The structure described by Li2Rh3B2 crystallizes in the orthorhombic Pbam space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded in a 14-coordinate geometry to three equivalent Li(1); two equivalent Rh(2); six equivalent Rh(1); and three B(1,1) atoms. In the second Li site, Li(1) is bonded in a 14-coordinate geometry to three Li(1,1); two equivalent Rh(2); six equivalent Rh(1); and three B(1,1,1) atoms. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a 8-coordinate geometry to six equivalent Li(1) and four B(1,1) atoms. In the second Rh site, Rh(2) is bonded in a body-centered cubic geometry to four Li(1,1) and four B(1,1) atoms. There are three inequivalent B sites. In the first B site, B(1) is bonded in a 8-coordinate geometry to three equivalent Li(1), two equivalent Rh(2), and four equivalent Rh(1) atoms. In the second B site, B(1) is bonded in a 8-coordinate geometry to three Li(1,1); two equivalent Rh(2); and four equivalent Rh(1) atoms. In the third B site, B(1) is bonded in a 8-coordinate geometry to three Li(1,1); two equivalent Rh(2); and four equivalent Rh(1) atoms. is represented by the CIF card [CIF]
data_Li2B2Rh3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.831
_cell_length_b   5.758
_cell_length_c   9.449
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   154.016
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.500  0.340  0.074  1.0
  Li  Li1  1  0.500  0.660  0.926  1.0
  Li  Li2  1  0.500  0.160  0.574  1.0
  Li  Li3  1  0.500  0.840  0.426  1.0
  B  B4  1  0.500  0.063  0.831  1.0
  B  B5  1  0.500  0.563  0.669  1.0
  B  B6  1  0.500  0.437  0.331  1.0
  B  B7  1  0.500  0.937  0.169  1.0
  Rh  Rh8  1  0.000  0.334  0.779  1.0
  Rh  Rh9  1  0.000  0.166  0.279  1.0
  Rh  Rh10  1  0.000  0.500  0.500  1.0
  Rh  Rh11  1  0.000  0.666  0.221  1.0
  Rh  Rh12  1  0.000  0.834  0.721  1.0
  Rh  Rh13  1  0.000  0.000  0.000  1.0
[/CIF]
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The structure described by Li2Rh3B2 crystallizes in the orthorhombic Pbam space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded in a 14-coordinate geometry to three equivalent Li(1); two equivalent Rh(2); six equivalent Rh(1); and three B(1,1) atoms. In the second Li site, Li(1) is bonded in a 14-coordinate geometry to three Li(1,1); two equivalent Rh(2); six equivalent Rh(1); and three B(1,1,1) atoms. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a 8-coordinate geometry to six equivalent Li(1) and four B(1,1) atoms. In the second Rh site, Rh(2) is bonded in a body-centered cubic geometry to four Li(1,1) and four B(1,1) atoms. There are three inequivalent B sites. In the first B site, B(1) is bonded in a 8-coordinate geometry to three equivalent Li(1), two equivalent Rh(2), and four equivalent Rh(1) atoms. In the second B site, B(1) is bonded in a 8-coordinate geometry to three Li(1,1); two equivalent Rh(2); and four equivalent Rh(1) atoms. In the third B site, B(1) is bonded in a 8-coordinate geometry to three Li(1,1); two equivalent Rh(2); and four equivalent Rh(1) atoms. is represented by the CIF card [CIF]
data_Li2B2Rh3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.831
_cell_length_b   5.758
_cell_length_c   9.449
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   154.016
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.500  0.340  0.074  1.0
  Li  Li1  1  0.500  0.660  0.926  1.0
  Li  Li2  1  0.500  0.160  0.574  1.0
  Li  Li3  1  0.500  0.840  0.426  1.0
  B  B4  1  0.500  0.063  0.831  1.0
  B  B5  1  0.500  0.563  0.669  1.0
  B  B6  1  0.500  0.437  0.331  1.0
  B  B7  1  0.500  0.937  0.169  1.0
  Rh  Rh8  1  0.000  0.334  0.779  1.0
  Rh  Rh9  1  0.000  0.166  0.279  1.0
  Rh  Rh10  1  0.000  0.500  0.500  1.0
  Rh  Rh11  1  0.000  0.666  0.221  1.0
  Rh  Rh12  1  0.000  0.834  0.721  1.0
  Rh  Rh13  1  0.000  0.000  0.000  1.0
[/CIF]
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