The material structure described by Li2VO2F is Caswellsilverite-derived structured and crystallizes in the triclinic P1 space group. There are eight inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(2), one O(5), one O(7), one F(1), and one F(4) atom to form LiO4F2 octahedra that share  a cornercorner with one Li(5)O3F3 octahedra,  a cornercorner with one Li(6)O3F3 octahedra,  a cornercorner with one Li(7)O3F3 octahedra,  a cornercorner with one Li(8)O3F3 octahedra, corners with two equivalent Li(2)O4F2 octahedra,  an edgeedge with one Li(5)O3F3 octahedra,  an edgeedge with one Li(6)O3F3 octahedra,  an edgeedge with one Li(7)O3F3 octahedra,  an edgeedge with one Li(8)O3F3 octahedra,  an edgeedge with one Li(3)O4F2 octahedra,  an edgeedge with one Li(4)O4F2 octahedra,  an edgeedge with one V(1)O5F octahedra,  an edgeedge with one V(2)O5F octahedra, edges with two equivalent V(3)O5F octahedra, and edges with two equivalent V(4)O5F octahedra. The corner-sharing octahedral tilt angles range from 2-7°. In the second Li site, Li(2) is bonded to one O(1), one O(2), one O(6), one O(8), one F(2), and one F(3) atom to form LiO4F2 octahedra that share  a cornercorner with one Li(5)O3F3 octahedra,  a cornercorner with one Li(6)O3F3 octahedra,  a cornercorner with one Li(7)O3F3 octahedra,  a cornercorner with one Li(8)O3F3 octahedra, corners with two equivalent Li(1)O4F2 octahedra,  an edgeedge with one Li(5)O3F3 octahedra,  an edgeedge with one Li(6)O3F3 octahedra,  an edgeedge with one Li(7)O3F3 octahedra,  an edgeedge with one Li(8)O3F3 octahedra,  an edgeedge with one Li(3)O4F2 octahedra,  an edgeedge with one Li(4)O4F2 octahedra,  an edgeedge with one V(3)O5F octahedra,  an edgeedge with one V(4)O5F octahedra, edges with two equivalent V(1)O5F octahedra, and edges with two equivalent V(2)O5F octahedra. The corner-sharing octahedral tilt angles range from 2-7°. In the third Li site, Li(3) is bonded to one O(3), one O(4), one O(5), one O(8), one F(1), and one F(3) atom to form LiO4F2 octahedra that share  a cornercorner with one V(1)O5F octahedra,  a cornercorner with one V(2)O5F octahedra,  a cornercorner with one V(3)O5F octahedra,  a cornercorner with one V(4)O5F octahedra, corners with two equivalent Li(4)O4F2 octahedra,  an edgeedge with one Li(5)O3F3 octahedra,  an edgeedge with one Li(8)O3F3 octahedra,  an edgeedge with one Li(1)O4F2 octahedra,  an edgeedge with one Li(2)O4F2 octahedra,  an edgeedge with one V(1)O5F octahedra,  an edgeedge with one V(2)O5F octahedra,  an edgeedge with one V(3)O5F octahedra,  an edgeedge with one V(4)O5F octahedra, edges with two equivalent Li(6)O3F3 octahedra, and edges with two equivalent Li(7)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 1-6°. In the fourth Li site, Li(4) is bonded to one O(3), one O(4), one O(6), one O(7), one F(2), and one F(4) atom to form LiO4F2 octahedra that share  a cornercorner with one V(1)O5F octahedra,  a cornercorner with one V(2)O5F octahedra,  a cornercorner with one V(3)O5F octahedra,  a cornercorner with one V(4)O5F octahedra, corners with two equivalent Li(3)O4F2 octahedra,  an edgeedge with one Li(6)O3F3 octahedra,  an edgeedge with one Li(7)O3F3 octahedra,  an edgeedge with one Li(1)O4F2 octahedra,  an edgeedge with one Li(2)O4F2 octahedra,  an edgeedge with one V(1)O5F octahedra,  an edgeedge with one V(2)O5F octahedra,  an edgeedge with one V(3)O5F octahedra,  an edgeedge with one V(4)O5F octahedra, edges with two equivalent Li(5)O3F3 octahedra, and edges with two equivalent Li(8)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 1-6°. In the fifth Li site, Li(5) is bonded to one O(1), one O(3), one O(6), one F(1), one F(2), and one F(4) atom to form LiO3F3 octahedra that share  a cornercorner with one Li(7)O3F3 octahedra,  a cornercorner with one Li(8)O3F3 octahedra,  a cornercorner with one Li(1)O4F2 octahedra,  a cornercorner with one Li(2)O4F2 octahedra, corners with two equivalent Li(6)O3F3 octahedra,  an edgeedge with one Li(7)O3F3 octahedra,  an edgeedge with one Li(8)O3F3 octahedra,  an edgeedge with one Li(1)O4F2 octahedra,  an edgeedge with one Li(2)O4F2 octahedra,  an edgeedge with one Li(3)O4F2 octahedra,  an edgeedge with one V(1)O5F octahedra,  an edgeedge with one V(2)O5F octahedra,  an edgeedge with one V(4)O5F octahedra, edges with two equivalent Li(4)O4F2 octahedra, and edges with two equivalent V(3)O5F octahedra. The corner-sharing octahedral tilt angles range from 2-7°. In the sixth Li site, Li(6) is bonded to one O(2), one O(4), one O(5), one F(1), one F(2), and one F(3) atom to form LiO3F3 octahedra that share  a cornercorner with one Li(7)O3F3 octahedra,  a cornercorner with one Li(8)O3F3 octahedra,  a cornercorner with one Li(1)O4F2 octahedra,  a cornercorner with one Li(2)O4F2 octahedra, corners with two equivalent Li(5)O3F3 octahedra,  an edgeedge with one Li(7)O3F3 octahedra,  an edgeedge with one Li(8)O3F3 octahedra,  an edgeedge with one Li(1)O4F2 octahedra,  an edgeedge with one Li(2)O4F2 octahedra,  an edgeedge with one Li(4)O4F2 octahedra,  an edgeedge with one V(2)O5F octahedra,  an edgeedge with one V(3)O5F octahedra,  an edgeedge with one V(4)O5F octahedra, edges with two equivalent Li(3)O4F2 octahedra, and edges with two equivalent V(1)O5F octahedra. The corner-sharing octahedral tilt angles range from 1-6°. In the seventh Li site, Li(7) is bonded to one O(2), one O(3), one O(8), one F(1), one F(3), and one F(4) atom to form LiO3F3 octahedra that share  a cornercorner with one Li(5)O3F3 octahedra,  a cornercorner with one Li(6)O3F3 octahedra,  a cornercorner with one Li(1)O4F2 octahedra,  a cornercorner with one Li(2)O4F2 octahedra, corners with two equivalent Li(8)O3F3 octahedra,  an edgeedge with one Li(5)O3F3 octahedra,  an edgeedge with one Li(6)O3F3 octahedra,  an edgeedge with one Li(1)O4F2 octahedra,  an edgeedge with one Li(2)O4F2 octahedra,  an edgeedge with one Li(4)O4F2 octahedra,  an edgeedge with one V(1)O5F octahedra,  an edgeedge with one V(2)O5F octahedra,  an edgeedge with one V(3)O5F octahedra, edges with two equivalent Li(3)O4F2 octahedra, and edges with two equivalent V(4)O5F octahedra. The corner-sharing octahedral tilt angles range from 2-7°. In the eighth Li site, Li(8) is bonded to one O(1), one O(4), one O(7), one F(2), one F(3), and one F(4) atom to form LiO3F3 octahedra that share  a cornercorner with one Li(5)O3F3 octahedra,  a cornercorner with one Li(6)O3F3 octahedra,  a cornercorner with one Li(1)O4F2 octahedra,  a cornercorner with one Li(2)O4F2 octahedra, corners with two equivalent Li(7)O3F3 octahedra,  an edgeedge with one Li(5)O3F3 octahedra,  an edgeedge with one Li(6)O3F3 octahedra,  an edgeedge with one Li(1)O4F2 octahedra,  an edgeedge with one Li(2)O4F2 octahedra,  an edgeedge with one Li(3)O4F2 octahedra,  an edgeedge with one V(1)O5F octahedra,  an edgeedge with one V(3)O5F octahedra,  an edgeedge with one V(4)O5F octahedra, edges with two equivalent Li(4)O4F2 octahedra, and edges with two equivalent V(2)O5F octahedra. The corner-sharing octahedral tilt angles range from 1-7°. There are four inequivalent V sites. In the first V site, V(1) is bonded to one O(2), one O(4), one O(5), one O(6), one O(8), and one F(2) atom to form VO5F octahedra that share  a cornercorner with one Li(3)O4F2 octahedra,  a cornercorner with one Li(4)O4F2 octahedra,  a cornercorner with one V(2)O5F octahedra,  a cornercorner with one V(4)O5F octahedra, corners with two equivalent V(3)O5F octahedra,  an edgeedge with one Li(5)O3F3 octahedra,  an edgeedge with one Li(7)O3F3 octahedra,  an edgeedge with one Li(8)O3F3 octahedra,  an edgeedge with one Li(1)O4F2 octahedra,  an edgeedge with one Li(3)O4F2 octahedra,  an edgeedge with one Li(4)O4F2 octahedra,  an edgeedge with one V(2)O5F octahedra,  an edgeedge with one V(4)O5F octahedra, edges with two equivalent Li(6)O3F3 octahedra, and edges with two equivalent Li(2)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 0-10°. In the second V site, V(2) is bonded to one O(1), one O(4), one O(6), one O(7), one O(8), and one F(3) atom to form VO5F octahedra that share  a cornercorner with one Li(3)O4F2 octahedra,  a cornercorner with one Li(4)O4F2 octahedra,  a cornercorner with one V(1)O5F octahedra,  a cornercorner with one V(3)O5F octahedra, corners with two equivalent V(4)O5F octahedra,  an edgeedge with one Li(5)O3F3 octahedra,  an edgeedge with one Li(6)O3F3 octahedra,  an edgeedge with one Li(7)O3F3 octahedra,  an edgeedge with one Li(1)O4F2 octahedra,  an edgeedge with one Li(3)O4F2 octahedra,  an edgeedge with one Li(4)O4F2 octahedra,  an edgeedge with one V(1)O5F octahedra,  an edgeedge with one V(3)O5F octahedra, edges with two equivalent Li(8)O3F3 octahedra, and edges with two equivalent Li(2)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 1-10°. In the third V site, V(3) is bonded to one O(1), one O(3), one O(5), one O(6), one O(7), and one F(1) atom to form VO5F octahedra that share  a cornercorner with one Li(3)O4F2 octahedra,  a cornercorner with one Li(4)O4F2 octahedra,  a cornercorner with one V(2)O5F octahedra,  a cornercorner with one V(4)O5F octahedra, corners with two equivalent V(1)O5F octahedra,  an edgeedge with one Li(6)O3F3 octahedra,  an edgeedge with one Li(7)O3F3 octahedra,  an edgeedge with one Li(8)O3F3 octahedra,  an edgeedge with one Li(2)O4F2 octahedra,  an edgeedge with one Li(3)O4F2 octahedra,  an edgeedge with one Li(4)O4F2 octahedra,  an edgeedge with one V(2)O5F octahedra,  an edgeedge with one V(4)O5F octahedra, edges with two equivalent Li(5)O3F3 octahedra, and edges with two equivalent Li(1)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 1-10°. In the fourth V site, V(4) is bonded to one O(2), one O(3), one O(5), one O(7), one O(8), and one F(4) atom to form VO5F octahedra that share  a cornercorner with one Li(3)O4F2 octahedra,  a cornercorner with one Li(4)O4F2 octahedra,  a cornercorner with one V(1)O5F octahedra,  a cornercorner with one V(3)O5F octahedra, corners with two equivalent V(2)O5F octahedra,  an edgeedge with one Li(5)O3F3 octahedra,  an edgeedge with one Li(6)O3F3 octahedra,  an edgeedge with one Li(8)O3F3 octahedra,  an edgeedge with one Li(2)O4F2 octahedra,  an edgeedge with one Li(3)O4F2 octahedra,  an edgeedge with one Li(4)O4F2 octahedra,  an edgeedge with one V(1)O5F octahedra,  an edgeedge with one V(3)O5F octahedra, edges with two equivalent Li(7)O3F3 octahedra, and edges with two equivalent Li(1)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 0-10°. There are eight inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), one Li(2), one Li(5), one Li(8), one V(2), and one V(3) atom to form OLi4V2 octahedra that share  a cornercorner with one F(1)Li5V octahedra,  a cornercorner with one F(2)Li5V octahedra,  a cornercorner with one F(3)Li5V octahedra,  a cornercorner with one F(4)Li5V octahedra, corners with two equivalent O(2)Li4V2 octahedra,  an edgeedge with one O(5)Li3V3 octahedra,  an edgeedge with one O(8)Li3V3 octahedra,  an edgeedge with one O(3)Li4V2 octahedra,  an edgeedge with one O(4)Li4V2 octahedra,  an edgeedge with one F(1)Li5V octahedra,  an edgeedge with one F(2)Li5V octahedra,  an edgeedge with one F(3)Li5V octahedra,  an edgeedge with one F(4)Li5V octahedra, edges with two equivalent O(6)Li3V3 octahedra, and edges with two equivalent O(7)Li3V3 octahedra. The corner-sharing octahedral tilt angles range from 2-7°. In the second O site, O(2) is bonded to one Li(1), one Li(2), one Li(6), one Li(7), one V(1), and one V(4) atom to form OLi4V2 octahedra that share  a cornercorner with one F(1)Li5V octahedra,  a cornercorner with one F(2)Li5V octahedra,  a cornercorner with one F(3)Li5V octahedra,  a cornercorner with one F(4)Li5V octahedra, corners with two equivalent O(1)Li4V2 octahedra,  an edgeedge with one O(6)Li3V3 octahedra,  an edgeedge with one O(7)Li3V3 octahedra,  an edgeedge with one O(3)Li4V2 octahedra,  an edgeedge with one O(4)Li4V2 octahedra,  an edgeedge with one F(1)Li5V octahedra,  an edgeedge with one F(2)Li5V octahedra,  an edgeedge with one F(3)Li5V octahedra,  an edgeedge with one F(4)Li5V octahedra, edges with two equivalent O(5)Li3V3 octahedra, and edges with two equivalent O(8)Li3V3 octahedra. The corner-sharing octahedral tilt angles range from 2-5°. In the third O site, O(3) is bonded to one Li(3), one Li(4), one Li(5), one Li(7), one V(3), and one V(4) atom to form OLi4V2 octahedra that share  a cornercorner with one O(5)Li3V3 octahedra,  a cornercorner with one O(6)Li3V3 octahedra,  a cornercorner with one O(7)Li3V3 octahedra,  a cornercorner with one O(8)Li3V3 octahedra, corners with two equivalent O(4)Li4V2 octahedra,  an edgeedge with one O(5)Li3V3 octahedra,  an edgeedge with one O(6)Li3V3 octahedra,  an edgeedge with one O(7)Li3V3 octahedra,  an edgeedge with one O(8)Li3V3 octahedra,  an edgeedge with one O(1)Li4V2 octahedra,  an edgeedge with one O(2)Li4V2 octahedra,  an edgeedge with one F(2)Li5V octahedra,  an edgeedge with one F(3)Li5V octahedra, edges with two equivalent F(1)Li5V octahedra, and edges with two equivalent F(4)Li5V octahedra. The corner-sharing octahedral tilt angles range from 1-10°. In the fourth O site, O(4) is bonded to one Li(3), one Li(4), one Li(6), one Li(8), one V(1), and one V(2) atom to form OLi4V2 octahedra that share  a cornercorner with one O(5)Li3V3 octahedra,  a cornercorner with one O(6)Li3V3 octahedra,  a cornercorner with one O(7)Li3V3 octahedra,  a cornercorner with one O(8)Li3V3 octahedra, corners with two equivalent O(3)Li4V2 octahedra,  an edgeedge with one O(5)Li3V3 octahedra,  an edgeedge with one O(6)Li3V3 octahedra,  an edgeedge with one O(7)Li3V3 octahedra,  an edgeedge with one O(8)Li3V3 octahedra,  an edgeedge with one O(1)Li4V2 octahedra,  an edgeedge with one O(2)Li4V2 octahedra,  an edgeedge with one F(1)Li5V octahedra,  an edgeedge with one F(4)Li5V octahedra, edges with two equivalent F(2)Li5V octahedra, and edges with two equivalent F(3)Li5V octahedra. The corner-sharing octahedral tilt angles range from 1-10°. In the fifth O site, O(5) is bonded to one Li(1), one Li(3), one Li(6), one V(1), one V(3), and one V(4) atom to form OLi3V3 octahedra that share  a cornercorner with one O(7)Li3V3 octahedra,  a cornercorner with one O(8)Li3V3 octahedra,  a cornercorner with one O(3)Li4V2 octahedra,  a cornercorner with one O(4)Li4V2 octahedra, corners with two equivalent O(6)Li3V3 octahedra,  an edgeedge with one O(7)Li3V3 octahedra,  an edgeedge with one O(8)Li3V3 octahedra,  an edgeedge with one O(1)Li4V2 octahedra,  an edgeedge with one O(3)Li4V2 octahedra,  an edgeedge with one O(4)Li4V2 octahedra,  an edgeedge with one F(2)Li5V octahedra,  an edgeedge with one F(3)Li5V octahedra,  an edgeedge with one F(4)Li5V octahedra, edges with two equivalent O(2)Li4V2 octahedra, and edges with two equivalent F(1)Li5V octahedra. The corner-sharing octahedral tilt angles range from 1-11°. In the sixth O site, O(6) is bonded to one Li(2), one Li(4), one Li(5), one V(1), one V(2), and one V(3) atom to form OLi3V3 octahedra that share  a cornercorner with one O(7)Li3V3 octahedra,  a cornercorner with one O(8)Li3V3 octahedra,  a cornercorner with one O(3)Li4V2 octahedra,  a cornercorner with one O(4)Li4V2 octahedra, corners with two equivalent O(5)Li3V3 octahedra,  an edgeedge with one O(7)Li3V3 octahedra,  an edgeedge with one O(8)Li3V3 octahedra,  an edgeedge with one O(2)Li4V2 octahedra,  an edgeedge with one O(3)Li4V2 octahedra,  an edgeedge with one O(4)Li4V2 octahedra,  an edgeedge with one F(1)Li5V octahedra,  an edgeedge with one F(3)Li5V octahedra,  an edgeedge with one F(4)Li5V octahedra, edges with two equivalent O(1)Li4V2 octahedra, and edges with two equivalent F(2)Li5V octahedra. The corner-sharing octahedral tilt angles range from 1-11°. In the seventh O site, O(7) is bonded to one Li(1), one Li(4), one Li(8), one V(2), one V(3), and one V(4) atom to form OLi3V3 octahedra that share  a cornercorner with one O(5)Li3V3 octahedra,  a cornercorner with one O(6)Li3V3 octahedra,  a cornercorner with one O(3)Li4V2 octahedra,  a cornercorner with one O(4)Li4V2 octahedra, corners with two equivalent O(8)Li3V3 octahedra,  an edgeedge with one O(5)Li3V3 octahedra,  an edgeedge with one O(6)Li3V3 octahedra,  an edgeedge with one O(2)Li4V2 octahedra,  an edgeedge with one O(3)Li4V2 octahedra,  an edgeedge with one O(4)Li4V2 octahedra,  an edgeedge with one F(1)Li5V octahedra,  an edgeedge with one F(2)Li5V octahedra,  an edgeedge with one F(3)Li5V octahedra, edges with two equivalent O(1)Li4V2 octahedra, and edges with two equivalent F(4)Li5V octahedra. The corner-sharing octahedral tilt angles range from 1-10°. In the eighth O site, O(8) is bonded to one Li(2), one Li(3), one Li(7), one V(1), one V(2), and one V(4) atom to form OLi3V3 octahedra that share  a cornercorner with one O(5)Li3V3 octahedra,  a cornercorner with one O(6)Li3V3 octahedra,  a cornercorner with one O(3)Li4V2 octahedra,  a cornercorner with one O(4)Li4V2 octahedra, corners with two equivalent O(7)Li3V3 octahedra,  an edgeedge with one O(5)Li3V3 octahedra,  an edgeedge with one O(6)Li3V3 octahedra,  an edgeedge with one O(1)Li4V2 octahedra,  an edgeedge with one O(3)Li4V2 octahedra,  an edgeedge with one O(4)Li4V2 octahedra,  an edgeedge with one F(1)Li5V octahedra,  an edgeedge with one F(2)Li5V octahedra,  an edgeedge with one F(4)Li5V octahedra, edges with two equivalent O(2)Li4V2 octahedra, and edges with two equivalent F(3)Li5V octahedra. The corner-sharing octahedral tilt angles range from 1-10°. There are four inequivalent F sites. In the first F site, F(1) is bonded to one Li(1), one Li(3), one Li(5), one Li(6), one Li(7), and one V(3) atom to form FLi5V octahedra that share  a cornercorner with one O(1)Li4V2 octahedra,  a cornercorner with one O(2)Li4V2 octahedra,  a cornercorner with one F(3)Li5V octahedra,  a cornercorner with one F(4)Li5V octahedra, corners with two equivalent F(2)Li5V octahedra,  an edgeedge with one O(6)Li3V3 octahedra,  an edgeedge with one O(7)Li3V3 octahedra,  an edgeedge with one O(8)Li3V3 octahedra,  an edgeedge with one O(1)Li4V2 octahedra,  an edgeedge with one O(2)Li4V2 octahedra,  an edgeedge with one O(4)Li4V2 octahedra,  an edgeedge with one F(3)Li5V octahedra,  an edgeedge with one F(4)Li5V octahedra, edges with two equivalent O(5)Li3V3 octahedra, and edges with two equivalent O(3)Li4V2 octahedra. The corner-sharing octahedral tilt angles range from 1-6°. In the second F site, F(2) is bonded to one Li(2), one Li(4), one Li(5), one Li(6), one Li(8), and one V(1) atom to form FLi5V octahedra that share  a cornercorner with one O(1)Li4V2 octahedra,  a cornercorner with one O(2)Li4V2 octahedra,  a cornercorner with one F(3)Li5V octahedra,  a cornercorner with one F(4)Li5V octahedra, corners with two equivalent F(1)Li5V octahedra,  an edgeedge with one O(5)Li3V3 octahedra,  an edgeedge with one O(7)Li3V3 octahedra,  an edgeedge with one O(8)Li3V3 octahedra,  an edgeedge with one O(1)Li4V2 octahedra,  an edgeedge with one O(2)Li4V2 octahedra,  an edgeedge with one O(3)Li4V2 octahedra,  an edgeedge with one F(3)Li5V octahedra,  an edgeedge with one F(4)Li5V octahedra, edges with two equivalent O(6)Li3V3 octahedra, and edges with two equivalent O(4)Li4V2 octahedra. The corner-sharing octahedral tilt angles range from 1-6°. In the third F site, F(3) is bonded to one Li(2), one Li(3), one Li(6), one Li(7), one Li(8), and one V(2) atom to form FLi5V octahedra that share  a cornercorner with one O(1)Li4V2 octahedra,  a cornercorner with one O(2)Li4V2 octahedra,  a cornercorner with one F(1)Li5V octahedra,  a cornercorner with one F(2)Li5V octahedra, corners with two equivalent F(4)Li5V octahedra,  an edgeedge with one O(5)Li3V3 octahedra,  an edgeedge with one O(6)Li3V3 octahedra,  an edgeedge with one O(7)Li3V3 octahedra,  an edgeedge with one O(1)Li4V2 octahedra,  an edgeedge with one O(2)Li4V2 octahedra,  an edgeedge with one O(3)Li4V2 octahedra,  an edgeedge with one F(1)Li5V octahedra,  an edgeedge with one F(2)Li5V octahedra, edges with two equivalent O(8)Li3V3 octahedra, and edges with two equivalent O(4)Li4V2 octahedra. The corner-sharing octahedral tilt angles range from 1-6°. In the fourth F site, F(4) is bonded to one Li(1), one Li(4), one Li(5), one Li(7), one Li(8), and one V(4) atom to form FLi5V octahedra that share  a cornercorner with one O(1)Li4V2 octahedra,  a cornercorner with one O(2)Li4V2 octahedra,  a cornercorner with one F(1)Li5V octahedra,  a cornercorner with one F(2)Li5V octahedra, corners with two equivalent F(3)Li5V octahedra,  an edgeedge with one O(5)Li3V3 octahedra,  an edgeedge with one O(6)Li3V3 octahedra,  an edgeedge with one O(8)Li3V3 octahedra,  an edgeedge with one O(1)Li4V2 octahedra,  an edgeedge with one O(2)Li4V2 octahedra,  an edgeedge with one O(4)Li4V2 octahedra,  an edgeedge with one F(1)Li5V octahedra,  an edgeedge with one F(2)Li5V octahedra, edges with two equivalent O(7)Li3V3 octahedra, and edges with two equivalent O(3)Li4V2 octahedra. The corner-sharing octahedral tilt angles range from 1-7°. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li2VO2F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.157
_cell_length_b   5.167
_cell_length_c   5.878
_cell_angle_alpha   108.892
_cell_angle_beta   90.036
_cell_angle_gamma   113.701
_symmetry_Int_Tables_number   1
_cell_volume   108.118
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  F  F0  1  0.487  0.973  0.499  1.0
  F  F1  1  0.845  0.690  0.170  1.0
  Li  Li2  1  0.667  0.334  0.833  1.0
  Li  Li3  1  0.668  0.337  0.335  1.0
  Li  Li4  1  0.998  0.997  0.506  1.0
  Li  Li5  1  0.334  0.668  0.162  1.0
  O  O6  1  0.170  0.340  0.831  1.0
  O  O7  1  0.169  0.339  0.337  1.0
  O  O8  1  0.835  0.671  0.675  1.0
  O  O9  1  0.496  0.992  0.985  1.0
  V  V10  1  0.314  0.630  0.665  1.0
  V  V11  1  0.017  0.029  0.003  1.0
[/CIF]
.
The material structure described by Li2VO2F is Caswellsilverite-derived structured and crystallizes in the triclinic P1 space group. There are eight inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(2), one O(5), one O(7), one F(1), and one F(4) atom to form LiO4F2 octahedra that share  a cornercorner with one Li(5)O3F3 octahedra,  a cornercorner with one Li(6)O3F3 octahedra,  a cornercorner with one Li(7)O3F3 octahedra,  a cornercorner with one Li(8)O3F3 octahedra, corners with two equivalent Li(2)O4F2 octahedra,  an edgeedge with one Li(5)O3F3 octahedra,  an edgeedge with one Li(6)O3F3 octahedra,  an edgeedge with one Li(7)O3F3 octahedra,  an edgeedge with one Li(8)O3F3 octahedra,  an edgeedge with one Li(3)O4F2 octahedra,  an edgeedge with one Li(4)O4F2 octahedra,  an edgeedge with one V(1)O5F octahedra,  an edgeedge with one V(2)O5F octahedra, edges with two equivalent V(3)O5F octahedra, and edges with two equivalent V(4)O5F octahedra. The corner-sharing octahedral tilt angles range from 2-7°. In the second Li site, Li(2) is bonded to one O(1), one O(2), one O(6), one O(8), one F(2), and one F(3) atom to form LiO4F2 octahedra that share  a cornercorner with one Li(5)O3F3 octahedra,  a cornercorner with one Li(6)O3F3 octahedra,  a cornercorner with one Li(7)O3F3 octahedra,  a cornercorner with one Li(8)O3F3 octahedra, corners with two equivalent Li(1)O4F2 octahedra,  an edgeedge with one Li(5)O3F3 octahedra,  an edgeedge with one Li(6)O3F3 octahedra,  an edgeedge with one Li(7)O3F3 octahedra,  an edgeedge with one Li(8)O3F3 octahedra,  an edgeedge with one Li(3)O4F2 octahedra,  an edgeedge with one Li(4)O4F2 octahedra,  an edgeedge with one V(3)O5F octahedra,  an edgeedge with one V(4)O5F octahedra, edges with two equivalent V(1)O5F octahedra, and edges with two equivalent V(2)O5F octahedra. The corner-sharing octahedral tilt angles range from 2-7°. In the third Li site, Li(3) is bonded to one O(3), one O(4), one O(5), one O(8), one F(1), and one F(3) atom to form LiO4F2 octahedra that share  a cornercorner with one V(1)O5F octahedra,  a cornercorner with one V(2)O5F octahedra,  a cornercorner with one V(3)O5F octahedra,  a cornercorner with one V(4)O5F octahedra, corners with two equivalent Li(4)O4F2 octahedra,  an edgeedge with one Li(5)O3F3 octahedra,  an edgeedge with one Li(8)O3F3 octahedra,  an edgeedge with one Li(1)O4F2 octahedra,  an edgeedge with one Li(2)O4F2 octahedra,  an edgeedge with one V(1)O5F octahedra,  an edgeedge with one V(2)O5F octahedra,  an edgeedge with one V(3)O5F octahedra,  an edgeedge with one V(4)O5F octahedra, edges with two equivalent Li(6)O3F3 octahedra, and edges with two equivalent Li(7)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 1-6°. In the fourth Li site, Li(4) is bonded to one O(3), one O(4), one O(6), one O(7), one F(2), and one F(4) atom to form LiO4F2 octahedra that share  a cornercorner with one V(1)O5F octahedra,  a cornercorner with one V(2)O5F octahedra,  a cornercorner with one V(3)O5F octahedra,  a cornercorner with one V(4)O5F octahedra, corners with two equivalent Li(3)O4F2 octahedra,  an edgeedge with one Li(6)O3F3 octahedra,  an edgeedge with one Li(7)O3F3 octahedra,  an edgeedge with one Li(1)O4F2 octahedra,  an edgeedge with one Li(2)O4F2 octahedra,  an edgeedge with one V(1)O5F octahedra,  an edgeedge with one V(2)O5F octahedra,  an edgeedge with one V(3)O5F octahedra,  an edgeedge with one V(4)O5F octahedra, edges with two equivalent Li(5)O3F3 octahedra, and edges with two equivalent Li(8)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 1-6°. In the fifth Li site, Li(5) is bonded to one O(1), one O(3), one O(6), one F(1), one F(2), and one F(4) atom to form LiO3F3 octahedra that share  a cornercorner with one Li(7)O3F3 octahedra,  a cornercorner with one Li(8)O3F3 octahedra,  a cornercorner with one Li(1)O4F2 octahedra,  a cornercorner with one Li(2)O4F2 octahedra, corners with two equivalent Li(6)O3F3 octahedra,  an edgeedge with one Li(7)O3F3 octahedra,  an edgeedge with one Li(8)O3F3 octahedra,  an edgeedge with one Li(1)O4F2 octahedra,  an edgeedge with one Li(2)O4F2 octahedra,  an edgeedge with one Li(3)O4F2 octahedra,  an edgeedge with one V(1)O5F octahedra,  an edgeedge with one V(2)O5F octahedra,  an edgeedge with one V(4)O5F octahedra, edges with two equivalent Li(4)O4F2 octahedra, and edges with two equivalent V(3)O5F octahedra. The corner-sharing octahedral tilt angles range from 2-7°. In the sixth Li site, Li(6) is bonded to one O(2), one O(4), one O(5), one F(1), one F(2), and one F(3) atom to form LiO3F3 octahedra that share  a cornercorner with one Li(7)O3F3 octahedra,  a cornercorner with one Li(8)O3F3 octahedra,  a cornercorner with one Li(1)O4F2 octahedra,  a cornercorner with one Li(2)O4F2 octahedra, corners with two equivalent Li(5)O3F3 octahedra,  an edgeedge with one Li(7)O3F3 octahedra,  an edgeedge with one Li(8)O3F3 octahedra,  an edgeedge with one Li(1)O4F2 octahedra,  an edgeedge with one Li(2)O4F2 octahedra,  an edgeedge with one Li(4)O4F2 octahedra,  an edgeedge with one V(2)O5F octahedra,  an edgeedge with one V(3)O5F octahedra,  an edgeedge with one V(4)O5F octahedra, edges with two equivalent Li(3)O4F2 octahedra, and edges with two equivalent V(1)O5F octahedra. The corner-sharing octahedral tilt angles range from 1-6°. In the seventh Li site, Li(7) is bonded to one O(2), one O(3), one O(8), one F(1), one F(3), and one F(4) atom to form LiO3F3 octahedra that share  a cornercorner with one Li(5)O3F3 octahedra,  a cornercorner with one Li(6)O3F3 octahedra,  a cornercorner with one Li(1)O4F2 octahedra,  a cornercorner with one Li(2)O4F2 octahedra, corners with two equivalent Li(8)O3F3 octahedra,  an edgeedge with one Li(5)O3F3 octahedra,  an edgeedge with one Li(6)O3F3 octahedra,  an edgeedge with one Li(1)O4F2 octahedra,  an edgeedge with one Li(2)O4F2 octahedra,  an edgeedge with one Li(4)O4F2 octahedra,  an edgeedge with one V(1)O5F octahedra,  an edgeedge with one V(2)O5F octahedra,  an edgeedge with one V(3)O5F octahedra, edges with two equivalent Li(3)O4F2 octahedra, and edges with two equivalent V(4)O5F octahedra. The corner-sharing octahedral tilt angles range from 2-7°. In the eighth Li site, Li(8) is bonded to one O(1), one O(4), one O(7), one F(2), one F(3), and one F(4) atom to form LiO3F3 octahedra that share  a cornercorner with one Li(5)O3F3 octahedra,  a cornercorner with one Li(6)O3F3 octahedra,  a cornercorner with one Li(1)O4F2 octahedra,  a cornercorner with one Li(2)O4F2 octahedra, corners with two equivalent Li(7)O3F3 octahedra,  an edgeedge with one Li(5)O3F3 octahedra,  an edgeedge with one Li(6)O3F3 octahedra,  an edgeedge with one Li(1)O4F2 octahedra,  an edgeedge with one Li(2)O4F2 octahedra,  an edgeedge with one Li(3)O4F2 octahedra,  an edgeedge with one V(1)O5F octahedra,  an edgeedge with one V(3)O5F octahedra,  an edgeedge with one V(4)O5F octahedra, edges with two equivalent Li(4)O4F2 octahedra, and edges with two equivalent V(2)O5F octahedra. The corner-sharing octahedral tilt angles range from 1-7°. There are four inequivalent V sites. In the first V site, V(1) is bonded to one O(2), one O(4), one O(5), one O(6), one O(8), and one F(2) atom to form VO5F octahedra that share  a cornercorner with one Li(3)O4F2 octahedra,  a cornercorner with one Li(4)O4F2 octahedra,  a cornercorner with one V(2)O5F octahedra,  a cornercorner with one V(4)O5F octahedra, corners with two equivalent V(3)O5F octahedra,  an edgeedge with one Li(5)O3F3 octahedra,  an edgeedge with one Li(7)O3F3 octahedra,  an edgeedge with one Li(8)O3F3 octahedra,  an edgeedge with one Li(1)O4F2 octahedra,  an edgeedge with one Li(3)O4F2 octahedra,  an edgeedge with one Li(4)O4F2 octahedra,  an edgeedge with one V(2)O5F octahedra,  an edgeedge with one V(4)O5F octahedra, edges with two equivalent Li(6)O3F3 octahedra, and edges with two equivalent Li(2)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 0-10°. In the second V site, V(2) is bonded to one O(1), one O(4), one O(6), one O(7), one O(8), and one F(3) atom to form VO5F octahedra that share  a cornercorner with one Li(3)O4F2 octahedra,  a cornercorner with one Li(4)O4F2 octahedra,  a cornercorner with one V(1)O5F octahedra,  a cornercorner with one V(3)O5F octahedra, corners with two equivalent V(4)O5F octahedra,  an edgeedge with one Li(5)O3F3 octahedra,  an edgeedge with one Li(6)O3F3 octahedra,  an edgeedge with one Li(7)O3F3 octahedra,  an edgeedge with one Li(1)O4F2 octahedra,  an edgeedge with one Li(3)O4F2 octahedra,  an edgeedge with one Li(4)O4F2 octahedra,  an edgeedge with one V(1)O5F octahedra,  an edgeedge with one V(3)O5F octahedra, edges with two equivalent Li(8)O3F3 octahedra, and edges with two equivalent Li(2)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 1-10°. In the third V site, V(3) is bonded to one O(1), one O(3), one O(5), one O(6), one O(7), and one F(1) atom to form VO5F octahedra that share  a cornercorner with one Li(3)O4F2 octahedra,  a cornercorner with one Li(4)O4F2 octahedra,  a cornercorner with one V(2)O5F octahedra,  a cornercorner with one V(4)O5F octahedra, corners with two equivalent V(1)O5F octahedra,  an edgeedge with one Li(6)O3F3 octahedra,  an edgeedge with one Li(7)O3F3 octahedra,  an edgeedge with one Li(8)O3F3 octahedra,  an edgeedge with one Li(2)O4F2 octahedra,  an edgeedge with one Li(3)O4F2 octahedra,  an edgeedge with one Li(4)O4F2 octahedra,  an edgeedge with one V(2)O5F octahedra,  an edgeedge with one V(4)O5F octahedra, edges with two equivalent Li(5)O3F3 octahedra, and edges with two equivalent Li(1)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 1-10°. In the fourth V site, V(4) is bonded to one O(2), one O(3), one O(5), one O(7), one O(8), and one F(4) atom to form VO5F octahedra that share  a cornercorner with one Li(3)O4F2 octahedra,  a cornercorner with one Li(4)O4F2 octahedra,  a cornercorner with one V(1)O5F octahedra,  a cornercorner with one V(3)O5F octahedra, corners with two equivalent V(2)O5F octahedra,  an edgeedge with one Li(5)O3F3 octahedra,  an edgeedge with one Li(6)O3F3 octahedra,  an edgeedge with one Li(8)O3F3 octahedra,  an edgeedge with one Li(2)O4F2 octahedra,  an edgeedge with one Li(3)O4F2 octahedra,  an edgeedge with one Li(4)O4F2 octahedra,  an edgeedge with one V(1)O5F octahedra,  an edgeedge with one V(3)O5F octahedra, edges with two equivalent Li(7)O3F3 octahedra, and edges with two equivalent Li(1)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 0-10°. There are eight inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), one Li(2), one Li(5), one Li(8), one V(2), and one V(3) atom to form OLi4V2 octahedra that share  a cornercorner with one F(1)Li5V octahedra,  a cornercorner with one F(2)Li5V octahedra,  a cornercorner with one F(3)Li5V octahedra,  a cornercorner with one F(4)Li5V octahedra, corners with two equivalent O(2)Li4V2 octahedra,  an edgeedge with one O(5)Li3V3 octahedra,  an edgeedge with one O(8)Li3V3 octahedra,  an edgeedge with one O(3)Li4V2 octahedra,  an edgeedge with one O(4)Li4V2 octahedra,  an edgeedge with one F(1)Li5V octahedra,  an edgeedge with one F(2)Li5V octahedra,  an edgeedge with one F(3)Li5V octahedra,  an edgeedge with one F(4)Li5V octahedra, edges with two equivalent O(6)Li3V3 octahedra, and edges with two equivalent O(7)Li3V3 octahedra. The corner-sharing octahedral tilt angles range from 2-7°. In the second O site, O(2) is bonded to one Li(1), one Li(2), one Li(6), one Li(7), one V(1), and one V(4) atom to form OLi4V2 octahedra that share  a cornercorner with one F(1)Li5V octahedra,  a cornercorner with one F(2)Li5V octahedra,  a cornercorner with one F(3)Li5V octahedra,  a cornercorner with one F(4)Li5V octahedra, corners with two equivalent O(1)Li4V2 octahedra,  an edgeedge with one O(6)Li3V3 octahedra,  an edgeedge with one O(7)Li3V3 octahedra,  an edgeedge with one O(3)Li4V2 octahedra,  an edgeedge with one O(4)Li4V2 octahedra,  an edgeedge with one F(1)Li5V octahedra,  an edgeedge with one F(2)Li5V octahedra,  an edgeedge with one F(3)Li5V octahedra,  an edgeedge with one F(4)Li5V octahedra, edges with two equivalent O(5)Li3V3 octahedra, and edges with two equivalent O(8)Li3V3 octahedra. The corner-sharing octahedral tilt angles range from 2-5°. In the third O site, O(3) is bonded to one Li(3), one Li(4), one Li(5), one Li(7), one V(3), and one V(4) atom to form OLi4V2 octahedra that share  a cornercorner with one O(5)Li3V3 octahedra,  a cornercorner with one O(6)Li3V3 octahedra,  a cornercorner with one O(7)Li3V3 octahedra,  a cornercorner with one O(8)Li3V3 octahedra, corners with two equivalent O(4)Li4V2 octahedra,  an edgeedge with one O(5)Li3V3 octahedra,  an edgeedge with one O(6)Li3V3 octahedra,  an edgeedge with one O(7)Li3V3 octahedra,  an edgeedge with one O(8)Li3V3 octahedra,  an edgeedge with one O(1)Li4V2 octahedra,  an edgeedge with one O(2)Li4V2 octahedra,  an edgeedge with one F(2)Li5V octahedra,  an edgeedge with one F(3)Li5V octahedra, edges with two equivalent F(1)Li5V octahedra, and edges with two equivalent F(4)Li5V octahedra. The corner-sharing octahedral tilt angles range from 1-10°. In the fourth O site, O(4) is bonded to one Li(3), one Li(4), one Li(6), one Li(8), one V(1), and one V(2) atom to form OLi4V2 octahedra that share  a cornercorner with one O(5)Li3V3 octahedra,  a cornercorner with one O(6)Li3V3 octahedra,  a cornercorner with one O(7)Li3V3 octahedra,  a cornercorner with one O(8)Li3V3 octahedra, corners with two equivalent O(3)Li4V2 octahedra,  an edgeedge with one O(5)Li3V3 octahedra,  an edgeedge with one O(6)Li3V3 octahedra,  an edgeedge with one O(7)Li3V3 octahedra,  an edgeedge with one O(8)Li3V3 octahedra,  an edgeedge with one O(1)Li4V2 octahedra,  an edgeedge with one O(2)Li4V2 octahedra,  an edgeedge with one F(1)Li5V octahedra,  an edgeedge with one F(4)Li5V octahedra, edges with two equivalent F(2)Li5V octahedra, and edges with two equivalent F(3)Li5V octahedra. The corner-sharing octahedral tilt angles range from 1-10°. In the fifth O site, O(5) is bonded to one Li(1), one Li(3), one Li(6), one V(1), one V(3), and one V(4) atom to form OLi3V3 octahedra that share  a cornercorner with one O(7)Li3V3 octahedra,  a cornercorner with one O(8)Li3V3 octahedra,  a cornercorner with one O(3)Li4V2 octahedra,  a cornercorner with one O(4)Li4V2 octahedra, corners with two equivalent O(6)Li3V3 octahedra,  an edgeedge with one O(7)Li3V3 octahedra,  an edgeedge with one O(8)Li3V3 octahedra,  an edgeedge with one O(1)Li4V2 octahedra,  an edgeedge with one O(3)Li4V2 octahedra,  an edgeedge with one O(4)Li4V2 octahedra,  an edgeedge with one F(2)Li5V octahedra,  an edgeedge with one F(3)Li5V octahedra,  an edgeedge with one F(4)Li5V octahedra, edges with two equivalent O(2)Li4V2 octahedra, and edges with two equivalent F(1)Li5V octahedra. The corner-sharing octahedral tilt angles range from 1-11°. In the sixth O site, O(6) is bonded to one Li(2), one Li(4), one Li(5), one V(1), one V(2), and one V(3) atom to form OLi3V3 octahedra that share  a cornercorner with one O(7)Li3V3 octahedra,  a cornercorner with one O(8)Li3V3 octahedra,  a cornercorner with one O(3)Li4V2 octahedra,  a cornercorner with one O(4)Li4V2 octahedra, corners with two equivalent O(5)Li3V3 octahedra,  an edgeedge with one O(7)Li3V3 octahedra,  an edgeedge with one O(8)Li3V3 octahedra,  an edgeedge with one O(2)Li4V2 octahedra,  an edgeedge with one O(3)Li4V2 octahedra,  an edgeedge with one O(4)Li4V2 octahedra,  an edgeedge with one F(1)Li5V octahedra,  an edgeedge with one F(3)Li5V octahedra,  an edgeedge with one F(4)Li5V octahedra, edges with two equivalent O(1)Li4V2 octahedra, and edges with two equivalent F(2)Li5V octahedra. The corner-sharing octahedral tilt angles range from 1-11°. In the seventh O site, O(7) is bonded to one Li(1), one Li(4), one Li(8), one V(2), one V(3), and one V(4) atom to form OLi3V3 octahedra that share  a cornercorner with one O(5)Li3V3 octahedra,  a cornercorner with one O(6)Li3V3 octahedra,  a cornercorner with one O(3)Li4V2 octahedra,  a cornercorner with one O(4)Li4V2 octahedra, corners with two equivalent O(8)Li3V3 octahedra,  an edgeedge with one O(5)Li3V3 octahedra,  an edgeedge with one O(6)Li3V3 octahedra,  an edgeedge with one O(2)Li4V2 octahedra,  an edgeedge with one O(3)Li4V2 octahedra,  an edgeedge with one O(4)Li4V2 octahedra,  an edgeedge with one F(1)Li5V octahedra,  an edgeedge with one F(2)Li5V octahedra,  an edgeedge with one F(3)Li5V octahedra, edges with two equivalent O(1)Li4V2 octahedra, and edges with two equivalent F(4)Li5V octahedra. The corner-sharing octahedral tilt angles range from 1-10°. In the eighth O site, O(8) is bonded to one Li(2), one Li(3), one Li(7), one V(1), one V(2), and one V(4) atom to form OLi3V3 octahedra that share  a cornercorner with one O(5)Li3V3 octahedra,  a cornercorner with one O(6)Li3V3 octahedra,  a cornercorner with one O(3)Li4V2 octahedra,  a cornercorner with one O(4)Li4V2 octahedra, corners with two equivalent O(7)Li3V3 octahedra,  an edgeedge with one O(5)Li3V3 octahedra,  an edgeedge with one O(6)Li3V3 octahedra,  an edgeedge with one O(1)Li4V2 octahedra,  an edgeedge with one O(3)Li4V2 octahedra,  an edgeedge with one O(4)Li4V2 octahedra,  an edgeedge with one F(1)Li5V octahedra,  an edgeedge with one F(2)Li5V octahedra,  an edgeedge with one F(4)Li5V octahedra, edges with two equivalent O(2)Li4V2 octahedra, and edges with two equivalent F(3)Li5V octahedra. The corner-sharing octahedral tilt angles range from 1-10°. There are four inequivalent F sites. In the first F site, F(1) is bonded to one Li(1), one Li(3), one Li(5), one Li(6), one Li(7), and one V(3) atom to form FLi5V octahedra that share  a cornercorner with one O(1)Li4V2 octahedra,  a cornercorner with one O(2)Li4V2 octahedra,  a cornercorner with one F(3)Li5V octahedra,  a cornercorner with one F(4)Li5V octahedra, corners with two equivalent F(2)Li5V octahedra,  an edgeedge with one O(6)Li3V3 octahedra,  an edgeedge with one O(7)Li3V3 octahedra,  an edgeedge with one O(8)Li3V3 octahedra,  an edgeedge with one O(1)Li4V2 octahedra,  an edgeedge with one O(2)Li4V2 octahedra,  an edgeedge with one O(4)Li4V2 octahedra,  an edgeedge with one F(3)Li5V octahedra,  an edgeedge with one F(4)Li5V octahedra, edges with two equivalent O(5)Li3V3 octahedra, and edges with two equivalent O(3)Li4V2 octahedra. The corner-sharing octahedral tilt angles range from 1-6°. In the second F site, F(2) is bonded to one Li(2), one Li(4), one Li(5), one Li(6), one Li(8), and one V(1) atom to form FLi5V octahedra that share  a cornercorner with one O(1)Li4V2 octahedra,  a cornercorner with one O(2)Li4V2 octahedra,  a cornercorner with one F(3)Li5V octahedra,  a cornercorner with one F(4)Li5V octahedra, corners with two equivalent F(1)Li5V octahedra,  an edgeedge with one O(5)Li3V3 octahedra,  an edgeedge with one O(7)Li3V3 octahedra,  an edgeedge with one O(8)Li3V3 octahedra,  an edgeedge with one O(1)Li4V2 octahedra,  an edgeedge with one O(2)Li4V2 octahedra,  an edgeedge with one O(3)Li4V2 octahedra,  an edgeedge with one F(3)Li5V octahedra,  an edgeedge with one F(4)Li5V octahedra, edges with two equivalent O(6)Li3V3 octahedra, and edges with two equivalent O(4)Li4V2 octahedra. The corner-sharing octahedral tilt angles range from 1-6°. In the third F site, F(3) is bonded to one Li(2), one Li(3), one Li(6), one Li(7), one Li(8), and one V(2) atom to form FLi5V octahedra that share  a cornercorner with one O(1)Li4V2 octahedra,  a cornercorner with one O(2)Li4V2 octahedra,  a cornercorner with one F(1)Li5V octahedra,  a cornercorner with one F(2)Li5V octahedra, corners with two equivalent F(4)Li5V octahedra,  an edgeedge with one O(5)Li3V3 octahedra,  an edgeedge with one O(6)Li3V3 octahedra,  an edgeedge with one O(7)Li3V3 octahedra,  an edgeedge with one O(1)Li4V2 octahedra,  an edgeedge with one O(2)Li4V2 octahedra,  an edgeedge with one O(3)Li4V2 octahedra,  an edgeedge with one F(1)Li5V octahedra,  an edgeedge with one F(2)Li5V octahedra, edges with two equivalent O(8)Li3V3 octahedra, and edges with two equivalent O(4)Li4V2 octahedra. The corner-sharing octahedral tilt angles range from 1-6°. In the fourth F site, F(4) is bonded to one Li(1), one Li(4), one Li(5), one Li(7), one Li(8), and one V(4) atom to form FLi5V octahedra that share  a cornercorner with one O(1)Li4V2 octahedra,  a cornercorner with one O(2)Li4V2 octahedra,  a cornercorner with one F(1)Li5V octahedra,  a cornercorner with one F(2)Li5V octahedra, corners with two equivalent F(3)Li5V octahedra,  an edgeedge with one O(5)Li3V3 octahedra,  an edgeedge with one O(6)Li3V3 octahedra,  an edgeedge with one O(8)Li3V3 octahedra,  an edgeedge with one O(1)Li4V2 octahedra,  an edgeedge with one O(2)Li4V2 octahedra,  an edgeedge with one O(4)Li4V2 octahedra,  an edgeedge with one F(1)Li5V octahedra,  an edgeedge with one F(2)Li5V octahedra, edges with two equivalent O(7)Li3V3 octahedra, and edges with two equivalent O(3)Li4V2 octahedra. The corner-sharing octahedral tilt angles range from 1-7°. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li2VO2F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.157
_cell_length_b   5.167
_cell_length_c   5.878
_cell_angle_alpha   108.892
_cell_angle_beta   90.036
_cell_angle_gamma   113.701
_symmetry_Int_Tables_number   1
_cell_volume   108.118
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  F  F0  1  0.487  0.973  0.499  1.0
  F  F1  1  0.845  0.690  0.170  1.0
  Li  Li2  1  0.667  0.334  0.833  1.0
  Li  Li3  1  0.668  0.337  0.335  1.0
  Li  Li4  1  0.998  0.997  0.506  1.0
  Li  Li5  1  0.334  0.668  0.162  1.0
  O  O6  1  0.170  0.340  0.831  1.0
  O  O7  1  0.169  0.339  0.337  1.0
  O  O8  1  0.835  0.671  0.675  1.0
  O  O9  1  0.496  0.992  0.985  1.0
  V  V10  1  0.314  0.630  0.665  1.0
  V  V11  1  0.017  0.029  0.003  1.0
[/CIF]
.