The crystal structure described by (PtN2Cl5)2N2(NO)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four ammonia atoms, four nitroxyl molecules, and four PtN2Cl5 clusters. In each PtN2Cl5 cluster, Pt(1) is bonded in a trigonal bipyramidal geometry to one N(1), one N(2), one Cl(1), one Cl(2), and one Cl(3) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one Pt(1) and one Cl(4) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one Pt(1) and one Cl(5) atom. There are five inequivalent Cl sites. In the first Cl site, Cl(4) is bonded in a single-bond geometry to one N(1) atom. In the second Cl site, Cl(5) is bonded in a single-bond geometry to one N(2) atom. In the third Cl site, Cl(1) is bonded in a single-bond geometry to one Pt(1) atom. In the fourth Cl site, Cl(2) is bonded in a single-bond geometry to one Pt(1) atom. In the fifth Cl site, Cl(3) is bonded in a single-bond geometry to one Pt(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_PtN4Cl5O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.653
_cell_length_b   12.172
_cell_length_c   14.519
_cell_angle_alpha   71.058
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1111.960
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pt  Pt0  1  0.728  0.311  0.417  1.0
  Pt  Pt1  1  0.228  0.689  0.083  1.0
  Pt  Pt2  1  0.272  0.689  0.583  1.0
  Pt  Pt3  1  0.772  0.311  0.917  1.0
  N  N4  1  0.929  0.412  0.440  1.0
  N  N5  1  0.429  0.588  0.060  1.0
  N  N6  1  0.071  0.588  0.560  1.0
  N  N7  1  0.571  0.412  0.940  1.0
  N  N8  1  0.530  0.262  0.520  1.0
  N  N9  1  0.030  0.738  0.980  1.0
  N  N10  1  0.470  0.738  0.480  1.0
  N  N11  1  0.970  0.262  0.020  1.0
  N  N12  1  0.244  0.186  0.369  1.0
  N  N13  1  0.744  0.814  0.131  1.0
  N  N14  1  0.756  0.814  0.631  1.0
  N  N15  1  0.256  0.186  0.869  1.0
  N  N16  1  0.445  0.060  0.191  1.0
  N  N17  1  0.945  0.940  0.309  1.0
  N  N18  1  0.555  0.940  0.809  1.0
  N  N19  1  0.055  0.060  0.691  1.0
  Cl  Cl20  1  0.523  0.474  0.353  1.0
  Cl  Cl21  1  0.023  0.526  0.147  1.0
  Cl  Cl22  1  0.477  0.526  0.647  1.0
  Cl  Cl23  1  0.977  0.474  0.853  1.0
  Cl  Cl24  1  0.721  0.277  0.268  1.0
  Cl  Cl25  1  0.221  0.723  0.232  1.0
  Cl  Cl26  1  0.279  0.723  0.732  1.0
  Cl  Cl27  1  0.779  0.277  0.768  1.0
  Cl  Cl28  1  0.933  0.142  0.471  1.0
  Cl  Cl29  1  0.433  0.858  0.029  1.0
  Cl  Cl30  1  0.067  0.858  0.529  1.0
  Cl  Cl31  1  0.567  0.142  0.971  1.0
  Cl  Cl32  1  0.116  0.369  0.515  1.0
  Cl  Cl33  1  0.616  0.631  0.985  1.0
  Cl  Cl34  1  0.884  0.631  0.485  1.0
  Cl  Cl35  1  0.384  0.369  0.015  1.0
  Cl  Cl36  1  0.947  0.138  0.111  1.0
  Cl  Cl37  1  0.447  0.862  0.389  1.0
  Cl  Cl38  1  0.053  0.862  0.889  1.0
  Cl  Cl39  1  0.553  0.138  0.611  1.0
  O  O40  1  0.216  0.241  0.290  1.0
  O  O41  1  0.716  0.759  0.210  1.0
  O  O42  1  0.784  0.759  0.710  1.0
  O  O43  1  0.284  0.241  0.790  1.0
[/CIF]
.
The crystal structure described by (PtN2Cl5)2N2(NO)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four ammonia atoms, four nitroxyl molecules, and four PtN2Cl5 clusters. In each PtN2Cl5 cluster, Pt(1) is bonded in a trigonal bipyramidal geometry to one N(1), one N(2), one Cl(1), one Cl(2), and one Cl(3) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one Pt(1) and one Cl(4) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one Pt(1) and one Cl(5) atom. There are five inequivalent Cl sites. In the first Cl site, Cl(4) is bonded in a single-bond geometry to one N(1) atom. In the second Cl site, Cl(5) is bonded in a single-bond geometry to one N(2) atom. In the third Cl site, Cl(1) is bonded in a single-bond geometry to one Pt(1) atom. In the fourth Cl site, Cl(2) is bonded in a single-bond geometry to one Pt(1) atom. In the fifth Cl site, Cl(3) is bonded in a single-bond geometry to one Pt(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_PtN4Cl5O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.653
_cell_length_b   12.172
_cell_length_c   14.519
_cell_angle_alpha   71.058
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1111.960
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pt  Pt0  1  0.728  0.311  0.417  1.0
  Pt  Pt1  1  0.228  0.689  0.083  1.0
  Pt  Pt2  1  0.272  0.689  0.583  1.0
  Pt  Pt3  1  0.772  0.311  0.917  1.0
  N  N4  1  0.929  0.412  0.440  1.0
  N  N5  1  0.429  0.588  0.060  1.0
  N  N6  1  0.071  0.588  0.560  1.0
  N  N7  1  0.571  0.412  0.940  1.0
  N  N8  1  0.530  0.262  0.520  1.0
  N  N9  1  0.030  0.738  0.980  1.0
  N  N10  1  0.470  0.738  0.480  1.0
  N  N11  1  0.970  0.262  0.020  1.0
  N  N12  1  0.244  0.186  0.369  1.0
  N  N13  1  0.744  0.814  0.131  1.0
  N  N14  1  0.756  0.814  0.631  1.0
  N  N15  1  0.256  0.186  0.869  1.0
  N  N16  1  0.445  0.060  0.191  1.0
  N  N17  1  0.945  0.940  0.309  1.0
  N  N18  1  0.555  0.940  0.809  1.0
  N  N19  1  0.055  0.060  0.691  1.0
  Cl  Cl20  1  0.523  0.474  0.353  1.0
  Cl  Cl21  1  0.023  0.526  0.147  1.0
  Cl  Cl22  1  0.477  0.526  0.647  1.0
  Cl  Cl23  1  0.977  0.474  0.853  1.0
  Cl  Cl24  1  0.721  0.277  0.268  1.0
  Cl  Cl25  1  0.221  0.723  0.232  1.0
  Cl  Cl26  1  0.279  0.723  0.732  1.0
  Cl  Cl27  1  0.779  0.277  0.768  1.0
  Cl  Cl28  1  0.933  0.142  0.471  1.0
  Cl  Cl29  1  0.433  0.858  0.029  1.0
  Cl  Cl30  1  0.067  0.858  0.529  1.0
  Cl  Cl31  1  0.567  0.142  0.971  1.0
  Cl  Cl32  1  0.116  0.369  0.515  1.0
  Cl  Cl33  1  0.616  0.631  0.985  1.0
  Cl  Cl34  1  0.884  0.631  0.485  1.0
  Cl  Cl35  1  0.384  0.369  0.015  1.0
  Cl  Cl36  1  0.947  0.138  0.111  1.0
  Cl  Cl37  1  0.447  0.862  0.389  1.0
  Cl  Cl38  1  0.053  0.862  0.889  1.0
  Cl  Cl39  1  0.553  0.138  0.611  1.0
  O  O40  1  0.216  0.241  0.290  1.0
  O  O41  1  0.716  0.759  0.210  1.0
  O  O42  1  0.784  0.759  0.710  1.0
  O  O43  1  0.284  0.241  0.790  1.0
[/CIF]
.