The material structure described by LiAgO2 crystallizes in the monoclinic P2/m space group. Li(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form LiO4 tetrahedra that share corners with two equivalent Li(1)O4 tetrahedra, corners with two equivalent O(1)Li2AgO tetrahedra, and  an edgeedge with one Li(1)O4 tetrahedra. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a square co-planar geometry to four equivalent O(2) atoms. In the second Ag site, Ag(2) is bonded in a linear geometry to two equivalent O(1) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Li(1), one Ag(2), and one O(1) atom to form distorted OLi2AgO tetrahedra that share corners with two equivalent Li(1)O4 tetrahedra, corners with three equivalent O(1)Li2AgO tetrahedra, and corners with four equivalent O(2)Li2Ag2 tetrahedra. In the second O site, O(2) is bonded to two equivalent Li(1) and two equivalent Ag(1) atoms to form OLi2Ag2 tetrahedra that share corners with four equivalent O(2)Li2Ag2 tetrahedra, corners with four equivalent O(1)Li2AgO tetrahedra, and edges with two equivalent O(2)Li2Ag2 tetrahedra. is represented by the CIF card [CIF]
data_LiAgO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.148
_cell_length_b   5.265
_cell_length_c   6.194
_cell_angle_alpha   87.793
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   102.590
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.000  0.025  0.769  1.0
  Li  Li1  1  0.000  0.975  0.231  1.0
  Ag  Ag2  1  0.500  0.500  0.000  1.0
  Ag  Ag3  1  0.500  0.500  0.500  1.0
  O  O4  1  0.500  0.093  0.587  1.0
  O  O5  1  0.000  0.748  0.985  1.0
  O  O6  1  0.000  0.252  0.015  1.0
  O  O7  1  0.500  0.907  0.413  1.0
[/CIF]
.
The material structure described by LiAgO2 crystallizes in the monoclinic P2/m space group. Li(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form LiO4 tetrahedra that share corners with two equivalent Li(1)O4 tetrahedra, corners with two equivalent O(1)Li2AgO tetrahedra, and  an edgeedge with one Li(1)O4 tetrahedra. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a square co-planar geometry to four equivalent O(2) atoms. In the second Ag site, Ag(2) is bonded in a linear geometry to two equivalent O(1) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Li(1), one Ag(2), and one O(1) atom to form distorted OLi2AgO tetrahedra that share corners with two equivalent Li(1)O4 tetrahedra, corners with three equivalent O(1)Li2AgO tetrahedra, and corners with four equivalent O(2)Li2Ag2 tetrahedra. In the second O site, O(2) is bonded to two equivalent Li(1) and two equivalent Ag(1) atoms to form OLi2Ag2 tetrahedra that share corners with four equivalent O(2)Li2Ag2 tetrahedra, corners with four equivalent O(1)Li2AgO tetrahedra, and edges with two equivalent O(2)Li2Ag2 tetrahedra. is represented by the CIF card [CIF]
data_LiAgO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.148
_cell_length_b   5.265
_cell_length_c   6.194
_cell_angle_alpha   87.793
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   102.590
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.000  0.025  0.769  1.0
  Li  Li1  1  0.000  0.975  0.231  1.0
  Ag  Ag2  1  0.500  0.500  0.000  1.0
  Ag  Ag3  1  0.500  0.500  0.500  1.0
  O  O4  1  0.500  0.093  0.587  1.0
  O  O5  1  0.000  0.748  0.985  1.0
  O  O6  1  0.000  0.252  0.015  1.0
  O  O7  1  0.500  0.907  0.413  1.0
[/CIF]
.