The material described by PtCl6(RuN5H15Cl)2Cl2 is Indium-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of four hydrochloric acid atoms, two PtCl6 clusters, and four RuN5H15Cl clusters. In each PtCl6 cluster, Pt(1) is bonded in an octahedral geometry to two equivalent Cl(4) and four equivalent Cl(1,3) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(4) is bonded in a single-bond geometry to one Pt(1) atom. In the second Cl site, Cl(1,3) is bonded in a single-bond geometry to one Pt(1) atom. In each RuN5H15Cl cluster, Ru(1) is bonded in an octahedral geometry to one N(2), two equivalent N(1), two equivalent N(3), and one Cl(2) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal non-coplanar geometry to one Ru(1), one H(1), one H(4), and one H(5) atom. In the second N site, N(2) is bonded in a distorted trigonal non-coplanar geometry to one Ru(1), one H(7), and two equivalent H(3) atoms. In the third N site, N(3) is bonded in a distorted trigonal non-coplanar geometry to one Ru(1), one H(2), one H(6), and one H(8) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(1) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(1) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(3) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one N(2) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one N(3) atom. Cl(2) is bonded in a single-bond geometry to one Ru(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_H30Ru2Pt(NCl)10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.328
_cell_length_b   7.328
_cell_length_c   13.406
_cell_angle_alpha   82.621
_cell_angle_beta   82.621
_cell_angle_gamma   70.120
_symmetry_Int_Tables_number   1
_cell_volume   668.587
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.453  0.030  0.756  1.0
  H  H1  1  0.547  0.970  0.244  1.0
  H  H2  1  0.970  0.547  0.244  1.0
  H  H3  1  0.030  0.453  0.756  1.0
  H  H4  1  0.385  0.951  0.607  1.0
  H  H5  1  0.615  0.049  0.393  1.0
  H  H6  1  0.049  0.615  0.393  1.0
  H  H7  1  0.951  0.385  0.607  1.0
  H  H8  1  0.595  0.401  0.836  1.0
  H  H9  1  0.405  0.599  0.164  1.0
  H  H10  1  0.599  0.405  0.164  1.0
  H  H11  1  0.401  0.595  0.836  1.0
  H  H12  1  0.478  0.882  0.860  1.0
  H  H13  1  0.522  0.118  0.140  1.0
  H  H14  1  0.118  0.522  0.140  1.0
  H  H15  1  0.882  0.478  0.860  1.0
  H  H16  1  0.657  0.959  0.810  1.0
  H  H17  1  0.343  0.041  0.190  1.0
  H  H18  1  0.041  0.343  0.190  1.0
  H  H19  1  0.959  0.657  0.810  1.0
  H  H20  1  0.322  0.753  0.628  1.0
  H  H21  1  0.678  0.247  0.372  1.0
  H  H22  1  0.247  0.678  0.372  1.0
  H  H23  1  0.753  0.322  0.628  1.0
  H  H24  1  0.450  0.450  0.743  1.0
  H  H25  1  0.550  0.550  0.257  1.0
  H  H26  1  0.483  0.773  0.533  1.0
  H  H27  1  0.517  0.227  0.467  1.0
  H  H28  1  0.227  0.517  0.467  1.0
  H  H29  1  0.773  0.483  0.533  1.0
  Ru  Ru30  1  0.675  0.675  0.700  1.0
  Ru  Ru31  1  0.325  0.325  0.300  1.0
  Pt  Pt32  1  0.000  0.000  0.000  1.0
  N  N33  1  0.550  0.912  0.792  1.0
  N  N34  1  0.450  0.088  0.208  1.0
  N  N35  1  0.088  0.450  0.208  1.0
  N  N36  1  0.912  0.550  0.792  1.0
  N  N37  1  0.512  0.512  0.789  1.0
  N  N38  1  0.488  0.488  0.211  1.0
  N  N39  1  0.438  0.802  0.607  1.0
  N  N40  1  0.562  0.198  0.393  1.0
  N  N41  1  0.198  0.562  0.393  1.0
  N  N42  1  0.802  0.438  0.607  1.0
  Cl  Cl43  1  0.999  0.999  0.824  1.0
  Cl  Cl44  1  0.001  0.001  0.176  1.0
  Cl  Cl45  1  0.148  0.148  0.400  1.0
  Cl  Cl46  1  0.852  0.852  0.600  1.0
  Cl  Cl47  1  0.198  0.198  0.975  1.0
  Cl  Cl48  1  0.802  0.802  0.025  1.0
  Cl  Cl49  1  0.277  0.723  0.000  1.0
  Cl  Cl50  1  0.723  0.277  0.000  1.0
  Cl  Cl51  1  0.331  0.331  0.629  1.0
  Cl  Cl52  1  0.669  0.669  0.371  1.0
[/CIF]
.
The material described by PtCl6(RuN5H15Cl)2Cl2 is Indium-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of four hydrochloric acid atoms, two PtCl6 clusters, and four RuN5H15Cl clusters. In each PtCl6 cluster, Pt(1) is bonded in an octahedral geometry to two equivalent Cl(4) and four equivalent Cl(1,3) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(4) is bonded in a single-bond geometry to one Pt(1) atom. In the second Cl site, Cl(1,3) is bonded in a single-bond geometry to one Pt(1) atom. In each RuN5H15Cl cluster, Ru(1) is bonded in an octahedral geometry to one N(2), two equivalent N(1), two equivalent N(3), and one Cl(2) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal non-coplanar geometry to one Ru(1), one H(1), one H(4), and one H(5) atom. In the second N site, N(2) is bonded in a distorted trigonal non-coplanar geometry to one Ru(1), one H(7), and two equivalent H(3) atoms. In the third N site, N(3) is bonded in a distorted trigonal non-coplanar geometry to one Ru(1), one H(2), one H(6), and one H(8) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(1) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(1) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(3) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one N(2) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one N(3) atom. Cl(2) is bonded in a single-bond geometry to one Ru(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_H30Ru2Pt(NCl)10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.328
_cell_length_b   7.328
_cell_length_c   13.406
_cell_angle_alpha   82.621
_cell_angle_beta   82.621
_cell_angle_gamma   70.120
_symmetry_Int_Tables_number   1
_cell_volume   668.587
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.453  0.030  0.756  1.0
  H  H1  1  0.547  0.970  0.244  1.0
  H  H2  1  0.970  0.547  0.244  1.0
  H  H3  1  0.030  0.453  0.756  1.0
  H  H4  1  0.385  0.951  0.607  1.0
  H  H5  1  0.615  0.049  0.393  1.0
  H  H6  1  0.049  0.615  0.393  1.0
  H  H7  1  0.951  0.385  0.607  1.0
  H  H8  1  0.595  0.401  0.836  1.0
  H  H9  1  0.405  0.599  0.164  1.0
  H  H10  1  0.599  0.405  0.164  1.0
  H  H11  1  0.401  0.595  0.836  1.0
  H  H12  1  0.478  0.882  0.860  1.0
  H  H13  1  0.522  0.118  0.140  1.0
  H  H14  1  0.118  0.522  0.140  1.0
  H  H15  1  0.882  0.478  0.860  1.0
  H  H16  1  0.657  0.959  0.810  1.0
  H  H17  1  0.343  0.041  0.190  1.0
  H  H18  1  0.041  0.343  0.190  1.0
  H  H19  1  0.959  0.657  0.810  1.0
  H  H20  1  0.322  0.753  0.628  1.0
  H  H21  1  0.678  0.247  0.372  1.0
  H  H22  1  0.247  0.678  0.372  1.0
  H  H23  1  0.753  0.322  0.628  1.0
  H  H24  1  0.450  0.450  0.743  1.0
  H  H25  1  0.550  0.550  0.257  1.0
  H  H26  1  0.483  0.773  0.533  1.0
  H  H27  1  0.517  0.227  0.467  1.0
  H  H28  1  0.227  0.517  0.467  1.0
  H  H29  1  0.773  0.483  0.533  1.0
  Ru  Ru30  1  0.675  0.675  0.700  1.0
  Ru  Ru31  1  0.325  0.325  0.300  1.0
  Pt  Pt32  1  0.000  0.000  0.000  1.0
  N  N33  1  0.550  0.912  0.792  1.0
  N  N34  1  0.450  0.088  0.208  1.0
  N  N35  1  0.088  0.450  0.208  1.0
  N  N36  1  0.912  0.550  0.792  1.0
  N  N37  1  0.512  0.512  0.789  1.0
  N  N38  1  0.488  0.488  0.211  1.0
  N  N39  1  0.438  0.802  0.607  1.0
  N  N40  1  0.562  0.198  0.393  1.0
  N  N41  1  0.198  0.562  0.393  1.0
  N  N42  1  0.802  0.438  0.607  1.0
  Cl  Cl43  1  0.999  0.999  0.824  1.0
  Cl  Cl44  1  0.001  0.001  0.176  1.0
  Cl  Cl45  1  0.148  0.148  0.400  1.0
  Cl  Cl46  1  0.852  0.852  0.600  1.0
  Cl  Cl47  1  0.198  0.198  0.975  1.0
  Cl  Cl48  1  0.802  0.802  0.025  1.0
  Cl  Cl49  1  0.277  0.723  0.000  1.0
  Cl  Cl50  1  0.723  0.277  0.000  1.0
  Cl  Cl51  1  0.331  0.331  0.629  1.0
  Cl  Cl52  1  0.669  0.669  0.371  1.0
[/CIF]
.