The compound described by BCl is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of seven chloroborane molecules, one B4Cl5 cluster, and one B7Cl6 cluster. In the B4Cl5 cluster, there are four inequivalent B sites. In the first B site, B(12) is bonded in a 1-coordinate geometry to one Cl(9) atom. In the second B site, B(14) is bonded in a distorted tetrahedral geometry to one B(17), one Cl(13), one Cl(14), and one Cl(9) atom. In the third B site, B(16) is bonded in a 1-coordinate geometry to one Cl(14) atom. In the fourth B site, B(17) is bonded in a distorted trigonal planar geometry to one B(14) and two equivalent Cl(15,18) atoms. There are four inequivalent Cl sites. In the first Cl site, Cl(15,18) is bonded in a single-bond geometry to one B(17) atom. In the second Cl site, Cl(9) is bonded in an L-shaped geometry to one B(12) and one B(14) atom. In the third Cl site, Cl(13) is bonded in a single-bond geometry to one B(14) atom. In the fourth Cl site, Cl(14) is bonded in an L-shaped geometry to one B(14) and one B(16) atom. In the B7Cl6 cluster, there are seven inequivalent B sites. In the first B site, B(1) is bonded in a trigonal planar geometry to one B(3), one B(5), and one B(7) atom. In the second B site, B(2) is bonded in a distorted single-bond geometry to one B(3), one B(8), and one Cl(2) atom. In the third B site, B(3) is bonded in a distorted trigonal planar geometry to one B(1), one B(2), and one Cl(3) atom. In the fourth B site, B(5) is bonded in a distorted single-bond geometry to one B(1) and one Cl(4) atom. In the fifth B site, B(7) is bonded in a distorted trigonal planar geometry to one B(1), one B(9), and one Cl(8) atom. In the sixth B site, B(8) is bonded in a distorted single-bond geometry to one B(2), one B(9), and one Cl(7) atom. In the seventh B site, B(9) is bonded in a distorted single-bond geometry to one B(7), one B(8), and one Cl(11) atom. There are six inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one B(2) atom. In the second Cl site, Cl(3) is bonded in a single-bond geometry to one B(3) atom. In the third Cl site, Cl(4) is bonded in a single-bond geometry to one B(5) atom. In the fourth Cl site, Cl(7) is bonded in a single-bond geometry to one B(8) atom. In the fifth Cl site, Cl(8) is bonded in a single-bond geometry to one B(7) atom. In the sixth Cl site, Cl(11) is bonded in a single-bond geometry to one B(9) atom. is represented by the CIF card [CIF]
data_BCl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.705
_cell_length_b   9.718
_cell_length_c   11.722
_cell_angle_alpha   81.178
_cell_angle_beta   83.754
_cell_angle_gamma   80.895
_symmetry_Int_Tables_number   1
_cell_volume   1296.147
_cell_formula_units_Z   18
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.272  0.491  0.271  1.0
  B  B1  1  0.258  0.244  0.427  1.0
  B  B2  1  0.225  0.418  0.400  1.0
  B  B3  1  0.235  0.740  0.725  1.0
  B  B4  1  0.241  0.653  0.239  1.0
  B  B5  1  0.297  0.253  0.784  1.0
  B  B6  1  0.402  0.418  0.226  1.0
  B  B7  1  0.401  0.217  0.400  1.0
  B  B8  1  0.427  0.244  0.257  1.0
  B  B9  1  0.593  0.766  0.743  1.0
  B  B10  1  0.600  0.745  0.598  1.0
  B  B11  1  0.613  0.604  0.717  1.0
  B  B12  1  0.727  0.742  0.232  1.0
  B  B13  1  0.732  0.341  0.731  1.0
  B  B14  1  0.786  0.248  0.299  1.0
  B  B15  1  0.718  0.603  0.613  1.0
  B  B16  1  0.814  0.415  0.812  1.0
  B  B17  1  0.745  0.765  0.593  1.0
  Cl  Cl18  1  0.094  0.794  0.776  1.0
  Cl  Cl19  1  0.163  0.120  0.476  1.0
  Cl  Cl20  1  0.147  0.513  0.510  1.0
  Cl  Cl21  1  0.223  0.829  0.220  1.0
  Cl  Cl22  1  0.247  0.238  0.929  1.0
  Cl  Cl23  1  0.541  0.885  0.836  1.0
  Cl  Cl24  1  0.503  0.179  0.503  1.0
  Cl  Cl25  1  0.516  0.509  0.151  1.0
  Cl  Cl26  1  0.565  0.432  0.762  1.0
  Cl  Cl27  1  0.501  0.815  0.497  1.0
  Cl  Cl28  1  0.476  0.118  0.163  1.0
  Cl  Cl29  1  0.777  0.795  0.090  1.0
  Cl  Cl30  1  0.744  0.157  0.743  1.0
  Cl  Cl31  1  0.763  0.430  0.564  1.0
  Cl  Cl32  1  0.763  0.446  0.953  1.0
  Cl  Cl33  1  0.929  0.244  0.244  1.0
  Cl  Cl34  1  0.838  0.882  0.542  1.0
  Cl  Cl35  1  0.956  0.442  0.761  1.0
[/CIF]
.
The compound described by BCl is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of seven chloroborane molecules, one B4Cl5 cluster, and one B7Cl6 cluster. In the B4Cl5 cluster, there are four inequivalent B sites. In the first B site, B(12) is bonded in a 1-coordinate geometry to one Cl(9) atom. In the second B site, B(14) is bonded in a distorted tetrahedral geometry to one B(17), one Cl(13), one Cl(14), and one Cl(9) atom. In the third B site, B(16) is bonded in a 1-coordinate geometry to one Cl(14) atom. In the fourth B site, B(17) is bonded in a distorted trigonal planar geometry to one B(14) and two equivalent Cl(15,18) atoms. There are four inequivalent Cl sites. In the first Cl site, Cl(15,18) is bonded in a single-bond geometry to one B(17) atom. In the second Cl site, Cl(9) is bonded in an L-shaped geometry to one B(12) and one B(14) atom. In the third Cl site, Cl(13) is bonded in a single-bond geometry to one B(14) atom. In the fourth Cl site, Cl(14) is bonded in an L-shaped geometry to one B(14) and one B(16) atom. In the B7Cl6 cluster, there are seven inequivalent B sites. In the first B site, B(1) is bonded in a trigonal planar geometry to one B(3), one B(5), and one B(7) atom. In the second B site, B(2) is bonded in a distorted single-bond geometry to one B(3), one B(8), and one Cl(2) atom. In the third B site, B(3) is bonded in a distorted trigonal planar geometry to one B(1), one B(2), and one Cl(3) atom. In the fourth B site, B(5) is bonded in a distorted single-bond geometry to one B(1) and one Cl(4) atom. In the fifth B site, B(7) is bonded in a distorted trigonal planar geometry to one B(1), one B(9), and one Cl(8) atom. In the sixth B site, B(8) is bonded in a distorted single-bond geometry to one B(2), one B(9), and one Cl(7) atom. In the seventh B site, B(9) is bonded in a distorted single-bond geometry to one B(7), one B(8), and one Cl(11) atom. There are six inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one B(2) atom. In the second Cl site, Cl(3) is bonded in a single-bond geometry to one B(3) atom. In the third Cl site, Cl(4) is bonded in a single-bond geometry to one B(5) atom. In the fourth Cl site, Cl(7) is bonded in a single-bond geometry to one B(8) atom. In the fifth Cl site, Cl(8) is bonded in a single-bond geometry to one B(7) atom. In the sixth Cl site, Cl(11) is bonded in a single-bond geometry to one B(9) atom. is represented by the CIF card [CIF]
data_BCl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.705
_cell_length_b   9.718
_cell_length_c   11.722
_cell_angle_alpha   81.178
_cell_angle_beta   83.754
_cell_angle_gamma   80.895
_symmetry_Int_Tables_number   1
_cell_volume   1296.147
_cell_formula_units_Z   18
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.272  0.491  0.271  1.0
  B  B1  1  0.258  0.244  0.427  1.0
  B  B2  1  0.225  0.418  0.400  1.0
  B  B3  1  0.235  0.740  0.725  1.0
  B  B4  1  0.241  0.653  0.239  1.0
  B  B5  1  0.297  0.253  0.784  1.0
  B  B6  1  0.402  0.418  0.226  1.0
  B  B7  1  0.401  0.217  0.400  1.0
  B  B8  1  0.427  0.244  0.257  1.0
  B  B9  1  0.593  0.766  0.743  1.0
  B  B10  1  0.600  0.745  0.598  1.0
  B  B11  1  0.613  0.604  0.717  1.0
  B  B12  1  0.727  0.742  0.232  1.0
  B  B13  1  0.732  0.341  0.731  1.0
  B  B14  1  0.786  0.248  0.299  1.0
  B  B15  1  0.718  0.603  0.613  1.0
  B  B16  1  0.814  0.415  0.812  1.0
  B  B17  1  0.745  0.765  0.593  1.0
  Cl  Cl18  1  0.094  0.794  0.776  1.0
  Cl  Cl19  1  0.163  0.120  0.476  1.0
  Cl  Cl20  1  0.147  0.513  0.510  1.0
  Cl  Cl21  1  0.223  0.829  0.220  1.0
  Cl  Cl22  1  0.247  0.238  0.929  1.0
  Cl  Cl23  1  0.541  0.885  0.836  1.0
  Cl  Cl24  1  0.503  0.179  0.503  1.0
  Cl  Cl25  1  0.516  0.509  0.151  1.0
  Cl  Cl26  1  0.565  0.432  0.762  1.0
  Cl  Cl27  1  0.501  0.815  0.497  1.0
  Cl  Cl28  1  0.476  0.118  0.163  1.0
  Cl  Cl29  1  0.777  0.795  0.090  1.0
  Cl  Cl30  1  0.744  0.157  0.743  1.0
  Cl  Cl31  1  0.763  0.430  0.564  1.0
  Cl  Cl32  1  0.763  0.446  0.953  1.0
  Cl  Cl33  1  0.929  0.244  0.244  1.0
  Cl  Cl34  1  0.838  0.882  0.542  1.0
  Cl  Cl35  1  0.956  0.442  0.761  1.0
[/CIF]
.