The compound described by K3RhC4H8(O6Cl)2 crystallizes in the monoclinic C2/m space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(2) atoms. In the second K site, K(2) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent Cl(1) atoms. Rh(1) is bonded in an octahedral geometry to four equivalent O(3) and two equivalent Cl(1) atoms. C(1) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(3) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one K(1), one K(2), one H(1), and one H(2) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one K(1), one K(2), and one C(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one K(2), one Rh(1), and one C(1) atom. Cl(1) is bonded in a distorted single-bond geometry to two equivalent K(2) and one Rh(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_K3H8RhC4(ClO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.348
_cell_length_b   8.348
_cell_length_c   6.448
_cell_angle_alpha   71.673
_cell_angle_beta   71.673
_cell_angle_gamma   91.803
_symmetry_Int_Tables_number   1
_cell_volume   400.670
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.500  0.500  0.000  1.0
  K  K1  1  0.769  0.231  0.500  1.0
  K  K2  1  0.231  0.769  0.500  1.0
  H  H3  1  0.873  0.546  0.978  1.0
  H  H4  1  0.546  0.873  0.978  1.0
  H  H5  1  0.377  0.870  0.923  1.0
  H  H6  1  0.870  0.377  0.923  1.0
  H  H7  1  0.623  0.130  0.077  1.0
  H  H8  1  0.130  0.623  0.077  1.0
  H  H9  1  0.454  0.127  0.022  1.0
  H  H10  1  0.127  0.454  0.022  1.0
  Rh  Rh11  1  0.000  0.000  0.000  1.0
  C  C12  1  0.703  0.832  0.392  1.0
  C  C13  1  0.832  0.703  0.392  1.0
  C  C14  1  0.297  0.168  0.608  1.0
  C  C15  1  0.168  0.297  0.608  1.0
  Cl  Cl16  1  0.861  0.861  0.821  1.0
  Cl  Cl17  1  0.139  0.139  0.179  1.0
  O  O18  1  0.573  0.182  0.956  1.0
  O  O19  1  0.182  0.573  0.956  1.0
  O  O20  1  0.787  0.555  0.532  1.0
  O  O21  1  0.555  0.787  0.532  1.0
  O  O22  1  0.763  0.985  0.240  1.0
  O  O23  1  0.985  0.763  0.240  1.0
  O  O24  1  0.237  0.015  0.760  1.0
  O  O25  1  0.015  0.237  0.760  1.0
  O  O26  1  0.445  0.213  0.468  1.0
  O  O27  1  0.213  0.445  0.468  1.0
  O  O28  1  0.818  0.427  0.044  1.0
  O  O29  1  0.427  0.818  0.044  1.0
[/CIF]
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The compound described by K3RhC4H8(O6Cl)2 crystallizes in the monoclinic C2/m space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(2) atoms. In the second K site, K(2) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent Cl(1) atoms. Rh(1) is bonded in an octahedral geometry to four equivalent O(3) and two equivalent Cl(1) atoms. C(1) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(3) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one K(1), one K(2), one H(1), and one H(2) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one K(1), one K(2), and one C(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one K(2), one Rh(1), and one C(1) atom. Cl(1) is bonded in a distorted single-bond geometry to two equivalent K(2) and one Rh(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_K3H8RhC4(ClO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.348
_cell_length_b   8.348
_cell_length_c   6.448
_cell_angle_alpha   71.673
_cell_angle_beta   71.673
_cell_angle_gamma   91.803
_symmetry_Int_Tables_number   1
_cell_volume   400.670
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.500  0.500  0.000  1.0
  K  K1  1  0.769  0.231  0.500  1.0
  K  K2  1  0.231  0.769  0.500  1.0
  H  H3  1  0.873  0.546  0.978  1.0
  H  H4  1  0.546  0.873  0.978  1.0
  H  H5  1  0.377  0.870  0.923  1.0
  H  H6  1  0.870  0.377  0.923  1.0
  H  H7  1  0.623  0.130  0.077  1.0
  H  H8  1  0.130  0.623  0.077  1.0
  H  H9  1  0.454  0.127  0.022  1.0
  H  H10  1  0.127  0.454  0.022  1.0
  Rh  Rh11  1  0.000  0.000  0.000  1.0
  C  C12  1  0.703  0.832  0.392  1.0
  C  C13  1  0.832  0.703  0.392  1.0
  C  C14  1  0.297  0.168  0.608  1.0
  C  C15  1  0.168  0.297  0.608  1.0
  Cl  Cl16  1  0.861  0.861  0.821  1.0
  Cl  Cl17  1  0.139  0.139  0.179  1.0
  O  O18  1  0.573  0.182  0.956  1.0
  O  O19  1  0.182  0.573  0.956  1.0
  O  O20  1  0.787  0.555  0.532  1.0
  O  O21  1  0.555  0.787  0.532  1.0
  O  O22  1  0.763  0.985  0.240  1.0
  O  O23  1  0.985  0.763  0.240  1.0
  O  O24  1  0.237  0.015  0.760  1.0
  O  O25  1  0.015  0.237  0.760  1.0
  O  O26  1  0.445  0.213  0.468  1.0
  O  O27  1  0.213  0.445  0.468  1.0
  O  O28  1  0.818  0.427  0.044  1.0
  O  O29  1  0.427  0.818  0.044  1.0
[/CIF]
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