The compound described by Li11Ni13O24 is Caswellsilverite-like structured and crystallizes in the monoclinic C2/m space group. There are five inequivalent Li sites. In the first Li site, Li(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form LiO6 octahedra that share corners with two equivalent Ni(1)O6 octahedra, corners with two equivalent Ni(2)O6 octahedra, corners with two equivalent Ni(5)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Ni(1)O6 octahedra, edges with two equivalent Ni(2)O6 octahedra, and edges with two equivalent Ni(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-8°. In the second Li site, Li(2) is bonded to one O(2), one O(6), two equivalent O(3), and two equivalent O(4) atoms to form LiO6 octahedra that share  a cornercorner with one Ni(3)O6 octahedra,  a cornercorner with one Ni(5)O6 octahedra, corners with two equivalent Ni(1)O6 octahedra, corners with two equivalent Ni(2)O6 octahedra,  an edgeedge with one Ni(3)O6 octahedra,  an edgeedge with one Ni(5)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Ni(1)O6 octahedra, and edges with two equivalent Ni(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-10°. In the third Li site, Li(3) is bonded to one O(1), one O(3), one O(4), one O(5), one O(7), and one O(8) atom to form LiO6 octahedra that share  a cornercorner with one Ni(3)O6 octahedra,  a cornercorner with one Ni(5)O6 octahedra, corners with two equivalent Ni(1)O6 octahedra, corners with two equivalent Ni(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Ni(3)O6 octahedra,  an edgeedge with one Ni(4)O6 octahedra,  an edgeedge with one Ni(5)O6 octahedra, edges with two equivalent Ni(1)O6 octahedra, and edges with two equivalent Ni(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-9°. In the fourth Li site, Li(4) is bonded to two equivalent O(4), two equivalent O(5), and two equivalent O(6) atoms to form LiO6 octahedra that share corners with two equivalent Ni(1)O6 octahedra, corners with two equivalent Ni(2)O6 octahedra, corners with two equivalent Ni(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Ni(4)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Ni(1)O6 octahedra, edges with two equivalent Ni(2)O6 octahedra, and edges with two equivalent Ni(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-7°. In the fifth Li site, Li(5) is bonded to two equivalent O(7) and four equivalent O(1) atoms to form LiO6 octahedra that share corners with two equivalent Ni(3)O6 octahedra, corners with four equivalent Ni(1)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Ni(5)O6 octahedra, edges with four equivalent Li(3)O6 octahedra, and edges with four equivalent Ni(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-8°. There are five inequivalent Ni sites. In the first Ni site, Ni(1) is bonded to one O(1), one O(2), one O(5), one O(8), and two equivalent O(4) atoms to form NiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra, corners with two equivalent Li(3)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Ni(2)O6 octahedra,  an edgeedge with one Ni(3)O6 octahedra,  an edgeedge with one Ni(4)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Ni(1)O6 octahedra, and edges with two equivalent Ni(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-9°. In the second Ni site, Ni(2) is bonded to one O(1), one O(5), one O(6), one O(7), and two equivalent O(3) atoms to form NiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Ni(4)O6 octahedra, corners with two equivalent Li(3)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(5)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Ni(2)O6 octahedra, and edges with two equivalent Ni(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-9°. In the third Ni site, Ni(3) is bonded to one O(2), one O(7), two equivalent O(3), and two equivalent O(5) atoms to form NiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra, corners with two equivalent Li(3)O6 octahedra, corners with two equivalent Li(4)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Ni(4)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Ni(1)O6 octahedra, and edges with four equivalent Ni(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-7°. In the fourth Ni site, Ni(4) is bonded to two equivalent O(8) and four equivalent O(5) atoms to form NiO6 octahedra that share corners with two equivalent Ni(5)O6 octahedra, corners with four equivalent Ni(2)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Ni(3)O6 octahedra, edges with four equivalent Li(3)O6 octahedra, and edges with four equivalent Ni(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-6°. In the fifth Ni site, Ni(5) is bonded to one O(6), one O(8), two equivalent O(1), and two equivalent O(4) atoms to form NiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Ni(4)O6 octahedra, corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(3)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Ni(2)O6 octahedra, and edges with four equivalent Ni(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-10°. There are eight inequivalent O sites. In the first O site, O(8) is bonded to two equivalent Li(3), one Ni(4), one Ni(5), and two equivalent Ni(1) atoms to form OLi2Ni4 octahedra that share  a cornercorner with one O(8)Li2Ni4 octahedra,  a cornercorner with one O(6)Li3Ni3 octahedra, corners with two equivalent O(1)Li3Ni3 octahedra, corners with two equivalent O(3)Li3Ni3 octahedra,  an edgeedge with one O(2)Li3Ni3 octahedra,  an edgeedge with one O(7)Li3Ni3 octahedra, edges with two equivalent O(1)Li3Ni3 octahedra, edges with four equivalent O(5)Li2Ni4 octahedra, and edges with four equivalent O(4)Li3Ni3 octahedra. The corner-sharing octahedral tilt angles range from 0-3°. In the second O site, O(1) is bonded to one Li(1), one Li(3), one Li(5), one Ni(1), one Ni(2), and one Ni(5) atom to form OLi3Ni3 octahedra that share  a cornercorner with one O(5)Li2Ni4 octahedra,  a cornercorner with one O(8)Li2Ni4 octahedra,  a cornercorner with one O(1)Li3Ni3 octahedra,  a cornercorner with one O(2)Li3Ni3 octahedra,  a cornercorner with one O(3)Li3Ni3 octahedra,  a cornercorner with one O(4)Li3Ni3 octahedra,  an edgeedge with one O(5)Li2Ni4 octahedra,  an edgeedge with one O(8)Li2Ni4 octahedra,  an edgeedge with one O(2)Li3Ni3 octahedra,  an edgeedge with one O(6)Li3Ni3 octahedra, edges with two equivalent O(1)Li3Ni3 octahedra, edges with two equivalent O(3)Li3Ni3 octahedra, edges with two equivalent O(4)Li3Ni3 octahedra, and edges with two equivalent O(7)Li3Ni3 octahedra. The corner-sharing octahedral tilt angles range from 0-3°. In the third O site, O(2) is bonded to one Li(2), two equivalent Li(1), one Ni(3), and two equivalent Ni(1) atoms to form OLi3Ni3 octahedra that share  a cornercorner with one O(6)Li3Ni3 octahedra,  a cornercorner with one O(7)Li3Ni3 octahedra, corners with two equivalent O(1)Li3Ni3 octahedra, corners with two equivalent O(4)Li3Ni3 octahedra,  an edgeedge with one O(8)Li2Ni4 octahedra,  an edgeedge with one O(2)Li3Ni3 octahedra, edges with two equivalent O(5)Li2Ni4 octahedra, edges with two equivalent O(1)Li3Ni3 octahedra, edges with two equivalent O(4)Li3Ni3 octahedra, and edges with four equivalent O(3)Li3Ni3 octahedra. The corner-sharing octahedral tilt angles range from 1-5°. In the fourth O site, O(3) is bonded to one Li(1), one Li(2), one Li(3), one Ni(3), and two equivalent Ni(2) atoms to form OLi3Ni3 octahedra that share  a cornercorner with one O(5)Li2Ni4 octahedra,  a cornercorner with one O(8)Li2Ni4 octahedra,  a cornercorner with one O(1)Li3Ni3 octahedra,  a cornercorner with one O(3)Li3Ni3 octahedra,  a cornercorner with one O(4)Li3Ni3 octahedra,  a cornercorner with one O(6)Li3Ni3 octahedra,  an edgeedge with one O(4)Li3Ni3 octahedra,  an edgeedge with one O(6)Li3Ni3 octahedra, edges with two equivalent O(5)Li2Ni4 octahedra, edges with two equivalent O(1)Li3Ni3 octahedra, edges with two equivalent O(2)Li3Ni3 octahedra, edges with two equivalent O(3)Li3Ni3 octahedra, and edges with two equivalent O(7)Li3Ni3 octahedra. The corner-sharing octahedral tilt angles range from 0-3°. In the fifth O site, O(4) is bonded to one Li(2), one Li(3), one Li(4), one Ni(5), and two equivalent Ni(1) atoms to form OLi3Ni3 octahedra that share  a cornercorner with one O(5)Li2Ni4 octahedra,  a cornercorner with one O(1)Li3Ni3 octahedra,  a cornercorner with one O(2)Li3Ni3 octahedra,  a cornercorner with one O(3)Li3Ni3 octahedra,  a cornercorner with one O(4)Li3Ni3 octahedra,  a cornercorner with one O(7)Li3Ni3 octahedra,  an edgeedge with one O(2)Li3Ni3 octahedra,  an edgeedge with one O(3)Li3Ni3 octahedra, edges with two equivalent O(5)Li2Ni4 octahedra, edges with two equivalent O(8)Li2Ni4 octahedra, edges with two equivalent O(1)Li3Ni3 octahedra, edges with two equivalent O(4)Li3Ni3 octahedra, and edges with two equivalent O(6)Li3Ni3 octahedra. The corner-sharing octahedral tilt angles range from 1-3°. In the sixth O site, O(5) is bonded to one Li(3), one Li(4), one Ni(1), one Ni(2), one Ni(3), and one Ni(4) atom to form OLi2Ni4 octahedra that share  a cornercorner with one O(5)Li2Ni4 octahedra,  a cornercorner with one O(1)Li3Ni3 octahedra,  a cornercorner with one O(3)Li3Ni3 octahedra,  a cornercorner with one O(4)Li3Ni3 octahedra,  a cornercorner with one O(6)Li3Ni3 octahedra,  a cornercorner with one O(7)Li3Ni3 octahedra,  an edgeedge with one O(1)Li3Ni3 octahedra,  an edgeedge with one O(2)Li3Ni3 octahedra,  an edgeedge with one O(6)Li3Ni3 octahedra,  an edgeedge with one O(7)Li3Ni3 octahedra, edges with two equivalent O(5)Li2Ni4 octahedra, edges with two equivalent O(8)Li2Ni4 octahedra, edges with two equivalent O(3)Li3Ni3 octahedra, and edges with two equivalent O(4)Li3Ni3 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the seventh O site, O(6) is bonded to one Li(2), two equivalent Li(4), one Ni(5), and two equivalent Ni(2) atoms to form OLi3Ni3 octahedra that share  a cornercorner with one O(8)Li2Ni4 octahedra,  a cornercorner with one O(2)Li3Ni3 octahedra, corners with two equivalent O(5)Li2Ni4 octahedra, corners with two equivalent O(3)Li3Ni3 octahedra,  an edgeedge with one O(6)Li3Ni3 octahedra,  an edgeedge with one O(7)Li3Ni3 octahedra, edges with two equivalent O(5)Li2Ni4 octahedra, edges with two equivalent O(1)Li3Ni3 octahedra, edges with two equivalent O(3)Li3Ni3 octahedra, and edges with four equivalent O(4)Li3Ni3 octahedra. The corner-sharing octahedral tilt angles range from 2-5°. In the eighth O site, O(7) is bonded to one Li(5), two equivalent Li(3), one Ni(3), and two equivalent Ni(2) atoms to form OLi3Ni3 octahedra that share  a cornercorner with one O(2)Li3Ni3 octahedra,  a cornercorner with one O(7)Li3Ni3 octahedra, corners with two equivalent O(5)Li2Ni4 octahedra, corners with two equivalent O(4)Li3Ni3 octahedra,  an edgeedge with one O(8)Li2Ni4 octahedra,  an edgeedge with one O(6)Li3Ni3 octahedra, edges with two equivalent O(5)Li2Ni4 octahedra, edges with four equivalent O(1)Li3Ni3 octahedra, and edges with four equivalent O(3)Li3Ni3 octahedra. The corner-sharing octahedral tilt angles range from 0-3°. is represented by the CIF card [CIF]
data_Li11Ni13O24
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.624
_cell_length_b   8.723
_cell_length_c   7.624
_cell_angle_alpha   72.559
_cell_angle_beta   69.497
_cell_angle_gamma   105.556
_symmetry_Int_Tables_number   1
_cell_volume   411.653
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.708  0.125  0.917  1.0
  Li  Li1  1  0.625  0.872  0.753  1.0
  Li  Li2  1  0.962  0.877  0.414  1.0
  Li  Li3  1  0.210  0.625  0.915  1.0
  Li  Li4  1  0.540  0.625  0.585  1.0
  Li  Li5  1  0.459  0.373  0.415  1.0
  Li  Li6  1  0.788  0.373  0.086  1.0
  Li  Li7  1  0.125  0.378  0.747  1.0
  Li  Li8  1  0.042  0.125  0.583  1.0
  Li  Li9  1  0.375  0.125  0.250  1.0
  Li  Li10  1  0.291  0.877  0.085  1.0
  Ni  Ni11  1  0.916  0.749  0.835  1.0
  Ni  Ni12  1  0.834  0.501  0.665  1.0
  Ni  Ni13  1  0.413  0.248  0.834  1.0
  Ni  Ni14  1  0.751  0.252  0.499  1.0
  Ni  Ni15  1  0.668  0.002  0.336  1.0
  Ni  Ni16  1  0.337  0.002  0.666  1.0
  Ni  Ni17  1  0.875  0.625  0.250  1.0
  Ni  Ni18  1  0.584  0.749  0.167  1.0
  Ni  Ni19  1  0.251  0.752  0.499  1.0
  Ni  Ni20  1  0.499  0.498  0.001  1.0
  Ni  Ni21  1  0.166  0.501  0.333  1.0
  Ni  Ni22  1  0.082  0.248  0.164  1.0
  Ni  Ni23  1  0.999  0.998  0.001  1.0
  O  O24  1  0.592  0.322  0.950  1.0
  O  O25  1  0.928  0.315  0.613  1.0
  O  O26  1  0.822  0.935  0.887  1.0
  O  O27  1  0.860  0.077  0.439  1.0
  O  O28  1  0.516  0.077  0.782  1.0
  O  O29  1  0.724  0.675  0.731  1.0
  O  O30  1  0.983  0.436  0.218  1.0
  O  O31  1  0.654  0.436  0.547  1.0
  O  O32  1  0.301  0.415  0.887  1.0
  O  O33  1  0.234  0.173  0.718  1.0
  O  O34  1  0.890  0.173  0.061  1.0
  O  O35  1  0.578  0.192  0.385  1.0
  O  O36  1  0.096  0.814  0.953  1.0
  O  O37  1  0.767  0.814  0.282  1.0
  O  O38  1  0.449  0.835  0.613  1.0
  O  O39  1  0.343  0.575  0.452  1.0
  O  O40  1  0.026  0.575  0.769  1.0
  O  O41  1  0.690  0.570  0.120  1.0
  O  O42  1  0.272  0.322  0.270  1.0
  O  O43  1  0.158  0.928  0.550  1.0
  O  O44  1  0.478  0.928  0.230  1.0
  O  O45  1  0.172  0.058  0.115  1.0
  O  O46  1  0.060  0.680  0.380  1.0
  O  O47  1  0.407  0.675  0.048  1.0
[/CIF]
.
The compound described by Li11Ni13O24 is Caswellsilverite-like structured and crystallizes in the monoclinic C2/m space group. There are five inequivalent Li sites. In the first Li site, Li(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form LiO6 octahedra that share corners with two equivalent Ni(1)O6 octahedra, corners with two equivalent Ni(2)O6 octahedra, corners with two equivalent Ni(5)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Ni(1)O6 octahedra, edges with two equivalent Ni(2)O6 octahedra, and edges with two equivalent Ni(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-8°. In the second Li site, Li(2) is bonded to one O(2), one O(6), two equivalent O(3), and two equivalent O(4) atoms to form LiO6 octahedra that share  a cornercorner with one Ni(3)O6 octahedra,  a cornercorner with one Ni(5)O6 octahedra, corners with two equivalent Ni(1)O6 octahedra, corners with two equivalent Ni(2)O6 octahedra,  an edgeedge with one Ni(3)O6 octahedra,  an edgeedge with one Ni(5)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Ni(1)O6 octahedra, and edges with two equivalent Ni(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-10°. In the third Li site, Li(3) is bonded to one O(1), one O(3), one O(4), one O(5), one O(7), and one O(8) atom to form LiO6 octahedra that share  a cornercorner with one Ni(3)O6 octahedra,  a cornercorner with one Ni(5)O6 octahedra, corners with two equivalent Ni(1)O6 octahedra, corners with two equivalent Ni(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Ni(3)O6 octahedra,  an edgeedge with one Ni(4)O6 octahedra,  an edgeedge with one Ni(5)O6 octahedra, edges with two equivalent Ni(1)O6 octahedra, and edges with two equivalent Ni(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-9°. In the fourth Li site, Li(4) is bonded to two equivalent O(4), two equivalent O(5), and two equivalent O(6) atoms to form LiO6 octahedra that share corners with two equivalent Ni(1)O6 octahedra, corners with two equivalent Ni(2)O6 octahedra, corners with two equivalent Ni(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Ni(4)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Ni(1)O6 octahedra, edges with two equivalent Ni(2)O6 octahedra, and edges with two equivalent Ni(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-7°. In the fifth Li site, Li(5) is bonded to two equivalent O(7) and four equivalent O(1) atoms to form LiO6 octahedra that share corners with two equivalent Ni(3)O6 octahedra, corners with four equivalent Ni(1)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Ni(5)O6 octahedra, edges with four equivalent Li(3)O6 octahedra, and edges with four equivalent Ni(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-8°. There are five inequivalent Ni sites. In the first Ni site, Ni(1) is bonded to one O(1), one O(2), one O(5), one O(8), and two equivalent O(4) atoms to form NiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra, corners with two equivalent Li(3)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Ni(2)O6 octahedra,  an edgeedge with one Ni(3)O6 octahedra,  an edgeedge with one Ni(4)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Ni(1)O6 octahedra, and edges with two equivalent Ni(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-9°. In the second Ni site, Ni(2) is bonded to one O(1), one O(5), one O(6), one O(7), and two equivalent O(3) atoms to form NiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Ni(4)O6 octahedra, corners with two equivalent Li(3)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(5)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Ni(2)O6 octahedra, and edges with two equivalent Ni(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-9°. In the third Ni site, Ni(3) is bonded to one O(2), one O(7), two equivalent O(3), and two equivalent O(5) atoms to form NiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra, corners with two equivalent Li(3)O6 octahedra, corners with two equivalent Li(4)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Ni(4)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Ni(1)O6 octahedra, and edges with four equivalent Ni(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-7°. In the fourth Ni site, Ni(4) is bonded to two equivalent O(8) and four equivalent O(5) atoms to form NiO6 octahedra that share corners with two equivalent Ni(5)O6 octahedra, corners with four equivalent Ni(2)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Ni(3)O6 octahedra, edges with four equivalent Li(3)O6 octahedra, and edges with four equivalent Ni(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-6°. In the fifth Ni site, Ni(5) is bonded to one O(6), one O(8), two equivalent O(1), and two equivalent O(4) atoms to form NiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Ni(4)O6 octahedra, corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(3)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Ni(2)O6 octahedra, and edges with four equivalent Ni(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-10°. There are eight inequivalent O sites. In the first O site, O(8) is bonded to two equivalent Li(3), one Ni(4), one Ni(5), and two equivalent Ni(1) atoms to form OLi2Ni4 octahedra that share  a cornercorner with one O(8)Li2Ni4 octahedra,  a cornercorner with one O(6)Li3Ni3 octahedra, corners with two equivalent O(1)Li3Ni3 octahedra, corners with two equivalent O(3)Li3Ni3 octahedra,  an edgeedge with one O(2)Li3Ni3 octahedra,  an edgeedge with one O(7)Li3Ni3 octahedra, edges with two equivalent O(1)Li3Ni3 octahedra, edges with four equivalent O(5)Li2Ni4 octahedra, and edges with four equivalent O(4)Li3Ni3 octahedra. The corner-sharing octahedral tilt angles range from 0-3°. In the second O site, O(1) is bonded to one Li(1), one Li(3), one Li(5), one Ni(1), one Ni(2), and one Ni(5) atom to form OLi3Ni3 octahedra that share  a cornercorner with one O(5)Li2Ni4 octahedra,  a cornercorner with one O(8)Li2Ni4 octahedra,  a cornercorner with one O(1)Li3Ni3 octahedra,  a cornercorner with one O(2)Li3Ni3 octahedra,  a cornercorner with one O(3)Li3Ni3 octahedra,  a cornercorner with one O(4)Li3Ni3 octahedra,  an edgeedge with one O(5)Li2Ni4 octahedra,  an edgeedge with one O(8)Li2Ni4 octahedra,  an edgeedge with one O(2)Li3Ni3 octahedra,  an edgeedge with one O(6)Li3Ni3 octahedra, edges with two equivalent O(1)Li3Ni3 octahedra, edges with two equivalent O(3)Li3Ni3 octahedra, edges with two equivalent O(4)Li3Ni3 octahedra, and edges with two equivalent O(7)Li3Ni3 octahedra. The corner-sharing octahedral tilt angles range from 0-3°. In the third O site, O(2) is bonded to one Li(2), two equivalent Li(1), one Ni(3), and two equivalent Ni(1) atoms to form OLi3Ni3 octahedra that share  a cornercorner with one O(6)Li3Ni3 octahedra,  a cornercorner with one O(7)Li3Ni3 octahedra, corners with two equivalent O(1)Li3Ni3 octahedra, corners with two equivalent O(4)Li3Ni3 octahedra,  an edgeedge with one O(8)Li2Ni4 octahedra,  an edgeedge with one O(2)Li3Ni3 octahedra, edges with two equivalent O(5)Li2Ni4 octahedra, edges with two equivalent O(1)Li3Ni3 octahedra, edges with two equivalent O(4)Li3Ni3 octahedra, and edges with four equivalent O(3)Li3Ni3 octahedra. The corner-sharing octahedral tilt angles range from 1-5°. In the fourth O site, O(3) is bonded to one Li(1), one Li(2), one Li(3), one Ni(3), and two equivalent Ni(2) atoms to form OLi3Ni3 octahedra that share  a cornercorner with one O(5)Li2Ni4 octahedra,  a cornercorner with one O(8)Li2Ni4 octahedra,  a cornercorner with one O(1)Li3Ni3 octahedra,  a cornercorner with one O(3)Li3Ni3 octahedra,  a cornercorner with one O(4)Li3Ni3 octahedra,  a cornercorner with one O(6)Li3Ni3 octahedra,  an edgeedge with one O(4)Li3Ni3 octahedra,  an edgeedge with one O(6)Li3Ni3 octahedra, edges with two equivalent O(5)Li2Ni4 octahedra, edges with two equivalent O(1)Li3Ni3 octahedra, edges with two equivalent O(2)Li3Ni3 octahedra, edges with two equivalent O(3)Li3Ni3 octahedra, and edges with two equivalent O(7)Li3Ni3 octahedra. The corner-sharing octahedral tilt angles range from 0-3°. In the fifth O site, O(4) is bonded to one Li(2), one Li(3), one Li(4), one Ni(5), and two equivalent Ni(1) atoms to form OLi3Ni3 octahedra that share  a cornercorner with one O(5)Li2Ni4 octahedra,  a cornercorner with one O(1)Li3Ni3 octahedra,  a cornercorner with one O(2)Li3Ni3 octahedra,  a cornercorner with one O(3)Li3Ni3 octahedra,  a cornercorner with one O(4)Li3Ni3 octahedra,  a cornercorner with one O(7)Li3Ni3 octahedra,  an edgeedge with one O(2)Li3Ni3 octahedra,  an edgeedge with one O(3)Li3Ni3 octahedra, edges with two equivalent O(5)Li2Ni4 octahedra, edges with two equivalent O(8)Li2Ni4 octahedra, edges with two equivalent O(1)Li3Ni3 octahedra, edges with two equivalent O(4)Li3Ni3 octahedra, and edges with two equivalent O(6)Li3Ni3 octahedra. The corner-sharing octahedral tilt angles range from 1-3°. In the sixth O site, O(5) is bonded to one Li(3), one Li(4), one Ni(1), one Ni(2), one Ni(3), and one Ni(4) atom to form OLi2Ni4 octahedra that share  a cornercorner with one O(5)Li2Ni4 octahedra,  a cornercorner with one O(1)Li3Ni3 octahedra,  a cornercorner with one O(3)Li3Ni3 octahedra,  a cornercorner with one O(4)Li3Ni3 octahedra,  a cornercorner with one O(6)Li3Ni3 octahedra,  a cornercorner with one O(7)Li3Ni3 octahedra,  an edgeedge with one O(1)Li3Ni3 octahedra,  an edgeedge with one O(2)Li3Ni3 octahedra,  an edgeedge with one O(6)Li3Ni3 octahedra,  an edgeedge with one O(7)Li3Ni3 octahedra, edges with two equivalent O(5)Li2Ni4 octahedra, edges with two equivalent O(8)Li2Ni4 octahedra, edges with two equivalent O(3)Li3Ni3 octahedra, and edges with two equivalent O(4)Li3Ni3 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the seventh O site, O(6) is bonded to one Li(2), two equivalent Li(4), one Ni(5), and two equivalent Ni(2) atoms to form OLi3Ni3 octahedra that share  a cornercorner with one O(8)Li2Ni4 octahedra,  a cornercorner with one O(2)Li3Ni3 octahedra, corners with two equivalent O(5)Li2Ni4 octahedra, corners with two equivalent O(3)Li3Ni3 octahedra,  an edgeedge with one O(6)Li3Ni3 octahedra,  an edgeedge with one O(7)Li3Ni3 octahedra, edges with two equivalent O(5)Li2Ni4 octahedra, edges with two equivalent O(1)Li3Ni3 octahedra, edges with two equivalent O(3)Li3Ni3 octahedra, and edges with four equivalent O(4)Li3Ni3 octahedra. The corner-sharing octahedral tilt angles range from 2-5°. In the eighth O site, O(7) is bonded to one Li(5), two equivalent Li(3), one Ni(3), and two equivalent Ni(2) atoms to form OLi3Ni3 octahedra that share  a cornercorner with one O(2)Li3Ni3 octahedra,  a cornercorner with one O(7)Li3Ni3 octahedra, corners with two equivalent O(5)Li2Ni4 octahedra, corners with two equivalent O(4)Li3Ni3 octahedra,  an edgeedge with one O(8)Li2Ni4 octahedra,  an edgeedge with one O(6)Li3Ni3 octahedra, edges with two equivalent O(5)Li2Ni4 octahedra, edges with four equivalent O(1)Li3Ni3 octahedra, and edges with four equivalent O(3)Li3Ni3 octahedra. The corner-sharing octahedral tilt angles range from 0-3°. is represented by the CIF card [CIF]
data_Li11Ni13O24
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.624
_cell_length_b   8.723
_cell_length_c   7.624
_cell_angle_alpha   72.559
_cell_angle_beta   69.497
_cell_angle_gamma   105.556
_symmetry_Int_Tables_number   1
_cell_volume   411.653
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.708  0.125  0.917  1.0
  Li  Li1  1  0.625  0.872  0.753  1.0
  Li  Li2  1  0.962  0.877  0.414  1.0
  Li  Li3  1  0.210  0.625  0.915  1.0
  Li  Li4  1  0.540  0.625  0.585  1.0
  Li  Li5  1  0.459  0.373  0.415  1.0
  Li  Li6  1  0.788  0.373  0.086  1.0
  Li  Li7  1  0.125  0.378  0.747  1.0
  Li  Li8  1  0.042  0.125  0.583  1.0
  Li  Li9  1  0.375  0.125  0.250  1.0
  Li  Li10  1  0.291  0.877  0.085  1.0
  Ni  Ni11  1  0.916  0.749  0.835  1.0
  Ni  Ni12  1  0.834  0.501  0.665  1.0
  Ni  Ni13  1  0.413  0.248  0.834  1.0
  Ni  Ni14  1  0.751  0.252  0.499  1.0
  Ni  Ni15  1  0.668  0.002  0.336  1.0
  Ni  Ni16  1  0.337  0.002  0.666  1.0
  Ni  Ni17  1  0.875  0.625  0.250  1.0
  Ni  Ni18  1  0.584  0.749  0.167  1.0
  Ni  Ni19  1  0.251  0.752  0.499  1.0
  Ni  Ni20  1  0.499  0.498  0.001  1.0
  Ni  Ni21  1  0.166  0.501  0.333  1.0
  Ni  Ni22  1  0.082  0.248  0.164  1.0
  Ni  Ni23  1  0.999  0.998  0.001  1.0
  O  O24  1  0.592  0.322  0.950  1.0
  O  O25  1  0.928  0.315  0.613  1.0
  O  O26  1  0.822  0.935  0.887  1.0
  O  O27  1  0.860  0.077  0.439  1.0
  O  O28  1  0.516  0.077  0.782  1.0
  O  O29  1  0.724  0.675  0.731  1.0
  O  O30  1  0.983  0.436  0.218  1.0
  O  O31  1  0.654  0.436  0.547  1.0
  O  O32  1  0.301  0.415  0.887  1.0
  O  O33  1  0.234  0.173  0.718  1.0
  O  O34  1  0.890  0.173  0.061  1.0
  O  O35  1  0.578  0.192  0.385  1.0
  O  O36  1  0.096  0.814  0.953  1.0
  O  O37  1  0.767  0.814  0.282  1.0
  O  O38  1  0.449  0.835  0.613  1.0
  O  O39  1  0.343  0.575  0.452  1.0
  O  O40  1  0.026  0.575  0.769  1.0
  O  O41  1  0.690  0.570  0.120  1.0
  O  O42  1  0.272  0.322  0.270  1.0
  O  O43  1  0.158  0.928  0.550  1.0
  O  O44  1  0.478  0.928  0.230  1.0
  O  O45  1  0.172  0.058  0.115  1.0
  O  O46  1  0.060  0.680  0.380  1.0
  O  O47  1  0.407  0.675  0.048  1.0
[/CIF]
.