The crystal structure described by Ag2CNSO4Cl crystallizes in the monoclinic C2/c space group. There are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to one N(1), two equivalent S(1), one O(3), and one O(4) atom to form distorted AgS2NO2 trigonal bipyramids that share corners with two equivalent Cl(1)O4 tetrahedra and corners with two equivalent Ag(1)S2NO2 trigonal bipyramids. In the second Ag site, Ag(2) is bonded in a distorted square co-planar geometry to two equivalent N(1) and two equivalent O(1) atoms. In the third Ag site, Ag(3) is bonded in a distorted see-saw-like geometry to two equivalent S(1) and two equivalent O(2) atoms. C(1) is bonded in a linear geometry to one N(1) and one S(1) atom. N(1) is bonded in a 3-coordinate geometry to one Ag(1), one Ag(2), and one C(1) atom. S(1) is bonded to one Ag(3), two equivalent Ag(1), and one C(1) atom to form corner-sharing SAg3C tetrahedra. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one Ag(2) and one Cl(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Ag(3) and one Cl(1) atom. In the third O site, O(3) is bonded in a 1-coordinate geometry to one Ag(1) and one Cl(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Ag(1) and one Cl(1) atom. Cl(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form ClO4 tetrahedra that share corners with two equivalent Ag(1)S2NO2 trigonal bipyramids. is represented by the CIF file [CIF]
data_Ag2CSNClO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.067
_cell_length_b   8.067
_cell_length_c   18.424
_cell_angle_alpha   70.926
_cell_angle_beta   70.926
_cell_angle_gamma   34.701
_symmetry_Int_Tables_number   1
_cell_volume   641.284
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.858  0.408  0.868  1.0
  Ag  Ag1  1  0.592  0.142  0.632  1.0
  Ag  Ag2  1  0.408  0.858  0.368  1.0
  Ag  Ag3  1  0.142  0.592  0.132  1.0
  Ag  Ag4  1  0.500  0.000  0.500  1.0
  Ag  Ag5  1  0.215  0.785  0.750  1.0
  Ag  Ag6  1  0.785  0.215  0.250  1.0
  Ag  Ag7  1  0.000  0.500  0.000  1.0
  C  C8  1  0.789  0.270  0.066  1.0
  C  C9  1  0.730  0.211  0.434  1.0
  C  C10  1  0.211  0.730  0.934  1.0
  C  C11  1  0.270  0.789  0.566  1.0
  S  S12  1  0.300  0.834  0.858  1.0
  S  S13  1  0.834  0.300  0.358  1.0
  S  S14  1  0.166  0.700  0.642  1.0
  S  S15  1  0.700  0.166  0.142  1.0
  N  N16  1  0.852  0.344  0.012  1.0
  N  N17  1  0.344  0.852  0.512  1.0
  N  N18  1  0.656  0.148  0.488  1.0
  N  N19  1  0.148  0.656  0.988  1.0
  Cl  Cl20  1  0.870  0.492  0.657  1.0
  Cl  Cl21  1  0.508  0.130  0.843  1.0
  Cl  Cl22  1  0.130  0.508  0.343  1.0
  Cl  Cl23  1  0.492  0.870  0.157  1.0
  O  O24  1  0.549  0.973  0.919  1.0
  O  O25  1  0.333  0.835  0.171  1.0
  O  O26  1  0.451  0.027  0.081  1.0
  O  O27  1  0.575  0.809  0.660  1.0
  O  O28  1  0.425  0.191  0.340  1.0
  O  O29  1  0.972  0.608  0.283  1.0
  O  O30  1  0.028  0.392  0.717  1.0
  O  O31  1  0.835  0.333  0.671  1.0
  O  O32  1  0.027  0.451  0.581  1.0
  O  O33  1  0.809  0.575  0.160  1.0
  O  O34  1  0.608  0.972  0.783  1.0
  O  O35  1  0.392  0.028  0.217  1.0
  O  O36  1  0.667  0.165  0.829  1.0
  O  O37  1  0.165  0.667  0.329  1.0
  O  O38  1  0.973  0.549  0.419  1.0
  O  O39  1  0.191  0.425  0.840  1.0
[/CIF]
.
The crystal structure described by Ag2CNSO4Cl crystallizes in the monoclinic C2/c space group. There are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to one N(1), two equivalent S(1), one O(3), and one O(4) atom to form distorted AgS2NO2 trigonal bipyramids that share corners with two equivalent Cl(1)O4 tetrahedra and corners with two equivalent Ag(1)S2NO2 trigonal bipyramids. In the second Ag site, Ag(2) is bonded in a distorted square co-planar geometry to two equivalent N(1) and two equivalent O(1) atoms. In the third Ag site, Ag(3) is bonded in a distorted see-saw-like geometry to two equivalent S(1) and two equivalent O(2) atoms. C(1) is bonded in a linear geometry to one N(1) and one S(1) atom. N(1) is bonded in a 3-coordinate geometry to one Ag(1), one Ag(2), and one C(1) atom. S(1) is bonded to one Ag(3), two equivalent Ag(1), and one C(1) atom to form corner-sharing SAg3C tetrahedra. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one Ag(2) and one Cl(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Ag(3) and one Cl(1) atom. In the third O site, O(3) is bonded in a 1-coordinate geometry to one Ag(1) and one Cl(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Ag(1) and one Cl(1) atom. Cl(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form ClO4 tetrahedra that share corners with two equivalent Ag(1)S2NO2 trigonal bipyramids. is represented by the CIF file [CIF]
data_Ag2CSNClO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.067
_cell_length_b   8.067
_cell_length_c   18.424
_cell_angle_alpha   70.926
_cell_angle_beta   70.926
_cell_angle_gamma   34.701
_symmetry_Int_Tables_number   1
_cell_volume   641.284
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.858  0.408  0.868  1.0
  Ag  Ag1  1  0.592  0.142  0.632  1.0
  Ag  Ag2  1  0.408  0.858  0.368  1.0
  Ag  Ag3  1  0.142  0.592  0.132  1.0
  Ag  Ag4  1  0.500  0.000  0.500  1.0
  Ag  Ag5  1  0.215  0.785  0.750  1.0
  Ag  Ag6  1  0.785  0.215  0.250  1.0
  Ag  Ag7  1  0.000  0.500  0.000  1.0
  C  C8  1  0.789  0.270  0.066  1.0
  C  C9  1  0.730  0.211  0.434  1.0
  C  C10  1  0.211  0.730  0.934  1.0
  C  C11  1  0.270  0.789  0.566  1.0
  S  S12  1  0.300  0.834  0.858  1.0
  S  S13  1  0.834  0.300  0.358  1.0
  S  S14  1  0.166  0.700  0.642  1.0
  S  S15  1  0.700  0.166  0.142  1.0
  N  N16  1  0.852  0.344  0.012  1.0
  N  N17  1  0.344  0.852  0.512  1.0
  N  N18  1  0.656  0.148  0.488  1.0
  N  N19  1  0.148  0.656  0.988  1.0
  Cl  Cl20  1  0.870  0.492  0.657  1.0
  Cl  Cl21  1  0.508  0.130  0.843  1.0
  Cl  Cl22  1  0.130  0.508  0.343  1.0
  Cl  Cl23  1  0.492  0.870  0.157  1.0
  O  O24  1  0.549  0.973  0.919  1.0
  O  O25  1  0.333  0.835  0.171  1.0
  O  O26  1  0.451  0.027  0.081  1.0
  O  O27  1  0.575  0.809  0.660  1.0
  O  O28  1  0.425  0.191  0.340  1.0
  O  O29  1  0.972  0.608  0.283  1.0
  O  O30  1  0.028  0.392  0.717  1.0
  O  O31  1  0.835  0.333  0.671  1.0
  O  O32  1  0.027  0.451  0.581  1.0
  O  O33  1  0.809  0.575  0.160  1.0
  O  O34  1  0.608  0.972  0.783  1.0
  O  O35  1  0.392  0.028  0.217  1.0
  O  O36  1  0.667  0.165  0.829  1.0
  O  O37  1  0.165  0.667  0.329  1.0
  O  O38  1  0.973  0.549  0.419  1.0
  O  O39  1  0.191  0.425  0.840  1.0
[/CIF]
.