The compound described by Re2O4Cl5 is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one Re2O4Cl5 cluster. There are two inequivalent Re sites. In the first Re site, Re(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one Cl(5) atom. In the second Re site, Re(2) is bonded in a 6-coordinate geometry to one O(3), one O(4), one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Re(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Re(1) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Re(1) and one Re(2) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Re(2) atom. There are five inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Re(2) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Re(2) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Re(2) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Re(2) atom. In the fifth Cl site, Cl(5) is bonded in a single-bond geometry to one Re(1) atom. is represented by the CIF file [CIF]
data_Re2Cl5O4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.591
_cell_length_b   6.369
_cell_length_c   8.525
_cell_angle_alpha   110.038
_cell_angle_beta   106.351
_cell_angle_gamma   94.115
_symmetry_Int_Tables_number   1
_cell_volume   268.870
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.885  0.446  0.441  1.0
  Re  Re1  1  0.966  0.009  0.995  1.0
  Cl  Cl2  1  0.249  0.983  0.238  1.0
  Cl  Cl3  1  0.628  0.112  0.833  1.0
  Cl  Cl4  1  0.684  0.737  0.002  1.0
  Cl  Cl5  1  0.191  0.365  0.075  1.0
  Cl  Cl6  1  0.116  0.325  0.637  1.0
  O  O7  1  0.612  0.504  0.485  1.0
  O  O8  1  0.047  0.686  0.446  1.0
  O  O9  1  0.811  0.235  0.233  1.0
  O  O10  1  0.074  0.854  0.835  1.0
[/CIF]
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The compound described by Re2O4Cl5 is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one Re2O4Cl5 cluster. There are two inequivalent Re sites. In the first Re site, Re(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one Cl(5) atom. In the second Re site, Re(2) is bonded in a 6-coordinate geometry to one O(3), one O(4), one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Re(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Re(1) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Re(1) and one Re(2) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Re(2) atom. There are five inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Re(2) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Re(2) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Re(2) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Re(2) atom. In the fifth Cl site, Cl(5) is bonded in a single-bond geometry to one Re(1) atom. is represented by the CIF file [CIF]
data_Re2Cl5O4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.591
_cell_length_b   6.369
_cell_length_c   8.525
_cell_angle_alpha   110.038
_cell_angle_beta   106.351
_cell_angle_gamma   94.115
_symmetry_Int_Tables_number   1
_cell_volume   268.870
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.885  0.446  0.441  1.0
  Re  Re1  1  0.966  0.009  0.995  1.0
  Cl  Cl2  1  0.249  0.983  0.238  1.0
  Cl  Cl3  1  0.628  0.112  0.833  1.0
  Cl  Cl4  1  0.684  0.737  0.002  1.0
  Cl  Cl5  1  0.191  0.365  0.075  1.0
  Cl  Cl6  1  0.116  0.325  0.637  1.0
  O  O7  1  0.612  0.504  0.485  1.0
  O  O8  1  0.047  0.686  0.446  1.0
  O  O9  1  0.811  0.235  0.233  1.0
  O  O10  1  0.074  0.854  0.835  1.0
[/CIF]
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