The material described by LaPdSb3 is Magnesium tetraboride-derived structured and crystallizes in the orthorhombic Pbcm space group. There are two inequivalent La sites. In the first La site, La(1) is bonded in a 11-coordinate geometry to two equivalent Pd(1), one Sb(3), two equivalent Sb(1), two equivalent Sb(4), and four equivalent Sb(5) atoms. In the second La site, La(2) is bonded in a 11-coordinate geometry to two equivalent Pd(1), one Sb(2), two equivalent Sb(1), two equivalent Sb(4), and four equivalent Sb(5) atoms. Pd(1) is bonded in a 9-coordinate geometry to one La(1), one La(2), one Pd(1), one Sb(1), one Sb(4), two equivalent Sb(2), and two equivalent Sb(3) atoms. There are five inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 7-coordinate geometry to two equivalent La(1), two equivalent La(2), two equivalent Pd(1), and one Sb(3) atom. In the second Sb site, Sb(2) is bonded in a 5-coordinate geometry to one La(2) and four equivalent Pd(1) atoms. In the third Sb site, Sb(3) is bonded in a 6-coordinate geometry to one La(1), four equivalent Pd(1), and one Sb(1) atom. In the fourth Sb site, Sb(4) is bonded in a 6-coordinate geometry to two equivalent La(1), two equivalent La(2), and two equivalent Pd(1) atoms. In the fifth Sb site, Sb(5) is bonded in a 8-coordinate geometry to two equivalent La(1), two equivalent La(2), and four equivalent Sb(5) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_LaSb3Pd
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.411
_cell_length_b   12.556
_cell_length_c   13.139
_cell_angle_alpha   90.001
_cell_angle_beta   89.999
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1057.675
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.276  0.250  0.191  1.0
  La  La1  1  0.724  0.750  0.809  1.0
  La  La2  1  0.776  0.250  0.809  1.0
  La  La3  1  0.224  0.750  0.191  1.0
  La  La4  1  0.250  1.000  0.802  1.0
  La  La5  1  0.750  0.000  0.198  1.0
  La  La6  1  0.750  0.500  0.198  1.0
  La  La7  1  0.250  0.500  0.802  1.0
  Sb  Sb8  1  0.263  0.250  0.720  1.0
  Sb  Sb9  1  0.737  0.750  0.280  1.0
  Sb  Sb10  1  0.763  0.250  0.280  1.0
  Sb  Sb11  1  0.237  0.750  0.720  1.0
  Sb  Sb12  1  0.250  0.000  0.525  1.0
  Sb  Sb13  1  0.750  0.000  0.475  1.0
  Sb  Sb14  1  0.750  0.500  0.475  1.0
  Sb  Sb15  1  0.250  0.500  0.525  1.0
  Sb  Sb16  1  0.420  0.250  0.438  1.0
  Sb  Sb17  1  0.580  0.750  0.562  1.0
  Sb  Sb18  1  0.920  0.250  0.562  1.0
  Sb  Sb19  1  0.080  0.750  0.438  1.0
  Sb  Sb20  1  0.250  0.000  0.268  1.0
  Sb  Sb21  1  0.750  0.000  0.732  1.0
  Sb  Sb22  1  0.750  0.500  0.732  1.0
  Sb  Sb23  1  0.250  0.500  0.268  1.0
  Sb  Sb24  1  0.012  0.121  0.003  1.0
  Sb  Sb25  1  0.989  0.879  0.997  1.0
  Sb  Sb26  1  0.989  0.621  0.997  1.0
  Sb  Sb27  1  0.512  0.379  0.997  1.0
  Sb  Sb28  1  0.012  0.379  0.003  1.0
  Sb  Sb29  1  0.488  0.621  0.003  1.0
  Sb  Sb30  1  0.489  0.879  0.003  1.0
  Sb  Sb31  1  0.511  0.121  0.997  1.0
  Pd  Pd32  1  0.049  0.134  0.400  1.0
  Pd  Pd33  1  0.951  0.866  0.600  1.0
  Pd  Pd34  1  0.951  0.634  0.600  1.0
  Pd  Pd35  1  0.549  0.366  0.600  1.0
  Pd  Pd36  1  0.049  0.366  0.400  1.0
  Pd  Pd37  1  0.451  0.634  0.400  1.0
  Pd  Pd38  1  0.451  0.866  0.400  1.0
  Pd  Pd39  1  0.549  0.134  0.600  1.0
[/CIF]
.
The material described by LaPdSb3 is Magnesium tetraboride-derived structured and crystallizes in the orthorhombic Pbcm space group. There are two inequivalent La sites. In the first La site, La(1) is bonded in a 11-coordinate geometry to two equivalent Pd(1), one Sb(3), two equivalent Sb(1), two equivalent Sb(4), and four equivalent Sb(5) atoms. In the second La site, La(2) is bonded in a 11-coordinate geometry to two equivalent Pd(1), one Sb(2), two equivalent Sb(1), two equivalent Sb(4), and four equivalent Sb(5) atoms. Pd(1) is bonded in a 9-coordinate geometry to one La(1), one La(2), one Pd(1), one Sb(1), one Sb(4), two equivalent Sb(2), and two equivalent Sb(3) atoms. There are five inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 7-coordinate geometry to two equivalent La(1), two equivalent La(2), two equivalent Pd(1), and one Sb(3) atom. In the second Sb site, Sb(2) is bonded in a 5-coordinate geometry to one La(2) and four equivalent Pd(1) atoms. In the third Sb site, Sb(3) is bonded in a 6-coordinate geometry to one La(1), four equivalent Pd(1), and one Sb(1) atom. In the fourth Sb site, Sb(4) is bonded in a 6-coordinate geometry to two equivalent La(1), two equivalent La(2), and two equivalent Pd(1) atoms. In the fifth Sb site, Sb(5) is bonded in a 8-coordinate geometry to two equivalent La(1), two equivalent La(2), and four equivalent Sb(5) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_LaSb3Pd
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.411
_cell_length_b   12.556
_cell_length_c   13.139
_cell_angle_alpha   90.001
_cell_angle_beta   89.999
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1057.675
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.276  0.250  0.191  1.0
  La  La1  1  0.724  0.750  0.809  1.0
  La  La2  1  0.776  0.250  0.809  1.0
  La  La3  1  0.224  0.750  0.191  1.0
  La  La4  1  0.250  1.000  0.802  1.0
  La  La5  1  0.750  0.000  0.198  1.0
  La  La6  1  0.750  0.500  0.198  1.0
  La  La7  1  0.250  0.500  0.802  1.0
  Sb  Sb8  1  0.263  0.250  0.720  1.0
  Sb  Sb9  1  0.737  0.750  0.280  1.0
  Sb  Sb10  1  0.763  0.250  0.280  1.0
  Sb  Sb11  1  0.237  0.750  0.720  1.0
  Sb  Sb12  1  0.250  0.000  0.525  1.0
  Sb  Sb13  1  0.750  0.000  0.475  1.0
  Sb  Sb14  1  0.750  0.500  0.475  1.0
  Sb  Sb15  1  0.250  0.500  0.525  1.0
  Sb  Sb16  1  0.420  0.250  0.438  1.0
  Sb  Sb17  1  0.580  0.750  0.562  1.0
  Sb  Sb18  1  0.920  0.250  0.562  1.0
  Sb  Sb19  1  0.080  0.750  0.438  1.0
  Sb  Sb20  1  0.250  0.000  0.268  1.0
  Sb  Sb21  1  0.750  0.000  0.732  1.0
  Sb  Sb22  1  0.750  0.500  0.732  1.0
  Sb  Sb23  1  0.250  0.500  0.268  1.0
  Sb  Sb24  1  0.012  0.121  0.003  1.0
  Sb  Sb25  1  0.989  0.879  0.997  1.0
  Sb  Sb26  1  0.989  0.621  0.997  1.0
  Sb  Sb27  1  0.512  0.379  0.997  1.0
  Sb  Sb28  1  0.012  0.379  0.003  1.0
  Sb  Sb29  1  0.488  0.621  0.003  1.0
  Sb  Sb30  1  0.489  0.879  0.003  1.0
  Sb  Sb31  1  0.511  0.121  0.997  1.0
  Pd  Pd32  1  0.049  0.134  0.400  1.0
  Pd  Pd33  1  0.951  0.866  0.600  1.0
  Pd  Pd34  1  0.951  0.634  0.600  1.0
  Pd  Pd35  1  0.549  0.366  0.600  1.0
  Pd  Pd36  1  0.049  0.366  0.400  1.0
  Pd  Pd37  1  0.451  0.634  0.400  1.0
  Pd  Pd38  1  0.451  0.866  0.400  1.0
  Pd  Pd39  1  0.549  0.134  0.600  1.0
[/CIF]
.