The crystal structure described by Cd11Na2 crystallizes in the cubic Pm-3 space group. Na(1) is bonded in a 12-coordinate geometry to four equivalent Cd(4), four equivalent Cd(5), and six equivalent Cd(2) atoms. There are five inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a cuboctahedral geometry to twelve equivalent Cd(2) atoms. In the second Cd site, Cd(2) is bonded in a 12-coordinate geometry to three equivalent Na(1), one Cd(1), one Cd(4), two equivalent Cd(5), and five equivalent Cd(2) atoms. In the third Cd site, Cd(3) is bonded in a 10-coordinate geometry to two equivalent Cd(4), four equivalent Cd(3), and four equivalent Cd(5) atoms. In the fourth Cd site, Cd(4) is bonded in a 13-coordinate geometry to four equivalent Na(1), one Cd(4), two equivalent Cd(2), two equivalent Cd(3), and four equivalent Cd(5) atoms. In the fifth Cd site, Cd(5) is bonded in a 9-coordinate geometry to three equivalent Na(1), three equivalent Cd(2), three equivalent Cd(3), and three equivalent Cd(4) atoms. is represented by the CIF card [CIF]
data_Na2Cd11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.622
_cell_length_b   9.622
_cell_length_c   9.622
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   890.733
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.500  0.198  0.000  1.0
  Na  Na1  1  0.500  0.802  0.000  1.0
  Na  Na2  1  0.000  0.500  0.198  1.0
  Na  Na3  1  0.000  0.500  0.802  1.0
  Na  Na4  1  0.198  0.000  0.500  1.0
  Na  Na5  1  0.802  0.000  0.500  1.0
  Cd  Cd6  1  0.000  0.000  0.000  1.0
  Cd  Cd7  1  0.733  0.000  0.157  1.0
  Cd  Cd8  1  0.267  0.000  0.843  1.0
  Cd  Cd9  1  0.267  0.000  0.157  1.0
  Cd  Cd10  1  0.733  0.000  0.843  1.0
  Cd  Cd11  1  0.157  0.733  0.000  1.0
  Cd  Cd12  1  0.843  0.267  0.000  1.0
  Cd  Cd13  1  0.157  0.267  0.000  1.0
  Cd  Cd14  1  0.843  0.733  0.000  1.0
  Cd  Cd15  1  0.000  0.157  0.733  1.0
  Cd  Cd16  1  0.000  0.843  0.267  1.0
  Cd  Cd17  1  0.000  0.157  0.267  1.0
  Cd  Cd18  1  0.000  0.843  0.733  1.0
  Cd  Cd19  1  0.500  0.268  0.500  1.0
  Cd  Cd20  1  0.500  0.732  0.500  1.0
  Cd  Cd21  1  0.500  0.500  0.268  1.0
  Cd  Cd22  1  0.500  0.500  0.732  1.0
  Cd  Cd23  1  0.268  0.500  0.500  1.0
  Cd  Cd24  1  0.732  0.500  0.500  1.0
  Cd  Cd25  1  0.000  0.341  0.500  1.0
  Cd  Cd26  1  0.000  0.659  0.500  1.0
  Cd  Cd27  1  0.500  0.000  0.341  1.0
  Cd  Cd28  1  0.500  0.000  0.659  1.0
  Cd  Cd29  1  0.341  0.500  0.000  1.0
  Cd  Cd30  1  0.659  0.500  0.000  1.0
  Cd  Cd31  1  0.719  0.281  0.281  1.0
  Cd  Cd32  1  0.281  0.281  0.719  1.0
  Cd  Cd33  1  0.281  0.719  0.281  1.0
  Cd  Cd34  1  0.719  0.719  0.719  1.0
  Cd  Cd35  1  0.281  0.719  0.719  1.0
  Cd  Cd36  1  0.719  0.719  0.281  1.0
  Cd  Cd37  1  0.719  0.281  0.719  1.0
  Cd  Cd38  1  0.281  0.281  0.281  1.0
[/CIF]
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The crystal structure described by Cd11Na2 crystallizes in the cubic Pm-3 space group. Na(1) is bonded in a 12-coordinate geometry to four equivalent Cd(4), four equivalent Cd(5), and six equivalent Cd(2) atoms. There are five inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a cuboctahedral geometry to twelve equivalent Cd(2) atoms. In the second Cd site, Cd(2) is bonded in a 12-coordinate geometry to three equivalent Na(1), one Cd(1), one Cd(4), two equivalent Cd(5), and five equivalent Cd(2) atoms. In the third Cd site, Cd(3) is bonded in a 10-coordinate geometry to two equivalent Cd(4), four equivalent Cd(3), and four equivalent Cd(5) atoms. In the fourth Cd site, Cd(4) is bonded in a 13-coordinate geometry to four equivalent Na(1), one Cd(4), two equivalent Cd(2), two equivalent Cd(3), and four equivalent Cd(5) atoms. In the fifth Cd site, Cd(5) is bonded in a 9-coordinate geometry to three equivalent Na(1), three equivalent Cd(2), three equivalent Cd(3), and three equivalent Cd(4) atoms. is represented by the CIF card [CIF]
data_Na2Cd11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.622
_cell_length_b   9.622
_cell_length_c   9.622
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   890.733
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.500  0.198  0.000  1.0
  Na  Na1  1  0.500  0.802  0.000  1.0
  Na  Na2  1  0.000  0.500  0.198  1.0
  Na  Na3  1  0.000  0.500  0.802  1.0
  Na  Na4  1  0.198  0.000  0.500  1.0
  Na  Na5  1  0.802  0.000  0.500  1.0
  Cd  Cd6  1  0.000  0.000  0.000  1.0
  Cd  Cd7  1  0.733  0.000  0.157  1.0
  Cd  Cd8  1  0.267  0.000  0.843  1.0
  Cd  Cd9  1  0.267  0.000  0.157  1.0
  Cd  Cd10  1  0.733  0.000  0.843  1.0
  Cd  Cd11  1  0.157  0.733  0.000  1.0
  Cd  Cd12  1  0.843  0.267  0.000  1.0
  Cd  Cd13  1  0.157  0.267  0.000  1.0
  Cd  Cd14  1  0.843  0.733  0.000  1.0
  Cd  Cd15  1  0.000  0.157  0.733  1.0
  Cd  Cd16  1  0.000  0.843  0.267  1.0
  Cd  Cd17  1  0.000  0.157  0.267  1.0
  Cd  Cd18  1  0.000  0.843  0.733  1.0
  Cd  Cd19  1  0.500  0.268  0.500  1.0
  Cd  Cd20  1  0.500  0.732  0.500  1.0
  Cd  Cd21  1  0.500  0.500  0.268  1.0
  Cd  Cd22  1  0.500  0.500  0.732  1.0
  Cd  Cd23  1  0.268  0.500  0.500  1.0
  Cd  Cd24  1  0.732  0.500  0.500  1.0
  Cd  Cd25  1  0.000  0.341  0.500  1.0
  Cd  Cd26  1  0.000  0.659  0.500  1.0
  Cd  Cd27  1  0.500  0.000  0.341  1.0
  Cd  Cd28  1  0.500  0.000  0.659  1.0
  Cd  Cd29  1  0.341  0.500  0.000  1.0
  Cd  Cd30  1  0.659  0.500  0.000  1.0
  Cd  Cd31  1  0.719  0.281  0.281  1.0
  Cd  Cd32  1  0.281  0.281  0.719  1.0
  Cd  Cd33  1  0.281  0.719  0.281  1.0
  Cd  Cd34  1  0.719  0.719  0.719  1.0
  Cd  Cd35  1  0.281  0.719  0.719  1.0
  Cd  Cd36  1  0.719  0.719  0.281  1.0
  Cd  Cd37  1  0.719  0.281  0.719  1.0
  Cd  Cd38  1  0.281  0.281  0.281  1.0
[/CIF]
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