The crystal structure described by K2RhH2OCl5 crystallizes in the orthorhombic Pnma space group. K(1) is bonded in a 6-coordinate geometry to one Cl(3), one Cl(4), two equivalent Cl(1), and two equivalent Cl(2) atoms. Rh(1) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one Cl(1), one Cl(2), and one Cl(3) atom. H(1) is bonded in a single-bond geometry to one Cl(4) atom. O(1) is bonded in a single-bond geometry to one Rh(1) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(4) is bonded in a single-bond geometry to one K(1) and one H(1) atom. In the second Cl site, Cl(1) is bonded to four equivalent K(1) and one Rh(1) atom to form distorted corner-sharing ClK4Rh square pyramids. In the third Cl site, Cl(2) is bonded in a 5-coordinate geometry to four equivalent K(1) and one Rh(1) atom. In the fourth Cl site, Cl(3) is bonded in a single-bond geometry to two equivalent K(1) and one Rh(1) atom. is represented by the CIF card [CIF]
data_K2H2RhCl5O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.056
_cell_length_b   9.773
_cell_length_c   14.603
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1149.635
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.802  0.006  0.831  1.0
  K  K1  1  0.698  0.494  0.331  1.0
  K  K2  1  0.198  0.506  0.169  1.0
  K  K3  1  0.302  0.994  0.669  1.0
  K  K4  1  0.198  0.994  0.169  1.0
  K  K5  1  0.302  0.506  0.669  1.0
  K  K6  1  0.802  0.494  0.831  1.0
  K  K7  1  0.698  0.006  0.331  1.0
  H  H8  1  0.338  0.047  0.442  1.0
  H  H9  1  0.162  0.453  0.942  1.0
  H  H10  1  0.662  0.547  0.558  1.0
  H  H11  1  0.838  0.953  0.058  1.0
  H  H12  1  0.662  0.953  0.558  1.0
  H  H13  1  0.838  0.547  0.058  1.0
  H  H14  1  0.338  0.453  0.442  1.0
  H  H15  1  0.162  0.047  0.942  1.0
  Rh  Rh16  1  0.702  0.250  0.105  1.0
  Rh  Rh17  1  0.798  0.250  0.605  1.0
  Rh  Rh18  1  0.298  0.750  0.895  1.0
  Rh  Rh19  1  0.202  0.750  0.395  1.0
  Cl  Cl20  1  0.893  0.250  0.235  1.0
  Cl  Cl21  1  0.607  0.250  0.735  1.0
  Cl  Cl22  1  0.107  0.750  0.765  1.0
  Cl  Cl23  1  0.393  0.750  0.265  1.0
  Cl  Cl24  1  0.464  0.250  0.208  1.0
  Cl  Cl25  1  0.036  0.250  0.708  1.0
  Cl  Cl26  1  0.536  0.750  0.792  1.0
  Cl  Cl27  1  0.964  0.750  0.292  1.0
  Cl  Cl28  1  0.948  0.250  0.008  1.0
  Cl  Cl29  1  0.552  0.250  0.508  1.0
  Cl  Cl30  1  0.052  0.750  0.992  1.0
  Cl  Cl31  1  0.448  0.750  0.492  1.0
  Cl  Cl32  1  0.698  0.917  0.093  1.0
  Cl  Cl33  1  0.802  0.583  0.593  1.0
  Cl  Cl34  1  0.302  0.417  0.907  1.0
  Cl  Cl35  1  0.198  0.083  0.407  1.0
  Cl  Cl36  1  0.302  0.083  0.907  1.0
  Cl  Cl37  1  0.198  0.417  0.407  1.0
  Cl  Cl38  1  0.698  0.583  0.093  1.0
  Cl  Cl39  1  0.802  0.917  0.593  1.0
  O  O40  1  0.576  0.250  0.006  1.0
  O  O41  1  0.924  0.250  0.506  1.0
  O  O42  1  0.424  0.750  0.994  1.0
  O  O43  1  0.076  0.750  0.494  1.0
[/CIF]
.
The crystal structure described by K2RhH2OCl5 crystallizes in the orthorhombic Pnma space group. K(1) is bonded in a 6-coordinate geometry to one Cl(3), one Cl(4), two equivalent Cl(1), and two equivalent Cl(2) atoms. Rh(1) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one Cl(1), one Cl(2), and one Cl(3) atom. H(1) is bonded in a single-bond geometry to one Cl(4) atom. O(1) is bonded in a single-bond geometry to one Rh(1) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(4) is bonded in a single-bond geometry to one K(1) and one H(1) atom. In the second Cl site, Cl(1) is bonded to four equivalent K(1) and one Rh(1) atom to form distorted corner-sharing ClK4Rh square pyramids. In the third Cl site, Cl(2) is bonded in a 5-coordinate geometry to four equivalent K(1) and one Rh(1) atom. In the fourth Cl site, Cl(3) is bonded in a single-bond geometry to two equivalent K(1) and one Rh(1) atom. is represented by the CIF card [CIF]
data_K2H2RhCl5O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.056
_cell_length_b   9.773
_cell_length_c   14.603
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1149.635
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.802  0.006  0.831  1.0
  K  K1  1  0.698  0.494  0.331  1.0
  K  K2  1  0.198  0.506  0.169  1.0
  K  K3  1  0.302  0.994  0.669  1.0
  K  K4  1  0.198  0.994  0.169  1.0
  K  K5  1  0.302  0.506  0.669  1.0
  K  K6  1  0.802  0.494  0.831  1.0
  K  K7  1  0.698  0.006  0.331  1.0
  H  H8  1  0.338  0.047  0.442  1.0
  H  H9  1  0.162  0.453  0.942  1.0
  H  H10  1  0.662  0.547  0.558  1.0
  H  H11  1  0.838  0.953  0.058  1.0
  H  H12  1  0.662  0.953  0.558  1.0
  H  H13  1  0.838  0.547  0.058  1.0
  H  H14  1  0.338  0.453  0.442  1.0
  H  H15  1  0.162  0.047  0.942  1.0
  Rh  Rh16  1  0.702  0.250  0.105  1.0
  Rh  Rh17  1  0.798  0.250  0.605  1.0
  Rh  Rh18  1  0.298  0.750  0.895  1.0
  Rh  Rh19  1  0.202  0.750  0.395  1.0
  Cl  Cl20  1  0.893  0.250  0.235  1.0
  Cl  Cl21  1  0.607  0.250  0.735  1.0
  Cl  Cl22  1  0.107  0.750  0.765  1.0
  Cl  Cl23  1  0.393  0.750  0.265  1.0
  Cl  Cl24  1  0.464  0.250  0.208  1.0
  Cl  Cl25  1  0.036  0.250  0.708  1.0
  Cl  Cl26  1  0.536  0.750  0.792  1.0
  Cl  Cl27  1  0.964  0.750  0.292  1.0
  Cl  Cl28  1  0.948  0.250  0.008  1.0
  Cl  Cl29  1  0.552  0.250  0.508  1.0
  Cl  Cl30  1  0.052  0.750  0.992  1.0
  Cl  Cl31  1  0.448  0.750  0.492  1.0
  Cl  Cl32  1  0.698  0.917  0.093  1.0
  Cl  Cl33  1  0.802  0.583  0.593  1.0
  Cl  Cl34  1  0.302  0.417  0.907  1.0
  Cl  Cl35  1  0.198  0.083  0.407  1.0
  Cl  Cl36  1  0.302  0.083  0.907  1.0
  Cl  Cl37  1  0.198  0.417  0.407  1.0
  Cl  Cl38  1  0.698  0.583  0.093  1.0
  Cl  Cl39  1  0.802  0.917  0.593  1.0
  O  O40  1  0.576  0.250  0.006  1.0
  O  O41  1  0.924  0.250  0.506  1.0
  O  O42  1  0.424  0.750  0.994  1.0
  O  O43  1  0.076  0.750  0.494  1.0
[/CIF]
.