The material structure described by Mn8O13F3 is Hydrophilite-derived structured and crystallizes in the triclinic P1 space group. There are eight inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(13), one O(2), one O(3), one O(6), one F(1), and one F(2) atom to form a mixture of edge and corner-sharing MnO4F2 octahedra. The corner-sharing octahedral tilt angles range from 47-55°. In the second Mn site, Mn(2) is bonded to one O(1), one O(12), one O(4), one O(5), one O(9), and one F(3) atom to form a mixture of edge and corner-sharing MnO5F octahedra. The corner-sharing octahedral tilt angles range from 48-56°. In the third Mn site, Mn(3) is bonded to one O(10), one O(13), one O(2), one O(3), one O(7), and one F(2) atom to form MnO5F octahedra that share corners with two equivalent Mn(5)O5F octahedra, corners with two equivalent Mn(7)O5F octahedra, corners with four equivalent Mn(8)O5F octahedra, and edges with two equivalent Mn(1)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 49-54°. In the fourth Mn site, Mn(4) is bonded to one O(1), one O(11), one O(12), one O(4), one O(8), and one F(3) atom to form a mixture of edge and corner-sharing MnO5F octahedra. The corner-sharing octahedral tilt angles range from 48-55°. In the fifth Mn site, Mn(5) is bonded to one O(10), one O(11), one O(4), one O(7), one O(8), and one F(3) atom to form a mixture of edge and corner-sharing MnO5F octahedra. The corner-sharing octahedral tilt angles range from 48-55°. In the sixth Mn site, Mn(6) is bonded to one O(1), one O(12), one O(5), one O(6), one O(9), and one F(1) atom to form MnO5F octahedra that share corners with two equivalent Mn(1)O4F2 octahedra, corners with two equivalent Mn(4)O5F octahedra, corners with four equivalent Mn(2)O5F octahedra, and edges with two equivalent Mn(7)O5F octahedra. The corner-sharing octahedral tilt angles range from 50-56°. In the seventh Mn site, Mn(7) is bonded to one O(13), one O(2), one O(5), one O(6), one O(9), and one F(1) atom to form MnO5F octahedra that share corners with two equivalent Mn(2)O5F octahedra, corners with two equivalent Mn(3)O5F octahedra, corners with four equivalent Mn(1)O4F2 octahedra, and edges with two equivalent Mn(6)O5F octahedra. The corner-sharing octahedral tilt angles range from 47-55°. In the eighth Mn site, Mn(8) is bonded to one O(10), one O(11), one O(3), one O(7), one O(8), and one F(2) atom to form MnO5F octahedra that share corners with two equivalent Mn(1)O4F2 octahedra, corners with two equivalent Mn(4)O5F octahedra, corners with four equivalent Mn(3)O5F octahedra, and edges with two equivalent Mn(5)O5F octahedra. The corner-sharing octahedral tilt angles range from 48-55°. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Mn(2), one Mn(4), and one Mn(6) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Mn(1), one Mn(3), and one Mn(7) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Mn(1), one Mn(3), and one Mn(8) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one Mn(2), one Mn(4), and one Mn(5) atom. In the fifth O site, O(5) is bonded in a trigonal planar geometry to one Mn(2), one Mn(6), and one Mn(7) atom. In the sixth O site, O(6) is bonded in a trigonal planar geometry to one Mn(1), one Mn(6), and one Mn(7) atom. In the seventh O site, O(7) is bonded in a distorted trigonal planar geometry to one Mn(3), one Mn(5), and one Mn(8) atom. In the eighth O site, O(8) is bonded in a trigonal planar geometry to one Mn(4), one Mn(5), and one Mn(8) atom. In the ninth O site, O(9) is bonded in a trigonal planar geometry to one Mn(2), one Mn(6), and one Mn(7) atom. In the tenth O site, O(10) is bonded in a distorted trigonal planar geometry to one Mn(3), one Mn(5), and one Mn(8) atom. In the eleventh O site, O(11) is bonded in a distorted trigonal planar geometry to one Mn(4), one Mn(5), and one Mn(8) atom. In the twelfth O site, O(12) is bonded in a trigonal planar geometry to one Mn(2), one Mn(4), and one Mn(6) atom. In the thirteenth O site, O(13) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(3), and one Mn(7) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(6), and one Mn(7) atom. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(3), and one Mn(8) atom. In the third F site, F(3) is bonded in a distorted trigonal planar geometry to one Mn(2), one Mn(4), and one Mn(5) atom. is represented by the CIF card [CIF]
data_Mn8O13F3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.520
_cell_length_b   5.001
_cell_length_c   11.077
_cell_angle_alpha   89.952
_cell_angle_beta   89.258
_cell_angle_gamma   89.662
_symmetry_Int_Tables_number   1
_cell_volume   250.379
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.969  0.244  0.576  1.0
  Mn  Mn1  1  0.990  0.743  0.918  1.0
  Mn  Mn2  1  0.995  0.762  0.426  1.0
  Mn  Mn3  1  0.999  0.264  0.075  1.0
  Mn  Mn4  1  0.518  0.739  0.183  1.0
  Mn  Mn5  1  0.504  0.241  0.835  1.0
  Mn  Mn6  1  0.498  0.761  0.676  1.0
  Mn  Mn7  1  0.514  0.239  0.316  1.0
  O  O8  1  0.778  0.075  0.948  1.0
  O  O9  1  0.761  0.583  0.554  1.0
  O  O10  1  0.765  0.084  0.439  1.0
  O  O11  1  0.772  0.582  0.058  1.0
  O  O12  1  0.718  0.574  0.803  1.0
  O  O13  1  0.713  0.079  0.697  1.0
  O  O14  1  0.742  0.572  0.305  1.0
  O  O15  1  0.744  0.073  0.194  1.0
  O  O16  1  0.263  0.923  0.806  1.0
  O  O17  1  0.277  0.920  0.305  1.0
  O  O18  1  0.281  0.421  0.194  1.0
  O  O19  1  0.229  0.424  0.945  1.0
  O  O20  1  0.219  0.928  0.555  1.0
  F  F21  1  0.255  0.425  0.689  1.0
  F  F22  1  0.246  0.420  0.439  1.0
  F  F23  1  0.250  0.921  0.062  1.0
[/CIF]
.
The material structure described by Mn8O13F3 is Hydrophilite-derived structured and crystallizes in the triclinic P1 space group. There are eight inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(13), one O(2), one O(3), one O(6), one F(1), and one F(2) atom to form a mixture of edge and corner-sharing MnO4F2 octahedra. The corner-sharing octahedral tilt angles range from 47-55°. In the second Mn site, Mn(2) is bonded to one O(1), one O(12), one O(4), one O(5), one O(9), and one F(3) atom to form a mixture of edge and corner-sharing MnO5F octahedra. The corner-sharing octahedral tilt angles range from 48-56°. In the third Mn site, Mn(3) is bonded to one O(10), one O(13), one O(2), one O(3), one O(7), and one F(2) atom to form MnO5F octahedra that share corners with two equivalent Mn(5)O5F octahedra, corners with two equivalent Mn(7)O5F octahedra, corners with four equivalent Mn(8)O5F octahedra, and edges with two equivalent Mn(1)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 49-54°. In the fourth Mn site, Mn(4) is bonded to one O(1), one O(11), one O(12), one O(4), one O(8), and one F(3) atom to form a mixture of edge and corner-sharing MnO5F octahedra. The corner-sharing octahedral tilt angles range from 48-55°. In the fifth Mn site, Mn(5) is bonded to one O(10), one O(11), one O(4), one O(7), one O(8), and one F(3) atom to form a mixture of edge and corner-sharing MnO5F octahedra. The corner-sharing octahedral tilt angles range from 48-55°. In the sixth Mn site, Mn(6) is bonded to one O(1), one O(12), one O(5), one O(6), one O(9), and one F(1) atom to form MnO5F octahedra that share corners with two equivalent Mn(1)O4F2 octahedra, corners with two equivalent Mn(4)O5F octahedra, corners with four equivalent Mn(2)O5F octahedra, and edges with two equivalent Mn(7)O5F octahedra. The corner-sharing octahedral tilt angles range from 50-56°. In the seventh Mn site, Mn(7) is bonded to one O(13), one O(2), one O(5), one O(6), one O(9), and one F(1) atom to form MnO5F octahedra that share corners with two equivalent Mn(2)O5F octahedra, corners with two equivalent Mn(3)O5F octahedra, corners with four equivalent Mn(1)O4F2 octahedra, and edges with two equivalent Mn(6)O5F octahedra. The corner-sharing octahedral tilt angles range from 47-55°. In the eighth Mn site, Mn(8) is bonded to one O(10), one O(11), one O(3), one O(7), one O(8), and one F(2) atom to form MnO5F octahedra that share corners with two equivalent Mn(1)O4F2 octahedra, corners with two equivalent Mn(4)O5F octahedra, corners with four equivalent Mn(3)O5F octahedra, and edges with two equivalent Mn(5)O5F octahedra. The corner-sharing octahedral tilt angles range from 48-55°. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Mn(2), one Mn(4), and one Mn(6) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Mn(1), one Mn(3), and one Mn(7) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Mn(1), one Mn(3), and one Mn(8) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one Mn(2), one Mn(4), and one Mn(5) atom. In the fifth O site, O(5) is bonded in a trigonal planar geometry to one Mn(2), one Mn(6), and one Mn(7) atom. In the sixth O site, O(6) is bonded in a trigonal planar geometry to one Mn(1), one Mn(6), and one Mn(7) atom. In the seventh O site, O(7) is bonded in a distorted trigonal planar geometry to one Mn(3), one Mn(5), and one Mn(8) atom. In the eighth O site, O(8) is bonded in a trigonal planar geometry to one Mn(4), one Mn(5), and one Mn(8) atom. In the ninth O site, O(9) is bonded in a trigonal planar geometry to one Mn(2), one Mn(6), and one Mn(7) atom. In the tenth O site, O(10) is bonded in a distorted trigonal planar geometry to one Mn(3), one Mn(5), and one Mn(8) atom. In the eleventh O site, O(11) is bonded in a distorted trigonal planar geometry to one Mn(4), one Mn(5), and one Mn(8) atom. In the twelfth O site, O(12) is bonded in a trigonal planar geometry to one Mn(2), one Mn(4), and one Mn(6) atom. In the thirteenth O site, O(13) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(3), and one Mn(7) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(6), and one Mn(7) atom. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(3), and one Mn(8) atom. In the third F site, F(3) is bonded in a distorted trigonal planar geometry to one Mn(2), one Mn(4), and one Mn(5) atom. is represented by the CIF card [CIF]
data_Mn8O13F3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.520
_cell_length_b   5.001
_cell_length_c   11.077
_cell_angle_alpha   89.952
_cell_angle_beta   89.258
_cell_angle_gamma   89.662
_symmetry_Int_Tables_number   1
_cell_volume   250.379
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.969  0.244  0.576  1.0
  Mn  Mn1  1  0.990  0.743  0.918  1.0
  Mn  Mn2  1  0.995  0.762  0.426  1.0
  Mn  Mn3  1  0.999  0.264  0.075  1.0
  Mn  Mn4  1  0.518  0.739  0.183  1.0
  Mn  Mn5  1  0.504  0.241  0.835  1.0
  Mn  Mn6  1  0.498  0.761  0.676  1.0
  Mn  Mn7  1  0.514  0.239  0.316  1.0
  O  O8  1  0.778  0.075  0.948  1.0
  O  O9  1  0.761  0.583  0.554  1.0
  O  O10  1  0.765  0.084  0.439  1.0
  O  O11  1  0.772  0.582  0.058  1.0
  O  O12  1  0.718  0.574  0.803  1.0
  O  O13  1  0.713  0.079  0.697  1.0
  O  O14  1  0.742  0.572  0.305  1.0
  O  O15  1  0.744  0.073  0.194  1.0
  O  O16  1  0.263  0.923  0.806  1.0
  O  O17  1  0.277  0.920  0.305  1.0
  O  O18  1  0.281  0.421  0.194  1.0
  O  O19  1  0.229  0.424  0.945  1.0
  O  O20  1  0.219  0.928  0.555  1.0
  F  F21  1  0.255  0.425  0.689  1.0
  F  F22  1  0.246  0.420  0.439  1.0
  F  F23  1  0.250  0.921  0.062  1.0
[/CIF]
.