The compound described by N2Te is beta Vanadium nitride-like structured and crystallizes in the monoclinic C2/m space group. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted T-shaped geometry to three equivalent Te(1) atoms. In the second N site, N(2) is bonded in a distorted T-shaped geometry to three equivalent Te(1) atoms. Te(1) is bonded to three equivalent N(1) and three equivalent N(2) atoms to form a mixture of distorted corner and edge-sharing TeN6 octahedra. The corner-sharing octahedral tilt angles are 28°. is represented by the CIF card [CIF]
data_TeN2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.813
_cell_length_b   5.813
_cell_length_c   4.037
_cell_angle_alpha   69.955
_cell_angle_beta   69.955
_cell_angle_gamma   40.652
_symmetry_Int_Tables_number   1
_cell_volume   82.711
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.625  0.625  0.126  1.0
  Te  Te1  1  0.375  0.375  0.874  1.0
  N  N2  1  0.826  0.826  0.910  1.0
  N  N3  1  0.174  0.174  0.090  1.0
  N  N4  1  0.576  0.576  0.675  1.0
  N  N5  1  0.424  0.424  0.325  1.0
[/CIF]
.
The compound described by N2Te is beta Vanadium nitride-like structured and crystallizes in the monoclinic C2/m space group. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted T-shaped geometry to three equivalent Te(1) atoms. In the second N site, N(2) is bonded in a distorted T-shaped geometry to three equivalent Te(1) atoms. Te(1) is bonded to three equivalent N(1) and three equivalent N(2) atoms to form a mixture of distorted corner and edge-sharing TeN6 octahedra. The corner-sharing octahedral tilt angles are 28°. is represented by the CIF card [CIF]
data_TeN2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.813
_cell_length_b   5.813
_cell_length_c   4.037
_cell_angle_alpha   69.955
_cell_angle_beta   69.955
_cell_angle_gamma   40.652
_symmetry_Int_Tables_number   1
_cell_volume   82.711
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.625  0.625  0.126  1.0
  Te  Te1  1  0.375  0.375  0.874  1.0
  N  N2  1  0.826  0.826  0.910  1.0
  N  N3  1  0.174  0.174  0.090  1.0
  N  N4  1  0.576  0.576  0.675  1.0
  N  N5  1  0.424  0.424  0.325  1.0
[/CIF]
.