The crystal structure described by Ag3Ge5P6 crystallizes in the cubic I-43m space group. Ag(1) is bonded in a distorted L-shaped geometry to two equivalent Ge(2) and two equivalent P(1) atoms. There are two inequivalent Ge sites. In the first Ge site, Ge(2) is bonded in a 6-coordinate geometry to three equivalent Ag(1) and three equivalent P(1) atoms. In the second Ge site, Ge(1) is bonded to four equivalent P(1) atoms to form corner-sharing GeP4 tetrahedra. P(1) is bonded to one Ag(1), one Ge(2), and two equivalent Ge(1) atoms to form corner-sharing PAgGe3 tetrahedra. is represented by the CIF card [CIF]
data_Ag3Ge5P6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.968
_cell_length_b   8.968
_cell_length_c   8.968
_cell_angle_alpha   109.471
_cell_angle_beta   109.471
_cell_angle_gamma   109.471
_symmetry_Int_Tables_number   1
_cell_volume   555.130
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.804  1.000  0.804  1.0
  Ag  Ag1  1  0.196  0.196  1.000  1.0
  Ag  Ag2  1  0.804  0.804  1.000  1.0
  Ag  Ag3  1  1.000  0.196  0.196  1.0
  Ag  Ag4  1  1.000  0.804  0.804  1.0
  Ag  Ag5  1  0.196  1.000  0.196  1.0
  Ge  Ge6  1  0.500  0.250  0.750  1.0
  Ge  Ge7  1  0.750  0.250  0.500  1.0
  Ge  Ge8  1  0.250  0.750  0.500  1.0
  Ge  Ge9  1  0.750  0.500  0.250  1.0
  Ge  Ge10  1  0.425  0.425  0.425  1.0
  Ge  Ge11  1  1.000  0.575  1.000  1.0
  Ge  Ge12  1  0.575  1.000  1.000  1.0
  Ge  Ge13  1  1.000  1.000  0.575  1.0
  Ge  Ge14  1  0.250  0.500  0.750  1.0
  Ge  Ge15  1  0.500  0.750  0.250  1.0
  P  P16  1  0.511  0.511  0.743  1.0
  P  P17  1  0.000  0.233  0.489  1.0
  P  P18  1  0.233  0.000  0.489  1.0
  P  P19  1  0.767  0.257  0.767  1.0
  P  P20  1  0.257  0.767  0.767  1.0
  P  P21  1  0.743  0.511  0.511  1.0
  P  P22  1  0.511  0.743  0.511  1.0
  P  P23  1  0.233  0.489  0.000  1.0
  P  P24  1  0.489  0.233  0.000  1.0
  P  P25  1  0.767  0.767  0.257  1.0
  P  P26  1  0.489  0.000  0.233  1.0
  P  P27  1  0.000  0.489  0.233  1.0
[/CIF]
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The crystal structure described by Ag3Ge5P6 crystallizes in the cubic I-43m space group. Ag(1) is bonded in a distorted L-shaped geometry to two equivalent Ge(2) and two equivalent P(1) atoms. There are two inequivalent Ge sites. In the first Ge site, Ge(2) is bonded in a 6-coordinate geometry to three equivalent Ag(1) and three equivalent P(1) atoms. In the second Ge site, Ge(1) is bonded to four equivalent P(1) atoms to form corner-sharing GeP4 tetrahedra. P(1) is bonded to one Ag(1), one Ge(2), and two equivalent Ge(1) atoms to form corner-sharing PAgGe3 tetrahedra. is represented by the CIF card [CIF]
data_Ag3Ge5P6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.968
_cell_length_b   8.968
_cell_length_c   8.968
_cell_angle_alpha   109.471
_cell_angle_beta   109.471
_cell_angle_gamma   109.471
_symmetry_Int_Tables_number   1
_cell_volume   555.130
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.804  1.000  0.804  1.0
  Ag  Ag1  1  0.196  0.196  1.000  1.0
  Ag  Ag2  1  0.804  0.804  1.000  1.0
  Ag  Ag3  1  1.000  0.196  0.196  1.0
  Ag  Ag4  1  1.000  0.804  0.804  1.0
  Ag  Ag5  1  0.196  1.000  0.196  1.0
  Ge  Ge6  1  0.500  0.250  0.750  1.0
  Ge  Ge7  1  0.750  0.250  0.500  1.0
  Ge  Ge8  1  0.250  0.750  0.500  1.0
  Ge  Ge9  1  0.750  0.500  0.250  1.0
  Ge  Ge10  1  0.425  0.425  0.425  1.0
  Ge  Ge11  1  1.000  0.575  1.000  1.0
  Ge  Ge12  1  0.575  1.000  1.000  1.0
  Ge  Ge13  1  1.000  1.000  0.575  1.0
  Ge  Ge14  1  0.250  0.500  0.750  1.0
  Ge  Ge15  1  0.500  0.750  0.250  1.0
  P  P16  1  0.511  0.511  0.743  1.0
  P  P17  1  0.000  0.233  0.489  1.0
  P  P18  1  0.233  0.000  0.489  1.0
  P  P19  1  0.767  0.257  0.767  1.0
  P  P20  1  0.257  0.767  0.767  1.0
  P  P21  1  0.743  0.511  0.511  1.0
  P  P22  1  0.511  0.743  0.511  1.0
  P  P23  1  0.233  0.489  0.000  1.0
  P  P24  1  0.489  0.233  0.000  1.0
  P  P25  1  0.767  0.767  0.257  1.0
  P  P26  1  0.489  0.000  0.233  1.0
  P  P27  1  0.000  0.489  0.233  1.0
[/CIF]
.