The structure described by CsAuF4 crystallizes in the orthorhombic Immm space group. Cs(1) is bonded in a 12-coordinate geometry to two equivalent F(1), four equivalent F(2), and six equivalent F(3) atoms. There are two inequivalent Au sites. In the first Au site, Au(1) is bonded in a square co-planar geometry to two equivalent F(1) and two equivalent F(2) atoms. In the second Au site, Au(2) is bonded in a square co-planar geometry to four equivalent F(3) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a distorted single-bond geometry to two equivalent Cs(1) and one Au(1) atom. In the second F site, F(2) is bonded in a distorted single-bond geometry to four equivalent Cs(1) and one Au(1) atom. In the third F site, F(3) is bonded in a 4-coordinate geometry to three equivalent Cs(1) and one Au(2) atom. is represented by the CIF file [CIF]
data_CsAuF4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.337
_cell_length_b   6.638
_cell_length_c   7.637
_cell_angle_alpha   115.770
_cell_angle_beta   110.460
_cell_angle_gamma   89.976
_symmetry_Int_Tables_number   1
_cell_volume   224.560
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.216  0.216  0.433  1.0
  Cs  Cs1  1  0.784  0.784  0.567  1.0
  Au  Au2  1  0.000  0.500  0.000  1.0
  Au  Au3  1  0.500  0.000  0.000  1.0
  F  F4  1  1.000  0.208  0.000  1.0
  F  F5  1  0.847  0.346  0.693  1.0
  F  F6  1  0.390  0.687  0.779  1.0
  F  F7  1  0.611  0.909  0.222  1.0
  F  F8  1  0.000  0.792  1.000  1.0
  F  F9  1  0.389  0.091  0.778  1.0
  F  F10  1  0.153  0.654  0.307  1.0
  F  F11  1  0.610  0.313  0.221  1.0
[/CIF]
.
The structure described by CsAuF4 crystallizes in the orthorhombic Immm space group. Cs(1) is bonded in a 12-coordinate geometry to two equivalent F(1), four equivalent F(2), and six equivalent F(3) atoms. There are two inequivalent Au sites. In the first Au site, Au(1) is bonded in a square co-planar geometry to two equivalent F(1) and two equivalent F(2) atoms. In the second Au site, Au(2) is bonded in a square co-planar geometry to four equivalent F(3) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a distorted single-bond geometry to two equivalent Cs(1) and one Au(1) atom. In the second F site, F(2) is bonded in a distorted single-bond geometry to four equivalent Cs(1) and one Au(1) atom. In the third F site, F(3) is bonded in a 4-coordinate geometry to three equivalent Cs(1) and one Au(2) atom. is represented by the CIF file [CIF]
data_CsAuF4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.337
_cell_length_b   6.638
_cell_length_c   7.637
_cell_angle_alpha   115.770
_cell_angle_beta   110.460
_cell_angle_gamma   89.976
_symmetry_Int_Tables_number   1
_cell_volume   224.560
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.216  0.216  0.433  1.0
  Cs  Cs1  1  0.784  0.784  0.567  1.0
  Au  Au2  1  0.000  0.500  0.000  1.0
  Au  Au3  1  0.500  0.000  0.000  1.0
  F  F4  1  1.000  0.208  0.000  1.0
  F  F5  1  0.847  0.346  0.693  1.0
  F  F6  1  0.390  0.687  0.779  1.0
  F  F7  1  0.611  0.909  0.222  1.0
  F  F8  1  0.000  0.792  1.000  1.0
  F  F9  1  0.389  0.091  0.778  1.0
  F  F10  1  0.153  0.654  0.307  1.0
  F  F11  1  0.610  0.313  0.221  1.0
[/CIF]
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