The structure described by CN2H4S is Indium-like structured and crystallizes in the orthorhombic Pmc2_1 space group. The structure is zero-dimensional and consists of two thiourea molecules. C(1) is bonded in a distorted trigonal planar geometry to two equivalent N(1) and one S(1) atom. N(1) is bonded in a trigonal planar geometry to one C(1), one H(1), and one H(2) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. S(1) is bonded in a single-bond geometry to one C(1) atom. is represented by the CIF file [CIF]
data_H4CSN2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.498
_cell_length_b   7.505
_cell_length_c   8.529
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   351.881
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.253  0.637  0.131  1.0
  H  H1  1  0.253  0.637  0.869  1.0
  H  H2  1  0.747  0.137  0.869  1.0
  H  H3  1  0.747  0.137  0.131  1.0
  H  H4  1  0.993  0.577  0.238  1.0
  H  H5  1  0.993  0.577  0.762  1.0
  H  H6  1  0.007  0.077  0.762  1.0
  H  H7  1  0.007  0.077  0.238  1.0
  C  C8  1  0.949  0.573  0.000  1.0
  C  C9  1  0.051  0.073  0.000  1.0
  S  S10  1  0.655  0.506  0.000  1.0
  S  S11  1  0.345  0.006  0.000  1.0
  N  N12  1  0.075  0.600  0.134  1.0
  N  N13  1  0.075  0.600  0.866  1.0
  N  N14  1  0.925  0.100  0.866  1.0
  N  N15  1  0.925  0.100  0.134  1.0
[/CIF]
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The structure described by CN2H4S is Indium-like structured and crystallizes in the orthorhombic Pmc2_1 space group. The structure is zero-dimensional and consists of two thiourea molecules. C(1) is bonded in a distorted trigonal planar geometry to two equivalent N(1) and one S(1) atom. N(1) is bonded in a trigonal planar geometry to one C(1), one H(1), and one H(2) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. S(1) is bonded in a single-bond geometry to one C(1) atom. is represented by the CIF file [CIF]
data_H4CSN2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.498
_cell_length_b   7.505
_cell_length_c   8.529
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   351.881
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.253  0.637  0.131  1.0
  H  H1  1  0.253  0.637  0.869  1.0
  H  H2  1  0.747  0.137  0.869  1.0
  H  H3  1  0.747  0.137  0.131  1.0
  H  H4  1  0.993  0.577  0.238  1.0
  H  H5  1  0.993  0.577  0.762  1.0
  H  H6  1  0.007  0.077  0.762  1.0
  H  H7  1  0.007  0.077  0.238  1.0
  C  C8  1  0.949  0.573  0.000  1.0
  C  C9  1  0.051  0.073  0.000  1.0
  S  S10  1  0.655  0.506  0.000  1.0
  S  S11  1  0.345  0.006  0.000  1.0
  N  N12  1  0.075  0.600  0.134  1.0
  N  N13  1  0.075  0.600  0.866  1.0
  N  N14  1  0.925  0.100  0.866  1.0
  N  N15  1  0.925  0.100  0.134  1.0
[/CIF]
.