The structure described by Cs2S5O crystallizes in the triclinic P-1 space group. There are two inequivalent Cs sites. In the first Cs site, Cs(1) is bonded in a 10-coordinate geometry to one S(3), one S(5), two equivalent S(1), two equivalent S(2), two equivalent S(4), and two equivalent O(1) atoms. In the second Cs site, Cs(2) is bonded in a 8-coordinate geometry to one S(1), one S(4), two equivalent S(3), three equivalent S(5), and one O(1) atom. There are five inequivalent S sites. In the first S site, S(1) is bonded in a single-bond geometry to one Cs(2), two equivalent Cs(1), one S(2), and one O(1) atom. In the second S site, S(2) is bonded in a 4-coordinate geometry to two equivalent Cs(1), one S(1), and one S(3) atom. In the third S site, S(3) is bonded in a 5-coordinate geometry to one Cs(1), two equivalent Cs(2), one S(2), and one S(4) atom. In the fourth S site, S(4) is bonded in a 5-coordinate geometry to one Cs(2), two equivalent Cs(1), one S(3), and one S(5) atom. In the fifth S site, S(5) is bonded in a 5-coordinate geometry to one Cs(1), three equivalent Cs(2), and one S(4) atom. O(1) is bonded in a 4-coordinate geometry to one Cs(2), two equivalent Cs(1), and one S(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Cs2S5O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.833
_cell_length_b   8.450
_cell_length_c   10.274
_cell_angle_alpha   70.626
_cell_angle_beta   76.893
_cell_angle_gamma   81.218
_symmetry_Int_Tables_number   1
_cell_volume   543.094
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.233  0.645  0.669  1.0
  Cs  Cs1  1  0.767  0.355  0.331  1.0
  Cs  Cs2  1  0.319  0.804  0.168  1.0
  Cs  Cs3  1  0.681  0.196  0.832  1.0
  S  S4  1  0.210  0.290  0.533  1.0
  S  S5  1  0.790  0.710  0.467  1.0
  S  S6  1  0.237  0.122  0.429  1.0
  S  S7  1  0.763  0.878  0.571  1.0
  S  S8  1  0.411  0.216  0.198  1.0
  S  S9  1  0.589  0.784  0.802  1.0
  S  S10  1  0.249  0.360  0.049  1.0
  S  S11  1  0.751  0.640  0.951  1.0
  S  S12  1  0.147  0.211  0.961  1.0
  S  S13  1  0.853  0.789  0.039  1.0
  O  O14  1  0.406  0.306  0.576  1.0
  O  O15  1  0.594  0.694  0.424  1.0
[/CIF]
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The structure described by Cs2S5O crystallizes in the triclinic P-1 space group. There are two inequivalent Cs sites. In the first Cs site, Cs(1) is bonded in a 10-coordinate geometry to one S(3), one S(5), two equivalent S(1), two equivalent S(2), two equivalent S(4), and two equivalent O(1) atoms. In the second Cs site, Cs(2) is bonded in a 8-coordinate geometry to one S(1), one S(4), two equivalent S(3), three equivalent S(5), and one O(1) atom. There are five inequivalent S sites. In the first S site, S(1) is bonded in a single-bond geometry to one Cs(2), two equivalent Cs(1), one S(2), and one O(1) atom. In the second S site, S(2) is bonded in a 4-coordinate geometry to two equivalent Cs(1), one S(1), and one S(3) atom. In the third S site, S(3) is bonded in a 5-coordinate geometry to one Cs(1), two equivalent Cs(2), one S(2), and one S(4) atom. In the fourth S site, S(4) is bonded in a 5-coordinate geometry to one Cs(2), two equivalent Cs(1), one S(3), and one S(5) atom. In the fifth S site, S(5) is bonded in a 5-coordinate geometry to one Cs(1), three equivalent Cs(2), and one S(4) atom. O(1) is bonded in a 4-coordinate geometry to one Cs(2), two equivalent Cs(1), and one S(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Cs2S5O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.833
_cell_length_b   8.450
_cell_length_c   10.274
_cell_angle_alpha   70.626
_cell_angle_beta   76.893
_cell_angle_gamma   81.218
_symmetry_Int_Tables_number   1
_cell_volume   543.094
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.233  0.645  0.669  1.0
  Cs  Cs1  1  0.767  0.355  0.331  1.0
  Cs  Cs2  1  0.319  0.804  0.168  1.0
  Cs  Cs3  1  0.681  0.196  0.832  1.0
  S  S4  1  0.210  0.290  0.533  1.0
  S  S5  1  0.790  0.710  0.467  1.0
  S  S6  1  0.237  0.122  0.429  1.0
  S  S7  1  0.763  0.878  0.571  1.0
  S  S8  1  0.411  0.216  0.198  1.0
  S  S9  1  0.589  0.784  0.802  1.0
  S  S10  1  0.249  0.360  0.049  1.0
  S  S11  1  0.751  0.640  0.951  1.0
  S  S12  1  0.147  0.211  0.961  1.0
  S  S13  1  0.853  0.789  0.039  1.0
  O  O14  1  0.406  0.306  0.576  1.0
  O  O15  1  0.594  0.694  0.424  1.0
[/CIF]
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