The crystal structure described by BiOF is Fluorite-derived structured and crystallizes in the monoclinic P2_1 space group. Bi(1) is bonded in a body-centered cubic geometry to four equivalent O(1) and four equivalent F(1) atoms. O(1) is bonded to four equivalent Bi(1) atoms to form OBi4 tetrahedra that share corners with four equivalent O(1)Bi4 tetrahedra, corners with twelve equivalent F(1)Bi4 tetrahedra, edges with two equivalent F(1)Bi4 tetrahedra, and edges with four equivalent O(1)Bi4 tetrahedra. F(1) is bonded to four equivalent Bi(1) atoms to form FBi4 tetrahedra that share corners with four equivalent F(1)Bi4 tetrahedra, corners with twelve equivalent O(1)Bi4 tetrahedra, edges with two equivalent O(1)Bi4 tetrahedra, and edges with four equivalent F(1)Bi4 tetrahedra. is represented by the CIF file [CIF]
data_BiOF
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.014
_cell_length_b   4.005
_cell_length_c   5.835
_cell_angle_alpha   89.993
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   93.826
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.256  0.752  0.283  1.0
  Bi  Bi1  1  0.756  0.248  0.717  1.0
  O  O2  1  0.253  0.249  0.501  1.0
  O  O3  1  0.753  0.751  0.499  1.0
  F  F4  1  0.247  0.242  0.002  1.0
  F  F5  1  0.747  0.758  0.998  1.0
[/CIF]
.
The crystal structure described by BiOF is Fluorite-derived structured and crystallizes in the monoclinic P2_1 space group. Bi(1) is bonded in a body-centered cubic geometry to four equivalent O(1) and four equivalent F(1) atoms. O(1) is bonded to four equivalent Bi(1) atoms to form OBi4 tetrahedra that share corners with four equivalent O(1)Bi4 tetrahedra, corners with twelve equivalent F(1)Bi4 tetrahedra, edges with two equivalent F(1)Bi4 tetrahedra, and edges with four equivalent O(1)Bi4 tetrahedra. F(1) is bonded to four equivalent Bi(1) atoms to form FBi4 tetrahedra that share corners with four equivalent F(1)Bi4 tetrahedra, corners with twelve equivalent O(1)Bi4 tetrahedra, edges with two equivalent O(1)Bi4 tetrahedra, and edges with four equivalent F(1)Bi4 tetrahedra. is represented by the CIF file [CIF]
data_BiOF
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.014
_cell_length_b   4.005
_cell_length_c   5.835
_cell_angle_alpha   89.993
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   93.826
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.256  0.752  0.283  1.0
  Bi  Bi1  1  0.756  0.248  0.717  1.0
  O  O2  1  0.253  0.249  0.501  1.0
  O  O3  1  0.753  0.751  0.499  1.0
  F  F4  1  0.247  0.242  0.002  1.0
  F  F5  1  0.747  0.758  0.998  1.0
[/CIF]
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