The material structure described by Zn2SO6 crystallizes in the orthorhombic P2_12_12_1 space group. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(2), one O(3), and two equivalent O(4) atoms to form distorted ZnO5 trigonal bipyramids that share corners with three equivalent Zn(2)O4 tetrahedra, corners with three equivalent S(1)O4 tetrahedra, and corners with two equivalent Zn(1)O5 trigonal bipyramids. In the second Zn site, Zn(2) is bonded to one O(2), one O(4), one O(5), and one O(6) atom to form distorted ZnO4 tetrahedra that share corners with two equivalent S(1)O4 tetrahedra and corners with three equivalent Zn(1)O5 trigonal bipyramids. S(1) is bonded to one O(1), one O(2), one O(3), and one O(5) atom to form SO4 tetrahedra that share corners with two equivalent Zn(2)O4 tetrahedra and corners with three equivalent Zn(1)O5 trigonal bipyramids. There are six inequivalent O sites. In the first O site, O(6) is bonded in a single-bond geometry to one Zn(2) atom. In the second O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one S(1) atom. In the third O site, O(2) is bonded in a distorted trigonal planar geometry to one Zn(1), one Zn(2), and one S(1) atom. In the fourth O site, O(3) is bonded in a bent 150 degrees geometry to one Zn(1) and one S(1) atom. In the fifth O site, O(4) is bonded in a trigonal planar geometry to one Zn(2) and two equivalent Zn(1) atoms. In the sixth O site, O(5) is bonded in a bent 150 degrees geometry to one Zn(2) and one S(1) atom. is represented by the CIF file [CIF]
data_Zn2SO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.638
_cell_length_b   6.767
_cell_length_c   14.992
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   470.595
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.736  0.055  0.495  1.0
  Zn  Zn1  1  0.764  0.945  0.995  1.0
  Zn  Zn2  1  0.236  0.445  0.505  1.0
  Zn  Zn3  1  0.264  0.555  0.005  1.0
  Zn  Zn4  1  0.642  0.359  0.346  1.0
  Zn  Zn5  1  0.858  0.641  0.846  1.0
  Zn  Zn6  1  0.142  0.141  0.654  1.0
  Zn  Zn7  1  0.358  0.859  0.154  1.0
  S  S8  1  0.270  0.802  0.371  1.0
  S  S9  1  0.230  0.198  0.871  1.0
  S  S10  1  0.770  0.698  0.629  1.0
  S  S11  1  0.730  0.302  0.129  1.0
  O  O12  1  0.007  0.821  0.424  1.0
  O  O13  1  0.493  0.179  0.924  1.0
  O  O14  1  0.507  0.679  0.576  1.0
  O  O15  1  0.993  0.321  0.076  1.0
  O  O16  1  0.405  0.603  0.396  1.0
  O  O17  1  0.095  0.397  0.896  1.0
  O  O18  1  0.905  0.897  0.604  1.0
  O  O19  1  0.595  0.103  0.104  1.0
  O  O20  1  0.484  0.960  0.390  1.0
  O  O21  1  0.016  0.040  0.890  1.0
  O  O22  1  0.984  0.540  0.610  1.0
  O  O23  1  0.516  0.460  0.110  1.0
  O  O24  1  0.913  0.298  0.441  1.0
  O  O25  1  0.587  0.702  0.941  1.0
  O  O26  1  0.413  0.202  0.559  1.0
  O  O27  1  0.087  0.798  0.059  1.0
  O  O28  1  0.206  0.800  0.274  1.0
  O  O29  1  0.294  0.200  0.774  1.0
  O  O30  1  0.706  0.700  0.726  1.0
  O  O31  1  0.794  0.300  0.226  1.0
  O  O32  1  0.255  0.235  0.338  1.0
  O  O33  1  0.245  0.765  0.838  1.0
  O  O34  1  0.755  0.265  0.662  1.0
  O  O35  1  0.745  0.735  0.162  1.0
[/CIF]
.
The material structure described by Zn2SO6 crystallizes in the orthorhombic P2_12_12_1 space group. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(2), one O(3), and two equivalent O(4) atoms to form distorted ZnO5 trigonal bipyramids that share corners with three equivalent Zn(2)O4 tetrahedra, corners with three equivalent S(1)O4 tetrahedra, and corners with two equivalent Zn(1)O5 trigonal bipyramids. In the second Zn site, Zn(2) is bonded to one O(2), one O(4), one O(5), and one O(6) atom to form distorted ZnO4 tetrahedra that share corners with two equivalent S(1)O4 tetrahedra and corners with three equivalent Zn(1)O5 trigonal bipyramids. S(1) is bonded to one O(1), one O(2), one O(3), and one O(5) atom to form SO4 tetrahedra that share corners with two equivalent Zn(2)O4 tetrahedra and corners with three equivalent Zn(1)O5 trigonal bipyramids. There are six inequivalent O sites. In the first O site, O(6) is bonded in a single-bond geometry to one Zn(2) atom. In the second O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one S(1) atom. In the third O site, O(2) is bonded in a distorted trigonal planar geometry to one Zn(1), one Zn(2), and one S(1) atom. In the fourth O site, O(3) is bonded in a bent 150 degrees geometry to one Zn(1) and one S(1) atom. In the fifth O site, O(4) is bonded in a trigonal planar geometry to one Zn(2) and two equivalent Zn(1) atoms. In the sixth O site, O(5) is bonded in a bent 150 degrees geometry to one Zn(2) and one S(1) atom. is represented by the CIF file [CIF]
data_Zn2SO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.638
_cell_length_b   6.767
_cell_length_c   14.992
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   470.595
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.736  0.055  0.495  1.0
  Zn  Zn1  1  0.764  0.945  0.995  1.0
  Zn  Zn2  1  0.236  0.445  0.505  1.0
  Zn  Zn3  1  0.264  0.555  0.005  1.0
  Zn  Zn4  1  0.642  0.359  0.346  1.0
  Zn  Zn5  1  0.858  0.641  0.846  1.0
  Zn  Zn6  1  0.142  0.141  0.654  1.0
  Zn  Zn7  1  0.358  0.859  0.154  1.0
  S  S8  1  0.270  0.802  0.371  1.0
  S  S9  1  0.230  0.198  0.871  1.0
  S  S10  1  0.770  0.698  0.629  1.0
  S  S11  1  0.730  0.302  0.129  1.0
  O  O12  1  0.007  0.821  0.424  1.0
  O  O13  1  0.493  0.179  0.924  1.0
  O  O14  1  0.507  0.679  0.576  1.0
  O  O15  1  0.993  0.321  0.076  1.0
  O  O16  1  0.405  0.603  0.396  1.0
  O  O17  1  0.095  0.397  0.896  1.0
  O  O18  1  0.905  0.897  0.604  1.0
  O  O19  1  0.595  0.103  0.104  1.0
  O  O20  1  0.484  0.960  0.390  1.0
  O  O21  1  0.016  0.040  0.890  1.0
  O  O22  1  0.984  0.540  0.610  1.0
  O  O23  1  0.516  0.460  0.110  1.0
  O  O24  1  0.913  0.298  0.441  1.0
  O  O25  1  0.587  0.702  0.941  1.0
  O  O26  1  0.413  0.202  0.559  1.0
  O  O27  1  0.087  0.798  0.059  1.0
  O  O28  1  0.206  0.800  0.274  1.0
  O  O29  1  0.294  0.200  0.774  1.0
  O  O30  1  0.706  0.700  0.726  1.0
  O  O31  1  0.794  0.300  0.226  1.0
  O  O32  1  0.255  0.235  0.338  1.0
  O  O33  1  0.245  0.765  0.838  1.0
  O  O34  1  0.755  0.265  0.662  1.0
  O  O35  1  0.745  0.735  0.162  1.0
[/CIF]
.