The crystal structure described by CdGe(BiO3)2 crystallizes in the orthorhombic Pbcn space group. Cd(1) is bonded in a 6-coordinate geometry to two equivalent O(2) and four equivalent O(3) atoms. Ge(1) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent O(2) atoms. Bi(1) is bonded in a 5-coordinate geometry to one O(2), two equivalent O(1), and two equivalent O(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Ge(1) and two equivalent Bi(1) atoms. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Cd(1), one Ge(1), and one Bi(1) atom. In the third O site, O(3) is bonded to two equivalent Cd(1) and two equivalent Bi(1) atoms to form a mixture of distorted edge and corner-sharing OCd2Bi2 tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_CdGe(BiO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.709
_cell_length_b   10.351
_cell_length_c   10.586
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   625.598
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.250  0.386  0.500  1.0
  Cd  Cd1  1  0.750  0.614  0.500  1.0
  Cd  Cd2  1  0.750  0.114  0.000  1.0
  Cd  Cd3  1  0.250  0.886  0.000  1.0
  Ge  Ge4  1  0.250  0.846  0.500  1.0
  Ge  Ge5  1  0.750  0.654  0.000  1.0
  Ge  Ge6  1  0.750  0.154  0.500  1.0
  Ge  Ge7  1  0.250  0.346  0.000  1.0
  Bi  Bi8  1  0.215  0.607  0.241  1.0
  Bi  Bi9  1  0.785  0.393  0.759  1.0
  Bi  Bi10  1  0.715  0.393  0.241  1.0
  Bi  Bi11  1  0.215  0.107  0.259  1.0
  Bi  Bi12  1  0.285  0.607  0.759  1.0
  Bi  Bi13  1  0.785  0.893  0.741  1.0
  Bi  Bi14  1  0.285  0.107  0.741  1.0
  Bi  Bi15  1  0.715  0.893  0.259  1.0
  O  O16  1  0.125  0.944  0.622  1.0
  O  O17  1  0.965  0.250  0.578  1.0
  O  O18  1  0.013  0.470  0.353  1.0
  O  O19  1  0.035  0.750  0.422  1.0
  O  O20  1  0.625  0.056  0.622  1.0
  O  O21  1  0.987  0.030  0.853  1.0
  O  O22  1  0.513  0.030  0.147  1.0
  O  O23  1  0.487  0.970  0.853  1.0
  O  O24  1  0.875  0.556  0.122  1.0
  O  O25  1  0.375  0.944  0.378  1.0
  O  O26  1  0.535  0.250  0.422  1.0
  O  O27  1  0.987  0.530  0.647  1.0
  O  O28  1  0.465  0.750  0.578  1.0
  O  O29  1  0.487  0.470  0.647  1.0
  O  O30  1  0.875  0.056  0.378  1.0
  O  O31  1  0.465  0.250  0.922  1.0
  O  O32  1  0.035  0.250  0.078  1.0
  O  O33  1  0.013  0.970  0.147  1.0
  O  O34  1  0.513  0.530  0.353  1.0
  O  O35  1  0.375  0.444  0.122  1.0
  O  O36  1  0.125  0.444  0.878  1.0
  O  O37  1  0.965  0.750  0.922  1.0
  O  O38  1  0.625  0.556  0.878  1.0
  O  O39  1  0.535  0.750  0.078  1.0
[/CIF]
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The crystal structure described by CdGe(BiO3)2 crystallizes in the orthorhombic Pbcn space group. Cd(1) is bonded in a 6-coordinate geometry to two equivalent O(2) and four equivalent O(3) atoms. Ge(1) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent O(2) atoms. Bi(1) is bonded in a 5-coordinate geometry to one O(2), two equivalent O(1), and two equivalent O(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Ge(1) and two equivalent Bi(1) atoms. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Cd(1), one Ge(1), and one Bi(1) atom. In the third O site, O(3) is bonded to two equivalent Cd(1) and two equivalent Bi(1) atoms to form a mixture of distorted edge and corner-sharing OCd2Bi2 tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_CdGe(BiO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.709
_cell_length_b   10.351
_cell_length_c   10.586
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   625.598
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.250  0.386  0.500  1.0
  Cd  Cd1  1  0.750  0.614  0.500  1.0
  Cd  Cd2  1  0.750  0.114  0.000  1.0
  Cd  Cd3  1  0.250  0.886  0.000  1.0
  Ge  Ge4  1  0.250  0.846  0.500  1.0
  Ge  Ge5  1  0.750  0.654  0.000  1.0
  Ge  Ge6  1  0.750  0.154  0.500  1.0
  Ge  Ge7  1  0.250  0.346  0.000  1.0
  Bi  Bi8  1  0.215  0.607  0.241  1.0
  Bi  Bi9  1  0.785  0.393  0.759  1.0
  Bi  Bi10  1  0.715  0.393  0.241  1.0
  Bi  Bi11  1  0.215  0.107  0.259  1.0
  Bi  Bi12  1  0.285  0.607  0.759  1.0
  Bi  Bi13  1  0.785  0.893  0.741  1.0
  Bi  Bi14  1  0.285  0.107  0.741  1.0
  Bi  Bi15  1  0.715  0.893  0.259  1.0
  O  O16  1  0.125  0.944  0.622  1.0
  O  O17  1  0.965  0.250  0.578  1.0
  O  O18  1  0.013  0.470  0.353  1.0
  O  O19  1  0.035  0.750  0.422  1.0
  O  O20  1  0.625  0.056  0.622  1.0
  O  O21  1  0.987  0.030  0.853  1.0
  O  O22  1  0.513  0.030  0.147  1.0
  O  O23  1  0.487  0.970  0.853  1.0
  O  O24  1  0.875  0.556  0.122  1.0
  O  O25  1  0.375  0.944  0.378  1.0
  O  O26  1  0.535  0.250  0.422  1.0
  O  O27  1  0.987  0.530  0.647  1.0
  O  O28  1  0.465  0.750  0.578  1.0
  O  O29  1  0.487  0.470  0.647  1.0
  O  O30  1  0.875  0.056  0.378  1.0
  O  O31  1  0.465  0.250  0.922  1.0
  O  O32  1  0.035  0.250  0.078  1.0
  O  O33  1  0.013  0.970  0.147  1.0
  O  O34  1  0.513  0.530  0.353  1.0
  O  O35  1  0.375  0.444  0.122  1.0
  O  O36  1  0.125  0.444  0.878  1.0
  O  O37  1  0.965  0.750  0.922  1.0
  O  O38  1  0.625  0.556  0.878  1.0
  O  O39  1  0.535  0.750  0.078  1.0
[/CIF]
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