The material structure described by AuB2H22(C2N)4AuI2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one AuB2H22(C2N)4 cluster and one AuI2 cluster. In the AuB2H22(C2N)4 cluster, Au(2) is bonded in a distorted linear geometry to two equivalent C(1) atoms. B(1) is bonded to one N(1), one N(2), one H(10), and one H(11) atom to form BH2N2 tetrahedra that share  a cornercorner with one C(2)H3N tetrahedra,  a cornercorner with one C(3)H3N tetrahedra, and  a cornercorner with one C(4)H3N tetrahedra. There are four inequivalent C sites. In the first C site, C(1) is bonded in a single-bond geometry to one Au(2) and one N(2) atom. In the second C site, C(2) is bonded to one N(1), one H(1), one H(2), and one H(3) atom to form CH3N tetrahedra that share  a cornercorner with one B(1)H2N2 tetrahedra,  a cornercorner with one C(3)H3N tetrahedra, and  a cornercorner with one C(4)H3N tetrahedra. In the third C site, C(3) is bonded to one N(1), one H(4), one H(5), and one H(6) atom to form CH3N tetrahedra that share  a cornercorner with one B(1)H2N2 tetrahedra,  a cornercorner with one C(2)H3N tetrahedra, and  a cornercorner with one C(4)H3N tetrahedra. In the fourth C site, C(4) is bonded to one N(1), one H(7), one H(8), and one H(9) atom to form CH3N tetrahedra that share  a cornercorner with one B(1)H2N2 tetrahedra,  a cornercorner with one C(2)H3N tetrahedra, and  a cornercorner with one C(3)H3N tetrahedra. There are two inequivalent N sites. In the first N site, N(1) is bonded in a tetrahedral geometry to one B(1), one C(2), one C(3), and one C(4) atom. In the second N site, N(2) is bonded in a linear geometry to one B(1) and one C(1) atom. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(3) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(4) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(4) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(4) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one B(1) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one B(1) atom. In the AuI2 cluster, Au(1) is bonded in a distorted linear geometry to two equivalent I(1) atoms. I(1) is bonded in a single-bond geometry to one Au(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_BH11AuC4IN2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.233
_cell_length_b   9.425
_cell_length_c   9.928
_cell_angle_alpha   116.511
_cell_angle_beta   90.973
_cell_angle_gamma   101.955
_symmetry_Int_Tables_number   1
_cell_volume   506.579
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.595  0.566  0.756  1.0
  B  B1  1  0.405  0.434  0.244  1.0
  H  H2  1  0.258  0.836  0.913  1.0
  H  H3  1  0.742  0.164  0.087  1.0
  H  H4  1  0.538  0.847  0.972  1.0
  H  H5  1  0.462  0.153  0.028  1.0
  H  H6  1  0.469  0.841  0.793  1.0
  H  H7  1  0.531  0.159  0.207  1.0
  H  H8  1  0.047  0.592  0.697  1.0
  H  H9  1  0.953  0.408  0.303  1.0
  H  H10  1  0.269  0.589  0.583  1.0
  H  H11  1  0.731  0.411  0.417  1.0
  H  H12  1  0.156  0.414  0.611  1.0
  H  H13  1  0.844  0.586  0.389  1.0
  H  H14  1  0.241  0.425  0.861  1.0
  H  H15  1  0.759  0.575  0.139  1.0
  H  H16  1  0.385  0.617  0.015  1.0
  H  H17  1  0.615  0.383  0.985  1.0
  H  H18  1  0.111  0.593  0.937  1.0
  H  H19  1  0.889  0.407  0.063  1.0
  H  H20  1  0.720  0.622  0.872  1.0
  H  H21  1  0.280  0.378  0.128  1.0
  H  H22  1  0.663  0.621  0.670  1.0
  H  H23  1  0.337  0.379  0.330  1.0
  Au  Au24  1  0.000  0.000  0.500  1.0
  Au  Au25  1  0.500  0.000  0.500  1.0
  C  C26  1  0.539  0.241  0.610  1.0
  C  C27  1  0.461  0.759  0.390  1.0
  C  C28  1  0.410  0.798  0.875  1.0
  C  C29  1  0.590  0.202  0.125  1.0
  C  C30  1  0.197  0.548  0.663  1.0
  C  C31  1  0.803  0.452  0.337  1.0
  C  C32  1  0.268  0.558  0.911  1.0
  C  C33  1  0.732  0.442  0.089  1.0
  I  I34  1  0.013  0.047  0.779  1.0
  I  I35  1  0.987  0.953  0.221  1.0
  N  N36  1  0.363  0.615  0.801  1.0
  N  N37  1  0.637  0.385  0.199  1.0
  N  N38  1  0.557  0.382  0.675  1.0
  N  N39  1  0.443  0.618  0.325  1.0
[/CIF]
.
The material structure described by AuB2H22(C2N)4AuI2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one AuB2H22(C2N)4 cluster and one AuI2 cluster. In the AuB2H22(C2N)4 cluster, Au(2) is bonded in a distorted linear geometry to two equivalent C(1) atoms. B(1) is bonded to one N(1), one N(2), one H(10), and one H(11) atom to form BH2N2 tetrahedra that share  a cornercorner with one C(2)H3N tetrahedra,  a cornercorner with one C(3)H3N tetrahedra, and  a cornercorner with one C(4)H3N tetrahedra. There are four inequivalent C sites. In the first C site, C(1) is bonded in a single-bond geometry to one Au(2) and one N(2) atom. In the second C site, C(2) is bonded to one N(1), one H(1), one H(2), and one H(3) atom to form CH3N tetrahedra that share  a cornercorner with one B(1)H2N2 tetrahedra,  a cornercorner with one C(3)H3N tetrahedra, and  a cornercorner with one C(4)H3N tetrahedra. In the third C site, C(3) is bonded to one N(1), one H(4), one H(5), and one H(6) atom to form CH3N tetrahedra that share  a cornercorner with one B(1)H2N2 tetrahedra,  a cornercorner with one C(2)H3N tetrahedra, and  a cornercorner with one C(4)H3N tetrahedra. In the fourth C site, C(4) is bonded to one N(1), one H(7), one H(8), and one H(9) atom to form CH3N tetrahedra that share  a cornercorner with one B(1)H2N2 tetrahedra,  a cornercorner with one C(2)H3N tetrahedra, and  a cornercorner with one C(3)H3N tetrahedra. There are two inequivalent N sites. In the first N site, N(1) is bonded in a tetrahedral geometry to one B(1), one C(2), one C(3), and one C(4) atom. In the second N site, N(2) is bonded in a linear geometry to one B(1) and one C(1) atom. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(3) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(4) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(4) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(4) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one B(1) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one B(1) atom. In the AuI2 cluster, Au(1) is bonded in a distorted linear geometry to two equivalent I(1) atoms. I(1) is bonded in a single-bond geometry to one Au(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_BH11AuC4IN2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.233
_cell_length_b   9.425
_cell_length_c   9.928
_cell_angle_alpha   116.511
_cell_angle_beta   90.973
_cell_angle_gamma   101.955
_symmetry_Int_Tables_number   1
_cell_volume   506.579
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.595  0.566  0.756  1.0
  B  B1  1  0.405  0.434  0.244  1.0
  H  H2  1  0.258  0.836  0.913  1.0
  H  H3  1  0.742  0.164  0.087  1.0
  H  H4  1  0.538  0.847  0.972  1.0
  H  H5  1  0.462  0.153  0.028  1.0
  H  H6  1  0.469  0.841  0.793  1.0
  H  H7  1  0.531  0.159  0.207  1.0
  H  H8  1  0.047  0.592  0.697  1.0
  H  H9  1  0.953  0.408  0.303  1.0
  H  H10  1  0.269  0.589  0.583  1.0
  H  H11  1  0.731  0.411  0.417  1.0
  H  H12  1  0.156  0.414  0.611  1.0
  H  H13  1  0.844  0.586  0.389  1.0
  H  H14  1  0.241  0.425  0.861  1.0
  H  H15  1  0.759  0.575  0.139  1.0
  H  H16  1  0.385  0.617  0.015  1.0
  H  H17  1  0.615  0.383  0.985  1.0
  H  H18  1  0.111  0.593  0.937  1.0
  H  H19  1  0.889  0.407  0.063  1.0
  H  H20  1  0.720  0.622  0.872  1.0
  H  H21  1  0.280  0.378  0.128  1.0
  H  H22  1  0.663  0.621  0.670  1.0
  H  H23  1  0.337  0.379  0.330  1.0
  Au  Au24  1  0.000  0.000  0.500  1.0
  Au  Au25  1  0.500  0.000  0.500  1.0
  C  C26  1  0.539  0.241  0.610  1.0
  C  C27  1  0.461  0.759  0.390  1.0
  C  C28  1  0.410  0.798  0.875  1.0
  C  C29  1  0.590  0.202  0.125  1.0
  C  C30  1  0.197  0.548  0.663  1.0
  C  C31  1  0.803  0.452  0.337  1.0
  C  C32  1  0.268  0.558  0.911  1.0
  C  C33  1  0.732  0.442  0.089  1.0
  I  I34  1  0.013  0.047  0.779  1.0
  I  I35  1  0.987  0.953  0.221  1.0
  N  N36  1  0.363  0.615  0.801  1.0
  N  N37  1  0.637  0.385  0.199  1.0
  N  N38  1  0.557  0.382  0.675  1.0
  N  N39  1  0.443  0.618  0.325  1.0
[/CIF]
.