The material described by RbNaS is Matlockite structured and crystallizes in the tetragonal P4/nmm space group. Rb(1) is bonded in a 5-coordinate geometry to five equivalent S(1) atoms. Na(1) is bonded to four equivalent S(1) atoms to form a mixture of corner and edge-sharing NaS4 tetrahedra. S(1) is bonded in a 9-coordinate geometry to five equivalent Rb(1) and four equivalent Na(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_RbNaS
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.690
_cell_length_b   4.690
_cell_length_c   7.576
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   166.636
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.750  0.750  0.351  1.0
  Rb  Rb1  1  0.250  0.250  0.649  1.0
  Na  Na2  1  0.750  0.250  0.000  1.0
  Na  Na3  1  0.250  0.750  0.000  1.0
  S  S4  1  0.250  0.250  0.204  1.0
  S  S5  1  0.750  0.750  0.796  1.0
[/CIF]
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The material described by RbNaS is Matlockite structured and crystallizes in the tetragonal P4/nmm space group. Rb(1) is bonded in a 5-coordinate geometry to five equivalent S(1) atoms. Na(1) is bonded to four equivalent S(1) atoms to form a mixture of corner and edge-sharing NaS4 tetrahedra. S(1) is bonded in a 9-coordinate geometry to five equivalent Rb(1) and four equivalent Na(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_RbNaS
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.690
_cell_length_b   4.690
_cell_length_c   7.576
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   166.636
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.750  0.750  0.351  1.0
  Rb  Rb1  1  0.250  0.250  0.649  1.0
  Na  Na2  1  0.750  0.250  0.000  1.0
  Na  Na3  1  0.250  0.750  0.000  1.0
  S  S4  1  0.250  0.250  0.204  1.0
  S  S5  1  0.750  0.750  0.796  1.0
[/CIF]
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