The structure described by Li(C3N2)2 crystallizes in the monoclinic P2/c space group. Li(1) is bonded in a tetrahedral geometry to two equivalent N(1) and two equivalent N(2) atoms. There are three inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one C(3) and one N(1) atom. In the second C site, C(2) is bonded in a distorted linear geometry to one C(3) and one N(2) atom. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(1), one C(2), and one C(3) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a linear geometry to one Li(1) and one C(1) atom. In the second N site, N(2) is bonded in a linear geometry to one Li(1) and one C(2) atom. is represented by the CIF card [CIF]
data_Li(C3N2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.608
_cell_length_b   5.414
_cell_length_c   12.249
_cell_angle_alpha   90.000
_cell_angle_beta   104.743
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   359.690
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.500  0.658  0.750  1.0
  Li  Li1  1  0.500  0.342  0.250  1.0
  C  C2  1  0.880  0.256  0.896  1.0
  C  C3  1  0.120  0.256  0.604  1.0
  C  C4  1  0.120  0.744  0.104  1.0
  C  C5  1  0.880  0.744  0.396  1.0
  C  C6  1  0.190  0.953  0.895  1.0
  C  C7  1  0.810  0.953  0.605  1.0
  C  C8  1  0.810  0.047  0.105  1.0
  C  C9  1  0.190  0.047  0.395  1.0
  C  C10  1  0.018  0.053  0.949  1.0
  C  C11  1  0.982  0.053  0.551  1.0
  C  C12  1  0.982  0.947  0.051  1.0
  C  C13  1  0.018  0.947  0.449  1.0
  N  N14  1  0.760  0.423  0.852  1.0
  N  N15  1  0.240  0.423  0.648  1.0
  N  N16  1  0.240  0.577  0.148  1.0
  N  N17  1  0.760  0.577  0.352  1.0
  N  N18  1  0.330  0.867  0.850  1.0
  N  N19  1  0.670  0.867  0.650  1.0
  N  N20  1  0.670  0.133  0.150  1.0
  N  N21  1  0.330  0.133  0.350  1.0
[/CIF]
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The structure described by Li(C3N2)2 crystallizes in the monoclinic P2/c space group. Li(1) is bonded in a tetrahedral geometry to two equivalent N(1) and two equivalent N(2) atoms. There are three inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one C(3) and one N(1) atom. In the second C site, C(2) is bonded in a distorted linear geometry to one C(3) and one N(2) atom. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(1), one C(2), and one C(3) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a linear geometry to one Li(1) and one C(1) atom. In the second N site, N(2) is bonded in a linear geometry to one Li(1) and one C(2) atom. is represented by the CIF card [CIF]
data_Li(C3N2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.608
_cell_length_b   5.414
_cell_length_c   12.249
_cell_angle_alpha   90.000
_cell_angle_beta   104.743
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   359.690
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.500  0.658  0.750  1.0
  Li  Li1  1  0.500  0.342  0.250  1.0
  C  C2  1  0.880  0.256  0.896  1.0
  C  C3  1  0.120  0.256  0.604  1.0
  C  C4  1  0.120  0.744  0.104  1.0
  C  C5  1  0.880  0.744  0.396  1.0
  C  C6  1  0.190  0.953  0.895  1.0
  C  C7  1  0.810  0.953  0.605  1.0
  C  C8  1  0.810  0.047  0.105  1.0
  C  C9  1  0.190  0.047  0.395  1.0
  C  C10  1  0.018  0.053  0.949  1.0
  C  C11  1  0.982  0.053  0.551  1.0
  C  C12  1  0.982  0.947  0.051  1.0
  C  C13  1  0.018  0.947  0.449  1.0
  N  N14  1  0.760  0.423  0.852  1.0
  N  N15  1  0.240  0.423  0.648  1.0
  N  N16  1  0.240  0.577  0.148  1.0
  N  N17  1  0.760  0.577  0.352  1.0
  N  N18  1  0.330  0.867  0.850  1.0
  N  N19  1  0.670  0.867  0.650  1.0
  N  N20  1  0.670  0.133  0.150  1.0
  N  N21  1  0.330  0.133  0.350  1.0
[/CIF]
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