The structure described by Gd2MoO6 crystallizes in the monoclinic C2/c space group. There are three inequivalent Gd sites. In the first Gd site, Gd(1) is bonded in a 8-coordinate geometry to one O(4), one O(6), two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. In the second Gd site, Gd(2) is bonded in a distorted body-centered cubic geometry to two equivalent O(4), two equivalent O(6), and four equivalent O(1) atoms. In the third Gd site, Gd(3) is bonded in a 8-coordinate geometry to two equivalent O(4), two equivalent O(6), and four equivalent O(5) atoms. Mo(1) is bonded in a distorted trigonal bipyramidal geometry to one O(2), one O(3), one O(4), one O(5), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(5) is bonded in a 3-coordinate geometry to two equivalent Gd(3) and one Mo(1) atom. In the second O site, O(6) is bonded to one Gd(1), one Gd(2), one Gd(3), and one Mo(1) atom to form OGd3Mo tetrahedra that share corners with two equivalent O(6)Gd3Mo tetrahedra, corners with four equivalent O(1)Gd4 tetrahedra, and  an edgeedge with one O(1)Gd4 tetrahedra. In the third O site, O(1) is bonded to two equivalent Gd(1) and two equivalent Gd(2) atoms to form OGd4 tetrahedra that share corners with two equivalent O(1)Gd4 tetrahedra, corners with four equivalent O(6)Gd3Mo tetrahedra,  an edgeedge with one O(6)Gd3Mo tetrahedra, and edges with three equivalent O(1)Gd4 tetrahedra. In the fourth O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Gd(1) and one Mo(1) atom. In the fifth O site, O(3) is bonded in a 3-coordinate geometry to two equivalent Gd(1) and one Mo(1) atom. In the sixth O site, O(4) is bonded in a 4-coordinate geometry to one Gd(1), one Gd(2), one Gd(3), and one Mo(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Gd2MoO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.979
_cell_length_b   9.979
_cell_length_c   5.421
_cell_angle_alpha   74.948
_cell_angle_beta   74.948
_cell_angle_gamma   68.152
_symmetry_Int_Tables_number   1
_cell_volume   475.863
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Gd  Gd0  1  0.786  0.553  0.619  1.0
  Gd  Gd1  1  0.214  0.447  0.381  1.0
  Gd  Gd2  1  0.609  0.391  0.250  1.0
  Gd  Gd3  1  0.391  0.609  0.750  1.0
  Gd  Gd4  1  0.553  0.786  0.119  1.0
  Gd  Gd5  1  0.135  0.865  0.250  1.0
  Gd  Gd6  1  0.447  0.214  0.881  1.0
  Gd  Gd7  1  0.865  0.135  0.750  1.0
  Mo  Mo8  1  0.296  0.013  0.561  1.0
  Mo  Mo9  1  0.704  0.987  0.439  1.0
  Mo  Mo10  1  0.987  0.704  0.939  1.0
  Mo  Mo11  1  0.013  0.296  0.061  1.0
  O  O12  1  0.391  0.425  0.579  1.0
  O  O13  1  0.569  0.975  0.736  1.0
  O  O14  1  0.820  0.713  0.862  1.0
  O  O15  1  0.673  0.114  0.137  1.0
  O  O16  1  0.114  0.673  0.637  1.0
  O  O17  1  0.327  0.886  0.863  1.0
  O  O18  1  0.287  0.180  0.638  1.0
  O  O19  1  0.975  0.569  0.236  1.0
  O  O20  1  0.575  0.609  0.921  1.0
  O  O21  1  0.431  0.025  0.264  1.0
  O  O22  1  0.114  0.047  0.516  1.0
  O  O23  1  0.190  0.663  0.085  1.0
  O  O24  1  0.810  0.337  0.915  1.0
  O  O25  1  0.337  0.810  0.415  1.0
  O  O26  1  0.886  0.327  0.363  1.0
  O  O27  1  0.953  0.886  0.984  1.0
  O  O28  1  0.886  0.953  0.484  1.0
  O  O29  1  0.663  0.190  0.585  1.0
  O  O30  1  0.713  0.820  0.362  1.0
  O  O31  1  0.047  0.114  0.016  1.0
  O  O32  1  0.180  0.287  0.138  1.0
  O  O33  1  0.609  0.575  0.421  1.0
  O  O34  1  0.425  0.391  0.079  1.0
  O  O35  1  0.025  0.431  0.764  1.0
[/CIF]
.
The structure described by Gd2MoO6 crystallizes in the monoclinic C2/c space group. There are three inequivalent Gd sites. In the first Gd site, Gd(1) is bonded in a 8-coordinate geometry to one O(4), one O(6), two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. In the second Gd site, Gd(2) is bonded in a distorted body-centered cubic geometry to two equivalent O(4), two equivalent O(6), and four equivalent O(1) atoms. In the third Gd site, Gd(3) is bonded in a 8-coordinate geometry to two equivalent O(4), two equivalent O(6), and four equivalent O(5) atoms. Mo(1) is bonded in a distorted trigonal bipyramidal geometry to one O(2), one O(3), one O(4), one O(5), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(5) is bonded in a 3-coordinate geometry to two equivalent Gd(3) and one Mo(1) atom. In the second O site, O(6) is bonded to one Gd(1), one Gd(2), one Gd(3), and one Mo(1) atom to form OGd3Mo tetrahedra that share corners with two equivalent O(6)Gd3Mo tetrahedra, corners with four equivalent O(1)Gd4 tetrahedra, and  an edgeedge with one O(1)Gd4 tetrahedra. In the third O site, O(1) is bonded to two equivalent Gd(1) and two equivalent Gd(2) atoms to form OGd4 tetrahedra that share corners with two equivalent O(1)Gd4 tetrahedra, corners with four equivalent O(6)Gd3Mo tetrahedra,  an edgeedge with one O(6)Gd3Mo tetrahedra, and edges with three equivalent O(1)Gd4 tetrahedra. In the fourth O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Gd(1) and one Mo(1) atom. In the fifth O site, O(3) is bonded in a 3-coordinate geometry to two equivalent Gd(1) and one Mo(1) atom. In the sixth O site, O(4) is bonded in a 4-coordinate geometry to one Gd(1), one Gd(2), one Gd(3), and one Mo(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Gd2MoO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.979
_cell_length_b   9.979
_cell_length_c   5.421
_cell_angle_alpha   74.948
_cell_angle_beta   74.948
_cell_angle_gamma   68.152
_symmetry_Int_Tables_number   1
_cell_volume   475.863
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Gd  Gd0  1  0.786  0.553  0.619  1.0
  Gd  Gd1  1  0.214  0.447  0.381  1.0
  Gd  Gd2  1  0.609  0.391  0.250  1.0
  Gd  Gd3  1  0.391  0.609  0.750  1.0
  Gd  Gd4  1  0.553  0.786  0.119  1.0
  Gd  Gd5  1  0.135  0.865  0.250  1.0
  Gd  Gd6  1  0.447  0.214  0.881  1.0
  Gd  Gd7  1  0.865  0.135  0.750  1.0
  Mo  Mo8  1  0.296  0.013  0.561  1.0
  Mo  Mo9  1  0.704  0.987  0.439  1.0
  Mo  Mo10  1  0.987  0.704  0.939  1.0
  Mo  Mo11  1  0.013  0.296  0.061  1.0
  O  O12  1  0.391  0.425  0.579  1.0
  O  O13  1  0.569  0.975  0.736  1.0
  O  O14  1  0.820  0.713  0.862  1.0
  O  O15  1  0.673  0.114  0.137  1.0
  O  O16  1  0.114  0.673  0.637  1.0
  O  O17  1  0.327  0.886  0.863  1.0
  O  O18  1  0.287  0.180  0.638  1.0
  O  O19  1  0.975  0.569  0.236  1.0
  O  O20  1  0.575  0.609  0.921  1.0
  O  O21  1  0.431  0.025  0.264  1.0
  O  O22  1  0.114  0.047  0.516  1.0
  O  O23  1  0.190  0.663  0.085  1.0
  O  O24  1  0.810  0.337  0.915  1.0
  O  O25  1  0.337  0.810  0.415  1.0
  O  O26  1  0.886  0.327  0.363  1.0
  O  O27  1  0.953  0.886  0.984  1.0
  O  O28  1  0.886  0.953  0.484  1.0
  O  O29  1  0.663  0.190  0.585  1.0
  O  O30  1  0.713  0.820  0.362  1.0
  O  O31  1  0.047  0.114  0.016  1.0
  O  O32  1  0.180  0.287  0.138  1.0
  O  O33  1  0.609  0.575  0.421  1.0
  O  O34  1  0.425  0.391  0.079  1.0
  O  O35  1  0.025  0.431  0.764  1.0
[/CIF]
.