The crystal structure described by Li2OI crystallizes in the orthorhombic Pnma space group. Li(1) is bonded in a distorted water-like geometry to two equivalent O(1) and two equivalent I(1) atoms. O(1) is bonded in a 5-coordinate geometry to four equivalent Li(1) and one I(1) atom. I(1) is bonded in a 5-coordinate geometry to four equivalent Li(1) and one O(1) atom. is represented by the CIF file [CIF]
data_Li2IO
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.872
_cell_length_b   10.323
_cell_length_c   5.570
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   337.615
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.998  0.595  0.621  1.0
  Li  Li1  1  0.002  0.405  0.379  1.0
  Li  Li2  1  0.002  0.905  0.121  1.0
  Li  Li3  1  0.498  0.405  0.379  1.0
  Li  Li4  1  0.998  0.095  0.879  1.0
  Li  Li5  1  0.502  0.595  0.621  1.0
  Li  Li6  1  0.502  0.095  0.879  1.0
  Li  Li7  1  0.498  0.905  0.121  1.0
  I  I8  1  0.750  0.841  0.566  1.0
  I  I9  1  0.250  0.159  0.434  1.0
  I  I10  1  0.250  0.659  0.066  1.0
  I  I11  1  0.750  0.341  0.934  1.0
  O  O12  1  0.750  0.981  0.953  1.0
  O  O13  1  0.250  0.019  0.047  1.0
  O  O14  1  0.250  0.519  0.453  1.0
  O  O15  1  0.750  0.481  0.547  1.0
[/CIF]
.
The crystal structure described by Li2OI crystallizes in the orthorhombic Pnma space group. Li(1) is bonded in a distorted water-like geometry to two equivalent O(1) and two equivalent I(1) atoms. O(1) is bonded in a 5-coordinate geometry to four equivalent Li(1) and one I(1) atom. I(1) is bonded in a 5-coordinate geometry to four equivalent Li(1) and one O(1) atom. is represented by the CIF file [CIF]
data_Li2IO
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.872
_cell_length_b   10.323
_cell_length_c   5.570
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   337.615
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.998  0.595  0.621  1.0
  Li  Li1  1  0.002  0.405  0.379  1.0
  Li  Li2  1  0.002  0.905  0.121  1.0
  Li  Li3  1  0.498  0.405  0.379  1.0
  Li  Li4  1  0.998  0.095  0.879  1.0
  Li  Li5  1  0.502  0.595  0.621  1.0
  Li  Li6  1  0.502  0.095  0.879  1.0
  Li  Li7  1  0.498  0.905  0.121  1.0
  I  I8  1  0.750  0.841  0.566  1.0
  I  I9  1  0.250  0.159  0.434  1.0
  I  I10  1  0.250  0.659  0.066  1.0
  I  I11  1  0.750  0.341  0.934  1.0
  O  O12  1  0.750  0.981  0.953  1.0
  O  O13  1  0.250  0.019  0.047  1.0
  O  O14  1  0.250  0.519  0.453  1.0
  O  O15  1  0.750  0.481  0.547  1.0
[/CIF]
.