The compound described by AuP2F6SbF6 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two AuP2F6 clusters and two SbF6 clusters. In each AuP2F6 cluster, Au(1) is bonded in a linear geometry to two equivalent P(1) atoms. P(1) is bonded in a 3-coordinate geometry to one Au(1), one F(4), one F(5), and one F(6) atom. There are three inequivalent F sites. In the first F site, F(4) is bonded in a single-bond geometry to one P(1) atom. In the second F site, F(5) is bonded in a single-bond geometry to one P(1) atom. In the third F site, F(6) is bonded in a single-bond geometry to one P(1) atom. In each SbF6 cluster, Sb(1) is bonded in an octahedral geometry to two equivalent F(2) and four equivalent F(1,3) atoms. There are two inequivalent F sites. In the first F site, F(1,3) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. is represented by the CIF card [CIF]
data_SbP2AuF12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.486
_cell_length_b   9.125
_cell_length_c   8.567
_cell_angle_alpha   90.000
_cell_angle_beta   119.759
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   575.870
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.000  0.500  0.500  1.0
  Sb  Sb1  1  0.000  0.000  0.000  1.0
  P  P2  1  0.690  0.027  0.347  1.0
  P  P3  1  0.310  0.527  0.153  1.0
  P  P4  1  0.310  0.973  0.653  1.0
  P  P5  1  0.690  0.473  0.847  1.0
  Au  Au6  1  0.000  0.000  0.500  1.0
  Au  Au7  1  0.000  0.500  0.000  1.0
  F  F8  1  0.164  0.421  0.733  1.0
  F  F9  1  0.836  0.921  0.767  1.0
  F  F10  1  0.836  0.579  0.267  1.0
  F  F11  1  0.164  0.079  0.233  1.0
  F  F12  1  0.140  0.410  0.405  1.0
  F  F13  1  0.860  0.910  0.095  1.0
  F  F14  1  0.860  0.590  0.595  1.0
  F  F15  1  0.140  0.090  0.905  1.0
  F  F16  1  0.148  0.674  0.560  1.0
  F  F17  1  0.852  0.174  0.940  1.0
  F  F18  1  0.852  0.326  0.440  1.0
  F  F19  1  0.148  0.826  0.060  1.0
  F  F20  1  0.602  0.114  0.439  1.0
  F  F21  1  0.398  0.614  0.061  1.0
  F  F22  1  0.398  0.886  0.561  1.0
  F  F23  1  0.602  0.386  0.939  1.0
  F  F24  1  0.605  0.102  0.160  1.0
  F  F25  1  0.395  0.602  0.340  1.0
  F  F26  1  0.395  0.898  0.840  1.0
  F  F27  1  0.605  0.398  0.660  1.0
  F  F28  1  0.581  0.881  0.299  1.0
  F  F29  1  0.419  0.381  0.201  1.0
  F  F30  1  0.419  0.119  0.701  1.0
  F  F31  1  0.581  0.619  0.799  1.0
[/CIF]
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The compound described by AuP2F6SbF6 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two AuP2F6 clusters and two SbF6 clusters. In each AuP2F6 cluster, Au(1) is bonded in a linear geometry to two equivalent P(1) atoms. P(1) is bonded in a 3-coordinate geometry to one Au(1), one F(4), one F(5), and one F(6) atom. There are three inequivalent F sites. In the first F site, F(4) is bonded in a single-bond geometry to one P(1) atom. In the second F site, F(5) is bonded in a single-bond geometry to one P(1) atom. In the third F site, F(6) is bonded in a single-bond geometry to one P(1) atom. In each SbF6 cluster, Sb(1) is bonded in an octahedral geometry to two equivalent F(2) and four equivalent F(1,3) atoms. There are two inequivalent F sites. In the first F site, F(1,3) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. is represented by the CIF card [CIF]
data_SbP2AuF12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.486
_cell_length_b   9.125
_cell_length_c   8.567
_cell_angle_alpha   90.000
_cell_angle_beta   119.759
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   575.870
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.000  0.500  0.500  1.0
  Sb  Sb1  1  0.000  0.000  0.000  1.0
  P  P2  1  0.690  0.027  0.347  1.0
  P  P3  1  0.310  0.527  0.153  1.0
  P  P4  1  0.310  0.973  0.653  1.0
  P  P5  1  0.690  0.473  0.847  1.0
  Au  Au6  1  0.000  0.000  0.500  1.0
  Au  Au7  1  0.000  0.500  0.000  1.0
  F  F8  1  0.164  0.421  0.733  1.0
  F  F9  1  0.836  0.921  0.767  1.0
  F  F10  1  0.836  0.579  0.267  1.0
  F  F11  1  0.164  0.079  0.233  1.0
  F  F12  1  0.140  0.410  0.405  1.0
  F  F13  1  0.860  0.910  0.095  1.0
  F  F14  1  0.860  0.590  0.595  1.0
  F  F15  1  0.140  0.090  0.905  1.0
  F  F16  1  0.148  0.674  0.560  1.0
  F  F17  1  0.852  0.174  0.940  1.0
  F  F18  1  0.852  0.326  0.440  1.0
  F  F19  1  0.148  0.826  0.060  1.0
  F  F20  1  0.602  0.114  0.439  1.0
  F  F21  1  0.398  0.614  0.061  1.0
  F  F22  1  0.398  0.886  0.561  1.0
  F  F23  1  0.602  0.386  0.939  1.0
  F  F24  1  0.605  0.102  0.160  1.0
  F  F25  1  0.395  0.602  0.340  1.0
  F  F26  1  0.395  0.898  0.840  1.0
  F  F27  1  0.605  0.398  0.660  1.0
  F  F28  1  0.581  0.881  0.299  1.0
  F  F29  1  0.419  0.381  0.201  1.0
  F  F30  1  0.419  0.119  0.701  1.0
  F  F31  1  0.581  0.619  0.799  1.0
[/CIF]
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