The structure described by NaFe3Al6B3Si6H3O30F crystallizes in the trigonal R3m space group. Na(1) is bonded in a 10-coordinate geometry to three equivalent O(1), three equivalent O(3), three equivalent O(4), and one F(1) atom. Fe(1) is bonded to one O(2), two equivalent O(1), two equivalent O(5), and one F(1) atom to form distorted FeO5F octahedra that share corners with two equivalent Si(1)O4 tetrahedra, edges with two equivalent Fe(1)O5F octahedra, and edges with two equivalent Al(1)O6 octahedra. Al(1) is bonded to one O(2), one O(5), two equivalent O(6), and two equivalent O(7) atoms to form AlO6 octahedra that share  a cornercorner with one Al(1)O6 octahedra, corners with three equivalent Si(1)O4 tetrahedra,  an edgeedge with one Fe(1)O5F octahedra, and edges with two equivalent Al(1)O6 octahedra. The corner-sharing octahedral tilt angles are 48°. B(1) is bonded in a trigonal planar geometry to one O(1) and two equivalent O(7) atoms. Si(1) is bonded to one O(3), one O(4), one O(5), and one O(6) atom to form SiO4 tetrahedra that share  a cornercorner with one Fe(1)O5F octahedra, corners with three equivalent Al(1)O6 octahedra, and corners with two equivalent Si(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 49-61°. H(1) is bonded in a single-bond geometry to one O(2) atom. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Na(1), two equivalent Fe(1), and one B(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Fe(1), two equivalent Al(1), and one H(1) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Na(1) and two equivalent Si(1) atoms. In the fourth O site, O(4) is bonded in a 2-coordinate geometry to one Na(1) and two equivalent Si(1) atoms. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Fe(1), one Al(1), and one Si(1) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to two equivalent Al(1) and one Si(1) atom. In the seventh O site, O(7) is bonded in a distorted trigonal planar geometry to two equivalent Al(1) and one B(1) atom. F(1) is bonded in a 4-coordinate geometry to one Na(1) and three equivalent Fe(1) atoms. is represented by the CIF file [CIF]
data_NaAl6Fe3Si6B3H3O30F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.592
_cell_length_b   9.592
_cell_length_c   9.592
_cell_angle_alpha   113.847
_cell_angle_beta   113.847
_cell_angle_gamma   113.847
_symmetry_Int_Tables_number   1
_cell_volume   542.160
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.219  0.219  0.219  1.0
  Al  Al1  1  0.906  0.573  0.349  1.0
  Al  Al2  1  0.349  0.906  0.573  1.0
  Al  Al3  1  0.573  0.349  0.906  1.0
  Al  Al4  1  0.349  0.573  0.906  1.0
  Al  Al5  1  0.906  0.349  0.573  1.0
  Al  Al6  1  0.573  0.906  0.349  1.0
  Fe  Fe7  1  0.577  0.744  0.577  1.0
  Fe  Fe8  1  0.577  0.577  0.744  1.0
  Fe  Fe9  1  0.744  0.577  0.577  1.0
  Si  Si10  1  0.188  0.994  0.805  1.0
  Si  Si11  1  0.805  0.188  0.994  1.0
  Si  Si12  1  0.994  0.805  0.188  1.0
  Si  Si13  1  0.805  0.994  0.188  1.0
  Si  Si14  1  0.188  0.805  0.994  1.0
  Si  Si15  1  0.994  0.188  0.805  1.0
  B  B16  1  0.560  0.227  0.560  1.0
  B  B17  1  0.560  0.560  0.227  1.0
  B  B18  1  0.227  0.560  0.560  1.0
  H  H19  1  0.245  0.643  0.245  1.0
  H  H20  1  0.245  0.245  0.643  1.0
  H  H21  1  0.643  0.245  0.245  1.0
  O  O22  1  0.528  0.342  0.528  1.0
  O  O23  1  0.528  0.528  0.342  1.0
  O  O24  1  0.342  0.528  0.528  1.0
  O  O25  1  0.376  0.782  0.376  1.0
  O  O26  1  0.376  0.376  0.782  1.0
  O  O27  1  0.782  0.376  0.376  1.0
  O  O28  1  0.160  0.881  0.160  1.0
  O  O29  1  0.160  0.160  0.881  1.0
  O  O30  1  0.881  0.160  0.160  1.0
  O  O31  1  0.993  0.273  0.993  1.0
  O  O32  1  0.993  0.993  0.273  1.0
  O  O33  1  0.273  0.993  0.993  1.0
  O  O34  1  0.969  0.765  0.585  1.0
  O  O35  1  0.585  0.969  0.765  1.0
  O  O36  1  0.765  0.585  0.969  1.0
  O  O37  1  0.585  0.765  0.969  1.0
  O  O38  1  0.969  0.585  0.765  1.0
  O  O39  1  0.765  0.969  0.585  1.0
  O  O40  1  0.364  0.079  0.793  1.0
  O  O41  1  0.793  0.364  0.079  1.0
  O  O42  1  0.079  0.793  0.364  1.0
  O  O43  1  0.793  0.079  0.364  1.0
  O  O44  1  0.364  0.793  0.079  1.0
  O  O45  1  0.079  0.364  0.793  1.0
  O  O46  1  0.652  0.503  0.168  1.0
  O  O47  1  0.168  0.652  0.503  1.0
  O  O48  1  0.503  0.168  0.652  1.0
  O  O49  1  0.168  0.503  0.652  1.0
  O  O50  1  0.652  0.168  0.503  1.0
  O  O51  1  0.503  0.652  0.168  1.0
  F  F52  1  0.849  0.849  0.849  1.0
[/CIF]
.
The structure described by NaFe3Al6B3Si6H3O30F crystallizes in the trigonal R3m space group. Na(1) is bonded in a 10-coordinate geometry to three equivalent O(1), three equivalent O(3), three equivalent O(4), and one F(1) atom. Fe(1) is bonded to one O(2), two equivalent O(1), two equivalent O(5), and one F(1) atom to form distorted FeO5F octahedra that share corners with two equivalent Si(1)O4 tetrahedra, edges with two equivalent Fe(1)O5F octahedra, and edges with two equivalent Al(1)O6 octahedra. Al(1) is bonded to one O(2), one O(5), two equivalent O(6), and two equivalent O(7) atoms to form AlO6 octahedra that share  a cornercorner with one Al(1)O6 octahedra, corners with three equivalent Si(1)O4 tetrahedra,  an edgeedge with one Fe(1)O5F octahedra, and edges with two equivalent Al(1)O6 octahedra. The corner-sharing octahedral tilt angles are 48°. B(1) is bonded in a trigonal planar geometry to one O(1) and two equivalent O(7) atoms. Si(1) is bonded to one O(3), one O(4), one O(5), and one O(6) atom to form SiO4 tetrahedra that share  a cornercorner with one Fe(1)O5F octahedra, corners with three equivalent Al(1)O6 octahedra, and corners with two equivalent Si(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 49-61°. H(1) is bonded in a single-bond geometry to one O(2) atom. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Na(1), two equivalent Fe(1), and one B(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Fe(1), two equivalent Al(1), and one H(1) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Na(1) and two equivalent Si(1) atoms. In the fourth O site, O(4) is bonded in a 2-coordinate geometry to one Na(1) and two equivalent Si(1) atoms. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Fe(1), one Al(1), and one Si(1) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to two equivalent Al(1) and one Si(1) atom. In the seventh O site, O(7) is bonded in a distorted trigonal planar geometry to two equivalent Al(1) and one B(1) atom. F(1) is bonded in a 4-coordinate geometry to one Na(1) and three equivalent Fe(1) atoms. is represented by the CIF file [CIF]
data_NaAl6Fe3Si6B3H3O30F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.592
_cell_length_b   9.592
_cell_length_c   9.592
_cell_angle_alpha   113.847
_cell_angle_beta   113.847
_cell_angle_gamma   113.847
_symmetry_Int_Tables_number   1
_cell_volume   542.160
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.219  0.219  0.219  1.0
  Al  Al1  1  0.906  0.573  0.349  1.0
  Al  Al2  1  0.349  0.906  0.573  1.0
  Al  Al3  1  0.573  0.349  0.906  1.0
  Al  Al4  1  0.349  0.573  0.906  1.0
  Al  Al5  1  0.906  0.349  0.573  1.0
  Al  Al6  1  0.573  0.906  0.349  1.0
  Fe  Fe7  1  0.577  0.744  0.577  1.0
  Fe  Fe8  1  0.577  0.577  0.744  1.0
  Fe  Fe9  1  0.744  0.577  0.577  1.0
  Si  Si10  1  0.188  0.994  0.805  1.0
  Si  Si11  1  0.805  0.188  0.994  1.0
  Si  Si12  1  0.994  0.805  0.188  1.0
  Si  Si13  1  0.805  0.994  0.188  1.0
  Si  Si14  1  0.188  0.805  0.994  1.0
  Si  Si15  1  0.994  0.188  0.805  1.0
  B  B16  1  0.560  0.227  0.560  1.0
  B  B17  1  0.560  0.560  0.227  1.0
  B  B18  1  0.227  0.560  0.560  1.0
  H  H19  1  0.245  0.643  0.245  1.0
  H  H20  1  0.245  0.245  0.643  1.0
  H  H21  1  0.643  0.245  0.245  1.0
  O  O22  1  0.528  0.342  0.528  1.0
  O  O23  1  0.528  0.528  0.342  1.0
  O  O24  1  0.342  0.528  0.528  1.0
  O  O25  1  0.376  0.782  0.376  1.0
  O  O26  1  0.376  0.376  0.782  1.0
  O  O27  1  0.782  0.376  0.376  1.0
  O  O28  1  0.160  0.881  0.160  1.0
  O  O29  1  0.160  0.160  0.881  1.0
  O  O30  1  0.881  0.160  0.160  1.0
  O  O31  1  0.993  0.273  0.993  1.0
  O  O32  1  0.993  0.993  0.273  1.0
  O  O33  1  0.273  0.993  0.993  1.0
  O  O34  1  0.969  0.765  0.585  1.0
  O  O35  1  0.585  0.969  0.765  1.0
  O  O36  1  0.765  0.585  0.969  1.0
  O  O37  1  0.585  0.765  0.969  1.0
  O  O38  1  0.969  0.585  0.765  1.0
  O  O39  1  0.765  0.969  0.585  1.0
  O  O40  1  0.364  0.079  0.793  1.0
  O  O41  1  0.793  0.364  0.079  1.0
  O  O42  1  0.079  0.793  0.364  1.0
  O  O43  1  0.793  0.079  0.364  1.0
  O  O44  1  0.364  0.793  0.079  1.0
  O  O45  1  0.079  0.364  0.793  1.0
  O  O46  1  0.652  0.503  0.168  1.0
  O  O47  1  0.168  0.652  0.503  1.0
  O  O48  1  0.503  0.168  0.652  1.0
  O  O49  1  0.168  0.503  0.652  1.0
  O  O50  1  0.652  0.168  0.503  1.0
  O  O51  1  0.503  0.652  0.168  1.0
  F  F52  1  0.849  0.849  0.849  1.0
[/CIF]
.