The material structure described by CNH3S(OCl)2 is alpha U structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four n,n-dichloromethanesulfonamide molecules. C(1) is bonded in a trigonal non-coplanar geometry to one H(2), two equivalent H(1), and one S(1) atom. N(1) is bonded in a trigonal non-coplanar geometry to one S(1) and two equivalent Cl(1) atoms. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. S(1) is bonded in a distorted tetrahedral geometry to one C(1), one N(1), and two equivalent O(1) atoms. O(1) is bonded in a single-bond geometry to one S(1) atom. Cl(1) is bonded in a single-bond geometry to one N(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_H3CSN(ClO)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.407
_cell_length_b   9.701
_cell_length_c   10.018
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   622.667
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.885  0.844  0.561  1.0
  H  H1  1  0.269  0.750  0.076  1.0
  H  H2  1  0.115  0.156  0.439  1.0
  H  H3  1  0.885  0.656  0.561  1.0
  H  H4  1  0.231  0.250  0.576  1.0
  H  H5  1  0.731  0.250  0.924  1.0
  H  H6  1  0.615  0.344  0.061  1.0
  H  H7  1  0.615  0.156  0.061  1.0
  H  H8  1  0.115  0.344  0.439  1.0
  H  H9  1  0.769  0.750  0.424  1.0
  H  H10  1  0.385  0.656  0.939  1.0
  H  H11  1  0.385  0.844  0.939  1.0
  C  C12  1  0.607  0.250  1.000  1.0
  C  C13  1  0.393  0.750  0.000  1.0
  C  C14  1  0.107  0.250  0.500  1.0
  C  C15  1  0.893  0.750  0.500  1.0
  S  S16  1  0.630  0.750  0.092  1.0
  S  S17  1  0.870  0.250  0.592  1.0
  S  S18  1  0.130  0.750  0.408  1.0
  S  S19  1  0.370  0.250  0.908  1.0
  N  N20  1  0.841  0.750  0.975  1.0
  N  N21  1  0.659  0.250  0.475  1.0
  N  N22  1  0.159  0.250  0.025  1.0
  N  N23  1  0.341  0.750  0.525  1.0
  Cl  Cl24  1  0.667  0.398  0.375  1.0
  Cl  Cl25  1  0.167  0.102  0.125  1.0
  Cl  Cl26  1  0.167  0.398  0.125  1.0
  Cl  Cl27  1  0.333  0.602  0.625  1.0
  Cl  Cl28  1  0.833  0.898  0.875  1.0
  Cl  Cl29  1  0.667  0.102  0.375  1.0
  Cl  Cl30  1  0.833  0.602  0.875  1.0
  Cl  Cl31  1  0.333  0.898  0.625  1.0
  O  O32  1  0.843  0.379  0.661  1.0
  O  O33  1  0.657  0.879  0.161  1.0
  O  O34  1  0.157  0.879  0.339  1.0
  O  O35  1  0.343  0.121  0.839  1.0
  O  O36  1  0.843  0.121  0.661  1.0
  O  O37  1  0.343  0.379  0.839  1.0
  O  O38  1  0.657  0.621  0.161  1.0
  O  O39  1  0.157  0.621  0.339  1.0
[/CIF]
.
The material structure described by CNH3S(OCl)2 is alpha U structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four n,n-dichloromethanesulfonamide molecules. C(1) is bonded in a trigonal non-coplanar geometry to one H(2), two equivalent H(1), and one S(1) atom. N(1) is bonded in a trigonal non-coplanar geometry to one S(1) and two equivalent Cl(1) atoms. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. S(1) is bonded in a distorted tetrahedral geometry to one C(1), one N(1), and two equivalent O(1) atoms. O(1) is bonded in a single-bond geometry to one S(1) atom. Cl(1) is bonded in a single-bond geometry to one N(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_H3CSN(ClO)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.407
_cell_length_b   9.701
_cell_length_c   10.018
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   622.667
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.885  0.844  0.561  1.0
  H  H1  1  0.269  0.750  0.076  1.0
  H  H2  1  0.115  0.156  0.439  1.0
  H  H3  1  0.885  0.656  0.561  1.0
  H  H4  1  0.231  0.250  0.576  1.0
  H  H5  1  0.731  0.250  0.924  1.0
  H  H6  1  0.615  0.344  0.061  1.0
  H  H7  1  0.615  0.156  0.061  1.0
  H  H8  1  0.115  0.344  0.439  1.0
  H  H9  1  0.769  0.750  0.424  1.0
  H  H10  1  0.385  0.656  0.939  1.0
  H  H11  1  0.385  0.844  0.939  1.0
  C  C12  1  0.607  0.250  1.000  1.0
  C  C13  1  0.393  0.750  0.000  1.0
  C  C14  1  0.107  0.250  0.500  1.0
  C  C15  1  0.893  0.750  0.500  1.0
  S  S16  1  0.630  0.750  0.092  1.0
  S  S17  1  0.870  0.250  0.592  1.0
  S  S18  1  0.130  0.750  0.408  1.0
  S  S19  1  0.370  0.250  0.908  1.0
  N  N20  1  0.841  0.750  0.975  1.0
  N  N21  1  0.659  0.250  0.475  1.0
  N  N22  1  0.159  0.250  0.025  1.0
  N  N23  1  0.341  0.750  0.525  1.0
  Cl  Cl24  1  0.667  0.398  0.375  1.0
  Cl  Cl25  1  0.167  0.102  0.125  1.0
  Cl  Cl26  1  0.167  0.398  0.125  1.0
  Cl  Cl27  1  0.333  0.602  0.625  1.0
  Cl  Cl28  1  0.833  0.898  0.875  1.0
  Cl  Cl29  1  0.667  0.102  0.375  1.0
  Cl  Cl30  1  0.833  0.602  0.875  1.0
  Cl  Cl31  1  0.333  0.898  0.625  1.0
  O  O32  1  0.843  0.379  0.661  1.0
  O  O33  1  0.657  0.879  0.161  1.0
  O  O34  1  0.157  0.879  0.339  1.0
  O  O35  1  0.343  0.121  0.839  1.0
  O  O36  1  0.843  0.121  0.661  1.0
  O  O37  1  0.343  0.379  0.839  1.0
  O  O38  1  0.657  0.621  0.161  1.0
  O  O39  1  0.157  0.621  0.339  1.0
[/CIF]
.