The structure described by V2O2F3 crystallizes in the monoclinic C2/c space group. V(1) is bonded to three equivalent O(1), one F(2), and two equivalent F(1) atoms to form a mixture of corner and edge-sharing VO3F3 octahedra. The corner-sharing octahedral tilt angles range from 31-51°. O(1) is bonded in a distorted trigonal planar geometry to three equivalent V(1) atoms. There are two inequivalent F sites. In the first F site, F(2) is bonded in a bent 150 degrees geometry to two equivalent V(1) atoms. In the second F site, F(1) is bonded in a water-like geometry to two equivalent V(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_V2O2F3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.546
_cell_length_b   5.546
_cell_length_c   7.097
_cell_angle_alpha   71.166
_cell_angle_beta   71.166
_cell_angle_gamma   54.332
_symmetry_Int_Tables_number   1
_cell_volume   165.258
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.781  0.813  0.882  1.0
  V  V1  1  0.187  0.219  0.618  1.0
  V  V2  1  0.813  0.781  0.382  1.0
  V  V3  1  0.219  0.187  0.118  1.0
  O  O4  1  0.383  0.050  0.848  1.0
  O  O5  1  0.050  0.383  0.348  1.0
  O  O6  1  0.950  0.617  0.652  1.0
  O  O7  1  0.617  0.950  0.152  1.0
  F  F8  1  0.197  0.558  0.960  1.0
  F  F9  1  0.558  0.197  0.460  1.0
  F  F10  1  0.882  0.118  0.750  1.0
  F  F11  1  0.118  0.882  0.250  1.0
  F  F12  1  0.442  0.803  0.540  1.0
  F  F13  1  0.803  0.442  0.040  1.0
[/CIF]
.
The structure described by V2O2F3 crystallizes in the monoclinic C2/c space group. V(1) is bonded to three equivalent O(1), one F(2), and two equivalent F(1) atoms to form a mixture of corner and edge-sharing VO3F3 octahedra. The corner-sharing octahedral tilt angles range from 31-51°. O(1) is bonded in a distorted trigonal planar geometry to three equivalent V(1) atoms. There are two inequivalent F sites. In the first F site, F(2) is bonded in a bent 150 degrees geometry to two equivalent V(1) atoms. In the second F site, F(1) is bonded in a water-like geometry to two equivalent V(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_V2O2F3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.546
_cell_length_b   5.546
_cell_length_c   7.097
_cell_angle_alpha   71.166
_cell_angle_beta   71.166
_cell_angle_gamma   54.332
_symmetry_Int_Tables_number   1
_cell_volume   165.258
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.781  0.813  0.882  1.0
  V  V1  1  0.187  0.219  0.618  1.0
  V  V2  1  0.813  0.781  0.382  1.0
  V  V3  1  0.219  0.187  0.118  1.0
  O  O4  1  0.383  0.050  0.848  1.0
  O  O5  1  0.050  0.383  0.348  1.0
  O  O6  1  0.950  0.617  0.652  1.0
  O  O7  1  0.617  0.950  0.152  1.0
  F  F8  1  0.197  0.558  0.960  1.0
  F  F9  1  0.558  0.197  0.460  1.0
  F  F10  1  0.882  0.118  0.750  1.0
  F  F11  1  0.118  0.882  0.250  1.0
  F  F12  1  0.442  0.803  0.540  1.0
  F  F13  1  0.803  0.442  0.040  1.0
[/CIF]
.