The structure described by Mn3Co3(SbO8)2 is Hydrophilite-derived structured and crystallizes in the triclinic P1 space group. There are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(14), one O(16), one O(3), one O(4), one O(7), and one O(8) atom to form MnO6 octahedra that share corners with two equivalent Sb(2)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles are 52°. In the second Mn site, Mn(2) is bonded to one O(1), one O(10), one O(11), one O(13), one O(15), and one O(5) atom to form MnO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, and edges with two equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-52°. In the third Mn site, Mn(3) is bonded to one O(10), one O(12), one O(13), one O(15), one O(5), and one O(6) atom to form MnO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, and edges with two equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles are 51°. There are three inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(14), one O(2), one O(3), one O(4), one O(7), and one O(9) atom to form CoO6 octahedra that share corners with two equivalent Sb(2)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and edges with two equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-52°. In the second Co site, Co(2) is bonded to one O(16), one O(2), one O(3), one O(4), one O(8), and one O(9) atom to form CoO6 octahedra that share corners with two equivalent Sb(2)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and edges with two equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-54°. In the third Co site, Co(3) is bonded to one O(1), one O(11), one O(12), one O(13), one O(5), and one O(6) atom to form CoO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, and edges with two equivalent Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-52°. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(1), one O(10), one O(2), one O(6), one O(7), and one O(8) atom to form SbO6 octahedra that share corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra, corners with two equivalent Co(3)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra, and  an edgeedge with one Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-52°. In the second Sb site, Sb(2) is bonded to one O(11), one O(12), one O(14), one O(15), one O(16), and one O(9) atom to form SbO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Co(2)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra, and  an edgeedge with one Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-54°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Mn(2), one Co(3), and one Sb(1) atom. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one Co(1), one Co(2), and one Sb(1) atom. In the third O site, O(3) is bonded in a distorted T-shaped geometry to one Mn(1), one Co(1), and one Co(2) atom. In the fourth O site, O(4) is bonded in a distorted trigonal non-coplanar geometry to one Mn(1), one Co(1), and one Co(2) atom. In the fifth O site, O(5) is bonded in a distorted trigonal non-coplanar geometry to one Mn(2), one Mn(3), and one Co(3) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Mn(3), one Co(3), and one Sb(1) atom. In the seventh O site, O(7) is bonded in a distorted T-shaped geometry to one Mn(1), one Co(1), and one Sb(1) atom. In the eighth O site, O(8) is bonded in a distorted trigonal non-coplanar geometry to one Mn(1), one Co(2), and one Sb(1) atom. In the ninth O site, O(9) is bonded in a trigonal planar geometry to one Co(1), one Co(2), and one Sb(2) atom. In the tenth O site, O(10) is bonded in a distorted trigonal planar geometry to one Mn(2), one Mn(3), and one Sb(1) atom. In the eleventh O site, O(11) is bonded in a distorted trigonal non-coplanar geometry to one Mn(2), one Co(3), and one Sb(2) atom. In the twelfth O site, O(12) is bonded in a distorted trigonal non-coplanar geometry to one Mn(3), one Co(3), and one Sb(2) atom. In the thirteenth O site, O(13) is bonded in a distorted T-shaped geometry to one Mn(2), one Mn(3), and one Co(3) atom. In the fourteenth O site, O(14) is bonded in a distorted trigonal planar geometry to one Mn(1), one Co(1), and one Sb(2) atom. In the fifteenth O site, O(15) is bonded in a 3-coordinate geometry to one Mn(2), one Mn(3), and one Sb(2) atom. In the sixteenth O site, O(16) is bonded in a distorted trigonal planar geometry to one Mn(1), one Co(2), and one Sb(2) atom. is represented by the CIF card [CIF]
data_Mn3Co3(SbO8)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.831
_cell_length_b   5.844
_cell_length_c   9.275
_cell_angle_alpha   90.528
_cell_angle_beta   89.893
_cell_angle_gamma   119.550
_symmetry_Int_Tables_number   1
_cell_volume   274.926
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.337  0.171  0.213  1.0
  Mn  Mn1  1  0.170  0.337  0.714  1.0
  Mn  Mn2  1  0.171  0.832  0.713  1.0
  Co  Co3  1  0.833  0.176  0.215  1.0
  Co  Co4  1  0.829  0.670  0.207  1.0
  Co  Co5  1  0.667  0.834  0.709  1.0
  Sb  Sb6  1  0.672  0.334  0.490  1.0
  Sb  Sb7  1  0.337  0.671  0.992  1.0
  O  O8  1  0.838  0.167  0.602  1.0
  O  O9  1  0.964  0.467  0.336  1.0
  O  O10  1  0.663  0.316  0.109  1.0
  O  O11  1  0.000  0.017  0.307  1.0
  O  O12  1  0.012  0.007  0.811  1.0
  O  O13  1  0.840  0.671  0.598  1.0
  O  O14  1  0.522  0.037  0.334  1.0
  O  O15  1  0.514  0.472  0.340  1.0
  O  O16  1  0.676  0.845  0.099  1.0
  O  O17  1  0.331  0.162  0.601  1.0
  O  O18  1  0.471  0.510  0.841  1.0
  O  O19  1  0.470  0.960  0.840  1.0
  O  O20  1  0.317  0.656  0.606  1.0
  O  O21  1  0.164  0.329  0.101  1.0
  O  O22  1  0.036  0.520  0.835  1.0
  O  O23  1  0.167  0.838  0.102  1.0
[/CIF]
.
The structure described by Mn3Co3(SbO8)2 is Hydrophilite-derived structured and crystallizes in the triclinic P1 space group. There are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(14), one O(16), one O(3), one O(4), one O(7), and one O(8) atom to form MnO6 octahedra that share corners with two equivalent Sb(2)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles are 52°. In the second Mn site, Mn(2) is bonded to one O(1), one O(10), one O(11), one O(13), one O(15), and one O(5) atom to form MnO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, and edges with two equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-52°. In the third Mn site, Mn(3) is bonded to one O(10), one O(12), one O(13), one O(15), one O(5), and one O(6) atom to form MnO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, and edges with two equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles are 51°. There are three inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(14), one O(2), one O(3), one O(4), one O(7), and one O(9) atom to form CoO6 octahedra that share corners with two equivalent Sb(2)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and edges with two equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-52°. In the second Co site, Co(2) is bonded to one O(16), one O(2), one O(3), one O(4), one O(8), and one O(9) atom to form CoO6 octahedra that share corners with two equivalent Sb(2)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and edges with two equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-54°. In the third Co site, Co(3) is bonded to one O(1), one O(11), one O(12), one O(13), one O(5), and one O(6) atom to form CoO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, and edges with two equivalent Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-52°. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(1), one O(10), one O(2), one O(6), one O(7), and one O(8) atom to form SbO6 octahedra that share corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra, corners with two equivalent Co(3)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra, and  an edgeedge with one Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-52°. In the second Sb site, Sb(2) is bonded to one O(11), one O(12), one O(14), one O(15), one O(16), and one O(9) atom to form SbO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Co(2)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra, and  an edgeedge with one Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-54°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Mn(2), one Co(3), and one Sb(1) atom. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one Co(1), one Co(2), and one Sb(1) atom. In the third O site, O(3) is bonded in a distorted T-shaped geometry to one Mn(1), one Co(1), and one Co(2) atom. In the fourth O site, O(4) is bonded in a distorted trigonal non-coplanar geometry to one Mn(1), one Co(1), and one Co(2) atom. In the fifth O site, O(5) is bonded in a distorted trigonal non-coplanar geometry to one Mn(2), one Mn(3), and one Co(3) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Mn(3), one Co(3), and one Sb(1) atom. In the seventh O site, O(7) is bonded in a distorted T-shaped geometry to one Mn(1), one Co(1), and one Sb(1) atom. In the eighth O site, O(8) is bonded in a distorted trigonal non-coplanar geometry to one Mn(1), one Co(2), and one Sb(1) atom. In the ninth O site, O(9) is bonded in a trigonal planar geometry to one Co(1), one Co(2), and one Sb(2) atom. In the tenth O site, O(10) is bonded in a distorted trigonal planar geometry to one Mn(2), one Mn(3), and one Sb(1) atom. In the eleventh O site, O(11) is bonded in a distorted trigonal non-coplanar geometry to one Mn(2), one Co(3), and one Sb(2) atom. In the twelfth O site, O(12) is bonded in a distorted trigonal non-coplanar geometry to one Mn(3), one Co(3), and one Sb(2) atom. In the thirteenth O site, O(13) is bonded in a distorted T-shaped geometry to one Mn(2), one Mn(3), and one Co(3) atom. In the fourteenth O site, O(14) is bonded in a distorted trigonal planar geometry to one Mn(1), one Co(1), and one Sb(2) atom. In the fifteenth O site, O(15) is bonded in a 3-coordinate geometry to one Mn(2), one Mn(3), and one Sb(2) atom. In the sixteenth O site, O(16) is bonded in a distorted trigonal planar geometry to one Mn(1), one Co(2), and one Sb(2) atom. is represented by the CIF card [CIF]
data_Mn3Co3(SbO8)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.831
_cell_length_b   5.844
_cell_length_c   9.275
_cell_angle_alpha   90.528
_cell_angle_beta   89.893
_cell_angle_gamma   119.550
_symmetry_Int_Tables_number   1
_cell_volume   274.926
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.337  0.171  0.213  1.0
  Mn  Mn1  1  0.170  0.337  0.714  1.0
  Mn  Mn2  1  0.171  0.832  0.713  1.0
  Co  Co3  1  0.833  0.176  0.215  1.0
  Co  Co4  1  0.829  0.670  0.207  1.0
  Co  Co5  1  0.667  0.834  0.709  1.0
  Sb  Sb6  1  0.672  0.334  0.490  1.0
  Sb  Sb7  1  0.337  0.671  0.992  1.0
  O  O8  1  0.838  0.167  0.602  1.0
  O  O9  1  0.964  0.467  0.336  1.0
  O  O10  1  0.663  0.316  0.109  1.0
  O  O11  1  0.000  0.017  0.307  1.0
  O  O12  1  0.012  0.007  0.811  1.0
  O  O13  1  0.840  0.671  0.598  1.0
  O  O14  1  0.522  0.037  0.334  1.0
  O  O15  1  0.514  0.472  0.340  1.0
  O  O16  1  0.676  0.845  0.099  1.0
  O  O17  1  0.331  0.162  0.601  1.0
  O  O18  1  0.471  0.510  0.841  1.0
  O  O19  1  0.470  0.960  0.840  1.0
  O  O20  1  0.317  0.656  0.606  1.0
  O  O21  1  0.164  0.329  0.101  1.0
  O  O22  1  0.036  0.520  0.835  1.0
  O  O23  1  0.167  0.838  0.102  1.0
[/CIF]
.