The crystal structure described by Yb4Sb2O is (La,Ba)CuO4 structured and crystallizes in the tetragonal I4/mmm space group. There are two inequivalent Yb sites. In the first Yb site, Yb(1) is bonded in a linear geometry to four equivalent Sb(1) and two equivalent O(1) atoms. In the second Yb site, Yb(2) is bonded in a distorted single-bond geometry to five equivalent Sb(1) and one O(1) atom. Sb(1) is bonded in a 9-coordinate geometry to four equivalent Yb(1) and five equivalent Yb(2) atoms. O(1) is bonded to two equivalent Yb(2) and four equivalent Yb(1) atoms to form corner-sharing OYb6 octahedra. The corner-sharing octahedra are not tilted. is represented by the CIF file [CIF]
data_Yb4Sb2O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.626
_cell_length_b   8.626
_cell_length_c   8.626
_cell_angle_alpha   148.976
_cell_angle_beta   148.976
_cell_angle_gamma   44.446
_symmetry_Int_Tables_number   1
_cell_volume   170.012
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Yb  Yb0  1  0.500  0.000  0.500  1.0
  Yb  Yb1  1  0.661  0.661  0.000  1.0
  Yb  Yb2  1  0.339  0.339  0.000  1.0
  Yb  Yb3  1  0.000  0.500  0.500  1.0
  Sb  Sb4  1  0.140  0.140  0.000  1.0
  Sb  Sb5  1  0.860  0.860  0.000  1.0
  O  O6  1  0.500  0.500  0.000  1.0
[/CIF]
.
The crystal structure described by Yb4Sb2O is (La,Ba)CuO4 structured and crystallizes in the tetragonal I4/mmm space group. There are two inequivalent Yb sites. In the first Yb site, Yb(1) is bonded in a linear geometry to four equivalent Sb(1) and two equivalent O(1) atoms. In the second Yb site, Yb(2) is bonded in a distorted single-bond geometry to five equivalent Sb(1) and one O(1) atom. Sb(1) is bonded in a 9-coordinate geometry to four equivalent Yb(1) and five equivalent Yb(2) atoms. O(1) is bonded to two equivalent Yb(2) and four equivalent Yb(1) atoms to form corner-sharing OYb6 octahedra. The corner-sharing octahedra are not tilted. is represented by the CIF file [CIF]
data_Yb4Sb2O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.626
_cell_length_b   8.626
_cell_length_c   8.626
_cell_angle_alpha   148.976
_cell_angle_beta   148.976
_cell_angle_gamma   44.446
_symmetry_Int_Tables_number   1
_cell_volume   170.012
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Yb  Yb0  1  0.500  0.000  0.500  1.0
  Yb  Yb1  1  0.661  0.661  0.000  1.0
  Yb  Yb2  1  0.339  0.339  0.000  1.0
  Yb  Yb3  1  0.000  0.500  0.500  1.0
  Sb  Sb4  1  0.140  0.140  0.000  1.0
  Sb  Sb5  1  0.860  0.860  0.000  1.0
  O  O6  1  0.500  0.500  0.000  1.0
[/CIF]
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