The material described by Li6V5O12 crystallizes in the monoclinic C2 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to two equivalent O(3), two equivalent O(4), and two equivalent O(6) atoms to form LiO6 octahedra that share corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Li(3)O6 octahedra, corners with two equivalent V(4)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent V(4)O6 octahedra, edges with three equivalent Li(4)O6 octahedra, and edges with three equivalent V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-15°. In the second Li site, Li(2) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form distorted LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra, edges with three equivalent Li(3)O6 octahedra, and edges with three equivalent V(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-15°. In the third Li site, Li(3) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form distorted LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra, edges with three equivalent Li(2)O6 octahedra, and edges with three equivalent V(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-16°. In the fourth Li site, Li(4) is bonded to two equivalent O(3), two equivalent O(4), and two equivalent O(6) atoms to form LiO6 octahedra that share corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Li(3)O6 octahedra, corners with two equivalent V(4)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent V(4)O6 octahedra, edges with three equivalent Li(1)O6 octahedra, and edges with three equivalent V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-16°. There are four inequivalent V sites. In the first V site, V(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(5) atoms to form VO6 octahedra that share corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Li(3)O6 octahedra, corners with two equivalent V(4)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent V(4)O6 octahedra, and edges with three equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-15°. In the second V site, V(2) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(5) atoms to form VO6 octahedra that share corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Li(3)O6 octahedra, corners with two equivalent V(4)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent V(4)O6 octahedra, and edges with three equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-13°. In the third V site, V(3) is bonded to two equivalent O(3), two equivalent O(4), and two equivalent O(6) atoms to form VO6 octahedra that share corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Li(3)O6 octahedra, corners with two equivalent V(4)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent V(4)O6 octahedra, edges with three equivalent Li(1)O6 octahedra, and edges with three equivalent Li(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-11°. In the fourth V site, V(4) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form VO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra, edges with three equivalent Li(2)O6 octahedra, and edges with three equivalent Li(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-14°. There are six inequivalent O sites. In the first O site, O(1) is bonded to one Li(2), one Li(3), one V(1), one V(2), and one V(4) atom to form OLi2V3 square pyramids that share  a cornercorner with one O(3)Li4V2 octahedra,  a cornercorner with one O(4)Li4V2 octahedra,  a cornercorner with one O(6)Li4V2 octahedra, corners with three equivalent O(2)Li2V3 square pyramids, corners with three equivalent O(5)Li2V3 square pyramids,  an edgeedge with one O(3)Li4V2 octahedra,  an edgeedge with one O(4)Li4V2 octahedra,  an edgeedge with one O(6)Li4V2 octahedra,  an edgeedge with one O(1)Li2V3 square pyramid, edges with two equivalent O(2)Li2V3 square pyramids, and edges with two equivalent O(5)Li2V3 square pyramids. The corner-sharing octahedral tilt angles range from 5-14°. In the second O site, O(2) is bonded to one Li(2), one Li(3), one V(1), one V(2), and one V(4) atom to form OLi2V3 square pyramids that share  a cornercorner with one O(3)Li4V2 octahedra,  a cornercorner with one O(4)Li4V2 octahedra,  a cornercorner with one O(6)Li4V2 octahedra,  a cornercorner with one O(5)Li2V3 square pyramid, corners with two equivalent O(2)Li2V3 square pyramids, corners with three equivalent O(1)Li2V3 square pyramids,  an edgeedge with one O(3)Li4V2 octahedra,  an edgeedge with one O(4)Li4V2 octahedra,  an edgeedge with one O(6)Li4V2 octahedra, edges with two equivalent O(1)Li2V3 square pyramids, and edges with three equivalent O(5)Li2V3 square pyramids. The corner-sharing octahedral tilt angles range from 2-21°. In the third O site, O(3) is bonded to one Li(1), one Li(2), one Li(3), one Li(4), one V(3), and one V(4) atom to form OLi4V2 octahedra that share  a cornercorner with one O(3)Li4V2 octahedra,  a cornercorner with one O(4)Li4V2 octahedra,  a cornercorner with one O(6)Li4V2 octahedra,  a cornercorner with one O(1)Li2V3 square pyramid,  a cornercorner with one O(2)Li2V3 square pyramid,  a cornercorner with one O(5)Li2V3 square pyramid,  an edgeedge with one O(3)Li4V2 octahedra, edges with four equivalent O(4)Li4V2 octahedra, edges with four equivalent O(6)Li4V2 octahedra,  an edgeedge with one O(1)Li2V3 square pyramid,  an edgeedge with one O(2)Li2V3 square pyramid, and  an edgeedge with one O(5)Li2V3 square pyramid. The corner-sharing octahedral tilt angles range from 5-7°. In the fourth O site, O(4) is bonded to one Li(1), one Li(2), one Li(3), one Li(4), one V(3), and one V(4) atom to form OLi4V2 octahedra that share  a cornercorner with one O(3)Li4V2 octahedra,  a cornercorner with one O(4)Li4V2 octahedra,  a cornercorner with one O(6)Li4V2 octahedra,  a cornercorner with one O(1)Li2V3 square pyramid,  a cornercorner with one O(2)Li2V3 square pyramid,  a cornercorner with one O(5)Li2V3 square pyramid,  an edgeedge with one O(4)Li4V2 octahedra, edges with four equivalent O(3)Li4V2 octahedra, edges with four equivalent O(6)Li4V2 octahedra,  an edgeedge with one O(1)Li2V3 square pyramid,  an edgeedge with one O(2)Li2V3 square pyramid, and  an edgeedge with one O(5)Li2V3 square pyramid. The corner-sharing octahedral tilt angles range from 6-13°. In the fifth O site, O(5) is bonded to one Li(2), one Li(3), one V(1), one V(2), and one V(4) atom to form distorted OLi2V3 square pyramids that share  a cornercorner with one O(3)Li4V2 octahedra,  a cornercorner with one O(4)Li4V2 octahedra,  a cornercorner with one O(6)Li4V2 octahedra,  a cornercorner with one O(2)Li2V3 square pyramid, corners with two equivalent O(5)Li2V3 square pyramids, corners with three equivalent O(1)Li2V3 square pyramids,  an edgeedge with one O(3)Li4V2 octahedra,  an edgeedge with one O(4)Li4V2 octahedra,  an edgeedge with one O(6)Li4V2 octahedra, edges with two equivalent O(1)Li2V3 square pyramids, and edges with three equivalent O(2)Li2V3 square pyramids. The corner-sharing octahedral tilt angles range from 1-14°. In the sixth O site, O(6) is bonded to one Li(1), one Li(2), one Li(3), one Li(4), one V(3), and one V(4) atom to form distorted OLi4V2 octahedra that share  a cornercorner with one O(3)Li4V2 octahedra,  a cornercorner with one O(4)Li4V2 octahedra,  a cornercorner with one O(6)Li4V2 octahedra,  a cornercorner with one O(1)Li2V3 square pyramid,  a cornercorner with one O(2)Li2V3 square pyramid,  a cornercorner with one O(5)Li2V3 square pyramid,  an edgeedge with one O(6)Li4V2 octahedra, edges with four equivalent O(3)Li4V2 octahedra, edges with four equivalent O(4)Li4V2 octahedra,  an edgeedge with one O(1)Li2V3 square pyramid,  an edgeedge with one O(2)Li2V3 square pyramid, and  an edgeedge with one O(5)Li2V3 square pyramid. The corner-sharing octahedral tilt angles range from 3-13°. is represented by the CIF card [CIF]
data_Li6V5O12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.046
_cell_length_b   5.046
_cell_length_c   9.545
_cell_angle_alpha   86.342
_cell_angle_beta   86.342
_cell_angle_gamma   116.195
_symmetry_Int_Tables_number   1
_cell_volume   216.472
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.758  0.242  0.000  1.0
  Li  Li1  1  0.832  0.644  0.757  1.0
  Li  Li2  1  0.694  0.868  0.239  1.0
  Li  Li3  1  0.356  0.168  0.243  1.0
  Li  Li4  1  0.132  0.306  0.761  1.0
  Li  Li5  1  0.086  0.914  0.000  1.0
  V  V6  1  0.921  0.079  0.500  1.0
  V  V7  1  0.571  0.429  0.500  1.0
  V  V8  1  0.428  0.572  0.000  1.0
  V  V9  1  0.479  0.989  0.750  1.0
  V  V10  1  0.011  0.521  0.250  1.0
  O  O11  1  0.819  0.332  0.632  1.0
  O  O12  1  0.668  0.181  0.368  1.0
  O  O13  1  0.918  0.764  0.377  1.0
  O  O14  1  0.735  0.544  0.124  1.0
  O  O15  1  0.738  0.907  0.888  1.0
  O  O16  1  0.456  0.265  0.876  1.0
  O  O17  1  0.572  0.752  0.625  1.0
  O  O18  1  0.236  0.082  0.623  1.0
  O  O19  1  0.248  0.428  0.375  1.0
  O  O20  1  0.361  0.831  0.132  1.0
  O  O21  1  0.093  0.262  0.112  1.0
  O  O22  1  0.169  0.639  0.868  1.0
[/CIF]
.
The material described by Li6V5O12 crystallizes in the monoclinic C2 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to two equivalent O(3), two equivalent O(4), and two equivalent O(6) atoms to form LiO6 octahedra that share corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Li(3)O6 octahedra, corners with two equivalent V(4)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent V(4)O6 octahedra, edges with three equivalent Li(4)O6 octahedra, and edges with three equivalent V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-15°. In the second Li site, Li(2) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form distorted LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra, edges with three equivalent Li(3)O6 octahedra, and edges with three equivalent V(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-15°. In the third Li site, Li(3) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form distorted LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra, edges with three equivalent Li(2)O6 octahedra, and edges with three equivalent V(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-16°. In the fourth Li site, Li(4) is bonded to two equivalent O(3), two equivalent O(4), and two equivalent O(6) atoms to form LiO6 octahedra that share corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Li(3)O6 octahedra, corners with two equivalent V(4)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent V(4)O6 octahedra, edges with three equivalent Li(1)O6 octahedra, and edges with three equivalent V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-16°. There are four inequivalent V sites. In the first V site, V(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(5) atoms to form VO6 octahedra that share corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Li(3)O6 octahedra, corners with two equivalent V(4)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent V(4)O6 octahedra, and edges with three equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-15°. In the second V site, V(2) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(5) atoms to form VO6 octahedra that share corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Li(3)O6 octahedra, corners with two equivalent V(4)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent V(4)O6 octahedra, and edges with three equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-13°. In the third V site, V(3) is bonded to two equivalent O(3), two equivalent O(4), and two equivalent O(6) atoms to form VO6 octahedra that share corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Li(3)O6 octahedra, corners with two equivalent V(4)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent V(4)O6 octahedra, edges with three equivalent Li(1)O6 octahedra, and edges with three equivalent Li(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-11°. In the fourth V site, V(4) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form VO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra, edges with three equivalent Li(2)O6 octahedra, and edges with three equivalent Li(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-14°. There are six inequivalent O sites. In the first O site, O(1) is bonded to one Li(2), one Li(3), one V(1), one V(2), and one V(4) atom to form OLi2V3 square pyramids that share  a cornercorner with one O(3)Li4V2 octahedra,  a cornercorner with one O(4)Li4V2 octahedra,  a cornercorner with one O(6)Li4V2 octahedra, corners with three equivalent O(2)Li2V3 square pyramids, corners with three equivalent O(5)Li2V3 square pyramids,  an edgeedge with one O(3)Li4V2 octahedra,  an edgeedge with one O(4)Li4V2 octahedra,  an edgeedge with one O(6)Li4V2 octahedra,  an edgeedge with one O(1)Li2V3 square pyramid, edges with two equivalent O(2)Li2V3 square pyramids, and edges with two equivalent O(5)Li2V3 square pyramids. The corner-sharing octahedral tilt angles range from 5-14°. In the second O site, O(2) is bonded to one Li(2), one Li(3), one V(1), one V(2), and one V(4) atom to form OLi2V3 square pyramids that share  a cornercorner with one O(3)Li4V2 octahedra,  a cornercorner with one O(4)Li4V2 octahedra,  a cornercorner with one O(6)Li4V2 octahedra,  a cornercorner with one O(5)Li2V3 square pyramid, corners with two equivalent O(2)Li2V3 square pyramids, corners with three equivalent O(1)Li2V3 square pyramids,  an edgeedge with one O(3)Li4V2 octahedra,  an edgeedge with one O(4)Li4V2 octahedra,  an edgeedge with one O(6)Li4V2 octahedra, edges with two equivalent O(1)Li2V3 square pyramids, and edges with three equivalent O(5)Li2V3 square pyramids. The corner-sharing octahedral tilt angles range from 2-21°. In the third O site, O(3) is bonded to one Li(1), one Li(2), one Li(3), one Li(4), one V(3), and one V(4) atom to form OLi4V2 octahedra that share  a cornercorner with one O(3)Li4V2 octahedra,  a cornercorner with one O(4)Li4V2 octahedra,  a cornercorner with one O(6)Li4V2 octahedra,  a cornercorner with one O(1)Li2V3 square pyramid,  a cornercorner with one O(2)Li2V3 square pyramid,  a cornercorner with one O(5)Li2V3 square pyramid,  an edgeedge with one O(3)Li4V2 octahedra, edges with four equivalent O(4)Li4V2 octahedra, edges with four equivalent O(6)Li4V2 octahedra,  an edgeedge with one O(1)Li2V3 square pyramid,  an edgeedge with one O(2)Li2V3 square pyramid, and  an edgeedge with one O(5)Li2V3 square pyramid. The corner-sharing octahedral tilt angles range from 5-7°. In the fourth O site, O(4) is bonded to one Li(1), one Li(2), one Li(3), one Li(4), one V(3), and one V(4) atom to form OLi4V2 octahedra that share  a cornercorner with one O(3)Li4V2 octahedra,  a cornercorner with one O(4)Li4V2 octahedra,  a cornercorner with one O(6)Li4V2 octahedra,  a cornercorner with one O(1)Li2V3 square pyramid,  a cornercorner with one O(2)Li2V3 square pyramid,  a cornercorner with one O(5)Li2V3 square pyramid,  an edgeedge with one O(4)Li4V2 octahedra, edges with four equivalent O(3)Li4V2 octahedra, edges with four equivalent O(6)Li4V2 octahedra,  an edgeedge with one O(1)Li2V3 square pyramid,  an edgeedge with one O(2)Li2V3 square pyramid, and  an edgeedge with one O(5)Li2V3 square pyramid. The corner-sharing octahedral tilt angles range from 6-13°. In the fifth O site, O(5) is bonded to one Li(2), one Li(3), one V(1), one V(2), and one V(4) atom to form distorted OLi2V3 square pyramids that share  a cornercorner with one O(3)Li4V2 octahedra,  a cornercorner with one O(4)Li4V2 octahedra,  a cornercorner with one O(6)Li4V2 octahedra,  a cornercorner with one O(2)Li2V3 square pyramid, corners with two equivalent O(5)Li2V3 square pyramids, corners with three equivalent O(1)Li2V3 square pyramids,  an edgeedge with one O(3)Li4V2 octahedra,  an edgeedge with one O(4)Li4V2 octahedra,  an edgeedge with one O(6)Li4V2 octahedra, edges with two equivalent O(1)Li2V3 square pyramids, and edges with three equivalent O(2)Li2V3 square pyramids. The corner-sharing octahedral tilt angles range from 1-14°. In the sixth O site, O(6) is bonded to one Li(1), one Li(2), one Li(3), one Li(4), one V(3), and one V(4) atom to form distorted OLi4V2 octahedra that share  a cornercorner with one O(3)Li4V2 octahedra,  a cornercorner with one O(4)Li4V2 octahedra,  a cornercorner with one O(6)Li4V2 octahedra,  a cornercorner with one O(1)Li2V3 square pyramid,  a cornercorner with one O(2)Li2V3 square pyramid,  a cornercorner with one O(5)Li2V3 square pyramid,  an edgeedge with one O(6)Li4V2 octahedra, edges with four equivalent O(3)Li4V2 octahedra, edges with four equivalent O(4)Li4V2 octahedra,  an edgeedge with one O(1)Li2V3 square pyramid,  an edgeedge with one O(2)Li2V3 square pyramid, and  an edgeedge with one O(5)Li2V3 square pyramid. The corner-sharing octahedral tilt angles range from 3-13°. is represented by the CIF card [CIF]
data_Li6V5O12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.046
_cell_length_b   5.046
_cell_length_c   9.545
_cell_angle_alpha   86.342
_cell_angle_beta   86.342
_cell_angle_gamma   116.195
_symmetry_Int_Tables_number   1
_cell_volume   216.472
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.758  0.242  0.000  1.0
  Li  Li1  1  0.832  0.644  0.757  1.0
  Li  Li2  1  0.694  0.868  0.239  1.0
  Li  Li3  1  0.356  0.168  0.243  1.0
  Li  Li4  1  0.132  0.306  0.761  1.0
  Li  Li5  1  0.086  0.914  0.000  1.0
  V  V6  1  0.921  0.079  0.500  1.0
  V  V7  1  0.571  0.429  0.500  1.0
  V  V8  1  0.428  0.572  0.000  1.0
  V  V9  1  0.479  0.989  0.750  1.0
  V  V10  1  0.011  0.521  0.250  1.0
  O  O11  1  0.819  0.332  0.632  1.0
  O  O12  1  0.668  0.181  0.368  1.0
  O  O13  1  0.918  0.764  0.377  1.0
  O  O14  1  0.735  0.544  0.124  1.0
  O  O15  1  0.738  0.907  0.888  1.0
  O  O16  1  0.456  0.265  0.876  1.0
  O  O17  1  0.572  0.752  0.625  1.0
  O  O18  1  0.236  0.082  0.623  1.0
  O  O19  1  0.248  0.428  0.375  1.0
  O  O20  1  0.361  0.831  0.132  1.0
  O  O21  1  0.093  0.262  0.112  1.0
  O  O22  1  0.169  0.639  0.868  1.0
[/CIF]
.