The structure described by VSO4 crystallizes in the orthorhombic Pnma space group. V(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form VO6 octahedra that share corners with six equivalent S(1)O4 tetrahedra and edges with two equivalent V(1)O6 octahedra. S(1) is bonded to one O(1), one O(2), and two equivalent O(3) atoms to form SO4 tetrahedra that share corners with six equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-53°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to two equivalent V(1) and one S(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent V(1) and one S(1) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one V(1) and one S(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_VSO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.905
_cell_length_b   8.924
_cell_length_c   6.852
_cell_angle_alpha   89.997
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   299.953
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  1.000  0.000  0.500  1.0
  V  V1  1  0.500  0.500  0.500  1.0
  V  V2  1  1.000  0.000  1.000  1.0
  V  V3  1  0.500  0.500  1.000  1.0
  S  S4  1  0.487  0.177  0.250  1.0
  S  S5  1  0.987  0.323  0.750  1.0
  S  S6  1  0.013  0.677  0.250  1.0
  S  S7  1  0.513  0.823  0.750  1.0
  O  O8  1  0.779  0.122  0.250  1.0
  O  O9  1  0.279  0.378  0.750  1.0
  O  O10  1  0.721  0.622  0.250  1.0
  O  O11  1  0.221  0.878  0.750  1.0
  O  O12  1  0.981  0.154  0.750  1.0
  O  O13  1  0.481  0.347  0.250  1.0
  O  O14  1  0.519  0.653  0.750  1.0
  O  O15  1  0.019  0.847  0.250  1.0
  O  O16  1  0.353  0.126  0.070  1.0
  O  O17  1  0.353  0.126  0.430  1.0
  O  O18  1  0.854  0.374  0.930  1.0
  O  O19  1  0.853  0.374  0.570  1.0
  O  O20  1  0.147  0.626  0.070  1.0
  O  O21  1  0.147  0.626  0.430  1.0
  O  O22  1  0.647  0.874  0.570  1.0
  O  O23  1  0.647  0.874  0.930  1.0
[/CIF]
.
The structure described by VSO4 crystallizes in the orthorhombic Pnma space group. V(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form VO6 octahedra that share corners with six equivalent S(1)O4 tetrahedra and edges with two equivalent V(1)O6 octahedra. S(1) is bonded to one O(1), one O(2), and two equivalent O(3) atoms to form SO4 tetrahedra that share corners with six equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-53°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to two equivalent V(1) and one S(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent V(1) and one S(1) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one V(1) and one S(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_VSO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.905
_cell_length_b   8.924
_cell_length_c   6.852
_cell_angle_alpha   89.997
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   299.953
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  1.000  0.000  0.500  1.0
  V  V1  1  0.500  0.500  0.500  1.0
  V  V2  1  1.000  0.000  1.000  1.0
  V  V3  1  0.500  0.500  1.000  1.0
  S  S4  1  0.487  0.177  0.250  1.0
  S  S5  1  0.987  0.323  0.750  1.0
  S  S6  1  0.013  0.677  0.250  1.0
  S  S7  1  0.513  0.823  0.750  1.0
  O  O8  1  0.779  0.122  0.250  1.0
  O  O9  1  0.279  0.378  0.750  1.0
  O  O10  1  0.721  0.622  0.250  1.0
  O  O11  1  0.221  0.878  0.750  1.0
  O  O12  1  0.981  0.154  0.750  1.0
  O  O13  1  0.481  0.347  0.250  1.0
  O  O14  1  0.519  0.653  0.750  1.0
  O  O15  1  0.019  0.847  0.250  1.0
  O  O16  1  0.353  0.126  0.070  1.0
  O  O17  1  0.353  0.126  0.430  1.0
  O  O18  1  0.854  0.374  0.930  1.0
  O  O19  1  0.853  0.374  0.570  1.0
  O  O20  1  0.147  0.626  0.070  1.0
  O  O21  1  0.147  0.626  0.430  1.0
  O  O22  1  0.647  0.874  0.570  1.0
  O  O23  1  0.647  0.874  0.930  1.0
[/CIF]
.