The structure described by N2(Sb4F13)2 is Indium-derived structured and crystallizes in the tetragonal I4/m space group. The structure is zero-dimensional and consists of two ammonia atoms and two Sb4F13 clusters. In each Sb4F13 cluster, Sb(1) is bonded in a 3-coordinate geometry to one F(1), one F(2), and two equivalent F(3) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(2) is bonded in a square co-planar geometry to four equivalent Sb(1) atoms. In the third F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. is represented by the CIF card [CIF]
data_Sb4NF13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.751
_cell_length_b   7.751
_cell_length_c   7.751
_cell_angle_alpha   98.845
_cell_angle_beta   98.845
_cell_angle_gamma   133.825
_symmetry_Int_Tables_number   1
_cell_volume   309.066
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.733  0.004  0.737  1.0
  Sb  Sb1  1  0.267  0.996  0.263  1.0
  Sb  Sb2  1  0.004  0.267  0.271  1.0
  Sb  Sb3  1  0.996  0.733  0.729  1.0
  N  N4  1  0.500  0.500  0.000  1.0
  F  F5  1  0.891  0.427  0.318  1.0
  F  F6  1  0.109  0.573  0.682  1.0
  F  F7  1  0.427  0.109  0.536  1.0
  F  F8  1  0.573  0.891  0.464  1.0
  F  F9  1  0.000  0.000  0.000  1.0
  F  F10  1  0.658  0.973  0.089  1.0
  F  F11  1  0.342  0.027  0.911  1.0
  F  F12  1  0.885  0.570  0.911  1.0
  F  F13  1  0.973  0.885  0.315  1.0
  F  F14  1  0.115  0.430  0.089  1.0
  F  F15  1  0.027  0.115  0.685  1.0
  F  F16  1  0.570  0.658  0.685  1.0
  F  F17  1  0.430  0.342  0.315  1.0
[/CIF]
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The structure described by N2(Sb4F13)2 is Indium-derived structured and crystallizes in the tetragonal I4/m space group. The structure is zero-dimensional and consists of two ammonia atoms and two Sb4F13 clusters. In each Sb4F13 cluster, Sb(1) is bonded in a 3-coordinate geometry to one F(1), one F(2), and two equivalent F(3) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(2) is bonded in a square co-planar geometry to four equivalent Sb(1) atoms. In the third F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. is represented by the CIF card [CIF]
data_Sb4NF13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.751
_cell_length_b   7.751
_cell_length_c   7.751
_cell_angle_alpha   98.845
_cell_angle_beta   98.845
_cell_angle_gamma   133.825
_symmetry_Int_Tables_number   1
_cell_volume   309.066
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.733  0.004  0.737  1.0
  Sb  Sb1  1  0.267  0.996  0.263  1.0
  Sb  Sb2  1  0.004  0.267  0.271  1.0
  Sb  Sb3  1  0.996  0.733  0.729  1.0
  N  N4  1  0.500  0.500  0.000  1.0
  F  F5  1  0.891  0.427  0.318  1.0
  F  F6  1  0.109  0.573  0.682  1.0
  F  F7  1  0.427  0.109  0.536  1.0
  F  F8  1  0.573  0.891  0.464  1.0
  F  F9  1  0.000  0.000  0.000  1.0
  F  F10  1  0.658  0.973  0.089  1.0
  F  F11  1  0.342  0.027  0.911  1.0
  F  F12  1  0.885  0.570  0.911  1.0
  F  F13  1  0.973  0.885  0.315  1.0
  F  F14  1  0.115  0.430  0.089  1.0
  F  F15  1  0.027  0.115  0.685  1.0
  F  F16  1  0.570  0.658  0.685  1.0
  F  F17  1  0.430  0.342  0.315  1.0
[/CIF]
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