The structure described by Li2(OH)Cl crystallizes in the orthorhombic Pnma space group. Li(1) is bonded in a 4-coordinate geometry to two equivalent O(1) and two equivalent Cl(1) atoms. H(1) is bonded in a single-bond geometry to one O(1) atom. O(1) is bonded in a distorted single-bond geometry to four equivalent Li(1) and one H(1) atom. Cl(1) is bonded in a 4-coordinate geometry to four equivalent Li(1) atoms. is represented by the CIF card [CIF]
data_Li2HClO
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.558
_cell_length_b   5.844
_cell_length_c   9.531
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   309.557
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.000  0.570  0.877  1.0
  Li  Li1  1  0.500  0.930  0.377  1.0
  Li  Li2  1  0.500  0.430  0.123  1.0
  Li  Li3  1  1.000  0.070  0.623  1.0
  Li  Li4  1  1.000  0.430  0.123  1.0
  Li  Li5  1  0.500  0.070  0.623  1.0
  Li  Li6  1  0.500  0.570  0.877  1.0
  Li  Li7  1  0.000  0.930  0.377  1.0
  H  H8  1  0.250  0.744  0.554  1.0
  H  H9  1  0.250  0.756  0.054  1.0
  H  H10  1  0.750  0.256  0.446  1.0
  H  H11  1  0.750  0.244  0.946  1.0
  Cl  Cl12  1  0.250  0.402  0.692  1.0
  Cl  Cl13  1  0.250  0.098  0.192  1.0
  Cl  Cl14  1  0.750  0.598  0.308  1.0
  Cl  Cl15  1  0.750  0.902  0.808  1.0
  O  O16  1  0.250  0.903  0.521  1.0
  O  O17  1  0.250  0.597  0.021  1.0
  O  O18  1  0.750  0.097  0.479  1.0
  O  O19  1  0.750  0.403  0.979  1.0
[/CIF]
.
The structure described by Li2(OH)Cl crystallizes in the orthorhombic Pnma space group. Li(1) is bonded in a 4-coordinate geometry to two equivalent O(1) and two equivalent Cl(1) atoms. H(1) is bonded in a single-bond geometry to one O(1) atom. O(1) is bonded in a distorted single-bond geometry to four equivalent Li(1) and one H(1) atom. Cl(1) is bonded in a 4-coordinate geometry to four equivalent Li(1) atoms. is represented by the CIF card [CIF]
data_Li2HClO
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.558
_cell_length_b   5.844
_cell_length_c   9.531
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   309.557
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.000  0.570  0.877  1.0
  Li  Li1  1  0.500  0.930  0.377  1.0
  Li  Li2  1  0.500  0.430  0.123  1.0
  Li  Li3  1  1.000  0.070  0.623  1.0
  Li  Li4  1  1.000  0.430  0.123  1.0
  Li  Li5  1  0.500  0.070  0.623  1.0
  Li  Li6  1  0.500  0.570  0.877  1.0
  Li  Li7  1  0.000  0.930  0.377  1.0
  H  H8  1  0.250  0.744  0.554  1.0
  H  H9  1  0.250  0.756  0.054  1.0
  H  H10  1  0.750  0.256  0.446  1.0
  H  H11  1  0.750  0.244  0.946  1.0
  Cl  Cl12  1  0.250  0.402  0.692  1.0
  Cl  Cl13  1  0.250  0.098  0.192  1.0
  Cl  Cl14  1  0.750  0.598  0.308  1.0
  Cl  Cl15  1  0.750  0.902  0.808  1.0
  O  O16  1  0.250  0.903  0.521  1.0
  O  O17  1  0.250  0.597  0.021  1.0
  O  O18  1  0.750  0.097  0.479  1.0
  O  O19  1  0.750  0.403  0.979  1.0
[/CIF]
.