The material structure described by RbV4O10 crystallizes in the monoclinic C2/m space group. Rb(1) is bonded in a body-centered cubic geometry to four equivalent O(2) and four equivalent O(3) atoms. There are two inequivalent V sites. In the first V site, V(1) is bonded in a 6-coordinate geometry to one O(2), one O(5), two equivalent O(1), and two equivalent O(4) atoms. In the second V site, V(2) is bonded in a 5-coordinate geometry to one O(1), one O(3), one O(4), and two equivalent O(5) atoms. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one V(2) and two equivalent V(1) atoms. In the second O site, O(2) is bonded in a single-bond geometry to two equivalent Rb(1) and one V(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to two equivalent Rb(1) and one V(2) atom. In the fourth O site, O(4) is bonded in a distorted T-shaped geometry to one V(2) and two equivalent V(1) atoms. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one V(1) and two equivalent V(2) atoms. is represented by the CIF card [CIF]
data_RbV4O10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.161
_cell_length_b   6.161
_cell_length_c   9.940
_cell_angle_alpha   79.696
_cell_angle_beta   79.696
_cell_angle_gamma   35.251
_symmetry_Int_Tables_number   1
_cell_volume   213.876
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.500  0.500  0.500  1.0
  V  V1  1  0.910  0.910  0.155  1.0
  V  V2  1  0.794  0.794  0.843  1.0
  V  V3  1  0.206  0.206  0.157  1.0
  V  V4  1  0.090  0.090  0.845  1.0
  O  O5  1  0.935  0.935  0.905  1.0
  O  O6  1  0.898  0.898  0.322  1.0
  O  O7  1  0.837  0.837  0.677  1.0
  O  O8  1  0.379  0.379  0.126  1.0
  O  O9  1  0.258  0.258  0.886  1.0
  O  O10  1  0.742  0.742  0.114  1.0
  O  O11  1  0.621  0.621  0.874  1.0
  O  O12  1  0.163  0.163  0.323  1.0
  O  O13  1  0.102  0.102  0.678  1.0
  O  O14  1  0.065  0.065  0.095  1.0
[/CIF]
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The material structure described by RbV4O10 crystallizes in the monoclinic C2/m space group. Rb(1) is bonded in a body-centered cubic geometry to four equivalent O(2) and four equivalent O(3) atoms. There are two inequivalent V sites. In the first V site, V(1) is bonded in a 6-coordinate geometry to one O(2), one O(5), two equivalent O(1), and two equivalent O(4) atoms. In the second V site, V(2) is bonded in a 5-coordinate geometry to one O(1), one O(3), one O(4), and two equivalent O(5) atoms. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one V(2) and two equivalent V(1) atoms. In the second O site, O(2) is bonded in a single-bond geometry to two equivalent Rb(1) and one V(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to two equivalent Rb(1) and one V(2) atom. In the fourth O site, O(4) is bonded in a distorted T-shaped geometry to one V(2) and two equivalent V(1) atoms. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one V(1) and two equivalent V(2) atoms. is represented by the CIF card [CIF]
data_RbV4O10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.161
_cell_length_b   6.161
_cell_length_c   9.940
_cell_angle_alpha   79.696
_cell_angle_beta   79.696
_cell_angle_gamma   35.251
_symmetry_Int_Tables_number   1
_cell_volume   213.876
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.500  0.500  0.500  1.0
  V  V1  1  0.910  0.910  0.155  1.0
  V  V2  1  0.794  0.794  0.843  1.0
  V  V3  1  0.206  0.206  0.157  1.0
  V  V4  1  0.090  0.090  0.845  1.0
  O  O5  1  0.935  0.935  0.905  1.0
  O  O6  1  0.898  0.898  0.322  1.0
  O  O7  1  0.837  0.837  0.677  1.0
  O  O8  1  0.379  0.379  0.126  1.0
  O  O9  1  0.258  0.258  0.886  1.0
  O  O10  1  0.742  0.742  0.114  1.0
  O  O11  1  0.621  0.621  0.874  1.0
  O  O12  1  0.163  0.163  0.323  1.0
  O  O13  1  0.102  0.102  0.678  1.0
  O  O14  1  0.065  0.065  0.095  1.0
[/CIF]
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