The crystal structure described by TlCdF3 is (Cubic) Perovskite structured and crystallizes in the monoclinic Cm space group. The structure consists of two 7440-28-0 atoms inside a CdF3 framework. In the CdF3 framework, Cd(1) is bonded to two equivalent F(2) and four equivalent F(1) atoms to form corner-sharing CdF6 octahedra. The corner-sharing octahedral tilt angles range from 0-2°. There are two inequivalent F sites. In the first F site, F(1) is bonded in a linear geometry to two equivalent Cd(1) atoms. In the second F site, F(2) is bonded in a linear geometry to two equivalent Cd(1) atoms. is represented by the CIF file [CIF]
data_TlCdF3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.418
_cell_length_b   4.418
_cell_length_c   4.419
_cell_angle_alpha   89.957
_cell_angle_beta   89.957
_cell_angle_gamma   90.034
_symmetry_Int_Tables_number   1
_cell_volume   86.275
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.993  0.993  0.015  1.0
  Cd  Cd1  1  0.499  0.499  0.505  1.0
  F  F2  1  1.000  0.505  0.500  1.0
  F  F3  1  0.505  1.000  0.500  1.0
  F  F4  1  0.500  0.500  0.004  1.0
[/CIF]
.
The crystal structure described by TlCdF3 is (Cubic) Perovskite structured and crystallizes in the monoclinic Cm space group. The structure consists of two 7440-28-0 atoms inside a CdF3 framework. In the CdF3 framework, Cd(1) is bonded to two equivalent F(2) and four equivalent F(1) atoms to form corner-sharing CdF6 octahedra. The corner-sharing octahedral tilt angles range from 0-2°. There are two inequivalent F sites. In the first F site, F(1) is bonded in a linear geometry to two equivalent Cd(1) atoms. In the second F site, F(2) is bonded in a linear geometry to two equivalent Cd(1) atoms. is represented by the CIF file [CIF]
data_TlCdF3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.418
_cell_length_b   4.418
_cell_length_c   4.419
_cell_angle_alpha   89.957
_cell_angle_beta   89.957
_cell_angle_gamma   90.034
_symmetry_Int_Tables_number   1
_cell_volume   86.275
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.993  0.993  0.015  1.0
  Cd  Cd1  1  0.499  0.499  0.505  1.0
  F  F2  1  1.000  0.505  0.500  1.0
  F  F3  1  0.505  1.000  0.500  1.0
  F  F4  1  0.500  0.500  0.004  1.0
[/CIF]
.