The compound described by CSb(OCl2)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two CSb(OCl2)2 clusters. In one of the CSb(OCl2)2 clusters, C(2) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(4) atom. Sb(1) is bonded in an octahedral geometry to one O(2), one O(4), one Cl(1), one Cl(4), one Cl(5), and one Cl(8) atom. There are two inequivalent O sites. In the first O site, O(2) is bonded in a bent 120 degrees geometry to one C(2) and one Sb(1) atom. In the second O site, O(4) is bonded in a bent 120 degrees geometry to one C(2) and one Sb(1) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second Cl site, Cl(4) is bonded in a single-bond geometry to one Sb(1) atom. In the third Cl site, Cl(5) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth Cl site, Cl(8) is bonded in a single-bond geometry to one Sb(1) atom. In one of the CSb(OCl2)2 clusters, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(3) atom. Sb(2) is bonded in an octahedral geometry to one O(1), one O(3), one Cl(2), one Cl(3), one Cl(6), and one Cl(7) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one C(1) and one Sb(2) atom. In the second O site, O(3) is bonded in a bent 120 degrees geometry to one C(1) and one Sb(2) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Sb(2) atom. In the second Cl site, Cl(3) is bonded in a single-bond geometry to one Sb(2) atom. In the third Cl site, Cl(6) is bonded in a single-bond geometry to one Sb(2) atom. In the fourth Cl site, Cl(7) is bonded in a single-bond geometry to one Sb(2) atom. is represented by the CIF card [CIF]
data_SbC(Cl2O)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.125
_cell_length_b   7.433
_cell_length_c   16.683
_cell_angle_alpha   80.049
_cell_angle_beta   84.220
_cell_angle_gamma   82.956
_symmetry_Int_Tables_number   1
_cell_volume   860.792
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.663  0.729  0.625  1.0
  Sb  Sb1  1  0.782  0.756  0.114  1.0
  Sb  Sb2  1  0.337  0.271  0.375  1.0
  Sb  Sb3  1  0.218  0.244  0.886  1.0
  C  C4  1  0.915  0.076  0.999  1.0
  C  C5  1  0.443  0.050  0.533  1.0
  C  C6  1  0.085  0.924  0.001  1.0
  C  C7  1  0.557  0.950  0.467  1.0
  Cl  Cl8  1  0.876  0.470  0.611  1.0
  Cl  Cl9  1  0.529  0.196  0.829  1.0
  Cl  Cl10  1  0.310  0.326  0.006  1.0
  Cl  Cl11  1  0.124  0.530  0.389  1.0
  Cl  Cl12  1  0.904  0.926  0.614  1.0
  Cl  Cl13  1  0.390  0.285  0.234  1.0
  Cl  Cl14  1  0.690  0.674  0.994  1.0
  Cl  Cl15  1  0.091  0.113  0.787  1.0
  Cl  Cl16  1  0.120  0.545  0.829  1.0
  Cl  Cl17  1  0.604  0.418  0.387  1.0
  Cl  Cl18  1  0.880  0.455  0.171  1.0
  Cl  Cl19  1  0.610  0.715  0.766  1.0
  Cl  Cl20  1  0.471  0.804  0.171  1.0
  Cl  Cl21  1  0.096  0.074  0.386  1.0
  Cl  Cl22  1  0.909  0.887  0.213  1.0
  Cl  Cl23  1  0.396  0.582  0.613  1.0
  O  O24  1  0.234  0.962  0.956  1.0
  O  O25  1  0.533  0.016  0.393  1.0
  O  O26  1  0.766  0.038  0.044  1.0
  O  O27  1  0.064  0.772  0.046  1.0
  O  O28  1  0.936  0.228  0.954  1.0
  O  O29  1  0.467  0.984  0.607  1.0
  O  O30  1  0.332  0.192  0.509  1.0
  O  O31  1  0.668  0.808  0.491  1.0
[/CIF]
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The compound described by CSb(OCl2)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two CSb(OCl2)2 clusters. In one of the CSb(OCl2)2 clusters, C(2) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(4) atom. Sb(1) is bonded in an octahedral geometry to one O(2), one O(4), one Cl(1), one Cl(4), one Cl(5), and one Cl(8) atom. There are two inequivalent O sites. In the first O site, O(2) is bonded in a bent 120 degrees geometry to one C(2) and one Sb(1) atom. In the second O site, O(4) is bonded in a bent 120 degrees geometry to one C(2) and one Sb(1) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second Cl site, Cl(4) is bonded in a single-bond geometry to one Sb(1) atom. In the third Cl site, Cl(5) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth Cl site, Cl(8) is bonded in a single-bond geometry to one Sb(1) atom. In one of the CSb(OCl2)2 clusters, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(3) atom. Sb(2) is bonded in an octahedral geometry to one O(1), one O(3), one Cl(2), one Cl(3), one Cl(6), and one Cl(7) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one C(1) and one Sb(2) atom. In the second O site, O(3) is bonded in a bent 120 degrees geometry to one C(1) and one Sb(2) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Sb(2) atom. In the second Cl site, Cl(3) is bonded in a single-bond geometry to one Sb(2) atom. In the third Cl site, Cl(6) is bonded in a single-bond geometry to one Sb(2) atom. In the fourth Cl site, Cl(7) is bonded in a single-bond geometry to one Sb(2) atom. is represented by the CIF card [CIF]
data_SbC(Cl2O)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.125
_cell_length_b   7.433
_cell_length_c   16.683
_cell_angle_alpha   80.049
_cell_angle_beta   84.220
_cell_angle_gamma   82.956
_symmetry_Int_Tables_number   1
_cell_volume   860.792
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.663  0.729  0.625  1.0
  Sb  Sb1  1  0.782  0.756  0.114  1.0
  Sb  Sb2  1  0.337  0.271  0.375  1.0
  Sb  Sb3  1  0.218  0.244  0.886  1.0
  C  C4  1  0.915  0.076  0.999  1.0
  C  C5  1  0.443  0.050  0.533  1.0
  C  C6  1  0.085  0.924  0.001  1.0
  C  C7  1  0.557  0.950  0.467  1.0
  Cl  Cl8  1  0.876  0.470  0.611  1.0
  Cl  Cl9  1  0.529  0.196  0.829  1.0
  Cl  Cl10  1  0.310  0.326  0.006  1.0
  Cl  Cl11  1  0.124  0.530  0.389  1.0
  Cl  Cl12  1  0.904  0.926  0.614  1.0
  Cl  Cl13  1  0.390  0.285  0.234  1.0
  Cl  Cl14  1  0.690  0.674  0.994  1.0
  Cl  Cl15  1  0.091  0.113  0.787  1.0
  Cl  Cl16  1  0.120  0.545  0.829  1.0
  Cl  Cl17  1  0.604  0.418  0.387  1.0
  Cl  Cl18  1  0.880  0.455  0.171  1.0
  Cl  Cl19  1  0.610  0.715  0.766  1.0
  Cl  Cl20  1  0.471  0.804  0.171  1.0
  Cl  Cl21  1  0.096  0.074  0.386  1.0
  Cl  Cl22  1  0.909  0.887  0.213  1.0
  Cl  Cl23  1  0.396  0.582  0.613  1.0
  O  O24  1  0.234  0.962  0.956  1.0
  O  O25  1  0.533  0.016  0.393  1.0
  O  O26  1  0.766  0.038  0.044  1.0
  O  O27  1  0.064  0.772  0.046  1.0
  O  O28  1  0.936  0.228  0.954  1.0
  O  O29  1  0.467  0.984  0.607  1.0
  O  O30  1  0.332  0.192  0.509  1.0
  O  O31  1  0.668  0.808  0.491  1.0
[/CIF]
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