The material structure described by Ti(CrS2)2 crystallizes in the monoclinic Cm space group. Ti(1) is bonded to one S(2), one S(3), two equivalent S(1), and two equivalent S(4) atoms to form TiS6 octahedra that share corners with six equivalent Cr(2)S6 octahedra, edges with two equivalent Ti(1)S6 octahedra, edges with four equivalent Cr(1)S6 octahedra, and  a faceface with one Cr(2)S6 octahedra. The corner-sharing octahedral tilt angles range from 49-53°. There are two inequivalent Cr sites. In the first Cr site, Cr(1) is bonded to one S(1), one S(4), two equivalent S(2), and two equivalent S(3) atoms to form CrS6 octahedra that share corners with six equivalent Cr(2)S6 octahedra, edges with two equivalent Cr(1)S6 octahedra, edges with four equivalent Ti(1)S6 octahedra, and  a faceface with one Cr(2)S6 octahedra. The corner-sharing octahedral tilt angles range from 46-52°. In the second Cr site, Cr(2) is bonded to one S(3), one S(4), two equivalent S(1), and two equivalent S(2) atoms to form CrS6 octahedra that share corners with six equivalent Ti(1)S6 octahedra, corners with six equivalent Cr(1)S6 octahedra, edges with two equivalent Cr(2)S6 octahedra,  a faceface with one Ti(1)S6 octahedra, and  a faceface with one Cr(1)S6 octahedra. The corner-sharing octahedral tilt angles range from 46-53°. There are four inequivalent S sites. In the first S site, S(1) is bonded to two equivalent Ti(1), one Cr(1), and two equivalent Cr(2) atoms to form distorted STi2Cr3 trigonal bipyramids that share corners with two equivalent S(2)TiCr4 trigonal bipyramids, edges with two equivalent S(1)Ti2Cr3 trigonal bipyramids, and edges with three equivalent S(2)TiCr4 trigonal bipyramids. In the second S site, S(2) is bonded to one Ti(1), two equivalent Cr(1), and two equivalent Cr(2) atoms to form distorted STiCr4 trigonal bipyramids that share corners with two equivalent S(1)Ti2Cr3 trigonal bipyramids, edges with two equivalent S(2)TiCr4 trigonal bipyramids, and edges with three equivalent S(1)Ti2Cr3 trigonal bipyramids. In the third S site, S(3) is bonded in a rectangular see-saw-like geometry to one Ti(1), one Cr(2), and two equivalent Cr(1) atoms. In the fourth S site, S(4) is bonded in a rectangular see-saw-like geometry to two equivalent Ti(1), one Cr(1), and one Cr(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ti(CrS2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.602
_cell_length_b   6.602
_cell_length_c   6.040
_cell_angle_alpha   64.604
_cell_angle_beta   64.604
_cell_angle_gamma   30.299
_symmetry_Int_Tables_number   1
_cell_volume   118.973
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.758  0.758  0.217  1.0
  Cr  Cr1  1  0.238  0.238  0.783  1.0
  Cr  Cr2  1  0.504  0.504  0.496  1.0
  S  S3  1  0.133  0.133  0.527  1.0
  S  S4  1  0.868  0.868  0.483  1.0
  S  S5  1  0.619  0.619  0.048  1.0
  S  S6  1  0.379  0.379  0.947  1.0
[/CIF]
.
The material structure described by Ti(CrS2)2 crystallizes in the monoclinic Cm space group. Ti(1) is bonded to one S(2), one S(3), two equivalent S(1), and two equivalent S(4) atoms to form TiS6 octahedra that share corners with six equivalent Cr(2)S6 octahedra, edges with two equivalent Ti(1)S6 octahedra, edges with four equivalent Cr(1)S6 octahedra, and  a faceface with one Cr(2)S6 octahedra. The corner-sharing octahedral tilt angles range from 49-53°. There are two inequivalent Cr sites. In the first Cr site, Cr(1) is bonded to one S(1), one S(4), two equivalent S(2), and two equivalent S(3) atoms to form CrS6 octahedra that share corners with six equivalent Cr(2)S6 octahedra, edges with two equivalent Cr(1)S6 octahedra, edges with four equivalent Ti(1)S6 octahedra, and  a faceface with one Cr(2)S6 octahedra. The corner-sharing octahedral tilt angles range from 46-52°. In the second Cr site, Cr(2) is bonded to one S(3), one S(4), two equivalent S(1), and two equivalent S(2) atoms to form CrS6 octahedra that share corners with six equivalent Ti(1)S6 octahedra, corners with six equivalent Cr(1)S6 octahedra, edges with two equivalent Cr(2)S6 octahedra,  a faceface with one Ti(1)S6 octahedra, and  a faceface with one Cr(1)S6 octahedra. The corner-sharing octahedral tilt angles range from 46-53°. There are four inequivalent S sites. In the first S site, S(1) is bonded to two equivalent Ti(1), one Cr(1), and two equivalent Cr(2) atoms to form distorted STi2Cr3 trigonal bipyramids that share corners with two equivalent S(2)TiCr4 trigonal bipyramids, edges with two equivalent S(1)Ti2Cr3 trigonal bipyramids, and edges with three equivalent S(2)TiCr4 trigonal bipyramids. In the second S site, S(2) is bonded to one Ti(1), two equivalent Cr(1), and two equivalent Cr(2) atoms to form distorted STiCr4 trigonal bipyramids that share corners with two equivalent S(1)Ti2Cr3 trigonal bipyramids, edges with two equivalent S(2)TiCr4 trigonal bipyramids, and edges with three equivalent S(1)Ti2Cr3 trigonal bipyramids. In the third S site, S(3) is bonded in a rectangular see-saw-like geometry to one Ti(1), one Cr(2), and two equivalent Cr(1) atoms. In the fourth S site, S(4) is bonded in a rectangular see-saw-like geometry to two equivalent Ti(1), one Cr(1), and one Cr(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ti(CrS2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.602
_cell_length_b   6.602
_cell_length_c   6.040
_cell_angle_alpha   64.604
_cell_angle_beta   64.604
_cell_angle_gamma   30.299
_symmetry_Int_Tables_number   1
_cell_volume   118.973
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.758  0.758  0.217  1.0
  Cr  Cr1  1  0.238  0.238  0.783  1.0
  Cr  Cr2  1  0.504  0.504  0.496  1.0
  S  S3  1  0.133  0.133  0.527  1.0
  S  S4  1  0.868  0.868  0.483  1.0
  S  S5  1  0.619  0.619  0.048  1.0
  S  S6  1  0.379  0.379  0.947  1.0
[/CIF]
.