The material structure described by Li3(WO3)8 crystallizes in the orthorhombic Pmmm space group. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded in a square co-planar geometry to four equivalent O(3) atoms. In the second Li site, Li(2) is bonded in a square co-planar geometry to four equivalent O(4) atoms. In the third Li site, Li(3) is bonded in a square co-planar geometry to four equivalent O(6) atoms. W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 26-31°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to two equivalent W(1) atoms. In the second O site, O(2) is bonded in a bent 150 degrees geometry to two equivalent W(1) atoms. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Li(1) and two equivalent W(1) atoms. In the fourth O site, O(4) is bonded in a distorted trigonal non-coplanar geometry to one Li(2) and two equivalent W(1) atoms. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to two equivalent W(1) atoms. In the sixth O site, O(6) is bonded in a distorted trigonal non-coplanar geometry to one Li(3) and two equivalent W(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li3(WO3)8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.555
_cell_length_b   7.559
_cell_length_c   7.595
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   433.752
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.000  0.500  0.500  1.0
  Li  Li1  1  0.500  0.000  0.000  1.0
  Li  Li2  1  0.000  0.000  0.500  1.0
  W  W3  1  0.749  0.749  0.751  1.0
  W  W4  1  0.251  0.251  0.249  1.0
  W  W5  1  0.749  0.251  0.249  1.0
  W  W6  1  0.251  0.749  0.751  1.0
  W  W7  1  0.749  0.749  0.249  1.0
  W  W8  1  0.251  0.251  0.751  1.0
  W  W9  1  0.749  0.251  0.751  1.0
  W  W10  1  0.251  0.749  0.249  1.0
  O  O11  1  0.500  0.792  0.707  1.0
  O  O12  1  0.000  0.292  0.206  1.0
  O  O13  1  0.000  0.708  0.794  1.0
  O  O14  1  0.500  0.208  0.293  1.0
  O  O15  1  0.500  0.208  0.707  1.0
  O  O16  1  0.000  0.708  0.206  1.0
  O  O17  1  0.000  0.292  0.794  1.0
  O  O18  1  0.500  0.792  0.293  1.0
  O  O19  1  0.202  0.299  0.500  1.0
  O  O20  1  0.705  0.803  0.000  1.0
  O  O21  1  0.295  0.197  0.000  1.0
  O  O22  1  0.798  0.701  0.500  1.0
  O  O23  1  0.798  0.299  0.500  1.0
  O  O24  1  0.295  0.803  0.000  1.0
  O  O25  1  0.705  0.197  0.000  1.0
  O  O26  1  0.202  0.701  0.500  1.0
  O  O27  1  0.705  0.500  0.213  1.0
  O  O28  1  0.199  0.000  0.705  1.0
  O  O29  1  0.801  0.000  0.295  1.0
  O  O30  1  0.295  0.500  0.787  1.0
  O  O31  1  0.705  0.500  0.787  1.0
  O  O32  1  0.199  0.000  0.295  1.0
  O  O33  1  0.801  0.000  0.705  1.0
  O  O34  1  0.295  0.500  0.213  1.0
[/CIF]
.
The material structure described by Li3(WO3)8 crystallizes in the orthorhombic Pmmm space group. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded in a square co-planar geometry to four equivalent O(3) atoms. In the second Li site, Li(2) is bonded in a square co-planar geometry to four equivalent O(4) atoms. In the third Li site, Li(3) is bonded in a square co-planar geometry to four equivalent O(6) atoms. W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 26-31°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to two equivalent W(1) atoms. In the second O site, O(2) is bonded in a bent 150 degrees geometry to two equivalent W(1) atoms. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Li(1) and two equivalent W(1) atoms. In the fourth O site, O(4) is bonded in a distorted trigonal non-coplanar geometry to one Li(2) and two equivalent W(1) atoms. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to two equivalent W(1) atoms. In the sixth O site, O(6) is bonded in a distorted trigonal non-coplanar geometry to one Li(3) and two equivalent W(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li3(WO3)8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.555
_cell_length_b   7.559
_cell_length_c   7.595
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   433.752
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.000  0.500  0.500  1.0
  Li  Li1  1  0.500  0.000  0.000  1.0
  Li  Li2  1  0.000  0.000  0.500  1.0
  W  W3  1  0.749  0.749  0.751  1.0
  W  W4  1  0.251  0.251  0.249  1.0
  W  W5  1  0.749  0.251  0.249  1.0
  W  W6  1  0.251  0.749  0.751  1.0
  W  W7  1  0.749  0.749  0.249  1.0
  W  W8  1  0.251  0.251  0.751  1.0
  W  W9  1  0.749  0.251  0.751  1.0
  W  W10  1  0.251  0.749  0.249  1.0
  O  O11  1  0.500  0.792  0.707  1.0
  O  O12  1  0.000  0.292  0.206  1.0
  O  O13  1  0.000  0.708  0.794  1.0
  O  O14  1  0.500  0.208  0.293  1.0
  O  O15  1  0.500  0.208  0.707  1.0
  O  O16  1  0.000  0.708  0.206  1.0
  O  O17  1  0.000  0.292  0.794  1.0
  O  O18  1  0.500  0.792  0.293  1.0
  O  O19  1  0.202  0.299  0.500  1.0
  O  O20  1  0.705  0.803  0.000  1.0
  O  O21  1  0.295  0.197  0.000  1.0
  O  O22  1  0.798  0.701  0.500  1.0
  O  O23  1  0.798  0.299  0.500  1.0
  O  O24  1  0.295  0.803  0.000  1.0
  O  O25  1  0.705  0.197  0.000  1.0
  O  O26  1  0.202  0.701  0.500  1.0
  O  O27  1  0.705  0.500  0.213  1.0
  O  O28  1  0.199  0.000  0.705  1.0
  O  O29  1  0.801  0.000  0.295  1.0
  O  O30  1  0.295  0.500  0.787  1.0
  O  O31  1  0.705  0.500  0.787  1.0
  O  O32  1  0.199  0.000  0.295  1.0
  O  O33  1  0.801  0.000  0.705  1.0
  O  O34  1  0.295  0.500  0.213  1.0
[/CIF]
.