The material structure described by SbP(OCl3)2 is beta Polonium structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two SbP(OCl3)2 clusters. Sb(1) is bonded to one O(1), one O(2), one Cl(1), one Cl(2), one Cl(4), and one Cl(5) atom to form SbCl4O2 octahedra that share corners with two equivalent P(1)Cl2O2 tetrahedra. P(1) is bonded to one O(1), one O(2), one Cl(3), and one Cl(6) atom to form PCl2O2 tetrahedra that share corners with two equivalent Sb(1)Cl4O2 octahedra. The corner-sharing octahedral tilt angles range from 37-39°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Sb(1) and one P(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Sb(1) and one P(1) atom. There are six inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Sb(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one P(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth Cl site, Cl(5) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth Cl site, Cl(6) is bonded in a single-bond geometry to one P(1) atom. is represented by the CIF file [CIF]
data_SbP(Cl3O)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.055
_cell_length_b   8.916
_cell_length_c   11.377
_cell_angle_alpha   71.213
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1157.662
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.539  0.191  0.270  1.0
  Sb  Sb1  1  0.961  0.191  0.770  1.0
  Sb  Sb2  1  0.039  0.809  0.230  1.0
  Sb  Sb3  1  0.461  0.809  0.730  1.0
  P  P4  1  0.594  0.810  0.458  1.0
  P  P5  1  0.094  0.190  0.042  1.0
  P  P6  1  0.406  0.190  0.542  1.0
  P  P7  1  0.906  0.810  0.958  1.0
  Cl  Cl8  1  0.706  0.312  0.295  1.0
  Cl  Cl9  1  0.626  0.958  0.715  1.0
  Cl  Cl10  1  0.737  0.718  0.535  1.0
  Cl  Cl11  1  0.294  0.688  0.705  1.0
  Cl  Cl12  1  0.598  0.140  0.090  1.0
  Cl  Cl13  1  0.550  0.565  0.830  1.0
  Cl  Cl14  1  0.950  0.565  0.330  1.0
  Cl  Cl15  1  0.050  0.435  0.670  1.0
  Cl  Cl16  1  0.237  0.282  0.965  1.0
  Cl  Cl17  1  0.263  0.282  0.465  1.0
  Cl  Cl18  1  0.874  0.958  0.215  1.0
  Cl  Cl19  1  0.448  0.315  0.652  1.0
  Cl  Cl20  1  0.374  0.042  0.285  1.0
  Cl  Cl21  1  0.052  0.315  0.152  1.0
  Cl  Cl22  1  0.126  0.042  0.785  1.0
  Cl  Cl23  1  0.902  0.140  0.590  1.0
  Cl  Cl24  1  0.763  0.718  0.035  1.0
  Cl  Cl25  1  0.948  0.685  0.848  1.0
  Cl  Cl26  1  0.552  0.685  0.348  1.0
  Cl  Cl27  1  0.402  0.860  0.910  1.0
  Cl  Cl28  1  0.794  0.312  0.795  1.0
  Cl  Cl29  1  0.206  0.688  0.205  1.0
  Cl  Cl30  1  0.450  0.435  0.170  1.0
  Cl  Cl31  1  0.098  0.860  0.410  1.0
  O  O32  1  0.498  0.217  0.445  1.0
  O  O33  1  0.619  0.981  0.382  1.0
  O  O34  1  0.998  0.783  0.055  1.0
  O  O35  1  0.502  0.783  0.555  1.0
  O  O36  1  0.881  0.981  0.882  1.0
  O  O37  1  0.119  0.019  0.118  1.0
  O  O38  1  0.002  0.217  0.945  1.0
  O  O39  1  0.381  0.019  0.618  1.0
[/CIF]
.
The material structure described by SbP(OCl3)2 is beta Polonium structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two SbP(OCl3)2 clusters. Sb(1) is bonded to one O(1), one O(2), one Cl(1), one Cl(2), one Cl(4), and one Cl(5) atom to form SbCl4O2 octahedra that share corners with two equivalent P(1)Cl2O2 tetrahedra. P(1) is bonded to one O(1), one O(2), one Cl(3), and one Cl(6) atom to form PCl2O2 tetrahedra that share corners with two equivalent Sb(1)Cl4O2 octahedra. The corner-sharing octahedral tilt angles range from 37-39°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Sb(1) and one P(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Sb(1) and one P(1) atom. There are six inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Sb(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one P(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth Cl site, Cl(5) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth Cl site, Cl(6) is bonded in a single-bond geometry to one P(1) atom. is represented by the CIF file [CIF]
data_SbP(Cl3O)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.055
_cell_length_b   8.916
_cell_length_c   11.377
_cell_angle_alpha   71.213
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1157.662
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.539  0.191  0.270  1.0
  Sb  Sb1  1  0.961  0.191  0.770  1.0
  Sb  Sb2  1  0.039  0.809  0.230  1.0
  Sb  Sb3  1  0.461  0.809  0.730  1.0
  P  P4  1  0.594  0.810  0.458  1.0
  P  P5  1  0.094  0.190  0.042  1.0
  P  P6  1  0.406  0.190  0.542  1.0
  P  P7  1  0.906  0.810  0.958  1.0
  Cl  Cl8  1  0.706  0.312  0.295  1.0
  Cl  Cl9  1  0.626  0.958  0.715  1.0
  Cl  Cl10  1  0.737  0.718  0.535  1.0
  Cl  Cl11  1  0.294  0.688  0.705  1.0
  Cl  Cl12  1  0.598  0.140  0.090  1.0
  Cl  Cl13  1  0.550  0.565  0.830  1.0
  Cl  Cl14  1  0.950  0.565  0.330  1.0
  Cl  Cl15  1  0.050  0.435  0.670  1.0
  Cl  Cl16  1  0.237  0.282  0.965  1.0
  Cl  Cl17  1  0.263  0.282  0.465  1.0
  Cl  Cl18  1  0.874  0.958  0.215  1.0
  Cl  Cl19  1  0.448  0.315  0.652  1.0
  Cl  Cl20  1  0.374  0.042  0.285  1.0
  Cl  Cl21  1  0.052  0.315  0.152  1.0
  Cl  Cl22  1  0.126  0.042  0.785  1.0
  Cl  Cl23  1  0.902  0.140  0.590  1.0
  Cl  Cl24  1  0.763  0.718  0.035  1.0
  Cl  Cl25  1  0.948  0.685  0.848  1.0
  Cl  Cl26  1  0.552  0.685  0.348  1.0
  Cl  Cl27  1  0.402  0.860  0.910  1.0
  Cl  Cl28  1  0.794  0.312  0.795  1.0
  Cl  Cl29  1  0.206  0.688  0.205  1.0
  Cl  Cl30  1  0.450  0.435  0.170  1.0
  Cl  Cl31  1  0.098  0.860  0.410  1.0
  O  O32  1  0.498  0.217  0.445  1.0
  O  O33  1  0.619  0.981  0.382  1.0
  O  O34  1  0.998  0.783  0.055  1.0
  O  O35  1  0.502  0.783  0.555  1.0
  O  O36  1  0.881  0.981  0.882  1.0
  O  O37  1  0.119  0.019  0.118  1.0
  O  O38  1  0.002  0.217  0.945  1.0
  O  O39  1  0.381  0.019  0.618  1.0
[/CIF]
.