The crystal structure described by GeH2(CF2)2(CF3)2 is Indium-derived structured and crystallizes in the orthorhombic Fdd2 space group. The structure is zero-dimensional and consists of sixteen trifluoromethane molecules and eight GeH2(CF2)2 clusters. In each GeH2(CF2)2 cluster, Ge(1) is bonded in a tetrahedral geometry to two equivalent C(1) and two equivalent H(1) atoms. C(1) is bonded in a distorted water-like geometry to one Ge(1), one F(1), and one F(2) atom. H(1) is bonded in a single-bond geometry to one Ge(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one C(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one C(1) atom. is represented by the CIF card [CIF]
data_GeH2(C2F5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.814
_cell_length_b   10.190
_cell_length_c   10.316
_cell_angle_alpha   85.388
_cell_angle_beta   73.631
_cell_angle_gamma   73.424
_symmetry_Int_Tables_number   1
_cell_volume   562.065
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ge  Ge0  1  0.754  0.500  0.500  1.0
  Ge  Ge1  1  0.004  0.000  0.000  1.0
  H  H2  1  0.814  0.531  0.627  1.0
  H  H3  1  0.972  0.469  0.373  1.0
  H  H4  1  0.095  0.969  0.127  1.0
  H  H5  1  0.190  0.031  0.873  1.0
  C  C6  1  0.593  0.344  0.543  1.0
  C  C7  1  0.480  0.656  0.457  1.0
  C  C8  1  0.687  0.156  0.043  1.0
  C  C9  1  0.887  0.844  0.957  1.0
  C  C10  1  0.778  0.199  0.535  1.0
  C  C11  1  0.512  0.801  0.465  1.0
  C  C12  1  0.727  0.301  0.035  1.0
  C  C13  1  0.063  0.699  0.965  1.0
  F  F14  1  0.449  0.345  0.457  1.0
  F  F15  1  0.251  0.655  0.543  1.0
  F  F16  1  0.543  0.155  0.957  1.0
  F  F17  1  0.656  0.845  0.043  1.0
  F  F18  1  0.438  0.360  0.673  1.0
  F  F19  1  0.471  0.640  0.327  1.0
  F  F20  1  0.548  0.140  0.173  1.0
  F  F21  1  0.861  0.860  0.827  1.0
  F  F22  1  0.923  0.172  0.406  1.0
  F  F23  1  0.501  0.828  0.594  1.0
  F  F24  1  0.844  0.328  0.906  1.0
  F  F25  1  0.079  0.672  0.094  1.0
  F  F26  1  0.930  0.192  0.616  1.0
  F  F27  1  0.737  0.808  0.384  1.0
  F  F28  1  0.872  0.308  0.116  1.0
  F  F29  1  0.295  0.692  0.884  1.0
  F  F30  1  0.656  0.101  0.574  1.0
  F  F31  1  0.332  0.899  0.426  1.0
  F  F32  1  0.507  0.399  0.074  1.0
  F  F33  1  0.980  0.601  0.926  1.0
[/CIF]
.
The crystal structure described by GeH2(CF2)2(CF3)2 is Indium-derived structured and crystallizes in the orthorhombic Fdd2 space group. The structure is zero-dimensional and consists of sixteen trifluoromethane molecules and eight GeH2(CF2)2 clusters. In each GeH2(CF2)2 cluster, Ge(1) is bonded in a tetrahedral geometry to two equivalent C(1) and two equivalent H(1) atoms. C(1) is bonded in a distorted water-like geometry to one Ge(1), one F(1), and one F(2) atom. H(1) is bonded in a single-bond geometry to one Ge(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one C(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one C(1) atom. is represented by the CIF card [CIF]
data_GeH2(C2F5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.814
_cell_length_b   10.190
_cell_length_c   10.316
_cell_angle_alpha   85.388
_cell_angle_beta   73.631
_cell_angle_gamma   73.424
_symmetry_Int_Tables_number   1
_cell_volume   562.065
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ge  Ge0  1  0.754  0.500  0.500  1.0
  Ge  Ge1  1  0.004  0.000  0.000  1.0
  H  H2  1  0.814  0.531  0.627  1.0
  H  H3  1  0.972  0.469  0.373  1.0
  H  H4  1  0.095  0.969  0.127  1.0
  H  H5  1  0.190  0.031  0.873  1.0
  C  C6  1  0.593  0.344  0.543  1.0
  C  C7  1  0.480  0.656  0.457  1.0
  C  C8  1  0.687  0.156  0.043  1.0
  C  C9  1  0.887  0.844  0.957  1.0
  C  C10  1  0.778  0.199  0.535  1.0
  C  C11  1  0.512  0.801  0.465  1.0
  C  C12  1  0.727  0.301  0.035  1.0
  C  C13  1  0.063  0.699  0.965  1.0
  F  F14  1  0.449  0.345  0.457  1.0
  F  F15  1  0.251  0.655  0.543  1.0
  F  F16  1  0.543  0.155  0.957  1.0
  F  F17  1  0.656  0.845  0.043  1.0
  F  F18  1  0.438  0.360  0.673  1.0
  F  F19  1  0.471  0.640  0.327  1.0
  F  F20  1  0.548  0.140  0.173  1.0
  F  F21  1  0.861  0.860  0.827  1.0
  F  F22  1  0.923  0.172  0.406  1.0
  F  F23  1  0.501  0.828  0.594  1.0
  F  F24  1  0.844  0.328  0.906  1.0
  F  F25  1  0.079  0.672  0.094  1.0
  F  F26  1  0.930  0.192  0.616  1.0
  F  F27  1  0.737  0.808  0.384  1.0
  F  F28  1  0.872  0.308  0.116  1.0
  F  F29  1  0.295  0.692  0.884  1.0
  F  F30  1  0.656  0.101  0.574  1.0
  F  F31  1  0.332  0.899  0.426  1.0
  F  F32  1  0.507  0.399  0.074  1.0
  F  F33  1  0.980  0.601  0.926  1.0
[/CIF]
.