The crystal structure described by Nd2MoTe4O14 crystallizes in the triclinic P-1 space group. There are two inequivalent Nd sites. In the first Nd site, Nd(1) is bonded in a 8-coordinate geometry to one O(1), one O(10), one O(13), one O(14), one O(2), one O(3), one O(4), and one O(7) atom. In the second Nd site, Nd(2) is bonded in a 7-coordinate geometry to one O(1), one O(10), one O(13), one O(14), one O(2), one O(4), one O(8), and one O(9) atom. Mo(1) is bonded in a tetrahedral geometry to one O(11), one O(3), one O(6), and one O(7) atom. There are four inequivalent Te sites. In the first Te site, Te(1) is bonded in a distorted rectangular see-saw-like geometry to one O(12), one O(13), one O(14), and one O(4) atom. In the second Te site, Te(2) is bonded in a 4-coordinate geometry to one O(1), one O(10), one O(12), and one O(2) atom. In the third Te site, Te(3) is bonded in a distorted rectangular see-saw-like geometry to one O(10), one O(5), one O(6), and one O(9) atom. In the fourth Te site, Te(4) is bonded in a 4-coordinate geometry to one O(4), one O(5), one O(8), and one O(9) atom. There are fourteen inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Nd(1), one Nd(2), and one Te(2) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Nd(1), one Nd(2), and one Te(2) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Nd(1) and one Mo(1) atom. In the fourth O site, O(4) is bonded in a distorted rectangular see-saw-like geometry to one Nd(1), one Nd(2), one Te(1), and one Te(4) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Te(3) and one Te(4) atom. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Mo(1) and one Te(3) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one Nd(1) and one Mo(1) atom. In the eighth O site, O(8) is bonded in a linear geometry to one Nd(2) and one Te(4) atom. In the ninth O site, O(9) is bonded in a distorted trigonal non-coplanar geometry to one Nd(2), one Te(3), and one Te(4) atom. In the tenth O site, O(10) is bonded in a 4-coordinate geometry to one Nd(1), one Nd(2), one Te(2), and one Te(3) atom. In the eleventh O site, O(11) is bonded in a single-bond geometry to one Mo(1) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Te(1) and one Te(2) atom. In the thirteenth O site, O(13) is bonded in a distorted trigonal planar geometry to one Nd(1), one Nd(2), and one Te(1) atom. In the fourteenth O site, O(14) is bonded in a 3-coordinate geometry to one Nd(1), one Nd(2), and one Te(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Nd2Te4MoO14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.049
_cell_length_b   10.183
_cell_length_c   10.278
_cell_angle_alpha   90.167
_cell_angle_beta   107.178
_cell_angle_gamma   93.248
_symmetry_Int_Tables_number   1
_cell_volume   703.515
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Nd  Nd0  1  0.643  0.310  0.086  1.0
  Nd  Nd1  1  0.357  0.690  0.914  1.0
  Nd  Nd2  1  0.221  0.466  0.215  1.0
  Nd  Nd3  1  0.779  0.534  0.785  1.0
  Te  Te4  1  0.743  0.608  0.280  1.0
  Te  Te5  1  0.257  0.392  0.720  1.0
  Te  Te6  1  0.056  0.212  0.958  1.0
  Te  Te7  1  0.073  0.167  0.367  1.0
  Te  Te8  1  0.365  0.728  0.542  1.0
  Te  Te9  1  0.927  0.833  0.633  1.0
  Te  Te10  1  0.944  0.788  0.042  1.0
  Te  Te11  1  0.635  0.272  0.458  1.0
  Mo  Mo12  1  0.478  0.963  0.231  1.0
  Mo  Mo13  1  0.522  0.037  0.769  1.0
  O  O14  1  0.894  0.355  0.950  1.0
  O  O15  1  0.707  0.702  0.931  1.0
  O  O16  1  0.293  0.298  0.069  1.0
  O  O17  1  0.623  0.117  0.231  1.0
  O  O18  1  0.585  0.395  0.312  1.0
  O  O19  1  0.072  0.723  0.540  1.0
  O  O20  1  0.251  1.000  0.265  1.0
  O  O21  1  0.413  0.876  0.070  1.0
  O  O22  1  0.749  0.000  0.735  1.0
  O  O23  1  0.690  0.391  0.604  1.0
  O  O24  1  0.286  0.297  0.398  1.0
  O  O25  1  0.027  0.773  0.814  1.0
  O  O26  1  0.587  0.124  0.930  1.0
  O  O27  1  0.614  0.863  0.364  1.0
  O  O28  1  0.131  0.236  0.791  1.0
  O  O29  1  0.881  0.490  0.204  1.0
  O  O30  1  0.928  0.277  0.460  1.0
  O  O31  1  0.973  0.227  0.186  1.0
  O  O32  1  0.415  0.605  0.688  1.0
  O  O33  1  0.310  0.609  0.396  1.0
  O  O34  1  0.499  0.418  0.866  1.0
  O  O35  1  0.106  0.645  0.050  1.0
  O  O36  1  0.119  0.510  0.796  1.0
  O  O37  1  0.501  0.582  0.134  1.0
  O  O38  1  0.377  0.883  0.769  1.0
  O  O39  1  0.869  0.764  0.209  1.0
  O  O40  1  0.386  0.137  0.636  1.0
  O  O41  1  0.714  0.703  0.602  1.0
[/CIF]
.
The crystal structure described by Nd2MoTe4O14 crystallizes in the triclinic P-1 space group. There are two inequivalent Nd sites. In the first Nd site, Nd(1) is bonded in a 8-coordinate geometry to one O(1), one O(10), one O(13), one O(14), one O(2), one O(3), one O(4), and one O(7) atom. In the second Nd site, Nd(2) is bonded in a 7-coordinate geometry to one O(1), one O(10), one O(13), one O(14), one O(2), one O(4), one O(8), and one O(9) atom. Mo(1) is bonded in a tetrahedral geometry to one O(11), one O(3), one O(6), and one O(7) atom. There are four inequivalent Te sites. In the first Te site, Te(1) is bonded in a distorted rectangular see-saw-like geometry to one O(12), one O(13), one O(14), and one O(4) atom. In the second Te site, Te(2) is bonded in a 4-coordinate geometry to one O(1), one O(10), one O(12), and one O(2) atom. In the third Te site, Te(3) is bonded in a distorted rectangular see-saw-like geometry to one O(10), one O(5), one O(6), and one O(9) atom. In the fourth Te site, Te(4) is bonded in a 4-coordinate geometry to one O(4), one O(5), one O(8), and one O(9) atom. There are fourteen inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Nd(1), one Nd(2), and one Te(2) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Nd(1), one Nd(2), and one Te(2) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Nd(1) and one Mo(1) atom. In the fourth O site, O(4) is bonded in a distorted rectangular see-saw-like geometry to one Nd(1), one Nd(2), one Te(1), and one Te(4) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Te(3) and one Te(4) atom. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Mo(1) and one Te(3) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one Nd(1) and one Mo(1) atom. In the eighth O site, O(8) is bonded in a linear geometry to one Nd(2) and one Te(4) atom. In the ninth O site, O(9) is bonded in a distorted trigonal non-coplanar geometry to one Nd(2), one Te(3), and one Te(4) atom. In the tenth O site, O(10) is bonded in a 4-coordinate geometry to one Nd(1), one Nd(2), one Te(2), and one Te(3) atom. In the eleventh O site, O(11) is bonded in a single-bond geometry to one Mo(1) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Te(1) and one Te(2) atom. In the thirteenth O site, O(13) is bonded in a distorted trigonal planar geometry to one Nd(1), one Nd(2), and one Te(1) atom. In the fourteenth O site, O(14) is bonded in a 3-coordinate geometry to one Nd(1), one Nd(2), and one Te(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Nd2Te4MoO14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.049
_cell_length_b   10.183
_cell_length_c   10.278
_cell_angle_alpha   90.167
_cell_angle_beta   107.178
_cell_angle_gamma   93.248
_symmetry_Int_Tables_number   1
_cell_volume   703.515
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Nd  Nd0  1  0.643  0.310  0.086  1.0
  Nd  Nd1  1  0.357  0.690  0.914  1.0
  Nd  Nd2  1  0.221  0.466  0.215  1.0
  Nd  Nd3  1  0.779  0.534  0.785  1.0
  Te  Te4  1  0.743  0.608  0.280  1.0
  Te  Te5  1  0.257  0.392  0.720  1.0
  Te  Te6  1  0.056  0.212  0.958  1.0
  Te  Te7  1  0.073  0.167  0.367  1.0
  Te  Te8  1  0.365  0.728  0.542  1.0
  Te  Te9  1  0.927  0.833  0.633  1.0
  Te  Te10  1  0.944  0.788  0.042  1.0
  Te  Te11  1  0.635  0.272  0.458  1.0
  Mo  Mo12  1  0.478  0.963  0.231  1.0
  Mo  Mo13  1  0.522  0.037  0.769  1.0
  O  O14  1  0.894  0.355  0.950  1.0
  O  O15  1  0.707  0.702  0.931  1.0
  O  O16  1  0.293  0.298  0.069  1.0
  O  O17  1  0.623  0.117  0.231  1.0
  O  O18  1  0.585  0.395  0.312  1.0
  O  O19  1  0.072  0.723  0.540  1.0
  O  O20  1  0.251  1.000  0.265  1.0
  O  O21  1  0.413  0.876  0.070  1.0
  O  O22  1  0.749  0.000  0.735  1.0
  O  O23  1  0.690  0.391  0.604  1.0
  O  O24  1  0.286  0.297  0.398  1.0
  O  O25  1  0.027  0.773  0.814  1.0
  O  O26  1  0.587  0.124  0.930  1.0
  O  O27  1  0.614  0.863  0.364  1.0
  O  O28  1  0.131  0.236  0.791  1.0
  O  O29  1  0.881  0.490  0.204  1.0
  O  O30  1  0.928  0.277  0.460  1.0
  O  O31  1  0.973  0.227  0.186  1.0
  O  O32  1  0.415  0.605  0.688  1.0
  O  O33  1  0.310  0.609  0.396  1.0
  O  O34  1  0.499  0.418  0.866  1.0
  O  O35  1  0.106  0.645  0.050  1.0
  O  O36  1  0.119  0.510  0.796  1.0
  O  O37  1  0.501  0.582  0.134  1.0
  O  O38  1  0.377  0.883  0.769  1.0
  O  O39  1  0.869  0.764  0.209  1.0
  O  O40  1  0.386  0.137  0.636  1.0
  O  O41  1  0.714  0.703  0.602  1.0
[/CIF]
.