The material structure described by ZnV2O6 crystallizes in the triclinic P1 space group. There are four inequivalent V sites. In the first V site, V(1) is bonded to one O(10), one O(11), one O(3), one O(4), one O(7), and one O(8) atom to form distorted VO6 octahedra that share  a cornercorner with one Zn(2)O5 trigonal bipyramid, corners with two equivalent Zn(1)O5 trigonal bipyramids, and  an edgeedge with one Zn(2)O5 trigonal bipyramid. In the second V site, V(2) is bonded in a 5-coordinate geometry to one O(12), one O(3), one O(4), one O(7), and one O(8) atom. In the third V site, V(3) is bonded to one O(1), one O(12), one O(2), one O(5), one O(6), and one O(9) atom to form distorted VO6 octahedra that share  a cornercorner with one Zn(1)O5 trigonal bipyramid, corners with two equivalent Zn(2)O5 trigonal bipyramids, and  an edgeedge with one Zn(1)O5 trigonal bipyramid. In the fourth V site, V(4) is bonded in a 5-coordinate geometry to one O(1), one O(11), one O(2), one O(5), and one O(6) atom. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(3), one O(6), one O(8), and one O(9) atom to form distorted ZnO5 trigonal bipyramids that share  a cornercorner with one V(3)O6 octahedra, corners with two equivalent V(1)O6 octahedra, and  an edgeedge with one V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-57°. In the second Zn site, Zn(2) is bonded to one O(10), one O(2), one O(4), one O(5), and one O(7) atom to form distorted ZnO5 trigonal bipyramids that share  a cornercorner with one V(1)O6 octahedra, corners with two equivalent V(3)O6 octahedra, and  an edgeedge with one V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-57°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to one V(3), one V(4), and one Zn(1) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one V(3), one V(4), and one Zn(2) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one V(1), one V(2), and one Zn(1) atom. In the fourth O site, O(4) is bonded in a distorted T-shaped geometry to one V(1), one V(2), and one Zn(2) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one V(3), one V(4), and one Zn(2) atom. In the sixth O site, O(6) is bonded in a distorted T-shaped geometry to one V(3), one V(4), and one Zn(1) atom. In the seventh O site, O(7) is bonded in a distorted T-shaped geometry to one V(1), one V(2), and one Zn(2) atom. In the eighth O site, O(8) is bonded in a distorted trigonal planar geometry to one V(1), one V(2), and one Zn(1) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one V(3) and one Zn(1) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one V(1) and one Zn(2) atom. In the eleventh O site, O(11) is bonded in a distorted bent 150 degrees geometry to one V(1) and one V(4) atom. In the twelfth O site, O(12) is bonded in a distorted bent 150 degrees geometry to one V(2) and one V(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_V2ZnO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.892
_cell_length_b   5.323
_cell_length_c   5.364
_cell_angle_alpha   60.585
_cell_angle_beta   64.118
_cell_angle_gamma   90.677
_symmetry_Int_Tables_number   1
_cell_volume   104.788
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  O  O0  1  0.156  0.179  0.126  1.0
  O  O1  1  0.789  0.337  0.863  1.0
  O  O2  1  0.792  0.805  0.862  1.0
  O  O3  1  0.159  0.703  0.121  1.0
  O  O4  1  0.467  0.796  0.408  1.0
  O  O5  1  0.621  0.254  0.492  1.0
  V  V6  1  0.522  0.986  0.018  1.0
  V  V7  1  0.934  0.443  0.107  1.0
  Zn  Zn8  1  0.822  0.747  0.503  1.0
[/CIF]
.
The material structure described by ZnV2O6 crystallizes in the triclinic P1 space group. There are four inequivalent V sites. In the first V site, V(1) is bonded to one O(10), one O(11), one O(3), one O(4), one O(7), and one O(8) atom to form distorted VO6 octahedra that share  a cornercorner with one Zn(2)O5 trigonal bipyramid, corners with two equivalent Zn(1)O5 trigonal bipyramids, and  an edgeedge with one Zn(2)O5 trigonal bipyramid. In the second V site, V(2) is bonded in a 5-coordinate geometry to one O(12), one O(3), one O(4), one O(7), and one O(8) atom. In the third V site, V(3) is bonded to one O(1), one O(12), one O(2), one O(5), one O(6), and one O(9) atom to form distorted VO6 octahedra that share  a cornercorner with one Zn(1)O5 trigonal bipyramid, corners with two equivalent Zn(2)O5 trigonal bipyramids, and  an edgeedge with one Zn(1)O5 trigonal bipyramid. In the fourth V site, V(4) is bonded in a 5-coordinate geometry to one O(1), one O(11), one O(2), one O(5), and one O(6) atom. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(3), one O(6), one O(8), and one O(9) atom to form distorted ZnO5 trigonal bipyramids that share  a cornercorner with one V(3)O6 octahedra, corners with two equivalent V(1)O6 octahedra, and  an edgeedge with one V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-57°. In the second Zn site, Zn(2) is bonded to one O(10), one O(2), one O(4), one O(5), and one O(7) atom to form distorted ZnO5 trigonal bipyramids that share  a cornercorner with one V(1)O6 octahedra, corners with two equivalent V(3)O6 octahedra, and  an edgeedge with one V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-57°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to one V(3), one V(4), and one Zn(1) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one V(3), one V(4), and one Zn(2) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one V(1), one V(2), and one Zn(1) atom. In the fourth O site, O(4) is bonded in a distorted T-shaped geometry to one V(1), one V(2), and one Zn(2) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one V(3), one V(4), and one Zn(2) atom. In the sixth O site, O(6) is bonded in a distorted T-shaped geometry to one V(3), one V(4), and one Zn(1) atom. In the seventh O site, O(7) is bonded in a distorted T-shaped geometry to one V(1), one V(2), and one Zn(2) atom. In the eighth O site, O(8) is bonded in a distorted trigonal planar geometry to one V(1), one V(2), and one Zn(1) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one V(3) and one Zn(1) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one V(1) and one Zn(2) atom. In the eleventh O site, O(11) is bonded in a distorted bent 150 degrees geometry to one V(1) and one V(4) atom. In the twelfth O site, O(12) is bonded in a distorted bent 150 degrees geometry to one V(2) and one V(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_V2ZnO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.892
_cell_length_b   5.323
_cell_length_c   5.364
_cell_angle_alpha   60.585
_cell_angle_beta   64.118
_cell_angle_gamma   90.677
_symmetry_Int_Tables_number   1
_cell_volume   104.788
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  O  O0  1  0.156  0.179  0.126  1.0
  O  O1  1  0.789  0.337  0.863  1.0
  O  O2  1  0.792  0.805  0.862  1.0
  O  O3  1  0.159  0.703  0.121  1.0
  O  O4  1  0.467  0.796  0.408  1.0
  O  O5  1  0.621  0.254  0.492  1.0
  V  V6  1  0.522  0.986  0.018  1.0
  V  V7  1  0.934  0.443  0.107  1.0
  Zn  Zn8  1  0.822  0.747  0.503  1.0
[/CIF]
.