The material described by AuSeCl7 is black P structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four AuSeCl7 clusters. Au(1) is bonded in a square co-planar geometry to one Cl(2), one Cl(3), one Cl(4), and one Cl(5) atom. Se(1) is bonded in a 3-coordinate geometry to one Cl(1), one Cl(2), one Cl(3), one Cl(6), and one Cl(7) atom. There are seven inequivalent Cl sites. In the first Cl site, Cl(7) is bonded in a single-bond geometry to one Se(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Se(1) atom. In the third Cl site, Cl(2) is bonded in a distorted L-shaped geometry to one Au(1) and one Se(1) atom. In the fourth Cl site, Cl(3) is bonded in a distorted L-shaped geometry to one Au(1) and one Se(1) atom. In the fifth Cl site, Cl(4) is bonded in a distorted single-bond geometry to one Au(1) atom. In the sixth Cl site, Cl(5) is bonded in a single-bond geometry to one Au(1) atom. In the seventh Cl site, Cl(6) is bonded in a single-bond geometry to one Se(1) atom. is represented by the CIF file [CIF]
data_AuSeCl7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.205
_cell_length_b   8.655
_cell_length_c   12.395
_cell_angle_alpha   71.483
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1038.143
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Au  Au0  1  0.085  0.781  0.050  1.0
  Au  Au1  1  0.585  0.219  0.450  1.0
  Au  Au2  1  0.915  0.219  0.950  1.0
  Au  Au3  1  0.415  0.781  0.550  1.0
  Se  Se4  1  0.711  0.765  0.997  1.0
  Se  Se5  1  0.211  0.235  0.503  1.0
  Se  Se6  1  0.289  0.235  0.003  1.0
  Se  Se7  1  0.789  0.765  0.497  1.0
  Cl  Cl8  1  0.704  0.533  0.963  1.0
  Cl  Cl9  1  0.204  0.467  0.537  1.0
  Cl  Cl10  1  0.296  0.467  0.037  1.0
  Cl  Cl11  1  0.796  0.533  0.463  1.0
  Cl  Cl12  1  0.582  0.625  0.655  1.0
  Cl  Cl13  1  0.082  0.375  0.845  1.0
  Cl  Cl14  1  0.418  0.375  0.345  1.0
  Cl  Cl15  1  0.918  0.625  0.155  1.0
  Cl  Cl16  1  0.539  0.841  0.385  1.0
  Cl  Cl17  1  0.039  0.159  0.115  1.0
  Cl  Cl18  1  0.461  0.159  0.615  1.0
  Cl  Cl19  1  0.961  0.841  0.885  1.0
  Cl  Cl20  1  0.247  0.935  0.445  1.0
  Cl  Cl21  1  0.747  0.065  0.055  1.0
  Cl  Cl22  1  0.753  0.065  0.555  1.0
  Cl  Cl23  1  0.253  0.935  0.945  1.0
  Cl  Cl24  1  0.290  0.717  0.711  1.0
  Cl  Cl25  1  0.790  0.283  0.789  1.0
  Cl  Cl26  1  0.710  0.283  0.289  1.0
  Cl  Cl27  1  0.210  0.717  0.211  1.0
  Cl  Cl28  1  0.559  0.713  0.126  1.0
  Cl  Cl29  1  0.059  0.287  0.374  1.0
  Cl  Cl30  1  0.441  0.287  0.874  1.0
  Cl  Cl31  1  0.941  0.713  0.626  1.0
  Cl  Cl32  1  0.902  0.900  0.350  1.0
  Cl  Cl33  1  0.402  0.100  0.150  1.0
  Cl  Cl34  1  0.098  0.100  0.650  1.0
  Cl  Cl35  1  0.598  0.900  0.850  1.0
[/CIF]
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The material described by AuSeCl7 is black P structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four AuSeCl7 clusters. Au(1) is bonded in a square co-planar geometry to one Cl(2), one Cl(3), one Cl(4), and one Cl(5) atom. Se(1) is bonded in a 3-coordinate geometry to one Cl(1), one Cl(2), one Cl(3), one Cl(6), and one Cl(7) atom. There are seven inequivalent Cl sites. In the first Cl site, Cl(7) is bonded in a single-bond geometry to one Se(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Se(1) atom. In the third Cl site, Cl(2) is bonded in a distorted L-shaped geometry to one Au(1) and one Se(1) atom. In the fourth Cl site, Cl(3) is bonded in a distorted L-shaped geometry to one Au(1) and one Se(1) atom. In the fifth Cl site, Cl(4) is bonded in a distorted single-bond geometry to one Au(1) atom. In the sixth Cl site, Cl(5) is bonded in a single-bond geometry to one Au(1) atom. In the seventh Cl site, Cl(6) is bonded in a single-bond geometry to one Se(1) atom. is represented by the CIF file [CIF]
data_AuSeCl7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.205
_cell_length_b   8.655
_cell_length_c   12.395
_cell_angle_alpha   71.483
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1038.143
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Au  Au0  1  0.085  0.781  0.050  1.0
  Au  Au1  1  0.585  0.219  0.450  1.0
  Au  Au2  1  0.915  0.219  0.950  1.0
  Au  Au3  1  0.415  0.781  0.550  1.0
  Se  Se4  1  0.711  0.765  0.997  1.0
  Se  Se5  1  0.211  0.235  0.503  1.0
  Se  Se6  1  0.289  0.235  0.003  1.0
  Se  Se7  1  0.789  0.765  0.497  1.0
  Cl  Cl8  1  0.704  0.533  0.963  1.0
  Cl  Cl9  1  0.204  0.467  0.537  1.0
  Cl  Cl10  1  0.296  0.467  0.037  1.0
  Cl  Cl11  1  0.796  0.533  0.463  1.0
  Cl  Cl12  1  0.582  0.625  0.655  1.0
  Cl  Cl13  1  0.082  0.375  0.845  1.0
  Cl  Cl14  1  0.418  0.375  0.345  1.0
  Cl  Cl15  1  0.918  0.625  0.155  1.0
  Cl  Cl16  1  0.539  0.841  0.385  1.0
  Cl  Cl17  1  0.039  0.159  0.115  1.0
  Cl  Cl18  1  0.461  0.159  0.615  1.0
  Cl  Cl19  1  0.961  0.841  0.885  1.0
  Cl  Cl20  1  0.247  0.935  0.445  1.0
  Cl  Cl21  1  0.747  0.065  0.055  1.0
  Cl  Cl22  1  0.753  0.065  0.555  1.0
  Cl  Cl23  1  0.253  0.935  0.945  1.0
  Cl  Cl24  1  0.290  0.717  0.711  1.0
  Cl  Cl25  1  0.790  0.283  0.789  1.0
  Cl  Cl26  1  0.710  0.283  0.289  1.0
  Cl  Cl27  1  0.210  0.717  0.211  1.0
  Cl  Cl28  1  0.559  0.713  0.126  1.0
  Cl  Cl29  1  0.059  0.287  0.374  1.0
  Cl  Cl30  1  0.441  0.287  0.874  1.0
  Cl  Cl31  1  0.941  0.713  0.626  1.0
  Cl  Cl32  1  0.902  0.900  0.350  1.0
  Cl  Cl33  1  0.402  0.100  0.150  1.0
  Cl  Cl34  1  0.098  0.100  0.650  1.0
  Cl  Cl35  1  0.598  0.900  0.850  1.0
[/CIF]
.