The crystal structure described by AgTl(PO3)2 crystallizes in the monoclinic P2_1/c space group. Ag(1) is bonded to one O(1), one O(2), one O(3), and two equivalent O(5) atoms to form distorted AgO5 trigonal bipyramids that share corners with two equivalent P(2)O4 tetrahedra, corners with three equivalent P(1)O4 tetrahedra, and  an edgeedge with one Ag(1)O5 trigonal bipyramid. Tl(1) is bonded in a 4-coordinate geometry to one O(3), one O(5), and two equivalent O(2) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(2), one O(4), one O(5), and one O(6) atom to form PO4 tetrahedra that share corners with two equivalent P(2)O4 tetrahedra and corners with three equivalent Ag(1)O5 trigonal bipyramids. In the second P site, P(2) is bonded to one O(1), one O(3), one O(4), and one O(6) atom to form PO4 tetrahedra that share corners with two equivalent P(1)O4 tetrahedra and corners with two equivalent Ag(1)O5 trigonal bipyramids. There are six inequivalent O sites. In the first O site, O(5) is bonded in a distorted single-bond geometry to two equivalent Ag(1), one Tl(1), and one P(1) atom. In the second O site, O(6) is bonded in a distorted bent 150 degrees geometry to one P(1) and one P(2) atom. In the third O site, O(1) is bonded in a distorted single-bond geometry to one Ag(1) and one P(2) atom. In the fourth O site, O(2) is bonded in a distorted single-bond geometry to one Ag(1), two equivalent Tl(1), and one P(1) atom. In the fifth O site, O(3) is bonded in a 2-coordinate geometry to one Ag(1), one Tl(1), and one P(2) atom. In the sixth O site, O(4) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. is represented by the CIF card [CIF]
data_TlAg(PO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.282
_cell_length_b   7.622
_cell_length_c   13.544
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   95.212
_symmetry_Int_Tables_number   1
_cell_volume   645.791
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.299  0.732  0.669  1.0
  Tl  Tl1  1  0.701  0.268  0.331  1.0
  Tl  Tl2  1  0.701  0.768  0.169  1.0
  Tl  Tl3  1  0.299  0.232  0.831  1.0
  Ag  Ag4  1  0.815  0.696  0.472  1.0
  Ag  Ag5  1  0.185  0.304  0.528  1.0
  Ag  Ag6  1  0.185  0.804  0.972  1.0
  Ag  Ag7  1  0.815  0.196  0.028  1.0
  P  P8  1  0.689  0.848  0.867  1.0
  P  P9  1  0.311  0.152  0.133  1.0
  P  P10  1  0.311  0.652  0.367  1.0
  P  P11  1  0.689  0.348  0.633  1.0
  P  P12  1  0.846  0.994  0.673  1.0
  P  P13  1  0.154  0.006  0.327  1.0
  P  P14  1  0.154  0.506  0.173  1.0
  P  P15  1  0.846  0.494  0.827  1.0
  O  O16  1  0.932  0.932  0.354  1.0
  O  O17  1  0.068  0.068  0.646  1.0
  O  O18  1  0.068  0.568  0.854  1.0
  O  O19  1  0.932  0.432  0.146  1.0
  O  O20  1  0.466  0.901  0.850  1.0
  O  O21  1  0.534  0.099  0.150  1.0
  O  O22  1  0.534  0.599  0.350  1.0
  O  O23  1  0.466  0.401  0.650  1.0
  O  O24  1  0.738  0.835  0.622  1.0
  O  O25  1  0.262  0.165  0.378  1.0
  O  O26  1  0.262  0.665  0.122  1.0
  O  O27  1  0.738  0.335  0.878  1.0
  O  O28  1  0.857  0.954  0.792  1.0
  O  O29  1  0.143  0.046  0.208  1.0
  O  O30  1  0.143  0.546  0.292  1.0
  O  O31  1  0.857  0.454  0.708  1.0
  O  O32  1  0.790  0.867  0.967  1.0
  O  O33  1  0.210  0.133  0.033  1.0
  O  O34  1  0.210  0.633  0.467  1.0
  O  O35  1  0.790  0.367  0.533  1.0
  O  O36  1  0.680  0.646  0.829  1.0
  O  O37  1  0.320  0.354  0.171  1.0
  O  O38  1  0.320  0.854  0.329  1.0
  O  O39  1  0.680  0.146  0.671  1.0
[/CIF]
.
The crystal structure described by AgTl(PO3)2 crystallizes in the monoclinic P2_1/c space group. Ag(1) is bonded to one O(1), one O(2), one O(3), and two equivalent O(5) atoms to form distorted AgO5 trigonal bipyramids that share corners with two equivalent P(2)O4 tetrahedra, corners with three equivalent P(1)O4 tetrahedra, and  an edgeedge with one Ag(1)O5 trigonal bipyramid. Tl(1) is bonded in a 4-coordinate geometry to one O(3), one O(5), and two equivalent O(2) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(2), one O(4), one O(5), and one O(6) atom to form PO4 tetrahedra that share corners with two equivalent P(2)O4 tetrahedra and corners with three equivalent Ag(1)O5 trigonal bipyramids. In the second P site, P(2) is bonded to one O(1), one O(3), one O(4), and one O(6) atom to form PO4 tetrahedra that share corners with two equivalent P(1)O4 tetrahedra and corners with two equivalent Ag(1)O5 trigonal bipyramids. There are six inequivalent O sites. In the first O site, O(5) is bonded in a distorted single-bond geometry to two equivalent Ag(1), one Tl(1), and one P(1) atom. In the second O site, O(6) is bonded in a distorted bent 150 degrees geometry to one P(1) and one P(2) atom. In the third O site, O(1) is bonded in a distorted single-bond geometry to one Ag(1) and one P(2) atom. In the fourth O site, O(2) is bonded in a distorted single-bond geometry to one Ag(1), two equivalent Tl(1), and one P(1) atom. In the fifth O site, O(3) is bonded in a 2-coordinate geometry to one Ag(1), one Tl(1), and one P(2) atom. In the sixth O site, O(4) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. is represented by the CIF card [CIF]
data_TlAg(PO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.282
_cell_length_b   7.622
_cell_length_c   13.544
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   95.212
_symmetry_Int_Tables_number   1
_cell_volume   645.791
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.299  0.732  0.669  1.0
  Tl  Tl1  1  0.701  0.268  0.331  1.0
  Tl  Tl2  1  0.701  0.768  0.169  1.0
  Tl  Tl3  1  0.299  0.232  0.831  1.0
  Ag  Ag4  1  0.815  0.696  0.472  1.0
  Ag  Ag5  1  0.185  0.304  0.528  1.0
  Ag  Ag6  1  0.185  0.804  0.972  1.0
  Ag  Ag7  1  0.815  0.196  0.028  1.0
  P  P8  1  0.689  0.848  0.867  1.0
  P  P9  1  0.311  0.152  0.133  1.0
  P  P10  1  0.311  0.652  0.367  1.0
  P  P11  1  0.689  0.348  0.633  1.0
  P  P12  1  0.846  0.994  0.673  1.0
  P  P13  1  0.154  0.006  0.327  1.0
  P  P14  1  0.154  0.506  0.173  1.0
  P  P15  1  0.846  0.494  0.827  1.0
  O  O16  1  0.932  0.932  0.354  1.0
  O  O17  1  0.068  0.068  0.646  1.0
  O  O18  1  0.068  0.568  0.854  1.0
  O  O19  1  0.932  0.432  0.146  1.0
  O  O20  1  0.466  0.901  0.850  1.0
  O  O21  1  0.534  0.099  0.150  1.0
  O  O22  1  0.534  0.599  0.350  1.0
  O  O23  1  0.466  0.401  0.650  1.0
  O  O24  1  0.738  0.835  0.622  1.0
  O  O25  1  0.262  0.165  0.378  1.0
  O  O26  1  0.262  0.665  0.122  1.0
  O  O27  1  0.738  0.335  0.878  1.0
  O  O28  1  0.857  0.954  0.792  1.0
  O  O29  1  0.143  0.046  0.208  1.0
  O  O30  1  0.143  0.546  0.292  1.0
  O  O31  1  0.857  0.454  0.708  1.0
  O  O32  1  0.790  0.867  0.967  1.0
  O  O33  1  0.210  0.133  0.033  1.0
  O  O34  1  0.210  0.633  0.467  1.0
  O  O35  1  0.790  0.367  0.533  1.0
  O  O36  1  0.680  0.646  0.829  1.0
  O  O37  1  0.320  0.354  0.171  1.0
  O  O38  1  0.320  0.854  0.329  1.0
  O  O39  1  0.680  0.146  0.671  1.0
[/CIF]
.