The material described by (NH4)2PdCl6 is Fluorite structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four ammonium molecules and two PdCl6 clusters. In each PdCl6 cluster, Pd(1) is bonded in an octahedral geometry to two equivalent Cl(1), two equivalent Cl(2), and two equivalent Cl(3) atoms. There are three inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Pd(1) atom. In the second Cl site, Cl(3) is bonded in a single-bond geometry to one Pd(1) atom. In the third Cl site, Cl(1) is bonded in a single-bond geometry to one Pd(1) atom. is represented by the CIF card [CIF]
data_H8Pd(NCl3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.896
_cell_length_b   6.875
_cell_length_c   10.025
_cell_angle_alpha   90.000
_cell_angle_beta   90.012
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   475.305
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.851  0.524  0.253  1.0
  H  H1  1  0.351  0.976  0.753  1.0
  H  H2  1  0.149  0.476  0.747  1.0
  H  H3  1  0.649  0.024  0.247  1.0
  H  H4  1  0.061  0.557  0.335  1.0
  H  H5  1  0.561  0.943  0.835  1.0
  H  H6  1  0.939  0.443  0.665  1.0
  H  H7  1  0.439  0.057  0.165  1.0
  H  H8  1  0.021  0.351  0.250  1.0
  H  H9  1  0.521  0.149  0.750  1.0
  H  H10  1  0.979  0.649  0.750  1.0
  H  H11  1  0.479  0.851  0.250  1.0
  H  H12  1  0.058  0.561  0.168  1.0
  H  H13  1  0.558  0.939  0.668  1.0
  H  H14  1  0.942  0.439  0.832  1.0
  H  H15  1  0.442  0.061  0.332  1.0
  Pd  Pd16  1  0.500  0.500  0.500  1.0
  Pd  Pd17  1  0.000  0.000  0.000  1.0
  N  N18  1  0.998  0.499  0.251  1.0
  N  N19  1  0.498  0.001  0.751  1.0
  N  N20  1  0.002  0.501  0.749  1.0
  N  N21  1  0.502  0.999  0.249  1.0
  Cl  Cl22  1  0.240  0.714  0.497  1.0
  Cl  Cl23  1  0.740  0.786  0.997  1.0
  Cl  Cl24  1  0.760  0.286  0.503  1.0
  Cl  Cl25  1  0.260  0.214  0.003  1.0
  Cl  Cl26  1  0.286  0.239  0.494  1.0
  Cl  Cl27  1  0.786  0.261  0.994  1.0
  Cl  Cl28  1  0.714  0.761  0.506  1.0
  Cl  Cl29  1  0.214  0.739  0.006  1.0
  Cl  Cl30  1  0.509  0.506  0.268  1.0
  Cl  Cl31  1  0.009  0.994  0.768  1.0
  Cl  Cl32  1  0.491  0.494  0.732  1.0
  Cl  Cl33  1  0.991  0.006  0.232  1.0
[/CIF]
.
The material described by (NH4)2PdCl6 is Fluorite structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four ammonium molecules and two PdCl6 clusters. In each PdCl6 cluster, Pd(1) is bonded in an octahedral geometry to two equivalent Cl(1), two equivalent Cl(2), and two equivalent Cl(3) atoms. There are three inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Pd(1) atom. In the second Cl site, Cl(3) is bonded in a single-bond geometry to one Pd(1) atom. In the third Cl site, Cl(1) is bonded in a single-bond geometry to one Pd(1) atom. is represented by the CIF card [CIF]
data_H8Pd(NCl3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.896
_cell_length_b   6.875
_cell_length_c   10.025
_cell_angle_alpha   90.000
_cell_angle_beta   90.012
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   475.305
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.851  0.524  0.253  1.0
  H  H1  1  0.351  0.976  0.753  1.0
  H  H2  1  0.149  0.476  0.747  1.0
  H  H3  1  0.649  0.024  0.247  1.0
  H  H4  1  0.061  0.557  0.335  1.0
  H  H5  1  0.561  0.943  0.835  1.0
  H  H6  1  0.939  0.443  0.665  1.0
  H  H7  1  0.439  0.057  0.165  1.0
  H  H8  1  0.021  0.351  0.250  1.0
  H  H9  1  0.521  0.149  0.750  1.0
  H  H10  1  0.979  0.649  0.750  1.0
  H  H11  1  0.479  0.851  0.250  1.0
  H  H12  1  0.058  0.561  0.168  1.0
  H  H13  1  0.558  0.939  0.668  1.0
  H  H14  1  0.942  0.439  0.832  1.0
  H  H15  1  0.442  0.061  0.332  1.0
  Pd  Pd16  1  0.500  0.500  0.500  1.0
  Pd  Pd17  1  0.000  0.000  0.000  1.0
  N  N18  1  0.998  0.499  0.251  1.0
  N  N19  1  0.498  0.001  0.751  1.0
  N  N20  1  0.002  0.501  0.749  1.0
  N  N21  1  0.502  0.999  0.249  1.0
  Cl  Cl22  1  0.240  0.714  0.497  1.0
  Cl  Cl23  1  0.740  0.786  0.997  1.0
  Cl  Cl24  1  0.760  0.286  0.503  1.0
  Cl  Cl25  1  0.260  0.214  0.003  1.0
  Cl  Cl26  1  0.286  0.239  0.494  1.0
  Cl  Cl27  1  0.786  0.261  0.994  1.0
  Cl  Cl28  1  0.714  0.761  0.506  1.0
  Cl  Cl29  1  0.214  0.739  0.006  1.0
  Cl  Cl30  1  0.509  0.506  0.268  1.0
  Cl  Cl31  1  0.009  0.994  0.768  1.0
  Cl  Cl32  1  0.491  0.494  0.732  1.0
  Cl  Cl33  1  0.991  0.006  0.232  1.0
[/CIF]
.