The crystal structure described by HoSF is Matlockite structured and crystallizes in the tetragonal P4/nmm space group. Ho(1) is bonded in a 9-coordinate geometry to five equivalent S(1) and four equivalent F(1) atoms. S(1) is bonded to five equivalent Ho(1) atoms to form distorted SHo5 trigonal bipyramids that share corners with twelve equivalent F(1)Ho4 tetrahedra, corners with four equivalent S(1)Ho5 trigonal bipyramids, edges with four equivalent F(1)Ho4 tetrahedra, and edges with eight equivalent S(1)Ho5 trigonal bipyramids. F(1) is bonded to four equivalent Ho(1) atoms to form FHo4 tetrahedra that share corners with four equivalent F(1)Ho4 tetrahedra, corners with twelve equivalent S(1)Ho5 trigonal bipyramids, edges with four equivalent F(1)Ho4 tetrahedra, and edges with four equivalent S(1)Ho5 trigonal bipyramids. is represented by the CIF file [CIF]
data_HoSF
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.744
_cell_length_b   3.744
_cell_length_c   6.787
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   95.133
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ho  Ho0  1  0.750  0.750  0.773  1.0
  Ho  Ho1  1  0.250  0.250  0.227  1.0
  S  S2  1  0.250  0.250  0.645  1.0
  S  S3  1  0.750  0.750  0.355  1.0
  F  F4  1  0.250  0.750  0.000  1.0
  F  F5  1  0.750  0.250  0.000  1.0
[/CIF]
.
The crystal structure described by HoSF is Matlockite structured and crystallizes in the tetragonal P4/nmm space group. Ho(1) is bonded in a 9-coordinate geometry to five equivalent S(1) and four equivalent F(1) atoms. S(1) is bonded to five equivalent Ho(1) atoms to form distorted SHo5 trigonal bipyramids that share corners with twelve equivalent F(1)Ho4 tetrahedra, corners with four equivalent S(1)Ho5 trigonal bipyramids, edges with four equivalent F(1)Ho4 tetrahedra, and edges with eight equivalent S(1)Ho5 trigonal bipyramids. F(1) is bonded to four equivalent Ho(1) atoms to form FHo4 tetrahedra that share corners with four equivalent F(1)Ho4 tetrahedra, corners with twelve equivalent S(1)Ho5 trigonal bipyramids, edges with four equivalent F(1)Ho4 tetrahedra, and edges with four equivalent S(1)Ho5 trigonal bipyramids. is represented by the CIF file [CIF]
data_HoSF
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.744
_cell_length_b   3.744
_cell_length_c   6.787
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   95.133
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ho  Ho0  1  0.750  0.750  0.773  1.0
  Ho  Ho1  1  0.250  0.250  0.227  1.0
  S  S2  1  0.250  0.250  0.645  1.0
  S  S3  1  0.750  0.750  0.355  1.0
  F  F4  1  0.250  0.750  0.000  1.0
  F  F5  1  0.750  0.250  0.000  1.0
[/CIF]
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