The structure described by LiLa(WO4)2 crystallizes in the triclinic P-1 space group. Li(1) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(6), and one O(7) atom. La(1) is bonded in a 8-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(7), one O(8), and two equivalent O(5) atoms. There are two inequivalent W sites. In the first W site, W(1) is bonded in a distorted octahedral geometry to one O(1), one O(2), one O(3), one O(6), one O(7), and one O(8) atom. In the second W site, W(2) is bonded in a 6-coordinate geometry to one O(3), one O(4), one O(5), one O(8), and two equivalent O(6) atoms. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one Li(1), one La(1), and one W(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Li(1), one La(1), and one W(1) atom. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one La(1), one W(1), and one W(2) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one La(1) and one W(2) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to two equivalent La(1) and one W(2) atom. In the sixth O site, O(6) is bonded to one Li(1), one W(1), and two equivalent W(2) atoms to form distorted edge-sharing OLiW3 tetrahedra. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one Li(1), one La(1), and one W(1) atom. In the eighth O site, O(8) is bonded in a distorted trigonal non-coplanar geometry to one La(1), one W(1), and one W(2) atom. is represented by the CIF card [CIF]
data_LiLa(WO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.275
_cell_length_b   7.498
_cell_length_c   7.626
_cell_angle_alpha   113.727
_cell_angle_beta   115.655
_cell_angle_gamma   91.322
_symmetry_Int_Tables_number   1
_cell_volume   333.304
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.250  0.677  0.010  1.0
  Li  Li1  1  0.750  0.323  0.990  1.0
  La  La2  1  0.185  0.287  0.462  1.0
  La  La3  1  0.815  0.713  0.538  1.0
  W  W4  1  0.262  0.292  0.029  1.0
  W  W5  1  0.738  0.708  0.971  1.0
  W  W6  1  0.646  0.103  0.283  1.0
  W  W7  1  0.354  0.897  0.717  1.0
  O  O8  1  0.185  0.365  0.809  1.0
  O  O9  1  0.815  0.635  0.191  1.0
  O  O10  1  0.445  0.535  0.249  1.0
  O  O11  1  0.555  0.465  0.751  1.0
  O  O12  1  0.861  0.009  0.198  1.0
  O  O13  1  0.139  0.991  0.802  1.0
  O  O14  1  0.705  0.011  0.481  1.0
  O  O15  1  0.295  0.989  0.519  1.0
  O  O16  1  0.180  0.643  0.564  1.0
  O  O17  1  0.820  0.357  0.436  1.0
  O  O18  1  0.481  0.828  0.009  1.0
  O  O19  1  0.519  0.172  0.991  1.0
  O  O20  1  0.043  0.303  0.089  1.0
  O  O21  1  0.957  0.697  0.911  1.0
  O  O22  1  0.385  0.171  0.256  1.0
  O  O23  1  0.615  0.829  0.744  1.0
[/CIF]
.
The structure described by LiLa(WO4)2 crystallizes in the triclinic P-1 space group. Li(1) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(6), and one O(7) atom. La(1) is bonded in a 8-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(7), one O(8), and two equivalent O(5) atoms. There are two inequivalent W sites. In the first W site, W(1) is bonded in a distorted octahedral geometry to one O(1), one O(2), one O(3), one O(6), one O(7), and one O(8) atom. In the second W site, W(2) is bonded in a 6-coordinate geometry to one O(3), one O(4), one O(5), one O(8), and two equivalent O(6) atoms. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one Li(1), one La(1), and one W(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Li(1), one La(1), and one W(1) atom. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one La(1), one W(1), and one W(2) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one La(1) and one W(2) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to two equivalent La(1) and one W(2) atom. In the sixth O site, O(6) is bonded to one Li(1), one W(1), and two equivalent W(2) atoms to form distorted edge-sharing OLiW3 tetrahedra. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one Li(1), one La(1), and one W(1) atom. In the eighth O site, O(8) is bonded in a distorted trigonal non-coplanar geometry to one La(1), one W(1), and one W(2) atom. is represented by the CIF card [CIF]
data_LiLa(WO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.275
_cell_length_b   7.498
_cell_length_c   7.626
_cell_angle_alpha   113.727
_cell_angle_beta   115.655
_cell_angle_gamma   91.322
_symmetry_Int_Tables_number   1
_cell_volume   333.304
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.250  0.677  0.010  1.0
  Li  Li1  1  0.750  0.323  0.990  1.0
  La  La2  1  0.185  0.287  0.462  1.0
  La  La3  1  0.815  0.713  0.538  1.0
  W  W4  1  0.262  0.292  0.029  1.0
  W  W5  1  0.738  0.708  0.971  1.0
  W  W6  1  0.646  0.103  0.283  1.0
  W  W7  1  0.354  0.897  0.717  1.0
  O  O8  1  0.185  0.365  0.809  1.0
  O  O9  1  0.815  0.635  0.191  1.0
  O  O10  1  0.445  0.535  0.249  1.0
  O  O11  1  0.555  0.465  0.751  1.0
  O  O12  1  0.861  0.009  0.198  1.0
  O  O13  1  0.139  0.991  0.802  1.0
  O  O14  1  0.705  0.011  0.481  1.0
  O  O15  1  0.295  0.989  0.519  1.0
  O  O16  1  0.180  0.643  0.564  1.0
  O  O17  1  0.820  0.357  0.436  1.0
  O  O18  1  0.481  0.828  0.009  1.0
  O  O19  1  0.519  0.172  0.991  1.0
  O  O20  1  0.043  0.303  0.089  1.0
  O  O21  1  0.957  0.697  0.911  1.0
  O  O22  1  0.385  0.171  0.256  1.0
  O  O23  1  0.615  0.829  0.744  1.0
[/CIF]
.