The structure described by (Bi)5(GaCl4)3 is Iron carbide-derived structured and crystallizes in the trigonal R3c space group. The structure is zero-dimensional and consists of six 7440-69-9 atoms, six Bi clusters, and eighteen GaCl4 clusters. In each Bi cluster, there are two inequivalent Bi sites. In the first Bi site, Bi(1) is bonded in a 4-coordinate geometry to one Bi(3) atom. In the second Bi site, Bi(3) is bonded in a 3-coordinate geometry to three equivalent Bi(1) atoms. In each GaCl4 cluster, Ga(1) is bonded in a tetrahedral geometry to one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Ga(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Ga(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Ga(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Ga(1) atom. is represented by the CIF card [CIF]
data_Ga3Bi5Cl12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.456
_cell_length_b   12.456
_cell_length_c   12.456
_cell_angle_alpha   57.965
_cell_angle_beta   57.965
_cell_angle_gamma   57.965
_symmetry_Int_Tables_number   1
_cell_volume   1302.857
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.230  0.748  0.273  1.0
  Ga  Ga1  1  0.748  0.273  0.230  1.0
  Ga  Ga2  1  0.730  0.773  0.248  1.0
  Ga  Ga3  1  0.273  0.230  0.748  1.0
  Ga  Ga4  1  0.248  0.730  0.773  1.0
  Ga  Ga5  1  0.773  0.248  0.730  1.0
  Bi  Bi6  1  0.406  0.253  0.091  1.0
  Bi  Bi7  1  0.906  0.591  0.753  1.0
  Bi  Bi8  1  0.172  0.172  0.172  1.0
  Bi  Bi9  1  0.672  0.672  0.672  1.0
  Bi  Bi10  1  0.591  0.753  0.906  1.0
  Bi  Bi11  1  0.827  0.827  0.827  1.0
  Bi  Bi12  1  0.327  0.327  0.327  1.0
  Bi  Bi13  1  0.091  0.406  0.253  1.0
  Bi  Bi14  1  0.753  0.906  0.591  1.0
  Bi  Bi15  1  0.253  0.091  0.406  1.0
  Cl  Cl16  1  0.072  0.696  0.959  1.0
  Cl  Cl17  1  0.459  0.196  0.572  1.0
  Cl  Cl18  1  0.196  0.572  0.459  1.0
  Cl  Cl19  1  0.299  0.898  0.726  1.0
  Cl  Cl20  1  0.608  0.197  0.771  1.0
  Cl  Cl21  1  0.696  0.959  0.072  1.0
  Cl  Cl22  1  0.726  0.299  0.898  1.0
  Cl  Cl23  1  0.197  0.771  0.608  1.0
  Cl  Cl24  1  0.809  0.426  0.545  1.0
  Cl  Cl25  1  0.697  0.108  0.271  1.0
  Cl  Cl26  1  0.959  0.072  0.696  1.0
  Cl  Cl27  1  0.545  0.809  0.426  1.0
  Cl  Cl28  1  0.926  0.309  0.045  1.0
  Cl  Cl29  1  0.309  0.045  0.926  1.0
  Cl  Cl30  1  0.271  0.697  0.108  1.0
  Cl  Cl31  1  0.799  0.226  0.398  1.0
  Cl  Cl32  1  0.226  0.398  0.799  1.0
  Cl  Cl33  1  0.771  0.608  0.197  1.0
  Cl  Cl34  1  0.108  0.271  0.697  1.0
  Cl  Cl35  1  0.045  0.926  0.309  1.0
  Cl  Cl36  1  0.572  0.459  0.196  1.0
  Cl  Cl37  1  0.426  0.545  0.809  1.0
  Cl  Cl38  1  0.898  0.726  0.299  1.0
  Cl  Cl39  1  0.398  0.799  0.226  1.0
[/CIF]
.
The structure described by (Bi)5(GaCl4)3 is Iron carbide-derived structured and crystallizes in the trigonal R3c space group. The structure is zero-dimensional and consists of six 7440-69-9 atoms, six Bi clusters, and eighteen GaCl4 clusters. In each Bi cluster, there are two inequivalent Bi sites. In the first Bi site, Bi(1) is bonded in a 4-coordinate geometry to one Bi(3) atom. In the second Bi site, Bi(3) is bonded in a 3-coordinate geometry to three equivalent Bi(1) atoms. In each GaCl4 cluster, Ga(1) is bonded in a tetrahedral geometry to one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Ga(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Ga(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Ga(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Ga(1) atom. is represented by the CIF card [CIF]
data_Ga3Bi5Cl12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.456
_cell_length_b   12.456
_cell_length_c   12.456
_cell_angle_alpha   57.965
_cell_angle_beta   57.965
_cell_angle_gamma   57.965
_symmetry_Int_Tables_number   1
_cell_volume   1302.857
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.230  0.748  0.273  1.0
  Ga  Ga1  1  0.748  0.273  0.230  1.0
  Ga  Ga2  1  0.730  0.773  0.248  1.0
  Ga  Ga3  1  0.273  0.230  0.748  1.0
  Ga  Ga4  1  0.248  0.730  0.773  1.0
  Ga  Ga5  1  0.773  0.248  0.730  1.0
  Bi  Bi6  1  0.406  0.253  0.091  1.0
  Bi  Bi7  1  0.906  0.591  0.753  1.0
  Bi  Bi8  1  0.172  0.172  0.172  1.0
  Bi  Bi9  1  0.672  0.672  0.672  1.0
  Bi  Bi10  1  0.591  0.753  0.906  1.0
  Bi  Bi11  1  0.827  0.827  0.827  1.0
  Bi  Bi12  1  0.327  0.327  0.327  1.0
  Bi  Bi13  1  0.091  0.406  0.253  1.0
  Bi  Bi14  1  0.753  0.906  0.591  1.0
  Bi  Bi15  1  0.253  0.091  0.406  1.0
  Cl  Cl16  1  0.072  0.696  0.959  1.0
  Cl  Cl17  1  0.459  0.196  0.572  1.0
  Cl  Cl18  1  0.196  0.572  0.459  1.0
  Cl  Cl19  1  0.299  0.898  0.726  1.0
  Cl  Cl20  1  0.608  0.197  0.771  1.0
  Cl  Cl21  1  0.696  0.959  0.072  1.0
  Cl  Cl22  1  0.726  0.299  0.898  1.0
  Cl  Cl23  1  0.197  0.771  0.608  1.0
  Cl  Cl24  1  0.809  0.426  0.545  1.0
  Cl  Cl25  1  0.697  0.108  0.271  1.0
  Cl  Cl26  1  0.959  0.072  0.696  1.0
  Cl  Cl27  1  0.545  0.809  0.426  1.0
  Cl  Cl28  1  0.926  0.309  0.045  1.0
  Cl  Cl29  1  0.309  0.045  0.926  1.0
  Cl  Cl30  1  0.271  0.697  0.108  1.0
  Cl  Cl31  1  0.799  0.226  0.398  1.0
  Cl  Cl32  1  0.226  0.398  0.799  1.0
  Cl  Cl33  1  0.771  0.608  0.197  1.0
  Cl  Cl34  1  0.108  0.271  0.697  1.0
  Cl  Cl35  1  0.045  0.926  0.309  1.0
  Cl  Cl36  1  0.572  0.459  0.196  1.0
  Cl  Cl37  1  0.426  0.545  0.809  1.0
  Cl  Cl38  1  0.898  0.726  0.299  1.0
  Cl  Cl39  1  0.398  0.799  0.226  1.0
[/CIF]
.