The material described by La5V3S6O7 crystallizes in the orthorhombic Pmn2_1 space group. There are five inequivalent La sites. In the first La site, La(1) is bonded in a 4-coordinate geometry to one S(3), two equivalent S(4), two equivalent S(5), one O(1), one O(4), and two equivalent O(2) atoms. In the second La site, La(2) is bonded in a 4-coordinate geometry to one S(1), two equivalent S(2), two equivalent S(6), one O(2), one O(6), and two equivalent O(1) atoms. In the third La site, La(3) is bonded in a 9-coordinate geometry to one S(1), one S(3), two equivalent S(4), one O(7), two equivalent O(3), and two equivalent O(5) atoms. In the fourth La site, La(4) is bonded in a 9-coordinate geometry to one S(3), one S(6), two equivalent S(5), one O(5), two equivalent O(6), and two equivalent O(7) atoms. In the fifth La site, La(5) is bonded in a 4-coordinate geometry to one S(6), two equivalent S(1), two equivalent S(2), one O(2), one O(3), and two equivalent O(4) atoms. There are three inequivalent V sites. In the first V site, V(1) is bonded in a distorted linear geometry to two equivalent S(1), two equivalent S(5), one O(1), and one O(5) atom. In the second V site, V(2) is bonded to two equivalent S(4), two equivalent S(6), one O(4), and one O(7) atom to form distorted edge-sharing VS4O2 octahedra. In the third V site, V(3) is bonded in a 2-coordinate geometry to two equivalent S(2), two equivalent S(3), one O(3), and one O(6) atom. There are six inequivalent S sites. In the first S site, S(1) is bonded in a 6-coordinate geometry to one La(2), one La(3), two equivalent La(5), and two equivalent V(1) atoms. In the second S site, S(2) is bonded in a 6-coordinate geometry to two equivalent La(2), two equivalent La(5), and two equivalent V(3) atoms. In the third S site, S(3) is bonded to one La(1), one La(3), one La(4), and two equivalent V(3) atoms to form distorted SLa3V2 trigonal bipyramids that share  a cornercorner with one O(1)La3V tetrahedra,  a cornercorner with one O(4)La3V tetrahedra, corners with two equivalent O(2)La4 tetrahedra, corners with three equivalent O(5)La3V tetrahedra, corners with three equivalent O(7)La3V tetrahedra, corners with two equivalent S(3)La3V2 trigonal bipyramids, edges with two equivalent O(3)La3V tetrahedra, and edges with two equivalent O(6)La3V tetrahedra. In the fourth S site, S(4) is bonded in a 6-coordinate geometry to two equivalent La(1), two equivalent La(3), and two equivalent V(2) atoms. In the fifth S site, S(5) is bonded in a 6-coordinate geometry to two equivalent La(1), two equivalent La(4), and two equivalent V(1) atoms. In the sixth S site, S(6) is bonded in a 6-coordinate geometry to one La(4), one La(5), two equivalent La(2), and two equivalent V(2) atoms. There are seven inequivalent O sites. In the first O site, O(1) is bonded to one La(1), two equivalent La(2), and one V(1) atom to form distorted OLa3V tetrahedra that share  a cornercorner with one O(4)La3V tetrahedra,  a cornercorner with one O(5)La3V tetrahedra, corners with two equivalent O(1)La3V tetrahedra, corners with two equivalent O(6)La3V tetrahedra,  a cornercorner with one S(3)La3V2 trigonal bipyramid, and edges with two equivalent O(2)La4 tetrahedra. In the second O site, O(2) is bonded to one La(2), one La(5), and two equivalent La(1) atoms to form OLa4 tetrahedra that share  a cornercorner with one O(3)La3V tetrahedra,  a cornercorner with one O(6)La3V tetrahedra, corners with two equivalent O(2)La4 tetrahedra, corners with two equivalent S(3)La3V2 trigonal bipyramids, edges with two equivalent O(1)La3V tetrahedra, and edges with two equivalent O(4)La3V tetrahedra. In the third O site, O(3) is bonded to one La(5), two equivalent La(3), and one V(3) atom to form distorted OLa3V tetrahedra that share  a cornercorner with one O(6)La3V tetrahedra,  a cornercorner with one O(2)La4 tetrahedra, corners with two equivalent O(3)La3V tetrahedra, corners with two equivalent O(4)La3V tetrahedra, corners with two equivalent O(5)La3V tetrahedra, corners with two equivalent O(7)La3V tetrahedra,  an edgeedge with one O(5)La3V tetrahedra, and edges with two equivalent S(3)La3V2 trigonal bipyramids. In the fourth O site, O(4) is bonded to one La(1), two equivalent La(5), and one V(2) atom to form OLa3V tetrahedra that share  a cornercorner with one O(1)La3V tetrahedra,  a cornercorner with one O(7)La3V tetrahedra, corners with two equivalent O(3)La3V tetrahedra, corners with two equivalent O(4)La3V tetrahedra,  a cornercorner with one S(3)La3V2 trigonal bipyramid, and edges with two equivalent O(2)La4 tetrahedra. In the fifth O site, O(5) is bonded to one La(4), two equivalent La(3), and one V(1) atom to form distorted OLa3V tetrahedra that share  a cornercorner with one O(1)La3V tetrahedra, corners with two equivalent O(3)La3V tetrahedra, corners with two equivalent O(5)La3V tetrahedra, corners with two equivalent O(6)La3V tetrahedra, corners with three equivalent S(3)La3V2 trigonal bipyramids,  an edgeedge with one O(3)La3V tetrahedra, and edges with two equivalent O(7)La3V tetrahedra. In the sixth O site, O(6) is bonded to one La(2), two equivalent La(4), and one V(3) atom to form distorted OLa3V tetrahedra that share  a cornercorner with one O(3)La3V tetrahedra,  a cornercorner with one O(2)La4 tetrahedra, corners with two equivalent O(1)La3V tetrahedra, corners with two equivalent O(5)La3V tetrahedra, corners with two equivalent O(6)La3V tetrahedra, corners with two equivalent O(7)La3V tetrahedra,  an edgeedge with one O(7)La3V tetrahedra, and edges with two equivalent S(3)La3V2 trigonal bipyramids. In the seventh O site, O(7) is bonded to one La(3), two equivalent La(4), and one V(2) atom to form OLa3V tetrahedra that share  a cornercorner with one O(4)La3V tetrahedra, corners with two equivalent O(3)La3V tetrahedra, corners with two equivalent O(6)La3V tetrahedra, corners with two equivalent O(7)La3V tetrahedra, corners with three equivalent S(3)La3V2 trigonal bipyramids,  an edgeedge with one O(6)La3V tetrahedra, and edges with two equivalent O(5)La3V tetrahedra. is represented by the CIF file [CIF]
data_La5V3S6O7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.826
_cell_length_b   10.333
_cell_length_c   18.111
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   716.041
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.000  0.730  0.752  1.0
  La  La1  1  0.000  0.531  0.135  1.0
  La  La2  1  0.000  0.084  0.913  1.0
  La  La3  1  0.500  0.911  0.085  1.0
  La  La4  1  0.500  0.474  0.864  1.0
  La  La5  1  0.000  0.526  0.364  1.0
  La  La6  1  0.500  0.916  0.413  1.0
  La  La7  1  0.500  0.469  0.635  1.0
  La  La8  1  0.000  0.089  0.585  1.0
  La  La9  1  0.500  0.270  0.252  1.0
  V  V10  1  0.500  0.253  0.057  1.0
  V  V11  1  0.500  0.251  0.443  1.0
  V  V12  1  0.000  0.747  0.557  1.0
  V  V13  1  0.500  0.188  0.750  1.0
  V  V14  1  0.000  0.812  0.250  1.0
  V  V15  1  0.000  0.749  0.943  1.0
  S  S16  1  0.000  0.350  0.988  1.0
  S  S17  1  0.500  0.642  0.250  1.0
  S  S18  1  0.000  0.039  0.749  1.0
  S  S19  1  0.500  0.854  0.869  1.0
  S  S20  1  0.000  0.146  0.369  1.0
  S  S21  1  0.500  0.852  0.631  1.0
  S  S22  1  0.500  0.646  0.016  1.0
  S  S23  1  0.500  0.650  0.488  1.0
  S  S24  1  0.000  0.358  0.750  1.0
  S  S25  1  0.500  0.961  0.249  1.0
  S  S26  1  0.000  0.354  0.516  1.0
  S  S27  1  0.000  0.148  0.131  1.0
  O  O28  1  0.500  0.387  0.126  1.0
  O  O29  1  0.000  0.403  0.248  1.0
  O  O30  1  0.000  0.613  0.626  1.0
  O  O31  1  0.500  0.208  0.851  1.0
  O  O32  1  0.500  0.396  0.370  1.0
  O  O33  1  0.500  0.109  0.999  1.0
  O  O34  1  0.500  0.597  0.748  1.0
  O  O35  1  0.000  0.792  0.351  1.0
  O  O36  1  0.000  0.788  0.149  1.0
  O  O37  1  0.500  0.096  0.505  1.0
  O  O38  1  0.000  0.904  0.005  1.0
  O  O39  1  0.500  0.212  0.649  1.0
  O  O40  1  0.000  0.604  0.870  1.0
  O  O41  1  0.000  0.891  0.499  1.0
[/CIF]
.
The material described by La5V3S6O7 crystallizes in the orthorhombic Pmn2_1 space group. There are five inequivalent La sites. In the first La site, La(1) is bonded in a 4-coordinate geometry to one S(3), two equivalent S(4), two equivalent S(5), one O(1), one O(4), and two equivalent O(2) atoms. In the second La site, La(2) is bonded in a 4-coordinate geometry to one S(1), two equivalent S(2), two equivalent S(6), one O(2), one O(6), and two equivalent O(1) atoms. In the third La site, La(3) is bonded in a 9-coordinate geometry to one S(1), one S(3), two equivalent S(4), one O(7), two equivalent O(3), and two equivalent O(5) atoms. In the fourth La site, La(4) is bonded in a 9-coordinate geometry to one S(3), one S(6), two equivalent S(5), one O(5), two equivalent O(6), and two equivalent O(7) atoms. In the fifth La site, La(5) is bonded in a 4-coordinate geometry to one S(6), two equivalent S(1), two equivalent S(2), one O(2), one O(3), and two equivalent O(4) atoms. There are three inequivalent V sites. In the first V site, V(1) is bonded in a distorted linear geometry to two equivalent S(1), two equivalent S(5), one O(1), and one O(5) atom. In the second V site, V(2) is bonded to two equivalent S(4), two equivalent S(6), one O(4), and one O(7) atom to form distorted edge-sharing VS4O2 octahedra. In the third V site, V(3) is bonded in a 2-coordinate geometry to two equivalent S(2), two equivalent S(3), one O(3), and one O(6) atom. There are six inequivalent S sites. In the first S site, S(1) is bonded in a 6-coordinate geometry to one La(2), one La(3), two equivalent La(5), and two equivalent V(1) atoms. In the second S site, S(2) is bonded in a 6-coordinate geometry to two equivalent La(2), two equivalent La(5), and two equivalent V(3) atoms. In the third S site, S(3) is bonded to one La(1), one La(3), one La(4), and two equivalent V(3) atoms to form distorted SLa3V2 trigonal bipyramids that share  a cornercorner with one O(1)La3V tetrahedra,  a cornercorner with one O(4)La3V tetrahedra, corners with two equivalent O(2)La4 tetrahedra, corners with three equivalent O(5)La3V tetrahedra, corners with three equivalent O(7)La3V tetrahedra, corners with two equivalent S(3)La3V2 trigonal bipyramids, edges with two equivalent O(3)La3V tetrahedra, and edges with two equivalent O(6)La3V tetrahedra. In the fourth S site, S(4) is bonded in a 6-coordinate geometry to two equivalent La(1), two equivalent La(3), and two equivalent V(2) atoms. In the fifth S site, S(5) is bonded in a 6-coordinate geometry to two equivalent La(1), two equivalent La(4), and two equivalent V(1) atoms. In the sixth S site, S(6) is bonded in a 6-coordinate geometry to one La(4), one La(5), two equivalent La(2), and two equivalent V(2) atoms. There are seven inequivalent O sites. In the first O site, O(1) is bonded to one La(1), two equivalent La(2), and one V(1) atom to form distorted OLa3V tetrahedra that share  a cornercorner with one O(4)La3V tetrahedra,  a cornercorner with one O(5)La3V tetrahedra, corners with two equivalent O(1)La3V tetrahedra, corners with two equivalent O(6)La3V tetrahedra,  a cornercorner with one S(3)La3V2 trigonal bipyramid, and edges with two equivalent O(2)La4 tetrahedra. In the second O site, O(2) is bonded to one La(2), one La(5), and two equivalent La(1) atoms to form OLa4 tetrahedra that share  a cornercorner with one O(3)La3V tetrahedra,  a cornercorner with one O(6)La3V tetrahedra, corners with two equivalent O(2)La4 tetrahedra, corners with two equivalent S(3)La3V2 trigonal bipyramids, edges with two equivalent O(1)La3V tetrahedra, and edges with two equivalent O(4)La3V tetrahedra. In the third O site, O(3) is bonded to one La(5), two equivalent La(3), and one V(3) atom to form distorted OLa3V tetrahedra that share  a cornercorner with one O(6)La3V tetrahedra,  a cornercorner with one O(2)La4 tetrahedra, corners with two equivalent O(3)La3V tetrahedra, corners with two equivalent O(4)La3V tetrahedra, corners with two equivalent O(5)La3V tetrahedra, corners with two equivalent O(7)La3V tetrahedra,  an edgeedge with one O(5)La3V tetrahedra, and edges with two equivalent S(3)La3V2 trigonal bipyramids. In the fourth O site, O(4) is bonded to one La(1), two equivalent La(5), and one V(2) atom to form OLa3V tetrahedra that share  a cornercorner with one O(1)La3V tetrahedra,  a cornercorner with one O(7)La3V tetrahedra, corners with two equivalent O(3)La3V tetrahedra, corners with two equivalent O(4)La3V tetrahedra,  a cornercorner with one S(3)La3V2 trigonal bipyramid, and edges with two equivalent O(2)La4 tetrahedra. In the fifth O site, O(5) is bonded to one La(4), two equivalent La(3), and one V(1) atom to form distorted OLa3V tetrahedra that share  a cornercorner with one O(1)La3V tetrahedra, corners with two equivalent O(3)La3V tetrahedra, corners with two equivalent O(5)La3V tetrahedra, corners with two equivalent O(6)La3V tetrahedra, corners with three equivalent S(3)La3V2 trigonal bipyramids,  an edgeedge with one O(3)La3V tetrahedra, and edges with two equivalent O(7)La3V tetrahedra. In the sixth O site, O(6) is bonded to one La(2), two equivalent La(4), and one V(3) atom to form distorted OLa3V tetrahedra that share  a cornercorner with one O(3)La3V tetrahedra,  a cornercorner with one O(2)La4 tetrahedra, corners with two equivalent O(1)La3V tetrahedra, corners with two equivalent O(5)La3V tetrahedra, corners with two equivalent O(6)La3V tetrahedra, corners with two equivalent O(7)La3V tetrahedra,  an edgeedge with one O(7)La3V tetrahedra, and edges with two equivalent S(3)La3V2 trigonal bipyramids. In the seventh O site, O(7) is bonded to one La(3), two equivalent La(4), and one V(2) atom to form OLa3V tetrahedra that share  a cornercorner with one O(4)La3V tetrahedra, corners with two equivalent O(3)La3V tetrahedra, corners with two equivalent O(6)La3V tetrahedra, corners with two equivalent O(7)La3V tetrahedra, corners with three equivalent S(3)La3V2 trigonal bipyramids,  an edgeedge with one O(6)La3V tetrahedra, and edges with two equivalent O(5)La3V tetrahedra. is represented by the CIF file [CIF]
data_La5V3S6O7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.826
_cell_length_b   10.333
_cell_length_c   18.111
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   716.041
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.000  0.730  0.752  1.0
  La  La1  1  0.000  0.531  0.135  1.0
  La  La2  1  0.000  0.084  0.913  1.0
  La  La3  1  0.500  0.911  0.085  1.0
  La  La4  1  0.500  0.474  0.864  1.0
  La  La5  1  0.000  0.526  0.364  1.0
  La  La6  1  0.500  0.916  0.413  1.0
  La  La7  1  0.500  0.469  0.635  1.0
  La  La8  1  0.000  0.089  0.585  1.0
  La  La9  1  0.500  0.270  0.252  1.0
  V  V10  1  0.500  0.253  0.057  1.0
  V  V11  1  0.500  0.251  0.443  1.0
  V  V12  1  0.000  0.747  0.557  1.0
  V  V13  1  0.500  0.188  0.750  1.0
  V  V14  1  0.000  0.812  0.250  1.0
  V  V15  1  0.000  0.749  0.943  1.0
  S  S16  1  0.000  0.350  0.988  1.0
  S  S17  1  0.500  0.642  0.250  1.0
  S  S18  1  0.000  0.039  0.749  1.0
  S  S19  1  0.500  0.854  0.869  1.0
  S  S20  1  0.000  0.146  0.369  1.0
  S  S21  1  0.500  0.852  0.631  1.0
  S  S22  1  0.500  0.646  0.016  1.0
  S  S23  1  0.500  0.650  0.488  1.0
  S  S24  1  0.000  0.358  0.750  1.0
  S  S25  1  0.500  0.961  0.249  1.0
  S  S26  1  0.000  0.354  0.516  1.0
  S  S27  1  0.000  0.148  0.131  1.0
  O  O28  1  0.500  0.387  0.126  1.0
  O  O29  1  0.000  0.403  0.248  1.0
  O  O30  1  0.000  0.613  0.626  1.0
  O  O31  1  0.500  0.208  0.851  1.0
  O  O32  1  0.500  0.396  0.370  1.0
  O  O33  1  0.500  0.109  0.999  1.0
  O  O34  1  0.500  0.597  0.748  1.0
  O  O35  1  0.000  0.792  0.351  1.0
  O  O36  1  0.000  0.788  0.149  1.0
  O  O37  1  0.500  0.096  0.505  1.0
  O  O38  1  0.000  0.904  0.005  1.0
  O  O39  1  0.500  0.212  0.649  1.0
  O  O40  1  0.000  0.604  0.870  1.0
  O  O41  1  0.000  0.891  0.499  1.0
[/CIF]
.