The crystal structure described by Zr(CoN)4 crystallizes in the triclinic P-1 space group. Zr(1) is bonded to one N(1), one N(3), one N(4), and two equivalent N(2) atoms to form distorted ZrN5 square pyramids that share  a cornercorner with one Co(4)N5 square pyramid, corners with three equivalent Co(3)N5 square pyramids,  an edgeedge with one Zr(1)N5 square pyramid,  an edgeedge with one Co(3)N5 square pyramid, and edges with two equivalent Co(4)N5 square pyramids. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded in a rectangular see-saw-like geometry to one N(1), one N(2), one N(3), and one N(4) atom. In the second Co site, Co(2) is bonded in a distorted T-shaped geometry to one N(3) and two equivalent N(2) atoms. In the third Co site, Co(3) is bonded to one N(3), two equivalent N(1), and two equivalent N(4) atoms to form CoN5 square pyramids that share corners with three equivalent Zr(1)N5 square pyramids, corners with three equivalent Co(4)N5 square pyramids,  an edgeedge with one Zr(1)N5 square pyramid, edges with two equivalent Co(3)N5 square pyramids, and edges with three equivalent Co(4)N5 square pyramids. In the fourth Co site, Co(4) is bonded to one N(3), two equivalent N(1), and two equivalent N(4) atoms to form CoN5 square pyramids that share  a cornercorner with one Zr(1)N5 square pyramid, corners with three equivalent Co(3)N5 square pyramids, edges with two equivalent Zr(1)N5 square pyramids, edges with two equivalent Co(4)N5 square pyramids, and edges with three equivalent Co(3)N5 square pyramids. There are four inequivalent N sites. In the first N site, N(1) is bonded to one Zr(1), one Co(1), two equivalent Co(3), and two equivalent Co(4) atoms to form NZrCo5 octahedra that share corners with two equivalent N(4)ZrCo5 octahedra, corners with two equivalent N(3)ZrCo4 square pyramids, corners with three equivalent N(2)Zr2Co3 trigonal bipyramids, edges with two equivalent N(1)ZrCo5 octahedra, edges with four equivalent N(4)ZrCo5 octahedra, and edges with two equivalent N(3)ZrCo4 square pyramids. The corner-sharing octahedral tilt angles range from 5-7°. In the second N site, N(2) is bonded to two equivalent Zr(1), one Co(1), and two equivalent Co(2) atoms to form distorted NZr2Co3 trigonal bipyramids that share  a cornercorner with one N(4)ZrCo5 octahedra, corners with three equivalent N(1)ZrCo5 octahedra, corners with three equivalent N(3)ZrCo4 square pyramids,  an edgeedge with one N(4)ZrCo5 octahedra,  an edgeedge with one N(3)ZrCo4 square pyramid, and edges with two equivalent N(2)Zr2Co3 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 17-58°. In the third N site, N(3) is bonded to one Zr(1), one Co(1), one Co(2), one Co(3), and one Co(4) atom to form NZrCo4 square pyramids that share corners with two equivalent N(1)ZrCo5 octahedra, corners with three equivalent N(2)Zr2Co3 trigonal bipyramids, edges with two equivalent N(1)ZrCo5 octahedra, edges with three equivalent N(4)ZrCo5 octahedra, and  an edgeedge with one N(2)Zr2Co3 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 6-7°. In the fourth N site, N(4) is bonded to one Zr(1), one Co(1), two equivalent Co(3), and two equivalent Co(4) atoms to form NZrCo5 octahedra that share corners with two equivalent N(1)ZrCo5 octahedra,  a cornercorner with one N(2)Zr2Co3 trigonal bipyramid, edges with two equivalent N(4)ZrCo5 octahedra, edges with four equivalent N(1)ZrCo5 octahedra, edges with three equivalent N(3)ZrCo4 square pyramids, and  an edgeedge with one N(2)Zr2Co3 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 5-7°. is represented by the CIF file [CIF]
data_Zr(CoN)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.185
_cell_length_b   4.846
_cell_length_c   8.160
_cell_angle_alpha   73.260
_cell_angle_beta   74.616
_cell_angle_gamma   71.301
_symmetry_Int_Tables_number   1
_cell_volume   182.585
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr0  1  0.655  0.885  0.797  1.0
  Zr  Zr1  1  0.345  0.115  0.203  1.0
  Co  Co2  1  0.823  0.605  0.238  1.0
  Co  Co3  1  0.177  0.395  0.762  1.0
  Co  Co4  1  0.871  0.211  0.064  1.0
  Co  Co5  1  0.129  0.789  0.936  1.0
  Co  Co6  1  0.736  0.464  0.589  1.0
  Co  Co7  1  0.264  0.536  0.411  1.0
  Co  Co8  1  0.236  0.962  0.596  1.0
  Co  Co9  1  0.764  0.038  0.404  1.0
  N  N10  1  0.974  0.714  0.582  1.0
  N  N11  1  0.026  0.286  0.418  1.0
  N  N12  1  0.762  0.896  0.038  1.0
  N  N13  1  0.238  0.104  0.962  1.0
  N  N14  1  0.402  0.630  0.768  1.0
  N  N15  1  0.598  0.370  0.232  1.0
  N  N16  1  0.540  0.778  0.416  1.0
  N  N17  1  0.460  0.222  0.584  1.0
[/CIF]
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The crystal structure described by Zr(CoN)4 crystallizes in the triclinic P-1 space group. Zr(1) is bonded to one N(1), one N(3), one N(4), and two equivalent N(2) atoms to form distorted ZrN5 square pyramids that share  a cornercorner with one Co(4)N5 square pyramid, corners with three equivalent Co(3)N5 square pyramids,  an edgeedge with one Zr(1)N5 square pyramid,  an edgeedge with one Co(3)N5 square pyramid, and edges with two equivalent Co(4)N5 square pyramids. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded in a rectangular see-saw-like geometry to one N(1), one N(2), one N(3), and one N(4) atom. In the second Co site, Co(2) is bonded in a distorted T-shaped geometry to one N(3) and two equivalent N(2) atoms. In the third Co site, Co(3) is bonded to one N(3), two equivalent N(1), and two equivalent N(4) atoms to form CoN5 square pyramids that share corners with three equivalent Zr(1)N5 square pyramids, corners with three equivalent Co(4)N5 square pyramids,  an edgeedge with one Zr(1)N5 square pyramid, edges with two equivalent Co(3)N5 square pyramids, and edges with three equivalent Co(4)N5 square pyramids. In the fourth Co site, Co(4) is bonded to one N(3), two equivalent N(1), and two equivalent N(4) atoms to form CoN5 square pyramids that share  a cornercorner with one Zr(1)N5 square pyramid, corners with three equivalent Co(3)N5 square pyramids, edges with two equivalent Zr(1)N5 square pyramids, edges with two equivalent Co(4)N5 square pyramids, and edges with three equivalent Co(3)N5 square pyramids. There are four inequivalent N sites. In the first N site, N(1) is bonded to one Zr(1), one Co(1), two equivalent Co(3), and two equivalent Co(4) atoms to form NZrCo5 octahedra that share corners with two equivalent N(4)ZrCo5 octahedra, corners with two equivalent N(3)ZrCo4 square pyramids, corners with three equivalent N(2)Zr2Co3 trigonal bipyramids, edges with two equivalent N(1)ZrCo5 octahedra, edges with four equivalent N(4)ZrCo5 octahedra, and edges with two equivalent N(3)ZrCo4 square pyramids. The corner-sharing octahedral tilt angles range from 5-7°. In the second N site, N(2) is bonded to two equivalent Zr(1), one Co(1), and two equivalent Co(2) atoms to form distorted NZr2Co3 trigonal bipyramids that share  a cornercorner with one N(4)ZrCo5 octahedra, corners with three equivalent N(1)ZrCo5 octahedra, corners with three equivalent N(3)ZrCo4 square pyramids,  an edgeedge with one N(4)ZrCo5 octahedra,  an edgeedge with one N(3)ZrCo4 square pyramid, and edges with two equivalent N(2)Zr2Co3 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 17-58°. In the third N site, N(3) is bonded to one Zr(1), one Co(1), one Co(2), one Co(3), and one Co(4) atom to form NZrCo4 square pyramids that share corners with two equivalent N(1)ZrCo5 octahedra, corners with three equivalent N(2)Zr2Co3 trigonal bipyramids, edges with two equivalent N(1)ZrCo5 octahedra, edges with three equivalent N(4)ZrCo5 octahedra, and  an edgeedge with one N(2)Zr2Co3 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 6-7°. In the fourth N site, N(4) is bonded to one Zr(1), one Co(1), two equivalent Co(3), and two equivalent Co(4) atoms to form NZrCo5 octahedra that share corners with two equivalent N(1)ZrCo5 octahedra,  a cornercorner with one N(2)Zr2Co3 trigonal bipyramid, edges with two equivalent N(4)ZrCo5 octahedra, edges with four equivalent N(1)ZrCo5 octahedra, edges with three equivalent N(3)ZrCo4 square pyramids, and  an edgeedge with one N(2)Zr2Co3 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 5-7°. is represented by the CIF file [CIF]
data_Zr(CoN)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.185
_cell_length_b   4.846
_cell_length_c   8.160
_cell_angle_alpha   73.260
_cell_angle_beta   74.616
_cell_angle_gamma   71.301
_symmetry_Int_Tables_number   1
_cell_volume   182.585
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr0  1  0.655  0.885  0.797  1.0
  Zr  Zr1  1  0.345  0.115  0.203  1.0
  Co  Co2  1  0.823  0.605  0.238  1.0
  Co  Co3  1  0.177  0.395  0.762  1.0
  Co  Co4  1  0.871  0.211  0.064  1.0
  Co  Co5  1  0.129  0.789  0.936  1.0
  Co  Co6  1  0.736  0.464  0.589  1.0
  Co  Co7  1  0.264  0.536  0.411  1.0
  Co  Co8  1  0.236  0.962  0.596  1.0
  Co  Co9  1  0.764  0.038  0.404  1.0
  N  N10  1  0.974  0.714  0.582  1.0
  N  N11  1  0.026  0.286  0.418  1.0
  N  N12  1  0.762  0.896  0.038  1.0
  N  N13  1  0.238  0.104  0.962  1.0
  N  N14  1  0.402  0.630  0.768  1.0
  N  N15  1  0.598  0.370  0.232  1.0
  N  N16  1  0.540  0.778  0.416  1.0
  N  N17  1  0.460  0.222  0.584  1.0
[/CIF]
.