The compound described by Co(PO3)3 crystallizes in the triclinic P-1 space group. Co(1) is bonded to one O(2), one O(7), one O(8), one O(9), and two equivalent O(3) atoms to form CoO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra, corners with two equivalent P(3)O4 tetrahedra, corners with three equivalent P(2)O4 tetrahedra, and  an edgeedge with one Co(1)O6 octahedra. There are three inequivalent P sites. In the first P site, P(1) is bonded to one O(4), one O(5), one O(6), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra, and  a cornercorner with one P(3)O4 tetrahedra. The corner-sharing octahedral tilt angles are 41°. In the second P site, P(2) is bonded to one O(1), one O(3), one O(6), and one O(7) atom to form PO4 tetrahedra that share corners with three equivalent Co(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra, and  a cornercorner with one P(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 18-60°. In the third P site, P(3) is bonded to one O(1), one O(2), one O(4), and one O(8) atom to form PO4 tetrahedra that share corners with two equivalent Co(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra, and  a cornercorner with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 46-47°. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one P(2) and one P(3) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one P(3) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to two equivalent Co(1) and one P(2) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one P(1) and one P(3) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one P(1) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one P(1) and one P(2) atom. In the seventh O site, O(7) is bonded in a distorted bent 150 degrees geometry to one Co(1) and one P(2) atom. In the eighth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one P(3) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one Co(1) and one P(1) atom. is represented by the CIF card [CIF]
data_Co(PO3)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.620
_cell_length_b   6.864
_cell_length_c   7.330
_cell_angle_alpha   101.560
_cell_angle_beta   93.520
_cell_angle_gamma   93.913
_symmetry_Int_Tables_number   1
_cell_volume   324.617
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.157  0.089  0.859  1.0
  Co  Co1  1  0.843  0.911  0.141  1.0
  P  P2  1  0.651  0.567  0.804  1.0
  P  P3  1  0.335  0.877  0.204  1.0
  P  P4  1  0.665  0.123  0.796  1.0
  P  P5  1  0.349  0.433  0.196  1.0
  P  P6  1  0.851  0.804  0.556  1.0
  P  P7  1  0.149  0.196  0.444  1.0
  O  O8  1  0.291  0.011  0.403  1.0
  O  O9  1  0.874  0.757  0.351  1.0
  O  O10  1  0.166  0.911  0.065  1.0
  O  O11  1  0.280  0.377  0.391  1.0
  O  O12  1  0.565  0.407  0.173  1.0
  O  O13  1  0.709  0.989  0.597  1.0
  O  O14  1  0.705  0.338  0.752  1.0
  O  O15  1  0.720  0.623  0.609  1.0
  O  O16  1  0.126  0.243  0.649  1.0
  O  O17  1  0.834  0.089  0.935  1.0
  O  O18  1  0.450  0.072  0.830  1.0
  O  O19  1  0.295  0.662  0.248  1.0
  O  O20  1  0.550  0.928  0.170  1.0
  O  O21  1  0.954  0.147  0.317  1.0
  O  O22  1  0.190  0.324  0.042  1.0
  O  O23  1  0.046  0.853  0.683  1.0
  O  O24  1  0.810  0.676  0.958  1.0
  O  O25  1  0.435  0.593  0.827  1.0
[/CIF]
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The compound described by Co(PO3)3 crystallizes in the triclinic P-1 space group. Co(1) is bonded to one O(2), one O(7), one O(8), one O(9), and two equivalent O(3) atoms to form CoO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra, corners with two equivalent P(3)O4 tetrahedra, corners with three equivalent P(2)O4 tetrahedra, and  an edgeedge with one Co(1)O6 octahedra. There are three inequivalent P sites. In the first P site, P(1) is bonded to one O(4), one O(5), one O(6), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra, and  a cornercorner with one P(3)O4 tetrahedra. The corner-sharing octahedral tilt angles are 41°. In the second P site, P(2) is bonded to one O(1), one O(3), one O(6), and one O(7) atom to form PO4 tetrahedra that share corners with three equivalent Co(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra, and  a cornercorner with one P(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 18-60°. In the third P site, P(3) is bonded to one O(1), one O(2), one O(4), and one O(8) atom to form PO4 tetrahedra that share corners with two equivalent Co(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra, and  a cornercorner with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 46-47°. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one P(2) and one P(3) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one P(3) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to two equivalent Co(1) and one P(2) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one P(1) and one P(3) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one P(1) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one P(1) and one P(2) atom. In the seventh O site, O(7) is bonded in a distorted bent 150 degrees geometry to one Co(1) and one P(2) atom. In the eighth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one P(3) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one Co(1) and one P(1) atom. is represented by the CIF card [CIF]
data_Co(PO3)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.620
_cell_length_b   6.864
_cell_length_c   7.330
_cell_angle_alpha   101.560
_cell_angle_beta   93.520
_cell_angle_gamma   93.913
_symmetry_Int_Tables_number   1
_cell_volume   324.617
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.157  0.089  0.859  1.0
  Co  Co1  1  0.843  0.911  0.141  1.0
  P  P2  1  0.651  0.567  0.804  1.0
  P  P3  1  0.335  0.877  0.204  1.0
  P  P4  1  0.665  0.123  0.796  1.0
  P  P5  1  0.349  0.433  0.196  1.0
  P  P6  1  0.851  0.804  0.556  1.0
  P  P7  1  0.149  0.196  0.444  1.0
  O  O8  1  0.291  0.011  0.403  1.0
  O  O9  1  0.874  0.757  0.351  1.0
  O  O10  1  0.166  0.911  0.065  1.0
  O  O11  1  0.280  0.377  0.391  1.0
  O  O12  1  0.565  0.407  0.173  1.0
  O  O13  1  0.709  0.989  0.597  1.0
  O  O14  1  0.705  0.338  0.752  1.0
  O  O15  1  0.720  0.623  0.609  1.0
  O  O16  1  0.126  0.243  0.649  1.0
  O  O17  1  0.834  0.089  0.935  1.0
  O  O18  1  0.450  0.072  0.830  1.0
  O  O19  1  0.295  0.662  0.248  1.0
  O  O20  1  0.550  0.928  0.170  1.0
  O  O21  1  0.954  0.147  0.317  1.0
  O  O22  1  0.190  0.324  0.042  1.0
  O  O23  1  0.046  0.853  0.683  1.0
  O  O24  1  0.810  0.676  0.958  1.0
  O  O25  1  0.435  0.593  0.827  1.0
[/CIF]
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