The compound described by C2Te(NO2)4 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four C2Te(NO2)4 clusters. C(1) is bonded in a 3-coordinate geometry to one N(1), one N(2), and one O(4) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 2-coordinate geometry to one C(1) and one O(4) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one C(1) and one O(1) atom. Te(1) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. There are four inequivalent O sites. In the first O site, O(2) is bonded in a single-bond geometry to one Te(1) atom. In the second O site, O(3) is bonded in a single-bond geometry to one Te(1) atom. In the third O site, O(4) is bonded in a 2-coordinate geometry to one C(1) and one N(1) atom. In the fourth O site, O(1) is bonded in a distorted bent 120 degrees geometry to one N(2) and one Te(1) atom. is represented by the CIF file [CIF]
data_TeC2(NO2)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.855
_cell_length_b   8.855
_cell_length_c   10.335
_cell_angle_alpha   58.913
_cell_angle_beta   58.913
_cell_angle_gamma   54.624
_symmetry_Int_Tables_number   1
_cell_volume   537.791
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.397  0.603  0.750  1.0
  Te  Te1  1  0.603  0.397  0.250  1.0
  C  C2  1  0.889  0.826  0.007  1.0
  C  C3  1  0.174  0.111  0.493  1.0
  C  C4  1  0.111  0.174  0.993  1.0
  C  C5  1  0.826  0.889  0.507  1.0
  N  N6  1  0.721  0.987  0.013  1.0
  N  N7  1  0.013  0.279  0.487  1.0
  N  N8  1  0.279  0.013  0.987  1.0
  N  N9  1  0.987  0.721  0.513  1.0
  N  N10  1  0.025  0.696  0.068  1.0
  N  N11  1  0.304  0.975  0.432  1.0
  N  N12  1  0.975  0.304  0.932  1.0
  N  N13  1  0.696  0.025  0.568  1.0
  O  O14  1  0.175  0.547  0.033  1.0
  O  O15  1  0.453  0.825  0.467  1.0
  O  O16  1  0.825  0.453  0.967  1.0
  O  O17  1  0.547  0.175  0.533  1.0
  O  O18  1  0.167  0.660  0.730  1.0
  O  O19  1  0.340  0.833  0.770  1.0
  O  O20  1  0.833  0.340  0.270  1.0
  O  O21  1  0.660  0.167  0.230  1.0
  O  O22  1  0.466  0.365  0.738  1.0
  O  O23  1  0.635  0.534  0.762  1.0
  O  O24  1  0.534  0.635  0.262  1.0
  O  O25  1  0.365  0.466  0.238  1.0
  O  O26  1  0.807  0.874  0.901  1.0
  O  O27  1  0.126  0.193  0.599  1.0
  O  O28  1  0.193  0.126  0.099  1.0
  O  O29  1  0.874  0.807  0.401  1.0
[/CIF]
.
The compound described by C2Te(NO2)4 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four C2Te(NO2)4 clusters. C(1) is bonded in a 3-coordinate geometry to one N(1), one N(2), and one O(4) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 2-coordinate geometry to one C(1) and one O(4) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one C(1) and one O(1) atom. Te(1) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. There are four inequivalent O sites. In the first O site, O(2) is bonded in a single-bond geometry to one Te(1) atom. In the second O site, O(3) is bonded in a single-bond geometry to one Te(1) atom. In the third O site, O(4) is bonded in a 2-coordinate geometry to one C(1) and one N(1) atom. In the fourth O site, O(1) is bonded in a distorted bent 120 degrees geometry to one N(2) and one Te(1) atom. is represented by the CIF file [CIF]
data_TeC2(NO2)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.855
_cell_length_b   8.855
_cell_length_c   10.335
_cell_angle_alpha   58.913
_cell_angle_beta   58.913
_cell_angle_gamma   54.624
_symmetry_Int_Tables_number   1
_cell_volume   537.791
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.397  0.603  0.750  1.0
  Te  Te1  1  0.603  0.397  0.250  1.0
  C  C2  1  0.889  0.826  0.007  1.0
  C  C3  1  0.174  0.111  0.493  1.0
  C  C4  1  0.111  0.174  0.993  1.0
  C  C5  1  0.826  0.889  0.507  1.0
  N  N6  1  0.721  0.987  0.013  1.0
  N  N7  1  0.013  0.279  0.487  1.0
  N  N8  1  0.279  0.013  0.987  1.0
  N  N9  1  0.987  0.721  0.513  1.0
  N  N10  1  0.025  0.696  0.068  1.0
  N  N11  1  0.304  0.975  0.432  1.0
  N  N12  1  0.975  0.304  0.932  1.0
  N  N13  1  0.696  0.025  0.568  1.0
  O  O14  1  0.175  0.547  0.033  1.0
  O  O15  1  0.453  0.825  0.467  1.0
  O  O16  1  0.825  0.453  0.967  1.0
  O  O17  1  0.547  0.175  0.533  1.0
  O  O18  1  0.167  0.660  0.730  1.0
  O  O19  1  0.340  0.833  0.770  1.0
  O  O20  1  0.833  0.340  0.270  1.0
  O  O21  1  0.660  0.167  0.230  1.0
  O  O22  1  0.466  0.365  0.738  1.0
  O  O23  1  0.635  0.534  0.762  1.0
  O  O24  1  0.534  0.635  0.262  1.0
  O  O25  1  0.365  0.466  0.238  1.0
  O  O26  1  0.807  0.874  0.901  1.0
  O  O27  1  0.126  0.193  0.599  1.0
  O  O28  1  0.193  0.126  0.099  1.0
  O  O29  1  0.874  0.807  0.401  1.0
[/CIF]
.