The material described by CuTeO5 crystallizes in the orthorhombic P2_12_12_1 space group. Cu(1) is bonded to one O(1), one O(2), one O(3), and two equivalent O(4) atoms to form distorted corner-sharing CuO5 trigonal bipyramids. Te(1) is bonded in a 5-coordinate geometry to one O(1), one O(3), one O(5), and two equivalent O(2) atoms. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Cu(1), one Te(1), and one O(4) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Cu(1) and two equivalent Te(1) atoms. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Cu(1) and one Te(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to two equivalent Cu(1) and one O(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one Te(1) atom. is represented by the CIF file [CIF]
data_CuTeO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.803
_cell_length_b   7.758
_cell_length_c   10.767
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   401.216
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cu  Cu0  1  0.320  0.640  0.319  1.0
  Cu  Cu1  1  0.180  0.140  0.681  1.0
  Cu  Cu2  1  0.820  0.360  0.181  1.0
  Cu  Cu3  1  0.680  0.860  0.819  1.0
  Te  Te4  1  0.577  0.941  0.119  1.0
  Te  Te5  1  0.923  0.441  0.881  1.0
  Te  Te6  1  0.077  0.059  0.381  1.0
  Te  Te7  1  0.423  0.559  0.619  1.0
  O  O8  1  0.215  0.296  0.247  1.0
  O  O9  1  0.285  0.796  0.753  1.0
  O  O10  1  0.715  0.704  0.253  1.0
  O  O11  1  0.785  0.204  0.747  1.0
  O  O12  1  0.787  0.111  0.216  1.0
  O  O13  1  0.713  0.611  0.784  1.0
  O  O14  1  0.287  0.889  0.284  1.0
  O  O15  1  0.213  0.389  0.716  1.0
  O  O16  1  0.196  0.640  0.489  1.0
  O  O17  1  0.304  0.140  0.511  1.0
  O  O18  1  0.696  0.360  0.011  1.0
  O  O19  1  0.804  0.860  0.989  1.0
  O  O20  1  0.917  0.592  0.226  1.0
  O  O21  1  0.583  0.092  0.774  1.0
  O  O22  1  0.417  0.408  0.274  1.0
  O  O23  1  0.083  0.908  0.726  1.0
  O  O24  1  0.311  0.064  0.039  1.0
  O  O25  1  0.189  0.564  0.961  1.0
  O  O26  1  0.811  0.936  0.461  1.0
  O  O27  1  0.689  0.436  0.539  1.0
[/CIF]
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The material described by CuTeO5 crystallizes in the orthorhombic P2_12_12_1 space group. Cu(1) is bonded to one O(1), one O(2), one O(3), and two equivalent O(4) atoms to form distorted corner-sharing CuO5 trigonal bipyramids. Te(1) is bonded in a 5-coordinate geometry to one O(1), one O(3), one O(5), and two equivalent O(2) atoms. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Cu(1), one Te(1), and one O(4) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Cu(1) and two equivalent Te(1) atoms. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Cu(1) and one Te(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to two equivalent Cu(1) and one O(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one Te(1) atom. is represented by the CIF file [CIF]
data_CuTeO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.803
_cell_length_b   7.758
_cell_length_c   10.767
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   401.216
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cu  Cu0  1  0.320  0.640  0.319  1.0
  Cu  Cu1  1  0.180  0.140  0.681  1.0
  Cu  Cu2  1  0.820  0.360  0.181  1.0
  Cu  Cu3  1  0.680  0.860  0.819  1.0
  Te  Te4  1  0.577  0.941  0.119  1.0
  Te  Te5  1  0.923  0.441  0.881  1.0
  Te  Te6  1  0.077  0.059  0.381  1.0
  Te  Te7  1  0.423  0.559  0.619  1.0
  O  O8  1  0.215  0.296  0.247  1.0
  O  O9  1  0.285  0.796  0.753  1.0
  O  O10  1  0.715  0.704  0.253  1.0
  O  O11  1  0.785  0.204  0.747  1.0
  O  O12  1  0.787  0.111  0.216  1.0
  O  O13  1  0.713  0.611  0.784  1.0
  O  O14  1  0.287  0.889  0.284  1.0
  O  O15  1  0.213  0.389  0.716  1.0
  O  O16  1  0.196  0.640  0.489  1.0
  O  O17  1  0.304  0.140  0.511  1.0
  O  O18  1  0.696  0.360  0.011  1.0
  O  O19  1  0.804  0.860  0.989  1.0
  O  O20  1  0.917  0.592  0.226  1.0
  O  O21  1  0.583  0.092  0.774  1.0
  O  O22  1  0.417  0.408  0.274  1.0
  O  O23  1  0.083  0.908  0.726  1.0
  O  O24  1  0.311  0.064  0.039  1.0
  O  O25  1  0.189  0.564  0.961  1.0
  O  O26  1  0.811  0.936  0.461  1.0
  O  O27  1  0.689  0.436  0.539  1.0
[/CIF]
.