The structure described by Ti3Mn3(TeO8)2 is Hydrophilite-derived structured and crystallizes in the monoclinic Cm space group. There are two inequivalent Ti sites. In the first Ti site, Ti(1) is bonded to one O(11), one O(2), one O(3), one O(4), one O(6), and one O(7) atom to form TiO6 octahedra that share corners with two equivalent Te(2)O6 octahedra,  an edgeedge with one Te(1)O6 octahedra, edges with two equivalent Ti(1)O6 octahedra, and edges with two equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles are 47°. In the second Ti site, Ti(2) is bonded to one O(10), one O(5), two equivalent O(1), and two equivalent O(9) atoms to form TiO6 octahedra that share corners with two equivalent Te(1)O6 octahedra,  an edgeedge with one Te(2)O6 octahedra, and edges with four equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles are 43°. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(3), one O(4), two equivalent O(11), and two equivalent O(6) atoms to form distorted MnO6 octahedra that share corners with two equivalent Te(2)O6 octahedra,  an edgeedge with one Te(1)O6 octahedra, and edges with four equivalent Ti(1)O6 octahedra. The corner-sharing octahedral tilt angles are 54°. In the second Mn site, Mn(2) is bonded to one O(1), one O(10), one O(12), one O(5), one O(8), and one O(9) atom to form distorted MnO6 octahedra that share corners with two equivalent Te(1)O6 octahedra,  an edgeedge with one Te(2)O6 octahedra, edges with two equivalent Ti(2)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-52°. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(2), one O(8), two equivalent O(1), and two equivalent O(6) atoms to form TeO6 octahedra that share corners with two equivalent Ti(2)O6 octahedra, corners with four equivalent Mn(2)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra, and edges with two equivalent Ti(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 43-52°. In the second Te site, Te(2) is bonded to one O(12), one O(7), two equivalent O(11), and two equivalent O(9) atoms to form TeO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra, corners with four equivalent Ti(1)O6 octahedra,  an edgeedge with one Ti(2)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-54°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to one Ti(2), one Mn(2), and one Te(1) atom. In the second O site, O(2) is bonded in a distorted T-shaped geometry to two equivalent Ti(1) and one Te(1) atom. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Ti(1) and one Mn(1) atom. In the fourth O site, O(4) is bonded in a trigonal non-coplanar geometry to two equivalent Ti(1) and one Mn(1) atom. In the fifth O site, O(5) is bonded in a trigonal non-coplanar geometry to one Ti(2) and two equivalent Mn(2) atoms. In the sixth O site, O(6) is bonded in a distorted trigonal non-coplanar geometry to one Ti(1), one Mn(1), and one Te(1) atom. In the seventh O site, O(7) is bonded in a distorted T-shaped geometry to two equivalent Ti(1) and one Te(2) atom. In the eighth O site, O(8) is bonded in a trigonal planar geometry to two equivalent Mn(2) and one Te(1) atom. In the ninth O site, O(9) is bonded in a distorted T-shaped geometry to one Ti(2), one Mn(2), and one Te(2) atom. In the tenth O site, O(10) is bonded in a trigonal non-coplanar geometry to one Ti(2) and two equivalent Mn(2) atoms. In the eleventh O site, O(11) is bonded in a distorted trigonal planar geometry to one Ti(1), one Mn(1), and one Te(2) atom. In the twelfth O site, O(12) is bonded in a trigonal non-coplanar geometry to two equivalent Mn(2) and one Te(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ti3Mn3(TeO8)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.184
_cell_length_b   6.184
_cell_length_c   9.286
_cell_angle_alpha   87.519
_cell_angle_beta   87.519
_cell_angle_gamma   58.209
_symmetry_Int_Tables_number   1
_cell_volume   301.429
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.339  0.837  0.793  1.0
  Ti  Ti1  1  0.837  0.339  0.793  1.0
  Ti  Ti2  1  0.166  0.166  0.285  1.0
  Mn  Mn3  1  0.831  0.831  0.797  1.0
  Mn  Mn4  1  0.169  0.662  0.296  1.0
  Mn  Mn5  1  0.662  0.169  0.296  1.0
  Te  Te6  1  0.671  0.671  0.513  1.0
  Te  Te7  1  0.335  0.335  0.013  1.0
  O  O8  1  0.367  0.836  0.396  1.0
  O  O9  1  0.526  0.526  0.654  1.0
  O  O10  1  0.646  0.646  0.897  1.0
  O  O11  1  0.012  0.012  0.709  1.0
  O  O12  1  0.004  0.004  0.210  1.0
  O  O13  1  0.836  0.367  0.396  1.0
  O  O14  1  0.507  0.949  0.650  1.0
  O  O15  1  0.949  0.507  0.650  1.0
  O  O16  1  0.183  0.183  0.892  1.0
  O  O17  1  0.832  0.832  0.408  1.0
  O  O18  1  0.040  0.461  0.147  1.0
  O  O19  1  0.461  0.040  0.147  1.0
  O  O20  1  0.329  0.329  0.387  1.0
  O  O21  1  0.186  0.649  0.900  1.0
  O  O22  1  0.469  0.469  0.155  1.0
  O  O23  1  0.649  0.186  0.900  1.0
[/CIF]
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The structure described by Ti3Mn3(TeO8)2 is Hydrophilite-derived structured and crystallizes in the monoclinic Cm space group. There are two inequivalent Ti sites. In the first Ti site, Ti(1) is bonded to one O(11), one O(2), one O(3), one O(4), one O(6), and one O(7) atom to form TiO6 octahedra that share corners with two equivalent Te(2)O6 octahedra,  an edgeedge with one Te(1)O6 octahedra, edges with two equivalent Ti(1)O6 octahedra, and edges with two equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles are 47°. In the second Ti site, Ti(2) is bonded to one O(10), one O(5), two equivalent O(1), and two equivalent O(9) atoms to form TiO6 octahedra that share corners with two equivalent Te(1)O6 octahedra,  an edgeedge with one Te(2)O6 octahedra, and edges with four equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles are 43°. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(3), one O(4), two equivalent O(11), and two equivalent O(6) atoms to form distorted MnO6 octahedra that share corners with two equivalent Te(2)O6 octahedra,  an edgeedge with one Te(1)O6 octahedra, and edges with four equivalent Ti(1)O6 octahedra. The corner-sharing octahedral tilt angles are 54°. In the second Mn site, Mn(2) is bonded to one O(1), one O(10), one O(12), one O(5), one O(8), and one O(9) atom to form distorted MnO6 octahedra that share corners with two equivalent Te(1)O6 octahedra,  an edgeedge with one Te(2)O6 octahedra, edges with two equivalent Ti(2)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-52°. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(2), one O(8), two equivalent O(1), and two equivalent O(6) atoms to form TeO6 octahedra that share corners with two equivalent Ti(2)O6 octahedra, corners with four equivalent Mn(2)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra, and edges with two equivalent Ti(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 43-52°. In the second Te site, Te(2) is bonded to one O(12), one O(7), two equivalent O(11), and two equivalent O(9) atoms to form TeO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra, corners with four equivalent Ti(1)O6 octahedra,  an edgeedge with one Ti(2)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-54°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to one Ti(2), one Mn(2), and one Te(1) atom. In the second O site, O(2) is bonded in a distorted T-shaped geometry to two equivalent Ti(1) and one Te(1) atom. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Ti(1) and one Mn(1) atom. In the fourth O site, O(4) is bonded in a trigonal non-coplanar geometry to two equivalent Ti(1) and one Mn(1) atom. In the fifth O site, O(5) is bonded in a trigonal non-coplanar geometry to one Ti(2) and two equivalent Mn(2) atoms. In the sixth O site, O(6) is bonded in a distorted trigonal non-coplanar geometry to one Ti(1), one Mn(1), and one Te(1) atom. In the seventh O site, O(7) is bonded in a distorted T-shaped geometry to two equivalent Ti(1) and one Te(2) atom. In the eighth O site, O(8) is bonded in a trigonal planar geometry to two equivalent Mn(2) and one Te(1) atom. In the ninth O site, O(9) is bonded in a distorted T-shaped geometry to one Ti(2), one Mn(2), and one Te(2) atom. In the tenth O site, O(10) is bonded in a trigonal non-coplanar geometry to one Ti(2) and two equivalent Mn(2) atoms. In the eleventh O site, O(11) is bonded in a distorted trigonal planar geometry to one Ti(1), one Mn(1), and one Te(2) atom. In the twelfth O site, O(12) is bonded in a trigonal non-coplanar geometry to two equivalent Mn(2) and one Te(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ti3Mn3(TeO8)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.184
_cell_length_b   6.184
_cell_length_c   9.286
_cell_angle_alpha   87.519
_cell_angle_beta   87.519
_cell_angle_gamma   58.209
_symmetry_Int_Tables_number   1
_cell_volume   301.429
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.339  0.837  0.793  1.0
  Ti  Ti1  1  0.837  0.339  0.793  1.0
  Ti  Ti2  1  0.166  0.166  0.285  1.0
  Mn  Mn3  1  0.831  0.831  0.797  1.0
  Mn  Mn4  1  0.169  0.662  0.296  1.0
  Mn  Mn5  1  0.662  0.169  0.296  1.0
  Te  Te6  1  0.671  0.671  0.513  1.0
  Te  Te7  1  0.335  0.335  0.013  1.0
  O  O8  1  0.367  0.836  0.396  1.0
  O  O9  1  0.526  0.526  0.654  1.0
  O  O10  1  0.646  0.646  0.897  1.0
  O  O11  1  0.012  0.012  0.709  1.0
  O  O12  1  0.004  0.004  0.210  1.0
  O  O13  1  0.836  0.367  0.396  1.0
  O  O14  1  0.507  0.949  0.650  1.0
  O  O15  1  0.949  0.507  0.650  1.0
  O  O16  1  0.183  0.183  0.892  1.0
  O  O17  1  0.832  0.832  0.408  1.0
  O  O18  1  0.040  0.461  0.147  1.0
  O  O19  1  0.461  0.040  0.147  1.0
  O  O20  1  0.329  0.329  0.387  1.0
  O  O21  1  0.186  0.649  0.900  1.0
  O  O22  1  0.469  0.469  0.155  1.0
  O  O23  1  0.649  0.186  0.900  1.0
[/CIF]
.