The material described by Li2AgF5 crystallizes in the monoclinic P2_1/c space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded in a trigonal non-coplanar geometry to one F(1), one F(2), and one F(5) atom. In the second Li site, Li(2) is bonded in a see-saw-like geometry to one F(2), one F(3), one F(4), and one F(5) atom. Ag(1) is bonded in a 5-coordinate geometry to one F(1), one F(2), one F(3), one F(4), and one F(5) atom. There are five inequivalent F sites. In the first F site, F(1) is bonded in a bent 150 degrees geometry to one Li(1) and one Ag(1) atom. In the second F site, F(2) is bonded in a distorted bent 120 degrees geometry to one Li(1), one Li(2), and one Ag(1) atom. In the third F site, F(3) is bonded in a distorted bent 150 degrees geometry to one Li(2) and one Ag(1) atom. In the fourth F site, F(4) is bonded in a water-like geometry to one Li(2) and one Ag(1) atom. In the fifth F site, F(5) is bonded in a trigonal planar geometry to one Li(1), one Li(2), and one Ag(1) atom. is represented by the CIF card [CIF]
data_Li2AgF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.009
_cell_length_b   6.123
_cell_length_c   8.053
_cell_angle_alpha   70.970
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   466.507
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.730  0.897  0.537  1.0
  Li  Li1  1  0.321  0.616  0.981  1.0
  Li  Li2  1  0.770  0.897  0.037  1.0
  Li  Li3  1  0.179  0.616  0.481  1.0
  Li  Li4  1  0.821  0.384  0.519  1.0
  Li  Li5  1  0.230  0.103  0.963  1.0
  Li  Li6  1  0.679  0.384  0.019  1.0
  Li  Li7  1  0.270  0.103  0.463  1.0
  Ag  Ag8  1  0.989  0.662  0.773  1.0
  Ag  Ag9  1  0.511  0.662  0.273  1.0
  Ag  Ag10  1  0.489  0.338  0.727  1.0
  Ag  Ag11  1  0.011  0.338  0.227  1.0
  F  F12  1  0.879  0.882  0.847  1.0
  F  F13  1  0.150  0.874  0.538  1.0
  F  F14  1  0.128  0.680  0.945  1.0
  F  F15  1  0.621  0.882  0.347  1.0
  F  F16  1  0.587  0.578  0.793  1.0
  F  F17  1  0.839  0.624  0.622  1.0
  F  F18  1  0.350  0.874  0.038  1.0
  F  F19  1  0.372  0.680  0.445  1.0
  F  F20  1  0.339  0.376  0.878  1.0
  F  F21  1  0.087  0.422  0.707  1.0
  F  F22  1  0.913  0.578  0.293  1.0
  F  F23  1  0.661  0.624  0.122  1.0
  F  F24  1  0.628  0.320  0.555  1.0
  F  F25  1  0.650  0.126  0.962  1.0
  F  F26  1  0.161  0.376  0.378  1.0
  F  F27  1  0.413  0.422  0.207  1.0
  F  F28  1  0.379  0.118  0.653  1.0
  F  F29  1  0.872  0.320  0.055  1.0
  F  F30  1  0.850  0.126  0.462  1.0
  F  F31  1  0.121  0.118  0.153  1.0
[/CIF]
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The material described by Li2AgF5 crystallizes in the monoclinic P2_1/c space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded in a trigonal non-coplanar geometry to one F(1), one F(2), and one F(5) atom. In the second Li site, Li(2) is bonded in a see-saw-like geometry to one F(2), one F(3), one F(4), and one F(5) atom. Ag(1) is bonded in a 5-coordinate geometry to one F(1), one F(2), one F(3), one F(4), and one F(5) atom. There are five inequivalent F sites. In the first F site, F(1) is bonded in a bent 150 degrees geometry to one Li(1) and one Ag(1) atom. In the second F site, F(2) is bonded in a distorted bent 120 degrees geometry to one Li(1), one Li(2), and one Ag(1) atom. In the third F site, F(3) is bonded in a distorted bent 150 degrees geometry to one Li(2) and one Ag(1) atom. In the fourth F site, F(4) is bonded in a water-like geometry to one Li(2) and one Ag(1) atom. In the fifth F site, F(5) is bonded in a trigonal planar geometry to one Li(1), one Li(2), and one Ag(1) atom. is represented by the CIF card [CIF]
data_Li2AgF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.009
_cell_length_b   6.123
_cell_length_c   8.053
_cell_angle_alpha   70.970
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   466.507
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.730  0.897  0.537  1.0
  Li  Li1  1  0.321  0.616  0.981  1.0
  Li  Li2  1  0.770  0.897  0.037  1.0
  Li  Li3  1  0.179  0.616  0.481  1.0
  Li  Li4  1  0.821  0.384  0.519  1.0
  Li  Li5  1  0.230  0.103  0.963  1.0
  Li  Li6  1  0.679  0.384  0.019  1.0
  Li  Li7  1  0.270  0.103  0.463  1.0
  Ag  Ag8  1  0.989  0.662  0.773  1.0
  Ag  Ag9  1  0.511  0.662  0.273  1.0
  Ag  Ag10  1  0.489  0.338  0.727  1.0
  Ag  Ag11  1  0.011  0.338  0.227  1.0
  F  F12  1  0.879  0.882  0.847  1.0
  F  F13  1  0.150  0.874  0.538  1.0
  F  F14  1  0.128  0.680  0.945  1.0
  F  F15  1  0.621  0.882  0.347  1.0
  F  F16  1  0.587  0.578  0.793  1.0
  F  F17  1  0.839  0.624  0.622  1.0
  F  F18  1  0.350  0.874  0.038  1.0
  F  F19  1  0.372  0.680  0.445  1.0
  F  F20  1  0.339  0.376  0.878  1.0
  F  F21  1  0.087  0.422  0.707  1.0
  F  F22  1  0.913  0.578  0.293  1.0
  F  F23  1  0.661  0.624  0.122  1.0
  F  F24  1  0.628  0.320  0.555  1.0
  F  F25  1  0.650  0.126  0.962  1.0
  F  F26  1  0.161  0.376  0.378  1.0
  F  F27  1  0.413  0.422  0.207  1.0
  F  F28  1  0.379  0.118  0.653  1.0
  F  F29  1  0.872  0.320  0.055  1.0
  F  F30  1  0.850  0.126  0.462  1.0
  F  F31  1  0.121  0.118  0.153  1.0
[/CIF]
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