The material structure described by LiIn(MoO4)2 crystallizes in the monoclinic P2_1/c space group. Li(1) is bonded to one O(1), one O(2), one O(3), one O(4), and one O(7) atom to form distorted LiO5 trigonal bipyramids that share corners with two equivalent Mo(1)O4 tetrahedra, corners with three equivalent Mo(2)O4 tetrahedra, and  an edgeedge with one In(1)O6 octahedra. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one O(4), one O(5), one O(6), and one O(7) atom to form MoO4 tetrahedra that share corners with three equivalent In(1)O6 octahedra and corners with two equivalent Li(1)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 10-45°. In the second Mo site, Mo(2) is bonded to one O(1), one O(2), one O(3), and one O(8) atom to form MoO4 tetrahedra that share corners with three equivalent In(1)O6 octahedra and corners with three equivalent Li(1)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 47-50°. In(1) is bonded to one O(1), one O(5), one O(6), one O(7), and two equivalent O(8) atoms to form InO6 octahedra that share corners with three equivalent Mo(1)O4 tetrahedra, corners with three equivalent Mo(2)O4 tetrahedra,  an edgeedge with one In(1)O6 octahedra, and  an edgeedge with one Li(1)O5 trigonal bipyramid. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one Li(1), one Mo(2), and one In(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Li(1) and one Mo(2) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Li(1) and one Mo(2) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Li(1) and one Mo(1) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Mo(1) and one In(1) atom. In the sixth O site, O(6) is bonded in a linear geometry to one Mo(1) and one In(1) atom. In the seventh O site, O(7) is bonded in a distorted trigonal planar geometry to one Li(1), one Mo(1), and one In(1) atom. In the eighth O site, O(8) is bonded in a distorted trigonal planar geometry to one Mo(2) and two equivalent In(1) atoms. is represented by the CIF file [CIF]
data_LiIn(MoO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.164
_cell_length_b   7.265
_cell_length_c   13.082
_cell_angle_alpha   75.951
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   752.593
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.151  0.962  0.858  1.0
  Li  Li1  1  0.349  0.962  0.358  1.0
  Li  Li2  1  0.849  0.038  0.142  1.0
  Li  Li3  1  0.651  0.038  0.642  1.0
  In  In4  1  0.661  0.381  0.968  1.0
  In  In5  1  0.161  0.619  0.532  1.0
  In  In6  1  0.839  0.381  0.468  1.0
  In  In7  1  0.339  0.619  0.032  1.0
  Mo  Mo8  1  0.588  0.517  0.672  1.0
  Mo  Mo9  1  0.289  0.096  0.076  1.0
  Mo  Mo10  1  0.912  0.517  0.172  1.0
  Mo  Mo11  1  0.412  0.483  0.328  1.0
  Mo  Mo12  1  0.711  0.904  0.924  1.0
  Mo  Mo13  1  0.211  0.096  0.576  1.0
  Mo  Mo14  1  0.789  0.904  0.424  1.0
  Mo  Mo15  1  0.088  0.483  0.828  1.0
  O  O16  1  0.687  0.078  0.005  1.0
  O  O17  1  0.579  0.870  0.410  1.0
  O  O18  1  0.861  0.010  0.298  1.0
  O  O19  1  0.139  0.990  0.702  1.0
  O  O20  1  0.675  0.746  0.647  1.0
  O  O21  1  0.437  0.577  0.188  1.0
  O  O22  1  0.639  0.010  0.798  1.0
  O  O23  1  0.890  0.459  0.888  1.0
  O  O24  1  0.813  0.078  0.505  1.0
  O  O25  1  0.110  0.541  0.112  1.0
  O  O26  1  0.282  0.641  0.383  1.0
  O  O27  1  0.406  0.327  0.030  1.0
  O  O28  1  0.079  0.130  0.090  1.0
  O  O29  1  0.906  0.673  0.470  1.0
  O  O30  1  0.094  0.327  0.530  1.0
  O  O31  1  0.313  0.922  0.995  1.0
  O  O32  1  0.390  0.541  0.612  1.0
  O  O33  1  0.610  0.459  0.388  1.0
  O  O34  1  0.921  0.870  0.910  1.0
  O  O35  1  0.782  0.359  0.117  1.0
  O  O36  1  0.825  0.746  0.147  1.0
  O  O37  1  0.563  0.423  0.812  1.0
  O  O38  1  0.175  0.254  0.853  1.0
  O  O39  1  0.063  0.577  0.688  1.0
  O  O40  1  0.718  0.359  0.617  1.0
  O  O41  1  0.325  0.254  0.353  1.0
  O  O42  1  0.594  0.673  0.970  1.0
  O  O43  1  0.421  0.130  0.590  1.0
  O  O44  1  0.937  0.423  0.312  1.0
  O  O45  1  0.361  0.990  0.202  1.0
  O  O46  1  0.187  0.922  0.495  1.0
  O  O47  1  0.218  0.641  0.883  1.0
[/CIF]
.
The material structure described by LiIn(MoO4)2 crystallizes in the monoclinic P2_1/c space group. Li(1) is bonded to one O(1), one O(2), one O(3), one O(4), and one O(7) atom to form distorted LiO5 trigonal bipyramids that share corners with two equivalent Mo(1)O4 tetrahedra, corners with three equivalent Mo(2)O4 tetrahedra, and  an edgeedge with one In(1)O6 octahedra. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one O(4), one O(5), one O(6), and one O(7) atom to form MoO4 tetrahedra that share corners with three equivalent In(1)O6 octahedra and corners with two equivalent Li(1)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 10-45°. In the second Mo site, Mo(2) is bonded to one O(1), one O(2), one O(3), and one O(8) atom to form MoO4 tetrahedra that share corners with three equivalent In(1)O6 octahedra and corners with three equivalent Li(1)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 47-50°. In(1) is bonded to one O(1), one O(5), one O(6), one O(7), and two equivalent O(8) atoms to form InO6 octahedra that share corners with three equivalent Mo(1)O4 tetrahedra, corners with three equivalent Mo(2)O4 tetrahedra,  an edgeedge with one In(1)O6 octahedra, and  an edgeedge with one Li(1)O5 trigonal bipyramid. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one Li(1), one Mo(2), and one In(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Li(1) and one Mo(2) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Li(1) and one Mo(2) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Li(1) and one Mo(1) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Mo(1) and one In(1) atom. In the sixth O site, O(6) is bonded in a linear geometry to one Mo(1) and one In(1) atom. In the seventh O site, O(7) is bonded in a distorted trigonal planar geometry to one Li(1), one Mo(1), and one In(1) atom. In the eighth O site, O(8) is bonded in a distorted trigonal planar geometry to one Mo(2) and two equivalent In(1) atoms. is represented by the CIF file [CIF]
data_LiIn(MoO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.164
_cell_length_b   7.265
_cell_length_c   13.082
_cell_angle_alpha   75.951
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   752.593
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.151  0.962  0.858  1.0
  Li  Li1  1  0.349  0.962  0.358  1.0
  Li  Li2  1  0.849  0.038  0.142  1.0
  Li  Li3  1  0.651  0.038  0.642  1.0
  In  In4  1  0.661  0.381  0.968  1.0
  In  In5  1  0.161  0.619  0.532  1.0
  In  In6  1  0.839  0.381  0.468  1.0
  In  In7  1  0.339  0.619  0.032  1.0
  Mo  Mo8  1  0.588  0.517  0.672  1.0
  Mo  Mo9  1  0.289  0.096  0.076  1.0
  Mo  Mo10  1  0.912  0.517  0.172  1.0
  Mo  Mo11  1  0.412  0.483  0.328  1.0
  Mo  Mo12  1  0.711  0.904  0.924  1.0
  Mo  Mo13  1  0.211  0.096  0.576  1.0
  Mo  Mo14  1  0.789  0.904  0.424  1.0
  Mo  Mo15  1  0.088  0.483  0.828  1.0
  O  O16  1  0.687  0.078  0.005  1.0
  O  O17  1  0.579  0.870  0.410  1.0
  O  O18  1  0.861  0.010  0.298  1.0
  O  O19  1  0.139  0.990  0.702  1.0
  O  O20  1  0.675  0.746  0.647  1.0
  O  O21  1  0.437  0.577  0.188  1.0
  O  O22  1  0.639  0.010  0.798  1.0
  O  O23  1  0.890  0.459  0.888  1.0
  O  O24  1  0.813  0.078  0.505  1.0
  O  O25  1  0.110  0.541  0.112  1.0
  O  O26  1  0.282  0.641  0.383  1.0
  O  O27  1  0.406  0.327  0.030  1.0
  O  O28  1  0.079  0.130  0.090  1.0
  O  O29  1  0.906  0.673  0.470  1.0
  O  O30  1  0.094  0.327  0.530  1.0
  O  O31  1  0.313  0.922  0.995  1.0
  O  O32  1  0.390  0.541  0.612  1.0
  O  O33  1  0.610  0.459  0.388  1.0
  O  O34  1  0.921  0.870  0.910  1.0
  O  O35  1  0.782  0.359  0.117  1.0
  O  O36  1  0.825  0.746  0.147  1.0
  O  O37  1  0.563  0.423  0.812  1.0
  O  O38  1  0.175  0.254  0.853  1.0
  O  O39  1  0.063  0.577  0.688  1.0
  O  O40  1  0.718  0.359  0.617  1.0
  O  O41  1  0.325  0.254  0.353  1.0
  O  O42  1  0.594  0.673  0.970  1.0
  O  O43  1  0.421  0.130  0.590  1.0
  O  O44  1  0.937  0.423  0.312  1.0
  O  O45  1  0.361  0.990  0.202  1.0
  O  O46  1  0.187  0.922  0.495  1.0
  O  O47  1  0.218  0.641  0.883  1.0
[/CIF]
.