The compound described by NHS2(O2F)2 is Silicon tetrafluoride-derived structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of two imidodisulfurylfluoride molecules. N(1) is bonded in a distorted trigonal planar geometry to one H(1), one S(1), and one S(2) atom. H(1) is bonded in a single-bond geometry to one N(1) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded to one N(1), one O(1), one O(2), and one F(1) atom to form corner-sharing SNO2F tetrahedra. In the second S site, S(2) is bonded to one N(1), one O(3), one O(4), and one F(2) atom to form corner-sharing SNO2F tetrahedra. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(2) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one S(2) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one S(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one S(2) atom. is represented by the CIF file [CIF]
data_HS2N(O2F)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.978
_cell_length_b   5.297
_cell_length_c   6.926
_cell_angle_alpha   79.636
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   287.933
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.004  0.041  0.220  1.0
  H  H1  1  0.504  0.959  0.780  1.0
  S  S2  1  0.932  0.676  0.105  1.0
  S  S3  1  0.432  0.324  0.895  1.0
  S  S4  1  0.210  0.771  0.367  1.0
  S  S5  1  0.710  0.229  0.633  1.0
  N  N6  1  0.028  0.847  0.249  1.0
  N  N7  1  0.528  0.153  0.751  1.0
  O  O8  1  0.776  0.798  0.051  1.0
  O  O9  1  0.276  0.202  0.949  1.0
  O  O10  1  0.950  0.411  0.186  1.0
  O  O11  1  0.450  0.589  0.814  1.0
  O  O12  1  0.319  0.637  0.258  1.0
  O  O13  1  0.819  0.363  0.742  1.0
  O  O14  1  0.256  0.991  0.445  1.0
  O  O15  1  0.756  0.009  0.555  1.0
  F  F16  1  0.047  0.727  0.915  1.0
  F  F17  1  0.547  0.273  0.085  1.0
  F  F18  1  0.141  0.564  0.543  1.0
  F  F19  1  0.641  0.436  0.457  1.0
[/CIF]
.
The compound described by NHS2(O2F)2 is Silicon tetrafluoride-derived structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of two imidodisulfurylfluoride molecules. N(1) is bonded in a distorted trigonal planar geometry to one H(1), one S(1), and one S(2) atom. H(1) is bonded in a single-bond geometry to one N(1) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded to one N(1), one O(1), one O(2), and one F(1) atom to form corner-sharing SNO2F tetrahedra. In the second S site, S(2) is bonded to one N(1), one O(3), one O(4), and one F(2) atom to form corner-sharing SNO2F tetrahedra. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(2) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one S(2) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one S(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one S(2) atom. is represented by the CIF file [CIF]
data_HS2N(O2F)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.978
_cell_length_b   5.297
_cell_length_c   6.926
_cell_angle_alpha   79.636
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   287.933
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.004  0.041  0.220  1.0
  H  H1  1  0.504  0.959  0.780  1.0
  S  S2  1  0.932  0.676  0.105  1.0
  S  S3  1  0.432  0.324  0.895  1.0
  S  S4  1  0.210  0.771  0.367  1.0
  S  S5  1  0.710  0.229  0.633  1.0
  N  N6  1  0.028  0.847  0.249  1.0
  N  N7  1  0.528  0.153  0.751  1.0
  O  O8  1  0.776  0.798  0.051  1.0
  O  O9  1  0.276  0.202  0.949  1.0
  O  O10  1  0.950  0.411  0.186  1.0
  O  O11  1  0.450  0.589  0.814  1.0
  O  O12  1  0.319  0.637  0.258  1.0
  O  O13  1  0.819  0.363  0.742  1.0
  O  O14  1  0.256  0.991  0.445  1.0
  O  O15  1  0.756  0.009  0.555  1.0
  F  F16  1  0.047  0.727  0.915  1.0
  F  F17  1  0.547  0.273  0.085  1.0
  F  F18  1  0.141  0.564  0.543  1.0
  F  F19  1  0.641  0.436  0.457  1.0
[/CIF]
.