The crystal structure described by (ReS2O9)2N2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two ammonia atoms and one ReS2O9 cluster. In the ReS2O9 cluster, Re(1) is bonded to one O(1), one O(2), one O(3), one O(4), and one O(9) atom to form distorted ReO5 trigonal bipyramids that share corners with two equivalent S(1)O4 tetrahedra and corners with two equivalent S(2)O4 tetrahedra. There are two inequivalent S sites. In the first S site, S(1) is bonded to one O(2), one O(3), one O(5), and one O(6) atom to form SO4 tetrahedra that share corners with two equivalent Re(1)O5 trigonal bipyramids. In the second S site, S(2) is bonded to one O(1), one O(4), one O(7), and one O(8) atom to form SO4 tetrahedra that share corners with two equivalent Re(1)O5 trigonal bipyramids. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Re(1) and one S(2) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Re(1) and one S(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Re(1) and one S(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Re(1) and one S(2) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one S(1) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one S(1) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one S(2) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one S(2) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one Re(1) atom. is represented by the CIF file [CIF]
data_ReS2NO9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.919
_cell_length_b   8.020
_cell_length_c   8.011
_cell_angle_alpha   105.037
_cell_angle_beta   104.327
_cell_angle_gamma   105.640
_symmetry_Int_Tables_number   1
_cell_volume   444.794
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.830  0.843  0.553  1.0
  Re  Re1  1  0.170  0.157  0.447  1.0
  S  S2  1  0.782  0.827  0.126  1.0
  S  S3  1  0.218  0.173  0.874  1.0
  S  S4  1  0.810  0.249  0.540  1.0
  S  S5  1  0.190  0.751  0.460  1.0
  N  N6  1  0.780  0.281  0.031  1.0
  N  N7  1  0.220  0.719  0.969  1.0
  O  O8  1  0.980  0.710  0.461  1.0
  O  O9  1  0.020  0.290  0.539  1.0
  O  O10  1  0.948  0.027  0.229  1.0
  O  O11  1  0.052  0.973  0.771  1.0
  O  O12  1  0.714  0.811  0.297  1.0
  O  O13  1  0.286  0.189  0.703  1.0
  O  O14  1  0.786  0.075  0.608  1.0
  O  O15  1  0.214  0.925  0.392  1.0
  O  O16  1  0.855  0.686  0.067  1.0
  O  O17  1  0.145  0.314  0.933  1.0
  O  O18  1  0.638  0.855  0.002  1.0
  O  O19  1  0.362  0.145  0.998  1.0
  O  O20  1  0.818  0.398  0.688  1.0
  O  O21  1  0.182  0.602  0.312  1.0
  O  O22  1  0.681  0.196  0.359  1.0
  O  O23  1  0.319  0.804  0.641  1.0
  O  O24  1  0.675  0.696  0.607  1.0
  O  O25  1  0.325  0.304  0.393  1.0
[/CIF]
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The crystal structure described by (ReS2O9)2N2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two ammonia atoms and one ReS2O9 cluster. In the ReS2O9 cluster, Re(1) is bonded to one O(1), one O(2), one O(3), one O(4), and one O(9) atom to form distorted ReO5 trigonal bipyramids that share corners with two equivalent S(1)O4 tetrahedra and corners with two equivalent S(2)O4 tetrahedra. There are two inequivalent S sites. In the first S site, S(1) is bonded to one O(2), one O(3), one O(5), and one O(6) atom to form SO4 tetrahedra that share corners with two equivalent Re(1)O5 trigonal bipyramids. In the second S site, S(2) is bonded to one O(1), one O(4), one O(7), and one O(8) atom to form SO4 tetrahedra that share corners with two equivalent Re(1)O5 trigonal bipyramids. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Re(1) and one S(2) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Re(1) and one S(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Re(1) and one S(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Re(1) and one S(2) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one S(1) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one S(1) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one S(2) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one S(2) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one Re(1) atom. is represented by the CIF file [CIF]
data_ReS2NO9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.919
_cell_length_b   8.020
_cell_length_c   8.011
_cell_angle_alpha   105.037
_cell_angle_beta   104.327
_cell_angle_gamma   105.640
_symmetry_Int_Tables_number   1
_cell_volume   444.794
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.830  0.843  0.553  1.0
  Re  Re1  1  0.170  0.157  0.447  1.0
  S  S2  1  0.782  0.827  0.126  1.0
  S  S3  1  0.218  0.173  0.874  1.0
  S  S4  1  0.810  0.249  0.540  1.0
  S  S5  1  0.190  0.751  0.460  1.0
  N  N6  1  0.780  0.281  0.031  1.0
  N  N7  1  0.220  0.719  0.969  1.0
  O  O8  1  0.980  0.710  0.461  1.0
  O  O9  1  0.020  0.290  0.539  1.0
  O  O10  1  0.948  0.027  0.229  1.0
  O  O11  1  0.052  0.973  0.771  1.0
  O  O12  1  0.714  0.811  0.297  1.0
  O  O13  1  0.286  0.189  0.703  1.0
  O  O14  1  0.786  0.075  0.608  1.0
  O  O15  1  0.214  0.925  0.392  1.0
  O  O16  1  0.855  0.686  0.067  1.0
  O  O17  1  0.145  0.314  0.933  1.0
  O  O18  1  0.638  0.855  0.002  1.0
  O  O19  1  0.362  0.145  0.998  1.0
  O  O20  1  0.818  0.398  0.688  1.0
  O  O21  1  0.182  0.602  0.312  1.0
  O  O22  1  0.681  0.196  0.359  1.0
  O  O23  1  0.319  0.804  0.641  1.0
  O  O24  1  0.675  0.696  0.607  1.0
  O  O25  1  0.325  0.304  0.393  1.0
[/CIF]
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