The material structure described by Ag2TeO6 crystallizes in the triclinic P1 space group. There are four inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to one O(1), one O(2), one O(5), one O(7), and one O(9) atom to form distorted AgO5 trigonal bipyramids that share  a cornercorner with one Te(2)O6 octahedra, corners with two equivalent Ag(3)O5 trigonal bipyramids, and edges with two equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles are 49°. In the second Ag site, Ag(2) is bonded in a rectangular see-saw-like geometry to one O(1), one O(10), one O(2), and one O(8) atom. In the third Ag site, Ag(3) is bonded to one O(11), one O(3), one O(4), one O(5), and one O(7) atom to form distorted AgO5 trigonal bipyramids that share  a cornercorner with one Te(1)O6 octahedra, corners with two equivalent Ag(1)O5 trigonal bipyramids, and edges with two equivalent Te(2)O6 octahedra. The corner-sharing octahedral tilt angles are 49°. In the fourth Ag site, Ag(4) is bonded in a rectangular see-saw-like geometry to one O(12), one O(3), one O(4), and one O(6) atom. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(1), one O(10), one O(2), one O(5), one O(6), and one O(9) atom to form TeO6 octahedra that share  a cornercorner with one Ag(3)O5 trigonal bipyramid and edges with two equivalent Ag(1)O5 trigonal bipyramids. In the second Te site, Te(2) is bonded to one O(11), one O(12), one O(3), one O(4), one O(7), and one O(8) atom to form TeO6 octahedra that share  a cornercorner with one Ag(1)O5 trigonal bipyramid and edges with two equivalent Ag(3)O5 trigonal bipyramids. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one Ag(1), one Ag(2), and one Te(1) atom. In the second O site, O(2) is bonded in a distorted T-shaped geometry to one Ag(1), one Ag(2), and one Te(1) atom. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one Ag(3), one Ag(4), and one Te(2) atom. In the fourth O site, O(4) is bonded in a distorted T-shaped geometry to one Ag(3), one Ag(4), and one Te(2) atom. In the fifth O site, O(5) is bonded in a distorted trigonal non-coplanar geometry to one Ag(1), one Ag(3), and one Te(1) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Ag(4) and one Te(1) atom. In the seventh O site, O(7) is bonded in a distorted trigonal non-coplanar geometry to one Ag(1), one Ag(3), and one Te(2) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Ag(2) and one Te(2) atom. In the ninth O site, O(9) is bonded in a water-like geometry to one Ag(1) and one Te(1) atom. In the tenth O site, O(10) is bonded in a water-like geometry to one Ag(2) and one Te(1) atom. In the eleventh O site, O(11) is bonded in a water-like geometry to one Ag(3) and one Te(2) atom. In the twelfth O site, O(12) is bonded in a water-like geometry to one Ag(4) and one Te(2) atom. is represented by the CIF card [CIF]
data_Ag2TeO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.507
_cell_length_b   6.766
_cell_length_c   10.143
_cell_angle_alpha   56.267
_cell_angle_beta   41.270
_cell_angle_gamma   82.145
_symmetry_Int_Tables_number   1
_cell_volume   275.155
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.892  0.654  0.778  1.0
  Ag  Ag1  1  0.697  0.658  0.630  1.0
  Ag  Ag2  1  0.469  0.575  0.358  1.0
  Ag  Ag3  1  0.619  0.237  0.552  1.0
  Te  Te4  1  0.229  0.277  0.265  1.0
  Te  Te5  1  0.984  0.021  0.021  1.0
  O  O6  1  0.621  0.359  0.929  1.0
  O  O7  1  0.097  0.923  0.378  1.0
  O  O8  1  0.319  0.159  0.629  1.0
  O  O9  1  0.871  0.648  0.153  1.0
  O  O10  1  0.457  0.571  0.137  1.0
  O  O11  1  0.879  0.254  0.526  1.0
  O  O12  1  0.112  0.415  0.793  1.0
  O  O13  1  0.722  0.909  0.370  1.0
  O  O14  1  0.168  0.025  0.543  1.0
  O  O15  1  0.276  0.482  0.996  1.0
  O  O16  1  0.705  0.986  0.082  1.0
  O  O17  1  0.253  0.005  0.972  1.0
[/CIF]
.
The material structure described by Ag2TeO6 crystallizes in the triclinic P1 space group. There are four inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to one O(1), one O(2), one O(5), one O(7), and one O(9) atom to form distorted AgO5 trigonal bipyramids that share  a cornercorner with one Te(2)O6 octahedra, corners with two equivalent Ag(3)O5 trigonal bipyramids, and edges with two equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles are 49°. In the second Ag site, Ag(2) is bonded in a rectangular see-saw-like geometry to one O(1), one O(10), one O(2), and one O(8) atom. In the third Ag site, Ag(3) is bonded to one O(11), one O(3), one O(4), one O(5), and one O(7) atom to form distorted AgO5 trigonal bipyramids that share  a cornercorner with one Te(1)O6 octahedra, corners with two equivalent Ag(1)O5 trigonal bipyramids, and edges with two equivalent Te(2)O6 octahedra. The corner-sharing octahedral tilt angles are 49°. In the fourth Ag site, Ag(4) is bonded in a rectangular see-saw-like geometry to one O(12), one O(3), one O(4), and one O(6) atom. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(1), one O(10), one O(2), one O(5), one O(6), and one O(9) atom to form TeO6 octahedra that share  a cornercorner with one Ag(3)O5 trigonal bipyramid and edges with two equivalent Ag(1)O5 trigonal bipyramids. In the second Te site, Te(2) is bonded to one O(11), one O(12), one O(3), one O(4), one O(7), and one O(8) atom to form TeO6 octahedra that share  a cornercorner with one Ag(1)O5 trigonal bipyramid and edges with two equivalent Ag(3)O5 trigonal bipyramids. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one Ag(1), one Ag(2), and one Te(1) atom. In the second O site, O(2) is bonded in a distorted T-shaped geometry to one Ag(1), one Ag(2), and one Te(1) atom. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one Ag(3), one Ag(4), and one Te(2) atom. In the fourth O site, O(4) is bonded in a distorted T-shaped geometry to one Ag(3), one Ag(4), and one Te(2) atom. In the fifth O site, O(5) is bonded in a distorted trigonal non-coplanar geometry to one Ag(1), one Ag(3), and one Te(1) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Ag(4) and one Te(1) atom. In the seventh O site, O(7) is bonded in a distorted trigonal non-coplanar geometry to one Ag(1), one Ag(3), and one Te(2) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Ag(2) and one Te(2) atom. In the ninth O site, O(9) is bonded in a water-like geometry to one Ag(1) and one Te(1) atom. In the tenth O site, O(10) is bonded in a water-like geometry to one Ag(2) and one Te(1) atom. In the eleventh O site, O(11) is bonded in a water-like geometry to one Ag(3) and one Te(2) atom. In the twelfth O site, O(12) is bonded in a water-like geometry to one Ag(4) and one Te(2) atom. is represented by the CIF card [CIF]
data_Ag2TeO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.507
_cell_length_b   6.766
_cell_length_c   10.143
_cell_angle_alpha   56.267
_cell_angle_beta   41.270
_cell_angle_gamma   82.145
_symmetry_Int_Tables_number   1
_cell_volume   275.155
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.892  0.654  0.778  1.0
  Ag  Ag1  1  0.697  0.658  0.630  1.0
  Ag  Ag2  1  0.469  0.575  0.358  1.0
  Ag  Ag3  1  0.619  0.237  0.552  1.0
  Te  Te4  1  0.229  0.277  0.265  1.0
  Te  Te5  1  0.984  0.021  0.021  1.0
  O  O6  1  0.621  0.359  0.929  1.0
  O  O7  1  0.097  0.923  0.378  1.0
  O  O8  1  0.319  0.159  0.629  1.0
  O  O9  1  0.871  0.648  0.153  1.0
  O  O10  1  0.457  0.571  0.137  1.0
  O  O11  1  0.879  0.254  0.526  1.0
  O  O12  1  0.112  0.415  0.793  1.0
  O  O13  1  0.722  0.909  0.370  1.0
  O  O14  1  0.168  0.025  0.543  1.0
  O  O15  1  0.276  0.482  0.996  1.0
  O  O16  1  0.705  0.986  0.082  1.0
  O  O17  1  0.253  0.005  0.972  1.0
[/CIF]
.