The material structure described by MgWFeZn2O6 crystallizes in the triclinic P1 space group. Mg(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form MgO6 octahedra that share corners with three equivalent Zn(1)O6 octahedra, edges with three equivalent W(1)O6 octahedra, and  a faceface with one Zn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 36-46°. W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form WO6 octahedra that share corners with three equivalent Zn(1)O6 octahedra, edges with three equivalent Mg(1)O6 octahedra, and  a faceface with one Zn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 43-48°. Fe(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form ZnO6 octahedra that share corners with three equivalent Mg(1)O6 octahedra, corners with three equivalent W(1)O6 octahedra,  a faceface with one Mg(1)O6 octahedra, and  a faceface with one W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 36-48°. In the second Zn site, Zn(2) is bonded in a trigonal planar geometry to one O(1), one O(5), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to one Mg(1), one W(1), one Fe(1), one Zn(1), and one Zn(2) atom. In the second O site, O(2) is bonded to one Mg(1), one W(1), one Fe(1), and one Zn(1) atom to form a mixture of distorted corner and edge-sharing OMgZnFeW trigonal pyramids. In the third O site, O(3) is bonded to one Mg(1), one W(1), one Fe(1), and one Zn(1) atom to form a mixture of distorted corner and edge-sharing OMgZnFeW trigonal pyramids. In the fourth O site, O(4) is bonded in a rectangular see-saw-like geometry to one Mg(1), one W(1), one Fe(1), and one Zn(1) atom. In the fifth O site, O(5) is bonded in a 5-coordinate geometry to one Mg(1), one W(1), one Fe(1), one Zn(1), and one Zn(2) atom. In the sixth O site, O(6) is bonded in a 5-coordinate geometry to one Mg(1), one W(1), one Fe(1), one Zn(1), and one Zn(2) atom. is represented by the CIF file [CIF]
data_MgZn2FeWO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.354
_cell_length_b   6.005
_cell_length_c   8.036
_cell_angle_alpha   98.072
_cell_angle_beta   130.777
_cell_angle_gamma   118.531
_symmetry_Int_Tables_number   1
_cell_volume   126.047
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.003  0.287  0.346  1.0
  Zn  Zn1  1  0.010  0.630  0.178  1.0
  Zn  Zn2  1  0.986  0.452  0.757  1.0
  Fe  Fe3  1  0.027  0.922  0.547  1.0
  W  W4  1  0.995  0.992  0.990  1.0
  O  O5  1  0.721  0.832  0.102  1.0
  O  O6  1  0.385  0.153  0.961  1.0
  O  O7  1  0.320  0.470  0.257  1.0
  O  O8  1  0.371  0.808  0.597  1.0
  O  O9  1  0.604  0.114  0.375  1.0
  O  O10  1  0.620  0.461  0.749  1.0
[/CIF]
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The material structure described by MgWFeZn2O6 crystallizes in the triclinic P1 space group. Mg(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form MgO6 octahedra that share corners with three equivalent Zn(1)O6 octahedra, edges with three equivalent W(1)O6 octahedra, and  a faceface with one Zn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 36-46°. W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form WO6 octahedra that share corners with three equivalent Zn(1)O6 octahedra, edges with three equivalent Mg(1)O6 octahedra, and  a faceface with one Zn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 43-48°. Fe(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form ZnO6 octahedra that share corners with three equivalent Mg(1)O6 octahedra, corners with three equivalent W(1)O6 octahedra,  a faceface with one Mg(1)O6 octahedra, and  a faceface with one W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 36-48°. In the second Zn site, Zn(2) is bonded in a trigonal planar geometry to one O(1), one O(5), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to one Mg(1), one W(1), one Fe(1), one Zn(1), and one Zn(2) atom. In the second O site, O(2) is bonded to one Mg(1), one W(1), one Fe(1), and one Zn(1) atom to form a mixture of distorted corner and edge-sharing OMgZnFeW trigonal pyramids. In the third O site, O(3) is bonded to one Mg(1), one W(1), one Fe(1), and one Zn(1) atom to form a mixture of distorted corner and edge-sharing OMgZnFeW trigonal pyramids. In the fourth O site, O(4) is bonded in a rectangular see-saw-like geometry to one Mg(1), one W(1), one Fe(1), and one Zn(1) atom. In the fifth O site, O(5) is bonded in a 5-coordinate geometry to one Mg(1), one W(1), one Fe(1), one Zn(1), and one Zn(2) atom. In the sixth O site, O(6) is bonded in a 5-coordinate geometry to one Mg(1), one W(1), one Fe(1), one Zn(1), and one Zn(2) atom. is represented by the CIF file [CIF]
data_MgZn2FeWO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.354
_cell_length_b   6.005
_cell_length_c   8.036
_cell_angle_alpha   98.072
_cell_angle_beta   130.777
_cell_angle_gamma   118.531
_symmetry_Int_Tables_number   1
_cell_volume   126.047
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.003  0.287  0.346  1.0
  Zn  Zn1  1  0.010  0.630  0.178  1.0
  Zn  Zn2  1  0.986  0.452  0.757  1.0
  Fe  Fe3  1  0.027  0.922  0.547  1.0
  W  W4  1  0.995  0.992  0.990  1.0
  O  O5  1  0.721  0.832  0.102  1.0
  O  O6  1  0.385  0.153  0.961  1.0
  O  O7  1  0.320  0.470  0.257  1.0
  O  O8  1  0.371  0.808  0.597  1.0
  O  O9  1  0.604  0.114  0.375  1.0
  O  O10  1  0.620  0.461  0.749  1.0
[/CIF]
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