The material structure described by K3VSO3 crystallizes in the monoclinic P2_1/m space group. There are three inequivalent K sites. In the first K site, K(1) is bonded in a 7-coordinate geometry to three equivalent S(1) and four equivalent O(2) atoms. In the second K site, K(2) is bonded in a 6-coordinate geometry to one S(1), two equivalent O(2), and three equivalent O(1) atoms. In the third K site, K(3) is bonded in a 3-coordinate geometry to three equivalent S(1), one O(1), and two equivalent O(2) atoms. V(1) is bonded in a distorted tetrahedral geometry to one S(1), one O(1), and two equivalent O(2) atoms. S(1) is bonded in a 8-coordinate geometry to one K(2), three equivalent K(1), three equivalent K(3), and one V(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to one K(3), three equivalent K(2), and one V(1) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to one K(2), one K(3), two equivalent K(1), and one V(1) atom. is represented by the CIF card [CIF]
data_K3VSO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.994
_cell_length_b   6.707
_cell_length_c   8.864
_cell_angle_alpha   77.361
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   347.675
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.750  0.687  0.468  1.0
  K  K1  1  0.250  0.247  0.003  1.0
  K  K2  1  0.250  0.313  0.532  1.0
  K  K3  1  0.750  0.753  0.997  1.0
  K  K4  1  0.250  0.781  0.722  1.0
  K  K5  1  0.750  0.219  0.278  1.0
  V  V6  1  0.750  0.304  0.791  1.0
  V  V7  1  0.250  0.696  0.209  1.0
  S  S8  1  0.750  0.058  0.652  1.0
  S  S9  1  0.250  0.942  0.348  1.0
  O  O10  1  0.250  0.807  0.014  1.0
  O  O11  1  0.750  0.193  0.986  1.0
  O  O12  1  0.984  0.454  0.742  1.0
  O  O13  1  0.016  0.546  0.258  1.0
  O  O14  1  0.516  0.454  0.742  1.0
  O  O15  1  0.484  0.546  0.258  1.0
[/CIF]
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The material structure described by K3VSO3 crystallizes in the monoclinic P2_1/m space group. There are three inequivalent K sites. In the first K site, K(1) is bonded in a 7-coordinate geometry to three equivalent S(1) and four equivalent O(2) atoms. In the second K site, K(2) is bonded in a 6-coordinate geometry to one S(1), two equivalent O(2), and three equivalent O(1) atoms. In the third K site, K(3) is bonded in a 3-coordinate geometry to three equivalent S(1), one O(1), and two equivalent O(2) atoms. V(1) is bonded in a distorted tetrahedral geometry to one S(1), one O(1), and two equivalent O(2) atoms. S(1) is bonded in a 8-coordinate geometry to one K(2), three equivalent K(1), three equivalent K(3), and one V(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to one K(3), three equivalent K(2), and one V(1) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to one K(2), one K(3), two equivalent K(1), and one V(1) atom. is represented by the CIF card [CIF]
data_K3VSO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.994
_cell_length_b   6.707
_cell_length_c   8.864
_cell_angle_alpha   77.361
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   347.675
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.750  0.687  0.468  1.0
  K  K1  1  0.250  0.247  0.003  1.0
  K  K2  1  0.250  0.313  0.532  1.0
  K  K3  1  0.750  0.753  0.997  1.0
  K  K4  1  0.250  0.781  0.722  1.0
  K  K5  1  0.750  0.219  0.278  1.0
  V  V6  1  0.750  0.304  0.791  1.0
  V  V7  1  0.250  0.696  0.209  1.0
  S  S8  1  0.750  0.058  0.652  1.0
  S  S9  1  0.250  0.942  0.348  1.0
  O  O10  1  0.250  0.807  0.014  1.0
  O  O11  1  0.750  0.193  0.986  1.0
  O  O12  1  0.984  0.454  0.742  1.0
  O  O13  1  0.016  0.546  0.258  1.0
  O  O14  1  0.516  0.454  0.742  1.0
  O  O15  1  0.484  0.546  0.258  1.0
[/CIF]
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