The structure described by BF4NH3NH2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight ammonia molecules, eight ammonia molecules, and eight BF4 clusters. In each BF4 cluster, B(1) is bonded in a tetrahedral geometry to one F(1), one F(2), one F(3), and one F(4) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one B(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one B(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one B(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one B(1) atom. is represented by the CIF file [CIF]
data_BH5(NF2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.541
_cell_length_b   7.541
_cell_length_c   12.459
_cell_angle_alpha   68.883
_cell_angle_beta   68.883
_cell_angle_gamma   41.686
_symmetry_Int_Tables_number   1
_cell_volume   434.712
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.964  0.820  0.422  1.0
  B  B1  1  0.180  0.036  0.078  1.0
  B  B2  1  0.036  0.180  0.578  1.0
  B  B3  1  0.820  0.964  0.922  1.0
  H  H4  1  0.221  0.612  0.124  1.0
  H  H5  1  0.388  0.779  0.376  1.0
  H  H6  1  0.779  0.388  0.876  1.0
  H  H7  1  0.612  0.221  0.624  1.0
  H  H8  1  0.289  0.376  0.083  1.0
  H  H9  1  0.624  0.711  0.417  1.0
  H  H10  1  0.711  0.624  0.917  1.0
  H  H11  1  0.376  0.289  0.583  1.0
  H  H12  1  0.051  0.520  0.198  1.0
  H  H13  1  0.480  0.949  0.302  1.0
  H  H14  1  0.949  0.480  0.802  1.0
  H  H15  1  0.520  0.051  0.698  1.0
  H  H16  1  0.618  0.175  0.190  1.0
  H  H17  1  0.825  0.382  0.310  1.0
  H  H18  1  0.382  0.825  0.810  1.0
  H  H19  1  0.175  0.618  0.690  1.0
  H  H20  1  0.376  0.327  0.300  1.0
  H  H21  1  0.673  0.624  0.200  1.0
  H  H22  1  0.624  0.673  0.700  1.0
  H  H23  1  0.327  0.376  0.800  1.0
  N  N24  1  0.238  0.453  0.154  1.0
  N  N25  1  0.547  0.762  0.346  1.0
  N  N26  1  0.762  0.547  0.846  1.0
  N  N27  1  0.453  0.238  0.654  1.0
  N  N28  1  0.436  0.240  0.232  1.0
  N  N29  1  0.760  0.564  0.268  1.0
  N  N30  1  0.564  0.760  0.768  1.0
  N  N31  1  0.240  0.436  0.732  1.0
  F  F32  1  0.929  0.777  0.332  1.0
  F  F33  1  0.223  0.071  0.168  1.0
  F  F34  1  0.071  0.223  0.668  1.0
  F  F35  1  0.777  0.929  0.832  1.0
  F  F36  1  0.834  0.788  0.530  1.0
  F  F37  1  0.212  0.166  0.970  1.0
  F  F38  1  0.166  0.212  0.470  1.0
  F  F39  1  0.788  0.834  0.030  1.0
  F  F40  1  0.247  0.625  0.426  1.0
  F  F41  1  0.375  0.753  0.074  1.0
  F  F42  1  0.753  0.375  0.574  1.0
  F  F43  1  0.625  0.247  0.926  1.0
  F  F44  1  0.855  0.082  0.399  1.0
  F  F45  1  0.918  0.145  0.101  1.0
  F  F46  1  0.145  0.918  0.601  1.0
  F  F47  1  0.082  0.855  0.899  1.0
[/CIF]
.
The structure described by BF4NH3NH2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight ammonia molecules, eight ammonia molecules, and eight BF4 clusters. In each BF4 cluster, B(1) is bonded in a tetrahedral geometry to one F(1), one F(2), one F(3), and one F(4) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one B(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one B(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one B(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one B(1) atom. is represented by the CIF file [CIF]
data_BH5(NF2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.541
_cell_length_b   7.541
_cell_length_c   12.459
_cell_angle_alpha   68.883
_cell_angle_beta   68.883
_cell_angle_gamma   41.686
_symmetry_Int_Tables_number   1
_cell_volume   434.712
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.964  0.820  0.422  1.0
  B  B1  1  0.180  0.036  0.078  1.0
  B  B2  1  0.036  0.180  0.578  1.0
  B  B3  1  0.820  0.964  0.922  1.0
  H  H4  1  0.221  0.612  0.124  1.0
  H  H5  1  0.388  0.779  0.376  1.0
  H  H6  1  0.779  0.388  0.876  1.0
  H  H7  1  0.612  0.221  0.624  1.0
  H  H8  1  0.289  0.376  0.083  1.0
  H  H9  1  0.624  0.711  0.417  1.0
  H  H10  1  0.711  0.624  0.917  1.0
  H  H11  1  0.376  0.289  0.583  1.0
  H  H12  1  0.051  0.520  0.198  1.0
  H  H13  1  0.480  0.949  0.302  1.0
  H  H14  1  0.949  0.480  0.802  1.0
  H  H15  1  0.520  0.051  0.698  1.0
  H  H16  1  0.618  0.175  0.190  1.0
  H  H17  1  0.825  0.382  0.310  1.0
  H  H18  1  0.382  0.825  0.810  1.0
  H  H19  1  0.175  0.618  0.690  1.0
  H  H20  1  0.376  0.327  0.300  1.0
  H  H21  1  0.673  0.624  0.200  1.0
  H  H22  1  0.624  0.673  0.700  1.0
  H  H23  1  0.327  0.376  0.800  1.0
  N  N24  1  0.238  0.453  0.154  1.0
  N  N25  1  0.547  0.762  0.346  1.0
  N  N26  1  0.762  0.547  0.846  1.0
  N  N27  1  0.453  0.238  0.654  1.0
  N  N28  1  0.436  0.240  0.232  1.0
  N  N29  1  0.760  0.564  0.268  1.0
  N  N30  1  0.564  0.760  0.768  1.0
  N  N31  1  0.240  0.436  0.732  1.0
  F  F32  1  0.929  0.777  0.332  1.0
  F  F33  1  0.223  0.071  0.168  1.0
  F  F34  1  0.071  0.223  0.668  1.0
  F  F35  1  0.777  0.929  0.832  1.0
  F  F36  1  0.834  0.788  0.530  1.0
  F  F37  1  0.212  0.166  0.970  1.0
  F  F38  1  0.166  0.212  0.470  1.0
  F  F39  1  0.788  0.834  0.030  1.0
  F  F40  1  0.247  0.625  0.426  1.0
  F  F41  1  0.375  0.753  0.074  1.0
  F  F42  1  0.753  0.375  0.574  1.0
  F  F43  1  0.625  0.247  0.926  1.0
  F  F44  1  0.855  0.082  0.399  1.0
  F  F45  1  0.918  0.145  0.101  1.0
  F  F46  1  0.145  0.918  0.601  1.0
  F  F47  1  0.082  0.855  0.899  1.0
[/CIF]
.