The structure described by Na5Mn2P2(CO7)2 crystallizes in the triclinic P-1 space group. There are five inequivalent Na sites. In the first Na site, Na(1) is bonded in a 6-coordinate geometry to one O(10), one O(4), one O(5), one O(9), and two equivalent O(2) atoms. In the second Na site, Na(2) is bonded in a 7-coordinate geometry to one O(1), one O(11), one O(14), one O(4), one O(5), and two equivalent O(7) atoms. In the third Na site, Na(3) is bonded in a 7-coordinate geometry to one O(1), one O(11), one O(13), one O(3), one O(6), and two equivalent O(8) atoms. In the fourth Na site, Na(4) is bonded in a 7-coordinate geometry to one O(12), one O(13), one O(2), one O(3), one O(6), and two equivalent O(9) atoms. In the fifth Na site, Na(5) is bonded in a 6-coordinate geometry to one O(10), one O(12), one O(14), one O(2), one O(4), and one O(5) atom. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(11), one O(13), one O(3), one O(6), one O(8), and one O(9) atom to form distorted MnO6 octahedra that share  a cornercorner with one P(2)O4 tetrahedra and corners with three equivalent P(1)O4 tetrahedra. In the second Mn site, Mn(2) is bonded to one O(10), one O(12), one O(14), one O(4), one O(5), and one O(7) atom to form distorted MnO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra and corners with three equivalent P(2)O4 tetrahedra. There are two inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one O(1), one O(3), and one O(6) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one O(2), one O(4), and one O(5) atom. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(11), one O(13), one O(7), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(2)O6 octahedra and corners with three equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 40-53°. In the second P site, P(2) is bonded to one O(10), one O(12), one O(14), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra and corners with three equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-58°. There are fourteen inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Na(2), one Na(3), and one C(1) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to one Na(4), one Na(5), two equivalent Na(1), and one C(2) atom. In the third O site, O(3) is bonded in a distorted rectangular see-saw-like geometry to one Na(3), one Na(4), one Mn(1), and one C(1) atom. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to one Na(1), one Na(2), one Na(5), one Mn(2), and one C(2) atom. In the fifth O site, O(5) is bonded to one Na(1), one Na(2), one Na(5), one Mn(2), and one C(2) atom to form distorted corner-sharing ONa3MnC trigonal bipyramids. In the sixth O site, O(6) is bonded to one Na(3), one Na(4), one Mn(1), and one C(1) atom to form distorted corner-sharing ONa2MnC trigonal pyramids. In the seventh O site, O(7) is bonded in a 4-coordinate geometry to two equivalent Na(2), one Mn(2), and one P(1) atom. In the eighth O site, O(8) is bonded in a 2-coordinate geometry to two equivalent Na(3), one Mn(1), and one P(1) atom. In the ninth O site, O(9) is bonded in a 4-coordinate geometry to one Na(1), two equivalent Na(4), one Mn(1), and one P(2) atom. In the tenth O site, O(10) is bonded in a 4-coordinate geometry to one Na(1), one Na(5), one Mn(2), and one P(2) atom. In the eleventh O site, O(11) is bonded in a 4-coordinate geometry to one Na(2), one Na(3), one Mn(1), and one P(1) atom. In the twelfth O site, O(12) is bonded to one Na(4), one Na(5), one Mn(2), and one P(2) atom to form distorted ONa2MnP tetrahedra that share corners with two equivalent O(5)Na3MnC trigonal bipyramids and  a cornercorner with one O(6)Na2MnC trigonal pyramid. In the thirteenth O site, O(13) is bonded in a rectangular see-saw-like geometry to one Na(3), one Na(4), one Mn(1), and one P(1) atom. In the fourteenth O site, O(14) is bonded in a distorted rectangular see-saw-like geometry to one Na(2), one Na(5), one Mn(2), and one P(2) atom. is represented by the CIF file [CIF]
data_Na5Mn2P2(CO7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.237
_cell_length_b   9.026
_cell_length_c   13.487
_cell_angle_alpha   89.932
_cell_angle_beta   89.949
_cell_angle_gamma   89.275
_symmetry_Int_Tables_number   1
_cell_volume   637.480
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.242  0.919  0.374  1.0
  Na  Na1  1  0.756  0.750  0.755  1.0
  Na  Na2  1  0.758  0.762  0.996  1.0
  Na  Na3  1  0.754  0.749  0.250  1.0
  Na  Na4  1  0.753  0.741  0.499  1.0
  Na  Na5  1  0.242  0.238  0.004  1.0
  Na  Na6  1  0.244  0.250  0.245  1.0
  Na  Na7  1  0.247  0.259  0.501  1.0
  Na  Na8  1  0.246  0.251  0.750  1.0
  Na  Na9  1  0.758  0.081  0.626  1.0
  Mn  Mn10  1  0.223  0.645  0.124  1.0
  Mn  Mn11  1  0.221  0.641  0.626  1.0
  Mn  Mn12  1  0.777  0.355  0.876  1.0
  Mn  Mn13  1  0.779  0.359  0.374  1.0
  P  P14  1  0.295  0.577  0.876  1.0
  P  P15  1  0.297  0.586  0.374  1.0
  P  P16  1  0.705  0.423  0.124  1.0
  P  P17  1  0.703  0.414  0.626  1.0
  C  C18  1  0.276  0.925  0.125  1.0
  C  C19  1  0.266  0.939  0.625  1.0
  C  C20  1  0.734  0.061  0.375  1.0
  C  C21  1  0.724  0.075  0.875  1.0
  O  O22  1  0.729  0.935  0.872  1.0
  O  O23  1  0.715  0.919  0.377  1.0
  O  O24  1  0.061  0.848  0.123  1.0
  O  O25  1  0.043  0.877  0.624  1.0
  O  O26  1  0.470  0.854  0.625  1.0
  O  O27  1  0.480  0.842  0.125  1.0
  O  O28  1  0.223  0.669  0.784  1.0
  O  O29  1  0.227  0.668  0.970  1.0
  O  O30  1  0.217  0.678  0.280  1.0
  O  O31  1  0.212  0.679  0.465  1.0
  O  O32  1  0.596  0.549  0.874  1.0
  O  O33  1  0.594  0.569  0.375  1.0
  O  O34  1  0.836  0.576  0.123  1.0
  O  O35  1  0.825  0.570  0.627  1.0
  O  O36  1  0.164  0.424  0.877  1.0
  O  O37  1  0.175  0.430  0.373  1.0
  O  O38  1  0.404  0.451  0.126  1.0
  O  O39  1  0.406  0.431  0.625  1.0
  O  O40  1  0.773  0.332  0.030  1.0
  O  O41  1  0.777  0.331  0.216  1.0
  O  O42  1  0.788  0.321  0.535  1.0
  O  O43  1  0.783  0.322  0.720  1.0
  O  O44  1  0.520  0.158  0.875  1.0
  O  O45  1  0.530  0.146  0.375  1.0
  O  O46  1  0.939  0.152  0.877  1.0
  O  O47  1  0.957  0.123  0.376  1.0
  O  O48  1  0.271  0.065  0.128  1.0
  O  O49  1  0.285  0.081  0.623  1.0
[/CIF]
.
The structure described by Na5Mn2P2(CO7)2 crystallizes in the triclinic P-1 space group. There are five inequivalent Na sites. In the first Na site, Na(1) is bonded in a 6-coordinate geometry to one O(10), one O(4), one O(5), one O(9), and two equivalent O(2) atoms. In the second Na site, Na(2) is bonded in a 7-coordinate geometry to one O(1), one O(11), one O(14), one O(4), one O(5), and two equivalent O(7) atoms. In the third Na site, Na(3) is bonded in a 7-coordinate geometry to one O(1), one O(11), one O(13), one O(3), one O(6), and two equivalent O(8) atoms. In the fourth Na site, Na(4) is bonded in a 7-coordinate geometry to one O(12), one O(13), one O(2), one O(3), one O(6), and two equivalent O(9) atoms. In the fifth Na site, Na(5) is bonded in a 6-coordinate geometry to one O(10), one O(12), one O(14), one O(2), one O(4), and one O(5) atom. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(11), one O(13), one O(3), one O(6), one O(8), and one O(9) atom to form distorted MnO6 octahedra that share  a cornercorner with one P(2)O4 tetrahedra and corners with three equivalent P(1)O4 tetrahedra. In the second Mn site, Mn(2) is bonded to one O(10), one O(12), one O(14), one O(4), one O(5), and one O(7) atom to form distorted MnO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra and corners with three equivalent P(2)O4 tetrahedra. There are two inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one O(1), one O(3), and one O(6) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one O(2), one O(4), and one O(5) atom. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(11), one O(13), one O(7), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(2)O6 octahedra and corners with three equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 40-53°. In the second P site, P(2) is bonded to one O(10), one O(12), one O(14), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra and corners with three equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-58°. There are fourteen inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Na(2), one Na(3), and one C(1) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to one Na(4), one Na(5), two equivalent Na(1), and one C(2) atom. In the third O site, O(3) is bonded in a distorted rectangular see-saw-like geometry to one Na(3), one Na(4), one Mn(1), and one C(1) atom. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to one Na(1), one Na(2), one Na(5), one Mn(2), and one C(2) atom. In the fifth O site, O(5) is bonded to one Na(1), one Na(2), one Na(5), one Mn(2), and one C(2) atom to form distorted corner-sharing ONa3MnC trigonal bipyramids. In the sixth O site, O(6) is bonded to one Na(3), one Na(4), one Mn(1), and one C(1) atom to form distorted corner-sharing ONa2MnC trigonal pyramids. In the seventh O site, O(7) is bonded in a 4-coordinate geometry to two equivalent Na(2), one Mn(2), and one P(1) atom. In the eighth O site, O(8) is bonded in a 2-coordinate geometry to two equivalent Na(3), one Mn(1), and one P(1) atom. In the ninth O site, O(9) is bonded in a 4-coordinate geometry to one Na(1), two equivalent Na(4), one Mn(1), and one P(2) atom. In the tenth O site, O(10) is bonded in a 4-coordinate geometry to one Na(1), one Na(5), one Mn(2), and one P(2) atom. In the eleventh O site, O(11) is bonded in a 4-coordinate geometry to one Na(2), one Na(3), one Mn(1), and one P(1) atom. In the twelfth O site, O(12) is bonded to one Na(4), one Na(5), one Mn(2), and one P(2) atom to form distorted ONa2MnP tetrahedra that share corners with two equivalent O(5)Na3MnC trigonal bipyramids and  a cornercorner with one O(6)Na2MnC trigonal pyramid. In the thirteenth O site, O(13) is bonded in a rectangular see-saw-like geometry to one Na(3), one Na(4), one Mn(1), and one P(1) atom. In the fourteenth O site, O(14) is bonded in a distorted rectangular see-saw-like geometry to one Na(2), one Na(5), one Mn(2), and one P(2) atom. is represented by the CIF file [CIF]
data_Na5Mn2P2(CO7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.237
_cell_length_b   9.026
_cell_length_c   13.487
_cell_angle_alpha   89.932
_cell_angle_beta   89.949
_cell_angle_gamma   89.275
_symmetry_Int_Tables_number   1
_cell_volume   637.480
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.242  0.919  0.374  1.0
  Na  Na1  1  0.756  0.750  0.755  1.0
  Na  Na2  1  0.758  0.762  0.996  1.0
  Na  Na3  1  0.754  0.749  0.250  1.0
  Na  Na4  1  0.753  0.741  0.499  1.0
  Na  Na5  1  0.242  0.238  0.004  1.0
  Na  Na6  1  0.244  0.250  0.245  1.0
  Na  Na7  1  0.247  0.259  0.501  1.0
  Na  Na8  1  0.246  0.251  0.750  1.0
  Na  Na9  1  0.758  0.081  0.626  1.0
  Mn  Mn10  1  0.223  0.645  0.124  1.0
  Mn  Mn11  1  0.221  0.641  0.626  1.0
  Mn  Mn12  1  0.777  0.355  0.876  1.0
  Mn  Mn13  1  0.779  0.359  0.374  1.0
  P  P14  1  0.295  0.577  0.876  1.0
  P  P15  1  0.297  0.586  0.374  1.0
  P  P16  1  0.705  0.423  0.124  1.0
  P  P17  1  0.703  0.414  0.626  1.0
  C  C18  1  0.276  0.925  0.125  1.0
  C  C19  1  0.266  0.939  0.625  1.0
  C  C20  1  0.734  0.061  0.375  1.0
  C  C21  1  0.724  0.075  0.875  1.0
  O  O22  1  0.729  0.935  0.872  1.0
  O  O23  1  0.715  0.919  0.377  1.0
  O  O24  1  0.061  0.848  0.123  1.0
  O  O25  1  0.043  0.877  0.624  1.0
  O  O26  1  0.470  0.854  0.625  1.0
  O  O27  1  0.480  0.842  0.125  1.0
  O  O28  1  0.223  0.669  0.784  1.0
  O  O29  1  0.227  0.668  0.970  1.0
  O  O30  1  0.217  0.678  0.280  1.0
  O  O31  1  0.212  0.679  0.465  1.0
  O  O32  1  0.596  0.549  0.874  1.0
  O  O33  1  0.594  0.569  0.375  1.0
  O  O34  1  0.836  0.576  0.123  1.0
  O  O35  1  0.825  0.570  0.627  1.0
  O  O36  1  0.164  0.424  0.877  1.0
  O  O37  1  0.175  0.430  0.373  1.0
  O  O38  1  0.404  0.451  0.126  1.0
  O  O39  1  0.406  0.431  0.625  1.0
  O  O40  1  0.773  0.332  0.030  1.0
  O  O41  1  0.777  0.331  0.216  1.0
  O  O42  1  0.788  0.321  0.535  1.0
  O  O43  1  0.783  0.322  0.720  1.0
  O  O44  1  0.520  0.158  0.875  1.0
  O  O45  1  0.530  0.146  0.375  1.0
  O  O46  1  0.939  0.152  0.877  1.0
  O  O47  1  0.957  0.123  0.376  1.0
  O  O48  1  0.271  0.065  0.128  1.0
  O  O49  1  0.285  0.081  0.623  1.0
[/CIF]
.