The compound described by Rb2N3I crystallizes in the tetragonal P4/mbm space group. Rb(1) is bonded in a 8-coordinate geometry to four equivalent N(1) and four equivalent I(1) atoms. There are two inequivalent N sites. In the first N site, N(2) is bonded in a linear geometry to two equivalent N(1) atoms. In the second N site, N(1) is bonded in a 5-coordinate geometry to four equivalent Rb(1) and one N(2) atom. I(1) is bonded in a body-centered cubic geometry to eight equivalent Rb(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Rb2IN3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.288
_cell_length_b   6.288
_cell_length_c   8.068
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   319.025
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.000  0.000  0.264  1.0
  Rb  Rb1  1  0.000  0.000  0.736  1.0
  Rb  Rb2  1  0.500  0.500  0.736  1.0
  Rb  Rb3  1  0.500  0.500  0.264  1.0
  I  I4  1  0.500  0.000  0.000  1.0
  I  I5  1  0.000  0.500  0.000  1.0
  N  N6  1  0.867  0.367  0.500  1.0
  N  N7  1  0.633  0.867  0.500  1.0
  N  N8  1  0.367  0.133  0.500  1.0
  N  N9  1  0.133  0.633  0.500  1.0
  N  N10  1  0.000  0.500  0.500  1.0
  N  N11  1  0.500  0.000  0.500  1.0
[/CIF]
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The compound described by Rb2N3I crystallizes in the tetragonal P4/mbm space group. Rb(1) is bonded in a 8-coordinate geometry to four equivalent N(1) and four equivalent I(1) atoms. There are two inequivalent N sites. In the first N site, N(2) is bonded in a linear geometry to two equivalent N(1) atoms. In the second N site, N(1) is bonded in a 5-coordinate geometry to four equivalent Rb(1) and one N(2) atom. I(1) is bonded in a body-centered cubic geometry to eight equivalent Rb(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Rb2IN3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.288
_cell_length_b   6.288
_cell_length_c   8.068
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   319.025
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.000  0.000  0.264  1.0
  Rb  Rb1  1  0.000  0.000  0.736  1.0
  Rb  Rb2  1  0.500  0.500  0.736  1.0
  Rb  Rb3  1  0.500  0.500  0.264  1.0
  I  I4  1  0.500  0.000  0.000  1.0
  I  I5  1  0.000  0.500  0.000  1.0
  N  N6  1  0.867  0.367  0.500  1.0
  N  N7  1  0.633  0.867  0.500  1.0
  N  N8  1  0.367  0.133  0.500  1.0
  N  N9  1  0.133  0.633  0.500  1.0
  N  N10  1  0.000  0.500  0.500  1.0
  N  N11  1  0.500  0.000  0.500  1.0
[/CIF]
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