The material described by XeOF4OsO3F2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one OsO3F2 cluster and two XeOF4 clusters. In the OsO3F2 cluster, Os(1) is bonded in a 6-coordinate geometry to one O(2), one O(3), one O(4), one F(3), and two equivalent F(2) atoms. There are three inequivalent O sites. In the first O site, O(2) is bonded in a single-bond geometry to one Os(1) atom. In the second O site, O(3) is bonded in a single-bond geometry to one Os(1) atom. In the third O site, O(4) is bonded in a single-bond geometry to one Os(1) atom. There are two inequivalent F sites. In the first F site, F(2) is bonded in a water-like geometry to two equivalent Os(1) atoms. In the second F site, F(3) is bonded in a single-bond geometry to one Os(1) atom. In each XeOF4 cluster, Xe(1) is bonded in a square pyramidal geometry to one O(1), one F(1), one F(4), one F(5), and one F(6) atom. O(1) is bonded in a single-bond geometry to one Xe(1) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Xe(1) atom. In the second F site, F(4) is bonded in a single-bond geometry to one Xe(1) atom. In the third F site, F(5) is bonded in a single-bond geometry to one Xe(1) atom. In the fourth F site, F(6) is bonded in a single-bond geometry to one Xe(1) atom. is represented by the CIF file [CIF]
data_OsXe(O2F3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.355
_cell_length_b   8.069
_cell_length_c   9.634
_cell_angle_alpha   80.771
_cell_angle_beta   81.610
_cell_angle_gamma   87.933
_symmetry_Int_Tables_number   1
_cell_volume   406.472
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Os  Os0  1  0.121  0.666  0.365  1.0
  Os  Os1  1  0.879  0.334  0.635  1.0
  Xe  Xe2  1  0.441  0.779  0.837  1.0
  Xe  Xe3  1  0.559  0.221  0.163  1.0
  O  O4  1  0.266  0.951  0.910  1.0
  O  O5  1  0.734  0.049  0.090  1.0
  O  O6  1  0.983  0.276  0.795  1.0
  O  O7  1  0.411  0.754  0.346  1.0
  O  O8  1  0.589  0.246  0.654  1.0
  O  O9  1  0.938  0.789  0.470  1.0
  O  O10  1  0.017  0.724  0.205  1.0
  O  O11  1  0.062  0.211  0.530  1.0
  F  F12  1  0.136  0.626  0.876  1.0
  F  F13  1  0.864  0.374  0.124  1.0
  F  F14  1  0.178  0.514  0.565  1.0
  F  F15  1  0.729  0.544  0.690  1.0
  F  F16  1  0.458  0.322  0.970  1.0
  F  F17  1  0.271  0.456  0.310  1.0
  F  F18  1  0.768  0.911  0.788  1.0
  F  F19  1  0.232  0.089  0.212  1.0
  F  F20  1  0.642  0.138  0.361  1.0
  F  F21  1  0.822  0.486  0.435  1.0
  F  F22  1  0.358  0.862  0.639  1.0
  F  F23  1  0.542  0.678  0.030  1.0
[/CIF]
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The material described by XeOF4OsO3F2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one OsO3F2 cluster and two XeOF4 clusters. In the OsO3F2 cluster, Os(1) is bonded in a 6-coordinate geometry to one O(2), one O(3), one O(4), one F(3), and two equivalent F(2) atoms. There are three inequivalent O sites. In the first O site, O(2) is bonded in a single-bond geometry to one Os(1) atom. In the second O site, O(3) is bonded in a single-bond geometry to one Os(1) atom. In the third O site, O(4) is bonded in a single-bond geometry to one Os(1) atom. There are two inequivalent F sites. In the first F site, F(2) is bonded in a water-like geometry to two equivalent Os(1) atoms. In the second F site, F(3) is bonded in a single-bond geometry to one Os(1) atom. In each XeOF4 cluster, Xe(1) is bonded in a square pyramidal geometry to one O(1), one F(1), one F(4), one F(5), and one F(6) atom. O(1) is bonded in a single-bond geometry to one Xe(1) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Xe(1) atom. In the second F site, F(4) is bonded in a single-bond geometry to one Xe(1) atom. In the third F site, F(5) is bonded in a single-bond geometry to one Xe(1) atom. In the fourth F site, F(6) is bonded in a single-bond geometry to one Xe(1) atom. is represented by the CIF file [CIF]
data_OsXe(O2F3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.355
_cell_length_b   8.069
_cell_length_c   9.634
_cell_angle_alpha   80.771
_cell_angle_beta   81.610
_cell_angle_gamma   87.933
_symmetry_Int_Tables_number   1
_cell_volume   406.472
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Os  Os0  1  0.121  0.666  0.365  1.0
  Os  Os1  1  0.879  0.334  0.635  1.0
  Xe  Xe2  1  0.441  0.779  0.837  1.0
  Xe  Xe3  1  0.559  0.221  0.163  1.0
  O  O4  1  0.266  0.951  0.910  1.0
  O  O5  1  0.734  0.049  0.090  1.0
  O  O6  1  0.983  0.276  0.795  1.0
  O  O7  1  0.411  0.754  0.346  1.0
  O  O8  1  0.589  0.246  0.654  1.0
  O  O9  1  0.938  0.789  0.470  1.0
  O  O10  1  0.017  0.724  0.205  1.0
  O  O11  1  0.062  0.211  0.530  1.0
  F  F12  1  0.136  0.626  0.876  1.0
  F  F13  1  0.864  0.374  0.124  1.0
  F  F14  1  0.178  0.514  0.565  1.0
  F  F15  1  0.729  0.544  0.690  1.0
  F  F16  1  0.458  0.322  0.970  1.0
  F  F17  1  0.271  0.456  0.310  1.0
  F  F18  1  0.768  0.911  0.788  1.0
  F  F19  1  0.232  0.089  0.212  1.0
  F  F20  1  0.642  0.138  0.361  1.0
  F  F21  1  0.822  0.486  0.435  1.0
  F  F22  1  0.358  0.862  0.639  1.0
  F  F23  1  0.542  0.678  0.030  1.0
[/CIF]
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