The structure described by N2S3AsF6 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four AsF6 clusters and four N2S3 clusters. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. There are six inequivalent F sites. In the first F site, F(5) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(6) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(3) is bonded in a single-bond geometry to one As(1) atom. In the sixth F site, F(4) is bonded in a single-bond geometry to one As(1) atom. In each N2S3 cluster, there are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one S(2) and one S(3) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a single-bond geometry to one N(2) atom. In the second S site, S(2) is bonded in a water-like geometry to one N(1) and one N(2) atom. In the third S site, S(3) is bonded in a single-bond geometry to one N(1) atom. is represented by the CIF card [CIF]
data_AsS3(NF3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.503
_cell_length_b   8.632
_cell_length_c   11.417
_cell_angle_alpha   84.317
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   833.907
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.105  0.732  0.127  1.0
  As  As1  1  0.605  0.268  0.373  1.0
  As  As2  1  0.895  0.268  0.873  1.0
  As  As3  1  0.395  0.732  0.627  1.0
  S  S4  1  0.650  0.962  0.113  1.0
  S  S5  1  0.431  0.351  0.859  1.0
  S  S6  1  0.350  0.038  0.887  1.0
  S  S7  1  0.631  0.854  0.944  1.0
  S  S8  1  0.131  0.146  0.556  1.0
  S  S9  1  0.369  0.146  0.056  1.0
  S  S10  1  0.931  0.649  0.641  1.0
  S  S11  1  0.850  0.962  0.613  1.0
  S  S12  1  0.869  0.854  0.444  1.0
  S  S13  1  0.569  0.649  0.141  1.0
  S  S14  1  0.150  0.038  0.387  1.0
  S  S15  1  0.069  0.351  0.359  1.0
  N  N16  1  0.913  0.684  0.503  1.0
  N  N17  1  0.587  0.684  0.003  1.0
  N  N18  1  0.390  0.194  0.805  1.0
  N  N19  1  0.087  0.316  0.497  1.0
  N  N20  1  0.890  0.806  0.695  1.0
  N  N21  1  0.110  0.194  0.305  1.0
  N  N22  1  0.413  0.316  0.997  1.0
  N  N23  1  0.610  0.806  0.195  1.0
  F  F24  1  0.719  0.159  0.922  1.0
  F  F25  1  0.219  0.841  0.578  1.0
  F  F26  1  0.980  0.091  0.837  1.0
  F  F27  1  0.813  0.294  0.730  1.0
  F  F28  1  0.520  0.091  0.337  1.0
  F  F29  1  0.281  0.841  0.078  1.0
  F  F30  1  0.566  0.629  0.677  1.0
  F  F31  1  0.934  0.629  0.177  1.0
  F  F32  1  0.528  0.236  0.517  1.0
  F  F33  1  0.472  0.764  0.483  1.0
  F  F34  1  0.480  0.909  0.663  1.0
  F  F35  1  0.972  0.236  0.017  1.0
  F  F36  1  0.302  0.559  0.593  1.0
  F  F37  1  0.198  0.559  0.093  1.0
  F  F38  1  0.187  0.706  0.270  1.0
  F  F39  1  0.687  0.294  0.230  1.0
  F  F40  1  0.781  0.159  0.422  1.0
  F  F41  1  0.434  0.371  0.323  1.0
  F  F42  1  0.802  0.441  0.907  1.0
  F  F43  1  0.028  0.764  0.983  1.0
  F  F44  1  0.066  0.371  0.823  1.0
  F  F45  1  0.313  0.706  0.770  1.0
  F  F46  1  0.020  0.909  0.163  1.0
  F  F47  1  0.698  0.441  0.407  1.0
[/CIF]
.
The structure described by N2S3AsF6 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four AsF6 clusters and four N2S3 clusters. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. There are six inequivalent F sites. In the first F site, F(5) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(6) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(3) is bonded in a single-bond geometry to one As(1) atom. In the sixth F site, F(4) is bonded in a single-bond geometry to one As(1) atom. In each N2S3 cluster, there are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one S(2) and one S(3) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a single-bond geometry to one N(2) atom. In the second S site, S(2) is bonded in a water-like geometry to one N(1) and one N(2) atom. In the third S site, S(3) is bonded in a single-bond geometry to one N(1) atom. is represented by the CIF card [CIF]
data_AsS3(NF3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.503
_cell_length_b   8.632
_cell_length_c   11.417
_cell_angle_alpha   84.317
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   833.907
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.105  0.732  0.127  1.0
  As  As1  1  0.605  0.268  0.373  1.0
  As  As2  1  0.895  0.268  0.873  1.0
  As  As3  1  0.395  0.732  0.627  1.0
  S  S4  1  0.650  0.962  0.113  1.0
  S  S5  1  0.431  0.351  0.859  1.0
  S  S6  1  0.350  0.038  0.887  1.0
  S  S7  1  0.631  0.854  0.944  1.0
  S  S8  1  0.131  0.146  0.556  1.0
  S  S9  1  0.369  0.146  0.056  1.0
  S  S10  1  0.931  0.649  0.641  1.0
  S  S11  1  0.850  0.962  0.613  1.0
  S  S12  1  0.869  0.854  0.444  1.0
  S  S13  1  0.569  0.649  0.141  1.0
  S  S14  1  0.150  0.038  0.387  1.0
  S  S15  1  0.069  0.351  0.359  1.0
  N  N16  1  0.913  0.684  0.503  1.0
  N  N17  1  0.587  0.684  0.003  1.0
  N  N18  1  0.390  0.194  0.805  1.0
  N  N19  1  0.087  0.316  0.497  1.0
  N  N20  1  0.890  0.806  0.695  1.0
  N  N21  1  0.110  0.194  0.305  1.0
  N  N22  1  0.413  0.316  0.997  1.0
  N  N23  1  0.610  0.806  0.195  1.0
  F  F24  1  0.719  0.159  0.922  1.0
  F  F25  1  0.219  0.841  0.578  1.0
  F  F26  1  0.980  0.091  0.837  1.0
  F  F27  1  0.813  0.294  0.730  1.0
  F  F28  1  0.520  0.091  0.337  1.0
  F  F29  1  0.281  0.841  0.078  1.0
  F  F30  1  0.566  0.629  0.677  1.0
  F  F31  1  0.934  0.629  0.177  1.0
  F  F32  1  0.528  0.236  0.517  1.0
  F  F33  1  0.472  0.764  0.483  1.0
  F  F34  1  0.480  0.909  0.663  1.0
  F  F35  1  0.972  0.236  0.017  1.0
  F  F36  1  0.302  0.559  0.593  1.0
  F  F37  1  0.198  0.559  0.093  1.0
  F  F38  1  0.187  0.706  0.270  1.0
  F  F39  1  0.687  0.294  0.230  1.0
  F  F40  1  0.781  0.159  0.422  1.0
  F  F41  1  0.434  0.371  0.323  1.0
  F  F42  1  0.802  0.441  0.907  1.0
  F  F43  1  0.028  0.764  0.983  1.0
  F  F44  1  0.066  0.371  0.823  1.0
  F  F45  1  0.313  0.706  0.770  1.0
  F  F46  1  0.020  0.909  0.163  1.0
  F  F47  1  0.698  0.441  0.407  1.0
[/CIF]
.