The compound described by RbSO2F is Potassium chlorate-derived structured and crystallizes in the monoclinic P2_1/m space group. Rb(1) is bonded in a 9-coordinate geometry to six equivalent O(1) and three equivalent F(1) atoms. S(1) is bonded in a trigonal non-coplanar geometry to two equivalent O(1) and one F(1) atom. O(1) is bonded in a distorted single-bond geometry to three equivalent Rb(1) and one S(1) atom. F(1) is bonded in a 4-coordinate geometry to three equivalent Rb(1) and one S(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_RbSO2F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.886
_cell_length_b   6.030
_cell_length_c   7.400
_cell_angle_alpha   90.000
_cell_angle_beta   107.792
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   207.588
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.843  0.750  0.715  1.0
  Rb  Rb1  1  0.157  0.250  0.285  1.0
  S  S2  1  0.601  0.750  0.184  1.0
  S  S3  1  0.399  0.250  0.816  1.0
  O  O4  1  0.665  0.547  0.302  1.0
  O  O5  1  0.335  0.047  0.698  1.0
  O  O6  1  0.335  0.453  0.698  1.0
  O  O7  1  0.665  0.953  0.302  1.0
  F  F8  1  0.792  0.250  0.877  1.0
  F  F9  1  0.208  0.750  0.123  1.0
[/CIF]
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The compound described by RbSO2F is Potassium chlorate-derived structured and crystallizes in the monoclinic P2_1/m space group. Rb(1) is bonded in a 9-coordinate geometry to six equivalent O(1) and three equivalent F(1) atoms. S(1) is bonded in a trigonal non-coplanar geometry to two equivalent O(1) and one F(1) atom. O(1) is bonded in a distorted single-bond geometry to three equivalent Rb(1) and one S(1) atom. F(1) is bonded in a 4-coordinate geometry to three equivalent Rb(1) and one S(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_RbSO2F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.886
_cell_length_b   6.030
_cell_length_c   7.400
_cell_angle_alpha   90.000
_cell_angle_beta   107.792
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   207.588
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.843  0.750  0.715  1.0
  Rb  Rb1  1  0.157  0.250  0.285  1.0
  S  S2  1  0.601  0.750  0.184  1.0
  S  S3  1  0.399  0.250  0.816  1.0
  O  O4  1  0.665  0.547  0.302  1.0
  O  O5  1  0.335  0.047  0.698  1.0
  O  O6  1  0.335  0.453  0.698  1.0
  O  O7  1  0.665  0.953  0.302  1.0
  F  F8  1  0.792  0.250  0.877  1.0
  F  F9  1  0.208  0.750  0.123  1.0
[/CIF]
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