The structure described by Tl2SO3 is alpha structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two Tl2SO3 clusters. There are two inequivalent Tl sites. In the first Tl site, Tl(1) is bonded in a 3-coordinate geometry to one O(1), one O(2), and one O(3) atom. In the second Tl site, Tl(2) is bonded in a 2-coordinate geometry to one O(1) and one O(2) atom. S(1) is bonded in a trigonal non-coplanar geometry to one O(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Tl(1), one Tl(2), and one S(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Tl(1), one Tl(2), and one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Tl(1) and one S(1) atom. is represented by the CIF file [CIF]
data_Tl2SO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.045
_cell_length_b   8.251
_cell_length_c   10.149
_cell_angle_alpha   90.000
_cell_angle_beta   85.668
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   504.709
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.243  0.029  0.702  1.0
  Tl  Tl1  1  0.256  0.184  0.072  1.0
  Tl  Tl2  1  0.257  0.529  0.798  1.0
  Tl  Tl3  1  0.244  0.684  0.428  1.0
  Tl  Tl4  1  0.756  0.316  0.572  1.0
  Tl  Tl5  1  0.743  0.471  0.202  1.0
  Tl  Tl6  1  0.744  0.816  0.928  1.0
  Tl  Tl7  1  0.757  0.971  0.298  1.0
  S  S8  1  0.242  0.708  0.101  1.0
  S  S9  1  0.258  0.208  0.399  1.0
  S  S10  1  0.758  0.292  0.899  1.0
  S  S11  1  0.742  0.792  0.601  1.0
  O  O12  1  0.031  0.240  0.343  1.0
  O  O13  1  0.238  0.526  0.068  1.0
  O  O14  1  0.250  0.797  0.967  1.0
  O  O15  1  0.262  0.026  0.432  1.0
  O  O16  1  0.250  0.297  0.533  1.0
  O  O17  1  0.469  0.740  0.157  1.0
  O  O18  1  0.531  0.260  0.843  1.0
  O  O19  1  0.750  0.203  0.033  1.0
  O  O20  1  0.762  0.474  0.932  1.0
  O  O21  1  0.750  0.703  0.467  1.0
  O  O22  1  0.738  0.974  0.568  1.0
  O  O23  1  0.969  0.760  0.657  1.0
[/CIF]
.
The structure described by Tl2SO3 is alpha structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two Tl2SO3 clusters. There are two inequivalent Tl sites. In the first Tl site, Tl(1) is bonded in a 3-coordinate geometry to one O(1), one O(2), and one O(3) atom. In the second Tl site, Tl(2) is bonded in a 2-coordinate geometry to one O(1) and one O(2) atom. S(1) is bonded in a trigonal non-coplanar geometry to one O(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Tl(1), one Tl(2), and one S(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Tl(1), one Tl(2), and one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Tl(1) and one S(1) atom. is represented by the CIF file [CIF]
data_Tl2SO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.045
_cell_length_b   8.251
_cell_length_c   10.149
_cell_angle_alpha   90.000
_cell_angle_beta   85.668
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   504.709
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.243  0.029  0.702  1.0
  Tl  Tl1  1  0.256  0.184  0.072  1.0
  Tl  Tl2  1  0.257  0.529  0.798  1.0
  Tl  Tl3  1  0.244  0.684  0.428  1.0
  Tl  Tl4  1  0.756  0.316  0.572  1.0
  Tl  Tl5  1  0.743  0.471  0.202  1.0
  Tl  Tl6  1  0.744  0.816  0.928  1.0
  Tl  Tl7  1  0.757  0.971  0.298  1.0
  S  S8  1  0.242  0.708  0.101  1.0
  S  S9  1  0.258  0.208  0.399  1.0
  S  S10  1  0.758  0.292  0.899  1.0
  S  S11  1  0.742  0.792  0.601  1.0
  O  O12  1  0.031  0.240  0.343  1.0
  O  O13  1  0.238  0.526  0.068  1.0
  O  O14  1  0.250  0.797  0.967  1.0
  O  O15  1  0.262  0.026  0.432  1.0
  O  O16  1  0.250  0.297  0.533  1.0
  O  O17  1  0.469  0.740  0.157  1.0
  O  O18  1  0.531  0.260  0.843  1.0
  O  O19  1  0.750  0.203  0.033  1.0
  O  O20  1  0.762  0.474  0.932  1.0
  O  O21  1  0.750  0.703  0.467  1.0
  O  O22  1  0.738  0.974  0.568  1.0
  O  O23  1  0.969  0.760  0.657  1.0
[/CIF]
.