The material structure described by VOF crystallizes in the trigonal R-3 space group. V(1) is bonded in a 6-coordinate geometry to four equivalent O(1) and two equivalent F(1) atoms. O(1) is bonded to four equivalent V(1) atoms to form a mixture of corner and edge-sharing OV4 tetrahedra. F(1) is bonded in a distorted water-like geometry to two equivalent V(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_VOF
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.018
_cell_length_b   6.018
_cell_length_c   6.019
_cell_angle_alpha   100.287
_cell_angle_beta   100.275
_cell_angle_gamma   100.281
_symmetry_Int_Tables_number   1
_cell_volume   206.032
_cell_formula_units_Z   6
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.670  0.853  0.398  1.0
  V  V1  1  0.397  0.670  0.853  1.0
  V  V2  1  0.853  0.397  0.670  1.0
  V  V3  1  0.147  0.603  0.330  1.0
  V  V4  1  0.603  0.330  0.147  1.0
  V  V5  1  0.330  0.147  0.602  1.0
  O  O6  1  0.426  0.823  0.584  1.0
  O  O7  1  0.416  0.574  0.177  1.0
  O  O8  1  0.177  0.416  0.574  1.0
  O  O9  1  0.823  0.584  0.426  1.0
  O  O10  1  0.584  0.426  0.823  1.0
  O  O11  1  0.574  0.177  0.416  1.0
  F  F12  1  0.907  0.073  0.668  1.0
  F  F13  1  0.332  0.093  0.927  1.0
  F  F14  1  0.927  0.332  0.093  1.0
  F  F15  1  0.073  0.668  0.907  1.0
  F  F16  1  0.668  0.907  0.073  1.0
  F  F17  1  0.093  0.927  0.332  1.0
[/CIF]
.
The material structure described by VOF crystallizes in the trigonal R-3 space group. V(1) is bonded in a 6-coordinate geometry to four equivalent O(1) and two equivalent F(1) atoms. O(1) is bonded to four equivalent V(1) atoms to form a mixture of corner and edge-sharing OV4 tetrahedra. F(1) is bonded in a distorted water-like geometry to two equivalent V(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_VOF
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.018
_cell_length_b   6.018
_cell_length_c   6.019
_cell_angle_alpha   100.287
_cell_angle_beta   100.275
_cell_angle_gamma   100.281
_symmetry_Int_Tables_number   1
_cell_volume   206.032
_cell_formula_units_Z   6
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.670  0.853  0.398  1.0
  V  V1  1  0.397  0.670  0.853  1.0
  V  V2  1  0.853  0.397  0.670  1.0
  V  V3  1  0.147  0.603  0.330  1.0
  V  V4  1  0.603  0.330  0.147  1.0
  V  V5  1  0.330  0.147  0.602  1.0
  O  O6  1  0.426  0.823  0.584  1.0
  O  O7  1  0.416  0.574  0.177  1.0
  O  O8  1  0.177  0.416  0.574  1.0
  O  O9  1  0.823  0.584  0.426  1.0
  O  O10  1  0.584  0.426  0.823  1.0
  O  O11  1  0.574  0.177  0.416  1.0
  F  F12  1  0.907  0.073  0.668  1.0
  F  F13  1  0.332  0.093  0.927  1.0
  F  F14  1  0.927  0.332  0.093  1.0
  F  F15  1  0.073  0.668  0.907  1.0
  F  F16  1  0.668  0.907  0.073  1.0
  F  F17  1  0.093  0.927  0.332  1.0
[/CIF]
.