The material structure described by RbNTeO3F4 crystallizes in the triclinic P-1 space group. There are two inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 10-coordinate geometry to one O(1), one O(2), one O(6), one F(1), one F(2), one F(3), one F(4), one F(5), one F(6), and one F(7) atom. In the second Rb site, Rb(2) is bonded in a 10-coordinate geometry to one O(2), one O(4), one O(6), one F(2), one F(4), one F(5), one F(6), one F(8), and two equivalent F(7) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(2), one O(3), and one O(6) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(1), one O(4), and one O(5) atom. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a 5-coordinate geometry to one O(4), one F(1), one F(3), one F(4), and one F(5) atom. In the second Te site, Te(2) is bonded in a distorted rectangular see-saw-like geometry to one F(2), one F(6), one F(7), and one F(8) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Rb(1) and one N(2) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(2), and one N(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one N(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Rb(2), one N(2), and one Te(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one N(2) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(2), and one N(1) atom. There are eight inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Rb(1) and one Te(1) atom. In the second F site, F(2) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(2), and one Te(2) atom. In the third F site, F(3) is bonded in a distorted single-bond geometry to one Rb(1) and one Te(1) atom. In the fourth F site, F(4) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(2), and one Te(1) atom. In the fifth F site, F(5) is bonded in a 3-coordinate geometry to one Rb(1), one Rb(2), and one Te(1) atom. In the sixth F site, F(6) is bonded in a 3-coordinate geometry to one Rb(1), one Rb(2), and one Te(2) atom. In the seventh F site, F(7) is bonded in a distorted single-bond geometry to one Rb(1), two equivalent Rb(2), and one Te(2) atom. In the eighth F site, F(8) is bonded in a distorted single-bond geometry to one Rb(2) and one Te(2) atom. is represented by the CIF card [CIF]
data_RbTeNO3F4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.210
_cell_length_b   8.367
_cell_length_c   10.796
_cell_angle_alpha   109.389
_cell_angle_beta   89.315
_cell_angle_gamma   108.019
_symmetry_Int_Tables_number   1
_cell_volume   661.839
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.117  0.259  0.778  1.0
  Rb  Rb1  1  0.599  0.234  0.852  1.0
  Rb  Rb2  1  0.401  0.766  0.148  1.0
  Rb  Rb3  1  0.883  0.741  0.222  1.0
  Te  Te4  1  0.180  0.760  0.539  1.0
  Te  Te5  1  0.684  0.758  0.829  1.0
  Te  Te6  1  0.316  0.242  0.171  1.0
  Te  Te7  1  0.820  0.240  0.461  1.0
  N  N8  1  0.016  0.674  0.873  1.0
  N  N9  1  0.482  0.330  0.539  1.0
  N  N10  1  0.518  0.670  0.461  1.0
  N  N11  1  0.984  0.326  0.127  1.0
  O  O12  1  0.369  0.394  0.588  1.0
  O  O13  1  0.631  0.606  0.412  1.0
  O  O14  1  0.149  0.640  0.894  1.0
  O  O15  1  0.019  0.795  0.826  1.0
  O  O16  1  0.368  0.618  0.392  1.0
  O  O17  1  0.464  0.217  0.424  1.0
  O  O18  1  0.132  0.416  0.102  1.0
  O  O19  1  0.632  0.382  0.608  1.0
  O  O20  1  0.981  0.205  0.174  1.0
  O  O21  1  0.851  0.360  0.106  1.0
  O  O22  1  0.536  0.783  0.576  1.0
  O  O23  1  0.868  0.584  0.898  1.0
  F  F24  1  0.014  0.156  0.425  1.0
  F  F25  1  0.268  0.143  0.982  1.0
  F  F26  1  0.989  0.440  0.605  1.0
  F  F27  1  0.011  0.560  0.395  1.0
  F  F28  1  0.784  0.139  0.598  1.0
  F  F29  1  0.309  0.016  0.650  1.0
  F  F30  1  0.812  0.013  0.846  1.0
  F  F31  1  0.986  0.844  0.575  1.0
  F  F32  1  0.188  0.987  0.154  1.0
  F  F33  1  0.509  0.565  0.879  1.0
  F  F34  1  0.732  0.857  0.018  1.0
  F  F35  1  0.495  0.853  0.846  1.0
  F  F36  1  0.505  0.147  0.154  1.0
  F  F37  1  0.691  0.984  0.350  1.0
  F  F38  1  0.491  0.435  0.121  1.0
  F  F39  1  0.216  0.861  0.402  1.0
[/CIF]
.
The material structure described by RbNTeO3F4 crystallizes in the triclinic P-1 space group. There are two inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 10-coordinate geometry to one O(1), one O(2), one O(6), one F(1), one F(2), one F(3), one F(4), one F(5), one F(6), and one F(7) atom. In the second Rb site, Rb(2) is bonded in a 10-coordinate geometry to one O(2), one O(4), one O(6), one F(2), one F(4), one F(5), one F(6), one F(8), and two equivalent F(7) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(2), one O(3), and one O(6) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(1), one O(4), and one O(5) atom. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a 5-coordinate geometry to one O(4), one F(1), one F(3), one F(4), and one F(5) atom. In the second Te site, Te(2) is bonded in a distorted rectangular see-saw-like geometry to one F(2), one F(6), one F(7), and one F(8) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Rb(1) and one N(2) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(2), and one N(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one N(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Rb(2), one N(2), and one Te(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one N(2) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(2), and one N(1) atom. There are eight inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Rb(1) and one Te(1) atom. In the second F site, F(2) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(2), and one Te(2) atom. In the third F site, F(3) is bonded in a distorted single-bond geometry to one Rb(1) and one Te(1) atom. In the fourth F site, F(4) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(2), and one Te(1) atom. In the fifth F site, F(5) is bonded in a 3-coordinate geometry to one Rb(1), one Rb(2), and one Te(1) atom. In the sixth F site, F(6) is bonded in a 3-coordinate geometry to one Rb(1), one Rb(2), and one Te(2) atom. In the seventh F site, F(7) is bonded in a distorted single-bond geometry to one Rb(1), two equivalent Rb(2), and one Te(2) atom. In the eighth F site, F(8) is bonded in a distorted single-bond geometry to one Rb(2) and one Te(2) atom. is represented by the CIF card [CIF]
data_RbTeNO3F4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.210
_cell_length_b   8.367
_cell_length_c   10.796
_cell_angle_alpha   109.389
_cell_angle_beta   89.315
_cell_angle_gamma   108.019
_symmetry_Int_Tables_number   1
_cell_volume   661.839
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.117  0.259  0.778  1.0
  Rb  Rb1  1  0.599  0.234  0.852  1.0
  Rb  Rb2  1  0.401  0.766  0.148  1.0
  Rb  Rb3  1  0.883  0.741  0.222  1.0
  Te  Te4  1  0.180  0.760  0.539  1.0
  Te  Te5  1  0.684  0.758  0.829  1.0
  Te  Te6  1  0.316  0.242  0.171  1.0
  Te  Te7  1  0.820  0.240  0.461  1.0
  N  N8  1  0.016  0.674  0.873  1.0
  N  N9  1  0.482  0.330  0.539  1.0
  N  N10  1  0.518  0.670  0.461  1.0
  N  N11  1  0.984  0.326  0.127  1.0
  O  O12  1  0.369  0.394  0.588  1.0
  O  O13  1  0.631  0.606  0.412  1.0
  O  O14  1  0.149  0.640  0.894  1.0
  O  O15  1  0.019  0.795  0.826  1.0
  O  O16  1  0.368  0.618  0.392  1.0
  O  O17  1  0.464  0.217  0.424  1.0
  O  O18  1  0.132  0.416  0.102  1.0
  O  O19  1  0.632  0.382  0.608  1.0
  O  O20  1  0.981  0.205  0.174  1.0
  O  O21  1  0.851  0.360  0.106  1.0
  O  O22  1  0.536  0.783  0.576  1.0
  O  O23  1  0.868  0.584  0.898  1.0
  F  F24  1  0.014  0.156  0.425  1.0
  F  F25  1  0.268  0.143  0.982  1.0
  F  F26  1  0.989  0.440  0.605  1.0
  F  F27  1  0.011  0.560  0.395  1.0
  F  F28  1  0.784  0.139  0.598  1.0
  F  F29  1  0.309  0.016  0.650  1.0
  F  F30  1  0.812  0.013  0.846  1.0
  F  F31  1  0.986  0.844  0.575  1.0
  F  F32  1  0.188  0.987  0.154  1.0
  F  F33  1  0.509  0.565  0.879  1.0
  F  F34  1  0.732  0.857  0.018  1.0
  F  F35  1  0.495  0.853  0.846  1.0
  F  F36  1  0.505  0.147  0.154  1.0
  F  F37  1  0.691  0.984  0.350  1.0
  F  F38  1  0.491  0.435  0.121  1.0
  F  F39  1  0.216  0.861  0.402  1.0
[/CIF]
.