The structure described by N(CH3)4I(OF)2 is Silicon tetrafluoride-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of four tetramethylammonium molecules and four I(OF)2 clusters. In each I(OF)2 cluster, there are two inequivalent O sites. In the first O site, O(2) is bonded in a single-bond geometry to one I(1) atom. In the second O site, O(1) is bonded in a single-bond geometry to one I(1) atom. I(1) is bonded in a see-saw-like geometry to one O(1), one O(2), and two equivalent F(1) atoms. F(1) is bonded in a single-bond geometry to one I(1) atom. is represented by the CIF card [CIF]
data_H12C4IN(OF)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.507
_cell_length_b   9.507
_cell_length_c   5.636
_cell_angle_alpha   88.757
_cell_angle_beta   88.757
_cell_angle_gamma   107.259
_symmetry_Int_Tables_number   1
_cell_volume   486.076
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.158  0.581  0.975  1.0
  H  H1  1  0.581  0.158  0.975  1.0
  H  H2  1  0.842  0.419  0.025  1.0
  H  H3  1  0.419  0.842  0.025  1.0
  H  H4  1  0.071  0.661  0.750  1.0
  H  H5  1  0.661  0.071  0.750  1.0
  H  H6  1  0.929  0.339  0.250  1.0
  H  H7  1  0.339  0.929  0.250  1.0
  H  H8  1  0.268  0.692  0.738  1.0
  H  H9  1  0.692  0.268  0.738  1.0
  H  H10  1  0.732  0.308  0.262  1.0
  H  H11  1  0.308  0.732  0.262  1.0
  H  H12  1  0.225  0.038  0.950  1.0
  H  H13  1  0.038  0.225  0.950  1.0
  H  H14  1  0.775  0.962  0.050  1.0
  H  H15  1  0.962  0.775  0.050  1.0
  H  H16  1  0.307  0.954  0.724  1.0
  H  H17  1  0.954  0.307  0.724  1.0
  H  H18  1  0.693  0.046  0.276  1.0
  H  H19  1  0.046  0.693  0.276  1.0
  H  H20  1  0.111  0.924  0.735  1.0
  H  H21  1  0.924  0.111  0.735  1.0
  H  H22  1  0.889  0.076  0.265  1.0
  H  H23  1  0.076  0.889  0.265  1.0
  C  C24  1  0.170  0.676  0.853  1.0
  C  C25  1  0.676  0.170  0.853  1.0
  C  C26  1  0.830  0.324  0.147  1.0
  C  C27  1  0.324  0.830  0.147  1.0
  C  C28  1  0.210  0.942  0.839  1.0
  C  C29  1  0.942  0.210  0.839  1.0
  C  C30  1  0.790  0.058  0.161  1.0
  C  C31  1  0.058  0.790  0.161  1.0
  I  I32  1  0.332  0.332  0.376  1.0
  I  I33  1  0.668  0.668  0.624  1.0
  N  N34  1  0.191  0.809  0.000  1.0
  N  N35  1  0.809  0.191  0.000  1.0
  O  O36  1  0.370  0.370  0.684  1.0
  O  O37  1  0.630  0.630  0.316  1.0
  O  O38  1  0.172  0.172  0.375  1.0
  O  O39  1  0.828  0.828  0.625  1.0
  F  F40  1  0.471  0.202  0.355  1.0
  F  F41  1  0.202  0.471  0.355  1.0
  F  F42  1  0.529  0.798  0.645  1.0
  F  F43  1  0.798  0.529  0.645  1.0
[/CIF]
.
The structure described by N(CH3)4I(OF)2 is Silicon tetrafluoride-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of four tetramethylammonium molecules and four I(OF)2 clusters. In each I(OF)2 cluster, there are two inequivalent O sites. In the first O site, O(2) is bonded in a single-bond geometry to one I(1) atom. In the second O site, O(1) is bonded in a single-bond geometry to one I(1) atom. I(1) is bonded in a see-saw-like geometry to one O(1), one O(2), and two equivalent F(1) atoms. F(1) is bonded in a single-bond geometry to one I(1) atom. is represented by the CIF card [CIF]
data_H12C4IN(OF)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.507
_cell_length_b   9.507
_cell_length_c   5.636
_cell_angle_alpha   88.757
_cell_angle_beta   88.757
_cell_angle_gamma   107.259
_symmetry_Int_Tables_number   1
_cell_volume   486.076
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.158  0.581  0.975  1.0
  H  H1  1  0.581  0.158  0.975  1.0
  H  H2  1  0.842  0.419  0.025  1.0
  H  H3  1  0.419  0.842  0.025  1.0
  H  H4  1  0.071  0.661  0.750  1.0
  H  H5  1  0.661  0.071  0.750  1.0
  H  H6  1  0.929  0.339  0.250  1.0
  H  H7  1  0.339  0.929  0.250  1.0
  H  H8  1  0.268  0.692  0.738  1.0
  H  H9  1  0.692  0.268  0.738  1.0
  H  H10  1  0.732  0.308  0.262  1.0
  H  H11  1  0.308  0.732  0.262  1.0
  H  H12  1  0.225  0.038  0.950  1.0
  H  H13  1  0.038  0.225  0.950  1.0
  H  H14  1  0.775  0.962  0.050  1.0
  H  H15  1  0.962  0.775  0.050  1.0
  H  H16  1  0.307  0.954  0.724  1.0
  H  H17  1  0.954  0.307  0.724  1.0
  H  H18  1  0.693  0.046  0.276  1.0
  H  H19  1  0.046  0.693  0.276  1.0
  H  H20  1  0.111  0.924  0.735  1.0
  H  H21  1  0.924  0.111  0.735  1.0
  H  H22  1  0.889  0.076  0.265  1.0
  H  H23  1  0.076  0.889  0.265  1.0
  C  C24  1  0.170  0.676  0.853  1.0
  C  C25  1  0.676  0.170  0.853  1.0
  C  C26  1  0.830  0.324  0.147  1.0
  C  C27  1  0.324  0.830  0.147  1.0
  C  C28  1  0.210  0.942  0.839  1.0
  C  C29  1  0.942  0.210  0.839  1.0
  C  C30  1  0.790  0.058  0.161  1.0
  C  C31  1  0.058  0.790  0.161  1.0
  I  I32  1  0.332  0.332  0.376  1.0
  I  I33  1  0.668  0.668  0.624  1.0
  N  N34  1  0.191  0.809  0.000  1.0
  N  N35  1  0.809  0.191  0.000  1.0
  O  O36  1  0.370  0.370  0.684  1.0
  O  O37  1  0.630  0.630  0.316  1.0
  O  O38  1  0.172  0.172  0.375  1.0
  O  O39  1  0.828  0.828  0.625  1.0
  F  F40  1  0.471  0.202  0.355  1.0
  F  F41  1  0.202  0.471  0.355  1.0
  F  F42  1  0.529  0.798  0.645  1.0
  F  F43  1  0.798  0.529  0.645  1.0
[/CIF]
.