The material structure described by CoH15(N3O)2(Br)2 is Indium-derived structured and crystallizes in the monoclinic Cc space group. The structure is zero-dimensional and consists of eight hydrogen bromide atoms and four CoH15(N3O)2 clusters. In each CoH15(N3O)2 cluster, Co(1) is bonded in an octahedral geometry to one N(1), one N(2), one N(3), one N(4), one N(5), and one N(6) atom. There are six inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Co(1), one O(1), and one O(2) atom. In the second N site, N(2) is bonded in a distorted trigonal non-coplanar geometry to one Co(1), one H(1), one H(3), and one H(7) atom. In the third N site, N(3) is bonded in a distorted trigonal non-coplanar geometry to one Co(1), one H(2), one H(4), and one H(8) atom. In the fourth N site, N(4) is bonded in a distorted trigonal non-coplanar geometry to one Co(1), one H(13), one H(14), and one H(15) atom. In the fifth N site, N(5) is bonded in a distorted trigonal non-coplanar geometry to one Co(1), one H(11), one H(5), and one H(9) atom. In the sixth N site, N(6) is bonded in a distorted trigonal non-coplanar geometry to one Co(1), one H(10), one H(12), and one H(6) atom. There are fifteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(5) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(6) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one N(2) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one N(3) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one N(5) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one N(6) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one N(5) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one N(6) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one N(4) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one N(4) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one N(4) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one N(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one N(1) atom. is represented by the CIF card [CIF]
data_CoH15Br2(N3O)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.255
_cell_length_b   7.255
_cell_length_c   11.484
_cell_angle_alpha   86.263
_cell_angle_beta   86.263
_cell_angle_gamma   78.943
_symmetry_Int_Tables_number   1
_cell_volume   591.168
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.712  0.288  0.250  1.0
  Co  Co1  1  0.288  0.712  0.750  1.0
  H  H2  1  0.030  0.416  0.277  1.0
  H  H3  1  0.587  0.970  0.220  1.0
  H  H4  1  0.970  0.587  0.720  1.0
  H  H5  1  0.416  0.030  0.777  1.0
  H  H6  1  0.912  0.548  0.172  1.0
  H  H7  1  0.454  0.086  0.327  1.0
  H  H8  1  0.086  0.454  0.827  1.0
  H  H9  1  0.548  0.912  0.672  1.0
  H  H10  1  0.741  0.440  0.035  1.0
  H  H11  1  0.562  0.258  0.465  1.0
  H  H12  1  0.258  0.562  0.965  1.0
  H  H13  1  0.440  0.741  0.535  1.0
  H  H14  1  0.845  0.577  0.311  1.0
  H  H15  1  0.424  0.155  0.188  1.0
  H  H16  1  0.155  0.424  0.688  1.0
  H  H17  1  0.577  0.845  0.811  1.0
  H  H18  1  0.595  0.289  0.038  1.0
  H  H19  1  0.713  0.404  0.461  1.0
  H  H20  1  0.404  0.713  0.961  1.0
  H  H21  1  0.289  0.595  0.538  1.0
  H  H22  1  0.825  0.212  0.029  1.0
  H  H23  1  0.790  0.174  0.469  1.0
  H  H24  1  0.174  0.790  0.969  1.0
  H  H25  1  0.212  0.825  0.529  1.0
  H  H26  1  0.986  0.032  0.172  1.0
  H  H27  1  0.032  0.986  0.672  1.0
  H  H28  1  0.895  0.952  0.298  1.0
  H  H29  1  0.952  0.895  0.798  1.0
  H  H30  1  0.040  0.100  0.300  1.0
  H  H31  1  0.100  0.040  0.800  1.0
  Br  Br32  1  0.199  0.210  0.479  1.0
  Br  Br33  1  0.786  0.796  0.009  1.0
  Br  Br34  1  0.796  0.786  0.509  1.0
  Br  Br35  1  0.210  0.199  0.979  1.0
  N  N36  1  0.497  0.502  0.250  1.0
  N  N37  1  0.502  0.497  0.750  1.0
  N  N38  1  0.899  0.477  0.251  1.0
  N  N39  1  0.525  0.100  0.247  1.0
  N  N40  1  0.100  0.525  0.747  1.0
  N  N41  1  0.477  0.899  0.751  1.0
  N  N42  1  0.933  0.068  0.254  1.0
  N  N43  1  0.068  0.933  0.754  1.0
  N  N44  1  0.720  0.309  0.067  1.0
  N  N45  1  0.693  0.279  0.432  1.0
  N  N46  1  0.279  0.693  0.932  1.0
  N  N47  1  0.309  0.720  0.567  1.0
  O  O48  1  0.365  0.496  0.187  1.0
  O  O49  1  0.502  0.634  0.312  1.0
  O  O50  1  0.634  0.502  0.812  1.0
  O  O51  1  0.496  0.365  0.687  1.0
[/CIF]
.
The material structure described by CoH15(N3O)2(Br)2 is Indium-derived structured and crystallizes in the monoclinic Cc space group. The structure is zero-dimensional and consists of eight hydrogen bromide atoms and four CoH15(N3O)2 clusters. In each CoH15(N3O)2 cluster, Co(1) is bonded in an octahedral geometry to one N(1), one N(2), one N(3), one N(4), one N(5), and one N(6) atom. There are six inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Co(1), one O(1), and one O(2) atom. In the second N site, N(2) is bonded in a distorted trigonal non-coplanar geometry to one Co(1), one H(1), one H(3), and one H(7) atom. In the third N site, N(3) is bonded in a distorted trigonal non-coplanar geometry to one Co(1), one H(2), one H(4), and one H(8) atom. In the fourth N site, N(4) is bonded in a distorted trigonal non-coplanar geometry to one Co(1), one H(13), one H(14), and one H(15) atom. In the fifth N site, N(5) is bonded in a distorted trigonal non-coplanar geometry to one Co(1), one H(11), one H(5), and one H(9) atom. In the sixth N site, N(6) is bonded in a distorted trigonal non-coplanar geometry to one Co(1), one H(10), one H(12), and one H(6) atom. There are fifteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(5) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(6) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one N(2) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one N(3) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one N(5) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one N(6) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one N(5) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one N(6) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one N(4) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one N(4) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one N(4) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one N(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one N(1) atom. is represented by the CIF card [CIF]
data_CoH15Br2(N3O)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.255
_cell_length_b   7.255
_cell_length_c   11.484
_cell_angle_alpha   86.263
_cell_angle_beta   86.263
_cell_angle_gamma   78.943
_symmetry_Int_Tables_number   1
_cell_volume   591.168
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.712  0.288  0.250  1.0
  Co  Co1  1  0.288  0.712  0.750  1.0
  H  H2  1  0.030  0.416  0.277  1.0
  H  H3  1  0.587  0.970  0.220  1.0
  H  H4  1  0.970  0.587  0.720  1.0
  H  H5  1  0.416  0.030  0.777  1.0
  H  H6  1  0.912  0.548  0.172  1.0
  H  H7  1  0.454  0.086  0.327  1.0
  H  H8  1  0.086  0.454  0.827  1.0
  H  H9  1  0.548  0.912  0.672  1.0
  H  H10  1  0.741  0.440  0.035  1.0
  H  H11  1  0.562  0.258  0.465  1.0
  H  H12  1  0.258  0.562  0.965  1.0
  H  H13  1  0.440  0.741  0.535  1.0
  H  H14  1  0.845  0.577  0.311  1.0
  H  H15  1  0.424  0.155  0.188  1.0
  H  H16  1  0.155  0.424  0.688  1.0
  H  H17  1  0.577  0.845  0.811  1.0
  H  H18  1  0.595  0.289  0.038  1.0
  H  H19  1  0.713  0.404  0.461  1.0
  H  H20  1  0.404  0.713  0.961  1.0
  H  H21  1  0.289  0.595  0.538  1.0
  H  H22  1  0.825  0.212  0.029  1.0
  H  H23  1  0.790  0.174  0.469  1.0
  H  H24  1  0.174  0.790  0.969  1.0
  H  H25  1  0.212  0.825  0.529  1.0
  H  H26  1  0.986  0.032  0.172  1.0
  H  H27  1  0.032  0.986  0.672  1.0
  H  H28  1  0.895  0.952  0.298  1.0
  H  H29  1  0.952  0.895  0.798  1.0
  H  H30  1  0.040  0.100  0.300  1.0
  H  H31  1  0.100  0.040  0.800  1.0
  Br  Br32  1  0.199  0.210  0.479  1.0
  Br  Br33  1  0.786  0.796  0.009  1.0
  Br  Br34  1  0.796  0.786  0.509  1.0
  Br  Br35  1  0.210  0.199  0.979  1.0
  N  N36  1  0.497  0.502  0.250  1.0
  N  N37  1  0.502  0.497  0.750  1.0
  N  N38  1  0.899  0.477  0.251  1.0
  N  N39  1  0.525  0.100  0.247  1.0
  N  N40  1  0.100  0.525  0.747  1.0
  N  N41  1  0.477  0.899  0.751  1.0
  N  N42  1  0.933  0.068  0.254  1.0
  N  N43  1  0.068  0.933  0.754  1.0
  N  N44  1  0.720  0.309  0.067  1.0
  N  N45  1  0.693  0.279  0.432  1.0
  N  N46  1  0.279  0.693  0.932  1.0
  N  N47  1  0.309  0.720  0.567  1.0
  O  O48  1  0.365  0.496  0.187  1.0
  O  O49  1  0.502  0.634  0.312  1.0
  O  O50  1  0.634  0.502  0.812  1.0
  O  O51  1  0.496  0.365  0.687  1.0
[/CIF]
.