The compound described by LiVO2 is Caswellsilverite structured and crystallizes in the monoclinic Pc space group. Li(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form LiO6 octahedra that share corners with six equivalent V(1)O6 octahedra, edges with six equivalent Li(1)O6 octahedra, and edges with six equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-4°. V(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form VO6 octahedra that share corners with six equivalent Li(1)O6 octahedra, edges with six equivalent Li(1)O6 octahedra, and edges with six equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-4°. There are two inequivalent O sites. In the first O site, O(1) is bonded to three equivalent Li(1) and three equivalent V(1) atoms to form a mixture of corner and edge-sharing OLi3V3 octahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the second O site, O(2) is bonded to three equivalent Li(1) and three equivalent V(1) atoms to form a mixture of corner and edge-sharing OLi3V3 octahedra. The corner-sharing octahedral tilt angles range from 0-2°. is represented by the CIF file [CIF]
data_LiVO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.881
_cell_length_b   2.882
_cell_length_c   5.114
_cell_angle_alpha   74.351
_cell_angle_beta   74.373
_cell_angle_gamma   60.428
_symmetry_Int_Tables_number   1
_cell_volume   35.089
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.000  1.000  1.000  1.0
  O  O1  1  0.751  0.752  0.735  1.0
  O  O2  1  0.248  0.248  0.265  1.0
  V  V3  1  0.500  0.500  0.500  1.0
[/CIF]
.
The compound described by LiVO2 is Caswellsilverite structured and crystallizes in the monoclinic Pc space group. Li(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form LiO6 octahedra that share corners with six equivalent V(1)O6 octahedra, edges with six equivalent Li(1)O6 octahedra, and edges with six equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-4°. V(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form VO6 octahedra that share corners with six equivalent Li(1)O6 octahedra, edges with six equivalent Li(1)O6 octahedra, and edges with six equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-4°. There are two inequivalent O sites. In the first O site, O(1) is bonded to three equivalent Li(1) and three equivalent V(1) atoms to form a mixture of corner and edge-sharing OLi3V3 octahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the second O site, O(2) is bonded to three equivalent Li(1) and three equivalent V(1) atoms to form a mixture of corner and edge-sharing OLi3V3 octahedra. The corner-sharing octahedral tilt angles range from 0-2°. is represented by the CIF file [CIF]
data_LiVO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.881
_cell_length_b   2.882
_cell_length_c   5.114
_cell_angle_alpha   74.351
_cell_angle_beta   74.373
_cell_angle_gamma   60.428
_symmetry_Int_Tables_number   1
_cell_volume   35.089
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.000  1.000  1.000  1.0
  O  O1  1  0.751  0.752  0.735  1.0
  O  O2  1  0.248  0.248  0.265  1.0
  V  V3  1  0.500  0.500  0.500  1.0
[/CIF]
.