The crystal structure described by CoN6(OCl)2 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four CoN6(OCl)2 clusters. Co(1) is bonded in a 7-coordinate geometry to one N(4), two equivalent N(2), two equivalent N(3), and two equivalent Cl(1) atoms. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one N(4) and two equivalent O(1) atoms. In the second N site, N(2) is bonded in a distorted T-shaped geometry to one Co(1) and two equivalent N(3) atoms. In the third N site, N(3) is bonded in a distorted T-shaped geometry to one Co(1) and two equivalent N(2) atoms. In the fourth N site, N(4) is bonded in a distorted linear geometry to one Co(1) and one N(1) atom. O(1) is bonded in a single-bond geometry to one N(1) atom. Cl(1) is bonded in a distorted single-bond geometry to one Co(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CoN6(ClO)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.443
_cell_length_b   6.443
_cell_length_c   9.344
_cell_angle_alpha   84.439
_cell_angle_beta   84.439
_cell_angle_gamma   84.437
_symmetry_Int_Tables_number   1
_cell_volume   382.750
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.913  0.087  0.750  1.0
  Co  Co1  1  0.087  0.913  0.250  1.0
  N  N2  1  0.301  0.699  0.750  1.0
  N  N3  1  0.699  0.301  0.250  1.0
  N  N4  1  0.725  0.290  0.856  1.0
  N  N5  1  0.710  0.275  0.644  1.0
  N  N6  1  0.275  0.710  0.144  1.0
  N  N7  1  0.290  0.725  0.356  1.0
  N  N8  1  0.820  0.391  0.731  1.0
  N  N9  1  0.609  0.180  0.769  1.0
  N  N10  1  0.180  0.609  0.269  1.0
  N  N11  1  0.391  0.820  0.231  1.0
  N  N12  1  0.147  0.853  0.750  1.0
  N  N13  1  0.853  0.147  0.250  1.0
  Cl  Cl14  1  0.185  0.162  0.586  1.0
  Cl  Cl15  1  0.838  0.815  0.914  1.0
  Cl  Cl16  1  0.815  0.838  0.414  1.0
  Cl  Cl17  1  0.162  0.185  0.086  1.0
  O  O18  1  0.454  0.720  0.660  1.0
  O  O19  1  0.280  0.546  0.840  1.0
  O  O20  1  0.546  0.280  0.340  1.0
  O  O21  1  0.720  0.454  0.160  1.0
[/CIF]
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The crystal structure described by CoN6(OCl)2 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four CoN6(OCl)2 clusters. Co(1) is bonded in a 7-coordinate geometry to one N(4), two equivalent N(2), two equivalent N(3), and two equivalent Cl(1) atoms. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one N(4) and two equivalent O(1) atoms. In the second N site, N(2) is bonded in a distorted T-shaped geometry to one Co(1) and two equivalent N(3) atoms. In the third N site, N(3) is bonded in a distorted T-shaped geometry to one Co(1) and two equivalent N(2) atoms. In the fourth N site, N(4) is bonded in a distorted linear geometry to one Co(1) and one N(1) atom. O(1) is bonded in a single-bond geometry to one N(1) atom. Cl(1) is bonded in a distorted single-bond geometry to one Co(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CoN6(ClO)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.443
_cell_length_b   6.443
_cell_length_c   9.344
_cell_angle_alpha   84.439
_cell_angle_beta   84.439
_cell_angle_gamma   84.437
_symmetry_Int_Tables_number   1
_cell_volume   382.750
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.913  0.087  0.750  1.0
  Co  Co1  1  0.087  0.913  0.250  1.0
  N  N2  1  0.301  0.699  0.750  1.0
  N  N3  1  0.699  0.301  0.250  1.0
  N  N4  1  0.725  0.290  0.856  1.0
  N  N5  1  0.710  0.275  0.644  1.0
  N  N6  1  0.275  0.710  0.144  1.0
  N  N7  1  0.290  0.725  0.356  1.0
  N  N8  1  0.820  0.391  0.731  1.0
  N  N9  1  0.609  0.180  0.769  1.0
  N  N10  1  0.180  0.609  0.269  1.0
  N  N11  1  0.391  0.820  0.231  1.0
  N  N12  1  0.147  0.853  0.750  1.0
  N  N13  1  0.853  0.147  0.250  1.0
  Cl  Cl14  1  0.185  0.162  0.586  1.0
  Cl  Cl15  1  0.838  0.815  0.914  1.0
  Cl  Cl16  1  0.815  0.838  0.414  1.0
  Cl  Cl17  1  0.162  0.185  0.086  1.0
  O  O18  1  0.454  0.720  0.660  1.0
  O  O19  1  0.280  0.546  0.840  1.0
  O  O20  1  0.546  0.280  0.340  1.0
  O  O21  1  0.720  0.454  0.160  1.0
[/CIF]
.