The material structure described by WTeBr9 is Indium-like structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two WTeBr9 clusters. W(1) is bonded to one Br(2), one Br(4), two equivalent Br(1), and two equivalent Br(5) atoms to form WBr6 octahedra that share  a faceface with one Te(1)Br6 octahedra. Te(1) is bonded to one Br(3), one Br(4), two equivalent Br(1), and two equivalent Br(6) atoms to form distorted TeBr6 octahedra that share  a faceface with one W(1)Br6 octahedra. There are six inequivalent Br sites. In the first Br site, Br(1) is bonded in an L-shaped geometry to one W(1) and one Te(1) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one W(1) atom. In the third Br site, Br(3) is bonded in a single-bond geometry to one Te(1) atom. In the fourth Br site, Br(4) is bonded in an L-shaped geometry to one W(1) and one Te(1) atom. In the fifth Br site, Br(5) is bonded in a single-bond geometry to one W(1) atom. In the sixth Br site, Br(6) is bonded in a single-bond geometry to one Te(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_TeWBr9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.171
_cell_length_b   7.113
_cell_length_c   10.386
_cell_angle_alpha   76.583
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   874.594
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.250  0.757  0.469  1.0
  Te  Te1  1  0.750  0.243  0.531  1.0
  W  W2  1  0.250  0.645  0.854  1.0
  W  W3  1  0.750  0.355  0.146  1.0
  Br  Br4  1  0.607  0.453  0.306  1.0
  Br  Br5  1  0.107  0.547  0.694  1.0
  Br  Br6  1  0.393  0.547  0.694  1.0
  Br  Br7  1  0.893  0.453  0.306  1.0
  Br  Br8  1  0.750  0.685  0.011  1.0
  Br  Br9  1  0.250  0.315  0.989  1.0
  Br  Br10  1  0.750  0.519  0.651  1.0
  Br  Br11  1  0.250  0.481  0.349  1.0
  Br  Br12  1  0.750  0.021  0.315  1.0
  Br  Br13  1  0.250  0.979  0.685  1.0
  Br  Br14  1  0.899  0.245  0.025  1.0
  Br  Br15  1  0.399  0.755  0.975  1.0
  Br  Br16  1  0.101  0.755  0.975  1.0
  Br  Br17  1  0.601  0.245  0.025  1.0
  Br  Br18  1  0.906  0.051  0.664  1.0
  Br  Br19  1  0.406  0.949  0.336  1.0
  Br  Br20  1  0.094  0.949  0.336  1.0
  Br  Br21  1  0.594  0.051  0.664  1.0
[/CIF]
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The material structure described by WTeBr9 is Indium-like structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two WTeBr9 clusters. W(1) is bonded to one Br(2), one Br(4), two equivalent Br(1), and two equivalent Br(5) atoms to form WBr6 octahedra that share  a faceface with one Te(1)Br6 octahedra. Te(1) is bonded to one Br(3), one Br(4), two equivalent Br(1), and two equivalent Br(6) atoms to form distorted TeBr6 octahedra that share  a faceface with one W(1)Br6 octahedra. There are six inequivalent Br sites. In the first Br site, Br(1) is bonded in an L-shaped geometry to one W(1) and one Te(1) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one W(1) atom. In the third Br site, Br(3) is bonded in a single-bond geometry to one Te(1) atom. In the fourth Br site, Br(4) is bonded in an L-shaped geometry to one W(1) and one Te(1) atom. In the fifth Br site, Br(5) is bonded in a single-bond geometry to one W(1) atom. In the sixth Br site, Br(6) is bonded in a single-bond geometry to one Te(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_TeWBr9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.171
_cell_length_b   7.113
_cell_length_c   10.386
_cell_angle_alpha   76.583
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   874.594
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.250  0.757  0.469  1.0
  Te  Te1  1  0.750  0.243  0.531  1.0
  W  W2  1  0.250  0.645  0.854  1.0
  W  W3  1  0.750  0.355  0.146  1.0
  Br  Br4  1  0.607  0.453  0.306  1.0
  Br  Br5  1  0.107  0.547  0.694  1.0
  Br  Br6  1  0.393  0.547  0.694  1.0
  Br  Br7  1  0.893  0.453  0.306  1.0
  Br  Br8  1  0.750  0.685  0.011  1.0
  Br  Br9  1  0.250  0.315  0.989  1.0
  Br  Br10  1  0.750  0.519  0.651  1.0
  Br  Br11  1  0.250  0.481  0.349  1.0
  Br  Br12  1  0.750  0.021  0.315  1.0
  Br  Br13  1  0.250  0.979  0.685  1.0
  Br  Br14  1  0.899  0.245  0.025  1.0
  Br  Br15  1  0.399  0.755  0.975  1.0
  Br  Br16  1  0.101  0.755  0.975  1.0
  Br  Br17  1  0.601  0.245  0.025  1.0
  Br  Br18  1  0.906  0.051  0.664  1.0
  Br  Br19  1  0.406  0.949  0.336  1.0
  Br  Br20  1  0.094  0.949  0.336  1.0
  Br  Br21  1  0.594  0.051  0.664  1.0
[/CIF]
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