The compound described by Rb2MgMo2P2(O5Cl)2 crystallizes in the monoclinic Cm space group. Rb(1) is bonded in a 8-coordinate geometry to one O(2), one O(3), one O(4), one O(5), two equivalent Cl(1), and two equivalent Cl(2) atoms. Mg(1) is bonded in a 5-coordinate geometry to one O(6), two equivalent O(1), one Cl(1), and one Cl(2) atom. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 6-coordinate geometry to one O(2), two equivalent O(1), two equivalent O(3), and one Cl(2) atom. In the second Mo site, Mo(2) is bonded in a 5-coordinate geometry to one O(6), two equivalent O(4), two equivalent O(5), and one Cl(1) atom. P(1) is bonded in a tetrahedral geometry to one O(1), one O(3), one O(4), and one O(5) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Mg(1), one Mo(1), and one P(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one Mo(1) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to one Rb(1), one Mo(1), and one P(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Rb(1), one Mo(2), and one P(1) atom. In the fifth O site, O(5) is bonded in a 2-coordinate geometry to one Rb(1), one Mo(2), and one P(1) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Mg(1) and one Mo(2) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a 6-coordinate geometry to four equivalent Rb(1), one Mg(1), and one Mo(2) atom. In the second Cl site, Cl(2) is bonded in a 6-coordinate geometry to four equivalent Rb(1), one Mg(1), and one Mo(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Rb2MgMo2P2(ClO5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.676
_cell_length_b   6.676
_cell_length_c   7.605
_cell_angle_alpha   97.328
_cell_angle_beta   82.672
_cell_angle_gamma   87.974
_symmetry_Int_Tables_number   1
_cell_volume   332.962
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.636  0.237  0.547  1.0
  Rb  Rb1  1  0.263  0.864  0.547  1.0
  Mg  Mg2  1  0.939  0.561  0.262  1.0
  Mo  Mo3  1  0.259  0.241  0.080  1.0
  Mo  Mo4  1  0.775  0.725  0.907  1.0
  P  P5  1  0.256  0.742  0.997  1.0
  P  P6  1  0.758  0.244  0.997  1.0
  Cl  Cl7  1  0.775  0.725  0.548  1.0
  Cl  Cl8  1  0.158  0.342  0.438  1.0
  O  O9  1  0.928  0.281  0.122  1.0
  O  O10  1  0.219  0.572  0.122  1.0
  O  O11  1  0.308  0.192  0.840  1.0
  O  O12  1  0.560  0.263  0.131  1.0
  O  O13  1  0.094  0.730  0.867  1.0
  O  O14  1  0.464  0.712  0.883  1.0
  O  O15  1  0.770  0.406  0.867  1.0
  O  O16  1  0.237  0.940  0.131  1.0
  O  O17  1  0.763  0.737  0.150  1.0
  O  O18  1  0.788  0.036  0.883  1.0
[/CIF]
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The compound described by Rb2MgMo2P2(O5Cl)2 crystallizes in the monoclinic Cm space group. Rb(1) is bonded in a 8-coordinate geometry to one O(2), one O(3), one O(4), one O(5), two equivalent Cl(1), and two equivalent Cl(2) atoms. Mg(1) is bonded in a 5-coordinate geometry to one O(6), two equivalent O(1), one Cl(1), and one Cl(2) atom. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 6-coordinate geometry to one O(2), two equivalent O(1), two equivalent O(3), and one Cl(2) atom. In the second Mo site, Mo(2) is bonded in a 5-coordinate geometry to one O(6), two equivalent O(4), two equivalent O(5), and one Cl(1) atom. P(1) is bonded in a tetrahedral geometry to one O(1), one O(3), one O(4), and one O(5) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Mg(1), one Mo(1), and one P(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one Mo(1) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to one Rb(1), one Mo(1), and one P(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Rb(1), one Mo(2), and one P(1) atom. In the fifth O site, O(5) is bonded in a 2-coordinate geometry to one Rb(1), one Mo(2), and one P(1) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Mg(1) and one Mo(2) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a 6-coordinate geometry to four equivalent Rb(1), one Mg(1), and one Mo(2) atom. In the second Cl site, Cl(2) is bonded in a 6-coordinate geometry to four equivalent Rb(1), one Mg(1), and one Mo(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Rb2MgMo2P2(ClO5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.676
_cell_length_b   6.676
_cell_length_c   7.605
_cell_angle_alpha   97.328
_cell_angle_beta   82.672
_cell_angle_gamma   87.974
_symmetry_Int_Tables_number   1
_cell_volume   332.962
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.636  0.237  0.547  1.0
  Rb  Rb1  1  0.263  0.864  0.547  1.0
  Mg  Mg2  1  0.939  0.561  0.262  1.0
  Mo  Mo3  1  0.259  0.241  0.080  1.0
  Mo  Mo4  1  0.775  0.725  0.907  1.0
  P  P5  1  0.256  0.742  0.997  1.0
  P  P6  1  0.758  0.244  0.997  1.0
  Cl  Cl7  1  0.775  0.725  0.548  1.0
  Cl  Cl8  1  0.158  0.342  0.438  1.0
  O  O9  1  0.928  0.281  0.122  1.0
  O  O10  1  0.219  0.572  0.122  1.0
  O  O11  1  0.308  0.192  0.840  1.0
  O  O12  1  0.560  0.263  0.131  1.0
  O  O13  1  0.094  0.730  0.867  1.0
  O  O14  1  0.464  0.712  0.883  1.0
  O  O15  1  0.770  0.406  0.867  1.0
  O  O16  1  0.237  0.940  0.131  1.0
  O  O17  1  0.763  0.737  0.150  1.0
  O  O18  1  0.788  0.036  0.883  1.0
[/CIF]
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