The material described by UCH2(OF)3 crystallizes in the monoclinic C2/c space group. U(1) is bonded in a 9-coordinate geometry to one O(1), one O(2), one O(3), two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms. C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(3) and one F(2) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one U(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one U(1) and one C(1) atom. In the third O site, O(3) is bonded in a water-like geometry to one U(1), one H(1), and one H(2) atom. There are three inequivalent F sites. In the first F site, F(3) is bonded in a bent 150 degrees geometry to two equivalent U(1) atoms. In the second F site, F(1) is bonded in a bent 150 degrees geometry to two equivalent U(1) atoms. In the third F site, F(2) is bonded in a 3-coordinate geometry to two equivalent U(1) and one H(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_UH2C(OF)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.266
_cell_length_b   8.633
_cell_length_c   9.284
_cell_angle_alpha   96.605
_cell_angle_beta   109.721
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   469.247
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  U  U0  1  0.712  0.872  0.653  1.0
  U  U1  1  0.059  0.628  0.347  1.0
  U  U2  1  0.288  0.128  0.347  1.0
  U  U3  1  0.941  0.372  0.653  1.0
  H  H4  1  0.396  0.814  0.838  1.0
  H  H5  1  0.558  0.686  0.162  1.0
  H  H6  1  0.604  0.186  0.162  1.0
  H  H7  1  0.442  0.314  0.838  1.0
  H  H8  1  0.387  0.660  0.725  1.0
  H  H9  1  0.662  0.840  0.275  1.0
  H  H10  1  0.613  0.340  0.275  1.0
  H  H11  1  0.338  0.160  0.725  1.0
  C  C12  1  0.894  0.040  0.009  1.0
  C  C13  1  0.886  0.460  0.991  1.0
  C  C14  1  0.106  0.960  0.991  1.0
  C  C15  1  0.114  0.540  0.009  1.0
  O  O16  1  0.712  0.015  0.896  1.0
  O  O17  1  0.815  0.485  0.104  1.0
  O  O18  1  0.288  0.985  0.104  1.0
  O  O19  1  0.185  0.515  0.896  1.0
  O  O20  1  0.079  0.875  0.864  1.0
  O  O21  1  0.215  0.625  0.136  1.0
  O  O22  1  0.921  0.125  0.136  1.0
  O  O23  1  0.785  0.375  0.864  1.0
  O  O24  1  0.484  0.753  0.783  1.0
  O  O25  1  0.701  0.747  0.216  1.0
  O  O26  1  0.516  0.247  0.216  1.0
  O  O27  1  0.299  0.253  0.783  1.0
  F  F28  1  0.959  0.790  0.529  1.0
  F  F29  1  0.430  0.710  0.471  1.0
  F  F30  1  0.041  0.210  0.471  1.0
  F  F31  1  0.570  0.290  0.529  1.0
  F  F32  1  0.400  0.024  0.599  1.0
  F  F33  1  0.802  0.476  0.401  1.0
  F  F34  1  0.600  0.976  0.401  1.0
  F  F35  1  0.198  0.524  0.599  1.0
  F  F36  1  0.886  0.109  0.685  1.0
  F  F37  1  0.200  0.391  0.315  1.0
  F  F38  1  0.114  0.891  0.315  1.0
  F  F39  1  0.800  0.609  0.685  1.0
[/CIF]
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The material described by UCH2(OF)3 crystallizes in the monoclinic C2/c space group. U(1) is bonded in a 9-coordinate geometry to one O(1), one O(2), one O(3), two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms. C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(3) and one F(2) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one U(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one U(1) and one C(1) atom. In the third O site, O(3) is bonded in a water-like geometry to one U(1), one H(1), and one H(2) atom. There are three inequivalent F sites. In the first F site, F(3) is bonded in a bent 150 degrees geometry to two equivalent U(1) atoms. In the second F site, F(1) is bonded in a bent 150 degrees geometry to two equivalent U(1) atoms. In the third F site, F(2) is bonded in a 3-coordinate geometry to two equivalent U(1) and one H(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_UH2C(OF)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.266
_cell_length_b   8.633
_cell_length_c   9.284
_cell_angle_alpha   96.605
_cell_angle_beta   109.721
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   469.247
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  U  U0  1  0.712  0.872  0.653  1.0
  U  U1  1  0.059  0.628  0.347  1.0
  U  U2  1  0.288  0.128  0.347  1.0
  U  U3  1  0.941  0.372  0.653  1.0
  H  H4  1  0.396  0.814  0.838  1.0
  H  H5  1  0.558  0.686  0.162  1.0
  H  H6  1  0.604  0.186  0.162  1.0
  H  H7  1  0.442  0.314  0.838  1.0
  H  H8  1  0.387  0.660  0.725  1.0
  H  H9  1  0.662  0.840  0.275  1.0
  H  H10  1  0.613  0.340  0.275  1.0
  H  H11  1  0.338  0.160  0.725  1.0
  C  C12  1  0.894  0.040  0.009  1.0
  C  C13  1  0.886  0.460  0.991  1.0
  C  C14  1  0.106  0.960  0.991  1.0
  C  C15  1  0.114  0.540  0.009  1.0
  O  O16  1  0.712  0.015  0.896  1.0
  O  O17  1  0.815  0.485  0.104  1.0
  O  O18  1  0.288  0.985  0.104  1.0
  O  O19  1  0.185  0.515  0.896  1.0
  O  O20  1  0.079  0.875  0.864  1.0
  O  O21  1  0.215  0.625  0.136  1.0
  O  O22  1  0.921  0.125  0.136  1.0
  O  O23  1  0.785  0.375  0.864  1.0
  O  O24  1  0.484  0.753  0.783  1.0
  O  O25  1  0.701  0.747  0.216  1.0
  O  O26  1  0.516  0.247  0.216  1.0
  O  O27  1  0.299  0.253  0.783  1.0
  F  F28  1  0.959  0.790  0.529  1.0
  F  F29  1  0.430  0.710  0.471  1.0
  F  F30  1  0.041  0.210  0.471  1.0
  F  F31  1  0.570  0.290  0.529  1.0
  F  F32  1  0.400  0.024  0.599  1.0
  F  F33  1  0.802  0.476  0.401  1.0
  F  F34  1  0.600  0.976  0.401  1.0
  F  F35  1  0.198  0.524  0.599  1.0
  F  F36  1  0.886  0.109  0.685  1.0
  F  F37  1  0.200  0.391  0.315  1.0
  F  F38  1  0.114  0.891  0.315  1.0
  F  F39  1  0.800  0.609  0.685  1.0
[/CIF]
.