The material described by CoPdAs is Matlockite structured and crystallizes in the tetragonal P4/nmm space group. Co(1) is bonded in a 1-coordinate geometry to four equivalent Pd(1) and five equivalent As(1) atoms. Pd(1) is bonded to four equivalent Co(1), four equivalent Pd(1), and four equivalent As(1) atoms to form a mixture of corner and face-sharing PdCo4As4Pd4 cuboctahedra. As(1) is bonded in a 9-coordinate geometry to five equivalent Co(1) and four equivalent Pd(1) atoms. is represented by the CIF file [CIF]
data_CoAsPd
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.731
_cell_length_b   3.731
_cell_length_c   6.309
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   87.832
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.000  0.500  0.634  1.0
  Co  Co1  1  0.500  0.000  0.366  1.0
  As  As2  1  0.000  0.500  0.283  1.0
  As  As3  1  0.500  0.000  0.717  1.0
  Pd  Pd4  1  0.000  0.000  0.000  1.0
  Pd  Pd5  1  0.500  0.500  0.000  1.0
[/CIF]
.
The material described by CoPdAs is Matlockite structured and crystallizes in the tetragonal P4/nmm space group. Co(1) is bonded in a 1-coordinate geometry to four equivalent Pd(1) and five equivalent As(1) atoms. Pd(1) is bonded to four equivalent Co(1), four equivalent Pd(1), and four equivalent As(1) atoms to form a mixture of corner and face-sharing PdCo4As4Pd4 cuboctahedra. As(1) is bonded in a 9-coordinate geometry to five equivalent Co(1) and four equivalent Pd(1) atoms. is represented by the CIF file [CIF]
data_CoAsPd
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.731
_cell_length_b   3.731
_cell_length_c   6.309
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   87.832
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.000  0.500  0.634  1.0
  Co  Co1  1  0.500  0.000  0.366  1.0
  As  As2  1  0.000  0.500  0.283  1.0
  As  As3  1  0.500  0.000  0.717  1.0
  Pd  Pd4  1  0.000  0.000  0.000  1.0
  Pd  Pd5  1  0.500  0.500  0.000  1.0
[/CIF]
.