The structure described by Co6O7F5 is Hydrophilite-derived structured and crystallizes in the monoclinic Pm space group. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(1), one O(2), one O(4), one F(1), one F(3), and one F(4) atom to form CoO3F3 octahedra that share corners with four equivalent Co(3)O4F2 octahedra, corners with four equivalent Co(4)O4F2 octahedra,  an edgeedge with one Co(1)O3F3 octahedra, and  an edgeedge with one Co(2)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 49-55°. In the second Co site, Co(2) is bonded to one O(3), two equivalent O(1), one F(2), and two equivalent F(4) atoms to form CoO3F3 octahedra that share corners with eight equivalent Co(4)O4F2 octahedra and edges with two equivalent Co(1)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 41-53°. In the third Co site, Co(3) is bonded to two equivalent O(2), two equivalent O(4), one F(1), and one F(3) atom to form CoO4F2 octahedra that share corners with eight equivalent Co(1)O3F3 octahedra and edges with two equivalent Co(4)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 49-50°. In the fourth Co site, Co(4) is bonded to one O(1), one O(2), one O(3), one O(4), one F(2), and one F(4) atom to form CoO4F2 octahedra that share corners with four equivalent Co(1)O3F3 octahedra, corners with four equivalent Co(2)O3F3 octahedra,  an edgeedge with one Co(3)O4F2 octahedra, and  an edgeedge with one Co(4)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 41-55°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Co(1), one Co(2), and one Co(4) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Co(1), one Co(3), and one Co(4) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Co(2) and two equivalent Co(4) atoms. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one Co(1), one Co(3), and one Co(4) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a trigonal planar geometry to one Co(3) and two equivalent Co(1) atoms. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one Co(2) and two equivalent Co(4) atoms. In the third F site, F(3) is bonded in a trigonal planar geometry to one Co(3) and two equivalent Co(1) atoms. In the fourth F site, F(4) is bonded in a distorted T-shaped geometry to one Co(1), one Co(2), and one Co(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Co6O7F5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.945
_cell_length_b   4.537
_cell_length_c   4.554
_cell_angle_alpha   85.801
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   184.321
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.174  0.984  0.992  1.0
  Co  Co1  1  0.826  0.984  0.992  1.0
  Co  Co2  1  0.500  0.010  0.962  1.0
  Co  Co3  1  0.000  0.487  0.496  1.0
  Co  Co4  1  0.329  0.514  0.526  1.0
  Co  Co5  1  0.671  0.514  0.526  1.0
  O  O6  1  0.340  0.815  0.808  1.0
  O  O7  1  0.660  0.815  0.808  1.0
  O  O8  1  0.835  0.301  0.697  1.0
  O  O9  1  0.165  0.301  0.697  1.0
  O  O10  1  0.500  0.317  0.696  1.0
  O  O11  1  0.165  0.687  0.311  1.0
  O  O12  1  0.835  0.687  0.311  1.0
  F  F13  1  0.000  0.790  0.800  1.0
  F  F14  1  0.500  0.714  0.301  1.0
  F  F15  1  0.000  0.176  0.186  1.0
  F  F16  1  0.343  0.203  0.196  1.0
  F  F17  1  0.657  0.203  0.196  1.0
[/CIF]
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The structure described by Co6O7F5 is Hydrophilite-derived structured and crystallizes in the monoclinic Pm space group. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(1), one O(2), one O(4), one F(1), one F(3), and one F(4) atom to form CoO3F3 octahedra that share corners with four equivalent Co(3)O4F2 octahedra, corners with four equivalent Co(4)O4F2 octahedra,  an edgeedge with one Co(1)O3F3 octahedra, and  an edgeedge with one Co(2)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 49-55°. In the second Co site, Co(2) is bonded to one O(3), two equivalent O(1), one F(2), and two equivalent F(4) atoms to form CoO3F3 octahedra that share corners with eight equivalent Co(4)O4F2 octahedra and edges with two equivalent Co(1)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 41-53°. In the third Co site, Co(3) is bonded to two equivalent O(2), two equivalent O(4), one F(1), and one F(3) atom to form CoO4F2 octahedra that share corners with eight equivalent Co(1)O3F3 octahedra and edges with two equivalent Co(4)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 49-50°. In the fourth Co site, Co(4) is bonded to one O(1), one O(2), one O(3), one O(4), one F(2), and one F(4) atom to form CoO4F2 octahedra that share corners with four equivalent Co(1)O3F3 octahedra, corners with four equivalent Co(2)O3F3 octahedra,  an edgeedge with one Co(3)O4F2 octahedra, and  an edgeedge with one Co(4)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 41-55°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Co(1), one Co(2), and one Co(4) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Co(1), one Co(3), and one Co(4) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Co(2) and two equivalent Co(4) atoms. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one Co(1), one Co(3), and one Co(4) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a trigonal planar geometry to one Co(3) and two equivalent Co(1) atoms. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one Co(2) and two equivalent Co(4) atoms. In the third F site, F(3) is bonded in a trigonal planar geometry to one Co(3) and two equivalent Co(1) atoms. In the fourth F site, F(4) is bonded in a distorted T-shaped geometry to one Co(1), one Co(2), and one Co(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Co6O7F5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.945
_cell_length_b   4.537
_cell_length_c   4.554
_cell_angle_alpha   85.801
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   184.321
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.174  0.984  0.992  1.0
  Co  Co1  1  0.826  0.984  0.992  1.0
  Co  Co2  1  0.500  0.010  0.962  1.0
  Co  Co3  1  0.000  0.487  0.496  1.0
  Co  Co4  1  0.329  0.514  0.526  1.0
  Co  Co5  1  0.671  0.514  0.526  1.0
  O  O6  1  0.340  0.815  0.808  1.0
  O  O7  1  0.660  0.815  0.808  1.0
  O  O8  1  0.835  0.301  0.697  1.0
  O  O9  1  0.165  0.301  0.697  1.0
  O  O10  1  0.500  0.317  0.696  1.0
  O  O11  1  0.165  0.687  0.311  1.0
  O  O12  1  0.835  0.687  0.311  1.0
  F  F13  1  0.000  0.790  0.800  1.0
  F  F14  1  0.500  0.714  0.301  1.0
  F  F15  1  0.000  0.176  0.186  1.0
  F  F16  1  0.343  0.203  0.196  1.0
  F  F17  1  0.657  0.203  0.196  1.0
[/CIF]
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