The structure described by RbAgCl3 is (Cubic) Perovskite structured and crystallizes in the monoclinic Pm space group. Rb(1) is bonded to four equivalent Cl(1), four equivalent Cl(2), and four equivalent Cl(3) atoms to form RbCl12 cuboctahedra that share corners with twelve equivalent Rb(1)Cl12 cuboctahedra, faces with six equivalent Rb(1)Cl12 cuboctahedra, and faces with eight equivalent Ag(1)Cl6 octahedra. Ag(1) is bonded to two equivalent Cl(1), two equivalent Cl(2), and two equivalent Cl(3) atoms to form AgCl6 octahedra that share corners with six equivalent Ag(1)Cl6 octahedra and faces with eight equivalent Rb(1)Cl12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded to four equivalent Rb(1) and two equivalent Ag(1) atoms to form a mixture of distorted edge, face, and corner-sharing ClRb4Ag2 octahedra. The corner-sharing octahedral tilt angles range from 0-61°. In the second Cl site, Cl(2) is bonded to four equivalent Rb(1) and two equivalent Ag(1) atoms to form a mixture of distorted edge, face, and corner-sharing ClRb4Ag2 octahedra. The corner-sharing octahedral tilt angles range from 1-61°. In the third Cl site, Cl(3) is bonded to four equivalent Rb(1) and two equivalent Ag(1) atoms to form a mixture of distorted edge, face, and corner-sharing ClRb4Ag2 octahedra. The corner-sharing octahedral tilt angles range from 1-61°. is represented by the CIF file [CIF]
data_RbAgCl3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.165
_cell_length_b   5.167
_cell_length_c   5.169
_cell_angle_alpha   89.937
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   137.971
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.000  1.000  0.995  1.0
  Ag  Ag1  1  0.500  0.503  0.486  1.0
  Cl  Cl2  1  0.000  0.505  0.486  1.0
  Cl  Cl3  1  0.500  0.498  0.986  1.0
  Cl  Cl4  1  0.500  0.003  0.488  1.0
[/CIF]
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The structure described by RbAgCl3 is (Cubic) Perovskite structured and crystallizes in the monoclinic Pm space group. Rb(1) is bonded to four equivalent Cl(1), four equivalent Cl(2), and four equivalent Cl(3) atoms to form RbCl12 cuboctahedra that share corners with twelve equivalent Rb(1)Cl12 cuboctahedra, faces with six equivalent Rb(1)Cl12 cuboctahedra, and faces with eight equivalent Ag(1)Cl6 octahedra. Ag(1) is bonded to two equivalent Cl(1), two equivalent Cl(2), and two equivalent Cl(3) atoms to form AgCl6 octahedra that share corners with six equivalent Ag(1)Cl6 octahedra and faces with eight equivalent Rb(1)Cl12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded to four equivalent Rb(1) and two equivalent Ag(1) atoms to form a mixture of distorted edge, face, and corner-sharing ClRb4Ag2 octahedra. The corner-sharing octahedral tilt angles range from 0-61°. In the second Cl site, Cl(2) is bonded to four equivalent Rb(1) and two equivalent Ag(1) atoms to form a mixture of distorted edge, face, and corner-sharing ClRb4Ag2 octahedra. The corner-sharing octahedral tilt angles range from 1-61°. In the third Cl site, Cl(3) is bonded to four equivalent Rb(1) and two equivalent Ag(1) atoms to form a mixture of distorted edge, face, and corner-sharing ClRb4Ag2 octahedra. The corner-sharing octahedral tilt angles range from 1-61°. is represented by the CIF file [CIF]
data_RbAgCl3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.165
_cell_length_b   5.167
_cell_length_c   5.169
_cell_angle_alpha   89.937
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   137.971
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.000  1.000  0.995  1.0
  Ag  Ag1  1  0.500  0.503  0.486  1.0
  Cl  Cl2  1  0.000  0.505  0.486  1.0
  Cl  Cl3  1  0.500  0.498  0.986  1.0
  Cl  Cl4  1  0.500  0.003  0.488  1.0
[/CIF]
.