The material structure described by Re3S4O3(O2)3 crystallizes in the trigonal R-3 space group. The structure is zero-dimensional and consists of eighteen hydrogen peroxide molecules and three Re3S4O3 clusters. In each Re3S4O3 cluster, Re(1) is bonded in a distorted single-bond geometry to one S(1), three equivalent S(2), and one O(1) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted T-shaped geometry to three equivalent Re(1) atoms. In the second S site, S(2) is bonded in a distorted T-shaped geometry to three equivalent Re(1) atoms. O(1) is bonded in a single-bond geometry to one Re(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Re3S4O9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.248
_cell_length_b   10.248
_cell_length_c   10.248
_cell_angle_alpha   110.792
_cell_angle_beta   110.792
_cell_angle_gamma   110.792
_symmetry_Int_Tables_number   1
_cell_volume   785.318
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.587  0.792  0.578  1.0
  Re  Re1  1  0.578  0.587  0.792  1.0
  Re  Re2  1  0.792  0.578  0.587  1.0
  Re  Re3  1  0.413  0.208  0.422  1.0
  Re  Re4  1  0.422  0.413  0.208  1.0
  Re  Re5  1  0.208  0.422  0.413  1.0
  S  S6  1  0.783  0.783  0.783  1.0
  S  S7  1  0.217  0.217  0.217  1.0
  S  S8  1  0.420  0.685  0.673  1.0
  S  S9  1  0.673  0.420  0.685  1.0
  S  S10  1  0.685  0.673  0.420  1.0
  S  S11  1  0.580  0.315  0.327  1.0
  S  S12  1  0.327  0.580  0.315  1.0
  S  S13  1  0.315  0.327  0.580  1.0
  O  O14  1  0.645  0.990  0.630  1.0
  O  O15  1  0.630  0.645  0.990  1.0
  O  O16  1  0.990  0.630  0.645  1.0
  O  O17  1  0.355  0.010  0.370  1.0
  O  O18  1  0.370  0.355  0.010  1.0
  O  O19  1  0.010  0.370  0.355  1.0
  O  O20  1  0.616  0.007  0.090  1.0
  O  O21  1  0.090  0.616  0.007  1.0
  O  O22  1  0.007  0.090  0.616  1.0
  O  O23  1  0.105  0.044  0.632  1.0
  O  O24  1  0.632  0.105  0.044  1.0
  O  O25  1  0.044  0.632  0.105  1.0
  O  O26  1  0.384  0.993  0.910  1.0
  O  O27  1  0.910  0.384  0.993  1.0
  O  O28  1  0.993  0.910  0.384  1.0
  O  O29  1  0.895  0.956  0.368  1.0
  O  O30  1  0.368  0.895  0.956  1.0
  O  O31  1  0.956  0.368  0.895  1.0
[/CIF]
.
The material structure described by Re3S4O3(O2)3 crystallizes in the trigonal R-3 space group. The structure is zero-dimensional and consists of eighteen hydrogen peroxide molecules and three Re3S4O3 clusters. In each Re3S4O3 cluster, Re(1) is bonded in a distorted single-bond geometry to one S(1), three equivalent S(2), and one O(1) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted T-shaped geometry to three equivalent Re(1) atoms. In the second S site, S(2) is bonded in a distorted T-shaped geometry to three equivalent Re(1) atoms. O(1) is bonded in a single-bond geometry to one Re(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Re3S4O9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.248
_cell_length_b   10.248
_cell_length_c   10.248
_cell_angle_alpha   110.792
_cell_angle_beta   110.792
_cell_angle_gamma   110.792
_symmetry_Int_Tables_number   1
_cell_volume   785.318
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.587  0.792  0.578  1.0
  Re  Re1  1  0.578  0.587  0.792  1.0
  Re  Re2  1  0.792  0.578  0.587  1.0
  Re  Re3  1  0.413  0.208  0.422  1.0
  Re  Re4  1  0.422  0.413  0.208  1.0
  Re  Re5  1  0.208  0.422  0.413  1.0
  S  S6  1  0.783  0.783  0.783  1.0
  S  S7  1  0.217  0.217  0.217  1.0
  S  S8  1  0.420  0.685  0.673  1.0
  S  S9  1  0.673  0.420  0.685  1.0
  S  S10  1  0.685  0.673  0.420  1.0
  S  S11  1  0.580  0.315  0.327  1.0
  S  S12  1  0.327  0.580  0.315  1.0
  S  S13  1  0.315  0.327  0.580  1.0
  O  O14  1  0.645  0.990  0.630  1.0
  O  O15  1  0.630  0.645  0.990  1.0
  O  O16  1  0.990  0.630  0.645  1.0
  O  O17  1  0.355  0.010  0.370  1.0
  O  O18  1  0.370  0.355  0.010  1.0
  O  O19  1  0.010  0.370  0.355  1.0
  O  O20  1  0.616  0.007  0.090  1.0
  O  O21  1  0.090  0.616  0.007  1.0
  O  O22  1  0.007  0.090  0.616  1.0
  O  O23  1  0.105  0.044  0.632  1.0
  O  O24  1  0.632  0.105  0.044  1.0
  O  O25  1  0.044  0.632  0.105  1.0
  O  O26  1  0.384  0.993  0.910  1.0
  O  O27  1  0.910  0.384  0.993  1.0
  O  O28  1  0.993  0.910  0.384  1.0
  O  O29  1  0.895  0.956  0.368  1.0
  O  O30  1  0.368  0.895  0.956  1.0
  O  O31  1  0.956  0.368  0.895  1.0
[/CIF]
.