The structure described by KPdN crystallizes in the orthorhombic Pmmm space group. K(1) is bonded in a 4-coordinate geometry to two equivalent N(1) and two equivalent N(2) atoms. Pd(1,2) is bonded in a linear geometry to two equivalent N(1) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded to four equivalent K(1) and two equivalent Pd(1,2) atoms to form a mixture of distorted edge and corner-sharing NK4Pd2 octahedra. The corner-sharing octahedral tilt angles range from 0-54°. In the second N site, N(2) is bonded to four equivalent K(1) and two equivalent Pd(1,2) atoms to form a mixture of distorted edge and corner-sharing NK4Pd2 octahedra. The corner-sharing octahedral tilt angles range from 0-54°. is represented by the Crystallographic Information File (CIF) [CIF]
data_KPdN
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.092
_cell_length_b   3.775
_cell_length_c   5.326
_cell_angle_alpha   44.957
_cell_angle_beta   90.003
_cell_angle_gamma   89.999
_symmetry_Int_Tables_number   1
_cell_volume   129.173
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.466  1.000  0.058  1.0
  K  K1  1  0.965  0.000  0.058  1.0
  Pd  Pd2  1  0.216  0.001  0.558  1.0
  Pd  Pd3  1  0.716  0.999  0.558  1.0
  N  N4  1  0.216  0.501  0.558  1.0
  N  N5  1  0.716  0.499  0.058  1.0
[/CIF]
.
The structure described by KPdN crystallizes in the orthorhombic Pmmm space group. K(1) is bonded in a 4-coordinate geometry to two equivalent N(1) and two equivalent N(2) atoms. Pd(1,2) is bonded in a linear geometry to two equivalent N(1) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded to four equivalent K(1) and two equivalent Pd(1,2) atoms to form a mixture of distorted edge and corner-sharing NK4Pd2 octahedra. The corner-sharing octahedral tilt angles range from 0-54°. In the second N site, N(2) is bonded to four equivalent K(1) and two equivalent Pd(1,2) atoms to form a mixture of distorted edge and corner-sharing NK4Pd2 octahedra. The corner-sharing octahedral tilt angles range from 0-54°. is represented by the Crystallographic Information File (CIF) [CIF]
data_KPdN
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.092
_cell_length_b   3.775
_cell_length_c   5.326
_cell_angle_alpha   44.957
_cell_angle_beta   90.003
_cell_angle_gamma   89.999
_symmetry_Int_Tables_number   1
_cell_volume   129.173
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.466  1.000  0.058  1.0
  K  K1  1  0.965  0.000  0.058  1.0
  Pd  Pd2  1  0.216  0.001  0.558  1.0
  Pd  Pd3  1  0.716  0.999  0.558  1.0
  N  N4  1  0.216  0.501  0.558  1.0
  N  N5  1  0.716  0.499  0.058  1.0
[/CIF]
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