The compound described by Sm5(PtIn2)2 crystallizes in the orthorhombic Pbam space group. There are three inequivalent Sm sites. In the first Sm site, Sm(1) is bonded in a 2-coordinate geometry to two equivalent Pt(1), two equivalent In(1), and four equivalent In(2) atoms. In the second Sm site, Sm(2) is bonded in a 10-coordinate geometry to four equivalent Pt(1), two equivalent In(2), and four equivalent In(1) atoms. In the third Sm site, Sm(3) is bonded in a distorted body-centered cubic geometry to four equivalent In(1) and four equivalent In(2) atoms. Pt(1) is bonded in a 8-coordinate geometry to two equivalent Sm(1), four equivalent Sm(2), one In(2), and two equivalent In(1) atoms. There are two inequivalent In sites. In the first In site, In(1) is bonded in a 11-coordinate geometry to two equivalent Sm(1), two equivalent Sm(3), four equivalent Sm(2), two equivalent Pt(1), and one In(2) atom. In the second In site, In(2) is bonded in a 10-coordinate geometry to two equivalent Sm(2), two equivalent Sm(3), four equivalent Sm(1), one Pt(1), and one In(1) atom. is represented by the CIF card [CIF]
data_Sm5(In2Pt)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.724
_cell_length_b   8.185
_cell_length_c   18.477
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   563.234
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sm  Sm0  1  0.000  0.116  0.416  1.0
  Sm  Sm1  1  0.000  0.884  0.584  1.0
  Sm  Sm2  1  0.000  0.384  0.916  1.0
  Sm  Sm3  1  0.000  0.616  0.084  1.0
  Sm  Sm4  1  0.000  0.242  0.221  1.0
  Sm  Sm5  1  0.000  0.758  0.779  1.0
  Sm  Sm6  1  0.000  0.258  0.721  1.0
  Sm  Sm7  1  0.000  0.742  0.279  1.0
  Sm  Sm8  1  0.000  0.000  0.000  1.0
  Sm  Sm9  1  0.000  0.500  0.500  1.0
  In  In10  1  0.500  0.427  0.351  1.0
  In  In11  1  0.500  0.573  0.649  1.0
  In  In12  1  0.500  0.073  0.851  1.0
  In  In13  1  0.500  0.927  0.149  1.0
  In  In14  1  0.500  0.289  0.070  1.0
  In  In15  1  0.500  0.711  0.930  1.0
  In  In16  1  0.500  0.211  0.570  1.0
  In  In17  1  0.500  0.789  0.430  1.0
  Pt  Pt18  1  0.500  0.023  0.304  1.0
  Pt  Pt19  1  0.500  0.977  0.696  1.0
  Pt  Pt20  1  0.500  0.477  0.804  1.0
  Pt  Pt21  1  0.500  0.523  0.196  1.0
[/CIF]
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The compound described by Sm5(PtIn2)2 crystallizes in the orthorhombic Pbam space group. There are three inequivalent Sm sites. In the first Sm site, Sm(1) is bonded in a 2-coordinate geometry to two equivalent Pt(1), two equivalent In(1), and four equivalent In(2) atoms. In the second Sm site, Sm(2) is bonded in a 10-coordinate geometry to four equivalent Pt(1), two equivalent In(2), and four equivalent In(1) atoms. In the third Sm site, Sm(3) is bonded in a distorted body-centered cubic geometry to four equivalent In(1) and four equivalent In(2) atoms. Pt(1) is bonded in a 8-coordinate geometry to two equivalent Sm(1), four equivalent Sm(2), one In(2), and two equivalent In(1) atoms. There are two inequivalent In sites. In the first In site, In(1) is bonded in a 11-coordinate geometry to two equivalent Sm(1), two equivalent Sm(3), four equivalent Sm(2), two equivalent Pt(1), and one In(2) atom. In the second In site, In(2) is bonded in a 10-coordinate geometry to two equivalent Sm(2), two equivalent Sm(3), four equivalent Sm(1), one Pt(1), and one In(1) atom. is represented by the CIF card [CIF]
data_Sm5(In2Pt)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.724
_cell_length_b   8.185
_cell_length_c   18.477
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   563.234
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sm  Sm0  1  0.000  0.116  0.416  1.0
  Sm  Sm1  1  0.000  0.884  0.584  1.0
  Sm  Sm2  1  0.000  0.384  0.916  1.0
  Sm  Sm3  1  0.000  0.616  0.084  1.0
  Sm  Sm4  1  0.000  0.242  0.221  1.0
  Sm  Sm5  1  0.000  0.758  0.779  1.0
  Sm  Sm6  1  0.000  0.258  0.721  1.0
  Sm  Sm7  1  0.000  0.742  0.279  1.0
  Sm  Sm8  1  0.000  0.000  0.000  1.0
  Sm  Sm9  1  0.000  0.500  0.500  1.0
  In  In10  1  0.500  0.427  0.351  1.0
  In  In11  1  0.500  0.573  0.649  1.0
  In  In12  1  0.500  0.073  0.851  1.0
  In  In13  1  0.500  0.927  0.149  1.0
  In  In14  1  0.500  0.289  0.070  1.0
  In  In15  1  0.500  0.711  0.930  1.0
  In  In16  1  0.500  0.211  0.570  1.0
  In  In17  1  0.500  0.789  0.430  1.0
  Pt  Pt18  1  0.500  0.023  0.304  1.0
  Pt  Pt19  1  0.500  0.977  0.696  1.0
  Pt  Pt20  1  0.500  0.477  0.804  1.0
  Pt  Pt21  1  0.500  0.523  0.196  1.0
[/CIF]
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