The material described by SnCl5PCl4 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two [pcl4]+1 molecules and one SnCl5 cluster. In the SnCl5 cluster, Sn(1) is bonded to one Cl(1), one Cl(2), one Cl(3), one Cl(4), and two equivalent Cl(5) atoms to form edge-sharing SnCl6 octahedra. There are five inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Sn(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Sn(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Sn(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Sn(1) atom. In the fifth Cl site, Cl(5) is bonded in a water-like geometry to two equivalent Sn(1) atoms. is represented by the CIF card [CIF]
data_SnPCl9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.157
_cell_length_b   9.106
_cell_length_c   9.632
_cell_angle_alpha   100.809
_cell_angle_beta   95.771
_cell_angle_gamma   95.475
_symmetry_Int_Tables_number   1
_cell_volume   609.252
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn0  1  0.614  0.640  0.679  1.0
  Sn  Sn1  1  0.386  0.360  0.321  1.0
  P  P2  1  0.051  0.192  0.778  1.0
  P  P3  1  0.949  0.808  0.222  1.0
  Cl  Cl4  1  0.374  0.578  0.214  1.0
  Cl  Cl5  1  0.626  0.422  0.786  1.0
  Cl  Cl6  1  0.418  0.159  0.447  1.0
  Cl  Cl7  1  0.582  0.841  0.553  1.0
  Cl  Cl8  1  0.057  0.280  0.243  1.0
  Cl  Cl9  1  0.943  0.720  0.757  1.0
  Cl  Cl10  1  0.520  0.226  0.122  1.0
  Cl  Cl11  1  0.480  0.774  0.878  1.0
  Cl  Cl12  1  0.286  0.520  0.552  1.0
  Cl  Cl13  1  0.714  0.480  0.448  1.0
  Cl  Cl14  1  0.843  0.612  0.114  1.0
  Cl  Cl15  1  0.157  0.388  0.886  1.0
  Cl  Cl16  1  0.951  0.207  0.587  1.0
  Cl  Cl17  1  0.049  0.793  0.413  1.0
  Cl  Cl18  1  0.247  0.058  0.769  1.0
  Cl  Cl19  1  0.753  0.942  0.231  1.0
  Cl  Cl20  1  0.849  0.111  0.872  1.0
  Cl  Cl21  1  0.151  0.889  0.128  1.0
[/CIF]
.
The material described by SnCl5PCl4 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two [pcl4]+1 molecules and one SnCl5 cluster. In the SnCl5 cluster, Sn(1) is bonded to one Cl(1), one Cl(2), one Cl(3), one Cl(4), and two equivalent Cl(5) atoms to form edge-sharing SnCl6 octahedra. There are five inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Sn(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Sn(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Sn(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Sn(1) atom. In the fifth Cl site, Cl(5) is bonded in a water-like geometry to two equivalent Sn(1) atoms. is represented by the CIF card [CIF]
data_SnPCl9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.157
_cell_length_b   9.106
_cell_length_c   9.632
_cell_angle_alpha   100.809
_cell_angle_beta   95.771
_cell_angle_gamma   95.475
_symmetry_Int_Tables_number   1
_cell_volume   609.252
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn0  1  0.614  0.640  0.679  1.0
  Sn  Sn1  1  0.386  0.360  0.321  1.0
  P  P2  1  0.051  0.192  0.778  1.0
  P  P3  1  0.949  0.808  0.222  1.0
  Cl  Cl4  1  0.374  0.578  0.214  1.0
  Cl  Cl5  1  0.626  0.422  0.786  1.0
  Cl  Cl6  1  0.418  0.159  0.447  1.0
  Cl  Cl7  1  0.582  0.841  0.553  1.0
  Cl  Cl8  1  0.057  0.280  0.243  1.0
  Cl  Cl9  1  0.943  0.720  0.757  1.0
  Cl  Cl10  1  0.520  0.226  0.122  1.0
  Cl  Cl11  1  0.480  0.774  0.878  1.0
  Cl  Cl12  1  0.286  0.520  0.552  1.0
  Cl  Cl13  1  0.714  0.480  0.448  1.0
  Cl  Cl14  1  0.843  0.612  0.114  1.0
  Cl  Cl15  1  0.157  0.388  0.886  1.0
  Cl  Cl16  1  0.951  0.207  0.587  1.0
  Cl  Cl17  1  0.049  0.793  0.413  1.0
  Cl  Cl18  1  0.247  0.058  0.769  1.0
  Cl  Cl19  1  0.753  0.942  0.231  1.0
  Cl  Cl20  1  0.849  0.111  0.872  1.0
  Cl  Cl21  1  0.151  0.889  0.128  1.0
[/CIF]
.