The compound described by K2Pd(S4O13)2 crystallizes in the triclinic P-1 space group. K(1) is bonded in a 9-coordinate geometry to one O(10), one O(11), one O(12), one O(13), one O(5), one O(6), one O(7), and two equivalent O(3) atoms. Pd(1) is bonded in a square co-planar geometry to two equivalent O(2) and two equivalent O(8) atoms. There are four inequivalent S sites. In the first S site, S(1) is bonded to one O(1), one O(2), one O(3), and one O(6) atom to form corner-sharing SO4 tetrahedra. In the second S site, S(2) is bonded to one O(1), one O(4), one O(5), and one O(7) atom to form corner-sharing SO4 tetrahedra. In the third S site, S(3) is bonded to one O(12), one O(13), one O(8), and one O(9) atom to form corner-sharing SO4 tetrahedra. In the fourth S site, S(4) is bonded to one O(10), one O(11), one O(4), and one O(9) atom to form corner-sharing SO4 tetrahedra. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Pd(1) and one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to two equivalent K(1) and one S(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one S(2) and one S(4) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one K(1) and one S(2) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one K(1) and one S(1) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one K(1) and one S(2) atom. In the eighth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Pd(1) and one S(3) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one S(3) and one S(4) atom. In the tenth O site, O(10) is bonded in a single-bond geometry to one K(1) and one S(4) atom. In the eleventh O site, O(11) is bonded in a single-bond geometry to one K(1) and one S(4) atom. In the twelfth O site, O(12) is bonded in a distorted single-bond geometry to one K(1) and one S(3) atom. In the thirteenth O site, O(13) is bonded in a distorted single-bond geometry to one K(1) and one S(3) atom. is represented by the CIF card [CIF]
data_K2Pd(S4O13)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.585
_cell_length_b   8.947
_cell_length_c   9.306
_cell_angle_alpha   106.899
_cell_angle_beta   89.102
_cell_angle_gamma   107.937
_symmetry_Int_Tables_number   1
_cell_volume   572.996
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.129  0.267  0.880  1.0
  K  K1  1  0.871  0.733  0.120  1.0
  Pd  Pd2  1  0.500  0.500  0.500  1.0
  S  S3  1  0.667  0.359  0.717  1.0
  S  S4  1  0.333  0.641  0.283  1.0
  S  S5  1  0.867  0.189  0.487  1.0
  S  S6  1  0.133  0.811  0.513  1.0
  S  S7  1  0.375  0.154  0.226  1.0
  S  S8  1  0.625  0.846  0.774  1.0
  S  S9  1  0.781  0.235  0.199  1.0
  S  S10  1  0.219  0.765  0.801  1.0
  O  O11  1  0.689  0.186  0.579  1.0
  O  O12  1  0.311  0.814  0.421  1.0
  O  O13  1  0.700  0.483  0.632  1.0
  O  O14  1  0.300  0.517  0.368  1.0
  O  O15  1  0.817  0.406  0.831  1.0
  O  O16  1  0.183  0.594  0.169  1.0
  O  O17  1  0.844  0.302  0.381  1.0
  O  O18  1  0.156  0.698  0.619  1.0
  O  O19  1  0.034  0.287  0.580  1.0
  O  O20  1  0.966  0.713  0.420  1.0
  O  O21  1  0.479  0.294  0.751  1.0
  O  O22  1  0.521  0.706  0.249  1.0
  O  O23  1  0.837  0.024  0.395  1.0
  O  O24  1  0.163  0.976  0.605  1.0
  O  O25  1  0.413  0.250  0.389  1.0
  O  O26  1  0.587  0.750  0.611  1.0
  O  O27  1  0.586  0.103  0.186  1.0
  O  O28  1  0.414  0.897  0.814  1.0
  O  O29  1  0.770  0.380  0.170  1.0
  O  O30  1  0.230  0.620  0.830  1.0
  O  O31  1  0.905  0.150  0.125  1.0
  O  O32  1  0.095  0.850  0.875  1.0
  O  O33  1  0.361  0.242  0.122  1.0
  O  O34  1  0.639  0.758  0.878  1.0
  O  O35  1  0.252  0.990  0.204  1.0
  O  O36  1  0.748  0.010  0.796  1.0
[/CIF]
.
The compound described by K2Pd(S4O13)2 crystallizes in the triclinic P-1 space group. K(1) is bonded in a 9-coordinate geometry to one O(10), one O(11), one O(12), one O(13), one O(5), one O(6), one O(7), and two equivalent O(3) atoms. Pd(1) is bonded in a square co-planar geometry to two equivalent O(2) and two equivalent O(8) atoms. There are four inequivalent S sites. In the first S site, S(1) is bonded to one O(1), one O(2), one O(3), and one O(6) atom to form corner-sharing SO4 tetrahedra. In the second S site, S(2) is bonded to one O(1), one O(4), one O(5), and one O(7) atom to form corner-sharing SO4 tetrahedra. In the third S site, S(3) is bonded to one O(12), one O(13), one O(8), and one O(9) atom to form corner-sharing SO4 tetrahedra. In the fourth S site, S(4) is bonded to one O(10), one O(11), one O(4), and one O(9) atom to form corner-sharing SO4 tetrahedra. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Pd(1) and one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to two equivalent K(1) and one S(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one S(2) and one S(4) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one K(1) and one S(2) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one K(1) and one S(1) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one K(1) and one S(2) atom. In the eighth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Pd(1) and one S(3) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one S(3) and one S(4) atom. In the tenth O site, O(10) is bonded in a single-bond geometry to one K(1) and one S(4) atom. In the eleventh O site, O(11) is bonded in a single-bond geometry to one K(1) and one S(4) atom. In the twelfth O site, O(12) is bonded in a distorted single-bond geometry to one K(1) and one S(3) atom. In the thirteenth O site, O(13) is bonded in a distorted single-bond geometry to one K(1) and one S(3) atom. is represented by the CIF card [CIF]
data_K2Pd(S4O13)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.585
_cell_length_b   8.947
_cell_length_c   9.306
_cell_angle_alpha   106.899
_cell_angle_beta   89.102
_cell_angle_gamma   107.937
_symmetry_Int_Tables_number   1
_cell_volume   572.996
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.129  0.267  0.880  1.0
  K  K1  1  0.871  0.733  0.120  1.0
  Pd  Pd2  1  0.500  0.500  0.500  1.0
  S  S3  1  0.667  0.359  0.717  1.0
  S  S4  1  0.333  0.641  0.283  1.0
  S  S5  1  0.867  0.189  0.487  1.0
  S  S6  1  0.133  0.811  0.513  1.0
  S  S7  1  0.375  0.154  0.226  1.0
  S  S8  1  0.625  0.846  0.774  1.0
  S  S9  1  0.781  0.235  0.199  1.0
  S  S10  1  0.219  0.765  0.801  1.0
  O  O11  1  0.689  0.186  0.579  1.0
  O  O12  1  0.311  0.814  0.421  1.0
  O  O13  1  0.700  0.483  0.632  1.0
  O  O14  1  0.300  0.517  0.368  1.0
  O  O15  1  0.817  0.406  0.831  1.0
  O  O16  1  0.183  0.594  0.169  1.0
  O  O17  1  0.844  0.302  0.381  1.0
  O  O18  1  0.156  0.698  0.619  1.0
  O  O19  1  0.034  0.287  0.580  1.0
  O  O20  1  0.966  0.713  0.420  1.0
  O  O21  1  0.479  0.294  0.751  1.0
  O  O22  1  0.521  0.706  0.249  1.0
  O  O23  1  0.837  0.024  0.395  1.0
  O  O24  1  0.163  0.976  0.605  1.0
  O  O25  1  0.413  0.250  0.389  1.0
  O  O26  1  0.587  0.750  0.611  1.0
  O  O27  1  0.586  0.103  0.186  1.0
  O  O28  1  0.414  0.897  0.814  1.0
  O  O29  1  0.770  0.380  0.170  1.0
  O  O30  1  0.230  0.620  0.830  1.0
  O  O31  1  0.905  0.150  0.125  1.0
  O  O32  1  0.095  0.850  0.875  1.0
  O  O33  1  0.361  0.242  0.122  1.0
  O  O34  1  0.639  0.758  0.878  1.0
  O  O35  1  0.252  0.990  0.204  1.0
  O  O36  1  0.748  0.010  0.796  1.0
[/CIF]
.