The compound described by CuTeO3 crystallizes in the orthorhombic Pnma space group. Cu(1) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(3), and two equivalent O(4) atoms. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a see-saw-like geometry to one O(1), one O(2), and two equivalent O(3) atoms. In the second Te site, Te(2) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(2), and two equivalent O(4) atoms. There are four inequivalent O sites. In the first O site, O(4) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Cu(1) and one Te(2) atom. In the second O site, O(1) is bonded in a 4-coordinate geometry to two equivalent Cu(1), one Te(1), and one Te(2) atom. In the third O site, O(2) is bonded in a 4-coordinate geometry to two equivalent Cu(1), one Te(1), and one Te(2) atom. In the fourth O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Cu(1) and one Te(1) atom. is represented by the CIF card [CIF]
data_CuTeO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.017
_cell_length_b   7.678
_cell_length_c   12.883
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   595.150
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cu  Cu0  1  0.350  0.955  0.095  1.0
  Cu  Cu1  1  0.850  0.045  0.405  1.0
  Cu  Cu2  1  0.650  0.455  0.905  1.0
  Cu  Cu3  1  0.150  0.545  0.595  1.0
  Cu  Cu4  1  0.650  0.045  0.905  1.0
  Cu  Cu5  1  0.150  0.955  0.595  1.0
  Cu  Cu6  1  0.350  0.545  0.095  1.0
  Cu  Cu7  1  0.850  0.455  0.405  1.0
  Te  Te8  1  0.586  0.250  0.656  1.0
  Te  Te9  1  0.086  0.750  0.844  1.0
  Te  Te10  1  0.414  0.750  0.344  1.0
  Te  Te11  1  0.914  0.250  0.156  1.0
  Te  Te12  1  0.679  0.750  0.611  1.0
  Te  Te13  1  0.179  0.250  0.889  1.0
  Te  Te14  1  0.321  0.250  0.389  1.0
  Te  Te15  1  0.821  0.750  0.111  1.0
  O  O16  1  0.943  0.250  0.990  1.0
  O  O17  1  0.443  0.750  0.510  1.0
  O  O18  1  0.057  0.750  0.010  1.0
  O  O19  1  0.557  0.250  0.490  1.0
  O  O20  1  0.576  0.250  0.819  1.0
  O  O21  1  0.076  0.750  0.681  1.0
  O  O22  1  0.424  0.750  0.181  1.0
  O  O23  1  0.924  0.250  0.319  1.0
  O  O24  1  0.097  0.047  0.168  1.0
  O  O25  1  0.597  0.953  0.332  1.0
  O  O26  1  0.903  0.547  0.832  1.0
  O  O27  1  0.403  0.453  0.668  1.0
  O  O28  1  0.903  0.953  0.832  1.0
  O  O29  1  0.403  0.047  0.668  1.0
  O  O30  1  0.097  0.453  0.168  1.0
  O  O31  1  0.597  0.547  0.332  1.0
  O  O32  1  0.654  0.569  0.042  1.0
  O  O33  1  0.154  0.431  0.458  1.0
  O  O34  1  0.346  0.069  0.958  1.0
  O  O35  1  0.846  0.931  0.542  1.0
  O  O36  1  0.346  0.431  0.958  1.0
  O  O37  1  0.846  0.569  0.542  1.0
  O  O38  1  0.654  0.931  0.042  1.0
  O  O39  1  0.154  0.069  0.458  1.0
[/CIF]
.
The compound described by CuTeO3 crystallizes in the orthorhombic Pnma space group. Cu(1) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(3), and two equivalent O(4) atoms. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a see-saw-like geometry to one O(1), one O(2), and two equivalent O(3) atoms. In the second Te site, Te(2) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(2), and two equivalent O(4) atoms. There are four inequivalent O sites. In the first O site, O(4) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Cu(1) and one Te(2) atom. In the second O site, O(1) is bonded in a 4-coordinate geometry to two equivalent Cu(1), one Te(1), and one Te(2) atom. In the third O site, O(2) is bonded in a 4-coordinate geometry to two equivalent Cu(1), one Te(1), and one Te(2) atom. In the fourth O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Cu(1) and one Te(1) atom. is represented by the CIF card [CIF]
data_CuTeO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.017
_cell_length_b   7.678
_cell_length_c   12.883
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   595.150
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cu  Cu0  1  0.350  0.955  0.095  1.0
  Cu  Cu1  1  0.850  0.045  0.405  1.0
  Cu  Cu2  1  0.650  0.455  0.905  1.0
  Cu  Cu3  1  0.150  0.545  0.595  1.0
  Cu  Cu4  1  0.650  0.045  0.905  1.0
  Cu  Cu5  1  0.150  0.955  0.595  1.0
  Cu  Cu6  1  0.350  0.545  0.095  1.0
  Cu  Cu7  1  0.850  0.455  0.405  1.0
  Te  Te8  1  0.586  0.250  0.656  1.0
  Te  Te9  1  0.086  0.750  0.844  1.0
  Te  Te10  1  0.414  0.750  0.344  1.0
  Te  Te11  1  0.914  0.250  0.156  1.0
  Te  Te12  1  0.679  0.750  0.611  1.0
  Te  Te13  1  0.179  0.250  0.889  1.0
  Te  Te14  1  0.321  0.250  0.389  1.0
  Te  Te15  1  0.821  0.750  0.111  1.0
  O  O16  1  0.943  0.250  0.990  1.0
  O  O17  1  0.443  0.750  0.510  1.0
  O  O18  1  0.057  0.750  0.010  1.0
  O  O19  1  0.557  0.250  0.490  1.0
  O  O20  1  0.576  0.250  0.819  1.0
  O  O21  1  0.076  0.750  0.681  1.0
  O  O22  1  0.424  0.750  0.181  1.0
  O  O23  1  0.924  0.250  0.319  1.0
  O  O24  1  0.097  0.047  0.168  1.0
  O  O25  1  0.597  0.953  0.332  1.0
  O  O26  1  0.903  0.547  0.832  1.0
  O  O27  1  0.403  0.453  0.668  1.0
  O  O28  1  0.903  0.953  0.832  1.0
  O  O29  1  0.403  0.047  0.668  1.0
  O  O30  1  0.097  0.453  0.168  1.0
  O  O31  1  0.597  0.547  0.332  1.0
  O  O32  1  0.654  0.569  0.042  1.0
  O  O33  1  0.154  0.431  0.458  1.0
  O  O34  1  0.346  0.069  0.958  1.0
  O  O35  1  0.846  0.931  0.542  1.0
  O  O36  1  0.346  0.431  0.958  1.0
  O  O37  1  0.846  0.569  0.542  1.0
  O  O38  1  0.654  0.931  0.042  1.0
  O  O39  1  0.154  0.069  0.458  1.0
[/CIF]
.