The structure described by CF3C2S2O2F is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four trifluoromethane molecules and four C2S2O2F clusters. In each C2S2O2F cluster, there are two inequivalent C sites. In the first C site, C(2) is bonded in a distorted single-bond geometry to one S(1) and one O(2) atom. In the second C site, C(3) is bonded in a distorted bent 120 degrees geometry to one S(2), one O(1), and one F(3) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one C(2) and one S(2) atom. In the second S site, S(2) is bonded in a water-like geometry to one C(3) and one S(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(3) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(2) atom. F(3) is bonded in a single-bond geometry to one C(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_C3S2(OF2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   24.349
_cell_length_b   5.425
_cell_length_c   7.026
_cell_angle_alpha   59.478
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   799.534
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  C  C0  1  0.562  0.006  0.735  1.0
  C  C1  1  0.062  0.994  0.765  1.0
  C  C2  1  0.938  0.006  0.235  1.0
  C  C3  1  0.882  0.977  0.351  1.0
  C  C4  1  0.118  0.023  0.649  1.0
  C  C5  1  0.822  0.681  0.897  1.0
  C  C6  1  0.678  0.681  0.397  1.0
  C  C7  1  0.618  0.977  0.851  1.0
  C  C8  1  0.438  0.994  0.265  1.0
  C  C9  1  0.178  0.319  0.103  1.0
  C  C10  1  0.322  0.319  0.603  1.0
  C  C11  1  0.382  0.023  0.149  1.0
  S  S12  1  0.115  0.869  0.475  1.0
  S  S13  1  0.691  0.028  0.169  1.0
  S  S14  1  0.385  0.869  0.975  1.0
  S  S15  1  0.191  0.972  0.331  1.0
  S  S16  1  0.309  0.972  0.831  1.0
  S  S17  1  0.885  0.131  0.525  1.0
  S  S18  1  0.809  0.028  0.669  1.0
  S  S19  1  0.615  0.131  0.025  1.0
  O  O20  1  0.862  0.533  0.947  1.0
  O  O21  1  0.638  0.533  0.447  1.0
  O  O22  1  0.156  0.150  0.670  1.0
  O  O23  1  0.344  0.150  0.170  1.0
  O  O24  1  0.362  0.467  0.553  1.0
  O  O25  1  0.138  0.467  0.053  1.0
  O  O26  1  0.844  0.850  0.330  1.0
  O  O27  1  0.656  0.850  0.830  1.0
  F  F28  1  0.069  0.980  0.961  1.0
  F  F29  1  0.966  0.241  0.201  1.0
  F  F30  1  0.726  0.595  0.520  1.0
  F  F31  1  0.931  0.020  0.039  1.0
  F  F32  1  0.431  0.980  0.461  1.0
  F  F33  1  0.469  0.229  0.133  1.0
  F  F34  1  0.569  0.020  0.539  1.0
  F  F35  1  0.774  0.595  0.020  1.0
  F  F36  1  0.531  0.771  0.867  1.0
  F  F37  1  0.031  0.229  0.633  1.0
  F  F38  1  0.466  0.759  0.299  1.0
  F  F39  1  0.969  0.771  0.367  1.0
  F  F40  1  0.534  0.241  0.701  1.0
  F  F41  1  0.034  0.759  0.799  1.0
  F  F42  1  0.274  0.405  0.480  1.0
  F  F43  1  0.226  0.405  0.980  1.0
[/CIF]
.
The structure described by CF3C2S2O2F is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four trifluoromethane molecules and four C2S2O2F clusters. In each C2S2O2F cluster, there are two inequivalent C sites. In the first C site, C(2) is bonded in a distorted single-bond geometry to one S(1) and one O(2) atom. In the second C site, C(3) is bonded in a distorted bent 120 degrees geometry to one S(2), one O(1), and one F(3) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one C(2) and one S(2) atom. In the second S site, S(2) is bonded in a water-like geometry to one C(3) and one S(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(3) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(2) atom. F(3) is bonded in a single-bond geometry to one C(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_C3S2(OF2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   24.349
_cell_length_b   5.425
_cell_length_c   7.026
_cell_angle_alpha   59.478
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   799.534
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  C  C0  1  0.562  0.006  0.735  1.0
  C  C1  1  0.062  0.994  0.765  1.0
  C  C2  1  0.938  0.006  0.235  1.0
  C  C3  1  0.882  0.977  0.351  1.0
  C  C4  1  0.118  0.023  0.649  1.0
  C  C5  1  0.822  0.681  0.897  1.0
  C  C6  1  0.678  0.681  0.397  1.0
  C  C7  1  0.618  0.977  0.851  1.0
  C  C8  1  0.438  0.994  0.265  1.0
  C  C9  1  0.178  0.319  0.103  1.0
  C  C10  1  0.322  0.319  0.603  1.0
  C  C11  1  0.382  0.023  0.149  1.0
  S  S12  1  0.115  0.869  0.475  1.0
  S  S13  1  0.691  0.028  0.169  1.0
  S  S14  1  0.385  0.869  0.975  1.0
  S  S15  1  0.191  0.972  0.331  1.0
  S  S16  1  0.309  0.972  0.831  1.0
  S  S17  1  0.885  0.131  0.525  1.0
  S  S18  1  0.809  0.028  0.669  1.0
  S  S19  1  0.615  0.131  0.025  1.0
  O  O20  1  0.862  0.533  0.947  1.0
  O  O21  1  0.638  0.533  0.447  1.0
  O  O22  1  0.156  0.150  0.670  1.0
  O  O23  1  0.344  0.150  0.170  1.0
  O  O24  1  0.362  0.467  0.553  1.0
  O  O25  1  0.138  0.467  0.053  1.0
  O  O26  1  0.844  0.850  0.330  1.0
  O  O27  1  0.656  0.850  0.830  1.0
  F  F28  1  0.069  0.980  0.961  1.0
  F  F29  1  0.966  0.241  0.201  1.0
  F  F30  1  0.726  0.595  0.520  1.0
  F  F31  1  0.931  0.020  0.039  1.0
  F  F32  1  0.431  0.980  0.461  1.0
  F  F33  1  0.469  0.229  0.133  1.0
  F  F34  1  0.569  0.020  0.539  1.0
  F  F35  1  0.774  0.595  0.020  1.0
  F  F36  1  0.531  0.771  0.867  1.0
  F  F37  1  0.031  0.229  0.633  1.0
  F  F38  1  0.466  0.759  0.299  1.0
  F  F39  1  0.969  0.771  0.367  1.0
  F  F40  1  0.534  0.241  0.701  1.0
  F  F41  1  0.034  0.759  0.799  1.0
  F  F42  1  0.274  0.405  0.480  1.0
  F  F43  1  0.226  0.405  0.980  1.0
[/CIF]
.