The compound described by NaCdIn2(PO4)3 crystallizes in the monoclinic C2/c space group. Na(1) is bonded in a 6-coordinate geometry to two equivalent O(4) and four equivalent O(2) atoms. Cd(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(6) atoms to form distorted CdO6 octahedra that share corners with two equivalent P(2)O4 tetrahedra, corners with four equivalent P(1)O4 tetrahedra, and edges with two equivalent In(1)O6 octahedra. In(1) is bonded to one O(1), one O(4), one O(5), one O(6), and two equivalent O(3) atoms to form InO6 octahedra that share corners with two equivalent P(2)O4 tetrahedra, corners with four equivalent P(1)O4 tetrahedra,  an edgeedge with one Cd(1)O6 octahedra, and  an edgeedge with one In(1)O6 octahedra. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(2), one O(3), one O(5), and one O(6) atom to form PO4 tetrahedra that share corners with two equivalent Cd(1)O6 octahedra and corners with four equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 39-57°. In the second P site, P(2) is bonded to two equivalent O(1) and two equivalent O(4) atoms to form PO4 tetrahedra that share corners with two equivalent Cd(1)O6 octahedra and corners with four equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-61°. There are six inequivalent O sites. In the first O site, O(5) is bonded in a bent 150 degrees geometry to one In(1) and one P(1) atom. In the second O site, O(6) is bonded in a 3-coordinate geometry to one Cd(1), one In(1), and one P(1) atom. In the third O site, O(1) is bonded in a distorted trigonal planar geometry to one Cd(1), one In(1), and one P(2) atom. In the fourth O site, O(2) is bonded in a 4-coordinate geometry to two equivalent Na(1), one Cd(1), and one P(1) atom. In the fifth O site, O(3) is bonded in a 3-coordinate geometry to two equivalent In(1) and one P(1) atom. In the sixth O site, O(4) is bonded in a distorted trigonal planar geometry to one Na(1), one In(1), and one P(2) atom. is represented by the CIF card [CIF]
data_NaCdIn2(PO4)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.694
_cell_length_b   9.136
_cell_length_c   9.136
_cell_angle_alpha   91.623
_cell_angle_beta   107.447
_cell_angle_gamma   107.447
_symmetry_Int_Tables_number   1
_cell_volume   504.177
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.000  0.500  0.500  1.0
  Na  Na1  1  0.500  0.500  0.500  1.0
  Cd  Cd2  1  0.250  0.260  0.740  1.0
  Cd  Cd3  1  0.750  0.740  0.260  1.0
  In  In4  1  0.369  0.930  0.629  1.0
  In  In5  1  0.131  0.371  0.070  1.0
  In  In6  1  0.869  0.629  0.930  1.0
  In  In7  1  0.631  0.070  0.371  1.0
  P  P8  1  0.366  0.647  0.866  1.0
  P  P9  1  0.750  0.287  0.713  1.0
  P  P10  1  0.134  0.134  0.353  1.0
  P  P11  1  0.866  0.866  0.647  1.0
  P  P12  1  0.250  0.713  0.287  1.0
  P  P13  1  0.634  0.353  0.134  1.0
  O  O14  1  0.960  0.264  0.828  1.0
  O  O15  1  0.181  0.272  0.474  1.0
  O  O16  1  0.187  0.591  0.950  1.0
  O  O17  1  0.261  0.547  0.267  1.0
  O  O18  1  0.142  0.185  0.195  1.0
  O  O19  1  0.405  0.334  0.010  1.0
  O  O20  1  0.460  0.828  0.264  1.0
  O  O21  1  0.681  0.474  0.272  1.0
  O  O22  1  0.687  0.950  0.591  1.0
  O  O23  1  0.761  0.267  0.547  1.0
  O  O24  1  0.642  0.195  0.185  1.0
  O  O25  1  0.095  0.990  0.666  1.0
  O  O26  1  0.905  0.010  0.334  1.0
  O  O27  1  0.358  0.805  0.815  1.0
  O  O28  1  0.239  0.733  0.453  1.0
  O  O29  1  0.313  0.050  0.409  1.0
  O  O30  1  0.319  0.526  0.728  1.0
  O  O31  1  0.540  0.172  0.736  1.0
  O  O32  1  0.595  0.666  0.990  1.0
  O  O33  1  0.858  0.815  0.805  1.0
  O  O34  1  0.739  0.453  0.733  1.0
  O  O35  1  0.813  0.409  0.050  1.0
  O  O36  1  0.819  0.728  0.526  1.0
  O  O37  1  0.040  0.736  0.172  1.0
[/CIF]
.
The compound described by NaCdIn2(PO4)3 crystallizes in the monoclinic C2/c space group. Na(1) is bonded in a 6-coordinate geometry to two equivalent O(4) and four equivalent O(2) atoms. Cd(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(6) atoms to form distorted CdO6 octahedra that share corners with two equivalent P(2)O4 tetrahedra, corners with four equivalent P(1)O4 tetrahedra, and edges with two equivalent In(1)O6 octahedra. In(1) is bonded to one O(1), one O(4), one O(5), one O(6), and two equivalent O(3) atoms to form InO6 octahedra that share corners with two equivalent P(2)O4 tetrahedra, corners with four equivalent P(1)O4 tetrahedra,  an edgeedge with one Cd(1)O6 octahedra, and  an edgeedge with one In(1)O6 octahedra. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(2), one O(3), one O(5), and one O(6) atom to form PO4 tetrahedra that share corners with two equivalent Cd(1)O6 octahedra and corners with four equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 39-57°. In the second P site, P(2) is bonded to two equivalent O(1) and two equivalent O(4) atoms to form PO4 tetrahedra that share corners with two equivalent Cd(1)O6 octahedra and corners with four equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-61°. There are six inequivalent O sites. In the first O site, O(5) is bonded in a bent 150 degrees geometry to one In(1) and one P(1) atom. In the second O site, O(6) is bonded in a 3-coordinate geometry to one Cd(1), one In(1), and one P(1) atom. In the third O site, O(1) is bonded in a distorted trigonal planar geometry to one Cd(1), one In(1), and one P(2) atom. In the fourth O site, O(2) is bonded in a 4-coordinate geometry to two equivalent Na(1), one Cd(1), and one P(1) atom. In the fifth O site, O(3) is bonded in a 3-coordinate geometry to two equivalent In(1) and one P(1) atom. In the sixth O site, O(4) is bonded in a distorted trigonal planar geometry to one Na(1), one In(1), and one P(2) atom. is represented by the CIF card [CIF]
data_NaCdIn2(PO4)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.694
_cell_length_b   9.136
_cell_length_c   9.136
_cell_angle_alpha   91.623
_cell_angle_beta   107.447
_cell_angle_gamma   107.447
_symmetry_Int_Tables_number   1
_cell_volume   504.177
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.000  0.500  0.500  1.0
  Na  Na1  1  0.500  0.500  0.500  1.0
  Cd  Cd2  1  0.250  0.260  0.740  1.0
  Cd  Cd3  1  0.750  0.740  0.260  1.0
  In  In4  1  0.369  0.930  0.629  1.0
  In  In5  1  0.131  0.371  0.070  1.0
  In  In6  1  0.869  0.629  0.930  1.0
  In  In7  1  0.631  0.070  0.371  1.0
  P  P8  1  0.366  0.647  0.866  1.0
  P  P9  1  0.750  0.287  0.713  1.0
  P  P10  1  0.134  0.134  0.353  1.0
  P  P11  1  0.866  0.866  0.647  1.0
  P  P12  1  0.250  0.713  0.287  1.0
  P  P13  1  0.634  0.353  0.134  1.0
  O  O14  1  0.960  0.264  0.828  1.0
  O  O15  1  0.181  0.272  0.474  1.0
  O  O16  1  0.187  0.591  0.950  1.0
  O  O17  1  0.261  0.547  0.267  1.0
  O  O18  1  0.142  0.185  0.195  1.0
  O  O19  1  0.405  0.334  0.010  1.0
  O  O20  1  0.460  0.828  0.264  1.0
  O  O21  1  0.681  0.474  0.272  1.0
  O  O22  1  0.687  0.950  0.591  1.0
  O  O23  1  0.761  0.267  0.547  1.0
  O  O24  1  0.642  0.195  0.185  1.0
  O  O25  1  0.095  0.990  0.666  1.0
  O  O26  1  0.905  0.010  0.334  1.0
  O  O27  1  0.358  0.805  0.815  1.0
  O  O28  1  0.239  0.733  0.453  1.0
  O  O29  1  0.313  0.050  0.409  1.0
  O  O30  1  0.319  0.526  0.728  1.0
  O  O31  1  0.540  0.172  0.736  1.0
  O  O32  1  0.595  0.666  0.990  1.0
  O  O33  1  0.858  0.815  0.805  1.0
  O  O34  1  0.739  0.453  0.733  1.0
  O  O35  1  0.813  0.409  0.050  1.0
  O  O36  1  0.819  0.728  0.526  1.0
  O  O37  1  0.040  0.736  0.172  1.0
[/CIF]
.