The crystal structure described by Mn3Co3(TeO8)2 is beta Vanadium nitride-derived structured and crystallizes in the monoclinic Cm space group. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(3), one O(4), two equivalent O(11), and two equivalent O(6) atoms to form MnO6 octahedra that share corners with two equivalent Te(2)O6 octahedra,  an edgeedge with one Te(1)O6 octahedra, and edges with four equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles are 54°. In the second Mn site, Mn(2) is bonded to one O(1), one O(10), one O(12), one O(5), one O(8), and one O(9) atom to form MnO6 octahedra that share corners with two equivalent Te(1)O6 octahedra,  an edgeedge with one Te(2)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, and edges with two equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-53°. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(11), one O(2), one O(3), one O(4), one O(6), and one O(7) atom to form CoO6 octahedra that share corners with two equivalent Te(2)O6 octahedra,  an edgeedge with one Te(1)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and edges with two equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-55°. In the second Co site, Co(2) is bonded to one O(10), one O(5), two equivalent O(1), and two equivalent O(9) atoms to form CoO6 octahedra that share corners with two equivalent Te(1)O6 octahedra,  an edgeedge with one Te(2)O6 octahedra, and edges with four equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles are 52°. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(2), one O(8), two equivalent O(1), and two equivalent O(6) atoms to form TeO6 octahedra that share corners with two equivalent Co(2)O6 octahedra, corners with four equivalent Mn(2)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra, and edges with two equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-53°. In the second Te site, Te(2) is bonded to one O(12), one O(7), two equivalent O(11), and two equivalent O(9) atoms to form distorted TeO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra, corners with four equivalent Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-55°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Mn(2), one Co(2), and one Te(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to two equivalent Co(1) and one Te(1) atom. In the third O site, O(3) is bonded in a distorted T-shaped geometry to one Mn(1) and two equivalent Co(1) atoms. In the fourth O site, O(4) is bonded in a distorted trigonal non-coplanar geometry to one Mn(1) and two equivalent Co(1) atoms. In the fifth O site, O(5) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Mn(2) and one Co(2) atom. In the sixth O site, O(6) is bonded in a distorted T-shaped geometry to one Mn(1), one Co(1), and one Te(1) atom. In the seventh O site, O(7) is bonded in a trigonal planar geometry to two equivalent Co(1) and one Te(2) atom. In the eighth O site, O(8) is bonded in a distorted trigonal planar geometry to two equivalent Mn(2) and one Te(1) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one Mn(2), one Co(2), and one Te(2) atom. In the tenth O site, O(10) is bonded in a distorted T-shaped geometry to two equivalent Mn(2) and one Co(2) atom. In the eleventh O site, O(11) is bonded in a distorted trigonal planar geometry to one Mn(1), one Co(1), and one Te(2) atom. In the twelfth O site, O(12) is bonded in a 3-coordinate geometry to two equivalent Mn(2) and one Te(2) atom. is represented by the CIF card [CIF]
data_Mn3Co3(TeO8)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.709
_cell_length_b   5.709
_cell_length_c   9.353
_cell_angle_alpha   89.920
_cell_angle_beta   89.920
_cell_angle_gamma   60.355
_symmetry_Int_Tables_number   1
_cell_volume   264.975
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.166  0.166  0.214  1.0
  Mn  Mn1  1  0.829  0.338  0.717  1.0
  Mn  Mn2  1  0.338  0.829  0.717  1.0
  Co  Co3  1  0.660  0.168  0.216  1.0
  Co  Co4  1  0.168  0.660  0.216  1.0
  Co  Co5  1  0.827  0.827  0.712  1.0
  Te  Te6  1  0.334  0.334  0.489  1.0
  Te  Te7  1  0.671  0.671  0.998  1.0
  O  O8  1  0.677  0.159  0.598  1.0
  O  O9  1  0.483  0.483  0.329  1.0
  O  O10  1  0.331  0.331  0.111  1.0
  O  O11  1  0.999  0.999  0.313  1.0
  O  O12  1  0.999  0.999  0.811  1.0
  O  O13  1  0.159  0.677  0.598  1.0
  O  O14  1  0.486  0.030  0.336  1.0
  O  O15  1  0.030  0.486  0.336  1.0
  O  O16  1  0.847  0.847  0.101  1.0
  O  O17  1  0.163  0.163  0.597  1.0
  O  O18  1  0.971  0.512  0.829  1.0
  O  O19  1  0.512  0.971  0.829  1.0
  O  O20  1  0.662  0.662  0.609  1.0
  O  O21  1  0.841  0.317  0.102  1.0
  O  O22  1  0.514  0.514  0.833  1.0
  O  O23  1  0.317  0.841  0.102  1.0
[/CIF]
.
The crystal structure described by Mn3Co3(TeO8)2 is beta Vanadium nitride-derived structured and crystallizes in the monoclinic Cm space group. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(3), one O(4), two equivalent O(11), and two equivalent O(6) atoms to form MnO6 octahedra that share corners with two equivalent Te(2)O6 octahedra,  an edgeedge with one Te(1)O6 octahedra, and edges with four equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles are 54°. In the second Mn site, Mn(2) is bonded to one O(1), one O(10), one O(12), one O(5), one O(8), and one O(9) atom to form MnO6 octahedra that share corners with two equivalent Te(1)O6 octahedra,  an edgeedge with one Te(2)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, and edges with two equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-53°. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(11), one O(2), one O(3), one O(4), one O(6), and one O(7) atom to form CoO6 octahedra that share corners with two equivalent Te(2)O6 octahedra,  an edgeedge with one Te(1)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and edges with two equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-55°. In the second Co site, Co(2) is bonded to one O(10), one O(5), two equivalent O(1), and two equivalent O(9) atoms to form CoO6 octahedra that share corners with two equivalent Te(1)O6 octahedra,  an edgeedge with one Te(2)O6 octahedra, and edges with four equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles are 52°. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(2), one O(8), two equivalent O(1), and two equivalent O(6) atoms to form TeO6 octahedra that share corners with two equivalent Co(2)O6 octahedra, corners with four equivalent Mn(2)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra, and edges with two equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-53°. In the second Te site, Te(2) is bonded to one O(12), one O(7), two equivalent O(11), and two equivalent O(9) atoms to form distorted TeO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra, corners with four equivalent Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-55°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Mn(2), one Co(2), and one Te(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to two equivalent Co(1) and one Te(1) atom. In the third O site, O(3) is bonded in a distorted T-shaped geometry to one Mn(1) and two equivalent Co(1) atoms. In the fourth O site, O(4) is bonded in a distorted trigonal non-coplanar geometry to one Mn(1) and two equivalent Co(1) atoms. In the fifth O site, O(5) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Mn(2) and one Co(2) atom. In the sixth O site, O(6) is bonded in a distorted T-shaped geometry to one Mn(1), one Co(1), and one Te(1) atom. In the seventh O site, O(7) is bonded in a trigonal planar geometry to two equivalent Co(1) and one Te(2) atom. In the eighth O site, O(8) is bonded in a distorted trigonal planar geometry to two equivalent Mn(2) and one Te(1) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one Mn(2), one Co(2), and one Te(2) atom. In the tenth O site, O(10) is bonded in a distorted T-shaped geometry to two equivalent Mn(2) and one Co(2) atom. In the eleventh O site, O(11) is bonded in a distorted trigonal planar geometry to one Mn(1), one Co(1), and one Te(2) atom. In the twelfth O site, O(12) is bonded in a 3-coordinate geometry to two equivalent Mn(2) and one Te(2) atom. is represented by the CIF card [CIF]
data_Mn3Co3(TeO8)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.709
_cell_length_b   5.709
_cell_length_c   9.353
_cell_angle_alpha   89.920
_cell_angle_beta   89.920
_cell_angle_gamma   60.355
_symmetry_Int_Tables_number   1
_cell_volume   264.975
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.166  0.166  0.214  1.0
  Mn  Mn1  1  0.829  0.338  0.717  1.0
  Mn  Mn2  1  0.338  0.829  0.717  1.0
  Co  Co3  1  0.660  0.168  0.216  1.0
  Co  Co4  1  0.168  0.660  0.216  1.0
  Co  Co5  1  0.827  0.827  0.712  1.0
  Te  Te6  1  0.334  0.334  0.489  1.0
  Te  Te7  1  0.671  0.671  0.998  1.0
  O  O8  1  0.677  0.159  0.598  1.0
  O  O9  1  0.483  0.483  0.329  1.0
  O  O10  1  0.331  0.331  0.111  1.0
  O  O11  1  0.999  0.999  0.313  1.0
  O  O12  1  0.999  0.999  0.811  1.0
  O  O13  1  0.159  0.677  0.598  1.0
  O  O14  1  0.486  0.030  0.336  1.0
  O  O15  1  0.030  0.486  0.336  1.0
  O  O16  1  0.847  0.847  0.101  1.0
  O  O17  1  0.163  0.163  0.597  1.0
  O  O18  1  0.971  0.512  0.829  1.0
  O  O19  1  0.512  0.971  0.829  1.0
  O  O20  1  0.662  0.662  0.609  1.0
  O  O21  1  0.841  0.317  0.102  1.0
  O  O22  1  0.514  0.514  0.833  1.0
  O  O23  1  0.317  0.841  0.102  1.0
[/CIF]
.