The material described by Rb2SbCl6 crystallizes in the cubic Fm-3m space group. Rb(1) is bonded to twelve equivalent Cl(1) atoms to form RbCl12 cuboctahedra that share corners with twelve equivalent Rb(1)Cl12 cuboctahedra, faces with six equivalent Rb(1)Cl12 cuboctahedra, and faces with four equivalent Sb(1)Cl6 octahedra. Sb(1) is bonded to six equivalent Cl(1) atoms to form SbCl6 octahedra that share faces with eight equivalent Rb(1)Cl12 cuboctahedra. Cl(1) is bonded to four equivalent Rb(1) and one Sb(1) atom to form a mixture of distorted face, corner, and edge-sharing ClRb4Sb square pyramids. is represented by the CIF file [CIF]
data_Rb2SbCl6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.206
_cell_length_b   7.206
_cell_length_c   7.206
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   264.544
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.250  0.250  0.250  1.0
  Rb  Rb1  1  0.750  0.750  0.750  1.0
  Sb  Sb2  1  0.000  0.000  0.000  1.0
  Cl  Cl3  1  0.753  0.247  0.247  1.0
  Cl  Cl4  1  0.247  0.753  0.753  1.0
  Cl  Cl5  1  0.247  0.753  0.247  1.0
  Cl  Cl6  1  0.753  0.247  0.753  1.0
  Cl  Cl7  1  0.247  0.247  0.753  1.0
  Cl  Cl8  1  0.753  0.753  0.247  1.0
[/CIF]
.
The material described by Rb2SbCl6 crystallizes in the cubic Fm-3m space group. Rb(1) is bonded to twelve equivalent Cl(1) atoms to form RbCl12 cuboctahedra that share corners with twelve equivalent Rb(1)Cl12 cuboctahedra, faces with six equivalent Rb(1)Cl12 cuboctahedra, and faces with four equivalent Sb(1)Cl6 octahedra. Sb(1) is bonded to six equivalent Cl(1) atoms to form SbCl6 octahedra that share faces with eight equivalent Rb(1)Cl12 cuboctahedra. Cl(1) is bonded to four equivalent Rb(1) and one Sb(1) atom to form a mixture of distorted face, corner, and edge-sharing ClRb4Sb square pyramids. is represented by the CIF file [CIF]
data_Rb2SbCl6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.206
_cell_length_b   7.206
_cell_length_c   7.206
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   264.544
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.250  0.250  0.250  1.0
  Rb  Rb1  1  0.750  0.750  0.750  1.0
  Sb  Sb2  1  0.000  0.000  0.000  1.0
  Cl  Cl3  1  0.753  0.247  0.247  1.0
  Cl  Cl4  1  0.247  0.753  0.753  1.0
  Cl  Cl5  1  0.247  0.753  0.247  1.0
  Cl  Cl6  1  0.753  0.247  0.753  1.0
  Cl  Cl7  1  0.247  0.247  0.753  1.0
  Cl  Cl8  1  0.753  0.753  0.247  1.0
[/CIF]
.