The material structure described by AlWO4 is beta Vanadium nitride-derived structured and crystallizes in the monoclinic C2/m space group. W(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form WO6 octahedra that share corners with eight equivalent Al(1)O6 octahedra and edges with two equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 41-51°. Al(1) is bonded to one O(1), one O(2), and four equivalent O(3) atoms to form AlO6 octahedra that share corners with eight equivalent W(1)O6 octahedra and edges with two equivalent Al(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 41-51°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to two equivalent W(1) and one Al(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to two equivalent W(1) and one Al(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one W(1) and two equivalent Al(1) atoms. is represented by the CIF card [CIF]
data_AlWO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.906
_cell_length_b   4.625
_cell_length_c   4.631
_cell_angle_alpha   92.354
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   62.201
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Al  Al0  1  1.000  0.500  0.500  1.0
  O  O1  1  0.000  0.212  0.789  1.0
  O  O2  1  1.000  0.788  0.211  1.0
  O  O3  1  0.500  0.304  0.305  1.0
  O  O4  1  0.500  0.696  0.695  1.0
  W  W5  1  0.500  1.000  0.000  1.0
[/CIF]
.
The material structure described by AlWO4 is beta Vanadium nitride-derived structured and crystallizes in the monoclinic C2/m space group. W(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form WO6 octahedra that share corners with eight equivalent Al(1)O6 octahedra and edges with two equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 41-51°. Al(1) is bonded to one O(1), one O(2), and four equivalent O(3) atoms to form AlO6 octahedra that share corners with eight equivalent W(1)O6 octahedra and edges with two equivalent Al(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 41-51°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to two equivalent W(1) and one Al(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to two equivalent W(1) and one Al(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one W(1) and two equivalent Al(1) atoms. is represented by the CIF card [CIF]
data_AlWO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.906
_cell_length_b   4.625
_cell_length_c   4.631
_cell_angle_alpha   92.354
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   62.201
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Al  Al0  1  1.000  0.500  0.500  1.0
  O  O1  1  0.000  0.212  0.789  1.0
  O  O2  1  1.000  0.788  0.211  1.0
  O  O3  1  0.500  0.304  0.305  1.0
  O  O4  1  0.500  0.696  0.695  1.0
  W  W5  1  0.500  1.000  0.000  1.0
[/CIF]
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