The material described by KHoS2 is Caswellsilverite structured and crystallizes in the trigonal R-3m space group. K(1) is bonded to six equivalent S(1) atoms to form distorted KS6 octahedra that share corners with six equivalent Ho(1)S6 octahedra, edges with six equivalent K(1)S6 octahedra, and edges with six equivalent Ho(1)S6 octahedra. The corner-sharing octahedral tilt angles are 11°. Ho(1) is bonded to six equivalent S(1) atoms to form HoS6 octahedra that share corners with six equivalent K(1)S6 octahedra, edges with six equivalent K(1)S6 octahedra, and edges with six equivalent Ho(1)S6 octahedra. The corner-sharing octahedral tilt angles are 11°. S(1) is bonded to three equivalent K(1) and three equivalent Ho(1) atoms to form a mixture of edge and corner-sharing SK3Ho3 octahedra. The corner-sharing octahedra are not tilted. is represented by the CIF card [CIF]
data_KHoS2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.664
_cell_length_b   7.664
_cell_length_c   7.664
_cell_angle_alpha   30.393
_cell_angle_beta   30.393
_cell_angle_gamma   30.393
_symmetry_Int_Tables_number   1
_cell_volume   102.137
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.500  0.500  0.500  1.0
  Ho  Ho1  1  0.000  0.000  0.000  1.0
  S  S2  1  0.734  0.734  0.734  1.0
  S  S3  1  0.266  0.266  0.266  1.0
[/CIF]
.
The material described by KHoS2 is Caswellsilverite structured and crystallizes in the trigonal R-3m space group. K(1) is bonded to six equivalent S(1) atoms to form distorted KS6 octahedra that share corners with six equivalent Ho(1)S6 octahedra, edges with six equivalent K(1)S6 octahedra, and edges with six equivalent Ho(1)S6 octahedra. The corner-sharing octahedral tilt angles are 11°. Ho(1) is bonded to six equivalent S(1) atoms to form HoS6 octahedra that share corners with six equivalent K(1)S6 octahedra, edges with six equivalent K(1)S6 octahedra, and edges with six equivalent Ho(1)S6 octahedra. The corner-sharing octahedral tilt angles are 11°. S(1) is bonded to three equivalent K(1) and three equivalent Ho(1) atoms to form a mixture of edge and corner-sharing SK3Ho3 octahedra. The corner-sharing octahedra are not tilted. is represented by the CIF card [CIF]
data_KHoS2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.664
_cell_length_b   7.664
_cell_length_c   7.664
_cell_angle_alpha   30.393
_cell_angle_beta   30.393
_cell_angle_gamma   30.393
_symmetry_Int_Tables_number   1
_cell_volume   102.137
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.500  0.500  0.500  1.0
  Ho  Ho1  1  0.000  0.000  0.000  1.0
  S  S2  1  0.734  0.734  0.734  1.0
  S  S3  1  0.266  0.266  0.266  1.0
[/CIF]
.