The structure described by KScF6(Tl)2 crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-28-0 atoms inside a KScF6 framework. In the KScF6 framework, K(1) is bonded to six equivalent F(1) atoms to form KF6 octahedra that share corners with six equivalent Sc(1)F6 octahedra. The corner-sharing octahedra are not tilted. Sc(1) is bonded to six equivalent F(1) atoms to form ScF6 octahedra that share corners with six equivalent K(1)F6 octahedra. The corner-sharing octahedra are not tilted. F(1) is bonded in a linear geometry to one K(1) and one Sc(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_KScTl2F6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.484
_cell_length_b   6.484
_cell_length_c   6.484
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   192.770
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.500  0.500  0.500  1.0
  Sc  Sc1  1  0.000  0.000  0.000  1.0
  Tl  Tl2  1  0.250  0.250  0.250  1.0
  Tl  Tl3  1  0.750  0.750  0.750  1.0
  F  F4  1  0.778  0.222  0.222  1.0
  F  F5  1  0.222  0.778  0.778  1.0
  F  F6  1  0.222  0.778  0.222  1.0
  F  F7  1  0.778  0.222  0.778  1.0
  F  F8  1  0.222  0.222  0.778  1.0
  F  F9  1  0.778  0.778  0.222  1.0
[/CIF]
.
The structure described by KScF6(Tl)2 crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-28-0 atoms inside a KScF6 framework. In the KScF6 framework, K(1) is bonded to six equivalent F(1) atoms to form KF6 octahedra that share corners with six equivalent Sc(1)F6 octahedra. The corner-sharing octahedra are not tilted. Sc(1) is bonded to six equivalent F(1) atoms to form ScF6 octahedra that share corners with six equivalent K(1)F6 octahedra. The corner-sharing octahedra are not tilted. F(1) is bonded in a linear geometry to one K(1) and one Sc(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_KScTl2F6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.484
_cell_length_b   6.484
_cell_length_c   6.484
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   192.770
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.500  0.500  0.500  1.0
  Sc  Sc1  1  0.000  0.000  0.000  1.0
  Tl  Tl2  1  0.250  0.250  0.250  1.0
  Tl  Tl3  1  0.750  0.750  0.750  1.0
  F  F4  1  0.778  0.222  0.222  1.0
  F  F5  1  0.222  0.778  0.778  1.0
  F  F6  1  0.222  0.778  0.222  1.0
  F  F7  1  0.778  0.222  0.778  1.0
  F  F8  1  0.222  0.222  0.778  1.0
  F  F9  1  0.778  0.778  0.222  1.0
[/CIF]
.