The structure described by Co2C5SO5 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two Co2C5SO5 clusters. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded to one C(1), one C(2), one C(5), and two equivalent S(1) atoms to form a mixture of distorted face and edge-sharing CoC3S2 square pyramids. In the second Co site, Co(2) is bonded to one C(2), one C(3), one C(4), and two equivalent S(1) atoms to form a mixture of distorted face and edge-sharing CoC3S2 square pyramids. There are five inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Co(1) and one O(3) atom. In the second C site, C(2) is bonded in a 3-coordinate geometry to one Co(1), one Co(2), and one O(4) atom. In the third C site, C(3) is bonded in a linear geometry to one Co(2) and one O(2) atom. In the fourth C site, C(4) is bonded in a linear geometry to one Co(2) and one O(1) atom. In the fifth C site, C(5) is bonded in a linear geometry to one Co(1) and one O(5) atom. S(1) is bonded in a 4-coordinate geometry to two equivalent Co(1) and two equivalent Co(2) atoms. There are five inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(4) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(3) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(2) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one C(5) atom. is represented by the CIF file [CIF]
data_Co2C5SO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.706
_cell_length_b   9.923
_cell_length_c   14.868
_cell_angle_alpha   55.275
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   813.160
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.072  0.854  0.970  1.0
  Co  Co1  1  0.428  0.854  0.470  1.0
  Co  Co2  1  0.543  0.843  0.643  1.0
  Co  Co3  1  0.928  0.146  0.030  1.0
  Co  Co4  1  0.572  0.146  0.530  1.0
  Co  Co5  1  0.457  0.157  0.357  1.0
  Co  Co6  1  0.043  0.157  0.857  1.0
  Co  Co7  1  0.957  0.843  0.143  1.0
  C  C8  1  0.204  0.739  0.508  1.0
  C  C9  1  0.296  0.739  0.008  1.0
  C  C10  1  0.379  0.012  0.319  1.0
  C  C11  1  0.366  0.730  0.749  1.0
  C  C12  1  0.796  0.261  0.492  1.0
  C  C13  1  0.742  0.700  0.701  1.0
  C  C14  1  0.258  0.300  0.299  1.0
  C  C15  1  0.419  0.278  0.545  1.0
  C  C16  1  0.081  0.278  0.045  1.0
  C  C17  1  0.121  0.012  0.819  1.0
  C  C18  1  0.134  0.730  0.249  1.0
  C  C19  1  0.919  0.722  0.955  1.0
  C  C20  1  0.866  0.270  0.751  1.0
  C  C21  1  0.879  0.988  0.181  1.0
  C  C22  1  0.704  0.261  0.992  1.0
  C  C23  1  0.634  0.270  0.251  1.0
  C  C24  1  0.242  0.300  0.799  1.0
  C  C25  1  0.758  0.700  0.201  1.0
  C  C26  1  0.621  0.988  0.681  1.0
  C  C27  1  0.581  0.722  0.455  1.0
  S  S28  1  0.194  0.012  0.023  1.0
  S  S29  1  0.806  0.988  0.977  1.0
  S  S30  1  0.306  0.012  0.523  1.0
  S  S31  1  0.694  0.988  0.477  1.0
  O  O32  1  0.865  0.601  0.742  1.0
  O  O33  1  0.635  0.601  0.242  1.0
  O  O34  1  0.744  0.349  0.180  1.0
  O  O35  1  0.244  0.651  0.320  1.0
  O  O36  1  0.937  0.343  0.464  1.0
  O  O37  1  0.669  0.983  0.759  1.0
  O  O38  1  0.331  0.017  0.241  1.0
  O  O39  1  0.671  0.633  0.444  1.0
  O  O40  1  0.169  0.017  0.741  1.0
  O  O41  1  0.365  0.399  0.758  1.0
  O  O42  1  0.437  0.657  0.036  1.0
  O  O43  1  0.831  0.983  0.259  1.0
  O  O44  1  0.563  0.343  0.964  1.0
  O  O45  1  0.171  0.367  0.056  1.0
  O  O46  1  0.063  0.657  0.536  1.0
  O  O47  1  0.135  0.399  0.258  1.0
  O  O48  1  0.256  0.651  0.820  1.0
  O  O49  1  0.829  0.633  0.944  1.0
  O  O50  1  0.329  0.367  0.556  1.0
  O  O51  1  0.756  0.349  0.680  1.0
[/CIF]
.
The structure described by Co2C5SO5 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two Co2C5SO5 clusters. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded to one C(1), one C(2), one C(5), and two equivalent S(1) atoms to form a mixture of distorted face and edge-sharing CoC3S2 square pyramids. In the second Co site, Co(2) is bonded to one C(2), one C(3), one C(4), and two equivalent S(1) atoms to form a mixture of distorted face and edge-sharing CoC3S2 square pyramids. There are five inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Co(1) and one O(3) atom. In the second C site, C(2) is bonded in a 3-coordinate geometry to one Co(1), one Co(2), and one O(4) atom. In the third C site, C(3) is bonded in a linear geometry to one Co(2) and one O(2) atom. In the fourth C site, C(4) is bonded in a linear geometry to one Co(2) and one O(1) atom. In the fifth C site, C(5) is bonded in a linear geometry to one Co(1) and one O(5) atom. S(1) is bonded in a 4-coordinate geometry to two equivalent Co(1) and two equivalent Co(2) atoms. There are five inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(4) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(3) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(2) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one C(5) atom. is represented by the CIF file [CIF]
data_Co2C5SO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.706
_cell_length_b   9.923
_cell_length_c   14.868
_cell_angle_alpha   55.275
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   813.160
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.072  0.854  0.970  1.0
  Co  Co1  1  0.428  0.854  0.470  1.0
  Co  Co2  1  0.543  0.843  0.643  1.0
  Co  Co3  1  0.928  0.146  0.030  1.0
  Co  Co4  1  0.572  0.146  0.530  1.0
  Co  Co5  1  0.457  0.157  0.357  1.0
  Co  Co6  1  0.043  0.157  0.857  1.0
  Co  Co7  1  0.957  0.843  0.143  1.0
  C  C8  1  0.204  0.739  0.508  1.0
  C  C9  1  0.296  0.739  0.008  1.0
  C  C10  1  0.379  0.012  0.319  1.0
  C  C11  1  0.366  0.730  0.749  1.0
  C  C12  1  0.796  0.261  0.492  1.0
  C  C13  1  0.742  0.700  0.701  1.0
  C  C14  1  0.258  0.300  0.299  1.0
  C  C15  1  0.419  0.278  0.545  1.0
  C  C16  1  0.081  0.278  0.045  1.0
  C  C17  1  0.121  0.012  0.819  1.0
  C  C18  1  0.134  0.730  0.249  1.0
  C  C19  1  0.919  0.722  0.955  1.0
  C  C20  1  0.866  0.270  0.751  1.0
  C  C21  1  0.879  0.988  0.181  1.0
  C  C22  1  0.704  0.261  0.992  1.0
  C  C23  1  0.634  0.270  0.251  1.0
  C  C24  1  0.242  0.300  0.799  1.0
  C  C25  1  0.758  0.700  0.201  1.0
  C  C26  1  0.621  0.988  0.681  1.0
  C  C27  1  0.581  0.722  0.455  1.0
  S  S28  1  0.194  0.012  0.023  1.0
  S  S29  1  0.806  0.988  0.977  1.0
  S  S30  1  0.306  0.012  0.523  1.0
  S  S31  1  0.694  0.988  0.477  1.0
  O  O32  1  0.865  0.601  0.742  1.0
  O  O33  1  0.635  0.601  0.242  1.0
  O  O34  1  0.744  0.349  0.180  1.0
  O  O35  1  0.244  0.651  0.320  1.0
  O  O36  1  0.937  0.343  0.464  1.0
  O  O37  1  0.669  0.983  0.759  1.0
  O  O38  1  0.331  0.017  0.241  1.0
  O  O39  1  0.671  0.633  0.444  1.0
  O  O40  1  0.169  0.017  0.741  1.0
  O  O41  1  0.365  0.399  0.758  1.0
  O  O42  1  0.437  0.657  0.036  1.0
  O  O43  1  0.831  0.983  0.259  1.0
  O  O44  1  0.563  0.343  0.964  1.0
  O  O45  1  0.171  0.367  0.056  1.0
  O  O46  1  0.063  0.657  0.536  1.0
  O  O47  1  0.135  0.399  0.258  1.0
  O  O48  1  0.256  0.651  0.820  1.0
  O  O49  1  0.829  0.633  0.944  1.0
  O  O50  1  0.329  0.367  0.556  1.0
  O  O51  1  0.756  0.349  0.680  1.0
[/CIF]
.