The material structure described by KMnO2Cl3 crystallizes in the triclinic P-1 space group. K(1) is bonded in a 8-coordinate geometry to one O(2), two equivalent Cl(1), two equivalent Cl(2), and three equivalent Cl(3) atoms. Mn(1) is bonded in a distorted trigonal bipyramidal geometry to one O(1), one O(2), one Cl(1), one Cl(2), and one Cl(3) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Mn(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one K(1) and one Mn(1) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a 3-coordinate geometry to two equivalent K(1) and one Mn(1) atom. In the second Cl site, Cl(2) is bonded in a distorted single-bond geometry to two equivalent K(1) and one Mn(1) atom. In the third Cl site, Cl(3) is bonded in a 4-coordinate geometry to three equivalent K(1) and one Mn(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_KMnCl3O2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.797
_cell_length_b   6.884
_cell_length_c   9.554
_cell_angle_alpha   75.699
_cell_angle_beta   76.607
_cell_angle_gamma   67.414
_symmetry_Int_Tables_number   1
_cell_volume   395.219
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.946  0.176  0.207  1.0
  K  K1  1  0.054  0.824  0.793  1.0
  Mn  Mn2  1  0.598  0.759  0.302  1.0
  Mn  Mn3  1  0.402  0.241  0.698  1.0
  Cl  Cl4  1  0.741  0.178  0.566  1.0
  Cl  Cl5  1  0.259  0.822  0.434  1.0
  Cl  Cl6  1  0.488  0.086  0.179  1.0
  Cl  Cl7  1  0.512  0.914  0.821  1.0
  Cl  Cl8  1  0.946  0.711  0.154  1.0
  Cl  Cl9  1  0.054  0.289  0.846  1.0
  O  O10  1  0.290  0.279  0.559  1.0
  O  O11  1  0.710  0.721  0.441  1.0
  O  O12  1  0.589  0.564  0.241  1.0
  O  O13  1  0.411  0.436  0.759  1.0
[/CIF]
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The material structure described by KMnO2Cl3 crystallizes in the triclinic P-1 space group. K(1) is bonded in a 8-coordinate geometry to one O(2), two equivalent Cl(1), two equivalent Cl(2), and three equivalent Cl(3) atoms. Mn(1) is bonded in a distorted trigonal bipyramidal geometry to one O(1), one O(2), one Cl(1), one Cl(2), and one Cl(3) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Mn(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one K(1) and one Mn(1) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a 3-coordinate geometry to two equivalent K(1) and one Mn(1) atom. In the second Cl site, Cl(2) is bonded in a distorted single-bond geometry to two equivalent K(1) and one Mn(1) atom. In the third Cl site, Cl(3) is bonded in a 4-coordinate geometry to three equivalent K(1) and one Mn(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_KMnCl3O2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.797
_cell_length_b   6.884
_cell_length_c   9.554
_cell_angle_alpha   75.699
_cell_angle_beta   76.607
_cell_angle_gamma   67.414
_symmetry_Int_Tables_number   1
_cell_volume   395.219
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.946  0.176  0.207  1.0
  K  K1  1  0.054  0.824  0.793  1.0
  Mn  Mn2  1  0.598  0.759  0.302  1.0
  Mn  Mn3  1  0.402  0.241  0.698  1.0
  Cl  Cl4  1  0.741  0.178  0.566  1.0
  Cl  Cl5  1  0.259  0.822  0.434  1.0
  Cl  Cl6  1  0.488  0.086  0.179  1.0
  Cl  Cl7  1  0.512  0.914  0.821  1.0
  Cl  Cl8  1  0.946  0.711  0.154  1.0
  Cl  Cl9  1  0.054  0.289  0.846  1.0
  O  O10  1  0.290  0.279  0.559  1.0
  O  O11  1  0.710  0.721  0.441  1.0
  O  O12  1  0.589  0.564  0.241  1.0
  O  O13  1  0.411  0.436  0.759  1.0
[/CIF]
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