The compound described by Mn(NO4)2(SO3)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four sulfur trioxide molecules and two Mn(NO4)2 clusters. In each Mn(NO4)2 cluster, Mn(1) is bonded in an octahedral geometry to two equivalent O(5), two equivalent O(6), and two equivalent O(7) atoms. N(1) is bonded in a bent 120 degrees geometry to one O(4) and one O(5) atom. There are four inequivalent O sites. In the first O site, O(7) is bonded in a 2-coordinate geometry to one Mn(1) and one O(6) atom. In the second O site, O(4) is bonded in a single-bond geometry to one N(1) atom. In the third O site, O(5) is bonded in a bent 120 degrees geometry to one Mn(1) and one N(1) atom. In the fourth O site, O(6) is bonded in a 2-coordinate geometry to one Mn(1) and one O(7) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_MnS2(NO7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.932
_cell_length_b   6.934
_cell_length_c   10.102
_cell_angle_alpha   64.153
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   689.186
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.500  0.000  0.500  1.0
  Mn  Mn1  1  0.000  0.000  0.000  1.0
  S  S2  1  0.375  0.331  0.922  1.0
  S  S3  1  0.875  0.669  0.578  1.0
  S  S4  1  0.625  0.669  0.078  1.0
  S  S5  1  0.125  0.331  0.422  1.0
  N  N6  1  0.239  0.791  0.604  1.0
  N  N7  1  0.739  0.209  0.896  1.0
  N  N8  1  0.761  0.209  0.396  1.0
  N  N9  1  0.261  0.791  0.104  1.0
  O  O10  1  0.247  0.381  0.897  1.0
  O  O11  1  0.747  0.619  0.603  1.0
  O  O12  1  0.753  0.619  0.103  1.0
  O  O13  1  0.253  0.381  0.397  1.0
  O  O14  1  0.425  0.265  0.067  1.0
  O  O15  1  0.925  0.735  0.433  1.0
  O  O16  1  0.575  0.735  0.933  1.0
  O  O17  1  0.075  0.265  0.567  1.0
  O  O18  1  0.453  0.354  0.802  1.0
  O  O19  1  0.953  0.646  0.698  1.0
  O  O20  1  0.547  0.646  0.198  1.0
  O  O21  1  0.047  0.354  0.302  1.0
  O  O22  1  0.309  0.893  0.984  1.0
  O  O23  1  0.809  0.107  0.516  1.0
  O  O24  1  0.691  0.107  0.016  1.0
  O  O25  1  0.191  0.893  0.484  1.0
  O  O26  1  0.342  0.837  0.639  1.0
  O  O27  1  0.842  0.163  0.861  1.0
  O  O28  1  0.658  0.163  0.361  1.0
  O  O29  1  0.158  0.837  0.139  1.0
  O  O30  1  0.441  0.866  0.371  1.0
  O  O31  1  0.941  0.134  0.129  1.0
  O  O32  1  0.559  0.134  0.629  1.0
  O  O33  1  0.059  0.866  0.871  1.0
  O  O34  1  0.521  0.738  0.469  1.0
  O  O35  1  0.021  0.262  0.031  1.0
  O  O36  1  0.479  0.262  0.531  1.0
  O  O37  1  0.979  0.738  0.969  1.0
[/CIF]
.
The compound described by Mn(NO4)2(SO3)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four sulfur trioxide molecules and two Mn(NO4)2 clusters. In each Mn(NO4)2 cluster, Mn(1) is bonded in an octahedral geometry to two equivalent O(5), two equivalent O(6), and two equivalent O(7) atoms. N(1) is bonded in a bent 120 degrees geometry to one O(4) and one O(5) atom. There are four inequivalent O sites. In the first O site, O(7) is bonded in a 2-coordinate geometry to one Mn(1) and one O(6) atom. In the second O site, O(4) is bonded in a single-bond geometry to one N(1) atom. In the third O site, O(5) is bonded in a bent 120 degrees geometry to one Mn(1) and one N(1) atom. In the fourth O site, O(6) is bonded in a 2-coordinate geometry to one Mn(1) and one O(7) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_MnS2(NO7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.932
_cell_length_b   6.934
_cell_length_c   10.102
_cell_angle_alpha   64.153
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   689.186
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.500  0.000  0.500  1.0
  Mn  Mn1  1  0.000  0.000  0.000  1.0
  S  S2  1  0.375  0.331  0.922  1.0
  S  S3  1  0.875  0.669  0.578  1.0
  S  S4  1  0.625  0.669  0.078  1.0
  S  S5  1  0.125  0.331  0.422  1.0
  N  N6  1  0.239  0.791  0.604  1.0
  N  N7  1  0.739  0.209  0.896  1.0
  N  N8  1  0.761  0.209  0.396  1.0
  N  N9  1  0.261  0.791  0.104  1.0
  O  O10  1  0.247  0.381  0.897  1.0
  O  O11  1  0.747  0.619  0.603  1.0
  O  O12  1  0.753  0.619  0.103  1.0
  O  O13  1  0.253  0.381  0.397  1.0
  O  O14  1  0.425  0.265  0.067  1.0
  O  O15  1  0.925  0.735  0.433  1.0
  O  O16  1  0.575  0.735  0.933  1.0
  O  O17  1  0.075  0.265  0.567  1.0
  O  O18  1  0.453  0.354  0.802  1.0
  O  O19  1  0.953  0.646  0.698  1.0
  O  O20  1  0.547  0.646  0.198  1.0
  O  O21  1  0.047  0.354  0.302  1.0
  O  O22  1  0.309  0.893  0.984  1.0
  O  O23  1  0.809  0.107  0.516  1.0
  O  O24  1  0.691  0.107  0.016  1.0
  O  O25  1  0.191  0.893  0.484  1.0
  O  O26  1  0.342  0.837  0.639  1.0
  O  O27  1  0.842  0.163  0.861  1.0
  O  O28  1  0.658  0.163  0.361  1.0
  O  O29  1  0.158  0.837  0.139  1.0
  O  O30  1  0.441  0.866  0.371  1.0
  O  O31  1  0.941  0.134  0.129  1.0
  O  O32  1  0.559  0.134  0.629  1.0
  O  O33  1  0.059  0.866  0.871  1.0
  O  O34  1  0.521  0.738  0.469  1.0
  O  O35  1  0.021  0.262  0.031  1.0
  O  O36  1  0.479  0.262  0.531  1.0
  O  O37  1  0.979  0.738  0.969  1.0
[/CIF]
.