The structure described by LiMn9CdO10 crystallizes in the triclinic P1 space group. Li(1) is bonded in a 4-coordinate geometry to one Mn(1), one Mn(4), one Mn(7), one O(10), one O(2), one O(4), and one O(7) atom. There are nine inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a 7-coordinate geometry to one Li(1), one O(10), one O(2), one O(3), one O(4), one O(5), and one O(9) atom. In the second Mn site, Mn(2) is bonded to one O(1), one O(3), one O(5), one O(6), one O(7), and one O(8) atom to form a mixture of edge and corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 11-12°. In the third Mn site, Mn(3) is bonded to one O(1), one O(3), one O(5), one O(6), one O(7), and one O(8) atom to form a mixture of edge and corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 3-12°. In the fourth Mn site, Mn(4) is bonded in a 7-coordinate geometry to one Li(1), one O(10), one O(2), one O(4), one O(6), one O(7), and one O(9) atom. In the fifth Mn site, Mn(5) is bonded to one O(1), one O(2), one O(3), one O(5), one O(8), and one O(9) atom to form a mixture of edge and corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 7-8°. In the sixth Mn site, Mn(6) is bonded to one O(1), one O(2), one O(3), one O(5), one O(8), and one O(9) atom to form a mixture of edge and corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 7-10°. In the seventh Mn site, Mn(7) is bonded in a 7-coordinate geometry to one Li(1), one O(10), one O(2), one O(4), one O(6), one O(7), and one O(9) atom. In the eighth Mn site, Mn(8) is bonded to one O(10), one O(2), one O(3), one O(4), one O(5), and one O(9) atom to form a mixture of edge and corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 3-4°. In the ninth Mn site, Mn(9) is bonded to one O(1), one O(10), one O(4), one O(6), one O(7), and one O(8) atom to form a mixture of edge and corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 9-10°. Cd(1) is bonded in a 3-coordinate geometry to one O(1), one O(6), one O(7), and one O(8) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded to one Mn(2), one Mn(3), one Mn(5), one Mn(6), one Mn(9), and one Cd(1) atom to form OMn5Cd octahedra that share corners with two equivalent O(8)Mn5Cd octahedra, corners with two equivalent O(9)Mn6 octahedra, edges with two equivalent O(6)Mn5Cd octahedra, edges with two equivalent O(8)Mn5Cd octahedra, edges with two equivalent O(3)Mn6 octahedra, and edges with two equivalent O(5)Mn6 octahedra. The corner-sharing octahedral tilt angles range from 2-13°. In the second O site, O(2) is bonded in a 7-coordinate geometry to one Li(1), one Mn(1), one Mn(4), one Mn(5), one Mn(6), one Mn(7), and one Mn(8) atom. In the third O site, O(3) is bonded to one Mn(1), one Mn(2), one Mn(3), one Mn(5), one Mn(6), and one Mn(8) atom to form OMn6 octahedra that share corners with two equivalent O(6)Mn5Cd octahedra, corners with two equivalent O(5)Mn6 octahedra, edges with two equivalent O(1)Mn5Cd octahedra, edges with two equivalent O(8)Mn5Cd octahedra, edges with two equivalent O(5)Mn6 octahedra, and edges with two equivalent O(9)Mn6 octahedra. The corner-sharing octahedral tilt angles range from 4-9°. In the fourth O site, O(4) is bonded in a 6-coordinate geometry to one Li(1), one Mn(1), one Mn(4), one Mn(7), one Mn(8), and one Mn(9) atom. In the fifth O site, O(5) is bonded to one Mn(1), one Mn(2), one Mn(3), one Mn(5), one Mn(6), and one Mn(8) atom to form OMn6 octahedra that share corners with two equivalent O(3)Mn6 octahedra,  an edgeedge with one O(6)Mn5Cd octahedra, edges with two equivalent O(1)Mn5Cd octahedra, edges with two equivalent O(8)Mn5Cd octahedra, edges with two equivalent O(3)Mn6 octahedra, and edges with two equivalent O(9)Mn6 octahedra. The corner-sharing octahedral tilt angles range from 7-9°. In the sixth O site, O(6) is bonded to one Mn(2), one Mn(3), one Mn(4), one Mn(7), one Mn(9), and one Cd(1) atom to form OMn5Cd octahedra that share corners with two equivalent O(3)Mn6 octahedra,  an edgeedge with one O(5)Mn6 octahedra,  an edgeedge with one O(9)Mn6 octahedra, edges with two equivalent O(1)Mn5Cd octahedra, and edges with two equivalent O(8)Mn5Cd octahedra. The corner-sharing octahedral tilt angles are 4°. In the seventh O site, O(7) is bonded in a 7-coordinate geometry to one Li(1), one Mn(2), one Mn(3), one Mn(4), one Mn(7), one Mn(9), and one Cd(1) atom. In the eighth O site, O(8) is bonded to one Mn(2), one Mn(3), one Mn(5), one Mn(6), one Mn(9), and one Cd(1) atom to form OMn5Cd octahedra that share corners with two equivalent O(1)Mn5Cd octahedra,  an edgeedge with one O(9)Mn6 octahedra, edges with two equivalent O(1)Mn5Cd octahedra, edges with two equivalent O(6)Mn5Cd octahedra, edges with two equivalent O(3)Mn6 octahedra, and edges with two equivalent O(5)Mn6 octahedra. The corner-sharing octahedral tilt angles range from 7-13°. In the ninth O site, O(9) is bonded to one Mn(1), one Mn(4), one Mn(5), one Mn(6), one Mn(7), and one Mn(8) atom to form OMn6 octahedra that share corners with two equivalent O(1)Mn5Cd octahedra,  an edgeedge with one O(6)Mn5Cd octahedra,  an edgeedge with one O(8)Mn5Cd octahedra, edges with two equivalent O(3)Mn6 octahedra, and edges with two equivalent O(5)Mn6 octahedra. The corner-sharing octahedral tilt angles are 2°. In the tenth O site, O(10) is bonded in a 6-coordinate geometry to one Li(1), one Mn(1), one Mn(4), one Mn(7), one Mn(8), and one Mn(9) atom. is represented by the CIF file [CIF]
data_LiMn9CdO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.642
_cell_length_b   8.789
_cell_length_c   5.646
_cell_angle_alpha   70.245
_cell_angle_beta   109.290
_cell_angle_gamma   96.650
_symmetry_Int_Tables_number   1
_cell_volume   248.710
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.615  0.609  0.079  1.0
  Mn  Mn1  1  0.494  0.362  0.324  1.0
  Mn  Mn2  1  0.991  0.006  0.003  1.0
  Mn  Mn3  1  0.497  0.993  0.520  1.0
  Mn  Mn4  1  0.053  0.599  0.196  1.0
  Mn  Mn5  1  0.993  0.208  0.398  1.0
  Mn  Mn6  1  0.501  0.211  0.904  1.0
  Mn  Mn7  1  0.506  0.597  0.647  1.0
  Mn  Mn8  1  0.005  0.400  0.797  1.0
  Mn  Mn9  1  0.999  0.800  0.602  1.0
  Cd  Cd10  1  0.482  0.848  0.096  1.0
  O  O11  1  0.759  0.025  0.262  1.0
  O  O12  1  0.746  0.409  0.049  1.0
  O  O13  1  0.743  0.190  0.667  1.0
  O  O14  1  0.762  0.573  0.450  1.0
  O  O15  1  0.248  0.193  0.147  1.0
  O  O16  1  0.227  0.802  0.369  1.0
  O  O17  1  0.762  0.780  0.841  1.0
  O  O18  1  0.226  0.022  0.724  1.0
  O  O19  1  0.256  0.398  0.544  1.0
  O  O20  1  0.262  0.575  0.951  1.0
[/CIF]
.
The structure described by LiMn9CdO10 crystallizes in the triclinic P1 space group. Li(1) is bonded in a 4-coordinate geometry to one Mn(1), one Mn(4), one Mn(7), one O(10), one O(2), one O(4), and one O(7) atom. There are nine inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a 7-coordinate geometry to one Li(1), one O(10), one O(2), one O(3), one O(4), one O(5), and one O(9) atom. In the second Mn site, Mn(2) is bonded to one O(1), one O(3), one O(5), one O(6), one O(7), and one O(8) atom to form a mixture of edge and corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 11-12°. In the third Mn site, Mn(3) is bonded to one O(1), one O(3), one O(5), one O(6), one O(7), and one O(8) atom to form a mixture of edge and corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 3-12°. In the fourth Mn site, Mn(4) is bonded in a 7-coordinate geometry to one Li(1), one O(10), one O(2), one O(4), one O(6), one O(7), and one O(9) atom. In the fifth Mn site, Mn(5) is bonded to one O(1), one O(2), one O(3), one O(5), one O(8), and one O(9) atom to form a mixture of edge and corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 7-8°. In the sixth Mn site, Mn(6) is bonded to one O(1), one O(2), one O(3), one O(5), one O(8), and one O(9) atom to form a mixture of edge and corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 7-10°. In the seventh Mn site, Mn(7) is bonded in a 7-coordinate geometry to one Li(1), one O(10), one O(2), one O(4), one O(6), one O(7), and one O(9) atom. In the eighth Mn site, Mn(8) is bonded to one O(10), one O(2), one O(3), one O(4), one O(5), and one O(9) atom to form a mixture of edge and corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 3-4°. In the ninth Mn site, Mn(9) is bonded to one O(1), one O(10), one O(4), one O(6), one O(7), and one O(8) atom to form a mixture of edge and corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 9-10°. Cd(1) is bonded in a 3-coordinate geometry to one O(1), one O(6), one O(7), and one O(8) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded to one Mn(2), one Mn(3), one Mn(5), one Mn(6), one Mn(9), and one Cd(1) atom to form OMn5Cd octahedra that share corners with two equivalent O(8)Mn5Cd octahedra, corners with two equivalent O(9)Mn6 octahedra, edges with two equivalent O(6)Mn5Cd octahedra, edges with two equivalent O(8)Mn5Cd octahedra, edges with two equivalent O(3)Mn6 octahedra, and edges with two equivalent O(5)Mn6 octahedra. The corner-sharing octahedral tilt angles range from 2-13°. In the second O site, O(2) is bonded in a 7-coordinate geometry to one Li(1), one Mn(1), one Mn(4), one Mn(5), one Mn(6), one Mn(7), and one Mn(8) atom. In the third O site, O(3) is bonded to one Mn(1), one Mn(2), one Mn(3), one Mn(5), one Mn(6), and one Mn(8) atom to form OMn6 octahedra that share corners with two equivalent O(6)Mn5Cd octahedra, corners with two equivalent O(5)Mn6 octahedra, edges with two equivalent O(1)Mn5Cd octahedra, edges with two equivalent O(8)Mn5Cd octahedra, edges with two equivalent O(5)Mn6 octahedra, and edges with two equivalent O(9)Mn6 octahedra. The corner-sharing octahedral tilt angles range from 4-9°. In the fourth O site, O(4) is bonded in a 6-coordinate geometry to one Li(1), one Mn(1), one Mn(4), one Mn(7), one Mn(8), and one Mn(9) atom. In the fifth O site, O(5) is bonded to one Mn(1), one Mn(2), one Mn(3), one Mn(5), one Mn(6), and one Mn(8) atom to form OMn6 octahedra that share corners with two equivalent O(3)Mn6 octahedra,  an edgeedge with one O(6)Mn5Cd octahedra, edges with two equivalent O(1)Mn5Cd octahedra, edges with two equivalent O(8)Mn5Cd octahedra, edges with two equivalent O(3)Mn6 octahedra, and edges with two equivalent O(9)Mn6 octahedra. The corner-sharing octahedral tilt angles range from 7-9°. In the sixth O site, O(6) is bonded to one Mn(2), one Mn(3), one Mn(4), one Mn(7), one Mn(9), and one Cd(1) atom to form OMn5Cd octahedra that share corners with two equivalent O(3)Mn6 octahedra,  an edgeedge with one O(5)Mn6 octahedra,  an edgeedge with one O(9)Mn6 octahedra, edges with two equivalent O(1)Mn5Cd octahedra, and edges with two equivalent O(8)Mn5Cd octahedra. The corner-sharing octahedral tilt angles are 4°. In the seventh O site, O(7) is bonded in a 7-coordinate geometry to one Li(1), one Mn(2), one Mn(3), one Mn(4), one Mn(7), one Mn(9), and one Cd(1) atom. In the eighth O site, O(8) is bonded to one Mn(2), one Mn(3), one Mn(5), one Mn(6), one Mn(9), and one Cd(1) atom to form OMn5Cd octahedra that share corners with two equivalent O(1)Mn5Cd octahedra,  an edgeedge with one O(9)Mn6 octahedra, edges with two equivalent O(1)Mn5Cd octahedra, edges with two equivalent O(6)Mn5Cd octahedra, edges with two equivalent O(3)Mn6 octahedra, and edges with two equivalent O(5)Mn6 octahedra. The corner-sharing octahedral tilt angles range from 7-13°. In the ninth O site, O(9) is bonded to one Mn(1), one Mn(4), one Mn(5), one Mn(6), one Mn(7), and one Mn(8) atom to form OMn6 octahedra that share corners with two equivalent O(1)Mn5Cd octahedra,  an edgeedge with one O(6)Mn5Cd octahedra,  an edgeedge with one O(8)Mn5Cd octahedra, edges with two equivalent O(3)Mn6 octahedra, and edges with two equivalent O(5)Mn6 octahedra. The corner-sharing octahedral tilt angles are 2°. In the tenth O site, O(10) is bonded in a 6-coordinate geometry to one Li(1), one Mn(1), one Mn(4), one Mn(7), one Mn(8), and one Mn(9) atom. is represented by the CIF file [CIF]
data_LiMn9CdO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.642
_cell_length_b   8.789
_cell_length_c   5.646
_cell_angle_alpha   70.245
_cell_angle_beta   109.290
_cell_angle_gamma   96.650
_symmetry_Int_Tables_number   1
_cell_volume   248.710
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.615  0.609  0.079  1.0
  Mn  Mn1  1  0.494  0.362  0.324  1.0
  Mn  Mn2  1  0.991  0.006  0.003  1.0
  Mn  Mn3  1  0.497  0.993  0.520  1.0
  Mn  Mn4  1  0.053  0.599  0.196  1.0
  Mn  Mn5  1  0.993  0.208  0.398  1.0
  Mn  Mn6  1  0.501  0.211  0.904  1.0
  Mn  Mn7  1  0.506  0.597  0.647  1.0
  Mn  Mn8  1  0.005  0.400  0.797  1.0
  Mn  Mn9  1  0.999  0.800  0.602  1.0
  Cd  Cd10  1  0.482  0.848  0.096  1.0
  O  O11  1  0.759  0.025  0.262  1.0
  O  O12  1  0.746  0.409  0.049  1.0
  O  O13  1  0.743  0.190  0.667  1.0
  O  O14  1  0.762  0.573  0.450  1.0
  O  O15  1  0.248  0.193  0.147  1.0
  O  O16  1  0.227  0.802  0.369  1.0
  O  O17  1  0.762  0.780  0.841  1.0
  O  O18  1  0.226  0.022  0.724  1.0
  O  O19  1  0.256  0.398  0.544  1.0
  O  O20  1  0.262  0.575  0.951  1.0
[/CIF]
.