The material described by Ce(PdSb)2 crystallizes in the tetragonal P4/nmm space group. Ce(1) is bonded in a 16-coordinate geometry to four equivalent Pd(1), four equivalent Pd(2), four equivalent Sb(1), and four equivalent Sb(2) atoms. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 8-coordinate geometry to four equivalent Ce(1) and four equivalent Sb(2) atoms. In the second Pd site, Pd(2) is bonded in a 5-coordinate geometry to four equivalent Ce(1), one Sb(2), and four equivalent Sb(1) atoms. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 8-coordinate geometry to four equivalent Ce(1) and four equivalent Pd(2) atoms. In the second Sb site, Sb(2) is bonded in a 9-coordinate geometry to four equivalent Ce(1), one Pd(2), and four equivalent Pd(1) atoms. is represented by the CIF card [CIF]
data_Ce(SbPd)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.674
_cell_length_b   4.674
_cell_length_c   10.471
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   228.722
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.000  0.500  0.241  1.0
  Ce  Ce1  1  0.500  0.000  0.759  1.0
  Sb  Sb2  1  0.000  0.000  0.500  1.0
  Sb  Sb3  1  0.500  0.500  0.500  1.0
  Sb  Sb4  1  0.000  0.500  0.871  1.0
  Sb  Sb5  1  0.500  0.000  0.129  1.0
  Pd  Pd6  1  0.000  0.000  0.000  1.0
  Pd  Pd7  1  0.500  0.500  0.000  1.0
  Pd  Pd8  1  0.000  0.500  0.625  1.0
  Pd  Pd9  1  0.500  0.000  0.375  1.0
[/CIF]
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The material described by Ce(PdSb)2 crystallizes in the tetragonal P4/nmm space group. Ce(1) is bonded in a 16-coordinate geometry to four equivalent Pd(1), four equivalent Pd(2), four equivalent Sb(1), and four equivalent Sb(2) atoms. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 8-coordinate geometry to four equivalent Ce(1) and four equivalent Sb(2) atoms. In the second Pd site, Pd(2) is bonded in a 5-coordinate geometry to four equivalent Ce(1), one Sb(2), and four equivalent Sb(1) atoms. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 8-coordinate geometry to four equivalent Ce(1) and four equivalent Pd(2) atoms. In the second Sb site, Sb(2) is bonded in a 9-coordinate geometry to four equivalent Ce(1), one Pd(2), and four equivalent Pd(1) atoms. is represented by the CIF card [CIF]
data_Ce(SbPd)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.674
_cell_length_b   4.674
_cell_length_c   10.471
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   228.722
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.000  0.500  0.241  1.0
  Ce  Ce1  1  0.500  0.000  0.759  1.0
  Sb  Sb2  1  0.000  0.000  0.500  1.0
  Sb  Sb3  1  0.500  0.500  0.500  1.0
  Sb  Sb4  1  0.000  0.500  0.871  1.0
  Sb  Sb5  1  0.500  0.000  0.129  1.0
  Pd  Pd6  1  0.000  0.000  0.000  1.0
  Pd  Pd7  1  0.500  0.500  0.000  1.0
  Pd  Pd8  1  0.000  0.500  0.625  1.0
  Pd  Pd9  1  0.500  0.000  0.375  1.0
[/CIF]
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