The structure described by Re(TeCl2)2 is Indium-like structured and crystallizes in the tetragonal I-4 space group. The structure is zero-dimensional and consists of two Re(TeCl2)2 clusters. Re(1) is bonded in a 2-coordinate geometry to one Te(2), three equivalent Te(1), one Cl(1), and one Cl(2) atom. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a 3-coordinate geometry to three equivalent Re(1) atoms. In the second Te site, Te(2) is bonded in a 5-coordinate geometry to one Re(1), one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in a single-bond geometry to one Te(2) atom. In the second Cl site, Cl(4) is bonded in a single-bond geometry to one Te(2) atom. In the third Cl site, Cl(1) is bonded in a 2-coordinate geometry to one Re(1) and one Te(2) atom. In the fourth Cl site, Cl(2) is bonded in a 2-coordinate geometry to one Re(1) and one Te(2) atom. is represented by the CIF card [CIF]
data_Re(TeCl2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.668
_cell_length_b   10.668
_cell_length_c   10.668
_cell_angle_alpha   116.656
_cell_angle_beta   116.656
_cell_angle_gamma   95.896
_symmetry_Int_Tables_number   1
_cell_volume   896.829
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.691  0.529  0.075  1.0
  Re  Re1  1  0.454  0.616  0.925  1.0
  Re  Re2  1  0.471  0.546  0.161  1.0
  Re  Re3  1  0.384  0.309  0.839  1.0
  Te  Te4  1  0.670  0.786  0.250  1.0
  Te  Te5  1  0.536  0.420  0.750  1.0
  Te  Te6  1  0.214  0.464  0.884  1.0
  Te  Te7  1  0.580  0.330  0.116  1.0
  Te  Te8  1  0.899  0.404  0.051  1.0
  Te  Te9  1  0.353  0.849  0.949  1.0
  Te  Te10  1  0.596  0.647  0.495  1.0
  Te  Te11  1  0.151  0.101  0.505  1.0
  Cl  Cl12  1  0.926  0.607  0.348  1.0
  Cl  Cl13  1  0.259  0.577  0.652  1.0
  Cl  Cl14  1  0.393  0.741  0.318  1.0
  Cl  Cl15  1  0.423  0.074  0.682  1.0
  Cl  Cl16  1  0.891  0.677  0.075  1.0
  Cl  Cl17  1  0.601  0.815  0.925  1.0
  Cl  Cl18  1  0.323  0.399  0.214  1.0
  Cl  Cl19  1  0.185  0.109  0.786  1.0
  Cl  Cl20  1  0.821  0.261  0.759  1.0
  Cl  Cl21  1  0.502  0.062  0.241  1.0
  Cl  Cl22  1  0.739  0.498  0.560  1.0
  Cl  Cl23  1  0.938  0.179  0.440  1.0
  Cl  Cl24  1  0.856  0.187  0.063  1.0
  Cl  Cl25  1  0.124  0.794  0.937  1.0
  Cl  Cl26  1  0.813  0.876  0.670  1.0
  Cl  Cl27  1  0.206  0.144  0.330  1.0
[/CIF]
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The structure described by Re(TeCl2)2 is Indium-like structured and crystallizes in the tetragonal I-4 space group. The structure is zero-dimensional and consists of two Re(TeCl2)2 clusters. Re(1) is bonded in a 2-coordinate geometry to one Te(2), three equivalent Te(1), one Cl(1), and one Cl(2) atom. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a 3-coordinate geometry to three equivalent Re(1) atoms. In the second Te site, Te(2) is bonded in a 5-coordinate geometry to one Re(1), one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in a single-bond geometry to one Te(2) atom. In the second Cl site, Cl(4) is bonded in a single-bond geometry to one Te(2) atom. In the third Cl site, Cl(1) is bonded in a 2-coordinate geometry to one Re(1) and one Te(2) atom. In the fourth Cl site, Cl(2) is bonded in a 2-coordinate geometry to one Re(1) and one Te(2) atom. is represented by the CIF card [CIF]
data_Re(TeCl2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.668
_cell_length_b   10.668
_cell_length_c   10.668
_cell_angle_alpha   116.656
_cell_angle_beta   116.656
_cell_angle_gamma   95.896
_symmetry_Int_Tables_number   1
_cell_volume   896.829
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.691  0.529  0.075  1.0
  Re  Re1  1  0.454  0.616  0.925  1.0
  Re  Re2  1  0.471  0.546  0.161  1.0
  Re  Re3  1  0.384  0.309  0.839  1.0
  Te  Te4  1  0.670  0.786  0.250  1.0
  Te  Te5  1  0.536  0.420  0.750  1.0
  Te  Te6  1  0.214  0.464  0.884  1.0
  Te  Te7  1  0.580  0.330  0.116  1.0
  Te  Te8  1  0.899  0.404  0.051  1.0
  Te  Te9  1  0.353  0.849  0.949  1.0
  Te  Te10  1  0.596  0.647  0.495  1.0
  Te  Te11  1  0.151  0.101  0.505  1.0
  Cl  Cl12  1  0.926  0.607  0.348  1.0
  Cl  Cl13  1  0.259  0.577  0.652  1.0
  Cl  Cl14  1  0.393  0.741  0.318  1.0
  Cl  Cl15  1  0.423  0.074  0.682  1.0
  Cl  Cl16  1  0.891  0.677  0.075  1.0
  Cl  Cl17  1  0.601  0.815  0.925  1.0
  Cl  Cl18  1  0.323  0.399  0.214  1.0
  Cl  Cl19  1  0.185  0.109  0.786  1.0
  Cl  Cl20  1  0.821  0.261  0.759  1.0
  Cl  Cl21  1  0.502  0.062  0.241  1.0
  Cl  Cl22  1  0.739  0.498  0.560  1.0
  Cl  Cl23  1  0.938  0.179  0.440  1.0
  Cl  Cl24  1  0.856  0.187  0.063  1.0
  Cl  Cl25  1  0.124  0.794  0.937  1.0
  Cl  Cl26  1  0.813  0.876  0.670  1.0
  Cl  Cl27  1  0.206  0.144  0.330  1.0
[/CIF]
.