The crystal structure described by SrRe3S4O9O2 crystallizes in the triclinic P-1 space group. The structure consists of two hydrogen peroxide molecules inside a SrRe3S4O9 framework. In the SrRe3S4O9 framework, Sr(1) is bonded in a 7-coordinate geometry to one O(1), one O(4), one O(6), one O(7), one O(8), and two equivalent O(5) atoms. There are three inequivalent Re sites. In the first Re site, Re(1) is bonded in a distorted single-bond geometry to one S(1), one S(2), one S(3), one S(4), and one O(1) atom. In the second Re site, Re(2) is bonded in a distorted single-bond geometry to one S(1), one S(2), one S(3), one S(4), and one O(2) atom. In the third Re site, Re(3) is bonded in a distorted single-bond geometry to one S(1), one S(2), one S(3), one S(4), and one O(3) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a distorted T-shaped geometry to one Re(1), one Re(2), and one Re(3) atom. In the second S site, S(2) is bonded in a distorted T-shaped geometry to one Re(1), one Re(2), and one Re(3) atom. In the third S site, S(3) is bonded in a distorted T-shaped geometry to one Re(1), one Re(2), and one Re(3) atom. In the fourth S site, S(4) is bonded in a distorted T-shaped geometry to one Re(1), one Re(2), and one Re(3) atom. There are nine inequivalent O sites. In the first O site, O(9) is bonded in a single-bond geometry to one O(8) atom. In the second O site, O(1) is bonded in a bent 120 degrees geometry to one Sr(1) and one Re(1) atom. In the third O site, O(2) is bonded in a single-bond geometry to one Re(2) atom. In the fourth O site, O(3) is bonded in a single-bond geometry to one Re(3) atom. In the fifth O site, O(4) is bonded in a bent 150 degrees geometry to one Sr(1) and one O(4) atom. In the sixth O site, O(5) is bonded in a 3-coordinate geometry to two equivalent Sr(1) and one O(5) atom. In the seventh O site, O(6) is bonded in a bent 120 degrees geometry to one Sr(1) and one O(7) atom. In the eighth O site, O(7) is bonded in a bent 120 degrees geometry to one Sr(1) and one O(6) atom. In the ninth O site, O(8) is bonded in a bent 120 degrees geometry to one Sr(1) and one O(9) atom. is represented by the CIF card [CIF]
data_SrRe3S4O11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.595
_cell_length_b   9.052
_cell_length_c   11.288
_cell_angle_alpha   79.764
_cell_angle_beta   73.315
_cell_angle_gamma   68.329
_symmetry_Int_Tables_number   1
_cell_volume   779.222
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.648  0.123  0.076  1.0
  Sr  Sr1  1  0.352  0.877  0.924  1.0
  Re  Re2  1  0.445  0.316  0.389  1.0
  Re  Re3  1  0.555  0.684  0.611  1.0
  Re  Re4  1  0.402  0.362  0.703  1.0
  Re  Re5  1  0.598  0.638  0.297  1.0
  Re  Re6  1  0.199  0.686  0.515  1.0
  Re  Re7  1  0.801  0.314  0.485  1.0
  S  S8  1  0.591  0.183  0.550  1.0
  S  S9  1  0.409  0.817  0.450  1.0
  S  S10  1  0.287  0.644  0.705  1.0
  S  S11  1  0.713  0.356  0.295  1.0
  S  S12  1  0.336  0.589  0.314  1.0
  S  S13  1  0.664  0.411  0.686  1.0
  S  S14  1  0.216  0.414  0.567  1.0
  S  S15  1  0.784  0.586  0.433  1.0
  O  O16  1  0.427  0.188  0.302  1.0
  O  O17  1  0.573  0.812  0.698  1.0
  O  O18  1  0.329  0.269  0.842  1.0
  O  O19  1  0.671  0.731  0.158  1.0
  O  O20  1  0.990  0.809  0.528  1.0
  O  O21  1  0.010  0.191  0.472  1.0
  O  O22  1  0.520  0.437  0.040  1.0
  O  O23  1  0.480  0.563  0.960  1.0
  O  O24  1  0.560  0.997  0.943  1.0
  O  O25  1  0.440  0.003  0.057  1.0
  O  O26  1  0.947  0.150  0.976  1.0
  O  O27  1  0.053  0.850  0.024  1.0
  O  O28  1  0.933  0.917  0.965  1.0
  O  O29  1  0.067  0.083  0.035  1.0
  O  O30  1  0.814  0.974  0.282  1.0
  O  O31  1  0.186  0.026  0.718  1.0
  O  O32  1  0.039  0.017  0.726  1.0
  O  O33  1  0.961  0.983  0.274  1.0
  O  O34  1  0.873  0.659  0.843  1.0
  O  O35  1  0.127  0.341  0.157  1.0
  O  O36  1  0.931  0.517  0.879  1.0
  O  O37  1  0.069  0.483  0.121  1.0
[/CIF]
.
The crystal structure described by SrRe3S4O9O2 crystallizes in the triclinic P-1 space group. The structure consists of two hydrogen peroxide molecules inside a SrRe3S4O9 framework. In the SrRe3S4O9 framework, Sr(1) is bonded in a 7-coordinate geometry to one O(1), one O(4), one O(6), one O(7), one O(8), and two equivalent O(5) atoms. There are three inequivalent Re sites. In the first Re site, Re(1) is bonded in a distorted single-bond geometry to one S(1), one S(2), one S(3), one S(4), and one O(1) atom. In the second Re site, Re(2) is bonded in a distorted single-bond geometry to one S(1), one S(2), one S(3), one S(4), and one O(2) atom. In the third Re site, Re(3) is bonded in a distorted single-bond geometry to one S(1), one S(2), one S(3), one S(4), and one O(3) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a distorted T-shaped geometry to one Re(1), one Re(2), and one Re(3) atom. In the second S site, S(2) is bonded in a distorted T-shaped geometry to one Re(1), one Re(2), and one Re(3) atom. In the third S site, S(3) is bonded in a distorted T-shaped geometry to one Re(1), one Re(2), and one Re(3) atom. In the fourth S site, S(4) is bonded in a distorted T-shaped geometry to one Re(1), one Re(2), and one Re(3) atom. There are nine inequivalent O sites. In the first O site, O(9) is bonded in a single-bond geometry to one O(8) atom. In the second O site, O(1) is bonded in a bent 120 degrees geometry to one Sr(1) and one Re(1) atom. In the third O site, O(2) is bonded in a single-bond geometry to one Re(2) atom. In the fourth O site, O(3) is bonded in a single-bond geometry to one Re(3) atom. In the fifth O site, O(4) is bonded in a bent 150 degrees geometry to one Sr(1) and one O(4) atom. In the sixth O site, O(5) is bonded in a 3-coordinate geometry to two equivalent Sr(1) and one O(5) atom. In the seventh O site, O(6) is bonded in a bent 120 degrees geometry to one Sr(1) and one O(7) atom. In the eighth O site, O(7) is bonded in a bent 120 degrees geometry to one Sr(1) and one O(6) atom. In the ninth O site, O(8) is bonded in a bent 120 degrees geometry to one Sr(1) and one O(9) atom. is represented by the CIF card [CIF]
data_SrRe3S4O11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.595
_cell_length_b   9.052
_cell_length_c   11.288
_cell_angle_alpha   79.764
_cell_angle_beta   73.315
_cell_angle_gamma   68.329
_symmetry_Int_Tables_number   1
_cell_volume   779.222
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.648  0.123  0.076  1.0
  Sr  Sr1  1  0.352  0.877  0.924  1.0
  Re  Re2  1  0.445  0.316  0.389  1.0
  Re  Re3  1  0.555  0.684  0.611  1.0
  Re  Re4  1  0.402  0.362  0.703  1.0
  Re  Re5  1  0.598  0.638  0.297  1.0
  Re  Re6  1  0.199  0.686  0.515  1.0
  Re  Re7  1  0.801  0.314  0.485  1.0
  S  S8  1  0.591  0.183  0.550  1.0
  S  S9  1  0.409  0.817  0.450  1.0
  S  S10  1  0.287  0.644  0.705  1.0
  S  S11  1  0.713  0.356  0.295  1.0
  S  S12  1  0.336  0.589  0.314  1.0
  S  S13  1  0.664  0.411  0.686  1.0
  S  S14  1  0.216  0.414  0.567  1.0
  S  S15  1  0.784  0.586  0.433  1.0
  O  O16  1  0.427  0.188  0.302  1.0
  O  O17  1  0.573  0.812  0.698  1.0
  O  O18  1  0.329  0.269  0.842  1.0
  O  O19  1  0.671  0.731  0.158  1.0
  O  O20  1  0.990  0.809  0.528  1.0
  O  O21  1  0.010  0.191  0.472  1.0
  O  O22  1  0.520  0.437  0.040  1.0
  O  O23  1  0.480  0.563  0.960  1.0
  O  O24  1  0.560  0.997  0.943  1.0
  O  O25  1  0.440  0.003  0.057  1.0
  O  O26  1  0.947  0.150  0.976  1.0
  O  O27  1  0.053  0.850  0.024  1.0
  O  O28  1  0.933  0.917  0.965  1.0
  O  O29  1  0.067  0.083  0.035  1.0
  O  O30  1  0.814  0.974  0.282  1.0
  O  O31  1  0.186  0.026  0.718  1.0
  O  O32  1  0.039  0.017  0.726  1.0
  O  O33  1  0.961  0.983  0.274  1.0
  O  O34  1  0.873  0.659  0.843  1.0
  O  O35  1  0.127  0.341  0.157  1.0
  O  O36  1  0.931  0.517  0.879  1.0
  O  O37  1  0.069  0.483  0.121  1.0
[/CIF]
.