 clusters. In each PrN3O14 cluster, Pr(1) is bonded in a 8-coordinate geometry to one O(1), one O(11), one O(13), one O(2), one O(4), one O(5), one O(7), and one O(8) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(4), one O(5), and one O(6) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one O(7), one O(8), and one O(9) atom. There are fourteen inequivalent O sites. In the first O site, O(13) is bonded in a bent 120 degrees geometry to one Pr(1) and one O(10) atom. In the second O site, O(14) is bonded in a single-bond geometry to one O(10) atom. In the third O site, O(15) is bonded in a single-bond geometry to one O(11) atom. In the fourth O site, O(1) is bonded in an L-shaped geometry to one Pr(1) and one N(1) atom. In the fifth O site, O(2) is bonded in a distorted L-shaped geometry to one Pr(1) and one N(1) atom. In the sixth O site, O(3) is bonded in a single-bond geometry to one N(1) atom. In the seventh O site, O(4) is bonded in a distorted water-like geometry to one Pr(1) and one N(2) atom. In the eighth O site, O(5) is bonded in a distorted water-like geometry to one Pr(1) and one N(2) atom. In the ninth O site, O(6) is bonded in a single-bond geometry to one N(2) atom. In the tenth O site, O(7) is bonded in a distorted water-like geometry to one Pr(1) and one N(3) atom. In the eleventh O site, O(8) is bonded in an L-shaped geometry to one Pr(1) and one N(3) atom. In the twelfth O site, O(9) is bonded in a single-bond geometry to one N(3) atom. In the thirteenth O site, O(10) is bonded in a bent 120 degrees geometry to one O(13) and one O(14) atom. In the fourteenth O site, O(11) is bonded in a bent 150 degrees geometry to one Pr(1) and one O(15) atom. is represented by the CIF file [CIF]
data_Pr(NO5)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.965
_cell_length_b   8.457
_cell_length_c   12.634
_cell_angle_alpha   99.259
_cell_angle_beta   103.901
_cell_angle_gamma   106.808
_symmetry_Int_Tables_number   1
_cell_volume   669.888
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pr  Pr0  1  0.234  0.388  0.234  1.0
  Pr  Pr1  1  0.766  0.612  0.766  1.0
  N  N2  1  0.616  0.681  0.327  1.0
  N  N3  1  0.384  0.319  0.673  1.0
  N  N4  1  0.272  0.102  0.338  1.0
  N  N5  1  0.728  0.898  0.662  1.0
  N  N6  1  0.262  0.347  0.007  1.0
  N  N7  1  0.738  0.653  0.993  1.0
  O  O8  1  0.606  0.532  0.346  1.0
  O  O9  1  0.394  0.468  0.654  1.0
  O  O10  1  0.439  0.688  0.269  1.0
  O  O11  1  0.561  0.312  0.731  1.0
  O  O12  1  0.778  0.803  0.361  1.0
  O  O13  1  0.222  0.197  0.639  1.0
  O  O14  1  0.250  0.094  0.231  1.0
  O  O15  1  0.750  0.906  0.769  1.0
  O  O16  1  0.262  0.241  0.393  1.0
  O  O17  1  0.738  0.759  0.607  1.0
  O  O18  1  0.302  0.989  0.381  1.0
  O  O19  1  0.698  0.011  0.619  1.0
  O  O20  1  0.397  0.326  0.090  1.0
  O  O21  1  0.603  0.674  0.910  1.0
  O  O22  1  0.108  0.384  0.031  1.0
  O  O23  1  0.892  0.616  0.969  1.0
  O  O24  1  0.280  0.330  0.912  1.0
  O  O25  1  0.720  0.670  0.088  1.0
  O  O26  1  0.744  0.134  0.244  1.0
  O  O27  1  0.256  0.866  0.756  1.0
  O  O28  1  0.169  0.580  0.434  1.0
  O  O29  1  0.831  0.420  0.566  1.0
  O  O30  1  0.935  0.028  0.015  1.0
  O  O31  1  0.065  0.972  0.985  1.0
  O  O32  1  0.836  0.270  0.208  1.0
  O  O33  1  0.164  0.730  0.792  1.0
  O  O34  1  0.568  0.034  0.181  1.0
  O  O35  1  0.432  0.966  0.819  1.0
  O  O36  1  0.177  0.717  0.490  1.0
  O  O37  1  0.823  0.283  0.510  1.0
[/CIF]
.
The crystal structure described by (PrN3O14)2O2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one hydrogen peroxide molecule and two PrN3O14 clusters. In each PrN3O14 cluster, Pr(1) is bonded in a 8-coordinate geometry to one O(1), one O(11), one O(13), one O(2), one O(4), one O(5), one O(7), and one O(8) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(4), one O(5), and one O(6) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one O(7), one O(8), and one O(9) atom. There are fourteen inequivalent O sites. In the first O site, O(13) is bonded in a bent 120 degrees geometry to one Pr(1) and one O(10) atom. In the second O site, O(14) is bonded in a single-bond geometry to one O(10) atom. In the third O site, O(15) is bonded in a single-bond geometry to one O(11) atom. In the fourth O site, O(1) is bonded in an L-shaped geometry to one Pr(1) and one N(1) atom. In the fifth O site, O(2) is bonded in a distorted L-shaped geometry to one Pr(1) and one N(1) atom. In the sixth O site, O(3) is bonded in a single-bond geometry to one N(1) atom. In the seventh O site, O(4) is bonded in a distorted water-like geometry to one Pr(1) and one N(2) atom. In the eighth O site, O(5) is bonded in a distorted water-like geometry to one Pr(1) and one N(2) atom. In the ninth O site, O(6) is bonded in a single-bond geometry to one N(2) atom. In the tenth O site, O(7) is bonded in a distorted water-like geometry to one Pr(1) and one N(3) atom. In the eleventh O site, O(8) is bonded in an L-shaped geometry to one Pr(1) and one N(3) atom. In the twelfth O site, O(9) is bonded in a single-bond geometry to one N(3) atom. In the thirteenth O site, O(10) is bonded in a bent 120 degrees geometry to one O(13) and one O(14) atom. In the fourteenth O site, O(11) is bonded in a bent 150 degrees geometry to one Pr(1) and one O(15) atom. is represented by the CIF file [CIF]
data_Pr(NO5)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.965
_cell_length_b   8.457
_cell_length_c   12.634
_cell_angle_alpha   99.259
_cell_angle_beta   103.901
_cell_angle_gamma   106.808
_symmetry_Int_Tables_number   1
_cell_volume   669.888
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pr  Pr0  1  0.234  0.388  0.234  1.0
  Pr  Pr1  1  0.766  0.612  0.766  1.0
  N  N2  1  0.616  0.681  0.327  1.0
  N  N3  1  0.384  0.319  0.673  1.0
  N  N4  1  0.272  0.102  0.338  1.0
  N  N5  1  0.728  0.898  0.662  1.0
  N  N6  1  0.262  0.347  0.007  1.0
  N  N7  1  0.738  0.653  0.993  1.0
  O  O8  1  0.606  0.532  0.346  1.0
  O  O9  1  0.394  0.468  0.654  1.0
  O  O10  1  0.439  0.688  0.269  1.0
  O  O11  1  0.561  0.312  0.731  1.0
  O  O12  1  0.778  0.803  0.361  1.0
  O  O13  1  0.222  0.197  0.639  1.0
  O  O14  1  0.250  0.094  0.231  1.0
  O  O15  1  0.750  0.906  0.769  1.0
  O  O16  1  0.262  0.241  0.393  1.0
  O  O17  1  0.738  0.759  0.607  1.0
  O  O18  1  0.302  0.989  0.381  1.0
  O  O19  1  0.698  0.011  0.619  1.0
  O  O20  1  0.397  0.326  0.090  1.0
  O  O21  1  0.603  0.674  0.910  1.0
  O  O22  1  0.108  0.384  0.031  1.0
  O  O23  1  0.892  0.616  0.969  1.0
  O  O24  1  0.280  0.330  0.912  1.0
  O  O25  1  0.720  0.670  0.088  1.0
  O  O26  1  0.744  0.134  0.244  1.0
  O  O27  1  0.256  0.866  0.756  1.0
  O  O28  1  0.169  0.580  0.434  1.0
  O  O29  1  0.831  0.420  0.566  1.0
  O  O30  1  0.935  0.028  0.015  1.0
  O  O31  1  0.065  0.972  0.985  1.0
  O  O32  1  0.836  0.270  0.208  1.0
  O  O33  1  0.164  0.730  0.792  1.0
  O  O34  1  0.568  0.034  0.181  1.0
  O  O35  1  0.432  0.966  0.819  1.0
  O  O36  1  0.177  0.717  0.490  1.0
  O  O37  1  0.823  0.283  0.510  1.0
[/CIF]
.