The structure described by Na3RuN2 crystallizes in the cubic Ia-3 space group. Na(1) is bonded in a 3-coordinate geometry to one N(1) and two equivalent N(2) atoms. Ru(1) is bonded to one N(1) and three equivalent N(2) atoms to form corner-sharing RuN4 tetrahedra. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted hexagonal bipyramidal geometry to six equivalent Na(1) and two equivalent Ru(1) atoms. In the second N site, N(2) is bonded in a 6-coordinate geometry to four equivalent Na(1) and two equivalent Ru(1) atoms. is represented by the CIF file [CIF]
data_Na3RuN2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.487
_cell_length_b   10.955
_cell_length_c   10.955
_cell_angle_alpha   90.000
_cell_angle_beta   125.264
_cell_angle_gamma   54.736
_symmetry_Int_Tables_number   1
_cell_volume   657.402
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.192  0.064  0.956  1.0
  Na  Na1  1  0.808  0.756  0.544  1.0
  Na  Na2  1  0.808  0.436  0.764  1.0
  Na  Na3  1  0.192  0.744  0.736  1.0
  Na  Na4  1  0.280  0.764  0.301  1.0
  Na  Na5  1  0.720  0.736  0.020  1.0
  Na  Na6  1  0.280  0.956  0.480  1.0
  Na  Na7  1  0.720  0.544  0.199  1.0
  Na  Na8  1  0.679  0.020  0.744  1.0
  Na  Na9  1  0.679  0.301  0.436  1.0
  Na  Na10  1  0.321  0.199  0.756  1.0
  Na  Na11  1  0.321  0.480  0.064  1.0
  Na  Na12  1  0.808  0.936  0.044  1.0
  Na  Na13  1  0.192  0.244  0.456  1.0
  Na  Na14  1  0.192  0.564  0.236  1.0
  Na  Na15  1  0.808  0.256  0.264  1.0
  Na  Na16  1  0.720  0.236  0.699  1.0
  Na  Na17  1  0.280  0.264  0.980  1.0
  Na  Na18  1  0.720  0.044  0.520  1.0
  Na  Na19  1  0.280  0.456  0.801  1.0
  Na  Na20  1  0.321  0.980  0.256  1.0
  Na  Na21  1  0.321  0.699  0.564  1.0
  Na  Na22  1  0.679  0.801  0.244  1.0
  Na  Na23  1  0.679  0.520  0.936  1.0
  Ru  Ru24  1  0.203  0.000  0.703  1.0
  Ru  Ru25  1  0.797  0.703  0.797  1.0
  Ru  Ru26  1  0.797  0.500  0.500  1.0
  Ru  Ru27  1  0.203  0.797  0.000  1.0
  Ru  Ru28  1  0.797  0.000  0.297  1.0
  Ru  Ru29  1  0.203  0.297  0.203  1.0
  Ru  Ru30  1  0.203  0.500  0.500  1.0
  Ru  Ru31  1  0.797  0.203  0.000  1.0
  N  N32  1  0.000  0.000  0.500  1.0
  N  N33  1  0.000  0.500  0.000  1.0
  N  N34  1  0.000  0.500  0.500  1.0
  N  N35  1  0.000  0.000  0.000  1.0
  N  N36  1  0.500  0.933  0.750  1.0
  N  N37  1  0.500  0.567  0.250  1.0
  N  N38  1  0.000  0.250  0.683  1.0
  N  N39  1  0.000  0.750  0.817  1.0
  N  N40  1  0.633  0.683  0.567  1.0
  N  N41  1  0.367  0.817  0.933  1.0
  N  N42  1  0.500  0.067  0.250  1.0
  N  N43  1  0.500  0.433  0.750  1.0
  N  N44  1  0.000  0.750  0.317  1.0
  N  N45  1  0.000  0.250  0.183  1.0
  N  N46  1  0.367  0.317  0.433  1.0
  N  N47  1  0.633  0.183  0.067  1.0
[/CIF]
.
The structure described by Na3RuN2 crystallizes in the cubic Ia-3 space group. Na(1) is bonded in a 3-coordinate geometry to one N(1) and two equivalent N(2) atoms. Ru(1) is bonded to one N(1) and three equivalent N(2) atoms to form corner-sharing RuN4 tetrahedra. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted hexagonal bipyramidal geometry to six equivalent Na(1) and two equivalent Ru(1) atoms. In the second N site, N(2) is bonded in a 6-coordinate geometry to four equivalent Na(1) and two equivalent Ru(1) atoms. is represented by the CIF file [CIF]
data_Na3RuN2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.487
_cell_length_b   10.955
_cell_length_c   10.955
_cell_angle_alpha   90.000
_cell_angle_beta   125.264
_cell_angle_gamma   54.736
_symmetry_Int_Tables_number   1
_cell_volume   657.402
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.192  0.064  0.956  1.0
  Na  Na1  1  0.808  0.756  0.544  1.0
  Na  Na2  1  0.808  0.436  0.764  1.0
  Na  Na3  1  0.192  0.744  0.736  1.0
  Na  Na4  1  0.280  0.764  0.301  1.0
  Na  Na5  1  0.720  0.736  0.020  1.0
  Na  Na6  1  0.280  0.956  0.480  1.0
  Na  Na7  1  0.720  0.544  0.199  1.0
  Na  Na8  1  0.679  0.020  0.744  1.0
  Na  Na9  1  0.679  0.301  0.436  1.0
  Na  Na10  1  0.321  0.199  0.756  1.0
  Na  Na11  1  0.321  0.480  0.064  1.0
  Na  Na12  1  0.808  0.936  0.044  1.0
  Na  Na13  1  0.192  0.244  0.456  1.0
  Na  Na14  1  0.192  0.564  0.236  1.0
  Na  Na15  1  0.808  0.256  0.264  1.0
  Na  Na16  1  0.720  0.236  0.699  1.0
  Na  Na17  1  0.280  0.264  0.980  1.0
  Na  Na18  1  0.720  0.044  0.520  1.0
  Na  Na19  1  0.280  0.456  0.801  1.0
  Na  Na20  1  0.321  0.980  0.256  1.0
  Na  Na21  1  0.321  0.699  0.564  1.0
  Na  Na22  1  0.679  0.801  0.244  1.0
  Na  Na23  1  0.679  0.520  0.936  1.0
  Ru  Ru24  1  0.203  0.000  0.703  1.0
  Ru  Ru25  1  0.797  0.703  0.797  1.0
  Ru  Ru26  1  0.797  0.500  0.500  1.0
  Ru  Ru27  1  0.203  0.797  0.000  1.0
  Ru  Ru28  1  0.797  0.000  0.297  1.0
  Ru  Ru29  1  0.203  0.297  0.203  1.0
  Ru  Ru30  1  0.203  0.500  0.500  1.0
  Ru  Ru31  1  0.797  0.203  0.000  1.0
  N  N32  1  0.000  0.000  0.500  1.0
  N  N33  1  0.000  0.500  0.000  1.0
  N  N34  1  0.000  0.500  0.500  1.0
  N  N35  1  0.000  0.000  0.000  1.0
  N  N36  1  0.500  0.933  0.750  1.0
  N  N37  1  0.500  0.567  0.250  1.0
  N  N38  1  0.000  0.250  0.683  1.0
  N  N39  1  0.000  0.750  0.817  1.0
  N  N40  1  0.633  0.683  0.567  1.0
  N  N41  1  0.367  0.817  0.933  1.0
  N  N42  1  0.500  0.067  0.250  1.0
  N  N43  1  0.500  0.433  0.750  1.0
  N  N44  1  0.000  0.750  0.317  1.0
  N  N45  1  0.000  0.250  0.183  1.0
  N  N46  1  0.367  0.317  0.433  1.0
  N  N47  1  0.633  0.183  0.067  1.0
[/CIF]
.