The material structure described by TbOOH crystallizes in the orthorhombic Pmmn space group. Tb(1) is bonded in a 8-coordinate geometry to two equivalent H(1), two equivalent O(2), and four equivalent O(1) atoms. H(1) is bonded in a single-bond geometry to two equivalent Tb(1), one O(1), and one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to four equivalent Tb(1) and one H(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent Tb(1) and one H(1) atom. is represented by the CIF card [CIF]
data_TbHO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.686
_cell_length_b   4.509
_cell_length_c   5.554
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   92.298
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tb  Tb0  1  0.000  0.000  0.809  1.0
  Tb  Tb1  1  0.500  0.500  0.191  1.0
  H  H2  1  0.500  0.000  0.393  1.0
  H  H3  1  0.000  0.500  0.607  1.0
  O  O4  1  0.500  0.000  0.077  1.0
  O  O5  1  0.000  0.500  0.923  1.0
  O  O6  1  0.500  0.000  0.571  1.0
  O  O7  1  0.000  0.500  0.429  1.0
[/CIF]
.
The material structure described by TbOOH crystallizes in the orthorhombic Pmmn space group. Tb(1) is bonded in a 8-coordinate geometry to two equivalent H(1), two equivalent O(2), and four equivalent O(1) atoms. H(1) is bonded in a single-bond geometry to two equivalent Tb(1), one O(1), and one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to four equivalent Tb(1) and one H(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent Tb(1) and one H(1) atom. is represented by the CIF card [CIF]
data_TbHO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.686
_cell_length_b   4.509
_cell_length_c   5.554
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   92.298
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tb  Tb0  1  0.000  0.000  0.809  1.0
  Tb  Tb1  1  0.500  0.500  0.191  1.0
  H  H2  1  0.500  0.000  0.393  1.0
  H  H3  1  0.000  0.500  0.607  1.0
  O  O4  1  0.500  0.000  0.077  1.0
  O  O5  1  0.000  0.500  0.923  1.0
  O  O6  1  0.500  0.000  0.571  1.0
  O  O7  1  0.000  0.500  0.429  1.0
[/CIF]
.