The crystal structure described by Rb2NaMn(CN)6 is Potassium Silver Cyanide-derived structured and crystallizes in the monoclinic P2_1/c space group. Rb(1) is bonded in a 5-coordinate geometry to one N(2), two equivalent N(1), and two equivalent N(3) atoms. Na(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent N(2), and two equivalent N(3) atoms. Mn(1) is bonded in an octahedral geometry to two equivalent C(1), two equivalent C(2), and two equivalent C(3) atoms. There are three inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Mn(1) and one N(1) atom. In the second C site, C(2) is bonded in a linear geometry to one Mn(1) and one N(2) atom. In the third C site, C(3) is bonded in a linear geometry to one Mn(1) and one N(3) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a 4-coordinate geometry to two equivalent Rb(1), one Na(1), and one C(1) atom. In the second N site, N(2) is bonded in a 2-coordinate geometry to one Rb(1), one Na(1), and one C(2) atom. In the third N site, N(3) is bonded in a 3-coordinate geometry to two equivalent Rb(1), one Na(1), and one C(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Rb2NaMn(CN)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.868
_cell_length_b   7.333
_cell_length_c   12.939
_cell_angle_alpha   56.248
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   620.648
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.927  0.725  0.751  1.0
  Rb  Rb1  1  0.427  0.275  0.749  1.0
  Rb  Rb2  1  0.073  0.275  0.249  1.0
  Rb  Rb3  1  0.573  0.725  0.251  1.0
  Na  Na4  1  0.000  0.500  0.500  1.0
  Na  Na5  1  0.500  0.500  0.000  1.0
  Mn  Mn6  1  0.000  0.000  0.000  1.0
  Mn  Mn7  1  0.500  0.000  0.500  1.0
  C  C8  1  0.021  0.103  0.824  1.0
  C  C9  1  0.521  0.897  0.676  1.0
  C  C10  1  0.979  0.897  0.176  1.0
  C  C11  1  0.479  0.103  0.324  1.0
  C  C12  1  0.137  0.252  0.966  1.0
  C  C13  1  0.637  0.748  0.534  1.0
  C  C14  1  0.863  0.748  0.034  1.0
  C  C15  1  0.363  0.252  0.466  1.0
  C  C16  1  0.209  0.825  0.042  1.0
  C  C17  1  0.709  0.175  0.458  1.0
  C  C18  1  0.791  0.175  0.958  1.0
  C  C19  1  0.291  0.825  0.542  1.0
  N  N20  1  0.035  0.167  0.719  1.0
  N  N21  1  0.535  0.833  0.781  1.0
  N  N22  1  0.965  0.833  0.281  1.0
  N  N23  1  0.465  0.167  0.219  1.0
  N  N24  1  0.220  0.403  0.944  1.0
  N  N25  1  0.720  0.597  0.556  1.0
  N  N26  1  0.780  0.597  0.056  1.0
  N  N27  1  0.280  0.403  0.444  1.0
  N  N28  1  0.333  0.718  0.067  1.0
  N  N29  1  0.833  0.282  0.433  1.0
  N  N30  1  0.667  0.282  0.933  1.0
  N  N31  1  0.167  0.718  0.567  1.0
[/CIF]
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The crystal structure described by Rb2NaMn(CN)6 is Potassium Silver Cyanide-derived structured and crystallizes in the monoclinic P2_1/c space group. Rb(1) is bonded in a 5-coordinate geometry to one N(2), two equivalent N(1), and two equivalent N(3) atoms. Na(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent N(2), and two equivalent N(3) atoms. Mn(1) is bonded in an octahedral geometry to two equivalent C(1), two equivalent C(2), and two equivalent C(3) atoms. There are three inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Mn(1) and one N(1) atom. In the second C site, C(2) is bonded in a linear geometry to one Mn(1) and one N(2) atom. In the third C site, C(3) is bonded in a linear geometry to one Mn(1) and one N(3) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a 4-coordinate geometry to two equivalent Rb(1), one Na(1), and one C(1) atom. In the second N site, N(2) is bonded in a 2-coordinate geometry to one Rb(1), one Na(1), and one C(2) atom. In the third N site, N(3) is bonded in a 3-coordinate geometry to two equivalent Rb(1), one Na(1), and one C(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Rb2NaMn(CN)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.868
_cell_length_b   7.333
_cell_length_c   12.939
_cell_angle_alpha   56.248
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   620.648
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.927  0.725  0.751  1.0
  Rb  Rb1  1  0.427  0.275  0.749  1.0
  Rb  Rb2  1  0.073  0.275  0.249  1.0
  Rb  Rb3  1  0.573  0.725  0.251  1.0
  Na  Na4  1  0.000  0.500  0.500  1.0
  Na  Na5  1  0.500  0.500  0.000  1.0
  Mn  Mn6  1  0.000  0.000  0.000  1.0
  Mn  Mn7  1  0.500  0.000  0.500  1.0
  C  C8  1  0.021  0.103  0.824  1.0
  C  C9  1  0.521  0.897  0.676  1.0
  C  C10  1  0.979  0.897  0.176  1.0
  C  C11  1  0.479  0.103  0.324  1.0
  C  C12  1  0.137  0.252  0.966  1.0
  C  C13  1  0.637  0.748  0.534  1.0
  C  C14  1  0.863  0.748  0.034  1.0
  C  C15  1  0.363  0.252  0.466  1.0
  C  C16  1  0.209  0.825  0.042  1.0
  C  C17  1  0.709  0.175  0.458  1.0
  C  C18  1  0.791  0.175  0.958  1.0
  C  C19  1  0.291  0.825  0.542  1.0
  N  N20  1  0.035  0.167  0.719  1.0
  N  N21  1  0.535  0.833  0.781  1.0
  N  N22  1  0.965  0.833  0.281  1.0
  N  N23  1  0.465  0.167  0.219  1.0
  N  N24  1  0.220  0.403  0.944  1.0
  N  N25  1  0.720  0.597  0.556  1.0
  N  N26  1  0.780  0.597  0.056  1.0
  N  N27  1  0.280  0.403  0.444  1.0
  N  N28  1  0.333  0.718  0.067  1.0
  N  N29  1  0.833  0.282  0.433  1.0
  N  N30  1  0.667  0.282  0.933  1.0
  N  N31  1  0.167  0.718  0.567  1.0
[/CIF]
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