The structure described by LiAg2F4 is Spinel structured and crystallizes in the cubic Fd-3m space group. Li(1) is bonded to four equivalent F(1) atoms to form LiF4 tetrahedra that share corners with twelve equivalent Ag(1)F6 octahedra. The corner-sharing octahedral tilt angles are 54°. Ag(1) is bonded to six equivalent F(1) atoms to form AgF6 octahedra that share corners with six equivalent Li(1)F4 tetrahedra and edges with six equivalent Ag(1)F6 octahedra. F(1) is bonded in a rectangular see-saw-like geometry to one Li(1) and three equivalent Ag(1) atoms. is represented by the CIF card [CIF]
data_LiAg2F4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.620
_cell_length_b   6.620
_cell_length_c   6.620
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   205.142
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.000  0.000  0.000  1.0
  Li  Li1  1  0.250  0.250  0.250  1.0
  Ag  Ag2  1  0.625  0.125  0.625  1.0
  Ag  Ag3  1  0.625  0.625  0.125  1.0
  Ag  Ag4  1  0.125  0.625  0.625  1.0
  Ag  Ag5  1  0.625  0.625  0.625  1.0
  F  F6  1  0.878  0.365  0.878  1.0
  F  F7  1  0.372  0.372  0.372  1.0
  F  F8  1  0.365  0.878  0.878  1.0
  F  F9  1  0.878  0.878  0.365  1.0
  F  F10  1  0.885  0.372  0.372  1.0
  F  F11  1  0.372  0.372  0.885  1.0
  F  F12  1  0.878  0.878  0.878  1.0
  F  F13  1  0.372  0.885  0.372  1.0
[/CIF]
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The structure described by LiAg2F4 is Spinel structured and crystallizes in the cubic Fd-3m space group. Li(1) is bonded to four equivalent F(1) atoms to form LiF4 tetrahedra that share corners with twelve equivalent Ag(1)F6 octahedra. The corner-sharing octahedral tilt angles are 54°. Ag(1) is bonded to six equivalent F(1) atoms to form AgF6 octahedra that share corners with six equivalent Li(1)F4 tetrahedra and edges with six equivalent Ag(1)F6 octahedra. F(1) is bonded in a rectangular see-saw-like geometry to one Li(1) and three equivalent Ag(1) atoms. is represented by the CIF card [CIF]
data_LiAg2F4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.620
_cell_length_b   6.620
_cell_length_c   6.620
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   205.142
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.000  0.000  0.000  1.0
  Li  Li1  1  0.250  0.250  0.250  1.0
  Ag  Ag2  1  0.625  0.125  0.625  1.0
  Ag  Ag3  1  0.625  0.625  0.125  1.0
  Ag  Ag4  1  0.125  0.625  0.625  1.0
  Ag  Ag5  1  0.625  0.625  0.625  1.0
  F  F6  1  0.878  0.365  0.878  1.0
  F  F7  1  0.372  0.372  0.372  1.0
  F  F8  1  0.365  0.878  0.878  1.0
  F  F9  1  0.878  0.878  0.365  1.0
  F  F10  1  0.885  0.372  0.372  1.0
  F  F11  1  0.372  0.372  0.885  1.0
  F  F12  1  0.878  0.878  0.878  1.0
  F  F13  1  0.372  0.885  0.372  1.0
[/CIF]
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