The crystal structure described by VOF is Hydrophilite-derived structured and crystallizes in the triclinic P-1 space group. There are six inequivalent V sites. In the first V site, V(1) is bonded to one O(2), one O(3), one O(4), one F(2), one F(3), and one F(4) atom to form VO3F3 octahedra that share corners with two equivalent V(5)O2F4 octahedra, corners with two equivalent V(6)O2F4 octahedra, corners with four equivalent V(4)O3F3 octahedra,  an edgeedge with one V(2)O4F2 octahedra, and  an edgeedge with one V(3)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 45-53°. In the second V site, V(2) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent F(4) atoms to form VO4F2 octahedra that share corners with four equivalent V(6)O2F4 octahedra, corners with four equivalent V(4)O3F3 octahedra, and edges with two equivalent V(1)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 46-55°. In the third V site, V(3) is bonded to two equivalent O(3), two equivalent O(4), and two equivalent F(1) atoms to form VO4F2 octahedra that share corners with four equivalent V(5)O2F4 octahedra, corners with four equivalent V(4)O3F3 octahedra, and edges with two equivalent V(1)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 46-54°. In the fourth V site, V(4) is bonded to one O(1), one O(2), one O(4), one F(1), one F(2), and one F(3) atom to form VO3F3 octahedra that share corners with two equivalent V(2)O4F2 octahedra, corners with two equivalent V(3)O4F2 octahedra, corners with four equivalent V(1)O3F3 octahedra,  an edgeedge with one V(5)O2F4 octahedra, and  an edgeedge with one V(6)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 47-55°. In the fifth V site, V(5) is bonded to two equivalent O(3), two equivalent F(1), and two equivalent F(2) atoms to form VO2F4 octahedra that share corners with four equivalent V(1)O3F3 octahedra, corners with four equivalent V(3)O4F2 octahedra, and edges with two equivalent V(4)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 46-54°. In the sixth V site, V(6) is bonded to two equivalent O(1), two equivalent F(3), and two equivalent F(4) atoms to form VO2F4 octahedra that share corners with four equivalent V(1)O3F3 octahedra, corners with four equivalent V(2)O4F2 octahedra, and edges with two equivalent V(4)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 45-54°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one V(2), one V(4), and one V(6) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one V(1), one V(2), and one V(4) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one V(1), one V(3), and one V(5) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one V(1), one V(3), and one V(4) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a trigonal planar geometry to one V(3), one V(4), and one V(5) atom. In the second F site, F(2) is bonded in a trigonal planar geometry to one V(1), one V(4), and one V(5) atom. In the third F site, F(3) is bonded in a distorted T-shaped geometry to one V(1), one V(4), and one V(6) atom. In the fourth F site, F(4) is bonded in a distorted trigonal planar geometry to one V(1), one V(2), and one V(6) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_VOF
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.679
_cell_length_b   5.638
_cell_length_c   10.543
_cell_angle_alpha   96.534
_cell_angle_beta   90.806
_cell_angle_gamma   92.008
_symmetry_Int_Tables_number   1
_cell_volume   276.080
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.487  0.749  0.739  1.0
  V  V1  1  0.500  0.500  0.000  1.0
  V  V2  1  0.513  0.251  0.261  1.0
  V  V3  1  0.500  0.000  0.500  1.0
  V  V4  1  0.983  0.255  0.762  1.0
  V  V5  1  0.017  0.745  0.238  1.0
  V  V6  1  0.000  0.500  0.500  1.0
  V  V7  1  0.000  0.000  0.000  1.0
  O  O8  1  0.805  0.265  0.931  1.0
  O  O9  1  0.690  0.521  0.177  1.0
  O  O10  1  0.705  0.274  0.433  1.0
  O  O11  1  0.701  0.018  0.673  1.0
  O  O12  1  0.295  0.726  0.567  1.0
  O  O13  1  0.299  0.982  0.327  1.0
  O  O14  1  0.310  0.479  0.823  1.0
  O  O15  1  0.195  0.735  0.069  1.0
  F  F16  1  0.806  0.769  0.416  1.0
  F  F17  1  0.801  0.528  0.675  1.0
  F  F18  1  0.797  0.025  0.173  1.0
  F  F19  1  0.701  0.776  0.918  1.0
  F  F20  1  0.299  0.224  0.082  1.0
  F  F21  1  0.199  0.472  0.325  1.0
  F  F22  1  0.203  0.975  0.827  1.0
  F  F23  1  0.194  0.231  0.584  1.0
[/CIF]
.
The crystal structure described by VOF is Hydrophilite-derived structured and crystallizes in the triclinic P-1 space group. There are six inequivalent V sites. In the first V site, V(1) is bonded to one O(2), one O(3), one O(4), one F(2), one F(3), and one F(4) atom to form VO3F3 octahedra that share corners with two equivalent V(5)O2F4 octahedra, corners with two equivalent V(6)O2F4 octahedra, corners with four equivalent V(4)O3F3 octahedra,  an edgeedge with one V(2)O4F2 octahedra, and  an edgeedge with one V(3)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 45-53°. In the second V site, V(2) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent F(4) atoms to form VO4F2 octahedra that share corners with four equivalent V(6)O2F4 octahedra, corners with four equivalent V(4)O3F3 octahedra, and edges with two equivalent V(1)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 46-55°. In the third V site, V(3) is bonded to two equivalent O(3), two equivalent O(4), and two equivalent F(1) atoms to form VO4F2 octahedra that share corners with four equivalent V(5)O2F4 octahedra, corners with four equivalent V(4)O3F3 octahedra, and edges with two equivalent V(1)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 46-54°. In the fourth V site, V(4) is bonded to one O(1), one O(2), one O(4), one F(1), one F(2), and one F(3) atom to form VO3F3 octahedra that share corners with two equivalent V(2)O4F2 octahedra, corners with two equivalent V(3)O4F2 octahedra, corners with four equivalent V(1)O3F3 octahedra,  an edgeedge with one V(5)O2F4 octahedra, and  an edgeedge with one V(6)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 47-55°. In the fifth V site, V(5) is bonded to two equivalent O(3), two equivalent F(1), and two equivalent F(2) atoms to form VO2F4 octahedra that share corners with four equivalent V(1)O3F3 octahedra, corners with four equivalent V(3)O4F2 octahedra, and edges with two equivalent V(4)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 46-54°. In the sixth V site, V(6) is bonded to two equivalent O(1), two equivalent F(3), and two equivalent F(4) atoms to form VO2F4 octahedra that share corners with four equivalent V(1)O3F3 octahedra, corners with four equivalent V(2)O4F2 octahedra, and edges with two equivalent V(4)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 45-54°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one V(2), one V(4), and one V(6) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one V(1), one V(2), and one V(4) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one V(1), one V(3), and one V(5) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one V(1), one V(3), and one V(4) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a trigonal planar geometry to one V(3), one V(4), and one V(5) atom. In the second F site, F(2) is bonded in a trigonal planar geometry to one V(1), one V(4), and one V(5) atom. In the third F site, F(3) is bonded in a distorted T-shaped geometry to one V(1), one V(4), and one V(6) atom. In the fourth F site, F(4) is bonded in a distorted trigonal planar geometry to one V(1), one V(2), and one V(6) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_VOF
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.679
_cell_length_b   5.638
_cell_length_c   10.543
_cell_angle_alpha   96.534
_cell_angle_beta   90.806
_cell_angle_gamma   92.008
_symmetry_Int_Tables_number   1
_cell_volume   276.080
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.487  0.749  0.739  1.0
  V  V1  1  0.500  0.500  0.000  1.0
  V  V2  1  0.513  0.251  0.261  1.0
  V  V3  1  0.500  0.000  0.500  1.0
  V  V4  1  0.983  0.255  0.762  1.0
  V  V5  1  0.017  0.745  0.238  1.0
  V  V6  1  0.000  0.500  0.500  1.0
  V  V7  1  0.000  0.000  0.000  1.0
  O  O8  1  0.805  0.265  0.931  1.0
  O  O9  1  0.690  0.521  0.177  1.0
  O  O10  1  0.705  0.274  0.433  1.0
  O  O11  1  0.701  0.018  0.673  1.0
  O  O12  1  0.295  0.726  0.567  1.0
  O  O13  1  0.299  0.982  0.327  1.0
  O  O14  1  0.310  0.479  0.823  1.0
  O  O15  1  0.195  0.735  0.069  1.0
  F  F16  1  0.806  0.769  0.416  1.0
  F  F17  1  0.801  0.528  0.675  1.0
  F  F18  1  0.797  0.025  0.173  1.0
  F  F19  1  0.701  0.776  0.918  1.0
  F  F20  1  0.299  0.224  0.082  1.0
  F  F21  1  0.199  0.472  0.325  1.0
  F  F22  1  0.203  0.975  0.827  1.0
  F  F23  1  0.194  0.231  0.584  1.0
[/CIF]
.