The material described by NdWO3N is Zircon-derived structured and crystallizes in the triclinic P1 space group. There are two inequivalent Nd sites. In the first Nd site, Nd(1) is bonded in a 8-coordinate geometry to one N(1), one N(2), one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. In the second Nd site, Nd(2) is bonded in a 8-coordinate geometry to one N(1), one N(2), one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. There are two inequivalent W sites. In the first W site, W(1) is bonded to one N(1), one O(1), one O(5), and one O(6) atom to form distorted corner-sharing WNO3 tetrahedra. In the second W site, W(2) is bonded to one N(1), one N(2), one O(2), one O(3), and one O(4) atom to form distorted corner-sharing WN2O3 trigonal bipyramids. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 4-coordinate geometry to one Nd(1), one Nd(2), one W(1), and one W(2) atom. In the second N site, N(2) is bonded in a 3-coordinate geometry to one Nd(1), one Nd(2), and one W(2) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Nd(1), one Nd(2), and one W(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Nd(1), one Nd(2), and one W(2) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Nd(1), one Nd(2), and one W(2) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Nd(1), one Nd(2), and one W(2) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Nd(1), one Nd(2), and one W(1) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Nd(1), one Nd(2), and one W(1) atom. is represented by the CIF file [CIF]
data_NdWNO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.486
_cell_length_b   5.274
_cell_length_c   7.095
_cell_angle_alpha   63.985
_cell_angle_beta   67.052
_cell_angle_gamma   87.826
_symmetry_Int_Tables_number   1
_cell_volume   167.660
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Nd  Nd0  1  0.365  0.615  0.258  1.0
  Nd  Nd1  1  0.631  0.375  0.747  1.0
  W  W2  1  0.867  0.144  0.239  1.0
  W  W3  1  0.132  0.820  0.786  1.0
  N  N4  1  0.178  0.406  0.057  1.0
  N  N5  1  0.365  0.727  0.576  1.0
  O  O6  1  0.711  0.044  0.083  1.0
  O  O7  1  0.058  0.182  0.603  1.0
  O  O8  1  0.772  0.618  0.922  1.0
  O  O9  1  0.316  0.960  0.911  1.0
  O  O10  1  0.649  0.309  0.413  1.0
  O  O11  1  0.956  0.801  0.404  1.0
[/CIF]
.
The material described by NdWO3N is Zircon-derived structured and crystallizes in the triclinic P1 space group. There are two inequivalent Nd sites. In the first Nd site, Nd(1) is bonded in a 8-coordinate geometry to one N(1), one N(2), one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. In the second Nd site, Nd(2) is bonded in a 8-coordinate geometry to one N(1), one N(2), one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. There are two inequivalent W sites. In the first W site, W(1) is bonded to one N(1), one O(1), one O(5), and one O(6) atom to form distorted corner-sharing WNO3 tetrahedra. In the second W site, W(2) is bonded to one N(1), one N(2), one O(2), one O(3), and one O(4) atom to form distorted corner-sharing WN2O3 trigonal bipyramids. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 4-coordinate geometry to one Nd(1), one Nd(2), one W(1), and one W(2) atom. In the second N site, N(2) is bonded in a 3-coordinate geometry to one Nd(1), one Nd(2), and one W(2) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Nd(1), one Nd(2), and one W(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Nd(1), one Nd(2), and one W(2) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Nd(1), one Nd(2), and one W(2) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Nd(1), one Nd(2), and one W(2) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Nd(1), one Nd(2), and one W(1) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Nd(1), one Nd(2), and one W(1) atom. is represented by the CIF file [CIF]
data_NdWNO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.486
_cell_length_b   5.274
_cell_length_c   7.095
_cell_angle_alpha   63.985
_cell_angle_beta   67.052
_cell_angle_gamma   87.826
_symmetry_Int_Tables_number   1
_cell_volume   167.660
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Nd  Nd0  1  0.365  0.615  0.258  1.0
  Nd  Nd1  1  0.631  0.375  0.747  1.0
  W  W2  1  0.867  0.144  0.239  1.0
  W  W3  1  0.132  0.820  0.786  1.0
  N  N4  1  0.178  0.406  0.057  1.0
  N  N5  1  0.365  0.727  0.576  1.0
  O  O6  1  0.711  0.044  0.083  1.0
  O  O7  1  0.058  0.182  0.603  1.0
  O  O8  1  0.772  0.618  0.922  1.0
  O  O9  1  0.316  0.960  0.911  1.0
  O  O10  1  0.649  0.309  0.413  1.0
  O  O11  1  0.956  0.801  0.404  1.0
[/CIF]
.