The crystal structure described by CsTh(MoO4)2Cl crystallizes in the monoclinic P2_1/c space group. Cs(1) is bonded in a 9-coordinate geometry to one O(4), one O(5), one O(6), one O(7), one O(8), and four equivalent Cl(1) atoms. Th(1) is bonded in a 8-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), one O(6), one O(7), and one Cl(1) atom. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(4), and one O(5) atom. In the second Mo site, Mo(2) is bonded in a tetrahedral geometry to one O(3), one O(6), one O(7), and one O(8) atom. There are eight inequivalent O sites. In the first O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Cs(1), one Th(1), and one Mo(1) atom. In the second O site, O(5) is bonded in a 3-coordinate geometry to one Cs(1), one Th(1), and one Mo(1) atom. In the third O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Cs(1), one Th(1), and one Mo(2) atom. In the fourth O site, O(7) is bonded in a 3-coordinate geometry to one Cs(1), one Th(1), and one Mo(2) atom. In the fifth O site, O(8) is bonded in a single-bond geometry to one Cs(1) and one Mo(2) atom. In the sixth O site, O(1) is bonded in a distorted linear geometry to one Th(1) and one Mo(1) atom. In the seventh O site, O(2) is bonded in a linear geometry to one Th(1) and one Mo(1) atom. In the eighth O site, O(3) is bonded in a bent 150 degrees geometry to one Th(1) and one Mo(2) atom. Cl(1) is bonded in a 5-coordinate geometry to four equivalent Cs(1) and one Th(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CsThMo2ClO8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.192
_cell_length_b   9.818
_cell_length_c   10.349
_cell_angle_alpha   84.111
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1030.046
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.276  0.994  0.517  1.0
  Cs  Cs1  1  0.776  0.506  0.483  1.0
  Cs  Cs2  1  0.724  0.006  0.483  1.0
  Cs  Cs3  1  0.224  0.494  0.517  1.0
  Th  Th4  1  0.466  0.696  0.169  1.0
  Th  Th5  1  0.966  0.804  0.831  1.0
  Th  Th6  1  0.534  0.304  0.831  1.0
  Th  Th7  1  0.034  0.196  0.169  1.0
  Mo  Mo8  1  0.777  0.504  0.082  1.0
  Mo  Mo9  1  0.277  0.996  0.918  1.0
  Mo  Mo10  1  0.223  0.496  0.918  1.0
  Mo  Mo11  1  0.723  0.004  0.082  1.0
  Mo  Mo12  1  0.091  0.790  0.207  1.0
  Mo  Mo13  1  0.591  0.710  0.793  1.0
  Mo  Mo14  1  0.909  0.210  0.793  1.0
  Mo  Mo15  1  0.409  0.290  0.207  1.0
  Cl  Cl16  1  0.005  0.772  0.564  1.0
  Cl  Cl17  1  0.505  0.728  0.436  1.0
  Cl  Cl18  1  0.995  0.228  0.436  1.0
  Cl  Cl19  1  0.495  0.272  0.564  1.0
  O  O20  1  0.330  0.595  0.007  1.0
  O  O21  1  0.830  0.905  0.993  1.0
  O  O22  1  0.670  0.405  0.993  1.0
  O  O23  1  0.170  0.095  0.007  1.0
  O  O24  1  0.370  0.884  0.033  1.0
  O  O25  1  0.870  0.616  0.967  1.0
  O  O26  1  0.630  0.116  0.967  1.0
  O  O27  1  0.130  0.384  0.033  1.0
  O  O28  1  0.085  0.798  0.032  1.0
  O  O29  1  0.585  0.702  0.968  1.0
  O  O30  1  0.915  0.202  0.968  1.0
  O  O31  1  0.415  0.298  0.032  1.0
  O  O32  1  0.612  0.890  0.175  1.0
  O  O33  1  0.112  0.610  0.825  1.0
  O  O34  1  0.388  0.110  0.825  1.0
  O  O35  1  0.888  0.390  0.175  1.0
  O  O36  1  0.681  0.588  0.198  1.0
  O  O37  1  0.181  0.912  0.802  1.0
  O  O38  1  0.319  0.412  0.802  1.0
  O  O39  1  0.819  0.088  0.198  1.0
  O  O40  1  0.071  0.963  0.254  1.0
  O  O41  1  0.571  0.537  0.746  1.0
  O  O42  1  0.929  0.037  0.746  1.0
  O  O43  1  0.429  0.463  0.254  1.0
  O  O44  1  0.250  0.719  0.262  1.0
  O  O45  1  0.750  0.781  0.738  1.0
  O  O46  1  0.750  0.281  0.738  1.0
  O  O47  1  0.250  0.219  0.262  1.0
  O  O48  1  0.466  0.820  0.731  1.0
  O  O49  1  0.966  0.680  0.269  1.0
  O  O50  1  0.534  0.180  0.269  1.0
  O  O51  1  0.034  0.320  0.731  1.0
[/CIF]
.
The crystal structure described by CsTh(MoO4)2Cl crystallizes in the monoclinic P2_1/c space group. Cs(1) is bonded in a 9-coordinate geometry to one O(4), one O(5), one O(6), one O(7), one O(8), and four equivalent Cl(1) atoms. Th(1) is bonded in a 8-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), one O(6), one O(7), and one Cl(1) atom. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(4), and one O(5) atom. In the second Mo site, Mo(2) is bonded in a tetrahedral geometry to one O(3), one O(6), one O(7), and one O(8) atom. There are eight inequivalent O sites. In the first O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Cs(1), one Th(1), and one Mo(1) atom. In the second O site, O(5) is bonded in a 3-coordinate geometry to one Cs(1), one Th(1), and one Mo(1) atom. In the third O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Cs(1), one Th(1), and one Mo(2) atom. In the fourth O site, O(7) is bonded in a 3-coordinate geometry to one Cs(1), one Th(1), and one Mo(2) atom. In the fifth O site, O(8) is bonded in a single-bond geometry to one Cs(1) and one Mo(2) atom. In the sixth O site, O(1) is bonded in a distorted linear geometry to one Th(1) and one Mo(1) atom. In the seventh O site, O(2) is bonded in a linear geometry to one Th(1) and one Mo(1) atom. In the eighth O site, O(3) is bonded in a bent 150 degrees geometry to one Th(1) and one Mo(2) atom. Cl(1) is bonded in a 5-coordinate geometry to four equivalent Cs(1) and one Th(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CsThMo2ClO8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.192
_cell_length_b   9.818
_cell_length_c   10.349
_cell_angle_alpha   84.111
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1030.046
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.276  0.994  0.517  1.0
  Cs  Cs1  1  0.776  0.506  0.483  1.0
  Cs  Cs2  1  0.724  0.006  0.483  1.0
  Cs  Cs3  1  0.224  0.494  0.517  1.0
  Th  Th4  1  0.466  0.696  0.169  1.0
  Th  Th5  1  0.966  0.804  0.831  1.0
  Th  Th6  1  0.534  0.304  0.831  1.0
  Th  Th7  1  0.034  0.196  0.169  1.0
  Mo  Mo8  1  0.777  0.504  0.082  1.0
  Mo  Mo9  1  0.277  0.996  0.918  1.0
  Mo  Mo10  1  0.223  0.496  0.918  1.0
  Mo  Mo11  1  0.723  0.004  0.082  1.0
  Mo  Mo12  1  0.091  0.790  0.207  1.0
  Mo  Mo13  1  0.591  0.710  0.793  1.0
  Mo  Mo14  1  0.909  0.210  0.793  1.0
  Mo  Mo15  1  0.409  0.290  0.207  1.0
  Cl  Cl16  1  0.005  0.772  0.564  1.0
  Cl  Cl17  1  0.505  0.728  0.436  1.0
  Cl  Cl18  1  0.995  0.228  0.436  1.0
  Cl  Cl19  1  0.495  0.272  0.564  1.0
  O  O20  1  0.330  0.595  0.007  1.0
  O  O21  1  0.830  0.905  0.993  1.0
  O  O22  1  0.670  0.405  0.993  1.0
  O  O23  1  0.170  0.095  0.007  1.0
  O  O24  1  0.370  0.884  0.033  1.0
  O  O25  1  0.870  0.616  0.967  1.0
  O  O26  1  0.630  0.116  0.967  1.0
  O  O27  1  0.130  0.384  0.033  1.0
  O  O28  1  0.085  0.798  0.032  1.0
  O  O29  1  0.585  0.702  0.968  1.0
  O  O30  1  0.915  0.202  0.968  1.0
  O  O31  1  0.415  0.298  0.032  1.0
  O  O32  1  0.612  0.890  0.175  1.0
  O  O33  1  0.112  0.610  0.825  1.0
  O  O34  1  0.388  0.110  0.825  1.0
  O  O35  1  0.888  0.390  0.175  1.0
  O  O36  1  0.681  0.588  0.198  1.0
  O  O37  1  0.181  0.912  0.802  1.0
  O  O38  1  0.319  0.412  0.802  1.0
  O  O39  1  0.819  0.088  0.198  1.0
  O  O40  1  0.071  0.963  0.254  1.0
  O  O41  1  0.571  0.537  0.746  1.0
  O  O42  1  0.929  0.037  0.746  1.0
  O  O43  1  0.429  0.463  0.254  1.0
  O  O44  1  0.250  0.719  0.262  1.0
  O  O45  1  0.750  0.781  0.738  1.0
  O  O46  1  0.750  0.281  0.738  1.0
  O  O47  1  0.250  0.219  0.262  1.0
  O  O48  1  0.466  0.820  0.731  1.0
  O  O49  1  0.966  0.680  0.269  1.0
  O  O50  1  0.534  0.180  0.269  1.0
  O  O51  1  0.034  0.320  0.731  1.0
[/CIF]
.