The crystal structure described by LiW2P3O13 crystallizes in the triclinic P-1 space group. Li(1) is bonded in a 5-coordinate geometry to one O(1), one O(11), one O(2), one O(6), and one O(8) atom. There are two inequivalent W sites. In the first W site, W(1) is bonded to one O(1), one O(10), one O(11), one O(6), one O(8), and one O(9) atom to form distorted WO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, and corners with three equivalent P(3)O4 tetrahedra. In the second W site, W(2) is bonded to one O(12), one O(13), one O(2), one O(3), one O(4), and one O(5) atom to form distorted WO6 octahedra that share  a cornercorner with one P(3)O4 tetrahedra, corners with two equivalent P(1)O4 tetrahedra, and corners with two equivalent P(2)O4 tetrahedra. There are three inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), one O(5), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one W(1)O6 octahedra, corners with two equivalent W(2)O6 octahedra, and  a cornercorner with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 18-55°. In the second P site, P(2) is bonded to one O(10), one O(13), one O(3), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one W(1)O6 octahedra, corners with two equivalent W(2)O6 octahedra, and  a cornercorner with one P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 20-50°. In the third P site, P(3) is bonded to one O(11), one O(4), one O(6), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one W(2)O6 octahedra and corners with three equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 35-49°. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Li(1), one W(1), and one P(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Li(1), one W(2), and one P(1) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one W(2) and one P(2) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one W(2) and one P(3) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one W(2) and one P(1) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Li(1), one W(1), and one P(3) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. In the eighth O site, O(8) is bonded in a linear geometry to one Li(1) and one W(1) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one W(1) and one P(3) atom. In the tenth O site, O(10) is bonded in a distorted bent 150 degrees geometry to one W(1) and one P(2) atom. In the eleventh O site, O(11) is bonded in a 2-coordinate geometry to one Li(1), one W(1), and one P(3) atom. In the twelfth O site, O(12) is bonded in a single-bond geometry to one W(2) atom. In the thirteenth O site, O(13) is bonded in a bent 150 degrees geometry to one W(2) and one P(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiP3W2O13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.467
_cell_length_b   7.497
_cell_length_c   11.280
_cell_angle_alpha   74.916
_cell_angle_beta   85.498
_cell_angle_gamma   80.482
_symmetry_Int_Tables_number   1
_cell_volume   520.455
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.265  0.566  0.795  1.0
  Li  Li1  1  0.735  0.434  0.205  1.0
  P  P2  1  0.118  0.474  0.308  1.0
  P  P3  1  0.259  0.801  0.334  1.0
  P  P4  1  0.262  0.926  0.892  1.0
  P  P5  1  0.738  0.074  0.108  1.0
  P  P6  1  0.741  0.199  0.666  1.0
  P  P7  1  0.882  0.526  0.692  1.0
  W  W8  1  0.225  0.211  0.086  1.0
  W  W9  1  0.241  0.195  0.596  1.0
  W  W10  1  0.759  0.805  0.404  1.0
  W  W11  1  0.775  0.789  0.914  1.0
  O  O12  1  0.132  0.386  0.199  1.0
  O  O13  1  0.113  0.462  0.661  1.0
  O  O14  1  0.076  0.783  0.429  1.0
  O  O15  1  0.223  0.102  0.786  1.0
  O  O16  1  0.246  0.352  0.416  1.0
  O  O17  1  0.091  0.799  0.901  1.0
  O  O18  1  0.237  0.655  0.254  1.0
  O  O19  1  0.250  0.379  0.945  1.0
  O  O20  1  0.271  0.985  0.012  1.0
  O  O21  1  0.244  0.995  0.249  1.0
  O  O22  1  0.534  0.206  0.128  1.0
  O  O23  1  0.308  0.968  0.580  1.0
  O  O24  1  0.530  0.269  0.605  1.0
  O  O25  1  0.470  0.731  0.395  1.0
  O  O26  1  0.692  0.032  0.420  1.0
  O  O27  1  0.466  0.794  0.872  1.0
  O  O28  1  0.756  0.005  0.751  1.0
  O  O29  1  0.729  0.015  0.988  1.0
  O  O30  1  0.750  0.621  0.055  1.0
  O  O31  1  0.763  0.345  0.746  1.0
  O  O32  1  0.909  0.201  0.099  1.0
  O  O33  1  0.754  0.648  0.584  1.0
  O  O34  1  0.777  0.898  0.214  1.0
  O  O35  1  0.924  0.217  0.571  1.0
  O  O36  1  0.887  0.538  0.339  1.0
  O  O37  1  0.868  0.614  0.801  1.0
[/CIF]
.
The crystal structure described by LiW2P3O13 crystallizes in the triclinic P-1 space group. Li(1) is bonded in a 5-coordinate geometry to one O(1), one O(11), one O(2), one O(6), and one O(8) atom. There are two inequivalent W sites. In the first W site, W(1) is bonded to one O(1), one O(10), one O(11), one O(6), one O(8), and one O(9) atom to form distorted WO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, and corners with three equivalent P(3)O4 tetrahedra. In the second W site, W(2) is bonded to one O(12), one O(13), one O(2), one O(3), one O(4), and one O(5) atom to form distorted WO6 octahedra that share  a cornercorner with one P(3)O4 tetrahedra, corners with two equivalent P(1)O4 tetrahedra, and corners with two equivalent P(2)O4 tetrahedra. There are three inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), one O(5), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one W(1)O6 octahedra, corners with two equivalent W(2)O6 octahedra, and  a cornercorner with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 18-55°. In the second P site, P(2) is bonded to one O(10), one O(13), one O(3), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one W(1)O6 octahedra, corners with two equivalent W(2)O6 octahedra, and  a cornercorner with one P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 20-50°. In the third P site, P(3) is bonded to one O(11), one O(4), one O(6), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one W(2)O6 octahedra and corners with three equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 35-49°. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Li(1), one W(1), and one P(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Li(1), one W(2), and one P(1) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one W(2) and one P(2) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one W(2) and one P(3) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one W(2) and one P(1) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Li(1), one W(1), and one P(3) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. In the eighth O site, O(8) is bonded in a linear geometry to one Li(1) and one W(1) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one W(1) and one P(3) atom. In the tenth O site, O(10) is bonded in a distorted bent 150 degrees geometry to one W(1) and one P(2) atom. In the eleventh O site, O(11) is bonded in a 2-coordinate geometry to one Li(1), one W(1), and one P(3) atom. In the twelfth O site, O(12) is bonded in a single-bond geometry to one W(2) atom. In the thirteenth O site, O(13) is bonded in a bent 150 degrees geometry to one W(2) and one P(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiP3W2O13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.467
_cell_length_b   7.497
_cell_length_c   11.280
_cell_angle_alpha   74.916
_cell_angle_beta   85.498
_cell_angle_gamma   80.482
_symmetry_Int_Tables_number   1
_cell_volume   520.455
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.265  0.566  0.795  1.0
  Li  Li1  1  0.735  0.434  0.205  1.0
  P  P2  1  0.118  0.474  0.308  1.0
  P  P3  1  0.259  0.801  0.334  1.0
  P  P4  1  0.262  0.926  0.892  1.0
  P  P5  1  0.738  0.074  0.108  1.0
  P  P6  1  0.741  0.199  0.666  1.0
  P  P7  1  0.882  0.526  0.692  1.0
  W  W8  1  0.225  0.211  0.086  1.0
  W  W9  1  0.241  0.195  0.596  1.0
  W  W10  1  0.759  0.805  0.404  1.0
  W  W11  1  0.775  0.789  0.914  1.0
  O  O12  1  0.132  0.386  0.199  1.0
  O  O13  1  0.113  0.462  0.661  1.0
  O  O14  1  0.076  0.783  0.429  1.0
  O  O15  1  0.223  0.102  0.786  1.0
  O  O16  1  0.246  0.352  0.416  1.0
  O  O17  1  0.091  0.799  0.901  1.0
  O  O18  1  0.237  0.655  0.254  1.0
  O  O19  1  0.250  0.379  0.945  1.0
  O  O20  1  0.271  0.985  0.012  1.0
  O  O21  1  0.244  0.995  0.249  1.0
  O  O22  1  0.534  0.206  0.128  1.0
  O  O23  1  0.308  0.968  0.580  1.0
  O  O24  1  0.530  0.269  0.605  1.0
  O  O25  1  0.470  0.731  0.395  1.0
  O  O26  1  0.692  0.032  0.420  1.0
  O  O27  1  0.466  0.794  0.872  1.0
  O  O28  1  0.756  0.005  0.751  1.0
  O  O29  1  0.729  0.015  0.988  1.0
  O  O30  1  0.750  0.621  0.055  1.0
  O  O31  1  0.763  0.345  0.746  1.0
  O  O32  1  0.909  0.201  0.099  1.0
  O  O33  1  0.754  0.648  0.584  1.0
  O  O34  1  0.777  0.898  0.214  1.0
  O  O35  1  0.924  0.217  0.571  1.0
  O  O36  1  0.887  0.538  0.339  1.0
  O  O37  1  0.868  0.614  0.801  1.0
[/CIF]
.