The structure described by Fe5O3F7 is Hydrophilite-derived structured and crystallizes in the monoclinic C2 space group. There are six inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to one O(1), one O(3), one F(1), one F(2), one F(6), and one F(8) atom to form a mixture of corner and edge-sharing FeO2F4 octahedra. The corner-sharing octahedral tilt angles range from 46-57°. In the second Fe site, Fe(2) is bonded to one O(1), one O(2), one F(3), one F(5), one F(7), and one F(8) atom to form FeO2F4 octahedra that share corners with four equivalent Fe(6)O2F4 octahedra, corners with four equivalent Fe(5)OF5 octahedra,  an edgeedge with one Fe(1)O2F4 octahedra, and  an edgeedge with one Fe(3)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 34-56°. In the third Fe site, Fe(3) is bonded to two equivalent O(2), two equivalent F(4), and two equivalent F(7) atoms to form FeO2F4 octahedra that share corners with eight equivalent Fe(5)OF5 octahedra and edges with two equivalent Fe(2)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 46-55°. In the fourth Fe site, Fe(4) is bonded to two equivalent O(3), one F(1), one F(6), and two equivalent F(2) atoms to form a mixture of corner and edge-sharing FeO2F4 octahedra. The corner-sharing octahedral tilt angles range from 46-51°. In the fifth Fe site, Fe(5) is bonded to one O(2), one F(3), one F(5), one F(7), and two equivalent F(4) atoms to form FeOF5 octahedra that share corners with four equivalent Fe(2)O2F4 octahedra, corners with four equivalent Fe(3)O2F4 octahedra,  an edgeedge with one Fe(6)O2F4 octahedra, and  an edgeedge with one Fe(5)OF5 octahedra. The corner-sharing octahedral tilt angles range from 46-56°. In the sixth Fe site, Fe(6) is bonded to one O(1), one O(3), one F(2), one F(3), one F(5), and one F(8) atom to form FeO2F4 octahedra that share corners with four equivalent Fe(1)O2F4 octahedra, corners with four equivalent Fe(2)O2F4 octahedra,  an edgeedge with one Fe(4)O2F4 octahedra, and  an edgeedge with one Fe(5)OF5 octahedra. The corner-sharing octahedral tilt angles range from 34-57°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Fe(1), one Fe(2), and one Fe(6) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Fe(2), one Fe(3), and one Fe(5) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Fe(1), one Fe(4), and one Fe(6) atom. There are eight inequivalent F sites. In the first F site, F(1) is bonded in a trigonal planar geometry to one Fe(4) and two equivalent Fe(1) atoms. In the second F site, F(2) is bonded in a distorted T-shaped geometry to one Fe(1), one Fe(4), and one Fe(6) atom. In the third F site, F(3) is bonded in a trigonal planar geometry to one Fe(2), one Fe(5), and one Fe(6) atom. In the fourth F site, F(4) is bonded in a distorted trigonal planar geometry to one Fe(3) and two equivalent Fe(5) atoms. In the fifth F site, F(5) is bonded in a distorted trigonal planar geometry to one Fe(2), one Fe(5), and one Fe(6) atom. In the sixth F site, F(6) is bonded in a trigonal planar geometry to one Fe(4) and two equivalent Fe(1) atoms. In the seventh F site, F(7) is bonded in a distorted T-shaped geometry to one Fe(2), one Fe(3), and one Fe(5) atom. In the eighth F site, F(8) is bonded in a distorted T-shaped geometry to one Fe(1), one Fe(2), and one Fe(6) atom. is represented by the CIF file [CIF]
data_Fe5O3F7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.816
_cell_length_b   4.816
_cell_length_c   15.715
_cell_angle_alpha   89.921
_cell_angle_beta   89.921
_cell_angle_gamma   88.639
_symmetry_Int_Tables_number   1
_cell_volume   364.308
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Fe  Fe0  1  0.966  0.981  0.395  1.0
  Fe  Fe1  1  0.019  0.034  0.605  1.0
  Fe  Fe2  1  0.972  0.020  0.800  1.0
  Fe  Fe3  1  0.975  0.025  0.000  1.0
  Fe  Fe4  1  0.980  0.028  0.200  1.0
  Fe  Fe5  1  0.497  0.503  0.500  1.0
  Fe  Fe6  1  0.512  0.489  0.898  1.0
  Fe  Fe7  1  0.509  0.470  0.692  1.0
  Fe  Fe8  1  0.511  0.488  0.102  1.0
  Fe  Fe9  1  0.530  0.491  0.308  1.0
  O  O10  1  0.805  0.201  0.705  1.0
  O  O11  1  0.812  0.186  0.900  1.0
  O  O12  1  0.814  0.188  0.100  1.0
  O  O13  1  0.799  0.195  0.295  1.0
  O  O14  1  0.321  0.329  0.596  1.0
  O  O15  1  0.671  0.679  0.404  1.0
  F  F16  1  0.794  0.206  0.500  1.0
  F  F17  1  0.299  0.298  0.401  1.0
  F  F18  1  0.301  0.297  0.795  1.0
  F  F19  1  0.296  0.292  1.000  1.0
  F  F20  1  0.302  0.300  0.206  1.0
  F  F21  1  0.702  0.701  0.599  1.0
  F  F22  1  0.700  0.698  0.794  1.0
  F  F23  1  0.708  0.704  0.000  1.0
  F  F24  1  0.703  0.699  0.205  1.0
  F  F25  1  0.193  0.807  0.500  1.0
  F  F26  1  0.194  0.804  0.901  1.0
  F  F27  1  0.212  0.795  0.710  1.0
  F  F28  1  0.205  0.788  0.290  1.0
  F  F29  1  0.196  0.806  0.099  1.0
[/CIF]
.
The structure described by Fe5O3F7 is Hydrophilite-derived structured and crystallizes in the monoclinic C2 space group. There are six inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to one O(1), one O(3), one F(1), one F(2), one F(6), and one F(8) atom to form a mixture of corner and edge-sharing FeO2F4 octahedra. The corner-sharing octahedral tilt angles range from 46-57°. In the second Fe site, Fe(2) is bonded to one O(1), one O(2), one F(3), one F(5), one F(7), and one F(8) atom to form FeO2F4 octahedra that share corners with four equivalent Fe(6)O2F4 octahedra, corners with four equivalent Fe(5)OF5 octahedra,  an edgeedge with one Fe(1)O2F4 octahedra, and  an edgeedge with one Fe(3)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 34-56°. In the third Fe site, Fe(3) is bonded to two equivalent O(2), two equivalent F(4), and two equivalent F(7) atoms to form FeO2F4 octahedra that share corners with eight equivalent Fe(5)OF5 octahedra and edges with two equivalent Fe(2)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 46-55°. In the fourth Fe site, Fe(4) is bonded to two equivalent O(3), one F(1), one F(6), and two equivalent F(2) atoms to form a mixture of corner and edge-sharing FeO2F4 octahedra. The corner-sharing octahedral tilt angles range from 46-51°. In the fifth Fe site, Fe(5) is bonded to one O(2), one F(3), one F(5), one F(7), and two equivalent F(4) atoms to form FeOF5 octahedra that share corners with four equivalent Fe(2)O2F4 octahedra, corners with four equivalent Fe(3)O2F4 octahedra,  an edgeedge with one Fe(6)O2F4 octahedra, and  an edgeedge with one Fe(5)OF5 octahedra. The corner-sharing octahedral tilt angles range from 46-56°. In the sixth Fe site, Fe(6) is bonded to one O(1), one O(3), one F(2), one F(3), one F(5), and one F(8) atom to form FeO2F4 octahedra that share corners with four equivalent Fe(1)O2F4 octahedra, corners with four equivalent Fe(2)O2F4 octahedra,  an edgeedge with one Fe(4)O2F4 octahedra, and  an edgeedge with one Fe(5)OF5 octahedra. The corner-sharing octahedral tilt angles range from 34-57°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Fe(1), one Fe(2), and one Fe(6) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Fe(2), one Fe(3), and one Fe(5) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Fe(1), one Fe(4), and one Fe(6) atom. There are eight inequivalent F sites. In the first F site, F(1) is bonded in a trigonal planar geometry to one Fe(4) and two equivalent Fe(1) atoms. In the second F site, F(2) is bonded in a distorted T-shaped geometry to one Fe(1), one Fe(4), and one Fe(6) atom. In the third F site, F(3) is bonded in a trigonal planar geometry to one Fe(2), one Fe(5), and one Fe(6) atom. In the fourth F site, F(4) is bonded in a distorted trigonal planar geometry to one Fe(3) and two equivalent Fe(5) atoms. In the fifth F site, F(5) is bonded in a distorted trigonal planar geometry to one Fe(2), one Fe(5), and one Fe(6) atom. In the sixth F site, F(6) is bonded in a trigonal planar geometry to one Fe(4) and two equivalent Fe(1) atoms. In the seventh F site, F(7) is bonded in a distorted T-shaped geometry to one Fe(2), one Fe(3), and one Fe(5) atom. In the eighth F site, F(8) is bonded in a distorted T-shaped geometry to one Fe(1), one Fe(2), and one Fe(6) atom. is represented by the CIF file [CIF]
data_Fe5O3F7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.816
_cell_length_b   4.816
_cell_length_c   15.715
_cell_angle_alpha   89.921
_cell_angle_beta   89.921
_cell_angle_gamma   88.639
_symmetry_Int_Tables_number   1
_cell_volume   364.308
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Fe  Fe0  1  0.966  0.981  0.395  1.0
  Fe  Fe1  1  0.019  0.034  0.605  1.0
  Fe  Fe2  1  0.972  0.020  0.800  1.0
  Fe  Fe3  1  0.975  0.025  0.000  1.0
  Fe  Fe4  1  0.980  0.028  0.200  1.0
  Fe  Fe5  1  0.497  0.503  0.500  1.0
  Fe  Fe6  1  0.512  0.489  0.898  1.0
  Fe  Fe7  1  0.509  0.470  0.692  1.0
  Fe  Fe8  1  0.511  0.488  0.102  1.0
  Fe  Fe9  1  0.530  0.491  0.308  1.0
  O  O10  1  0.805  0.201  0.705  1.0
  O  O11  1  0.812  0.186  0.900  1.0
  O  O12  1  0.814  0.188  0.100  1.0
  O  O13  1  0.799  0.195  0.295  1.0
  O  O14  1  0.321  0.329  0.596  1.0
  O  O15  1  0.671  0.679  0.404  1.0
  F  F16  1  0.794  0.206  0.500  1.0
  F  F17  1  0.299  0.298  0.401  1.0
  F  F18  1  0.301  0.297  0.795  1.0
  F  F19  1  0.296  0.292  1.000  1.0
  F  F20  1  0.302  0.300  0.206  1.0
  F  F21  1  0.702  0.701  0.599  1.0
  F  F22  1  0.700  0.698  0.794  1.0
  F  F23  1  0.708  0.704  0.000  1.0
  F  F24  1  0.703  0.699  0.205  1.0
  F  F25  1  0.193  0.807  0.500  1.0
  F  F26  1  0.194  0.804  0.901  1.0
  F  F27  1  0.212  0.795  0.710  1.0
  F  F28  1  0.205  0.788  0.290  1.0
  F  F29  1  0.196  0.806  0.099  1.0
[/CIF]
.