The material described by MnO3Cl is Silicon tetrafluoride-derived structured and crystallizes in the orthorhombic Cmc2_1 space group. The structure is zero-dimensional and consists of four MnO3Cl clusters. Mn(1) is bonded in a tetrahedral geometry to one O(2), two equivalent O(1), and one Cl(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Mn(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Mn(1) atom. Cl(1) is bonded in a single-bond geometry to one Mn(1) atom. is represented by the CIF file [CIF]
data_MnClO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.432
_cell_length_b   6.432
_cell_length_c   5.245
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   109.389
_symmetry_Int_Tables_number   1
_cell_volume   204.677
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.826  0.174  0.592  1.0
  Mn  Mn1  1  0.174  0.826  0.092  1.0
  Cl  Cl2  1  0.636  0.364  0.714  1.0
  Cl  Cl3  1  0.364  0.636  0.214  1.0
  O  O4  1  0.069  0.282  0.699  1.0
  O  O5  1  0.718  0.931  0.699  1.0
  O  O6  1  0.931  0.718  0.199  1.0
  O  O7  1  0.827  0.173  0.290  1.0
  O  O8  1  0.282  0.069  0.199  1.0
  O  O9  1  0.173  0.827  0.790  1.0
[/CIF]
.
The material described by MnO3Cl is Silicon tetrafluoride-derived structured and crystallizes in the orthorhombic Cmc2_1 space group. The structure is zero-dimensional and consists of four MnO3Cl clusters. Mn(1) is bonded in a tetrahedral geometry to one O(2), two equivalent O(1), and one Cl(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Mn(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Mn(1) atom. Cl(1) is bonded in a single-bond geometry to one Mn(1) atom. is represented by the CIF file [CIF]
data_MnClO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.432
_cell_length_b   6.432
_cell_length_c   5.245
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   109.389
_symmetry_Int_Tables_number   1
_cell_volume   204.677
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.826  0.174  0.592  1.0
  Mn  Mn1  1  0.174  0.826  0.092  1.0
  Cl  Cl2  1  0.636  0.364  0.714  1.0
  Cl  Cl3  1  0.364  0.636  0.214  1.0
  O  O4  1  0.069  0.282  0.699  1.0
  O  O5  1  0.718  0.931  0.699  1.0
  O  O6  1  0.931  0.718  0.199  1.0
  O  O7  1  0.827  0.173  0.290  1.0
  O  O8  1  0.282  0.069  0.199  1.0
  O  O9  1  0.173  0.827  0.790  1.0
[/CIF]
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