The material structure described by CrBiO4 is Zircon-like structured and crystallizes in the monoclinic P2/c space group. There are two inequivalent Cr sites. In the first Cr site, Cr(1) is bonded in a tetrahedral geometry to two equivalent O(2) and two equivalent O(4) atoms. In the second Cr site, Cr(2) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent O(3) atoms. There are two inequivalent Bi sites. In the first Bi site, Bi(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), and four equivalent O(3) atoms. In the second Bi site, Bi(2) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(4) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Cr(2), one Bi(1), and one Bi(2) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Cr(1), one Bi(1), and one Bi(2) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Cr(2) and two equivalent Bi(1) atoms. In the fourth O site, O(4) is bonded in a single-bond geometry to one Cr(1) and one Bi(2) atom. is represented by the CIF file [CIF]
data_CrBiO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.077
_cell_length_b   10.890
_cell_length_c   6.089
_cell_angle_alpha   90.006
_cell_angle_beta   114.507
_cell_angle_gamma   89.967
_symmetry_Int_Tables_number   1
_cell_volume   366.634
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.750  0.873  0.500  1.0
  Cr  Cr1  1  0.750  0.627  1.000  1.0
  Cr  Cr2  1  0.250  0.375  1.000  1.0
  Cr  Cr3  1  0.250  0.125  0.500  1.0
  Bi  Bi4  1  0.750  0.146  1.000  1.0
  Bi  Bi5  1  0.250  0.593  0.500  1.0
  Bi  Bi6  1  0.750  0.354  0.500  1.0
  Bi  Bi7  1  0.250  0.907  0.000  1.0
  O  O8  1  0.164  0.459  0.721  1.0
  O  O9  1  0.661  0.960  0.248  1.0
  O  O10  1  0.526  0.288  0.094  1.0
  O  O11  1  0.990  0.789  0.541  1.0
  O  O12  1  0.974  0.288  0.906  1.0
  O  O13  1  0.511  0.789  0.459  1.0
  O  O14  1  0.336  0.459  0.279  1.0
  O  O15  1  0.839  0.960  0.753  1.0
  O  O16  1  0.164  0.041  0.221  1.0
  O  O17  1  0.661  0.540  0.748  1.0
  O  O18  1  0.526  0.212  0.594  1.0
  O  O19  1  0.990  0.711  0.041  1.0
  O  O20  1  0.974  0.212  0.406  1.0
  O  O21  1  0.511  0.711  0.959  1.0
  O  O22  1  0.336  0.041  0.779  1.0
  O  O23  1  0.839  0.540  0.253  1.0
[/CIF]
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The material structure described by CrBiO4 is Zircon-like structured and crystallizes in the monoclinic P2/c space group. There are two inequivalent Cr sites. In the first Cr site, Cr(1) is bonded in a tetrahedral geometry to two equivalent O(2) and two equivalent O(4) atoms. In the second Cr site, Cr(2) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent O(3) atoms. There are two inequivalent Bi sites. In the first Bi site, Bi(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), and four equivalent O(3) atoms. In the second Bi site, Bi(2) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(4) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Cr(2), one Bi(1), and one Bi(2) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Cr(1), one Bi(1), and one Bi(2) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Cr(2) and two equivalent Bi(1) atoms. In the fourth O site, O(4) is bonded in a single-bond geometry to one Cr(1) and one Bi(2) atom. is represented by the CIF file [CIF]
data_CrBiO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.077
_cell_length_b   10.890
_cell_length_c   6.089
_cell_angle_alpha   90.006
_cell_angle_beta   114.507
_cell_angle_gamma   89.967
_symmetry_Int_Tables_number   1
_cell_volume   366.634
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.750  0.873  0.500  1.0
  Cr  Cr1  1  0.750  0.627  1.000  1.0
  Cr  Cr2  1  0.250  0.375  1.000  1.0
  Cr  Cr3  1  0.250  0.125  0.500  1.0
  Bi  Bi4  1  0.750  0.146  1.000  1.0
  Bi  Bi5  1  0.250  0.593  0.500  1.0
  Bi  Bi6  1  0.750  0.354  0.500  1.0
  Bi  Bi7  1  0.250  0.907  0.000  1.0
  O  O8  1  0.164  0.459  0.721  1.0
  O  O9  1  0.661  0.960  0.248  1.0
  O  O10  1  0.526  0.288  0.094  1.0
  O  O11  1  0.990  0.789  0.541  1.0
  O  O12  1  0.974  0.288  0.906  1.0
  O  O13  1  0.511  0.789  0.459  1.0
  O  O14  1  0.336  0.459  0.279  1.0
  O  O15  1  0.839  0.960  0.753  1.0
  O  O16  1  0.164  0.041  0.221  1.0
  O  O17  1  0.661  0.540  0.748  1.0
  O  O18  1  0.526  0.212  0.594  1.0
  O  O19  1  0.990  0.711  0.041  1.0
  O  O20  1  0.974  0.212  0.406  1.0
  O  O21  1  0.511  0.711  0.959  1.0
  O  O22  1  0.336  0.041  0.779  1.0
  O  O23  1  0.839  0.540  0.253  1.0
[/CIF]
.