The compound described by PtN2H8(OCl)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two azane;dichloroplatinum(2+);dihydrate molecules. Pt(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent O(1), and two equivalent Cl(1) atoms. N(1) is bonded in a distorted trigonal non-coplanar geometry to one Pt(1), one H(1), one H(2), and one H(3) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(1) atom. O(1) is bonded in a distorted single-bond geometry to one Pt(1) and one H(4) atom. Cl(1) is bonded in a single-bond geometry to one Pt(1) atom. is represented by the CIF file [CIF]
data_H8PtN2(ClO)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.971
_cell_length_b   6.239
_cell_length_c   8.178
_cell_angle_alpha   74.051
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   341.998
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.736  0.337  0.438  1.0
  H  H1  1  0.236  0.663  0.062  1.0
  H  H2  1  0.264  0.663  0.562  1.0
  H  H3  1  0.764  0.337  0.938  1.0
  H  H4  1  0.840  0.132  0.370  1.0
  H  H5  1  0.340  0.868  0.130  1.0
  H  H6  1  0.160  0.868  0.630  1.0
  H  H7  1  0.660  0.132  0.870  1.0
  H  H8  1  0.839  0.118  0.580  1.0
  H  H9  1  0.339  0.882  0.920  1.0
  H  H10  1  0.161  0.882  0.420  1.0
  H  H11  1  0.661  0.118  0.080  1.0
  H  H12  1  0.611  0.819  0.281  1.0
  H  H13  1  0.111  0.181  0.219  1.0
  H  H14  1  0.889  0.819  0.781  1.0
  H  H15  1  0.389  0.181  0.719  1.0
  Pt  Pt16  1  0.500  0.000  0.500  1.0
  Pt  Pt17  1  0.000  0.000  0.000  1.0
  N  N18  1  0.760  0.168  0.467  1.0
  N  N19  1  0.260  0.832  0.033  1.0
  N  N20  1  0.240  0.832  0.533  1.0
  N  N21  1  0.740  0.168  0.967  1.0
  Cl  Cl22  1  0.661  0.664  0.619  1.0
  Cl  Cl23  1  0.161  0.336  0.881  1.0
  Cl  Cl24  1  0.339  0.336  0.381  1.0
  Cl  Cl25  1  0.839  0.664  0.119  1.0
  O  O26  1  0.525  0.948  0.265  1.0
  O  O27  1  0.025  0.052  0.235  1.0
  O  O28  1  0.475  0.052  0.735  1.0
  O  O29  1  0.975  0.948  0.765  1.0
[/CIF]
.
The compound described by PtN2H8(OCl)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two azane;dichloroplatinum(2+);dihydrate molecules. Pt(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent O(1), and two equivalent Cl(1) atoms. N(1) is bonded in a distorted trigonal non-coplanar geometry to one Pt(1), one H(1), one H(2), and one H(3) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(1) atom. O(1) is bonded in a distorted single-bond geometry to one Pt(1) and one H(4) atom. Cl(1) is bonded in a single-bond geometry to one Pt(1) atom. is represented by the CIF file [CIF]
data_H8PtN2(ClO)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.971
_cell_length_b   6.239
_cell_length_c   8.178
_cell_angle_alpha   74.051
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   341.998
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.736  0.337  0.438  1.0
  H  H1  1  0.236  0.663  0.062  1.0
  H  H2  1  0.264  0.663  0.562  1.0
  H  H3  1  0.764  0.337  0.938  1.0
  H  H4  1  0.840  0.132  0.370  1.0
  H  H5  1  0.340  0.868  0.130  1.0
  H  H6  1  0.160  0.868  0.630  1.0
  H  H7  1  0.660  0.132  0.870  1.0
  H  H8  1  0.839  0.118  0.580  1.0
  H  H9  1  0.339  0.882  0.920  1.0
  H  H10  1  0.161  0.882  0.420  1.0
  H  H11  1  0.661  0.118  0.080  1.0
  H  H12  1  0.611  0.819  0.281  1.0
  H  H13  1  0.111  0.181  0.219  1.0
  H  H14  1  0.889  0.819  0.781  1.0
  H  H15  1  0.389  0.181  0.719  1.0
  Pt  Pt16  1  0.500  0.000  0.500  1.0
  Pt  Pt17  1  0.000  0.000  0.000  1.0
  N  N18  1  0.760  0.168  0.467  1.0
  N  N19  1  0.260  0.832  0.033  1.0
  N  N20  1  0.240  0.832  0.533  1.0
  N  N21  1  0.740  0.168  0.967  1.0
  Cl  Cl22  1  0.661  0.664  0.619  1.0
  Cl  Cl23  1  0.161  0.336  0.881  1.0
  Cl  Cl24  1  0.339  0.336  0.381  1.0
  Cl  Cl25  1  0.839  0.664  0.119  1.0
  O  O26  1  0.525  0.948  0.265  1.0
  O  O27  1  0.025  0.052  0.235  1.0
  O  O28  1  0.475  0.052  0.735  1.0
  O  O29  1  0.975  0.948  0.765  1.0
[/CIF]
.