The structure described by KVSO6 crystallizes in the orthorhombic P2_12_12_1 space group. K(1) is bonded in a 9-coordinate geometry to one O(5), one O(6), two equivalent O(1), two equivalent O(4), and three equivalent O(3) atoms. V(1) is bonded in a 6-coordinate geometry to one O(1), one O(4), one O(5), one O(6), and two equivalent O(2) atoms. S(1) is bonded in a tetrahedral geometry to one O(1), one O(3), one O(4), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to two equivalent K(1), one V(1), and one S(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to two equivalent V(1) atoms. In the third O site, O(3) is bonded in a distorted single-bond geometry to three equivalent K(1) and one S(1) atom. In the fourth O site, O(4) is bonded in a 2-coordinate geometry to two equivalent K(1), one V(1), and one S(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one K(1) and one V(1) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one K(1), one V(1), and one S(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_KVSO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.558
_cell_length_b   8.641
_cell_length_c   11.266
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   541.065
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.027  0.190  0.640  1.0
  K  K1  1  0.527  0.310  0.360  1.0
  K  K2  1  0.473  0.810  0.140  1.0
  K  K3  1  0.973  0.690  0.860  1.0
  V  V4  1  0.032  0.654  0.437  1.0
  V  V5  1  0.532  0.846  0.563  1.0
  V  V6  1  0.968  0.154  0.063  1.0
  V  V7  1  0.468  0.346  0.937  1.0
  S  S8  1  0.533  0.446  0.711  1.0
  S  S9  1  0.467  0.946  0.789  1.0
  S  S10  1  0.967  0.554  0.211  1.0
  S  S11  1  0.033  0.054  0.289  1.0
  O  O12  1  0.709  0.370  0.800  1.0
  O  O13  1  0.674  0.217  0.009  1.0
  O  O14  1  0.791  0.630  0.300  1.0
  O  O15  1  0.489  0.854  0.896  1.0
  O  O16  1  0.174  0.283  0.991  1.0
  O  O17  1  0.198  0.564  0.286  1.0
  O  O18  1  0.507  0.509  0.006  1.0
  O  O19  1  0.302  0.436  0.786  1.0
  O  O20  1  0.698  0.936  0.714  1.0
  O  O21  1  0.011  0.146  0.396  1.0
  O  O22  1  0.989  0.646  0.104  1.0
  O  O23  1  0.802  0.064  0.214  1.0
  O  O24  1  0.007  0.991  0.994  1.0
  O  O25  1  0.993  0.491  0.506  1.0
  O  O26  1  0.326  0.717  0.491  1.0
  O  O27  1  0.826  0.783  0.509  1.0
  O  O28  1  0.892  0.394  0.192  1.0
  O  O29  1  0.511  0.353  0.604  1.0
  O  O30  1  0.108  0.894  0.308  1.0
  O  O31  1  0.493  0.009  0.494  1.0
  O  O32  1  0.608  0.606  0.692  1.0
  O  O33  1  0.291  0.870  0.700  1.0
  O  O34  1  0.392  0.106  0.808  1.0
  O  O35  1  0.209  0.130  0.200  1.0
[/CIF]
.
The structure described by KVSO6 crystallizes in the orthorhombic P2_12_12_1 space group. K(1) is bonded in a 9-coordinate geometry to one O(5), one O(6), two equivalent O(1), two equivalent O(4), and three equivalent O(3) atoms. V(1) is bonded in a 6-coordinate geometry to one O(1), one O(4), one O(5), one O(6), and two equivalent O(2) atoms. S(1) is bonded in a tetrahedral geometry to one O(1), one O(3), one O(4), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to two equivalent K(1), one V(1), and one S(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to two equivalent V(1) atoms. In the third O site, O(3) is bonded in a distorted single-bond geometry to three equivalent K(1) and one S(1) atom. In the fourth O site, O(4) is bonded in a 2-coordinate geometry to two equivalent K(1), one V(1), and one S(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one K(1) and one V(1) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one K(1), one V(1), and one S(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_KVSO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.558
_cell_length_b   8.641
_cell_length_c   11.266
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   541.065
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.027  0.190  0.640  1.0
  K  K1  1  0.527  0.310  0.360  1.0
  K  K2  1  0.473  0.810  0.140  1.0
  K  K3  1  0.973  0.690  0.860  1.0
  V  V4  1  0.032  0.654  0.437  1.0
  V  V5  1  0.532  0.846  0.563  1.0
  V  V6  1  0.968  0.154  0.063  1.0
  V  V7  1  0.468  0.346  0.937  1.0
  S  S8  1  0.533  0.446  0.711  1.0
  S  S9  1  0.467  0.946  0.789  1.0
  S  S10  1  0.967  0.554  0.211  1.0
  S  S11  1  0.033  0.054  0.289  1.0
  O  O12  1  0.709  0.370  0.800  1.0
  O  O13  1  0.674  0.217  0.009  1.0
  O  O14  1  0.791  0.630  0.300  1.0
  O  O15  1  0.489  0.854  0.896  1.0
  O  O16  1  0.174  0.283  0.991  1.0
  O  O17  1  0.198  0.564  0.286  1.0
  O  O18  1  0.507  0.509  0.006  1.0
  O  O19  1  0.302  0.436  0.786  1.0
  O  O20  1  0.698  0.936  0.714  1.0
  O  O21  1  0.011  0.146  0.396  1.0
  O  O22  1  0.989  0.646  0.104  1.0
  O  O23  1  0.802  0.064  0.214  1.0
  O  O24  1  0.007  0.991  0.994  1.0
  O  O25  1  0.993  0.491  0.506  1.0
  O  O26  1  0.326  0.717  0.491  1.0
  O  O27  1  0.826  0.783  0.509  1.0
  O  O28  1  0.892  0.394  0.192  1.0
  O  O29  1  0.511  0.353  0.604  1.0
  O  O30  1  0.108  0.894  0.308  1.0
  O  O31  1  0.493  0.009  0.494  1.0
  O  O32  1  0.608  0.606  0.692  1.0
  O  O33  1  0.291  0.870  0.700  1.0
  O  O34  1  0.392  0.106  0.808  1.0
  O  O35  1  0.209  0.130  0.200  1.0
[/CIF]
.