The material structure described by VGeN2 crystallizes in the orthorhombic Pnma space group. V(1) is bonded in a 4-coordinate geometry to two equivalent N(1) and three equivalent N(2) atoms. Ge(1) is bonded in a distorted T-shaped geometry to one N(2) and two equivalent N(1) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 4-coordinate geometry to two equivalent V(1) and two equivalent Ge(1) atoms. In the second N site, N(2) is bonded in a see-saw-like geometry to three equivalent V(1) and one Ge(1) atom. is represented by the CIF card [CIF]
data_VGeN2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.542
_cell_length_b   9.693
_cell_length_c   3.357
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   212.893
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.530  0.895  0.938  1.0
  V  V1  1  0.470  0.105  0.438  1.0
  V  V2  1  0.970  0.395  0.438  1.0
  V  V3  1  0.030  0.605  0.938  1.0
  Ge  Ge4  1  0.561  0.383  0.938  1.0
  Ge  Ge5  1  0.439  0.617  0.438  1.0
  Ge  Ge6  1  0.939  0.883  0.438  1.0
  Ge  Ge7  1  0.061  0.117  0.938  1.0
  N  N8  1  0.614  0.263  0.438  1.0
  N  N9  1  0.386  0.737  0.938  1.0
  N  N10  1  0.886  0.763  0.938  1.0
  N  N11  1  0.114  0.237  0.438  1.0
  N  N12  1  0.650  0.941  0.438  1.0
  N  N13  1  0.350  0.059  0.938  1.0
  N  N14  1  0.850  0.441  0.938  1.0
  N  N15  1  0.150  0.559  0.438  1.0
[/CIF]
.
The material structure described by VGeN2 crystallizes in the orthorhombic Pnma space group. V(1) is bonded in a 4-coordinate geometry to two equivalent N(1) and three equivalent N(2) atoms. Ge(1) is bonded in a distorted T-shaped geometry to one N(2) and two equivalent N(1) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 4-coordinate geometry to two equivalent V(1) and two equivalent Ge(1) atoms. In the second N site, N(2) is bonded in a see-saw-like geometry to three equivalent V(1) and one Ge(1) atom. is represented by the CIF card [CIF]
data_VGeN2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.542
_cell_length_b   9.693
_cell_length_c   3.357
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   212.893
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.530  0.895  0.938  1.0
  V  V1  1  0.470  0.105  0.438  1.0
  V  V2  1  0.970  0.395  0.438  1.0
  V  V3  1  0.030  0.605  0.938  1.0
  Ge  Ge4  1  0.561  0.383  0.938  1.0
  Ge  Ge5  1  0.439  0.617  0.438  1.0
  Ge  Ge6  1  0.939  0.883  0.438  1.0
  Ge  Ge7  1  0.061  0.117  0.938  1.0
  N  N8  1  0.614  0.263  0.438  1.0
  N  N9  1  0.386  0.737  0.938  1.0
  N  N10  1  0.886  0.763  0.938  1.0
  N  N11  1  0.114  0.237  0.438  1.0
  N  N12  1  0.650  0.941  0.438  1.0
  N  N13  1  0.350  0.059  0.938  1.0
  N  N14  1  0.850  0.441  0.938  1.0
  N  N15  1  0.150  0.559  0.438  1.0
[/CIF]
.