The compound described by ZrS2O11O2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 7782-44-7 molecules and one ZrS2O11 cluster. In the ZrS2O11 cluster, Zr(1) is bonded in a 5-coordinate geometry to one O(1), one O(11), one O(2), one O(3), one O(4), and one O(7) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a tetrahedral geometry to one O(3), one O(4), one O(8), and one O(9) atom. In the second S site, S(2) is bonded in a tetrahedral geometry to one O(10), one O(11), one O(12), and one O(2) atom. There are eleven inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Zr(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Zr(1) and one S(2) atom. In the third O site, O(3) is bonded in a water-like geometry to one Zr(1) and one S(1) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one Zr(1) and one S(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one O(7) atom. In the sixth O site, O(7) is bonded in a water-like geometry to one Zr(1) and one O(5) atom. In the seventh O site, O(8) is bonded in a single-bond geometry to one S(1) atom. In the eighth O site, O(9) is bonded in a single-bond geometry to one S(1) atom. In the ninth O site, O(10) is bonded in a single-bond geometry to one S(2) atom. In the tenth O site, O(11) is bonded in a bent 150 degrees geometry to one Zr(1) and one S(2) atom. In the eleventh O site, O(12) is bonded in a single-bond geometry to one S(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_ZrS2O13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.780
_cell_length_b   8.084
_cell_length_c   11.799
_cell_angle_alpha   98.554
_cell_angle_beta   101.085
_cell_angle_gamma   106.492
_symmetry_Int_Tables_number   1
_cell_volume   594.200
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr0  1  0.936  0.762  0.813  1.0
  Zr  Zr1  1  0.064  0.238  0.187  1.0
  S  S2  1  0.931  0.756  0.570  1.0
  S  S3  1  0.069  0.244  0.430  1.0
  S  S4  1  0.257  0.203  0.937  1.0
  S  S5  1  0.743  0.797  0.063  1.0
  O  O6  1  0.149  0.657  0.847  1.0
  O  O7  1  0.851  0.343  0.153  1.0
  O  O8  1  0.755  0.719  0.940  1.0
  O  O9  1  0.245  0.281  0.060  1.0
  O  O10  1  0.882  0.602  0.635  1.0
  O  O11  1  0.118  0.398  0.365  1.0
  O  O12  1  0.953  0.909  0.669  1.0
  O  O13  1  0.047  0.091  0.331  1.0
  O  O14  1  0.504  0.883  0.744  1.0
  O  O15  1  0.496  0.117  0.256  1.0
  O  O16  1  0.674  0.348  0.763  1.0
  O  O17  1  0.326  0.652  0.237  1.0
  O  O18  1  0.517  0.736  0.708  1.0
  O  O19  1  0.483  0.264  0.292  1.0
  O  O20  1  0.129  0.779  0.534  1.0
  O  O21  1  0.871  0.221  0.466  1.0
  O  O22  1  0.248  0.275  0.530  1.0
  O  O23  1  0.752  0.725  0.470  1.0
  O  O24  1  0.165  0.288  0.850  1.0
  O  O25  1  0.835  0.712  0.150  1.0
  O  O26  1  0.120  0.009  0.915  1.0
  O  O27  1  0.880  0.991  0.085  1.0
  O  O28  1  0.475  0.211  0.937  1.0
  O  O29  1  0.525  0.789  0.063  1.0
  O  O30  1  0.646  0.234  0.677  1.0
  O  O31  1  0.354  0.766  0.323  1.0
[/CIF]
.
The compound described by ZrS2O11O2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 7782-44-7 molecules and one ZrS2O11 cluster. In the ZrS2O11 cluster, Zr(1) is bonded in a 5-coordinate geometry to one O(1), one O(11), one O(2), one O(3), one O(4), and one O(7) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a tetrahedral geometry to one O(3), one O(4), one O(8), and one O(9) atom. In the second S site, S(2) is bonded in a tetrahedral geometry to one O(10), one O(11), one O(12), and one O(2) atom. There are eleven inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Zr(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Zr(1) and one S(2) atom. In the third O site, O(3) is bonded in a water-like geometry to one Zr(1) and one S(1) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one Zr(1) and one S(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one O(7) atom. In the sixth O site, O(7) is bonded in a water-like geometry to one Zr(1) and one O(5) atom. In the seventh O site, O(8) is bonded in a single-bond geometry to one S(1) atom. In the eighth O site, O(9) is bonded in a single-bond geometry to one S(1) atom. In the ninth O site, O(10) is bonded in a single-bond geometry to one S(2) atom. In the tenth O site, O(11) is bonded in a bent 150 degrees geometry to one Zr(1) and one S(2) atom. In the eleventh O site, O(12) is bonded in a single-bond geometry to one S(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_ZrS2O13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.780
_cell_length_b   8.084
_cell_length_c   11.799
_cell_angle_alpha   98.554
_cell_angle_beta   101.085
_cell_angle_gamma   106.492
_symmetry_Int_Tables_number   1
_cell_volume   594.200
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr0  1  0.936  0.762  0.813  1.0
  Zr  Zr1  1  0.064  0.238  0.187  1.0
  S  S2  1  0.931  0.756  0.570  1.0
  S  S3  1  0.069  0.244  0.430  1.0
  S  S4  1  0.257  0.203  0.937  1.0
  S  S5  1  0.743  0.797  0.063  1.0
  O  O6  1  0.149  0.657  0.847  1.0
  O  O7  1  0.851  0.343  0.153  1.0
  O  O8  1  0.755  0.719  0.940  1.0
  O  O9  1  0.245  0.281  0.060  1.0
  O  O10  1  0.882  0.602  0.635  1.0
  O  O11  1  0.118  0.398  0.365  1.0
  O  O12  1  0.953  0.909  0.669  1.0
  O  O13  1  0.047  0.091  0.331  1.0
  O  O14  1  0.504  0.883  0.744  1.0
  O  O15  1  0.496  0.117  0.256  1.0
  O  O16  1  0.674  0.348  0.763  1.0
  O  O17  1  0.326  0.652  0.237  1.0
  O  O18  1  0.517  0.736  0.708  1.0
  O  O19  1  0.483  0.264  0.292  1.0
  O  O20  1  0.129  0.779  0.534  1.0
  O  O21  1  0.871  0.221  0.466  1.0
  O  O22  1  0.248  0.275  0.530  1.0
  O  O23  1  0.752  0.725  0.470  1.0
  O  O24  1  0.165  0.288  0.850  1.0
  O  O25  1  0.835  0.712  0.150  1.0
  O  O26  1  0.120  0.009  0.915  1.0
  O  O27  1  0.880  0.991  0.085  1.0
  O  O28  1  0.475  0.211  0.937  1.0
  O  O29  1  0.525  0.789  0.063  1.0
  O  O30  1  0.646  0.234  0.677  1.0
  O  O31  1  0.354  0.766  0.323  1.0
[/CIF]
.