The material structure described by CrN5ClPdBr4 is Indium-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four tetrabromopalladium molecules and four CrN5Cl clusters. In each CrN5Cl cluster, Cr(1) is bonded in a 4-coordinate geometry to one N(1), two equivalent N(2), two equivalent N(3), and one Cl(1) atom. There are three inequivalent N sites. In the first N site, N(3) is bonded in a single-bond geometry to one Cr(1) atom. In the second N site, N(1) is bonded in a T-shaped geometry to one Cr(1) and two equivalent N(2) atoms. In the third N site, N(2) is bonded in a 2-coordinate geometry to one Cr(1) and one N(1) atom. Cl(1) is bonded in a single-bond geometry to one Cr(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CrPdBr4N5Cl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.581
_cell_length_b   8.866
_cell_length_c   17.183
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1307.266
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.657  0.750  0.062  1.0
  Cr  Cr1  1  0.843  0.750  0.562  1.0
  Cr  Cr2  1  0.343  0.250  0.938  1.0
  Cr  Cr3  1  0.157  0.250  0.438  1.0
  Pd  Pd4  1  0.156  0.750  0.163  1.0
  Pd  Pd5  1  0.344  0.750  0.663  1.0
  Pd  Pd6  1  0.844  0.250  0.837  1.0
  Pd  Pd7  1  0.656  0.250  0.337  1.0
  Br  Br8  1  0.051  0.750  0.031  1.0
  Br  Br9  1  0.449  0.750  0.531  1.0
  Br  Br10  1  0.949  0.250  0.969  1.0
  Br  Br11  1  0.551  0.250  0.469  1.0
  Br  Br12  1  0.157  0.476  0.156  1.0
  Br  Br13  1  0.343  0.024  0.656  1.0
  Br  Br14  1  0.843  0.976  0.844  1.0
  Br  Br15  1  0.657  0.524  0.344  1.0
  Br  Br16  1  0.843  0.524  0.844  1.0
  Br  Br17  1  0.657  0.976  0.344  1.0
  Br  Br18  1  0.157  0.024  0.156  1.0
  Br  Br19  1  0.343  0.476  0.656  1.0
  Br  Br20  1  0.262  0.750  0.292  1.0
  Br  Br21  1  0.238  0.750  0.792  1.0
  Br  Br22  1  0.738  0.250  0.708  1.0
  Br  Br23  1  0.762  0.250  0.208  1.0
  N  N24  1  0.611  0.750  0.189  1.0
  N  N25  1  0.889  0.750  0.689  1.0
  N  N26  1  0.389  0.250  0.811  1.0
  N  N27  1  0.111  0.250  0.311  1.0
  N  N28  1  0.611  0.614  0.187  1.0
  N  N29  1  0.889  0.886  0.687  1.0
  N  N30  1  0.389  0.114  0.813  1.0
  N  N31  1  0.111  0.386  0.313  1.0
  N  N32  1  0.389  0.386  0.813  1.0
  N  N33  1  0.111  0.114  0.313  1.0
  N  N34  1  0.611  0.886  0.187  1.0
  N  N35  1  0.889  0.614  0.687  1.0
  N  N36  1  0.780  0.617  0.043  1.0
  N  N37  1  0.720  0.883  0.543  1.0
  N  N38  1  0.220  0.117  0.957  1.0
  N  N39  1  0.280  0.383  0.457  1.0
  N  N40  1  0.220  0.383  0.957  1.0
  N  N41  1  0.280  0.117  0.457  1.0
  N  N42  1  0.780  0.883  0.043  1.0
  N  N43  1  0.720  0.617  0.543  1.0
  Cl  Cl44  1  0.468  0.750  0.980  1.0
  Cl  Cl45  1  0.032  0.750  0.480  1.0
  Cl  Cl46  1  0.532  0.250  0.020  1.0
  Cl  Cl47  1  0.968  0.250  0.520  1.0
[/CIF]
.
The material structure described by CrN5ClPdBr4 is Indium-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four tetrabromopalladium molecules and four CrN5Cl clusters. In each CrN5Cl cluster, Cr(1) is bonded in a 4-coordinate geometry to one N(1), two equivalent N(2), two equivalent N(3), and one Cl(1) atom. There are three inequivalent N sites. In the first N site, N(3) is bonded in a single-bond geometry to one Cr(1) atom. In the second N site, N(1) is bonded in a T-shaped geometry to one Cr(1) and two equivalent N(2) atoms. In the third N site, N(2) is bonded in a 2-coordinate geometry to one Cr(1) and one N(1) atom. Cl(1) is bonded in a single-bond geometry to one Cr(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CrPdBr4N5Cl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.581
_cell_length_b   8.866
_cell_length_c   17.183
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1307.266
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.657  0.750  0.062  1.0
  Cr  Cr1  1  0.843  0.750  0.562  1.0
  Cr  Cr2  1  0.343  0.250  0.938  1.0
  Cr  Cr3  1  0.157  0.250  0.438  1.0
  Pd  Pd4  1  0.156  0.750  0.163  1.0
  Pd  Pd5  1  0.344  0.750  0.663  1.0
  Pd  Pd6  1  0.844  0.250  0.837  1.0
  Pd  Pd7  1  0.656  0.250  0.337  1.0
  Br  Br8  1  0.051  0.750  0.031  1.0
  Br  Br9  1  0.449  0.750  0.531  1.0
  Br  Br10  1  0.949  0.250  0.969  1.0
  Br  Br11  1  0.551  0.250  0.469  1.0
  Br  Br12  1  0.157  0.476  0.156  1.0
  Br  Br13  1  0.343  0.024  0.656  1.0
  Br  Br14  1  0.843  0.976  0.844  1.0
  Br  Br15  1  0.657  0.524  0.344  1.0
  Br  Br16  1  0.843  0.524  0.844  1.0
  Br  Br17  1  0.657  0.976  0.344  1.0
  Br  Br18  1  0.157  0.024  0.156  1.0
  Br  Br19  1  0.343  0.476  0.656  1.0
  Br  Br20  1  0.262  0.750  0.292  1.0
  Br  Br21  1  0.238  0.750  0.792  1.0
  Br  Br22  1  0.738  0.250  0.708  1.0
  Br  Br23  1  0.762  0.250  0.208  1.0
  N  N24  1  0.611  0.750  0.189  1.0
  N  N25  1  0.889  0.750  0.689  1.0
  N  N26  1  0.389  0.250  0.811  1.0
  N  N27  1  0.111  0.250  0.311  1.0
  N  N28  1  0.611  0.614  0.187  1.0
  N  N29  1  0.889  0.886  0.687  1.0
  N  N30  1  0.389  0.114  0.813  1.0
  N  N31  1  0.111  0.386  0.313  1.0
  N  N32  1  0.389  0.386  0.813  1.0
  N  N33  1  0.111  0.114  0.313  1.0
  N  N34  1  0.611  0.886  0.187  1.0
  N  N35  1  0.889  0.614  0.687  1.0
  N  N36  1  0.780  0.617  0.043  1.0
  N  N37  1  0.720  0.883  0.543  1.0
  N  N38  1  0.220  0.117  0.957  1.0
  N  N39  1  0.280  0.383  0.457  1.0
  N  N40  1  0.220  0.383  0.957  1.0
  N  N41  1  0.280  0.117  0.457  1.0
  N  N42  1  0.780  0.883  0.043  1.0
  N  N43  1  0.720  0.617  0.543  1.0
  Cl  Cl44  1  0.468  0.750  0.980  1.0
  Cl  Cl45  1  0.032  0.750  0.480  1.0
  Cl  Cl46  1  0.532  0.250  0.020  1.0
  Cl  Cl47  1  0.968  0.250  0.520  1.0
[/CIF]
.