The material described by P2V crystallizes in the monoclinic C2/m space group. V(1) is bonded in a 8-coordinate geometry to three equivalent P(1) and five equivalent P(2) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded in a 6-coordinate geometry to three equivalent V(1) and three equivalent P(1) atoms. In the second P site, P(2) is bonded in a 5-coordinate geometry to five equivalent V(1) atoms. is represented by the CIF file [CIF]
data_VP2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.115
_cell_length_b   4.484
_cell_length_c   6.473
_cell_angle_alpha   79.262
_cell_angle_beta   76.079
_cell_angle_gamma   69.678
_symmetry_Int_Tables_number   1
_cell_volume   81.780
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.843  0.615  0.698  1.0
  V  V1  1  0.157  0.385  0.302  1.0
  P  P2  1  0.142  0.746  0.970  1.0
  P  P3  1  0.858  0.254  0.030  1.0
  P  P4  1  0.399  0.798  0.403  1.0
  P  P5  1  0.601  0.202  0.597  1.0
[/CIF]
.
The material described by P2V crystallizes in the monoclinic C2/m space group. V(1) is bonded in a 8-coordinate geometry to three equivalent P(1) and five equivalent P(2) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded in a 6-coordinate geometry to three equivalent V(1) and three equivalent P(1) atoms. In the second P site, P(2) is bonded in a 5-coordinate geometry to five equivalent V(1) atoms. is represented by the CIF file [CIF]
data_VP2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.115
_cell_length_b   4.484
_cell_length_c   6.473
_cell_angle_alpha   79.262
_cell_angle_beta   76.079
_cell_angle_gamma   69.678
_symmetry_Int_Tables_number   1
_cell_volume   81.780
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.843  0.615  0.698  1.0
  V  V1  1  0.157  0.385  0.302  1.0
  P  P2  1  0.142  0.746  0.970  1.0
  P  P3  1  0.858  0.254  0.030  1.0
  P  P4  1  0.399  0.798  0.403  1.0
  P  P5  1  0.601  0.202  0.597  1.0
[/CIF]
.