The compound described by N2GeF6 is Indium-derived structured and crystallizes in the hexagonal P6_3mc space group. The structure is zero-dimensional and consists of four ammonia atoms and two GeF6 clusters. In each GeF6 cluster, Ge(1) is bonded in an octahedral geometry to three equivalent F(1) and three equivalent F(2) atoms. There are two inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one Ge(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one Ge(1) atom. is represented by the CIF file [CIF]
data_Ge(NF3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.262
_cell_length_b   5.262
_cell_length_c   9.501
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   227.800
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ge  Ge0  1  0.667  0.333  0.750  1.0
  Ge  Ge1  1  0.333  0.667  0.250  1.0
  N  N2  1  0.667  0.333  0.365  1.0
  N  N3  1  0.333  0.667  0.865  1.0
  N  N4  1  0.000  0.000  0.091  1.0
  N  N5  1  0.000  0.000  0.591  1.0
  F  F6  1  0.830  0.170  0.860  1.0
  F  F7  1  0.340  0.170  0.860  1.0
  F  F8  1  0.830  0.660  0.860  1.0
  F  F9  1  0.170  0.830  0.360  1.0
  F  F10  1  0.660  0.830  0.360  1.0
  F  F11  1  0.170  0.340  0.360  1.0
  F  F12  1  0.505  0.495  0.635  1.0
  F  F13  1  0.990  0.495  0.635  1.0
  F  F14  1  0.505  0.010  0.635  1.0
  F  F15  1  0.495  0.505  0.135  1.0
  F  F16  1  0.010  0.505  0.135  1.0
  F  F17  1  0.495  0.990  0.135  1.0
[/CIF]
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The compound described by N2GeF6 is Indium-derived structured and crystallizes in the hexagonal P6_3mc space group. The structure is zero-dimensional and consists of four ammonia atoms and two GeF6 clusters. In each GeF6 cluster, Ge(1) is bonded in an octahedral geometry to three equivalent F(1) and three equivalent F(2) atoms. There are two inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one Ge(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one Ge(1) atom. is represented by the CIF file [CIF]
data_Ge(NF3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.262
_cell_length_b   5.262
_cell_length_c   9.501
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   227.800
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ge  Ge0  1  0.667  0.333  0.750  1.0
  Ge  Ge1  1  0.333  0.667  0.250  1.0
  N  N2  1  0.667  0.333  0.365  1.0
  N  N3  1  0.333  0.667  0.865  1.0
  N  N4  1  0.000  0.000  0.091  1.0
  N  N5  1  0.000  0.000  0.591  1.0
  F  F6  1  0.830  0.170  0.860  1.0
  F  F7  1  0.340  0.170  0.860  1.0
  F  F8  1  0.830  0.660  0.860  1.0
  F  F9  1  0.170  0.830  0.360  1.0
  F  F10  1  0.660  0.830  0.360  1.0
  F  F11  1  0.170  0.340  0.360  1.0
  F  F12  1  0.505  0.495  0.635  1.0
  F  F13  1  0.990  0.495  0.635  1.0
  F  F14  1  0.505  0.010  0.635  1.0
  F  F15  1  0.495  0.505  0.135  1.0
  F  F16  1  0.010  0.505  0.135  1.0
  F  F17  1  0.495  0.990  0.135  1.0
[/CIF]
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