The compound described by NaMoZnHO5 crystallizes in the orthorhombic Pnma space group. Na(1) is bonded in a 7-coordinate geometry to one O(2), one O(3), one O(4), and four equivalent O(1) atoms. Mo(1) is bonded to one O(2), one O(4), and two equivalent O(1) atoms to form MoO4 tetrahedra that share corners with four equivalent Zn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-54°. Zn(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms to form ZnO6 octahedra that share corners with four equivalent Mo(1)O4 tetrahedra and edges with two equivalent Zn(1)O6 octahedra. H(1) is bonded in a single-bond geometry to one O(2) and one O(3) atom. There are four inequivalent O sites. In the first O site, O(4) is bonded to one Na(1), one Mo(1), and two equivalent Zn(1) atoms to form distorted ONaZn2Mo trigonal pyramids that share corners with three equivalent O(3)NaZn2H tetrahedra, corners with two equivalent O(4)NaZn2Mo trigonal pyramids, and  an edgeedge with one O(3)NaZn2H tetrahedra. In the second O site, O(1) is bonded in a 4-coordinate geometry to two equivalent Na(1), one Mo(1), and one Zn(1) atom. In the third O site, O(2) is bonded in a 3-coordinate geometry to one Na(1), one Mo(1), and one H(1) atom. In the fourth O site, O(3) is bonded to one Na(1), two equivalent Zn(1), and one H(1) atom to form distorted ONaZn2H tetrahedra that share corners with two equivalent O(3)NaZn2H tetrahedra, corners with three equivalent O(4)NaZn2Mo trigonal pyramids, and  an edgeedge with one O(4)NaZn2Mo trigonal pyramid. is represented by the Crystallographic Information File (CIF) [CIF]
data_NaZnMoHO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.260
_cell_length_b   7.950
_cell_length_c   9.398
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   467.726
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.750  0.352  0.694  1.0
  Na  Na1  1  0.250  0.648  0.306  1.0
  Na  Na2  1  0.750  0.852  0.806  1.0
  Na  Na3  1  0.250  0.148  0.194  1.0
  Zn  Zn4  1  0.500  0.500  0.000  1.0
  Zn  Zn5  1  0.000  0.500  0.000  1.0
  Zn  Zn6  1  0.000  0.000  0.500  1.0
  Zn  Zn7  1  0.500  0.000  0.500  1.0
  Mo  Mo8  1  0.250  0.117  0.836  1.0
  Mo  Mo9  1  0.750  0.883  0.164  1.0
  Mo  Mo10  1  0.250  0.617  0.664  1.0
  Mo  Mo11  1  0.750  0.383  0.336  1.0
  H  H12  1  0.750  0.755  0.518  1.0
  H  H13  1  0.250  0.245  0.482  1.0
  H  H14  1  0.750  0.255  0.982  1.0
  H  H15  1  0.250  0.745  0.018  1.0
  O  O16  1  0.015  0.106  0.725  1.0
  O  O17  1  0.515  0.894  0.275  1.0
  O  O18  1  0.485  0.606  0.775  1.0
  O  O19  1  0.985  0.394  0.225  1.0
  O  O20  1  0.985  0.894  0.275  1.0
  O  O21  1  0.485  0.106  0.725  1.0
  O  O22  1  0.515  0.394  0.225  1.0
  O  O23  1  0.015  0.606  0.775  1.0
  O  O24  1  0.250  0.447  0.542  1.0
  O  O25  1  0.750  0.553  0.458  1.0
  O  O26  1  0.250  0.947  0.958  1.0
  O  O27  1  0.750  0.053  0.042  1.0
  O  O28  1  0.750  0.869  0.561  1.0
  O  O29  1  0.250  0.131  0.439  1.0
  O  O30  1  0.750  0.369  0.939  1.0
  O  O31  1  0.250  0.631  0.061  1.0
  O  O32  1  0.250  0.309  0.943  1.0
  O  O33  1  0.750  0.691  0.057  1.0
  O  O34  1  0.250  0.809  0.557  1.0
  O  O35  1  0.750  0.191  0.443  1.0
[/CIF]
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The compound described by NaMoZnHO5 crystallizes in the orthorhombic Pnma space group. Na(1) is bonded in a 7-coordinate geometry to one O(2), one O(3), one O(4), and four equivalent O(1) atoms. Mo(1) is bonded to one O(2), one O(4), and two equivalent O(1) atoms to form MoO4 tetrahedra that share corners with four equivalent Zn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-54°. Zn(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms to form ZnO6 octahedra that share corners with four equivalent Mo(1)O4 tetrahedra and edges with two equivalent Zn(1)O6 octahedra. H(1) is bonded in a single-bond geometry to one O(2) and one O(3) atom. There are four inequivalent O sites. In the first O site, O(4) is bonded to one Na(1), one Mo(1), and two equivalent Zn(1) atoms to form distorted ONaZn2Mo trigonal pyramids that share corners with three equivalent O(3)NaZn2H tetrahedra, corners with two equivalent O(4)NaZn2Mo trigonal pyramids, and  an edgeedge with one O(3)NaZn2H tetrahedra. In the second O site, O(1) is bonded in a 4-coordinate geometry to two equivalent Na(1), one Mo(1), and one Zn(1) atom. In the third O site, O(2) is bonded in a 3-coordinate geometry to one Na(1), one Mo(1), and one H(1) atom. In the fourth O site, O(3) is bonded to one Na(1), two equivalent Zn(1), and one H(1) atom to form distorted ONaZn2H tetrahedra that share corners with two equivalent O(3)NaZn2H tetrahedra, corners with three equivalent O(4)NaZn2Mo trigonal pyramids, and  an edgeedge with one O(4)NaZn2Mo trigonal pyramid. is represented by the Crystallographic Information File (CIF) [CIF]
data_NaZnMoHO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.260
_cell_length_b   7.950
_cell_length_c   9.398
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   467.726
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.750  0.352  0.694  1.0
  Na  Na1  1  0.250  0.648  0.306  1.0
  Na  Na2  1  0.750  0.852  0.806  1.0
  Na  Na3  1  0.250  0.148  0.194  1.0
  Zn  Zn4  1  0.500  0.500  0.000  1.0
  Zn  Zn5  1  0.000  0.500  0.000  1.0
  Zn  Zn6  1  0.000  0.000  0.500  1.0
  Zn  Zn7  1  0.500  0.000  0.500  1.0
  Mo  Mo8  1  0.250  0.117  0.836  1.0
  Mo  Mo9  1  0.750  0.883  0.164  1.0
  Mo  Mo10  1  0.250  0.617  0.664  1.0
  Mo  Mo11  1  0.750  0.383  0.336  1.0
  H  H12  1  0.750  0.755  0.518  1.0
  H  H13  1  0.250  0.245  0.482  1.0
  H  H14  1  0.750  0.255  0.982  1.0
  H  H15  1  0.250  0.745  0.018  1.0
  O  O16  1  0.015  0.106  0.725  1.0
  O  O17  1  0.515  0.894  0.275  1.0
  O  O18  1  0.485  0.606  0.775  1.0
  O  O19  1  0.985  0.394  0.225  1.0
  O  O20  1  0.985  0.894  0.275  1.0
  O  O21  1  0.485  0.106  0.725  1.0
  O  O22  1  0.515  0.394  0.225  1.0
  O  O23  1  0.015  0.606  0.775  1.0
  O  O24  1  0.250  0.447  0.542  1.0
  O  O25  1  0.750  0.553  0.458  1.0
  O  O26  1  0.250  0.947  0.958  1.0
  O  O27  1  0.750  0.053  0.042  1.0
  O  O28  1  0.750  0.869  0.561  1.0
  O  O29  1  0.250  0.131  0.439  1.0
  O  O30  1  0.750  0.369  0.939  1.0
  O  O31  1  0.250  0.631  0.061  1.0
  O  O32  1  0.250  0.309  0.943  1.0
  O  O33  1  0.750  0.691  0.057  1.0
  O  O34  1  0.250  0.809  0.557  1.0
  O  O35  1  0.750  0.191  0.443  1.0
[/CIF]
.