The crystal structure described by Ag3N5O6 crystallizes in the orthorhombic Cmc2_1 space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 6-coordinate geometry to one N(3), one N(4), two equivalent O(1), and two equivalent O(2) atoms. In the second Ag site, Ag(2) is bonded to one N(3), one N(4), one O(1), one O(2), and one O(3) atom to form distorted edge-sharing AgN2O3 square pyramids. There are four inequivalent N sites. In the first N site, N(1) is bonded in a linear geometry to one N(3) and one N(4) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. In the third N site, N(3) is bonded to one Ag(1), two equivalent Ag(2), and one N(1) atom to form a mixture of distorted edge and corner-sharing NAg3N tetrahedra. In the fourth N site, N(4) is bonded to one Ag(1), two equivalent Ag(2), and one N(1) atom to form a mixture of distorted edge and corner-sharing NAg3N tetrahedra. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Ag(1), one Ag(2), and one N(2) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Ag(1), one Ag(2), and one N(2) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Ag(2) and one N(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ag3N5O6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.387
_cell_length_b   7.387
_cell_length_c   9.328
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   130.663
_symmetry_Int_Tables_number   1
_cell_volume   386.149
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.576  0.576  0.044  1.0
  Ag  Ag1  1  0.776  0.048  0.606  1.0
  Ag  Ag2  1  0.424  0.424  0.544  1.0
  Ag  Ag3  1  0.224  0.952  0.106  1.0
  Ag  Ag4  1  0.048  0.776  0.606  1.0
  Ag  Ag5  1  0.952  0.224  0.106  1.0
  N  N6  1  0.182  0.182  0.833  1.0
  N  N7  1  0.434  0.831  0.876  1.0
  N  N8  1  0.566  0.169  0.376  1.0
  N  N9  1  0.818  0.818  0.333  1.0
  N  N10  1  0.852  0.852  0.208  1.0
  N  N11  1  0.788  0.788  0.459  1.0
  N  N12  1  0.212  0.212  0.959  1.0
  N  N13  1  0.169  0.566  0.376  1.0
  N  N14  1  0.148  0.148  0.708  1.0
  N  N15  1  0.831  0.434  0.876  1.0
  O  O16  1  0.373  0.773  0.008  1.0
  O  O17  1  0.443  0.216  0.319  1.0
  O  O18  1  0.067  0.622  0.307  1.0
  O  O19  1  0.216  0.443  0.319  1.0
  O  O20  1  0.627  0.227  0.508  1.0
  O  O21  1  0.784  0.557  0.819  1.0
  O  O22  1  0.933  0.378  0.807  1.0
  O  O23  1  0.773  0.373  0.008  1.0
  O  O24  1  0.378  0.933  0.807  1.0
  O  O25  1  0.557  0.784  0.819  1.0
  O  O26  1  0.227  0.627  0.508  1.0
  O  O27  1  0.622  0.067  0.307  1.0
[/CIF]
.
The crystal structure described by Ag3N5O6 crystallizes in the orthorhombic Cmc2_1 space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 6-coordinate geometry to one N(3), one N(4), two equivalent O(1), and two equivalent O(2) atoms. In the second Ag site, Ag(2) is bonded to one N(3), one N(4), one O(1), one O(2), and one O(3) atom to form distorted edge-sharing AgN2O3 square pyramids. There are four inequivalent N sites. In the first N site, N(1) is bonded in a linear geometry to one N(3) and one N(4) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. In the third N site, N(3) is bonded to one Ag(1), two equivalent Ag(2), and one N(1) atom to form a mixture of distorted edge and corner-sharing NAg3N tetrahedra. In the fourth N site, N(4) is bonded to one Ag(1), two equivalent Ag(2), and one N(1) atom to form a mixture of distorted edge and corner-sharing NAg3N tetrahedra. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Ag(1), one Ag(2), and one N(2) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Ag(1), one Ag(2), and one N(2) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Ag(2) and one N(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ag3N5O6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.387
_cell_length_b   7.387
_cell_length_c   9.328
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   130.663
_symmetry_Int_Tables_number   1
_cell_volume   386.149
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.576  0.576  0.044  1.0
  Ag  Ag1  1  0.776  0.048  0.606  1.0
  Ag  Ag2  1  0.424  0.424  0.544  1.0
  Ag  Ag3  1  0.224  0.952  0.106  1.0
  Ag  Ag4  1  0.048  0.776  0.606  1.0
  Ag  Ag5  1  0.952  0.224  0.106  1.0
  N  N6  1  0.182  0.182  0.833  1.0
  N  N7  1  0.434  0.831  0.876  1.0
  N  N8  1  0.566  0.169  0.376  1.0
  N  N9  1  0.818  0.818  0.333  1.0
  N  N10  1  0.852  0.852  0.208  1.0
  N  N11  1  0.788  0.788  0.459  1.0
  N  N12  1  0.212  0.212  0.959  1.0
  N  N13  1  0.169  0.566  0.376  1.0
  N  N14  1  0.148  0.148  0.708  1.0
  N  N15  1  0.831  0.434  0.876  1.0
  O  O16  1  0.373  0.773  0.008  1.0
  O  O17  1  0.443  0.216  0.319  1.0
  O  O18  1  0.067  0.622  0.307  1.0
  O  O19  1  0.216  0.443  0.319  1.0
  O  O20  1  0.627  0.227  0.508  1.0
  O  O21  1  0.784  0.557  0.819  1.0
  O  O22  1  0.933  0.378  0.807  1.0
  O  O23  1  0.773  0.373  0.008  1.0
  O  O24  1  0.378  0.933  0.807  1.0
  O  O25  1  0.557  0.784  0.819  1.0
  O  O26  1  0.227  0.627  0.508  1.0
  O  O27  1  0.622  0.067  0.307  1.0
[/CIF]
.