The material described by VOF is Hydrophilite-derived structured and crystallizes in the monoclinic P2_1/c space group. V(1) is bonded to three equivalent O(1) and three equivalent F(1) atoms to form a mixture of corner and edge-sharing VO3F3 octahedra. The corner-sharing octahedral tilt angles range from 47-56°. O(1) is bonded in a distorted trigonal planar geometry to three equivalent V(1) atoms. F(1) is bonded in a trigonal planar geometry to three equivalent V(1) atoms. is represented by the CIF file [CIF]
data_VOF
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.226
_cell_length_b   4.675
_cell_length_c   5.713
_cell_angle_alpha   90.000
_cell_angle_beta   87.624
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   139.474
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.223  0.482  0.656  1.0
  V  V1  1  0.223  0.018  0.156  1.0
  V  V2  1  0.777  0.982  0.844  1.0
  V  V3  1  0.777  0.518  0.344  1.0
  O  O4  1  0.081  0.220  0.879  1.0
  O  O5  1  0.081  0.280  0.379  1.0
  O  O6  1  0.919  0.720  0.621  1.0
  O  O7  1  0.919  0.780  0.121  1.0
  F  F8  1  0.418  0.769  0.888  1.0
  F  F9  1  0.418  0.731  0.388  1.0
  F  F10  1  0.582  0.269  0.612  1.0
  F  F11  1  0.582  0.231  0.112  1.0
[/CIF]
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The material described by VOF is Hydrophilite-derived structured and crystallizes in the monoclinic P2_1/c space group. V(1) is bonded to three equivalent O(1) and three equivalent F(1) atoms to form a mixture of corner and edge-sharing VO3F3 octahedra. The corner-sharing octahedral tilt angles range from 47-56°. O(1) is bonded in a distorted trigonal planar geometry to three equivalent V(1) atoms. F(1) is bonded in a trigonal planar geometry to three equivalent V(1) atoms. is represented by the CIF file [CIF]
data_VOF
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.226
_cell_length_b   4.675
_cell_length_c   5.713
_cell_angle_alpha   90.000
_cell_angle_beta   87.624
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   139.474
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.223  0.482  0.656  1.0
  V  V1  1  0.223  0.018  0.156  1.0
  V  V2  1  0.777  0.982  0.844  1.0
  V  V3  1  0.777  0.518  0.344  1.0
  O  O4  1  0.081  0.220  0.879  1.0
  O  O5  1  0.081  0.280  0.379  1.0
  O  O6  1  0.919  0.720  0.621  1.0
  O  O7  1  0.919  0.780  0.121  1.0
  F  F8  1  0.418  0.769  0.888  1.0
  F  F9  1  0.418  0.731  0.388  1.0
  F  F10  1  0.582  0.269  0.612  1.0
  F  F11  1  0.582  0.231  0.112  1.0
[/CIF]
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