The material structure described by RhC5NH9O5 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one RhC5NH9O5 cluster. Rh(1) is bonded in a distorted square pyramidal geometry to one O(1), one O(2), one O(3), one O(4), and one O(5) atom. There are five inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one H(1), one O(1), and one O(3) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one H(2), one O(2), and one O(4) atom. In the third C site, C(3) is bonded in a trigonal planar geometry to one N(1), one H(3), and one O(5) atom. In the fourth C site, C(4) is bonded to one N(1), one H(4), one H(5), and one H(6) atom to form corner-sharing CH3N tetrahedra. In the fifth C site, C(5) is bonded to one N(1), one H(7), one H(8), and one H(9) atom to form corner-sharing CH3N tetrahedra. N(1) is bonded in a trigonal planar geometry to one C(3), one C(4), and one C(5) atom. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(4) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(5) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(5) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(5) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Rh(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Rh(1) and one C(2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Rh(1) and one C(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Rh(1) and one C(2) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Rh(1) and one C(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_H9RhC5NO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.793
_cell_length_b   7.822
_cell_length_c   10.245
_cell_angle_alpha   97.796
_cell_angle_beta   100.692
_cell_angle_gamma   111.565
_symmetry_Int_Tables_number   1
_cell_volume   484.955
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.582  0.662  0.135  1.0
  H  H1  1  0.418  0.338  0.865  1.0
  H  H2  1  0.215  0.629  0.947  1.0
  H  H3  1  0.785  0.371  0.053  1.0
  H  H4  1  0.396  0.867  0.725  1.0
  H  H5  1  0.604  0.133  0.275  1.0
  H  H6  1  0.555  0.730  0.419  1.0
  H  H7  1  0.445  0.270  0.581  1.0
  H  H8  1  0.297  0.533  0.371  1.0
  H  H9  1  0.703  0.467  0.629  1.0
  H  H10  1  0.322  0.744  0.314  1.0
  H  H11  1  0.678  0.256  0.686  1.0
  H  H12  1  0.088  0.822  0.601  1.0
  H  H13  1  0.912  0.178  0.399  1.0
  H  H14  1  0.105  0.875  0.438  1.0
  H  H15  1  0.895  0.125  0.562  1.0
  H  H16  1  0.979  0.636  0.453  1.0
  H  H17  1  0.021  0.364  0.547  1.0
  Rh  Rh18  1  0.878  0.936  0.886  1.0
  Rh  Rh19  1  0.122  0.064  0.114  1.0
  C  C20  1  0.704  0.765  0.096  1.0
  C  C21  1  0.296  0.235  0.904  1.0
  C  C22  1  0.153  0.741  0.961  1.0
  C  C23  1  0.847  0.259  0.039  1.0
  C  C24  1  0.463  0.817  0.644  1.0
  C  C25  1  0.537  0.183  0.356  1.0
  C  C26  1  0.378  0.688  0.399  1.0
  C  C27  1  0.622  0.312  0.601  1.0
  C  C28  1  0.113  0.775  0.502  1.0
  C  C29  1  0.887  0.225  0.498  1.0
  N  N30  1  0.324  0.761  0.520  1.0
  N  N31  1  0.676  0.239  0.480  1.0
  O  O32  1  0.653  0.754  0.968  1.0
  O  O33  1  0.347  0.246  0.032  1.0
  O  O34  1  0.010  0.738  0.860  1.0
  O  O35  1  0.990  0.262  0.140  1.0
  O  O36  1  0.121  0.121  0.816  1.0
  O  O37  1  0.879  0.879  0.184  1.0
  O  O38  1  0.764  0.143  0.923  1.0
  O  O39  1  0.236  0.857  0.077  1.0
  O  O40  1  0.650  0.814  0.668  1.0
  O  O41  1  0.350  0.186  0.332  1.0
[/CIF]
.
The material structure described by RhC5NH9O5 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one RhC5NH9O5 cluster. Rh(1) is bonded in a distorted square pyramidal geometry to one O(1), one O(2), one O(3), one O(4), and one O(5) atom. There are five inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one H(1), one O(1), and one O(3) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one H(2), one O(2), and one O(4) atom. In the third C site, C(3) is bonded in a trigonal planar geometry to one N(1), one H(3), and one O(5) atom. In the fourth C site, C(4) is bonded to one N(1), one H(4), one H(5), and one H(6) atom to form corner-sharing CH3N tetrahedra. In the fifth C site, C(5) is bonded to one N(1), one H(7), one H(8), and one H(9) atom to form corner-sharing CH3N tetrahedra. N(1) is bonded in a trigonal planar geometry to one C(3), one C(4), and one C(5) atom. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(4) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(5) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(5) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(5) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Rh(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Rh(1) and one C(2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Rh(1) and one C(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Rh(1) and one C(2) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Rh(1) and one C(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_H9RhC5NO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.793
_cell_length_b   7.822
_cell_length_c   10.245
_cell_angle_alpha   97.796
_cell_angle_beta   100.692
_cell_angle_gamma   111.565
_symmetry_Int_Tables_number   1
_cell_volume   484.955
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.582  0.662  0.135  1.0
  H  H1  1  0.418  0.338  0.865  1.0
  H  H2  1  0.215  0.629  0.947  1.0
  H  H3  1  0.785  0.371  0.053  1.0
  H  H4  1  0.396  0.867  0.725  1.0
  H  H5  1  0.604  0.133  0.275  1.0
  H  H6  1  0.555  0.730  0.419  1.0
  H  H7  1  0.445  0.270  0.581  1.0
  H  H8  1  0.297  0.533  0.371  1.0
  H  H9  1  0.703  0.467  0.629  1.0
  H  H10  1  0.322  0.744  0.314  1.0
  H  H11  1  0.678  0.256  0.686  1.0
  H  H12  1  0.088  0.822  0.601  1.0
  H  H13  1  0.912  0.178  0.399  1.0
  H  H14  1  0.105  0.875  0.438  1.0
  H  H15  1  0.895  0.125  0.562  1.0
  H  H16  1  0.979  0.636  0.453  1.0
  H  H17  1  0.021  0.364  0.547  1.0
  Rh  Rh18  1  0.878  0.936  0.886  1.0
  Rh  Rh19  1  0.122  0.064  0.114  1.0
  C  C20  1  0.704  0.765  0.096  1.0
  C  C21  1  0.296  0.235  0.904  1.0
  C  C22  1  0.153  0.741  0.961  1.0
  C  C23  1  0.847  0.259  0.039  1.0
  C  C24  1  0.463  0.817  0.644  1.0
  C  C25  1  0.537  0.183  0.356  1.0
  C  C26  1  0.378  0.688  0.399  1.0
  C  C27  1  0.622  0.312  0.601  1.0
  C  C28  1  0.113  0.775  0.502  1.0
  C  C29  1  0.887  0.225  0.498  1.0
  N  N30  1  0.324  0.761  0.520  1.0
  N  N31  1  0.676  0.239  0.480  1.0
  O  O32  1  0.653  0.754  0.968  1.0
  O  O33  1  0.347  0.246  0.032  1.0
  O  O34  1  0.010  0.738  0.860  1.0
  O  O35  1  0.990  0.262  0.140  1.0
  O  O36  1  0.121  0.121  0.816  1.0
  O  O37  1  0.879  0.879  0.184  1.0
  O  O38  1  0.764  0.143  0.923  1.0
  O  O39  1  0.236  0.857  0.077  1.0
  O  O40  1  0.650  0.814  0.668  1.0
  O  O41  1  0.350  0.186  0.332  1.0
[/CIF]
.