The material described by FeCl4N2S3Cl is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four tetrachloroferrat(iii) molecules and four N2S3Cl clusters. In each N2S3Cl cluster, there are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one S(1) and one S(3) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one S(2) and one S(3) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a distorted water-like geometry to one N(1) and one Cl(1) atom. In the second S site, S(2) is bonded in a single-bond geometry to one N(2) atom. In the third S site, S(3) is bonded in a water-like geometry to one N(1) and one N(2) atom. Cl(1) is bonded in a single-bond geometry to one S(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_FeS3N2Cl5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.897
_cell_length_b   9.577
_cell_length_c   14.915
_cell_angle_alpha   51.752
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1222.422
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Fe  Fe0  1  0.366  0.218  0.309  1.0
  Fe  Fe1  1  0.866  0.782  0.191  1.0
  Fe  Fe2  1  0.634  0.782  0.691  1.0
  Fe  Fe3  1  0.134  0.218  0.809  1.0
  S  S4  1  0.235  0.668  0.388  1.0
  S  S5  1  0.735  0.332  0.112  1.0
  S  S6  1  0.252  0.845  0.195  1.0
  S  S7  1  0.248  0.845  0.695  1.0
  S  S8  1  0.748  0.155  0.805  1.0
  S  S9  1  0.765  0.332  0.612  1.0
  S  S10  1  0.031  0.676  0.809  1.0
  S  S11  1  0.265  0.668  0.888  1.0
  S  S12  1  0.469  0.676  0.309  1.0
  S  S13  1  0.752  0.155  0.305  1.0
  S  S14  1  0.531  0.324  0.691  1.0
  S  S15  1  0.969  0.324  0.191  1.0
  N  N16  1  0.623  0.370  0.590  1.0
  N  N17  1  0.392  0.797  0.196  1.0
  N  N18  1  0.877  0.370  0.090  1.0
  N  N19  1  0.377  0.630  0.410  1.0
  N  N20  1  0.108  0.797  0.696  1.0
  N  N21  1  0.608  0.203  0.804  1.0
  N  N22  1  0.892  0.203  0.304  1.0
  N  N23  1  0.123  0.630  0.910  1.0
  Cl  Cl24  1  0.352  0.444  0.920  1.0
  Cl  Cl25  1  0.528  0.747  0.581  1.0
  Cl  Cl26  1  0.028  0.253  0.919  1.0
  Cl  Cl27  1  0.710  0.965  0.098  1.0
  Cl  Cl28  1  0.012  0.110  0.744  1.0
  Cl  Cl29  1  0.794  0.521  0.337  1.0
  Cl  Cl30  1  0.488  0.110  0.244  1.0
  Cl  Cl31  1  0.206  0.479  0.663  1.0
  Cl  Cl32  1  0.472  0.253  0.419  1.0
  Cl  Cl33  1  0.290  0.035  0.902  1.0
  Cl  Cl34  1  0.706  0.521  0.837  1.0
  Cl  Cl35  1  0.294  0.479  0.163  1.0
  Cl  Cl36  1  0.148  0.444  0.420  1.0
  Cl  Cl37  1  0.988  0.890  0.256  1.0
  Cl  Cl38  1  0.210  0.035  0.402  1.0
  Cl  Cl39  1  0.790  0.965  0.598  1.0
  Cl  Cl40  1  0.648  0.556  0.080  1.0
  Cl  Cl41  1  0.852  0.556  0.580  1.0
  Cl  Cl42  1  0.512  0.890  0.756  1.0
  Cl  Cl43  1  0.972  0.747  0.081  1.0
[/CIF]
.
The material described by FeCl4N2S3Cl is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four tetrachloroferrat(iii) molecules and four N2S3Cl clusters. In each N2S3Cl cluster, there are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one S(1) and one S(3) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one S(2) and one S(3) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a distorted water-like geometry to one N(1) and one Cl(1) atom. In the second S site, S(2) is bonded in a single-bond geometry to one N(2) atom. In the third S site, S(3) is bonded in a water-like geometry to one N(1) and one N(2) atom. Cl(1) is bonded in a single-bond geometry to one S(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_FeS3N2Cl5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.897
_cell_length_b   9.577
_cell_length_c   14.915
_cell_angle_alpha   51.752
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1222.422
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Fe  Fe0  1  0.366  0.218  0.309  1.0
  Fe  Fe1  1  0.866  0.782  0.191  1.0
  Fe  Fe2  1  0.634  0.782  0.691  1.0
  Fe  Fe3  1  0.134  0.218  0.809  1.0
  S  S4  1  0.235  0.668  0.388  1.0
  S  S5  1  0.735  0.332  0.112  1.0
  S  S6  1  0.252  0.845  0.195  1.0
  S  S7  1  0.248  0.845  0.695  1.0
  S  S8  1  0.748  0.155  0.805  1.0
  S  S9  1  0.765  0.332  0.612  1.0
  S  S10  1  0.031  0.676  0.809  1.0
  S  S11  1  0.265  0.668  0.888  1.0
  S  S12  1  0.469  0.676  0.309  1.0
  S  S13  1  0.752  0.155  0.305  1.0
  S  S14  1  0.531  0.324  0.691  1.0
  S  S15  1  0.969  0.324  0.191  1.0
  N  N16  1  0.623  0.370  0.590  1.0
  N  N17  1  0.392  0.797  0.196  1.0
  N  N18  1  0.877  0.370  0.090  1.0
  N  N19  1  0.377  0.630  0.410  1.0
  N  N20  1  0.108  0.797  0.696  1.0
  N  N21  1  0.608  0.203  0.804  1.0
  N  N22  1  0.892  0.203  0.304  1.0
  N  N23  1  0.123  0.630  0.910  1.0
  Cl  Cl24  1  0.352  0.444  0.920  1.0
  Cl  Cl25  1  0.528  0.747  0.581  1.0
  Cl  Cl26  1  0.028  0.253  0.919  1.0
  Cl  Cl27  1  0.710  0.965  0.098  1.0
  Cl  Cl28  1  0.012  0.110  0.744  1.0
  Cl  Cl29  1  0.794  0.521  0.337  1.0
  Cl  Cl30  1  0.488  0.110  0.244  1.0
  Cl  Cl31  1  0.206  0.479  0.663  1.0
  Cl  Cl32  1  0.472  0.253  0.419  1.0
  Cl  Cl33  1  0.290  0.035  0.902  1.0
  Cl  Cl34  1  0.706  0.521  0.837  1.0
  Cl  Cl35  1  0.294  0.479  0.163  1.0
  Cl  Cl36  1  0.148  0.444  0.420  1.0
  Cl  Cl37  1  0.988  0.890  0.256  1.0
  Cl  Cl38  1  0.210  0.035  0.402  1.0
  Cl  Cl39  1  0.790  0.965  0.598  1.0
  Cl  Cl40  1  0.648  0.556  0.080  1.0
  Cl  Cl41  1  0.852  0.556  0.580  1.0
  Cl  Cl42  1  0.512  0.890  0.756  1.0
  Cl  Cl43  1  0.972  0.747  0.081  1.0
[/CIF]
.