The crystal structure described by Li2PbN2 crystallizes in the trigonal P-3m1 space group. Li(1) is bonded to four equivalent N(1) atoms to form LiN4 tetrahedra that share corners with six equivalent Pb(1)N6 octahedra, corners with six equivalent Li(1)N4 tetrahedra, edges with three equivalent Pb(1)N6 octahedra, and edges with three equivalent Li(1)N4 tetrahedra. The corner-sharing octahedral tilt angles range from 13-56°. Pb(1) is bonded to six equivalent N(1) atoms to form PbN6 octahedra that share corners with twelve equivalent Li(1)N4 tetrahedra, edges with six equivalent Pb(1)N6 octahedra, and edges with six equivalent Li(1)N4 tetrahedra. N(1) is bonded in a 7-coordinate geometry to four equivalent Li(1) and three equivalent Pb(1) atoms. is represented by the CIF card [CIF]
data_Li2PbN2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.443
_cell_length_b   3.443
_cell_length_c   5.608
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   57.582
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.667  0.333  0.380  1.0
  Li  Li1  1  0.333  0.667  0.620  1.0
  Pb  Pb2  1  0.000  0.000  0.000  1.0
  N  N3  1  0.667  0.333  0.760  1.0
  N  N4  1  0.333  0.667  0.240  1.0
[/CIF]
.
The crystal structure described by Li2PbN2 crystallizes in the trigonal P-3m1 space group. Li(1) is bonded to four equivalent N(1) atoms to form LiN4 tetrahedra that share corners with six equivalent Pb(1)N6 octahedra, corners with six equivalent Li(1)N4 tetrahedra, edges with three equivalent Pb(1)N6 octahedra, and edges with three equivalent Li(1)N4 tetrahedra. The corner-sharing octahedral tilt angles range from 13-56°. Pb(1) is bonded to six equivalent N(1) atoms to form PbN6 octahedra that share corners with twelve equivalent Li(1)N4 tetrahedra, edges with six equivalent Pb(1)N6 octahedra, and edges with six equivalent Li(1)N4 tetrahedra. N(1) is bonded in a 7-coordinate geometry to four equivalent Li(1) and three equivalent Pb(1) atoms. is represented by the CIF card [CIF]
data_Li2PbN2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.443
_cell_length_b   3.443
_cell_length_c   5.608
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   57.582
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.667  0.333  0.380  1.0
  Li  Li1  1  0.333  0.667  0.620  1.0
  Pb  Pb2  1  0.000  0.000  0.000  1.0
  N  N3  1  0.667  0.333  0.760  1.0
  N  N4  1  0.333  0.667  0.240  1.0
[/CIF]
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