The crystal structure described by LiKCO3 crystallizes in the monoclinic P2_1/c space group. K(1) is bonded in a 7-coordinate geometry to two equivalent O(1), two equivalent O(2), and three equivalent O(3) atoms. Li(1) is bonded in a 5-coordinate geometry to one O(3), two equivalent O(1), and two equivalent O(2) atoms. C(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to two equivalent K(1), two equivalent Li(1), and one C(1) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to two equivalent K(1), two equivalent Li(1), and one C(1) atom. In the third O site, O(3) is bonded in a 5-coordinate geometry to three equivalent K(1), one Li(1), and one C(1) atom. is represented by the CIF file [CIF]
data_KLiCO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.175
_cell_length_b   6.736
_cell_length_c   7.770
_cell_angle_alpha   60.135
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   325.684
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.646  0.167  0.655  1.0
  K  K1  1  0.146  0.833  0.845  1.0
  K  K2  1  0.354  0.833  0.345  1.0
  K  K3  1  0.854  0.167  0.155  1.0
  Li  Li4  1  0.430  0.403  0.201  1.0
  Li  Li5  1  0.570  0.597  0.799  1.0
  Li  Li6  1  0.930  0.597  0.299  1.0
  Li  Li7  1  0.070  0.403  0.701  1.0
  C  C8  1  0.332  0.296  0.918  1.0
  C  C9  1  0.668  0.704  0.082  1.0
  C  C10  1  0.832  0.704  0.582  1.0
  C  C11  1  0.168  0.296  0.418  1.0
  O  O12  1  0.333  0.482  0.741  1.0
  O  O13  1  0.667  0.518  0.259  1.0
  O  O14  1  0.474  0.259  0.035  1.0
  O  O15  1  0.167  0.482  0.241  1.0
  O  O16  1  0.833  0.518  0.759  1.0
  O  O17  1  0.310  0.160  0.469  1.0
  O  O18  1  0.190  0.160  0.969  1.0
  O  O19  1  0.026  0.259  0.535  1.0
  O  O20  1  0.526  0.741  0.965  1.0
  O  O21  1  0.810  0.840  0.031  1.0
  O  O22  1  0.974  0.741  0.465  1.0
  O  O23  1  0.690  0.840  0.531  1.0
[/CIF]
.
The crystal structure described by LiKCO3 crystallizes in the monoclinic P2_1/c space group. K(1) is bonded in a 7-coordinate geometry to two equivalent O(1), two equivalent O(2), and three equivalent O(3) atoms. Li(1) is bonded in a 5-coordinate geometry to one O(3), two equivalent O(1), and two equivalent O(2) atoms. C(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to two equivalent K(1), two equivalent Li(1), and one C(1) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to two equivalent K(1), two equivalent Li(1), and one C(1) atom. In the third O site, O(3) is bonded in a 5-coordinate geometry to three equivalent K(1), one Li(1), and one C(1) atom. is represented by the CIF file [CIF]
data_KLiCO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.175
_cell_length_b   6.736
_cell_length_c   7.770
_cell_angle_alpha   60.135
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   325.684
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.646  0.167  0.655  1.0
  K  K1  1  0.146  0.833  0.845  1.0
  K  K2  1  0.354  0.833  0.345  1.0
  K  K3  1  0.854  0.167  0.155  1.0
  Li  Li4  1  0.430  0.403  0.201  1.0
  Li  Li5  1  0.570  0.597  0.799  1.0
  Li  Li6  1  0.930  0.597  0.299  1.0
  Li  Li7  1  0.070  0.403  0.701  1.0
  C  C8  1  0.332  0.296  0.918  1.0
  C  C9  1  0.668  0.704  0.082  1.0
  C  C10  1  0.832  0.704  0.582  1.0
  C  C11  1  0.168  0.296  0.418  1.0
  O  O12  1  0.333  0.482  0.741  1.0
  O  O13  1  0.667  0.518  0.259  1.0
  O  O14  1  0.474  0.259  0.035  1.0
  O  O15  1  0.167  0.482  0.241  1.0
  O  O16  1  0.833  0.518  0.759  1.0
  O  O17  1  0.310  0.160  0.469  1.0
  O  O18  1  0.190  0.160  0.969  1.0
  O  O19  1  0.026  0.259  0.535  1.0
  O  O20  1  0.526  0.741  0.965  1.0
  O  O21  1  0.810  0.840  0.031  1.0
  O  O22  1  0.974  0.741  0.465  1.0
  O  O23  1  0.690  0.840  0.531  1.0
[/CIF]
.