The structure described by CF3FS(O2)OCO is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four trifluoromethane molecules and four FS(O2)OCO clusters. In each FS(O2)OCO cluster, C(2) is bonded in a trigonal planar geometry to one O(2), one O(3), and one F(2) atom. S(1) is bonded in a distorted trigonal non-coplanar geometry to one O(1), one O(2), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one C(2) and one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one S(1) atom. F(2) is bonded in a single-bond geometry to one C(2) atom. is represented by the CIF card [CIF]
data_C2S(OF)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.635
_cell_length_b   9.174
_cell_length_c   11.305
_cell_angle_alpha   74.776
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   664.082
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  C  C0  1  0.381  0.259  0.162  1.0
  C  C1  1  0.273  0.338  0.570  1.0
  C  C2  1  0.619  0.741  0.838  1.0
  C  C3  1  0.227  0.838  0.570  1.0
  C  C4  1  0.119  0.759  0.162  1.0
  C  C5  1  0.727  0.662  0.430  1.0
  C  C6  1  0.881  0.241  0.838  1.0
  C  C7  1  0.773  0.162  0.430  1.0
  S  S8  1  0.384  0.675  0.773  1.0
  S  S9  1  0.616  0.325  0.227  1.0
  S  S10  1  0.116  0.175  0.773  1.0
  S  S11  1  0.884  0.825  0.227  1.0
  O  O12  1  0.065  0.046  0.730  1.0
  O  O13  1  0.623  0.171  0.346  1.0
  O  O14  1  0.094  0.751  0.569  1.0
  O  O15  1  0.935  0.954  0.270  1.0
  O  O16  1  0.377  0.829  0.654  1.0
  O  O17  1  0.565  0.454  0.270  1.0
  O  O18  1  0.719  0.823  0.146  1.0
  O  O19  1  0.219  0.677  0.854  1.0
  O  O20  1  0.906  0.249  0.431  1.0
  O  O21  1  0.123  0.329  0.654  1.0
  O  O22  1  0.281  0.177  0.854  1.0
  O  O23  1  0.406  0.251  0.569  1.0
  O  O24  1  0.877  0.671  0.346  1.0
  O  O25  1  0.435  0.546  0.730  1.0
  O  O26  1  0.594  0.749  0.431  1.0
  O  O27  1  0.781  0.323  0.146  1.0
  F  F28  1  0.162  0.866  0.059  1.0
  F  F29  1  0.255  0.969  0.484  1.0
  F  F30  1  0.745  0.031  0.516  1.0
  F  F31  1  0.755  0.531  0.516  1.0
  F  F32  1  0.085  0.626  0.137  1.0
  F  F33  1  0.838  0.134  0.941  1.0
  F  F34  1  0.245  0.469  0.484  1.0
  F  F35  1  0.338  0.366  0.059  1.0
  F  F36  1  0.229  0.246  0.242  1.0
  F  F37  1  0.585  0.874  0.863  1.0
  F  F38  1  0.771  0.754  0.758  1.0
  F  F39  1  0.915  0.374  0.863  1.0
  F  F40  1  0.662  0.634  0.941  1.0
  F  F41  1  0.271  0.746  0.242  1.0
  F  F42  1  0.729  0.254  0.758  1.0
  F  F43  1  0.415  0.126  0.137  1.0
[/CIF]
.
The structure described by CF3FS(O2)OCO is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four trifluoromethane molecules and four FS(O2)OCO clusters. In each FS(O2)OCO cluster, C(2) is bonded in a trigonal planar geometry to one O(2), one O(3), and one F(2) atom. S(1) is bonded in a distorted trigonal non-coplanar geometry to one O(1), one O(2), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one C(2) and one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one S(1) atom. F(2) is bonded in a single-bond geometry to one C(2) atom. is represented by the CIF card [CIF]
data_C2S(OF)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.635
_cell_length_b   9.174
_cell_length_c   11.305
_cell_angle_alpha   74.776
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   664.082
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  C  C0  1  0.381  0.259  0.162  1.0
  C  C1  1  0.273  0.338  0.570  1.0
  C  C2  1  0.619  0.741  0.838  1.0
  C  C3  1  0.227  0.838  0.570  1.0
  C  C4  1  0.119  0.759  0.162  1.0
  C  C5  1  0.727  0.662  0.430  1.0
  C  C6  1  0.881  0.241  0.838  1.0
  C  C7  1  0.773  0.162  0.430  1.0
  S  S8  1  0.384  0.675  0.773  1.0
  S  S9  1  0.616  0.325  0.227  1.0
  S  S10  1  0.116  0.175  0.773  1.0
  S  S11  1  0.884  0.825  0.227  1.0
  O  O12  1  0.065  0.046  0.730  1.0
  O  O13  1  0.623  0.171  0.346  1.0
  O  O14  1  0.094  0.751  0.569  1.0
  O  O15  1  0.935  0.954  0.270  1.0
  O  O16  1  0.377  0.829  0.654  1.0
  O  O17  1  0.565  0.454  0.270  1.0
  O  O18  1  0.719  0.823  0.146  1.0
  O  O19  1  0.219  0.677  0.854  1.0
  O  O20  1  0.906  0.249  0.431  1.0
  O  O21  1  0.123  0.329  0.654  1.0
  O  O22  1  0.281  0.177  0.854  1.0
  O  O23  1  0.406  0.251  0.569  1.0
  O  O24  1  0.877  0.671  0.346  1.0
  O  O25  1  0.435  0.546  0.730  1.0
  O  O26  1  0.594  0.749  0.431  1.0
  O  O27  1  0.781  0.323  0.146  1.0
  F  F28  1  0.162  0.866  0.059  1.0
  F  F29  1  0.255  0.969  0.484  1.0
  F  F30  1  0.745  0.031  0.516  1.0
  F  F31  1  0.755  0.531  0.516  1.0
  F  F32  1  0.085  0.626  0.137  1.0
  F  F33  1  0.838  0.134  0.941  1.0
  F  F34  1  0.245  0.469  0.484  1.0
  F  F35  1  0.338  0.366  0.059  1.0
  F  F36  1  0.229  0.246  0.242  1.0
  F  F37  1  0.585  0.874  0.863  1.0
  F  F38  1  0.771  0.754  0.758  1.0
  F  F39  1  0.915  0.374  0.863  1.0
  F  F40  1  0.662  0.634  0.941  1.0
  F  F41  1  0.271  0.746  0.242  1.0
  F  F42  1  0.729  0.254  0.758  1.0
  F  F43  1  0.415  0.126  0.137  1.0
[/CIF]
.