The material described by (CrO6)2(Cl2)3 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four 7782-50-5 molecules, four hydrochloric acid atoms, and four CrO6 clusters. In each CrO6 cluster, Cr(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent O(1) and two equivalent O(2) atoms. There are three inequivalent O sites. In the first O site, O(2) is bonded in a distorted L-shaped geometry to one Cr(1) and one O(3) atom. In the second O site, O(3) is bonded in a water-like geometry to one O(1) and one O(2) atom. In the third O site, O(1) is bonded in a distorted L-shaped geometry to one Cr(1) and one O(3) atom. is represented by the CIF card [CIF]
data_Cr(ClO2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.356
_cell_length_b   9.356
_cell_length_c   8.231
_cell_angle_alpha   76.472
_cell_angle_beta   76.472
_cell_angle_gamma   122.146
_symmetry_Int_Tables_number   1
_cell_volume   533.982
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.000  0.000  0.000  1.0
  Cr  Cr1  1  0.000  0.000  0.500  1.0
  Cl  Cl2  1  0.687  0.487  0.291  1.0
  Cl  Cl3  1  0.191  0.809  0.750  1.0
  Cl  Cl4  1  0.513  0.313  0.209  1.0
  Cl  Cl5  1  0.313  0.513  0.709  1.0
  Cl  Cl6  1  0.809  0.191  0.250  1.0
  Cl  Cl7  1  0.487  0.687  0.791  1.0
  O  O8  1  0.101  0.240  0.282  1.0
  O  O9  1  0.084  0.219  0.561  1.0
  O  O10  1  0.341  0.147  0.881  1.0
  O  O11  1  0.899  0.760  0.718  1.0
  O  O12  1  0.916  0.781  0.439  1.0
  O  O13  1  0.659  0.853  0.119  1.0
  O  O14  1  0.219  0.084  0.061  1.0
  O  O15  1  0.147  0.341  0.381  1.0
  O  O16  1  0.240  0.101  0.782  1.0
  O  O17  1  0.781  0.916  0.939  1.0
  O  O18  1  0.853  0.659  0.619  1.0
  O  O19  1  0.760  0.899  0.218  1.0
[/CIF]
.
The material described by (CrO6)2(Cl2)3 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four 7782-50-5 molecules, four hydrochloric acid atoms, and four CrO6 clusters. In each CrO6 cluster, Cr(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent O(1) and two equivalent O(2) atoms. There are three inequivalent O sites. In the first O site, O(2) is bonded in a distorted L-shaped geometry to one Cr(1) and one O(3) atom. In the second O site, O(3) is bonded in a water-like geometry to one O(1) and one O(2) atom. In the third O site, O(1) is bonded in a distorted L-shaped geometry to one Cr(1) and one O(3) atom. is represented by the CIF card [CIF]
data_Cr(ClO2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.356
_cell_length_b   9.356
_cell_length_c   8.231
_cell_angle_alpha   76.472
_cell_angle_beta   76.472
_cell_angle_gamma   122.146
_symmetry_Int_Tables_number   1
_cell_volume   533.982
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.000  0.000  0.000  1.0
  Cr  Cr1  1  0.000  0.000  0.500  1.0
  Cl  Cl2  1  0.687  0.487  0.291  1.0
  Cl  Cl3  1  0.191  0.809  0.750  1.0
  Cl  Cl4  1  0.513  0.313  0.209  1.0
  Cl  Cl5  1  0.313  0.513  0.709  1.0
  Cl  Cl6  1  0.809  0.191  0.250  1.0
  Cl  Cl7  1  0.487  0.687  0.791  1.0
  O  O8  1  0.101  0.240  0.282  1.0
  O  O9  1  0.084  0.219  0.561  1.0
  O  O10  1  0.341  0.147  0.881  1.0
  O  O11  1  0.899  0.760  0.718  1.0
  O  O12  1  0.916  0.781  0.439  1.0
  O  O13  1  0.659  0.853  0.119  1.0
  O  O14  1  0.219  0.084  0.061  1.0
  O  O15  1  0.147  0.341  0.381  1.0
  O  O16  1  0.240  0.101  0.782  1.0
  O  O17  1  0.781  0.916  0.939  1.0
  O  O18  1  0.853  0.659  0.619  1.0
  O  O19  1  0.760  0.899  0.218  1.0
[/CIF]
.