The structure described by Na3Co6Ag(P2O7)4 crystallizes in the triclinic P1 space group. There are three inequivalent Na sites. In the first Na site, Na(1) is bonded in a 7-coordinate geometry to one O(11), one O(18), one O(2), one O(20), one O(22), one O(28), and one O(8) atom. In the second Na site, Na(2) is bonded in a 7-coordinate geometry to one O(11), one O(12), one O(17), one O(18), one O(20), one O(7), and one O(8) atom. In the third Na site, Na(3) is bonded in a 7-coordinate geometry to one O(11), one O(12), one O(17), one O(18), one O(19), one O(7), and one O(8) atom. There are six inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(15), one O(25), one O(3), one O(6), and one O(9) atom to form CoO5 trigonal bipyramids that share  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(7)O4 tetrahedra, corners with two equivalent P(3)O4 tetrahedra, and edges with two equivalent Co(5)O6 octahedra. In the second Co site, Co(2) is bonded to one O(10), one O(16), one O(26), one O(4), and one O(5) atom to form CoO5 trigonal bipyramids that share  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a cornercorner with one P(8)O4 tetrahedra, corners with two equivalent P(4)O4 tetrahedra, and edges with two equivalent Co(6)O6 octahedra. In the third Co site, Co(3) is bonded to one O(17), one O(19), one O(21), one O(23), one O(27), and one O(7) atom to form CoO6 octahedra that share corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(5)O4 tetrahedra, corners with two equivalent P(7)O4 tetrahedra, and  an edgeedge with one Co(5)O6 octahedra. In the fourth Co site, Co(4) is bonded to one O(18), one O(20), one O(22), one O(24), one O(28), and one O(8) atom to form CoO6 octahedra that share corners with two equivalent P(2)O4 tetrahedra, corners with two equivalent P(6)O4 tetrahedra, corners with two equivalent P(8)O4 tetrahedra, and  an edgeedge with one Co(6)O6 octahedra. In the fifth Co site, Co(5) is bonded to one O(15), one O(23), one O(27), one O(3), one O(6), and one O(9) atom to form distorted CoO6 octahedra that share  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, corners with two equivalent P(5)O4 tetrahedra, corners with two equivalent P(7)O4 tetrahedra,  an edgeedge with one Co(3)O6 octahedra, and edges with two equivalent Co(1)O5 trigonal bipyramids. In the sixth Co site, Co(6) is bonded to one O(10), one O(16), one O(24), one O(28), one O(4), and one O(5) atom to form distorted CoO6 octahedra that share  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, corners with two equivalent P(6)O4 tetrahedra, corners with two equivalent P(8)O4 tetrahedra,  an edgeedge with one Co(4)O6 octahedra, and edges with two equivalent Co(2)O5 trigonal bipyramids. Ag(1) is bonded in a 6-coordinate geometry to one O(1), one O(12), one O(17), one O(19), one O(21), and one O(27) atom. There are eight inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(11), one O(17), and one O(7) atom to form PO4 tetrahedra that share corners with two equivalent Co(3)O6 octahedra and  a cornercorner with one P(7)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 47-50°. In the second P site, P(2) is bonded to one O(12), one O(18), one O(2), and one O(8) atom to form PO4 tetrahedra that share corners with two equivalent Co(4)O6 octahedra and  a cornercorner with one P(8)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 47-51°. In the third P site, P(3) is bonded to one O(13), one O(25), one O(3), and one O(5) atom to form PO4 tetrahedra that share  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one Co(2)O5 trigonal bipyramid, and corners with two equivalent Co(1)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 48-49°. In the fourth P site, P(4) is bonded to one O(14), one O(26), one O(4), and one O(6) atom to form PO4 tetrahedra that share  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one P(6)O4 tetrahedra,  a cornercorner with one Co(1)O5 trigonal bipyramid, and corners with two equivalent Co(2)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 48-49°. In the fifth P site, P(5) is bonded to one O(13), one O(21), one O(23), and one O(9) atom to form PO4 tetrahedra that share corners with two equivalent Co(3)O6 octahedra, corners with two equivalent Co(5)O6 octahedra,  a cornercorner with one P(3)O4 tetrahedra, and  a cornercorner with one Co(1)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 19-55°. In the sixth P site, P(6) is bonded to one O(10), one O(14), one O(22), and one O(24) atom to form PO4 tetrahedra that share corners with two equivalent Co(4)O6 octahedra, corners with two equivalent Co(6)O6 octahedra,  a cornercorner with one P(4)O4 tetrahedra, and  a cornercorner with one Co(2)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 20-55°. In the seventh P site, P(7) is bonded to one O(1), one O(15), one O(19), and one O(27) atom to form PO4 tetrahedra that share corners with two equivalent Co(3)O6 octahedra, corners with two equivalent Co(5)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra, and  a cornercorner with one Co(1)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 43-59°. In the eighth P site, P(8) is bonded to one O(16), one O(2), one O(20), and one O(28) atom to form PO4 tetrahedra that share corners with two equivalent Co(4)O6 octahedra, corners with two equivalent Co(6)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra, and  a cornercorner with one Co(2)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 44-60°. There are twenty-eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Ag(1), one P(1), and one P(7) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Na(1), one P(2), and one P(8) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Co(1), one Co(5), and one P(3) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Co(2), one Co(6), and one P(4) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Co(2), one Co(6), and one P(3) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Co(1), one Co(5), and one P(4) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one Na(2), one Na(3), one Co(3), and one P(1) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one Na(1), one Na(2), one Na(3), one Co(4), and one P(2) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one Co(1), one Co(5), and one P(5) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Co(2), one Co(6), and one P(6) atom. In the eleventh O site, O(11) is bonded to one Na(1), one Na(2), one Na(3), and one P(1) atom to form distorted edge-sharing ONa3P trigonal pyramids. In the twelfth O site, O(12) is bonded to one Na(2), one Na(3), one Ag(1), and one P(2) atom to form distorted edge-sharing ONa2AgP trigonal pyramids. In the thirteenth O site, O(13) is bonded in a bent 150 degrees geometry to one P(3) and one P(5) atom. In the fourteenth O site, O(14) is bonded in a bent 150 degrees geometry to one P(4) and one P(6) atom. In the fifteenth O site, O(15) is bonded in a distorted trigonal planar geometry to one Co(1), one Co(5), and one P(7) atom. In the sixteenth O site, O(16) is bonded in a distorted trigonal planar geometry to one Co(2), one Co(6), and one P(8) atom. In the seventeenth O site, O(17) is bonded in a 5-coordinate geometry to one Na(2), one Na(3), one Co(3), one Ag(1), and one P(1) atom. In the eighteenth O site, O(18) is bonded in a 5-coordinate geometry to one Na(1), one Na(2), one Na(3), one Co(4), and one P(2) atom. In the nineteenth O site, O(19) is bonded in a 4-coordinate geometry to one Na(3), one Co(3), one Ag(1), and one P(7) atom. In the twentieth O site, O(20) is bonded in a 4-coordinate geometry to one Na(1), one Na(2), one Co(4), and one P(8) atom. In the twenty-first O site, O(21) is bonded in a 3-coordinate geometry to one Co(3), one Ag(1), and one P(5) atom. In the twenty-second O site, O(22) is bonded in a 3-coordinate geometry to one Na(1), one Co(4), and one P(6) atom. In the twenty-third O site, O(23) is bonded in a distorted trigonal planar geometry to one Co(3), one Co(5), and one P(5) atom. In the twenty-fourth O site, O(24) is bonded in a distorted trigonal planar geometry to one Co(4), one Co(6), and one P(6) atom. In the twenty-fifth O site, O(25) is bonded in a bent 150 degrees geometry to one Co(1) and one P(3) atom. In the twenty-sixth O site, O(26) is bonded in a bent 150 degrees geometry to one Co(2) and one P(4) atom. In the twenty-seventh O site, O(27) is bonded in a 4-coordinate geometry to one Co(3), one Co(5), one Ag(1), and one P(7) atom. In the twenty-eighth O site, O(28) is bonded in a 4-coordinate geometry to one Na(1), one Co(4), one Co(6), and one P(8) atom. is represented by the CIF file [CIF]
data_Na3Co6Ag(P2O7)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.386
_cell_length_b   6.444
_cell_length_c   16.485
_cell_angle_alpha   80.710
_cell_angle_beta   81.567
_cell_angle_gamma   72.779
_symmetry_Int_Tables_number   1
_cell_volume   536.332
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.386  0.726  0.139  1.0
  Na  Na1  1  0.907  0.747  0.019  1.0
  Na  Na2  1  0.094  0.253  0.980  1.0
  Co  Co3  1  0.204  0.279  0.589  1.0
  Co  Co4  1  0.796  0.721  0.411  1.0
  Co  Co5  1  0.037  0.636  0.804  1.0
  Co  Co6  1  0.961  0.365  0.196  1.0
  Co  Co7  1  0.769  0.038  0.659  1.0
  Co  Co8  1  0.231  0.961  0.342  1.0
  Ag  Ag9  1  0.610  0.272  0.862  1.0
  P  P10  1  0.434  0.750  0.918  1.0
  P  P11  1  0.566  0.251  0.083  1.0
  P  P12  1  0.295  0.781  0.542  1.0
  P  P13  1  0.705  0.219  0.458  1.0
  P  P14  1  0.643  0.573  0.677  1.0
  P  P15  1  0.357  0.427  0.323  1.0
  P  P16  1  0.190  0.098  0.782  1.0
  P  P17  1  0.811  0.902  0.217  1.0
  O  O18  1  0.405  0.951  0.842  1.0
  O  O19  1  0.595  0.047  0.158  1.0
  O  O20  1  0.120  0.986  0.581  1.0
  O  O21  1  0.881  0.014  0.420  1.0
  O  O22  1  0.411  0.842  0.453  1.0
  O  O23  1  0.589  0.158  0.547  1.0
  O  O24  1  0.730  0.646  0.910  1.0
  O  O25  1  0.271  0.356  0.090  1.0
  O  O26  1  0.826  0.347  0.658  1.0
  O  O27  1  0.173  0.653  0.342  1.0
  O  O28  1  0.323  0.853  0.997  1.0
  O  O29  1  0.680  0.143  0.004  1.0
  O  O30  1  0.558  0.701  0.588  1.0
  O  O31  1  0.442  0.299  0.412  1.0
  O  O32  1  0.356  0.138  0.701  1.0
  O  O33  1  0.644  0.862  0.299  1.0
  O  O34  1  0.268  0.604  0.902  1.0
  O  O35  1  0.727  0.400  0.098  1.0
  O  O36  1  0.057  0.303  0.826  1.0
  O  O37  1  0.945  0.698  0.174  1.0
  O  O38  1  0.404  0.552  0.734  1.0
  O  O39  1  0.593  0.450  0.265  1.0
  O  O40  1  0.797  0.712  0.705  1.0
  O  O41  1  0.203  0.287  0.296  1.0
  O  O42  1  0.164  0.600  0.550  1.0
  O  O43  1  0.836  0.400  0.450  1.0
  O  O44  1  0.991  0.973  0.776  1.0
  O  O45  1  0.012  0.027  0.223  1.0
[/CIF]
.
The structure described by Na3Co6Ag(P2O7)4 crystallizes in the triclinic P1 space group. There are three inequivalent Na sites. In the first Na site, Na(1) is bonded in a 7-coordinate geometry to one O(11), one O(18), one O(2), one O(20), one O(22), one O(28), and one O(8) atom. In the second Na site, Na(2) is bonded in a 7-coordinate geometry to one O(11), one O(12), one O(17), one O(18), one O(20), one O(7), and one O(8) atom. In the third Na site, Na(3) is bonded in a 7-coordinate geometry to one O(11), one O(12), one O(17), one O(18), one O(19), one O(7), and one O(8) atom. There are six inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(15), one O(25), one O(3), one O(6), and one O(9) atom to form CoO5 trigonal bipyramids that share  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(7)O4 tetrahedra, corners with two equivalent P(3)O4 tetrahedra, and edges with two equivalent Co(5)O6 octahedra. In the second Co site, Co(2) is bonded to one O(10), one O(16), one O(26), one O(4), and one O(5) atom to form CoO5 trigonal bipyramids that share  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a cornercorner with one P(8)O4 tetrahedra, corners with two equivalent P(4)O4 tetrahedra, and edges with two equivalent Co(6)O6 octahedra. In the third Co site, Co(3) is bonded to one O(17), one O(19), one O(21), one O(23), one O(27), and one O(7) atom to form CoO6 octahedra that share corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(5)O4 tetrahedra, corners with two equivalent P(7)O4 tetrahedra, and  an edgeedge with one Co(5)O6 octahedra. In the fourth Co site, Co(4) is bonded to one O(18), one O(20), one O(22), one O(24), one O(28), and one O(8) atom to form CoO6 octahedra that share corners with two equivalent P(2)O4 tetrahedra, corners with two equivalent P(6)O4 tetrahedra, corners with two equivalent P(8)O4 tetrahedra, and  an edgeedge with one Co(6)O6 octahedra. In the fifth Co site, Co(5) is bonded to one O(15), one O(23), one O(27), one O(3), one O(6), and one O(9) atom to form distorted CoO6 octahedra that share  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, corners with two equivalent P(5)O4 tetrahedra, corners with two equivalent P(7)O4 tetrahedra,  an edgeedge with one Co(3)O6 octahedra, and edges with two equivalent Co(1)O5 trigonal bipyramids. In the sixth Co site, Co(6) is bonded to one O(10), one O(16), one O(24), one O(28), one O(4), and one O(5) atom to form distorted CoO6 octahedra that share  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, corners with two equivalent P(6)O4 tetrahedra, corners with two equivalent P(8)O4 tetrahedra,  an edgeedge with one Co(4)O6 octahedra, and edges with two equivalent Co(2)O5 trigonal bipyramids. Ag(1) is bonded in a 6-coordinate geometry to one O(1), one O(12), one O(17), one O(19), one O(21), and one O(27) atom. There are eight inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(11), one O(17), and one O(7) atom to form PO4 tetrahedra that share corners with two equivalent Co(3)O6 octahedra and  a cornercorner with one P(7)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 47-50°. In the second P site, P(2) is bonded to one O(12), one O(18), one O(2), and one O(8) atom to form PO4 tetrahedra that share corners with two equivalent Co(4)O6 octahedra and  a cornercorner with one P(8)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 47-51°. In the third P site, P(3) is bonded to one O(13), one O(25), one O(3), and one O(5) atom to form PO4 tetrahedra that share  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one Co(2)O5 trigonal bipyramid, and corners with two equivalent Co(1)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 48-49°. In the fourth P site, P(4) is bonded to one O(14), one O(26), one O(4), and one O(6) atom to form PO4 tetrahedra that share  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one P(6)O4 tetrahedra,  a cornercorner with one Co(1)O5 trigonal bipyramid, and corners with two equivalent Co(2)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 48-49°. In the fifth P site, P(5) is bonded to one O(13), one O(21), one O(23), and one O(9) atom to form PO4 tetrahedra that share corners with two equivalent Co(3)O6 octahedra, corners with two equivalent Co(5)O6 octahedra,  a cornercorner with one P(3)O4 tetrahedra, and  a cornercorner with one Co(1)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 19-55°. In the sixth P site, P(6) is bonded to one O(10), one O(14), one O(22), and one O(24) atom to form PO4 tetrahedra that share corners with two equivalent Co(4)O6 octahedra, corners with two equivalent Co(6)O6 octahedra,  a cornercorner with one P(4)O4 tetrahedra, and  a cornercorner with one Co(2)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 20-55°. In the seventh P site, P(7) is bonded to one O(1), one O(15), one O(19), and one O(27) atom to form PO4 tetrahedra that share corners with two equivalent Co(3)O6 octahedra, corners with two equivalent Co(5)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra, and  a cornercorner with one Co(1)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 43-59°. In the eighth P site, P(8) is bonded to one O(16), one O(2), one O(20), and one O(28) atom to form PO4 tetrahedra that share corners with two equivalent Co(4)O6 octahedra, corners with two equivalent Co(6)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra, and  a cornercorner with one Co(2)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 44-60°. There are twenty-eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Ag(1), one P(1), and one P(7) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Na(1), one P(2), and one P(8) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Co(1), one Co(5), and one P(3) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Co(2), one Co(6), and one P(4) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Co(2), one Co(6), and one P(3) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Co(1), one Co(5), and one P(4) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one Na(2), one Na(3), one Co(3), and one P(1) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one Na(1), one Na(2), one Na(3), one Co(4), and one P(2) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one Co(1), one Co(5), and one P(5) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Co(2), one Co(6), and one P(6) atom. In the eleventh O site, O(11) is bonded to one Na(1), one Na(2), one Na(3), and one P(1) atom to form distorted edge-sharing ONa3P trigonal pyramids. In the twelfth O site, O(12) is bonded to one Na(2), one Na(3), one Ag(1), and one P(2) atom to form distorted edge-sharing ONa2AgP trigonal pyramids. In the thirteenth O site, O(13) is bonded in a bent 150 degrees geometry to one P(3) and one P(5) atom. In the fourteenth O site, O(14) is bonded in a bent 150 degrees geometry to one P(4) and one P(6) atom. In the fifteenth O site, O(15) is bonded in a distorted trigonal planar geometry to one Co(1), one Co(5), and one P(7) atom. In the sixteenth O site, O(16) is bonded in a distorted trigonal planar geometry to one Co(2), one Co(6), and one P(8) atom. In the seventeenth O site, O(17) is bonded in a 5-coordinate geometry to one Na(2), one Na(3), one Co(3), one Ag(1), and one P(1) atom. In the eighteenth O site, O(18) is bonded in a 5-coordinate geometry to one Na(1), one Na(2), one Na(3), one Co(4), and one P(2) atom. In the nineteenth O site, O(19) is bonded in a 4-coordinate geometry to one Na(3), one Co(3), one Ag(1), and one P(7) atom. In the twentieth O site, O(20) is bonded in a 4-coordinate geometry to one Na(1), one Na(2), one Co(4), and one P(8) atom. In the twenty-first O site, O(21) is bonded in a 3-coordinate geometry to one Co(3), one Ag(1), and one P(5) atom. In the twenty-second O site, O(22) is bonded in a 3-coordinate geometry to one Na(1), one Co(4), and one P(6) atom. In the twenty-third O site, O(23) is bonded in a distorted trigonal planar geometry to one Co(3), one Co(5), and one P(5) atom. In the twenty-fourth O site, O(24) is bonded in a distorted trigonal planar geometry to one Co(4), one Co(6), and one P(6) atom. In the twenty-fifth O site, O(25) is bonded in a bent 150 degrees geometry to one Co(1) and one P(3) atom. In the twenty-sixth O site, O(26) is bonded in a bent 150 degrees geometry to one Co(2) and one P(4) atom. In the twenty-seventh O site, O(27) is bonded in a 4-coordinate geometry to one Co(3), one Co(5), one Ag(1), and one P(7) atom. In the twenty-eighth O site, O(28) is bonded in a 4-coordinate geometry to one Na(1), one Co(4), one Co(6), and one P(8) atom. is represented by the CIF file [CIF]
data_Na3Co6Ag(P2O7)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.386
_cell_length_b   6.444
_cell_length_c   16.485
_cell_angle_alpha   80.710
_cell_angle_beta   81.567
_cell_angle_gamma   72.779
_symmetry_Int_Tables_number   1
_cell_volume   536.332
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.386  0.726  0.139  1.0
  Na  Na1  1  0.907  0.747  0.019  1.0
  Na  Na2  1  0.094  0.253  0.980  1.0
  Co  Co3  1  0.204  0.279  0.589  1.0
  Co  Co4  1  0.796  0.721  0.411  1.0
  Co  Co5  1  0.037  0.636  0.804  1.0
  Co  Co6  1  0.961  0.365  0.196  1.0
  Co  Co7  1  0.769  0.038  0.659  1.0
  Co  Co8  1  0.231  0.961  0.342  1.0
  Ag  Ag9  1  0.610  0.272  0.862  1.0
  P  P10  1  0.434  0.750  0.918  1.0
  P  P11  1  0.566  0.251  0.083  1.0
  P  P12  1  0.295  0.781  0.542  1.0
  P  P13  1  0.705  0.219  0.458  1.0
  P  P14  1  0.643  0.573  0.677  1.0
  P  P15  1  0.357  0.427  0.323  1.0
  P  P16  1  0.190  0.098  0.782  1.0
  P  P17  1  0.811  0.902  0.217  1.0
  O  O18  1  0.405  0.951  0.842  1.0
  O  O19  1  0.595  0.047  0.158  1.0
  O  O20  1  0.120  0.986  0.581  1.0
  O  O21  1  0.881  0.014  0.420  1.0
  O  O22  1  0.411  0.842  0.453  1.0
  O  O23  1  0.589  0.158  0.547  1.0
  O  O24  1  0.730  0.646  0.910  1.0
  O  O25  1  0.271  0.356  0.090  1.0
  O  O26  1  0.826  0.347  0.658  1.0
  O  O27  1  0.173  0.653  0.342  1.0
  O  O28  1  0.323  0.853  0.997  1.0
  O  O29  1  0.680  0.143  0.004  1.0
  O  O30  1  0.558  0.701  0.588  1.0
  O  O31  1  0.442  0.299  0.412  1.0
  O  O32  1  0.356  0.138  0.701  1.0
  O  O33  1  0.644  0.862  0.299  1.0
  O  O34  1  0.268  0.604  0.902  1.0
  O  O35  1  0.727  0.400  0.098  1.0
  O  O36  1  0.057  0.303  0.826  1.0
  O  O37  1  0.945  0.698  0.174  1.0
  O  O38  1  0.404  0.552  0.734  1.0
  O  O39  1  0.593  0.450  0.265  1.0
  O  O40  1  0.797  0.712  0.705  1.0
  O  O41  1  0.203  0.287  0.296  1.0
  O  O42  1  0.164  0.600  0.550  1.0
  O  O43  1  0.836  0.400  0.450  1.0
  O  O44  1  0.991  0.973  0.776  1.0
  O  O45  1  0.012  0.027  0.223  1.0
[/CIF]
.