The structure described by LaNH2SO7 crystallizes in the tetragonal P4_1 space group. La(1) is bonded in a 5-coordinate geometry to one O(3), one O(4), one O(5), and two equivalent O(7) atoms. N(1) is bonded in a bent 120 degrees geometry to one O(5) and one O(6) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to one O(1) and one O(6) atom. In the second H site, H(2) is bonded in a distorted single-bond geometry to one O(2) and one O(7) atom. S(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are seven inequivalent O sites. In the first O site, O(4) is bonded in a distorted single-bond geometry to one La(1) and one S(1) atom. In the second O site, O(5) is bonded in a distorted single-bond geometry to one La(1) and one N(1) atom. In the third O site, O(6) is bonded in a distorted bent 150 degrees geometry to one N(1) and one H(1) atom. In the fourth O site, O(7) is bonded in a distorted single-bond geometry to two equivalent La(1) and one H(2) atom. In the fifth O site, O(1) is bonded in a distorted water-like geometry to one H(1) and one S(1) atom. In the sixth O site, O(2) is bonded in a distorted bent 120 degrees geometry to one H(2) and one S(1) atom. In the seventh O site, O(3) is bonded in a distorted single-bond geometry to one La(1) and one S(1) atom. is represented by the CIF card [CIF]
data_LaH2SNO7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.558
_cell_length_b   7.558
_cell_length_c   12.444
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   710.830
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.790  0.364  0.539  1.0
  La  La1  1  0.210  0.636  0.039  1.0
  La  La2  1  0.364  0.210  0.289  1.0
  La  La3  1  0.636  0.790  0.789  1.0
  H  H4  1  0.597  0.076  0.927  1.0
  H  H5  1  0.403  0.924  0.427  1.0
  H  H6  1  0.076  0.403  0.677  1.0
  H  H7  1  0.924  0.597  0.177  1.0
  H  H8  1  0.532  0.572  0.963  1.0
  H  H9  1  0.468  0.428  0.463  1.0
  H  H10  1  0.572  0.468  0.713  1.0
  H  H11  1  0.428  0.532  0.213  1.0
  S  S12  1  0.237  0.583  0.752  1.0
  S  S13  1  0.763  0.417  0.252  1.0
  S  S14  1  0.583  0.763  0.502  1.0
  S  S15  1  0.417  0.237  0.002  1.0
  N  N16  1  0.911  0.084  0.745  1.0
  N  N17  1  0.089  0.916  0.245  1.0
  N  N18  1  0.084  0.089  0.495  1.0
  N  N19  1  0.916  0.911  0.995  1.0
  O  O20  1  0.100  0.530  0.658  1.0
  O  O21  1  0.900  0.470  0.158  1.0
  O  O22  1  0.530  0.900  0.408  1.0
  O  O23  1  0.470  0.100  0.908  1.0
  O  O24  1  0.363  0.438  0.757  1.0
  O  O25  1  0.637  0.562  0.257  1.0
  O  O26  1  0.438  0.637  0.507  1.0
  O  O27  1  0.562  0.363  0.007  1.0
  O  O28  1  0.315  0.753  0.721  1.0
  O  O29  1  0.685  0.247  0.221  1.0
  O  O30  1  0.753  0.685  0.471  1.0
  O  O31  1  0.247  0.315  0.971  1.0
  O  O32  1  0.124  0.601  0.848  1.0
  O  O33  1  0.876  0.399  0.348  1.0
  O  O34  1  0.601  0.876  0.598  1.0
  O  O35  1  0.399  0.124  0.098  1.0
  O  O36  1  0.747  0.104  0.720  1.0
  O  O37  1  0.253  0.896  0.220  1.0
  O  O38  1  0.104  0.253  0.470  1.0
  O  O39  1  0.896  0.747  0.970  1.0
  O  O40  1  0.012  0.197  0.704  1.0
  O  O41  1  0.988  0.803  0.204  1.0
  O  O42  1  0.197  0.988  0.454  1.0
  O  O43  1  0.803  0.012  0.954  1.0
  O  O44  1  0.525  0.312  0.445  1.0
  O  O45  1  0.475  0.688  0.945  1.0
  O  O46  1  0.312  0.475  0.195  1.0
  O  O47  1  0.688  0.525  0.695  1.0
[/CIF]
.
The structure described by LaNH2SO7 crystallizes in the tetragonal P4_1 space group. La(1) is bonded in a 5-coordinate geometry to one O(3), one O(4), one O(5), and two equivalent O(7) atoms. N(1) is bonded in a bent 120 degrees geometry to one O(5) and one O(6) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to one O(1) and one O(6) atom. In the second H site, H(2) is bonded in a distorted single-bond geometry to one O(2) and one O(7) atom. S(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are seven inequivalent O sites. In the first O site, O(4) is bonded in a distorted single-bond geometry to one La(1) and one S(1) atom. In the second O site, O(5) is bonded in a distorted single-bond geometry to one La(1) and one N(1) atom. In the third O site, O(6) is bonded in a distorted bent 150 degrees geometry to one N(1) and one H(1) atom. In the fourth O site, O(7) is bonded in a distorted single-bond geometry to two equivalent La(1) and one H(2) atom. In the fifth O site, O(1) is bonded in a distorted water-like geometry to one H(1) and one S(1) atom. In the sixth O site, O(2) is bonded in a distorted bent 120 degrees geometry to one H(2) and one S(1) atom. In the seventh O site, O(3) is bonded in a distorted single-bond geometry to one La(1) and one S(1) atom. is represented by the CIF card [CIF]
data_LaH2SNO7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.558
_cell_length_b   7.558
_cell_length_c   12.444
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   710.830
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.790  0.364  0.539  1.0
  La  La1  1  0.210  0.636  0.039  1.0
  La  La2  1  0.364  0.210  0.289  1.0
  La  La3  1  0.636  0.790  0.789  1.0
  H  H4  1  0.597  0.076  0.927  1.0
  H  H5  1  0.403  0.924  0.427  1.0
  H  H6  1  0.076  0.403  0.677  1.0
  H  H7  1  0.924  0.597  0.177  1.0
  H  H8  1  0.532  0.572  0.963  1.0
  H  H9  1  0.468  0.428  0.463  1.0
  H  H10  1  0.572  0.468  0.713  1.0
  H  H11  1  0.428  0.532  0.213  1.0
  S  S12  1  0.237  0.583  0.752  1.0
  S  S13  1  0.763  0.417  0.252  1.0
  S  S14  1  0.583  0.763  0.502  1.0
  S  S15  1  0.417  0.237  0.002  1.0
  N  N16  1  0.911  0.084  0.745  1.0
  N  N17  1  0.089  0.916  0.245  1.0
  N  N18  1  0.084  0.089  0.495  1.0
  N  N19  1  0.916  0.911  0.995  1.0
  O  O20  1  0.100  0.530  0.658  1.0
  O  O21  1  0.900  0.470  0.158  1.0
  O  O22  1  0.530  0.900  0.408  1.0
  O  O23  1  0.470  0.100  0.908  1.0
  O  O24  1  0.363  0.438  0.757  1.0
  O  O25  1  0.637  0.562  0.257  1.0
  O  O26  1  0.438  0.637  0.507  1.0
  O  O27  1  0.562  0.363  0.007  1.0
  O  O28  1  0.315  0.753  0.721  1.0
  O  O29  1  0.685  0.247  0.221  1.0
  O  O30  1  0.753  0.685  0.471  1.0
  O  O31  1  0.247  0.315  0.971  1.0
  O  O32  1  0.124  0.601  0.848  1.0
  O  O33  1  0.876  0.399  0.348  1.0
  O  O34  1  0.601  0.876  0.598  1.0
  O  O35  1  0.399  0.124  0.098  1.0
  O  O36  1  0.747  0.104  0.720  1.0
  O  O37  1  0.253  0.896  0.220  1.0
  O  O38  1  0.104  0.253  0.470  1.0
  O  O39  1  0.896  0.747  0.970  1.0
  O  O40  1  0.012  0.197  0.704  1.0
  O  O41  1  0.988  0.803  0.204  1.0
  O  O42  1  0.197  0.988  0.454  1.0
  O  O43  1  0.803  0.012  0.954  1.0
  O  O44  1  0.525  0.312  0.445  1.0
  O  O45  1  0.475  0.688  0.945  1.0
  O  O46  1  0.312  0.475  0.195  1.0
  O  O47  1  0.688  0.525  0.695  1.0
[/CIF]
.