The material structure described by TaCl6(Te)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one tellurium tetramer molecule and two TaCl6 clusters. In each TaCl6 cluster, Ta(1) is bonded in an octahedral geometry to one Cl(1), one Cl(2), one Cl(3), one Cl(4), one Cl(5), and one Cl(6) atom. There are six inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Ta(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Ta(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Ta(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Ta(1) atom. In the fifth Cl site, Cl(5) is bonded in a single-bond geometry to one Ta(1) atom. In the sixth Cl site, Cl(6) is bonded in a single-bond geometry to one Ta(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ta(TeCl3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.824
_cell_length_b   7.430
_cell_length_c   11.274
_cell_angle_alpha   80.377
_cell_angle_beta   77.827
_cell_angle_gamma   86.434
_symmetry_Int_Tables_number   1
_cell_volume   550.709
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ta  Ta0  1  0.790  0.329  0.805  1.0
  Ta  Ta1  1  0.210  0.671  0.195  1.0
  Te  Te2  1  0.266  0.153  0.491  1.0
  Te  Te3  1  0.734  0.847  0.509  1.0
  Te  Te4  1  0.386  0.905  0.666  1.0
  Te  Te5  1  0.614  0.095  0.334  1.0
  Cl  Cl6  1  0.865  0.282  0.999  1.0
  Cl  Cl7  1  0.135  0.718  0.001  1.0
  Cl  Cl8  1  0.938  0.035  0.766  1.0
  Cl  Cl9  1  0.062  0.965  0.234  1.0
  Cl  Cl10  1  0.107  0.458  0.720  1.0
  Cl  Cl11  1  0.893  0.542  0.280  1.0
  Cl  Cl12  1  0.277  0.631  0.398  1.0
  Cl  Cl13  1  0.723  0.369  0.602  1.0
  Cl  Cl14  1  0.518  0.808  0.120  1.0
  Cl  Cl15  1  0.482  0.192  0.880  1.0
  Cl  Cl16  1  0.352  0.378  0.174  1.0
  Cl  Cl17  1  0.648  0.622  0.826  1.0
[/CIF]
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The material structure described by TaCl6(Te)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one tellurium tetramer molecule and two TaCl6 clusters. In each TaCl6 cluster, Ta(1) is bonded in an octahedral geometry to one Cl(1), one Cl(2), one Cl(3), one Cl(4), one Cl(5), and one Cl(6) atom. There are six inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Ta(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Ta(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Ta(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Ta(1) atom. In the fifth Cl site, Cl(5) is bonded in a single-bond geometry to one Ta(1) atom. In the sixth Cl site, Cl(6) is bonded in a single-bond geometry to one Ta(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ta(TeCl3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.824
_cell_length_b   7.430
_cell_length_c   11.274
_cell_angle_alpha   80.377
_cell_angle_beta   77.827
_cell_angle_gamma   86.434
_symmetry_Int_Tables_number   1
_cell_volume   550.709
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ta  Ta0  1  0.790  0.329  0.805  1.0
  Ta  Ta1  1  0.210  0.671  0.195  1.0
  Te  Te2  1  0.266  0.153  0.491  1.0
  Te  Te3  1  0.734  0.847  0.509  1.0
  Te  Te4  1  0.386  0.905  0.666  1.0
  Te  Te5  1  0.614  0.095  0.334  1.0
  Cl  Cl6  1  0.865  0.282  0.999  1.0
  Cl  Cl7  1  0.135  0.718  0.001  1.0
  Cl  Cl8  1  0.938  0.035  0.766  1.0
  Cl  Cl9  1  0.062  0.965  0.234  1.0
  Cl  Cl10  1  0.107  0.458  0.720  1.0
  Cl  Cl11  1  0.893  0.542  0.280  1.0
  Cl  Cl12  1  0.277  0.631  0.398  1.0
  Cl  Cl13  1  0.723  0.369  0.602  1.0
  Cl  Cl14  1  0.518  0.808  0.120  1.0
  Cl  Cl15  1  0.482  0.192  0.880  1.0
  Cl  Cl16  1  0.352  0.378  0.174  1.0
  Cl  Cl17  1  0.648  0.622  0.826  1.0
[/CIF]
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