The structure described by (ZnBr3)2Zn(H2O)6 is Indium-like structured and crystallizes in the orthorhombic Immm space group. The structure is zero-dimensional and consists of two ZnBr3 clusters and two zinkhexahydrat molecules. In each ZnBr3 cluster, Zn(1) is bonded to two equivalent Br(1) and two equivalent Br(2) atoms to form edge-sharing ZnBr4 tetrahedra. There are two inequivalent Br sites. In the first Br site, Br(2) is bonded in a single-bond geometry to one Zn(1) atom. In the second Br site, Br(1) is bonded in an L-shaped geometry to two equivalent Zn(1) atoms. is represented by the CIF file [CIF]
data_ZnH4(BrO)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.449
_cell_length_b   8.449
_cell_length_c   8.449
_cell_angle_alpha   122.156
_cell_angle_beta   105.750
_cell_angle_gamma   101.323
_symmetry_Int_Tables_number   1
_cell_volume   446.337
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.344  0.844  0.500  1.0
  Zn  Zn1  1  0.656  0.156  0.500  1.0
  Zn  Zn2  1  0.000  0.000  0.000  1.0
  H  H3  1  0.090  0.177  0.413  1.0
  H  H4  1  0.236  0.823  0.913  1.0
  H  H5  1  0.764  0.678  0.587  1.0
  H  H6  1  0.910  0.322  0.087  1.0
  H  H7  1  0.910  0.823  0.587  1.0
  H  H8  1  0.764  0.177  0.087  1.0
  H  H9  1  0.236  0.322  0.413  1.0
  H  H10  1  0.090  0.678  0.913  1.0
  H  H11  1  0.830  0.750  0.080  1.0
  H  H12  1  0.330  0.250  0.080  1.0
  H  H13  1  0.670  0.750  0.920  1.0
  H  H14  1  0.170  0.250  0.920  1.0
  Br  Br15  1  0.500  0.225  0.725  1.0
  Br  Br16  1  0.500  0.775  0.275  1.0
  Br  Br17  1  0.017  0.707  0.311  1.0
  Br  Br18  1  0.604  0.293  0.311  1.0
  Br  Br19  1  0.396  0.707  0.689  1.0
  Br  Br20  1  0.983  0.293  0.689  1.0
  O  O21  1  0.153  0.177  0.330  1.0
  O  O22  1  0.153  0.823  0.976  1.0
  O  O23  1  0.847  0.823  0.670  1.0
  O  O24  1  0.847  0.177  0.024  1.0
  O  O25  1  0.802  0.802  0.000  1.0
  O  O26  1  0.198  0.198  0.000  1.0
[/CIF]
.
The structure described by (ZnBr3)2Zn(H2O)6 is Indium-like structured and crystallizes in the orthorhombic Immm space group. The structure is zero-dimensional and consists of two ZnBr3 clusters and two zinkhexahydrat molecules. In each ZnBr3 cluster, Zn(1) is bonded to two equivalent Br(1) and two equivalent Br(2) atoms to form edge-sharing ZnBr4 tetrahedra. There are two inequivalent Br sites. In the first Br site, Br(2) is bonded in a single-bond geometry to one Zn(1) atom. In the second Br site, Br(1) is bonded in an L-shaped geometry to two equivalent Zn(1) atoms. is represented by the CIF file [CIF]
data_ZnH4(BrO)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.449
_cell_length_b   8.449
_cell_length_c   8.449
_cell_angle_alpha   122.156
_cell_angle_beta   105.750
_cell_angle_gamma   101.323
_symmetry_Int_Tables_number   1
_cell_volume   446.337
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.344  0.844  0.500  1.0
  Zn  Zn1  1  0.656  0.156  0.500  1.0
  Zn  Zn2  1  0.000  0.000  0.000  1.0
  H  H3  1  0.090  0.177  0.413  1.0
  H  H4  1  0.236  0.823  0.913  1.0
  H  H5  1  0.764  0.678  0.587  1.0
  H  H6  1  0.910  0.322  0.087  1.0
  H  H7  1  0.910  0.823  0.587  1.0
  H  H8  1  0.764  0.177  0.087  1.0
  H  H9  1  0.236  0.322  0.413  1.0
  H  H10  1  0.090  0.678  0.913  1.0
  H  H11  1  0.830  0.750  0.080  1.0
  H  H12  1  0.330  0.250  0.080  1.0
  H  H13  1  0.670  0.750  0.920  1.0
  H  H14  1  0.170  0.250  0.920  1.0
  Br  Br15  1  0.500  0.225  0.725  1.0
  Br  Br16  1  0.500  0.775  0.275  1.0
  Br  Br17  1  0.017  0.707  0.311  1.0
  Br  Br18  1  0.604  0.293  0.311  1.0
  Br  Br19  1  0.396  0.707  0.689  1.0
  Br  Br20  1  0.983  0.293  0.689  1.0
  O  O21  1  0.153  0.177  0.330  1.0
  O  O22  1  0.153  0.823  0.976  1.0
  O  O23  1  0.847  0.823  0.670  1.0
  O  O24  1  0.847  0.177  0.024  1.0
  O  O25  1  0.802  0.802  0.000  1.0
  O  O26  1  0.198  0.198  0.000  1.0
[/CIF]
.