The structure described by Na(RuO2)4 crystallizes in the tetragonal I4/m space group. Na(1) is bonded in a body-centered cubic geometry to eight equivalent O(1) atoms. Ru(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form a mixture of edge and corner-sharing RuO6 octahedra. The corner-sharing octahedral tilt angles are 53°. There are two inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Na(1) and three equivalent Ru(1) atoms to form a mixture of distorted edge and corner-sharing ONa2Ru3 trigonal bipyramids. In the second O site, O(2) is bonded in a trigonal planar geometry to three equivalent Ru(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Na(RuO2)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.096
_cell_length_b   7.096
_cell_length_c   7.096
_cell_angle_alpha   92.864
_cell_angle_beta   92.864
_cell_angle_gamma   154.169
_symmetry_Int_Tables_number   1
_cell_volume   151.759
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.000  0.000  0.000  1.0
  Ru  Ru1  1  0.672  0.150  0.822  1.0
  Ru  Ru2  1  0.328  0.850  0.178  1.0
  Ru  Ru3  1  0.150  0.328  0.478  1.0
  Ru  Ru4  1  0.850  0.672  0.522  1.0
  O  O5  1  0.692  0.358  0.051  1.0
  O  O6  1  0.308  0.642  0.949  1.0
  O  O7  1  0.358  0.308  0.666  1.0
  O  O8  1  0.642  0.692  0.334  1.0
  O  O9  1  0.951  0.341  0.292  1.0
  O  O10  1  0.049  0.659  0.708  1.0
  O  O11  1  0.341  0.049  0.389  1.0
  O  O12  1  0.659  0.951  0.611  1.0
[/CIF]
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The structure described by Na(RuO2)4 crystallizes in the tetragonal I4/m space group. Na(1) is bonded in a body-centered cubic geometry to eight equivalent O(1) atoms. Ru(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form a mixture of edge and corner-sharing RuO6 octahedra. The corner-sharing octahedral tilt angles are 53°. There are two inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Na(1) and three equivalent Ru(1) atoms to form a mixture of distorted edge and corner-sharing ONa2Ru3 trigonal bipyramids. In the second O site, O(2) is bonded in a trigonal planar geometry to three equivalent Ru(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Na(RuO2)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.096
_cell_length_b   7.096
_cell_length_c   7.096
_cell_angle_alpha   92.864
_cell_angle_beta   92.864
_cell_angle_gamma   154.169
_symmetry_Int_Tables_number   1
_cell_volume   151.759
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.000  0.000  0.000  1.0
  Ru  Ru1  1  0.672  0.150  0.822  1.0
  Ru  Ru2  1  0.328  0.850  0.178  1.0
  Ru  Ru3  1  0.150  0.328  0.478  1.0
  Ru  Ru4  1  0.850  0.672  0.522  1.0
  O  O5  1  0.692  0.358  0.051  1.0
  O  O6  1  0.308  0.642  0.949  1.0
  O  O7  1  0.358  0.308  0.666  1.0
  O  O8  1  0.642  0.692  0.334  1.0
  O  O9  1  0.951  0.341  0.292  1.0
  O  O10  1  0.049  0.659  0.708  1.0
  O  O11  1  0.341  0.049  0.389  1.0
  O  O12  1  0.659  0.951  0.611  1.0
[/CIF]
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