The material described by CeRhCo crystallizes in the orthorhombic Imma space group. Ce(1) is bonded in a 12-coordinate geometry to six equivalent Rh(1) and six equivalent Co(1) atoms. Rh(1) is bonded to six equivalent Ce(1), two equivalent Rh(1), and four equivalent Co(1) atoms to form distorted RhCe6Co4Rh2 cuboctahedra that share corners with eight equivalent Co(1)Ce6Co2Rh4 cuboctahedra, corners with ten equivalent Rh(1)Ce6Co4Rh2 cuboctahedra, edges with six equivalent Rh(1)Ce6Co4Rh2 cuboctahedra, faces with six equivalent Rh(1)Ce6Co4Rh2 cuboctahedra, and faces with twelve equivalent Co(1)Ce6Co2Rh4 cuboctahedra. Co(1) is bonded to six equivalent Ce(1), four equivalent Rh(1), and two equivalent Co(1) atoms to form CoCe6Co2Rh4 cuboctahedra that share corners with eight equivalent Rh(1)Ce6Co4Rh2 cuboctahedra, corners with ten equivalent Co(1)Ce6Co2Rh4 cuboctahedra, edges with six equivalent Co(1)Ce6Co2Rh4 cuboctahedra, faces with six equivalent Co(1)Ce6Co2Rh4 cuboctahedra, and faces with twelve equivalent Rh(1)Ce6Co4Rh2 cuboctahedra. is represented by the CIF file [CIF]
data_CeCoRh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.171
_cell_length_b   5.171
_cell_length_c   5.171
_cell_angle_alpha   121.321
_cell_angle_beta   117.119
_cell_angle_gamma   91.393
_symmetry_Int_Tables_number   1
_cell_volume   98.720
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.368  0.118  0.250  1.0
  Ce  Ce1  1  0.632  0.882  0.750  1.0
  Co  Co2  1  0.000  0.500  0.000  1.0
  Co  Co3  1  0.000  0.000  0.500  1.0
  Rh  Rh4  1  0.500  0.500  0.000  1.0
  Rh  Rh5  1  0.000  0.500  0.500  1.0
[/CIF]
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The material described by CeRhCo crystallizes in the orthorhombic Imma space group. Ce(1) is bonded in a 12-coordinate geometry to six equivalent Rh(1) and six equivalent Co(1) atoms. Rh(1) is bonded to six equivalent Ce(1), two equivalent Rh(1), and four equivalent Co(1) atoms to form distorted RhCe6Co4Rh2 cuboctahedra that share corners with eight equivalent Co(1)Ce6Co2Rh4 cuboctahedra, corners with ten equivalent Rh(1)Ce6Co4Rh2 cuboctahedra, edges with six equivalent Rh(1)Ce6Co4Rh2 cuboctahedra, faces with six equivalent Rh(1)Ce6Co4Rh2 cuboctahedra, and faces with twelve equivalent Co(1)Ce6Co2Rh4 cuboctahedra. Co(1) is bonded to six equivalent Ce(1), four equivalent Rh(1), and two equivalent Co(1) atoms to form CoCe6Co2Rh4 cuboctahedra that share corners with eight equivalent Rh(1)Ce6Co4Rh2 cuboctahedra, corners with ten equivalent Co(1)Ce6Co2Rh4 cuboctahedra, edges with six equivalent Co(1)Ce6Co2Rh4 cuboctahedra, faces with six equivalent Co(1)Ce6Co2Rh4 cuboctahedra, and faces with twelve equivalent Rh(1)Ce6Co4Rh2 cuboctahedra. is represented by the CIF file [CIF]
data_CeCoRh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.171
_cell_length_b   5.171
_cell_length_c   5.171
_cell_angle_alpha   121.321
_cell_angle_beta   117.119
_cell_angle_gamma   91.393
_symmetry_Int_Tables_number   1
_cell_volume   98.720
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.368  0.118  0.250  1.0
  Ce  Ce1  1  0.632  0.882  0.750  1.0
  Co  Co2  1  0.000  0.500  0.000  1.0
  Co  Co3  1  0.000  0.000  0.500  1.0
  Rh  Rh4  1  0.500  0.500  0.000  1.0
  Rh  Rh5  1  0.000  0.500  0.500  1.0
[/CIF]
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