The compound described by Li4V5Sn3O16 is Spinel-derived structured and crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(12), one O(15), and one O(3) atom to form LiO4 tetrahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Sn(1)O6 octahedra,  a cornercorner with one Sn(2)O6 octahedra, corners with two equivalent V(4)O6 octahedra, corners with two equivalent V(5)O6 octahedra, corners with two equivalent Sn(3)O6 octahedra, and corners with three equivalent V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-65°. In the second Li site, Li(2) is bonded in a distorted rectangular see-saw-like geometry to one O(14), one O(16), one O(5), and one O(9) atom. In the third Li site, Li(3) is bonded to one O(1), one O(10), one O(4), and one O(6) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Sn(1)O6 octahedra,  a cornercorner with one Sn(2)O6 octahedra, corners with three equivalent V(1)O6 octahedra,  an edgeedge with one V(4)O6 octahedra,  an edgeedge with one V(5)O6 octahedra, and  an edgeedge with one Sn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 59-66°. In the fourth Li site, Li(4) is bonded to one O(13), one O(2), one O(7), and one O(8) atom to form LiO4 tetrahedra that share  a cornercorner with one V(4)O6 octahedra,  a cornercorner with one V(5)O6 octahedra,  a cornercorner with one Sn(3)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent Sn(1)O6 octahedra, corners with two equivalent Sn(2)O6 octahedra, and corners with three equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-62°. There are five inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(10), one O(2), one O(6), one O(7), and one O(8) atom to form VO6 octahedra that share corners with two equivalent V(4)O6 octahedra, corners with two equivalent V(5)O6 octahedra, corners with two equivalent Sn(3)O6 octahedra, corners with three equivalent Li(3)O4 tetrahedra, corners with three equivalent Li(4)O4 tetrahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one Sn(1)O6 octahedra, and  an edgeedge with one Sn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-55°. In the second V site, V(2) is bonded to one O(14), one O(16), one O(3), one O(4), one O(7), and one O(8) atom to form VO6 octahedra that share corners with two equivalent V(3)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one V(1)O6 octahedra, edges with two equivalent Sn(1)O6 octahedra, and edges with two equivalent Sn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-50°. In the third V site, V(3) is bonded to one O(11), one O(12), one O(14), one O(15), one O(16), and one O(9) atom to form VO6 octahedra that share corners with two equivalent V(2)O6 octahedra, corners with two equivalent Sn(1)O6 octahedra, corners with two equivalent Sn(2)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra,  an edgeedge with one V(4)O6 octahedra,  an edgeedge with one V(5)O6 octahedra, and  an edgeedge with one Sn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-53°. In the fourth V site, V(4) is bonded to one O(10), one O(12), one O(13), one O(15), one O(5), and one O(6) atom to form VO6 octahedra that share corners with two equivalent V(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one V(3)O6 octahedra, edges with two equivalent V(5)O6 octahedra, edges with two equivalent Sn(3)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 50-55°. In the fifth V site, V(5) is bonded to one O(1), one O(10), one O(11), one O(13), one O(15), and one O(5) atom to form VO6 octahedra that share corners with two equivalent V(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one V(3)O6 octahedra, edges with two equivalent V(4)O6 octahedra, edges with two equivalent Sn(3)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles are 50°. There are three inequivalent Sn sites. In the first Sn site, Sn(1) is bonded to one O(14), one O(2), one O(3), one O(4), one O(7), and one O(9) atom to form SnO6 octahedra that share corners with two equivalent V(3)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one V(1)O6 octahedra, edges with two equivalent V(2)O6 octahedra, and edges with two equivalent Sn(2)O6 octahedra. The corner-sharing octahedral tilt angles are 53°. In the second Sn site, Sn(2) is bonded to one O(16), one O(2), one O(3), one O(4), one O(8), and one O(9) atom to form SnO6 octahedra that share corners with two equivalent V(3)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one V(1)O6 octahedra, edges with two equivalent V(2)O6 octahedra, and edges with two equivalent Sn(1)O6 octahedra. The corner-sharing octahedral tilt angles are 53°. In the third Sn site, Sn(3) is bonded to one O(1), one O(11), one O(12), one O(13), one O(5), and one O(6) atom to form SnO6 octahedra that share corners with two equivalent V(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one V(3)O6 octahedra, edges with two equivalent V(4)O6 octahedra, edges with two equivalent V(5)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 54-55°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one V(1), one V(5), and one Sn(3) atom. In the second O site, O(2) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), one V(1), one Sn(1), and one Sn(2) atom. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Li(1), one V(2), one Sn(1), and one Sn(2) atom. In the fourth O site, O(4) is bonded to one Li(3), one V(2), one Sn(1), and one Sn(2) atom to form distorted OLiVSn2 tetrahedra that share corners with two equivalent O(7)LiV2Sn tetrahedra, corners with two equivalent O(8)LiV2Sn tetrahedra, and  a cornercorner with one O(10)LiV3 trigonal pyramid. In the fifth O site, O(5) is bonded to one Li(2), one V(4), one V(5), and one Sn(3) atom to form distorted OLiV2Sn tetrahedra that share corners with two equivalent O(12)LiV2Sn tetrahedra, corners with two equivalent O(15)LiV3 tetrahedra, and  an edgeedge with one O(10)LiV3 trigonal pyramid. In the sixth O site, O(6) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one V(1), one V(4), and one Sn(3) atom. In the seventh O site, O(7) is bonded to one Li(4), one V(1), one V(2), and one Sn(1) atom to form distorted OLiV2Sn tetrahedra that share  a cornercorner with one O(8)LiV2Sn tetrahedra, corners with two equivalent O(4)LiVSn2 tetrahedra,  a cornercorner with one O(10)LiV3 trigonal pyramid, and  an edgeedge with one O(8)LiV2Sn tetrahedra. In the eighth O site, O(8) is bonded to one Li(4), one V(1), one V(2), and one Sn(2) atom to form distorted OLiV2Sn tetrahedra that share  a cornercorner with one O(7)LiV2Sn tetrahedra, corners with two equivalent O(4)LiVSn2 tetrahedra,  a cornercorner with one O(10)LiV3 trigonal pyramid, and  an edgeedge with one O(7)LiV2Sn tetrahedra. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one Li(2), one V(3), one Sn(1), and one Sn(2) atom. In the tenth O site, O(10) is bonded to one Li(3), one V(1), one V(4), and one V(5) atom to form distorted OLiV3 trigonal pyramids that share  a cornercorner with one O(12)LiV2Sn tetrahedra,  a cornercorner with one O(7)LiV2Sn tetrahedra,  a cornercorner with one O(8)LiV2Sn tetrahedra,  a cornercorner with one O(4)LiVSn2 tetrahedra, corners with two equivalent O(15)LiV3 tetrahedra, and  an edgeedge with one O(5)LiV2Sn tetrahedra. In the eleventh O site, O(11) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one V(3), one V(5), and one Sn(3) atom. In the twelfth O site, O(12) is bonded to one Li(1), one V(3), one V(4), and one Sn(3) atom to form distorted OLiV2Sn tetrahedra that share  a cornercorner with one O(15)LiV3 tetrahedra, corners with two equivalent O(5)LiV2Sn tetrahedra,  a cornercorner with one O(10)LiV3 trigonal pyramid, and  an edgeedge with one O(15)LiV3 tetrahedra. In the thirteenth O site, O(13) is bonded in a rectangular see-saw-like geometry to one Li(4), one V(4), one V(5), and one Sn(3) atom. In the fourteenth O site, O(14) is bonded in a rectangular see-saw-like geometry to one Li(2), one V(2), one V(3), and one Sn(1) atom. In the fifteenth O site, O(15) is bonded to one Li(1), one V(3), one V(4), and one V(5) atom to form distorted OLiV3 tetrahedra that share  a cornercorner with one O(12)LiV2Sn tetrahedra, corners with two equivalent O(5)LiV2Sn tetrahedra, corners with two equivalent O(10)LiV3 trigonal pyramids, and  an edgeedge with one O(12)LiV2Sn tetrahedra. In the sixteenth O site, O(16) is bonded in a rectangular see-saw-like geometry to one Li(2), one V(2), one V(3), and one Sn(2) atom. is represented by the CIF card [CIF]
data_Li4V5Sn3O16
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.115
_cell_length_b   6.144
_cell_length_c   9.733
_cell_angle_alpha   90.644
_cell_angle_beta   89.702
_cell_angle_gamma   119.724
_symmetry_Int_Tables_number   1
_cell_volume   317.550
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.328  0.652  0.891  1.0
  Li  Li1  1  0.012  0.025  0.992  1.0
  Li  Li2  1  0.005  0.012  0.500  1.0
  Li  Li3  1  0.667  0.331  0.396  1.0
  V  V4  1  0.328  0.663  0.490  1.0
  V  V5  1  0.169  0.338  0.214  1.0
  V  V6  1  0.666  0.327  0.986  1.0
  V  V7  1  0.338  0.169  0.711  1.0
  V  V8  1  0.825  0.166  0.714  1.0
  Sn  Sn9  1  0.661  0.830  0.214  1.0
  Sn  Sn10  1  0.169  0.830  0.213  1.0
  Sn  Sn11  1  0.830  0.660  0.714  1.0
  O  O12  1  0.669  0.842  0.600  1.0
  O  O13  1  0.480  0.964  0.346  1.0
  O  O14  1  0.334  0.666  0.097  1.0
  O  O15  1  0.999  0.001  0.317  1.0
  O  O16  1  0.993  0.005  0.810  1.0
  O  O17  1  0.170  0.843  0.600  1.0
  O  O18  1  0.475  0.516  0.342  1.0
  O  O19  1  0.040  0.517  0.342  1.0
  O  O20  1  0.839  0.676  0.091  1.0
  O  O21  1  0.148  0.321  0.610  1.0
  O  O22  1  0.959  0.469  0.841  1.0
  O  O23  1  0.512  0.467  0.841  1.0
  O  O24  1  0.677  0.329  0.601  1.0
  O  O25  1  0.842  0.170  0.102  1.0
  O  O26  1  0.538  0.044  0.833  1.0
  O  O27  1  0.328  0.168  0.100  1.0
[/CIF]
.
The compound described by Li4V5Sn3O16 is Spinel-derived structured and crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(12), one O(15), and one O(3) atom to form LiO4 tetrahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Sn(1)O6 octahedra,  a cornercorner with one Sn(2)O6 octahedra, corners with two equivalent V(4)O6 octahedra, corners with two equivalent V(5)O6 octahedra, corners with two equivalent Sn(3)O6 octahedra, and corners with three equivalent V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-65°. In the second Li site, Li(2) is bonded in a distorted rectangular see-saw-like geometry to one O(14), one O(16), one O(5), and one O(9) atom. In the third Li site, Li(3) is bonded to one O(1), one O(10), one O(4), and one O(6) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Sn(1)O6 octahedra,  a cornercorner with one Sn(2)O6 octahedra, corners with three equivalent V(1)O6 octahedra,  an edgeedge with one V(4)O6 octahedra,  an edgeedge with one V(5)O6 octahedra, and  an edgeedge with one Sn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 59-66°. In the fourth Li site, Li(4) is bonded to one O(13), one O(2), one O(7), and one O(8) atom to form LiO4 tetrahedra that share  a cornercorner with one V(4)O6 octahedra,  a cornercorner with one V(5)O6 octahedra,  a cornercorner with one Sn(3)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent Sn(1)O6 octahedra, corners with two equivalent Sn(2)O6 octahedra, and corners with three equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-62°. There are five inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(10), one O(2), one O(6), one O(7), and one O(8) atom to form VO6 octahedra that share corners with two equivalent V(4)O6 octahedra, corners with two equivalent V(5)O6 octahedra, corners with two equivalent Sn(3)O6 octahedra, corners with three equivalent Li(3)O4 tetrahedra, corners with three equivalent Li(4)O4 tetrahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one Sn(1)O6 octahedra, and  an edgeedge with one Sn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-55°. In the second V site, V(2) is bonded to one O(14), one O(16), one O(3), one O(4), one O(7), and one O(8) atom to form VO6 octahedra that share corners with two equivalent V(3)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one V(1)O6 octahedra, edges with two equivalent Sn(1)O6 octahedra, and edges with two equivalent Sn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-50°. In the third V site, V(3) is bonded to one O(11), one O(12), one O(14), one O(15), one O(16), and one O(9) atom to form VO6 octahedra that share corners with two equivalent V(2)O6 octahedra, corners with two equivalent Sn(1)O6 octahedra, corners with two equivalent Sn(2)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra,  an edgeedge with one V(4)O6 octahedra,  an edgeedge with one V(5)O6 octahedra, and  an edgeedge with one Sn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-53°. In the fourth V site, V(4) is bonded to one O(10), one O(12), one O(13), one O(15), one O(5), and one O(6) atom to form VO6 octahedra that share corners with two equivalent V(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one V(3)O6 octahedra, edges with two equivalent V(5)O6 octahedra, edges with two equivalent Sn(3)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 50-55°. In the fifth V site, V(5) is bonded to one O(1), one O(10), one O(11), one O(13), one O(15), and one O(5) atom to form VO6 octahedra that share corners with two equivalent V(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one V(3)O6 octahedra, edges with two equivalent V(4)O6 octahedra, edges with two equivalent Sn(3)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles are 50°. There are three inequivalent Sn sites. In the first Sn site, Sn(1) is bonded to one O(14), one O(2), one O(3), one O(4), one O(7), and one O(9) atom to form SnO6 octahedra that share corners with two equivalent V(3)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one V(1)O6 octahedra, edges with two equivalent V(2)O6 octahedra, and edges with two equivalent Sn(2)O6 octahedra. The corner-sharing octahedral tilt angles are 53°. In the second Sn site, Sn(2) is bonded to one O(16), one O(2), one O(3), one O(4), one O(8), and one O(9) atom to form SnO6 octahedra that share corners with two equivalent V(3)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one V(1)O6 octahedra, edges with two equivalent V(2)O6 octahedra, and edges with two equivalent Sn(1)O6 octahedra. The corner-sharing octahedral tilt angles are 53°. In the third Sn site, Sn(3) is bonded to one O(1), one O(11), one O(12), one O(13), one O(5), and one O(6) atom to form SnO6 octahedra that share corners with two equivalent V(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one V(3)O6 octahedra, edges with two equivalent V(4)O6 octahedra, edges with two equivalent V(5)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 54-55°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one V(1), one V(5), and one Sn(3) atom. In the second O site, O(2) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), one V(1), one Sn(1), and one Sn(2) atom. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Li(1), one V(2), one Sn(1), and one Sn(2) atom. In the fourth O site, O(4) is bonded to one Li(3), one V(2), one Sn(1), and one Sn(2) atom to form distorted OLiVSn2 tetrahedra that share corners with two equivalent O(7)LiV2Sn tetrahedra, corners with two equivalent O(8)LiV2Sn tetrahedra, and  a cornercorner with one O(10)LiV3 trigonal pyramid. In the fifth O site, O(5) is bonded to one Li(2), one V(4), one V(5), and one Sn(3) atom to form distorted OLiV2Sn tetrahedra that share corners with two equivalent O(12)LiV2Sn tetrahedra, corners with two equivalent O(15)LiV3 tetrahedra, and  an edgeedge with one O(10)LiV3 trigonal pyramid. In the sixth O site, O(6) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one V(1), one V(4), and one Sn(3) atom. In the seventh O site, O(7) is bonded to one Li(4), one V(1), one V(2), and one Sn(1) atom to form distorted OLiV2Sn tetrahedra that share  a cornercorner with one O(8)LiV2Sn tetrahedra, corners with two equivalent O(4)LiVSn2 tetrahedra,  a cornercorner with one O(10)LiV3 trigonal pyramid, and  an edgeedge with one O(8)LiV2Sn tetrahedra. In the eighth O site, O(8) is bonded to one Li(4), one V(1), one V(2), and one Sn(2) atom to form distorted OLiV2Sn tetrahedra that share  a cornercorner with one O(7)LiV2Sn tetrahedra, corners with two equivalent O(4)LiVSn2 tetrahedra,  a cornercorner with one O(10)LiV3 trigonal pyramid, and  an edgeedge with one O(7)LiV2Sn tetrahedra. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one Li(2), one V(3), one Sn(1), and one Sn(2) atom. In the tenth O site, O(10) is bonded to one Li(3), one V(1), one V(4), and one V(5) atom to form distorted OLiV3 trigonal pyramids that share  a cornercorner with one O(12)LiV2Sn tetrahedra,  a cornercorner with one O(7)LiV2Sn tetrahedra,  a cornercorner with one O(8)LiV2Sn tetrahedra,  a cornercorner with one O(4)LiVSn2 tetrahedra, corners with two equivalent O(15)LiV3 tetrahedra, and  an edgeedge with one O(5)LiV2Sn tetrahedra. In the eleventh O site, O(11) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one V(3), one V(5), and one Sn(3) atom. In the twelfth O site, O(12) is bonded to one Li(1), one V(3), one V(4), and one Sn(3) atom to form distorted OLiV2Sn tetrahedra that share  a cornercorner with one O(15)LiV3 tetrahedra, corners with two equivalent O(5)LiV2Sn tetrahedra,  a cornercorner with one O(10)LiV3 trigonal pyramid, and  an edgeedge with one O(15)LiV3 tetrahedra. In the thirteenth O site, O(13) is bonded in a rectangular see-saw-like geometry to one Li(4), one V(4), one V(5), and one Sn(3) atom. In the fourteenth O site, O(14) is bonded in a rectangular see-saw-like geometry to one Li(2), one V(2), one V(3), and one Sn(1) atom. In the fifteenth O site, O(15) is bonded to one Li(1), one V(3), one V(4), and one V(5) atom to form distorted OLiV3 tetrahedra that share  a cornercorner with one O(12)LiV2Sn tetrahedra, corners with two equivalent O(5)LiV2Sn tetrahedra, corners with two equivalent O(10)LiV3 trigonal pyramids, and  an edgeedge with one O(12)LiV2Sn tetrahedra. In the sixteenth O site, O(16) is bonded in a rectangular see-saw-like geometry to one Li(2), one V(2), one V(3), and one Sn(2) atom. is represented by the CIF card [CIF]
data_Li4V5Sn3O16
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.115
_cell_length_b   6.144
_cell_length_c   9.733
_cell_angle_alpha   90.644
_cell_angle_beta   89.702
_cell_angle_gamma   119.724
_symmetry_Int_Tables_number   1
_cell_volume   317.550
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.328  0.652  0.891  1.0
  Li  Li1  1  0.012  0.025  0.992  1.0
  Li  Li2  1  0.005  0.012  0.500  1.0
  Li  Li3  1  0.667  0.331  0.396  1.0
  V  V4  1  0.328  0.663  0.490  1.0
  V  V5  1  0.169  0.338  0.214  1.0
  V  V6  1  0.666  0.327  0.986  1.0
  V  V7  1  0.338  0.169  0.711  1.0
  V  V8  1  0.825  0.166  0.714  1.0
  Sn  Sn9  1  0.661  0.830  0.214  1.0
  Sn  Sn10  1  0.169  0.830  0.213  1.0
  Sn  Sn11  1  0.830  0.660  0.714  1.0
  O  O12  1  0.669  0.842  0.600  1.0
  O  O13  1  0.480  0.964  0.346  1.0
  O  O14  1  0.334  0.666  0.097  1.0
  O  O15  1  0.999  0.001  0.317  1.0
  O  O16  1  0.993  0.005  0.810  1.0
  O  O17  1  0.170  0.843  0.600  1.0
  O  O18  1  0.475  0.516  0.342  1.0
  O  O19  1  0.040  0.517  0.342  1.0
  O  O20  1  0.839  0.676  0.091  1.0
  O  O21  1  0.148  0.321  0.610  1.0
  O  O22  1  0.959  0.469  0.841  1.0
  O  O23  1  0.512  0.467  0.841  1.0
  O  O24  1  0.677  0.329  0.601  1.0
  O  O25  1  0.842  0.170  0.102  1.0
  O  O26  1  0.538  0.044  0.833  1.0
  O  O27  1  0.328  0.168  0.100  1.0
[/CIF]
.