The material structure described by VSb(SeO3)4 crystallizes in the monoclinic P2_1/c space group. V(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(4), and two equivalent O(6) atoms. Sb(1) is bonded in an octahedral geometry to two equivalent O(2), two equivalent O(3), and two equivalent O(5) atoms. There are two inequivalent Se sites. In the first Se site, Se(1) is bonded in a distorted trigonal non-coplanar geometry to one O(1), one O(4), and one O(5) atom. In the second Se site, Se(2) is bonded in a distorted T-shaped geometry to one O(2), one O(3), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one V(1) and one Se(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Sb(1) and one Se(2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Sb(1) and one Se(2) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one V(1) and one Se(1) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Sb(1) and one Se(1) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one V(1) and one Se(2) atom. is represented by the CIF card [CIF]
data_VSb(SeO3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.073
_cell_length_b   8.044
_cell_length_c   8.097
_cell_angle_alpha   89.228
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   525.778
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.000  0.500  0.000  1.0
  V  V1  1  0.500  0.500  0.500  1.0
  Sb  Sb2  1  0.000  0.000  0.500  1.0
  Sb  Sb3  1  0.500  0.000  0.000  1.0
  Se  Se4  1  0.330  0.659  0.169  1.0
  Se  Se5  1  0.830  0.341  0.331  1.0
  Se  Se6  1  0.665  0.826  0.666  1.0
  Se  Se7  1  0.165  0.174  0.834  1.0
  Se  Se8  1  0.670  0.341  0.831  1.0
  Se  Se9  1  0.170  0.659  0.669  1.0
  Se  Se10  1  0.335  0.174  0.334  1.0
  Se  Se11  1  0.835  0.826  0.166  1.0
  O  O12  1  0.242  0.530  0.030  1.0
  O  O13  1  0.742  0.470  0.470  1.0
  O  O14  1  0.758  0.974  0.535  1.0
  O  O15  1  0.258  0.026  0.965  1.0
  O  O16  1  0.532  0.969  0.758  1.0
  O  O17  1  0.467  0.527  0.258  1.0
  O  O18  1  0.967  0.473  0.242  1.0
  O  O19  1  0.032  0.031  0.742  1.0
  O  O20  1  0.973  0.242  0.469  1.0
  O  O21  1  0.532  0.747  0.530  1.0
  O  O22  1  0.473  0.758  0.031  1.0
  O  O23  1  0.032  0.253  0.970  1.0
  O  O24  1  0.758  0.470  0.970  1.0
  O  O25  1  0.258  0.530  0.530  1.0
  O  O26  1  0.242  0.026  0.465  1.0
  O  O27  1  0.742  0.974  0.035  1.0
  O  O28  1  0.468  0.031  0.242  1.0
  O  O29  1  0.533  0.473  0.742  1.0
  O  O30  1  0.033  0.527  0.758  1.0
  O  O31  1  0.968  0.969  0.258  1.0
  O  O32  1  0.027  0.758  0.531  1.0
  O  O33  1  0.468  0.253  0.470  1.0
  O  O34  1  0.527  0.242  0.969  1.0
  O  O35  1  0.968  0.747  0.030  1.0
[/CIF]
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The material structure described by VSb(SeO3)4 crystallizes in the monoclinic P2_1/c space group. V(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(4), and two equivalent O(6) atoms. Sb(1) is bonded in an octahedral geometry to two equivalent O(2), two equivalent O(3), and two equivalent O(5) atoms. There are two inequivalent Se sites. In the first Se site, Se(1) is bonded in a distorted trigonal non-coplanar geometry to one O(1), one O(4), and one O(5) atom. In the second Se site, Se(2) is bonded in a distorted T-shaped geometry to one O(2), one O(3), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one V(1) and one Se(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Sb(1) and one Se(2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Sb(1) and one Se(2) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one V(1) and one Se(1) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Sb(1) and one Se(1) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one V(1) and one Se(2) atom. is represented by the CIF card [CIF]
data_VSb(SeO3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.073
_cell_length_b   8.044
_cell_length_c   8.097
_cell_angle_alpha   89.228
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   525.778
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.000  0.500  0.000  1.0
  V  V1  1  0.500  0.500  0.500  1.0
  Sb  Sb2  1  0.000  0.000  0.500  1.0
  Sb  Sb3  1  0.500  0.000  0.000  1.0
  Se  Se4  1  0.330  0.659  0.169  1.0
  Se  Se5  1  0.830  0.341  0.331  1.0
  Se  Se6  1  0.665  0.826  0.666  1.0
  Se  Se7  1  0.165  0.174  0.834  1.0
  Se  Se8  1  0.670  0.341  0.831  1.0
  Se  Se9  1  0.170  0.659  0.669  1.0
  Se  Se10  1  0.335  0.174  0.334  1.0
  Se  Se11  1  0.835  0.826  0.166  1.0
  O  O12  1  0.242  0.530  0.030  1.0
  O  O13  1  0.742  0.470  0.470  1.0
  O  O14  1  0.758  0.974  0.535  1.0
  O  O15  1  0.258  0.026  0.965  1.0
  O  O16  1  0.532  0.969  0.758  1.0
  O  O17  1  0.467  0.527  0.258  1.0
  O  O18  1  0.967  0.473  0.242  1.0
  O  O19  1  0.032  0.031  0.742  1.0
  O  O20  1  0.973  0.242  0.469  1.0
  O  O21  1  0.532  0.747  0.530  1.0
  O  O22  1  0.473  0.758  0.031  1.0
  O  O23  1  0.032  0.253  0.970  1.0
  O  O24  1  0.758  0.470  0.970  1.0
  O  O25  1  0.258  0.530  0.530  1.0
  O  O26  1  0.242  0.026  0.465  1.0
  O  O27  1  0.742  0.974  0.035  1.0
  O  O28  1  0.468  0.031  0.242  1.0
  O  O29  1  0.533  0.473  0.742  1.0
  O  O30  1  0.033  0.527  0.758  1.0
  O  O31  1  0.968  0.969  0.258  1.0
  O  O32  1  0.027  0.758  0.531  1.0
  O  O33  1  0.468  0.253  0.470  1.0
  O  O34  1  0.527  0.242  0.969  1.0
  O  O35  1  0.968  0.747  0.030  1.0
[/CIF]
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