The compound described by (NH4)3H(SO4)2 is Indium-like structured and crystallizes in the monoclinic Cc space group. The structure is zero-dimensional and consists of twelve ammonium molecules and four H(SO4)2 clusters. In each H(SO4)2 cluster, H(13) is bonded in a linear geometry to one O(5) and one O(6) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a tetrahedral geometry to one O(1), one O(3), one O(5), and one O(7) atom. In the second S site, S(2) is bonded in a tetrahedral geometry to one O(2), one O(4), one O(6), and one O(8) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one S(2) atom. In the fifth O site, O(5) is bonded in a water-like geometry to one H(13) and one S(1) atom. In the sixth O site, O(6) is bonded in a water-like geometry to one H(13) and one S(2) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one S(1) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one S(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_H13S2N3O8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.808
_cell_length_b   8.513
_cell_length_c   10.376
_cell_angle_alpha   99.362
_cell_angle_beta   90.000
_cell_angle_gamma   70.055
_symmetry_Int_Tables_number   1
_cell_volume   474.956
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.505  0.647  0.262  1.0
  H  H1  1  0.147  0.362  0.238  1.0
  H  H2  1  0.491  0.362  0.738  1.0
  H  H3  1  0.849  0.647  0.762  1.0
  H  H4  1  0.544  0.674  0.426  1.0
  H  H5  1  0.214  0.326  0.075  1.0
  H  H6  1  0.460  0.326  0.575  1.0
  H  H7  1  0.782  0.674  0.926  1.0
  H  H8  1  0.782  0.066  0.207  1.0
  H  H9  1  0.843  0.910  0.296  1.0
  H  H10  1  0.248  0.910  0.796  1.0
  H  H11  1  0.152  0.066  0.707  1.0
  H  H12  1  0.569  0.074  0.317  1.0
  H  H13  1  0.641  0.919  0.181  1.0
  H  H14  1  0.440  0.919  0.681  1.0
  H  H15  1  0.357  0.074  0.817  1.0
  H  H16  1  0.586  0.481  0.343  1.0
  H  H17  1  0.072  0.523  0.153  1.0
  H  H18  1  0.404  0.523  0.653  1.0
  H  H19  1  0.933  0.481  0.843  1.0
  H  H20  1  0.294  0.631  0.367  1.0
  H  H21  1  0.921  0.378  0.134  1.0
  H  H22  1  0.701  0.378  0.634  1.0
  H  H23  1  0.075  0.631  0.867  1.0
  H  H24  1  0.024  0.004  0.492  1.0
  H  H25  1  0.972  0.004  0.992  1.0
  S  S26  1  0.313  0.776  0.042  1.0
  S  S27  1  0.088  0.232  0.458  1.0
  S  S28  1  0.680  0.232  0.958  1.0
  S  S29  1  0.912  0.776  0.542  1.0
  N  N30  1  0.482  0.608  0.349  1.0
  N  N31  1  0.087  0.398  0.151  1.0
  N  N32  1  0.515  0.398  0.651  1.0
  N  N33  1  0.910  0.608  0.849  1.0
  N  N34  1  0.709  0.993  0.250  1.0
  N  N35  1  0.299  0.993  0.750  1.0
  O  O36  1  0.172  0.704  0.119  1.0
  O  O37  1  0.874  0.294  0.382  1.0
  O  O38  1  0.832  0.294  0.882  1.0
  O  O39  1  0.124  0.704  0.619  1.0
  O  O40  1  0.567  0.742  0.088  1.0
  O  O41  1  0.307  0.261  0.408  1.0
  O  O42  1  0.432  0.261  0.908  1.0
  O  O43  1  0.691  0.742  0.588  1.0
  O  O44  1  0.187  0.966  0.059  1.0
  O  O45  1  0.163  0.034  0.440  1.0
  O  O46  1  0.803  0.034  0.940  1.0
  O  O47  1  0.847  0.966  0.559  1.0
  O  O48  1  0.325  0.704  0.900  1.0
  O  O49  1  0.034  0.298  0.600  1.0
  O  O50  1  0.669  0.298  0.100  1.0
  O  O51  1  0.971  0.704  0.400  1.0
[/CIF]
.
The compound described by (NH4)3H(SO4)2 is Indium-like structured and crystallizes in the monoclinic Cc space group. The structure is zero-dimensional and consists of twelve ammonium molecules and four H(SO4)2 clusters. In each H(SO4)2 cluster, H(13) is bonded in a linear geometry to one O(5) and one O(6) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a tetrahedral geometry to one O(1), one O(3), one O(5), and one O(7) atom. In the second S site, S(2) is bonded in a tetrahedral geometry to one O(2), one O(4), one O(6), and one O(8) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one S(2) atom. In the fifth O site, O(5) is bonded in a water-like geometry to one H(13) and one S(1) atom. In the sixth O site, O(6) is bonded in a water-like geometry to one H(13) and one S(2) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one S(1) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one S(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_H13S2N3O8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.808
_cell_length_b   8.513
_cell_length_c   10.376
_cell_angle_alpha   99.362
_cell_angle_beta   90.000
_cell_angle_gamma   70.055
_symmetry_Int_Tables_number   1
_cell_volume   474.956
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.505  0.647  0.262  1.0
  H  H1  1  0.147  0.362  0.238  1.0
  H  H2  1  0.491  0.362  0.738  1.0
  H  H3  1  0.849  0.647  0.762  1.0
  H  H4  1  0.544  0.674  0.426  1.0
  H  H5  1  0.214  0.326  0.075  1.0
  H  H6  1  0.460  0.326  0.575  1.0
  H  H7  1  0.782  0.674  0.926  1.0
  H  H8  1  0.782  0.066  0.207  1.0
  H  H9  1  0.843  0.910  0.296  1.0
  H  H10  1  0.248  0.910  0.796  1.0
  H  H11  1  0.152  0.066  0.707  1.0
  H  H12  1  0.569  0.074  0.317  1.0
  H  H13  1  0.641  0.919  0.181  1.0
  H  H14  1  0.440  0.919  0.681  1.0
  H  H15  1  0.357  0.074  0.817  1.0
  H  H16  1  0.586  0.481  0.343  1.0
  H  H17  1  0.072  0.523  0.153  1.0
  H  H18  1  0.404  0.523  0.653  1.0
  H  H19  1  0.933  0.481  0.843  1.0
  H  H20  1  0.294  0.631  0.367  1.0
  H  H21  1  0.921  0.378  0.134  1.0
  H  H22  1  0.701  0.378  0.634  1.0
  H  H23  1  0.075  0.631  0.867  1.0
  H  H24  1  0.024  0.004  0.492  1.0
  H  H25  1  0.972  0.004  0.992  1.0
  S  S26  1  0.313  0.776  0.042  1.0
  S  S27  1  0.088  0.232  0.458  1.0
  S  S28  1  0.680  0.232  0.958  1.0
  S  S29  1  0.912  0.776  0.542  1.0
  N  N30  1  0.482  0.608  0.349  1.0
  N  N31  1  0.087  0.398  0.151  1.0
  N  N32  1  0.515  0.398  0.651  1.0
  N  N33  1  0.910  0.608  0.849  1.0
  N  N34  1  0.709  0.993  0.250  1.0
  N  N35  1  0.299  0.993  0.750  1.0
  O  O36  1  0.172  0.704  0.119  1.0
  O  O37  1  0.874  0.294  0.382  1.0
  O  O38  1  0.832  0.294  0.882  1.0
  O  O39  1  0.124  0.704  0.619  1.0
  O  O40  1  0.567  0.742  0.088  1.0
  O  O41  1  0.307  0.261  0.408  1.0
  O  O42  1  0.432  0.261  0.908  1.0
  O  O43  1  0.691  0.742  0.588  1.0
  O  O44  1  0.187  0.966  0.059  1.0
  O  O45  1  0.163  0.034  0.440  1.0
  O  O46  1  0.803  0.034  0.940  1.0
  O  O47  1  0.847  0.966  0.559  1.0
  O  O48  1  0.325  0.704  0.900  1.0
  O  O49  1  0.034  0.298  0.600  1.0
  O  O50  1  0.669  0.298  0.100  1.0
  O  O51  1  0.971  0.704  0.400  1.0
[/CIF]
.