The structure described by Cs3SbH2S4O crystallizes in the monoclinic P2_1/c space group. There are three inequivalent Cs sites. In the first Cs site, Cs(1) is bonded in a 11-coordinate geometry to one H(1), two equivalent H(2), one S(3), two equivalent S(1), two equivalent S(2), two equivalent S(4), and one O(1) atom. In the second Cs site, Cs(2) is bonded in a 9-coordinate geometry to one H(1), one S(1), two equivalent S(2), two equivalent S(3), two equivalent S(4), and one O(1) atom. In the third Cs site, Cs(3) is bonded in a 7-coordinate geometry to one H(2), one S(1), one S(4), two equivalent S(3), and two equivalent O(1) atoms. Sb(1) is bonded in a tetrahedral geometry to one S(1), one S(2), one S(3), and one S(4) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one Cs(1), one Cs(2), and one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one Cs(3), two equivalent Cs(1), and one O(1) atom. There are four inequivalent S sites. In the first S site, S(3) is bonded to one Cs(1), two equivalent Cs(2), two equivalent Cs(3), and one Sb(1) atom to form edge-sharing SCs5Sb octahedra. In the second S site, S(4) is bonded in a 6-coordinate geometry to one Cs(3), two equivalent Cs(1), two equivalent Cs(2), and one Sb(1) atom. In the third S site, S(1) is bonded in a 1-coordinate geometry to one Cs(2), one Cs(3), two equivalent Cs(1), and one Sb(1) atom. In the fourth S site, S(2) is bonded in a distorted single-bond geometry to two equivalent Cs(1), two equivalent Cs(2), and one Sb(1) atom. O(1) is bonded in a water-like geometry to one Cs(1), one Cs(2), two equivalent Cs(3), one H(1), and one H(2) atom. is represented by the CIF card [CIF]
data_Cs3SbH2S4O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.206
_cell_length_b   10.027
_cell_length_c   16.327
_cell_angle_alpha   53.766
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1347.692
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.369  0.899  0.203  1.0
  Cs  Cs1  1  0.869  0.101  0.297  1.0
  Cs  Cs2  1  0.631  0.101  0.797  1.0
  Cs  Cs3  1  0.131  0.899  0.703  1.0
  Cs  Cs4  1  0.078  0.716  0.047  1.0
  Cs  Cs5  1  0.578  0.284  0.453  1.0
  Cs  Cs6  1  0.922  0.284  0.953  1.0
  Cs  Cs7  1  0.422  0.716  0.547  1.0
  Cs  Cs8  1  0.084  0.423  0.421  1.0
  Cs  Cs9  1  0.584  0.577  0.079  1.0
  Cs  Cs10  1  0.916  0.577  0.579  1.0
  Cs  Cs11  1  0.416  0.423  0.921  1.0
  Sb  Sb12  1  0.292  0.248  0.275  1.0
  Sb  Sb13  1  0.792  0.752  0.225  1.0
  Sb  Sb14  1  0.708  0.752  0.725  1.0
  Sb  Sb15  1  0.208  0.248  0.775  1.0
  H  H16  1  0.156  0.871  0.407  1.0
  H  H17  1  0.656  0.129  0.093  1.0
  H  H18  1  0.844  0.129  0.593  1.0
  H  H19  1  0.344  0.871  0.907  1.0
  H  H20  1  0.098  0.814  0.342  1.0
  H  H21  1  0.598  0.186  0.158  1.0
  H  H22  1  0.902  0.186  0.658  1.0
  H  H23  1  0.402  0.814  0.842  1.0
  S  S24  1  0.669  0.928  0.074  1.0
  S  S25  1  0.169  0.072  0.426  1.0
  S  S26  1  0.331  0.072  0.926  1.0
  S  S27  1  0.831  0.928  0.574  1.0
  S  S28  1  0.998  0.880  0.200  1.0
  S  S29  1  0.498  0.120  0.300  1.0
  S  S30  1  0.002  0.120  0.800  1.0
  S  S31  1  0.502  0.880  0.700  1.0
  S  S32  1  0.327  0.504  0.248  1.0
  S  S33  1  0.827  0.496  0.252  1.0
  S  S34  1  0.673  0.496  0.752  1.0
  S  S35  1  0.173  0.504  0.748  1.0
  S  S36  1  0.183  0.284  0.136  1.0
  S  S37  1  0.683  0.716  0.364  1.0
  S  S38  1  0.817  0.716  0.864  1.0
  S  S39  1  0.317  0.284  0.636  1.0
  O  O40  1  0.149  0.774  0.404  1.0
  O  O41  1  0.649  0.226  0.096  1.0
  O  O42  1  0.851  0.226  0.596  1.0
  O  O43  1  0.351  0.774  0.904  1.0
[/CIF]
.
The structure described by Cs3SbH2S4O crystallizes in the monoclinic P2_1/c space group. There are three inequivalent Cs sites. In the first Cs site, Cs(1) is bonded in a 11-coordinate geometry to one H(1), two equivalent H(2), one S(3), two equivalent S(1), two equivalent S(2), two equivalent S(4), and one O(1) atom. In the second Cs site, Cs(2) is bonded in a 9-coordinate geometry to one H(1), one S(1), two equivalent S(2), two equivalent S(3), two equivalent S(4), and one O(1) atom. In the third Cs site, Cs(3) is bonded in a 7-coordinate geometry to one H(2), one S(1), one S(4), two equivalent S(3), and two equivalent O(1) atoms. Sb(1) is bonded in a tetrahedral geometry to one S(1), one S(2), one S(3), and one S(4) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one Cs(1), one Cs(2), and one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one Cs(3), two equivalent Cs(1), and one O(1) atom. There are four inequivalent S sites. In the first S site, S(3) is bonded to one Cs(1), two equivalent Cs(2), two equivalent Cs(3), and one Sb(1) atom to form edge-sharing SCs5Sb octahedra. In the second S site, S(4) is bonded in a 6-coordinate geometry to one Cs(3), two equivalent Cs(1), two equivalent Cs(2), and one Sb(1) atom. In the third S site, S(1) is bonded in a 1-coordinate geometry to one Cs(2), one Cs(3), two equivalent Cs(1), and one Sb(1) atom. In the fourth S site, S(2) is bonded in a distorted single-bond geometry to two equivalent Cs(1), two equivalent Cs(2), and one Sb(1) atom. O(1) is bonded in a water-like geometry to one Cs(1), one Cs(2), two equivalent Cs(3), one H(1), and one H(2) atom. is represented by the CIF card [CIF]
data_Cs3SbH2S4O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.206
_cell_length_b   10.027
_cell_length_c   16.327
_cell_angle_alpha   53.766
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1347.692
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.369  0.899  0.203  1.0
  Cs  Cs1  1  0.869  0.101  0.297  1.0
  Cs  Cs2  1  0.631  0.101  0.797  1.0
  Cs  Cs3  1  0.131  0.899  0.703  1.0
  Cs  Cs4  1  0.078  0.716  0.047  1.0
  Cs  Cs5  1  0.578  0.284  0.453  1.0
  Cs  Cs6  1  0.922  0.284  0.953  1.0
  Cs  Cs7  1  0.422  0.716  0.547  1.0
  Cs  Cs8  1  0.084  0.423  0.421  1.0
  Cs  Cs9  1  0.584  0.577  0.079  1.0
  Cs  Cs10  1  0.916  0.577  0.579  1.0
  Cs  Cs11  1  0.416  0.423  0.921  1.0
  Sb  Sb12  1  0.292  0.248  0.275  1.0
  Sb  Sb13  1  0.792  0.752  0.225  1.0
  Sb  Sb14  1  0.708  0.752  0.725  1.0
  Sb  Sb15  1  0.208  0.248  0.775  1.0
  H  H16  1  0.156  0.871  0.407  1.0
  H  H17  1  0.656  0.129  0.093  1.0
  H  H18  1  0.844  0.129  0.593  1.0
  H  H19  1  0.344  0.871  0.907  1.0
  H  H20  1  0.098  0.814  0.342  1.0
  H  H21  1  0.598  0.186  0.158  1.0
  H  H22  1  0.902  0.186  0.658  1.0
  H  H23  1  0.402  0.814  0.842  1.0
  S  S24  1  0.669  0.928  0.074  1.0
  S  S25  1  0.169  0.072  0.426  1.0
  S  S26  1  0.331  0.072  0.926  1.0
  S  S27  1  0.831  0.928  0.574  1.0
  S  S28  1  0.998  0.880  0.200  1.0
  S  S29  1  0.498  0.120  0.300  1.0
  S  S30  1  0.002  0.120  0.800  1.0
  S  S31  1  0.502  0.880  0.700  1.0
  S  S32  1  0.327  0.504  0.248  1.0
  S  S33  1  0.827  0.496  0.252  1.0
  S  S34  1  0.673  0.496  0.752  1.0
  S  S35  1  0.173  0.504  0.748  1.0
  S  S36  1  0.183  0.284  0.136  1.0
  S  S37  1  0.683  0.716  0.364  1.0
  S  S38  1  0.817  0.716  0.864  1.0
  S  S39  1  0.317  0.284  0.636  1.0
  O  O40  1  0.149  0.774  0.404  1.0
  O  O41  1  0.649  0.226  0.096  1.0
  O  O42  1  0.851  0.226  0.596  1.0
  O  O43  1  0.351  0.774  0.904  1.0
[/CIF]
.