The material structure described by ZnFeGaO4 is Spinel-derived structured and crystallizes in the orthorhombic Imma space group. Fe(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form FeO6 octahedra that share corners with six equivalent Zn(1)O4 tetrahedra, edges with two equivalent Fe(1)O6 octahedra, and edges with four equivalent Ga(1)O6 octahedra. Zn(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form ZnO4 tetrahedra that share corners with six equivalent Fe(1)O6 octahedra and corners with six equivalent Ga(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 58-59°. Ga(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form GaO6 octahedra that share corners with six equivalent Zn(1)O4 tetrahedra, edges with two equivalent Ga(1)O6 octahedra, and edges with four equivalent Fe(1)O6 octahedra. There are two inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Fe(1), one Zn(1), and one Ga(1) atom to form distorted OZnGaFe2 trigonal pyramids that share corners with six equivalent O(2)ZnGa2Fe trigonal pyramids, corners with six equivalent O(1)ZnGaFe2 trigonal pyramids,  an edgeedge with one O(1)ZnGaFe2 trigonal pyramid, and edges with two equivalent O(2)ZnGa2Fe trigonal pyramids. In the second O site, O(2) is bonded to one Fe(1), one Zn(1), and two equivalent Ga(1) atoms to form distorted OZnGa2Fe trigonal pyramids that share corners with six equivalent O(2)ZnGa2Fe trigonal pyramids, corners with six equivalent O(1)ZnGaFe2 trigonal pyramids,  an edgeedge with one O(2)ZnGa2Fe trigonal pyramid, and edges with two equivalent O(1)ZnGaFe2 trigonal pyramids. is represented by the CIF card [CIF]
data_ZnGaFeO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.002
_cell_length_b   6.011
_cell_length_c   6.012
_cell_angle_alpha   60.008
_cell_angle_beta   60.053
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   153.514
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Fe  Fe0  1  0.500  0.000  1.000  1.0
  Fe  Fe1  1  0.500  0.500  0.000  1.0
  Ga  Ga2  1  0.500  0.000  0.500  1.0
  Ga  Ga3  1  0.000  0.000  0.500  1.0
  O  O4  1  0.258  0.238  0.025  1.0
  O  O5  1  0.717  0.238  0.025  1.0
  O  O6  1  0.742  0.762  0.975  1.0
  O  O7  1  0.283  0.762  0.975  1.0
  O  O8  1  0.260  0.235  0.480  1.0
  O  O9  1  0.260  0.784  0.480  1.0
  O  O10  1  0.740  0.765  0.520  1.0
  O  O11  1  0.740  0.216  0.520  1.0
  Zn  Zn12  1  0.124  0.374  0.752  1.0
  Zn  Zn13  1  0.876  0.626  0.248  1.0
[/CIF]
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The material structure described by ZnFeGaO4 is Spinel-derived structured and crystallizes in the orthorhombic Imma space group. Fe(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form FeO6 octahedra that share corners with six equivalent Zn(1)O4 tetrahedra, edges with two equivalent Fe(1)O6 octahedra, and edges with four equivalent Ga(1)O6 octahedra. Zn(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form ZnO4 tetrahedra that share corners with six equivalent Fe(1)O6 octahedra and corners with six equivalent Ga(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 58-59°. Ga(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form GaO6 octahedra that share corners with six equivalent Zn(1)O4 tetrahedra, edges with two equivalent Ga(1)O6 octahedra, and edges with four equivalent Fe(1)O6 octahedra. There are two inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Fe(1), one Zn(1), and one Ga(1) atom to form distorted OZnGaFe2 trigonal pyramids that share corners with six equivalent O(2)ZnGa2Fe trigonal pyramids, corners with six equivalent O(1)ZnGaFe2 trigonal pyramids,  an edgeedge with one O(1)ZnGaFe2 trigonal pyramid, and edges with two equivalent O(2)ZnGa2Fe trigonal pyramids. In the second O site, O(2) is bonded to one Fe(1), one Zn(1), and two equivalent Ga(1) atoms to form distorted OZnGa2Fe trigonal pyramids that share corners with six equivalent O(2)ZnGa2Fe trigonal pyramids, corners with six equivalent O(1)ZnGaFe2 trigonal pyramids,  an edgeedge with one O(2)ZnGa2Fe trigonal pyramid, and edges with two equivalent O(1)ZnGaFe2 trigonal pyramids. is represented by the CIF card [CIF]
data_ZnGaFeO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.002
_cell_length_b   6.011
_cell_length_c   6.012
_cell_angle_alpha   60.008
_cell_angle_beta   60.053
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   153.514
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Fe  Fe0  1  0.500  0.000  1.000  1.0
  Fe  Fe1  1  0.500  0.500  0.000  1.0
  Ga  Ga2  1  0.500  0.000  0.500  1.0
  Ga  Ga3  1  0.000  0.000  0.500  1.0
  O  O4  1  0.258  0.238  0.025  1.0
  O  O5  1  0.717  0.238  0.025  1.0
  O  O6  1  0.742  0.762  0.975  1.0
  O  O7  1  0.283  0.762  0.975  1.0
  O  O8  1  0.260  0.235  0.480  1.0
  O  O9  1  0.260  0.784  0.480  1.0
  O  O10  1  0.740  0.765  0.520  1.0
  O  O11  1  0.740  0.216  0.520  1.0
  Zn  Zn12  1  0.124  0.374  0.752  1.0
  Zn  Zn13  1  0.876  0.626  0.248  1.0
[/CIF]
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