The compound described by CuVO3 is Ilmenite structured and crystallizes in the trigonal R-3 space group. V(1) is bonded to six equivalent O(1) atoms to form distorted VO6 octahedra that share corners with nine equivalent Cu(1)O6 octahedra, edges with three equivalent V(1)O6 octahedra, and  a faceface with one Cu(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-59°. Cu(1) is bonded to six equivalent O(1) atoms to form distorted CuO6 octahedra that share corners with nine equivalent V(1)O6 octahedra, edges with three equivalent Cu(1)O6 octahedra, and  a faceface with one V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-59°. O(1) is bonded in a distorted see-saw-like geometry to two equivalent V(1) and two equivalent Cu(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_VCuO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.562
_cell_length_b   5.562
_cell_length_c   5.562
_cell_angle_alpha   53.426
_cell_angle_beta   53.426
_cell_angle_gamma   53.426
_symmetry_Int_Tables_number   1
_cell_volume   102.935
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.353  0.353  0.353  1.0
  V  V1  1  0.647  0.647  0.647  1.0
  Cu  Cu2  1  0.140  0.140  0.140  1.0
  Cu  Cu3  1  0.860  0.860  0.860  1.0
  O  O4  1  0.716  0.066  0.446  1.0
  O  O5  1  0.066  0.446  0.716  1.0
  O  O6  1  0.446  0.716  0.066  1.0
  O  O7  1  0.284  0.934  0.554  1.0
  O  O8  1  0.554  0.284  0.934  1.0
  O  O9  1  0.934  0.554  0.284  1.0
[/CIF]
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The compound described by CuVO3 is Ilmenite structured and crystallizes in the trigonal R-3 space group. V(1) is bonded to six equivalent O(1) atoms to form distorted VO6 octahedra that share corners with nine equivalent Cu(1)O6 octahedra, edges with three equivalent V(1)O6 octahedra, and  a faceface with one Cu(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-59°. Cu(1) is bonded to six equivalent O(1) atoms to form distorted CuO6 octahedra that share corners with nine equivalent V(1)O6 octahedra, edges with three equivalent Cu(1)O6 octahedra, and  a faceface with one V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-59°. O(1) is bonded in a distorted see-saw-like geometry to two equivalent V(1) and two equivalent Cu(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_VCuO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.562
_cell_length_b   5.562
_cell_length_c   5.562
_cell_angle_alpha   53.426
_cell_angle_beta   53.426
_cell_angle_gamma   53.426
_symmetry_Int_Tables_number   1
_cell_volume   102.935
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.353  0.353  0.353  1.0
  V  V1  1  0.647  0.647  0.647  1.0
  Cu  Cu2  1  0.140  0.140  0.140  1.0
  Cu  Cu3  1  0.860  0.860  0.860  1.0
  O  O4  1  0.716  0.066  0.446  1.0
  O  O5  1  0.066  0.446  0.716  1.0
  O  O6  1  0.446  0.716  0.066  1.0
  O  O7  1  0.284  0.934  0.554  1.0
  O  O8  1  0.554  0.284  0.934  1.0
  O  O9  1  0.934  0.554  0.284  1.0
[/CIF]
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