The compound described by S2C2N3H5 is Indium-derived structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of two 1333-74-0 molecules, two aminothiol molecules, two isothiocyanatocyanamide molecules, two methanimine molecules, and two CNH4S2 clusters. In each CNH4S2 cluster, C(4) is bonded in a distorted single-bond geometry to one H(2), one S(3), and one S(4) atom. N(5) is bonded in a bent 120 degrees geometry to one H(4) and one S(4) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one S(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(4) is bonded in a single-bond geometry to one N(5) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one S(3) atom. There are two inequivalent S sites. In the first S site, S(3) is bonded in a distorted trigonal non-coplanar geometry to one C(4), one H(1), and one H(5) atom. In the second S site, S(4) is bonded in a bent 120 degrees geometry to one C(4) and one N(5) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_H5C2S2N3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.927
_cell_length_b   10.499
_cell_length_c   16.907
_cell_angle_alpha   90.000
_cell_angle_beta   83.505
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   869.064
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.255  0.970  0.164  1.0
  H  H1  1  0.745  0.470  0.836  1.0
  H  H2  1  0.074  0.689  0.932  1.0
  H  H3  1  0.926  0.189  0.068  1.0
  H  H4  1  0.135  0.432  0.303  1.0
  H  H5  1  0.865  0.932  0.697  1.0
  H  H6  1  0.372  0.359  0.052  1.0
  H  H7  1  0.628  0.859  0.948  1.0
  H  H8  1  0.883  0.987  0.220  1.0
  H  H9  1  0.117  0.487  0.780  1.0
  H  H10  1  0.047  0.758  0.554  1.0
  H  H11  1  0.953  0.258  0.446  1.0
  H  H12  1  0.532  0.120  0.519  1.0
  H  H13  1  0.468  0.620  0.481  1.0
  H  H14  1  0.450  0.207  0.287  1.0
  H  H15  1  0.550  0.707  0.713  1.0
  H  H16  1  0.700  0.355  0.428  1.0
  H  H17  1  0.300  0.855  0.572  1.0
  H  H18  1  0.562  0.666  0.458  1.0
  H  H19  1  0.438  0.166  0.542  1.0
  C  C20  1  0.462  0.683  0.116  1.0
  C  C21  1  0.538  0.183  0.884  1.0
  C  C22  1  0.806  0.744  0.279  1.0
  C  C23  1  0.194  0.244  0.721  1.0
  C  C24  1  0.468  0.032  0.355  1.0
  C  C25  1  0.532  0.532  0.645  1.0
  C  C26  1  0.023  0.162  0.120  1.0
  C  C27  1  0.977  0.662  0.880  1.0
  S  S28  1  0.990  0.783  0.346  1.0
  S  S29  1  0.010  0.283  0.654  1.0
  S  S30  1  0.117  0.438  0.383  1.0
  S  S31  1  0.883  0.938  0.617  1.0
  S  S32  1  0.002  0.002  0.143  1.0
  S  S33  1  0.998  0.502  0.857  1.0
  S  S34  1  0.254  0.250  0.161  1.0
  S  S35  1  0.746  0.750  0.839  1.0
  N  N36  1  0.496  0.750  0.179  1.0
  N  N37  1  0.504  0.250  0.821  1.0
  N  N38  1  0.690  0.708  0.224  1.0
  N  N39  1  0.310  0.208  0.776  1.0
  N  N40  1  0.405  0.638  0.056  1.0
  N  N41  1  0.595  0.138  0.944  1.0
  N  N42  1  0.885  0.318  0.405  1.0
  N  N43  1  0.115  0.818  0.595  1.0
  N  N44  1  0.405  0.357  0.110  1.0
  N  N45  1  0.595  0.857  0.890  1.0
  N  N46  1  0.468  0.124  0.316  1.0
  N  N47  1  0.532  0.624  0.684  1.0
[/CIF]
.
The compound described by S2C2N3H5 is Indium-derived structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of two 1333-74-0 molecules, two aminothiol molecules, two isothiocyanatocyanamide molecules, two methanimine molecules, and two CNH4S2 clusters. In each CNH4S2 cluster, C(4) is bonded in a distorted single-bond geometry to one H(2), one S(3), and one S(4) atom. N(5) is bonded in a bent 120 degrees geometry to one H(4) and one S(4) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one S(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(4) is bonded in a single-bond geometry to one N(5) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one S(3) atom. There are two inequivalent S sites. In the first S site, S(3) is bonded in a distorted trigonal non-coplanar geometry to one C(4), one H(1), and one H(5) atom. In the second S site, S(4) is bonded in a bent 120 degrees geometry to one C(4) and one N(5) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_H5C2S2N3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.927
_cell_length_b   10.499
_cell_length_c   16.907
_cell_angle_alpha   90.000
_cell_angle_beta   83.505
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   869.064
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.255  0.970  0.164  1.0
  H  H1  1  0.745  0.470  0.836  1.0
  H  H2  1  0.074  0.689  0.932  1.0
  H  H3  1  0.926  0.189  0.068  1.0
  H  H4  1  0.135  0.432  0.303  1.0
  H  H5  1  0.865  0.932  0.697  1.0
  H  H6  1  0.372  0.359  0.052  1.0
  H  H7  1  0.628  0.859  0.948  1.0
  H  H8  1  0.883  0.987  0.220  1.0
  H  H9  1  0.117  0.487  0.780  1.0
  H  H10  1  0.047  0.758  0.554  1.0
  H  H11  1  0.953  0.258  0.446  1.0
  H  H12  1  0.532  0.120  0.519  1.0
  H  H13  1  0.468  0.620  0.481  1.0
  H  H14  1  0.450  0.207  0.287  1.0
  H  H15  1  0.550  0.707  0.713  1.0
  H  H16  1  0.700  0.355  0.428  1.0
  H  H17  1  0.300  0.855  0.572  1.0
  H  H18  1  0.562  0.666  0.458  1.0
  H  H19  1  0.438  0.166  0.542  1.0
  C  C20  1  0.462  0.683  0.116  1.0
  C  C21  1  0.538  0.183  0.884  1.0
  C  C22  1  0.806  0.744  0.279  1.0
  C  C23  1  0.194  0.244  0.721  1.0
  C  C24  1  0.468  0.032  0.355  1.0
  C  C25  1  0.532  0.532  0.645  1.0
  C  C26  1  0.023  0.162  0.120  1.0
  C  C27  1  0.977  0.662  0.880  1.0
  S  S28  1  0.990  0.783  0.346  1.0
  S  S29  1  0.010  0.283  0.654  1.0
  S  S30  1  0.117  0.438  0.383  1.0
  S  S31  1  0.883  0.938  0.617  1.0
  S  S32  1  0.002  0.002  0.143  1.0
  S  S33  1  0.998  0.502  0.857  1.0
  S  S34  1  0.254  0.250  0.161  1.0
  S  S35  1  0.746  0.750  0.839  1.0
  N  N36  1  0.496  0.750  0.179  1.0
  N  N37  1  0.504  0.250  0.821  1.0
  N  N38  1  0.690  0.708  0.224  1.0
  N  N39  1  0.310  0.208  0.776  1.0
  N  N40  1  0.405  0.638  0.056  1.0
  N  N41  1  0.595  0.138  0.944  1.0
  N  N42  1  0.885  0.318  0.405  1.0
  N  N43  1  0.115  0.818  0.595  1.0
  N  N44  1  0.405  0.357  0.110  1.0
  N  N45  1  0.595  0.857  0.890  1.0
  N  N46  1  0.468  0.124  0.316  1.0
  N  N47  1  0.532  0.624  0.684  1.0
[/CIF]
.