The crystal structure described by LiMnPO4 crystallizes in the orthorhombic Pna2_1 space group. Li(1) is bonded in a 4-coordinate geometry to one O(2), one O(4), and two equivalent O(1) atoms. Mn(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), two equivalent O(3), and two equivalent O(4) atoms. P(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Li(1), one Mn(1), and one P(1) atom to form distorted corner-sharing OLi2MnP tetrahedra. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Li(1), one Mn(1), and one P(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to two equivalent Mn(1) and one P(1) atom. In the fourth O site, O(4) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), two equivalent Mn(1), and one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiMnPO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.676
_cell_length_b   5.681
_cell_length_c   5.546
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   89.991
_symmetry_Int_Tables_number   1
_cell_volume   336.349
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.040  0.372  0.925  1.0
  Li  Li1  1  0.460  0.872  0.425  1.0
  Li  Li2  1  0.540  0.128  0.925  1.0
  Li  Li3  1  0.960  0.628  0.425  1.0
  Mn  Mn4  1  0.175  0.923  0.023  1.0
  Mn  Mn5  1  0.325  0.423  0.523  1.0
  Mn  Mn6  1  0.675  0.577  0.023  1.0
  Mn  Mn7  1  0.825  0.078  0.523  1.0
  P  P8  1  0.100  0.146  0.519  1.0
  P  P9  1  0.400  0.646  0.019  1.0
  P  P10  1  0.600  0.354  0.519  1.0
  P  P11  1  0.900  0.854  0.019  1.0
  O  O12  1  0.984  0.315  0.534  1.0
  O  O13  1  0.053  0.893  0.521  1.0
  O  O14  1  0.315  0.704  0.799  1.0
  O  O15  1  0.317  0.705  0.247  1.0
  O  O16  1  0.183  0.205  0.747  1.0
  O  O17  1  0.185  0.204  0.299  1.0
  O  O18  1  0.447  0.393  0.021  1.0
  O  O19  1  0.516  0.815  0.034  1.0
  O  O20  1  0.484  0.185  0.534  1.0
  O  O21  1  0.553  0.607  0.521  1.0
  O  O22  1  0.815  0.796  0.799  1.0
  O  O23  1  0.817  0.795  0.247  1.0
  O  O24  1  0.683  0.295  0.747  1.0
  O  O25  1  0.685  0.296  0.299  1.0
  O  O26  1  0.947  0.107  0.021  1.0
  O  O27  1  0.016  0.685  0.034  1.0
[/CIF]
.
The crystal structure described by LiMnPO4 crystallizes in the orthorhombic Pna2_1 space group. Li(1) is bonded in a 4-coordinate geometry to one O(2), one O(4), and two equivalent O(1) atoms. Mn(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), two equivalent O(3), and two equivalent O(4) atoms. P(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Li(1), one Mn(1), and one P(1) atom to form distorted corner-sharing OLi2MnP tetrahedra. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Li(1), one Mn(1), and one P(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to two equivalent Mn(1) and one P(1) atom. In the fourth O site, O(4) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), two equivalent Mn(1), and one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiMnPO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.676
_cell_length_b   5.681
_cell_length_c   5.546
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   89.991
_symmetry_Int_Tables_number   1
_cell_volume   336.349
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.040  0.372  0.925  1.0
  Li  Li1  1  0.460  0.872  0.425  1.0
  Li  Li2  1  0.540  0.128  0.925  1.0
  Li  Li3  1  0.960  0.628  0.425  1.0
  Mn  Mn4  1  0.175  0.923  0.023  1.0
  Mn  Mn5  1  0.325  0.423  0.523  1.0
  Mn  Mn6  1  0.675  0.577  0.023  1.0
  Mn  Mn7  1  0.825  0.078  0.523  1.0
  P  P8  1  0.100  0.146  0.519  1.0
  P  P9  1  0.400  0.646  0.019  1.0
  P  P10  1  0.600  0.354  0.519  1.0
  P  P11  1  0.900  0.854  0.019  1.0
  O  O12  1  0.984  0.315  0.534  1.0
  O  O13  1  0.053  0.893  0.521  1.0
  O  O14  1  0.315  0.704  0.799  1.0
  O  O15  1  0.317  0.705  0.247  1.0
  O  O16  1  0.183  0.205  0.747  1.0
  O  O17  1  0.185  0.204  0.299  1.0
  O  O18  1  0.447  0.393  0.021  1.0
  O  O19  1  0.516  0.815  0.034  1.0
  O  O20  1  0.484  0.185  0.534  1.0
  O  O21  1  0.553  0.607  0.521  1.0
  O  O22  1  0.815  0.796  0.799  1.0
  O  O23  1  0.817  0.795  0.247  1.0
  O  O24  1  0.683  0.295  0.747  1.0
  O  O25  1  0.685  0.296  0.299  1.0
  O  O26  1  0.947  0.107  0.021  1.0
  O  O27  1  0.016  0.685  0.034  1.0
[/CIF]
.