The structure described by VTl3O4 crystallizes in the orthorhombic Imm2 space group. V(1) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent O(2) atoms. There are two inequivalent Tl sites. In the first Tl site, Tl(1) is bonded in a 3-coordinate geometry to one O(1) and two equivalent O(2) atoms. In the second Tl site, Tl(2) is bonded in a 4-coordinate geometry to two equivalent O(1) and two equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 1-coordinate geometry to one V(1), one Tl(1), and one Tl(2) atom. In the second O site, O(2) is bonded in a distorted rectangular see-saw-like geometry to one V(1), one Tl(2), and two equivalent Tl(1) atoms. is represented by the CIF file [CIF]
data_Tl3VO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.896
_cell_length_b   6.004
_cell_length_c   6.004
_cell_angle_alpha   65.204
_cell_angle_beta   60.590
_cell_angle_gamma   60.590
_symmetry_Int_Tables_number   1
_cell_volume   156.758
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.765  0.762  0.709  1.0
  Tl  Tl1  1  0.000  0.049  0.951  1.0
  Tl  Tl2  1  0.235  0.291  0.238  1.0
  V  V3  1  0.500  0.509  0.491  1.0
  O  O4  1  0.327  0.831  0.514  1.0
  O  O5  1  0.673  0.486  0.169  1.0
  O  O6  1  0.746  0.362  0.638  1.0
  O  O7  1  0.254  0.362  0.638  1.0
[/CIF]
.
The structure described by VTl3O4 crystallizes in the orthorhombic Imm2 space group. V(1) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent O(2) atoms. There are two inequivalent Tl sites. In the first Tl site, Tl(1) is bonded in a 3-coordinate geometry to one O(1) and two equivalent O(2) atoms. In the second Tl site, Tl(2) is bonded in a 4-coordinate geometry to two equivalent O(1) and two equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 1-coordinate geometry to one V(1), one Tl(1), and one Tl(2) atom. In the second O site, O(2) is bonded in a distorted rectangular see-saw-like geometry to one V(1), one Tl(2), and two equivalent Tl(1) atoms. is represented by the CIF file [CIF]
data_Tl3VO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.896
_cell_length_b   6.004
_cell_length_c   6.004
_cell_angle_alpha   65.204
_cell_angle_beta   60.590
_cell_angle_gamma   60.590
_symmetry_Int_Tables_number   1
_cell_volume   156.758
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.765  0.762  0.709  1.0
  Tl  Tl1  1  0.000  0.049  0.951  1.0
  Tl  Tl2  1  0.235  0.291  0.238  1.0
  V  V3  1  0.500  0.509  0.491  1.0
  O  O4  1  0.327  0.831  0.514  1.0
  O  O5  1  0.673  0.486  0.169  1.0
  O  O6  1  0.746  0.362  0.638  1.0
  O  O7  1  0.254  0.362  0.638  1.0
[/CIF]
.