The crystal structure described by Li12V3CoP4(CO7)4 crystallizes in the monoclinic Pm space group. There are eight inequivalent Li sites. In the first Li site, Li(1) is bonded in a 4-coordinate geometry to one O(2), one O(24), and two equivalent O(7) atoms. In the second Li site, Li(2) is bonded in a 4-coordinate geometry to one O(22), one O(5), and two equivalent O(8) atoms. In the third Li site, Li(3) is bonded to one O(10), one O(2), one O(4), one O(8), and one O(9) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  an edgeedge with one V(2)O6 octahedra, and edges with two equivalent Li(3)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 67-88°. In the fourth Li site, Li(4) is bonded to one O(11), one O(12), one O(5), one O(6), and one O(7) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  an edgeedge with one V(1)O6 octahedra, and edges with two equivalent Li(4)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 66-88°. In the fifth Li site, Li(5) is bonded to one O(13), one O(14), one O(18), one O(19), and one O(20) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  an edgeedge with one Co(1)O6 octahedra, and edges with two equivalent Li(5)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 67-87°. In the sixth Li site, Li(6) is bonded to one O(15), one O(16), one O(17), one O(21), and one O(23) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  an edgeedge with one V(3)O6 octahedra, and edges with two equivalent Li(6)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 67-87°. In the seventh Li site, Li(7) is bonded in a 4-coordinate geometry to one O(20), one O(3), and two equivalent O(17) atoms. In the eighth Li site, Li(8) is bonded in a 4-coordinate geometry to one O(1), one O(23), and two equivalent O(18) atoms. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(11), one O(13), one O(4), and two equivalent O(7) atoms to form VO6 octahedra that share  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent Li(3)O5 trigonal bipyramids, corners with two equivalent Li(5)O5 trigonal bipyramids, and edges with two equivalent Li(4)O5 trigonal bipyramids. In the second V site, V(2) is bonded to one O(15), one O(3), one O(6), one O(9), and two equivalent O(8) atoms to form VO6 octahedra that share  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, corners with two equivalent Li(4)O5 trigonal bipyramids, corners with two equivalent Li(6)O5 trigonal bipyramids, and edges with two equivalent Li(3)O5 trigonal bipyramids. In the third V site, V(3) is bonded to one O(10), one O(16), one O(19), one O(22), and two equivalent O(17) atoms to form VO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, corners with two equivalent P(3)O4 tetrahedra, corners with two equivalent Li(3)O5 trigonal bipyramids, corners with two equivalent Li(5)O5 trigonal bipyramids, and edges with two equivalent Li(6)O5 trigonal bipyramids. Co(1) is bonded to one O(12), one O(14), one O(21), one O(24), and two equivalent O(18) atoms to form distorted CoO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, corners with two equivalent P(4)O4 tetrahedra, corners with two equivalent Li(4)O5 trigonal bipyramids, corners with two equivalent Li(6)O5 trigonal bipyramids, and edges with two equivalent Li(5)O5 trigonal bipyramids. There are four inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one O(1), one O(20), and one O(4) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one O(23), one O(3), and one O(6) atom. In the third C site, C(3) is bonded in a trigonal planar geometry to one O(19), one O(2), and one O(22) atom. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one O(21), one O(24), and one O(5) atom. There are four inequivalent P sites. In the first P site, P(1) is bonded to one O(10), one O(14), and two equivalent O(7) atoms to form PO4 tetrahedra that share  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra, corners with two equivalent V(1)O6 octahedra, corners with two equivalent Li(3)O5 trigonal bipyramids, corners with two equivalent Li(4)O5 trigonal bipyramids, and corners with two equivalent Li(5)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 44-62°. In the second P site, P(2) is bonded to one O(12), one O(16), and two equivalent O(8) atoms to form PO4 tetrahedra that share  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent Li(3)O5 trigonal bipyramids, corners with two equivalent Li(4)O5 trigonal bipyramids, and corners with two equivalent Li(6)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 44-61°. In the third P site, P(3) is bonded to one O(13), one O(9), and two equivalent O(17) atoms to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra, corners with two equivalent V(3)O6 octahedra, corners with two equivalent Li(3)O5 trigonal bipyramids, corners with two equivalent Li(5)O5 trigonal bipyramids, and corners with two equivalent Li(6)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 44-62°. In the fourth P site, P(4) is bonded to one O(11), one O(15), and two equivalent O(18) atoms to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Li(4)O5 trigonal bipyramids, corners with two equivalent Li(5)O5 trigonal bipyramids, and corners with two equivalent Li(6)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 44-62°. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Li(8), one V(1), and one C(1) atom. In the second O site, O(2) is bonded to one Li(1), two equivalent Li(3), and one C(3) atom to form a mixture of corner and edge-sharing OLi3C tetrahedra. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Li(7), one V(2), and one C(2) atom. In the fourth O site, O(4) is bonded in a 1-coordinate geometry to two equivalent Li(3), one V(1), and one C(1) atom. In the fifth O site, O(5) is bonded to one Li(2), two equivalent Li(4), and one C(4) atom to form OLi3C tetrahedra that share corners with two equivalent O(11)Li2VP trigonal pyramids, corners with two equivalent O(7)Li2VP trigonal pyramids, corners with two equivalent O(8)Li2VP trigonal pyramids, and  an edgeedge with one O(12)Li2CoP tetrahedra. In the sixth O site, O(6) is bonded in a 1-coordinate geometry to two equivalent Li(4), one V(2), and one C(2) atom. In the seventh O site, O(7) is bonded to one Li(1), one Li(4), one V(1), and one P(1) atom to form distorted OLi2VP trigonal pyramids that share  a cornercorner with one O(12)Li2CoP tetrahedra,  a cornercorner with one O(10)Li2VP tetrahedra,  a cornercorner with one O(13)Li2VP tetrahedra,  a cornercorner with one O(2)Li3C tetrahedra,  a cornercorner with one O(5)Li3C tetrahedra,  a cornercorner with one O(14)Li2CoP trigonal pyramid,  a cornercorner with one O(7)Li2VP trigonal pyramid,  an edgeedge with one O(11)Li2VP trigonal pyramid, and  an edgeedge with one O(7)Li2VP trigonal pyramid. In the eighth O site, O(8) is bonded to one Li(2), one Li(3), one V(2), and one P(2) atom to form distorted OLi2VP trigonal pyramids that share  a cornercorner with one O(12)Li2CoP tetrahedra,  a cornercorner with one O(10)Li2VP tetrahedra,  a cornercorner with one O(15)Li2VP tetrahedra,  a cornercorner with one O(2)Li3C tetrahedra,  a cornercorner with one O(5)Li3C tetrahedra,  a cornercorner with one O(16)Li2VP trigonal pyramid,  a cornercorner with one O(8)Li2VP trigonal pyramid,  an edgeedge with one O(8)Li2VP trigonal pyramid, and  an edgeedge with one O(9)Li2VP trigonal pyramid. In the ninth O site, O(9) is bonded to two equivalent Li(3), one V(2), and one P(3) atom to form distorted OLi2VP trigonal pyramids that share  a cornercorner with one O(13)Li2VP tetrahedra,  a cornercorner with one O(15)Li2VP tetrahedra, corners with two equivalent O(10)Li2VP tetrahedra, corners with two equivalent O(2)Li3C tetrahedra, corners with two equivalent O(17)Li2VP trigonal pyramids, and edges with two equivalent O(8)Li2VP trigonal pyramids. In the tenth O site, O(10) is bonded to two equivalent Li(3), one V(3), and one P(1) atom to form OLi2VP tetrahedra that share  a cornercorner with one O(14)Li2CoP trigonal pyramid,  a cornercorner with one O(16)Li2VP trigonal pyramid, corners with two equivalent O(17)Li2VP trigonal pyramids, corners with two equivalent O(7)Li2VP trigonal pyramids, corners with two equivalent O(8)Li2VP trigonal pyramids, corners with two equivalent O(9)Li2VP trigonal pyramids, and  an edgeedge with one O(2)Li3C tetrahedra. In the eleventh O site, O(11) is bonded to two equivalent Li(4), one V(1), and one P(4) atom to form distorted OLi2VP trigonal pyramids that share  a cornercorner with one O(13)Li2VP tetrahedra,  a cornercorner with one O(15)Li2VP tetrahedra, corners with two equivalent O(12)Li2CoP tetrahedra, corners with two equivalent O(5)Li3C tetrahedra, corners with two equivalent O(18)Li2CoP trigonal pyramids, and edges with two equivalent O(7)Li2VP trigonal pyramids. In the twelfth O site, O(12) is bonded to two equivalent Li(4), one Co(1), and one P(2) atom to form distorted OLi2CoP tetrahedra that share  a cornercorner with one O(14)Li2CoP trigonal pyramid,  a cornercorner with one O(16)Li2VP trigonal pyramid, corners with two equivalent O(18)Li2CoP trigonal pyramids, corners with two equivalent O(11)Li2VP trigonal pyramids, corners with two equivalent O(7)Li2VP trigonal pyramids, corners with two equivalent O(8)Li2VP trigonal pyramids, and  an edgeedge with one O(5)Li3C tetrahedra. In the thirteenth O site, O(13) is bonded to two equivalent Li(5), one V(1), and one P(3) atom to form OLi2VP tetrahedra that share  a cornercorner with one O(11)Li2VP trigonal pyramid,  a cornercorner with one O(9)Li2VP trigonal pyramid, corners with two equivalent O(14)Li2CoP trigonal pyramids, corners with two equivalent O(18)Li2CoP trigonal pyramids, corners with two equivalent O(17)Li2VP trigonal pyramids, corners with two equivalent O(7)Li2VP trigonal pyramids, and  an edgeedge with one O(20)Li3C tetrahedra. In the fourteenth O site, O(14) is bonded to two equivalent Li(5), one Co(1), and one P(1) atom to form distorted OLi2CoP trigonal pyramids that share  a cornercorner with one O(12)Li2CoP tetrahedra,  a cornercorner with one O(10)Li2VP tetrahedra, corners with two equivalent O(13)Li2VP tetrahedra, corners with two equivalent O(20)Li3C tetrahedra, corners with two equivalent O(7)Li2VP trigonal pyramids, and edges with two equivalent O(18)Li2CoP trigonal pyramids. In the fifteenth O site, O(15) is bonded to two equivalent Li(6), one V(2), and one P(4) atom to form OLi2VP tetrahedra that share  a cornercorner with one O(11)Li2VP trigonal pyramid,  a cornercorner with one O(9)Li2VP trigonal pyramid, corners with two equivalent O(18)Li2CoP trigonal pyramids, corners with two equivalent O(16)Li2VP trigonal pyramids, corners with two equivalent O(17)Li2VP trigonal pyramids, corners with two equivalent O(8)Li2VP trigonal pyramids, and  an edgeedge with one O(23)Li3C tetrahedra. In the sixteenth O site, O(16) is bonded to two equivalent Li(6), one V(3), and one P(2) atom to form distorted OLi2VP trigonal pyramids that share  a cornercorner with one O(12)Li2CoP tetrahedra,  a cornercorner with one O(10)Li2VP tetrahedra, corners with two equivalent O(15)Li2VP tetrahedra, corners with two equivalent O(23)Li3C tetrahedra, corners with two equivalent O(8)Li2VP trigonal pyramids, and edges with two equivalent O(17)Li2VP trigonal pyramids. In the seventeenth O site, O(17) is bonded to one Li(6), one Li(7), one V(3), and one P(3) atom to form distorted OLi2VP trigonal pyramids that share  a cornercorner with one O(10)Li2VP tetrahedra,  a cornercorner with one O(13)Li2VP tetrahedra,  a cornercorner with one O(15)Li2VP tetrahedra,  a cornercorner with one O(20)Li3C tetrahedra,  a cornercorner with one O(23)Li3C tetrahedra,  a cornercorner with one O(17)Li2VP trigonal pyramid,  a cornercorner with one O(9)Li2VP trigonal pyramid,  an edgeedge with one O(16)Li2VP trigonal pyramid, and  an edgeedge with one O(17)Li2VP trigonal pyramid. In the eighteenth O site, O(18) is bonded to one Li(5), one Li(8), one Co(1), and one P(4) atom to form distorted OLi2CoP trigonal pyramids that share  a cornercorner with one O(12)Li2CoP tetrahedra,  a cornercorner with one O(13)Li2VP tetrahedra,  a cornercorner with one O(15)Li2VP tetrahedra,  a cornercorner with one O(20)Li3C tetrahedra,  a cornercorner with one O(23)Li3C tetrahedra,  a cornercorner with one O(18)Li2CoP trigonal pyramid,  a cornercorner with one O(11)Li2VP trigonal pyramid,  an edgeedge with one O(14)Li2CoP trigonal pyramid, and  an edgeedge with one O(18)Li2CoP trigonal pyramid. In the nineteenth O site, O(19) is bonded in a 1-coordinate geometry to two equivalent Li(5), one V(3), and one C(3) atom. In the twentieth O site, O(20) is bonded to one Li(7), two equivalent Li(5), and one C(1) atom to form OLi3C tetrahedra that share corners with two equivalent O(14)Li2CoP trigonal pyramids, corners with two equivalent O(18)Li2CoP trigonal pyramids, corners with two equivalent O(17)Li2VP trigonal pyramids, and  an edgeedge with one O(13)Li2VP tetrahedra. In the twenty-first O site, O(21) is bonded in a 4-coordinate geometry to two equivalent Li(6), one Co(1), and one C(4) atom. In the twenty-second O site, O(22) is bonded in a 3-coordinate geometry to one Li(2), one V(3), and one C(3) atom. In the twenty-third O site, O(23) is bonded to one Li(8), two equivalent Li(6), and one C(2) atom to form OLi3C tetrahedra that share corners with two equivalent O(18)Li2CoP trigonal pyramids, corners with two equivalent O(16)Li2VP trigonal pyramids, corners with two equivalent O(17)Li2VP trigonal pyramids, and  an edgeedge with one O(15)Li2VP tetrahedra. In the twenty-fourth O site, O(24) is bonded in a 3-coordinate geometry to one Li(1), one Co(1), and one C(4) atom. is represented by the CIF file [CIF]
data_Li12V3CoP4(CO7)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.595
_cell_length_b   8.482
_cell_length_c   10.008
_cell_angle_alpha   84.634
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   557.337
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.000  0.901  0.616  1.0
  Li  Li1  1  0.000  0.903  0.116  1.0
  Li  Li2  1  0.224  0.720  0.875  1.0
  Li  Li3  1  0.776  0.720  0.875  1.0
  Li  Li4  1  0.222  0.721  0.374  1.0
  Li  Li5  1  0.778  0.721  0.374  1.0
  Li  Li6  1  0.728  0.278  0.623  1.0
  Li  Li7  1  0.272  0.278  0.623  1.0
  Li  Li8  1  0.727  0.279  0.128  1.0
  Li  Li9  1  0.273  0.279  0.128  1.0
  Li  Li10  1  0.500  0.098  0.885  1.0
  Li  Li11  1  0.500  0.097  0.385  1.0
  V  V12  1  0.500  0.671  0.604  1.0
  V  V13  1  0.500  0.671  0.103  1.0
  V  V14  1  0.000  0.329  0.896  1.0
  Co  Co15  1  0.000  0.331  0.395  1.0
  P  P16  1  0.000  0.588  0.639  1.0
  P  P17  1  0.000  0.589  0.139  1.0
  P  P18  1  0.500  0.410  0.861  1.0
  P  P19  1  0.500  0.411  0.361  1.0
  C  C20  1  0.500  0.965  0.652  1.0
  C  C21  1  0.500  0.965  0.152  1.0
  C  C22  1  0.000  0.034  0.848  1.0
  C  C23  1  0.000  0.037  0.349  1.0
  O  O24  1  0.500  0.927  0.530  1.0
  O  O25  1  0.000  0.888  0.820  1.0
  O  O26  1  0.500  0.927  0.030  1.0
  O  O27  1  0.500  0.850  0.748  1.0
  O  O28  1  0.000  0.891  0.319  1.0
  O  O29  1  0.500  0.850  0.248  1.0
  O  O30  1  0.183  0.692  0.587  1.0
  O  O31  1  0.817  0.692  0.587  1.0
  O  O32  1  0.183  0.693  0.086  1.0
  O  O33  1  0.817  0.693  0.086  1.0
  O  O34  1  0.500  0.577  0.911  1.0
  O  O35  1  0.000  0.568  0.796  1.0
  O  O36  1  0.500  0.577  0.412  1.0
  O  O37  1  0.000  0.567  0.296  1.0
  O  O38  1  0.500  0.432  0.704  1.0
  O  O39  1  0.000  0.422  0.587  1.0
  O  O40  1  0.500  0.431  0.204  1.0
  O  O41  1  0.000  0.423  0.089  1.0
  O  O42  1  0.317  0.307  0.913  1.0
  O  O43  1  0.683  0.307  0.913  1.0
  O  O44  1  0.686  0.309  0.412  1.0
  O  O45  1  0.314  0.309  0.412  1.0
  O  O46  1  0.000  0.149  0.752  1.0
  O  O47  1  0.500  0.111  0.680  1.0
  O  O48  1  0.000  0.154  0.255  1.0
  O  O49  1  0.000  0.072  0.971  1.0
  O  O50  1  0.500  0.111  0.180  1.0
  O  O51  1  0.000  0.072  0.472  1.0
[/CIF]
.
The crystal structure described by Li12V3CoP4(CO7)4 crystallizes in the monoclinic Pm space group. There are eight inequivalent Li sites. In the first Li site, Li(1) is bonded in a 4-coordinate geometry to one O(2), one O(24), and two equivalent O(7) atoms. In the second Li site, Li(2) is bonded in a 4-coordinate geometry to one O(22), one O(5), and two equivalent O(8) atoms. In the third Li site, Li(3) is bonded to one O(10), one O(2), one O(4), one O(8), and one O(9) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  an edgeedge with one V(2)O6 octahedra, and edges with two equivalent Li(3)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 67-88°. In the fourth Li site, Li(4) is bonded to one O(11), one O(12), one O(5), one O(6), and one O(7) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  an edgeedge with one V(1)O6 octahedra, and edges with two equivalent Li(4)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 66-88°. In the fifth Li site, Li(5) is bonded to one O(13), one O(14), one O(18), one O(19), and one O(20) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  an edgeedge with one Co(1)O6 octahedra, and edges with two equivalent Li(5)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 67-87°. In the sixth Li site, Li(6) is bonded to one O(15), one O(16), one O(17), one O(21), and one O(23) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  an edgeedge with one V(3)O6 octahedra, and edges with two equivalent Li(6)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 67-87°. In the seventh Li site, Li(7) is bonded in a 4-coordinate geometry to one O(20), one O(3), and two equivalent O(17) atoms. In the eighth Li site, Li(8) is bonded in a 4-coordinate geometry to one O(1), one O(23), and two equivalent O(18) atoms. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(11), one O(13), one O(4), and two equivalent O(7) atoms to form VO6 octahedra that share  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent Li(3)O5 trigonal bipyramids, corners with two equivalent Li(5)O5 trigonal bipyramids, and edges with two equivalent Li(4)O5 trigonal bipyramids. In the second V site, V(2) is bonded to one O(15), one O(3), one O(6), one O(9), and two equivalent O(8) atoms to form VO6 octahedra that share  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, corners with two equivalent Li(4)O5 trigonal bipyramids, corners with two equivalent Li(6)O5 trigonal bipyramids, and edges with two equivalent Li(3)O5 trigonal bipyramids. In the third V site, V(3) is bonded to one O(10), one O(16), one O(19), one O(22), and two equivalent O(17) atoms to form VO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, corners with two equivalent P(3)O4 tetrahedra, corners with two equivalent Li(3)O5 trigonal bipyramids, corners with two equivalent Li(5)O5 trigonal bipyramids, and edges with two equivalent Li(6)O5 trigonal bipyramids. Co(1) is bonded to one O(12), one O(14), one O(21), one O(24), and two equivalent O(18) atoms to form distorted CoO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, corners with two equivalent P(4)O4 tetrahedra, corners with two equivalent Li(4)O5 trigonal bipyramids, corners with two equivalent Li(6)O5 trigonal bipyramids, and edges with two equivalent Li(5)O5 trigonal bipyramids. There are four inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one O(1), one O(20), and one O(4) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one O(23), one O(3), and one O(6) atom. In the third C site, C(3) is bonded in a trigonal planar geometry to one O(19), one O(2), and one O(22) atom. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one O(21), one O(24), and one O(5) atom. There are four inequivalent P sites. In the first P site, P(1) is bonded to one O(10), one O(14), and two equivalent O(7) atoms to form PO4 tetrahedra that share  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra, corners with two equivalent V(1)O6 octahedra, corners with two equivalent Li(3)O5 trigonal bipyramids, corners with two equivalent Li(4)O5 trigonal bipyramids, and corners with two equivalent Li(5)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 44-62°. In the second P site, P(2) is bonded to one O(12), one O(16), and two equivalent O(8) atoms to form PO4 tetrahedra that share  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent Li(3)O5 trigonal bipyramids, corners with two equivalent Li(4)O5 trigonal bipyramids, and corners with two equivalent Li(6)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 44-61°. In the third P site, P(3) is bonded to one O(13), one O(9), and two equivalent O(17) atoms to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra, corners with two equivalent V(3)O6 octahedra, corners with two equivalent Li(3)O5 trigonal bipyramids, corners with two equivalent Li(5)O5 trigonal bipyramids, and corners with two equivalent Li(6)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 44-62°. In the fourth P site, P(4) is bonded to one O(11), one O(15), and two equivalent O(18) atoms to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Li(4)O5 trigonal bipyramids, corners with two equivalent Li(5)O5 trigonal bipyramids, and corners with two equivalent Li(6)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 44-62°. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Li(8), one V(1), and one C(1) atom. In the second O site, O(2) is bonded to one Li(1), two equivalent Li(3), and one C(3) atom to form a mixture of corner and edge-sharing OLi3C tetrahedra. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Li(7), one V(2), and one C(2) atom. In the fourth O site, O(4) is bonded in a 1-coordinate geometry to two equivalent Li(3), one V(1), and one C(1) atom. In the fifth O site, O(5) is bonded to one Li(2), two equivalent Li(4), and one C(4) atom to form OLi3C tetrahedra that share corners with two equivalent O(11)Li2VP trigonal pyramids, corners with two equivalent O(7)Li2VP trigonal pyramids, corners with two equivalent O(8)Li2VP trigonal pyramids, and  an edgeedge with one O(12)Li2CoP tetrahedra. In the sixth O site, O(6) is bonded in a 1-coordinate geometry to two equivalent Li(4), one V(2), and one C(2) atom. In the seventh O site, O(7) is bonded to one Li(1), one Li(4), one V(1), and one P(1) atom to form distorted OLi2VP trigonal pyramids that share  a cornercorner with one O(12)Li2CoP tetrahedra,  a cornercorner with one O(10)Li2VP tetrahedra,  a cornercorner with one O(13)Li2VP tetrahedra,  a cornercorner with one O(2)Li3C tetrahedra,  a cornercorner with one O(5)Li3C tetrahedra,  a cornercorner with one O(14)Li2CoP trigonal pyramid,  a cornercorner with one O(7)Li2VP trigonal pyramid,  an edgeedge with one O(11)Li2VP trigonal pyramid, and  an edgeedge with one O(7)Li2VP trigonal pyramid. In the eighth O site, O(8) is bonded to one Li(2), one Li(3), one V(2), and one P(2) atom to form distorted OLi2VP trigonal pyramids that share  a cornercorner with one O(12)Li2CoP tetrahedra,  a cornercorner with one O(10)Li2VP tetrahedra,  a cornercorner with one O(15)Li2VP tetrahedra,  a cornercorner with one O(2)Li3C tetrahedra,  a cornercorner with one O(5)Li3C tetrahedra,  a cornercorner with one O(16)Li2VP trigonal pyramid,  a cornercorner with one O(8)Li2VP trigonal pyramid,  an edgeedge with one O(8)Li2VP trigonal pyramid, and  an edgeedge with one O(9)Li2VP trigonal pyramid. In the ninth O site, O(9) is bonded to two equivalent Li(3), one V(2), and one P(3) atom to form distorted OLi2VP trigonal pyramids that share  a cornercorner with one O(13)Li2VP tetrahedra,  a cornercorner with one O(15)Li2VP tetrahedra, corners with two equivalent O(10)Li2VP tetrahedra, corners with two equivalent O(2)Li3C tetrahedra, corners with two equivalent O(17)Li2VP trigonal pyramids, and edges with two equivalent O(8)Li2VP trigonal pyramids. In the tenth O site, O(10) is bonded to two equivalent Li(3), one V(3), and one P(1) atom to form OLi2VP tetrahedra that share  a cornercorner with one O(14)Li2CoP trigonal pyramid,  a cornercorner with one O(16)Li2VP trigonal pyramid, corners with two equivalent O(17)Li2VP trigonal pyramids, corners with two equivalent O(7)Li2VP trigonal pyramids, corners with two equivalent O(8)Li2VP trigonal pyramids, corners with two equivalent O(9)Li2VP trigonal pyramids, and  an edgeedge with one O(2)Li3C tetrahedra. In the eleventh O site, O(11) is bonded to two equivalent Li(4), one V(1), and one P(4) atom to form distorted OLi2VP trigonal pyramids that share  a cornercorner with one O(13)Li2VP tetrahedra,  a cornercorner with one O(15)Li2VP tetrahedra, corners with two equivalent O(12)Li2CoP tetrahedra, corners with two equivalent O(5)Li3C tetrahedra, corners with two equivalent O(18)Li2CoP trigonal pyramids, and edges with two equivalent O(7)Li2VP trigonal pyramids. In the twelfth O site, O(12) is bonded to two equivalent Li(4), one Co(1), and one P(2) atom to form distorted OLi2CoP tetrahedra that share  a cornercorner with one O(14)Li2CoP trigonal pyramid,  a cornercorner with one O(16)Li2VP trigonal pyramid, corners with two equivalent O(18)Li2CoP trigonal pyramids, corners with two equivalent O(11)Li2VP trigonal pyramids, corners with two equivalent O(7)Li2VP trigonal pyramids, corners with two equivalent O(8)Li2VP trigonal pyramids, and  an edgeedge with one O(5)Li3C tetrahedra. In the thirteenth O site, O(13) is bonded to two equivalent Li(5), one V(1), and one P(3) atom to form OLi2VP tetrahedra that share  a cornercorner with one O(11)Li2VP trigonal pyramid,  a cornercorner with one O(9)Li2VP trigonal pyramid, corners with two equivalent O(14)Li2CoP trigonal pyramids, corners with two equivalent O(18)Li2CoP trigonal pyramids, corners with two equivalent O(17)Li2VP trigonal pyramids, corners with two equivalent O(7)Li2VP trigonal pyramids, and  an edgeedge with one O(20)Li3C tetrahedra. In the fourteenth O site, O(14) is bonded to two equivalent Li(5), one Co(1), and one P(1) atom to form distorted OLi2CoP trigonal pyramids that share  a cornercorner with one O(12)Li2CoP tetrahedra,  a cornercorner with one O(10)Li2VP tetrahedra, corners with two equivalent O(13)Li2VP tetrahedra, corners with two equivalent O(20)Li3C tetrahedra, corners with two equivalent O(7)Li2VP trigonal pyramids, and edges with two equivalent O(18)Li2CoP trigonal pyramids. In the fifteenth O site, O(15) is bonded to two equivalent Li(6), one V(2), and one P(4) atom to form OLi2VP tetrahedra that share  a cornercorner with one O(11)Li2VP trigonal pyramid,  a cornercorner with one O(9)Li2VP trigonal pyramid, corners with two equivalent O(18)Li2CoP trigonal pyramids, corners with two equivalent O(16)Li2VP trigonal pyramids, corners with two equivalent O(17)Li2VP trigonal pyramids, corners with two equivalent O(8)Li2VP trigonal pyramids, and  an edgeedge with one O(23)Li3C tetrahedra. In the sixteenth O site, O(16) is bonded to two equivalent Li(6), one V(3), and one P(2) atom to form distorted OLi2VP trigonal pyramids that share  a cornercorner with one O(12)Li2CoP tetrahedra,  a cornercorner with one O(10)Li2VP tetrahedra, corners with two equivalent O(15)Li2VP tetrahedra, corners with two equivalent O(23)Li3C tetrahedra, corners with two equivalent O(8)Li2VP trigonal pyramids, and edges with two equivalent O(17)Li2VP trigonal pyramids. In the seventeenth O site, O(17) is bonded to one Li(6), one Li(7), one V(3), and one P(3) atom to form distorted OLi2VP trigonal pyramids that share  a cornercorner with one O(10)Li2VP tetrahedra,  a cornercorner with one O(13)Li2VP tetrahedra,  a cornercorner with one O(15)Li2VP tetrahedra,  a cornercorner with one O(20)Li3C tetrahedra,  a cornercorner with one O(23)Li3C tetrahedra,  a cornercorner with one O(17)Li2VP trigonal pyramid,  a cornercorner with one O(9)Li2VP trigonal pyramid,  an edgeedge with one O(16)Li2VP trigonal pyramid, and  an edgeedge with one O(17)Li2VP trigonal pyramid. In the eighteenth O site, O(18) is bonded to one Li(5), one Li(8), one Co(1), and one P(4) atom to form distorted OLi2CoP trigonal pyramids that share  a cornercorner with one O(12)Li2CoP tetrahedra,  a cornercorner with one O(13)Li2VP tetrahedra,  a cornercorner with one O(15)Li2VP tetrahedra,  a cornercorner with one O(20)Li3C tetrahedra,  a cornercorner with one O(23)Li3C tetrahedra,  a cornercorner with one O(18)Li2CoP trigonal pyramid,  a cornercorner with one O(11)Li2VP trigonal pyramid,  an edgeedge with one O(14)Li2CoP trigonal pyramid, and  an edgeedge with one O(18)Li2CoP trigonal pyramid. In the nineteenth O site, O(19) is bonded in a 1-coordinate geometry to two equivalent Li(5), one V(3), and one C(3) atom. In the twentieth O site, O(20) is bonded to one Li(7), two equivalent Li(5), and one C(1) atom to form OLi3C tetrahedra that share corners with two equivalent O(14)Li2CoP trigonal pyramids, corners with two equivalent O(18)Li2CoP trigonal pyramids, corners with two equivalent O(17)Li2VP trigonal pyramids, and  an edgeedge with one O(13)Li2VP tetrahedra. In the twenty-first O site, O(21) is bonded in a 4-coordinate geometry to two equivalent Li(6), one Co(1), and one C(4) atom. In the twenty-second O site, O(22) is bonded in a 3-coordinate geometry to one Li(2), one V(3), and one C(3) atom. In the twenty-third O site, O(23) is bonded to one Li(8), two equivalent Li(6), and one C(2) atom to form OLi3C tetrahedra that share corners with two equivalent O(18)Li2CoP trigonal pyramids, corners with two equivalent O(16)Li2VP trigonal pyramids, corners with two equivalent O(17)Li2VP trigonal pyramids, and  an edgeedge with one O(15)Li2VP tetrahedra. In the twenty-fourth O site, O(24) is bonded in a 3-coordinate geometry to one Li(1), one Co(1), and one C(4) atom. is represented by the CIF file [CIF]
data_Li12V3CoP4(CO7)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.595
_cell_length_b   8.482
_cell_length_c   10.008
_cell_angle_alpha   84.634
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   557.337
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.000  0.901  0.616  1.0
  Li  Li1  1  0.000  0.903  0.116  1.0
  Li  Li2  1  0.224  0.720  0.875  1.0
  Li  Li3  1  0.776  0.720  0.875  1.0
  Li  Li4  1  0.222  0.721  0.374  1.0
  Li  Li5  1  0.778  0.721  0.374  1.0
  Li  Li6  1  0.728  0.278  0.623  1.0
  Li  Li7  1  0.272  0.278  0.623  1.0
  Li  Li8  1  0.727  0.279  0.128  1.0
  Li  Li9  1  0.273  0.279  0.128  1.0
  Li  Li10  1  0.500  0.098  0.885  1.0
  Li  Li11  1  0.500  0.097  0.385  1.0
  V  V12  1  0.500  0.671  0.604  1.0
  V  V13  1  0.500  0.671  0.103  1.0
  V  V14  1  0.000  0.329  0.896  1.0
  Co  Co15  1  0.000  0.331  0.395  1.0
  P  P16  1  0.000  0.588  0.639  1.0
  P  P17  1  0.000  0.589  0.139  1.0
  P  P18  1  0.500  0.410  0.861  1.0
  P  P19  1  0.500  0.411  0.361  1.0
  C  C20  1  0.500  0.965  0.652  1.0
  C  C21  1  0.500  0.965  0.152  1.0
  C  C22  1  0.000  0.034  0.848  1.0
  C  C23  1  0.000  0.037  0.349  1.0
  O  O24  1  0.500  0.927  0.530  1.0
  O  O25  1  0.000  0.888  0.820  1.0
  O  O26  1  0.500  0.927  0.030  1.0
  O  O27  1  0.500  0.850  0.748  1.0
  O  O28  1  0.000  0.891  0.319  1.0
  O  O29  1  0.500  0.850  0.248  1.0
  O  O30  1  0.183  0.692  0.587  1.0
  O  O31  1  0.817  0.692  0.587  1.0
  O  O32  1  0.183  0.693  0.086  1.0
  O  O33  1  0.817  0.693  0.086  1.0
  O  O34  1  0.500  0.577  0.911  1.0
  O  O35  1  0.000  0.568  0.796  1.0
  O  O36  1  0.500  0.577  0.412  1.0
  O  O37  1  0.000  0.567  0.296  1.0
  O  O38  1  0.500  0.432  0.704  1.0
  O  O39  1  0.000  0.422  0.587  1.0
  O  O40  1  0.500  0.431  0.204  1.0
  O  O41  1  0.000  0.423  0.089  1.0
  O  O42  1  0.317  0.307  0.913  1.0
  O  O43  1  0.683  0.307  0.913  1.0
  O  O44  1  0.686  0.309  0.412  1.0
  O  O45  1  0.314  0.309  0.412  1.0
  O  O46  1  0.000  0.149  0.752  1.0
  O  O47  1  0.500  0.111  0.680  1.0
  O  O48  1  0.000  0.154  0.255  1.0
  O  O49  1  0.000  0.072  0.971  1.0
  O  O50  1  0.500  0.111  0.180  1.0
  O  O51  1  0.000  0.072  0.472  1.0
[/CIF]
.