The material structure described by RbIn(MoO4)2 crystallizes in the orthorhombic Pnma space group. Rb(1) is bonded in a 11-coordinate geometry to one O(1), two equivalent O(2), two equivalent O(3), two equivalent O(4), and four equivalent O(6) atoms. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one O(1), one O(3), and two equivalent O(2) atoms to form MoO4 tetrahedra that share corners with three equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 32-33°. In the second Mo site, Mo(2) is bonded to one O(4), one O(5), and two equivalent O(6) atoms to form MoO4 tetrahedra that share corners with three equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 25-42°. In(1) is bonded to one O(3), one O(5), two equivalent O(2), and two equivalent O(6) atoms to form InO6 octahedra that share corners with three equivalent Mo(1)O4 tetrahedra and corners with three equivalent Mo(2)O4 tetrahedra. There are six inequivalent O sites. In the first O site, O(4) is bonded in a single-bond geometry to two equivalent Rb(1) and one Mo(2) atom. In the second O site, O(5) is bonded in a bent 150 degrees geometry to one Mo(2) and one In(1) atom. In the third O site, O(6) is bonded in a 2-coordinate geometry to two equivalent Rb(1), one Mo(2), and one In(1) atom. In the fourth O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Rb(1) and one Mo(1) atom. In the fifth O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Rb(1), one Mo(1), and one In(1) atom. In the sixth O site, O(3) is bonded in a bent 150 degrees geometry to two equivalent Rb(1), one Mo(1), and one In(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_RbIn(MoO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.960
_cell_length_b   9.124
_cell_length_c   15.635
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   850.157
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.750  0.450  0.876  1.0
  Rb  Rb1  1  0.250  0.550  0.124  1.0
  Rb  Rb2  1  0.250  0.950  0.624  1.0
  Rb  Rb3  1  0.750  0.050  0.376  1.0
  In  In4  1  0.250  0.812  0.886  1.0
  In  In5  1  0.750  0.188  0.114  1.0
  In  In6  1  0.750  0.312  0.614  1.0
  In  In7  1  0.250  0.688  0.386  1.0
  Mo  Mo8  1  0.250  0.509  0.716  1.0
  Mo  Mo9  1  0.750  0.491  0.284  1.0
  Mo  Mo10  1  0.750  0.009  0.784  1.0
  Mo  Mo11  1  0.250  0.991  0.216  1.0
  Mo  Mo12  1  0.250  0.212  0.969  1.0
  Mo  Mo13  1  0.750  0.788  0.031  1.0
  Mo  Mo14  1  0.750  0.712  0.531  1.0
  Mo  Mo15  1  0.250  0.288  0.469  1.0
  O  O16  1  0.750  0.140  0.864  1.0
  O  O17  1  0.250  0.860  0.136  1.0
  O  O18  1  0.250  0.640  0.636  1.0
  O  O19  1  0.750  0.360  0.364  1.0
  O  O20  1  0.002  0.899  0.797  1.0
  O  O21  1  0.502  0.101  0.203  1.0
  O  O22  1  0.998  0.399  0.703  1.0
  O  O23  1  0.498  0.601  0.297  1.0
  O  O24  1  0.998  0.101  0.203  1.0
  O  O25  1  0.498  0.899  0.797  1.0
  O  O26  1  0.002  0.601  0.297  1.0
  O  O27  1  0.502  0.399  0.703  1.0
  O  O28  1  0.250  0.605  0.819  1.0
  O  O29  1  0.750  0.395  0.181  1.0
  O  O30  1  0.750  0.105  0.681  1.0
  O  O31  1  0.250  0.895  0.319  1.0
  O  O32  1  0.250  0.299  0.870  1.0
  O  O33  1  0.750  0.701  0.130  1.0
  O  O34  1  0.750  0.799  0.630  1.0
  O  O35  1  0.250  0.201  0.370  1.0
  O  O36  1  0.250  0.016  0.957  1.0
  O  O37  1  0.750  0.984  0.043  1.0
  O  O38  1  0.750  0.516  0.543  1.0
  O  O39  1  0.250  0.484  0.457  1.0
  O  O40  1  0.506  0.723  0.971  1.0
  O  O41  1  0.006  0.277  0.029  1.0
  O  O42  1  0.494  0.223  0.529  1.0
  O  O43  1  0.994  0.777  0.471  1.0
  O  O44  1  0.494  0.277  0.029  1.0
  O  O45  1  0.994  0.723  0.971  1.0
  O  O46  1  0.506  0.777  0.471  1.0
  O  O47  1  0.006  0.223  0.529  1.0
[/CIF]
.
The material structure described by RbIn(MoO4)2 crystallizes in the orthorhombic Pnma space group. Rb(1) is bonded in a 11-coordinate geometry to one O(1), two equivalent O(2), two equivalent O(3), two equivalent O(4), and four equivalent O(6) atoms. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one O(1), one O(3), and two equivalent O(2) atoms to form MoO4 tetrahedra that share corners with three equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 32-33°. In the second Mo site, Mo(2) is bonded to one O(4), one O(5), and two equivalent O(6) atoms to form MoO4 tetrahedra that share corners with three equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 25-42°. In(1) is bonded to one O(3), one O(5), two equivalent O(2), and two equivalent O(6) atoms to form InO6 octahedra that share corners with three equivalent Mo(1)O4 tetrahedra and corners with three equivalent Mo(2)O4 tetrahedra. There are six inequivalent O sites. In the first O site, O(4) is bonded in a single-bond geometry to two equivalent Rb(1) and one Mo(2) atom. In the second O site, O(5) is bonded in a bent 150 degrees geometry to one Mo(2) and one In(1) atom. In the third O site, O(6) is bonded in a 2-coordinate geometry to two equivalent Rb(1), one Mo(2), and one In(1) atom. In the fourth O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Rb(1) and one Mo(1) atom. In the fifth O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Rb(1), one Mo(1), and one In(1) atom. In the sixth O site, O(3) is bonded in a bent 150 degrees geometry to two equivalent Rb(1), one Mo(1), and one In(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_RbIn(MoO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.960
_cell_length_b   9.124
_cell_length_c   15.635
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   850.157
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.750  0.450  0.876  1.0
  Rb  Rb1  1  0.250  0.550  0.124  1.0
  Rb  Rb2  1  0.250  0.950  0.624  1.0
  Rb  Rb3  1  0.750  0.050  0.376  1.0
  In  In4  1  0.250  0.812  0.886  1.0
  In  In5  1  0.750  0.188  0.114  1.0
  In  In6  1  0.750  0.312  0.614  1.0
  In  In7  1  0.250  0.688  0.386  1.0
  Mo  Mo8  1  0.250  0.509  0.716  1.0
  Mo  Mo9  1  0.750  0.491  0.284  1.0
  Mo  Mo10  1  0.750  0.009  0.784  1.0
  Mo  Mo11  1  0.250  0.991  0.216  1.0
  Mo  Mo12  1  0.250  0.212  0.969  1.0
  Mo  Mo13  1  0.750  0.788  0.031  1.0
  Mo  Mo14  1  0.750  0.712  0.531  1.0
  Mo  Mo15  1  0.250  0.288  0.469  1.0
  O  O16  1  0.750  0.140  0.864  1.0
  O  O17  1  0.250  0.860  0.136  1.0
  O  O18  1  0.250  0.640  0.636  1.0
  O  O19  1  0.750  0.360  0.364  1.0
  O  O20  1  0.002  0.899  0.797  1.0
  O  O21  1  0.502  0.101  0.203  1.0
  O  O22  1  0.998  0.399  0.703  1.0
  O  O23  1  0.498  0.601  0.297  1.0
  O  O24  1  0.998  0.101  0.203  1.0
  O  O25  1  0.498  0.899  0.797  1.0
  O  O26  1  0.002  0.601  0.297  1.0
  O  O27  1  0.502  0.399  0.703  1.0
  O  O28  1  0.250  0.605  0.819  1.0
  O  O29  1  0.750  0.395  0.181  1.0
  O  O30  1  0.750  0.105  0.681  1.0
  O  O31  1  0.250  0.895  0.319  1.0
  O  O32  1  0.250  0.299  0.870  1.0
  O  O33  1  0.750  0.701  0.130  1.0
  O  O34  1  0.750  0.799  0.630  1.0
  O  O35  1  0.250  0.201  0.370  1.0
  O  O36  1  0.250  0.016  0.957  1.0
  O  O37  1  0.750  0.984  0.043  1.0
  O  O38  1  0.750  0.516  0.543  1.0
  O  O39  1  0.250  0.484  0.457  1.0
  O  O40  1  0.506  0.723  0.971  1.0
  O  O41  1  0.006  0.277  0.029  1.0
  O  O42  1  0.494  0.223  0.529  1.0
  O  O43  1  0.994  0.777  0.471  1.0
  O  O44  1  0.494  0.277  0.029  1.0
  O  O45  1  0.994  0.723  0.971  1.0
  O  O46  1  0.506  0.777  0.471  1.0
  O  O47  1  0.006  0.223  0.529  1.0
[/CIF]
.