The material described by K2PtS6 crystallizes in the triclinic P-1 space group. K(1) is bonded in a distorted square co-planar geometry to one S(2), one S(3), and two equivalent S(1) atoms. Pt(1) is bonded in a distorted octahedral geometry to two equivalent S(1), two equivalent S(2), and two equivalent S(3) atoms. There are three inequivalent S sites. In the first S site, S(1) is bonded in a distorted trigonal planar geometry to two equivalent K(1) and one Pt(1) atom. In the second S site, S(2) is bonded in a 3-coordinate geometry to one K(1), one Pt(1), and one S(3) atom. In the third S site, S(3) is bonded in a 3-coordinate geometry to one K(1), one Pt(1), and one S(2) atom. is represented by the CIF card [CIF]
data_K2PtS6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.002
_cell_length_b   7.309
_cell_length_c   8.310
_cell_angle_alpha   108.665
_cell_angle_beta   107.056
_cell_angle_gamma   101.645
_symmetry_Int_Tables_number   1
_cell_volume   364.106
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.705  0.295  0.504  1.0
  K  K1  1  0.295  0.705  0.496  1.0
  Pt  Pt2  1  0.000  0.000  1.000  1.0
  S  S3  1  0.728  0.724  0.751  1.0
  S  S4  1  0.272  0.276  0.249  1.0
  S  S5  1  0.013  0.195  0.819  1.0
  S  S6  1  0.987  0.805  0.181  1.0
  S  S7  1  0.208  0.021  0.820  1.0
  S  S8  1  0.792  0.979  0.180  1.0
[/CIF]
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The material described by K2PtS6 crystallizes in the triclinic P-1 space group. K(1) is bonded in a distorted square co-planar geometry to one S(2), one S(3), and two equivalent S(1) atoms. Pt(1) is bonded in a distorted octahedral geometry to two equivalent S(1), two equivalent S(2), and two equivalent S(3) atoms. There are three inequivalent S sites. In the first S site, S(1) is bonded in a distorted trigonal planar geometry to two equivalent K(1) and one Pt(1) atom. In the second S site, S(2) is bonded in a 3-coordinate geometry to one K(1), one Pt(1), and one S(3) atom. In the third S site, S(3) is bonded in a 3-coordinate geometry to one K(1), one Pt(1), and one S(2) atom. is represented by the CIF card [CIF]
data_K2PtS6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.002
_cell_length_b   7.309
_cell_length_c   8.310
_cell_angle_alpha   108.665
_cell_angle_beta   107.056
_cell_angle_gamma   101.645
_symmetry_Int_Tables_number   1
_cell_volume   364.106
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.705  0.295  0.504  1.0
  K  K1  1  0.295  0.705  0.496  1.0
  Pt  Pt2  1  0.000  0.000  1.000  1.0
  S  S3  1  0.728  0.724  0.751  1.0
  S  S4  1  0.272  0.276  0.249  1.0
  S  S5  1  0.013  0.195  0.819  1.0
  S  S6  1  0.987  0.805  0.181  1.0
  S  S7  1  0.208  0.021  0.820  1.0
  S  S8  1  0.792  0.979  0.180  1.0
[/CIF]
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