The compound described by MgWMnZn2O6 crystallizes in the triclinic P1 space group. Mg(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form MgO6 octahedra that share corners with two equivalent W(1)O6 octahedra,  a cornercorner with one Zn(2)O5 trigonal bipyramid, corners with three equivalent Zn(1)O5 trigonal bipyramids, edges with two equivalent W(1)O6 octahedra, edges with three equivalent Mn(1)O6 octahedra,  an edgeedge with one Zn(1)O5 trigonal bipyramid, and edges with two equivalent Zn(2)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 11-19°. W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form WO6 octahedra that share corners with two equivalent Mg(1)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra,  a cornercorner with one Zn(1)O5 trigonal bipyramid,  a cornercorner with one Zn(2)O5 trigonal bipyramid, edges with two equivalent Mg(1)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Zn(1)O5 trigonal bipyramids, and edges with two equivalent Zn(2)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 11-25°. Mn(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form MnO6 octahedra that share corners with two equivalent W(1)O6 octahedra,  a cornercorner with one Zn(1)O5 trigonal bipyramid, corners with three equivalent Zn(2)O5 trigonal bipyramids, edges with two equivalent W(1)O6 octahedra, edges with three equivalent Mg(1)O6 octahedra,  an edgeedge with one Zn(2)O5 trigonal bipyramid, and edges with two equivalent Zn(1)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 14-25°. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form ZnO5 trigonal bipyramids that share  a cornercorner with one W(1)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra, corners with three equivalent Mg(1)O6 octahedra,  an edgeedge with one Mg(1)O6 octahedra, edges with two equivalent W(1)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and edges with two equivalent Zn(2)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 7-77°. In the second Zn site, Zn(2) is bonded to one O(1), one O(3), one O(4), one O(5), and one O(6) atom to form ZnO5 trigonal bipyramids that share  a cornercorner with one Mg(1)O6 octahedra,  a cornercorner with one W(1)O6 octahedra, corners with three equivalent Mn(1)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra, edges with two equivalent Mg(1)O6 octahedra, edges with two equivalent W(1)O6 octahedra, and edges with two equivalent Zn(1)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 6-79°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Mg(1), one W(1), one Mn(1), and one Zn(2) atom. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to one Mg(1), one W(1), one Mn(1), and one Zn(1) atom. In the third O site, O(3) is bonded to one Mg(1), one W(1), one Mn(1), one Zn(1), and one Zn(2) atom to form a mixture of edge and corner-sharing OMgMnZn2W trigonal bipyramids. In the fourth O site, O(4) is bonded to one Mg(1), one W(1), one Mn(1), one Zn(1), and one Zn(2) atom to form a mixture of edge and corner-sharing OMgMnZn2W square pyramids. In the fifth O site, O(5) is bonded to one Mg(1), one W(1), one Mn(1), one Zn(1), and one Zn(2) atom to form a mixture of edge and corner-sharing OMgMnZn2W square pyramids. In the sixth O site, O(6) is bonded to one Mg(1), one W(1), one Mn(1), one Zn(1), and one Zn(2) atom to form a mixture of edge and corner-sharing OMgMnZn2W trigonal bipyramids. is represented by the CIF file [CIF]
data_MgMnZn2WO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.313
_cell_length_b   5.561
_cell_length_c   9.044
_cell_angle_alpha   100.754
_cell_angle_beta   139.486
_cell_angle_gamma   105.184
_symmetry_Int_Tables_number   1
_cell_volume   132.096
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.493  0.655  0.154  1.0
  Mn  Mn1  1  0.385  0.256  0.777  1.0
  Zn  Zn2  1  0.992  0.369  0.330  1.0
  Zn  Zn3  1  0.886  0.542  0.599  1.0
  W  W4  1  0.940  0.956  0.966  1.0
  O  O5  1  0.617  0.736  0.995  1.0
  O  O6  1  0.269  0.203  0.950  1.0
  O  O7  1  0.165  0.391  0.193  1.0
  O  O8  1  0.185  0.797  0.567  1.0
  O  O9  1  0.681  0.099  0.351  1.0
  O  O10  1  0.741  0.533  0.752  1.0
[/CIF]
.
The compound described by MgWMnZn2O6 crystallizes in the triclinic P1 space group. Mg(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form MgO6 octahedra that share corners with two equivalent W(1)O6 octahedra,  a cornercorner with one Zn(2)O5 trigonal bipyramid, corners with three equivalent Zn(1)O5 trigonal bipyramids, edges with two equivalent W(1)O6 octahedra, edges with three equivalent Mn(1)O6 octahedra,  an edgeedge with one Zn(1)O5 trigonal bipyramid, and edges with two equivalent Zn(2)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 11-19°. W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form WO6 octahedra that share corners with two equivalent Mg(1)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra,  a cornercorner with one Zn(1)O5 trigonal bipyramid,  a cornercorner with one Zn(2)O5 trigonal bipyramid, edges with two equivalent Mg(1)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Zn(1)O5 trigonal bipyramids, and edges with two equivalent Zn(2)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 11-25°. Mn(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form MnO6 octahedra that share corners with two equivalent W(1)O6 octahedra,  a cornercorner with one Zn(1)O5 trigonal bipyramid, corners with three equivalent Zn(2)O5 trigonal bipyramids, edges with two equivalent W(1)O6 octahedra, edges with three equivalent Mg(1)O6 octahedra,  an edgeedge with one Zn(2)O5 trigonal bipyramid, and edges with two equivalent Zn(1)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 14-25°. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form ZnO5 trigonal bipyramids that share  a cornercorner with one W(1)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra, corners with three equivalent Mg(1)O6 octahedra,  an edgeedge with one Mg(1)O6 octahedra, edges with two equivalent W(1)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and edges with two equivalent Zn(2)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 7-77°. In the second Zn site, Zn(2) is bonded to one O(1), one O(3), one O(4), one O(5), and one O(6) atom to form ZnO5 trigonal bipyramids that share  a cornercorner with one Mg(1)O6 octahedra,  a cornercorner with one W(1)O6 octahedra, corners with three equivalent Mn(1)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra, edges with two equivalent Mg(1)O6 octahedra, edges with two equivalent W(1)O6 octahedra, and edges with two equivalent Zn(1)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 6-79°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Mg(1), one W(1), one Mn(1), and one Zn(2) atom. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to one Mg(1), one W(1), one Mn(1), and one Zn(1) atom. In the third O site, O(3) is bonded to one Mg(1), one W(1), one Mn(1), one Zn(1), and one Zn(2) atom to form a mixture of edge and corner-sharing OMgMnZn2W trigonal bipyramids. In the fourth O site, O(4) is bonded to one Mg(1), one W(1), one Mn(1), one Zn(1), and one Zn(2) atom to form a mixture of edge and corner-sharing OMgMnZn2W square pyramids. In the fifth O site, O(5) is bonded to one Mg(1), one W(1), one Mn(1), one Zn(1), and one Zn(2) atom to form a mixture of edge and corner-sharing OMgMnZn2W square pyramids. In the sixth O site, O(6) is bonded to one Mg(1), one W(1), one Mn(1), one Zn(1), and one Zn(2) atom to form a mixture of edge and corner-sharing OMgMnZn2W trigonal bipyramids. is represented by the CIF file [CIF]
data_MgMnZn2WO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.313
_cell_length_b   5.561
_cell_length_c   9.044
_cell_angle_alpha   100.754
_cell_angle_beta   139.486
_cell_angle_gamma   105.184
_symmetry_Int_Tables_number   1
_cell_volume   132.096
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.493  0.655  0.154  1.0
  Mn  Mn1  1  0.385  0.256  0.777  1.0
  Zn  Zn2  1  0.992  0.369  0.330  1.0
  Zn  Zn3  1  0.886  0.542  0.599  1.0
  W  W4  1  0.940  0.956  0.966  1.0
  O  O5  1  0.617  0.736  0.995  1.0
  O  O6  1  0.269  0.203  0.950  1.0
  O  O7  1  0.165  0.391  0.193  1.0
  O  O8  1  0.185  0.797  0.567  1.0
  O  O9  1  0.681  0.099  0.351  1.0
  O  O10  1  0.741  0.533  0.752  1.0
[/CIF]
.