The material structure described by La(SbO3)3 crystallizes in the orthorhombic Cmcm space group. La(1) is bonded in a 7-coordinate geometry to one O(1), two equivalent O(2), and four equivalent O(4) atoms. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(1), one O(3), two equivalent O(2), and two equivalent O(4) atoms to form a mixture of edge and corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 33-52°. In the second Sb site, Sb(2) is bonded to two equivalent O(3) and four equivalent O(4) atoms to form corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 50-52°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one La(1) and two equivalent Sb(1) atoms. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one La(1) and two equivalent Sb(1) atoms. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Sb(1) and one Sb(2) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one La(1), one Sb(1), and one Sb(2) atom. is represented by the CIF card [CIF]
data_La(SbO3)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.520
_cell_length_b   5.520
_cell_length_c   11.810
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   107.190
_symmetry_Int_Tables_number   1
_cell_volume   343.772
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.755  0.245  0.750  1.0
  La  La1  1  0.245  0.755  0.250  1.0
  Sb  Sb2  1  0.122  0.878  0.908  1.0
  Sb  Sb3  1  0.878  0.122  0.408  1.0
  Sb  Sb4  1  0.878  0.122  0.092  1.0
  Sb  Sb5  1  0.122  0.878  0.592  1.0
  Sb  Sb6  1  0.500  0.500  0.000  1.0
  Sb  Sb7  1  0.500  0.500  0.500  1.0
  O  O8  1  0.940  0.060  0.250  1.0
  O  O9  1  0.060  0.940  0.750  1.0
  O  O10  1  0.104  0.896  0.074  1.0
  O  O11  1  0.896  0.104  0.574  1.0
  O  O12  1  0.896  0.104  0.926  1.0
  O  O13  1  0.104  0.896  0.426  1.0
  O  O14  1  0.337  0.663  0.884  1.0
  O  O15  1  0.663  0.337  0.384  1.0
  O  O16  1  0.417  0.192  0.598  1.0
  O  O17  1  0.583  0.808  0.098  1.0
  O  O18  1  0.192  0.417  0.402  1.0
  O  O19  1  0.808  0.583  0.902  1.0
  O  O20  1  0.583  0.808  0.402  1.0
  O  O21  1  0.417  0.192  0.902  1.0
  O  O22  1  0.808  0.583  0.598  1.0
  O  O23  1  0.192  0.417  0.098  1.0
  O  O24  1  0.337  0.663  0.616  1.0
  O  O25  1  0.663  0.337  0.116  1.0
[/CIF]
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The material structure described by La(SbO3)3 crystallizes in the orthorhombic Cmcm space group. La(1) is bonded in a 7-coordinate geometry to one O(1), two equivalent O(2), and four equivalent O(4) atoms. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(1), one O(3), two equivalent O(2), and two equivalent O(4) atoms to form a mixture of edge and corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 33-52°. In the second Sb site, Sb(2) is bonded to two equivalent O(3) and four equivalent O(4) atoms to form corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 50-52°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one La(1) and two equivalent Sb(1) atoms. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one La(1) and two equivalent Sb(1) atoms. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Sb(1) and one Sb(2) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one La(1), one Sb(1), and one Sb(2) atom. is represented by the CIF card [CIF]
data_La(SbO3)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.520
_cell_length_b   5.520
_cell_length_c   11.810
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   107.190
_symmetry_Int_Tables_number   1
_cell_volume   343.772
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.755  0.245  0.750  1.0
  La  La1  1  0.245  0.755  0.250  1.0
  Sb  Sb2  1  0.122  0.878  0.908  1.0
  Sb  Sb3  1  0.878  0.122  0.408  1.0
  Sb  Sb4  1  0.878  0.122  0.092  1.0
  Sb  Sb5  1  0.122  0.878  0.592  1.0
  Sb  Sb6  1  0.500  0.500  0.000  1.0
  Sb  Sb7  1  0.500  0.500  0.500  1.0
  O  O8  1  0.940  0.060  0.250  1.0
  O  O9  1  0.060  0.940  0.750  1.0
  O  O10  1  0.104  0.896  0.074  1.0
  O  O11  1  0.896  0.104  0.574  1.0
  O  O12  1  0.896  0.104  0.926  1.0
  O  O13  1  0.104  0.896  0.426  1.0
  O  O14  1  0.337  0.663  0.884  1.0
  O  O15  1  0.663  0.337  0.384  1.0
  O  O16  1  0.417  0.192  0.598  1.0
  O  O17  1  0.583  0.808  0.098  1.0
  O  O18  1  0.192  0.417  0.402  1.0
  O  O19  1  0.808  0.583  0.902  1.0
  O  O20  1  0.583  0.808  0.402  1.0
  O  O21  1  0.417  0.192  0.902  1.0
  O  O22  1  0.808  0.583  0.598  1.0
  O  O23  1  0.192  0.417  0.098  1.0
  O  O24  1  0.337  0.663  0.616  1.0
  O  O25  1  0.663  0.337  0.116  1.0
[/CIF]
.