The structure described by In11(SbO8)3 crystallizes in the triclinic P1 space group. There are eleven inequivalent In sites. In the first In site, In(1) is bonded in a 7-coordinate geometry to one O(18), one O(2), one O(20), one O(22), one O(4), one O(7), and one O(9) atom. In the second In site, In(2) is bonded in a 6-coordinate geometry to one O(2), one O(22), one O(24), one O(3), one O(5), and one O(6) atom. In the third In site, In(3) is bonded in a 7-coordinate geometry to one O(1), one O(14), one O(17), one O(3), one O(4), one O(7), and one O(8) atom. In the fourth In site, In(4) is bonded in a 6-coordinate geometry to one O(1), one O(10), one O(20), one O(5), one O(6), and one O(9) atom. In the fifth In site, In(5) is bonded to one O(10), one O(13), one O(16), one O(19), one O(21), one O(6), and one O(8) atom to form distorted InO7 pentagonal bipyramids that share  a cornercorner with one In(10)O6 octahedra,  a cornercorner with one Sb(2)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra, and  an edgeedge with one Sb(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-64°. In the sixth In site, In(6) is bonded in a 6-coordinate geometry to one O(10), one O(11), one O(12), one O(15), one O(7), and one O(8) atom. In the seventh In site, In(7) is bonded in a 7-coordinate geometry to one O(12), one O(15), one O(17), one O(19), one O(4), one O(6), and one O(9) atom. In the eighth In site, In(8) is bonded in a 7-coordinate geometry to one O(11), one O(15), one O(16), one O(19), one O(20), one O(24), and one O(5) atom. In the ninth In site, In(9) is bonded in a 7-coordinate geometry to one O(11), one O(17), one O(18), one O(21), one O(22), one O(24), and one O(8) atom. In the tenth In site, In(10) is bonded to one O(1), one O(19), one O(20), one O(22), one O(23), and one O(3) atom to form distorted InO6 octahedra that share  a cornercorner with one Sb(1)O6 octahedra,  a cornercorner with one Sb(2)O6 octahedra, and  a cornercorner with one In(5)O7 pentagonal bipyramid. The corner-sharing octahedral tilt angles range from 43-63°. In the eleventh In site, In(11) is bonded in a 7-coordinate geometry to one O(16), one O(18), one O(21), one O(23), one O(3), one O(5), and one O(7) atom. There are three inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(1), one O(12), one O(13), one O(21), one O(24), and one O(4) atom to form SbO6 octahedra that share  a cornercorner with one In(10)O6 octahedra,  a cornercorner with one Sb(3)O6 octahedra, and  an edgeedge with one In(5)O7 pentagonal bipyramid. The corner-sharing octahedral tilt angles range from 41-63°. In the second Sb site, Sb(2) is bonded to one O(11), one O(14), one O(16), one O(2), one O(23), and one O(9) atom to form SbO6 octahedra that share  a cornercorner with one In(10)O6 octahedra,  a cornercorner with one Sb(3)O6 octahedra, and  a cornercorner with one In(5)O7 pentagonal bipyramid. The corner-sharing octahedral tilt angles range from 43-58°. In the third Sb site, Sb(3) is bonded to one O(10), one O(13), one O(14), one O(15), one O(17), and one O(18) atom to form distorted SbO6 octahedra that share  a cornercorner with one Sb(1)O6 octahedra,  a cornercorner with one Sb(2)O6 octahedra, and  an edgeedge with one In(5)O7 pentagonal bipyramid. The corner-sharing octahedral tilt angles range from 41-58°. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one In(10), one In(3), one In(4), and one Sb(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one In(1), one In(2), and one Sb(2) atom. In the third O site, O(3) is bonded to one In(10), one In(11), one In(2), and one In(3) atom to form distorted OIn4 tetrahedra that share  a cornercorner with one O(17)In3Sb tetrahedra,  a cornercorner with one O(18)In3Sb tetrahedra,  a cornercorner with one O(19)In4 tetrahedra,  a cornercorner with one O(20)In4 tetrahedra,  a cornercorner with one O(6)In4 tetrahedra,  a cornercorner with one O(8)In4 tetrahedra,  an edgeedge with one O(22)In4 tetrahedra,  an edgeedge with one O(5)In4 tetrahedra, and  an edgeedge with one O(7)In4 tetrahedra. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one In(1), one In(3), one In(7), and one Sb(1) atom. In the fifth O site, O(5) is bonded to one In(11), one In(2), one In(4), and one In(8) atom to form OIn4 tetrahedra that share  a cornercorner with one O(10)In3Sb tetrahedra,  a cornercorner with one O(15)In3Sb tetrahedra,  a cornercorner with one O(18)In3Sb tetrahedra,  a cornercorner with one O(19)In4 tetrahedra,  a cornercorner with one O(22)In4 tetrahedra,  a cornercorner with one O(7)In4 tetrahedra,  an edgeedge with one O(20)In4 tetrahedra,  an edgeedge with one O(3)In4 tetrahedra, and  an edgeedge with one O(6)In4 tetrahedra. In the sixth O site, O(6) is bonded to one In(2), one In(4), one In(5), and one In(7) atom to form OIn4 tetrahedra that share  a cornercorner with one O(15)In3Sb tetrahedra,  a cornercorner with one O(17)In3Sb tetrahedra,  a cornercorner with one O(20)In4 tetrahedra,  a cornercorner with one O(22)In4 tetrahedra,  a cornercorner with one O(3)In4 tetrahedra,  a cornercorner with one O(8)In4 tetrahedra,  an edgeedge with one O(10)In3Sb tetrahedra,  an edgeedge with one O(19)In4 tetrahedra, and  an edgeedge with one O(5)In4 tetrahedra. In the seventh O site, O(7) is bonded to one In(1), one In(11), one In(3), and one In(6) atom to form OIn4 tetrahedra that share  a cornercorner with one O(10)In3Sb tetrahedra,  a cornercorner with one O(15)In3Sb tetrahedra,  a cornercorner with one O(17)In3Sb tetrahedra,  a cornercorner with one O(20)In4 tetrahedra,  a cornercorner with one O(22)In4 tetrahedra,  a cornercorner with one O(5)In4 tetrahedra,  an edgeedge with one O(18)In3Sb tetrahedra,  an edgeedge with one O(3)In4 tetrahedra, and  an edgeedge with one O(8)In4 tetrahedra. In the eighth O site, O(8) is bonded to one In(3), one In(5), one In(6), and one In(9) atom to form OIn4 tetrahedra that share  a cornercorner with one O(15)In3Sb tetrahedra,  a cornercorner with one O(18)In3Sb tetrahedra,  a cornercorner with one O(19)In4 tetrahedra,  a cornercorner with one O(22)In4 tetrahedra,  a cornercorner with one O(3)In4 tetrahedra,  a cornercorner with one O(6)In4 tetrahedra,  an edgeedge with one O(10)In3Sb tetrahedra,  an edgeedge with one O(17)In3Sb tetrahedra, and  an edgeedge with one O(7)In4 tetrahedra. In the ninth O site, O(9) is bonded in a 4-coordinate geometry to one In(1), one In(4), one In(7), and one Sb(2) atom. In the tenth O site, O(10) is bonded to one In(4), one In(5), one In(6), and one Sb(3) atom to form distorted OIn3Sb tetrahedra that share  a cornercorner with one O(17)In3Sb tetrahedra,  a cornercorner with one O(18)In3Sb tetrahedra,  a cornercorner with one O(19)In4 tetrahedra,  a cornercorner with one O(20)In4 tetrahedra,  a cornercorner with one O(5)In4 tetrahedra,  a cornercorner with one O(7)In4 tetrahedra,  an edgeedge with one O(15)In3Sb tetrahedra,  an edgeedge with one O(6)In4 tetrahedra, and  an edgeedge with one O(8)In4 tetrahedra. In the eleventh O site, O(11) is bonded in a 4-coordinate geometry to one In(6), one In(8), one In(9), and one Sb(2) atom. In the twelfth O site, O(12) is bonded in a 3-coordinate geometry to one In(6), one In(7), and one Sb(1) atom. In the thirteenth O site, O(13) is bonded in a distorted trigonal non-coplanar geometry to one In(5), one Sb(1), and one Sb(3) atom. In the fourteenth O site, O(14) is bonded in a distorted trigonal planar geometry to one In(3), one Sb(2), and one Sb(3) atom. In the fifteenth O site, O(15) is bonded to one In(6), one In(7), one In(8), and one Sb(3) atom to form distorted OIn3Sb tetrahedra that share  a cornercorner with one O(18)In3Sb tetrahedra,  a cornercorner with one O(20)In4 tetrahedra,  a cornercorner with one O(5)In4 tetrahedra,  a cornercorner with one O(6)In4 tetrahedra,  a cornercorner with one O(7)In4 tetrahedra,  a cornercorner with one O(8)In4 tetrahedra,  an edgeedge with one O(10)In3Sb tetrahedra,  an edgeedge with one O(17)In3Sb tetrahedra, and  an edgeedge with one O(19)In4 tetrahedra. In the sixteenth O site, O(16) is bonded in a 4-coordinate geometry to one In(11), one In(5), one In(8), and one Sb(2) atom. In the seventeenth O site, O(17) is bonded to one In(3), one In(7), one In(9), and one Sb(3) atom to form OIn3Sb tetrahedra that share  a cornercorner with one O(10)In3Sb tetrahedra,  a cornercorner with one O(19)In4 tetrahedra,  a cornercorner with one O(22)In4 tetrahedra,  a cornercorner with one O(3)In4 tetrahedra,  a cornercorner with one O(6)In4 tetrahedra,  a cornercorner with one O(7)In4 tetrahedra,  an edgeedge with one O(15)In3Sb tetrahedra,  an edgeedge with one O(18)In3Sb tetrahedra, and  an edgeedge with one O(8)In4 tetrahedra. In the eighteenth O site, O(18) is bonded to one In(1), one In(11), one In(9), and one Sb(3) atom to form distorted OIn3Sb tetrahedra that share  a cornercorner with one O(10)In3Sb tetrahedra,  a cornercorner with one O(15)In3Sb tetrahedra,  a cornercorner with one O(20)In4 tetrahedra,  a cornercorner with one O(3)In4 tetrahedra,  a cornercorner with one O(5)In4 tetrahedra,  a cornercorner with one O(8)In4 tetrahedra,  an edgeedge with one O(17)In3Sb tetrahedra,  an edgeedge with one O(22)In4 tetrahedra, and  an edgeedge with one O(7)In4 tetrahedra. In the nineteenth O site, O(19) is bonded to one In(10), one In(5), one In(7), and one In(8) atom to form OIn4 tetrahedra that share  a cornercorner with one O(10)In3Sb tetrahedra,  a cornercorner with one O(17)In3Sb tetrahedra,  a cornercorner with one O(22)In4 tetrahedra,  a cornercorner with one O(3)In4 tetrahedra,  a cornercorner with one O(5)In4 tetrahedra,  a cornercorner with one O(8)In4 tetrahedra,  an edgeedge with one O(15)In3Sb tetrahedra,  an edgeedge with one O(20)In4 tetrahedra, and  an edgeedge with one O(6)In4 tetrahedra. In the twentieth O site, O(20) is bonded to one In(1), one In(10), one In(4), and one In(8) atom to form OIn4 tetrahedra that share  a cornercorner with one O(10)In3Sb tetrahedra,  a cornercorner with one O(15)In3Sb tetrahedra,  a cornercorner with one O(18)In3Sb tetrahedra,  a cornercorner with one O(3)In4 tetrahedra,  a cornercorner with one O(6)In4 tetrahedra,  a cornercorner with one O(7)In4 tetrahedra,  an edgeedge with one O(19)In4 tetrahedra,  an edgeedge with one O(22)In4 tetrahedra, and  an edgeedge with one O(5)In4 tetrahedra. In the twenty-first O site, O(21) is bonded in a 4-coordinate geometry to one In(11), one In(5), one In(9), and one Sb(1) atom. In the twenty-second O site, O(22) is bonded to one In(1), one In(10), one In(2), and one In(9) atom to form OIn4 tetrahedra that share  a cornercorner with one O(17)In3Sb tetrahedra,  a cornercorner with one O(19)In4 tetrahedra,  a cornercorner with one O(5)In4 tetrahedra,  a cornercorner with one O(6)In4 tetrahedra,  a cornercorner with one O(7)In4 tetrahedra,  a cornercorner with one O(8)In4 tetrahedra,  an edgeedge with one O(18)In3Sb tetrahedra,  an edgeedge with one O(20)In4 tetrahedra, and  an edgeedge with one O(3)In4 tetrahedra. In the twenty-third O site, O(23) is bonded in a distorted trigonal non-coplanar geometry to one In(10), one In(11), and one Sb(2) atom. In the twenty-fourth O site, O(24) is bonded in a 4-coordinate geometry to one In(2), one In(8), one In(9), and one Sb(1) atom. is represented by the CIF card [CIF]
data_In11(SbO8)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.069
_cell_length_b   8.102
_cell_length_c   8.155
_cell_angle_alpha   71.067
_cell_angle_beta   72.121
_cell_angle_gamma   72.246
_symmetry_Int_Tables_number   1
_cell_volume   467.264
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.392  0.916  0.220  1.0
  In  In1  1  0.714  0.889  0.428  1.0
  In  In2  1  0.422  0.720  0.891  1.0
  In  In3  1  0.072  0.790  0.608  1.0
  In  In4  1  0.887  0.418  0.715  1.0
  In  In5  1  0.782  0.615  0.076  1.0
  In  In6  1  0.108  0.581  0.291  1.0
  In  In7  1  0.922  0.212  0.392  1.0
  In  In8  1  0.589  0.284  0.107  1.0
  In  In9  1  0.289  0.108  0.562  1.0
  In  In10  1  0.608  0.082  0.779  1.0
  Sb  Sb11  1  0.002  0.999  0.003  1.0
  Sb  Sb12  1  0.499  0.494  0.499  1.0
  Sb  Sb13  1  0.208  0.397  0.936  1.0
  O  O14  1  0.131  0.923  0.780  1.0
  O  O15  1  0.583  0.717  0.379  1.0
  O  O16  1  0.502  0.913  0.669  1.0
  O  O17  1  0.222  0.864  0.088  1.0
  O  O18  1  0.825  0.995  0.586  1.0
  O  O19  1  0.916  0.670  0.512  1.0
  O  O20  1  0.582  0.838  0.997  1.0
  O  O21  1  0.675  0.511  0.914  1.0
  O  O22  1  0.280  0.634  0.416  1.0
  O  O23  1  0.013  0.582  0.835  1.0
  O  O24  1  0.637  0.418  0.276  1.0
  O  O25  1  0.917  0.774  0.133  1.0
  O  O26  1  0.090  0.235  0.880  1.0
  O  O27  1  0.364  0.558  0.737  1.0
  O  O28  1  0.015  0.405  0.160  1.0
  O  O29  1  0.716  0.361  0.589  1.0
  O  O30  1  0.314  0.498  0.077  1.0
  O  O31  1  0.404  0.191  0.992  1.0
  O  O32  1  0.079  0.327  0.495  1.0
  O  O33  1  0.173  0.003  0.413  1.0
  O  O34  1  0.786  0.140  0.909  1.0
  O  O35  1  0.500  0.082  0.314  1.0
  O  O36  1  0.415  0.273  0.620  1.0
  O  O37  1  0.868  0.083  0.220  1.0
[/CIF]
.
The structure described by In11(SbO8)3 crystallizes in the triclinic P1 space group. There are eleven inequivalent In sites. In the first In site, In(1) is bonded in a 7-coordinate geometry to one O(18), one O(2), one O(20), one O(22), one O(4), one O(7), and one O(9) atom. In the second In site, In(2) is bonded in a 6-coordinate geometry to one O(2), one O(22), one O(24), one O(3), one O(5), and one O(6) atom. In the third In site, In(3) is bonded in a 7-coordinate geometry to one O(1), one O(14), one O(17), one O(3), one O(4), one O(7), and one O(8) atom. In the fourth In site, In(4) is bonded in a 6-coordinate geometry to one O(1), one O(10), one O(20), one O(5), one O(6), and one O(9) atom. In the fifth In site, In(5) is bonded to one O(10), one O(13), one O(16), one O(19), one O(21), one O(6), and one O(8) atom to form distorted InO7 pentagonal bipyramids that share  a cornercorner with one In(10)O6 octahedra,  a cornercorner with one Sb(2)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra, and  an edgeedge with one Sb(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-64°. In the sixth In site, In(6) is bonded in a 6-coordinate geometry to one O(10), one O(11), one O(12), one O(15), one O(7), and one O(8) atom. In the seventh In site, In(7) is bonded in a 7-coordinate geometry to one O(12), one O(15), one O(17), one O(19), one O(4), one O(6), and one O(9) atom. In the eighth In site, In(8) is bonded in a 7-coordinate geometry to one O(11), one O(15), one O(16), one O(19), one O(20), one O(24), and one O(5) atom. In the ninth In site, In(9) is bonded in a 7-coordinate geometry to one O(11), one O(17), one O(18), one O(21), one O(22), one O(24), and one O(8) atom. In the tenth In site, In(10) is bonded to one O(1), one O(19), one O(20), one O(22), one O(23), and one O(3) atom to form distorted InO6 octahedra that share  a cornercorner with one Sb(1)O6 octahedra,  a cornercorner with one Sb(2)O6 octahedra, and  a cornercorner with one In(5)O7 pentagonal bipyramid. The corner-sharing octahedral tilt angles range from 43-63°. In the eleventh In site, In(11) is bonded in a 7-coordinate geometry to one O(16), one O(18), one O(21), one O(23), one O(3), one O(5), and one O(7) atom. There are three inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(1), one O(12), one O(13), one O(21), one O(24), and one O(4) atom to form SbO6 octahedra that share  a cornercorner with one In(10)O6 octahedra,  a cornercorner with one Sb(3)O6 octahedra, and  an edgeedge with one In(5)O7 pentagonal bipyramid. The corner-sharing octahedral tilt angles range from 41-63°. In the second Sb site, Sb(2) is bonded to one O(11), one O(14), one O(16), one O(2), one O(23), and one O(9) atom to form SbO6 octahedra that share  a cornercorner with one In(10)O6 octahedra,  a cornercorner with one Sb(3)O6 octahedra, and  a cornercorner with one In(5)O7 pentagonal bipyramid. The corner-sharing octahedral tilt angles range from 43-58°. In the third Sb site, Sb(3) is bonded to one O(10), one O(13), one O(14), one O(15), one O(17), and one O(18) atom to form distorted SbO6 octahedra that share  a cornercorner with one Sb(1)O6 octahedra,  a cornercorner with one Sb(2)O6 octahedra, and  an edgeedge with one In(5)O7 pentagonal bipyramid. The corner-sharing octahedral tilt angles range from 41-58°. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one In(10), one In(3), one In(4), and one Sb(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one In(1), one In(2), and one Sb(2) atom. In the third O site, O(3) is bonded to one In(10), one In(11), one In(2), and one In(3) atom to form distorted OIn4 tetrahedra that share  a cornercorner with one O(17)In3Sb tetrahedra,  a cornercorner with one O(18)In3Sb tetrahedra,  a cornercorner with one O(19)In4 tetrahedra,  a cornercorner with one O(20)In4 tetrahedra,  a cornercorner with one O(6)In4 tetrahedra,  a cornercorner with one O(8)In4 tetrahedra,  an edgeedge with one O(22)In4 tetrahedra,  an edgeedge with one O(5)In4 tetrahedra, and  an edgeedge with one O(7)In4 tetrahedra. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one In(1), one In(3), one In(7), and one Sb(1) atom. In the fifth O site, O(5) is bonded to one In(11), one In(2), one In(4), and one In(8) atom to form OIn4 tetrahedra that share  a cornercorner with one O(10)In3Sb tetrahedra,  a cornercorner with one O(15)In3Sb tetrahedra,  a cornercorner with one O(18)In3Sb tetrahedra,  a cornercorner with one O(19)In4 tetrahedra,  a cornercorner with one O(22)In4 tetrahedra,  a cornercorner with one O(7)In4 tetrahedra,  an edgeedge with one O(20)In4 tetrahedra,  an edgeedge with one O(3)In4 tetrahedra, and  an edgeedge with one O(6)In4 tetrahedra. In the sixth O site, O(6) is bonded to one In(2), one In(4), one In(5), and one In(7) atom to form OIn4 tetrahedra that share  a cornercorner with one O(15)In3Sb tetrahedra,  a cornercorner with one O(17)In3Sb tetrahedra,  a cornercorner with one O(20)In4 tetrahedra,  a cornercorner with one O(22)In4 tetrahedra,  a cornercorner with one O(3)In4 tetrahedra,  a cornercorner with one O(8)In4 tetrahedra,  an edgeedge with one O(10)In3Sb tetrahedra,  an edgeedge with one O(19)In4 tetrahedra, and  an edgeedge with one O(5)In4 tetrahedra. In the seventh O site, O(7) is bonded to one In(1), one In(11), one In(3), and one In(6) atom to form OIn4 tetrahedra that share  a cornercorner with one O(10)In3Sb tetrahedra,  a cornercorner with one O(15)In3Sb tetrahedra,  a cornercorner with one O(17)In3Sb tetrahedra,  a cornercorner with one O(20)In4 tetrahedra,  a cornercorner with one O(22)In4 tetrahedra,  a cornercorner with one O(5)In4 tetrahedra,  an edgeedge with one O(18)In3Sb tetrahedra,  an edgeedge with one O(3)In4 tetrahedra, and  an edgeedge with one O(8)In4 tetrahedra. In the eighth O site, O(8) is bonded to one In(3), one In(5), one In(6), and one In(9) atom to form OIn4 tetrahedra that share  a cornercorner with one O(15)In3Sb tetrahedra,  a cornercorner with one O(18)In3Sb tetrahedra,  a cornercorner with one O(19)In4 tetrahedra,  a cornercorner with one O(22)In4 tetrahedra,  a cornercorner with one O(3)In4 tetrahedra,  a cornercorner with one O(6)In4 tetrahedra,  an edgeedge with one O(10)In3Sb tetrahedra,  an edgeedge with one O(17)In3Sb tetrahedra, and  an edgeedge with one O(7)In4 tetrahedra. In the ninth O site, O(9) is bonded in a 4-coordinate geometry to one In(1), one In(4), one In(7), and one Sb(2) atom. In the tenth O site, O(10) is bonded to one In(4), one In(5), one In(6), and one Sb(3) atom to form distorted OIn3Sb tetrahedra that share  a cornercorner with one O(17)In3Sb tetrahedra,  a cornercorner with one O(18)In3Sb tetrahedra,  a cornercorner with one O(19)In4 tetrahedra,  a cornercorner with one O(20)In4 tetrahedra,  a cornercorner with one O(5)In4 tetrahedra,  a cornercorner with one O(7)In4 tetrahedra,  an edgeedge with one O(15)In3Sb tetrahedra,  an edgeedge with one O(6)In4 tetrahedra, and  an edgeedge with one O(8)In4 tetrahedra. In the eleventh O site, O(11) is bonded in a 4-coordinate geometry to one In(6), one In(8), one In(9), and one Sb(2) atom. In the twelfth O site, O(12) is bonded in a 3-coordinate geometry to one In(6), one In(7), and one Sb(1) atom. In the thirteenth O site, O(13) is bonded in a distorted trigonal non-coplanar geometry to one In(5), one Sb(1), and one Sb(3) atom. In the fourteenth O site, O(14) is bonded in a distorted trigonal planar geometry to one In(3), one Sb(2), and one Sb(3) atom. In the fifteenth O site, O(15) is bonded to one In(6), one In(7), one In(8), and one Sb(3) atom to form distorted OIn3Sb tetrahedra that share  a cornercorner with one O(18)In3Sb tetrahedra,  a cornercorner with one O(20)In4 tetrahedra,  a cornercorner with one O(5)In4 tetrahedra,  a cornercorner with one O(6)In4 tetrahedra,  a cornercorner with one O(7)In4 tetrahedra,  a cornercorner with one O(8)In4 tetrahedra,  an edgeedge with one O(10)In3Sb tetrahedra,  an edgeedge with one O(17)In3Sb tetrahedra, and  an edgeedge with one O(19)In4 tetrahedra. In the sixteenth O site, O(16) is bonded in a 4-coordinate geometry to one In(11), one In(5), one In(8), and one Sb(2) atom. In the seventeenth O site, O(17) is bonded to one In(3), one In(7), one In(9), and one Sb(3) atom to form OIn3Sb tetrahedra that share  a cornercorner with one O(10)In3Sb tetrahedra,  a cornercorner with one O(19)In4 tetrahedra,  a cornercorner with one O(22)In4 tetrahedra,  a cornercorner with one O(3)In4 tetrahedra,  a cornercorner with one O(6)In4 tetrahedra,  a cornercorner with one O(7)In4 tetrahedra,  an edgeedge with one O(15)In3Sb tetrahedra,  an edgeedge with one O(18)In3Sb tetrahedra, and  an edgeedge with one O(8)In4 tetrahedra. In the eighteenth O site, O(18) is bonded to one In(1), one In(11), one In(9), and one Sb(3) atom to form distorted OIn3Sb tetrahedra that share  a cornercorner with one O(10)In3Sb tetrahedra,  a cornercorner with one O(15)In3Sb tetrahedra,  a cornercorner with one O(20)In4 tetrahedra,  a cornercorner with one O(3)In4 tetrahedra,  a cornercorner with one O(5)In4 tetrahedra,  a cornercorner with one O(8)In4 tetrahedra,  an edgeedge with one O(17)In3Sb tetrahedra,  an edgeedge with one O(22)In4 tetrahedra, and  an edgeedge with one O(7)In4 tetrahedra. In the nineteenth O site, O(19) is bonded to one In(10), one In(5), one In(7), and one In(8) atom to form OIn4 tetrahedra that share  a cornercorner with one O(10)In3Sb tetrahedra,  a cornercorner with one O(17)In3Sb tetrahedra,  a cornercorner with one O(22)In4 tetrahedra,  a cornercorner with one O(3)In4 tetrahedra,  a cornercorner with one O(5)In4 tetrahedra,  a cornercorner with one O(8)In4 tetrahedra,  an edgeedge with one O(15)In3Sb tetrahedra,  an edgeedge with one O(20)In4 tetrahedra, and  an edgeedge with one O(6)In4 tetrahedra. In the twentieth O site, O(20) is bonded to one In(1), one In(10), one In(4), and one In(8) atom to form OIn4 tetrahedra that share  a cornercorner with one O(10)In3Sb tetrahedra,  a cornercorner with one O(15)In3Sb tetrahedra,  a cornercorner with one O(18)In3Sb tetrahedra,  a cornercorner with one O(3)In4 tetrahedra,  a cornercorner with one O(6)In4 tetrahedra,  a cornercorner with one O(7)In4 tetrahedra,  an edgeedge with one O(19)In4 tetrahedra,  an edgeedge with one O(22)In4 tetrahedra, and  an edgeedge with one O(5)In4 tetrahedra. In the twenty-first O site, O(21) is bonded in a 4-coordinate geometry to one In(11), one In(5), one In(9), and one Sb(1) atom. In the twenty-second O site, O(22) is bonded to one In(1), one In(10), one In(2), and one In(9) atom to form OIn4 tetrahedra that share  a cornercorner with one O(17)In3Sb tetrahedra,  a cornercorner with one O(19)In4 tetrahedra,  a cornercorner with one O(5)In4 tetrahedra,  a cornercorner with one O(6)In4 tetrahedra,  a cornercorner with one O(7)In4 tetrahedra,  a cornercorner with one O(8)In4 tetrahedra,  an edgeedge with one O(18)In3Sb tetrahedra,  an edgeedge with one O(20)In4 tetrahedra, and  an edgeedge with one O(3)In4 tetrahedra. In the twenty-third O site, O(23) is bonded in a distorted trigonal non-coplanar geometry to one In(10), one In(11), and one Sb(2) atom. In the twenty-fourth O site, O(24) is bonded in a 4-coordinate geometry to one In(2), one In(8), one In(9), and one Sb(1) atom. is represented by the CIF card [CIF]
data_In11(SbO8)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.069
_cell_length_b   8.102
_cell_length_c   8.155
_cell_angle_alpha   71.067
_cell_angle_beta   72.121
_cell_angle_gamma   72.246
_symmetry_Int_Tables_number   1
_cell_volume   467.264
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.392  0.916  0.220  1.0
  In  In1  1  0.714  0.889  0.428  1.0
  In  In2  1  0.422  0.720  0.891  1.0
  In  In3  1  0.072  0.790  0.608  1.0
  In  In4  1  0.887  0.418  0.715  1.0
  In  In5  1  0.782  0.615  0.076  1.0
  In  In6  1  0.108  0.581  0.291  1.0
  In  In7  1  0.922  0.212  0.392  1.0
  In  In8  1  0.589  0.284  0.107  1.0
  In  In9  1  0.289  0.108  0.562  1.0
  In  In10  1  0.608  0.082  0.779  1.0
  Sb  Sb11  1  0.002  0.999  0.003  1.0
  Sb  Sb12  1  0.499  0.494  0.499  1.0
  Sb  Sb13  1  0.208  0.397  0.936  1.0
  O  O14  1  0.131  0.923  0.780  1.0
  O  O15  1  0.583  0.717  0.379  1.0
  O  O16  1  0.502  0.913  0.669  1.0
  O  O17  1  0.222  0.864  0.088  1.0
  O  O18  1  0.825  0.995  0.586  1.0
  O  O19  1  0.916  0.670  0.512  1.0
  O  O20  1  0.582  0.838  0.997  1.0
  O  O21  1  0.675  0.511  0.914  1.0
  O  O22  1  0.280  0.634  0.416  1.0
  O  O23  1  0.013  0.582  0.835  1.0
  O  O24  1  0.637  0.418  0.276  1.0
  O  O25  1  0.917  0.774  0.133  1.0
  O  O26  1  0.090  0.235  0.880  1.0
  O  O27  1  0.364  0.558  0.737  1.0
  O  O28  1  0.015  0.405  0.160  1.0
  O  O29  1  0.716  0.361  0.589  1.0
  O  O30  1  0.314  0.498  0.077  1.0
  O  O31  1  0.404  0.191  0.992  1.0
  O  O32  1  0.079  0.327  0.495  1.0
  O  O33  1  0.173  0.003  0.413  1.0
  O  O34  1  0.786  0.140  0.909  1.0
  O  O35  1  0.500  0.082  0.314  1.0
  O  O36  1  0.415  0.273  0.620  1.0
  O  O37  1  0.868  0.083  0.220  1.0
[/CIF]
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