The structure described by Ce4Pd10In21 crystallizes in the monoclinic C2/m space group. There are two inequivalent Ce sites. In the first Ce site, Ce(1) is bonded in a 15-coordinate geometry to two equivalent Pd(3), two equivalent Pd(4), one In(2), one In(4), one In(5), one In(9), two equivalent In(7), two equivalent In(8), and three equivalent In(10) atoms. In the second Ce site, Ce(2) is bonded in a 15-coordinate geometry to two equivalent Pd(1), two equivalent Pd(5), one In(2), one In(4), one In(6), one In(7), two equivalent In(3), two equivalent In(5), and three equivalent In(11) atoms. There are five inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 9-coordinate geometry to two equivalent Ce(2), one In(2), one In(5), two equivalent In(7), and three equivalent In(11) atoms. In the second Pd site, Pd(2) is bonded in a 9-coordinate geometry to one In(4), two equivalent In(1), two equivalent In(2), two equivalent In(3), and two equivalent In(8) atoms. In the third Pd site, Pd(3) is bonded in a 9-coordinate geometry to two equivalent Ce(1), one In(8), one In(9), two equivalent In(4), and three equivalent In(10) atoms. In the fourth Pd site, Pd(4) is bonded in a 10-coordinate geometry to two equivalent Ce(1), one In(10), one In(7), two equivalent In(5), two equivalent In(6), and two equivalent In(9) atoms. In the fifth Pd site, Pd(5) is bonded in a 9-coordinate geometry to two equivalent Ce(2), one In(3), one In(5), one In(9), two equivalent In(4), and two equivalent In(6) atoms. There are eleven inequivalent In sites. In the first In site, In(1) is bonded in a 4-coordinate geometry to four equivalent Pd(2) atoms. In the second In site, In(2) is bonded in a 3-coordinate geometry to one Ce(1), one Ce(2), one Pd(1), and two equivalent Pd(2) atoms. In the third In site, In(3) is bonded in a 5-coordinate geometry to two equivalent Ce(2), one Pd(5), and two equivalent Pd(2) atoms. In the fourth In site, In(4) is bonded in a 5-coordinate geometry to one Ce(1), one Ce(2), one Pd(2), two equivalent Pd(3), and two equivalent Pd(5) atoms. In the fifth In site, In(5) is bonded in a 6-coordinate geometry to one Ce(1), two equivalent Ce(2), one Pd(1), one Pd(5), and two equivalent Pd(4) atoms. In the sixth In site, In(6) is bonded in a 3-coordinate geometry to one Ce(2), two equivalent Pd(4), and two equivalent Pd(5) atoms. In the seventh In site, In(7) is bonded in a 5-coordinate geometry to one Ce(2), two equivalent Ce(1), one Pd(4), and two equivalent Pd(1) atoms. In the eighth In site, In(8) is bonded in a 5-coordinate geometry to two equivalent Ce(1), one Pd(3), and two equivalent Pd(2) atoms. In the ninth In site, In(9) is bonded in a 4-coordinate geometry to one Ce(1), one Pd(3), one Pd(5), and two equivalent Pd(4) atoms. In the tenth In site, In(10) is bonded in a 6-coordinate geometry to three equivalent Ce(1), one Pd(4), and three equivalent Pd(3) atoms. In the eleventh In site, In(11) is bonded in a 5-coordinate geometry to three equivalent Ce(2) and three equivalent Pd(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ce4In21Pd10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.042
_cell_length_b   12.042
_cell_length_c   17.591
_cell_angle_alpha   56.024
_cell_angle_beta   56.024
_cell_angle_gamma   21.202
_symmetry_Int_Tables_number   1
_cell_volume   758.890
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.229  0.229  0.675  1.0
  Ce  Ce1  1  0.771  0.771  0.325  1.0
  Ce  Ce2  1  0.878  0.878  0.833  1.0
  Ce  Ce3  1  0.122  0.122  0.167  1.0
  In  In4  1  0.500  0.500  0.000  1.0
  In  In5  1  0.116  0.116  0.947  1.0
  In  In6  1  0.884  0.884  0.053  1.0
  In  In7  1  0.458  0.458  0.868  1.0
  In  In8  1  0.542  0.542  0.132  1.0
  In  In9  1  0.065  0.065  0.702  1.0
  In  In10  1  0.935  0.935  0.298  1.0
  In  In11  1  0.369  0.369  0.701  1.0
  In  In12  1  0.631  0.631  0.299  1.0
  In  In13  1  0.990  0.990  0.592  1.0
  In  In14  1  0.010  0.010  0.408  1.0
  In  In15  1  0.749  0.749  0.793  1.0
  In  In16  1  0.251  0.251  0.207  1.0
  In  In17  1  0.616  0.616  0.795  1.0
  In  In18  1  0.384  0.384  0.205  1.0
  In  In19  1  0.602  0.602  0.504  1.0
  In  In20  1  0.398  0.398  0.496  1.0
  In  In21  1  0.202  0.202  0.493  1.0
  In  In22  1  0.798  0.798  0.507  1.0
  In  In23  1  0.701  0.701  0.001  1.0
  In  In24  1  0.299  0.299  0.999  1.0
  Pd  Pd25  1  0.249  0.249  0.886  1.0
  Pd  Pd26  1  0.751  0.751  0.114  1.0
  Pd  Pd27  1  0.024  0.024  0.889  1.0
  Pd  Pd28  1  0.976  0.976  0.111  1.0
  Pd  Pd29  1  0.654  0.654  0.613  1.0
  Pd  Pd30  1  0.346  0.346  0.387  1.0
  Pd  Pd31  1  0.864  0.864  0.607  1.0
  Pd  Pd32  1  0.136  0.136  0.393  1.0
  Pd  Pd33  1  0.495  0.495  0.687  1.0
  Pd  Pd34  1  0.505  0.505  0.313  1.0
[/CIF]
.
The structure described by Ce4Pd10In21 crystallizes in the monoclinic C2/m space group. There are two inequivalent Ce sites. In the first Ce site, Ce(1) is bonded in a 15-coordinate geometry to two equivalent Pd(3), two equivalent Pd(4), one In(2), one In(4), one In(5), one In(9), two equivalent In(7), two equivalent In(8), and three equivalent In(10) atoms. In the second Ce site, Ce(2) is bonded in a 15-coordinate geometry to two equivalent Pd(1), two equivalent Pd(5), one In(2), one In(4), one In(6), one In(7), two equivalent In(3), two equivalent In(5), and three equivalent In(11) atoms. There are five inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 9-coordinate geometry to two equivalent Ce(2), one In(2), one In(5), two equivalent In(7), and three equivalent In(11) atoms. In the second Pd site, Pd(2) is bonded in a 9-coordinate geometry to one In(4), two equivalent In(1), two equivalent In(2), two equivalent In(3), and two equivalent In(8) atoms. In the third Pd site, Pd(3) is bonded in a 9-coordinate geometry to two equivalent Ce(1), one In(8), one In(9), two equivalent In(4), and three equivalent In(10) atoms. In the fourth Pd site, Pd(4) is bonded in a 10-coordinate geometry to two equivalent Ce(1), one In(10), one In(7), two equivalent In(5), two equivalent In(6), and two equivalent In(9) atoms. In the fifth Pd site, Pd(5) is bonded in a 9-coordinate geometry to two equivalent Ce(2), one In(3), one In(5), one In(9), two equivalent In(4), and two equivalent In(6) atoms. There are eleven inequivalent In sites. In the first In site, In(1) is bonded in a 4-coordinate geometry to four equivalent Pd(2) atoms. In the second In site, In(2) is bonded in a 3-coordinate geometry to one Ce(1), one Ce(2), one Pd(1), and two equivalent Pd(2) atoms. In the third In site, In(3) is bonded in a 5-coordinate geometry to two equivalent Ce(2), one Pd(5), and two equivalent Pd(2) atoms. In the fourth In site, In(4) is bonded in a 5-coordinate geometry to one Ce(1), one Ce(2), one Pd(2), two equivalent Pd(3), and two equivalent Pd(5) atoms. In the fifth In site, In(5) is bonded in a 6-coordinate geometry to one Ce(1), two equivalent Ce(2), one Pd(1), one Pd(5), and two equivalent Pd(4) atoms. In the sixth In site, In(6) is bonded in a 3-coordinate geometry to one Ce(2), two equivalent Pd(4), and two equivalent Pd(5) atoms. In the seventh In site, In(7) is bonded in a 5-coordinate geometry to one Ce(2), two equivalent Ce(1), one Pd(4), and two equivalent Pd(1) atoms. In the eighth In site, In(8) is bonded in a 5-coordinate geometry to two equivalent Ce(1), one Pd(3), and two equivalent Pd(2) atoms. In the ninth In site, In(9) is bonded in a 4-coordinate geometry to one Ce(1), one Pd(3), one Pd(5), and two equivalent Pd(4) atoms. In the tenth In site, In(10) is bonded in a 6-coordinate geometry to three equivalent Ce(1), one Pd(4), and three equivalent Pd(3) atoms. In the eleventh In site, In(11) is bonded in a 5-coordinate geometry to three equivalent Ce(2) and three equivalent Pd(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ce4In21Pd10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.042
_cell_length_b   12.042
_cell_length_c   17.591
_cell_angle_alpha   56.024
_cell_angle_beta   56.024
_cell_angle_gamma   21.202
_symmetry_Int_Tables_number   1
_cell_volume   758.890
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.229  0.229  0.675  1.0
  Ce  Ce1  1  0.771  0.771  0.325  1.0
  Ce  Ce2  1  0.878  0.878  0.833  1.0
  Ce  Ce3  1  0.122  0.122  0.167  1.0
  In  In4  1  0.500  0.500  0.000  1.0
  In  In5  1  0.116  0.116  0.947  1.0
  In  In6  1  0.884  0.884  0.053  1.0
  In  In7  1  0.458  0.458  0.868  1.0
  In  In8  1  0.542  0.542  0.132  1.0
  In  In9  1  0.065  0.065  0.702  1.0
  In  In10  1  0.935  0.935  0.298  1.0
  In  In11  1  0.369  0.369  0.701  1.0
  In  In12  1  0.631  0.631  0.299  1.0
  In  In13  1  0.990  0.990  0.592  1.0
  In  In14  1  0.010  0.010  0.408  1.0
  In  In15  1  0.749  0.749  0.793  1.0
  In  In16  1  0.251  0.251  0.207  1.0
  In  In17  1  0.616  0.616  0.795  1.0
  In  In18  1  0.384  0.384  0.205  1.0
  In  In19  1  0.602  0.602  0.504  1.0
  In  In20  1  0.398  0.398  0.496  1.0
  In  In21  1  0.202  0.202  0.493  1.0
  In  In22  1  0.798  0.798  0.507  1.0
  In  In23  1  0.701  0.701  0.001  1.0
  In  In24  1  0.299  0.299  0.999  1.0
  Pd  Pd25  1  0.249  0.249  0.886  1.0
  Pd  Pd26  1  0.751  0.751  0.114  1.0
  Pd  Pd27  1  0.024  0.024  0.889  1.0
  Pd  Pd28  1  0.976  0.976  0.111  1.0
  Pd  Pd29  1  0.654  0.654  0.613  1.0
  Pd  Pd30  1  0.346  0.346  0.387  1.0
  Pd  Pd31  1  0.864  0.864  0.607  1.0
  Pd  Pd32  1  0.136  0.136  0.393  1.0
  Pd  Pd33  1  0.495  0.495  0.687  1.0
  Pd  Pd34  1  0.505  0.505  0.313  1.0
[/CIF]
.