The material described by Sr4LaMn5O13 crystallizes in the tetragonal P4_2/m space group. Sr(1) is bonded in a 10-coordinate geometry to one O(1), one O(2), one O(5), two equivalent O(4), two equivalent O(6), and three equivalent O(3) atoms. La(1) is bonded to four equivalent O(1), four equivalent O(2), and four equivalent O(3) atoms to form distorted LaO12 cuboctahedra that share faces with two equivalent La(1)O12 cuboctahedra, faces with four equivalent Mn(1)O5 square pyramids, and faces with four equivalent Mn(2)O5 square pyramids. There are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(2), one O(4), and two equivalent O(3) atoms to form MnO5 square pyramids that share  a cornercorner with one Mn(3)O6 octahedra, corners with four equivalent Mn(2)O5 square pyramids, and faces with two equivalent La(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles are 14°. In the second Mn site, Mn(2) is bonded to one O(1), one O(2), one O(6), and two equivalent O(3) atoms to form MnO5 square pyramids that share  a cornercorner with one Mn(3)O6 octahedra, corners with four equivalent Mn(1)O5 square pyramids, and faces with two equivalent La(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles are 22°. In the third Mn site, Mn(3) is bonded to two equivalent O(4), two equivalent O(5), and two equivalent O(6) atoms to form MnO6 octahedra that share corners with two equivalent Mn(3)O6 octahedra, corners with two equivalent Mn(1)O5 square pyramids, and corners with two equivalent Mn(2)O5 square pyramids. The corner-sharing octahedra are not tilted. There are six inequivalent O sites. In the first O site, O(4) is bonded in a 6-coordinate geometry to four equivalent Sr(1), one Mn(1), and one Mn(3) atom. In the second O site, O(5) is bonded to four equivalent Sr(1) and two equivalent Mn(3) atoms to form distorted OSr4Mn2 octahedra that share corners with two equivalent O(5)Sr4Mn2 octahedra, corners with four equivalent O(3)Sr3LaMn2 octahedra, and edges with four equivalent O(3)Sr3LaMn2 octahedra. The corner-sharing octahedral tilt angles range from 0-8°. In the third O site, O(6) is bonded in a 6-coordinate geometry to four equivalent Sr(1), one Mn(2), and one Mn(3) atom. In the fourth O site, O(1) is bonded in a 4-coordinate geometry to two equivalent Sr(1), two equivalent La(1), one Mn(1), and one Mn(2) atom. In the fifth O site, O(2) is bonded in a 6-coordinate geometry to two equivalent Sr(1), two equivalent La(1), one Mn(1), and one Mn(2) atom. In the sixth O site, O(3) is bonded to three equivalent Sr(1), one La(1), one Mn(1), and one Mn(2) atom to form distorted OSr3LaMn2 octahedra that share  a cornercorner with one O(5)Sr4Mn2 octahedra, corners with five equivalent O(3)Sr3LaMn2 octahedra,  an edgeedge with one O(5)Sr4Mn2 octahedra, and edges with three equivalent O(3)Sr3LaMn2 octahedra. The corner-sharing octahedral tilt angles range from 0-12°. is represented by the CIF card [CIF]
data_Sr4LaMn5O13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.881
_cell_length_b   8.786
_cell_length_c   8.786
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   608.411
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.251  0.279  0.112  1.0
  Sr  Sr1  1  0.251  0.721  0.888  1.0
  Sr  Sr2  1  0.751  0.112  0.721  1.0
  Sr  Sr3  1  0.751  0.888  0.279  1.0
  Sr  Sr4  1  0.749  0.721  0.888  1.0
  Sr  Sr5  1  0.749  0.279  0.112  1.0
  Sr  Sr6  1  0.249  0.888  0.279  1.0
  Sr  Sr7  1  0.249  0.112  0.721  1.0
  La  La8  1  0.250  0.500  0.500  1.0
  La  La9  1  0.750  0.500  0.500  1.0
  Mn  Mn10  1  0.500  0.596  0.195  1.0
  Mn  Mn11  1  0.500  0.404  0.805  1.0
  Mn  Mn12  1  0.000  0.195  0.404  1.0
  Mn  Mn13  1  0.000  0.805  0.596  1.0
  Mn  Mn14  1  0.000  0.603  0.201  1.0
  Mn  Mn15  1  0.000  0.397  0.799  1.0
  Mn  Mn16  1  0.500  0.201  0.397  1.0
  Mn  Mn17  1  0.500  0.799  0.603  1.0
  Mn  Mn18  1  0.500  0.000  0.000  1.0
  Mn  Mn19  1  0.000  0.000  0.000  1.0
  O  O20  1  0.000  0.731  0.392  1.0
  O  O21  1  0.000  0.269  0.608  1.0
  O  O22  1  0.500  0.392  0.269  1.0
  O  O23  1  0.500  0.608  0.731  1.0
  O  O24  1  0.500  0.676  0.417  1.0
  O  O25  1  0.500  0.324  0.583  1.0
  O  O26  1  0.000  0.417  0.324  1.0
  O  O27  1  0.000  0.583  0.676  1.0
  O  O28  1  0.249  0.583  0.186  1.0
  O  O29  1  0.249  0.417  0.814  1.0
  O  O30  1  0.749  0.186  0.417  1.0
  O  O31  1  0.749  0.814  0.583  1.0
  O  O32  1  0.751  0.417  0.814  1.0
  O  O33  1  0.751  0.583  0.186  1.0
  O  O34  1  0.251  0.814  0.583  1.0
  O  O35  1  0.251  0.186  0.417  1.0
  O  O36  1  0.500  0.781  0.075  1.0
  O  O37  1  0.500  0.219  0.925  1.0
  O  O38  1  0.000  0.075  0.219  1.0
  O  O39  1  0.000  0.925  0.781  1.0
  O  O40  1  0.250  0.000  0.000  1.0
  O  O41  1  0.750  0.000  0.000  1.0
  O  O42  1  0.000  0.773  0.066  1.0
  O  O43  1  0.000  0.227  0.934  1.0
  O  O44  1  0.500  0.066  0.227  1.0
  O  O45  1  0.500  0.934  0.773  1.0
[/CIF]
.
The material described by Sr4LaMn5O13 crystallizes in the tetragonal P4_2/m space group. Sr(1) is bonded in a 10-coordinate geometry to one O(1), one O(2), one O(5), two equivalent O(4), two equivalent O(6), and three equivalent O(3) atoms. La(1) is bonded to four equivalent O(1), four equivalent O(2), and four equivalent O(3) atoms to form distorted LaO12 cuboctahedra that share faces with two equivalent La(1)O12 cuboctahedra, faces with four equivalent Mn(1)O5 square pyramids, and faces with four equivalent Mn(2)O5 square pyramids. There are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(2), one O(4), and two equivalent O(3) atoms to form MnO5 square pyramids that share  a cornercorner with one Mn(3)O6 octahedra, corners with four equivalent Mn(2)O5 square pyramids, and faces with two equivalent La(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles are 14°. In the second Mn site, Mn(2) is bonded to one O(1), one O(2), one O(6), and two equivalent O(3) atoms to form MnO5 square pyramids that share  a cornercorner with one Mn(3)O6 octahedra, corners with four equivalent Mn(1)O5 square pyramids, and faces with two equivalent La(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles are 22°. In the third Mn site, Mn(3) is bonded to two equivalent O(4), two equivalent O(5), and two equivalent O(6) atoms to form MnO6 octahedra that share corners with two equivalent Mn(3)O6 octahedra, corners with two equivalent Mn(1)O5 square pyramids, and corners with two equivalent Mn(2)O5 square pyramids. The corner-sharing octahedra are not tilted. There are six inequivalent O sites. In the first O site, O(4) is bonded in a 6-coordinate geometry to four equivalent Sr(1), one Mn(1), and one Mn(3) atom. In the second O site, O(5) is bonded to four equivalent Sr(1) and two equivalent Mn(3) atoms to form distorted OSr4Mn2 octahedra that share corners with two equivalent O(5)Sr4Mn2 octahedra, corners with four equivalent O(3)Sr3LaMn2 octahedra, and edges with four equivalent O(3)Sr3LaMn2 octahedra. The corner-sharing octahedral tilt angles range from 0-8°. In the third O site, O(6) is bonded in a 6-coordinate geometry to four equivalent Sr(1), one Mn(2), and one Mn(3) atom. In the fourth O site, O(1) is bonded in a 4-coordinate geometry to two equivalent Sr(1), two equivalent La(1), one Mn(1), and one Mn(2) atom. In the fifth O site, O(2) is bonded in a 6-coordinate geometry to two equivalent Sr(1), two equivalent La(1), one Mn(1), and one Mn(2) atom. In the sixth O site, O(3) is bonded to three equivalent Sr(1), one La(1), one Mn(1), and one Mn(2) atom to form distorted OSr3LaMn2 octahedra that share  a cornercorner with one O(5)Sr4Mn2 octahedra, corners with five equivalent O(3)Sr3LaMn2 octahedra,  an edgeedge with one O(5)Sr4Mn2 octahedra, and edges with three equivalent O(3)Sr3LaMn2 octahedra. The corner-sharing octahedral tilt angles range from 0-12°. is represented by the CIF card [CIF]
data_Sr4LaMn5O13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.881
_cell_length_b   8.786
_cell_length_c   8.786
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   608.411
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.251  0.279  0.112  1.0
  Sr  Sr1  1  0.251  0.721  0.888  1.0
  Sr  Sr2  1  0.751  0.112  0.721  1.0
  Sr  Sr3  1  0.751  0.888  0.279  1.0
  Sr  Sr4  1  0.749  0.721  0.888  1.0
  Sr  Sr5  1  0.749  0.279  0.112  1.0
  Sr  Sr6  1  0.249  0.888  0.279  1.0
  Sr  Sr7  1  0.249  0.112  0.721  1.0
  La  La8  1  0.250  0.500  0.500  1.0
  La  La9  1  0.750  0.500  0.500  1.0
  Mn  Mn10  1  0.500  0.596  0.195  1.0
  Mn  Mn11  1  0.500  0.404  0.805  1.0
  Mn  Mn12  1  0.000  0.195  0.404  1.0
  Mn  Mn13  1  0.000  0.805  0.596  1.0
  Mn  Mn14  1  0.000  0.603  0.201  1.0
  Mn  Mn15  1  0.000  0.397  0.799  1.0
  Mn  Mn16  1  0.500  0.201  0.397  1.0
  Mn  Mn17  1  0.500  0.799  0.603  1.0
  Mn  Mn18  1  0.500  0.000  0.000  1.0
  Mn  Mn19  1  0.000  0.000  0.000  1.0
  O  O20  1  0.000  0.731  0.392  1.0
  O  O21  1  0.000  0.269  0.608  1.0
  O  O22  1  0.500  0.392  0.269  1.0
  O  O23  1  0.500  0.608  0.731  1.0
  O  O24  1  0.500  0.676  0.417  1.0
  O  O25  1  0.500  0.324  0.583  1.0
  O  O26  1  0.000  0.417  0.324  1.0
  O  O27  1  0.000  0.583  0.676  1.0
  O  O28  1  0.249  0.583  0.186  1.0
  O  O29  1  0.249  0.417  0.814  1.0
  O  O30  1  0.749  0.186  0.417  1.0
  O  O31  1  0.749  0.814  0.583  1.0
  O  O32  1  0.751  0.417  0.814  1.0
  O  O33  1  0.751  0.583  0.186  1.0
  O  O34  1  0.251  0.814  0.583  1.0
  O  O35  1  0.251  0.186  0.417  1.0
  O  O36  1  0.500  0.781  0.075  1.0
  O  O37  1  0.500  0.219  0.925  1.0
  O  O38  1  0.000  0.075  0.219  1.0
  O  O39  1  0.000  0.925  0.781  1.0
  O  O40  1  0.250  0.000  0.000  1.0
  O  O41  1  0.750  0.000  0.000  1.0
  O  O42  1  0.000  0.773  0.066  1.0
  O  O43  1  0.000  0.227  0.934  1.0
  O  O44  1  0.500  0.066  0.227  1.0
  O  O45  1  0.500  0.934  0.773  1.0
[/CIF]
.