The material described by CsAu2F7 crystallizes in the monoclinic C2/c space group. Cs(1) is bonded in a 10-coordinate geometry to two equivalent F(1), four equivalent F(2), and four equivalent F(3) atoms. Au(1) is bonded in a rectangular see-saw-like geometry to one F(1), one F(2), one F(3), and one F(4) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a distorted single-bond geometry to one Cs(1) and one Au(1) atom. In the second F site, F(2) is bonded in a distorted single-bond geometry to two equivalent Cs(1) and one Au(1) atom. In the third F site, F(3) is bonded in a distorted single-bond geometry to two equivalent Cs(1) and one Au(1) atom. In the fourth F site, F(4) is bonded in a bent 120 degrees geometry to two equivalent Au(1) atoms. is represented by the CIF card [CIF]
data_CsAu2F7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.843
_cell_length_b   7.843
_cell_length_c   7.385
_cell_angle_alpha   65.325
_cell_angle_beta   65.323
_cell_angle_gamma   86.680
_symmetry_Int_Tables_number   1
_cell_volume   371.352
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.306  0.694  0.250  1.0
  Cs  Cs1  1  0.694  0.306  0.750  1.0
  Au  Au2  1  0.086  0.288  0.145  1.0
  Au  Au3  1  0.712  0.914  0.355  1.0
  Au  Au4  1  0.914  0.712  0.855  1.0
  Au  Au5  1  0.288  0.086  0.645  1.0
  F  F6  1  0.906  0.813  0.450  1.0
  F  F7  1  0.663  0.599  0.954  1.0
  F  F8  1  0.813  0.906  0.950  1.0
  F  F9  1  0.514  0.015  0.264  1.0
  F  F10  1  0.187  0.094  0.050  1.0
  F  F11  1  0.486  0.985  0.736  1.0
  F  F12  1  0.816  0.184  0.250  1.0
  F  F13  1  0.985  0.486  0.236  1.0
  F  F14  1  0.015  0.514  0.764  1.0
  F  F15  1  0.337  0.401  0.046  1.0
  F  F16  1  0.094  0.187  0.550  1.0
  F  F17  1  0.401  0.337  0.546  1.0
  F  F18  1  0.184  0.816  0.750  1.0
  F  F19  1  0.599  0.663  0.454  1.0
[/CIF]
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The material described by CsAu2F7 crystallizes in the monoclinic C2/c space group. Cs(1) is bonded in a 10-coordinate geometry to two equivalent F(1), four equivalent F(2), and four equivalent F(3) atoms. Au(1) is bonded in a rectangular see-saw-like geometry to one F(1), one F(2), one F(3), and one F(4) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a distorted single-bond geometry to one Cs(1) and one Au(1) atom. In the second F site, F(2) is bonded in a distorted single-bond geometry to two equivalent Cs(1) and one Au(1) atom. In the third F site, F(3) is bonded in a distorted single-bond geometry to two equivalent Cs(1) and one Au(1) atom. In the fourth F site, F(4) is bonded in a bent 120 degrees geometry to two equivalent Au(1) atoms. is represented by the CIF card [CIF]
data_CsAu2F7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.843
_cell_length_b   7.843
_cell_length_c   7.385
_cell_angle_alpha   65.325
_cell_angle_beta   65.323
_cell_angle_gamma   86.680
_symmetry_Int_Tables_number   1
_cell_volume   371.352
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.306  0.694  0.250  1.0
  Cs  Cs1  1  0.694  0.306  0.750  1.0
  Au  Au2  1  0.086  0.288  0.145  1.0
  Au  Au3  1  0.712  0.914  0.355  1.0
  Au  Au4  1  0.914  0.712  0.855  1.0
  Au  Au5  1  0.288  0.086  0.645  1.0
  F  F6  1  0.906  0.813  0.450  1.0
  F  F7  1  0.663  0.599  0.954  1.0
  F  F8  1  0.813  0.906  0.950  1.0
  F  F9  1  0.514  0.015  0.264  1.0
  F  F10  1  0.187  0.094  0.050  1.0
  F  F11  1  0.486  0.985  0.736  1.0
  F  F12  1  0.816  0.184  0.250  1.0
  F  F13  1  0.985  0.486  0.236  1.0
  F  F14  1  0.015  0.514  0.764  1.0
  F  F15  1  0.337  0.401  0.046  1.0
  F  F16  1  0.094  0.187  0.550  1.0
  F  F17  1  0.401  0.337  0.546  1.0
  F  F18  1  0.184  0.816  0.750  1.0
  F  F19  1  0.599  0.663  0.454  1.0
[/CIF]
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