The structure described by CdV2O6 crystallizes in the monoclinic C2/m space group. V(1) is bonded in a 5-coordinate geometry to one O(1), one O(3), and three equivalent O(2) atoms. Cd(1) is bonded to two equivalent O(1) and four equivalent O(3) atoms to form edge-sharing CdO6 octahedra. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one V(1) and one Cd(1) atom. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to three equivalent V(1) atoms. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one V(1) and two equivalent Cd(1) atoms. is represented by the CIF file [CIF]
data_V2CdO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.600
_cell_length_b   5.252
_cell_length_c   7.091
_cell_angle_alpha   102.308
_cell_angle_beta   90.024
_cell_angle_gamma   110.010
_symmetry_Int_Tables_number   1
_cell_volume   122.707
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.233  0.466  0.673  1.0
  V  V1  1  0.767  0.534  0.327  1.0
  Cd  Cd2  1  1.000  0.000  1.000  1.0
  O  O3  1  0.081  0.160  0.729  1.0
  O  O4  1  0.249  0.498  0.397  1.0
  O  O5  1  0.751  0.502  0.603  1.0
  O  O6  1  0.359  0.718  0.879  1.0
  O  O7  1  0.641  0.282  0.121  1.0
  O  O8  1  0.919  0.839  0.271  1.0
[/CIF]
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The structure described by CdV2O6 crystallizes in the monoclinic C2/m space group. V(1) is bonded in a 5-coordinate geometry to one O(1), one O(3), and three equivalent O(2) atoms. Cd(1) is bonded to two equivalent O(1) and four equivalent O(3) atoms to form edge-sharing CdO6 octahedra. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one V(1) and one Cd(1) atom. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to three equivalent V(1) atoms. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one V(1) and two equivalent Cd(1) atoms. is represented by the CIF file [CIF]
data_V2CdO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.600
_cell_length_b   5.252
_cell_length_c   7.091
_cell_angle_alpha   102.308
_cell_angle_beta   90.024
_cell_angle_gamma   110.010
_symmetry_Int_Tables_number   1
_cell_volume   122.707
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.233  0.466  0.673  1.0
  V  V1  1  0.767  0.534  0.327  1.0
  Cd  Cd2  1  1.000  0.000  1.000  1.0
  O  O3  1  0.081  0.160  0.729  1.0
  O  O4  1  0.249  0.498  0.397  1.0
  O  O5  1  0.751  0.502  0.603  1.0
  O  O6  1  0.359  0.718  0.879  1.0
  O  O7  1  0.641  0.282  0.121  1.0
  O  O8  1  0.919  0.839  0.271  1.0
[/CIF]
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