The structure described by Na2Pd(C2O5)2 crystallizes in the triclinic P-1 space group. Na(1) is bonded in a 7-coordinate geometry to two equivalent O(1), two equivalent O(4), and three equivalent O(5) atoms. Pd(1) is bonded in a square co-planar geometry to two equivalent O(2) and two equivalent O(3) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(4) atom. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(5) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to two equivalent Na(1) atoms. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Pd(1) and one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Pd(1) and one C(2) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to two equivalent Na(1) and one C(1) atom. In the fifth O site, O(5) is bonded in a 1-coordinate geometry to three equivalent Na(1) and one C(2) atom. is represented by the CIF file [CIF]
data_Na2Pd(C2O5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.068
_cell_length_b   7.265
_cell_length_c   9.789
_cell_angle_alpha   72.676
_cell_angle_beta   87.173
_cell_angle_gamma   75.242
_symmetry_Int_Tables_number   1
_cell_volume   266.927
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.380  0.299  0.419  1.0
  Na  Na1  1  0.620  0.701  0.581  1.0
  Pd  Pd2  1  0.000  0.000  0.000  1.0
  C  C3  1  0.741  0.025  0.734  1.0
  C  C4  1  0.259  0.975  0.266  1.0
  C  C5  1  0.833  0.227  0.715  1.0
  C  C6  1  0.167  0.773  0.285  1.0
  O  O7  1  0.132  0.600  0.724  1.0
  O  O8  1  0.868  0.400  0.276  1.0
  O  O9  1  0.822  0.894  0.858  1.0
  O  O10  1  0.178  0.106  0.142  1.0
  O  O11  1  0.972  0.241  0.826  1.0
  O  O12  1  0.028  0.759  0.174  1.0
  O  O13  1  0.602  0.002  0.633  1.0
  O  O14  1  0.398  0.998  0.367  1.0
  O  O15  1  0.778  0.356  0.597  1.0
  O  O16  1  0.222  0.644  0.403  1.0
[/CIF]
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The structure described by Na2Pd(C2O5)2 crystallizes in the triclinic P-1 space group. Na(1) is bonded in a 7-coordinate geometry to two equivalent O(1), two equivalent O(4), and three equivalent O(5) atoms. Pd(1) is bonded in a square co-planar geometry to two equivalent O(2) and two equivalent O(3) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(4) atom. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(5) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to two equivalent Na(1) atoms. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Pd(1) and one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Pd(1) and one C(2) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to two equivalent Na(1) and one C(1) atom. In the fifth O site, O(5) is bonded in a 1-coordinate geometry to three equivalent Na(1) and one C(2) atom. is represented by the CIF file [CIF]
data_Na2Pd(C2O5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.068
_cell_length_b   7.265
_cell_length_c   9.789
_cell_angle_alpha   72.676
_cell_angle_beta   87.173
_cell_angle_gamma   75.242
_symmetry_Int_Tables_number   1
_cell_volume   266.927
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.380  0.299  0.419  1.0
  Na  Na1  1  0.620  0.701  0.581  1.0
  Pd  Pd2  1  0.000  0.000  0.000  1.0
  C  C3  1  0.741  0.025  0.734  1.0
  C  C4  1  0.259  0.975  0.266  1.0
  C  C5  1  0.833  0.227  0.715  1.0
  C  C6  1  0.167  0.773  0.285  1.0
  O  O7  1  0.132  0.600  0.724  1.0
  O  O8  1  0.868  0.400  0.276  1.0
  O  O9  1  0.822  0.894  0.858  1.0
  O  O10  1  0.178  0.106  0.142  1.0
  O  O11  1  0.972  0.241  0.826  1.0
  O  O12  1  0.028  0.759  0.174  1.0
  O  O13  1  0.602  0.002  0.633  1.0
  O  O14  1  0.398  0.998  0.367  1.0
  O  O15  1  0.778  0.356  0.597  1.0
  O  O16  1  0.222  0.644  0.403  1.0
[/CIF]
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