The compound described by Te(MoO4)3N2 crystallizes in the hexagonal P6_3 space group. The structure consists of four ammonia atoms inside a Te(MoO4)3 framework. In the Te(MoO4)3 framework, Mo(1) is bonded to one O(2), one O(4), two equivalent O(1), and two equivalent O(3) atoms to form distorted MoO6 octahedra that share corners with two equivalent Te(1)O6 octahedra and corners with four equivalent Mo(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 21-47°. Te(1) is bonded to three equivalent O(2) and three equivalent O(4) atoms to form TeO6 octahedra that share corners with six equivalent Mo(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-47°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to two equivalent Mo(1) atoms. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Mo(1) and one Te(1) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to two equivalent Mo(1) atoms. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Mo(1) and one Te(1) atom. is represented by the CIF card [CIF]
data_TeMo3(NO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.481
_cell_length_b   7.481
_cell_length_c   11.743
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   569.215
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.000  0.000  0.633  1.0
  Te  Te1  1  0.000  0.000  0.133  1.0
  Mo  Mo2  1  0.797  0.115  0.883  1.0
  Mo  Mo3  1  0.318  0.203  0.883  1.0
  Mo  Mo4  1  0.885  0.682  0.883  1.0
  Mo  Mo5  1  0.203  0.885  0.383  1.0
  Mo  Mo6  1  0.682  0.797  0.383  1.0
  Mo  Mo7  1  0.115  0.318  0.383  1.0
  N  N8  1  0.667  0.333  0.598  1.0
  N  N9  1  0.333  0.667  0.098  1.0
  N  N10  1  0.333  0.667  0.713  1.0
  N  N11  1  0.667  0.333  0.213  1.0
  O  O12  1  0.129  0.280  0.883  1.0
  O  O13  1  0.151  0.871  0.883  1.0
  O  O14  1  0.720  0.849  0.883  1.0
  O  O15  1  0.871  0.720  0.383  1.0
  O  O16  1  0.849  0.129  0.383  1.0
  O  O17  1  0.280  0.151  0.383  1.0
  O  O18  1  0.132  0.257  0.543  1.0
  O  O19  1  0.125  0.868  0.543  1.0
  O  O20  1  0.743  0.875  0.543  1.0
  O  O21  1  0.868  0.743  0.043  1.0
  O  O22  1  0.875  0.132  0.043  1.0
  O  O23  1  0.257  0.125  0.043  1.0
  O  O24  1  0.554  0.099  0.883  1.0
  O  O25  1  0.545  0.446  0.883  1.0
  O  O26  1  0.901  0.455  0.883  1.0
  O  O27  1  0.446  0.901  0.383  1.0
  O  O28  1  0.455  0.554  0.383  1.0
  O  O29  1  0.099  0.545  0.383  1.0
  O  O30  1  0.876  0.131  0.723  1.0
  O  O31  1  0.256  0.124  0.723  1.0
  O  O32  1  0.869  0.744  0.723  1.0
  O  O33  1  0.124  0.869  0.223  1.0
  O  O34  1  0.744  0.876  0.223  1.0
  O  O35  1  0.131  0.256  0.223  1.0
[/CIF]
.
The compound described by Te(MoO4)3N2 crystallizes in the hexagonal P6_3 space group. The structure consists of four ammonia atoms inside a Te(MoO4)3 framework. In the Te(MoO4)3 framework, Mo(1) is bonded to one O(2), one O(4), two equivalent O(1), and two equivalent O(3) atoms to form distorted MoO6 octahedra that share corners with two equivalent Te(1)O6 octahedra and corners with four equivalent Mo(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 21-47°. Te(1) is bonded to three equivalent O(2) and three equivalent O(4) atoms to form TeO6 octahedra that share corners with six equivalent Mo(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-47°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to two equivalent Mo(1) atoms. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Mo(1) and one Te(1) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to two equivalent Mo(1) atoms. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Mo(1) and one Te(1) atom. is represented by the CIF card [CIF]
data_TeMo3(NO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.481
_cell_length_b   7.481
_cell_length_c   11.743
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   569.215
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.000  0.000  0.633  1.0
  Te  Te1  1  0.000  0.000  0.133  1.0
  Mo  Mo2  1  0.797  0.115  0.883  1.0
  Mo  Mo3  1  0.318  0.203  0.883  1.0
  Mo  Mo4  1  0.885  0.682  0.883  1.0
  Mo  Mo5  1  0.203  0.885  0.383  1.0
  Mo  Mo6  1  0.682  0.797  0.383  1.0
  Mo  Mo7  1  0.115  0.318  0.383  1.0
  N  N8  1  0.667  0.333  0.598  1.0
  N  N9  1  0.333  0.667  0.098  1.0
  N  N10  1  0.333  0.667  0.713  1.0
  N  N11  1  0.667  0.333  0.213  1.0
  O  O12  1  0.129  0.280  0.883  1.0
  O  O13  1  0.151  0.871  0.883  1.0
  O  O14  1  0.720  0.849  0.883  1.0
  O  O15  1  0.871  0.720  0.383  1.0
  O  O16  1  0.849  0.129  0.383  1.0
  O  O17  1  0.280  0.151  0.383  1.0
  O  O18  1  0.132  0.257  0.543  1.0
  O  O19  1  0.125  0.868  0.543  1.0
  O  O20  1  0.743  0.875  0.543  1.0
  O  O21  1  0.868  0.743  0.043  1.0
  O  O22  1  0.875  0.132  0.043  1.0
  O  O23  1  0.257  0.125  0.043  1.0
  O  O24  1  0.554  0.099  0.883  1.0
  O  O25  1  0.545  0.446  0.883  1.0
  O  O26  1  0.901  0.455  0.883  1.0
  O  O27  1  0.446  0.901  0.383  1.0
  O  O28  1  0.455  0.554  0.383  1.0
  O  O29  1  0.099  0.545  0.383  1.0
  O  O30  1  0.876  0.131  0.723  1.0
  O  O31  1  0.256  0.124  0.723  1.0
  O  O32  1  0.869  0.744  0.723  1.0
  O  O33  1  0.124  0.869  0.223  1.0
  O  O34  1  0.744  0.876  0.223  1.0
  O  O35  1  0.131  0.256  0.223  1.0
[/CIF]
.