The structure described by ZrCrCo crystallizes in the orthorhombic Amm2 space group. There are seven inequivalent Zr sites. In the first Zr site, Zr(1) is bonded in a 16-coordinate geometry to one Zr(1); three Zr(2,2); two equivalent Cr(1); three equivalent Cr(2); one Co(3); two equivalent Co(1); and four equivalent Co(2) atoms. In the second Zr site, Zr(2) is bonded in a 16-coordinate geometry to one Zr(2); three Zr(1,1); three equivalent Cr(2); four equivalent Cr(1); one Co(1); two equivalent Co(2); and two equivalent Co(3) atoms. In the third Zr site, Zr(2) is bonded in a 16-coordinate geometry to one Zr(2); three Zr(1,1); three equivalent Cr(2); four equivalent Cr(1); one Co(1); two equivalent Co(2); and two equivalent Co(3) atoms. In the fourth Zr site, Zr(1) is bonded in a 16-coordinate geometry to one Zr(1); three Zr(2,2); two equivalent Cr(1); three equivalent Cr(2); one Co(3); two equivalent Co(1); and four equivalent Co(2) atoms. In the fifth Zr site, Zr(2) is bonded in a 16-coordinate geometry to one Zr(2); three Zr(1,1); three equivalent Cr(2); four equivalent Cr(1); one Co(1); two equivalent Co(2); and two equivalent Co(3) atoms. In the sixth Zr site, Zr(2) is bonded in a 16-coordinate geometry to one Zr(2); three Zr(1,1); three equivalent Cr(2); four equivalent Cr(1); one Co(1); two equivalent Co(2); and two equivalent Co(3) atoms. In the seventh Zr site, Zr(1) is bonded in a 16-coordinate geometry to one Zr(1); three Zr(2,2); two equivalent Cr(1); three equivalent Cr(2); one Co(3); two equivalent Co(1); and four equivalent Co(2) atoms. There are two inequivalent Cr sites. In the first Cr site, Cr(1) is bonded to two Zr(1,1); four Zr(2,2,2,2); two equivalent Cr(1); two equivalent Cr(2); and two equivalent Co(3) atoms to form distorted CrZr6Cr4Co2 cuboctahedra that share corners with four equivalent Cr(2)Zr6Cr2Co4 cuboctahedra, corners with four equivalent Cr(1)Zr6Cr4Co2 cuboctahedra, corners with four equivalent Co(1)Zr6Cr2Co4 cuboctahedra, corners with six equivalent Co(2)Zr6Cr2Co4 cuboctahedra, edges with two equivalent Cr(1)Zr6Cr4Co2 cuboctahedra, edges with four equivalent Co(2)Zr6Cr2Co4 cuboctahedra, faces with two equivalent Co(1)Zr6Cr2Co4 cuboctahedra, faces with two equivalent Co(2)Zr6Cr2Co4 cuboctahedra, faces with four equivalent Cr(1)Zr6Cr4Co2 cuboctahedra, faces with four equivalent Co(3)Zr6Cr6 cuboctahedra, and faces with six equivalent Cr(2)Zr6Cr2Co4 cuboctahedra. In the second Cr site, Cr(2) is bonded to three Zr(1,1); three Zr(2,2); two equivalent Cr(1); one Co(1); one Co(3); and two equivalent Co(2) atoms to form distorted CrZr6Cr2Co4 cuboctahedra that share corners with two equivalent Co(1)Zr6Cr2Co4 cuboctahedra, corners with two equivalent Co(3)Zr6Cr6 cuboctahedra, corners with four equivalent Cr(1)Zr6Cr4Co2 cuboctahedra, corners with four equivalent Co(2)Zr6Cr2Co4 cuboctahedra, edges with six equivalent Cr(2)Zr6Cr2Co4 cuboctahedra, faces with two equivalent Cr(2)Zr6Cr2Co4 cuboctahedra, faces with three equivalent Co(1)Zr6Cr2Co4 cuboctahedra, faces with three equivalent Co(3)Zr6Cr6 cuboctahedra, faces with six equivalent Cr(1)Zr6Cr4Co2 cuboctahedra, and faces with six equivalent Co(2)Zr6Cr2Co4 cuboctahedra. There are three inequivalent Co sites. In the first Co site, Co(1) is bonded to two Zr(2,2); four Zr(1,1); two equivalent Cr(2); and four equivalent Co(2) atoms to form distorted CoZr6Cr2Co4 cuboctahedra that share corners with two equivalent Co(3)Zr6Cr6 cuboctahedra, corners with four equivalent Cr(2)Zr6Cr2Co4 cuboctahedra, corners with four equivalent Co(1)Zr6Cr2Co4 cuboctahedra, corners with eight equivalent Cr(1)Zr6Cr4Co2 cuboctahedra, edges with two equivalent Co(1)Zr6Cr2Co4 cuboctahedra, edges with four equivalent Co(3)Zr6Cr6 cuboctahedra, faces with four equivalent Cr(1)Zr6Cr4Co2 cuboctahedra, faces with six equivalent Cr(2)Zr6Cr2Co4 cuboctahedra, and faces with eight equivalent Co(2)Zr6Cr2Co4 cuboctahedra. In the second Co site, Co(2) is bonded to two Zr(2,2); four Zr(1,1,1); two equivalent Cr(2); two equivalent Co(1); and two equivalent Co(2) atoms to form distorted CoZr6Cr2Co4 cuboctahedra that share corners with four equivalent Cr(2)Zr6Cr2Co4 cuboctahedra, corners with four equivalent Co(2)Zr6Cr2Co4 cuboctahedra, corners with four equivalent Co(3)Zr6Cr6 cuboctahedra, corners with six equivalent Cr(1)Zr6Cr4Co2 cuboctahedra, edges with two equivalent Co(2)Zr6Cr2Co4 cuboctahedra, edges with four equivalent Cr(1)Zr6Cr4Co2 cuboctahedra, faces with two equivalent Cr(1)Zr6Cr4Co2 cuboctahedra, faces with two equivalent Co(3)Zr6Cr6 cuboctahedra, faces with four equivalent Co(1)Zr6Cr2Co4 cuboctahedra, faces with four equivalent Co(2)Zr6Cr2Co4 cuboctahedra, and faces with six equivalent Cr(2)Zr6Cr2Co4 cuboctahedra. In the third Co site, Co(3) is bonded to two Zr(1,1); four Zr(2,2); two equivalent Cr(2); and four equivalent Cr(1) atoms to form CoZr6Cr6 cuboctahedra that share corners with two equivalent Co(1)Zr6Cr2Co4 cuboctahedra, corners with four equivalent Cr(2)Zr6Cr2Co4 cuboctahedra, corners with four equivalent Co(3)Zr6Cr6 cuboctahedra, corners with eight equivalent Co(2)Zr6Cr2Co4 cuboctahedra, edges with two equivalent Co(3)Zr6Cr6 cuboctahedra, edges with four equivalent Co(1)Zr6Cr2Co4 cuboctahedra, faces with four equivalent Co(2)Zr6Cr2Co4 cuboctahedra, faces with six equivalent Cr(2)Zr6Cr2Co4 cuboctahedra, and faces with eight equivalent Cr(1)Zr6Cr4Co2 cuboctahedra. is represented by the CIF card [CIF]
data_ZrCrCo
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.056
_cell_length_b   5.056
_cell_length_c   7.886
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   121.173
_symmetry_Int_Tables_number   1
_cell_volume   172.495
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr0  1  0.334  0.666  0.684  1.0
  Zr  Zr1  1  0.666  0.334  0.807  1.0
  Zr  Zr2  1  0.666  0.334  0.193  1.0
  Zr  Zr3  1  0.334  0.666  0.316  1.0
  Cr  Cr4  1  0.666  0.832  0.000  1.0
  Cr  Cr5  1  0.168  0.334  0.000  1.0
  Cr  Cr6  1  0.997  0.003  0.251  1.0
  Cr  Cr7  1  0.997  0.003  0.749  1.0
  Co  Co8  1  0.832  0.168  0.500  1.0
  Co  Co9  1  0.332  0.166  0.500  1.0
  Co  Co10  1  0.834  0.668  0.500  1.0
  Co  Co11  1  0.172  0.828  0.000  1.0
[/CIF]
.
The structure described by ZrCrCo crystallizes in the orthorhombic Amm2 space group. There are seven inequivalent Zr sites. In the first Zr site, Zr(1) is bonded in a 16-coordinate geometry to one Zr(1); three Zr(2,2); two equivalent Cr(1); three equivalent Cr(2); one Co(3); two equivalent Co(1); and four equivalent Co(2) atoms. In the second Zr site, Zr(2) is bonded in a 16-coordinate geometry to one Zr(2); three Zr(1,1); three equivalent Cr(2); four equivalent Cr(1); one Co(1); two equivalent Co(2); and two equivalent Co(3) atoms. In the third Zr site, Zr(2) is bonded in a 16-coordinate geometry to one Zr(2); three Zr(1,1); three equivalent Cr(2); four equivalent Cr(1); one Co(1); two equivalent Co(2); and two equivalent Co(3) atoms. In the fourth Zr site, Zr(1) is bonded in a 16-coordinate geometry to one Zr(1); three Zr(2,2); two equivalent Cr(1); three equivalent Cr(2); one Co(3); two equivalent Co(1); and four equivalent Co(2) atoms. In the fifth Zr site, Zr(2) is bonded in a 16-coordinate geometry to one Zr(2); three Zr(1,1); three equivalent Cr(2); four equivalent Cr(1); one Co(1); two equivalent Co(2); and two equivalent Co(3) atoms. In the sixth Zr site, Zr(2) is bonded in a 16-coordinate geometry to one Zr(2); three Zr(1,1); three equivalent Cr(2); four equivalent Cr(1); one Co(1); two equivalent Co(2); and two equivalent Co(3) atoms. In the seventh Zr site, Zr(1) is bonded in a 16-coordinate geometry to one Zr(1); three Zr(2,2); two equivalent Cr(1); three equivalent Cr(2); one Co(3); two equivalent Co(1); and four equivalent Co(2) atoms. There are two inequivalent Cr sites. In the first Cr site, Cr(1) is bonded to two Zr(1,1); four Zr(2,2,2,2); two equivalent Cr(1); two equivalent Cr(2); and two equivalent Co(3) atoms to form distorted CrZr6Cr4Co2 cuboctahedra that share corners with four equivalent Cr(2)Zr6Cr2Co4 cuboctahedra, corners with four equivalent Cr(1)Zr6Cr4Co2 cuboctahedra, corners with four equivalent Co(1)Zr6Cr2Co4 cuboctahedra, corners with six equivalent Co(2)Zr6Cr2Co4 cuboctahedra, edges with two equivalent Cr(1)Zr6Cr4Co2 cuboctahedra, edges with four equivalent Co(2)Zr6Cr2Co4 cuboctahedra, faces with two equivalent Co(1)Zr6Cr2Co4 cuboctahedra, faces with two equivalent Co(2)Zr6Cr2Co4 cuboctahedra, faces with four equivalent Cr(1)Zr6Cr4Co2 cuboctahedra, faces with four equivalent Co(3)Zr6Cr6 cuboctahedra, and faces with six equivalent Cr(2)Zr6Cr2Co4 cuboctahedra. In the second Cr site, Cr(2) is bonded to three Zr(1,1); three Zr(2,2); two equivalent Cr(1); one Co(1); one Co(3); and two equivalent Co(2) atoms to form distorted CrZr6Cr2Co4 cuboctahedra that share corners with two equivalent Co(1)Zr6Cr2Co4 cuboctahedra, corners with two equivalent Co(3)Zr6Cr6 cuboctahedra, corners with four equivalent Cr(1)Zr6Cr4Co2 cuboctahedra, corners with four equivalent Co(2)Zr6Cr2Co4 cuboctahedra, edges with six equivalent Cr(2)Zr6Cr2Co4 cuboctahedra, faces with two equivalent Cr(2)Zr6Cr2Co4 cuboctahedra, faces with three equivalent Co(1)Zr6Cr2Co4 cuboctahedra, faces with three equivalent Co(3)Zr6Cr6 cuboctahedra, faces with six equivalent Cr(1)Zr6Cr4Co2 cuboctahedra, and faces with six equivalent Co(2)Zr6Cr2Co4 cuboctahedra. There are three inequivalent Co sites. In the first Co site, Co(1) is bonded to two Zr(2,2); four Zr(1,1); two equivalent Cr(2); and four equivalent Co(2) atoms to form distorted CoZr6Cr2Co4 cuboctahedra that share corners with two equivalent Co(3)Zr6Cr6 cuboctahedra, corners with four equivalent Cr(2)Zr6Cr2Co4 cuboctahedra, corners with four equivalent Co(1)Zr6Cr2Co4 cuboctahedra, corners with eight equivalent Cr(1)Zr6Cr4Co2 cuboctahedra, edges with two equivalent Co(1)Zr6Cr2Co4 cuboctahedra, edges with four equivalent Co(3)Zr6Cr6 cuboctahedra, faces with four equivalent Cr(1)Zr6Cr4Co2 cuboctahedra, faces with six equivalent Cr(2)Zr6Cr2Co4 cuboctahedra, and faces with eight equivalent Co(2)Zr6Cr2Co4 cuboctahedra. In the second Co site, Co(2) is bonded to two Zr(2,2); four Zr(1,1,1); two equivalent Cr(2); two equivalent Co(1); and two equivalent Co(2) atoms to form distorted CoZr6Cr2Co4 cuboctahedra that share corners with four equivalent Cr(2)Zr6Cr2Co4 cuboctahedra, corners with four equivalent Co(2)Zr6Cr2Co4 cuboctahedra, corners with four equivalent Co(3)Zr6Cr6 cuboctahedra, corners with six equivalent Cr(1)Zr6Cr4Co2 cuboctahedra, edges with two equivalent Co(2)Zr6Cr2Co4 cuboctahedra, edges with four equivalent Cr(1)Zr6Cr4Co2 cuboctahedra, faces with two equivalent Cr(1)Zr6Cr4Co2 cuboctahedra, faces with two equivalent Co(3)Zr6Cr6 cuboctahedra, faces with four equivalent Co(1)Zr6Cr2Co4 cuboctahedra, faces with four equivalent Co(2)Zr6Cr2Co4 cuboctahedra, and faces with six equivalent Cr(2)Zr6Cr2Co4 cuboctahedra. In the third Co site, Co(3) is bonded to two Zr(1,1); four Zr(2,2); two equivalent Cr(2); and four equivalent Cr(1) atoms to form CoZr6Cr6 cuboctahedra that share corners with two equivalent Co(1)Zr6Cr2Co4 cuboctahedra, corners with four equivalent Cr(2)Zr6Cr2Co4 cuboctahedra, corners with four equivalent Co(3)Zr6Cr6 cuboctahedra, corners with eight equivalent Co(2)Zr6Cr2Co4 cuboctahedra, edges with two equivalent Co(3)Zr6Cr6 cuboctahedra, edges with four equivalent Co(1)Zr6Cr2Co4 cuboctahedra, faces with four equivalent Co(2)Zr6Cr2Co4 cuboctahedra, faces with six equivalent Cr(2)Zr6Cr2Co4 cuboctahedra, and faces with eight equivalent Cr(1)Zr6Cr4Co2 cuboctahedra. is represented by the CIF card [CIF]
data_ZrCrCo
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.056
_cell_length_b   5.056
_cell_length_c   7.886
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   121.173
_symmetry_Int_Tables_number   1
_cell_volume   172.495
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr0  1  0.334  0.666  0.684  1.0
  Zr  Zr1  1  0.666  0.334  0.807  1.0
  Zr  Zr2  1  0.666  0.334  0.193  1.0
  Zr  Zr3  1  0.334  0.666  0.316  1.0
  Cr  Cr4  1  0.666  0.832  0.000  1.0
  Cr  Cr5  1  0.168  0.334  0.000  1.0
  Cr  Cr6  1  0.997  0.003  0.251  1.0
  Cr  Cr7  1  0.997  0.003  0.749  1.0
  Co  Co8  1  0.832  0.168  0.500  1.0
  Co  Co9  1  0.332  0.166  0.500  1.0
  Co  Co10  1  0.834  0.668  0.500  1.0
  Co  Co11  1  0.172  0.828  0.000  1.0
[/CIF]
.