The structure described by Gd3YV4O16 is Zircon-derived structured and crystallizes in the orthorhombic C222 space group. There are two inequivalent Gd sites. In the first Gd site, Gd(1) is bonded in a 8-coordinate geometry to four equivalent O(2) and four equivalent O(4) atoms. In the second Gd site, Gd(2) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms. Y(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(3) atoms. There are three inequivalent V sites. In the first V site, V(1) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent O(2) atoms. In the second V site, V(2) is bonded in a tetrahedral geometry to four equivalent O(3) atoms. In the third V site, V(3) is bonded in a tetrahedral geometry to four equivalent O(4) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Gd(2), one Y(1), and one V(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Gd(1), one Gd(2), and one V(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Gd(2), one Y(1), and one V(2) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Gd(1), one Gd(2), and one V(3) atom. is represented by the CIF file [CIF]
data_Gd3YV4O16
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.060
_cell_length_b   6.060
_cell_length_c   10.281
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   116.065
_symmetry_Int_Tables_number   1
_cell_volume   339.160
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Gd  Gd0  1  0.500  0.500  0.000  1.0
  Gd  Gd1  1  0.500  0.000  0.251  1.0
  Gd  Gd2  1  0.000  0.500  0.749  1.0
  Y  Y3  1  0.000  0.000  0.500  1.0
  V  V4  1  0.000  0.500  0.252  1.0
  V  V5  1  0.500  0.000  0.748  1.0
  V  V6  1  0.500  0.500  0.500  1.0
  V  V7  1  0.000  0.000  0.000  1.0
  O  O8  1  0.920  0.234  0.343  1.0
  O  O9  1  0.418  0.735  0.841  1.0
  O  O10  1  0.233  0.416  0.591  1.0
  O  O11  1  0.734  0.918  0.092  1.0
  O  O12  1  0.416  0.233  0.409  1.0
  O  O13  1  0.918  0.734  0.908  1.0
  O  O14  1  0.735  0.418  0.159  1.0
  O  O15  1  0.234  0.920  0.657  1.0
  O  O16  1  0.584  0.767  0.409  1.0
  O  O17  1  0.082  0.266  0.908  1.0
  O  O18  1  0.265  0.582  0.159  1.0
  O  O19  1  0.766  0.080  0.657  1.0
  O  O20  1  0.080  0.766  0.343  1.0
  O  O21  1  0.582  0.265  0.841  1.0
  O  O22  1  0.767  0.584  0.591  1.0
  O  O23  1  0.266  0.082  0.092  1.0
[/CIF]
.
The structure described by Gd3YV4O16 is Zircon-derived structured and crystallizes in the orthorhombic C222 space group. There are two inequivalent Gd sites. In the first Gd site, Gd(1) is bonded in a 8-coordinate geometry to four equivalent O(2) and four equivalent O(4) atoms. In the second Gd site, Gd(2) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms. Y(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(3) atoms. There are three inequivalent V sites. In the first V site, V(1) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent O(2) atoms. In the second V site, V(2) is bonded in a tetrahedral geometry to four equivalent O(3) atoms. In the third V site, V(3) is bonded in a tetrahedral geometry to four equivalent O(4) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Gd(2), one Y(1), and one V(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Gd(1), one Gd(2), and one V(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Gd(2), one Y(1), and one V(2) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Gd(1), one Gd(2), and one V(3) atom. is represented by the CIF file [CIF]
data_Gd3YV4O16
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.060
_cell_length_b   6.060
_cell_length_c   10.281
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   116.065
_symmetry_Int_Tables_number   1
_cell_volume   339.160
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Gd  Gd0  1  0.500  0.500  0.000  1.0
  Gd  Gd1  1  0.500  0.000  0.251  1.0
  Gd  Gd2  1  0.000  0.500  0.749  1.0
  Y  Y3  1  0.000  0.000  0.500  1.0
  V  V4  1  0.000  0.500  0.252  1.0
  V  V5  1  0.500  0.000  0.748  1.0
  V  V6  1  0.500  0.500  0.500  1.0
  V  V7  1  0.000  0.000  0.000  1.0
  O  O8  1  0.920  0.234  0.343  1.0
  O  O9  1  0.418  0.735  0.841  1.0
  O  O10  1  0.233  0.416  0.591  1.0
  O  O11  1  0.734  0.918  0.092  1.0
  O  O12  1  0.416  0.233  0.409  1.0
  O  O13  1  0.918  0.734  0.908  1.0
  O  O14  1  0.735  0.418  0.159  1.0
  O  O15  1  0.234  0.920  0.657  1.0
  O  O16  1  0.584  0.767  0.409  1.0
  O  O17  1  0.082  0.266  0.908  1.0
  O  O18  1  0.265  0.582  0.159  1.0
  O  O19  1  0.766  0.080  0.657  1.0
  O  O20  1  0.080  0.766  0.343  1.0
  O  O21  1  0.582  0.265  0.841  1.0
  O  O22  1  0.767  0.584  0.591  1.0
  O  O23  1  0.266  0.082  0.092  1.0
[/CIF]
.