The material structure described by NH(NH2O3)2HNO3 is Indium-like structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of two ammonia molecules, two nitric acid molecules, and two NH2O3 clusters. In each NH2O3 cluster, there are two inequivalent N sites. In the first N site, N(2) is bonded in a trigonal non-coplanar geometry to one O(1), one O(2), and one O(3) atom. In the second N site, N(4) is bonded in a trigonal planar geometry to one O(5), one O(7), and one O(9) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(3) atom. In the fourth H site, H(4) is bonded in a distorted bent 150 degrees geometry to one O(3) and one O(5) atom. There are six inequivalent O sites. In the first O site, O(9) is bonded in a single-bond geometry to one N(4) atom. In the second O site, O(1) is bonded in a water-like geometry to one N(2) and one H(1) atom. In the third O site, O(2) is bonded in a water-like geometry to one N(2) and one H(2) atom. In the fourth O site, O(3) is bonded in a 3-coordinate geometry to one N(2), one H(3), and one H(4) atom. In the fifth O site, O(5) is bonded in a water-like geometry to one N(4) and one H(4) atom. In the sixth O site, O(7) is bonded in a single-bond geometry to one N(4) atom. is represented by the CIF file [CIF]
data_H6N4O9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.086
_cell_length_b   5.396
_cell_length_c   6.588
_cell_angle_alpha   87.210
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   464.647
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.054  0.746  0.827  1.0
  H  H1  1  0.554  0.254  0.173  1.0
  H  H2  1  0.981  0.990  0.334  1.0
  H  H3  1  0.062  0.450  0.427  1.0
  H  H4  1  0.562  0.550  0.573  1.0
  H  H5  1  0.481  0.010  0.666  1.0
  H  H6  1  0.379  0.520  0.605  1.0
  H  H7  1  0.879  0.480  0.395  1.0
  H  H8  1  0.832  0.419  0.877  1.0
  H  H9  1  0.061  0.242  0.983  1.0
  H  H10  1  0.561  0.758  0.017  1.0
  H  H11  1  0.332  0.581  0.123  1.0
  N  N12  1  0.518  0.818  0.891  1.0
  N  N13  1  0.018  0.182  0.109  1.0
  N  N14  1  0.022  0.762  0.548  1.0
  N  N15  1  0.522  0.238  0.452  1.0
  N  N16  1  0.735  0.169  0.817  1.0
  N  N17  1  0.270  0.372  0.768  1.0
  N  N18  1  0.770  0.628  0.232  1.0
  N  N19  1  0.235  0.831  0.183  1.0
  O  O20  1  0.989  0.746  0.752  1.0
  O  O21  1  0.489  0.254  0.248  1.0
  O  O22  1  0.947  0.912  0.456  1.0
  O  O23  1  0.996  0.508  0.476  1.0
  O  O24  1  0.496  0.492  0.524  1.0
  O  O25  1  0.447  0.088  0.544  1.0
  O  O26  1  0.721  0.977  0.733  1.0
  O  O27  1  0.301  0.523  0.606  1.0
  O  O28  1  0.801  0.477  0.394  1.0
  O  O29  1  0.221  0.023  0.267  1.0
  O  O30  1  0.672  0.291  0.912  1.0
  O  O31  1  0.331  0.330  0.908  1.0
  O  O32  1  0.831  0.670  0.092  1.0
  O  O33  1  0.172  0.709  0.088  1.0
  O  O34  1  0.834  0.262  0.803  1.0
  O  O35  1  0.182  0.298  0.757  1.0
  O  O36  1  0.682  0.702  0.243  1.0
  O  O37  1  0.334  0.738  0.197  1.0
[/CIF]
.
The material structure described by NH(NH2O3)2HNO3 is Indium-like structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of two ammonia molecules, two nitric acid molecules, and two NH2O3 clusters. In each NH2O3 cluster, there are two inequivalent N sites. In the first N site, N(2) is bonded in a trigonal non-coplanar geometry to one O(1), one O(2), and one O(3) atom. In the second N site, N(4) is bonded in a trigonal planar geometry to one O(5), one O(7), and one O(9) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(3) atom. In the fourth H site, H(4) is bonded in a distorted bent 150 degrees geometry to one O(3) and one O(5) atom. There are six inequivalent O sites. In the first O site, O(9) is bonded in a single-bond geometry to one N(4) atom. In the second O site, O(1) is bonded in a water-like geometry to one N(2) and one H(1) atom. In the third O site, O(2) is bonded in a water-like geometry to one N(2) and one H(2) atom. In the fourth O site, O(3) is bonded in a 3-coordinate geometry to one N(2), one H(3), and one H(4) atom. In the fifth O site, O(5) is bonded in a water-like geometry to one N(4) and one H(4) atom. In the sixth O site, O(7) is bonded in a single-bond geometry to one N(4) atom. is represented by the CIF file [CIF]
data_H6N4O9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.086
_cell_length_b   5.396
_cell_length_c   6.588
_cell_angle_alpha   87.210
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   464.647
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.054  0.746  0.827  1.0
  H  H1  1  0.554  0.254  0.173  1.0
  H  H2  1  0.981  0.990  0.334  1.0
  H  H3  1  0.062  0.450  0.427  1.0
  H  H4  1  0.562  0.550  0.573  1.0
  H  H5  1  0.481  0.010  0.666  1.0
  H  H6  1  0.379  0.520  0.605  1.0
  H  H7  1  0.879  0.480  0.395  1.0
  H  H8  1  0.832  0.419  0.877  1.0
  H  H9  1  0.061  0.242  0.983  1.0
  H  H10  1  0.561  0.758  0.017  1.0
  H  H11  1  0.332  0.581  0.123  1.0
  N  N12  1  0.518  0.818  0.891  1.0
  N  N13  1  0.018  0.182  0.109  1.0
  N  N14  1  0.022  0.762  0.548  1.0
  N  N15  1  0.522  0.238  0.452  1.0
  N  N16  1  0.735  0.169  0.817  1.0
  N  N17  1  0.270  0.372  0.768  1.0
  N  N18  1  0.770  0.628  0.232  1.0
  N  N19  1  0.235  0.831  0.183  1.0
  O  O20  1  0.989  0.746  0.752  1.0
  O  O21  1  0.489  0.254  0.248  1.0
  O  O22  1  0.947  0.912  0.456  1.0
  O  O23  1  0.996  0.508  0.476  1.0
  O  O24  1  0.496  0.492  0.524  1.0
  O  O25  1  0.447  0.088  0.544  1.0
  O  O26  1  0.721  0.977  0.733  1.0
  O  O27  1  0.301  0.523  0.606  1.0
  O  O28  1  0.801  0.477  0.394  1.0
  O  O29  1  0.221  0.023  0.267  1.0
  O  O30  1  0.672  0.291  0.912  1.0
  O  O31  1  0.331  0.330  0.908  1.0
  O  O32  1  0.831  0.670  0.092  1.0
  O  O33  1  0.172  0.709  0.088  1.0
  O  O34  1  0.834  0.262  0.803  1.0
  O  O35  1  0.182  0.298  0.757  1.0
  O  O36  1  0.682  0.702  0.243  1.0
  O  O37  1  0.334  0.738  0.197  1.0
[/CIF]
.