The material described by Au(O7Cl2)2O2ClO2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four hydroxychloride hydrate molecules, eight water atoms, and four Au(O7Cl2)2 clusters. In each Au(O7Cl2)2 cluster, Au(1) is bonded in a square co-planar geometry to two equivalent O(2) and two equivalent O(3) atoms. There are seven inequivalent O sites. In the first O site, O(7) is bonded in a single-bond geometry to one Cl(1) atom. In the second O site, O(8) is bonded in a single-bond geometry to one Cl(1) atom. In the third O site, O(9) is bonded in a single-bond geometry to one Cl(3) atom. In the fourth O site, O(2) is bonded in a bent 120 degrees geometry to one Au(1) and one Cl(3) atom. In the fifth O site, O(3) is bonded in a bent 120 degrees geometry to one Au(1) and one Cl(1) atom. In the sixth O site, O(5) is bonded in a single-bond geometry to one Cl(3) atom. In the seventh O site, O(6) is bonded in a single-bond geometry to one Cl(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a tetrahedral geometry to one O(3), one O(6), one O(7), and one O(8) atom. In the second Cl site, Cl(3) is bonded in a trigonal non-coplanar geometry to one O(2), one O(5), and one O(9) atom. is represented by the CIF file [CIF]
data_AuCl5O18
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.612
_cell_length_b   8.612
_cell_length_c   18.164
_cell_angle_alpha   85.694
_cell_angle_beta   85.694
_cell_angle_gamma   37.323
_symmetry_Int_Tables_number   1
_cell_volume   814.165
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Au  Au0  1  0.000  0.500  0.000  1.0
  Au  Au1  1  0.500  0.000  0.500  1.0
  Cl  Cl2  1  0.395  0.975  0.670  1.0
  Cl  Cl3  1  0.025  0.605  0.830  1.0
  Cl  Cl4  1  0.975  0.395  0.170  1.0
  Cl  Cl5  1  0.777  0.223  0.750  1.0
  Cl  Cl6  1  0.985  0.232  0.455  1.0
  Cl  Cl7  1  0.605  0.025  0.330  1.0
  Cl  Cl8  1  0.768  0.015  0.045  1.0
  Cl  Cl9  1  0.232  0.985  0.955  1.0
  Cl  Cl10  1  0.015  0.768  0.545  1.0
  Cl  Cl11  1  0.223  0.777  0.250  1.0
  O  O12  1  0.152  0.883  0.615  1.0
  O  O13  1  0.117  0.848  0.885  1.0
  O  O14  1  0.296  0.986  0.457  1.0
  O  O15  1  0.462  0.174  0.407  1.0
  O  O16  1  0.325  0.606  0.191  1.0
  O  O17  1  0.538  0.826  0.593  1.0
  O  O18  1  0.879  0.257  0.527  1.0
  O  O19  1  0.125  0.205  0.657  1.0
  O  O20  1  0.786  0.458  0.215  1.0
  O  O21  1  0.458  0.786  0.715  1.0
  O  O22  1  0.494  0.974  0.305  1.0
  O  O23  1  0.848  0.117  0.385  1.0
  O  O24  1  0.826  0.538  0.093  1.0
  O  O25  1  0.214  0.542  0.785  1.0
  O  O26  1  0.542  0.214  0.285  1.0
  O  O27  1  0.458  0.900  0.934  1.0
  O  O28  1  0.675  0.394  0.809  1.0
  O  O29  1  0.900  0.458  0.434  1.0
  O  O30  1  0.121  0.743  0.473  1.0
  O  O31  1  0.026  0.506  0.195  1.0
  O  O32  1  0.743  0.121  0.973  1.0
  O  O33  1  0.174  0.462  0.907  1.0
  O  O34  1  0.014  0.704  0.043  1.0
  O  O35  1  0.506  0.026  0.695  1.0
  O  O36  1  0.974  0.494  0.805  1.0
  O  O37  1  0.986  0.296  0.957  1.0
  O  O38  1  0.257  0.879  0.027  1.0
  O  O39  1  0.606  0.325  0.691  1.0
  O  O40  1  0.100  0.542  0.566  1.0
  O  O41  1  0.704  0.014  0.543  1.0
  O  O42  1  0.795  0.875  0.843  1.0
  O  O43  1  0.542  0.100  0.066  1.0
  O  O44  1  0.883  0.152  0.115  1.0
  O  O45  1  0.205  0.125  0.157  1.0
  O  O46  1  0.875  0.795  0.343  1.0
  O  O47  1  0.394  0.675  0.309  1.0
[/CIF]
.
The material described by Au(O7Cl2)2O2ClO2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four hydroxychloride hydrate molecules, eight water atoms, and four Au(O7Cl2)2 clusters. In each Au(O7Cl2)2 cluster, Au(1) is bonded in a square co-planar geometry to two equivalent O(2) and two equivalent O(3) atoms. There are seven inequivalent O sites. In the first O site, O(7) is bonded in a single-bond geometry to one Cl(1) atom. In the second O site, O(8) is bonded in a single-bond geometry to one Cl(1) atom. In the third O site, O(9) is bonded in a single-bond geometry to one Cl(3) atom. In the fourth O site, O(2) is bonded in a bent 120 degrees geometry to one Au(1) and one Cl(3) atom. In the fifth O site, O(3) is bonded in a bent 120 degrees geometry to one Au(1) and one Cl(1) atom. In the sixth O site, O(5) is bonded in a single-bond geometry to one Cl(3) atom. In the seventh O site, O(6) is bonded in a single-bond geometry to one Cl(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a tetrahedral geometry to one O(3), one O(6), one O(7), and one O(8) atom. In the second Cl site, Cl(3) is bonded in a trigonal non-coplanar geometry to one O(2), one O(5), and one O(9) atom. is represented by the CIF file [CIF]
data_AuCl5O18
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.612
_cell_length_b   8.612
_cell_length_c   18.164
_cell_angle_alpha   85.694
_cell_angle_beta   85.694
_cell_angle_gamma   37.323
_symmetry_Int_Tables_number   1
_cell_volume   814.165
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Au  Au0  1  0.000  0.500  0.000  1.0
  Au  Au1  1  0.500  0.000  0.500  1.0
  Cl  Cl2  1  0.395  0.975  0.670  1.0
  Cl  Cl3  1  0.025  0.605  0.830  1.0
  Cl  Cl4  1  0.975  0.395  0.170  1.0
  Cl  Cl5  1  0.777  0.223  0.750  1.0
  Cl  Cl6  1  0.985  0.232  0.455  1.0
  Cl  Cl7  1  0.605  0.025  0.330  1.0
  Cl  Cl8  1  0.768  0.015  0.045  1.0
  Cl  Cl9  1  0.232  0.985  0.955  1.0
  Cl  Cl10  1  0.015  0.768  0.545  1.0
  Cl  Cl11  1  0.223  0.777  0.250  1.0
  O  O12  1  0.152  0.883  0.615  1.0
  O  O13  1  0.117  0.848  0.885  1.0
  O  O14  1  0.296  0.986  0.457  1.0
  O  O15  1  0.462  0.174  0.407  1.0
  O  O16  1  0.325  0.606  0.191  1.0
  O  O17  1  0.538  0.826  0.593  1.0
  O  O18  1  0.879  0.257  0.527  1.0
  O  O19  1  0.125  0.205  0.657  1.0
  O  O20  1  0.786  0.458  0.215  1.0
  O  O21  1  0.458  0.786  0.715  1.0
  O  O22  1  0.494  0.974  0.305  1.0
  O  O23  1  0.848  0.117  0.385  1.0
  O  O24  1  0.826  0.538  0.093  1.0
  O  O25  1  0.214  0.542  0.785  1.0
  O  O26  1  0.542  0.214  0.285  1.0
  O  O27  1  0.458  0.900  0.934  1.0
  O  O28  1  0.675  0.394  0.809  1.0
  O  O29  1  0.900  0.458  0.434  1.0
  O  O30  1  0.121  0.743  0.473  1.0
  O  O31  1  0.026  0.506  0.195  1.0
  O  O32  1  0.743  0.121  0.973  1.0
  O  O33  1  0.174  0.462  0.907  1.0
  O  O34  1  0.014  0.704  0.043  1.0
  O  O35  1  0.506  0.026  0.695  1.0
  O  O36  1  0.974  0.494  0.805  1.0
  O  O37  1  0.986  0.296  0.957  1.0
  O  O38  1  0.257  0.879  0.027  1.0
  O  O39  1  0.606  0.325  0.691  1.0
  O  O40  1  0.100  0.542  0.566  1.0
  O  O41  1  0.704  0.014  0.543  1.0
  O  O42  1  0.795  0.875  0.843  1.0
  O  O43  1  0.542  0.100  0.066  1.0
  O  O44  1  0.883  0.152  0.115  1.0
  O  O45  1  0.205  0.125  0.157  1.0
  O  O46  1  0.875  0.795  0.343  1.0
  O  O47  1  0.394  0.675  0.309  1.0
[/CIF]
.