The compound described by Li3Ag3Ge2 crystallizes in the orthorhombic Pmmm space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded to two equivalent Ag(1), two equivalent Ag(2), two equivalent Ag(3), and four equivalent Ge(1) atoms to form distorted LiAg6Ge4 cuboctahedra that share corners with four equivalent Ag(2)Li8Ge4 cuboctahedra, corners with four equivalent Ge(1)Li6Ag6 cuboctahedra, corners with ten equivalent Li(1)Ag6Ge4 cuboctahedra,  an edgeedge with one Li(1)Ag6Ge4 cuboctahedra, edges with two equivalent Ag(2)Li8Ge4 cuboctahedra, edges with four equivalent Li(2)Ag4Ge4 cuboctahedra, edges with four equivalent Ag(1)Li4Ag4Ge4 cuboctahedra, edges with four equivalent Ag(3)Li4Ag4Ge4 cuboctahedra, edges with four equivalent Ge(1)Li6Ag6 cuboctahedra, faces with two equivalent Li(2)Ag4Ge4 cuboctahedra, faces with two equivalent Ag(1)Li4Ag4Ge4 cuboctahedra, faces with two equivalent Ag(3)Li4Ag4Ge4 cuboctahedra, faces with four equivalent Ge(1)Li6Ag6 cuboctahedra, and faces with five equivalent Li(1)Ag6Ge4 cuboctahedra. In the second Li site, Li(2) is bonded to four equivalent Ag(2) and four equivalent Ge(1) atoms to form distorted LiAg4Ge4 cuboctahedra that share corners with four equivalent Li(2)Ag4Ge4 cuboctahedra, corners with four equivalent Ag(1)Li4Ag4Ge4 cuboctahedra, corners with eight equivalent Ag(3)Li4Ag4Ge4 cuboctahedra, corners with eight equivalent Ge(1)Li6Ag6 cuboctahedra, edges with two equivalent Li(2)Ag4Ge4 cuboctahedra, edges with two equivalent Ag(1)Li4Ag4Ge4 cuboctahedra, edges with four equivalent Ag(2)Li8Ge4 cuboctahedra, edges with four equivalent Ge(1)Li6Ag6 cuboctahedra, edges with eight equivalent Li(1)Ag6Ge4 cuboctahedra, faces with two equivalent Li(2)Ag4Ge4 cuboctahedra, and faces with four equivalent Li(1)Ag6Ge4 cuboctahedra. There are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to four equivalent Li(1), four equivalent Ag(3), and four equivalent Ge(1) atoms to form distorted AgLi4Ag4Ge4 cuboctahedra that share corners with four equivalent Li(2)Ag4Ge4 cuboctahedra, corners with four equivalent Ag(1)Li4Ag4Ge4 cuboctahedra, edges with two equivalent Li(2)Ag4Ge4 cuboctahedra, edges with eight equivalent Li(1)Ag6Ge4 cuboctahedra, edges with eight equivalent Ag(2)Li8Ge4 cuboctahedra, edges with eight equivalent Ge(1)Li6Ag6 cuboctahedra, faces with four equivalent Li(1)Ag6Ge4 cuboctahedra, faces with four equivalent Ag(1)Li4Ag4Ge4 cuboctahedra, faces with four equivalent Ag(3)Li4Ag4Ge4 cuboctahedra, and faces with four equivalent Ge(1)Li6Ag6 cuboctahedra. In the second Ag site, Ag(2) is bonded to four equivalent Li(1), four equivalent Li(2), and four equivalent Ge(1) atoms to form AgLi8Ge4 cuboctahedra that share corners with four equivalent Ag(2)Li8Ge4 cuboctahedra, corners with eight equivalent Li(1)Ag6Ge4 cuboctahedra, corners with eight equivalent Ag(3)Li4Ag4Ge4 cuboctahedra, edges with four equivalent Li(2)Ag4Ge4 cuboctahedra, edges with four equivalent Li(1)Ag6Ge4 cuboctahedra, edges with eight equivalent Ag(1)Li4Ag4Ge4 cuboctahedra, edges with eight equivalent Ge(1)Li6Ag6 cuboctahedra, faces with two equivalent Ag(3)Li4Ag4Ge4 cuboctahedra, faces with four equivalent Ag(2)Li8Ge4 cuboctahedra, and faces with four equivalent Ge(1)Li6Ag6 cuboctahedra. In the third Ag site, Ag(3) is bonded to four equivalent Li(1), four equivalent Ag(1), and four equivalent Ge(1) atoms to form distorted AgLi4Ag4Ge4 cuboctahedra that share corners with four equivalent Ag(3)Li4Ag4Ge4 cuboctahedra, corners with eight equivalent Li(2)Ag4Ge4 cuboctahedra, corners with eight equivalent Ag(2)Li8Ge4 cuboctahedra, edges with eight equivalent Li(1)Ag6Ge4 cuboctahedra, edges with eight equivalent Ge(1)Li6Ag6 cuboctahedra, faces with two equivalent Ag(2)Li8Ge4 cuboctahedra, faces with four equivalent Li(1)Ag6Ge4 cuboctahedra, faces with four equivalent Ag(1)Li4Ag4Ge4 cuboctahedra, faces with four equivalent Ag(3)Li4Ag4Ge4 cuboctahedra, and faces with four equivalent Ge(1)Li6Ag6 cuboctahedra. Ge(1) is bonded to two equivalent Li(2), four equivalent Li(1), two equivalent Ag(1), two equivalent Ag(2), and two equivalent Ag(3) atoms to form GeLi6Ag6 cuboctahedra that share corners with four equivalent Li(2)Ag4Ge4 cuboctahedra, corners with four equivalent Li(1)Ag6Ge4 cuboctahedra, corners with twelve equivalent Ge(1)Li6Ag6 cuboctahedra, edges with two equivalent Li(2)Ag4Ge4 cuboctahedra, edges with four equivalent Li(1)Ag6Ge4 cuboctahedra, edges with four equivalent Ag(1)Li4Ag4Ge4 cuboctahedra, edges with four equivalent Ag(3)Li4Ag4Ge4 cuboctahedra, edges with four equivalent Ag(2)Li8Ge4 cuboctahedra, faces with two equivalent Ag(1)Li4Ag4Ge4 cuboctahedra, faces with two equivalent Ag(3)Li4Ag4Ge4 cuboctahedra, faces with two equivalent Ag(2)Li8Ge4 cuboctahedra, faces with four equivalent Li(1)Ag6Ge4 cuboctahedra, and faces with six equivalent Ge(1)Li6Ag6 cuboctahedra. is represented by the CIF card [CIF]
data_Li3Ag3Ge2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.047
_cell_length_b   4.067
_cell_length_c   7.960
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   131.017
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.500  0.500  0.749  1.0
  Li  Li1  1  0.500  0.500  0.251  1.0
  Li  Li2  1  0.500  0.000  0.000  1.0
  Ag  Ag3  1  0.500  0.000  0.500  1.0
  Ag  Ag4  1  0.000  0.500  0.000  1.0
  Ag  Ag5  1  0.000  0.500  0.500  1.0
  Ge  Ge6  1  0.000  0.000  0.751  1.0
  Ge  Ge7  1  0.000  0.000  0.249  1.0
[/CIF]
.
The compound described by Li3Ag3Ge2 crystallizes in the orthorhombic Pmmm space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded to two equivalent Ag(1), two equivalent Ag(2), two equivalent Ag(3), and four equivalent Ge(1) atoms to form distorted LiAg6Ge4 cuboctahedra that share corners with four equivalent Ag(2)Li8Ge4 cuboctahedra, corners with four equivalent Ge(1)Li6Ag6 cuboctahedra, corners with ten equivalent Li(1)Ag6Ge4 cuboctahedra,  an edgeedge with one Li(1)Ag6Ge4 cuboctahedra, edges with two equivalent Ag(2)Li8Ge4 cuboctahedra, edges with four equivalent Li(2)Ag4Ge4 cuboctahedra, edges with four equivalent Ag(1)Li4Ag4Ge4 cuboctahedra, edges with four equivalent Ag(3)Li4Ag4Ge4 cuboctahedra, edges with four equivalent Ge(1)Li6Ag6 cuboctahedra, faces with two equivalent Li(2)Ag4Ge4 cuboctahedra, faces with two equivalent Ag(1)Li4Ag4Ge4 cuboctahedra, faces with two equivalent Ag(3)Li4Ag4Ge4 cuboctahedra, faces with four equivalent Ge(1)Li6Ag6 cuboctahedra, and faces with five equivalent Li(1)Ag6Ge4 cuboctahedra. In the second Li site, Li(2) is bonded to four equivalent Ag(2) and four equivalent Ge(1) atoms to form distorted LiAg4Ge4 cuboctahedra that share corners with four equivalent Li(2)Ag4Ge4 cuboctahedra, corners with four equivalent Ag(1)Li4Ag4Ge4 cuboctahedra, corners with eight equivalent Ag(3)Li4Ag4Ge4 cuboctahedra, corners with eight equivalent Ge(1)Li6Ag6 cuboctahedra, edges with two equivalent Li(2)Ag4Ge4 cuboctahedra, edges with two equivalent Ag(1)Li4Ag4Ge4 cuboctahedra, edges with four equivalent Ag(2)Li8Ge4 cuboctahedra, edges with four equivalent Ge(1)Li6Ag6 cuboctahedra, edges with eight equivalent Li(1)Ag6Ge4 cuboctahedra, faces with two equivalent Li(2)Ag4Ge4 cuboctahedra, and faces with four equivalent Li(1)Ag6Ge4 cuboctahedra. There are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to four equivalent Li(1), four equivalent Ag(3), and four equivalent Ge(1) atoms to form distorted AgLi4Ag4Ge4 cuboctahedra that share corners with four equivalent Li(2)Ag4Ge4 cuboctahedra, corners with four equivalent Ag(1)Li4Ag4Ge4 cuboctahedra, edges with two equivalent Li(2)Ag4Ge4 cuboctahedra, edges with eight equivalent Li(1)Ag6Ge4 cuboctahedra, edges with eight equivalent Ag(2)Li8Ge4 cuboctahedra, edges with eight equivalent Ge(1)Li6Ag6 cuboctahedra, faces with four equivalent Li(1)Ag6Ge4 cuboctahedra, faces with four equivalent Ag(1)Li4Ag4Ge4 cuboctahedra, faces with four equivalent Ag(3)Li4Ag4Ge4 cuboctahedra, and faces with four equivalent Ge(1)Li6Ag6 cuboctahedra. In the second Ag site, Ag(2) is bonded to four equivalent Li(1), four equivalent Li(2), and four equivalent Ge(1) atoms to form AgLi8Ge4 cuboctahedra that share corners with four equivalent Ag(2)Li8Ge4 cuboctahedra, corners with eight equivalent Li(1)Ag6Ge4 cuboctahedra, corners with eight equivalent Ag(3)Li4Ag4Ge4 cuboctahedra, edges with four equivalent Li(2)Ag4Ge4 cuboctahedra, edges with four equivalent Li(1)Ag6Ge4 cuboctahedra, edges with eight equivalent Ag(1)Li4Ag4Ge4 cuboctahedra, edges with eight equivalent Ge(1)Li6Ag6 cuboctahedra, faces with two equivalent Ag(3)Li4Ag4Ge4 cuboctahedra, faces with four equivalent Ag(2)Li8Ge4 cuboctahedra, and faces with four equivalent Ge(1)Li6Ag6 cuboctahedra. In the third Ag site, Ag(3) is bonded to four equivalent Li(1), four equivalent Ag(1), and four equivalent Ge(1) atoms to form distorted AgLi4Ag4Ge4 cuboctahedra that share corners with four equivalent Ag(3)Li4Ag4Ge4 cuboctahedra, corners with eight equivalent Li(2)Ag4Ge4 cuboctahedra, corners with eight equivalent Ag(2)Li8Ge4 cuboctahedra, edges with eight equivalent Li(1)Ag6Ge4 cuboctahedra, edges with eight equivalent Ge(1)Li6Ag6 cuboctahedra, faces with two equivalent Ag(2)Li8Ge4 cuboctahedra, faces with four equivalent Li(1)Ag6Ge4 cuboctahedra, faces with four equivalent Ag(1)Li4Ag4Ge4 cuboctahedra, faces with four equivalent Ag(3)Li4Ag4Ge4 cuboctahedra, and faces with four equivalent Ge(1)Li6Ag6 cuboctahedra. Ge(1) is bonded to two equivalent Li(2), four equivalent Li(1), two equivalent Ag(1), two equivalent Ag(2), and two equivalent Ag(3) atoms to form GeLi6Ag6 cuboctahedra that share corners with four equivalent Li(2)Ag4Ge4 cuboctahedra, corners with four equivalent Li(1)Ag6Ge4 cuboctahedra, corners with twelve equivalent Ge(1)Li6Ag6 cuboctahedra, edges with two equivalent Li(2)Ag4Ge4 cuboctahedra, edges with four equivalent Li(1)Ag6Ge4 cuboctahedra, edges with four equivalent Ag(1)Li4Ag4Ge4 cuboctahedra, edges with four equivalent Ag(3)Li4Ag4Ge4 cuboctahedra, edges with four equivalent Ag(2)Li8Ge4 cuboctahedra, faces with two equivalent Ag(1)Li4Ag4Ge4 cuboctahedra, faces with two equivalent Ag(3)Li4Ag4Ge4 cuboctahedra, faces with two equivalent Ag(2)Li8Ge4 cuboctahedra, faces with four equivalent Li(1)Ag6Ge4 cuboctahedra, and faces with six equivalent Ge(1)Li6Ag6 cuboctahedra. is represented by the CIF card [CIF]
data_Li3Ag3Ge2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.047
_cell_length_b   4.067
_cell_length_c   7.960
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   131.017
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.500  0.500  0.749  1.0
  Li  Li1  1  0.500  0.500  0.251  1.0
  Li  Li2  1  0.500  0.000  0.000  1.0
  Ag  Ag3  1  0.500  0.000  0.500  1.0
  Ag  Ag4  1  0.000  0.500  0.000  1.0
  Ag  Ag5  1  0.000  0.500  0.500  1.0
  Ge  Ge6  1  0.000  0.000  0.751  1.0
  Ge  Ge7  1  0.000  0.000  0.249  1.0
[/CIF]
.