The crystal structure described by Co(MoO4)6GaO12(O2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 7782-44-7 molecules, one Co(MoO4)6 cluster, and one GaO12 cluster. In the Co(MoO4)6 cluster, there are three inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. In the second Mo site, Mo(2) is bonded in a 6-coordinate geometry to one O(10), one O(5), one O(6), one O(7), one O(8), and one O(9) atom. In the third Mo site, Mo(3) is bonded in a 6-coordinate geometry to one O(1), one O(10), one O(11), one O(12), one O(2), and one O(9) atom. Co(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(5), and two equivalent O(9) atoms. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one Mo(1), one Mo(3), and one Co(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Mo(1) and one Mo(3) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Mo(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Mo(1) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Mo(1), one Mo(2), and one Co(1) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Mo(1) and one Mo(2) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one Mo(2) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one Mo(2) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one Mo(2), one Mo(3), and one Co(1) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Mo(2) and one Mo(3) atom. In the eleventh O site, O(11) is bonded in a single-bond geometry to one Mo(3) atom. In the twelfth O site, O(12) is bonded in a single-bond geometry to one Mo(3) atom. In the GaO12 cluster, Ga(1) is bonded in a distorted linear geometry to two equivalent O(13), two equivalent O(14), and two equivalent O(15) atoms. There are six inequivalent O sites. In the first O site, O(13) is bonded in a bent 150 degrees geometry to one Ga(1) and one O(18) atom. In the second O site, O(14) is bonded in a bent 120 degrees geometry to one Ga(1) and one O(17) atom. In the third O site, O(15) is bonded in a single-bond geometry to one Ga(1) atom. In the fourth O site, O(16) is bonded in a single-bond geometry to one O(18) atom. In the fifth O site, O(17) is bonded in a single-bond geometry to one O(14) atom. In the sixth O site, O(18) is bonded in a bent 120 degrees geometry to one O(13) and one O(16) atom. is represented by the CIF card [CIF]
data_GaCo(Mo3O20)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.914
_cell_length_b   11.211
_cell_length_c   11.319
_cell_angle_alpha   98.305
_cell_angle_beta   95.832
_cell_angle_gamma   103.920
_symmetry_Int_Tables_number   1
_cell_volume   834.215
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.500  0.000  0.500  1.0
  Co  Co1  1  0.500  0.500  0.000  1.0
  Mo  Mo2  1  0.902  0.675  0.889  1.0
  Mo  Mo3  1  0.098  0.325  0.111  1.0
  Mo  Mo4  1  0.855  0.760  0.185  1.0
  Mo  Mo5  1  0.145  0.240  0.815  1.0
  Mo  Mo6  1  0.466  0.571  0.300  1.0
  Mo  Mo7  1  0.534  0.429  0.700  1.0
  O  O8  1  0.697  0.486  0.896  1.0
  O  O9  1  0.303  0.514  0.104  1.0
  O  O10  1  0.653  0.608  0.767  1.0
  O  O11  1  0.347  0.392  0.233  1.0
  O  O12  1  0.095  0.634  0.821  1.0
  O  O13  1  0.905  0.366  0.179  1.0
  O  O14  1  0.916  0.828  0.876  1.0
  O  O15  1  0.084  0.172  0.124  1.0
  O  O16  1  0.585  0.664  0.009  1.0
  O  O17  1  0.415  0.336  0.991  1.0
  O  O18  1  0.989  0.691  0.060  1.0
  O  O19  1  0.011  0.309  0.940  1.0
  O  O20  1  0.021  0.772  0.314  1.0
  O  O21  1  0.979  0.228  0.686  1.0
  O  O22  1  0.875  0.910  0.160  1.0
  O  O23  1  0.125  0.090  0.840  1.0
  O  O24  1  0.681  0.541  0.135  1.0
  O  O25  1  0.319  0.459  0.865  1.0
  O  O26  1  0.592  0.726  0.246  1.0
  O  O27  1  0.408  0.274  0.754  1.0
  O  O28  1  0.287  0.612  0.380  1.0
  O  O29  1  0.713  0.388  0.620  1.0
  O  O30  1  0.656  0.558  0.406  1.0
  O  O31  1  0.344  0.442  0.594  1.0
  O  O32  1  0.149  0.906  0.548  1.0
  O  O33  1  0.851  0.094  0.452  1.0
  O  O34  1  0.429  0.193  0.429  1.0
  O  O35  1  0.571  0.807  0.571  1.0
  O  O36  1  0.504  0.055  0.651  1.0
  O  O37  1  0.496  0.945  0.349  1.0
  O  O38  1  0.041  0.720  0.599  1.0
  O  O39  1  0.959  0.280  0.401  1.0
  O  O40  1  0.451  0.762  0.635  1.0
  O  O41  1  0.549  0.238  0.365  1.0
  O  O42  1  0.979  0.171  0.402  1.0
  O  O43  1  0.021  0.829  0.598  1.0
  O  O44  1  0.398  0.024  0.111  1.0
  O  O45  1  0.602  0.976  0.889  1.0
  O  O46  1  0.483  0.884  0.909  1.0
  O  O47  1  0.517  0.116  0.091  1.0
[/CIF]
.
The crystal structure described by Co(MoO4)6GaO12(O2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 7782-44-7 molecules, one Co(MoO4)6 cluster, and one GaO12 cluster. In the Co(MoO4)6 cluster, there are three inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. In the second Mo site, Mo(2) is bonded in a 6-coordinate geometry to one O(10), one O(5), one O(6), one O(7), one O(8), and one O(9) atom. In the third Mo site, Mo(3) is bonded in a 6-coordinate geometry to one O(1), one O(10), one O(11), one O(12), one O(2), and one O(9) atom. Co(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(5), and two equivalent O(9) atoms. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one Mo(1), one Mo(3), and one Co(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Mo(1) and one Mo(3) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Mo(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Mo(1) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Mo(1), one Mo(2), and one Co(1) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Mo(1) and one Mo(2) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one Mo(2) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one Mo(2) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one Mo(2), one Mo(3), and one Co(1) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Mo(2) and one Mo(3) atom. In the eleventh O site, O(11) is bonded in a single-bond geometry to one Mo(3) atom. In the twelfth O site, O(12) is bonded in a single-bond geometry to one Mo(3) atom. In the GaO12 cluster, Ga(1) is bonded in a distorted linear geometry to two equivalent O(13), two equivalent O(14), and two equivalent O(15) atoms. There are six inequivalent O sites. In the first O site, O(13) is bonded in a bent 150 degrees geometry to one Ga(1) and one O(18) atom. In the second O site, O(14) is bonded in a bent 120 degrees geometry to one Ga(1) and one O(17) atom. In the third O site, O(15) is bonded in a single-bond geometry to one Ga(1) atom. In the fourth O site, O(16) is bonded in a single-bond geometry to one O(18) atom. In the fifth O site, O(17) is bonded in a single-bond geometry to one O(14) atom. In the sixth O site, O(18) is bonded in a bent 120 degrees geometry to one O(13) and one O(16) atom. is represented by the CIF card [CIF]
data_GaCo(Mo3O20)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.914
_cell_length_b   11.211
_cell_length_c   11.319
_cell_angle_alpha   98.305
_cell_angle_beta   95.832
_cell_angle_gamma   103.920
_symmetry_Int_Tables_number   1
_cell_volume   834.215
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.500  0.000  0.500  1.0
  Co  Co1  1  0.500  0.500  0.000  1.0
  Mo  Mo2  1  0.902  0.675  0.889  1.0
  Mo  Mo3  1  0.098  0.325  0.111  1.0
  Mo  Mo4  1  0.855  0.760  0.185  1.0
  Mo  Mo5  1  0.145  0.240  0.815  1.0
  Mo  Mo6  1  0.466  0.571  0.300  1.0
  Mo  Mo7  1  0.534  0.429  0.700  1.0
  O  O8  1  0.697  0.486  0.896  1.0
  O  O9  1  0.303  0.514  0.104  1.0
  O  O10  1  0.653  0.608  0.767  1.0
  O  O11  1  0.347  0.392  0.233  1.0
  O  O12  1  0.095  0.634  0.821  1.0
  O  O13  1  0.905  0.366  0.179  1.0
  O  O14  1  0.916  0.828  0.876  1.0
  O  O15  1  0.084  0.172  0.124  1.0
  O  O16  1  0.585  0.664  0.009  1.0
  O  O17  1  0.415  0.336  0.991  1.0
  O  O18  1  0.989  0.691  0.060  1.0
  O  O19  1  0.011  0.309  0.940  1.0
  O  O20  1  0.021  0.772  0.314  1.0
  O  O21  1  0.979  0.228  0.686  1.0
  O  O22  1  0.875  0.910  0.160  1.0
  O  O23  1  0.125  0.090  0.840  1.0
  O  O24  1  0.681  0.541  0.135  1.0
  O  O25  1  0.319  0.459  0.865  1.0
  O  O26  1  0.592  0.726  0.246  1.0
  O  O27  1  0.408  0.274  0.754  1.0
  O  O28  1  0.287  0.612  0.380  1.0
  O  O29  1  0.713  0.388  0.620  1.0
  O  O30  1  0.656  0.558  0.406  1.0
  O  O31  1  0.344  0.442  0.594  1.0
  O  O32  1  0.149  0.906  0.548  1.0
  O  O33  1  0.851  0.094  0.452  1.0
  O  O34  1  0.429  0.193  0.429  1.0
  O  O35  1  0.571  0.807  0.571  1.0
  O  O36  1  0.504  0.055  0.651  1.0
  O  O37  1  0.496  0.945  0.349  1.0
  O  O38  1  0.041  0.720  0.599  1.0
  O  O39  1  0.959  0.280  0.401  1.0
  O  O40  1  0.451  0.762  0.635  1.0
  O  O41  1  0.549  0.238  0.365  1.0
  O  O42  1  0.979  0.171  0.402  1.0
  O  O43  1  0.021  0.829  0.598  1.0
  O  O44  1  0.398  0.024  0.111  1.0
  O  O45  1  0.602  0.976  0.889  1.0
  O  O46  1  0.483  0.884  0.909  1.0
  O  O47  1  0.517  0.116  0.091  1.0
[/CIF]
.