The material described by In3Ti2FeO10 crystallizes in the monoclinic P2_1 space group. There are two inequivalent Ti sites. In the first Ti site, Ti(1) is bonded to one O(1), one O(2), one O(4), one O(5), one O(6), and one O(9) atom to form TiO6 octahedra that share corners with two equivalent Ti(2)O6 octahedra, corners with two equivalent Fe(1)O6 octahedra, corners with two equivalent In(1)O6 octahedra, corners with two equivalent In(2)O6 octahedra, corners with two equivalent In(3)O6 octahedra,  an edgeedge with one Ti(2)O6 octahedra, and  an edgeedge with one Fe(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 27-65°. In the second Ti site, Ti(2) is bonded to one O(1), one O(2), one O(5), one O(6), one O(7), and one O(8) atom to form TiO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra, corners with two equivalent Fe(1)O6 octahedra, corners with two equivalent In(1)O6 octahedra, corners with two equivalent In(2)O6 octahedra, corners with two equivalent In(3)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra, and  an edgeedge with one Fe(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 26-64°. Fe(1) is bonded to one O(1), one O(10), one O(2), one O(3), one O(5), and one O(6) atom to form FeO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra, corners with two equivalent Ti(2)O6 octahedra, corners with two equivalent In(1)O6 octahedra, corners with two equivalent In(2)O6 octahedra, corners with two equivalent In(3)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra, and  an edgeedge with one Ti(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 26-66°. There are three inequivalent In sites. In the first In site, In(1) is bonded to one O(10), one O(3), one O(4), one O(7), one O(8), and one O(9) atom to form InO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra, corners with two equivalent Ti(2)O6 octahedra, corners with two equivalent Fe(1)O6 octahedra, edges with three equivalent In(2)O6 octahedra, and edges with three equivalent In(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 60-66°. In the second In site, In(2) is bonded to one O(10), one O(3), one O(4), one O(7), one O(8), and one O(9) atom to form InO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra, corners with two equivalent Ti(2)O6 octahedra, corners with two equivalent Fe(1)O6 octahedra, edges with three equivalent In(1)O6 octahedra, and edges with three equivalent In(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 57-65°. In the third In site, In(3) is bonded to one O(10), one O(3), one O(4), one O(7), one O(8), and one O(9) atom to form InO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra, corners with two equivalent Ti(2)O6 octahedra, corners with two equivalent Fe(1)O6 octahedra, edges with three equivalent In(1)O6 octahedra, and edges with three equivalent In(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 57-66°. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Ti(1), one Ti(2), and one Fe(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Ti(1), one Ti(2), and one Fe(1) atom. In the third O site, O(3) is bonded to one Fe(1), one In(1), one In(2), and one In(3) atom to form OIn3Fe tetrahedra that share  a cornercorner with one O(7)TiIn3 tetrahedra,  a cornercorner with one O(9)TiIn3 tetrahedra, corners with two equivalent O(10)In3Fe tetrahedra, corners with three equivalent O(4)TiIn3 tetrahedra, corners with three equivalent O(8)TiIn3 tetrahedra,  an edgeedge with one O(10)In3Fe tetrahedra,  an edgeedge with one O(7)TiIn3 tetrahedra, and  an edgeedge with one O(9)TiIn3 tetrahedra. In the fourth O site, O(4) is bonded to one Ti(1), one In(1), one In(2), and one In(3) atom to form distorted OTiIn3 tetrahedra that share  a cornercorner with one O(10)In3Fe tetrahedra,  a cornercorner with one O(8)TiIn3 tetrahedra, corners with two equivalent O(9)TiIn3 tetrahedra, corners with three equivalent O(3)In3Fe tetrahedra, corners with three equivalent O(7)TiIn3 tetrahedra,  an edgeedge with one O(10)In3Fe tetrahedra,  an edgeedge with one O(8)TiIn3 tetrahedra, and  an edgeedge with one O(9)TiIn3 tetrahedra. In the fifth O site, O(5) is bonded in a trigonal planar geometry to one Ti(1), one Ti(2), and one Fe(1) atom. In the sixth O site, O(6) is bonded in a trigonal planar geometry to one Ti(1), one Ti(2), and one Fe(1) atom. In the seventh O site, O(7) is bonded to one Ti(2), one In(1), one In(2), and one In(3) atom to form distorted OTiIn3 tetrahedra that share  a cornercorner with one O(3)In3Fe tetrahedra,  a cornercorner with one O(9)TiIn3 tetrahedra, corners with two equivalent O(8)TiIn3 tetrahedra, corners with three equivalent O(10)In3Fe tetrahedra, corners with three equivalent O(4)TiIn3 tetrahedra,  an edgeedge with one O(3)In3Fe tetrahedra,  an edgeedge with one O(8)TiIn3 tetrahedra, and  an edgeedge with one O(9)TiIn3 tetrahedra. In the eighth O site, O(8) is bonded to one Ti(2), one In(1), one In(2), and one In(3) atom to form OTiIn3 tetrahedra that share  a cornercorner with one O(10)In3Fe tetrahedra,  a cornercorner with one O(4)TiIn3 tetrahedra, corners with two equivalent O(7)TiIn3 tetrahedra, corners with three equivalent O(3)In3Fe tetrahedra, corners with three equivalent O(9)TiIn3 tetrahedra,  an edgeedge with one O(10)In3Fe tetrahedra,  an edgeedge with one O(4)TiIn3 tetrahedra, and  an edgeedge with one O(7)TiIn3 tetrahedra. In the ninth O site, O(9) is bonded to one Ti(1), one In(1), one In(2), and one In(3) atom to form distorted OTiIn3 tetrahedra that share  a cornercorner with one O(3)In3Fe tetrahedra,  a cornercorner with one O(7)TiIn3 tetrahedra, corners with two equivalent O(4)TiIn3 tetrahedra, corners with three equivalent O(10)In3Fe tetrahedra, corners with three equivalent O(8)TiIn3 tetrahedra,  an edgeedge with one O(3)In3Fe tetrahedra,  an edgeedge with one O(4)TiIn3 tetrahedra, and  an edgeedge with one O(7)TiIn3 tetrahedra. In the tenth O site, O(10) is bonded to one Fe(1), one In(1), one In(2), and one In(3) atom to form OIn3Fe tetrahedra that share  a cornercorner with one O(4)TiIn3 tetrahedra,  a cornercorner with one O(8)TiIn3 tetrahedra, corners with two equivalent O(3)In3Fe tetrahedra, corners with three equivalent O(7)TiIn3 tetrahedra, corners with three equivalent O(9)TiIn3 tetrahedra,  an edgeedge with one O(3)In3Fe tetrahedra,  an edgeedge with one O(4)TiIn3 tetrahedra, and  an edgeedge with one O(8)TiIn3 tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ti2In3FeO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.226
_cell_length_b   5.975
_cell_length_c   6.506
_cell_angle_alpha   72.261
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   378.626
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.155  0.303  0.491  1.0
  Ti  Ti1  1  0.655  0.697  0.509  1.0
  Ti  Ti2  1  0.501  0.256  0.500  1.0
  Ti  Ti3  1  0.001  0.744  0.500  1.0
  In  In4  1  0.998  0.250  0.998  1.0
  In  In5  1  0.498  0.750  0.002  1.0
  In  In6  1  0.668  0.229  0.002  1.0
  In  In7  1  0.168  0.771  0.998  1.0
  In  In8  1  0.333  0.270  0.997  1.0
  In  In9  1  0.833  0.730  0.003  1.0
  Fe  Fe10  1  0.844  0.193  0.506  1.0
  Fe  Fe11  1  0.344  0.807  0.494  1.0
  O  O12  1  0.541  0.944  0.498  1.0
  O  O13  1  0.041  0.056  0.502  1.0
  O  O14  1  0.462  0.555  0.501  1.0
  O  O15  1  0.962  0.445  0.499  1.0
  O  O16  1  0.333  0.891  0.167  1.0
  O  O17  1  0.833  0.109  0.833  1.0
  O  O18  1  0.666  0.612  0.829  1.0
  O  O19  1  0.166  0.388  0.171  1.0
  O  O20  1  0.816  0.858  0.501  1.0
  O  O21  1  0.316  0.142  0.499  1.0
  O  O22  1  0.180  0.627  0.497  1.0
  O  O23  1  0.680  0.373  0.503  1.0
  O  O24  1  0.001  0.863  0.170  1.0
  O  O25  1  0.501  0.137  0.830  1.0
  O  O26  1  0.001  0.640  0.832  1.0
  O  O27  1  0.501  0.360  0.168  1.0
  O  O28  1  0.666  0.830  0.172  1.0
  O  O29  1  0.166  0.170  0.828  1.0
  O  O30  1  0.333  0.665  0.831  1.0
  O  O31  1  0.833  0.335  0.169  1.0
[/CIF]
.
The material described by In3Ti2FeO10 crystallizes in the monoclinic P2_1 space group. There are two inequivalent Ti sites. In the first Ti site, Ti(1) is bonded to one O(1), one O(2), one O(4), one O(5), one O(6), and one O(9) atom to form TiO6 octahedra that share corners with two equivalent Ti(2)O6 octahedra, corners with two equivalent Fe(1)O6 octahedra, corners with two equivalent In(1)O6 octahedra, corners with two equivalent In(2)O6 octahedra, corners with two equivalent In(3)O6 octahedra,  an edgeedge with one Ti(2)O6 octahedra, and  an edgeedge with one Fe(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 27-65°. In the second Ti site, Ti(2) is bonded to one O(1), one O(2), one O(5), one O(6), one O(7), and one O(8) atom to form TiO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra, corners with two equivalent Fe(1)O6 octahedra, corners with two equivalent In(1)O6 octahedra, corners with two equivalent In(2)O6 octahedra, corners with two equivalent In(3)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra, and  an edgeedge with one Fe(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 26-64°. Fe(1) is bonded to one O(1), one O(10), one O(2), one O(3), one O(5), and one O(6) atom to form FeO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra, corners with two equivalent Ti(2)O6 octahedra, corners with two equivalent In(1)O6 octahedra, corners with two equivalent In(2)O6 octahedra, corners with two equivalent In(3)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra, and  an edgeedge with one Ti(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 26-66°. There are three inequivalent In sites. In the first In site, In(1) is bonded to one O(10), one O(3), one O(4), one O(7), one O(8), and one O(9) atom to form InO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra, corners with two equivalent Ti(2)O6 octahedra, corners with two equivalent Fe(1)O6 octahedra, edges with three equivalent In(2)O6 octahedra, and edges with three equivalent In(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 60-66°. In the second In site, In(2) is bonded to one O(10), one O(3), one O(4), one O(7), one O(8), and one O(9) atom to form InO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra, corners with two equivalent Ti(2)O6 octahedra, corners with two equivalent Fe(1)O6 octahedra, edges with three equivalent In(1)O6 octahedra, and edges with three equivalent In(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 57-65°. In the third In site, In(3) is bonded to one O(10), one O(3), one O(4), one O(7), one O(8), and one O(9) atom to form InO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra, corners with two equivalent Ti(2)O6 octahedra, corners with two equivalent Fe(1)O6 octahedra, edges with three equivalent In(1)O6 octahedra, and edges with three equivalent In(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 57-66°. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Ti(1), one Ti(2), and one Fe(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Ti(1), one Ti(2), and one Fe(1) atom. In the third O site, O(3) is bonded to one Fe(1), one In(1), one In(2), and one In(3) atom to form OIn3Fe tetrahedra that share  a cornercorner with one O(7)TiIn3 tetrahedra,  a cornercorner with one O(9)TiIn3 tetrahedra, corners with two equivalent O(10)In3Fe tetrahedra, corners with three equivalent O(4)TiIn3 tetrahedra, corners with three equivalent O(8)TiIn3 tetrahedra,  an edgeedge with one O(10)In3Fe tetrahedra,  an edgeedge with one O(7)TiIn3 tetrahedra, and  an edgeedge with one O(9)TiIn3 tetrahedra. In the fourth O site, O(4) is bonded to one Ti(1), one In(1), one In(2), and one In(3) atom to form distorted OTiIn3 tetrahedra that share  a cornercorner with one O(10)In3Fe tetrahedra,  a cornercorner with one O(8)TiIn3 tetrahedra, corners with two equivalent O(9)TiIn3 tetrahedra, corners with three equivalent O(3)In3Fe tetrahedra, corners with three equivalent O(7)TiIn3 tetrahedra,  an edgeedge with one O(10)In3Fe tetrahedra,  an edgeedge with one O(8)TiIn3 tetrahedra, and  an edgeedge with one O(9)TiIn3 tetrahedra. In the fifth O site, O(5) is bonded in a trigonal planar geometry to one Ti(1), one Ti(2), and one Fe(1) atom. In the sixth O site, O(6) is bonded in a trigonal planar geometry to one Ti(1), one Ti(2), and one Fe(1) atom. In the seventh O site, O(7) is bonded to one Ti(2), one In(1), one In(2), and one In(3) atom to form distorted OTiIn3 tetrahedra that share  a cornercorner with one O(3)In3Fe tetrahedra,  a cornercorner with one O(9)TiIn3 tetrahedra, corners with two equivalent O(8)TiIn3 tetrahedra, corners with three equivalent O(10)In3Fe tetrahedra, corners with three equivalent O(4)TiIn3 tetrahedra,  an edgeedge with one O(3)In3Fe tetrahedra,  an edgeedge with one O(8)TiIn3 tetrahedra, and  an edgeedge with one O(9)TiIn3 tetrahedra. In the eighth O site, O(8) is bonded to one Ti(2), one In(1), one In(2), and one In(3) atom to form OTiIn3 tetrahedra that share  a cornercorner with one O(10)In3Fe tetrahedra,  a cornercorner with one O(4)TiIn3 tetrahedra, corners with two equivalent O(7)TiIn3 tetrahedra, corners with three equivalent O(3)In3Fe tetrahedra, corners with three equivalent O(9)TiIn3 tetrahedra,  an edgeedge with one O(10)In3Fe tetrahedra,  an edgeedge with one O(4)TiIn3 tetrahedra, and  an edgeedge with one O(7)TiIn3 tetrahedra. In the ninth O site, O(9) is bonded to one Ti(1), one In(1), one In(2), and one In(3) atom to form distorted OTiIn3 tetrahedra that share  a cornercorner with one O(3)In3Fe tetrahedra,  a cornercorner with one O(7)TiIn3 tetrahedra, corners with two equivalent O(4)TiIn3 tetrahedra, corners with three equivalent O(10)In3Fe tetrahedra, corners with three equivalent O(8)TiIn3 tetrahedra,  an edgeedge with one O(3)In3Fe tetrahedra,  an edgeedge with one O(4)TiIn3 tetrahedra, and  an edgeedge with one O(7)TiIn3 tetrahedra. In the tenth O site, O(10) is bonded to one Fe(1), one In(1), one In(2), and one In(3) atom to form OIn3Fe tetrahedra that share  a cornercorner with one O(4)TiIn3 tetrahedra,  a cornercorner with one O(8)TiIn3 tetrahedra, corners with two equivalent O(3)In3Fe tetrahedra, corners with three equivalent O(7)TiIn3 tetrahedra, corners with three equivalent O(9)TiIn3 tetrahedra,  an edgeedge with one O(3)In3Fe tetrahedra,  an edgeedge with one O(4)TiIn3 tetrahedra, and  an edgeedge with one O(8)TiIn3 tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ti2In3FeO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.226
_cell_length_b   5.975
_cell_length_c   6.506
_cell_angle_alpha   72.261
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   378.626
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.155  0.303  0.491  1.0
  Ti  Ti1  1  0.655  0.697  0.509  1.0
  Ti  Ti2  1  0.501  0.256  0.500  1.0
  Ti  Ti3  1  0.001  0.744  0.500  1.0
  In  In4  1  0.998  0.250  0.998  1.0
  In  In5  1  0.498  0.750  0.002  1.0
  In  In6  1  0.668  0.229  0.002  1.0
  In  In7  1  0.168  0.771  0.998  1.0
  In  In8  1  0.333  0.270  0.997  1.0
  In  In9  1  0.833  0.730  0.003  1.0
  Fe  Fe10  1  0.844  0.193  0.506  1.0
  Fe  Fe11  1  0.344  0.807  0.494  1.0
  O  O12  1  0.541  0.944  0.498  1.0
  O  O13  1  0.041  0.056  0.502  1.0
  O  O14  1  0.462  0.555  0.501  1.0
  O  O15  1  0.962  0.445  0.499  1.0
  O  O16  1  0.333  0.891  0.167  1.0
  O  O17  1  0.833  0.109  0.833  1.0
  O  O18  1  0.666  0.612  0.829  1.0
  O  O19  1  0.166  0.388  0.171  1.0
  O  O20  1  0.816  0.858  0.501  1.0
  O  O21  1  0.316  0.142  0.499  1.0
  O  O22  1  0.180  0.627  0.497  1.0
  O  O23  1  0.680  0.373  0.503  1.0
  O  O24  1  0.001  0.863  0.170  1.0
  O  O25  1  0.501  0.137  0.830  1.0
  O  O26  1  0.001  0.640  0.832  1.0
  O  O27  1  0.501  0.360  0.168  1.0
  O  O28  1  0.666  0.830  0.172  1.0
  O  O29  1  0.166  0.170  0.828  1.0
  O  O30  1  0.333  0.665  0.831  1.0
  O  O31  1  0.833  0.335  0.169  1.0
[/CIF]
.