The structure described by BNH2 is Indium-like structured and crystallizes in the tetragonal P4_32_12 space group. The structure is zero-dimensional and consists of four 1,3,5,2,4,6-triazatriborinane molecules. There are two inequivalent B sites. In the first B site, B(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(3) atom. In the second B site, B(2) is bonded in a trigonal planar geometry to two equivalent N(1) and one H(1) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one B(1), one B(2), and one H(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to two equivalent B(1) and one H(4) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one B(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one B(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_BH2N
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.609
_cell_length_b   5.609
_cell_length_c   16.842
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   529.835
_cell_formula_units_Z   12
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.348  0.554  0.057  1.0
  B  B1  1  0.675  0.325  0.250  1.0
  B  B2  1  0.325  0.675  0.750  1.0
  B  B3  1  0.175  0.175  0.000  1.0
  B  B4  1  0.446  0.652  0.443  1.0
  B  B5  1  0.554  0.348  0.943  1.0
  B  B6  1  0.652  0.446  0.557  1.0
  B  B7  1  0.152  0.054  0.693  1.0
  B  B8  1  0.848  0.946  0.193  1.0
  B  B9  1  0.054  0.152  0.307  1.0
  B  B10  1  0.946  0.848  0.807  1.0
  B  B11  1  0.825  0.825  0.500  1.0
  H  H12  1  0.976  0.976  0.500  1.0
  H  H13  1  0.524  0.476  0.250  1.0
  H  H14  1  0.476  0.524  0.750  1.0
  H  H15  1  0.024  0.024  0.000  1.0
  H  H16  1  0.624  0.966  0.405  1.0
  H  H17  1  0.376  0.034  0.905  1.0
  H  H18  1  0.966  0.624  0.595  1.0
  H  H19  1  0.466  0.876  0.655  1.0
  H  H20  1  0.534  0.124  0.155  1.0
  H  H21  1  0.876  0.466  0.345  1.0
  H  H22  1  0.124  0.534  0.845  1.0
  H  H23  1  0.034  0.376  0.095  1.0
  H  H24  1  0.285  0.663  0.396  1.0
  H  H25  1  0.715  0.337  0.896  1.0
  H  H26  1  0.663  0.285  0.604  1.0
  H  H27  1  0.163  0.215  0.646  1.0
  H  H28  1  0.837  0.785  0.146  1.0
  H  H29  1  0.665  0.665  0.000  1.0
  H  H30  1  0.785  0.837  0.854  1.0
  H  H31  1  0.337  0.715  0.104  1.0
  H  H32  1  0.335  0.335  0.500  1.0
  H  H33  1  0.165  0.835  0.250  1.0
  H  H34  1  0.835  0.165  0.750  1.0
  H  H35  1  0.215  0.163  0.354  1.0
  N  N36  1  0.632  0.829  0.444  1.0
  N  N37  1  0.368  0.171  0.944  1.0
  N  N38  1  0.829  0.632  0.556  1.0
  N  N39  1  0.329  0.868  0.694  1.0
  N  N40  1  0.671  0.132  0.194  1.0
  N  N41  1  0.868  0.329  0.306  1.0
  N  N42  1  0.132  0.671  0.806  1.0
  N  N43  1  0.171  0.368  0.056  1.0
  N  N44  1  0.463  0.463  0.500  1.0
  N  N45  1  0.037  0.963  0.250  1.0
  N  N46  1  0.963  0.037  0.750  1.0
  N  N47  1  0.537  0.537  0.000  1.0
[/CIF]
.
The structure described by BNH2 is Indium-like structured and crystallizes in the tetragonal P4_32_12 space group. The structure is zero-dimensional and consists of four 1,3,5,2,4,6-triazatriborinane molecules. There are two inequivalent B sites. In the first B site, B(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(3) atom. In the second B site, B(2) is bonded in a trigonal planar geometry to two equivalent N(1) and one H(1) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one B(1), one B(2), and one H(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to two equivalent B(1) and one H(4) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one B(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one B(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_BH2N
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.609
_cell_length_b   5.609
_cell_length_c   16.842
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   529.835
_cell_formula_units_Z   12
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.348  0.554  0.057  1.0
  B  B1  1  0.675  0.325  0.250  1.0
  B  B2  1  0.325  0.675  0.750  1.0
  B  B3  1  0.175  0.175  0.000  1.0
  B  B4  1  0.446  0.652  0.443  1.0
  B  B5  1  0.554  0.348  0.943  1.0
  B  B6  1  0.652  0.446  0.557  1.0
  B  B7  1  0.152  0.054  0.693  1.0
  B  B8  1  0.848  0.946  0.193  1.0
  B  B9  1  0.054  0.152  0.307  1.0
  B  B10  1  0.946  0.848  0.807  1.0
  B  B11  1  0.825  0.825  0.500  1.0
  H  H12  1  0.976  0.976  0.500  1.0
  H  H13  1  0.524  0.476  0.250  1.0
  H  H14  1  0.476  0.524  0.750  1.0
  H  H15  1  0.024  0.024  0.000  1.0
  H  H16  1  0.624  0.966  0.405  1.0
  H  H17  1  0.376  0.034  0.905  1.0
  H  H18  1  0.966  0.624  0.595  1.0
  H  H19  1  0.466  0.876  0.655  1.0
  H  H20  1  0.534  0.124  0.155  1.0
  H  H21  1  0.876  0.466  0.345  1.0
  H  H22  1  0.124  0.534  0.845  1.0
  H  H23  1  0.034  0.376  0.095  1.0
  H  H24  1  0.285  0.663  0.396  1.0
  H  H25  1  0.715  0.337  0.896  1.0
  H  H26  1  0.663  0.285  0.604  1.0
  H  H27  1  0.163  0.215  0.646  1.0
  H  H28  1  0.837  0.785  0.146  1.0
  H  H29  1  0.665  0.665  0.000  1.0
  H  H30  1  0.785  0.837  0.854  1.0
  H  H31  1  0.337  0.715  0.104  1.0
  H  H32  1  0.335  0.335  0.500  1.0
  H  H33  1  0.165  0.835  0.250  1.0
  H  H34  1  0.835  0.165  0.750  1.0
  H  H35  1  0.215  0.163  0.354  1.0
  N  N36  1  0.632  0.829  0.444  1.0
  N  N37  1  0.368  0.171  0.944  1.0
  N  N38  1  0.829  0.632  0.556  1.0
  N  N39  1  0.329  0.868  0.694  1.0
  N  N40  1  0.671  0.132  0.194  1.0
  N  N41  1  0.868  0.329  0.306  1.0
  N  N42  1  0.132  0.671  0.806  1.0
  N  N43  1  0.171  0.368  0.056  1.0
  N  N44  1  0.463  0.463  0.500  1.0
  N  N45  1  0.037  0.963  0.250  1.0
  N  N46  1  0.963  0.037  0.750  1.0
  N  N47  1  0.537  0.537  0.000  1.0
[/CIF]
.