The material structure described by HoC5H9(NO4)2 crystallizes in the monoclinic C2 space group. Ho(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms. There are three inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one H(3), and one O(1) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one H(4), one O(3), and one O(4) atom. In the third C site, C(3) is bonded in a trigonal planar geometry to one H(5) and two equivalent O(2) atoms. N(1) is bonded in a trigonal planar geometry to one C(1), one H(1), and one H(2) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(3) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Ho(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Ho(1) and one C(3) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Ho(1) and one C(2) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Ho(1) and one C(2) atom. is represented by the CIF card [CIF]
data_HoH9C5(NO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.698
_cell_length_b   6.698
_cell_length_c   6.647
_cell_angle_alpha   75.359
_cell_angle_beta   75.359
_cell_angle_gamma   65.813
_symmetry_Int_Tables_number   1
_cell_volume   259.440
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ho  Ho0  1  0.093  0.907  0.000  1.0
  H  H1  1  0.896  0.549  0.421  1.0
  H  H2  1  0.451  0.104  0.579  1.0
  H  H3  1  0.613  0.641  0.540  1.0
  H  H4  1  0.359  0.387  0.460  1.0
  H  H5  1  0.654  0.367  0.818  1.0
  H  H6  1  0.633  0.346  0.182  1.0
  H  H7  1  0.629  0.746  0.125  1.0
  H  H8  1  0.254  0.371  0.875  1.0
  H  H9  1  0.010  0.990  0.500  1.0
  C  C10  1  0.807  0.368  0.707  1.0
  C  C11  1  0.632  0.193  0.293  1.0
  C  C12  1  0.622  0.850  0.966  1.0
  C  C13  1  0.150  0.378  0.034  1.0
  C  C14  1  0.161  0.839  0.500  1.0
  N  N15  1  0.772  0.533  0.544  1.0
  N  N16  1  0.467  0.228  0.456  1.0
  O  O17  1  0.993  0.223  0.738  1.0
  O  O18  1  0.777  0.007  0.262  1.0
  O  O19  1  0.239  0.753  0.333  1.0
  O  O20  1  0.247  0.761  0.667  1.0
  O  O21  1  0.452  0.894  0.886  1.0
  O  O22  1  0.106  0.548  0.114  1.0
  O  O23  1  0.083  0.222  0.122  1.0
  O  O24  1  0.778  0.917  0.878  1.0
[/CIF]
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The material structure described by HoC5H9(NO4)2 crystallizes in the monoclinic C2 space group. Ho(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms. There are three inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one H(3), and one O(1) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one H(4), one O(3), and one O(4) atom. In the third C site, C(3) is bonded in a trigonal planar geometry to one H(5) and two equivalent O(2) atoms. N(1) is bonded in a trigonal planar geometry to one C(1), one H(1), and one H(2) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(3) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Ho(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Ho(1) and one C(3) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Ho(1) and one C(2) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Ho(1) and one C(2) atom. is represented by the CIF card [CIF]
data_HoH9C5(NO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.698
_cell_length_b   6.698
_cell_length_c   6.647
_cell_angle_alpha   75.359
_cell_angle_beta   75.359
_cell_angle_gamma   65.813
_symmetry_Int_Tables_number   1
_cell_volume   259.440
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ho  Ho0  1  0.093  0.907  0.000  1.0
  H  H1  1  0.896  0.549  0.421  1.0
  H  H2  1  0.451  0.104  0.579  1.0
  H  H3  1  0.613  0.641  0.540  1.0
  H  H4  1  0.359  0.387  0.460  1.0
  H  H5  1  0.654  0.367  0.818  1.0
  H  H6  1  0.633  0.346  0.182  1.0
  H  H7  1  0.629  0.746  0.125  1.0
  H  H8  1  0.254  0.371  0.875  1.0
  H  H9  1  0.010  0.990  0.500  1.0
  C  C10  1  0.807  0.368  0.707  1.0
  C  C11  1  0.632  0.193  0.293  1.0
  C  C12  1  0.622  0.850  0.966  1.0
  C  C13  1  0.150  0.378  0.034  1.0
  C  C14  1  0.161  0.839  0.500  1.0
  N  N15  1  0.772  0.533  0.544  1.0
  N  N16  1  0.467  0.228  0.456  1.0
  O  O17  1  0.993  0.223  0.738  1.0
  O  O18  1  0.777  0.007  0.262  1.0
  O  O19  1  0.239  0.753  0.333  1.0
  O  O20  1  0.247  0.761  0.667  1.0
  O  O21  1  0.452  0.894  0.886  1.0
  O  O22  1  0.106  0.548  0.114  1.0
  O  O23  1  0.083  0.222  0.122  1.0
  O  O24  1  0.778  0.917  0.878  1.0
[/CIF]
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