The crystal structure described by Zn(PO4)2C4N crystallizes in the orthorhombic Fdd2 space group. The structure consists of eight 5-azabicyclo[2.1.0]pentane molecules inside a Zn(PO4)2 framework. In the Zn(PO4)2 framework, Zn(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form ZnO4 tetrahedra that share corners with four equivalent P(1)O4 tetrahedra. P(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form PO4 tetrahedra that share corners with two equivalent Zn(1)O4 tetrahedra. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one P(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one P(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one P(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one P(1) atom. is represented by the CIF card [CIF]
data_ZnP2C4NO8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.160
_cell_length_b   9.263
_cell_length_c   9.259
_cell_angle_alpha   74.102
_cell_angle_beta   52.963
_cell_angle_gamma   52.935
_symmetry_Int_Tables_number   1
_cell_volume   603.711
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.250  0.250  0.750  1.0
  Zn  Zn1  1  0.500  0.500  0.000  1.0
  P  P2  1  0.253  0.937  0.009  1.0
  P  P3  1  0.937  0.253  0.801  1.0
  P  P4  1  0.241  0.449  0.997  1.0
  P  P5  1  0.449  0.241  0.313  1.0
  C  C6  1  0.641  0.607  0.277  1.0
  C  C7  1  0.607  0.641  0.474  1.0
  C  C8  1  0.973  0.776  0.609  1.0
  C  C9  1  0.776  0.973  0.643  1.0
  C  C10  1  0.478  0.602  0.538  1.0
  C  C11  1  0.602  0.478  0.382  1.0
  C  C12  1  0.712  0.868  0.772  1.0
  C  C13  1  0.868  0.712  0.648  1.0
  N  N14  1  0.691  0.691  0.309  1.0
  N  N15  1  0.941  0.941  0.559  1.0
  O  O16  1  0.346  0.008  0.831  1.0
  O  O17  1  0.008  0.346  0.815  1.0
  O  O18  1  0.419  0.435  0.904  1.0
  O  O19  1  0.435  0.419  0.242  1.0
  O  O20  1  0.399  0.758  0.026  1.0
  O  O21  1  0.758  0.399  0.817  1.0
  O  O22  1  0.224  0.433  0.851  1.0
  O  O23  1  0.433  0.224  0.492  1.0
  O  O24  1  0.128  0.903  0.017  1.0
  O  O25  1  0.903  0.128  0.953  1.0
  O  O26  1  0.233  0.297  0.122  1.0
  O  O27  1  0.297  0.233  0.347  1.0
  O  O28  1  0.105  0.084  0.179  1.0
  O  O29  1  0.084  0.105  0.633  1.0
  O  O30  1  0.071  0.617  0.145  1.0
  O  O31  1  0.617  0.071  0.166  1.0
[/CIF]
.
The crystal structure described by Zn(PO4)2C4N crystallizes in the orthorhombic Fdd2 space group. The structure consists of eight 5-azabicyclo[2.1.0]pentane molecules inside a Zn(PO4)2 framework. In the Zn(PO4)2 framework, Zn(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form ZnO4 tetrahedra that share corners with four equivalent P(1)O4 tetrahedra. P(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form PO4 tetrahedra that share corners with two equivalent Zn(1)O4 tetrahedra. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one P(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one P(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one P(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one P(1) atom. is represented by the CIF card [CIF]
data_ZnP2C4NO8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.160
_cell_length_b   9.263
_cell_length_c   9.259
_cell_angle_alpha   74.102
_cell_angle_beta   52.963
_cell_angle_gamma   52.935
_symmetry_Int_Tables_number   1
_cell_volume   603.711
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.250  0.250  0.750  1.0
  Zn  Zn1  1  0.500  0.500  0.000  1.0
  P  P2  1  0.253  0.937  0.009  1.0
  P  P3  1  0.937  0.253  0.801  1.0
  P  P4  1  0.241  0.449  0.997  1.0
  P  P5  1  0.449  0.241  0.313  1.0
  C  C6  1  0.641  0.607  0.277  1.0
  C  C7  1  0.607  0.641  0.474  1.0
  C  C8  1  0.973  0.776  0.609  1.0
  C  C9  1  0.776  0.973  0.643  1.0
  C  C10  1  0.478  0.602  0.538  1.0
  C  C11  1  0.602  0.478  0.382  1.0
  C  C12  1  0.712  0.868  0.772  1.0
  C  C13  1  0.868  0.712  0.648  1.0
  N  N14  1  0.691  0.691  0.309  1.0
  N  N15  1  0.941  0.941  0.559  1.0
  O  O16  1  0.346  0.008  0.831  1.0
  O  O17  1  0.008  0.346  0.815  1.0
  O  O18  1  0.419  0.435  0.904  1.0
  O  O19  1  0.435  0.419  0.242  1.0
  O  O20  1  0.399  0.758  0.026  1.0
  O  O21  1  0.758  0.399  0.817  1.0
  O  O22  1  0.224  0.433  0.851  1.0
  O  O23  1  0.433  0.224  0.492  1.0
  O  O24  1  0.128  0.903  0.017  1.0
  O  O25  1  0.903  0.128  0.953  1.0
  O  O26  1  0.233  0.297  0.122  1.0
  O  O27  1  0.297  0.233  0.347  1.0
  O  O28  1  0.105  0.084  0.179  1.0
  O  O29  1  0.084  0.105  0.633  1.0
  O  O30  1  0.071  0.617  0.145  1.0
  O  O31  1  0.617  0.071  0.166  1.0
[/CIF]
.