The compound described by Mn6OF11 is Hydrophilite-derived structured and crystallizes in the monoclinic Cm space group. There are six inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one F(4), one F(7), two equivalent F(1), and two equivalent F(8) atoms to form MnF6 octahedra that share corners with two equivalent Mn(3)OF5 octahedra, corners with three equivalent Mn(6)F6 octahedra, corners with three equivalent Mn(2)OF5 octahedra,  an edgeedge with one Mn(5)F6 octahedra, and  an edgeedge with one Mn(4)OF5 octahedra. The corner-sharing octahedral tilt angles range from 47-56°. In the second Mn site, Mn(2) is bonded to one O(1), one F(4), one F(5), one F(6), and two equivalent F(1) atoms to form MnOF5 octahedra that share corners with two equivalent Mn(4)OF5 octahedra, corners with three equivalent Mn(1)F6 octahedra, corners with three equivalent Mn(5)F6 octahedra,  an edgeedge with one Mn(6)F6 octahedra, and  an edgeedge with one Mn(3)OF5 octahedra. The corner-sharing octahedral tilt angles range from 47-56°. In the third Mn site, Mn(3) is bonded to one O(1), one F(3), one F(4), one F(7), and two equivalent F(2) atoms to form MnOF5 octahedra that share corners with two equivalent Mn(1)F6 octahedra, corners with three equivalent Mn(5)F6 octahedra, corners with three equivalent Mn(4)OF5 octahedra,  an edgeedge with one Mn(6)F6 octahedra, and  an edgeedge with one Mn(2)OF5 octahedra. The corner-sharing octahedral tilt angles range from 47-56°. In the fourth Mn site, Mn(4) is bonded to one O(1), one F(5), two equivalent F(2), and two equivalent F(8) atoms to form MnOF5 octahedra that share corners with two equivalent Mn(2)OF5 octahedra, corners with three equivalent Mn(6)F6 octahedra, corners with three equivalent Mn(3)OF5 octahedra,  an edgeedge with one Mn(1)F6 octahedra, and  an edgeedge with one Mn(5)F6 octahedra. The corner-sharing octahedral tilt angles range from 47-51°. In the fifth Mn site, Mn(5) is bonded to one F(3), one F(6), two equivalent F(1), and two equivalent F(2) atoms to form MnF6 octahedra that share corners with two equivalent Mn(6)F6 octahedra, corners with three equivalent Mn(2)OF5 octahedra, corners with three equivalent Mn(3)OF5 octahedra,  an edgeedge with one Mn(1)F6 octahedra, and  an edgeedge with one Mn(4)OF5 octahedra. The corner-sharing octahedral tilt angles range from 48-56°. In the sixth Mn site, Mn(6) is bonded to one F(3), one F(5), one F(6), one F(7), and two equivalent F(8) atoms to form MnF6 octahedra that share corners with two equivalent Mn(5)F6 octahedra, corners with three equivalent Mn(1)F6 octahedra, corners with three equivalent Mn(4)OF5 octahedra,  an edgeedge with one Mn(2)OF5 octahedra, and  an edgeedge with one Mn(3)OF5 octahedra. The corner-sharing octahedral tilt angles range from 49-56°. O(1) is bonded in a distorted trigonal planar geometry to one Mn(2), one Mn(3), and one Mn(4) atom. There are eight inequivalent F sites. In the first F site, F(1) is bonded in a trigonal planar geometry to one Mn(1), one Mn(2), and one Mn(5) atom. In the second F site, F(2) is bonded in a trigonal planar geometry to one Mn(3), one Mn(4), and one Mn(5) atom. In the third F site, F(3) is bonded in a trigonal planar geometry to one Mn(3), one Mn(5), and one Mn(6) atom. In the fourth F site, F(4) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(2), and one Mn(3) atom. In the fifth F site, F(5) is bonded in a distorted trigonal planar geometry to one Mn(2), one Mn(4), and one Mn(6) atom. In the sixth F site, F(6) is bonded in a trigonal planar geometry to one Mn(2), one Mn(5), and one Mn(6) atom. In the seventh F site, F(7) is bonded in a trigonal planar geometry to one Mn(1), one Mn(3), and one Mn(6) atom. In the eighth F site, F(8) is bonded in a trigonal planar geometry to one Mn(1), one Mn(4), and one Mn(6) atom. is represented by the CIF card [CIF]
data_Mn6OF11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.916
_cell_length_b   5.916
_cell_length_c   7.627
_cell_angle_alpha   74.057
_cell_angle_beta   74.057
_cell_angle_gamma   72.747
_symmetry_Int_Tables_number   1
_cell_volume   239.651
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.333  0.333  0.167  1.0
  Mn  Mn1  1  0.663  0.663  0.352  1.0
  Mn  Mn2  1  0.347  0.347  0.671  1.0
  Mn  Mn3  1  0.660  0.660  0.821  1.0
  Mn  Mn4  1  0.003  0.003  0.501  1.0
  Mn  Mn5  1  0.996  0.996  0.995  1.0
  O  O6  1  0.569  0.569  0.640  1.0
  F  F7  1  0.970  0.363  0.330  1.0
  F  F8  1  0.639  0.022  0.671  1.0
  F  F9  1  0.111  0.111  0.700  1.0
  F  F10  1  0.433  0.433  0.373  1.0
  F  F11  1  0.759  0.759  0.028  1.0
  F  F12  1  0.900  0.900  0.292  1.0
  F  F13  1  0.229  0.229  0.966  1.0
  F  F14  1  0.022  0.639  0.671  1.0
  F  F15  1  0.363  0.970  0.330  1.0
  F  F16  1  0.696  0.308  0.996  1.0
  F  F17  1  0.308  0.696  0.996  1.0
[/CIF]
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The compound described by Mn6OF11 is Hydrophilite-derived structured and crystallizes in the monoclinic Cm space group. There are six inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one F(4), one F(7), two equivalent F(1), and two equivalent F(8) atoms to form MnF6 octahedra that share corners with two equivalent Mn(3)OF5 octahedra, corners with three equivalent Mn(6)F6 octahedra, corners with three equivalent Mn(2)OF5 octahedra,  an edgeedge with one Mn(5)F6 octahedra, and  an edgeedge with one Mn(4)OF5 octahedra. The corner-sharing octahedral tilt angles range from 47-56°. In the second Mn site, Mn(2) is bonded to one O(1), one F(4), one F(5), one F(6), and two equivalent F(1) atoms to form MnOF5 octahedra that share corners with two equivalent Mn(4)OF5 octahedra, corners with three equivalent Mn(1)F6 octahedra, corners with three equivalent Mn(5)F6 octahedra,  an edgeedge with one Mn(6)F6 octahedra, and  an edgeedge with one Mn(3)OF5 octahedra. The corner-sharing octahedral tilt angles range from 47-56°. In the third Mn site, Mn(3) is bonded to one O(1), one F(3), one F(4), one F(7), and two equivalent F(2) atoms to form MnOF5 octahedra that share corners with two equivalent Mn(1)F6 octahedra, corners with three equivalent Mn(5)F6 octahedra, corners with three equivalent Mn(4)OF5 octahedra,  an edgeedge with one Mn(6)F6 octahedra, and  an edgeedge with one Mn(2)OF5 octahedra. The corner-sharing octahedral tilt angles range from 47-56°. In the fourth Mn site, Mn(4) is bonded to one O(1), one F(5), two equivalent F(2), and two equivalent F(8) atoms to form MnOF5 octahedra that share corners with two equivalent Mn(2)OF5 octahedra, corners with three equivalent Mn(6)F6 octahedra, corners with three equivalent Mn(3)OF5 octahedra,  an edgeedge with one Mn(1)F6 octahedra, and  an edgeedge with one Mn(5)F6 octahedra. The corner-sharing octahedral tilt angles range from 47-51°. In the fifth Mn site, Mn(5) is bonded to one F(3), one F(6), two equivalent F(1), and two equivalent F(2) atoms to form MnF6 octahedra that share corners with two equivalent Mn(6)F6 octahedra, corners with three equivalent Mn(2)OF5 octahedra, corners with three equivalent Mn(3)OF5 octahedra,  an edgeedge with one Mn(1)F6 octahedra, and  an edgeedge with one Mn(4)OF5 octahedra. The corner-sharing octahedral tilt angles range from 48-56°. In the sixth Mn site, Mn(6) is bonded to one F(3), one F(5), one F(6), one F(7), and two equivalent F(8) atoms to form MnF6 octahedra that share corners with two equivalent Mn(5)F6 octahedra, corners with three equivalent Mn(1)F6 octahedra, corners with three equivalent Mn(4)OF5 octahedra,  an edgeedge with one Mn(2)OF5 octahedra, and  an edgeedge with one Mn(3)OF5 octahedra. The corner-sharing octahedral tilt angles range from 49-56°. O(1) is bonded in a distorted trigonal planar geometry to one Mn(2), one Mn(3), and one Mn(4) atom. There are eight inequivalent F sites. In the first F site, F(1) is bonded in a trigonal planar geometry to one Mn(1), one Mn(2), and one Mn(5) atom. In the second F site, F(2) is bonded in a trigonal planar geometry to one Mn(3), one Mn(4), and one Mn(5) atom. In the third F site, F(3) is bonded in a trigonal planar geometry to one Mn(3), one Mn(5), and one Mn(6) atom. In the fourth F site, F(4) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(2), and one Mn(3) atom. In the fifth F site, F(5) is bonded in a distorted trigonal planar geometry to one Mn(2), one Mn(4), and one Mn(6) atom. In the sixth F site, F(6) is bonded in a trigonal planar geometry to one Mn(2), one Mn(5), and one Mn(6) atom. In the seventh F site, F(7) is bonded in a trigonal planar geometry to one Mn(1), one Mn(3), and one Mn(6) atom. In the eighth F site, F(8) is bonded in a trigonal planar geometry to one Mn(1), one Mn(4), and one Mn(6) atom. is represented by the CIF card [CIF]
data_Mn6OF11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.916
_cell_length_b   5.916
_cell_length_c   7.627
_cell_angle_alpha   74.057
_cell_angle_beta   74.057
_cell_angle_gamma   72.747
_symmetry_Int_Tables_number   1
_cell_volume   239.651
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.333  0.333  0.167  1.0
  Mn  Mn1  1  0.663  0.663  0.352  1.0
  Mn  Mn2  1  0.347  0.347  0.671  1.0
  Mn  Mn3  1  0.660  0.660  0.821  1.0
  Mn  Mn4  1  0.003  0.003  0.501  1.0
  Mn  Mn5  1  0.996  0.996  0.995  1.0
  O  O6  1  0.569  0.569  0.640  1.0
  F  F7  1  0.970  0.363  0.330  1.0
  F  F8  1  0.639  0.022  0.671  1.0
  F  F9  1  0.111  0.111  0.700  1.0
  F  F10  1  0.433  0.433  0.373  1.0
  F  F11  1  0.759  0.759  0.028  1.0
  F  F12  1  0.900  0.900  0.292  1.0
  F  F13  1  0.229  0.229  0.966  1.0
  F  F14  1  0.022  0.639  0.671  1.0
  F  F15  1  0.363  0.970  0.330  1.0
  F  F16  1  0.696  0.308  0.996  1.0
  F  F17  1  0.308  0.696  0.996  1.0
[/CIF]
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