The material described by Cu17Zn35 is gamma-brass-like structured and crystallizes in the triclinic P1 space group. There are seventeen inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a 13-coordinate geometry to one Cu(13), one Cu(14), one Cu(7), one Zn(10), one Zn(11), one Zn(13), one Zn(17), one Zn(2), one Zn(23), one Zn(27), one Zn(29), one Zn(31), and one Zn(7) atom. In the second Cu site, Cu(2) is bonded in a 13-coordinate geometry to one Cu(12), one Cu(15), one Cu(8), one Zn(1), one Zn(12), one Zn(14), one Zn(18), one Zn(24), one Zn(28), one Zn(30), one Zn(32), one Zn(8), and one Zn(9) atom. In the third Cu site, Cu(3) is bonded in a 13-coordinate geometry to one Cu(12), one Cu(16), one Cu(9), one Zn(1), one Zn(11), one Zn(13), one Zn(19), one Zn(21), one Zn(23), one Zn(25), one Zn(31), one Zn(5), and one Zn(9) atom. In the fourth Cu site, Cu(4) is bonded in a 13-coordinate geometry to one Cu(13), one Cu(17), one Zn(10), one Zn(12), one Zn(14), one Zn(2), one Zn(20), one Zn(22), one Zn(24), one Zn(26), one Zn(32), one Zn(33), and one Zn(6) atom. In the fifth Cu site, Cu(5) is bonded in a 13-coordinate geometry to one Cu(15), one Cu(16), one Zn(1), one Zn(11), one Zn(14), one Zn(16), one Zn(18), one Zn(19), one Zn(22), one Zn(27), one Zn(34), one Zn(4), and one Zn(9) atom. In the sixth Cu site, Cu(6) is bonded in a 13-coordinate geometry to one Cu(14), one Cu(17), one Zn(10), one Zn(12), one Zn(13), one Zn(15), one Zn(17), one Zn(2), one Zn(20), one Zn(21), one Zn(28), one Zn(3), and one Zn(35) atom. In the seventh Cu site, Cu(7) is bonded in a 13-coordinate geometry to one Cu(1), one Cu(10), one Cu(16), one Zn(11), one Zn(16), one Zn(17), one Zn(19), one Zn(21), one Zn(23), one Zn(25), one Zn(29), one Zn(4), and one Zn(5) atom. In the eighth Cu site, Cu(8) is bonded in a 13-coordinate geometry to one Cu(11), one Cu(17), one Cu(2), one Zn(12), one Zn(15), one Zn(18), one Zn(20), one Zn(22), one Zn(24), one Zn(26), one Zn(3), one Zn(30), and one Zn(6) atom. In the ninth Cu site, Cu(9) is bonded in a 13-coordinate geometry to one Cu(11), one Cu(14), one Cu(3), one Zn(13), one Zn(15), one Zn(17), one Zn(19), one Zn(25), one Zn(27), one Zn(29), one Zn(3), one Zn(31), and one Zn(7) atom. In the tenth Cu site, Cu(10) is bonded in a 12-coordinate geometry to one Cu(7), one Zn(11), one Zn(14), one Zn(16), one Zn(25), one Zn(30), one Zn(33), one Zn(34), one Zn(4), one Zn(5), one Zn(8), and one Zn(9) atom. In the eleventh Cu site, Cu(11) is bonded in a 12-coordinate geometry to one Cu(8), one Cu(9), one Zn(10), one Zn(12), one Zn(13), one Zn(15), one Zn(26), one Zn(29), one Zn(3), one Zn(35), one Zn(6), and one Zn(7) atom. In the twelfth Cu site, Cu(12) is bonded in a 12-coordinate geometry to one Cu(2), one Cu(3), one Zn(1), one Zn(16), one Zn(18), one Zn(19), one Zn(23), one Zn(32), one Zn(34), one Zn(5), one Zn(8), and one Zn(9) atom. In the thirteenth Cu site, Cu(13) is bonded in a 12-coordinate geometry to one Cu(1), one Cu(4), one Zn(10), one Zn(15), one Zn(17), one Zn(2), one Zn(20), one Zn(24), one Zn(31), one Zn(35), one Zn(6), and one Zn(7) atom. In the fourteenth Cu site, Cu(14) is bonded in a 9-coordinate geometry to one Cu(1), one Cu(6), one Cu(9), one Zn(13), one Zn(17), one Zn(2), one Zn(21), one Zn(23), one Zn(25), one Zn(27), one Zn(3), and one Zn(7) atom. In the fifteenth Cu site, Cu(15) is bonded in a 12-coordinate geometry to one Cu(2), one Cu(5), one Zn(1), one Zn(14), one Zn(18), one Zn(22), one Zn(24), one Zn(26), one Zn(28), one Zn(33), one Zn(4), and one Zn(8) atom. In the sixteenth Cu site, Cu(16) is bonded in a 9-coordinate geometry to one Cu(3), one Cu(5), one Cu(7), one Zn(1), one Zn(11), one Zn(19), one Zn(21), one Zn(27), one Zn(29), one Zn(31), one Zn(4), and one Zn(5) atom. In the seventeenth Cu site, Cu(17) is bonded in a 9-coordinate geometry to one Cu(4), one Cu(6), one Cu(8), one Zn(12), one Zn(2), one Zn(20), one Zn(22), one Zn(28), one Zn(3), one Zn(30), one Zn(32), and one Zn(6) atom. There are thirty-five inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a 12-coordinate geometry to one Cu(12), one Cu(15), one Cu(16), one Cu(2), one Cu(3), one Cu(5), one Zn(11), one Zn(14), one Zn(4), one Zn(5), one Zn(8), and one Zn(9) atom. In the second Zn site, Zn(2) is bonded in a 12-coordinate geometry to one Cu(1), one Cu(13), one Cu(14), one Cu(17), one Cu(4), one Cu(6), one Zn(10), one Zn(12), one Zn(13), one Zn(3), one Zn(6), and one Zn(7) atom. In the third Zn site, Zn(3) is bonded in a 12-coordinate geometry to one Cu(11), one Cu(14), one Cu(17), one Cu(6), one Cu(8), one Cu(9), one Zn(15), one Zn(17), one Zn(2), one Zn(20), one Zn(6), and one Zn(7) atom. In the fourth Zn site, Zn(4) is bonded in a 12-coordinate geometry to one Cu(10), one Cu(15), one Cu(16), one Cu(5), one Cu(7), one Zn(1), one Zn(16), one Zn(18), one Zn(19), one Zn(33), one Zn(5), and one Zn(8) atom. In the fifth Zn site, Zn(5) is bonded in a 12-coordinate geometry to one Cu(10), one Cu(12), one Cu(16), one Cu(3), one Cu(7), one Zn(1), one Zn(21), one Zn(23), one Zn(25), one Zn(34), one Zn(4), and one Zn(8) atom. In the sixth Zn site, Zn(6) is bonded in a 12-coordinate geometry to one Cu(11), one Cu(13), one Cu(17), one Cu(4), one Cu(8), one Zn(2), one Zn(22), one Zn(24), one Zn(26), one Zn(3), one Zn(35), and one Zn(7) atom. In the seventh Zn site, Zn(7) is bonded in a 12-coordinate geometry to one Cu(1), one Cu(11), one Cu(13), one Cu(14), one Cu(9), one Zn(2), one Zn(27), one Zn(29), one Zn(3), one Zn(31), one Zn(35), and one Zn(6) atom. In the eighth Zn site, Zn(8) is bonded in a 12-coordinate geometry to one Cu(10), one Cu(12), one Cu(15), one Cu(2), one Zn(1), one Zn(28), one Zn(30), one Zn(32), one Zn(33), one Zn(34), one Zn(4), and one Zn(5) atom. In the ninth Zn site, Zn(9) is bonded in a 11-coordinate geometry to one Cu(10), one Cu(12), one Cu(2), one Cu(3), one Cu(5), one Zn(1), one Zn(18), one Zn(19), one Zn(25), one Zn(30), and one Zn(34) atom. In the tenth Zn site, Zn(10) is bonded in a 11-coordinate geometry to one Cu(1), one Cu(11), one Cu(13), one Cu(4), one Cu(6), one Zn(17), one Zn(2), one Zn(20), one Zn(26), one Zn(29), and one Zn(35) atom. In the eleventh Zn site, Zn(11) is bonded in a 11-coordinate geometry to one Cu(1), one Cu(10), one Cu(16), one Cu(3), one Cu(5), one Cu(7), one Zn(1), one Zn(16), one Zn(25), one Zn(27), and one Zn(31) atom. In the twelfth Zn site, Zn(12) is bonded in a 11-coordinate geometry to one Cu(11), one Cu(17), one Cu(2), one Cu(4), one Cu(6), one Cu(8), one Zn(15), one Zn(2), one Zn(26), one Zn(28), and one Zn(32) atom. In the thirteenth Zn site, Zn(13) is bonded in a 11-coordinate geometry to one Cu(1), one Cu(11), one Cu(14), one Cu(3), one Cu(6), one Cu(9), one Zn(15), one Zn(2), one Zn(21), one Zn(23), and one Zn(29) atom. In the fourteenth Zn site, Zn(14) is bonded in a 11-coordinate geometry to one Cu(10), one Cu(15), one Cu(2), one Cu(4), one Cu(5), one Zn(1), one Zn(16), one Zn(22), one Zn(24), one Zn(30), and one Zn(33) atom. In the fifteenth Zn site, Zn(15) is bonded in a 11-coordinate geometry to one Cu(11), one Cu(13), one Cu(6), one Cu(8), one Cu(9), one Zn(12), one Zn(13), one Zn(24), one Zn(3), one Zn(31), and one Zn(35) atom. In the sixteenth Zn site, Zn(16) is bonded in a 11-coordinate geometry to one Cu(10), one Cu(12), one Cu(5), one Cu(7), one Zn(11), one Zn(14), one Zn(23), one Zn(32), one Zn(33), one Zn(34), and one Zn(4) atom. In the seventeenth Zn site, Zn(17) is bonded in a 11-coordinate geometry to one Cu(1), one Cu(13), one Cu(14), one Cu(6), one Cu(7), one Cu(9), one Zn(10), one Zn(21), one Zn(25), one Zn(3), and one Zn(31) atom. In the eighteenth Zn site, Zn(18) is bonded in a 11-coordinate geometry to one Cu(12), one Cu(15), one Cu(2), one Cu(5), one Cu(8), one Zn(22), one Zn(26), one Zn(32), one Zn(33), one Zn(4), and one Zn(9) atom. In the nineteenth Zn site, Zn(19) is bonded in a 11-coordinate geometry to one Cu(12), one Cu(16), one Cu(3), one Cu(5), one Cu(7), one Cu(9), one Zn(23), one Zn(27), one Zn(29), one Zn(4), and one Zn(9) atom. In the twentieth Zn site, Zn(20) is bonded in a 11-coordinate geometry to one Cu(13), one Cu(17), one Cu(4), one Cu(6), one Cu(8), one Zn(10), one Zn(24), one Zn(28), one Zn(3), one Zn(30), and one Zn(33) atom. In the twenty-first Zn site, Zn(21) is bonded in a 11-coordinate geometry to one Cu(14), one Cu(16), one Cu(3), one Cu(6), one Cu(7), one Zn(13), one Zn(17), one Zn(29), one Zn(31), one Zn(35), and one Zn(5) atom. In the twenty-second Zn site, Zn(22) is bonded in a 11-coordinate geometry to one Cu(15), one Cu(17), one Cu(4), one Cu(5), one Cu(8), one Zn(14), one Zn(18), one Zn(30), one Zn(32), one Zn(34), and one Zn(6) atom. In the twenty-third Zn site, Zn(23) is bonded in a 11-coordinate geometry to one Cu(1), one Cu(12), one Cu(14), one Cu(3), one Cu(7), one Zn(13), one Zn(16), one Zn(19), one Zn(27), one Zn(34), and one Zn(5) atom. In the twenty-fourth Zn site, Zn(24) is bonded in a 11-coordinate geometry to one Cu(13), one Cu(15), one Cu(2), one Cu(4), one Cu(8), one Zn(14), one Zn(15), one Zn(20), one Zn(28), one Zn(35), and one Zn(6) atom. In the twenty-fifth Zn site, Zn(25) is bonded in a 11-coordinate geometry to one Cu(10), one Cu(14), one Cu(3), one Cu(7), one Cu(9), one Zn(11), one Zn(17), one Zn(27), one Zn(34), one Zn(5), and one Zn(9) atom. In the twenty-sixth Zn site, Zn(26) is bonded in a 11-coordinate geometry to one Cu(11), one Cu(15), one Cu(4), one Cu(8), one Zn(10), one Zn(12), one Zn(18), one Zn(28), one Zn(33), one Zn(35), and one Zn(6) atom. In the twenty-seventh Zn site, Zn(27) is bonded in a 11-coordinate geometry to one Cu(1), one Cu(14), one Cu(16), one Cu(5), one Cu(9), one Zn(11), one Zn(19), one Zn(23), one Zn(25), one Zn(34), and one Zn(7) atom. In the twenty-eighth Zn site, Zn(28) is bonded in a 11-coordinate geometry to one Cu(15), one Cu(17), one Cu(2), one Cu(6), one Zn(12), one Zn(20), one Zn(24), one Zn(26), one Zn(33), one Zn(35), and one Zn(8) atom. In the twenty-ninth Zn site, Zn(29) is bonded in a 11-coordinate geometry to one Cu(1), one Cu(11), one Cu(16), one Cu(7), one Cu(9), one Zn(10), one Zn(13), one Zn(19), one Zn(21), one Zn(35), and one Zn(7) atom. In the thirtieth Zn site, Zn(30) is bonded in a 11-coordinate geometry to one Cu(10), one Cu(17), one Cu(2), one Cu(8), one Zn(14), one Zn(20), one Zn(22), one Zn(33), one Zn(34), one Zn(8), and one Zn(9) atom. In the thirty-first Zn site, Zn(31) is bonded in a 11-coordinate geometry to one Cu(1), one Cu(13), one Cu(16), one Cu(3), one Cu(9), one Zn(11), one Zn(15), one Zn(17), one Zn(21), one Zn(35), and one Zn(7) atom. In the thirty-second Zn site, Zn(32) is bonded in a 11-coordinate geometry to one Cu(12), one Cu(17), one Cu(2), one Cu(4), one Zn(12), one Zn(16), one Zn(18), one Zn(22), one Zn(33), one Zn(34), and one Zn(8) atom. In the thirty-third Zn site, Zn(33) is bonded in a 13-coordinate geometry to one Cu(10), one Cu(15), one Cu(4), one Zn(14), one Zn(16), one Zn(18), one Zn(20), one Zn(26), one Zn(28), one Zn(30), one Zn(32), one Zn(4), and one Zn(8) atom. In the thirty-fourth Zn site, Zn(34) is bonded in a 13-coordinate geometry to one Cu(10), one Cu(12), one Cu(5), one Zn(16), one Zn(22), one Zn(23), one Zn(25), one Zn(27), one Zn(30), one Zn(32), one Zn(5), one Zn(8), and one Zn(9) atom. In the thirty-fifth Zn site, Zn(35) is bonded in a 13-coordinate geometry to one Cu(11), one Cu(13), one Cu(6), one Zn(10), one Zn(15), one Zn(21), one Zn(24), one Zn(26), one Zn(28), one Zn(29), one Zn(31), one Zn(6), and one Zn(7) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Zn35Cu17
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.686
_cell_length_b   7.688
_cell_length_c   12.624
_cell_angle_alpha   89.937
_cell_angle_beta   89.926
_cell_angle_gamma   70.683
_symmetry_Int_Tables_number   1
_cell_volume   703.898
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.216  0.000  0.999  1.0
  Zn  Zn1  1  0.717  0.499  0.500  1.0
  Zn  Zn2  1  0.500  0.284  0.501  1.0
  Zn  Zn3  1  0.003  0.782  0.998  1.0
  Zn  Zn4  1  0.895  0.105  0.890  1.0
  Zn  Zn5  1  0.395  0.605  0.391  1.0
  Zn  Zn6  1  0.395  0.605  0.610  1.0
  Zn  Zn7  1  0.896  0.108  0.109  1.0
  Zn  Zn8  1  0.345  0.273  0.999  1.0
  Zn  Zn9  1  0.845  0.774  0.500  1.0
  Zn  Zn10  1  0.486  0.862  0.861  1.0
  Zn  Zn11  1  0.987  0.362  0.362  1.0
  Zn  Zn12  1  0.987  0.362  0.638  1.0
  Zn  Zn13  1  0.481  0.863  0.137  1.0
  Zn  Zn14  1  0.226  0.156  0.500  1.0
  Zn  Zn15  1  0.725  0.654  0.998  1.0
  Zn  Zn16  1  0.638  0.013  0.638  1.0
  Zn  Zn17  1  0.141  0.511  0.138  1.0
  Zn  Zn18  1  0.138  0.513  0.861  1.0
  Zn  Zn19  1  0.636  0.016  0.364  1.0
  Zn  Zn20  1  0.963  0.038  0.689  1.0
  Zn  Zn21  1  0.462  0.538  0.190  1.0
  Zn  Zn22  1  0.828  0.450  0.824  1.0
  Zn  Zn23  1  0.328  0.951  0.324  1.0
  Zn  Zn24  1  0.549  0.172  0.824  1.0
  Zn  Zn25  1  0.053  0.670  0.327  1.0
  Zn  Zn26  1  0.462  0.537  0.810  1.0
  Zn  Zn27  1  0.964  0.040  0.312  1.0
  Zn  Zn28  1  0.049  0.673  0.676  1.0
  Zn  Zn29  1  0.546  0.176  0.176  1.0
  Zn  Zn30  1  0.328  0.951  0.676  1.0
  Zn  Zn31  1  0.828  0.448  0.176  1.0
  Zn  Zn32  1  0.820  0.820  0.180  1.0
  Zn  Zn33  1  0.640  0.359  1.000  1.0
  Zn  Zn34  1  0.141  0.860  0.500  1.0
  Cu  Cu35  1  0.679  0.679  0.678  1.0
  Cu  Cu36  1  0.179  0.178  0.178  1.0
  Cu  Cu37  1  0.179  0.179  0.822  1.0
  Cu  Cu38  1  0.679  0.678  0.322  1.0
  Cu  Cu39  1  0.357  0.643  0.000  1.0
  Cu  Cu40  1  0.856  0.143  0.500  1.0
  Cu  Cu41  1  0.821  0.821  0.822  1.0
  Cu  Cu42  1  0.321  0.321  0.322  1.0
  Cu  Cu43  1  0.321  0.321  0.678  1.0
  Cu  Cu44  1  0.655  0.001  0.000  1.0
  Cu  Cu45  1  0.156  0.501  0.500  1.0
  Cu  Cu46  1  0.999  0.345  1.000  1.0
  Cu  Cu47  1  0.498  0.845  0.500  1.0
  Cu  Cu48  1  0.672  0.328  0.672  1.0
  Cu  Cu49  1  0.171  0.828  0.172  1.0
  Cu  Cu50  1  0.173  0.828  0.828  1.0
  Cu  Cu51  1  0.672  0.328  0.328  1.0
[/CIF]
.
The material described by Cu17Zn35 is gamma-brass-like structured and crystallizes in the triclinic P1 space group. There are seventeen inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a 13-coordinate geometry to one Cu(13), one Cu(14), one Cu(7), one Zn(10), one Zn(11), one Zn(13), one Zn(17), one Zn(2), one Zn(23), one Zn(27), one Zn(29), one Zn(31), and one Zn(7) atom. In the second Cu site, Cu(2) is bonded in a 13-coordinate geometry to one Cu(12), one Cu(15), one Cu(8), one Zn(1), one Zn(12), one Zn(14), one Zn(18), one Zn(24), one Zn(28), one Zn(30), one Zn(32), one Zn(8), and one Zn(9) atom. In the third Cu site, Cu(3) is bonded in a 13-coordinate geometry to one Cu(12), one Cu(16), one Cu(9), one Zn(1), one Zn(11), one Zn(13), one Zn(19), one Zn(21), one Zn(23), one Zn(25), one Zn(31), one Zn(5), and one Zn(9) atom. In the fourth Cu site, Cu(4) is bonded in a 13-coordinate geometry to one Cu(13), one Cu(17), one Zn(10), one Zn(12), one Zn(14), one Zn(2), one Zn(20), one Zn(22), one Zn(24), one Zn(26), one Zn(32), one Zn(33), and one Zn(6) atom. In the fifth Cu site, Cu(5) is bonded in a 13-coordinate geometry to one Cu(15), one Cu(16), one Zn(1), one Zn(11), one Zn(14), one Zn(16), one Zn(18), one Zn(19), one Zn(22), one Zn(27), one Zn(34), one Zn(4), and one Zn(9) atom. In the sixth Cu site, Cu(6) is bonded in a 13-coordinate geometry to one Cu(14), one Cu(17), one Zn(10), one Zn(12), one Zn(13), one Zn(15), one Zn(17), one Zn(2), one Zn(20), one Zn(21), one Zn(28), one Zn(3), and one Zn(35) atom. In the seventh Cu site, Cu(7) is bonded in a 13-coordinate geometry to one Cu(1), one Cu(10), one Cu(16), one Zn(11), one Zn(16), one Zn(17), one Zn(19), one Zn(21), one Zn(23), one Zn(25), one Zn(29), one Zn(4), and one Zn(5) atom. In the eighth Cu site, Cu(8) is bonded in a 13-coordinate geometry to one Cu(11), one Cu(17), one Cu(2), one Zn(12), one Zn(15), one Zn(18), one Zn(20), one Zn(22), one Zn(24), one Zn(26), one Zn(3), one Zn(30), and one Zn(6) atom. In the ninth Cu site, Cu(9) is bonded in a 13-coordinate geometry to one Cu(11), one Cu(14), one Cu(3), one Zn(13), one Zn(15), one Zn(17), one Zn(19), one Zn(25), one Zn(27), one Zn(29), one Zn(3), one Zn(31), and one Zn(7) atom. In the tenth Cu site, Cu(10) is bonded in a 12-coordinate geometry to one Cu(7), one Zn(11), one Zn(14), one Zn(16), one Zn(25), one Zn(30), one Zn(33), one Zn(34), one Zn(4), one Zn(5), one Zn(8), and one Zn(9) atom. In the eleventh Cu site, Cu(11) is bonded in a 12-coordinate geometry to one Cu(8), one Cu(9), one Zn(10), one Zn(12), one Zn(13), one Zn(15), one Zn(26), one Zn(29), one Zn(3), one Zn(35), one Zn(6), and one Zn(7) atom. In the twelfth Cu site, Cu(12) is bonded in a 12-coordinate geometry to one Cu(2), one Cu(3), one Zn(1), one Zn(16), one Zn(18), one Zn(19), one Zn(23), one Zn(32), one Zn(34), one Zn(5), one Zn(8), and one Zn(9) atom. In the thirteenth Cu site, Cu(13) is bonded in a 12-coordinate geometry to one Cu(1), one Cu(4), one Zn(10), one Zn(15), one Zn(17), one Zn(2), one Zn(20), one Zn(24), one Zn(31), one Zn(35), one Zn(6), and one Zn(7) atom. In the fourteenth Cu site, Cu(14) is bonded in a 9-coordinate geometry to one Cu(1), one Cu(6), one Cu(9), one Zn(13), one Zn(17), one Zn(2), one Zn(21), one Zn(23), one Zn(25), one Zn(27), one Zn(3), and one Zn(7) atom. In the fifteenth Cu site, Cu(15) is bonded in a 12-coordinate geometry to one Cu(2), one Cu(5), one Zn(1), one Zn(14), one Zn(18), one Zn(22), one Zn(24), one Zn(26), one Zn(28), one Zn(33), one Zn(4), and one Zn(8) atom. In the sixteenth Cu site, Cu(16) is bonded in a 9-coordinate geometry to one Cu(3), one Cu(5), one Cu(7), one Zn(1), one Zn(11), one Zn(19), one Zn(21), one Zn(27), one Zn(29), one Zn(31), one Zn(4), and one Zn(5) atom. In the seventeenth Cu site, Cu(17) is bonded in a 9-coordinate geometry to one Cu(4), one Cu(6), one Cu(8), one Zn(12), one Zn(2), one Zn(20), one Zn(22), one Zn(28), one Zn(3), one Zn(30), one Zn(32), and one Zn(6) atom. There are thirty-five inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a 12-coordinate geometry to one Cu(12), one Cu(15), one Cu(16), one Cu(2), one Cu(3), one Cu(5), one Zn(11), one Zn(14), one Zn(4), one Zn(5), one Zn(8), and one Zn(9) atom. In the second Zn site, Zn(2) is bonded in a 12-coordinate geometry to one Cu(1), one Cu(13), one Cu(14), one Cu(17), one Cu(4), one Cu(6), one Zn(10), one Zn(12), one Zn(13), one Zn(3), one Zn(6), and one Zn(7) atom. In the third Zn site, Zn(3) is bonded in a 12-coordinate geometry to one Cu(11), one Cu(14), one Cu(17), one Cu(6), one Cu(8), one Cu(9), one Zn(15), one Zn(17), one Zn(2), one Zn(20), one Zn(6), and one Zn(7) atom. In the fourth Zn site, Zn(4) is bonded in a 12-coordinate geometry to one Cu(10), one Cu(15), one Cu(16), one Cu(5), one Cu(7), one Zn(1), one Zn(16), one Zn(18), one Zn(19), one Zn(33), one Zn(5), and one Zn(8) atom. In the fifth Zn site, Zn(5) is bonded in a 12-coordinate geometry to one Cu(10), one Cu(12), one Cu(16), one Cu(3), one Cu(7), one Zn(1), one Zn(21), one Zn(23), one Zn(25), one Zn(34), one Zn(4), and one Zn(8) atom. In the sixth Zn site, Zn(6) is bonded in a 12-coordinate geometry to one Cu(11), one Cu(13), one Cu(17), one Cu(4), one Cu(8), one Zn(2), one Zn(22), one Zn(24), one Zn(26), one Zn(3), one Zn(35), and one Zn(7) atom. In the seventh Zn site, Zn(7) is bonded in a 12-coordinate geometry to one Cu(1), one Cu(11), one Cu(13), one Cu(14), one Cu(9), one Zn(2), one Zn(27), one Zn(29), one Zn(3), one Zn(31), one Zn(35), and one Zn(6) atom. In the eighth Zn site, Zn(8) is bonded in a 12-coordinate geometry to one Cu(10), one Cu(12), one Cu(15), one Cu(2), one Zn(1), one Zn(28), one Zn(30), one Zn(32), one Zn(33), one Zn(34), one Zn(4), and one Zn(5) atom. In the ninth Zn site, Zn(9) is bonded in a 11-coordinate geometry to one Cu(10), one Cu(12), one Cu(2), one Cu(3), one Cu(5), one Zn(1), one Zn(18), one Zn(19), one Zn(25), one Zn(30), and one Zn(34) atom. In the tenth Zn site, Zn(10) is bonded in a 11-coordinate geometry to one Cu(1), one Cu(11), one Cu(13), one Cu(4), one Cu(6), one Zn(17), one Zn(2), one Zn(20), one Zn(26), one Zn(29), and one Zn(35) atom. In the eleventh Zn site, Zn(11) is bonded in a 11-coordinate geometry to one Cu(1), one Cu(10), one Cu(16), one Cu(3), one Cu(5), one Cu(7), one Zn(1), one Zn(16), one Zn(25), one Zn(27), and one Zn(31) atom. In the twelfth Zn site, Zn(12) is bonded in a 11-coordinate geometry to one Cu(11), one Cu(17), one Cu(2), one Cu(4), one Cu(6), one Cu(8), one Zn(15), one Zn(2), one Zn(26), one Zn(28), and one Zn(32) atom. In the thirteenth Zn site, Zn(13) is bonded in a 11-coordinate geometry to one Cu(1), one Cu(11), one Cu(14), one Cu(3), one Cu(6), one Cu(9), one Zn(15), one Zn(2), one Zn(21), one Zn(23), and one Zn(29) atom. In the fourteenth Zn site, Zn(14) is bonded in a 11-coordinate geometry to one Cu(10), one Cu(15), one Cu(2), one Cu(4), one Cu(5), one Zn(1), one Zn(16), one Zn(22), one Zn(24), one Zn(30), and one Zn(33) atom. In the fifteenth Zn site, Zn(15) is bonded in a 11-coordinate geometry to one Cu(11), one Cu(13), one Cu(6), one Cu(8), one Cu(9), one Zn(12), one Zn(13), one Zn(24), one Zn(3), one Zn(31), and one Zn(35) atom. In the sixteenth Zn site, Zn(16) is bonded in a 11-coordinate geometry to one Cu(10), one Cu(12), one Cu(5), one Cu(7), one Zn(11), one Zn(14), one Zn(23), one Zn(32), one Zn(33), one Zn(34), and one Zn(4) atom. In the seventeenth Zn site, Zn(17) is bonded in a 11-coordinate geometry to one Cu(1), one Cu(13), one Cu(14), one Cu(6), one Cu(7), one Cu(9), one Zn(10), one Zn(21), one Zn(25), one Zn(3), and one Zn(31) atom. In the eighteenth Zn site, Zn(18) is bonded in a 11-coordinate geometry to one Cu(12), one Cu(15), one Cu(2), one Cu(5), one Cu(8), one Zn(22), one Zn(26), one Zn(32), one Zn(33), one Zn(4), and one Zn(9) atom. In the nineteenth Zn site, Zn(19) is bonded in a 11-coordinate geometry to one Cu(12), one Cu(16), one Cu(3), one Cu(5), one Cu(7), one Cu(9), one Zn(23), one Zn(27), one Zn(29), one Zn(4), and one Zn(9) atom. In the twentieth Zn site, Zn(20) is bonded in a 11-coordinate geometry to one Cu(13), one Cu(17), one Cu(4), one Cu(6), one Cu(8), one Zn(10), one Zn(24), one Zn(28), one Zn(3), one Zn(30), and one Zn(33) atom. In the twenty-first Zn site, Zn(21) is bonded in a 11-coordinate geometry to one Cu(14), one Cu(16), one Cu(3), one Cu(6), one Cu(7), one Zn(13), one Zn(17), one Zn(29), one Zn(31), one Zn(35), and one Zn(5) atom. In the twenty-second Zn site, Zn(22) is bonded in a 11-coordinate geometry to one Cu(15), one Cu(17), one Cu(4), one Cu(5), one Cu(8), one Zn(14), one Zn(18), one Zn(30), one Zn(32), one Zn(34), and one Zn(6) atom. In the twenty-third Zn site, Zn(23) is bonded in a 11-coordinate geometry to one Cu(1), one Cu(12), one Cu(14), one Cu(3), one Cu(7), one Zn(13), one Zn(16), one Zn(19), one Zn(27), one Zn(34), and one Zn(5) atom. In the twenty-fourth Zn site, Zn(24) is bonded in a 11-coordinate geometry to one Cu(13), one Cu(15), one Cu(2), one Cu(4), one Cu(8), one Zn(14), one Zn(15), one Zn(20), one Zn(28), one Zn(35), and one Zn(6) atom. In the twenty-fifth Zn site, Zn(25) is bonded in a 11-coordinate geometry to one Cu(10), one Cu(14), one Cu(3), one Cu(7), one Cu(9), one Zn(11), one Zn(17), one Zn(27), one Zn(34), one Zn(5), and one Zn(9) atom. In the twenty-sixth Zn site, Zn(26) is bonded in a 11-coordinate geometry to one Cu(11), one Cu(15), one Cu(4), one Cu(8), one Zn(10), one Zn(12), one Zn(18), one Zn(28), one Zn(33), one Zn(35), and one Zn(6) atom. In the twenty-seventh Zn site, Zn(27) is bonded in a 11-coordinate geometry to one Cu(1), one Cu(14), one Cu(16), one Cu(5), one Cu(9), one Zn(11), one Zn(19), one Zn(23), one Zn(25), one Zn(34), and one Zn(7) atom. In the twenty-eighth Zn site, Zn(28) is bonded in a 11-coordinate geometry to one Cu(15), one Cu(17), one Cu(2), one Cu(6), one Zn(12), one Zn(20), one Zn(24), one Zn(26), one Zn(33), one Zn(35), and one Zn(8) atom. In the twenty-ninth Zn site, Zn(29) is bonded in a 11-coordinate geometry to one Cu(1), one Cu(11), one Cu(16), one Cu(7), one Cu(9), one Zn(10), one Zn(13), one Zn(19), one Zn(21), one Zn(35), and one Zn(7) atom. In the thirtieth Zn site, Zn(30) is bonded in a 11-coordinate geometry to one Cu(10), one Cu(17), one Cu(2), one Cu(8), one Zn(14), one Zn(20), one Zn(22), one Zn(33), one Zn(34), one Zn(8), and one Zn(9) atom. In the thirty-first Zn site, Zn(31) is bonded in a 11-coordinate geometry to one Cu(1), one Cu(13), one Cu(16), one Cu(3), one Cu(9), one Zn(11), one Zn(15), one Zn(17), one Zn(21), one Zn(35), and one Zn(7) atom. In the thirty-second Zn site, Zn(32) is bonded in a 11-coordinate geometry to one Cu(12), one Cu(17), one Cu(2), one Cu(4), one Zn(12), one Zn(16), one Zn(18), one Zn(22), one Zn(33), one Zn(34), and one Zn(8) atom. In the thirty-third Zn site, Zn(33) is bonded in a 13-coordinate geometry to one Cu(10), one Cu(15), one Cu(4), one Zn(14), one Zn(16), one Zn(18), one Zn(20), one Zn(26), one Zn(28), one Zn(30), one Zn(32), one Zn(4), and one Zn(8) atom. In the thirty-fourth Zn site, Zn(34) is bonded in a 13-coordinate geometry to one Cu(10), one Cu(12), one Cu(5), one Zn(16), one Zn(22), one Zn(23), one Zn(25), one Zn(27), one Zn(30), one Zn(32), one Zn(5), one Zn(8), and one Zn(9) atom. In the thirty-fifth Zn site, Zn(35) is bonded in a 13-coordinate geometry to one Cu(11), one Cu(13), one Cu(6), one Zn(10), one Zn(15), one Zn(21), one Zn(24), one Zn(26), one Zn(28), one Zn(29), one Zn(31), one Zn(6), and one Zn(7) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Zn35Cu17
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.686
_cell_length_b   7.688
_cell_length_c   12.624
_cell_angle_alpha   89.937
_cell_angle_beta   89.926
_cell_angle_gamma   70.683
_symmetry_Int_Tables_number   1
_cell_volume   703.898
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.216  0.000  0.999  1.0
  Zn  Zn1  1  0.717  0.499  0.500  1.0
  Zn  Zn2  1  0.500  0.284  0.501  1.0
  Zn  Zn3  1  0.003  0.782  0.998  1.0
  Zn  Zn4  1  0.895  0.105  0.890  1.0
  Zn  Zn5  1  0.395  0.605  0.391  1.0
  Zn  Zn6  1  0.395  0.605  0.610  1.0
  Zn  Zn7  1  0.896  0.108  0.109  1.0
  Zn  Zn8  1  0.345  0.273  0.999  1.0
  Zn  Zn9  1  0.845  0.774  0.500  1.0
  Zn  Zn10  1  0.486  0.862  0.861  1.0
  Zn  Zn11  1  0.987  0.362  0.362  1.0
  Zn  Zn12  1  0.987  0.362  0.638  1.0
  Zn  Zn13  1  0.481  0.863  0.137  1.0
  Zn  Zn14  1  0.226  0.156  0.500  1.0
  Zn  Zn15  1  0.725  0.654  0.998  1.0
  Zn  Zn16  1  0.638  0.013  0.638  1.0
  Zn  Zn17  1  0.141  0.511  0.138  1.0
  Zn  Zn18  1  0.138  0.513  0.861  1.0
  Zn  Zn19  1  0.636  0.016  0.364  1.0
  Zn  Zn20  1  0.963  0.038  0.689  1.0
  Zn  Zn21  1  0.462  0.538  0.190  1.0
  Zn  Zn22  1  0.828  0.450  0.824  1.0
  Zn  Zn23  1  0.328  0.951  0.324  1.0
  Zn  Zn24  1  0.549  0.172  0.824  1.0
  Zn  Zn25  1  0.053  0.670  0.327  1.0
  Zn  Zn26  1  0.462  0.537  0.810  1.0
  Zn  Zn27  1  0.964  0.040  0.312  1.0
  Zn  Zn28  1  0.049  0.673  0.676  1.0
  Zn  Zn29  1  0.546  0.176  0.176  1.0
  Zn  Zn30  1  0.328  0.951  0.676  1.0
  Zn  Zn31  1  0.828  0.448  0.176  1.0
  Zn  Zn32  1  0.820  0.820  0.180  1.0
  Zn  Zn33  1  0.640  0.359  1.000  1.0
  Zn  Zn34  1  0.141  0.860  0.500  1.0
  Cu  Cu35  1  0.679  0.679  0.678  1.0
  Cu  Cu36  1  0.179  0.178  0.178  1.0
  Cu  Cu37  1  0.179  0.179  0.822  1.0
  Cu  Cu38  1  0.679  0.678  0.322  1.0
  Cu  Cu39  1  0.357  0.643  0.000  1.0
  Cu  Cu40  1  0.856  0.143  0.500  1.0
  Cu  Cu41  1  0.821  0.821  0.822  1.0
  Cu  Cu42  1  0.321  0.321  0.322  1.0
  Cu  Cu43  1  0.321  0.321  0.678  1.0
  Cu  Cu44  1  0.655  0.001  0.000  1.0
  Cu  Cu45  1  0.156  0.501  0.500  1.0
  Cu  Cu46  1  0.999  0.345  1.000  1.0
  Cu  Cu47  1  0.498  0.845  0.500  1.0
  Cu  Cu48  1  0.672  0.328  0.672  1.0
  Cu  Cu49  1  0.171  0.828  0.172  1.0
  Cu  Cu50  1  0.173  0.828  0.828  1.0
  Cu  Cu51  1  0.672  0.328  0.328  1.0
[/CIF]
.