The compound described by Pb2ScSbO6 crystallizes in the orthorhombic Imm2 space group. Sc(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form ScO6 octahedra that share corners with six equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-5°. Pb(1) is bonded in a 3-coordinate geometry to one O(2) and two equivalent O(1) atoms. Sb(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form SbO6 octahedra that share corners with six equivalent Sc(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-5°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to one Sc(1), two equivalent Pb(1), and one Sb(1) atom. In the second O site, O(2) is bonded in a distorted linear geometry to one Sc(1), one Pb(1), and one Sb(1) atom. In the third O site, O(3) is bonded in a linear geometry to one Sc(1) and one Sb(1) atom. is represented by the CIF card [CIF]
data_ScSb(PbO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.791
_cell_length_b   5.791
_cell_length_c   5.791
_cell_angle_alpha   120.137
_cell_angle_beta   119.815
_cell_angle_gamma   90.042
_symmetry_Int_Tables_number   1
_cell_volume   137.403
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sc  Sc0  1  0.990  0.000  0.990  1.0
  Sb  Sb1  1  0.496  0.500  0.996  1.0
  Pb  Pb2  1  0.232  0.759  0.473  1.0
  Pb  Pb3  1  0.714  0.241  0.473  1.0
  O  O4  1  0.261  0.248  0.510  1.0
  O  O5  1  0.261  0.752  0.013  1.0
  O  O6  1  0.750  0.744  0.006  1.0
  O  O7  1  0.742  0.743  0.485  1.0
  O  O8  1  0.742  0.257  0.999  1.0
  O  O9  1  0.262  0.256  0.006  1.0
[/CIF]
.
The compound described by Pb2ScSbO6 crystallizes in the orthorhombic Imm2 space group. Sc(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form ScO6 octahedra that share corners with six equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-5°. Pb(1) is bonded in a 3-coordinate geometry to one O(2) and two equivalent O(1) atoms. Sb(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form SbO6 octahedra that share corners with six equivalent Sc(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-5°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to one Sc(1), two equivalent Pb(1), and one Sb(1) atom. In the second O site, O(2) is bonded in a distorted linear geometry to one Sc(1), one Pb(1), and one Sb(1) atom. In the third O site, O(3) is bonded in a linear geometry to one Sc(1) and one Sb(1) atom. is represented by the CIF card [CIF]
data_ScSb(PbO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.791
_cell_length_b   5.791
_cell_length_c   5.791
_cell_angle_alpha   120.137
_cell_angle_beta   119.815
_cell_angle_gamma   90.042
_symmetry_Int_Tables_number   1
_cell_volume   137.403
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sc  Sc0  1  0.990  0.000  0.990  1.0
  Sb  Sb1  1  0.496  0.500  0.996  1.0
  Pb  Pb2  1  0.232  0.759  0.473  1.0
  Pb  Pb3  1  0.714  0.241  0.473  1.0
  O  O4  1  0.261  0.248  0.510  1.0
  O  O5  1  0.261  0.752  0.013  1.0
  O  O6  1  0.750  0.744  0.006  1.0
  O  O7  1  0.742  0.743  0.485  1.0
  O  O8  1  0.742  0.257  0.999  1.0
  O  O9  1  0.262  0.256  0.006  1.0
[/CIF]
.