The crystal structure described by NaSbP2S6 crystallizes in the monoclinic P2_1 space group. Na(1) is bonded in a 7-coordinate geometry to one S(5), two equivalent S(3), two equivalent S(4), and two equivalent S(6) atoms. Sb(1) is bonded in a distorted rectangular see-saw-like geometry to one S(1), one S(2), one S(4), and one S(5) atom. There are two inequivalent P sites. In the first P site, P(1) is bonded in a distorted tetrahedral geometry to one P(2), one S(1), one S(5), and one S(6) atom. In the second P site, P(2) is bonded in a 4-coordinate geometry to one P(1), one S(2), one S(3), and one S(4) atom. There are six inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one Sb(1) and one P(1) atom. In the second S site, S(2) is bonded in an L-shaped geometry to one Sb(1) and one P(2) atom. In the third S site, S(3) is bonded in a distorted water-like geometry to two equivalent Na(1) and one P(2) atom. In the fourth S site, S(4) is bonded in a 4-coordinate geometry to two equivalent Na(1), one Sb(1), and one P(2) atom. In the fifth S site, S(5) is bonded in a distorted water-like geometry to one Na(1), one Sb(1), and one P(1) atom. In the sixth S site, S(6) is bonded in a 3-coordinate geometry to two equivalent Na(1) and one P(1) atom. is represented by the CIF file [CIF]
data_NaSb(PS3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.703
_cell_length_b   6.643
_cell_length_c   9.604
_cell_angle_alpha   86.612
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   490.563
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.535  0.303  0.507  1.0
  Na  Na1  1  0.035  0.697  0.493  1.0
  Sb  Sb2  1  0.252  0.188  0.984  1.0
  Sb  Sb3  1  0.752  0.812  0.016  1.0
  P  P4  1  0.835  0.310  0.819  1.0
  P  P5  1  0.051  0.194  0.686  1.0
  P  P6  1  0.551  0.806  0.314  1.0
  P  P7  1  0.335  0.690  0.181  1.0
  S  S8  1  0.950  0.342  0.013  1.0
  S  S9  1  0.128  0.945  0.812  1.0
  S  S10  1  0.952  0.135  0.504  1.0
  S  S11  1  0.452  0.865  0.496  1.0
  S  S12  1  0.237  0.408  0.700  1.0
  S  S13  1  0.628  0.055  0.188  1.0
  S  S14  1  0.644  0.091  0.827  1.0
  S  S15  1  0.742  0.568  0.731  1.0
  S  S16  1  0.144  0.909  0.173  1.0
  S  S17  1  0.242  0.432  0.269  1.0
  S  S18  1  0.450  0.658  0.987  1.0
  S  S19  1  0.737  0.592  0.300  1.0
[/CIF]
.
The crystal structure described by NaSbP2S6 crystallizes in the monoclinic P2_1 space group. Na(1) is bonded in a 7-coordinate geometry to one S(5), two equivalent S(3), two equivalent S(4), and two equivalent S(6) atoms. Sb(1) is bonded in a distorted rectangular see-saw-like geometry to one S(1), one S(2), one S(4), and one S(5) atom. There are two inequivalent P sites. In the first P site, P(1) is bonded in a distorted tetrahedral geometry to one P(2), one S(1), one S(5), and one S(6) atom. In the second P site, P(2) is bonded in a 4-coordinate geometry to one P(1), one S(2), one S(3), and one S(4) atom. There are six inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one Sb(1) and one P(1) atom. In the second S site, S(2) is bonded in an L-shaped geometry to one Sb(1) and one P(2) atom. In the third S site, S(3) is bonded in a distorted water-like geometry to two equivalent Na(1) and one P(2) atom. In the fourth S site, S(4) is bonded in a 4-coordinate geometry to two equivalent Na(1), one Sb(1), and one P(2) atom. In the fifth S site, S(5) is bonded in a distorted water-like geometry to one Na(1), one Sb(1), and one P(1) atom. In the sixth S site, S(6) is bonded in a 3-coordinate geometry to two equivalent Na(1) and one P(1) atom. is represented by the CIF file [CIF]
data_NaSb(PS3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.703
_cell_length_b   6.643
_cell_length_c   9.604
_cell_angle_alpha   86.612
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   490.563
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.535  0.303  0.507  1.0
  Na  Na1  1  0.035  0.697  0.493  1.0
  Sb  Sb2  1  0.252  0.188  0.984  1.0
  Sb  Sb3  1  0.752  0.812  0.016  1.0
  P  P4  1  0.835  0.310  0.819  1.0
  P  P5  1  0.051  0.194  0.686  1.0
  P  P6  1  0.551  0.806  0.314  1.0
  P  P7  1  0.335  0.690  0.181  1.0
  S  S8  1  0.950  0.342  0.013  1.0
  S  S9  1  0.128  0.945  0.812  1.0
  S  S10  1  0.952  0.135  0.504  1.0
  S  S11  1  0.452  0.865  0.496  1.0
  S  S12  1  0.237  0.408  0.700  1.0
  S  S13  1  0.628  0.055  0.188  1.0
  S  S14  1  0.644  0.091  0.827  1.0
  S  S15  1  0.742  0.568  0.731  1.0
  S  S16  1  0.144  0.909  0.173  1.0
  S  S17  1  0.242  0.432  0.269  1.0
  S  S18  1  0.450  0.658  0.987  1.0
  S  S19  1  0.737  0.592  0.300  1.0
[/CIF]
.