The material structure described by KCN3O2 crystallizes in the monoclinic P2_1/c space group. K(1) is bonded in a 9-coordinate geometry to one N(3), three equivalent N(1), two equivalent O(1), and three equivalent O(2) atoms. C(1) is bonded in a linear geometry to one N(1) and one N(3) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a distorted single-bond geometry to three equivalent K(1) and one C(1) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one N(3), one O(1), and one O(2) atom. In the third N site, N(3) is bonded in a distorted single-bond geometry to one K(1), one C(1), and one N(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent K(1) and one N(2) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to three equivalent K(1) and one N(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_KCN3O2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.789
_cell_length_b   6.971
_cell_length_c   8.722
_cell_angle_alpha   70.997
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   447.769
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.095  0.148  0.651  1.0
  K  K1  1  0.405  0.148  0.151  1.0
  K  K2  1  0.905  0.852  0.349  1.0
  K  K3  1  0.595  0.852  0.849  1.0
  C  C4  1  0.567  0.570  0.292  1.0
  C  C5  1  0.067  0.430  0.208  1.0
  C  C6  1  0.933  0.570  0.792  1.0
  C  C7  1  0.433  0.430  0.708  1.0
  N  N8  1  0.052  0.254  0.272  1.0
  N  N9  1  0.701  0.299  0.457  1.0
  N  N10  1  0.799  0.299  0.957  1.0
  N  N11  1  0.948  0.746  0.728  1.0
  N  N12  1  0.448  0.254  0.772  1.0
  N  N13  1  0.930  0.370  0.853  1.0
  N  N14  1  0.070  0.630  0.147  1.0
  N  N15  1  0.552  0.746  0.228  1.0
  N  N16  1  0.299  0.701  0.543  1.0
  N  N17  1  0.570  0.370  0.353  1.0
  N  N18  1  0.201  0.701  0.043  1.0
  N  N19  1  0.430  0.630  0.647  1.0
  O  O20  1  0.697  0.419  0.993  1.0
  O  O21  1  0.803  0.419  0.493  1.0
  O  O22  1  0.303  0.581  0.007  1.0
  O  O23  1  0.283  0.890  0.485  1.0
  O  O24  1  0.217  0.890  0.985  1.0
  O  O25  1  0.197  0.581  0.507  1.0
  O  O26  1  0.783  0.110  0.015  1.0
  O  O27  1  0.717  0.110  0.515  1.0
[/CIF]
.
The material structure described by KCN3O2 crystallizes in the monoclinic P2_1/c space group. K(1) is bonded in a 9-coordinate geometry to one N(3), three equivalent N(1), two equivalent O(1), and three equivalent O(2) atoms. C(1) is bonded in a linear geometry to one N(1) and one N(3) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a distorted single-bond geometry to three equivalent K(1) and one C(1) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one N(3), one O(1), and one O(2) atom. In the third N site, N(3) is bonded in a distorted single-bond geometry to one K(1), one C(1), and one N(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent K(1) and one N(2) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to three equivalent K(1) and one N(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_KCN3O2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.789
_cell_length_b   6.971
_cell_length_c   8.722
_cell_angle_alpha   70.997
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   447.769
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.095  0.148  0.651  1.0
  K  K1  1  0.405  0.148  0.151  1.0
  K  K2  1  0.905  0.852  0.349  1.0
  K  K3  1  0.595  0.852  0.849  1.0
  C  C4  1  0.567  0.570  0.292  1.0
  C  C5  1  0.067  0.430  0.208  1.0
  C  C6  1  0.933  0.570  0.792  1.0
  C  C7  1  0.433  0.430  0.708  1.0
  N  N8  1  0.052  0.254  0.272  1.0
  N  N9  1  0.701  0.299  0.457  1.0
  N  N10  1  0.799  0.299  0.957  1.0
  N  N11  1  0.948  0.746  0.728  1.0
  N  N12  1  0.448  0.254  0.772  1.0
  N  N13  1  0.930  0.370  0.853  1.0
  N  N14  1  0.070  0.630  0.147  1.0
  N  N15  1  0.552  0.746  0.228  1.0
  N  N16  1  0.299  0.701  0.543  1.0
  N  N17  1  0.570  0.370  0.353  1.0
  N  N18  1  0.201  0.701  0.043  1.0
  N  N19  1  0.430  0.630  0.647  1.0
  O  O20  1  0.697  0.419  0.993  1.0
  O  O21  1  0.803  0.419  0.493  1.0
  O  O22  1  0.303  0.581  0.007  1.0
  O  O23  1  0.283  0.890  0.485  1.0
  O  O24  1  0.217  0.890  0.985  1.0
  O  O25  1  0.197  0.581  0.507  1.0
  O  O26  1  0.783  0.110  0.015  1.0
  O  O27  1  0.717  0.110  0.515  1.0
[/CIF]
.