The material structure described by F2PNNNO is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four F2PNNNO clusters. In two of the F2PNNNO clusters, P(1) is bonded in a tetrahedral geometry to one N(1), one O(1), one F(1), and one F(2) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one P(1) and one N(2) atom. In the second N site, N(2) is bonded in a linear geometry to one N(1) and one N(3) atom. In the third N site, N(3) is bonded in a single-bond geometry to one N(2) atom. O(1) is bonded in a single-bond geometry to one P(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one P(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one P(1) atom. In two of the F2PNNNO clusters, P(2) is bonded in a distorted tetrahedral geometry to one N(4), one O(2), one F(3), and one F(4) atom. There are three inequivalent N sites. In the first N site, N(4) is bonded in a bent 120 degrees geometry to one P(2) and one N(5) atom. In the second N site, N(5) is bonded in a linear geometry to one N(4) and one N(6) atom. In the third N site, N(6) is bonded in a single-bond geometry to one N(5) atom. O(2) is bonded in a single-bond geometry to one P(2) atom. There are two inequivalent F sites. In the first F site, F(3) is bonded in a single-bond geometry to one P(2) atom. In the second F site, F(4) is bonded in a single-bond geometry to one P(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_PN3OF2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.041
_cell_length_b   6.089
_cell_length_c   13.151
_cell_angle_alpha   97.130
_cell_angle_beta   91.217
_cell_angle_gamma   90.108
_symmetry_Int_Tables_number   1
_cell_volume   479.891
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.743  0.881  0.903  1.0
  P  P1  1  0.257  0.119  0.097  1.0
  P  P2  1  0.675  0.227  0.424  1.0
  P  P3  1  0.325  0.773  0.576  1.0
  N  N4  1  0.746  0.647  0.957  1.0
  N  N5  1  0.254  0.353  0.043  1.0
  N  N6  1  0.754  0.654  0.051  1.0
  N  N7  1  0.246  0.346  0.949  1.0
  N  N8  1  0.761  0.641  0.137  1.0
  N  N9  1  0.239  0.359  0.863  1.0
  N  N10  1  0.852  0.257  0.523  1.0
  N  N11  1  0.148  0.743  0.477  1.0
  N  N12  1  0.784  0.282  0.612  1.0
  N  N13  1  0.216  0.718  0.388  1.0
  N  N14  1  0.742  0.306  0.697  1.0
  N  N15  1  0.258  0.694  0.303  1.0
  O  O16  1  0.749  0.095  0.967  1.0
  O  O17  1  0.251  0.905  0.033  1.0
  O  O18  1  0.436  0.232  0.440  1.0
  O  O19  1  0.564  0.768  0.560  1.0
  F  F20  1  0.932  0.843  0.824  1.0
  F  F21  1  0.068  0.157  0.176  1.0
  F  F22  1  0.540  0.845  0.828  1.0
  F  F23  1  0.460  0.155  0.172  1.0
  F  F24  1  0.762  0.403  0.358  1.0
  F  F25  1  0.238  0.597  0.642  1.0
  F  F26  1  0.761  0.015  0.358  1.0
  F  F27  1  0.239  0.985  0.642  1.0
[/CIF]
.
The material structure described by F2PNNNO is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four F2PNNNO clusters. In two of the F2PNNNO clusters, P(1) is bonded in a tetrahedral geometry to one N(1), one O(1), one F(1), and one F(2) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one P(1) and one N(2) atom. In the second N site, N(2) is bonded in a linear geometry to one N(1) and one N(3) atom. In the third N site, N(3) is bonded in a single-bond geometry to one N(2) atom. O(1) is bonded in a single-bond geometry to one P(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one P(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one P(1) atom. In two of the F2PNNNO clusters, P(2) is bonded in a distorted tetrahedral geometry to one N(4), one O(2), one F(3), and one F(4) atom. There are three inequivalent N sites. In the first N site, N(4) is bonded in a bent 120 degrees geometry to one P(2) and one N(5) atom. In the second N site, N(5) is bonded in a linear geometry to one N(4) and one N(6) atom. In the third N site, N(6) is bonded in a single-bond geometry to one N(5) atom. O(2) is bonded in a single-bond geometry to one P(2) atom. There are two inequivalent F sites. In the first F site, F(3) is bonded in a single-bond geometry to one P(2) atom. In the second F site, F(4) is bonded in a single-bond geometry to one P(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_PN3OF2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.041
_cell_length_b   6.089
_cell_length_c   13.151
_cell_angle_alpha   97.130
_cell_angle_beta   91.217
_cell_angle_gamma   90.108
_symmetry_Int_Tables_number   1
_cell_volume   479.891
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.743  0.881  0.903  1.0
  P  P1  1  0.257  0.119  0.097  1.0
  P  P2  1  0.675  0.227  0.424  1.0
  P  P3  1  0.325  0.773  0.576  1.0
  N  N4  1  0.746  0.647  0.957  1.0
  N  N5  1  0.254  0.353  0.043  1.0
  N  N6  1  0.754  0.654  0.051  1.0
  N  N7  1  0.246  0.346  0.949  1.0
  N  N8  1  0.761  0.641  0.137  1.0
  N  N9  1  0.239  0.359  0.863  1.0
  N  N10  1  0.852  0.257  0.523  1.0
  N  N11  1  0.148  0.743  0.477  1.0
  N  N12  1  0.784  0.282  0.612  1.0
  N  N13  1  0.216  0.718  0.388  1.0
  N  N14  1  0.742  0.306  0.697  1.0
  N  N15  1  0.258  0.694  0.303  1.0
  O  O16  1  0.749  0.095  0.967  1.0
  O  O17  1  0.251  0.905  0.033  1.0
  O  O18  1  0.436  0.232  0.440  1.0
  O  O19  1  0.564  0.768  0.560  1.0
  F  F20  1  0.932  0.843  0.824  1.0
  F  F21  1  0.068  0.157  0.176  1.0
  F  F22  1  0.540  0.845  0.828  1.0
  F  F23  1  0.460  0.155  0.172  1.0
  F  F24  1  0.762  0.403  0.358  1.0
  F  F25  1  0.238  0.597  0.642  1.0
  F  F26  1  0.761  0.015  0.358  1.0
  F  F27  1  0.239  0.985  0.642  1.0
[/CIF]
.