The material structure described by V2AgN3 crystallizes in the trigonal P3_121 space group. V(1) is bonded to three equivalent N(1) and three equivalent N(2) atoms to form a mixture of distorted corner and edge-sharing VN6 octahedra. The corner-sharing octahedra are not tilted. Ag(1) is bonded in a linear geometry to two equivalent N(2) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded to six equivalent V(1) atoms to form edge-sharing NV6 octahedra. In the second N site, N(2) is bonded in a distorted rectangular see-saw-like geometry to three equivalent V(1) and one Ag(1) atom. is represented by the CIF file [CIF]
data_V2AgN3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.949
_cell_length_b   2.949
_cell_length_c   26.202
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   197.381
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.765  0.710  0.214  1.0
  V  V1  1  0.945  0.235  0.880  1.0
  V  V2  1  0.290  0.055  0.547  1.0
  V  V3  1  0.235  0.945  0.120  1.0
  V  V4  1  0.710  0.765  0.786  1.0
  V  V5  1  0.055  0.290  0.453  1.0
  Ag  Ag6  1  0.000  0.362  0.667  1.0
  Ag  Ag7  1  0.362  0.000  0.333  1.0
  Ag  Ag8  1  0.638  0.638  0.000  1.0
  N  N9  1  0.000  0.327  0.167  1.0
  N  N10  1  0.327  0.000  0.833  1.0
  N  N11  1  0.673  0.673  0.500  1.0
  N  N12  1  0.355  0.989  0.415  1.0
  N  N13  1  0.634  0.645  0.082  1.0
  N  N14  1  0.011  0.366  0.748  1.0
  N  N15  1  0.645  0.634  0.918  1.0
  N  N16  1  0.989  0.355  0.585  1.0
  N  N17  1  0.366  0.011  0.252  1.0
[/CIF]
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The material structure described by V2AgN3 crystallizes in the trigonal P3_121 space group. V(1) is bonded to three equivalent N(1) and three equivalent N(2) atoms to form a mixture of distorted corner and edge-sharing VN6 octahedra. The corner-sharing octahedra are not tilted. Ag(1) is bonded in a linear geometry to two equivalent N(2) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded to six equivalent V(1) atoms to form edge-sharing NV6 octahedra. In the second N site, N(2) is bonded in a distorted rectangular see-saw-like geometry to three equivalent V(1) and one Ag(1) atom. is represented by the CIF file [CIF]
data_V2AgN3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.949
_cell_length_b   2.949
_cell_length_c   26.202
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   197.381
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.765  0.710  0.214  1.0
  V  V1  1  0.945  0.235  0.880  1.0
  V  V2  1  0.290  0.055  0.547  1.0
  V  V3  1  0.235  0.945  0.120  1.0
  V  V4  1  0.710  0.765  0.786  1.0
  V  V5  1  0.055  0.290  0.453  1.0
  Ag  Ag6  1  0.000  0.362  0.667  1.0
  Ag  Ag7  1  0.362  0.000  0.333  1.0
  Ag  Ag8  1  0.638  0.638  0.000  1.0
  N  N9  1  0.000  0.327  0.167  1.0
  N  N10  1  0.327  0.000  0.833  1.0
  N  N11  1  0.673  0.673  0.500  1.0
  N  N12  1  0.355  0.989  0.415  1.0
  N  N13  1  0.634  0.645  0.082  1.0
  N  N14  1  0.011  0.366  0.748  1.0
  N  N15  1  0.645  0.634  0.918  1.0
  N  N16  1  0.989  0.355  0.585  1.0
  N  N17  1  0.366  0.011  0.252  1.0
[/CIF]
.