The structure described by OsC4(O2Cl)2 is alpha U structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four OsC4(O2Cl)2 clusters. Os(1) is bonded in an octahedral geometry to two equivalent C(1), two equivalent C(2), and two equivalent Cl(1) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Os(1) and one O(2) atom. In the second C site, C(2) is bonded in a distorted linear geometry to one Os(1) and one O(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. Cl(1) is bonded in a single-bond geometry to one Os(1) atom. is represented by the CIF file [CIF]
data_OsC4(ClO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.169
_cell_length_b   6.169
_cell_length_c   11.817
_cell_angle_alpha   86.475
_cell_angle_beta   86.475
_cell_angle_gamma   114.235
_symmetry_Int_Tables_number   1
_cell_volume   407.486
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Os  Os0  1  0.431  0.569  0.750  1.0
  Os  Os1  1  0.569  0.431  0.250  1.0
  C  C2  1  0.394  0.791  0.848  1.0
  C  C3  1  0.209  0.606  0.652  1.0
  C  C4  1  0.606  0.209  0.152  1.0
  C  C5  1  0.168  0.298  0.843  1.0
  C  C6  1  0.832  0.702  0.157  1.0
  C  C7  1  0.298  0.168  0.343  1.0
  C  C8  1  0.791  0.394  0.348  1.0
  C  C9  1  0.702  0.832  0.657  1.0
  Cl  Cl10  1  0.473  0.270  0.634  1.0
  Cl  Cl11  1  0.270  0.473  0.134  1.0
  Cl  Cl12  1  0.527  0.730  0.366  1.0
  Cl  Cl13  1  0.730  0.527  0.866  1.0
  O  O14  1  0.860  0.990  0.608  1.0
  O  O15  1  0.140  0.010  0.392  1.0
  O  O16  1  0.990  0.860  0.108  1.0
  O  O17  1  0.634  0.078  0.093  1.0
  O  O18  1  0.922  0.366  0.407  1.0
  O  O19  1  0.010  0.140  0.892  1.0
  O  O20  1  0.366  0.922  0.907  1.0
  O  O21  1  0.078  0.634  0.593  1.0
[/CIF]
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The structure described by OsC4(O2Cl)2 is alpha U structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four OsC4(O2Cl)2 clusters. Os(1) is bonded in an octahedral geometry to two equivalent C(1), two equivalent C(2), and two equivalent Cl(1) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Os(1) and one O(2) atom. In the second C site, C(2) is bonded in a distorted linear geometry to one Os(1) and one O(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. Cl(1) is bonded in a single-bond geometry to one Os(1) atom. is represented by the CIF file [CIF]
data_OsC4(ClO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.169
_cell_length_b   6.169
_cell_length_c   11.817
_cell_angle_alpha   86.475
_cell_angle_beta   86.475
_cell_angle_gamma   114.235
_symmetry_Int_Tables_number   1
_cell_volume   407.486
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Os  Os0  1  0.431  0.569  0.750  1.0
  Os  Os1  1  0.569  0.431  0.250  1.0
  C  C2  1  0.394  0.791  0.848  1.0
  C  C3  1  0.209  0.606  0.652  1.0
  C  C4  1  0.606  0.209  0.152  1.0
  C  C5  1  0.168  0.298  0.843  1.0
  C  C6  1  0.832  0.702  0.157  1.0
  C  C7  1  0.298  0.168  0.343  1.0
  C  C8  1  0.791  0.394  0.348  1.0
  C  C9  1  0.702  0.832  0.657  1.0
  Cl  Cl10  1  0.473  0.270  0.634  1.0
  Cl  Cl11  1  0.270  0.473  0.134  1.0
  Cl  Cl12  1  0.527  0.730  0.366  1.0
  Cl  Cl13  1  0.730  0.527  0.866  1.0
  O  O14  1  0.860  0.990  0.608  1.0
  O  O15  1  0.140  0.010  0.392  1.0
  O  O16  1  0.990  0.860  0.108  1.0
  O  O17  1  0.634  0.078  0.093  1.0
  O  O18  1  0.922  0.366  0.407  1.0
  O  O19  1  0.010  0.140  0.892  1.0
  O  O20  1  0.366  0.922  0.907  1.0
  O  O21  1  0.078  0.634  0.593  1.0
[/CIF]
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