The material described by CoBiO4 is trigonal omega-derived structured and crystallizes in the orthorhombic Imma space group. Co(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form CoO6 octahedra that share edges with two equivalent Co(1)O6 octahedra and edges with four equivalent Bi(1)O6 octahedra. Bi(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form distorted BiO6 octahedra that share edges with two equivalent Bi(1)O6 octahedra and edges with four equivalent Co(1)O6 octahedra. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Co(1) and two equivalent Bi(1) atoms. In the second O site, O(2) is bonded in a 3-coordinate geometry to two equivalent Co(1) and one Bi(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CoBiO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.169
_cell_length_b   6.169
_cell_length_c   6.169
_cell_angle_alpha   125.015
_cell_angle_beta   113.000
_cell_angle_gamma   92.033
_symmetry_Int_Tables_number   1
_cell_volume   166.172
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.500  0.500  0.500  1.0
  Co  Co1  1  0.500  0.000  0.000  1.0
  Bi  Bi2  1  0.500  0.000  0.500  1.0
  Bi  Bi3  1  0.000  0.000  0.000  1.0
  O  O4  1  0.276  0.775  1.000  1.0
  O  O5  1  0.313  0.752  0.561  1.0
  O  O6  1  0.310  0.248  0.061  1.0
  O  O7  1  0.724  0.724  0.500  1.0
  O  O8  1  0.276  0.276  0.500  1.0
  O  O9  1  0.690  0.752  0.939  1.0
  O  O10  1  0.687  0.248  0.439  1.0
  O  O11  1  0.724  0.225  0.000  1.0
[/CIF]
.
The material described by CoBiO4 is trigonal omega-derived structured and crystallizes in the orthorhombic Imma space group. Co(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form CoO6 octahedra that share edges with two equivalent Co(1)O6 octahedra and edges with four equivalent Bi(1)O6 octahedra. Bi(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form distorted BiO6 octahedra that share edges with two equivalent Bi(1)O6 octahedra and edges with four equivalent Co(1)O6 octahedra. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Co(1) and two equivalent Bi(1) atoms. In the second O site, O(2) is bonded in a 3-coordinate geometry to two equivalent Co(1) and one Bi(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CoBiO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.169
_cell_length_b   6.169
_cell_length_c   6.169
_cell_angle_alpha   125.015
_cell_angle_beta   113.000
_cell_angle_gamma   92.033
_symmetry_Int_Tables_number   1
_cell_volume   166.172
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.500  0.500  0.500  1.0
  Co  Co1  1  0.500  0.000  0.000  1.0
  Bi  Bi2  1  0.500  0.000  0.500  1.0
  Bi  Bi3  1  0.000  0.000  0.000  1.0
  O  O4  1  0.276  0.775  1.000  1.0
  O  O5  1  0.313  0.752  0.561  1.0
  O  O6  1  0.310  0.248  0.061  1.0
  O  O7  1  0.724  0.724  0.500  1.0
  O  O8  1  0.276  0.276  0.500  1.0
  O  O9  1  0.690  0.752  0.939  1.0
  O  O10  1  0.687  0.248  0.439  1.0
  O  O11  1  0.724  0.225  0.000  1.0
[/CIF]
.