The material described by NaAg3O2 crystallizes in the orthorhombic Ibam space group. Na(1) is bonded to four equivalent O(1) atoms to form distorted edge-sharing NaO4 tetrahedra. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a linear geometry to two equivalent O(1) atoms. In the second Ag site, Ag(2) is bonded in a linear geometry to two equivalent O(1) atoms. O(1) is bonded to two equivalent Na(1), one Ag(2), and two equivalent Ag(1) atoms to form a mixture of distorted corner and edge-sharing ONa2Ag3 trigonal bipyramids. is represented by the CIF card [CIF]
data_NaAg3O2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.956
_cell_length_b   6.108
_cell_length_c   6.735
_cell_angle_alpha   116.967
_cell_angle_beta   116.242
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   189.618
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.750  0.500  0.000  1.0
  Na  Na1  1  0.250  0.500  0.000  1.0
  Ag  Ag2  1  0.000  0.500  0.500  1.0
  Ag  Ag3  1  0.500  0.000  0.500  1.0
  Ag  Ag4  1  0.500  0.500  0.500  1.0
  Ag  Ag5  1  0.500  0.000  0.000  1.0
  Ag  Ag6  1  0.000  0.000  0.000  1.0
  Ag  Ag7  1  0.000  0.000  0.500  1.0
  O  O8  1  0.610  0.821  0.221  1.0
  O  O9  1  0.110  0.400  0.221  1.0
  O  O10  1  0.890  0.600  0.779  1.0
  O  O11  1  0.390  0.179  0.779  1.0
[/CIF]
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The material described by NaAg3O2 crystallizes in the orthorhombic Ibam space group. Na(1) is bonded to four equivalent O(1) atoms to form distorted edge-sharing NaO4 tetrahedra. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a linear geometry to two equivalent O(1) atoms. In the second Ag site, Ag(2) is bonded in a linear geometry to two equivalent O(1) atoms. O(1) is bonded to two equivalent Na(1), one Ag(2), and two equivalent Ag(1) atoms to form a mixture of distorted corner and edge-sharing ONa2Ag3 trigonal bipyramids. is represented by the CIF card [CIF]
data_NaAg3O2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.956
_cell_length_b   6.108
_cell_length_c   6.735
_cell_angle_alpha   116.967
_cell_angle_beta   116.242
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   189.618
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.750  0.500  0.000  1.0
  Na  Na1  1  0.250  0.500  0.000  1.0
  Ag  Ag2  1  0.000  0.500  0.500  1.0
  Ag  Ag3  1  0.500  0.000  0.500  1.0
  Ag  Ag4  1  0.500  0.500  0.500  1.0
  Ag  Ag5  1  0.500  0.000  0.000  1.0
  Ag  Ag6  1  0.000  0.000  0.000  1.0
  Ag  Ag7  1  0.000  0.000  0.500  1.0
  O  O8  1  0.610  0.821  0.221  1.0
  O  O9  1  0.110  0.400  0.221  1.0
  O  O10  1  0.890  0.600  0.779  1.0
  O  O11  1  0.390  0.179  0.779  1.0
[/CIF]
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