The structure described by NaZnSiHO4 crystallizes in the orthorhombic P2_12_12_1 space group. Na(1) is bonded to one O(2), two equivalent O(1), and two equivalent O(4) atoms to form distorted NaO5 trigonal bipyramids that share corners with three equivalent Zn(1)O4 tetrahedra, corners with five equivalent Si(1)O4 tetrahedra, and corners with four equivalent Na(1)O5 trigonal bipyramids. Zn(1) is bonded to one O(1), one O(2), and two equivalent O(3) atoms to form ZnO4 tetrahedra that share corners with two equivalent Zn(1)O4 tetrahedra, corners with four equivalent Si(1)O4 tetrahedra, and corners with three equivalent Na(1)O5 trigonal bipyramids. Si(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form SiO4 tetrahedra that share corners with four equivalent Zn(1)O4 tetrahedra and corners with five equivalent Na(1)O5 trigonal bipyramids. H(1) is bonded in a distorted linear geometry to one O(2) and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Na(1), one Zn(1), and one Si(1) atom to form distorted corner-sharing ONa2ZnSi tetrahedra. In the second O site, O(2) is bonded in a 4-coordinate geometry to one Na(1), one Zn(1), one Si(1), and one H(1) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to two equivalent Zn(1) and one Si(1) atom. In the fourth O site, O(4) is bonded in a 2-coordinate geometry to two equivalent Na(1), one Si(1), and one H(1) atom. is represented by the CIF card [CIF]
data_NaZnSiHO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.225
_cell_length_b   7.761
_cell_length_c   9.496
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   385.047
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.024  0.205  0.334  1.0
  Na  Na1  1  0.524  0.295  0.666  1.0
  Na  Na2  1  0.976  0.705  0.166  1.0
  Na  Na3  1  0.476  0.795  0.834  1.0
  Zn  Zn4  1  0.478  0.889  0.489  1.0
  Zn  Zn5  1  0.978  0.611  0.511  1.0
  Zn  Zn6  1  0.522  0.389  0.011  1.0
  Zn  Zn7  1  0.022  0.111  0.989  1.0
  Si  Si8  1  0.511  0.015  0.161  1.0
  Si  Si9  1  0.011  0.485  0.839  1.0
  Si  Si10  1  0.489  0.515  0.339  1.0
  Si  Si11  1  0.989  0.985  0.661  1.0
  H  H12  1  0.974  0.780  0.875  1.0
  H  H13  1  0.474  0.720  0.125  1.0
  H  H14  1  0.026  0.280  0.625  1.0
  H  H15  1  0.526  0.220  0.375  1.0
  O  O16  1  0.823  0.019  0.149  1.0
  O  O17  1  0.323  0.481  0.851  1.0
  O  O18  1  0.177  0.519  0.351  1.0
  O  O19  1  0.677  0.981  0.649  1.0
  O  O20  1  0.423  0.040  0.326  1.0
  O  O21  1  0.923  0.460  0.674  1.0
  O  O22  1  0.577  0.540  0.174  1.0
  O  O23  1  0.077  0.960  0.826  1.0
  O  O24  1  0.634  0.668  0.430  1.0
  O  O25  1  0.134  0.832  0.570  1.0
  O  O26  1  0.366  0.168  0.070  1.0
  O  O27  1  0.866  0.332  0.930  1.0
  O  O28  1  0.608  0.333  0.407  1.0
  O  O29  1  0.108  0.167  0.593  1.0
  O  O30  1  0.392  0.833  0.093  1.0
  O  O31  1  0.892  0.667  0.907  1.0
[/CIF]
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The structure described by NaZnSiHO4 crystallizes in the orthorhombic P2_12_12_1 space group. Na(1) is bonded to one O(2), two equivalent O(1), and two equivalent O(4) atoms to form distorted NaO5 trigonal bipyramids that share corners with three equivalent Zn(1)O4 tetrahedra, corners with five equivalent Si(1)O4 tetrahedra, and corners with four equivalent Na(1)O5 trigonal bipyramids. Zn(1) is bonded to one O(1), one O(2), and two equivalent O(3) atoms to form ZnO4 tetrahedra that share corners with two equivalent Zn(1)O4 tetrahedra, corners with four equivalent Si(1)O4 tetrahedra, and corners with three equivalent Na(1)O5 trigonal bipyramids. Si(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form SiO4 tetrahedra that share corners with four equivalent Zn(1)O4 tetrahedra and corners with five equivalent Na(1)O5 trigonal bipyramids. H(1) is bonded in a distorted linear geometry to one O(2) and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Na(1), one Zn(1), and one Si(1) atom to form distorted corner-sharing ONa2ZnSi tetrahedra. In the second O site, O(2) is bonded in a 4-coordinate geometry to one Na(1), one Zn(1), one Si(1), and one H(1) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to two equivalent Zn(1) and one Si(1) atom. In the fourth O site, O(4) is bonded in a 2-coordinate geometry to two equivalent Na(1), one Si(1), and one H(1) atom. is represented by the CIF card [CIF]
data_NaZnSiHO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.225
_cell_length_b   7.761
_cell_length_c   9.496
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   385.047
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.024  0.205  0.334  1.0
  Na  Na1  1  0.524  0.295  0.666  1.0
  Na  Na2  1  0.976  0.705  0.166  1.0
  Na  Na3  1  0.476  0.795  0.834  1.0
  Zn  Zn4  1  0.478  0.889  0.489  1.0
  Zn  Zn5  1  0.978  0.611  0.511  1.0
  Zn  Zn6  1  0.522  0.389  0.011  1.0
  Zn  Zn7  1  0.022  0.111  0.989  1.0
  Si  Si8  1  0.511  0.015  0.161  1.0
  Si  Si9  1  0.011  0.485  0.839  1.0
  Si  Si10  1  0.489  0.515  0.339  1.0
  Si  Si11  1  0.989  0.985  0.661  1.0
  H  H12  1  0.974  0.780  0.875  1.0
  H  H13  1  0.474  0.720  0.125  1.0
  H  H14  1  0.026  0.280  0.625  1.0
  H  H15  1  0.526  0.220  0.375  1.0
  O  O16  1  0.823  0.019  0.149  1.0
  O  O17  1  0.323  0.481  0.851  1.0
  O  O18  1  0.177  0.519  0.351  1.0
  O  O19  1  0.677  0.981  0.649  1.0
  O  O20  1  0.423  0.040  0.326  1.0
  O  O21  1  0.923  0.460  0.674  1.0
  O  O22  1  0.577  0.540  0.174  1.0
  O  O23  1  0.077  0.960  0.826  1.0
  O  O24  1  0.634  0.668  0.430  1.0
  O  O25  1  0.134  0.832  0.570  1.0
  O  O26  1  0.366  0.168  0.070  1.0
  O  O27  1  0.866  0.332  0.930  1.0
  O  O28  1  0.608  0.333  0.407  1.0
  O  O29  1  0.108  0.167  0.593  1.0
  O  O30  1  0.392  0.833  0.093  1.0
  O  O31  1  0.892  0.667  0.907  1.0
[/CIF]
.