The crystal structure described by N3S4ICl2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four ICl2 clusters and four N3S4 clusters. In each ICl2 cluster, I(1) is bonded in a linear geometry to one Cl(1) and one Cl(2) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one I(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one I(1) atom. In each N3S4 cluster, there are three inequivalent N sites. In the first N site, N(1) is bonded in a bent 150 degrees geometry to one S(2) and one S(4) atom. In the second N site, N(2) is bonded in a bent 150 degrees geometry to one S(3) and one S(4) atom. In the third N site, N(3) is bonded in a bent 150 degrees geometry to one S(1) and one S(2) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a distorted single-bond geometry to one N(3) atom. In the second S site, S(2) is bonded in a bent 120 degrees geometry to one N(1) and one N(3) atom. In the third S site, S(3) is bonded in a distorted single-bond geometry to one N(2) atom. In the fourth S site, S(4) is bonded in a bent 120 degrees geometry to one N(1) and one N(2) atom. is represented by the CIF card [CIF]
data_S4IN3Cl2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.255
_cell_length_b   6.463
_cell_length_c   18.219
_cell_angle_alpha   87.041
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1088.314
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  S  S0  1  0.256  0.783  0.240  1.0
  S  S1  1  0.397  0.992  0.106  1.0
  S  S2  1  0.157  0.535  0.186  1.0
  S  S3  1  0.744  0.217  0.760  1.0
  S  S4  1  0.603  0.008  0.894  1.0
  S  S5  1  0.756  0.217  0.260  1.0
  S  S6  1  0.757  0.350  0.469  1.0
  S  S7  1  0.897  0.008  0.394  1.0
  S  S8  1  0.243  0.650  0.531  1.0
  S  S9  1  0.657  0.465  0.314  1.0
  S  S10  1  0.103  0.992  0.606  1.0
  S  S11  1  0.343  0.535  0.686  1.0
  S  S12  1  0.743  0.350  0.969  1.0
  S  S13  1  0.244  0.783  0.740  1.0
  S  S14  1  0.843  0.465  0.814  1.0
  S  S15  1  0.257  0.650  0.031  1.0
  I  I16  1  0.710  0.776  0.628  1.0
  I  I17  1  0.290  0.224  0.372  1.0
  I  I18  1  0.210  0.224  0.872  1.0
  I  I19  1  0.790  0.776  0.128  1.0
  N  N20  1  0.851  0.148  0.459  1.0
  N  N21  1  0.310  0.544  0.602  1.0
  N  N22  1  0.810  0.456  0.898  1.0
  N  N23  1  0.351  0.852  0.041  1.0
  N  N24  1  0.343  0.929  0.184  1.0
  N  N25  1  0.690  0.456  0.398  1.0
  N  N26  1  0.843  0.071  0.316  1.0
  N  N27  1  0.149  0.852  0.541  1.0
  N  N28  1  0.190  0.544  0.102  1.0
  N  N29  1  0.649  0.148  0.959  1.0
  N  N30  1  0.657  0.071  0.816  1.0
  N  N31  1  0.157  0.929  0.684  1.0
  Cl  Cl32  1  0.089  0.510  0.347  1.0
  Cl  Cl33  1  0.911  0.490  0.653  1.0
  Cl  Cl34  1  0.589  0.490  0.153  1.0
  Cl  Cl35  1  0.411  0.510  0.847  1.0
  Cl  Cl36  1  0.482  0.953  0.392  1.0
  Cl  Cl37  1  0.518  0.047  0.608  1.0
  Cl  Cl38  1  0.018  0.953  0.892  1.0
  Cl  Cl39  1  0.982  0.047  0.108  1.0
[/CIF]
.
The crystal structure described by N3S4ICl2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four ICl2 clusters and four N3S4 clusters. In each ICl2 cluster, I(1) is bonded in a linear geometry to one Cl(1) and one Cl(2) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one I(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one I(1) atom. In each N3S4 cluster, there are three inequivalent N sites. In the first N site, N(1) is bonded in a bent 150 degrees geometry to one S(2) and one S(4) atom. In the second N site, N(2) is bonded in a bent 150 degrees geometry to one S(3) and one S(4) atom. In the third N site, N(3) is bonded in a bent 150 degrees geometry to one S(1) and one S(2) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a distorted single-bond geometry to one N(3) atom. In the second S site, S(2) is bonded in a bent 120 degrees geometry to one N(1) and one N(3) atom. In the third S site, S(3) is bonded in a distorted single-bond geometry to one N(2) atom. In the fourth S site, S(4) is bonded in a bent 120 degrees geometry to one N(1) and one N(2) atom. is represented by the CIF card [CIF]
data_S4IN3Cl2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.255
_cell_length_b   6.463
_cell_length_c   18.219
_cell_angle_alpha   87.041
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1088.314
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  S  S0  1  0.256  0.783  0.240  1.0
  S  S1  1  0.397  0.992  0.106  1.0
  S  S2  1  0.157  0.535  0.186  1.0
  S  S3  1  0.744  0.217  0.760  1.0
  S  S4  1  0.603  0.008  0.894  1.0
  S  S5  1  0.756  0.217  0.260  1.0
  S  S6  1  0.757  0.350  0.469  1.0
  S  S7  1  0.897  0.008  0.394  1.0
  S  S8  1  0.243  0.650  0.531  1.0
  S  S9  1  0.657  0.465  0.314  1.0
  S  S10  1  0.103  0.992  0.606  1.0
  S  S11  1  0.343  0.535  0.686  1.0
  S  S12  1  0.743  0.350  0.969  1.0
  S  S13  1  0.244  0.783  0.740  1.0
  S  S14  1  0.843  0.465  0.814  1.0
  S  S15  1  0.257  0.650  0.031  1.0
  I  I16  1  0.710  0.776  0.628  1.0
  I  I17  1  0.290  0.224  0.372  1.0
  I  I18  1  0.210  0.224  0.872  1.0
  I  I19  1  0.790  0.776  0.128  1.0
  N  N20  1  0.851  0.148  0.459  1.0
  N  N21  1  0.310  0.544  0.602  1.0
  N  N22  1  0.810  0.456  0.898  1.0
  N  N23  1  0.351  0.852  0.041  1.0
  N  N24  1  0.343  0.929  0.184  1.0
  N  N25  1  0.690  0.456  0.398  1.0
  N  N26  1  0.843  0.071  0.316  1.0
  N  N27  1  0.149  0.852  0.541  1.0
  N  N28  1  0.190  0.544  0.102  1.0
  N  N29  1  0.649  0.148  0.959  1.0
  N  N30  1  0.657  0.071  0.816  1.0
  N  N31  1  0.157  0.929  0.684  1.0
  Cl  Cl32  1  0.089  0.510  0.347  1.0
  Cl  Cl33  1  0.911  0.490  0.653  1.0
  Cl  Cl34  1  0.589  0.490  0.153  1.0
  Cl  Cl35  1  0.411  0.510  0.847  1.0
  Cl  Cl36  1  0.482  0.953  0.392  1.0
  Cl  Cl37  1  0.518  0.047  0.608  1.0
  Cl  Cl38  1  0.018  0.953  0.892  1.0
  Cl  Cl39  1  0.982  0.047  0.108  1.0
[/CIF]
.