The structure described by MoO5F2(NH4)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four ammonium molecules and two MoO5F2 clusters. In each MoO5F2 cluster, Mo(1) is bonded in a distorted pentagonal bipyramidal geometry to one O(1), one O(2), one O(3), one O(4), one O(5), one F(1), and one F(2) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Mo(1) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Mo(1) and one O(3) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to one Mo(1) and one O(2) atom. In the fourth O site, O(4) is bonded in a 2-coordinate geometry to one Mo(1) and one O(5) atom. In the fifth O site, O(5) is bonded in a 2-coordinate geometry to one Mo(1) and one O(4) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Mo(1) atom. In the second F site, F(2) is bonded in a 1-coordinate geometry to one Mo(1) atom. is represented by the CIF card [CIF]
data_MoH8N2O5F2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.983
_cell_length_b   7.662
_cell_length_c   6.177
_cell_angle_alpha   84.182
_cell_angle_beta   110.191
_cell_angle_gamma   97.728
_symmetry_Int_Tables_number   1
_cell_volume   350.776
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mo  Mo0  1  0.741  0.799  0.907  1.0
  Mo  Mo1  1  0.259  0.201  0.093  1.0
  H  H2  1  0.563  0.304  0.899  1.0
  H  H3  1  0.437  0.696  0.101  1.0
  H  H4  1  0.616  0.190  0.715  1.0
  H  H5  1  0.384  0.810  0.285  1.0
  H  H6  1  0.445  0.318  0.612  1.0
  H  H7  1  0.555  0.682  0.388  1.0
  H  H8  1  0.657  0.418  0.713  1.0
  H  H9  1  0.343  0.582  0.287  1.0
  H  H10  1  0.955  0.707  0.613  1.0
  H  H11  1  0.045  0.293  0.387  1.0
  H  H12  1  0.141  0.853  0.639  1.0
  H  H13  1  0.859  0.147  0.361  1.0
  H  H14  1  0.157  0.635  0.664  1.0
  H  H15  1  0.843  0.365  0.336  1.0
  H  H16  1  0.048  0.735  0.401  1.0
  H  H17  1  0.952  0.265  0.599  1.0
  N  N18  1  0.572  0.307  0.736  1.0
  N  N19  1  0.428  0.693  0.264  1.0
  N  N20  1  0.076  0.733  0.579  1.0
  N  N21  1  0.924  0.267  0.421  1.0
  O  O22  1  0.727  0.934  0.106  1.0
  O  O23  1  0.273  0.066  0.894  1.0
  O  O24  1  0.679  0.967  0.627  1.0
  O  O25  1  0.321  0.033  0.373  1.0
  O  O26  1  0.874  0.961  0.741  1.0
  O  O27  1  0.126  0.039  0.259  1.0
  O  O28  1  0.963  0.690  0.089  1.0
  O  O29  1  0.037  0.310  0.911  1.0
  O  O30  1  0.801  0.576  0.100  1.0
  O  O31  1  0.199  0.424  0.900  1.0
  F  F32  1  0.483  0.695  0.816  1.0
  F  F33  1  0.517  0.305  0.184  1.0
  F  F34  1  0.739  0.624  0.633  1.0
  F  F35  1  0.261  0.376  0.367  1.0
[/CIF]
.
The structure described by MoO5F2(NH4)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four ammonium molecules and two MoO5F2 clusters. In each MoO5F2 cluster, Mo(1) is bonded in a distorted pentagonal bipyramidal geometry to one O(1), one O(2), one O(3), one O(4), one O(5), one F(1), and one F(2) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Mo(1) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Mo(1) and one O(3) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to one Mo(1) and one O(2) atom. In the fourth O site, O(4) is bonded in a 2-coordinate geometry to one Mo(1) and one O(5) atom. In the fifth O site, O(5) is bonded in a 2-coordinate geometry to one Mo(1) and one O(4) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Mo(1) atom. In the second F site, F(2) is bonded in a 1-coordinate geometry to one Mo(1) atom. is represented by the CIF card [CIF]
data_MoH8N2O5F2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.983
_cell_length_b   7.662
_cell_length_c   6.177
_cell_angle_alpha   84.182
_cell_angle_beta   110.191
_cell_angle_gamma   97.728
_symmetry_Int_Tables_number   1
_cell_volume   350.776
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mo  Mo0  1  0.741  0.799  0.907  1.0
  Mo  Mo1  1  0.259  0.201  0.093  1.0
  H  H2  1  0.563  0.304  0.899  1.0
  H  H3  1  0.437  0.696  0.101  1.0
  H  H4  1  0.616  0.190  0.715  1.0
  H  H5  1  0.384  0.810  0.285  1.0
  H  H6  1  0.445  0.318  0.612  1.0
  H  H7  1  0.555  0.682  0.388  1.0
  H  H8  1  0.657  0.418  0.713  1.0
  H  H9  1  0.343  0.582  0.287  1.0
  H  H10  1  0.955  0.707  0.613  1.0
  H  H11  1  0.045  0.293  0.387  1.0
  H  H12  1  0.141  0.853  0.639  1.0
  H  H13  1  0.859  0.147  0.361  1.0
  H  H14  1  0.157  0.635  0.664  1.0
  H  H15  1  0.843  0.365  0.336  1.0
  H  H16  1  0.048  0.735  0.401  1.0
  H  H17  1  0.952  0.265  0.599  1.0
  N  N18  1  0.572  0.307  0.736  1.0
  N  N19  1  0.428  0.693  0.264  1.0
  N  N20  1  0.076  0.733  0.579  1.0
  N  N21  1  0.924  0.267  0.421  1.0
  O  O22  1  0.727  0.934  0.106  1.0
  O  O23  1  0.273  0.066  0.894  1.0
  O  O24  1  0.679  0.967  0.627  1.0
  O  O25  1  0.321  0.033  0.373  1.0
  O  O26  1  0.874  0.961  0.741  1.0
  O  O27  1  0.126  0.039  0.259  1.0
  O  O28  1  0.963  0.690  0.089  1.0
  O  O29  1  0.037  0.310  0.911  1.0
  O  O30  1  0.801  0.576  0.100  1.0
  O  O31  1  0.199  0.424  0.900  1.0
  F  F32  1  0.483  0.695  0.816  1.0
  F  F33  1  0.517  0.305  0.184  1.0
  F  F34  1  0.739  0.624  0.633  1.0
  F  F35  1  0.261  0.376  0.367  1.0
[/CIF]
.