The compound described by ReNi2N3 crystallizes in the monoclinic C2/c space group. Re(1) is bonded to one N(1), one N(2), one N(3), and one N(4) atom to form corner-sharing ReN4 tetrahedra. There are two inequivalent Ni sites. In the first Ni site, Ni(1) is bonded in a 3-coordinate geometry to one N(2) and two equivalent N(3) atoms. In the second Ni site, Ni(2) is bonded in a distorted T-shaped geometry to one N(3) and two equivalent N(2) atoms. There are four inequivalent N sites. In the first N site, N(4) is bonded in a linear geometry to two equivalent Re(1) atoms. In the second N site, N(1) is bonded in a linear geometry to two equivalent Re(1) atoms. In the third N site, N(2) is bonded in a 4-coordinate geometry to one Re(1), one Ni(1), and two equivalent Ni(2) atoms. In the fourth N site, N(3) is bonded in a rectangular see-saw-like geometry to one Re(1), one Ni(2), and two equivalent Ni(1) atoms. is represented by the CIF card [CIF]
data_ReNi2N3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.008
_cell_length_b   7.858
_cell_length_c   13.484
_cell_angle_alpha   90.000
_cell_angle_beta   85.401
_cell_angle_gamma   141.679
_symmetry_Int_Tables_number   1
_cell_volume   326.228
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.542  0.219  0.674  1.0
  Re  Re1  1  0.458  0.677  0.826  1.0
  Re  Re2  1  0.458  0.781  0.326  1.0
  Re  Re3  1  0.542  0.323  0.174  1.0
  Ni  Ni4  1  0.859  0.212  0.968  1.0
  Ni  Ni5  1  0.141  0.353  0.532  1.0
  Ni  Ni6  1  0.141  0.788  0.032  1.0
  Ni  Ni7  1  0.859  0.647  0.468  1.0
  Ni  Ni8  1  0.510  0.839  0.511  1.0
  Ni  Ni9  1  0.490  0.329  0.989  1.0
  Ni  Ni10  1  0.490  0.161  0.489  1.0
  Ni  Ni11  1  0.510  0.671  0.011  1.0
  N  N12  1  0.000  0.472  0.750  1.0
  N  N13  1  0.000  0.528  0.250  1.0
  N  N14  1  0.602  0.040  0.607  1.0
  N  N15  1  0.398  0.438  0.893  1.0
  N  N16  1  0.398  0.960  0.393  1.0
  N  N17  1  0.602  0.562  0.107  1.0
  N  N18  1  0.500  0.139  0.072  1.0
  N  N19  1  0.500  0.639  0.428  1.0
  N  N20  1  0.500  0.861  0.928  1.0
  N  N21  1  0.500  0.361  0.572  1.0
  N  N22  1  0.000  0.954  0.750  1.0
  N  N23  1  0.000  0.046  0.250  1.0
[/CIF]
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The compound described by ReNi2N3 crystallizes in the monoclinic C2/c space group. Re(1) is bonded to one N(1), one N(2), one N(3), and one N(4) atom to form corner-sharing ReN4 tetrahedra. There are two inequivalent Ni sites. In the first Ni site, Ni(1) is bonded in a 3-coordinate geometry to one N(2) and two equivalent N(3) atoms. In the second Ni site, Ni(2) is bonded in a distorted T-shaped geometry to one N(3) and two equivalent N(2) atoms. There are four inequivalent N sites. In the first N site, N(4) is bonded in a linear geometry to two equivalent Re(1) atoms. In the second N site, N(1) is bonded in a linear geometry to two equivalent Re(1) atoms. In the third N site, N(2) is bonded in a 4-coordinate geometry to one Re(1), one Ni(1), and two equivalent Ni(2) atoms. In the fourth N site, N(3) is bonded in a rectangular see-saw-like geometry to one Re(1), one Ni(2), and two equivalent Ni(1) atoms. is represented by the CIF card [CIF]
data_ReNi2N3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.008
_cell_length_b   7.858
_cell_length_c   13.484
_cell_angle_alpha   90.000
_cell_angle_beta   85.401
_cell_angle_gamma   141.679
_symmetry_Int_Tables_number   1
_cell_volume   326.228
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.542  0.219  0.674  1.0
  Re  Re1  1  0.458  0.677  0.826  1.0
  Re  Re2  1  0.458  0.781  0.326  1.0
  Re  Re3  1  0.542  0.323  0.174  1.0
  Ni  Ni4  1  0.859  0.212  0.968  1.0
  Ni  Ni5  1  0.141  0.353  0.532  1.0
  Ni  Ni6  1  0.141  0.788  0.032  1.0
  Ni  Ni7  1  0.859  0.647  0.468  1.0
  Ni  Ni8  1  0.510  0.839  0.511  1.0
  Ni  Ni9  1  0.490  0.329  0.989  1.0
  Ni  Ni10  1  0.490  0.161  0.489  1.0
  Ni  Ni11  1  0.510  0.671  0.011  1.0
  N  N12  1  0.000  0.472  0.750  1.0
  N  N13  1  0.000  0.528  0.250  1.0
  N  N14  1  0.602  0.040  0.607  1.0
  N  N15  1  0.398  0.438  0.893  1.0
  N  N16  1  0.398  0.960  0.393  1.0
  N  N17  1  0.602  0.562  0.107  1.0
  N  N18  1  0.500  0.139  0.072  1.0
  N  N19  1  0.500  0.639  0.428  1.0
  N  N20  1  0.500  0.861  0.928  1.0
  N  N21  1  0.500  0.361  0.572  1.0
  N  N22  1  0.000  0.954  0.750  1.0
  N  N23  1  0.000  0.046  0.250  1.0
[/CIF]
.