The structure described by NaCdSbS3 crystallizes in the monoclinic C2/c space group. Na(1) is bonded to one S(3), two equivalent S(1), and three equivalent S(2) atoms to form NaS6 octahedra that share  a cornercorner with one Cd(2)S6 octahedra, corners with four equivalent Na(1)S6 octahedra, edges with two equivalent Na(1)S6 octahedra, edges with two equivalent Cd(1)S6 octahedra, and edges with two equivalent Cd(2)S6 octahedra. The corner-sharing octahedral tilt angles range from 16-22°. There are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded to two equivalent S(1) and four equivalent S(3) atoms to form distorted CdS6 octahedra that share corners with four equivalent Cd(1)S6 octahedra, edges with four equivalent Na(1)S6 octahedra, and edges with four equivalent Cd(2)S6 octahedra. The corner-sharing octahedral tilt angles are 10°. In the second Cd site, Cd(2) is bonded to two equivalent S(2) and four equivalent S(3) atoms to form distorted CdS6 octahedra that share corners with two equivalent Na(1)S6 octahedra, corners with four equivalent Cd(2)S6 octahedra, edges with four equivalent Na(1)S6 octahedra, and edges with four equivalent Cd(1)S6 octahedra. The corner-sharing octahedral tilt angles range from 12-22°. Sb(1) is bonded in a distorted T-shaped geometry to one S(1), one S(2), and one S(3) atom. There are three inequivalent S sites. In the first S site, S(3) is bonded to one Na(1), two equivalent Cd(1), two equivalent Cd(2), and one Sb(1) atom to form distorted SNaCd4Sb octahedra that share corners with four equivalent S(3)NaCd4Sb octahedra, corners with two equivalent S(2)Na3CdSb square pyramids, edges with four equivalent S(3)NaCd4Sb octahedra, and edges with three equivalent S(2)Na3CdSb square pyramids. The corner-sharing octahedral tilt angles range from 10-12°. In the second S site, S(1) is bonded in a rectangular see-saw-like geometry to two equivalent Na(1), one Cd(1), and one Sb(1) atom. In the third S site, S(2) is bonded to three equivalent Na(1), one Cd(2), and one Sb(1) atom to form SNa3CdSb square pyramids that share corners with two equivalent S(3)NaCd4Sb octahedra, corners with three equivalent S(2)Na3CdSb square pyramids, edges with three equivalent S(3)NaCd4Sb octahedra, and edges with two equivalent S(2)Na3CdSb square pyramids. The corner-sharing octahedral tilt angles range from 10-85°. is represented by the CIF file [CIF]
data_NaCdSbS3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.853
_cell_length_b   5.853
_cell_length_c   17.278
_cell_angle_alpha   80.818
_cell_angle_beta   80.818
_cell_angle_gamma   90.574
_symmetry_Int_Tables_number   1
_cell_volume   576.533
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.188  0.489  0.079  1.0
  Na  Na1  1  0.511  0.812  0.421  1.0
  Na  Na2  1  0.812  0.511  0.921  1.0
  Na  Na3  1  0.489  0.188  0.579  1.0
  Cd  Cd4  1  0.115  0.885  0.250  1.0
  Cd  Cd5  1  0.885  0.115  0.750  1.0
  Cd  Cd6  1  0.619  0.381  0.250  1.0
  Cd  Cd7  1  0.381  0.619  0.750  1.0
  Sb  Sb8  1  0.948  0.698  0.594  1.0
  Sb  Sb9  1  0.302  0.052  0.906  1.0
  Sb  Sb10  1  0.052  0.302  0.406  1.0
  Sb  Sb11  1  0.698  0.948  0.094  1.0
  S  S12  1  0.015  0.883  0.402  1.0
  S  S13  1  0.117  0.985  0.098  1.0
  S  S14  1  0.985  0.117  0.598  1.0
  S  S15  1  0.883  0.015  0.902  1.0
  S  S16  1  0.672  0.524  0.097  1.0
  S  S17  1  0.476  0.328  0.403  1.0
  S  S18  1  0.328  0.476  0.903  1.0
  S  S19  1  0.524  0.672  0.597  1.0
  S  S20  1  0.078  0.417  0.260  1.0
  S  S21  1  0.583  0.922  0.240  1.0
  S  S22  1  0.922  0.583  0.740  1.0
  S  S23  1  0.417  0.078  0.760  1.0
[/CIF]
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The structure described by NaCdSbS3 crystallizes in the monoclinic C2/c space group. Na(1) is bonded to one S(3), two equivalent S(1), and three equivalent S(2) atoms to form NaS6 octahedra that share  a cornercorner with one Cd(2)S6 octahedra, corners with four equivalent Na(1)S6 octahedra, edges with two equivalent Na(1)S6 octahedra, edges with two equivalent Cd(1)S6 octahedra, and edges with two equivalent Cd(2)S6 octahedra. The corner-sharing octahedral tilt angles range from 16-22°. There are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded to two equivalent S(1) and four equivalent S(3) atoms to form distorted CdS6 octahedra that share corners with four equivalent Cd(1)S6 octahedra, edges with four equivalent Na(1)S6 octahedra, and edges with four equivalent Cd(2)S6 octahedra. The corner-sharing octahedral tilt angles are 10°. In the second Cd site, Cd(2) is bonded to two equivalent S(2) and four equivalent S(3) atoms to form distorted CdS6 octahedra that share corners with two equivalent Na(1)S6 octahedra, corners with four equivalent Cd(2)S6 octahedra, edges with four equivalent Na(1)S6 octahedra, and edges with four equivalent Cd(1)S6 octahedra. The corner-sharing octahedral tilt angles range from 12-22°. Sb(1) is bonded in a distorted T-shaped geometry to one S(1), one S(2), and one S(3) atom. There are three inequivalent S sites. In the first S site, S(3) is bonded to one Na(1), two equivalent Cd(1), two equivalent Cd(2), and one Sb(1) atom to form distorted SNaCd4Sb octahedra that share corners with four equivalent S(3)NaCd4Sb octahedra, corners with two equivalent S(2)Na3CdSb square pyramids, edges with four equivalent S(3)NaCd4Sb octahedra, and edges with three equivalent S(2)Na3CdSb square pyramids. The corner-sharing octahedral tilt angles range from 10-12°. In the second S site, S(1) is bonded in a rectangular see-saw-like geometry to two equivalent Na(1), one Cd(1), and one Sb(1) atom. In the third S site, S(2) is bonded to three equivalent Na(1), one Cd(2), and one Sb(1) atom to form SNa3CdSb square pyramids that share corners with two equivalent S(3)NaCd4Sb octahedra, corners with three equivalent S(2)Na3CdSb square pyramids, edges with three equivalent S(3)NaCd4Sb octahedra, and edges with two equivalent S(2)Na3CdSb square pyramids. The corner-sharing octahedral tilt angles range from 10-85°. is represented by the CIF file [CIF]
data_NaCdSbS3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.853
_cell_length_b   5.853
_cell_length_c   17.278
_cell_angle_alpha   80.818
_cell_angle_beta   80.818
_cell_angle_gamma   90.574
_symmetry_Int_Tables_number   1
_cell_volume   576.533
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.188  0.489  0.079  1.0
  Na  Na1  1  0.511  0.812  0.421  1.0
  Na  Na2  1  0.812  0.511  0.921  1.0
  Na  Na3  1  0.489  0.188  0.579  1.0
  Cd  Cd4  1  0.115  0.885  0.250  1.0
  Cd  Cd5  1  0.885  0.115  0.750  1.0
  Cd  Cd6  1  0.619  0.381  0.250  1.0
  Cd  Cd7  1  0.381  0.619  0.750  1.0
  Sb  Sb8  1  0.948  0.698  0.594  1.0
  Sb  Sb9  1  0.302  0.052  0.906  1.0
  Sb  Sb10  1  0.052  0.302  0.406  1.0
  Sb  Sb11  1  0.698  0.948  0.094  1.0
  S  S12  1  0.015  0.883  0.402  1.0
  S  S13  1  0.117  0.985  0.098  1.0
  S  S14  1  0.985  0.117  0.598  1.0
  S  S15  1  0.883  0.015  0.902  1.0
  S  S16  1  0.672  0.524  0.097  1.0
  S  S17  1  0.476  0.328  0.403  1.0
  S  S18  1  0.328  0.476  0.903  1.0
  S  S19  1  0.524  0.672  0.597  1.0
  S  S20  1  0.078  0.417  0.260  1.0
  S  S21  1  0.583  0.922  0.240  1.0
  S  S22  1  0.922  0.583  0.740  1.0
  S  S23  1  0.417  0.078  0.760  1.0
[/CIF]
.