The crystal structure described by Sr2MgWCoO6 is Pb (Zr_0.50 Ti_0.48) O_3-derived structured and crystallizes in the triclinic P-1 space group. Sr(1) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. Mg(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form MgO6 octahedra that share faces with two equivalent W(1)O6 octahedra. W(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form WO6 octahedra that share faces with two equivalent Mg(1)O6 octahedra. Co(1) is bonded in a linear geometry to two equivalent O(1) and two equivalent O(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to two equivalent Sr(1), one Mg(1), one W(1), and one Co(1) atom. In the second O site, O(2) is bonded in a distorted see-saw-like geometry to two equivalent Sr(1), one Mg(1), and one W(1) atom. In the third O site, O(3) is bonded in a 5-coordinate geometry to two equivalent Sr(1), one Mg(1), one W(1), and one Co(1) atom. is represented by the CIF card [CIF]
data_Sr2MgCoWO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.993
_cell_length_b   6.648
_cell_length_c   5.416
_cell_angle_alpha   113.573
_cell_angle_beta   122.393
_cell_angle_gamma   101.122
_symmetry_Int_Tables_number   1
_cell_volume   165.726
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.177  0.768  0.503  1.0
  Sr  Sr1  1  0.823  0.232  0.497  1.0
  Mg  Mg2  1  0.500  0.500  0.500  1.0
  Co  Co3  1  1.000  1.000  1.000  1.0
  W  W4  1  0.500  0.500  1.000  1.0
  O  O5  1  0.602  0.796  0.967  1.0
  O  O6  1  0.309  0.597  0.141  1.0
  O  O7  1  0.691  0.403  0.859  1.0
  O  O8  1  0.398  0.204  0.033  1.0
  O  O9  1  0.174  0.320  0.449  1.0
  O  O10  1  0.826  0.680  0.551  1.0
[/CIF]
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The crystal structure described by Sr2MgWCoO6 is Pb (Zr_0.50 Ti_0.48) O_3-derived structured and crystallizes in the triclinic P-1 space group. Sr(1) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. Mg(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form MgO6 octahedra that share faces with two equivalent W(1)O6 octahedra. W(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form WO6 octahedra that share faces with two equivalent Mg(1)O6 octahedra. Co(1) is bonded in a linear geometry to two equivalent O(1) and two equivalent O(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to two equivalent Sr(1), one Mg(1), one W(1), and one Co(1) atom. In the second O site, O(2) is bonded in a distorted see-saw-like geometry to two equivalent Sr(1), one Mg(1), and one W(1) atom. In the third O site, O(3) is bonded in a 5-coordinate geometry to two equivalent Sr(1), one Mg(1), one W(1), and one Co(1) atom. is represented by the CIF card [CIF]
data_Sr2MgCoWO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.993
_cell_length_b   6.648
_cell_length_c   5.416
_cell_angle_alpha   113.573
_cell_angle_beta   122.393
_cell_angle_gamma   101.122
_symmetry_Int_Tables_number   1
_cell_volume   165.726
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.177  0.768  0.503  1.0
  Sr  Sr1  1  0.823  0.232  0.497  1.0
  Mg  Mg2  1  0.500  0.500  0.500  1.0
  Co  Co3  1  1.000  1.000  1.000  1.0
  W  W4  1  0.500  0.500  1.000  1.0
  O  O5  1  0.602  0.796  0.967  1.0
  O  O6  1  0.309  0.597  0.141  1.0
  O  O7  1  0.691  0.403  0.859  1.0
  O  O8  1  0.398  0.204  0.033  1.0
  O  O9  1  0.174  0.320  0.449  1.0
  O  O10  1  0.826  0.680  0.551  1.0
[/CIF]
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