The compound described by CdH8(CO3)2(CO)2(H(CO)2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two formaldehyde molecules, two methanol with formaldehyde molecules, and one CdH8(CO3)2 cluster. In the CdH8(CO3)2 cluster, Cd(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(5), and two equivalent O(6) atoms. C(1) is bonded in a distorted single-bond geometry to one O(1) atom. There are four inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one O(5) atom. In the second H site, H(4) is bonded in a single-bond geometry to one O(5) atom. In the third H site, H(5) is bonded in a single-bond geometry to one O(6) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one O(6) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Cd(1) and one C(1) atom. In the second O site, O(5) is bonded in a water-like geometry to one Cd(1), one H(3), and one H(4) atom. In the third O site, O(6) is bonded in a distorted trigonal non-coplanar geometry to one Cd(1), one H(5), and one H(6) atom. is represented by the CIF card [CIF]
data_CdH10(C2O3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.375
_cell_length_b   8.015
_cell_length_c   9.170
_cell_angle_alpha   69.834
_cell_angle_beta   79.484
_cell_angle_gamma   70.121
_symmetry_Int_Tables_number   1
_cell_volume   347.799
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.500  0.500  0.000  1.0
  H  H1  1  0.500  0.500  0.500  1.0
  H  H2  1  0.500  0.000  0.500  1.0
  H  H3  1  0.583  0.869  0.870  1.0
  H  H4  1  0.417  0.131  0.130  1.0
  H  H5  1  0.685  0.794  0.037  1.0
  H  H6  1  0.315  0.206  0.963  1.0
  H  H7  1  0.974  0.285  0.147  1.0
  H  H8  1  0.026  0.715  0.853  1.0
  H  H9  1  0.748  0.337  0.280  1.0
  H  H10  1  0.252  0.663  0.720  1.0
  C  C11  1  0.904  0.324  0.712  1.0
  C  C12  1  0.096  0.676  0.288  1.0
  C  C13  1  0.875  0.306  0.563  1.0
  C  C14  1  0.125  0.694  0.437  1.0
  C  C15  1  0.137  0.174  0.565  1.0
  C  C16  1  0.863  0.826  0.435  1.0
  C  C17  1  0.173  0.186  0.717  1.0
  C  C18  1  0.827  0.814  0.283  1.0
  O  O19  1  0.764  0.421  0.795  1.0
  O  O20  1  0.236  0.579  0.205  1.0
  O  O21  1  0.694  0.383  0.465  1.0
  O  O22  1  0.306  0.617  0.535  1.0
  O  O23  1  0.275  0.090  0.467  1.0
  O  O24  1  0.725  0.910  0.533  1.0
  O  O25  1  0.353  0.116  0.809  1.0
  O  O26  1  0.647  0.884  0.191  1.0
  O  O27  1  0.692  0.755  0.943  1.0
  O  O28  1  0.308  0.245  0.057  1.0
  O  O29  1  0.783  0.304  0.182  1.0
  O  O30  1  0.217  0.696  0.818  1.0
[/CIF]
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The compound described by CdH8(CO3)2(CO)2(H(CO)2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two formaldehyde molecules, two methanol with formaldehyde molecules, and one CdH8(CO3)2 cluster. In the CdH8(CO3)2 cluster, Cd(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(5), and two equivalent O(6) atoms. C(1) is bonded in a distorted single-bond geometry to one O(1) atom. There are four inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one O(5) atom. In the second H site, H(4) is bonded in a single-bond geometry to one O(5) atom. In the third H site, H(5) is bonded in a single-bond geometry to one O(6) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one O(6) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Cd(1) and one C(1) atom. In the second O site, O(5) is bonded in a water-like geometry to one Cd(1), one H(3), and one H(4) atom. In the third O site, O(6) is bonded in a distorted trigonal non-coplanar geometry to one Cd(1), one H(5), and one H(6) atom. is represented by the CIF card [CIF]
data_CdH10(C2O3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.375
_cell_length_b   8.015
_cell_length_c   9.170
_cell_angle_alpha   69.834
_cell_angle_beta   79.484
_cell_angle_gamma   70.121
_symmetry_Int_Tables_number   1
_cell_volume   347.799
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.500  0.500  0.000  1.0
  H  H1  1  0.500  0.500  0.500  1.0
  H  H2  1  0.500  0.000  0.500  1.0
  H  H3  1  0.583  0.869  0.870  1.0
  H  H4  1  0.417  0.131  0.130  1.0
  H  H5  1  0.685  0.794  0.037  1.0
  H  H6  1  0.315  0.206  0.963  1.0
  H  H7  1  0.974  0.285  0.147  1.0
  H  H8  1  0.026  0.715  0.853  1.0
  H  H9  1  0.748  0.337  0.280  1.0
  H  H10  1  0.252  0.663  0.720  1.0
  C  C11  1  0.904  0.324  0.712  1.0
  C  C12  1  0.096  0.676  0.288  1.0
  C  C13  1  0.875  0.306  0.563  1.0
  C  C14  1  0.125  0.694  0.437  1.0
  C  C15  1  0.137  0.174  0.565  1.0
  C  C16  1  0.863  0.826  0.435  1.0
  C  C17  1  0.173  0.186  0.717  1.0
  C  C18  1  0.827  0.814  0.283  1.0
  O  O19  1  0.764  0.421  0.795  1.0
  O  O20  1  0.236  0.579  0.205  1.0
  O  O21  1  0.694  0.383  0.465  1.0
  O  O22  1  0.306  0.617  0.535  1.0
  O  O23  1  0.275  0.090  0.467  1.0
  O  O24  1  0.725  0.910  0.533  1.0
  O  O25  1  0.353  0.116  0.809  1.0
  O  O26  1  0.647  0.884  0.191  1.0
  O  O27  1  0.692  0.755  0.943  1.0
  O  O28  1  0.308  0.245  0.057  1.0
  O  O29  1  0.783  0.304  0.182  1.0
  O  O30  1  0.217  0.696  0.818  1.0
[/CIF]
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