The structure described by MoMn2P12 crystallizes in the monoclinic C2/c space group. Mo(1) is bonded in a 8-coordinate geometry to two equivalent P(2), two equivalent P(3), two equivalent P(4), and two equivalent P(5) atoms. Mn(1) is bonded to one P(1), one P(3), one P(4), one P(5), and two equivalent P(6) atoms to form MnP6 octahedra that share corners with four equivalent P(2)MoP3 tetrahedra and  an edgeedge with one Mn(1)P6 octahedra. There are six inequivalent P sites. In the first P site, P(1) is bonded in a distorted single-bond geometry to one Mn(1), one P(1), one P(3), and one P(5) atom. In the second P site, P(2) is bonded to one Mo(1), one P(4), one P(5), and one P(6) atom to form distorted PMoP3 tetrahedra that share corners with four equivalent Mn(1)P6 octahedra and  a cornercorner with one P(2)MoP3 tetrahedra. The corner-sharing octahedral tilt angles range from 54-74°. In the third P site, P(3) is bonded in a distorted single-bond geometry to one Mo(1), one Mn(1), one P(1), and one P(6) atom. In the fourth P site, P(4) is bonded in a distorted single-bond geometry to one Mo(1), one Mn(1), and one P(2) atom. In the fifth P site, P(5) is bonded in a distorted single-bond geometry to one Mo(1), one Mn(1), one P(1), and one P(2) atom. In the sixth P site, P(6) is bonded in a 4-coordinate geometry to two equivalent Mn(1), one P(2), and one P(3) atom. is represented by the CIF file [CIF]
data_Mn2MoP12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.476
_cell_length_b   8.476
_cell_length_c   10.559
_cell_angle_alpha   65.674
_cell_angle_beta   65.674
_cell_angle_gamma   39.394
_symmetry_Int_Tables_number   1
_cell_volume   432.889
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.371  0.990  0.454  1.0
  Mn  Mn1  1  0.010  0.629  0.046  1.0
  Mn  Mn2  1  0.629  0.010  0.546  1.0
  Mn  Mn3  1  0.990  0.371  0.954  1.0
  Mo  Mo4  1  0.305  0.695  0.250  1.0
  Mo  Mo5  1  0.695  0.305  0.750  1.0
  P  P6  1  0.596  0.950  0.075  1.0
  P  P7  1  0.050  0.404  0.425  1.0
  P  P8  1  0.404  0.050  0.925  1.0
  P  P9  1  0.950  0.596  0.575  1.0
  P  P10  1  0.579  0.298  0.167  1.0
  P  P11  1  0.702  0.421  0.333  1.0
  P  P12  1  0.979  0.328  0.759  1.0
  P  P13  1  0.672  0.021  0.741  1.0
  P  P14  1  0.021  0.672  0.241  1.0
  P  P15  1  0.328  0.979  0.259  1.0
  P  P16  1  0.012  0.921  0.927  1.0
  P  P17  1  0.079  0.988  0.573  1.0
  P  P18  1  0.988  0.079  0.073  1.0
  P  P19  1  0.921  0.012  0.427  1.0
  P  P20  1  0.331  0.435  0.505  1.0
  P  P21  1  0.565  0.669  0.995  1.0
  P  P22  1  0.669  0.565  0.495  1.0
  P  P23  1  0.435  0.331  0.005  1.0
  P  P24  1  0.998  0.646  0.836  1.0
  P  P25  1  0.354  0.002  0.664  1.0
  P  P26  1  0.002  0.354  0.164  1.0
  P  P27  1  0.646  0.998  0.336  1.0
  P  P28  1  0.298  0.579  0.667  1.0
  P  P29  1  0.421  0.702  0.833  1.0
[/CIF]
.
The structure described by MoMn2P12 crystallizes in the monoclinic C2/c space group. Mo(1) is bonded in a 8-coordinate geometry to two equivalent P(2), two equivalent P(3), two equivalent P(4), and two equivalent P(5) atoms. Mn(1) is bonded to one P(1), one P(3), one P(4), one P(5), and two equivalent P(6) atoms to form MnP6 octahedra that share corners with four equivalent P(2)MoP3 tetrahedra and  an edgeedge with one Mn(1)P6 octahedra. There are six inequivalent P sites. In the first P site, P(1) is bonded in a distorted single-bond geometry to one Mn(1), one P(1), one P(3), and one P(5) atom. In the second P site, P(2) is bonded to one Mo(1), one P(4), one P(5), and one P(6) atom to form distorted PMoP3 tetrahedra that share corners with four equivalent Mn(1)P6 octahedra and  a cornercorner with one P(2)MoP3 tetrahedra. The corner-sharing octahedral tilt angles range from 54-74°. In the third P site, P(3) is bonded in a distorted single-bond geometry to one Mo(1), one Mn(1), one P(1), and one P(6) atom. In the fourth P site, P(4) is bonded in a distorted single-bond geometry to one Mo(1), one Mn(1), and one P(2) atom. In the fifth P site, P(5) is bonded in a distorted single-bond geometry to one Mo(1), one Mn(1), one P(1), and one P(2) atom. In the sixth P site, P(6) is bonded in a 4-coordinate geometry to two equivalent Mn(1), one P(2), and one P(3) atom. is represented by the CIF file [CIF]
data_Mn2MoP12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.476
_cell_length_b   8.476
_cell_length_c   10.559
_cell_angle_alpha   65.674
_cell_angle_beta   65.674
_cell_angle_gamma   39.394
_symmetry_Int_Tables_number   1
_cell_volume   432.889
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.371  0.990  0.454  1.0
  Mn  Mn1  1  0.010  0.629  0.046  1.0
  Mn  Mn2  1  0.629  0.010  0.546  1.0
  Mn  Mn3  1  0.990  0.371  0.954  1.0
  Mo  Mo4  1  0.305  0.695  0.250  1.0
  Mo  Mo5  1  0.695  0.305  0.750  1.0
  P  P6  1  0.596  0.950  0.075  1.0
  P  P7  1  0.050  0.404  0.425  1.0
  P  P8  1  0.404  0.050  0.925  1.0
  P  P9  1  0.950  0.596  0.575  1.0
  P  P10  1  0.579  0.298  0.167  1.0
  P  P11  1  0.702  0.421  0.333  1.0
  P  P12  1  0.979  0.328  0.759  1.0
  P  P13  1  0.672  0.021  0.741  1.0
  P  P14  1  0.021  0.672  0.241  1.0
  P  P15  1  0.328  0.979  0.259  1.0
  P  P16  1  0.012  0.921  0.927  1.0
  P  P17  1  0.079  0.988  0.573  1.0
  P  P18  1  0.988  0.079  0.073  1.0
  P  P19  1  0.921  0.012  0.427  1.0
  P  P20  1  0.331  0.435  0.505  1.0
  P  P21  1  0.565  0.669  0.995  1.0
  P  P22  1  0.669  0.565  0.495  1.0
  P  P23  1  0.435  0.331  0.005  1.0
  P  P24  1  0.998  0.646  0.836  1.0
  P  P25  1  0.354  0.002  0.664  1.0
  P  P26  1  0.002  0.354  0.164  1.0
  P  P27  1  0.646  0.998  0.336  1.0
  P  P28  1  0.298  0.579  0.667  1.0
  P  P29  1  0.421  0.702  0.833  1.0
[/CIF]
.