The material described by CoCl4N2NCl is Silicon tetrafluoride-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of eight ammonia atoms, four chloramine molecules, and four CoCl4 clusters. In each CoCl4 cluster, Co(1) is bonded in a tetrahedral geometry to one Cl(1), one Cl(2), and two equivalent Cl(4) atoms. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Co(1) atom. In the second Cl site, Cl(4) is bonded in a single-bond geometry to one Co(1) atom. In the third Cl site, Cl(2) is bonded in a single-bond geometry to one Co(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CoN3Cl5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.329
_cell_length_b   9.440
_cell_length_c   12.658
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1114.759
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.818  0.250  0.392  1.0
  Co  Co1  1  0.318  0.250  0.108  1.0
  Co  Co2  1  0.182  0.750  0.608  1.0
  Co  Co3  1  0.682  0.750  0.892  1.0
  N  N4  1  0.964  0.250  0.897  1.0
  N  N5  1  0.464  0.250  0.603  1.0
  N  N6  1  0.036  0.750  0.103  1.0
  N  N7  1  0.536  0.750  0.397  1.0
  N  N8  1  0.890  0.026  0.682  1.0
  N  N9  1  0.390  0.474  0.818  1.0
  N  N10  1  0.110  0.526  0.318  1.0
  N  N11  1  0.610  0.974  0.182  1.0
  N  N12  1  0.110  0.974  0.318  1.0
  N  N13  1  0.610  0.526  0.182  1.0
  N  N14  1  0.890  0.474  0.682  1.0
  N  N15  1  0.390  0.026  0.818  1.0
  Cl  Cl16  1  0.862  0.250  0.226  1.0
  Cl  Cl17  1  0.362  0.250  0.274  1.0
  Cl  Cl18  1  0.138  0.750  0.774  1.0
  Cl  Cl19  1  0.638  0.750  0.726  1.0
  Cl  Cl20  1  0.512  0.250  0.018  1.0
  Cl  Cl21  1  0.012  0.250  0.482  1.0
  Cl  Cl22  1  0.488  0.750  0.982  1.0
  Cl  Cl23  1  0.988  0.750  0.518  1.0
  Cl  Cl24  1  0.597  0.250  0.683  1.0
  Cl  Cl25  1  0.097  0.250  0.817  1.0
  Cl  Cl26  1  0.403  0.750  0.317  1.0
  Cl  Cl27  1  0.903  0.750  0.183  1.0
  Cl  Cl28  1  0.695  0.064  0.429  1.0
  Cl  Cl29  1  0.195  0.436  0.071  1.0
  Cl  Cl30  1  0.305  0.564  0.571  1.0
  Cl  Cl31  1  0.805  0.936  0.929  1.0
  Cl  Cl32  1  0.305  0.936  0.571  1.0
  Cl  Cl33  1  0.805  0.564  0.929  1.0
  Cl  Cl34  1  0.695  0.436  0.429  1.0
  Cl  Cl35  1  0.195  0.064  0.071  1.0
[/CIF]
.
The material described by CoCl4N2NCl is Silicon tetrafluoride-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of eight ammonia atoms, four chloramine molecules, and four CoCl4 clusters. In each CoCl4 cluster, Co(1) is bonded in a tetrahedral geometry to one Cl(1), one Cl(2), and two equivalent Cl(4) atoms. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Co(1) atom. In the second Cl site, Cl(4) is bonded in a single-bond geometry to one Co(1) atom. In the third Cl site, Cl(2) is bonded in a single-bond geometry to one Co(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CoN3Cl5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.329
_cell_length_b   9.440
_cell_length_c   12.658
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1114.759
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.818  0.250  0.392  1.0
  Co  Co1  1  0.318  0.250  0.108  1.0
  Co  Co2  1  0.182  0.750  0.608  1.0
  Co  Co3  1  0.682  0.750  0.892  1.0
  N  N4  1  0.964  0.250  0.897  1.0
  N  N5  1  0.464  0.250  0.603  1.0
  N  N6  1  0.036  0.750  0.103  1.0
  N  N7  1  0.536  0.750  0.397  1.0
  N  N8  1  0.890  0.026  0.682  1.0
  N  N9  1  0.390  0.474  0.818  1.0
  N  N10  1  0.110  0.526  0.318  1.0
  N  N11  1  0.610  0.974  0.182  1.0
  N  N12  1  0.110  0.974  0.318  1.0
  N  N13  1  0.610  0.526  0.182  1.0
  N  N14  1  0.890  0.474  0.682  1.0
  N  N15  1  0.390  0.026  0.818  1.0
  Cl  Cl16  1  0.862  0.250  0.226  1.0
  Cl  Cl17  1  0.362  0.250  0.274  1.0
  Cl  Cl18  1  0.138  0.750  0.774  1.0
  Cl  Cl19  1  0.638  0.750  0.726  1.0
  Cl  Cl20  1  0.512  0.250  0.018  1.0
  Cl  Cl21  1  0.012  0.250  0.482  1.0
  Cl  Cl22  1  0.488  0.750  0.982  1.0
  Cl  Cl23  1  0.988  0.750  0.518  1.0
  Cl  Cl24  1  0.597  0.250  0.683  1.0
  Cl  Cl25  1  0.097  0.250  0.817  1.0
  Cl  Cl26  1  0.403  0.750  0.317  1.0
  Cl  Cl27  1  0.903  0.750  0.183  1.0
  Cl  Cl28  1  0.695  0.064  0.429  1.0
  Cl  Cl29  1  0.195  0.436  0.071  1.0
  Cl  Cl30  1  0.305  0.564  0.571  1.0
  Cl  Cl31  1  0.805  0.936  0.929  1.0
  Cl  Cl32  1  0.305  0.936  0.571  1.0
  Cl  Cl33  1  0.805  0.564  0.929  1.0
  Cl  Cl34  1  0.695  0.436  0.429  1.0
  Cl  Cl35  1  0.195  0.064  0.071  1.0
[/CIF]
.