The crystal structure described by Li2VF4 crystallizes in the monoclinic P2_1/c space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded in a 3-coordinate geometry to one F(1), one F(2), and one F(3) atom. In the second Li site, Li(2) is bonded in a 5-coordinate geometry to one F(4), two equivalent F(2), and two equivalent F(3) atoms. V(1) is bonded to one F(2), one F(3), two equivalent F(1), and two equivalent F(4) atoms to form edge-sharing VF6 octahedra. There are four inequivalent F sites. In the first F site, F(1) is bonded in a 3-coordinate geometry to one Li(1) and two equivalent V(1) atoms. In the second F site, F(2) is bonded in a 4-coordinate geometry to one Li(1), two equivalent Li(2), and one V(1) atom. In the third F site, F(3) is bonded to one Li(1), two equivalent Li(2), and one V(1) atom to form distorted edge-sharing FLi3V trigonal pyramids. In the fourth F site, F(4) is bonded in a trigonal non-coplanar geometry to one Li(2) and two equivalent V(1) atoms. is represented by the CIF file [CIF]
data_Li2VF4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.192
_cell_length_b   5.382
_cell_length_c   11.041
_cell_angle_alpha   65.803
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   335.624
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.566  0.591  0.724  1.0
  Li  Li1  1  0.113  0.201  0.052  1.0
  Li  Li2  1  0.066  0.409  0.776  1.0
  Li  Li3  1  0.613  0.799  0.448  1.0
  Li  Li4  1  0.387  0.201  0.552  1.0
  Li  Li5  1  0.934  0.591  0.224  1.0
  Li  Li6  1  0.887  0.799  0.948  1.0
  Li  Li7  1  0.434  0.409  0.276  1.0
  V  V8  1  0.634  0.233  0.012  1.0
  V  V9  1  0.134  0.767  0.488  1.0
  V  V10  1  0.866  0.233  0.512  1.0
  V  V11  1  0.366  0.767  0.988  1.0
  F  F12  1  0.394  0.509  0.884  1.0
  F  F13  1  0.878  0.497  0.893  1.0
  F  F14  1  0.377  0.044  0.386  1.0
  F  F15  1  0.871  0.017  0.391  1.0
  F  F16  1  0.378  0.503  0.607  1.0
  F  F17  1  0.894  0.491  0.616  1.0
  F  F18  1  0.371  0.983  0.109  1.0
  F  F19  1  0.877  0.956  0.114  1.0
  F  F20  1  0.123  0.044  0.886  1.0
  F  F21  1  0.629  0.017  0.891  1.0
  F  F22  1  0.106  0.509  0.384  1.0
  F  F23  1  0.622  0.497  0.393  1.0
  F  F24  1  0.129  0.983  0.609  1.0
  F  F25  1  0.623  0.956  0.614  1.0
  F  F26  1  0.122  0.503  0.107  1.0
  F  F27  1  0.606  0.491  0.116  1.0
[/CIF]
.
The crystal structure described by Li2VF4 crystallizes in the monoclinic P2_1/c space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded in a 3-coordinate geometry to one F(1), one F(2), and one F(3) atom. In the second Li site, Li(2) is bonded in a 5-coordinate geometry to one F(4), two equivalent F(2), and two equivalent F(3) atoms. V(1) is bonded to one F(2), one F(3), two equivalent F(1), and two equivalent F(4) atoms to form edge-sharing VF6 octahedra. There are four inequivalent F sites. In the first F site, F(1) is bonded in a 3-coordinate geometry to one Li(1) and two equivalent V(1) atoms. In the second F site, F(2) is bonded in a 4-coordinate geometry to one Li(1), two equivalent Li(2), and one V(1) atom. In the third F site, F(3) is bonded to one Li(1), two equivalent Li(2), and one V(1) atom to form distorted edge-sharing FLi3V trigonal pyramids. In the fourth F site, F(4) is bonded in a trigonal non-coplanar geometry to one Li(2) and two equivalent V(1) atoms. is represented by the CIF file [CIF]
data_Li2VF4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.192
_cell_length_b   5.382
_cell_length_c   11.041
_cell_angle_alpha   65.803
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   335.624
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.566  0.591  0.724  1.0
  Li  Li1  1  0.113  0.201  0.052  1.0
  Li  Li2  1  0.066  0.409  0.776  1.0
  Li  Li3  1  0.613  0.799  0.448  1.0
  Li  Li4  1  0.387  0.201  0.552  1.0
  Li  Li5  1  0.934  0.591  0.224  1.0
  Li  Li6  1  0.887  0.799  0.948  1.0
  Li  Li7  1  0.434  0.409  0.276  1.0
  V  V8  1  0.634  0.233  0.012  1.0
  V  V9  1  0.134  0.767  0.488  1.0
  V  V10  1  0.866  0.233  0.512  1.0
  V  V11  1  0.366  0.767  0.988  1.0
  F  F12  1  0.394  0.509  0.884  1.0
  F  F13  1  0.878  0.497  0.893  1.0
  F  F14  1  0.377  0.044  0.386  1.0
  F  F15  1  0.871  0.017  0.391  1.0
  F  F16  1  0.378  0.503  0.607  1.0
  F  F17  1  0.894  0.491  0.616  1.0
  F  F18  1  0.371  0.983  0.109  1.0
  F  F19  1  0.877  0.956  0.114  1.0
  F  F20  1  0.123  0.044  0.886  1.0
  F  F21  1  0.629  0.017  0.891  1.0
  F  F22  1  0.106  0.509  0.384  1.0
  F  F23  1  0.622  0.497  0.393  1.0
  F  F24  1  0.129  0.983  0.609  1.0
  F  F25  1  0.623  0.956  0.614  1.0
  F  F26  1  0.122  0.503  0.107  1.0
  F  F27  1  0.606  0.491  0.116  1.0
[/CIF]
.