The crystal structure described by Rb3SbS3 crystallizes in the cubic P2_13 space group. There are three inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 6-coordinate geometry to six equivalent S(1) atoms. In the second Rb site, Rb(2) is bonded in a 6-coordinate geometry to six equivalent S(1) atoms. In the third Rb site, Rb(3) is bonded in a 6-coordinate geometry to six equivalent S(1) atoms. Sb(1) is bonded in a distorted trigonal non-coplanar geometry to three equivalent S(1) atoms. S(1) is bonded to two equivalent Rb(1), two equivalent Rb(2), two equivalent Rb(3), and one Sb(1) atom to form a mixture of distorted face, corner, and edge-sharing SRb6Sb pentagonal bipyramids. is represented by the CIF file [CIF]
data_Rb3SbS3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.893
_cell_length_b   9.893
_cell_length_c   9.893
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   968.291
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.441  0.941  0.559  1.0
  Rb  Rb1  1  0.941  0.559  0.441  1.0
  Rb  Rb2  1  0.559  0.441  0.941  1.0
  Rb  Rb3  1  0.059  0.059  0.059  1.0
  Rb  Rb4  1  0.937  0.437  0.063  1.0
  Rb  Rb5  1  0.437  0.063  0.937  1.0
  Rb  Rb6  1  0.063  0.937  0.437  1.0
  Rb  Rb7  1  0.563  0.563  0.563  1.0
  Rb  Rb8  1  0.678  0.178  0.322  1.0
  Rb  Rb9  1  0.178  0.322  0.678  1.0
  Rb  Rb10  1  0.322  0.678  0.178  1.0
  Rb  Rb11  1  0.822  0.822  0.822  1.0
  Sb  Sb12  1  0.223  0.723  0.777  1.0
  Sb  Sb13  1  0.723  0.777  0.223  1.0
  Sb  Sb14  1  0.777  0.223  0.723  1.0
  Sb  Sb15  1  0.277  0.277  0.277  1.0
  S  S16  1  0.155  0.959  0.756  1.0
  S  S17  1  0.244  0.655  0.541  1.0
  S  S18  1  0.459  0.744  0.845  1.0
  S  S19  1  0.655  0.541  0.244  1.0
  S  S20  1  0.744  0.845  0.459  1.0
  S  S21  1  0.959  0.756  0.155  1.0
  S  S22  1  0.845  0.459  0.744  1.0
  S  S23  1  0.756  0.155  0.959  1.0
  S  S24  1  0.541  0.244  0.655  1.0
  S  S25  1  0.345  0.041  0.256  1.0
  S  S26  1  0.256  0.345  0.041  1.0
  S  S27  1  0.041  0.256  0.345  1.0
[/CIF]
.
The crystal structure described by Rb3SbS3 crystallizes in the cubic P2_13 space group. There are three inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 6-coordinate geometry to six equivalent S(1) atoms. In the second Rb site, Rb(2) is bonded in a 6-coordinate geometry to six equivalent S(1) atoms. In the third Rb site, Rb(3) is bonded in a 6-coordinate geometry to six equivalent S(1) atoms. Sb(1) is bonded in a distorted trigonal non-coplanar geometry to three equivalent S(1) atoms. S(1) is bonded to two equivalent Rb(1), two equivalent Rb(2), two equivalent Rb(3), and one Sb(1) atom to form a mixture of distorted face, corner, and edge-sharing SRb6Sb pentagonal bipyramids. is represented by the CIF file [CIF]
data_Rb3SbS3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.893
_cell_length_b   9.893
_cell_length_c   9.893
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   968.291
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.441  0.941  0.559  1.0
  Rb  Rb1  1  0.941  0.559  0.441  1.0
  Rb  Rb2  1  0.559  0.441  0.941  1.0
  Rb  Rb3  1  0.059  0.059  0.059  1.0
  Rb  Rb4  1  0.937  0.437  0.063  1.0
  Rb  Rb5  1  0.437  0.063  0.937  1.0
  Rb  Rb6  1  0.063  0.937  0.437  1.0
  Rb  Rb7  1  0.563  0.563  0.563  1.0
  Rb  Rb8  1  0.678  0.178  0.322  1.0
  Rb  Rb9  1  0.178  0.322  0.678  1.0
  Rb  Rb10  1  0.322  0.678  0.178  1.0
  Rb  Rb11  1  0.822  0.822  0.822  1.0
  Sb  Sb12  1  0.223  0.723  0.777  1.0
  Sb  Sb13  1  0.723  0.777  0.223  1.0
  Sb  Sb14  1  0.777  0.223  0.723  1.0
  Sb  Sb15  1  0.277  0.277  0.277  1.0
  S  S16  1  0.155  0.959  0.756  1.0
  S  S17  1  0.244  0.655  0.541  1.0
  S  S18  1  0.459  0.744  0.845  1.0
  S  S19  1  0.655  0.541  0.244  1.0
  S  S20  1  0.744  0.845  0.459  1.0
  S  S21  1  0.959  0.756  0.155  1.0
  S  S22  1  0.845  0.459  0.744  1.0
  S  S23  1  0.756  0.155  0.959  1.0
  S  S24  1  0.541  0.244  0.655  1.0
  S  S25  1  0.345  0.041  0.256  1.0
  S  S26  1  0.256  0.345  0.041  1.0
  S  S27  1  0.041  0.256  0.345  1.0
[/CIF]
.