The crystal structure described by Pr(NO4)2NO3(O2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four hydrogen peroxide molecules, two nitric acid molecules, and two Pr(NO4)2 clusters. In each Pr(NO4)2 cluster, Pr(1) is bonded in a 3-coordinate geometry to one N(3), one O(11), one O(13), one O(5), and one O(9) atom. There are two inequivalent N sites. In the first N site, N(2) is bonded in a 3-coordinate geometry to one O(4), one O(5), and one O(6) atom. In the second N site, N(3) is bonded in a distorted rectangular see-saw-like geometry to one Pr(1), one O(7), one O(8), and one O(9) atom. There are eight inequivalent O sites. In the first O site, O(13) is bonded in a distorted L-shaped geometry to one Pr(1) and one O(11) atom. In the second O site, O(4) is bonded in a single-bond geometry to one N(2) atom. In the third O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Pr(1) and one N(2) atom. In the fourth O site, O(6) is bonded in a single-bond geometry to one N(2) atom. In the fifth O site, O(7) is bonded in a distorted single-bond geometry to one N(3) atom. In the sixth O site, O(8) is bonded in a single-bond geometry to one N(3) atom. In the seventh O site, O(9) is bonded in a 2-coordinate geometry to one Pr(1) and one N(3) atom. In the eighth O site, O(11) is bonded in a distorted single-bond geometry to one Pr(1) and one O(13) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Pr(NO5)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.073
_cell_length_b   8.836
_cell_length_c   11.701
_cell_angle_alpha   110.998
_cell_angle_beta   88.492
_cell_angle_gamma   111.296
_symmetry_Int_Tables_number   1
_cell_volume   631.578
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pr  Pr0  1  0.996  0.845  0.288  1.0
  Pr  Pr1  1  0.004  0.155  0.712  1.0
  N  N2  1  0.265  0.178  0.164  1.0
  N  N3  1  0.735  0.822  0.836  1.0
  N  N4  1  0.264  0.818  0.519  1.0
  N  N5  1  0.736  0.182  0.481  1.0
  N  N6  1  0.076  0.420  0.819  1.0
  N  N7  1  0.924  0.580  0.181  1.0
  O  O8  1  0.392  0.312  0.119  1.0
  O  O9  1  0.608  0.688  0.881  1.0
  O  O10  1  0.258  0.030  0.157  1.0
  O  O11  1  0.742  0.970  0.843  1.0
  O  O12  1  0.124  0.165  0.223  1.0
  O  O13  1  0.876  0.835  0.777  1.0
  O  O14  1  0.246  0.734  0.445  1.0
  O  O15  1  0.754  0.266  0.555  1.0
  O  O16  1  0.129  0.897  0.493  1.0
  O  O17  1  0.871  0.103  0.507  1.0
  O  O18  1  0.400  0.821  0.605  1.0
  O  O19  1  0.600  0.179  0.395  1.0
  O  O20  1  0.067  0.454  0.701  1.0
  O  O21  1  0.933  0.546  0.299  1.0
  O  O22  1  0.080  0.526  0.862  1.0
  O  O23  1  0.920  0.474  0.138  1.0
  O  O24  1  0.075  0.263  0.887  1.0
  O  O25  1  0.925  0.737  0.113  1.0
  O  O26  1  0.700  0.108  0.058  1.0
  O  O27  1  0.300  0.892  0.942  1.0
  O  O28  1  0.593  0.866  0.286  1.0
  O  O29  1  0.407  0.134  0.714  1.0
  O  O30  1  0.702  0.620  0.544  1.0
  O  O31  1  0.298  0.380  0.456  1.0
  O  O32  1  0.433  0.261  0.747  1.0
  O  O33  1  0.567  0.739  0.253  1.0
  O  O34  1  0.665  0.245  0.994  1.0
  O  O35  1  0.335  0.755  0.006  1.0
  O  O36  1  0.652  0.574  0.647  1.0
  O  O37  1  0.348  0.426  0.353  1.0
[/CIF]
.
The crystal structure described by Pr(NO4)2NO3(O2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four hydrogen peroxide molecules, two nitric acid molecules, and two Pr(NO4)2 clusters. In each Pr(NO4)2 cluster, Pr(1) is bonded in a 3-coordinate geometry to one N(3), one O(11), one O(13), one O(5), and one O(9) atom. There are two inequivalent N sites. In the first N site, N(2) is bonded in a 3-coordinate geometry to one O(4), one O(5), and one O(6) atom. In the second N site, N(3) is bonded in a distorted rectangular see-saw-like geometry to one Pr(1), one O(7), one O(8), and one O(9) atom. There are eight inequivalent O sites. In the first O site, O(13) is bonded in a distorted L-shaped geometry to one Pr(1) and one O(11) atom. In the second O site, O(4) is bonded in a single-bond geometry to one N(2) atom. In the third O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Pr(1) and one N(2) atom. In the fourth O site, O(6) is bonded in a single-bond geometry to one N(2) atom. In the fifth O site, O(7) is bonded in a distorted single-bond geometry to one N(3) atom. In the sixth O site, O(8) is bonded in a single-bond geometry to one N(3) atom. In the seventh O site, O(9) is bonded in a 2-coordinate geometry to one Pr(1) and one N(3) atom. In the eighth O site, O(11) is bonded in a distorted single-bond geometry to one Pr(1) and one O(13) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Pr(NO5)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.073
_cell_length_b   8.836
_cell_length_c   11.701
_cell_angle_alpha   110.998
_cell_angle_beta   88.492
_cell_angle_gamma   111.296
_symmetry_Int_Tables_number   1
_cell_volume   631.578
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pr  Pr0  1  0.996  0.845  0.288  1.0
  Pr  Pr1  1  0.004  0.155  0.712  1.0
  N  N2  1  0.265  0.178  0.164  1.0
  N  N3  1  0.735  0.822  0.836  1.0
  N  N4  1  0.264  0.818  0.519  1.0
  N  N5  1  0.736  0.182  0.481  1.0
  N  N6  1  0.076  0.420  0.819  1.0
  N  N7  1  0.924  0.580  0.181  1.0
  O  O8  1  0.392  0.312  0.119  1.0
  O  O9  1  0.608  0.688  0.881  1.0
  O  O10  1  0.258  0.030  0.157  1.0
  O  O11  1  0.742  0.970  0.843  1.0
  O  O12  1  0.124  0.165  0.223  1.0
  O  O13  1  0.876  0.835  0.777  1.0
  O  O14  1  0.246  0.734  0.445  1.0
  O  O15  1  0.754  0.266  0.555  1.0
  O  O16  1  0.129  0.897  0.493  1.0
  O  O17  1  0.871  0.103  0.507  1.0
  O  O18  1  0.400  0.821  0.605  1.0
  O  O19  1  0.600  0.179  0.395  1.0
  O  O20  1  0.067  0.454  0.701  1.0
  O  O21  1  0.933  0.546  0.299  1.0
  O  O22  1  0.080  0.526  0.862  1.0
  O  O23  1  0.920  0.474  0.138  1.0
  O  O24  1  0.075  0.263  0.887  1.0
  O  O25  1  0.925  0.737  0.113  1.0
  O  O26  1  0.700  0.108  0.058  1.0
  O  O27  1  0.300  0.892  0.942  1.0
  O  O28  1  0.593  0.866  0.286  1.0
  O  O29  1  0.407  0.134  0.714  1.0
  O  O30  1  0.702  0.620  0.544  1.0
  O  O31  1  0.298  0.380  0.456  1.0
  O  O32  1  0.433  0.261  0.747  1.0
  O  O33  1  0.567  0.739  0.253  1.0
  O  O34  1  0.665  0.245  0.994  1.0
  O  O35  1  0.335  0.755  0.006  1.0
  O  O36  1  0.652  0.574  0.647  1.0
  O  O37  1  0.348  0.426  0.353  1.0
[/CIF]
.