The crystal structure described by CsVP3HO10 crystallizes in the monoclinic C2/c space group. Cs(1) is bonded in a 10-coordinate geometry to two equivalent O(2), two equivalent O(3), two equivalent O(4), and four equivalent O(5) atoms. V(1) is bonded to two equivalent O(3), two equivalent O(4), and two equivalent O(5) atoms to form VO6 octahedra that share corners with two equivalent P(1)O4 tetrahedra and corners with four equivalent P(2)O4 tetrahedra. There are two inequivalent P sites. In the first P site, P(1) is bonded to two equivalent O(1) and two equivalent O(4) atoms to form PO4 tetrahedra that share corners with two equivalent V(1)O6 octahedra and corners with two equivalent P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 47°. In the second P site, P(2) is bonded to one O(1), one O(2), one O(3), and one O(5) atom to form PO4 tetrahedra that share corners with two equivalent V(1)O6 octahedra and  a cornercorner with one P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 27-49°. H(1) is bonded in a linear geometry to two equivalent O(2) atoms. There are five inequivalent O sites. In the first O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Cs(1), one V(1), and one P(2) atom. In the second O site, O(4) is bonded in a 2-coordinate geometry to one Cs(1), one V(1), and one P(1) atom. In the third O site, O(5) is bonded in a distorted bent 120 degrees geometry to two equivalent Cs(1), one V(1), and one P(2) atom. In the fourth O site, O(1) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. In the fifth O site, O(2) is bonded in a bent 120 degrees geometry to one Cs(1), one P(2), and one H(1) atom. is represented by the CIF card [CIF]
data_CsVP3HO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.589
_cell_length_b   7.589
_cell_length_c   9.217
_cell_angle_alpha   73.137
_cell_angle_beta   73.131
_cell_angle_gamma   71.533
_symmetry_Int_Tables_number   1
_cell_volume   470.203
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.936  0.064  0.250  1.0
  Cs  Cs1  1  0.064  0.936  0.750  1.0
  H  H2  1  0.000  0.500  1.000  1.0
  H  H3  1  0.500  1.000  0.500  1.0
  O  O4  1  0.404  0.432  0.197  1.0
  O  O5  1  0.568  0.596  0.303  1.0
  O  O6  1  0.596  0.568  0.803  1.0
  O  O7  1  0.432  0.404  0.697  1.0
  O  O8  1  0.859  0.496  0.102  1.0
  O  O9  1  0.504  0.141  0.398  1.0
  O  O10  1  0.141  0.504  0.898  1.0
  O  O11  1  0.496  0.859  0.602  1.0
  O  O12  1  0.880  0.636  0.316  1.0
  O  O13  1  0.364  0.120  0.184  1.0
  O  O14  1  0.120  0.364  0.684  1.0
  O  O15  1  0.636  0.880  0.816  1.0
  O  O16  1  0.215  0.641  0.392  1.0
  O  O17  1  0.359  0.784  0.108  1.0
  O  O18  1  0.785  0.359  0.608  1.0
  O  O19  1  0.641  0.216  0.892  1.0
  O  O20  1  0.149  0.279  0.397  1.0
  O  O21  1  0.721  0.851  0.103  1.0
  O  O22  1  0.851  0.721  0.603  1.0
  O  O23  1  0.279  0.149  0.897  1.0
  P  P24  1  0.376  0.624  0.250  1.0
  P  P25  1  0.624  0.376  0.750  1.0
  P  P26  1  0.768  0.647  0.200  1.0
  P  P27  1  0.353  0.232  0.300  1.0
  P  P28  1  0.232  0.353  0.800  1.0
  P  P29  1  0.647  0.768  0.700  1.0
  V  V30  1  1.000  0.500  0.500  1.0
  V  V31  1  0.500  0.000  0.000  1.0
[/CIF]
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The crystal structure described by CsVP3HO10 crystallizes in the monoclinic C2/c space group. Cs(1) is bonded in a 10-coordinate geometry to two equivalent O(2), two equivalent O(3), two equivalent O(4), and four equivalent O(5) atoms. V(1) is bonded to two equivalent O(3), two equivalent O(4), and two equivalent O(5) atoms to form VO6 octahedra that share corners with two equivalent P(1)O4 tetrahedra and corners with four equivalent P(2)O4 tetrahedra. There are two inequivalent P sites. In the first P site, P(1) is bonded to two equivalent O(1) and two equivalent O(4) atoms to form PO4 tetrahedra that share corners with two equivalent V(1)O6 octahedra and corners with two equivalent P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 47°. In the second P site, P(2) is bonded to one O(1), one O(2), one O(3), and one O(5) atom to form PO4 tetrahedra that share corners with two equivalent V(1)O6 octahedra and  a cornercorner with one P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 27-49°. H(1) is bonded in a linear geometry to two equivalent O(2) atoms. There are five inequivalent O sites. In the first O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Cs(1), one V(1), and one P(2) atom. In the second O site, O(4) is bonded in a 2-coordinate geometry to one Cs(1), one V(1), and one P(1) atom. In the third O site, O(5) is bonded in a distorted bent 120 degrees geometry to two equivalent Cs(1), one V(1), and one P(2) atom. In the fourth O site, O(1) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. In the fifth O site, O(2) is bonded in a bent 120 degrees geometry to one Cs(1), one P(2), and one H(1) atom. is represented by the CIF card [CIF]
data_CsVP3HO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.589
_cell_length_b   7.589
_cell_length_c   9.217
_cell_angle_alpha   73.137
_cell_angle_beta   73.131
_cell_angle_gamma   71.533
_symmetry_Int_Tables_number   1
_cell_volume   470.203
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.936  0.064  0.250  1.0
  Cs  Cs1  1  0.064  0.936  0.750  1.0
  H  H2  1  0.000  0.500  1.000  1.0
  H  H3  1  0.500  1.000  0.500  1.0
  O  O4  1  0.404  0.432  0.197  1.0
  O  O5  1  0.568  0.596  0.303  1.0
  O  O6  1  0.596  0.568  0.803  1.0
  O  O7  1  0.432  0.404  0.697  1.0
  O  O8  1  0.859  0.496  0.102  1.0
  O  O9  1  0.504  0.141  0.398  1.0
  O  O10  1  0.141  0.504  0.898  1.0
  O  O11  1  0.496  0.859  0.602  1.0
  O  O12  1  0.880  0.636  0.316  1.0
  O  O13  1  0.364  0.120  0.184  1.0
  O  O14  1  0.120  0.364  0.684  1.0
  O  O15  1  0.636  0.880  0.816  1.0
  O  O16  1  0.215  0.641  0.392  1.0
  O  O17  1  0.359  0.784  0.108  1.0
  O  O18  1  0.785  0.359  0.608  1.0
  O  O19  1  0.641  0.216  0.892  1.0
  O  O20  1  0.149  0.279  0.397  1.0
  O  O21  1  0.721  0.851  0.103  1.0
  O  O22  1  0.851  0.721  0.603  1.0
  O  O23  1  0.279  0.149  0.897  1.0
  P  P24  1  0.376  0.624  0.250  1.0
  P  P25  1  0.624  0.376  0.750  1.0
  P  P26  1  0.768  0.647  0.200  1.0
  P  P27  1  0.353  0.232  0.300  1.0
  P  P28  1  0.232  0.353  0.800  1.0
  P  P29  1  0.647  0.768  0.700  1.0
  V  V30  1  1.000  0.500  0.500  1.0
  V  V31  1  0.500  0.000  0.000  1.0
[/CIF]
.