The compound described by GaCl4N2Se3Cl is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four GaCl4 clusters and four N2Se3Cl clusters. In each GaCl4 cluster, Ga(1) is bonded in a tetrahedral geometry to one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Ga(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Ga(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Ga(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Ga(1) atom. In each N2Se3Cl cluster, there are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one Se(1) and one Se(3) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one Se(2) and one Se(3) atom. There are three inequivalent Se sites. In the first Se site, Se(1) is bonded in a single-bond geometry to one N(1) atom. In the second Se site, Se(2) is bonded in a distorted water-like geometry to one N(2) and one Cl(5) atom. In the third Se site, Se(3) is bonded in a water-like geometry to one N(1) and one N(2) atom. Cl(5) is bonded in a single-bond geometry to one Se(2) atom. is represented by the CIF file [CIF]
data_GaSe3N2Cl5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.176
_cell_length_b   9.809
_cell_length_c   15.249
_cell_angle_alpha   50.924
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1297.719
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.366  0.285  0.688  1.0
  Ga  Ga1  1  0.134  0.285  0.188  1.0
  Ga  Ga2  1  0.866  0.715  0.812  1.0
  Ga  Ga3  1  0.634  0.715  0.312  1.0
  Se  Se4  1  0.250  0.644  0.814  1.0
  Se  Se5  1  0.774  0.162  0.396  1.0
  Se  Se6  1  0.750  0.356  0.686  1.0
  Se  Se7  1  0.750  0.356  0.186  1.0
  Se  Se8  1  0.274  0.838  0.104  1.0
  Se  Se9  1  0.226  0.838  0.604  1.0
  Se  Se10  1  0.482  0.832  0.683  1.0
  Se  Se11  1  0.018  0.832  0.183  1.0
  Se  Se12  1  0.518  0.168  0.317  1.0
  Se  Se13  1  0.726  0.162  0.896  1.0
  Se  Se14  1  0.982  0.168  0.817  1.0
  Se  Se15  1  0.250  0.644  0.314  1.0
  N  N16  1  0.097  0.694  0.308  1.0
  N  N17  1  0.379  0.887  0.574  1.0
  N  N18  1  0.879  0.113  0.926  1.0
  N  N19  1  0.597  0.306  0.192  1.0
  N  N20  1  0.621  0.113  0.426  1.0
  N  N21  1  0.121  0.887  0.074  1.0
  N  N22  1  0.403  0.694  0.808  1.0
  N  N23  1  0.903  0.306  0.692  1.0
  Cl  Cl24  1  0.986  0.615  0.748  1.0
  Cl  Cl25  1  0.293  0.027  0.830  1.0
  Cl  Cl26  1  0.716  0.528  0.901  1.0
  Cl  Cl27  1  0.532  0.740  0.424  1.0
  Cl  Cl28  1  0.216  0.472  0.599  1.0
  Cl  Cl29  1  0.968  0.740  0.924  1.0
  Cl  Cl30  1  0.138  0.074  0.574  1.0
  Cl  Cl31  1  0.486  0.385  0.752  1.0
  Cl  Cl32  1  0.014  0.385  0.252  1.0
  Cl  Cl33  1  0.793  0.973  0.670  1.0
  Cl  Cl34  1  0.514  0.615  0.248  1.0
  Cl  Cl35  1  0.707  0.973  0.170  1.0
  Cl  Cl36  1  0.468  0.260  0.576  1.0
  Cl  Cl37  1  0.207  0.027  0.330  1.0
  Cl  Cl38  1  0.362  0.074  0.074  1.0
  Cl  Cl39  1  0.638  0.926  0.926  1.0
  Cl  Cl40  1  0.784  0.528  0.401  1.0
  Cl  Cl41  1  0.284  0.472  0.099  1.0
  Cl  Cl42  1  0.862  0.926  0.426  1.0
  Cl  Cl43  1  0.032  0.260  0.076  1.0
[/CIF]
.
The compound described by GaCl4N2Se3Cl is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four GaCl4 clusters and four N2Se3Cl clusters. In each GaCl4 cluster, Ga(1) is bonded in a tetrahedral geometry to one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Ga(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Ga(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Ga(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Ga(1) atom. In each N2Se3Cl cluster, there are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one Se(1) and one Se(3) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one Se(2) and one Se(3) atom. There are three inequivalent Se sites. In the first Se site, Se(1) is bonded in a single-bond geometry to one N(1) atom. In the second Se site, Se(2) is bonded in a distorted water-like geometry to one N(2) and one Cl(5) atom. In the third Se site, Se(3) is bonded in a water-like geometry to one N(1) and one N(2) atom. Cl(5) is bonded in a single-bond geometry to one Se(2) atom. is represented by the CIF file [CIF]
data_GaSe3N2Cl5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.176
_cell_length_b   9.809
_cell_length_c   15.249
_cell_angle_alpha   50.924
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1297.719
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.366  0.285  0.688  1.0
  Ga  Ga1  1  0.134  0.285  0.188  1.0
  Ga  Ga2  1  0.866  0.715  0.812  1.0
  Ga  Ga3  1  0.634  0.715  0.312  1.0
  Se  Se4  1  0.250  0.644  0.814  1.0
  Se  Se5  1  0.774  0.162  0.396  1.0
  Se  Se6  1  0.750  0.356  0.686  1.0
  Se  Se7  1  0.750  0.356  0.186  1.0
  Se  Se8  1  0.274  0.838  0.104  1.0
  Se  Se9  1  0.226  0.838  0.604  1.0
  Se  Se10  1  0.482  0.832  0.683  1.0
  Se  Se11  1  0.018  0.832  0.183  1.0
  Se  Se12  1  0.518  0.168  0.317  1.0
  Se  Se13  1  0.726  0.162  0.896  1.0
  Se  Se14  1  0.982  0.168  0.817  1.0
  Se  Se15  1  0.250  0.644  0.314  1.0
  N  N16  1  0.097  0.694  0.308  1.0
  N  N17  1  0.379  0.887  0.574  1.0
  N  N18  1  0.879  0.113  0.926  1.0
  N  N19  1  0.597  0.306  0.192  1.0
  N  N20  1  0.621  0.113  0.426  1.0
  N  N21  1  0.121  0.887  0.074  1.0
  N  N22  1  0.403  0.694  0.808  1.0
  N  N23  1  0.903  0.306  0.692  1.0
  Cl  Cl24  1  0.986  0.615  0.748  1.0
  Cl  Cl25  1  0.293  0.027  0.830  1.0
  Cl  Cl26  1  0.716  0.528  0.901  1.0
  Cl  Cl27  1  0.532  0.740  0.424  1.0
  Cl  Cl28  1  0.216  0.472  0.599  1.0
  Cl  Cl29  1  0.968  0.740  0.924  1.0
  Cl  Cl30  1  0.138  0.074  0.574  1.0
  Cl  Cl31  1  0.486  0.385  0.752  1.0
  Cl  Cl32  1  0.014  0.385  0.252  1.0
  Cl  Cl33  1  0.793  0.973  0.670  1.0
  Cl  Cl34  1  0.514  0.615  0.248  1.0
  Cl  Cl35  1  0.707  0.973  0.170  1.0
  Cl  Cl36  1  0.468  0.260  0.576  1.0
  Cl  Cl37  1  0.207  0.027  0.330  1.0
  Cl  Cl38  1  0.362  0.074  0.074  1.0
  Cl  Cl39  1  0.638  0.926  0.926  1.0
  Cl  Cl40  1  0.784  0.528  0.401  1.0
  Cl  Cl41  1  0.284  0.472  0.099  1.0
  Cl  Cl42  1  0.862  0.926  0.426  1.0
  Cl  Cl43  1  0.032  0.260  0.076  1.0
[/CIF]
.