The material structure described by BaBi5 crystallizes in the monoclinic P2/m space group. Ba(1) is bonded to four equivalent Bi(1), four equivalent Bi(2), and four equivalent Bi(3) atoms to form a mixture of corner and face-sharing BaBi12 cuboctahedra. There are three inequivalent Bi sites. In the first Bi site, Bi(1) is bonded in a 6-coordinate geometry to two equivalent Ba(1), one Bi(1), one Bi(3), and two equivalent Bi(2) atoms. In the second Bi site, Bi(2) is bonded in a 5-coordinate geometry to two equivalent Ba(1), one Bi(2), and two equivalent Bi(1) atoms. In the third Bi site, Bi(3) is bonded in a distorted square co-planar geometry to four equivalent Ba(1) and two equivalent Bi(1) atoms. is represented by the CIF card [CIF]
data_BaBi5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.907
_cell_length_b   9.103
_cell_length_c   5.113
_cell_angle_alpha   68.111
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   211.905
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.000  0.000  0.000  1.0
  Bi  Bi1  1  0.500  0.327  0.711  1.0
  Bi  Bi2  1  0.000  0.322  0.281  1.0
  Bi  Bi3  1  0.500  0.673  0.289  1.0
  Bi  Bi4  1  0.000  0.678  0.719  1.0
  Bi  Bi5  1  0.500  0.000  0.500  1.0
[/CIF]
.
The material structure described by BaBi5 crystallizes in the monoclinic P2/m space group. Ba(1) is bonded to four equivalent Bi(1), four equivalent Bi(2), and four equivalent Bi(3) atoms to form a mixture of corner and face-sharing BaBi12 cuboctahedra. There are three inequivalent Bi sites. In the first Bi site, Bi(1) is bonded in a 6-coordinate geometry to two equivalent Ba(1), one Bi(1), one Bi(3), and two equivalent Bi(2) atoms. In the second Bi site, Bi(2) is bonded in a 5-coordinate geometry to two equivalent Ba(1), one Bi(2), and two equivalent Bi(1) atoms. In the third Bi site, Bi(3) is bonded in a distorted square co-planar geometry to four equivalent Ba(1) and two equivalent Bi(1) atoms. is represented by the CIF card [CIF]
data_BaBi5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.907
_cell_length_b   9.103
_cell_length_c   5.113
_cell_angle_alpha   68.111
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   211.905
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.000  0.000  0.000  1.0
  Bi  Bi1  1  0.500  0.327  0.711  1.0
  Bi  Bi2  1  0.000  0.322  0.281  1.0
  Bi  Bi3  1  0.500  0.673  0.289  1.0
  Bi  Bi4  1  0.000  0.678  0.719  1.0
  Bi  Bi5  1  0.500  0.000  0.500  1.0
[/CIF]
.