The structure described by NiO6(SO3)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two sulfur trioxide molecules and one NiO6 cluster. In the NiO6 cluster, Ni(1) is bonded in an octahedral geometry to two equivalent O(4), two equivalent O(5), and two equivalent O(6) atoms. There are three inequivalent O sites. In the first O site, O(4) is bonded in a 2-coordinate geometry to one Ni(1) and one O(6) atom. In the second O site, O(5) is bonded in a single-bond geometry to one Ni(1) atom. In the third O site, O(6) is bonded in a 2-coordinate geometry to one Ni(1) and one O(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ni(SO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.289
_cell_length_b   6.992
_cell_length_c   7.920
_cell_angle_alpha   106.740
_cell_angle_beta   109.420
_cell_angle_gamma   88.757
_symmetry_Int_Tables_number   1
_cell_volume   313.469
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ni  Ni0  1  0.000  0.000  0.000  1.0
  S  S1  1  0.485  0.426  0.696  1.0
  S  S2  1  0.515  0.574  0.304  1.0
  O  O3  1  0.310  0.265  0.599  1.0
  O  O4  1  0.690  0.735  0.401  1.0
  O  O5  1  0.438  0.617  0.799  1.0
  O  O6  1  0.562  0.383  0.201  1.0
  O  O7  1  0.708  0.396  0.685  1.0
  O  O8  1  0.292  0.604  0.315  1.0
  O  O9  1  0.020  0.937  0.225  1.0
  O  O10  1  0.980  0.063  0.775  1.0
  O  O11  1  0.943  0.247  0.084  1.0
  O  O12  1  0.057  0.753  0.916  1.0
  O  O13  1  0.808  0.934  0.125  1.0
  O  O14  1  0.192  0.066  0.875  1.0
[/CIF]
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The structure described by NiO6(SO3)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two sulfur trioxide molecules and one NiO6 cluster. In the NiO6 cluster, Ni(1) is bonded in an octahedral geometry to two equivalent O(4), two equivalent O(5), and two equivalent O(6) atoms. There are three inequivalent O sites. In the first O site, O(4) is bonded in a 2-coordinate geometry to one Ni(1) and one O(6) atom. In the second O site, O(5) is bonded in a single-bond geometry to one Ni(1) atom. In the third O site, O(6) is bonded in a 2-coordinate geometry to one Ni(1) and one O(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ni(SO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.289
_cell_length_b   6.992
_cell_length_c   7.920
_cell_angle_alpha   106.740
_cell_angle_beta   109.420
_cell_angle_gamma   88.757
_symmetry_Int_Tables_number   1
_cell_volume   313.469
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ni  Ni0  1  0.000  0.000  0.000  1.0
  S  S1  1  0.485  0.426  0.696  1.0
  S  S2  1  0.515  0.574  0.304  1.0
  O  O3  1  0.310  0.265  0.599  1.0
  O  O4  1  0.690  0.735  0.401  1.0
  O  O5  1  0.438  0.617  0.799  1.0
  O  O6  1  0.562  0.383  0.201  1.0
  O  O7  1  0.708  0.396  0.685  1.0
  O  O8  1  0.292  0.604  0.315  1.0
  O  O9  1  0.020  0.937  0.225  1.0
  O  O10  1  0.980  0.063  0.775  1.0
  O  O11  1  0.943  0.247  0.084  1.0
  O  O12  1  0.057  0.753  0.916  1.0
  O  O13  1  0.808  0.934  0.125  1.0
  O  O14  1  0.192  0.066  0.875  1.0
[/CIF]
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