The compound described by Cs2Li3GaO4 crystallizes in the orthorhombic Ibam space group. Cs(1) is bonded in a distorted body-centered cubic geometry to eight equivalent O(1) atoms. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded to four equivalent O(1) atoms to form distorted LiO4 tetrahedra that share corners with two equivalent Ga(1)O4 tetrahedra,  an edgeedge with one Ga(1)O4 tetrahedra, and edges with two equivalent Li(1)O4 tetrahedra. In the second Li site, Li(2) is bonded in a 4-coordinate geometry to four equivalent O(1) atoms. Ga(1) is bonded to four equivalent O(1) atoms to form distorted GaO4 tetrahedra that share corners with four equivalent Li(1)O4 tetrahedra and edges with two equivalent Li(1)O4 tetrahedra. O(1) is bonded in a 4-coordinate geometry to four equivalent Cs(1), one Li(2), two equivalent Li(1), and one Ga(1) atom. is represented by the CIF card [CIF]
data_Cs2Li3GaO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.260
_cell_length_b   8.260
_cell_length_c   8.260
_cell_angle_alpha   144.102
_cell_angle_beta   104.377
_cell_angle_gamma   86.654
_symmetry_Int_Tables_number   1
_cell_volume   309.858
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.372  0.239  0.611  1.0
  Cs  Cs1  1  0.628  0.761  0.389  1.0
  Cs  Cs2  1  0.872  0.261  0.134  1.0
  Cs  Cs3  1  0.128  0.739  0.866  1.0
  Li  Li4  1  0.490  0.750  0.740  1.0
  Li  Li5  1  0.990  0.250  0.740  1.0
  Li  Li6  1  0.010  0.750  0.260  1.0
  Li  Li7  1  0.250  0.750  0.500  1.0
  Li  Li8  1  0.510  0.250  0.260  1.0
  Li  Li9  1  0.750  0.250  0.500  1.0
  Ga  Ga10  1  0.750  0.750  0.000  1.0
  Ga  Ga11  1  0.250  0.250  0.000  1.0
  O  O12  1  0.058  0.944  0.650  1.0
  O  O13  1  0.207  0.556  0.115  1.0
  O  O14  1  0.793  0.444  0.885  1.0
  O  O15  1  0.558  0.908  0.115  1.0
  O  O16  1  0.942  0.056  0.350  1.0
  O  O17  1  0.707  0.592  0.650  1.0
  O  O18  1  0.442  0.092  0.885  1.0
  O  O19  1  0.293  0.408  0.350  1.0
[/CIF]
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The compound described by Cs2Li3GaO4 crystallizes in the orthorhombic Ibam space group. Cs(1) is bonded in a distorted body-centered cubic geometry to eight equivalent O(1) atoms. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded to four equivalent O(1) atoms to form distorted LiO4 tetrahedra that share corners with two equivalent Ga(1)O4 tetrahedra,  an edgeedge with one Ga(1)O4 tetrahedra, and edges with two equivalent Li(1)O4 tetrahedra. In the second Li site, Li(2) is bonded in a 4-coordinate geometry to four equivalent O(1) atoms. Ga(1) is bonded to four equivalent O(1) atoms to form distorted GaO4 tetrahedra that share corners with four equivalent Li(1)O4 tetrahedra and edges with two equivalent Li(1)O4 tetrahedra. O(1) is bonded in a 4-coordinate geometry to four equivalent Cs(1), one Li(2), two equivalent Li(1), and one Ga(1) atom. is represented by the CIF card [CIF]
data_Cs2Li3GaO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.260
_cell_length_b   8.260
_cell_length_c   8.260
_cell_angle_alpha   144.102
_cell_angle_beta   104.377
_cell_angle_gamma   86.654
_symmetry_Int_Tables_number   1
_cell_volume   309.858
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.372  0.239  0.611  1.0
  Cs  Cs1  1  0.628  0.761  0.389  1.0
  Cs  Cs2  1  0.872  0.261  0.134  1.0
  Cs  Cs3  1  0.128  0.739  0.866  1.0
  Li  Li4  1  0.490  0.750  0.740  1.0
  Li  Li5  1  0.990  0.250  0.740  1.0
  Li  Li6  1  0.010  0.750  0.260  1.0
  Li  Li7  1  0.250  0.750  0.500  1.0
  Li  Li8  1  0.510  0.250  0.260  1.0
  Li  Li9  1  0.750  0.250  0.500  1.0
  Ga  Ga10  1  0.750  0.750  0.000  1.0
  Ga  Ga11  1  0.250  0.250  0.000  1.0
  O  O12  1  0.058  0.944  0.650  1.0
  O  O13  1  0.207  0.556  0.115  1.0
  O  O14  1  0.793  0.444  0.885  1.0
  O  O15  1  0.558  0.908  0.115  1.0
  O  O16  1  0.942  0.056  0.350  1.0
  O  O17  1  0.707  0.592  0.650  1.0
  O  O18  1  0.442  0.092  0.885  1.0
  O  O19  1  0.293  0.408  0.350  1.0
[/CIF]
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