The crystal structure described by PbO2 is Hydrophilite-like structured and crystallizes in the orthorhombic Pbcn space group. Pb(1) is bonded to six equivalent O(1) atoms to form a mixture of corner and edge-sharing PbO6 octahedra. The corner-sharing octahedral tilt angles range from 54-55°. O(1) is bonded in a trigonal planar geometry to three equivalent Pb(1) atoms. is represented by the CIF card [CIF]
data_PbO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.047
_cell_length_b   5.493
_cell_length_c   5.955
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   165.097
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pb  Pb0  1  0.500  0.750  0.821  1.0
  Pb  Pb1  1  0.000  0.250  0.679  1.0
  Pb  Pb2  1  0.500  0.250  0.179  1.0
  Pb  Pb3  1  0.000  0.750  0.321  1.0
  O  O4  1  0.267  0.428  0.904  1.0
  O  O5  1  0.767  0.572  0.596  1.0
  O  O6  1  0.233  0.928  0.596  1.0
  O  O7  1  0.733  0.072  0.904  1.0
  O  O8  1  0.267  0.928  0.096  1.0
  O  O9  1  0.767  0.072  0.404  1.0
  O  O10  1  0.233  0.428  0.404  1.0
  O  O11  1  0.733  0.572  0.096  1.0
[/CIF]
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The crystal structure described by PbO2 is Hydrophilite-like structured and crystallizes in the orthorhombic Pbcn space group. Pb(1) is bonded to six equivalent O(1) atoms to form a mixture of corner and edge-sharing PbO6 octahedra. The corner-sharing octahedral tilt angles range from 54-55°. O(1) is bonded in a trigonal planar geometry to three equivalent Pb(1) atoms. is represented by the CIF card [CIF]
data_PbO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.047
_cell_length_b   5.493
_cell_length_c   5.955
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   165.097
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pb  Pb0  1  0.500  0.750  0.821  1.0
  Pb  Pb1  1  0.000  0.250  0.679  1.0
  Pb  Pb2  1  0.500  0.250  0.179  1.0
  Pb  Pb3  1  0.000  0.750  0.321  1.0
  O  O4  1  0.267  0.428  0.904  1.0
  O  O5  1  0.767  0.572  0.596  1.0
  O  O6  1  0.233  0.928  0.596  1.0
  O  O7  1  0.733  0.072  0.904  1.0
  O  O8  1  0.267  0.928  0.096  1.0
  O  O9  1  0.767  0.072  0.404  1.0
  O  O10  1  0.233  0.428  0.404  1.0
  O  O11  1  0.733  0.572  0.096  1.0
[/CIF]
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