The structure described by WP2 crystallizes in the orthorhombic Cmc2_1 space group. W(1) is bonded to three equivalent P(2) and four equivalent P(1) atoms to form a mixture of distorted corner, edge, and face-sharing WP7 pentagonal bipyramids. There are two inequivalent P sites. In the first P site, P(1) is bonded in a 5-coordinate geometry to four equivalent W(1) and one P(2) atom. In the second P site, P(2) is bonded in a distorted rectangular see-saw-like geometry to three equivalent W(1) and one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_P2W
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.185
_cell_length_b   4.984
_cell_length_c   5.808
_cell_angle_alpha   90.000
_cell_angle_beta   105.916
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   88.674
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.431  0.617  0.861  1.0
  P  P1  1  0.569  0.117  0.139  1.0
  P  P2  1  0.700  0.801  0.401  1.0
  P  P3  1  0.300  0.301  0.599  1.0
  W  W4  1  0.094  0.499  0.187  1.0
  W  W5  1  0.906  0.999  0.813  1.0
[/CIF]
.
The structure described by WP2 crystallizes in the orthorhombic Cmc2_1 space group. W(1) is bonded to three equivalent P(2) and four equivalent P(1) atoms to form a mixture of distorted corner, edge, and face-sharing WP7 pentagonal bipyramids. There are two inequivalent P sites. In the first P site, P(1) is bonded in a 5-coordinate geometry to four equivalent W(1) and one P(2) atom. In the second P site, P(2) is bonded in a distorted rectangular see-saw-like geometry to three equivalent W(1) and one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_P2W
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.185
_cell_length_b   4.984
_cell_length_c   5.808
_cell_angle_alpha   90.000
_cell_angle_beta   105.916
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   88.674
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.431  0.617  0.861  1.0
  P  P1  1  0.569  0.117  0.139  1.0
  P  P2  1  0.700  0.801  0.401  1.0
  P  P3  1  0.300  0.301  0.599  1.0
  W  W4  1  0.094  0.499  0.187  1.0
  W  W5  1  0.906  0.999  0.813  1.0
[/CIF]
.