The structure described by UMo2O8 crystallizes in the orthorhombic Pban space group. U(1) is bonded to one O(1), two equivalent O(5), and four equivalent O(6) atoms to form a mixture of edge and corner-sharing UO7 pentagonal bipyramids. Mo(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(4), one O(6), and two equivalent O(3) atoms. There are six inequivalent O sites. In the first O site, O(5) is bonded in a linear geometry to two equivalent U(1) atoms. In the second O site, O(6) is bonded in a distorted trigonal planar geometry to two equivalent U(1) and one Mo(1) atom. In the third O site, O(1) is bonded in a distorted trigonal planar geometry to one U(1) and two equivalent Mo(1) atoms. In the fourth O site, O(2) is bonded in a bent 150 degrees geometry to two equivalent Mo(1) atoms. In the fifth O site, O(3) is bonded in a distorted linear geometry to two equivalent Mo(1) atoms. In the sixth O site, O(4) is bonded in a linear geometry to two equivalent Mo(1) atoms. is represented by the CIF card [CIF]
data_U(MoO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.143
_cell_length_b   7.455
_cell_length_c   20.370
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   629.123
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  U  U0  1  0.000  0.500  0.763  1.0
  U  U1  1  0.000  0.500  0.237  1.0
  U  U2  1  0.000  0.000  0.737  1.0
  U  U3  1  0.000  0.000  0.263  1.0
  Mo  Mo4  1  0.912  0.251  0.590  1.0
  Mo  Mo5  1  0.912  0.749  0.410  1.0
  Mo  Mo6  1  0.088  0.251  0.410  1.0
  Mo  Mo7  1  0.088  0.749  0.590  1.0
  Mo  Mo8  1  0.088  0.249  0.910  1.0
  Mo  Mo9  1  0.088  0.751  0.090  1.0
  Mo  Mo10  1  0.912  0.249  0.090  1.0
  Mo  Mo11  1  0.912  0.751  0.910  1.0
  O  O12  1  0.000  0.500  0.121  1.0
  O  O13  1  0.000  0.500  0.879  1.0
  O  O14  1  0.000  0.000  0.379  1.0
  O  O15  1  0.000  0.000  0.621  1.0
  O  O16  1  0.000  0.314  0.000  1.0
  O  O17  1  0.000  0.686  0.000  1.0
  O  O18  1  0.000  0.186  0.500  1.0
  O  O19  1  0.000  0.814  0.500  1.0
  O  O20  1  0.508  0.250  0.409  1.0
  O  O21  1  0.508  0.750  0.591  1.0
  O  O22  1  0.492  0.250  0.591  1.0
  O  O23  1  0.492  0.750  0.409  1.0
  O  O24  1  0.492  0.250  0.091  1.0
  O  O25  1  0.492  0.750  0.909  1.0
  O  O26  1  0.508  0.250  0.909  1.0
  O  O27  1  0.508  0.750  0.091  1.0
  O  O28  1  0.000  0.500  0.424  1.0
  O  O29  1  0.000  0.500  0.576  1.0
  O  O30  1  0.000  0.000  0.076  1.0
  O  O31  1  0.000  0.000  0.924  1.0
  O  O32  1  0.500  0.500  0.236  1.0
  O  O33  1  0.500  0.500  0.764  1.0
  O  O34  1  0.500  0.000  0.264  1.0
  O  O35  1  0.500  0.000  0.736  1.0
  O  O36  1  0.992  0.710  0.312  1.0
  O  O37  1  0.992  0.290  0.688  1.0
  O  O38  1  0.008  0.710  0.688  1.0
  O  O39  1  0.008  0.290  0.312  1.0
  O  O40  1  0.008  0.790  0.188  1.0
  O  O41  1  0.008  0.210  0.812  1.0
  O  O42  1  0.992  0.790  0.812  1.0
  O  O43  1  0.992  0.210  0.188  1.0
[/CIF]
.
The structure described by UMo2O8 crystallizes in the orthorhombic Pban space group. U(1) is bonded to one O(1), two equivalent O(5), and four equivalent O(6) atoms to form a mixture of edge and corner-sharing UO7 pentagonal bipyramids. Mo(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(4), one O(6), and two equivalent O(3) atoms. There are six inequivalent O sites. In the first O site, O(5) is bonded in a linear geometry to two equivalent U(1) atoms. In the second O site, O(6) is bonded in a distorted trigonal planar geometry to two equivalent U(1) and one Mo(1) atom. In the third O site, O(1) is bonded in a distorted trigonal planar geometry to one U(1) and two equivalent Mo(1) atoms. In the fourth O site, O(2) is bonded in a bent 150 degrees geometry to two equivalent Mo(1) atoms. In the fifth O site, O(3) is bonded in a distorted linear geometry to two equivalent Mo(1) atoms. In the sixth O site, O(4) is bonded in a linear geometry to two equivalent Mo(1) atoms. is represented by the CIF card [CIF]
data_U(MoO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.143
_cell_length_b   7.455
_cell_length_c   20.370
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   629.123
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  U  U0  1  0.000  0.500  0.763  1.0
  U  U1  1  0.000  0.500  0.237  1.0
  U  U2  1  0.000  0.000  0.737  1.0
  U  U3  1  0.000  0.000  0.263  1.0
  Mo  Mo4  1  0.912  0.251  0.590  1.0
  Mo  Mo5  1  0.912  0.749  0.410  1.0
  Mo  Mo6  1  0.088  0.251  0.410  1.0
  Mo  Mo7  1  0.088  0.749  0.590  1.0
  Mo  Mo8  1  0.088  0.249  0.910  1.0
  Mo  Mo9  1  0.088  0.751  0.090  1.0
  Mo  Mo10  1  0.912  0.249  0.090  1.0
  Mo  Mo11  1  0.912  0.751  0.910  1.0
  O  O12  1  0.000  0.500  0.121  1.0
  O  O13  1  0.000  0.500  0.879  1.0
  O  O14  1  0.000  0.000  0.379  1.0
  O  O15  1  0.000  0.000  0.621  1.0
  O  O16  1  0.000  0.314  0.000  1.0
  O  O17  1  0.000  0.686  0.000  1.0
  O  O18  1  0.000  0.186  0.500  1.0
  O  O19  1  0.000  0.814  0.500  1.0
  O  O20  1  0.508  0.250  0.409  1.0
  O  O21  1  0.508  0.750  0.591  1.0
  O  O22  1  0.492  0.250  0.591  1.0
  O  O23  1  0.492  0.750  0.409  1.0
  O  O24  1  0.492  0.250  0.091  1.0
  O  O25  1  0.492  0.750  0.909  1.0
  O  O26  1  0.508  0.250  0.909  1.0
  O  O27  1  0.508  0.750  0.091  1.0
  O  O28  1  0.000  0.500  0.424  1.0
  O  O29  1  0.000  0.500  0.576  1.0
  O  O30  1  0.000  0.000  0.076  1.0
  O  O31  1  0.000  0.000  0.924  1.0
  O  O32  1  0.500  0.500  0.236  1.0
  O  O33  1  0.500  0.500  0.764  1.0
  O  O34  1  0.500  0.000  0.264  1.0
  O  O35  1  0.500  0.000  0.736  1.0
  O  O36  1  0.992  0.710  0.312  1.0
  O  O37  1  0.992  0.290  0.688  1.0
  O  O38  1  0.008  0.710  0.688  1.0
  O  O39  1  0.008  0.290  0.312  1.0
  O  O40  1  0.008  0.790  0.188  1.0
  O  O41  1  0.008  0.210  0.812  1.0
  O  O42  1  0.992  0.790  0.812  1.0
  O  O43  1  0.992  0.210  0.188  1.0
[/CIF]
.