The structure described by Li2SbP(OF3)2 crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded in a 3-coordinate geometry to one O(4), one F(4), one F(5), and one F(9) atom. In the second Li site, Li(2) is bonded in a 4-coordinate geometry to one O(3), one F(1), one F(3), and one F(6) atom. In the third Li site, Li(3) is bonded in a distorted see-saw-like geometry to one O(2), one F(10), one F(12), and one F(7) atom. In the fourth Li site, Li(4) is bonded in a distorted trigonal non-coplanar geometry to one F(1), one F(11), and one F(7) atom. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 6-coordinate geometry to one O(1), one O(3), one F(1), one F(4), one F(7), and one F(8) atom. In the second Sb site, Sb(2) is bonded in a 4-coordinate geometry to one F(12), one F(5), one F(6), and one F(9) atom. There are two inequivalent P sites. In the first P site, P(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one F(10), and one F(2) atom. In the second P site, P(2) is bonded in a tetrahedral geometry to one O(3), one O(4), one F(11), and one F(3) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Sb(1) and one P(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Li(3) and one P(1) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Li(2), one Sb(1), and one P(2) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Li(1) and one P(2) atom. There are twelve inequivalent F sites. In the first F site, F(1) is bonded in a distorted bent 150 degrees geometry to one Li(2), one Li(4), and one Sb(1) atom. In the second F site, F(2) is bonded in a distorted single-bond geometry to one P(1) atom. In the third F site, F(3) is bonded in a linear geometry to one Li(2) and one P(2) atom. In the fourth F site, F(4) is bonded in a distorted bent 150 degrees geometry to one Li(1) and one Sb(1) atom. In the fifth F site, F(5) is bonded in a distorted linear geometry to one Li(1) and one Sb(2) atom. In the sixth F site, F(6) is bonded in a bent 120 degrees geometry to one Li(2) and one Sb(2) atom. In the seventh F site, F(7) is bonded in a distorted trigonal non-coplanar geometry to one Li(3), one Li(4), and one Sb(1) atom. In the eighth F site, F(8) is bonded in a single-bond geometry to one Sb(1) atom. In the ninth F site, F(9) is bonded in a distorted L-shaped geometry to one Li(1) and one Sb(2) atom. In the tenth F site, F(10) is bonded in a linear geometry to one Li(3) and one P(1) atom. In the eleventh F site, F(11) is bonded in a linear geometry to one Li(4) and one P(2) atom. In the twelfth F site, F(12) is bonded in a water-like geometry to one Li(3) and one Sb(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li2SbP(OF3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.087
_cell_length_b   7.871
_cell_length_c   8.172
_cell_angle_alpha   88.157
_cell_angle_beta   85.617
_cell_angle_gamma   77.787
_symmetry_Int_Tables_number   1
_cell_volume   381.530
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.927  0.386  0.956  1.0
  Li  Li1  1  0.707  0.064  0.419  1.0
  Li  Li2  1  0.301  0.915  0.590  1.0
  Li  Li3  1  0.103  0.647  0.415  1.0
  Sb  Sb4  1  0.588  0.740  0.214  1.0
  Sb  Sb5  1  0.430  0.241  0.768  1.0
  P  P6  1  0.757  0.813  0.791  1.0
  P  P7  1  0.223  0.197  0.231  1.0
  O  O8  1  0.737  0.833  0.973  1.0
  O  O9  1  0.585  0.917  0.686  1.0
  O  O10  1  0.433  0.075  0.280  1.0
  O  O11  1  0.173  0.227  0.056  1.0
  F  F12  1  0.865  0.826  0.392  1.0
  F  F13  1  0.786  0.616  0.748  1.0
  F  F14  1  0.011  0.143  0.326  1.0
  F  F15  1  0.765  0.497  0.152  1.0
  F  F16  1  0.726  0.294  0.859  1.0
  F  F17  1  0.590  0.272  0.547  1.0
  F  F18  1  0.356  0.725  0.445  1.0
  F  F19  1  0.325  0.705  0.101  1.0
  F  F20  1  0.224  0.476  0.763  1.0
  F  F21  1  0.997  0.844  0.727  1.0
  F  F22  1  0.206  0.380  0.315  1.0
  F  F23  1  0.200  0.150  0.622  1.0
[/CIF]
.
The structure described by Li2SbP(OF3)2 crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded in a 3-coordinate geometry to one O(4), one F(4), one F(5), and one F(9) atom. In the second Li site, Li(2) is bonded in a 4-coordinate geometry to one O(3), one F(1), one F(3), and one F(6) atom. In the third Li site, Li(3) is bonded in a distorted see-saw-like geometry to one O(2), one F(10), one F(12), and one F(7) atom. In the fourth Li site, Li(4) is bonded in a distorted trigonal non-coplanar geometry to one F(1), one F(11), and one F(7) atom. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 6-coordinate geometry to one O(1), one O(3), one F(1), one F(4), one F(7), and one F(8) atom. In the second Sb site, Sb(2) is bonded in a 4-coordinate geometry to one F(12), one F(5), one F(6), and one F(9) atom. There are two inequivalent P sites. In the first P site, P(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one F(10), and one F(2) atom. In the second P site, P(2) is bonded in a tetrahedral geometry to one O(3), one O(4), one F(11), and one F(3) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Sb(1) and one P(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Li(3) and one P(1) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Li(2), one Sb(1), and one P(2) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Li(1) and one P(2) atom. There are twelve inequivalent F sites. In the first F site, F(1) is bonded in a distorted bent 150 degrees geometry to one Li(2), one Li(4), and one Sb(1) atom. In the second F site, F(2) is bonded in a distorted single-bond geometry to one P(1) atom. In the third F site, F(3) is bonded in a linear geometry to one Li(2) and one P(2) atom. In the fourth F site, F(4) is bonded in a distorted bent 150 degrees geometry to one Li(1) and one Sb(1) atom. In the fifth F site, F(5) is bonded in a distorted linear geometry to one Li(1) and one Sb(2) atom. In the sixth F site, F(6) is bonded in a bent 120 degrees geometry to one Li(2) and one Sb(2) atom. In the seventh F site, F(7) is bonded in a distorted trigonal non-coplanar geometry to one Li(3), one Li(4), and one Sb(1) atom. In the eighth F site, F(8) is bonded in a single-bond geometry to one Sb(1) atom. In the ninth F site, F(9) is bonded in a distorted L-shaped geometry to one Li(1) and one Sb(2) atom. In the tenth F site, F(10) is bonded in a linear geometry to one Li(3) and one P(1) atom. In the eleventh F site, F(11) is bonded in a linear geometry to one Li(4) and one P(2) atom. In the twelfth F site, F(12) is bonded in a water-like geometry to one Li(3) and one Sb(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li2SbP(OF3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.087
_cell_length_b   7.871
_cell_length_c   8.172
_cell_angle_alpha   88.157
_cell_angle_beta   85.617
_cell_angle_gamma   77.787
_symmetry_Int_Tables_number   1
_cell_volume   381.530
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.927  0.386  0.956  1.0
  Li  Li1  1  0.707  0.064  0.419  1.0
  Li  Li2  1  0.301  0.915  0.590  1.0
  Li  Li3  1  0.103  0.647  0.415  1.0
  Sb  Sb4  1  0.588  0.740  0.214  1.0
  Sb  Sb5  1  0.430  0.241  0.768  1.0
  P  P6  1  0.757  0.813  0.791  1.0
  P  P7  1  0.223  0.197  0.231  1.0
  O  O8  1  0.737  0.833  0.973  1.0
  O  O9  1  0.585  0.917  0.686  1.0
  O  O10  1  0.433  0.075  0.280  1.0
  O  O11  1  0.173  0.227  0.056  1.0
  F  F12  1  0.865  0.826  0.392  1.0
  F  F13  1  0.786  0.616  0.748  1.0
  F  F14  1  0.011  0.143  0.326  1.0
  F  F15  1  0.765  0.497  0.152  1.0
  F  F16  1  0.726  0.294  0.859  1.0
  F  F17  1  0.590  0.272  0.547  1.0
  F  F18  1  0.356  0.725  0.445  1.0
  F  F19  1  0.325  0.705  0.101  1.0
  F  F20  1  0.224  0.476  0.763  1.0
  F  F21  1  0.997  0.844  0.727  1.0
  F  F22  1  0.206  0.380  0.315  1.0
  F  F23  1  0.200  0.150  0.622  1.0
[/CIF]
.