The compound described by (VH12(O3Cl)2)2Cl2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two hydrochloric acid atoms and two VH12(O3Cl)2 clusters. In each VH12(O3Cl)2 cluster, V(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(3), and two equivalent Cl(1) atoms. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(3) atom. In the second H site, H(2) is bonded in a distorted single-bond geometry to one O(3) atom. In the third H site, H(3) is bonded in a distorted linear geometry to one O(1) and one O(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(1) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(2) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(2) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one V(1), one H(3), and one H(4) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one H(3), one H(5), and one H(6) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one V(1), one H(1), and one H(2) atom. Cl(1) is bonded in a single-bond geometry to one V(1) atom. is represented by the CIF file [CIF]
data_VH12(ClO2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.425
_cell_length_b   6.550
_cell_length_c   11.998
_cell_angle_alpha   81.207
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   499.000
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.000  0.000  0.000  1.0
  V  V1  1  0.500  0.000  0.500  1.0
  H  H2  1  0.345  0.215  0.047  1.0
  H  H3  1  0.845  0.785  0.453  1.0
  H  H4  1  0.655  0.785  0.953  1.0
  H  H5  1  0.155  0.215  0.547  1.0
  H  H6  1  0.366  0.981  0.119  1.0
  H  H7  1  0.866  0.019  0.381  1.0
  H  H8  1  0.634  0.019  0.881  1.0
  H  H9  1  0.134  0.981  0.619  1.0
  H  H10  1  0.904  0.210  0.169  1.0
  H  H11  1  0.404  0.790  0.331  1.0
  H  H12  1  0.096  0.790  0.831  1.0
  H  H13  1  0.596  0.210  0.669  1.0
  H  H14  1  0.763  0.312  0.061  1.0
  H  H15  1  0.263  0.688  0.439  1.0
  H  H16  1  0.237  0.688  0.939  1.0
  H  H17  1  0.737  0.312  0.561  1.0
  H  H18  1  0.950  0.337  0.328  1.0
  H  H19  1  0.450  0.663  0.172  1.0
  H  H20  1  0.050  0.663  0.672  1.0
  H  H21  1  0.550  0.337  0.828  1.0
  H  H22  1  0.146  0.211  0.305  1.0
  H  H23  1  0.646  0.789  0.195  1.0
  H  H24  1  0.854  0.789  0.695  1.0
  H  H25  1  0.354  0.211  0.805  1.0
  Cl  Cl26  1  0.966  0.728  0.158  1.0
  Cl  Cl27  1  0.000  0.500  0.500  1.0
  Cl  Cl28  1  0.500  0.500  0.000  1.0
  Cl  Cl29  1  0.534  0.728  0.658  1.0
  Cl  Cl30  1  0.034  0.272  0.842  1.0
  Cl  Cl31  1  0.466  0.272  0.342  1.0
  O  O32  1  0.852  0.193  0.092  1.0
  O  O33  1  0.509  0.211  0.798  1.0
  O  O34  1  0.009  0.789  0.702  1.0
  O  O35  1  0.491  0.789  0.202  1.0
  O  O36  1  0.991  0.211  0.298  1.0
  O  O37  1  0.648  0.193  0.592  1.0
  O  O38  1  0.277  0.078  0.066  1.0
  O  O39  1  0.777  0.922  0.434  1.0
  O  O40  1  0.723  0.922  0.934  1.0
  O  O41  1  0.223  0.078  0.566  1.0
  O  O42  1  0.352  0.807  0.408  1.0
  O  O43  1  0.148  0.807  0.908  1.0
[/CIF]
.
The compound described by (VH12(O3Cl)2)2Cl2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two hydrochloric acid atoms and two VH12(O3Cl)2 clusters. In each VH12(O3Cl)2 cluster, V(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(3), and two equivalent Cl(1) atoms. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(3) atom. In the second H site, H(2) is bonded in a distorted single-bond geometry to one O(3) atom. In the third H site, H(3) is bonded in a distorted linear geometry to one O(1) and one O(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(1) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(2) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(2) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one V(1), one H(3), and one H(4) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one H(3), one H(5), and one H(6) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one V(1), one H(1), and one H(2) atom. Cl(1) is bonded in a single-bond geometry to one V(1) atom. is represented by the CIF file [CIF]
data_VH12(ClO2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.425
_cell_length_b   6.550
_cell_length_c   11.998
_cell_angle_alpha   81.207
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   499.000
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.000  0.000  0.000  1.0
  V  V1  1  0.500  0.000  0.500  1.0
  H  H2  1  0.345  0.215  0.047  1.0
  H  H3  1  0.845  0.785  0.453  1.0
  H  H4  1  0.655  0.785  0.953  1.0
  H  H5  1  0.155  0.215  0.547  1.0
  H  H6  1  0.366  0.981  0.119  1.0
  H  H7  1  0.866  0.019  0.381  1.0
  H  H8  1  0.634  0.019  0.881  1.0
  H  H9  1  0.134  0.981  0.619  1.0
  H  H10  1  0.904  0.210  0.169  1.0
  H  H11  1  0.404  0.790  0.331  1.0
  H  H12  1  0.096  0.790  0.831  1.0
  H  H13  1  0.596  0.210  0.669  1.0
  H  H14  1  0.763  0.312  0.061  1.0
  H  H15  1  0.263  0.688  0.439  1.0
  H  H16  1  0.237  0.688  0.939  1.0
  H  H17  1  0.737  0.312  0.561  1.0
  H  H18  1  0.950  0.337  0.328  1.0
  H  H19  1  0.450  0.663  0.172  1.0
  H  H20  1  0.050  0.663  0.672  1.0
  H  H21  1  0.550  0.337  0.828  1.0
  H  H22  1  0.146  0.211  0.305  1.0
  H  H23  1  0.646  0.789  0.195  1.0
  H  H24  1  0.854  0.789  0.695  1.0
  H  H25  1  0.354  0.211  0.805  1.0
  Cl  Cl26  1  0.966  0.728  0.158  1.0
  Cl  Cl27  1  0.000  0.500  0.500  1.0
  Cl  Cl28  1  0.500  0.500  0.000  1.0
  Cl  Cl29  1  0.534  0.728  0.658  1.0
  Cl  Cl30  1  0.034  0.272  0.842  1.0
  Cl  Cl31  1  0.466  0.272  0.342  1.0
  O  O32  1  0.852  0.193  0.092  1.0
  O  O33  1  0.509  0.211  0.798  1.0
  O  O34  1  0.009  0.789  0.702  1.0
  O  O35  1  0.491  0.789  0.202  1.0
  O  O36  1  0.991  0.211  0.298  1.0
  O  O37  1  0.648  0.193  0.592  1.0
  O  O38  1  0.277  0.078  0.066  1.0
  O  O39  1  0.777  0.922  0.434  1.0
  O  O40  1  0.723  0.922  0.934  1.0
  O  O41  1  0.223  0.078  0.566  1.0
  O  O42  1  0.352  0.807  0.408  1.0
  O  O43  1  0.148  0.807  0.908  1.0
[/CIF]
.