The material described by RbNa2P3(HO2)6 crystallizes in the triclinic P-1 space group. Rb(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(6), one O(8), and two equivalent O(9) atoms. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded to one O(1), one O(10), one O(11), one O(12), one O(7), and one O(9) atom to form NaO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, and  a cornercorner with one P(3)O4 tetrahedra. In the second Na site, Na(2) is bonded in a 6-coordinate geometry to one O(10), one O(12), one O(3), one O(8), and two equivalent O(6) atoms. There are three inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form PO4 tetrahedra that share  a cornercorner with one Na(1)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra, and  a cornercorner with one P(3)O4 tetrahedra. The corner-sharing octahedral tilt angles are 56°. In the second P site, P(2) is bonded to one O(3), one O(5), one O(6), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one Na(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra, and  a cornercorner with one P(3)O4 tetrahedra. The corner-sharing octahedral tilt angles are 56°. In the third P site, P(3) is bonded to one O(4), one O(5), one O(8), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Na(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra, and  a cornercorner with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 50°. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(10) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(10) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(11) and one O(7) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(11) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(12) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(12) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a 1-coordinate geometry to one Rb(1), one Na(1), and one P(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Rb(1) and one P(1) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Na(2), one P(1), and one P(2) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one P(1) and one P(3) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one P(2) and one P(3) atom. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to one Rb(1), two equivalent Na(2), and one P(2) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one Na(1), one P(2), and one H(3) atom. In the eighth O site, O(8) is bonded in a 1-coordinate geometry to one Rb(1), one Na(2), and one P(3) atom. In the ninth O site, O(9) is bonded in a 1-coordinate geometry to two equivalent Rb(1), one Na(1), and one P(3) atom. In the tenth O site, O(10) is bonded in a distorted water-like geometry to one Na(1), one Na(2), one H(1), and one H(2) atom. In the eleventh O site, O(11) is bonded in a distorted water-like geometry to one Na(1), one H(3), and one H(4) atom. In the twelfth O site, O(12) is bonded in a distorted water-like geometry to one Na(1), one Na(2), one H(5), and one H(6) atom. is represented by the CIF card [CIF]
data_RbNa2P3(HO2)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.637
_cell_length_b   8.806
_cell_length_c   9.868
_cell_angle_alpha   65.997
_cell_angle_beta   84.583
_cell_angle_gamma   77.756
_symmetry_Int_Tables_number   1
_cell_volume   592.418
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.754  0.853  0.620  1.0
  Rb  Rb1  1  0.246  0.147  0.380  1.0
  Na  Na2  1  0.470  0.222  0.714  1.0
  Na  Na3  1  0.530  0.778  0.286  1.0
  Na  Na4  1  0.852  0.527  0.141  1.0
  Na  Na5  1  0.148  0.473  0.859  1.0
  P  P6  1  0.927  0.138  0.757  1.0
  P  P7  1  0.073  0.862  0.243  1.0
  P  P8  1  0.258  0.619  0.118  1.0
  P  P9  1  0.742  0.381  0.882  1.0
  P  P10  1  0.755  0.128  0.200  1.0
  P  P11  1  0.245  0.872  0.800  1.0
  H  H12  1  0.715  0.902  0.970  1.0
  H  H13  1  0.285  0.098  0.030  1.0
  H  H14  1  0.569  0.794  0.993  1.0
  H  H15  1  0.431  0.206  0.007  1.0
  H  H16  1  0.487  0.397  0.387  1.0
  H  H17  1  0.513  0.603  0.613  1.0
  H  H18  1  0.656  0.259  0.404  1.0
  H  H19  1  0.344  0.741  0.596  1.0
  H  H20  1  0.817  0.443  0.461  1.0
  H  H21  1  0.183  0.557  0.539  1.0
  H  H22  1  0.880  0.618  0.401  1.0
  H  H23  1  0.120  0.382  0.599  1.0
  O  O24  1  0.238  0.938  0.211  1.0
  O  O25  1  0.762  0.062  0.789  1.0
  O  O26  1  0.017  0.769  0.401  1.0
  O  O27  1  0.983  0.231  0.599  1.0
  O  O28  1  0.916  0.262  0.844  1.0
  O  O29  1  0.084  0.738  0.156  1.0
  O  O30  1  0.909  0.004  0.148  1.0
  O  O31  1  0.091  0.996  0.852  1.0
  O  O32  1  0.666  0.252  0.038  1.0
  O  O33  1  0.334  0.748  0.962  1.0
  O  O34  1  0.181  0.488  0.094  1.0
  O  O35  1  0.819  0.512  0.906  1.0
  O  O36  1  0.403  0.569  0.229  1.0
  O  O37  1  0.597  0.431  0.771  1.0
  O  O38  1  0.839  0.226  0.263  1.0
  O  O39  1  0.161  0.774  0.737  1.0
  O  O40  1  0.385  0.970  0.710  1.0
  O  O41  1  0.615  0.030  0.290  1.0
  O  O42  1  0.665  0.806  0.045  1.0
  O  O43  1  0.335  0.194  0.955  1.0
  O  O44  1  0.449  0.711  0.539  1.0
  O  O45  1  0.551  0.289  0.461  1.0
  O  O46  1  0.796  0.557  0.382  1.0
  O  O47  1  0.204  0.443  0.618  1.0
[/CIF]
.
The material described by RbNa2P3(HO2)6 crystallizes in the triclinic P-1 space group. Rb(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(6), one O(8), and two equivalent O(9) atoms. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded to one O(1), one O(10), one O(11), one O(12), one O(7), and one O(9) atom to form NaO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, and  a cornercorner with one P(3)O4 tetrahedra. In the second Na site, Na(2) is bonded in a 6-coordinate geometry to one O(10), one O(12), one O(3), one O(8), and two equivalent O(6) atoms. There are three inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form PO4 tetrahedra that share  a cornercorner with one Na(1)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra, and  a cornercorner with one P(3)O4 tetrahedra. The corner-sharing octahedral tilt angles are 56°. In the second P site, P(2) is bonded to one O(3), one O(5), one O(6), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one Na(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra, and  a cornercorner with one P(3)O4 tetrahedra. The corner-sharing octahedral tilt angles are 56°. In the third P site, P(3) is bonded to one O(4), one O(5), one O(8), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Na(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra, and  a cornercorner with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 50°. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(10) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(10) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(11) and one O(7) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(11) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(12) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(12) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a 1-coordinate geometry to one Rb(1), one Na(1), and one P(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Rb(1) and one P(1) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Na(2), one P(1), and one P(2) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one P(1) and one P(3) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one P(2) and one P(3) atom. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to one Rb(1), two equivalent Na(2), and one P(2) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one Na(1), one P(2), and one H(3) atom. In the eighth O site, O(8) is bonded in a 1-coordinate geometry to one Rb(1), one Na(2), and one P(3) atom. In the ninth O site, O(9) is bonded in a 1-coordinate geometry to two equivalent Rb(1), one Na(1), and one P(3) atom. In the tenth O site, O(10) is bonded in a distorted water-like geometry to one Na(1), one Na(2), one H(1), and one H(2) atom. In the eleventh O site, O(11) is bonded in a distorted water-like geometry to one Na(1), one H(3), and one H(4) atom. In the twelfth O site, O(12) is bonded in a distorted water-like geometry to one Na(1), one Na(2), one H(5), and one H(6) atom. is represented by the CIF card [CIF]
data_RbNa2P3(HO2)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.637
_cell_length_b   8.806
_cell_length_c   9.868
_cell_angle_alpha   65.997
_cell_angle_beta   84.583
_cell_angle_gamma   77.756
_symmetry_Int_Tables_number   1
_cell_volume   592.418
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.754  0.853  0.620  1.0
  Rb  Rb1  1  0.246  0.147  0.380  1.0
  Na  Na2  1  0.470  0.222  0.714  1.0
  Na  Na3  1  0.530  0.778  0.286  1.0
  Na  Na4  1  0.852  0.527  0.141  1.0
  Na  Na5  1  0.148  0.473  0.859  1.0
  P  P6  1  0.927  0.138  0.757  1.0
  P  P7  1  0.073  0.862  0.243  1.0
  P  P8  1  0.258  0.619  0.118  1.0
  P  P9  1  0.742  0.381  0.882  1.0
  P  P10  1  0.755  0.128  0.200  1.0
  P  P11  1  0.245  0.872  0.800  1.0
  H  H12  1  0.715  0.902  0.970  1.0
  H  H13  1  0.285  0.098  0.030  1.0
  H  H14  1  0.569  0.794  0.993  1.0
  H  H15  1  0.431  0.206  0.007  1.0
  H  H16  1  0.487  0.397  0.387  1.0
  H  H17  1  0.513  0.603  0.613  1.0
  H  H18  1  0.656  0.259  0.404  1.0
  H  H19  1  0.344  0.741  0.596  1.0
  H  H20  1  0.817  0.443  0.461  1.0
  H  H21  1  0.183  0.557  0.539  1.0
  H  H22  1  0.880  0.618  0.401  1.0
  H  H23  1  0.120  0.382  0.599  1.0
  O  O24  1  0.238  0.938  0.211  1.0
  O  O25  1  0.762  0.062  0.789  1.0
  O  O26  1  0.017  0.769  0.401  1.0
  O  O27  1  0.983  0.231  0.599  1.0
  O  O28  1  0.916  0.262  0.844  1.0
  O  O29  1  0.084  0.738  0.156  1.0
  O  O30  1  0.909  0.004  0.148  1.0
  O  O31  1  0.091  0.996  0.852  1.0
  O  O32  1  0.666  0.252  0.038  1.0
  O  O33  1  0.334  0.748  0.962  1.0
  O  O34  1  0.181  0.488  0.094  1.0
  O  O35  1  0.819  0.512  0.906  1.0
  O  O36  1  0.403  0.569  0.229  1.0
  O  O37  1  0.597  0.431  0.771  1.0
  O  O38  1  0.839  0.226  0.263  1.0
  O  O39  1  0.161  0.774  0.737  1.0
  O  O40  1  0.385  0.970  0.710  1.0
  O  O41  1  0.615  0.030  0.290  1.0
  O  O42  1  0.665  0.806  0.045  1.0
  O  O43  1  0.335  0.194  0.955  1.0
  O  O44  1  0.449  0.711  0.539  1.0
  O  O45  1  0.551  0.289  0.461  1.0
  O  O46  1  0.796  0.557  0.382  1.0
  O  O47  1  0.204  0.443  0.618  1.0
[/CIF]
.