The crystal structure described by CoBr(N2O)2NO2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four nitrous acid molecules and four CoBr(N2O)2 clusters. In each CoBr(N2O)2 cluster, Co(1) is bonded in a 5-coordinate geometry to one N(2), one N(3), one N(4), one N(5), and one Br(1) atom. There are four inequivalent N sites. In the first N site, N(2) is bonded in a trigonal planar geometry to one Co(1), one O(3), and one O(4) atom. In the second N site, N(3) is bonded in a single-bond geometry to one Co(1) atom. In the third N site, N(4) is bonded in a single-bond geometry to one Co(1) atom. In the fourth N site, N(5) is bonded in a single-bond geometry to one Co(1) atom. There are two inequivalent O sites. In the first O site, O(3) is bonded in a single-bond geometry to one N(2) atom. In the second O site, O(4) is bonded in a single-bond geometry to one N(2) atom. Br(1) is bonded in a single-bond geometry to one Co(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CoBrN5O4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.861
_cell_length_b   6.699
_cell_length_c   12.488
_cell_angle_alpha   70.422
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   934.937
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.483  0.230  0.283  1.0
  Co  Co1  1  0.017  0.230  0.783  1.0
  Co  Co2  1  0.517  0.770  0.717  1.0
  Co  Co3  1  0.983  0.770  0.217  1.0
  Br  Br4  1  0.388  0.920  0.376  1.0
  Br  Br5  1  0.112  0.920  0.876  1.0
  Br  Br6  1  0.612  0.080  0.624  1.0
  Br  Br7  1  0.888  0.080  0.124  1.0
  N  N8  1  0.237  0.264  0.146  1.0
  N  N9  1  0.263  0.264  0.646  1.0
  N  N10  1  0.763  0.736  0.854  1.0
  N  N11  1  0.737  0.736  0.354  1.0
  N  N12  1  0.497  0.524  0.150  1.0
  N  N13  1  0.003  0.524  0.650  1.0
  N  N14  1  0.503  0.476  0.850  1.0
  N  N15  1  0.997  0.476  0.350  1.0
  N  N16  1  0.597  0.231  0.341  1.0
  N  N17  1  0.903  0.231  0.841  1.0
  N  N18  1  0.403  0.769  0.659  1.0
  N  N19  1  0.097  0.769  0.159  1.0
  N  N20  1  0.496  0.122  0.169  1.0
  N  N21  1  0.004  0.122  0.669  1.0
  N  N22  1  0.504  0.878  0.831  1.0
  N  N23  1  0.996  0.878  0.331  1.0
  N  N24  1  0.378  0.353  0.344  1.0
  N  N25  1  0.122  0.353  0.844  1.0
  N  N26  1  0.622  0.647  0.656  1.0
  N  N27  1  0.878  0.647  0.156  1.0
  O  O28  1  0.241  0.155  0.086  1.0
  O  O29  1  0.259  0.155  0.586  1.0
  O  O30  1  0.759  0.845  0.914  1.0
  O  O31  1  0.741  0.845  0.414  1.0
  O  O32  1  0.161  0.341  0.184  1.0
  O  O33  1  0.339  0.341  0.684  1.0
  O  O34  1  0.839  0.659  0.816  1.0
  O  O35  1  0.661  0.659  0.316  1.0
  O  O36  1  0.415  0.639  0.141  1.0
  O  O37  1  0.085  0.639  0.641  1.0
  O  O38  1  0.585  0.361  0.859  1.0
  O  O39  1  0.915  0.361  0.359  1.0
  O  O40  1  0.581  0.553  0.091  1.0
  O  O41  1  0.919  0.553  0.591  1.0
  O  O42  1  0.419  0.447  0.909  1.0
  O  O43  1  0.081  0.447  0.409  1.0
[/CIF]
.
The crystal structure described by CoBr(N2O)2NO2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four nitrous acid molecules and four CoBr(N2O)2 clusters. In each CoBr(N2O)2 cluster, Co(1) is bonded in a 5-coordinate geometry to one N(2), one N(3), one N(4), one N(5), and one Br(1) atom. There are four inequivalent N sites. In the first N site, N(2) is bonded in a trigonal planar geometry to one Co(1), one O(3), and one O(4) atom. In the second N site, N(3) is bonded in a single-bond geometry to one Co(1) atom. In the third N site, N(4) is bonded in a single-bond geometry to one Co(1) atom. In the fourth N site, N(5) is bonded in a single-bond geometry to one Co(1) atom. There are two inequivalent O sites. In the first O site, O(3) is bonded in a single-bond geometry to one N(2) atom. In the second O site, O(4) is bonded in a single-bond geometry to one N(2) atom. Br(1) is bonded in a single-bond geometry to one Co(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CoBrN5O4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.861
_cell_length_b   6.699
_cell_length_c   12.488
_cell_angle_alpha   70.422
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   934.937
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.483  0.230  0.283  1.0
  Co  Co1  1  0.017  0.230  0.783  1.0
  Co  Co2  1  0.517  0.770  0.717  1.0
  Co  Co3  1  0.983  0.770  0.217  1.0
  Br  Br4  1  0.388  0.920  0.376  1.0
  Br  Br5  1  0.112  0.920  0.876  1.0
  Br  Br6  1  0.612  0.080  0.624  1.0
  Br  Br7  1  0.888  0.080  0.124  1.0
  N  N8  1  0.237  0.264  0.146  1.0
  N  N9  1  0.263  0.264  0.646  1.0
  N  N10  1  0.763  0.736  0.854  1.0
  N  N11  1  0.737  0.736  0.354  1.0
  N  N12  1  0.497  0.524  0.150  1.0
  N  N13  1  0.003  0.524  0.650  1.0
  N  N14  1  0.503  0.476  0.850  1.0
  N  N15  1  0.997  0.476  0.350  1.0
  N  N16  1  0.597  0.231  0.341  1.0
  N  N17  1  0.903  0.231  0.841  1.0
  N  N18  1  0.403  0.769  0.659  1.0
  N  N19  1  0.097  0.769  0.159  1.0
  N  N20  1  0.496  0.122  0.169  1.0
  N  N21  1  0.004  0.122  0.669  1.0
  N  N22  1  0.504  0.878  0.831  1.0
  N  N23  1  0.996  0.878  0.331  1.0
  N  N24  1  0.378  0.353  0.344  1.0
  N  N25  1  0.122  0.353  0.844  1.0
  N  N26  1  0.622  0.647  0.656  1.0
  N  N27  1  0.878  0.647  0.156  1.0
  O  O28  1  0.241  0.155  0.086  1.0
  O  O29  1  0.259  0.155  0.586  1.0
  O  O30  1  0.759  0.845  0.914  1.0
  O  O31  1  0.741  0.845  0.414  1.0
  O  O32  1  0.161  0.341  0.184  1.0
  O  O33  1  0.339  0.341  0.684  1.0
  O  O34  1  0.839  0.659  0.816  1.0
  O  O35  1  0.661  0.659  0.316  1.0
  O  O36  1  0.415  0.639  0.141  1.0
  O  O37  1  0.085  0.639  0.641  1.0
  O  O38  1  0.585  0.361  0.859  1.0
  O  O39  1  0.915  0.361  0.359  1.0
  O  O40  1  0.581  0.553  0.091  1.0
  O  O41  1  0.919  0.553  0.591  1.0
  O  O42  1  0.419  0.447  0.909  1.0
  O  O43  1  0.081  0.447  0.409  1.0
[/CIF]
.