The material structure described by Cs2Co(SO7)2 crystallizes in the monoclinic P2_1/c space group. Cs(1) is bonded in a 9-coordinate geometry to one O(1), one O(3), one O(4), one O(5), two equivalent O(7), and three equivalent O(2) atoms. Co(1) is bonded in a distorted octahedral geometry to two equivalent O(3), two equivalent O(5), and two equivalent O(6) atoms. S(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(4), and one O(7) atom. There are seven inequivalent O sites. In the first O site, O(7) is bonded in a distorted single-bond geometry to two equivalent Cs(1) and one S(1) atom. In the second O site, O(1) is bonded in a distorted single-bond geometry to one Cs(1) and one S(1) atom. In the third O site, O(2) is bonded in a single-bond geometry to three equivalent Cs(1) and one S(1) atom. In the fourth O site, O(3) is bonded in a single-bond geometry to one Cs(1) and one Co(1) atom. In the fifth O site, O(4) is bonded in a single-bond geometry to one Cs(1) and one S(1) atom. In the sixth O site, O(5) is bonded in a single-bond geometry to one Cs(1) and one Co(1) atom. In the seventh O site, O(6) is bonded in a single-bond geometry to one Co(1) atom. is represented by the CIF card [CIF]
data_Cs2Co(SO7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.101
_cell_length_b   6.607
_cell_length_c   9.369
_cell_angle_alpha   74.770
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   782.501
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.655  0.845  0.860  1.0
  Cs  Cs1  1  0.345  0.155  0.140  1.0
  Cs  Cs2  1  0.155  0.155  0.640  1.0
  Cs  Cs3  1  0.845  0.845  0.360  1.0
  Co  Co4  1  0.500  0.500  0.500  1.0
  Co  Co5  1  0.000  0.500  0.000  1.0
  S  S6  1  0.356  0.758  0.905  1.0
  S  S7  1  0.644  0.242  0.095  1.0
  S  S8  1  0.856  0.242  0.595  1.0
  S  S9  1  0.144  0.758  0.405  1.0
  O  O10  1  0.321  0.563  0.867  1.0
  O  O11  1  0.679  0.437  0.133  1.0
  O  O12  1  0.821  0.437  0.633  1.0
  O  O13  1  0.179  0.563  0.367  1.0
  O  O14  1  0.080  0.711  0.539  1.0
  O  O15  1  0.920  0.289  0.461  1.0
  O  O16  1  0.580  0.289  0.961  1.0
  O  O17  1  0.420  0.711  0.039  1.0
  O  O18  1  0.412  0.341  0.625  1.0
  O  O19  1  0.588  0.659  0.375  1.0
  O  O20  1  0.912  0.659  0.875  1.0
  O  O21  1  0.088  0.341  0.125  1.0
  O  O22  1  0.420  0.857  0.770  1.0
  O  O23  1  0.580  0.143  0.230  1.0
  O  O24  1  0.920  0.143  0.730  1.0
  O  O25  1  0.080  0.857  0.270  1.0
  O  O26  1  0.091  0.433  0.879  1.0
  O  O27  1  0.909  0.567  0.121  1.0
  O  O28  1  0.591  0.567  0.621  1.0
  O  O29  1  0.409  0.433  0.379  1.0
  O  O30  1  0.462  0.758  0.501  1.0
  O  O31  1  0.538  0.242  0.499  1.0
  O  O32  1  0.962  0.242  0.999  1.0
  O  O33  1  0.038  0.758  0.001  1.0
  O  O34  1  0.270  0.896  0.914  1.0
  O  O35  1  0.730  0.104  0.086  1.0
  O  O36  1  0.770  0.104  0.586  1.0
  O  O37  1  0.230  0.896  0.414  1.0
[/CIF]
.
The material structure described by Cs2Co(SO7)2 crystallizes in the monoclinic P2_1/c space group. Cs(1) is bonded in a 9-coordinate geometry to one O(1), one O(3), one O(4), one O(5), two equivalent O(7), and three equivalent O(2) atoms. Co(1) is bonded in a distorted octahedral geometry to two equivalent O(3), two equivalent O(5), and two equivalent O(6) atoms. S(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(4), and one O(7) atom. There are seven inequivalent O sites. In the first O site, O(7) is bonded in a distorted single-bond geometry to two equivalent Cs(1) and one S(1) atom. In the second O site, O(1) is bonded in a distorted single-bond geometry to one Cs(1) and one S(1) atom. In the third O site, O(2) is bonded in a single-bond geometry to three equivalent Cs(1) and one S(1) atom. In the fourth O site, O(3) is bonded in a single-bond geometry to one Cs(1) and one Co(1) atom. In the fifth O site, O(4) is bonded in a single-bond geometry to one Cs(1) and one S(1) atom. In the sixth O site, O(5) is bonded in a single-bond geometry to one Cs(1) and one Co(1) atom. In the seventh O site, O(6) is bonded in a single-bond geometry to one Co(1) atom. is represented by the CIF card [CIF]
data_Cs2Co(SO7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.101
_cell_length_b   6.607
_cell_length_c   9.369
_cell_angle_alpha   74.770
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   782.501
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.655  0.845  0.860  1.0
  Cs  Cs1  1  0.345  0.155  0.140  1.0
  Cs  Cs2  1  0.155  0.155  0.640  1.0
  Cs  Cs3  1  0.845  0.845  0.360  1.0
  Co  Co4  1  0.500  0.500  0.500  1.0
  Co  Co5  1  0.000  0.500  0.000  1.0
  S  S6  1  0.356  0.758  0.905  1.0
  S  S7  1  0.644  0.242  0.095  1.0
  S  S8  1  0.856  0.242  0.595  1.0
  S  S9  1  0.144  0.758  0.405  1.0
  O  O10  1  0.321  0.563  0.867  1.0
  O  O11  1  0.679  0.437  0.133  1.0
  O  O12  1  0.821  0.437  0.633  1.0
  O  O13  1  0.179  0.563  0.367  1.0
  O  O14  1  0.080  0.711  0.539  1.0
  O  O15  1  0.920  0.289  0.461  1.0
  O  O16  1  0.580  0.289  0.961  1.0
  O  O17  1  0.420  0.711  0.039  1.0
  O  O18  1  0.412  0.341  0.625  1.0
  O  O19  1  0.588  0.659  0.375  1.0
  O  O20  1  0.912  0.659  0.875  1.0
  O  O21  1  0.088  0.341  0.125  1.0
  O  O22  1  0.420  0.857  0.770  1.0
  O  O23  1  0.580  0.143  0.230  1.0
  O  O24  1  0.920  0.143  0.730  1.0
  O  O25  1  0.080  0.857  0.270  1.0
  O  O26  1  0.091  0.433  0.879  1.0
  O  O27  1  0.909  0.567  0.121  1.0
  O  O28  1  0.591  0.567  0.621  1.0
  O  O29  1  0.409  0.433  0.379  1.0
  O  O30  1  0.462  0.758  0.501  1.0
  O  O31  1  0.538  0.242  0.499  1.0
  O  O32  1  0.962  0.242  0.999  1.0
  O  O33  1  0.038  0.758  0.001  1.0
  O  O34  1  0.270  0.896  0.914  1.0
  O  O35  1  0.730  0.104  0.086  1.0
  O  O36  1  0.770  0.104  0.586  1.0
  O  O37  1  0.230  0.896  0.414  1.0
[/CIF]
.