The material described by XeF5PtF6 is Indium-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four PtF6 clusters and four XeF5 clusters. In each PtF6 cluster, Pt(1) is bonded in an octahedral geometry to one F(2), one F(5), one F(6), one F(7), and two equivalent F(8) atoms. There are five inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one Pt(1) atom. In the second F site, F(5) is bonded in a single-bond geometry to one Pt(1) atom. In the third F site, F(6) is bonded in a single-bond geometry to one Pt(1) atom. In the fourth F site, F(7) is bonded in a single-bond geometry to one Pt(1) atom. In the fifth F site, F(8) is bonded in a single-bond geometry to one Pt(1) atom. In each XeF5 cluster, Xe(1) is bonded in a distorted square pyramidal geometry to one F(1), two equivalent F(3), and two equivalent F(4) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Xe(1) atom. In the second F site, F(4) is bonded in a single-bond geometry to one Xe(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Xe(1) atom. is represented by the CIF card [CIF]
data_PtXeF11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.801
_cell_length_b   8.371
_cell_length_c   17.114
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   831.065
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pt  Pt0  1  0.282  0.250  0.040  1.0
  Pt  Pt1  1  0.718  0.750  0.960  1.0
  Pt  Pt2  1  0.782  0.750  0.460  1.0
  Pt  Pt3  1  0.218  0.250  0.540  1.0
  Xe  Xe4  1  0.695  0.250  0.349  1.0
  Xe  Xe5  1  0.305  0.750  0.651  1.0
  Xe  Xe6  1  0.195  0.750  0.151  1.0
  Xe  Xe7  1  0.805  0.250  0.849  1.0
  F  F8  1  0.389  0.750  0.763  1.0
  F  F9  1  0.889  0.250  0.737  1.0
  F  F10  1  0.111  0.750  0.263  1.0
  F  F11  1  0.023  0.750  0.010  1.0
  F  F12  1  0.547  0.917  0.649  1.0
  F  F13  1  0.415  0.585  0.189  1.0
  F  F14  1  0.931  0.750  0.563  1.0
  F  F15  1  0.453  0.083  0.351  1.0
  F  F16  1  0.477  0.750  0.510  1.0
  F  F17  1  0.953  0.583  0.149  1.0
  F  F18  1  0.634  0.750  0.360  1.0
  F  F19  1  0.915  0.085  0.311  1.0
  F  F20  1  0.134  0.250  0.140  1.0
  F  F21  1  0.928  0.250  0.592  1.0
  F  F22  1  0.219  0.479  0.538  1.0
  F  F23  1  0.281  0.021  0.038  1.0
  F  F24  1  0.719  0.979  0.962  1.0
  F  F25  1  0.547  0.583  0.649  1.0
  F  F26  1  0.585  0.085  0.811  1.0
  F  F27  1  0.085  0.915  0.689  1.0
  F  F28  1  0.523  0.250  0.490  1.0
  F  F29  1  0.047  0.083  0.851  1.0
  F  F30  1  0.781  0.521  0.462  1.0
  F  F31  1  0.047  0.417  0.851  1.0
  F  F32  1  0.431  0.250  0.937  1.0
  F  F33  1  0.572  0.250  0.092  1.0
  F  F34  1  0.585  0.415  0.811  1.0
  F  F35  1  0.453  0.417  0.351  1.0
  F  F36  1  0.953  0.917  0.149  1.0
  F  F37  1  0.415  0.915  0.189  1.0
  F  F38  1  0.611  0.250  0.237  1.0
  F  F39  1  0.719  0.521  0.962  1.0
  F  F40  1  0.428  0.750  0.908  1.0
  F  F41  1  0.569  0.750  0.063  1.0
  F  F42  1  0.069  0.250  0.437  1.0
  F  F43  1  0.085  0.585  0.689  1.0
  F  F44  1  0.781  0.979  0.462  1.0
  F  F45  1  0.366  0.250  0.640  1.0
  F  F46  1  0.977  0.250  0.990  1.0
  F  F47  1  0.219  0.021  0.538  1.0
  F  F48  1  0.072  0.750  0.408  1.0
  F  F49  1  0.281  0.479  0.038  1.0
  F  F50  1  0.866  0.750  0.860  1.0
  F  F51  1  0.915  0.415  0.311  1.0
[/CIF]
.
The material described by XeF5PtF6 is Indium-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four PtF6 clusters and four XeF5 clusters. In each PtF6 cluster, Pt(1) is bonded in an octahedral geometry to one F(2), one F(5), one F(6), one F(7), and two equivalent F(8) atoms. There are five inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one Pt(1) atom. In the second F site, F(5) is bonded in a single-bond geometry to one Pt(1) atom. In the third F site, F(6) is bonded in a single-bond geometry to one Pt(1) atom. In the fourth F site, F(7) is bonded in a single-bond geometry to one Pt(1) atom. In the fifth F site, F(8) is bonded in a single-bond geometry to one Pt(1) atom. In each XeF5 cluster, Xe(1) is bonded in a distorted square pyramidal geometry to one F(1), two equivalent F(3), and two equivalent F(4) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Xe(1) atom. In the second F site, F(4) is bonded in a single-bond geometry to one Xe(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Xe(1) atom. is represented by the CIF card [CIF]
data_PtXeF11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.801
_cell_length_b   8.371
_cell_length_c   17.114
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   831.065
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pt  Pt0  1  0.282  0.250  0.040  1.0
  Pt  Pt1  1  0.718  0.750  0.960  1.0
  Pt  Pt2  1  0.782  0.750  0.460  1.0
  Pt  Pt3  1  0.218  0.250  0.540  1.0
  Xe  Xe4  1  0.695  0.250  0.349  1.0
  Xe  Xe5  1  0.305  0.750  0.651  1.0
  Xe  Xe6  1  0.195  0.750  0.151  1.0
  Xe  Xe7  1  0.805  0.250  0.849  1.0
  F  F8  1  0.389  0.750  0.763  1.0
  F  F9  1  0.889  0.250  0.737  1.0
  F  F10  1  0.111  0.750  0.263  1.0
  F  F11  1  0.023  0.750  0.010  1.0
  F  F12  1  0.547  0.917  0.649  1.0
  F  F13  1  0.415  0.585  0.189  1.0
  F  F14  1  0.931  0.750  0.563  1.0
  F  F15  1  0.453  0.083  0.351  1.0
  F  F16  1  0.477  0.750  0.510  1.0
  F  F17  1  0.953  0.583  0.149  1.0
  F  F18  1  0.634  0.750  0.360  1.0
  F  F19  1  0.915  0.085  0.311  1.0
  F  F20  1  0.134  0.250  0.140  1.0
  F  F21  1  0.928  0.250  0.592  1.0
  F  F22  1  0.219  0.479  0.538  1.0
  F  F23  1  0.281  0.021  0.038  1.0
  F  F24  1  0.719  0.979  0.962  1.0
  F  F25  1  0.547  0.583  0.649  1.0
  F  F26  1  0.585  0.085  0.811  1.0
  F  F27  1  0.085  0.915  0.689  1.0
  F  F28  1  0.523  0.250  0.490  1.0
  F  F29  1  0.047  0.083  0.851  1.0
  F  F30  1  0.781  0.521  0.462  1.0
  F  F31  1  0.047  0.417  0.851  1.0
  F  F32  1  0.431  0.250  0.937  1.0
  F  F33  1  0.572  0.250  0.092  1.0
  F  F34  1  0.585  0.415  0.811  1.0
  F  F35  1  0.453  0.417  0.351  1.0
  F  F36  1  0.953  0.917  0.149  1.0
  F  F37  1  0.415  0.915  0.189  1.0
  F  F38  1  0.611  0.250  0.237  1.0
  F  F39  1  0.719  0.521  0.962  1.0
  F  F40  1  0.428  0.750  0.908  1.0
  F  F41  1  0.569  0.750  0.063  1.0
  F  F42  1  0.069  0.250  0.437  1.0
  F  F43  1  0.085  0.585  0.689  1.0
  F  F44  1  0.781  0.979  0.462  1.0
  F  F45  1  0.366  0.250  0.640  1.0
  F  F46  1  0.977  0.250  0.990  1.0
  F  F47  1  0.219  0.021  0.538  1.0
  F  F48  1  0.072  0.750  0.408  1.0
  F  F49  1  0.281  0.479  0.038  1.0
  F  F50  1  0.866  0.750  0.860  1.0
  F  F51  1  0.915  0.415  0.311  1.0
[/CIF]
.