The crystal structure described by (Sn(OCl2)2)2(O2)3 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four trioxidane molecules and four Sn(OCl2)2 clusters. In each Sn(OCl2)2 cluster, Sn(1) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent Cl(1), and two equivalent Cl(2) atoms. O(1) is bonded in a single-bond geometry to one Sn(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Sn(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Sn(1) atom. is represented by the CIF file [CIF]
data_SnCl4O5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.536
_cell_length_b   7.536
_cell_length_c   9.176
_cell_angle_alpha   76.961
_cell_angle_beta   76.961
_cell_angle_gamma   74.632
_symmetry_Int_Tables_number   1
_cell_volume   481.841
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn0  1  0.236  0.764  0.750  1.0
  Sn  Sn1  1  0.764  0.236  0.250  1.0
  Cl  Cl2  1  0.148  0.539  0.632  1.0
  Cl  Cl3  1  0.461  0.852  0.868  1.0
  Cl  Cl4  1  0.852  0.461  0.368  1.0
  Cl  Cl5  1  0.539  0.148  0.132  1.0
  Cl  Cl6  1  0.967  0.796  0.940  1.0
  Cl  Cl7  1  0.204  0.033  0.560  1.0
  Cl  Cl8  1  0.033  0.204  0.060  1.0
  Cl  Cl9  1  0.796  0.967  0.440  1.0
  O  O10  1  0.325  0.471  0.843  1.0
  O  O11  1  0.529  0.675  0.657  1.0
  O  O12  1  0.675  0.529  0.157  1.0
  O  O13  1  0.471  0.325  0.343  1.0
  O  O14  1  0.281  0.565  0.206  1.0
  O  O15  1  0.435  0.719  0.294  1.0
  O  O16  1  0.719  0.435  0.794  1.0
  O  O17  1  0.565  0.281  0.706  1.0
  O  O18  1  0.286  0.714  0.250  1.0
  O  O19  1  0.714  0.286  0.750  1.0
[/CIF]
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The crystal structure described by (Sn(OCl2)2)2(O2)3 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four trioxidane molecules and four Sn(OCl2)2 clusters. In each Sn(OCl2)2 cluster, Sn(1) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent Cl(1), and two equivalent Cl(2) atoms. O(1) is bonded in a single-bond geometry to one Sn(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Sn(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Sn(1) atom. is represented by the CIF file [CIF]
data_SnCl4O5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.536
_cell_length_b   7.536
_cell_length_c   9.176
_cell_angle_alpha   76.961
_cell_angle_beta   76.961
_cell_angle_gamma   74.632
_symmetry_Int_Tables_number   1
_cell_volume   481.841
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn0  1  0.236  0.764  0.750  1.0
  Sn  Sn1  1  0.764  0.236  0.250  1.0
  Cl  Cl2  1  0.148  0.539  0.632  1.0
  Cl  Cl3  1  0.461  0.852  0.868  1.0
  Cl  Cl4  1  0.852  0.461  0.368  1.0
  Cl  Cl5  1  0.539  0.148  0.132  1.0
  Cl  Cl6  1  0.967  0.796  0.940  1.0
  Cl  Cl7  1  0.204  0.033  0.560  1.0
  Cl  Cl8  1  0.033  0.204  0.060  1.0
  Cl  Cl9  1  0.796  0.967  0.440  1.0
  O  O10  1  0.325  0.471  0.843  1.0
  O  O11  1  0.529  0.675  0.657  1.0
  O  O12  1  0.675  0.529  0.157  1.0
  O  O13  1  0.471  0.325  0.343  1.0
  O  O14  1  0.281  0.565  0.206  1.0
  O  O15  1  0.435  0.719  0.294  1.0
  O  O16  1  0.719  0.435  0.794  1.0
  O  O17  1  0.565  0.281  0.706  1.0
  O  O18  1  0.286  0.714  0.250  1.0
  O  O19  1  0.714  0.286  0.750  1.0
[/CIF]
.