The crystal structure described by Mo(SO)2(NH4)2 is Silicon tetrafluoride-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight ammonium molecules and four Mo(SO)2 clusters. In each Mo(SO)2 cluster, Mo(1) is bonded in a tetrahedral geometry to two equivalent S(1) and two equivalent O(1) atoms. S(1) is bonded in a single-bond geometry to one Mo(1) atom. O(1) is bonded in a single-bond geometry to one Mo(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_MoH8S2(NO)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.891
_cell_length_b   6.891
_cell_length_c   9.620
_cell_angle_alpha   66.941
_cell_angle_beta   66.941
_cell_angle_gamma   64.817
_symmetry_Int_Tables_number   1
_cell_volume   366.219
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mo  Mo0  1  0.083  0.917  0.750  1.0
  Mo  Mo1  1  0.917  0.083  0.250  1.0
  H  H2  1  0.795  0.723  0.714  1.0
  H  H3  1  0.277  0.205  0.786  1.0
  H  H4  1  0.205  0.277  0.286  1.0
  H  H5  1  0.723  0.795  0.214  1.0
  H  H6  1  0.794  0.713  0.539  1.0
  H  H7  1  0.287  0.206  0.961  1.0
  H  H8  1  0.206  0.287  0.461  1.0
  H  H9  1  0.713  0.794  0.039  1.0
  H  H10  1  0.880  0.472  0.676  1.0
  H  H11  1  0.528  0.120  0.824  1.0
  H  H12  1  0.120  0.528  0.324  1.0
  H  H13  1  0.472  0.880  0.176  1.0
  H  H14  1  0.606  0.636  0.709  1.0
  H  H15  1  0.364  0.394  0.791  1.0
  H  H16  1  0.394  0.364  0.291  1.0
  H  H17  1  0.636  0.606  0.209  1.0
  S  S18  1  0.253  0.728  0.939  1.0
  S  S19  1  0.272  0.747  0.561  1.0
  S  S20  1  0.747  0.272  0.061  1.0
  S  S21  1  0.728  0.253  0.439  1.0
  N  N22  1  0.769  0.635  0.659  1.0
  N  N23  1  0.365  0.231  0.841  1.0
  N  N24  1  0.231  0.365  0.341  1.0
  N  N25  1  0.635  0.769  0.159  1.0
  O  O26  1  0.097  0.197  0.677  1.0
  O  O27  1  0.803  0.903  0.823  1.0
  O  O28  1  0.903  0.803  0.323  1.0
  O  O29  1  0.197  0.097  0.177  1.0
[/CIF]
.
The crystal structure described by Mo(SO)2(NH4)2 is Silicon tetrafluoride-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight ammonium molecules and four Mo(SO)2 clusters. In each Mo(SO)2 cluster, Mo(1) is bonded in a tetrahedral geometry to two equivalent S(1) and two equivalent O(1) atoms. S(1) is bonded in a single-bond geometry to one Mo(1) atom. O(1) is bonded in a single-bond geometry to one Mo(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_MoH8S2(NO)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.891
_cell_length_b   6.891
_cell_length_c   9.620
_cell_angle_alpha   66.941
_cell_angle_beta   66.941
_cell_angle_gamma   64.817
_symmetry_Int_Tables_number   1
_cell_volume   366.219
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mo  Mo0  1  0.083  0.917  0.750  1.0
  Mo  Mo1  1  0.917  0.083  0.250  1.0
  H  H2  1  0.795  0.723  0.714  1.0
  H  H3  1  0.277  0.205  0.786  1.0
  H  H4  1  0.205  0.277  0.286  1.0
  H  H5  1  0.723  0.795  0.214  1.0
  H  H6  1  0.794  0.713  0.539  1.0
  H  H7  1  0.287  0.206  0.961  1.0
  H  H8  1  0.206  0.287  0.461  1.0
  H  H9  1  0.713  0.794  0.039  1.0
  H  H10  1  0.880  0.472  0.676  1.0
  H  H11  1  0.528  0.120  0.824  1.0
  H  H12  1  0.120  0.528  0.324  1.0
  H  H13  1  0.472  0.880  0.176  1.0
  H  H14  1  0.606  0.636  0.709  1.0
  H  H15  1  0.364  0.394  0.791  1.0
  H  H16  1  0.394  0.364  0.291  1.0
  H  H17  1  0.636  0.606  0.209  1.0
  S  S18  1  0.253  0.728  0.939  1.0
  S  S19  1  0.272  0.747  0.561  1.0
  S  S20  1  0.747  0.272  0.061  1.0
  S  S21  1  0.728  0.253  0.439  1.0
  N  N22  1  0.769  0.635  0.659  1.0
  N  N23  1  0.365  0.231  0.841  1.0
  N  N24  1  0.231  0.365  0.341  1.0
  N  N25  1  0.635  0.769  0.159  1.0
  O  O26  1  0.097  0.197  0.677  1.0
  O  O27  1  0.803  0.903  0.823  1.0
  O  O28  1  0.903  0.803  0.323  1.0
  O  O29  1  0.197  0.097  0.177  1.0
[/CIF]
.