The compound described by Mn6OF11 crystallizes in the monoclinic Cm space group. There are nine inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a body-centered cubic geometry to one F(12), one F(15), one F(2), one F(9), two equivalent F(5), and two equivalent F(7) atoms. In the second Mn site, Mn(2) is bonded in a body-centered cubic geometry to one O(2), one F(15), one F(2), one F(8), two equivalent F(1), and two equivalent F(7) atoms. In the third Mn site, Mn(3) is bonded in a distorted trigonal bipyramidal geometry to one O(2), one F(14), one F(4), and two equivalent F(1) atoms. In the fourth Mn site, Mn(4) is bonded in a distorted body-centered cubic geometry to one O(1), one F(13), one F(14), one F(4), two equivalent F(11), and two equivalent F(3) atoms. In the fifth Mn site, Mn(5) is bonded in a distorted body-centered cubic geometry to one O(1), one F(13), one F(16), one F(6), two equivalent F(10), and two equivalent F(3) atoms. In the sixth Mn site, Mn(6) is bonded in a body-centered cubic geometry to one F(12), one F(16), one F(6), one F(9), two equivalent F(10), and two equivalent F(5) atoms. In the seventh Mn site, Mn(7) is bonded in a body-centered cubic geometry to one F(12), one F(15), one F(2), one F(9), two equivalent F(5), and two equivalent F(7) atoms. In the eighth Mn site, Mn(8) is bonded in a 8-coordinate geometry to one O(1), one F(13), one F(16), one F(6), two equivalent F(10), and two equivalent F(3) atoms. In the ninth Mn site, Mn(9) is bonded in a 7-coordinate geometry to one O(2), one F(14), one F(8), two equivalent F(1), and two equivalent F(11) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded to one Mn(5), one Mn(8), and two equivalent Mn(4) atoms to form distorted OMn4 tetrahedra that share corners with four equivalent F(10)Mn4 tetrahedra, corners with four equivalent F(13)Mn4 tetrahedra, corners with two equivalent F(14)Mn4 trigonal pyramids,  an edgeedge with one F(6)Mn4 tetrahedra, and edges with four equivalent F(3)Mn4 tetrahedra. In the second O site, O(2) is bonded to one Mn(3), one Mn(9), and two equivalent Mn(2) atoms to form OMn4 tetrahedra that share corners with two equivalent F(2)Mn4 tetrahedra, corners with four equivalent F(7)Mn4 tetrahedra,  an edgeedge with one F(15)Mn4 tetrahedra, edges with four equivalent F(1)Mn4 tetrahedra, and  an edgeedge with one F(14)Mn4 trigonal pyramid. There are sixteen inequivalent F sites. In the first F site, F(1) is bonded to one Mn(3), one Mn(9), and two equivalent Mn(2) atoms to form distorted FMn4 tetrahedra that share corners with two equivalent F(15)Mn4 tetrahedra, corners with two equivalent F(2)Mn4 tetrahedra, corners with two equivalent F(7)Mn4 tetrahedra, corners with four equivalent F(1)Mn4 tetrahedra, corners with two equivalent F(14)Mn4 trigonal pyramids,  an edgeedge with one F(7)Mn4 tetrahedra, and edges with two equivalent O(2)Mn4 tetrahedra. In the second F site, F(2) is bonded to one Mn(1), one Mn(7), and two equivalent Mn(2) atoms to form FMn4 tetrahedra that share corners with two equivalent O(2)Mn4 tetrahedra, corners with two equivalent F(12)Mn4 tetrahedra, corners with four equivalent F(1)Mn4 tetrahedra, corners with four equivalent F(15)Mn4 tetrahedra, corners with four equivalent F(5)Mn4 tetrahedra,  an edgeedge with one F(9)Mn4 tetrahedra, and edges with four equivalent F(7)Mn4 tetrahedra. In the third F site, F(3) is bonded to one Mn(5), one Mn(8), and two equivalent Mn(4) atoms to form FMn4 tetrahedra that share corners with two equivalent F(10)Mn4 tetrahedra, corners with two equivalent F(6)Mn4 tetrahedra, corners with four equivalent F(3)Mn4 tetrahedra, corners with two equivalent F(14)Mn4 trigonal pyramids,  an edgeedge with one F(10)Mn4 tetrahedra, edges with two equivalent O(1)Mn4 tetrahedra, and edges with two equivalent F(13)Mn4 tetrahedra. In the fourth F site, F(4) is bonded in a distorted trigonal planar geometry to one Mn(3) and two equivalent Mn(4) atoms. In the fifth F site, F(5) is bonded to one Mn(1), one Mn(7), and two equivalent Mn(6) atoms to form a mixture of edge and corner-sharing FMn4 tetrahedra. In the sixth F site, F(6) is bonded to one Mn(5), one Mn(8), and two equivalent Mn(6) atoms to form distorted FMn4 tetrahedra that share corners with two equivalent F(12)Mn4 tetrahedra, corners with two equivalent F(13)Mn4 tetrahedra, corners with four equivalent F(3)Mn4 tetrahedra, corners with four equivalent F(5)Mn4 tetrahedra,  an edgeedge with one O(1)Mn4 tetrahedra,  an edgeedge with one F(9)Mn4 tetrahedra, and edges with four equivalent F(10)Mn4 tetrahedra. In the seventh F site, F(7) is bonded to one Mn(1), one Mn(7), and two equivalent Mn(2) atoms to form FMn4 tetrahedra that share corners with two equivalent O(2)Mn4 tetrahedra, corners with two equivalent F(1)Mn4 tetrahedra, corners with two equivalent F(12)Mn4 tetrahedra, corners with two equivalent F(5)Mn4 tetrahedra, corners with two equivalent F(9)Mn4 tetrahedra, corners with four equivalent F(7)Mn4 tetrahedra,  an edgeedge with one F(1)Mn4 tetrahedra,  an edgeedge with one F(5)Mn4 tetrahedra, edges with two equivalent F(15)Mn4 tetrahedra, and edges with two equivalent F(2)Mn4 tetrahedra. In the eighth F site, F(8) is bonded in a trigonal non-coplanar geometry to one Mn(9) and two equivalent Mn(2) atoms. In the ninth F site, F(9) is bonded to one Mn(1), one Mn(7), and two equivalent Mn(6) atoms to form a mixture of edge and corner-sharing FMn4 tetrahedra. In the tenth F site, F(10) is bonded to one Mn(5), one Mn(8), and two equivalent Mn(6) atoms to form distorted FMn4 tetrahedra that share corners with two equivalent O(1)Mn4 tetrahedra, corners with two equivalent F(12)Mn4 tetrahedra, corners with two equivalent F(13)Mn4 tetrahedra, corners with two equivalent F(3)Mn4 tetrahedra, corners with two equivalent F(5)Mn4 tetrahedra, corners with two equivalent F(9)Mn4 tetrahedra, corners with four equivalent F(10)Mn4 tetrahedra,  an edgeedge with one F(3)Mn4 tetrahedra,  an edgeedge with one F(5)Mn4 tetrahedra, and edges with two equivalent F(6)Mn4 tetrahedra. In the eleventh F site, F(11) is bonded in a 3-coordinate geometry to one Mn(9) and two equivalent Mn(4) atoms. In the twelfth F site, F(12) is bonded to one Mn(1), one Mn(7), and two equivalent Mn(6) atoms to form a mixture of edge and corner-sharing FMn4 tetrahedra. In the thirteenth F site, F(13) is bonded to one Mn(5), one Mn(8), and two equivalent Mn(4) atoms to form distorted FMn4 tetrahedra that share corners with two equivalent F(6)Mn4 tetrahedra, corners with four equivalent O(1)Mn4 tetrahedra, corners with four equivalent F(10)Mn4 tetrahedra, edges with four equivalent F(3)Mn4 tetrahedra, and  an edgeedge with one F(14)Mn4 trigonal pyramid. In the fourteenth F site, F(14) is bonded to one Mn(3), one Mn(9), and two equivalent Mn(4) atoms to form distorted FMn4 trigonal pyramids that share corners with two equivalent O(1)Mn4 tetrahedra, corners with four equivalent F(1)Mn4 tetrahedra, corners with four equivalent F(3)Mn4 tetrahedra,  an edgeedge with one O(2)Mn4 tetrahedra, and  an edgeedge with one F(13)Mn4 tetrahedra. In the fifteenth F site, F(15) is bonded to one Mn(1), one Mn(7), and two equivalent Mn(2) atoms to form FMn4 tetrahedra that share corners with two equivalent F(9)Mn4 tetrahedra, corners with four equivalent F(1)Mn4 tetrahedra, corners with four equivalent F(2)Mn4 tetrahedra, corners with four equivalent F(5)Mn4 tetrahedra,  an edgeedge with one O(2)Mn4 tetrahedra,  an edgeedge with one F(12)Mn4 tetrahedra, and edges with four equivalent F(7)Mn4 tetrahedra. In the sixteenth F site, F(16) is bonded in a distorted trigonal non-coplanar geometry to one Mn(5), one Mn(8), and two equivalent Mn(6) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mn6OF11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.270
_cell_length_b   5.270
_cell_length_c   15.623
_cell_angle_alpha   88.531
_cell_angle_beta   88.531
_cell_angle_gamma   89.137
_symmetry_Int_Tables_number   1
_cell_volume   433.587
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.999  0.999  0.001  1.0
  Mn  Mn1  1  0.998  0.488  0.170  1.0
  Mn  Mn2  1  0.040  0.040  0.329  1.0
  Mn  Mn3  1  0.994  0.525  0.501  1.0
  Mn  Mn4  1  0.997  0.997  0.665  1.0
  Mn  Mn5  1  0.003  0.498  0.833  1.0
  Mn  Mn6  1  0.488  0.998  0.170  1.0
  Mn  Mn7  1  0.500  0.500  0.001  1.0
  Mn  Mn8  1  0.518  0.518  0.656  1.0
  Mn  Mn9  1  0.525  0.994  0.501  1.0
  Mn  Mn10  1  0.474  0.474  0.327  1.0
  Mn  Mn11  1  0.498  0.003  0.833  1.0
  O  O12  1  0.721  0.721  0.580  1.0
  O  O13  1  0.246  0.246  0.257  1.0
  F  F14  1  0.760  0.192  0.254  1.0
  F  F15  1  0.767  0.767  0.084  1.0
  F  F16  1  0.785  0.227  0.580  1.0
  F  F17  1  0.828  0.828  0.409  1.0
  F  F18  1  0.771  0.231  0.914  1.0
  F  F19  1  0.775  0.775  0.753  1.0
  F  F20  1  0.732  0.267  0.087  1.0
  F  F21  1  0.695  0.695  0.244  1.0
  F  F22  1  0.732  0.732  0.917  1.0
  F  F23  1  0.712  0.282  0.746  1.0
  F  F24  1  0.715  0.315  0.421  1.0
  F  F25  1  0.272  0.272  0.916  1.0
  F  F26  1  0.290  0.290  0.585  1.0
  F  F27  1  0.267  0.732  0.087  1.0
  F  F28  1  0.315  0.715  0.421  1.0
  F  F29  1  0.282  0.712  0.746  1.0
  F  F30  1  0.209  0.209  0.427  1.0
  F  F31  1  0.233  0.233  0.083  1.0
  F  F32  1  0.212  0.212  0.752  1.0
  F  F33  1  0.227  0.785  0.580  1.0
  F  F34  1  0.231  0.771  0.914  1.0
  F  F35  1  0.192  0.760  0.254  1.0
[/CIF]
.
The compound described by Mn6OF11 crystallizes in the monoclinic Cm space group. There are nine inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a body-centered cubic geometry to one F(12), one F(15), one F(2), one F(9), two equivalent F(5), and two equivalent F(7) atoms. In the second Mn site, Mn(2) is bonded in a body-centered cubic geometry to one O(2), one F(15), one F(2), one F(8), two equivalent F(1), and two equivalent F(7) atoms. In the third Mn site, Mn(3) is bonded in a distorted trigonal bipyramidal geometry to one O(2), one F(14), one F(4), and two equivalent F(1) atoms. In the fourth Mn site, Mn(4) is bonded in a distorted body-centered cubic geometry to one O(1), one F(13), one F(14), one F(4), two equivalent F(11), and two equivalent F(3) atoms. In the fifth Mn site, Mn(5) is bonded in a distorted body-centered cubic geometry to one O(1), one F(13), one F(16), one F(6), two equivalent F(10), and two equivalent F(3) atoms. In the sixth Mn site, Mn(6) is bonded in a body-centered cubic geometry to one F(12), one F(16), one F(6), one F(9), two equivalent F(10), and two equivalent F(5) atoms. In the seventh Mn site, Mn(7) is bonded in a body-centered cubic geometry to one F(12), one F(15), one F(2), one F(9), two equivalent F(5), and two equivalent F(7) atoms. In the eighth Mn site, Mn(8) is bonded in a 8-coordinate geometry to one O(1), one F(13), one F(16), one F(6), two equivalent F(10), and two equivalent F(3) atoms. In the ninth Mn site, Mn(9) is bonded in a 7-coordinate geometry to one O(2), one F(14), one F(8), two equivalent F(1), and two equivalent F(11) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded to one Mn(5), one Mn(8), and two equivalent Mn(4) atoms to form distorted OMn4 tetrahedra that share corners with four equivalent F(10)Mn4 tetrahedra, corners with four equivalent F(13)Mn4 tetrahedra, corners with two equivalent F(14)Mn4 trigonal pyramids,  an edgeedge with one F(6)Mn4 tetrahedra, and edges with four equivalent F(3)Mn4 tetrahedra. In the second O site, O(2) is bonded to one Mn(3), one Mn(9), and two equivalent Mn(2) atoms to form OMn4 tetrahedra that share corners with two equivalent F(2)Mn4 tetrahedra, corners with four equivalent F(7)Mn4 tetrahedra,  an edgeedge with one F(15)Mn4 tetrahedra, edges with four equivalent F(1)Mn4 tetrahedra, and  an edgeedge with one F(14)Mn4 trigonal pyramid. There are sixteen inequivalent F sites. In the first F site, F(1) is bonded to one Mn(3), one Mn(9), and two equivalent Mn(2) atoms to form distorted FMn4 tetrahedra that share corners with two equivalent F(15)Mn4 tetrahedra, corners with two equivalent F(2)Mn4 tetrahedra, corners with two equivalent F(7)Mn4 tetrahedra, corners with four equivalent F(1)Mn4 tetrahedra, corners with two equivalent F(14)Mn4 trigonal pyramids,  an edgeedge with one F(7)Mn4 tetrahedra, and edges with two equivalent O(2)Mn4 tetrahedra. In the second F site, F(2) is bonded to one Mn(1), one Mn(7), and two equivalent Mn(2) atoms to form FMn4 tetrahedra that share corners with two equivalent O(2)Mn4 tetrahedra, corners with two equivalent F(12)Mn4 tetrahedra, corners with four equivalent F(1)Mn4 tetrahedra, corners with four equivalent F(15)Mn4 tetrahedra, corners with four equivalent F(5)Mn4 tetrahedra,  an edgeedge with one F(9)Mn4 tetrahedra, and edges with four equivalent F(7)Mn4 tetrahedra. In the third F site, F(3) is bonded to one Mn(5), one Mn(8), and two equivalent Mn(4) atoms to form FMn4 tetrahedra that share corners with two equivalent F(10)Mn4 tetrahedra, corners with two equivalent F(6)Mn4 tetrahedra, corners with four equivalent F(3)Mn4 tetrahedra, corners with two equivalent F(14)Mn4 trigonal pyramids,  an edgeedge with one F(10)Mn4 tetrahedra, edges with two equivalent O(1)Mn4 tetrahedra, and edges with two equivalent F(13)Mn4 tetrahedra. In the fourth F site, F(4) is bonded in a distorted trigonal planar geometry to one Mn(3) and two equivalent Mn(4) atoms. In the fifth F site, F(5) is bonded to one Mn(1), one Mn(7), and two equivalent Mn(6) atoms to form a mixture of edge and corner-sharing FMn4 tetrahedra. In the sixth F site, F(6) is bonded to one Mn(5), one Mn(8), and two equivalent Mn(6) atoms to form distorted FMn4 tetrahedra that share corners with two equivalent F(12)Mn4 tetrahedra, corners with two equivalent F(13)Mn4 tetrahedra, corners with four equivalent F(3)Mn4 tetrahedra, corners with four equivalent F(5)Mn4 tetrahedra,  an edgeedge with one O(1)Mn4 tetrahedra,  an edgeedge with one F(9)Mn4 tetrahedra, and edges with four equivalent F(10)Mn4 tetrahedra. In the seventh F site, F(7) is bonded to one Mn(1), one Mn(7), and two equivalent Mn(2) atoms to form FMn4 tetrahedra that share corners with two equivalent O(2)Mn4 tetrahedra, corners with two equivalent F(1)Mn4 tetrahedra, corners with two equivalent F(12)Mn4 tetrahedra, corners with two equivalent F(5)Mn4 tetrahedra, corners with two equivalent F(9)Mn4 tetrahedra, corners with four equivalent F(7)Mn4 tetrahedra,  an edgeedge with one F(1)Mn4 tetrahedra,  an edgeedge with one F(5)Mn4 tetrahedra, edges with two equivalent F(15)Mn4 tetrahedra, and edges with two equivalent F(2)Mn4 tetrahedra. In the eighth F site, F(8) is bonded in a trigonal non-coplanar geometry to one Mn(9) and two equivalent Mn(2) atoms. In the ninth F site, F(9) is bonded to one Mn(1), one Mn(7), and two equivalent Mn(6) atoms to form a mixture of edge and corner-sharing FMn4 tetrahedra. In the tenth F site, F(10) is bonded to one Mn(5), one Mn(8), and two equivalent Mn(6) atoms to form distorted FMn4 tetrahedra that share corners with two equivalent O(1)Mn4 tetrahedra, corners with two equivalent F(12)Mn4 tetrahedra, corners with two equivalent F(13)Mn4 tetrahedra, corners with two equivalent F(3)Mn4 tetrahedra, corners with two equivalent F(5)Mn4 tetrahedra, corners with two equivalent F(9)Mn4 tetrahedra, corners with four equivalent F(10)Mn4 tetrahedra,  an edgeedge with one F(3)Mn4 tetrahedra,  an edgeedge with one F(5)Mn4 tetrahedra, and edges with two equivalent F(6)Mn4 tetrahedra. In the eleventh F site, F(11) is bonded in a 3-coordinate geometry to one Mn(9) and two equivalent Mn(4) atoms. In the twelfth F site, F(12) is bonded to one Mn(1), one Mn(7), and two equivalent Mn(6) atoms to form a mixture of edge and corner-sharing FMn4 tetrahedra. In the thirteenth F site, F(13) is bonded to one Mn(5), one Mn(8), and two equivalent Mn(4) atoms to form distorted FMn4 tetrahedra that share corners with two equivalent F(6)Mn4 tetrahedra, corners with four equivalent O(1)Mn4 tetrahedra, corners with four equivalent F(10)Mn4 tetrahedra, edges with four equivalent F(3)Mn4 tetrahedra, and  an edgeedge with one F(14)Mn4 trigonal pyramid. In the fourteenth F site, F(14) is bonded to one Mn(3), one Mn(9), and two equivalent Mn(4) atoms to form distorted FMn4 trigonal pyramids that share corners with two equivalent O(1)Mn4 tetrahedra, corners with four equivalent F(1)Mn4 tetrahedra, corners with four equivalent F(3)Mn4 tetrahedra,  an edgeedge with one O(2)Mn4 tetrahedra, and  an edgeedge with one F(13)Mn4 tetrahedra. In the fifteenth F site, F(15) is bonded to one Mn(1), one Mn(7), and two equivalent Mn(2) atoms to form FMn4 tetrahedra that share corners with two equivalent F(9)Mn4 tetrahedra, corners with four equivalent F(1)Mn4 tetrahedra, corners with four equivalent F(2)Mn4 tetrahedra, corners with four equivalent F(5)Mn4 tetrahedra,  an edgeedge with one O(2)Mn4 tetrahedra,  an edgeedge with one F(12)Mn4 tetrahedra, and edges with four equivalent F(7)Mn4 tetrahedra. In the sixteenth F site, F(16) is bonded in a distorted trigonal non-coplanar geometry to one Mn(5), one Mn(8), and two equivalent Mn(6) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mn6OF11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.270
_cell_length_b   5.270
_cell_length_c   15.623
_cell_angle_alpha   88.531
_cell_angle_beta   88.531
_cell_angle_gamma   89.137
_symmetry_Int_Tables_number   1
_cell_volume   433.587
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.999  0.999  0.001  1.0
  Mn  Mn1  1  0.998  0.488  0.170  1.0
  Mn  Mn2  1  0.040  0.040  0.329  1.0
  Mn  Mn3  1  0.994  0.525  0.501  1.0
  Mn  Mn4  1  0.997  0.997  0.665  1.0
  Mn  Mn5  1  0.003  0.498  0.833  1.0
  Mn  Mn6  1  0.488  0.998  0.170  1.0
  Mn  Mn7  1  0.500  0.500  0.001  1.0
  Mn  Mn8  1  0.518  0.518  0.656  1.0
  Mn  Mn9  1  0.525  0.994  0.501  1.0
  Mn  Mn10  1  0.474  0.474  0.327  1.0
  Mn  Mn11  1  0.498  0.003  0.833  1.0
  O  O12  1  0.721  0.721  0.580  1.0
  O  O13  1  0.246  0.246  0.257  1.0
  F  F14  1  0.760  0.192  0.254  1.0
  F  F15  1  0.767  0.767  0.084  1.0
  F  F16  1  0.785  0.227  0.580  1.0
  F  F17  1  0.828  0.828  0.409  1.0
  F  F18  1  0.771  0.231  0.914  1.0
  F  F19  1  0.775  0.775  0.753  1.0
  F  F20  1  0.732  0.267  0.087  1.0
  F  F21  1  0.695  0.695  0.244  1.0
  F  F22  1  0.732  0.732  0.917  1.0
  F  F23  1  0.712  0.282  0.746  1.0
  F  F24  1  0.715  0.315  0.421  1.0
  F  F25  1  0.272  0.272  0.916  1.0
  F  F26  1  0.290  0.290  0.585  1.0
  F  F27  1  0.267  0.732  0.087  1.0
  F  F28  1  0.315  0.715  0.421  1.0
  F  F29  1  0.282  0.712  0.746  1.0
  F  F30  1  0.209  0.209  0.427  1.0
  F  F31  1  0.233  0.233  0.083  1.0
  F  F32  1  0.212  0.212  0.752  1.0
  F  F33  1  0.227  0.785  0.580  1.0
  F  F34  1  0.231  0.771  0.914  1.0
  F  F35  1  0.192  0.760  0.254  1.0
[/CIF]
.