The structure described by W2Ga5 crystallizes in the tetragonal P4/mbm space group. W(1) is bonded to two equivalent W(1), two equivalent Ga(1), and eight equivalent Ga(2) atoms to form a mixture of distorted face, corner, and edge-sharing WGa10W2 cuboctahedra. There are two inequivalent Ga sites. In the first Ga site, Ga(1) is bonded in a 10-coordinate geometry to four equivalent W(1), two equivalent Ga(1), and four equivalent Ga(2) atoms. In the second Ga site, Ga(2) is bonded in a 9-coordinate geometry to four equivalent W(1), one Ga(1), and four equivalent Ga(2) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ga5W2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.180
_cell_length_b   9.180
_cell_length_c   2.735
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   230.453
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.500  0.000  0.000  1.0
  Ga  Ga1  1  0.000  0.500  0.000  1.0
  Ga  Ga2  1  0.560  0.701  0.000  1.0
  Ga  Ga3  1  0.440  0.299  0.000  1.0
  Ga  Ga4  1  0.060  0.799  0.000  1.0
  Ga  Ga5  1  0.940  0.201  0.000  1.0
  Ga  Ga6  1  0.299  0.560  0.000  1.0
  Ga  Ga7  1  0.701  0.440  0.000  1.0
  Ga  Ga8  1  0.201  0.060  0.000  1.0
  Ga  Ga9  1  0.799  0.940  0.000  1.0
  W  W10  1  0.679  0.179  0.500  1.0
  W  W11  1  0.321  0.821  0.500  1.0
  W  W12  1  0.179  0.321  0.500  1.0
  W  W13  1  0.821  0.679  0.500  1.0
[/CIF]
.
The structure described by W2Ga5 crystallizes in the tetragonal P4/mbm space group. W(1) is bonded to two equivalent W(1), two equivalent Ga(1), and eight equivalent Ga(2) atoms to form a mixture of distorted face, corner, and edge-sharing WGa10W2 cuboctahedra. There are two inequivalent Ga sites. In the first Ga site, Ga(1) is bonded in a 10-coordinate geometry to four equivalent W(1), two equivalent Ga(1), and four equivalent Ga(2) atoms. In the second Ga site, Ga(2) is bonded in a 9-coordinate geometry to four equivalent W(1), one Ga(1), and four equivalent Ga(2) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ga5W2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.180
_cell_length_b   9.180
_cell_length_c   2.735
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   230.453
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.500  0.000  0.000  1.0
  Ga  Ga1  1  0.000  0.500  0.000  1.0
  Ga  Ga2  1  0.560  0.701  0.000  1.0
  Ga  Ga3  1  0.440  0.299  0.000  1.0
  Ga  Ga4  1  0.060  0.799  0.000  1.0
  Ga  Ga5  1  0.940  0.201  0.000  1.0
  Ga  Ga6  1  0.299  0.560  0.000  1.0
  Ga  Ga7  1  0.701  0.440  0.000  1.0
  Ga  Ga8  1  0.201  0.060  0.000  1.0
  Ga  Ga9  1  0.799  0.940  0.000  1.0
  W  W10  1  0.679  0.179  0.500  1.0
  W  W11  1  0.321  0.821  0.500  1.0
  W  W12  1  0.179  0.321  0.500  1.0
  W  W13  1  0.821  0.679  0.500  1.0
[/CIF]
.