The material described by KLiMnO2 crystallizes in the orthorhombic Cccm space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 6-coordinate geometry to two equivalent O(2) and four equivalent O(1) atoms. In the second K site, K(2) is bonded in a 6-coordinate geometry to two equivalent O(1) and four equivalent O(2) atoms. Li(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form distorted LiO4 tetrahedra that share corners with two equivalent Li(1)O4 tetrahedra, corners with four equivalent Mn(1)O4 tetrahedra,  an edgeedge with one Li(1)O4 tetrahedra, and edges with two equivalent Mn(1)O4 tetrahedra. Mn(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form MnO4 tetrahedra that share corners with two equivalent Mn(1)O4 tetrahedra, corners with four equivalent Li(1)O4 tetrahedra,  an edgeedge with one Mn(1)O4 tetrahedra, and edges with two equivalent Li(1)O4 tetrahedra. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one K(2), two equivalent K(1), two equivalent Li(1), and two equivalent Mn(1) atoms. In the second O site, O(2) is bonded in a 7-coordinate geometry to one K(1), two equivalent K(2), two equivalent Li(1), and two equivalent Mn(1) atoms. is represented by the CIF card [CIF]
data_KLiMnO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.419
_cell_length_b   6.419
_cell_length_c   6.935
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   88.873
_symmetry_Int_Tables_number   1
_cell_volume   285.684
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.000  0.500  0.000  1.0
  K  K1  1  0.500  1.000  0.500  1.0
  K  K2  1  1.000  0.000  0.250  1.0
  K  K3  1  1.000  1.000  0.750  1.0
  Li  Li4  1  0.640  0.640  0.250  1.0
  Li  Li5  1  0.360  0.360  0.750  1.0
  Li  Li6  1  0.640  0.640  0.750  1.0
  Li  Li7  1  0.360  0.360  0.250  1.0
  Mn  Mn8  1  0.167  0.618  0.500  1.0
  Mn  Mn9  1  0.618  0.167  0.000  1.0
  Mn  Mn10  1  0.382  0.833  1.000  1.0
  Mn  Mn11  1  0.833  0.382  0.500  1.0
  O  O12  1  0.322  0.678  0.250  1.0
  O  O13  1  0.322  0.678  0.750  1.0
  O  O14  1  0.678  0.322  0.750  1.0
  O  O15  1  0.678  0.322  0.250  1.0
  O  O16  1  0.160  0.295  0.500  1.0
  O  O17  1  0.705  0.840  1.000  1.0
  O  O18  1  0.295  0.160  1.000  1.0
  O  O19  1  0.840  0.705  0.500  1.0
[/CIF]
.
The material described by KLiMnO2 crystallizes in the orthorhombic Cccm space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 6-coordinate geometry to two equivalent O(2) and four equivalent O(1) atoms. In the second K site, K(2) is bonded in a 6-coordinate geometry to two equivalent O(1) and four equivalent O(2) atoms. Li(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form distorted LiO4 tetrahedra that share corners with two equivalent Li(1)O4 tetrahedra, corners with four equivalent Mn(1)O4 tetrahedra,  an edgeedge with one Li(1)O4 tetrahedra, and edges with two equivalent Mn(1)O4 tetrahedra. Mn(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form MnO4 tetrahedra that share corners with two equivalent Mn(1)O4 tetrahedra, corners with four equivalent Li(1)O4 tetrahedra,  an edgeedge with one Mn(1)O4 tetrahedra, and edges with two equivalent Li(1)O4 tetrahedra. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one K(2), two equivalent K(1), two equivalent Li(1), and two equivalent Mn(1) atoms. In the second O site, O(2) is bonded in a 7-coordinate geometry to one K(1), two equivalent K(2), two equivalent Li(1), and two equivalent Mn(1) atoms. is represented by the CIF card [CIF]
data_KLiMnO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.419
_cell_length_b   6.419
_cell_length_c   6.935
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   88.873
_symmetry_Int_Tables_number   1
_cell_volume   285.684
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.000  0.500  0.000  1.0
  K  K1  1  0.500  1.000  0.500  1.0
  K  K2  1  1.000  0.000  0.250  1.0
  K  K3  1  1.000  1.000  0.750  1.0
  Li  Li4  1  0.640  0.640  0.250  1.0
  Li  Li5  1  0.360  0.360  0.750  1.0
  Li  Li6  1  0.640  0.640  0.750  1.0
  Li  Li7  1  0.360  0.360  0.250  1.0
  Mn  Mn8  1  0.167  0.618  0.500  1.0
  Mn  Mn9  1  0.618  0.167  0.000  1.0
  Mn  Mn10  1  0.382  0.833  1.000  1.0
  Mn  Mn11  1  0.833  0.382  0.500  1.0
  O  O12  1  0.322  0.678  0.250  1.0
  O  O13  1  0.322  0.678  0.750  1.0
  O  O14  1  0.678  0.322  0.750  1.0
  O  O15  1  0.678  0.322  0.250  1.0
  O  O16  1  0.160  0.295  0.500  1.0
  O  O17  1  0.705  0.840  1.000  1.0
  O  O18  1  0.295  0.160  1.000  1.0
  O  O19  1  0.840  0.705  0.500  1.0
[/CIF]
.