The material described by H3OClO4 is Indium-like structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four H3OClO4 clusters. There are three inequivalent H sites. In the first H site, H(1) is bonded in a bent 150 degrees geometry to one O(2) and one O(4) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(4) atom. There are four inequivalent O sites. In the first O site, O(4) is bonded in a trigonal planar geometry to one H(1), one H(2), and one H(3) atom. In the second O site, O(1) is bonded in a single-bond geometry to one Cl(1) atom. In the third O site, O(2) is bonded in a distorted bent 150 degrees geometry to one H(1) and one Cl(1) atom. In the fourth O site, O(3) is bonded in a single-bond geometry to one Cl(1) atom. Cl(1) is bonded in a tetrahedral geometry to one O(1), one O(2), and two equivalent O(3) atoms. is represented by the CIF card [CIF]
data_H3ClO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.321
_cell_length_b   7.535
_cell_length_c   8.705
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   414.563
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.250  0.537  0.182  1.0
  H  H1  1  0.250  0.963  0.682  1.0
  H  H2  1  0.750  0.463  0.818  1.0
  H  H3  1  0.750  0.037  0.318  1.0
  H  H4  1  0.250  0.737  0.758  1.0
  H  H5  1  0.250  0.908  0.878  1.0
  H  H6  1  0.250  0.763  0.258  1.0
  H  H7  1  0.250  0.592  0.378  1.0
  H  H8  1  0.750  0.092  0.122  1.0
  H  H9  1  0.750  0.263  0.242  1.0
  H  H10  1  0.750  0.408  0.622  1.0
  H  H11  1  0.750  0.237  0.742  1.0
  Cl  Cl12  1  0.250  0.312  0.948  1.0
  Cl  Cl13  1  0.250  0.188  0.448  1.0
  Cl  Cl14  1  0.750  0.688  0.052  1.0
  Cl  Cl15  1  0.750  0.812  0.552  1.0
  O  O16  1  0.250  0.462  0.845  1.0
  O  O17  1  0.250  0.038  0.345  1.0
  O  O18  1  0.750  0.538  0.155  1.0
  O  O19  1  0.750  0.962  0.655  1.0
  O  O20  1  0.250  0.375  0.111  1.0
  O  O21  1  0.250  0.125  0.611  1.0
  O  O22  1  0.750  0.625  0.889  1.0
  O  O23  1  0.750  0.875  0.389  1.0
  O  O24  1  0.062  0.203  0.929  1.0
  O  O25  1  0.438  0.297  0.429  1.0
  O  O26  1  0.562  0.797  0.071  1.0
  O  O27  1  0.938  0.703  0.571  1.0
  O  O28  1  0.938  0.797  0.071  1.0
  O  O29  1  0.562  0.703  0.571  1.0
  O  O30  1  0.438  0.203  0.929  1.0
  O  O31  1  0.062  0.297  0.429  1.0
  O  O32  1  0.250  0.865  0.772  1.0
  O  O33  1  0.250  0.635  0.272  1.0
  O  O34  1  0.750  0.135  0.228  1.0
  O  O35  1  0.750  0.365  0.728  1.0
[/CIF]
.
The material described by H3OClO4 is Indium-like structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four H3OClO4 clusters. There are three inequivalent H sites. In the first H site, H(1) is bonded in a bent 150 degrees geometry to one O(2) and one O(4) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(4) atom. There are four inequivalent O sites. In the first O site, O(4) is bonded in a trigonal planar geometry to one H(1), one H(2), and one H(3) atom. In the second O site, O(1) is bonded in a single-bond geometry to one Cl(1) atom. In the third O site, O(2) is bonded in a distorted bent 150 degrees geometry to one H(1) and one Cl(1) atom. In the fourth O site, O(3) is bonded in a single-bond geometry to one Cl(1) atom. Cl(1) is bonded in a tetrahedral geometry to one O(1), one O(2), and two equivalent O(3) atoms. is represented by the CIF card [CIF]
data_H3ClO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.321
_cell_length_b   7.535
_cell_length_c   8.705
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   414.563
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.250  0.537  0.182  1.0
  H  H1  1  0.250  0.963  0.682  1.0
  H  H2  1  0.750  0.463  0.818  1.0
  H  H3  1  0.750  0.037  0.318  1.0
  H  H4  1  0.250  0.737  0.758  1.0
  H  H5  1  0.250  0.908  0.878  1.0
  H  H6  1  0.250  0.763  0.258  1.0
  H  H7  1  0.250  0.592  0.378  1.0
  H  H8  1  0.750  0.092  0.122  1.0
  H  H9  1  0.750  0.263  0.242  1.0
  H  H10  1  0.750  0.408  0.622  1.0
  H  H11  1  0.750  0.237  0.742  1.0
  Cl  Cl12  1  0.250  0.312  0.948  1.0
  Cl  Cl13  1  0.250  0.188  0.448  1.0
  Cl  Cl14  1  0.750  0.688  0.052  1.0
  Cl  Cl15  1  0.750  0.812  0.552  1.0
  O  O16  1  0.250  0.462  0.845  1.0
  O  O17  1  0.250  0.038  0.345  1.0
  O  O18  1  0.750  0.538  0.155  1.0
  O  O19  1  0.750  0.962  0.655  1.0
  O  O20  1  0.250  0.375  0.111  1.0
  O  O21  1  0.250  0.125  0.611  1.0
  O  O22  1  0.750  0.625  0.889  1.0
  O  O23  1  0.750  0.875  0.389  1.0
  O  O24  1  0.062  0.203  0.929  1.0
  O  O25  1  0.438  0.297  0.429  1.0
  O  O26  1  0.562  0.797  0.071  1.0
  O  O27  1  0.938  0.703  0.571  1.0
  O  O28  1  0.938  0.797  0.071  1.0
  O  O29  1  0.562  0.703  0.571  1.0
  O  O30  1  0.438  0.203  0.929  1.0
  O  O31  1  0.062  0.297  0.429  1.0
  O  O32  1  0.250  0.865  0.772  1.0
  O  O33  1  0.250  0.635  0.272  1.0
  O  O34  1  0.750  0.135  0.228  1.0
  O  O35  1  0.750  0.365  0.728  1.0
[/CIF]
.