The material structure described by VCdPO7 crystallizes in the monoclinic P2_1 space group. V(1) is bonded in a 6-coordinate geometry to one O(2), one O(4), one O(5), one O(6), and two equivalent O(7) atoms. Cd(1) is bonded to one O(2), one O(4), two equivalent O(1), and two equivalent O(3) atoms to form CdO6 octahedra that share corners with four equivalent P(1)O4 tetrahedra and edges with two equivalent Cd(1)O6 octahedra. P(1) is bonded to one O(1), one O(3), one O(5), and one O(6) atom to form PO4 tetrahedra that share corners with four equivalent Cd(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-56°. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to two equivalent Cd(1) and one P(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one V(1) and one Cd(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to two equivalent Cd(1) and one P(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one V(1) and one Cd(1) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one V(1) and one P(1) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one V(1) and one P(1) atom. In the seventh O site, O(7) is bonded in a distorted bent 150 degrees geometry to two equivalent V(1) atoms. is represented by the CIF file [CIF]
data_VCdPO7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.531
_cell_length_b   6.982
_cell_length_c   7.480
_cell_angle_alpha   90.000
_cell_angle_beta   106.674
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   276.696
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.544  0.532  0.039  1.0
  V  V1  1  0.456  0.032  0.961  1.0
  Cd  Cd2  1  0.993  0.000  0.510  1.0
  Cd  Cd3  1  0.007  0.500  0.490  1.0
  P  P4  1  0.554  0.748  0.659  1.0
  P  P5  1  0.446  0.248  0.341  1.0
  O  O6  1  0.279  0.755  0.534  1.0
  O  O7  1  0.721  0.255  0.466  1.0
  O  O8  1  0.833  0.585  0.175  1.0
  O  O9  1  0.167  0.085  0.825  1.0
  O  O10  1  0.751  0.742  0.550  1.0
  O  O11  1  0.249  0.242  0.450  1.0
  O  O12  1  0.781  0.970  0.182  1.0
  O  O13  1  0.219  0.470  0.818  1.0
  O  O14  1  0.596  0.561  0.782  1.0
  O  O15  1  0.404  0.061  0.218  1.0
  O  O16  1  0.608  0.931  0.784  1.0
  O  O17  1  0.392  0.431  0.216  1.0
  O  O18  1  0.381  0.750  0.004  1.0
  O  O19  1  0.619  0.250  0.996  1.0
[/CIF]
.
The material structure described by VCdPO7 crystallizes in the monoclinic P2_1 space group. V(1) is bonded in a 6-coordinate geometry to one O(2), one O(4), one O(5), one O(6), and two equivalent O(7) atoms. Cd(1) is bonded to one O(2), one O(4), two equivalent O(1), and two equivalent O(3) atoms to form CdO6 octahedra that share corners with four equivalent P(1)O4 tetrahedra and edges with two equivalent Cd(1)O6 octahedra. P(1) is bonded to one O(1), one O(3), one O(5), and one O(6) atom to form PO4 tetrahedra that share corners with four equivalent Cd(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-56°. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to two equivalent Cd(1) and one P(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one V(1) and one Cd(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to two equivalent Cd(1) and one P(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one V(1) and one Cd(1) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one V(1) and one P(1) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one V(1) and one P(1) atom. In the seventh O site, O(7) is bonded in a distorted bent 150 degrees geometry to two equivalent V(1) atoms. is represented by the CIF file [CIF]
data_VCdPO7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.531
_cell_length_b   6.982
_cell_length_c   7.480
_cell_angle_alpha   90.000
_cell_angle_beta   106.674
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   276.696
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.544  0.532  0.039  1.0
  V  V1  1  0.456  0.032  0.961  1.0
  Cd  Cd2  1  0.993  0.000  0.510  1.0
  Cd  Cd3  1  0.007  0.500  0.490  1.0
  P  P4  1  0.554  0.748  0.659  1.0
  P  P5  1  0.446  0.248  0.341  1.0
  O  O6  1  0.279  0.755  0.534  1.0
  O  O7  1  0.721  0.255  0.466  1.0
  O  O8  1  0.833  0.585  0.175  1.0
  O  O9  1  0.167  0.085  0.825  1.0
  O  O10  1  0.751  0.742  0.550  1.0
  O  O11  1  0.249  0.242  0.450  1.0
  O  O12  1  0.781  0.970  0.182  1.0
  O  O13  1  0.219  0.470  0.818  1.0
  O  O14  1  0.596  0.561  0.782  1.0
  O  O15  1  0.404  0.061  0.218  1.0
  O  O16  1  0.608  0.931  0.784  1.0
  O  O17  1  0.392  0.431  0.216  1.0
  O  O18  1  0.381  0.750  0.004  1.0
  O  O19  1  0.619  0.250  0.996  1.0
[/CIF]
.