The material structure described by S is alpha-like structured and crystallizes in the monoclinic P2/c space group. The structure is zero-dimensional and consists of four octathiocane molecules. There are four inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one S(1) and one S(3) atom. In the second S site, S(3) is bonded in a water-like geometry to one S(1) and one S(2) atom. In the third S site, S(2) is bonded in a water-like geometry to one S(3) and one S(4) atom. In the fourth S site, S(4) is bonded in a water-like geometry to one S(2) and one S(4) atom. is represented by the CIF card [CIF]
data_S
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.429
_cell_length_b   8.601
_cell_length_c   13.381
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   112.045
_symmetry_Int_Tables_number   1
_cell_volume   899.204
_cell_formula_units_Z   32
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  S  S0  1  0.325  0.680  0.649  1.0
  S  S1  1  0.175  0.820  0.649  1.0
  S  S2  1  0.675  0.320  0.351  1.0
  S  S3  1  0.825  0.180  0.351  1.0
  S  S4  1  0.469  0.663  0.419  1.0
  S  S5  1  0.031  0.837  0.419  1.0
  S  S6  1  0.531  0.337  0.581  1.0
  S  S7  1  0.969  0.163  0.581  1.0
  S  S8  1  0.527  0.786  0.553  1.0
  S  S9  1  0.973  0.714  0.553  1.0
  S  S10  1  0.473  0.214  0.447  1.0
  S  S11  1  0.027  0.286  0.447  1.0
  S  S12  1  0.381  0.798  0.322  1.0
  S  S13  1  0.119  0.702  0.322  1.0
  S  S14  1  0.619  0.202  0.678  1.0
  S  S15  1  0.881  0.298  0.678  1.0
  S  S16  1  0.201  0.121  0.202  1.0
  S  S17  1  0.299  0.379  0.202  1.0
  S  S18  1  0.799  0.879  0.798  1.0
  S  S19  1  0.701  0.621  0.798  1.0
  S  S20  1  0.221  0.980  0.972  1.0
  S  S21  1  0.279  0.520  0.972  1.0
  S  S22  1  0.779  0.020  0.028  1.0
  S  S23  1  0.721  0.480  0.028  1.0
  S  S24  1  0.344  0.040  0.107  1.0
  S  S25  1  0.156  0.460  0.107  1.0
  S  S26  1  0.656  0.960  0.893  1.0
  S  S27  1  0.844  0.540  0.893  1.0
  S  S28  1  0.325  0.180  0.877  1.0
  S  S29  1  0.175  0.320  0.877  1.0
  S  S30  1  0.675  0.820  0.123  1.0
  S  S31  1  0.825  0.680  0.123  1.0
[/CIF]
.
The material structure described by S is alpha-like structured and crystallizes in the monoclinic P2/c space group. The structure is zero-dimensional and consists of four octathiocane molecules. There are four inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one S(1) and one S(3) atom. In the second S site, S(3) is bonded in a water-like geometry to one S(1) and one S(2) atom. In the third S site, S(2) is bonded in a water-like geometry to one S(3) and one S(4) atom. In the fourth S site, S(4) is bonded in a water-like geometry to one S(2) and one S(4) atom. is represented by the CIF card [CIF]
data_S
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.429
_cell_length_b   8.601
_cell_length_c   13.381
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   112.045
_symmetry_Int_Tables_number   1
_cell_volume   899.204
_cell_formula_units_Z   32
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  S  S0  1  0.325  0.680  0.649  1.0
  S  S1  1  0.175  0.820  0.649  1.0
  S  S2  1  0.675  0.320  0.351  1.0
  S  S3  1  0.825  0.180  0.351  1.0
  S  S4  1  0.469  0.663  0.419  1.0
  S  S5  1  0.031  0.837  0.419  1.0
  S  S6  1  0.531  0.337  0.581  1.0
  S  S7  1  0.969  0.163  0.581  1.0
  S  S8  1  0.527  0.786  0.553  1.0
  S  S9  1  0.973  0.714  0.553  1.0
  S  S10  1  0.473  0.214  0.447  1.0
  S  S11  1  0.027  0.286  0.447  1.0
  S  S12  1  0.381  0.798  0.322  1.0
  S  S13  1  0.119  0.702  0.322  1.0
  S  S14  1  0.619  0.202  0.678  1.0
  S  S15  1  0.881  0.298  0.678  1.0
  S  S16  1  0.201  0.121  0.202  1.0
  S  S17  1  0.299  0.379  0.202  1.0
  S  S18  1  0.799  0.879  0.798  1.0
  S  S19  1  0.701  0.621  0.798  1.0
  S  S20  1  0.221  0.980  0.972  1.0
  S  S21  1  0.279  0.520  0.972  1.0
  S  S22  1  0.779  0.020  0.028  1.0
  S  S23  1  0.721  0.480  0.028  1.0
  S  S24  1  0.344  0.040  0.107  1.0
  S  S25  1  0.156  0.460  0.107  1.0
  S  S26  1  0.656  0.960  0.893  1.0
  S  S27  1  0.844  0.540  0.893  1.0
  S  S28  1  0.325  0.180  0.877  1.0
  S  S29  1  0.175  0.320  0.877  1.0
  S  S30  1  0.675  0.820  0.123  1.0
  S  S31  1  0.825  0.680  0.123  1.0
[/CIF]
.