The structure described by MnSb2O6 is Hydrophilite-derived structured and crystallizes in the trigonal P321 space group. Mn(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form MnO6 octahedra that share corners with four equivalent Sb(2)O6 octahedra, corners with six equivalent Sb(3)O6 octahedra, and  an edgeedge with one Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-57°. There are three inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to six equivalent O(3) atoms to form SbO6 octahedra that share corners with six equivalent Sb(3)O6 octahedra and edges with three equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles are 51°. In the second Sb site, Sb(2) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form SbO6 octahedra that share corners with six equivalent Mn(1)O6 octahedra and edges with three equivalent Sb(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-57°. In the third Sb site, Sb(3) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form SbO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra, corners with six equivalent Mn(1)O6 octahedra, and edges with two equivalent Sb(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-52°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Mn(1), one Sb(2), and one Sb(3) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Mn(1), one Sb(2), and one Sb(3) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Mn(1), one Sb(1), and one Sb(3) atom. is represented by the CIF card [CIF]
data_Mn(SbO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.719
_cell_length_b   8.831
_cell_length_c   8.831
_cell_angle_alpha   120.000
_cell_angle_beta   90.000
_cell_angle_gamma   89.997
_symmetry_Int_Tables_number   1
_cell_volume   318.758
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  1.000  1.000  0.368  1.0
  Mn  Mn1  1  1.000  0.632  0.632  1.0
  Mn  Mn2  1  0.000  0.368  1.000  1.0
  O  O3  1  0.281  0.779  0.555  1.0
  O  O4  1  0.281  0.776  0.221  1.0
  O  O5  1  0.281  0.445  0.224  1.0
  O  O6  1  0.719  0.555  0.779  1.0
  O  O7  1  0.719  0.221  0.776  1.0
  O  O8  1  0.719  0.224  0.445  1.0
  O  O9  1  0.730  0.588  0.117  1.0
  O  O10  1  0.730  0.529  0.412  1.0
  O  O11  1  0.730  0.883  0.471  1.0
  O  O12  1  0.270  0.117  0.588  1.0
  O  O13  1  0.270  0.471  0.883  1.0
  O  O14  1  0.270  0.412  0.529  1.0
  O  O15  1  0.236  0.104  0.214  1.0
  O  O16  1  0.236  0.110  0.896  1.0
  O  O17  1  0.236  0.786  0.890  1.0
  O  O18  1  0.764  0.214  0.104  1.0
  O  O19  1  0.764  0.890  0.786  1.0
  O  O20  1  0.764  0.896  0.110  1.0
  Sb  Sb21  1  1.000  0.000  0.000  1.0
  Sb  Sb22  1  0.507  0.667  0.333  1.0
  Sb  Sb23  1  0.493  0.333  0.667  1.0
  Sb  Sb24  1  0.500  0.000  0.695  1.0
  Sb  Sb25  1  0.500  0.695  0.000  1.0
  Sb  Sb26  1  0.500  0.305  0.305  1.0
[/CIF]
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The structure described by MnSb2O6 is Hydrophilite-derived structured and crystallizes in the trigonal P321 space group. Mn(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form MnO6 octahedra that share corners with four equivalent Sb(2)O6 octahedra, corners with six equivalent Sb(3)O6 octahedra, and  an edgeedge with one Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-57°. There are three inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to six equivalent O(3) atoms to form SbO6 octahedra that share corners with six equivalent Sb(3)O6 octahedra and edges with three equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles are 51°. In the second Sb site, Sb(2) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form SbO6 octahedra that share corners with six equivalent Mn(1)O6 octahedra and edges with three equivalent Sb(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-57°. In the third Sb site, Sb(3) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form SbO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra, corners with six equivalent Mn(1)O6 octahedra, and edges with two equivalent Sb(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-52°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Mn(1), one Sb(2), and one Sb(3) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Mn(1), one Sb(2), and one Sb(3) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Mn(1), one Sb(1), and one Sb(3) atom. is represented by the CIF card [CIF]
data_Mn(SbO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.719
_cell_length_b   8.831
_cell_length_c   8.831
_cell_angle_alpha   120.000
_cell_angle_beta   90.000
_cell_angle_gamma   89.997
_symmetry_Int_Tables_number   1
_cell_volume   318.758
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  1.000  1.000  0.368  1.0
  Mn  Mn1  1  1.000  0.632  0.632  1.0
  Mn  Mn2  1  0.000  0.368  1.000  1.0
  O  O3  1  0.281  0.779  0.555  1.0
  O  O4  1  0.281  0.776  0.221  1.0
  O  O5  1  0.281  0.445  0.224  1.0
  O  O6  1  0.719  0.555  0.779  1.0
  O  O7  1  0.719  0.221  0.776  1.0
  O  O8  1  0.719  0.224  0.445  1.0
  O  O9  1  0.730  0.588  0.117  1.0
  O  O10  1  0.730  0.529  0.412  1.0
  O  O11  1  0.730  0.883  0.471  1.0
  O  O12  1  0.270  0.117  0.588  1.0
  O  O13  1  0.270  0.471  0.883  1.0
  O  O14  1  0.270  0.412  0.529  1.0
  O  O15  1  0.236  0.104  0.214  1.0
  O  O16  1  0.236  0.110  0.896  1.0
  O  O17  1  0.236  0.786  0.890  1.0
  O  O18  1  0.764  0.214  0.104  1.0
  O  O19  1  0.764  0.890  0.786  1.0
  O  O20  1  0.764  0.896  0.110  1.0
  Sb  Sb21  1  1.000  0.000  0.000  1.0
  Sb  Sb22  1  0.507  0.667  0.333  1.0
  Sb  Sb23  1  0.493  0.333  0.667  1.0
  Sb  Sb24  1  0.500  0.000  0.695  1.0
  Sb  Sb25  1  0.500  0.695  0.000  1.0
  Sb  Sb26  1  0.500  0.305  0.305  1.0
[/CIF]
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